stec misc spill waterwell 082809 coc9834

09081447Certificate of Analysis Number:

Spectra Energy Transmission, LLC

HOUSTON LABORATORY8880 INTERCHANGE DRIVE

HOUSTON, TX 77054(713) 660-0901


5400 Westheimer Court

HoustonTX77056-

Joe Bauer

Date Reported: 8/31/2009

Project Name: Spectra Energy

PO Number: Agreement No. ENV-0506

Site: Steckman Ridge

State: Pennsylvania

State Cert. No.: 68-03598

Report To:

Site Address:

(713) 627-5400ph: fax:

This Report Contains A Total Of 23 Pages

Excluding This Page, Chain Of Custody

Any Attachments

And

Date

9/1/2009

Test results meet all requirements of NELAC, unless specified in the narrative.

Case Narrative for:




HOUSTON, TX 77054(713) 660-0901



HoustonTX77056-

Joe Bauer





State: Pennsylvania


Report To:

Site Address:

(713) 627-5400ph: fax:

I. SAMPLE RECEIPT:

All samples were received intact. The internal ice chest temperatures were measured on receipt and are recorded on the attached Sample Receipt Checklist.

Samples for COC ARF 9834 were received at a temperature of 15.2 and 15.9 degrees Celsius.

Collection date and times were missing from the Chain of Custody; however, were noted on the sample containers.

Please note, containers received for COC ARF 9834 were labeled as "Kuhne-Well-082809". Per client request via e-mail on August 31, 2009, samples were logged in as per sample IDs noted on the Chain of Custody "MISC Drinking Water - 2321".

Containers for the Metals analyses by Method E200.8 were received unpreserved and were preserved upon receipt with 3 milliliters of Nitric acid Lot # 072709-2EE.

Containers for the COD analyses by Method SM5220 C were received unpreserved and were preserved upon receipt with 2 milliliters of Sulfuric acid Lot # 052509-2U.

Client was notified of the nonconformances mentioned above via Sample Receipt Confirmation e-mail on August 31, 2009. Per client request via e-mail on August 31, 2009 SPL, Inc. continued with analyses requested. Please see attached sample receipt checklist for any further nonconformance issues.

II: ANALYSES AND EXCEPTIONS:

N-Hexane Extractable Material (1664A):

Due to limited sample volume a Matrix Spike Duplicate (MSD) was not extracted with Batch ID R282534. A Matrix Spike (MS) as well as a Laboratory Control Sample / Laboratory Control Sample Duplicate (LCS/LCSD) were extracted with the analytical batch and serve as the batch quality control (QC). Spike recoveries for the MS, LCS and LCSD were within QC limits.

PCB (E608):

Due to limited sample volume, a Matrix Spike (MS) or Matrix Spike Duplicate (MSD) was not extracted with Batch ID: (93407) for the PCBs analysis by EPA Method E608. A Laboratory Control Sample (LCS) and a Laboratory Control Sample Duplicate (LCSD) were extracted with the analytical batch and serve as the batch quality control (QC). The LCS and LCSD recovered acceptably and precision criteria were met.

Volatile Organics (SW8260):

Client sample ID "MISC Drinking Water - 2321" (SPL ID: 09081447-01) was randomly selected for use in SPL's quality control program (Batch ID: R282519). The Matrix Spike and/or Matrix Spike Duplicate (MS/MSD) recoveries were outside of the advisory limits for the target analytes toluene, 1,2,3-trichlorobenzene and o-xylene. A Laboratory Control Sample (LCS) was analyzed as a quality control check for the analytical batch and all recoveries were within acceptable limits.

DateSylvia Grice

9/1/2009

Senior Project Manager

09081447 Page 1


Case Narrative for:




HOUSTON, TX 77054(713) 660-0901

SIM PAH (SW8270C):

Due to limited sample volume, a Matrix Spike (MS) or Matrix Spike Duplicate (MSD) was not extracted with Batch ID: 93398 for the Semivolatile Organics analysis by SW846 Method 8270C. A Laboratory Control Sample (LCS) and a Laboratory Control Sample Duplicate (LCSD) were extracted with the analytical batch and serve as the batch quality control (QC). The LCS and LCSD recovered acceptably and precision criteria were met.

III. GENERAL REPORTING COMMENTS:

Results are reported on a wet weight basis unless dry-weight correction is denoted in the units field on the analytical report (" mg\kg-dry " or " ug\kg-dry " ).

Matrix spike (MS) and matrix spike duplicate (MSD) samples are chosen and tested at random from an analytical batch of "like" matrix to check for possible matrix effect. The MS and MSD will provide site specific matrix data only for those samples which are spiked by the laboratory. Since the MS and MSD are chosen at random from an analytical batch, the sample chosen for spike purposes may or may not have been a sample submitted in this sample delivery group. The validity of the analytical procedures for which data is reported in this analytical report is determined by the Laboratory Control Sample (LCS) and the Method Blank (MB). The Laboratory Control Sample (LCS) and the Method Blank (MB) are processed with the samples and the MS/MSD to ensure method criteria are achieved throughout the entire analytical process.

Some of the percent recoveries and RPD's on the QC report for the MS/MSD may be different than the calculated recoveries and RPD's using the sample result and the MS/MSD results that appear on the report because, the actual raw result is used to perform the calculations for percent recovery and RPD.

Any other exceptions associated with this report will be footnoted in the analytical result page(s) or the quality control summary page(s).

Please do not hesitate to contact us if you have any questions or comments pertaining to this data report. Please reference the above Certificate of Analysis Number.

