M/s. Supreme Chemical Industries. GIDC Vatva, Ahmedabad-382445

M/s. Jyoti Om Chemical Research Centre Pvt. Ltd. 13

ANNEXURE-I PROPOSED TERMS OF REFERENCE

Standard TOR of MoEF & CC for organic sector will be followed.

M/s. Jyot

COPY OF C

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CTE

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h Centre Pvt

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DC Vatva, A

Ahmedabad

ANNEX

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XURE-II

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ti Om Chem

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upreme Chem

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mical Indus

t. Ltd.

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DC Vatva, A

Ahmedabad

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M/s. Jyot

COPY OF C

ti Om Chem

CCA

M/s. Su

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upreme Chem

h Centre Pvt

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t. Ltd.

stries. GID

DC Vatva, A

Ahmedabad

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ti Om Chem

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upreme Chem

h Centre Pvt

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Ahmedabad

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upreme Chem

h Centre Pvt

mical Indus

t. Ltd.

stries. GID

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Ahmedabad

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M/s. Jyotti Om Chem

M/s. Su

ical Research

upreme Chem

h Centre Pvt

mical Indus

t. Ltd.

stries. GID

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Ahmedabad

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upreme Chem

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t. Ltd.

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Ahmedabad

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M/s. Supreme Chemical Industries. GIDC Vatva, Ahmedabad-382445

M/s. Jyoti Om Chemical Research Centre Pvt. Ltd. 21

ANNEXURE-III

LIST OF EXISTING & PROPOSED PRODUCTS AND THEIR PRODUCTION CAPACITY

Sr. No.

Product Name

As Per Valid CCA No.

AWH-49560 (MT/Month)

Existing as per CTE

Amendment No-55251

(MT/Month)

Proposed Quantity

(MT/Month)

Total after expansion Quantity

(MT/Month)

1. Copper Sulphate 30 -20 --- 10 2. Copper Hydroxide 15 -15 --- 0 3. Copper Carbonate 15 -15 --- 0 4. Pigment Beta Blue --- --- 150 150 5. Pigment Blue Additives --- --- 25 25 6. Grinding operation of Blue

ADBM --- 50 --- 50

Total 60 50 175 235

M/s. Supreme Chemical Industries. GIDC Vatva, Ahmedabad-382445

M/s. Jyoti Om Chemical Research Centre Pvt. Ltd. 22

ANNEXURE-IV LIST OF PROPRIETOR

Sr. No.

Name of Proprietor Designation Residential Address Mobile No.

1. Mr. G. Jayabal Proprietor No.3, Bhumi Bunglow, Opp. Bank of Baroda,

Maninagar Cross Road, Maninagar,

Ahmedabad-380008

+91 94260 76089

GROUND FLOOR

FIRST FLOOR PLAN @ +6.00 MTR SECOND FLOOR PLAN @ +12.00 MTR

2

OF C

AS

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OF BLOWER

125NB-150#

125NB-150#

125NB-150#

125NB-150#

R.I

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TERRACE LVL PLAN

2

HITESH

PROPOSED PLOT LAYOUT FOR

INQ. 2017-02-0397

M/s SUPREME CHEMICALS, VATVA

R2

M/s. Supreme Chemical Industries. GIDC Vatva, Ahmedabad-382445

M/s. Jyoti Om Chemical Research Centre Pvt. Ltd. 24

ANNEXURE-VI

LIST OF PROPOSED RAW MATERIALS

Sr. No.

Name of Product Production quantity in MT/Month

Name of Raw material

Raw material consumption quantity in MT/Month

1 Copper Sulphate

10 Sulphuric Acid 30.0 Copper 10.0

2 Activation of CPC Blue (Grinding process)

50 Copper Phthalocyanine Blue 50.0

3 Pigment Blue Additives

25 Sulphuric Acid 100.0 Phthalamide 7.5 Para formaldehyde 2.5 Copper Phthalocyanine Blue 21.0

4 Pigment Beta Blue

150 Copper Phthalocyanine Blue 160.0 Dilute HCL 3.0 IBA/Xylene 1.6 Caustic Lye 4.0

M/s. Supreme Chemical Industries. GIDC Vatva, Ahmedabad-382445

M/s. Jyoti Om Chemical Research Centre Pvt. Ltd. 25

ANNEXURE-VII

BRIEF MANUFACTURING PROCESS EXISTING PRODUCT MANUFACTURING PROCESSAND CHEMICAL REACTION AND MATERIAL BALANCE (as per CTE)

