stec misc spill pond2493 082809 coc9833

09081449Certificate of Analysis Number:

Spectra Energy Transmission, LLC

HOUSTON LABORATORY8880 INTERCHANGE DRIVE

HOUSTON, TX 77054(713) 660-0901


5400 Westheimer Court

HoustonTX77056-

Joe Bauer

Date Reported: 8/31/2009

Project Name: Spectra Energy

PO Number: Agreement No. ENV-0506

Site: Steckman Ridge

State: Pennsylvania

State Cert. No.: 68-03598

Report To:

Site Address:

(713) 627-5400ph: fax:

This Report Contains A Total Of 20 Pages

Excluding This Page, Chain Of Custody

Any Attachments

And

Date

8/31/2009

Test results meet all requirements of NELAC, unless specified in the narrative.

Case Narrative for:




HOUSTON, TX 77054(713) 660-0901



HoustonTX77056-

Joe Bauer





State: Pennsylvania


Report To:

Site Address:

(713) 627-5400ph: fax:

I. SAMPLE RECEIPT:

All samples were received intact. The internal ice chest temperatures were measured on receipt and are recorded on the attached Sample Receipt Checklist.

Samples for COC ARF 9833 were received at a temperature of 15.2 and 15.9 degrees Celsius.

Collection date and times were missing from the Chain of Custody; however, were noted on the sample containers.

Please note, SPL received two samples for COC ARF 9833 IDs: "Pond-082809-1" and "Pond-082809-2", per client request via e-mail on August 31, 2009 samples were composited per analyses and treated as one sample and logged in as sample ID "MISC Pond-2493".

Containers for the RCRA Metals by Method SW6010B were received unpreserved and were preserved upon receipt with 3 milliliters of Nitric acid Lot # 072709-2EE.

Original Chain of Custody requested piano analyses by Method GPA2186; however, due to sample matrix a piano analyses was not possible. Sample was logged in as per revised Chain of Custody for Oil and Grease analyses by Method 1664A in addition to existing analyses per client request via e-mail on August 31, 2009.

Client was notified of the nonconformaces mentioned above via Sample Receipt Confirmation e-mail on August 31, 2009 and per client request via e-mail on August 31, 2009, SPL continued with the analyses requested. Please see attached sample receipt checklist for any further nonconformance issues.

II: ANALYSES AND EXCEPTIONS:

N-Hexane Extractable Material (1664A):

Due to limited sample volume a Matrix Spike Duplicate (MSD) was not extracted with Batch ID R282534. A Matrix Spike (MS) as well as a Laboratory Control Sample / Laboratory Control Sample Duplicate (LCS/LCSD) were extracted with the analytical batch and serve as the batch quality control (QC). Spike recoveries for the MS, LCS and LCSD were within QC limits.

PCB (E608):

Due to limited sample volume, a Matrix Spike (MS) or Matrix Spike Duplicate (MSD) was not extracted with Batch ID: (93407) for the PCBs analysis by EPA Method E608. A Laboratory Control Sample (LCS) and a Laboratory Control Sample Duplicate (LCSD) were extracted with the analytical batch and serve as the batch quality control (QC). The LCS and LCSD recovered acceptably and precision criteria were met.

III. GENERAL REPORTING COMMENTS:

Results are reported on a wet weight basis unless dry-weight correction is denoted in the units field on the analytical report (" mg\kg-dry " or " ug\kg-dry " ).

DateSylvia Grice

8/31/2009

Senior Project Manager

09081449 Page 1


Case Narrative for:




HOUSTON, TX 77054(713) 660-0901

Matrix spike (MS) and matrix spike duplicate (MSD) samples are chosen and tested at random from an analytical batch of "like" matrix to check for possible matrix effect. The MS and MSD will provide site specific matrix data only for those samples which are spiked by the laboratory. Since the MS and MSD are chosen at random from an analytical batch, the sample chosen for spike purposes may or may not have been a sample submitted in this sample delivery group. The validity of the analytical procedures for which data is reported in this analytical report is determined by the Laboratory Control Sample (LCS) and the Method Blank (MB). The Laboratory Control Sample (LCS) and the Method Blank (MB) are processed with the samples and the MS/MSD to ensure method criteria are achieved throughout the entire analytical process.

Some of the percent recoveries and RPD's on the QC report for the MS/MSD may be different than the calculated recoveries and RPD's using the sample result and the MS/MSD results that appear on the report because, the actual raw result is used to perform the calculations for percent recovery and RPD.

Any other exceptions associated with this report will be footnoted in the analytical result page(s) or the quality control summary page(s).

Please do not hesitate to contact us if you have any questions or comments pertaining to this data report. Please reference the above Certificate of Analysis Number.

