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13NANO DIGEST February 2011

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BET surface area, m2g-1

Cumulative pore volume, m3g-1

Pore area, m2g-1

Average pore diameter, nm

523 0.58 496 0.65

Table 1. Surface properties of Molecularly imprinted polymer

PAH Initial concentration, ug L-1

Residual concentration of PAHs after adsorption onto MIP and other adsorbents, ug L-1 (%adsorbed on the adsorbents) MIP PAC XAD

Chrysene 0.96 0.63 (66) 0.33 (34) 0.24 (25) Benzo[a]pyrene 0.98 0.67 (68) 0.37 (38) 0.26 (26) Benzo[b]fluoranthene 0.92 0.53 (61) 0.32 (35) 0.21 (23) Indeno[1,2,3-c,d] pyrene

0.94 0.69 (71) 0.34 (36) 0.19 (20)

Dibenzo[a,h] anthracene

0.98 0.61 (62) 0.29 (30) 0.22 (22)

5PAHs 4.78 1.93 (40) 1.31 (27) 1.12 (23)

Sediment (Costal) Samples (BS) (10g)

Wastewater (industrial effluent) Sample (WW) (1L)

Industrial ly Originated dust (Particulate) Samples (IOD) (10g)

PAH standard (10L)

Rec (%) RSD LOD

Rec (%) RSD LOD

Rec (%)

RSD LOD

Rec. (%) RSD LOD

Chrysene 91 3.5 7 84 5.3 10 92 3.1 34 102 4.3 3 Benzo[a]pyrene 95 1.2 14 98 4.4 17 91 2.4 97 98 5.0 5 Benzo[b]fluoranthene 82 2.4 11 87 6.1 12 90 1.9 68 97 4.4 5 Indeno[1,2,3-c,d] pyrene 86 3.5 8 83 4.3 19 87 2.5 38 107 4.7 6

Dibenzo[a,h] anthracene 83 2.5 10 91 4.8 14 90 3.1 7 100 4.2 6

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