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Biomimetic and Nature-Inspired Surfaces: Innovation in Chemistry and Engineering

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Page 1: Biomimetic and Nature-Inspired Surfaces: Innovation in

Biomimetic

and

Nature-Inspired Surfaces:

Innovation in Chemistry

and Engineering

Page 2: Biomimetic and Nature-Inspired Surfaces: Innovation in

Yoseph Bar-Cohen-Biomimetics_ Nature-Based Innovation-CRC Press (2011)

Biomimetics and Bio-Inspired Engineering

Page 3: Biomimetic and Nature-Inspired Surfaces: Innovation in

Yoseph Bar-Cohen-Biomimetics_ Biologically Inspired Technologies-CRC Press (2005)

Biological vs. Synthetic Polymers and Materials

Page 4: Biomimetic and Nature-Inspired Surfaces: Innovation in

Nature Uses Surface and Interfacial Tensions

Annu. Rev. Fluid. Mech. 2006.38:339-369.

Page 5: Biomimetic and Nature-Inspired Surfaces: Innovation in

Nature Uses Surface and Interfacial Tensions

Page 6: Biomimetic and Nature-Inspired Surfaces: Innovation in

Nature, 2004, 432, 36.

Nature Uses Surface and Interfacial Tensions

Page 7: Biomimetic and Nature-Inspired Surfaces: Innovation in

Nature, 2004, 432, 36.

Nature Uses Surface and Interfacial Tensions

https://youtu.be/Z83l347rh6E?t=9

Page 8: Biomimetic and Nature-Inspired Surfaces: Innovation in

Nature Uses Surface and Interfacial Tensions

Page 9: Biomimetic and Nature-Inspired Surfaces: Innovation in

Nature Uses Surface and Interfacial Tensions

Page 10: Biomimetic and Nature-Inspired Surfaces: Innovation in

Elizabeth Pennisi Science 2014;343:1194-1197

Published by AAAS

Page 11: Biomimetic and Nature-Inspired Surfaces: Innovation in

The Cheerio Effect

Cheerio Effect-NIcNrsTlbVU_x264

Page 12: Biomimetic and Nature-Inspired Surfaces: Innovation in

The Cheerio Effect

From: Karpitschka et al., Liquid drops attract or repel by the inverted Cheerios effect, PNAS 2016, 113, 7403–7407,

doi: 10.1073/pnas.1601411113

See also: Anand Jagota, Role reversal: Liquid “Cheerios” on a solid sense each other, PNAS, 2016, 113, 7294–7295, doi:

10.1073/pnas.1607893113

Page 13: Biomimetic and Nature-Inspired Surfaces: Innovation in

Superhydrophobic on the Top Surface

Superoleophobic on the Bottom Surface

The Lotus Leaf

Water Drops

Hexane Drops

Page 14: Biomimetic and Nature-Inspired Surfaces: Innovation in

The Lotus Leaf and Rose Petal Effects

Water Drops

Hexane Drops

lotus leaf and rose petal effect

Page 15: Biomimetic and Nature-Inspired Surfaces: Innovation in

Zoom Into a Lotus Leaf (Narrated)

Zoom Into the Upper Side of a Lotus Leaf

Page 16: Biomimetic and Nature-Inspired Surfaces: Innovation in

Defining Hydrophilic and Hydrophobic Surfaces from Contact Angle

Page 17: Biomimetic and Nature-Inspired Surfaces: Innovation in

Defining Oleophilic and Oleophobic Surfaces from Contact Angle

Page 18: Biomimetic and Nature-Inspired Surfaces: Innovation in

Water Drop Bouncing on a Superhydrophobic Surface

Bouncing Water Droplet Falling onto Super-Hydrophobic Surface-riXp_Q-fDv8_x264

Page 19: Biomimetic and Nature-Inspired Surfaces: Innovation in

Removing Water Drops from Hydrophilic and Hydrophobic Surfaces

Page 20: Biomimetic and Nature-Inspired Surfaces: Innovation in

Practical Applications of Superhydrophobic Surfaces

The SECOND Official Ultra-Ever Dry Video - Superhydrophobic coating - Repels almost any liquid!-BvTkefJHfC0_x264

Page 21: Biomimetic and Nature-Inspired Surfaces: Innovation in

Yongmei, Zheng-Bio-inspired wettability surfaces _ developments in micro- and nanostructures-Pan Stanford Publishing (2016)

The Underside of the Lotus Leaf

Page 22: Biomimetic and Nature-Inspired Surfaces: Innovation in

Yongmei, Zheng-Bio-inspired wettability surfaces _ developments in micro- and nanostructures-Pan Stanford Publishing (2016)