This report shall not be reproduced except in full, without the written approval of the laboratory. The reported results are only representative of the samples submitted for testing.

SPL, Inc. is pleased to be of service to you. We anticipate working with you in fulfilling all your current and future analytical needs.

I certify that this data package is in compliance with the terms and conditions of the contract, both technically and for completeness, for other than the conditions detailed above. Release of the data contained in this hardcopy data package has been authorized by the Laboratory Manager or by his designee, as verified by the following signature.

DateSylvia Grice

8/31/2009


09081449 Page 2





HOUSTON, TX 77054(713) 660-0901



HoustonTX77056-

(713) 627-5400

Joe Bauer





State: Pennsylvania


Report To:

Site Address:

(713) 989-8347ph: fax:

Fax To:

Client Sample ID Lab Sample ID Date Collected Date Received COC IDMatrix HOLD

Field Sampler: Mary Velasquez

09081449-01 8/31/2009 9:00:00 AMMISC Pond-2493 8/28/2009 12:30:00 PMAqueous 9833

Date

Laboratory Director

Quality Assurance Officer

Sylvia Grice

09081449 Page 3

8/31/2009

8/31/2009 9:03:49 PM


Kesavalu M. Bagawandoss Ph.D., J.D.

Ted Yen

Client Sample ID:MISC Pond-2493

Analyses/Method Result Date AnalyzedRep.Limit

SPL Sample ID: 09081449-01

Dil. Factor AnalystQUAL Seq. #

Collected: 08/28/2009 12:30



HOUSTON, TX 77054(713) 660-0901

MERCURY, TOTAL SW7470A mg/LUnits:MCLMercury 08/31/09 15:340.0002 1ND F_S 5184997

Prep Method Prep Date Prep Initials Prep Factor08/31/2009 12:50 F_SSW7470A 1.00

METALS BY METHOD 6010B, TOTAL SW6010B mg/LUnits:MCLArsenic 08/31/09 20:460.005 1ND AB1 5185298Barium 08/31/09 20:460.005 10.0791 AB1 5185298Cadmium 08/31/09 20:460.005 1ND AB1 5185298Chromium 08/31/09 20:460.005 1ND AB1 5185298Lead 08/31/09 20:460.005 1ND AB1 5185298Selenium 08/31/09 20:460.01 1ND AB1 5185298Silver 08/31/09 20:460.005 1ND AB1 5185298

Prep Method Prep Date Prep Initials Prep Factor08/31/2009 13:30 R_VSW3010A 1.00

N-HEXANE EXTRACTABLE MATERIAL 1664A mg/LUnits:MCLn-Hexane Extractable Material 08/31/09 16:155 19.3 KAM 5185091

Prep Method Prep Date Prep Initials Prep Factor08/31/2009 14:00 1.00

PESTICIDE/PCBS E608 ug/LUnits:MCLAroclor 1016 08/31/09 17:150.5 1ND RLR 5185209Aroclor 1221 08/31/09 17:150.5 1ND RLR 5185209Aroclor 1232 08/31/09 17:150.5 1ND RLR 5185209Aroclor 1242 08/31/09 17:150.5 1ND RLR 5185209Aroclor 1248 08/31/09 17:150.5 1ND RLR 5185209Aroclor 1254 08/31/09 17:150.5 1ND RLR 5185209Aroclor 1260 08/31/09 17:150.5 1ND RLR 5185209Total PCB 08/31/09 17:150.5 1ND RLR 5185209 Surr: Decachlorobiphenyl 08/31/09 17:15% 14-159 170.8 RLR 5185209 Surr: Tetrachloro-m-xylene 08/31/09 17:15% 48-120 177.7 RLR 5185209

Prep Method Prep Date Prep Initials Prep Factor08/31/2009 13:39 N_ME608 1.00

Qualifiers: B/V - Analyte detected in the associated Method BlankND/U - Not Detected at the Reporting Limit

* - Surrogate Recovery Outside Advisable QC Limits

>MCL - Result Over Maximum Contamination Limit(MCL)D - Surrogate Recovery Unreportable due to Dilution