This report shall not be reproduced except in full, without the written approval of the laboratory. The reported results are only representative of the samples submitted for testing.

SPL, Inc. is pleased to be of service to you. We anticipate working with you in fulfilling all your current and future analytical needs.

I certify that this data package is in compliance with the terms and conditions of the contract, both technically and for completeness, for other than the conditions detailed above. Release of the data contained in this hardcopy data package has been authorized by the Laboratory Manager or by his designee, as verified by the following signature.

DateSylvia Grice

9/1/2009


09081447 Page 2





HOUSTON, TX 77054(713) 660-0901



HoustonTX77056-

(713) 627-5400

Joe Bauer





State: Pennsylvania


Report To:

Site Address:

(713) 989-8347ph: fax:

Fax To:

Client Sample ID Lab Sample ID Date Collected Date Received COC IDMatrix HOLD

Field Sampler: Mary Velasquez

09081447-01 8/31/2009 9:00:00 AMMISC Drinking Water - 2321 8/28/2009 2:15:00 PMAqueous 9834

Date

Laboratory Director

Quality Assurance Officer

Sylvia Grice

09081447 Page 3

9/1/2009

9/1/2009 9:28:28 AM


Kesavalu M. Bagawandoss Ph.D., J.D.

Ted Yen

Client Sample ID:MISC Drinking Water - 2321

Analyses/Method Result Date AnalyzedRep.Limit

SPL Sample ID: 09081447-01

Dil. Factor AnalystQUAL Seq. #

Collected: 08/28/2009 14:15



HOUSTON, TX 77054(713) 660-0901

CHEMICAL OXYGEN DEMAND SM5220 C mg/LUnits:MCLChemical Oxygen Demand 08/31/09 14:003 1ND BDG 5185027

N-HEXANE EXTRACTABLE MATERIAL 1664A mg/LUnits:MCLn-Hexane Extractable Material 08/31/09 16:155 1ND KAM 5185090

Prep Method Prep Date Prep Initials Prep Factor08/31/2009 14:00 1.00

PESTICIDE/PCBS E608 ug/LUnits:MCLAroclor 1016 08/31/09 16:580.5 1ND RLR 5185208Aroclor 1221 08/31/09 16:580.5 1ND RLR 5185208Aroclor 1232 08/31/09 16:580.5 1ND RLR 5185208Aroclor 1242 08/31/09 16:580.5 1ND RLR 5185208Aroclor 1248 08/31/09 16:580.5 1ND RLR 5185208Aroclor 1254 08/31/09 16:580.5 1ND RLR 5185208Aroclor 1260 08/31/09 16:580.5 1ND RLR 5185208Total PCB 08/31/09 16:580.5 1ND RLR 5185208 Surr: Decachlorobiphenyl 08/31/09 16:58% 14-159 186.0 RLR 5185208 Surr: Tetrachloro-m-xylene 08/31/09 16:58% 48-120 185.6 RLR 5185208

Prep Method Prep Date Prep Initials Prep Factor08/31/2009 13:39 N_ME608 1.00

Qualifiers: B/V - Analyte detected in the associated Method BlankND/U - Not Detected at the Reporting Limit

* - Surrogate Recovery Outside Advisable QC Limits

>MCL - Result Over Maximum Contamination Limit(MCL)D - Surrogate Recovery Unreportable due to Dilution

9/1/2009 9:28:39 AM

J - Estimated Value between MDL and PQLMI - Matrix Interference

09081447 Page 4TNTC - Too numerous to countE - Estimated Value exceeds calibration curve





Collected: 08/28/2009 14:15



HOUSTON, TX 77054(713) 660-0901

SIM SEMIVOLATILES ORGANICS BY METHOD 8270C SW8270C ug/LUnits:MCL2-Methylnaphthalene 08/31/09 16:510.05 1ND S_G 5185163Acenaphthene 08/31/09 16:510.05 1ND S_G 5185163Acenaphthylene 08/31/09 16:510.05 1ND S_G 5185163Anthracene 08/31/09 16:510.05 1ND S_G 5185163Benz(a)anthracene 08/31/09 16:510.05 1ND S_G 5185163Benzo(a)pyrene 08/31/09 16:510.05 1ND S_G 5185163Benzo(b)fluoranthene 08/31/09 16:510.05 1ND S_G 5185163Benzo(g,h,i)perylene 08/31/09 16:510.05 1ND S_G 5185163Benzo(k)fluoranthene 08/31/09 16:510.05 1ND S_G 5185163Chrysene 08/31/09 16:510.05 1ND S_G 5185163Dibenz(a,h)anthracene 08/31/09 16:510.05 1ND S_G 5185163Fluoranthene 08/31/09 16:510.05 1ND S_G 5185163Fluorene 08/31/09 16:510.05 1ND S_G 5185163Indeno(1,2,3-cd)pyrene 08/31/09 16:510.05 1ND S_G 5185163Naphthalene 08/31/09 16:510.05 1ND S_G 5185163Phenanthrene 08/31/09 16:510.05 1ND S_G 5185163Pyrene 08/31/09 16:510.05 1ND S_G 5185163 Surr: 2-Fluorobiphenyl 08/31/09 16:51% 10-123 141.2 S_G 5185163 Surr: Nitrobenzene-d5 08/31/09 16:51% 10-165 130.6 S_G 5185163 Surr: Terphenyl-d14 08/31/09 16:51% 10-150 143.4 S_G 5185163

