balance de masa - proceso acido citrico
DESCRIPTION
acTRANSCRIPT
Materials & Streams Reportfor ejemplo
February 13, 2015
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1. OVERALL PROCESS DATA
Annual Operating Time 7,687.27h
Recipe Batch Time 613.27h
Recipe Cycle Time 294.75h
Number of Batches per Year 25.00
MP = Undefined
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2.1 STARTING MATERIAL REQUIREMENTS (per Section)
Section Starting Material Active Product
AmountNeeded
(kgSin/kg
MP)
MolarYield
(%)
MassYield
(%)
GrossMassYield
(%)
Main Section (none) (none) Unknown Unknown Unknown Unknown
Sin = Section Starting Material, Aout = Section Active Product
2.2 BULK MATERIALS (Entire Process)
Material kg/yr kg/batch kg/kg MPGlucosa 15,750 630.000
Water 522,220 20,888.791
Biomass 0 0.010
Air 5,289,215 211,568.614
TOTAL 5,827,185 233,087.415
2.3 BULK MATERIALS (per Section)
SECTIONS IN: Main Branch
Main Section
Material kg/yr kg/batch kg/kg MPGlucosa 15,750 630.000
Water 522,220 20,888.791
Biomass 0 0.010
Air 5,289,215 211,568.614
TOTAL 5,827,185 233,087.415
2.4 BULK MATERIALS (per Material)
Glucosa
Procedure % Total kg/yr kg/batch kg/kg MP
Main Section (Main Branch)P-1 100.00 15,750 630.000
TOTAL 100.00 15,750 630.000
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Water
Procedure % Total kg/yr kg/batch kg/kg MP
Main Section (Main Branch)P-1 100.00 522,220 20,888.791
TOTAL 100.00 522,220 20,888.791
Biomass
Procedure % Total kg/yr kg/batch kg/kg MP
Main Section (Main Branch)P-2 100.00 0 0.010
TOTAL 100.00 0 0.010
Air
Procedure % Total kg/yr kg/batch kg/kg MP
Main Section (Main Branch)P-2 11.11 587,668 23,506.723
P-7 88.89 4,701,547 188,061.892
TOTAL 100.00 5,289,215 211,568.614
2.5 BULK MATERIALS: SECTION TOTALS (kg/batch)
Raw Material Main SectionGlucosa 630.000
Water 20,888.791
Biomass 0.010
Air 211,568.614
TOTAL 233,087.415
2.6 BULK MATERIALS: SECTION TOTALS (kg/yr)
Raw Material Main SectionGlucosa 15,750
Water 522,220
Biomass 0
Air 5,289,215
TOTAL 5,827,185
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3. STREAM DETAILS
Stream Name S-109Entrada de aire
industrNutrientes agua
Source INPUT P-7 INPUT INPUT
Destination P-7 P-3 P-1 P-1
Stream PropertiesActivity (U/ml) 0.00 0.00 0.00 0.00
Temperature (°C) 25.00 40.00 25.00 25.00
Pressure (bar) 1.01 6.01 1.01 1.01
Density (g/L) 1.18 6.66 1,509.84 994.70
Total Enthalpy (kW-h) 0.00 793.86 0.00 0.00
Specific Enthalpy (kcal/kg) 0.00 3.63 0.00 0.00
Heat Capacity (kcal/kg-°C) 0.24 0.24 0.30 1.00
Component Flowrates (kg/batch)Nitrogen 144,265.639 144,265.639 0.000 0.000
Oxygen 43,796.253 43,796.253 0.000 0.000
Glucosa 0.000 0.000 630.000 0.000
Water 0.000 0.000 0.000 20,888.791
TOTAL (kg/batch) 188,061.892 188,061.892 630.000 20,888.791
TOTAL (L/batch) 159,479,685.725 28,224,764.435 417.264 21,000.000
Stream Name S-101 S-102 S-104 S-103
Source P-1 P-6 P-6 P-4
Destination P-6 P-4 P-5 P-2
Stream PropertiesActivity (U/ml) 0.00 0.00 0.00 0.00
Temperature (°C) 25.00 25.00 25.00 25.00
Pressure (bar) 10.12 10.12 10.12 10.12
Density (g/L) 1,004.74 1,004.74 1,004.74 1,004.74
Total Enthalpy (kW-h) 0.00 0.00 0.00 0.00
Specific Enthalpy (kcal/kg) 0.00 0.00 0.00 0.00
Heat Capacity (kcal/kg-°C) 0.98 0.98 0.98 0.98
Component Flowrates (kg/batch)Glucosa 630.000 63.000 567.000 63.000
Water 20,888.791 2,088.879 18,799.912 2,088.879
TOTAL (kg/batch) 21,518.791 2,151.879 19,366.912 2,151.879
TOTAL (L/batch) 21,417.264 2,141.726 19,275.537 2,141.726
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Stream Name Preinoculoentrada de aire
inoculoVenteo
inoculaciónInoculo
industrial