8/31/2009 9:03:57 PM

J - Estimated Value between MDL and PQLMI - Matrix Interference

09081449 Page 4TNTC - Too numerous to countE - Estimated Value exceeds calibration curve





Collected: 08/28/2009 12:30



HOUSTON, TX 77054(713) 660-0901

VOLATILE ORGANICS BY METHOD 8260B SW8260B ug/LUnits:MCL1,1,1,2-Tetrachloroethane 08/31/09 15:041 1ND E_G 51848021,1,1-Trichloroethane 08/31/09 15:041 1ND E_G 51848021,1,2,2-Tetrachloroethane 08/31/09 15:041 1ND E_G 51848021,1,2-Trichloroethane 08/31/09 15:041 1ND E_G 51848021,1-Dichloroethane 08/31/09 15:041 1ND E_G 51848021,1-Dichloroethene 08/31/09 15:041 1ND E_G 51848021,1-Dichloropropene 08/31/09 15:041 1ND E_G 51848021,2,3-Trichlorobenzene 08/31/09 15:041 1ND E_G 51848021,2,3-Trichloropropane 08/31/09 15:041 1ND E_G 51848021,2,4-Trichlorobenzene 08/31/09 15:041 1ND E_G 51848021,2,4-Trimethylbenzene 08/31/09 15:041 1ND E_G 51848021,2-Dibromo-3-chloropropane 08/31/09 15:045 1ND E_G 51848021,2-Dibromoethane 08/31/09 15:041 1ND E_G 51848021,2-Dichlorobenzene 08/31/09 15:041 1ND E_G 51848021,2-Dichloroethane 08/31/09 15:041 1ND E_G 51848021,2-Dichloropropane 08/31/09 15:041 1ND E_G 51848021,3,5-Trimethylbenzene 08/31/09 15:041 1ND E_G 51848021,3-Dichlorobenzene 08/31/09 15:041 1ND E_G 51848021,3-Dichloropropane 08/31/09 15:041 1ND E_G 51848021,4-Dichlorobenzene 08/31/09 15:041 1ND E_G 51848022,2-Dichloropropane 08/31/09 15:041 1ND E_G 51848022-Chlorotoluene 08/31/09 15:041 1ND E_G 51848024-Chlorotoluene 08/31/09 15:041 1ND E_G 51848024-Isopropyltoluene 08/31/09 15:041 1ND E_G 5184802Benzene 08/31/09 15:041 1ND E_G 5184802Bromobenzene 08/31/09 15:041 1ND E_G 5184802Bromochloromethane 08/31/09 15:041 1ND E_G 5184802Bromodichloromethane 08/31/09 15:041 1ND E_G 5184802Bromoform 08/31/09 15:041 1ND E_G 5184802Bromomethane 08/31/09 15:041 1ND E_G 5184802Carbon tetrachloride 08/31/09 15:041 1ND E_G 5184802Chlorobenzene 08/31/09 15:041 1ND E_G 5184802Chloroethane 08/31/09 15:041 1ND E_G 5184802Chloroform 08/31/09 15:041 1ND E_G 5184802Chloromethane 08/31/09 15:041 1ND E_G 5184802Dibromochloromethane 08/31/09 15:041 1ND E_G 5184802Dibromomethane 08/31/09 15:041 1ND E_G 5184802Dichlorodifluoromethane 08/31/09 15:041 1ND E_G 5184802Ethylbenzene 08/31/09 15:041 1ND E_G 5184802




8/31/2009 9:03:58 PM







Collected: 08/28/2009 12:30



HOUSTON, TX 77054(713) 660-0901

Hexachlorobutadiene 08/31/09 15:041 1ND E_G 5184802Isopropylbenzene 08/31/09 15:041 1ND E_G 5184802Methyl tert-butyl ether 08/31/09 15:041 1ND E_G 5184802Methylene chloride 08/31/09 15:041 1ND E_G 5184802Naphthalene 08/31/09 15:041 1ND E_G 5184802n-Butylbenzene 08/31/09 15:041 1ND E_G 5184802n-Propylbenzene 08/31/09 15:041 1ND E_G 5184802sec-Butylbenzene 08/31/09 15:041 1ND E_G 5184802Styrene 08/31/09 15:041 1ND E_G 5184802tert-Butylbenzene 08/31/09 15:041 1ND E_G 5184802Tetrachloroethene 08/31/09 15:041 1ND E_G 5184802Toluene 08/31/09 15:041 1ND E_G 5184802Trichloroethene 08/31/09 15:041 1ND E_G 5184802Trichlorofluoromethane 08/31/09 15:041 1ND E_G 5184802Vinyl chloride 08/31/09 15:041 1ND E_G 5184802cis-1,2-Dichloroethene 08/31/09 15:041 1ND E_G 5184802cis-1,3-Dichloropropene 08/31/09 15:041 1ND E_G 5184802m,p-Xylene 08/31/09 15:042 1ND E_G 5184802o-Xylene 08/31/09 15:041 1ND E_G 5184802trans-1,2-Dichloroethene 08/31/09 15:041 1ND E_G 5184802trans-1,3-Dichloropropene 08/31/09 15:041 1ND E_G 5184802Xylenes,Total 08/31/09 15:041 1ND E_G 5184802 Surr: 1,2-Dichloroethane-d4 08/31/09 15:04% 78-116 1109 E_G 5184802 Surr: 4-Bromofluorobenzene 08/31/09 15:04% 74-125 1110 E_G 5184802 Surr: Toluene-d8 08/31/09 15:04% 82-118 1102 E_G 5184802