Prep Method Prep Date Prep Initials Prep Factor08/31/2009 13:45 A_GSW3510C 1.00

TOTAL METALS BY METHOD 200.8 E200.8 mg/LUnits:MCLArsenic 08/31/09 19:020.001 10.0038 S_C 5185281Cadmium 08/31/09 19:020.0005 1ND S_C 5185281Chromium 08/31/09 19:020.001 1ND S_C 5185281Copper 08/31/09 19:020.001 10.117 S_C 5185281Lead 08/31/09 19:020.001 1ND S_C 5185281Nickel 08/31/09 19:020.001 1ND S_C 5185281Silver 08/31/09 19:020.0005 1ND S_C 5185281Zinc 08/31/09 19:020.001 10.0064 S_C 5185281

Prep Method Prep Date Prep Initials Prep Factor08/31/2009 14:00 R_VE200.7/200.8 1.00




9/1/2009 9:28:40 AM







Collected: 08/28/2009 14:15



HOUSTON, TX 77054(713) 660-0901

VOLATILE ORGANICS BY METHOD 8260B SW8260B ug/LUnits:MCL1,1,1,2-Tetrachloroethane 08/31/09 13:531 1ND E_G 51847991,1,1-Trichloroethane 08/31/09 13:531 1ND E_G 51847991,1,2,2-Tetrachloroethane 08/31/09 13:531 1ND E_G 51847991,1,2-Trichloroethane 08/31/09 13:531 1ND E_G 51847991,1-Dichloroethane 08/31/09 13:531 1ND E_G 51847991,1-Dichloroethene 08/31/09 13:531 1ND E_G 51847991,1-Dichloropropene 08/31/09 13:531 1ND E_G 51847991,2,3-Trichlorobenzene 08/31/09 13:531 1ND E_G 51847991,2,3-Trichloropropane 08/31/09 13:531 1ND E_G 51847991,2,4-Trichlorobenzene 08/31/09 13:531 1ND E_G 51847991,2,4-Trimethylbenzene 08/31/09 13:531 1ND E_G 51847991,2-Dibromo-3-chloropropane 08/31/09 13:535 1ND E_G 51847991,2-Dibromoethane 08/31/09 13:531 1ND E_G 51847991,2-Dichlorobenzene 08/31/09 13:531 1ND E_G 51847991,2-Dichloroethane 08/31/09 13:531 1ND E_G 51847991,2-Dichloropropane 08/31/09 13:531 1ND E_G 51847991,3,5-Trimethylbenzene 08/31/09 13:531 1ND E_G 51847991,3-Dichlorobenzene 08/31/09 13:531 1ND E_G 51847991,3-Dichloropropane 08/31/09 13:531 1ND E_G 51847991,4-Dichlorobenzene 08/31/09 13:531 1ND E_G 51847992,2-Dichloropropane 08/31/09 13:531 1ND E_G 51847992-Chlorotoluene 08/31/09 13:531 1ND E_G 51847994-Chlorotoluene 08/31/09 13:531 1ND E_G 51847994-Isopropyltoluene 08/31/09 13:531 1ND E_G 5184799Benzene 08/31/09 13:531 1ND E_G 5184799Bromobenzene 08/31/09 13:531 1ND E_G 5184799Bromochloromethane 08/31/09 13:531 1ND E_G 5184799Bromodichloromethane 08/31/09 13:531 1ND E_G 5184799Bromoform 08/31/09 13:531 1ND E_G 5184799Bromomethane 08/31/09 13:531 1ND E_G 5184799Carbon tetrachloride 08/31/09 13:531 1ND E_G 5184799Chlorobenzene 08/31/09 13:531 1ND E_G 5184799Chloroethane 08/31/09 13:531 1ND E_G 5184799Chloroform 08/31/09 13:531 1ND E_G 5184799Chloromethane 08/31/09 13:531 1ND E_G 5184799Dibromochloromethane 08/31/09 13:531 1ND E_G 5184799Dibromomethane 08/31/09 13:531 1ND E_G 5184799Dichlorodifluoromethane 08/31/09 13:531 1ND E_G 5184799Ethylbenzene 08/31/09 13:531 1ND E_G 5184799




9/1/2009 9:28:41 AM







Collected: 08/28/2009 14:15



HOUSTON, TX 77054(713) 660-0901

Hexachlorobutadiene 08/31/09 13:531 1ND E_G 5184799Isopropylbenzene 08/31/09 13:531 1ND E_G 5184799Methyl tert-butyl ether 08/31/09 13:531 1ND E_G 5184799Methylene chloride 08/31/09 13:531 1ND E_G 5184799Naphthalene 08/31/09 13:531 1ND E_G 5184799n-Butylbenzene 08/31/09 13:531 1ND E_G 5184799n-Propylbenzene 08/31/09 13:531 1ND E_G 5184799sec-Butylbenzene 08/31/09 13:531 1ND E_G 5184799Styrene 08/31/09 13:531 1ND E_G 5184799tert-Butylbenzene 08/31/09 13:531 1ND E_G 5184799Tetrachloroethene 08/31/09 13:531 1ND E_G 5184799Toluene 08/31/09 13:531 1ND E_G 5184799Trichloroethene 08/31/09 13:531 1ND E_G 5184799Trichlorofluoromethane 08/31/09 13:531 1ND E_G 5184799Vinyl chloride 08/31/09 13:531 1ND E_G 5184799cis-1,2-Dichloroethene 08/31/09 13:531 1ND E_G 5184799cis-1,3-Dichloropropene 08/31/09 13:531 1ND E_G 5184799m,p-Xylene 08/31/09 13:532 1ND E_G 5184799o-Xylene 08/31/09 13:531 1ND E_G 5184799trans-1,2-Dichloroethene 08/31/09 13:531 1ND E_G 5184799trans-1,3-Dichloropropene 08/31/09 13:531 1ND E_G 5184799Xylenes,Total 08/31/09 13:531 1ND E_G 5184799 Surr: 1,2-Dichloroethane-d4 08/31/09 13:53% 78-116 1111 E_G 5184799 Surr: 4-Bromofluorobenzene 08/31/09 13:53% 74-125 1113 E_G 5184799 Surr: Toluene-d8 08/31/09 13:53% 82-118 1100 E_G 5184799