The Underside of the Lotus Leaf

Page 23: Biomimetic and Nature-Inspired Surfaces: Innovation in

Yongmei, Zheng-Bio-inspired wettability surfaces _ developments in micro- and nanostructures-Pan Stanford Publishing (2016)

Similarly Patterned Superoleophobic Fish Scales

Page 24: Biomimetic and Nature-Inspired Surfaces: Innovation in

Biomimetic Nanomaterials_chap01

Shark Skin and Sharkskin-Mimetic Surfaces

Page 25: Biomimetic and Nature-Inspired Surfaces: Innovation in

Yongmei, Zheng-Bio-inspired wettability surfaces _ developments in micro- and nanostructures-Pan Stanford Publishing (2016)

Lotus Leaf Mimetics of Both Surfaces

Page 26: Biomimetic and Nature-Inspired Surfaces: Innovation in

Yongmei, Zheng-Bio-inspired wettability surfaces _ developments in micro- and nanostructures-Pan Stanford Publishing (2016)

Lotus Leaf Mimetics of Both Surfaces

Page 27: Biomimetic and Nature-Inspired Surfaces: Innovation in

Switchable Wetting of Surfaces

Page 28: Biomimetic and Nature-Inspired Surfaces: Innovation in

The Aquatic Plant Salvinia molesta

Giant Salvinia - A Very Wicked Plant-CWsq7cX3tWg_x264

Page 29: Biomimetic and Nature-Inspired Surfaces: Innovation in

Bharat Bhushan-Biomimetics_ Bioinspired Hierarchical-Structured Surfaces for Green Science and Technology, Springer-Verlag, 2012.

The Aquatic Plant Salvinia molesta

Hairs with

Hydrophilic

Tips that

secure the

water drops

Page 30: Biomimetic and Nature-Inspired Surfaces: Innovation in

Mosquito Eye (2005) Scanning Electron Microscope Zoom

Scanning Electron Microscope Zoom of the Mosquito Eye

Page 31: Biomimetic and Nature-Inspired Surfaces: Innovation in

Xuefeng Gao, Xin Yan, Xi Yao, Liang Xu,

Kai Zhang, Junhu Zhang, Bai Yang, and

Lei Jiang, “The Dry-Style Antifogging

Properties of Mosquito Compound Eyes

and Artificial Analogues Prepared by Soft

Lithography”, Adv. Mater. 2007, 19,

2213–2217.

Anti-Fogging Mosquito Eyes

http://www.photomacrography.net/forum/viewtopic.php?t=854

7

Two Adjacent Omatidia Nano-Nipples on the Omatidia

A Water Drop on the

Artificial Biomimetic Surface

Page 32: Biomimetic and Nature-Inspired Surfaces: Innovation in

Holger F. Bohn and Walter Federle, “Insect

aquaplaning: Nepenthes pitcher plants

capture prey with the peristome, a fully

wettable water-lubricated anisotropic

surface”, PNAS, 101, 14138–14143 (2004).

Ulrike Bauer and Walter Federle, ”The

insect-trapping rim of Nepenthes pitchers.

Surface structure and function”, Plant

Signaling & Behavior, 4, 1019-1023 (2009).

Tak-Sing Wong, Sung Hoon Kang, Sindy K. Y.

Tang, Elizabeth J. Smythe, Benjamin D.

Hatton, Alison Grinthal & Joanna Aizenberg.

“Bioinspired self-repairing slippery surfaces

with pressure-stable omniphobicity”,

Nature, 477, 443-447 (2011).

Insect Capture by the Insectivorous Plant Nepenthes

Page 33: Biomimetic and Nature-Inspired Surfaces: Innovation in

How flesh-eating pitcher plants trap insects-ya2ndp1OrPQ_x264

The Insectivorous Pitcher Plant Nepenthes

Page 34: Biomimetic and Nature-Inspired Surfaces: Innovation in

MythBusters - Banana Peel Slip

MythBusters - Banana Peel Slip

Page 35: Biomimetic and Nature-Inspired Surfaces: Innovation in

Police demonstrate the effectiveness of 'instant banana peel' as a tool to curb ...HD Stock Footage

Instant Banana Peel or Riotrol

Page 36: Biomimetic and Nature-Inspired Surfaces: Innovation in

Pista de ski em São Roque-SP

Sliding Angle Permits Skiing in Tropical Brazil

Page 37: Biomimetic and Nature-Inspired Surfaces: Innovation in

Functional Biomimetic Surfaces - Durham University

Page 38: Biomimetic and Nature-Inspired Surfaces: Innovation in

Yongmei, Zheng-Bio-inspired wettability surfaces _ developments in micro- and nanostructures-Pan Stanford Publishing (2016)