8/31/2009 9:03:58 PM



Quality Control Documentation

8/31/2009 9:03:59 PM

09081449 Page 7

Quality Control Report

Spectra Energy Transmission, LLCSpectra Energy

Lab Batch ID: R282534WorkOrder: 09081449

Method: 1664AAnalysis: N-Hexane Extractable Material


HOUSTON, TX 77054(713) 660-0901

Analyte LCS Spike Added

LCS Result

LCS Percent Recovery

Lower Limit

Upper Limit

Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD)

LCSD Spike Added

LCSD Result

LCSD Percent Recovery

RPD RPD Limit

Analysis Date: 08/31/2009 16:15Preparation Date: 08/31/2009 14:00

Analyst: KAMPrep By: Method:

RunID: EX_090831D-5185087 Units: mg/L

n-Hexane Extractable Material 40.0 40.0 100 78 11440.0 39.8 99.5 0.5 18

Analyte Spike Added

Matrix Spike (MS)

Sample Result Low Limit

High Limit

MS Result MS % Recovery

Sample Spiked: 09081447-01


Analyst: KAMPrep By: Method:


n-Hexane Extractable Material 40 78 114ND 40.0 100

Analyte Result Rep Limit

Method Blank


Analyst: KAM


Prep By: Method:

n-Hexane Extractable Material 5.0ND

Samples in Analytical Batch:

Lab Sample ID Client Sample ID09081449-01E MISC Pond-2493


* - Recovery Outside Advisable QC LimitsD - Recovery Unreportable due to Dilution

8/31/2009 9:04:00 PM

J - Estimated value between MDL and PQL

MI - Matrix Interference

QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.

09081449 Page 8N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.TNTC - Too numerous to count

E - Estimated Value exceeds calibration curve



Lab Batch ID: 93407WorkOrder: 09081449

Method: E608Analysis: Pesticide/PCBs


HOUSTON, TX 77054(713) 660-0901

Analyte LCS Spike Added

LCS Result

LCS Percent Recovery

Lower Limit

Upper Limit

Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD)

LCSD Spike Added

LCSD Result

LCSD Percent Recovery

RPD RPD Limit


Analyst: RLRPrep By: N_M Method: E608

RunID: HP_A_090831C-5185206 Units: ug/L

Aroclor 1016 10.0 9.43 94.3 50 11410.0 9.66 96.6 2.4 30Aroclor 1260 10.0 9.85 98.5 8 12710.0 9.66 96.6 1.9 30 Surr: Decachlorobiphenyl 1.00 0.987 98.7 14 1591.00 1.00 100 1.8 30 Surr: Tetrachloro-m-xylene 1.00 0.931 93.1 48 1201.00 0.946 94.6 1.7 30


Method Blank


Analyst: RLR

RunID: HP_A_090831C-5185210 Units: ug/L

Prep By: N_M Method: E608

Aroclor 1016 0.50NDAroclor 1221 0.50NDAroclor 1232 0.50NDAroclor 1242 0.50NDAroclor 1248 0.50NDAroclor 1254 0.50NDAroclor 1260 0.50NDTotal PCB 0.50ND Surr: Decachlorobiphenyl 14-15997.1 Surr: Tetrachloro-m-xylene 48-12089.1


Lab Sample ID Client Sample ID09081449-01D MISC Pond-2493



8/31/2009 9:04:01 PM









Method: SW7470AAnalysis: Mercury, Total


HOUSTON, TX 77054(713) 660-0901

Analyte MS Spike Added

MSDResult

MSD % Recovery

RPD RPD Limit

Matrix Spike (MS) / Matrix Spike Duplicate (MSD)

SampleResult

Low Limit

High Limit

MSResult

MS % Recovery


MSD Spike Added


Analyst: F_SPrep By: F_S Method: SW7470A

RunID: HGLD_090831A-5184998 Units: mg/L

Mercury 0.002 0.001863 93.15 75 125ND 203.6700.001933 96.63 0.002

Analyte Spike Added

Result Percent Recovery

Lower Limit

Upper Limit

Laboratory Control Sample (LCS)