9/1/2009 9:28:41 AM



Quality Control Documentation

9/1/2009 9:28:41 AM

09081447 Page 8

Quality Control Report

Spectra Energy Transmission, LLCSpectra Energy

Lab Batch ID: R282534WorkOrder: 09081447

Method: 1664AAnalysis: N-Hexane Extractable Material


HOUSTON, TX 77054(713) 660-0901

Analyte LCS Spike Added

LCS Result

LCS Percent Recovery

Lower Limit

Upper Limit

Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD)

LCSD Spike Added

LCSD Result

LCSD Percent Recovery

RPD RPD Limit

Analysis Date: 08/31/2009 16:15Preparation Date: 08/31/2009 14:00

Analyst: KAMPrep By: Method:

RunID: EX_090831D-5185087 Units: mg/L

n-Hexane Extractable Material 40.0 40.0 100 78 11440.0 39.8 99.5 0.5 18

Analyte Spike Added

Matrix Spike (MS)

Sample Result Low Limit

High Limit

MS Result MS % Recovery

Sample Spiked: 09081447-01


Analyst: KAMPrep By: Method:


n-Hexane Extractable Material 40 78 114ND 40.0 100

Analyte Result Rep Limit

Method Blank


Analyst: KAM


Prep By: Method:

n-Hexane Extractable Material 5.0ND

Samples in Analytical Batch:

Lab Sample ID Client Sample ID09081447-01F MISC Drinking Water - 2321


* - Recovery Outside Advisable QC LimitsD - Recovery Unreportable due to Dilution

9/1/2009 9:28:43 AM

J - Estimated value between MDL and PQL

MI - Matrix Interference

QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.

09081447 Page 9N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.TNTC - Too numerous to count

E - Estimated Value exceeds calibration curve



Lab Batch ID: 93407WorkOrder: 09081447

Method: E608Analysis: Pesticide/PCBs


HOUSTON, TX 77054(713) 660-0901


LCS Result


Lower Limit

Upper Limit


LCSD Spike Added

LCSD Result


RPD RPD Limit


Analyst: RLRPrep By: N_M Method: E608

RunID: HP_A_090831C-5185206 Units: ug/L

Aroclor 1016 10.0 9.43 94.3 50 11410.0 9.66 96.6 2.4 30Aroclor 1260 10.0 9.85 98.5 8 12710.0 9.66 96.6 1.9 30 Surr: Decachlorobiphenyl 1.00 0.987 98.7 14 1591.00 1.00 100 1.8 30 Surr: Tetrachloro-m-xylene 1.00 0.931 93.1 48 1201.00 0.946 94.6 1.7 30


Method Blank


Analyst: RLR

RunID: HP_A_090831C-5185210 Units: ug/L

Prep By: N_M Method: E608

Aroclor 1016 0.50NDAroclor 1221 0.50NDAroclor 1232 0.50NDAroclor 1242 0.50NDAroclor 1248 0.50NDAroclor 1254 0.50NDAroclor 1260 0.50NDTotal PCB 0.50ND Surr: Decachlorobiphenyl 14-15997.1 Surr: Tetrachloro-m-xylene 48-12089.1


Lab Sample ID Client Sample ID09081447-01C MISC Drinking Water - 2321



9/1/2009 9:28:43 AM








Lab Batch ID: 93430-IWorkOrder: 09081447

Method: E200.8Analysis: Total Metals by Method 200.8


HOUSTON, TX 77054(713) 660-0901

Matrix Spike (MS) / Matrix Spike Duplicate (MSD)



Analyst: S_CPrep By: R_V Method: E200.7/200.8

RunID: ICPMS_090831B-5185282 Units: mg/L

Analyte Spike Added

Result Percent Recovery

Lower Limit

Upper Limit

Laboratory Control Sample (LCS)


Analyst: S_CPrep By: R_V Method: E200.7/200.8


Arsenic 0.1000 0.09622 96.22 85 115Cadmium 0.1000 0.09748 97.48 85 115Chromium 0.1000 0.09454 94.54 85 115Copper 0.1000 0.09791 97.91 85 115Lead 0.1000 0.08778 87.78 85 115Nickel 0.1000 0.1008 100.8 85 115Silver 0.1000 0.08901 89.01 85 115Zinc 0.1000 0.09803 98.03 85 115


Method Blank


Analyst: S_C


Prep By: R_V Method: E200.7/200.8

Arsenic 0.001NDCadmium 0.0005NDChromium 0.001NDCopper 0.001NDLead 0.001NDNickel 0.001NDSilver 0.0005NDZinc 0.001ND