1. Copper Sulphate Process Description In Empty Clean Reactor take 98% Sulphuric Acid 4000 Kgs charge slowly copper in small piece raise temperature to 600 Stir it and drown mass in 5000 Liters water and maintain for 2 hours. Then Filter in filter press and mother liquor to be collected in storage tank as dilute sulphuric Acid around 50 % and it will be stored for reuse and recycling purpose. In filter press aeration to be given for 6 hrs then unload the wet cake and pack as per customer requirement. There is no generation of effluent and entire dilute sulphuric acid reused and recycled for the next coming batches.

M/s. Supreme Chemical Industries. GIDC Vatva, Ahmedabad-382445

M/s. Jyoti Om Chemical Research Centre Pvt. Ltd. 26

Process flow diagram

Reactor

Sulphuric Acid + Copper

Filtration

Drowning

Aeration

Unloading

Final Packing Copper Sulphate

M/s. Supreme Chemical Industries. GIDC Vatva, Ahmedabad-382445

M/s. Jyoti Om Chemical Research Centre Pvt. Ltd. 27

2. Grinding operation of Blue ADBM (Activated CPC Blue)

Process Description CPC Blue Crude charged in Ball mill and activation to be carried out from 18 hours to 24 hours as per the customer requirement and to be unloaded and to be packed through dust collector, Magnet, siever and screw conveyor. Process Flow Diagram

CPC Blue Crude Milling

Dust Collector

Unloading

Magnet

Siever

Screw Conveyor

Final Packing of Activated CPC Blue

Ball mill

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M/s. Supreme Chemical Industries. GIDC Vatva, Ahmedabad-382445

M/s. Jyoti Om Chemical Research Centre Pvt. Ltd. 29

Material Balance

Input Kg Output Kg

Copper phthalocyanine 1030 Reaction Mass 1130

Salt 100 Ball Mill

Total 1130 Total 1130

Input Kg Output Kg

Reaction Mass 1130 Reaction Mass 3461Dilute HCL 20

Caustic Soda Flakes 11

Water 1800 Reaction Vessel

IBA/Xyalene (Fresh) 10Recovered IBA/Xyalene 490

Total 3461 Total 3461

Input Kg Output Kg

Reaction Mass 3461 Recovered IBA/Xyalene 490

Live steam 320 Distillation Atmosphere solvent loss 10Reaction Mass 3281

Total 3781 Total 3781

Input Kg Output Kg

Reaction Mass 3281 Effleunt  5481

Water (Washing) 4930 Filter Press Reaction Mass 2730

Total 8211 Total 8211

Input Kg Output Kg

Reaction Mass 2730 Evporation loss 1730

Dryer/SFD Product 1000

Total 2730 Total 2730

M/s. Supreme Chemical Industries. GIDC Vatva, Ahmedabad-382445

M/s. Jyoti Om Chemical Research Centre Pvt. Ltd. 30

2. Pigment Blue Additives Process Description Charge Sulphuric Acid in Reaction Vessel. Add CPC slowly at room temperature with vigorous stirring. Then Charge required Phthalamide and Para formaldehyde stir for one hours, Allow the reaction to be completed by raising temperature up to 80 Degree and maintain for 8 Hours and then drown the mass from vessel to MSRL vessel containing ice, & water. Settle it for 10 hrs. Then stir again and filter through filter press. Discharge the wet cake from filter press. Then pack it into drums and bags. Chemical Reaction Chemical Formula

H2SO4 + C32H16N8Cu4 HSO2C32H14N2Cu + 3H2O

Chemical Name

Sulphuric Acid

Copper

Phthalocyanine Blue

Blue Additive Water

M.W. 98 764 170 54

Material Balance

Input Kg Output Kg

CPC 375 Reaction Mass 2250

Oleum (23‐25%) 1500 M.S. Reaction vesselH2SO4 375

Total 2250 Total 2250

Input Kg Output Kg

1st Wash 4500 Effluent 68502nd wash 1500 Product (38 %) 1400

Reaction Mass 2250

Drowning Vessel and Filtration  

Total 8250 Total 8250

H2SO4

      1000 

   4900 

Phthalamide 

 PF    110 

      6385

Phthalamide Phthala

    6385 

    5000 

 35885   35885

(30%) Wet Cake  4400By Product Dilute Sulphuric Acid 25‐30% To Novel Spent Acid 

16000Final Washing   20000 

 15485

M/s. Supreme Chemical Industries. GIDC Vatva, Ahmedabad-382445

M/s. Jyoti Om Chemical Research Centre Pvt. Ltd. 31

ANNEXURE-VIII

DETAILS OF FUEL AND ELECTRICITY

Sr. No.

