2nd puc chemistry jan 2016.pdf
TRANSCRIPT
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8/20/2019 2nd PUC Chemistry Jan 2016.pdf
1/2
SECOND
PUC
PREPARATORY
EXAMINATION
-2,016
lFEdlEl'
Max
Marks:70
Total
No.of
Ques.:37
Time:
3-15
hours
No.of
Pages:
O2
cHEMISTRY
(a+)
General
Instructions:
i]
The
questlon
paper
has
four
pafis A,
B,
C,
and
D.
All_
the
parts are
compulsory
iit
p rt.A
carriei
tb
*u.ir,
Each
question carries
one
mark.
Part-B
caries
10 marks
,
Each
question
carries
two
marks. part-'C
canies
15
marks. Each question
carries
three marks.
Part-D
carries
35
marks
.
Each
question
caries
five
marks.
iii] write
balanced
chemical
equations
and
draw
diagrams
wherever
necessary.
iv]us
logtables
and
simple
calculators
if
necessary.
(Use
of scientifrc
calculators
are
not
allowed)
PART-A
I
AnswerAll
the
questions
in
one
word
or
in
a sentence.Each
q''estion
carries
one
mark.
l0x1:10
k)
What
is
the name
of
the
solution
which
distills
without
chanle
in composition
'
withtemPerature?
2)
Why
is
common
salt
added
to water
used
for
boiling'eggs to
get
hard
boiled
eggs?
2f
One
Coulomb
of electrical
charge
is
passed through
solutions
ofAgNO.
and
CuSOo
connected
in series
using
platinum electrode.
What
is
the mass
ratio
of
Ag/Cu?
g
A
reaction
is 50%
complete
in
4 hours
andl5oh
complets
in
8 hours.
What
is
the
order of
the
reaction
?
5
)
Give
reason.
A lump
of coal burns
at
moderate
rate
in
air,
which
coal
dust
burns
explossively?
6)
IdentiSz
the
reducing
agent
in the
following
reactions
3MnO,
+
4AL -+
3Mn
+
2AlrO
7)
Why
does
Ammonia
NH.
form
hydrogen bond
but
PH does
not ?
8)
Complete
the
reaction:
CH3CH2CH:
CHr+HBr-lgrs41dsJ,
9)
Write
the
IUPAC
name
of
O-
CHO.
10)
.Name
products
obtained
r,vhen
sucrose
is subjected
to
hydrolysis.
PART -B
tr Answer
any
FIVE of
the
following
questions,Each
question
carries
2
marks.
5x2:10
)k)
Gold
with atomic
radius
0.144
nm
crystalises
in fcc form.
What
is
the
edge
length of
the
unit
cell?
yy
The standard electrode
potential for Daniel
cell
is 1.1V.
Calculate
the standard
-
free
energy change
for the reaction.
Zt'\s1+
Cu2tuq)
->
Zn2\uq1+
Cu(s)
13)
Explain
psuedo
first
order
reaction
rvith
an
example.
14)
What
is
lanthanoid contraction?
Mention
one
of
its
consequences.
15)
Name the
reagents used
in the follor,ving
reactions.
i) Oxidation
of
Primary alcohol
to aldehyde.
ii)
Bromination
of
phenol
to2,4,6
tribromo
phenol.
16)
Explain Gattermann-Koch
reaction with
equation
.
17)
What
are
food
preservatives?
Give
an
example.
18)
Give
an
example
for each
ofthe
follorving.
i)
Non-narcotic
analgesic
ii) Narcdtic
analgesic
PART-C
m
Answer
any
FIVE
of
the
fotlowing
questions.Each
question carries
3 marks
.
5x3:15
i9)
Write
the
reactions occuring
in different
zones
in the blast furnace
during
the
.;-
manufacture
oflron
from
heamatite
ore'
:.