Lab Sample ID Client Sample ID09081447-01B MISC Drinking Water - 2321



9/1/2009 9:28:43 AM








Lab Batch ID: 93430-IWorkOrder: 09081447

Method: E200.8Analysis: Total Metals by Method 200.8


HOUSTON, TX 77054(713) 660-0901

Analyte MS Spike Added

MSDResult

MSD % Recovery

RPD RPD Limit

SampleResult

Low Limit

High Limit

MSResult

MS % Recovery

MSD Spike Added

Arsenic 0.1 0.08812 84.32 70 1300.003802 201.8880.08980 86.00 0.1Cadmium 0.1 0.09687 96.87 70 130ND 202.2250.09905 99.05 0.1Chromium 0.1 0.09842 98.42 70 130ND 202.8840.1013 101.3 0.1Copper 0.1 0.2090 91.90 70 1300.1171 201.4250.2120 94.90 0.1Lead 0.1 0.09313 93.13 70 130ND 202.7430.09572 95.72 0.1Nickel 0.1 0.1006 99.80 70 130ND 201.1860.1018 101.0 0.1Silver 0.1 0.09238 92.38 70 130ND 200.84080.09316 93.16 0.1Zinc 0.1 0.08813 81.73 70 1300.006396 201.2740.08926 82.86 0.1



9/1/2009 9:28:43 AM









Method: SW8270CAnalysis: SIM Semivolatiles Organics by Method 8270C


HOUSTON, TX 77054(713) 660-0901


LCS Result


Lower Limit

Upper Limit


LCSD Spike Added

LCSD Result


RPD RPD Limit


Analyst: S_GPrep By: A_G Method: SW3510C

RunID: J_090831C-5185366 Units: ug/L

2-Methylnaphthalene 0.500 0.249 49.8 21 1250.500 0.248 49.6 0.4 30Acenaphthene 0.500 0.251 50.2 21 1380.500 0.245 49.0 2.4 30Acenaphthylene 0.500 0.233 46.6 20 1310.500 0.228 45.6 2.2 30Anthracene 0.500 0.210 42.0 20 1300.500 0.201 40.2 4.4 30Benz(a)anthracene 0.500 0.220 44.0 27 1330.500 0.198 39.6 10.5 30Benzo(a)pyrene 0.500 0.252 50.4 27 1220.500 0.245 49.0 2.8 30Benzo(b)fluoranthene 0.500 0.266 53.2 23 1260.500 0.260 52.0 2.3 30Benzo(g,h,i)perylene 0.500 0.270 54.0 29 1250.500 0.263 52.6 2.6 30Benzo(k)fluoranthene 0.500 0.245 49.0 31 1330.500 0.246 49.2 0.4 30


Method Blank


Analyst: S_G


Prep By: A_G Method: SW3510C

2-Methylnaphthalene 0.050NDAcenaphthene 0.050NDAcenaphthylene 0.050NDAnthracene 0.050NDBenz(a)anthracene 0.050NDBenzo(a)pyrene 0.050NDBenzo(b)fluoranthene 0.050NDBenzo(g,h,i)perylene 0.050NDBenzo(k)fluoranthene 0.050NDChrysene 0.050NDDibenz(a,h)anthracene 0.050NDFluoranthene 0.050NDFluorene 0.050NDIndeno(1,2,3-cd)pyrene 0.050NDNaphthalene 0.050NDPhenanthrene 0.050NDPyrene 0.050ND Surr: 2-Fluorobiphenyl 10-12339.6 Surr: Nitrobenzene-d5 10-16531.8 Surr: Terphenyl-d14 10-15038.6


Lab Sample ID Client Sample ID09081447-01D MISC Drinking Water - 2321



9/1/2009 9:28:43 AM









Method: SW8270CAnalysis: SIM Semivolatiles Organics by Method 8270C


HOUSTON, TX 77054(713) 660-0901


LCS Result


Lower Limit

Upper Limit


LCSD Spike Added

LCSD Result


RPD RPD Limit


Analyst: S_GPrep By: A_G Method: SW3510C


Chrysene 0.500 0.237 47.4 36 1350.500 0.244 48.8 2.9 30Dibenz(a,h)anthracene 0.500 0.254 50.8 24 1200.500 0.264 52.8 3.9 30Fluoranthene 0.500 0.229 45.8 26 1250.500 0.215 43.0 6.3 30Fluorene 0.500 0.252 50.4 22 1320.500 0.254 50.8 0.8 30Indeno(1,2,3-cd)pyrene 0.500 0.274 54.8 23 1270.500 0.279 55.8 1.8 30Naphthalene 0.500 0.248 49.6 23 1360.500 0.250 50.0 0.8 30Phenanthrene 0.500 0.236 47.2 22 1330.500 0.232 46.4 1.7 30Pyrene 0.500 0.214 42.8 31 1420.500 0.217 43.4 1.4 30 Surr: 2-Fluorobiphenyl 0.500 0.128 25.6 10 1230.500 0.126 25.2 1.6 30 Surr: Nitrobenzene-d5 0.500 0.127 25.4 10 1650.500 0.127 25.4 0.0 30 Surr: Terphenyl-d14 0.500 0.133 26.6 10 1500.500 0.129 25.8 3.1 30