Source INPUT INPUT P-2 P-2
Destination P-2 P-2 OUTPUT P-3
Stream PropertiesActivity (U/ml) 0.00 0.00 0.00 0.00
Temperature (°C) 25.00 25.00 25.00 25.00
Pressure (bar) 1.01 1.01 1.01 1.01
Density (g/L) 1,050.00 1.18 1.18 995.22
Total Enthalpy (kW-h) 0.00 0.00 1.98 0.00
Specific Enthalpy (kcal/kg) 0.00 0.00 0.07 0.00
Heat Capacity (kcal/kg-°C) 1.00 0.24 0.24 1.00
Component Flowrates (kg/batch)Biomass 0.010 0.000 0.000 20.908
Carb. Dioxide 0.000 0.000 59.858 0.000
Nitrogen 0.000 18,032.427 18,034.366 0.000
Oxygen 0.000 5,474.296 5,434.425 0.000
Water 0.000 0.000 0.000 2,111.591
TOTAL (kg/batch) 0.010 23,506.723 23,528.648 2,132.499
TOTAL (L/batch) 0.010 19,934,100.972 19,938,585.181 2,142.745
Stream Name S-106 Salida industrial Cosecha medio agotado
Source P-5 P-3 P-3 P-9
Destination P-3 OUTPUT P-9 OUTPUT
Stream PropertiesActivity (U/ml) 0.00 0.00 0.00 0.00
Temperature (°C) 25.00 25.00 25.00 25.14
Pressure (bar) 10.12 1.01 1.01 1.01
Density (g/L) 1,004.74 1.18 995.22 994.66
Total Enthalpy (kW-h) 0.00 17.85 0.00 3.28
Specific Enthalpy (kcal/kg) 0.00 0.08 0.00 0.14
Heat Capacity (kcal/kg-°C) 0.98 0.24 1.00 1.00
Component Flowrates (kg/batch)Biomass 0.000 0.000 208.988 2.090
Carb. Dioxide 0.000 538.714 0.000 0.000
Nitrogen 0.000 144,285.023 0.000 0.000
Oxygen 0.000 43,438.008 0.000 0.000
Glucosa 567.000 0.000 0.000 0.000
Water 18,799.912 0.000 21,115.913 19,939.900
TOTAL (kg/batch) 19,366.912 188,261.745 21,324.901 19,941.990
TOTAL (L/batch) 19,275.537 159,522,186.264 21,427.368 20,049.090
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Stream Name biomasa S-117 residual
Source P-9 P-11 P-8
Destination P-11 P-8 OUTPUT
Stream PropertiesActivity (U/ml) 0.00 0.00 0.00
Temperature (°C) 25.14 25.00 40.00
Pressure (bar) 1.01 1.01 1.01
Density (g/L) 1,002.56 994.92 989.47
Total Enthalpy (kW-h) 0.23 0.00 24.07
Specific Enthalpy (kcal/kg) 0.14 0.00 14.97
Heat Capacity (kcal/kg-°C) 1.00 1.00 1.00
Component Flowrates (kg/batch)Biomass 206.898 5.653 5.653
Citric Acid 0.000 120.747 120.747
residuos 0.000 80.498 80.498
Water 1,176.013 1,176.013 1,176.013
TOTAL (kg/batch) 1,382.911 1,382.911 1,382.911
TOTAL (L/batch) 1,379.381 1,389.974 1,397.627
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4. OVERALL COMPONENT BALANCE (kg/batch)
COMPONENT INITIAL INPUT OUTPUT FINAL IN-OUTBiomass 0.000 0.010 7.743 0.000 - 7.733
Carb. Dioxide 0.000 0.000 598.572 0.020 - 598.592
Nitrogen 48.179 162,298.066 162,319.388 26.856 0.000
Citric Acid 0.000 0.000 120.747 0.000 - 120.747
Oxygen 14.626 49,270.548 48,872.433 8.140 404.602
residuos 0.000 0.000 80.498 0.000 - 80.498
Glucosa 0.000 630.000 0.000 0.000 630.000
Water 0.000 20,888.791 21,115.913 0.000 - 227.122
TOTAL 62.805 233,087.415 233,115.294 35.016 0.090
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5. EQUIPMENT CONTENTS
V-101
Procedure Operation Time (in h) Volume (in L)P-1 START 0.000 0.000
P-1 CHARGE-1 (Charge) 0.917 417.264
P-1 CHARGE-2 (Charge) 4.167 21,417.264
P-1 AGITATE-1 (Agitation) 5.167 21,417.264
P-1 TRANSFER-OUT-1 (Transfer Out) 7.417 0.000
SFR-101
Procedure Operation Time (in h) Volume (in L)P-2 START 11.417 0.000
P-2 CHARGE-1 (Charge) 11.917 0.010
P-2 TRANSFER-IN-1 (Transfer In) 12.517 2,141.736
P-2FERMENT-1 (Batch Stoich.Fermentation)
300.517 2,142.745
P-2 TRANSFER-OUT-1 (Transfer Out) 303.767 0.000
FR-101
Procedure Operation Time (in h) Volume (in L)P-3 START 304.517 0.000
P-3 TRANSFER-IN-1 (Transfer In) 305.767 2,142.745
P-3 TRANSFER-IN-2 (Transfer In) 308.017 21,418.283
P-3FERMENT-1 (Batch Stoich.Fermentation)
596.017 21,427.368
P-3 TRANSFER-OUT-1 (Transfer Out) 599.267 0.000