Namib Desert Beetle Wing Cover Surface

Page 39: Biomimetic and Nature-Inspired Surfaces: Innovation in

Nature Using Surface and Interfacial Tensions

http://www.yankodesign.com/2010/07/05/beetle-juice-inspired/

http://thireaultdesign.blogspot.com.br/2011/09/namib-desert-

beetles.html

Namib Desert Beetle

Hydrophilic bumps/Hydrophobic channels

Page 40: Biomimetic and Nature-Inspired Surfaces: Innovation in

Primitive Man Watching Nature Use Surface and Interfacial Tensions

Atacama

Desert

Oxidized Nylon fishing line

L. Sepúlveda, Univ. Chile (1983)

Page 41: Biomimetic and Nature-Inspired Surfaces: Innovation in

Bio-Inspired Fog Harvesting – Durham University

Page 42: Biomimetic and Nature-Inspired Surfaces: Innovation in

Superhydrophobic Surfaces – Durham University

Page 43: Biomimetic and Nature-Inspired Surfaces: Innovation in

Superhydrophilicity

http://www.iskweb.co.jp/eng/products/functional05.html

Page 44: Biomimetic and Nature-Inspired Surfaces: Innovation in

Yongmei, Zheng-Bio-inspired wettability surfaces _ developments in micro- and nanostructures-Pan Stanford Publishing (2016)

Water Drops on a Spider Web

Page 45: Biomimetic and Nature-Inspired Surfaces: Innovation in

Yongmei, Zheng-Bio-inspired wettability surfaces _ developments in micro- and nanostructures-Pan Stanford Publishing (2016)

Spider Silk

Page 46: Biomimetic and Nature-Inspired Surfaces: Innovation in

Yongmei, Zheng-Bio-inspired wettability surfaces _ developments in micro- and nanostructures-Pan Stanford Publishing (2016)

Spindles on Spider Silk

Page 47: Biomimetic and Nature-Inspired Surfaces: Innovation in

Yongmei, Zheng-Bio-inspired wettability surfaces _ developments in micro- and nanostructures-Pan Stanford Publishing (2016)

Time-Dependence of Directional Water Collection by a Spider Web

Page 48: Biomimetic and Nature-Inspired Surfaces: Innovation in

Yongmei, Zheng-Bio-inspired wettability surfaces _ developments in micro- and nanostructures-Pan Stanford Publishing (2016)

Nature Uses Surface and Interfacial Tensions

Page 49: Biomimetic and Nature-Inspired Surfaces: Innovation in

Mechanism of directional water collection on

wet-rebuilt spider silk.

Nature, 2010, 463, 640-643.

Nature Uses Surface and Interfacial Tensions

Page 50: Biomimetic and Nature-Inspired Surfaces: Innovation in

Yongmei, Zheng-Bio-inspired wettability surfaces _ developments in micro- and nanostructures-Pan Stanford Publishing (2016)

Making Fibers with Artificial Spindles

Page 51: Biomimetic and Nature-Inspired Surfaces: Innovation in

Fluid-Coating Method for Making Fibers with Artificial Spindles

Yongmei, Zheng-Bio-inspired wettability surfaces _ developments in micro- and nanostructures-Pan Stanford Publishing (2016)

Page 52: Biomimetic and Nature-Inspired Surfaces: Innovation in

Yongmei, Zheng-Bio-inspired wettability surfaces _ developments in micro- and nanostructures-Pan Stanford Publishing (2016)

Applications:

Controlling the Motion of Liquid Drops

High Efficiency Water Collection

Enhanced Solid-Liquid Adhesion

Fibers Responsive to their Environment

Page 53: Biomimetic and Nature-Inspired Surfaces: Innovation in

Bharat Bhushan-Biomimetics_ Bioinspired Hierarchical-Structured Surfaces for Green Science and Technology, Springer-Verlag, 2012.

Bio-Inspired and Biomimetic Adhesion

Page 54: Biomimetic and Nature-Inspired Surfaces: Innovation in

Yongmei, Zheng-Bio-inspired wettability surfaces _ developments in micro- and nanostructures-Pan Stanford Publishing (2016)

Spider Capture Silk

Page 55: Biomimetic and Nature-Inspired Surfaces: Innovation in

The Insectivorous Sundew Plant Drosera

Drosera hunting insect-_ebJ6Fgr0Vg_x264

Page 56: Biomimetic and Nature-Inspired Surfaces: Innovation in

Bharat Bhushan-Biomimetics_ Bioinspired Hierarchical-Structured Surfaces for Green Science and Technology, Springer-Verlag, 2012.

The Tokay Gecko Foot

Page 57: Biomimetic and Nature-Inspired Surfaces: Innovation in

The Gecko Foot

Smart materials (1 of 5)_ Gecko Adhesive fit for Spiderman-gzm7yD-JuyM_x264

Page 58: Biomimetic and Nature-Inspired Surfaces: Innovation in

Bharat Bhushan-Biomimetics_ Bioinspired Hierarchical-Structured Surfaces for Green Science and Technology, Springer-Verlag, 2012.