9/1/2009 9:28:43 AM









Method: SW8260BAnalysis: Volatile Organics by Method 8260B


HOUSTON, TX 77054(713) 660-0901


Method Blank

Analysis Date: 08/31/2009 11:07 Analyst: E_G

RunID: L_090831A-5184798 Units: ug/L

1,1,1,2-Tetrachloroethane 1.0ND1,1,1-Trichloroethane 1.0ND1,1,2,2-Tetrachloroethane 1.0ND1,1,2-Trichloroethane 1.0ND1,1-Dichloroethane 1.0ND1,1-Dichloroethene 1.0ND1,1-Dichloropropene 1.0ND1,2,3-Trichlorobenzene 1.0ND1,2,3-Trichloropropane 1.0ND1,2,4-Trichlorobenzene 1.0ND1,2,4-Trimethylbenzene 1.0ND1,2-Dibromo-3-chloropropane 5.0ND1,2-Dibromoethane 1.0ND1,2-Dichlorobenzene 1.0ND1,2-Dichloroethane 1.0ND1,2-Dichloropropane 1.0ND1,3,5-Trimethylbenzene 1.0ND1,3-Dichlorobenzene 1.0ND1,3-Dichloropropane 1.0ND1,4-Dichlorobenzene 1.0ND2,2-Dichloropropane 1.0ND2-Chlorotoluene 1.0ND4-Chlorotoluene 1.0ND4-Isopropyltoluene 1.0NDBenzene 1.0NDBromobenzene 1.0NDBromochloromethane 1.0NDBromodichloromethane 1.0NDBromoform 1.0NDBromomethane 1.0NDCarbon tetrachloride 1.0NDChlorobenzene 1.0NDChloroethane 1.0NDChloroform 1.0NDChloromethane 1.0NDDibromochloromethane 1.0NDDibromomethane 1.0NDDichlorodifluoromethane 1.0NDEthylbenzene 1.0NDHexachlorobutadiene 1.0NDIsopropylbenzene 1.0NDMethyl tert-butyl ether 1.0NDMethylene chloride 1.0NDNaphthalene 1.0NDn-Butylbenzene 1.0NDn-Propylbenzene 1.0ND


Lab Sample ID Client Sample ID09081447-01A MISC Drinking Water - 2321



9/1/2009 9:28:44 AM











HOUSTON, TX 77054(713) 660-0901

Analyte Spike Added


Lower Limit

Upper Limit


Analysis Date: 08/31/2009 9:33 Analyst: E_GRunID: L_090831A-5184797 Units: ug/L

1,1,1,2-Tetrachloroethane 20.0 20.3 102 71 1281,1,1-Trichloroethane 20.0 24.5 122 61 1351,1,2,2-Tetrachloroethane 20.0 23.3 117 60 1331,1,2-Trichloroethane 20.0 20.0 99.9 77 1271,1-Dichloroethane 20.0 22.8 114 68 1321,1-Dichloroethene 20.0 24.6 123 65 1341,1-Dichloropropene 20.0 19.1 95.6 68 1261,2,3-Trichlorobenzene 20.0 18.0 90.2 36 1541,2,3-Trichloropropane 20.0 23.7 118 38 1531,2,4-Trichlorobenzene 20.0 19.3 96.4 69 1441,2,4-Trimethylbenzene 20.0 20.0 100 64 128


Method Blank

Analysis Date: 08/31/2009 11:07 Analyst: E_G

RunID: L_090831A-5184798 Units: ug/L

sec-Butylbenzene 1.0NDStyrene 1.0NDtert-Butylbenzene 1.0NDTetrachloroethene 1.0NDToluene 1.0NDTrichloroethene 1.0NDTrichlorofluoromethane 1.0NDVinyl chloride 1.0NDcis-1,2-Dichloroethene 1.0NDcis-1,3-Dichloropropene 1.0NDm,p-Xylene 2.0NDo-Xylene 1.0NDtrans-1,2-Dichloroethene 1.0NDtrans-1,3-Dichloropropene 1.0NDXylenes,Total 1.0ND Surr: 1,2-Dichloroethane-d4 78-116106.5 Surr: 4-Bromofluorobenzene 74-125107.0 Surr: Toluene-d8 82-118101.1



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HOUSTON, TX 77054(713) 660-0901

Analyte Spike Added


Lower Limit

Upper Limit



1,2-Dibromo-3-chloropropane 20.0 22.8 114 44 1411,2-Dibromoethane 20.0 19.5 97.6 75 1241,2-Dichlorobenzene 20.0 20.8 104 68 1241,2-Dichloroethane 20.0 19.5 97.7 61 1381,2-Dichloropropane 20.0 20.9 105 76 1231,3,5-Trimethylbenzene 20.0 19.8 99.0 61 1271,3-Dichlorobenzene 20.0 20.1 100 68 1271,3-Dichloropropane 20.0 18.2 90.8 76 1251,4-Dichlorobenzene 20.0 19.7 98.4 68 1242,2-Dichloropropane 20.0 24.3 122 42 1422-Chlorotoluene 20.0 19.0 95.0 64 1324-Chlorotoluene 20.0 19.2 95.9 61 1324-Isopropyltoluene 20.0 20.6 103 63 136Benzene 20.0 20.3 101 74 123Bromobenzene 20.0 19.2 95.9 68 125Bromochloromethane 20.0 21.4 107 71 124Bromodichloromethane 20.0 21.1 105 72 128Bromoform 20.0 18.8 94.1 60 128Bromomethane 20.0 19.2 95.9 53 130Carbon tetrachloride 20.0 26.2 131 59 142Chlorobenzene 20.0 18.5 92.3 75 125Chloroethane 20.0 20.8 104 60 134Chloroform 20.0 21.8 109 71 127Chloromethane 20.0 23.0 115 50 139Dibromochloromethane 20.0 18.6 93.1 65 130Dibromomethane 20.0 23.0 115 79 124Dichlorodifluoromethane 20.0 24.2 121 22 162Ethylbenzene 20.0 18.7 93.3 72 127Hexachlorobutadiene 20.0 21.2 106 45 152Isopropylbenzene 20.0 18.3 91.6 58 130Methyl tert-butyl ether 40.0 47.7 119 63 123Methylene chloride 20.0 23.1 116 61 135Naphthalene 20.0 19.4 97.0 33 148n-Butylbenzene 20.0 21.7 108 62 136