Analyst: F_SPrep By: F_S Method: SW7470A


Mercury 0.002000 0.002002 100.1 80 120


Method Blank


Analyst: F_S


Prep By: F_S Method: SW7470A

Mercury 0.0002ND


Lab Sample ID Client Sample ID09081449-01C MISC Pond-2493



8/31/2009 9:04:01 PM









Method: SW6010BAnalysis: Metals by Method 6010B, Total


HOUSTON, TX 77054(713) 660-0901


MSDResult

MSD % Recovery

RPD RPD Limit


SampleResult

Low Limit

High Limit

MSResult

MS % Recovery


MSD Spike Added


Analyst: AB1Prep By: R_V Method: SW3010A

RunID: ICP2_090831B-5185293 Units: mg/L

Arsenic 0.1 0.1139 113.9 75 125ND 203.2820.1177 117.7 0.1

Analyte Spike Added


Lower Limit

Upper Limit





Arsenic 0.1000 0.09670 96.70 80 120Barium 0.1000 0.1003 100.3 80 120Cadmium 0.1000 0.09890 98.90 80 120Chromium 0.1000 0.09920 99.20 80 120Lead 0.1000 0.1012 101.2 80 120Selenium 0.1000 0.09820 98.20 80 120Silver 0.1000 0.09970 99.70 80 120


Method Blank


Analyst: AB1


Prep By: R_V Method: SW3010A

Arsenic 0.005NDBarium 0.005NDCadmium 0.005NDChromium 0.005NDLead 0.005NDSelenium 0.01NDSilver 0.005ND


Lab Sample ID Client Sample ID09081449-01C MISC Pond-2493



8/31/2009 9:04:01 PM









Method: SW6010BAnalysis: Metals by Method 6010B, Total


HOUSTON, TX 77054(713) 660-0901


MSDResult

MSD % Recovery

RPD RPD Limit


SampleResult

Low Limit

High Limit

MSResult

MS % Recovery


MSD Spike Added




Barium 0.1 0.1326 101.8 75 1250.03080 201.1250.1341 103.3 0.1Cadmium 0.1 0.09290 92.90 75 125ND 201.6020.09440 94.40 0.1Chromium 0.1 0.09460 94.60 75 125ND 200.73720.09530 95.30 0.1Lead 0.1 0.08930 87.30 75 125ND 200.33540.08960 87.60 0.1Selenium 0.1 0.1352 117.1 75 1250.01810 202.2670.1383 120.2 0.1Silver 0.1 0.1216 121.6 75 125ND 201.3070.1232 123.2 0.1



8/31/2009 9:04:01 PM









Method: SW8260BAnalysis: Volatile Organics by Method 8260B


HOUSTON, TX 77054(713) 660-0901


Method Blank

Analysis Date: 08/31/2009 11:07 Analyst: E_G

RunID: L_090831A-5184798 Units: ug/L

1,1,1,2-Tetrachloroethane 1.0ND1,1,1-Trichloroethane 1.0ND1,1,2,2-Tetrachloroethane 1.0ND1,1,2-Trichloroethane 1.0ND1,1-Dichloroethane 1.0ND1,1-Dichloroethene 1.0ND1,1-Dichloropropene 1.0ND1,2,3-Trichlorobenzene 1.0ND1,2,3-Trichloropropane 1.0ND1,2,4-Trichlorobenzene 1.0ND1,2,4-Trimethylbenzene 1.0ND1,2-Dibromo-3-chloropropane 5.0ND1,2-Dibromoethane 1.0ND1,2-Dichlorobenzene 1.0ND1,2-Dichloroethane 1.0ND1,2-Dichloropropane 1.0ND1,3,5-Trimethylbenzene 1.0ND1,3-Dichlorobenzene 1.0ND1,3-Dichloropropane 1.0ND1,4-Dichlorobenzene 1.0ND2,2-Dichloropropane 1.0ND2-Chlorotoluene 1.0ND4-Chlorotoluene 1.0ND4-Isopropyltoluene 1.0NDBenzene 1.0NDBromobenzene 1.0NDBromochloromethane 1.0NDBromodichloromethane 1.0NDBromoform 1.0NDBromomethane 1.0NDCarbon tetrachloride 1.0NDChlorobenzene 1.0NDChloroethane 1.0NDChloroform 1.0NDChloromethane 1.0NDDibromochloromethane 1.0NDDibromomethane 1.0NDDichlorodifluoromethane 1.0NDEthylbenzene 1.0NDHexachlorobutadiene 1.0NDIsopropylbenzene 1.0NDMethyl tert-butyl ether 1.0NDMethylene chloride 1.0NDNaphthalene 1.0NDn-Butylbenzene 1.0NDn-Propylbenzene 1.0ND