A Tokay Gecko Foot Mimic

Page 59: Biomimetic and Nature-Inspired Surfaces: Innovation in

Gecko Foot Peeling Off Surfaces

Cremaldi et al. In: Havazelet Bianco-Peled_ Maya Davidovich-Pinhas-Bioadhesion and biomimetics _ from nature to applications-Pan Stanford Publishing (2015), pp. 85ff

Page 60: Biomimetic and Nature-Inspired Surfaces: Innovation in

Gecko Foot Inspired Adhesive Patch

Raz Jelinek, Biomimetics-A Molecular Perspective-de Gruyter (2013)

Page 61: Biomimetic and Nature-Inspired Surfaces: Innovation in

Smart materials (1 of 5)_ Gecko Adhesive fit for Spiderman-gzm7yD-JuyM_x264

Smart materials based on Gecko Adhesion

Page 62: Biomimetic and Nature-Inspired Surfaces: Innovation in

Bharat Bhushan-Biomimetics_ Bioinspired Hierarchical-Structured Surfaces for Green Science and Technology, Springer-Verlag, 2012.

Fly Feet

Page 63: Biomimetic and Nature-Inspired Surfaces: Innovation in

Yoseph Bar-Cohen-Biomimetics_ Biologically Inspired Technologies-CRC Press (2005)

Biomimetic Attachment Structures of Flies

Page 64: Biomimetic and Nature-Inspired Surfaces: Innovation in

Yoseph Bar-Cohen-Biomimetics_ Biologically Inspired Technologies-CRC Press (2005)

Biomimetic Attachment Structures of Flies

Page 65: Biomimetic and Nature-Inspired Surfaces: Innovation in

Yoseph Bar-Cohen-Biomimetics_ Biologically Inspired Technologies-CRC Press (2005)

Biomimetic Attachment Devices Based on a Tree Frog

Page 66: Biomimetic and Nature-Inspired Surfaces: Innovation in

Mussel Adhesion

https://cosmosmagazine.com/biology/new-underwater-glue-inspired-mussels

Page 67: Biomimetic and Nature-Inspired Surfaces: Innovation in

Byssal threads and adhesive pads are clearly visible in this photo of a mussel attached to a

pane of glass.

Stephen Ornes PNAS 2013;110:16697-16699

©2013 by National Academy of Sciences

Page 68: Biomimetic and Nature-Inspired Surfaces: Innovation in

Mussel Adhesion

Zeng et al. In: Havazelet Bianco-Peled_ Maya Davidovich-Pinhas-Bioadhesion and biomimetics _ from nature to applications-Pan Stanford Publishing (2015), pp. 49ff

Page 69: Biomimetic and Nature-Inspired Surfaces: Innovation in

The adhesion mechanisms of Mussel foot proteins between

mica and Self Assembled Monolayer (SAM) surfaces.

Jing Yu et al. PNAS 2013;110:15680-15685

©2013 by National Academy of Sciences

See also: Levine et al., Surface force measurements and simulations of mussel-derived peptide adhesives on wet

organic surfaces, PNAS 2016, 113, 4332–4337; doi: 10.1073/pnas.1603065113

Page 70: Biomimetic and Nature-Inspired Surfaces: Innovation in

L-Dopa Derived Mussel Glue Mimetics

Ceylan et al. In: Patrick Flammang-Biological and biomimetic adhesives-Royal Society of Chemistry (2013), pp. 103ff

Page 71: Biomimetic and Nature-Inspired Surfaces: Innovation in

The Centipede Henia vesuviana

www.zobodat.at/pdf/BERI_S10_0071-0079.pdf

Page 72: Biomimetic and Nature-Inspired Surfaces: Innovation in

2008 2014 2012 2009

2010 2014 2016

http://www.intechopen.com/books/

biomimetics-learning-from-nature

2012 2006

2010

Page 73: Biomimetic and Nature-Inspired Surfaces: Innovation in

2015 2014 2015 2015

2013 2015 2014 2015 2011

2015

Page 74: Biomimetic and Nature-Inspired Surfaces: Innovation in

2006 2013 2011

2013 2013

2011

Page 75: Biomimetic and Nature-Inspired Surfaces: Innovation in

Bouncing Drops and Quantum Mechanics

Page 76: Biomimetic and Nature-Inspired Surfaces: Innovation in

#02 Fog Catchers in Atacama Desert - Living Atlas Chile

Fog Catchers in the Atacama Desert – North of Chile

Page 77: Biomimetic and Nature-Inspired Surfaces: Innovation in

Frank H. QuinaInstituto de Química

Universidade de São Paulo

São Paulo

e-mail: [email protected]

Associated Laboratory