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HOUSTON, TX 77054(713) 660-0901


MSDResult

MSD % Recovery

RPD RPD Limit


SampleResult

Low Limit

High Limit

MSResult

MS % Recovery


MSD Spike Added


1,1,1,2-Tetrachloroethane 20 16.1 80.6 68 124ND 200.92016.3 81.4 201,1,1-Trichloroethane 20 17.6 88.2 69 123ND 200.21517.7 88.4 201,1,2,2-Tetrachloroethane 20 18.0 89.9 69 130ND 202.1918.4 91.9 20

Analyte Spike Added


Lower Limit

Upper Limit



n-Propylbenzene 20.0 18.9 94.5 57 131sec-Butylbenzene 20.0 20.4 102 63 131Styrene 20.0 19.4 96.8 69 120tert-Butylbenzene 20.0 20.5 102 59 131Tetrachloroethene 20.0 19.1 95.5 45 173Toluene 20.0 16.4 82.2 74 126Trichloroethene 20.0 20.7 104 79 131Trichlorofluoromethane 20.0 28.9 144 49 153Vinyl chloride 20.0 21.8 109 51 148cis-1,2-Dichloroethene 20.0 21.1 106 71 128cis-1,3-Dichloropropene 20.0 19.6 97.8 67 128m,p-Xylene 40.0 39.2 98.0 71 129o-Xylene 20.0 20.7 104 74 130trans-1,2-Dichloroethene 20.0 22.3 111 66 128trans-1,3-Dichloropropene 20.0 19.3 96.4 60 128Xylenes,Total 60.0 59.9 99.9 71 130 Surr: 1,2-Dichloroethane-d4 50.0 55 110 78 116 Surr: 4-Bromofluorobenzene 50.0 57.2 114 74 125 Surr: Toluene-d8 50.0 47.5 95.0 82 118



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HOUSTON, TX 77054(713) 660-0901


MSDResult

MSD % Recovery

RPD RPD Limit


SampleResult

Low Limit

High Limit

MSResult

MS % Recovery


MSD Spike Added


1,1,2-Trichloroethane 20 18.5 92.5 75 126ND 201.5718.2 91.1 201,1-Dichloroethane 20 15.7 78.4 65 129ND 201.0615.5 77.5 201,1-Dichloroethene 20 16.0 79.9 61 139ND 220.23815.9 79.7 201,1-Dichloropropene 20 16.1 80.3 69 121ND 203.3716.6 83.1 201,2,3-Trichlorobenzene 20 7.63 38.1 * 53 127ND 201.807.49 37.5 * 201,2,3-Trichloropropane 20 18.4 91.9 79 124ND 200.59518.3 91.4 201,2,4-Trichlorobenzene 20 12.3 61.3 58 118ND 203.7611.8 59.0 201,2,4-Trimethylbenzene 20 16.4 82.1 43 132ND 200.26216.5 82.3 201,2-Dibromo-3-chloropropane 20 17.5 87.5 46 131ND 200.43917.6 87.9 201,2-Dibromoethane 20 17.8 88.9 76 122ND 201.6617.5 87.4 201,2-Dichlorobenzene 20 17.3 86.6 74 110ND 200.45717.2 86.2 201,2-Dichloroethane 20 16.1 80.3 60 129ND 201.7215.8 78.9 201,2-Dichloropropane 20 17.6 88.2 76 116ND 201.1117.5 87.3 201,3,5-Trimethylbenzene 20 16.5 82.3 51 121ND 201.0816.6 83.2 201,3-Dichlorobenzene 20 16.7 83.3 71 110ND 200.72916.8 83.9 201,3-Dichloropropane 20 16.7 83.6 80 119ND 200.50416.6 83.2 201,4-Dichlorobenzene 20 16.4 81.8 69 110ND 200.72416.2 81.2 202,2-Dichloropropane 20 18.2 90.9 52 122ND 200.027518.2 91.0 202-Chlorotoluene 20 16.6 83.0 69 112ND 201.7816.9 84.5 204-Chlorotoluene 20 16.8 84.0 37 110ND 200.87716.9 84.7 204-Isopropyltoluene 20 16.2 81.2 65 116ND 200.20916.3 81.4 20Benzene 20 16.2 81.0 70 124ND 221.1416.4 81.9 20Bromobenzene 20 17.0 84.8 72 111ND 200.88316.8 84.0 20Bromochloromethane 20 16.7 83.7 73 126ND 201.8816.4 82.2 20Bromodichloromethane 20 16.9 84.5 68 125ND 204.9216.1 80.5 20Bromoform 20 13.3 66.3 44 132ND 203.3812.8 64.1 20Bromomethane 20 11.8 58.8 50 140ND 201.6412.0 59.8 20Carbon tetrachloride 20 17.0 85.0 66 126ND 201.3917.2 86.2 20Chlorobenzene 20 15.8 79.1 68 123ND 210.76815.9 79.7 20Chloroethane 20 12.7 63.7 59 134ND 201.1912.9 64.4 20Chloroform 20 16.5 82.5 68 127ND 200.012116.5 82.6 20Chloromethane 20 14.6 72.9 51 137ND 200.35614.6 73.1 20



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HOUSTON, TX 77054(713) 660-0901