Lab Sample ID Client Sample ID09081449-01B MISC Pond-2493



8/31/2009 9:04:01 PM











HOUSTON, TX 77054(713) 660-0901

Analyte Spike Added


Lower Limit

Upper Limit


Analysis Date: 08/31/2009 9:33 Analyst: E_GRunID: L_090831A-5184797 Units: ug/L

1,1,1,2-Tetrachloroethane 20.0 20.3 102 71 1281,1,1-Trichloroethane 20.0 24.5 122 61 1351,1,2,2-Tetrachloroethane 20.0 23.3 117 60 1331,1,2-Trichloroethane 20.0 20.0 99.9 77 1271,1-Dichloroethane 20.0 22.8 114 68 1321,1-Dichloroethene 20.0 24.6 123 65 1341,1-Dichloropropene 20.0 19.1 95.6 68 1261,2,3-Trichlorobenzene 20.0 18.0 90.2 36 1541,2,3-Trichloropropane 20.0 23.7 118 38 1531,2,4-Trichlorobenzene 20.0 19.3 96.4 69 1441,2,4-Trimethylbenzene 20.0 20.0 100 64 128


Method Blank

Analysis Date: 08/31/2009 11:07 Analyst: E_G

RunID: L_090831A-5184798 Units: ug/L

sec-Butylbenzene 1.0NDStyrene 1.0NDtert-Butylbenzene 1.0NDTetrachloroethene 1.0NDToluene 1.0NDTrichloroethene 1.0NDTrichlorofluoromethane 1.0NDVinyl chloride 1.0NDcis-1,2-Dichloroethene 1.0NDcis-1,3-Dichloropropene 1.0NDm,p-Xylene 2.0NDo-Xylene 1.0NDtrans-1,2-Dichloroethene 1.0NDtrans-1,3-Dichloropropene 1.0NDXylenes,Total 1.0ND Surr: 1,2-Dichloroethane-d4 78-116106.5 Surr: 4-Bromofluorobenzene 74-125107.0 Surr: Toluene-d8 82-118101.1



8/31/2009 9:04:01 PM











HOUSTON, TX 77054(713) 660-0901

Analyte Spike Added


Lower Limit

Upper Limit



1,2-Dibromo-3-chloropropane 20.0 22.8 114 44 1411,2-Dibromoethane 20.0 19.5 97.6 75 1241,2-Dichlorobenzene 20.0 20.8 104 68 1241,2-Dichloroethane 20.0 19.5 97.7 61 1381,2-Dichloropropane 20.0 20.9 105 76 1231,3,5-Trimethylbenzene 20.0 19.8 99.0 61 1271,3-Dichlorobenzene 20.0 20.1 100 68 1271,3-Dichloropropane 20.0 18.2 90.8 76 1251,4-Dichlorobenzene 20.0 19.7 98.4 68 1242,2-Dichloropropane 20.0 24.3 122 42 1422-Chlorotoluene 20.0 19.0 95.0 64 1324-Chlorotoluene 20.0 19.2 95.9 61 1324-Isopropyltoluene 20.0 20.6 103 63 136Benzene 20.0 20.3 101 74 123Bromobenzene 20.0 19.2 95.9 68 125Bromochloromethane 20.0 21.4 107 71 124Bromodichloromethane 20.0 21.1 105 72 128Bromoform 20.0 18.8 94.1 60 128Bromomethane 20.0 19.2 95.9 53 130Carbon tetrachloride 20.0 26.2 131 59 142Chlorobenzene 20.0 18.5 92.3 75 125Chloroethane 20.0 20.8 104 60 134Chloroform 20.0 21.8 109 71 127Chloromethane 20.0 23.0 115 50 139Dibromochloromethane 20.0 18.6 93.1 65 130Dibromomethane 20.0 23.0 115 79 124Dichlorodifluoromethane 20.0 24.2 121 22 162Ethylbenzene 20.0 18.7 93.3 72 127Hexachlorobutadiene 20.0 21.2 106 45 152Isopropylbenzene 20.0 18.3 91.6 58 130Methyl tert-butyl ether 40.0 47.7 119 63 123Methylene chloride 20.0 23.1 116 61 135Naphthalene 20.0 19.4 97.0 33 148n-Butylbenzene 20.0 21.7 108 62 136



8/31/2009 9:04:02 PM











HOUSTON, TX 77054(713) 660-0901


MSDResult

MSD % Recovery

RPD RPD Limit


SampleResult

Low Limit

High Limit

MSResult

MS % Recovery


MSD Spike Added


1,1,1,2-Tetrachloroethane 20 16.1 80.6 68 124ND 200.92016.3 81.4 201,1,1-Trichloroethane 20 17.6 88.2 69 123ND 200.21517.7 88.4 201,1,2,2-Tetrachloroethane 20 18.0 89.9 69 130ND 202.1918.4 91.9 20