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8/20/2019 2nd PUC Chemistry Jan 2016.pdf
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-
.%t
24)
2r)
26)
Ln
Complete
the
foliowing
reactions
and
write
the
balanced
equations.
i)KCIO3
#F
ii)SO2+O2
\,',o,
,
iii)
C,rHrrD,,_c:fldg*
22)
Give
reasons.
i)HF
acid is
stored
in
wax
coated
glass
bottles.
ii)
DF2
is
called oxygen
deflouride
not
flourine
oxide.
iii)
ClF3
exists
but
FCl,
does
not.
How
is
potassium
dichrornats prepared
from
chromite
ore?
Write
dquations
.
a]
Why
do
transitron
elements
form
compiex
compounds
?
b] Name
the
element
which
shows
highest
oxidation
state
in
3d elements
.
state
any three
postulates
of werner's
theory
of
coordination
compounds
.
using
vBT
account
for geometry
hybridisation
and
magnetic properry
of
I
coG{H3)6]3*.
PART:D
Answer
any
THREE
of
the
following
questions.Each
question
carries
5
marks
.
21)
alcalculate
the
packing
efficiency
in
BCC
crystal
lattice
.
Jx5:15
b]
Mention
any
trvo
differences
between
Schotty
and
Frenkel
defects
.(3+2)
28)
a]
The vapour pressure
ofpure
benzene
at
ceftain temperature
is 0.850bar.
A
non
volatile,
non-electrolyte
solid
weighing
0.5g rvhen
added
to 39.0
g
of
benzene
(molar
mass 78g
mol-l)
The
vapour pressure
of
the
solution
then
is
0.845bar.
Calculate
molar
mass
of
the
sorid
substance
.
b]
State
Henry's
law
and
mention
one
application
of
it
.
29)
al Describe
the
construction
and
working
of
SHE.
bl
rhe
value_
of
) 0*
forHCr,
Nacl
and
CH cooNa
are 426.1,
126.5
and
91.0f1-rcm2mol-l
iespectively.
calculate
ion
of acetic
acid.
(3+2)
30)
a]
Derive
an
expression
for
the
rate
constant
of
a
zero
order
reaction
.
bl Calculat:
tlr.
half life
period of
a
first
order
reaction having
the
constant
of2xl0-3s-1.
(3+2)
31)
alMention
any
three
diff'erences
betw,een
hyophillic
andhyophobic
solutions
b]
Explain
homogeneous
catalysis
r,vith
an
example.
G+2)
Answer
any
FOUR
of the
following
.
Each question
carries
five
rnarks
.4xS:20
32)
al
Explain
with
equations
SN,
mechanism
forthe
hydrolysis
oftert.
butyl
bromide
into
tert.
butyl
alcohol.
b]complete
the
following
reaction
and
name
the
reaction
.
2.C6HsCl
+
2Na
dry
ether
,
33)
a]
How
is
phenol manufactured f,y cumene's process.
Give
the
chemical
equations.
(3+2)
(1+4)
(.2+3)
b] Explain
the
mechanism
of
acid
catalysed
dehydration
of
ethanol
to
ethene
.
34)
a]Name
the
follgwing
reactions
.
i)
RCOCI--Td-E
sol
RCHO
iii)
RCOR
Zn-HgHCt
,RCH,R
b]
Explain
Cannizaro's
reaction
with
equation.
3
5)
al
Explain
the follor,ving
reactions
with
equations
i)carbylaminereaction
ii)Hofinann'sbromamidereaction.
bl
write the
IUPAC
name
ofthe
following
compound
(cH )3cNH2.
36)
a]
Draw
the
structure
of
Lactose
b]
Write
theZwitter
ion
form
of
an
o_amino
acid.
ii)
RCH2COOH
XrlredP
.R-qHCOOH
--?
x
(3+2)
cl
Mention
the
name
of
the
disease
caused
by the
deficiency
ofthe
following
vitamins
i)
VitaminA
ii)
Vitamin
B.
37)
a]write
the
monomers
used
for getting
the
follor.ving
polymers
i)Poiyvinyl
chloride
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