Fuel Existing Proposed Total Remark

1 Natural

Gas 255

SCM/Day 3130

SCM/Day 3385

SCM/Day ---

4 Electricity 350 KW -- 350 KW Torrent Power Ltd. in Vatva

M/s. Supreme Chemical Industries. GIDC Vatva, Ahmedabad-382445

M/s. Jyoti Om Chemical Research Centre Pvt. Ltd. 32

ANNEXURE-IX WATER CONSUMPTION AND WASTEWATER GENERATION

WATER CONSUMPTION

Sr. No.

Category

Existing Quantity [as per

CTE Amendment no: 55251 KL/day

Proposed water

consumption in KL/day

Total water consumption

in KL/day

1. Domestic 0.5 4.5 5 2. Industrial 2.1 Process & washing 1.0 44 45 2.2 Cooling --- 15 15 2.3 Boiler 0.4 16.6 17 3. Gardening --- 9 9

Total (Industrial) 1.4 84.6 86 Total (Domestic + Industrial)

1.9 89.1 91

WASTE WATER GENERATION

Sr. No.

Category

Existing Quantity [as per

CTE Amendment no: 55251 KL/day

Proposed wastewater

consumption in KL/Day

Total Wastewater Generation

KL/Day

1. Domestic 0.3 3.7 4 1.1 Domestic 2. Industrial

2.1 Process & Washing

1.0 39 40

2.2 Cooling --- 5 5 2.3 Boiler --- 10 10 3. Gardening --- --- ---

Total (Industrial ) 1.0 54 55 Total (Domestic + Industrial )

1.3 57.7 59

M/s. Supreme Chemical Industries. GIDC Vatva, Ahmedabad-382445

M/s. Jyoti Om Chemical Research Centre Pvt. Ltd. 33

PROPOSED WATER BALANCE DIAGRAM

C.E.T.P, Vatva 59.0 KL/day

G.I.D.C (91.0 KL/day)

PROCESS & WASHING 45.0 KL/day

COOLING 15.0 KL/day

BOILER 17.0 KL/day

DOMESTIC 5.0 KL/day

BLOW DOWN 5.0 KL/day

BLOW DOWN 10.0 KL/day

E.T.P 59.0 KL/day

SOAKPIT 3.9 KL/day

Effluent 40.0 KL/day

GARDENING 9 KL/day

M/s. Supreme Chemical Industries. GIDC Vatva, Ahmedabad-382445

M/s. Jyoti Om Chemical Research Centre Pvt. Ltd. 34

ANNEXURE-X

DETAILS OF EFFLUENT TREATMENT PLANT EXISTING EFFLUENT TREATMENT PLANT: Raw Effluent Collected in Collection Sump through Oil and Greece trap and pumped to neutralizer. Further it is to be neutralizer by lime water with small quantity of poly electroplate of settling agent and allowed for settling. Superannuated clean water pumped to treat effluent storage tank for further filtration. The Bottom Slurry to be transfer to filter press. Filtrate collected in collection sump. We have Treated effluent from storage tank further to be filtered through filter press to remove SPM. Again filtrate collected in final treated effluent storage tank and pumped to overhead tank send to CETP through pipeline as per the CETP norms. PROPOSED EFFLUENT TREATMENT PROCESS DESCRIPTION: Process description same as above, only capacity increased as mentioned below of ETP Unit. DETAILS OF DIFFERENT ETP UNITS:

Sr. No.

Name of Unit No of Unit

Capacity

1 Collection Sump, RCC RLBL 1 25 KL 2 Neutralizer with Agitator 1 30 KL 3 Lime Preparation Tank 1 2 KL 4 36” Filter Press for Gypsum 1 36X36X49 5 24” Filter Press for Treated Effluent Clarification 1 24X24X35 6 Treated Effluent Storage Tank 1 40 KL 7 Final Treated Effluent Storage Tank 1 40 KL 8 Final Treated Effluent Storage Tank 1 20 KL 9 Dilute Sulphuric Acid Storage Tank for Novel 1 25 KL

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AGRAM

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M/s. Supreme Chemical Industries. GIDC Vatva, Ahmedabad-382445

M/s. Jyoti Om Chemical Research Centre Pvt. Ltd. 36

EFFLUENT QUALITY BEFORE TREATMENT & AFTER TREATMENT IN ETP

Sr. No.