Analyte Spike Added


Lower Limit

Upper Limit



n-Propylbenzene 20.0 18.9 94.5 57 131sec-Butylbenzene 20.0 20.4 102 63 131Styrene 20.0 19.4 96.8 69 120tert-Butylbenzene 20.0 20.5 102 59 131Tetrachloroethene 20.0 19.1 95.5 45 173Toluene 20.0 16.4 82.2 74 126Trichloroethene 20.0 20.7 104 79 131Trichlorofluoromethane 20.0 28.9 144 49 153Vinyl chloride 20.0 21.8 109 51 148cis-1,2-Dichloroethene 20.0 21.1 106 71 128cis-1,3-Dichloropropene 20.0 19.6 97.8 67 128m,p-Xylene 40.0 39.2 98.0 71 129o-Xylene 20.0 20.7 104 74 130trans-1,2-Dichloroethene 20.0 22.3 111 66 128trans-1,3-Dichloropropene 20.0 19.3 96.4 60 128Xylenes,Total 60.0 59.9 99.9 71 130 Surr: 1,2-Dichloroethane-d4 50.0 55 110 78 116 Surr: 4-Bromofluorobenzene 50.0 57.2 114 74 125 Surr: Toluene-d8 50.0 47.5 95.0 82 118



8/31/2009 9:04:02 PM











HOUSTON, TX 77054(713) 660-0901


MSDResult

MSD % Recovery

RPD RPD Limit


SampleResult

Low Limit

High Limit

MSResult

MS % Recovery


MSD Spike Added


1,1,2-Trichloroethane 20 18.5 92.5 75 126ND 201.5718.2 91.1 201,1-Dichloroethane 20 15.7 78.4 65 129ND 201.0615.5 77.5 201,1-Dichloroethene 20 16.0 79.9 61 139ND 220.23815.9 79.7 201,1-Dichloropropene 20 16.1 80.3 69 121ND 203.3716.6 83.1 201,2,3-Trichlorobenzene 20 7.63 38.1 * 53 127ND 201.807.49 37.5 * 201,2,3-Trichloropropane 20 18.4 91.9 79 124ND 200.59518.3 91.4 201,2,4-Trichlorobenzene 20 12.3 61.3 58 118ND 203.7611.8 59.0 201,2,4-Trimethylbenzene 20 16.4 82.1 43 132ND 200.26216.5 82.3 201,2-Dibromo-3-chloropropane 20 17.5 87.5 46 131ND 200.43917.6 87.9 201,2-Dibromoethane 20 17.8 88.9 76 122ND 201.6617.5 87.4 201,2-Dichlorobenzene 20 17.3 86.6 74 110ND 200.45717.2 86.2 201,2-Dichloroethane 20 16.1 80.3 60 129ND 201.7215.8 78.9 201,2-Dichloropropane 20 17.6 88.2 76 116ND 201.1117.5 87.3 201,3,5-Trimethylbenzene 20 16.5 82.3 51 121ND 201.0816.6 83.2 201,3-Dichlorobenzene 20 16.7 83.3 71 110ND 200.72916.8 83.9 201,3-Dichloropropane 20 16.7 83.6 80 119ND 200.50416.6 83.2 201,4-Dichlorobenzene 20 16.4 81.8 69 110ND 200.72416.2 81.2 202,2-Dichloropropane 20 18.2 90.9 52 122ND 200.027518.2 91.0 202-Chlorotoluene 20 16.6 83.0 69 112ND 201.7816.9 84.5 204-Chlorotoluene 20 16.8 84.0 37 110ND 200.87716.9 84.7 204-Isopropyltoluene 20 16.2 81.2 65 116ND 200.20916.3 81.4 20Benzene 20 16.2 81.0 70 124ND 221.1416.4 81.9 20Bromobenzene 20 17.0 84.8 72 111ND 200.88316.8 84.0 20Bromochloromethane 20 16.7 83.7 73 126ND 201.8816.4 82.2 20Bromodichloromethane 20 16.9 84.5 68 125ND 204.9216.1 80.5 20Bromoform 20 13.3 66.3 44 132ND 203.3812.8 64.1 20Bromomethane 20 11.8 58.8 50 140ND 201.6412.0 59.8 20Carbon tetrachloride 20 17.0 85.0 66 126ND 201.3917.2 86.2 20Chlorobenzene 20 15.8 79.1 68 123ND 210.76815.9 79.7 20Chloroethane 20 12.7 63.7 59 134ND 201.1912.9 64.4 20Chloroform 20 16.5 82.5 68 127ND 200.012116.5 82.6 20Chloromethane 20 14.6 72.9 51 137ND 200.35614.6 73.1 20