MSDResult

MSD % Recovery

RPD RPD Limit


SampleResult

Low Limit

High Limit

MSResult

MS % Recovery


MSD Spike Added


Dibromochloromethane 20 15.2 76.1 58 131ND 202.2314.9 74.4 20Dibromomethane 20 18.7 93.4 82 123ND 203.0518.1 90.6 20Dichlorodifluoromethane 20 12.3 61.4 35 143ND 204.1711.8 58.9 20Ethylbenzene 20 15.6 78.0 76 122ND 203.4716.2 80.8 20Hexachlorobutadiene 20 10.7 53.7 43 137ND 201.8110.9 54.6 20Isopropylbenzene 20 13.7 68.3 57 124ND 202.9114.1 70.3 20Methyl tert-butyl ether 40 36.2 90.6 10 200ND 203.7934.9 87.3 40Methylene chloride 20 15.3 76.4 70 134ND 203.1614.8 74.1 20Naphthalene 20 10.5 52.3 42 140ND 201.1210.3 51.7 20n-Butylbenzene 20 16.6 83.0 82 112ND 200.36716.7 83.4 20n-Propylbenzene 20 16.1 80.7 73 108ND 200.68616.2 81.2 20sec-Butylbenzene 20 16.5 82.4 76 110ND 200.52316.4 82.0 20Styrene 20 15.9 79.3 58 152ND 200.40915.9 79.6 20tert-Butylbenzene 20 16.5 82.5 66 120ND 200.53816.6 82.9 20Tetrachloroethene 20 17.1 85.4 71 130ND 204.7417.9 89.6 20Toluene 20 14.7 73.7 * 80 117ND 244.0415.3 76.7 * 20Trichloroethene 20 17.8 88.8 82 121ND 211.5818.0 90.2 20Trichlorofluoromethane 20 18.1 90.3 74 138ND 202.1018.4 92.2 20Vinyl chloride 20 12.8 64.2 45 143ND 2012.914.6 73.0 20cis-1,2-Dichloroethene 20 15.9 79.4 67 132ND 200.0063015.9 79.4 20cis-1,3-Dichloropropene 20 17.4 86.8 67 116ND 203.8316.7 83.5 20m,p-Xylene 40 32.1 80.3 69 127ND 201.7332.7 81.7 40o-Xylene 20 16.5 82.4 * 84 114ND 202.2516.8 84.2 20trans-1,2-Dichloroethene 20 14.9 74.7 68 131ND 200.50314.9 74.3 20trans-1,3-Dichloropropene 20 16.4 81.8 56 131ND 207.1615.2 76.1 20Xylenes,Total 60 48.6 81.0 69 127ND 201.9149.5 82.6 60 Surr: 1,2-Dichloroethane-d4 50 53.8 108 78 116ND 302.6852.4 105 50 Surr: 4-Bromofluorobenzene 50 53.2 106 74 125ND 300.52553.5 107 50 Surr: Toluene-d8 50 50.0 100 82 118ND 301.2450.7 101 50



9/1/2009 9:28:44 AM








Lab Batch ID: R282512AWorkOrder: 09081447

Method: SM5220 CAnalysis: Chemical Oxygen Demand


HOUSTON, TX 77054(713) 660-0901


MSDResult

MSD % Recovery

RPD RPD Limit


SampleResult

Low Limit

High Limit

MSResult

MS % Recovery


MSD Spike Added

Analysis Date: 08/31/2009 14:00 Analyst: BDGRunID: WET_090831K-5185028 Units: mg/L

Chemical Oxygen Demand 50 52.63 105.3 80 120ND 10052.63 105.3 50

Analyte Spike Added


Lower Limit

Upper Limit


Analysis Date: 08/31/2009 12:00 Analyst: BDGRunID: WET_090831K-5184712 Units: mg/L

Chemical Oxygen Demand 104.0 102.6 98.68 85 115


Method Blank

Analysis Date: 08/31/2009 12:00 Analyst: BDG

RunID: WET_090831K-5184710 Units: mg/L

Chemical Oxygen Demand 3.0ND


Lab Sample ID Client Sample ID09081447-01E MISC Drinking Water - 2321



9/1/2009 9:28:45 AM






Chain of CustodyAnd

Sample Receipt Checklist

9/1/2009 9:28:45 AM

09081447 Page 22

Sample Receipt Checklist


HOUSTON, TX 77054(713) 660-0901

Workorder: 09081447

Date and Time Received: 8/31/2009 9:00:00 AM Carrier name: Fedex-Priority

Shipping container/cooler in good condition? Yes No Not Present

Custody seals intact on shippping container/cooler? Yes No Not Present

Custody seals intact on sample bottles? Yes No Not Present

Chain of custody present? Yes No

Chain of custody signed when relinquished and received? Yes No

Chain of custody agrees with sample labels? Yes No

Samples in proper container/bottle? Yes No

Sample containers intact? Yes No

Sufficient sample volume for indicated test? Yes No

All samples received within holding time? Yes No

Container/Temp Blank temperature in compliance? Yes No

Water - VOA vials have zero headspace? Yes No VOA Vials Not Present

Temperature: 15.2, 15.9°C

Received By: CAW

2. Well sample for COD and metals was received unpreserved.

1. 795503878505-15.9C, 870101736740- 15.2C

SPL Representative:

Non Conformance Issues:

1. Proceed as per client. 2. Preserved COD with 2 mls Sulfuric Lot # 052509-2U. Preserved metals with 3 mls. Nitric Acid Lot#072709-2EE

Client Name Contacted:

Contact Date & Time:

Client Instructions:

Water IceChilled by:

Yes No Not ApplicableWater - Preservation checked upon receipt (except VOA*)?

1.

3.

4.

5.

2.

7.

8.

9.

6.

10.

11.

12.

13.

*VOA Preservation Checked After Sample Analysis

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09081447 Page 23

stec misc spill waterwell 082809 coc9834

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