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    Mud Composition

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    Composition:Phases

    Phases of a Drilling Fluid

    Water (continuous) phase

    Reactive commercial clay solids

    Reactive formation (drilled) solids

    Inert formation (drilled) solids

    Inert commercial solids

    Soluble chemicals

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    Composition:Water phase

    Definition: The continuous (liquid)phase of the drilling fluid (mud)

    Can be fresh water, brackish water, seawater, saturated salt water, or another

    type of brine fluid

    Can be hard water containing a high

    concentration of calcium or magnesium

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    Composition:Fresh water

    Usually available only on land locations

    Advantages:

    Commercial clays hydrate more

    Most chemicals are more soluble

    Disadvantages:

    Formation clays hydrate more, whichcan result in hole problems anddamage to the producing zone

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    Composition:Brackish water

    Usually in a marine environment

    Slightly salty

    Higher calcium and magnesium than

    fresh water

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    Composition:Sea water

    Chlorides and hardness varies

    Chlorides in Gulf of Mexico 15,000 -

    30,000 mg/l Calcium in Gulf of Mexico 400 mg/l

    Magnesium in Gulf of Mexico 1200

    mg/l Hardness in North Sea much higher

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    Composition:Saturated salt water

    Used primarily to drill through large saltformations

    Salt must be added to achieve saturation Prevents hole enlargement due to

    leaching or dissolving salt from the

    formation Leaching could result in hole problems

    and expensive mud and cement costs

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    Composition:Brine water

    Usually used for clay (shale) inhibition

    Potassium chloride (KCl)

    Calcium Chloride CaCl2

    Formates (Na+, K+)

    Bromides

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    Composition:Reactive solids

    S.G. = 2.6, Density = 21.67 ppg

    Commercial clays

    Sodium Montmorillonite or bentonite

    M-I GEL

    Attapulgite

    SALT GEL

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    Composition:Reactive solids

    Formation clays (drilled solids)

    S.G. = 2.6, Density = 21.67 ppg

    Montmorillonite (swelling clay)

    Illite (non-swelling clay)

    Kaolinite (non-swelling clay)

    Chlorite (non-swelling clay)

    Gumbo Shale (combination of aboveclays)

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    Composition:Inert solids

    Commercial

    Barite (barium sulfate)

    S.G. = 4.2, Density = 35 ppg

    (M-I BAR)

    Used to increase mud density up to

    maximum of 22 ppg

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    Composition:Inert solids

    Hematite (iron oxide)

    S.G. = 5.0, Density = 41.67 ppg

    Fer-Ox

    Used to increase mud density up tomaximum of 25 ppg

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    Composition:Inert solids

    Calcium Carbonate

    S.G. = 2.8, Density = 23.34 ppg

    Acid soluble

    Lo-Wate

    Used to increase fluid density up to

    maximum of 14.0 ppg Used as bridging agent in drill-in,

    oil and synthetic fluids

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    Composition:Inert solids

    Lost Circulation Material

    Material used to bridge off (seal)

    formations where whole mud is beinglost to the formation

    Nut shells (mostly pecan & walnut)

    Mica Fiber (wood, paper, plastic, etc.)

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    Composition:Inert solids

    Formation solids

    S.G. = 2.6 , Density = 21.67 ppg

    Sand

    Limestone

    Dolomite

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    Composition:Soluble chemicals

    Caustic Soda (NaOH) pH 13.3

    Caustic Potash (KOH) pH 13.3

    Lime [Ca(OH)2] pH 12.4

    Soda Ash (Na2CO3) pH 11 - 11.5

    Sodium Bicarb (NaHCO3) pH 8.4

    Zinc Oxide (ZnO)

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    Composition:Soluble chemicals

    Lignosulfonate (organic acid)

    Spersene (chrome lignosulfonate)

    Spersene CF (chrome-freelignosulfonate)

    Chemical de-flocculant (mud thinner)

    adds anionic (negative) charges to themud.

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    Composition:Soluble chemicals

    Lignite (organic acid)

    Tannathin (lignite)

    XP-20 (chrome lignite)

    Chemical de-flocculant (mud thinner)adds anionic (negative) charges to the

    mud. Neutralizes positive sites on the clays

    causing them to repel each other.