8/31/2009 9:04:02 PM











HOUSTON, TX 77054(713) 660-0901


MSDResult

MSD % Recovery

RPD RPD Limit


SampleResult

Low Limit

High Limit

MSResult

MS % Recovery


MSD Spike Added


Dibromochloromethane 20 15.2 76.1 58 131ND 202.2314.9 74.4 20Dibromomethane 20 18.7 93.4 82 123ND 203.0518.1 90.6 20Dichlorodifluoromethane 20 12.3 61.4 35 143ND 204.1711.8 58.9 20Ethylbenzene 20 15.6 78.0 76 122ND 203.4716.2 80.8 20Hexachlorobutadiene 20 10.7 53.7 43 137ND 201.8110.9 54.6 20Isopropylbenzene 20 13.7 68.3 57 124ND 202.9114.1 70.3 20Methyl tert-butyl ether 40 36.2 90.6 10 200ND 203.7934.9 87.3 40Methylene chloride 20 15.3 76.4 70 134ND 203.1614.8 74.1 20Naphthalene 20 10.5 52.3 42 140ND 201.1210.3 51.7 20n-Butylbenzene 20 16.6 83.0 82 112ND 200.36716.7 83.4 20n-Propylbenzene 20 16.1 80.7 73 108ND 200.68616.2 81.2 20sec-Butylbenzene 20 16.5 82.4 76 110ND 200.52316.4 82.0 20Styrene 20 15.9 79.3 58 152ND 200.40915.9 79.6 20tert-Butylbenzene 20 16.5 82.5 66 120ND 200.53816.6 82.9 20Tetrachloroethene 20 17.1 85.4 71 130ND 204.7417.9 89.6 20Toluene 20 14.7 73.7 * 80 117ND 244.0415.3 76.7 * 20Trichloroethene 20 17.8 88.8 82 121ND 211.5818.0 90.2 20Trichlorofluoromethane 20 18.1 90.3 74 138ND 202.1018.4 92.2 20Vinyl chloride 20 12.8 64.2 45 143ND 2012.914.6 73.0 20cis-1,2-Dichloroethene 20 15.9 79.4 67 132ND 200.0063015.9 79.4 20cis-1,3-Dichloropropene 20 17.4 86.8 67 116ND 203.8316.7 83.5 20m,p-Xylene 40 32.1 80.3 69 127ND 201.7332.7 81.7 40o-Xylene 20 16.5 82.4 * 84 114ND 202.2516.8 84.2 20trans-1,2-Dichloroethene 20 14.9 74.7 68 131ND 200.50314.9 74.3 20trans-1,3-Dichloropropene 20 16.4 81.8 56 131ND 207.1615.2 76.1 20Xylenes,Total 60 48.6 81.0 69 127ND 201.9149.5 82.6 60 Surr: 1,2-Dichloroethane-d4 50 53.8 108 78 116ND 302.6852.4 105 50 Surr: 4-Bromofluorobenzene 50 53.2 106 74 125ND 300.52553.5 107 50 Surr: Toluene-d8 50 50.0 100 82 118ND 301.2450.7 101 50



8/31/2009 9:04:02 PM






Chain of CustodyAnd

Sample Receipt Checklist

8/31/2009 9:04:02 PM

09081449 Page 19

Sample Receipt Checklist


HOUSTON, TX 77054(713) 660-0901

Workorder: 09081449

Date and Time Received: 8/31/2009 9:00:00 AM Carrier name: Fedex-Priority

Shipping container/cooler in good condition? Yes No Not Present

Custody seals intact on shippping container/cooler? Yes No Not Present

Custody seals intact on sample bottles? Yes No Not Present

Chain of custody present? Yes No

Chain of custody signed when relinquished and received? Yes No

Chain of custody agrees with sample labels? Yes No

Samples in proper container/bottle? Yes No

Sample containers intact? Yes No

Sufficient sample volume for indicated test? Yes No

All samples received within holding time? Yes No

Container/Temp Blank temperature in compliance? Yes No

Water - VOA vials have zero headspace? Yes No VOA Vials Not Present

Temperature: 15.9, 15.2C

Received By: CAW

3. Received 4 liters unpreserved that were composited and 4 liters preserved with HCl as extra containers with no analysis listed.4. Received a set of trip blanks not listed on Spectra chain.

1. Sample for Pond 1&2 metals sample was not preserved.

2. 795503878505-15.9C, 870101736740- 15.2C

SPL Representative:

Non Conformance Issues:

1. Preserved sample with 3 mls Nitric acid Lot # 072709-2EE 2.Proceed as per client. 3. Logged on hold as per SG.4. Logged for no analysis as per SG.

Client Name Contacted:

Contact Date & Time:

Client Instructions:

Water IceChilled by:

Yes No Not ApplicableWater - Preservation checked upon receipt (except VOA*)?

1.

3.

4.

5.

2.

7.

8.

9.

6.

10.

11.

12.

13.

*VOA Preservation Checked After Sample Analysis

8/31/2009 9:04:03 PM

09081449 Page 20

stec misc spill pond2493 082809 coc9833

Documents

sample matrix

sample containers

laboratory control sample

limited sample volume

sample id misc pond

spectra energy transmission

piano analyses

matrix spike ms