Category of Waste Water Before

Treatment

After Primary

Treatment 1. pH 2 – 5 6.5 – 8.5 2. COD (mg/l) 600 400-500 3. BOD (mg/l) 190 150 4. TDS (mg/l) 3500 2500 5. Ammonical Nitrogen (mg/l) 43 < 20 6. TSS (mg/l) 150 < 100

M/s. Supreme Chemical Industries. GIDC Vatva, Ahmedabad-382445

M/s. Jyoti Om Chemical Research Centre Pvt. Ltd. 37

ANNEXURE-XI FLUE GAS AND PROCESS GAS EMISSIONS

FLUE GAS EMISSIONS

Sr. No.

Stack Attached To

Stack Height (M)

Type of Fuel

Fuel Consumption

Type of Emission

Permissible Limit

APCM

As Per Valid CCA No.-AWH-49560 1. Small

Industrial Boiler

15 Fire Wood

50 Kg/Day

PM

SO2

NOx

150 mg/NM3

100 PPM 50 PPM

---

Note: Existing as per CTE No-55251 There is no flue gas emission from existing unit.

Proposed

1. Thermax

Steam Boiler (850 Kg/hr)

20 Natural

gas 970 SCM/day

SPM SO2

NOx

150 mg/NM3

100 PPM 50 PPM

--

2.

Thermic Fluid Heater (10 Lakh K.

Cal)

20 Natural

gas 2160

SCM/day

SPM SO2

NOx

150 mg/NM3

100 PPM 50 PPM

--

M/s. Supreme Chemical Industries. GIDC Vatva, Ahmedabad-382445

M/s. Jyoti Om Chemical Research Centre Pvt. Ltd. 38

PROCESS EMISSION

Sr. No.

Stack Attached To

Stack Height In Meter

Probable Pollutant Emission

Permissible Limit

APCM

As Per Valid CCA No.-AWH-49560 There is no process emission from existing unit. Existing as per CTE No-55251

1. Ball Mill --- PM 150 mg/NM3

In built Dust Collector

Proposed

1. Spin Flash Dryer 22 PM 150 mg/NM3

Bag Filter

M/s. Supreme Chemical Industries. GIDC Vatva, Ahmedabad-382445

M/s. Jyoti Om Chemical Research Centre Pvt. Ltd. 39

ANNEXURE-XII

DETAILS OF HAZARDOUS WASTE

Sr. No

Hazardous Waste

Waste category

Waste generation quantity

Method of Disposal

Existing Quantity as

per CTE Amendment

No: 55251

Proposed Total

1. ETP Sludge 35.3 0.6

MT/Year 180

MT/Year 180.6

MT/Year

Collection, Storage,

Transportation, Disposal at TSDF

of Green Environment Co.

Op. Soc. Ltd. Vatva,

Ahmedabad.

2. Used Oil 5.1 15

Liter/Month 200

Liter/Year 215

Liter/Year

Collection, Storage and

disposal by selling to registered authorized recyclers.

3. Discarded

Containers & Bags

33.3 600

Nos./Year 2500

Nos./Year 3100

Nos./Year

Collection, Storage, and

Decontamination within factory

premises and sell to authorize

dealer.

4.

By Product Dilute

Sulphuric Acid (Around

25%-30 %)

D2 --- 300

MT/Month 300

MT/Month

Collection, Storage,

Transportation, Disposal at Novel

Spent Acid

M/s. Supreme Chemical Industries. GIDC Vatva, Ahmedabad-382445

M/s. Jyoti Om Chemical Research Centre Pvt. Ltd. 40

Management System

(Approved by GPCB) in Vatva

and obtained permission

M/s. Supreme Chemical Industries. GIDC Vatva, Ahmedabad-382445

M/s. Jyoti Om Chemical Research Centre Pvt. Ltd. 41

ANNEXURE-XIII

DETAILS OF HAZARDOUS CHEMICALS

Sr. No.

Name of Chemical

1 Sulphuric Acid 2 IBA/Xylene 3 Caustic Lye 4 Hydrochloric Acid