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    Psychrometric properties of air

    Topic 1

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    1. Introduction

    ! In all engineering work, consistent units must be employed. In this subject,

    as in the ASHRAE handbooks, two systems of units will be used.

    ! English Engineering System - most commonly used in the U.S. with

    some modification, such as use of inches instead of feet. Also knownas inch-pound or IP system.

    ! International System or SI - use in engineering practice throughout

    most of the world and widely adopted in the U.S.

    ! Reason: Equipment that was designed using IP units will be operational for

    years (or even decades). It will be necessary for engineers to work in either

    IP or SI systems of units and to be able to make conversion from one

    system to another.

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    1. Introduction

    ! Psychrometryis the study of the properties of mixtures of air and water

    vapour.

    ! Atmospheric airis a mixture of many gases plus water vapour and a number

    of pollutants.

    ! The amount of water vapour and pollutants vary from place to place. The

    concentration of water vapour and pollutants decrease with altitude, and

    above an altitude of about 10 km, atmospheric air consists of only dry air.

    The pollutants have to be filtered out before processing the air.

    ! Moist air- the processed air which is a mixture of various gases that

    constitutes of air and water vapour.

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    1. Introduction

    ! The moist air can be thought of as a mixture of dry air and moisture. For all

    practical purposes, the composition of dry air can be considered as constant.

    In 1949, a standard composition of dry air was fixed by the International Joint

    Committee on Psychrometric data.

    ! Based on the above composition the molecular weight of dry air is found to

    be 28.966 and the gas constant R is 287.035 J/kg.K.

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    1. Introduction

    ! At a given temperature and pressure the dry air can only hold a certain

    maximum amount of moisture. When the moisture content is maximum, then

    the air is known as saturated air.

    ! This condition is established by a neutral equilibrium between the moist airand the liquid or solid phases of water.

    ! For calculation purposes, the molecular weight of water vapour is taken as

    18.015 and its gas constant is 461.52 J/kg.K.

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    1. Introduction

    ! Sensible heat

    - energy added to a substance that produces a change in its temperature.

    ! Latent heat

    - energy added to a substance that produces a change in its phase.

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    2. Properties of moist air

    ! Mixture of perfect gases according to Gibbs-Dalton law:

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    2. Properties of moist air

    ! Dry bulb temperature (DBT)is the temperature of the moist air as measured by a

    standard thermometer or other temperature measuring instruments.

    ! Saturated vapour pressure (psat)is the saturated partial pressure of water vapour at

    the dry bulb temperature. It is readily available in thermodynamic tables and charts.

    ASHRAE suggests the following regression equation for saturated vapour pressure ofwater, which is valid for 0 to 100oC.

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    2. Properties of moist air

    ! Relative humidityis the ratio of the mole fraction of water vapour in moist air

    to mole fraction of water vapour in saturated air at the same temperature and

    pressure. Using perfect gas equation:

    ! It is normally expressed as a percentage. When the value is 100 percent, the

    air is saturated.

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    2. Properties of moist air

    ! Humidity ratio (W)(or specific humidity) is the mass of water associated with each

    kilogram of dry air. Assuming both water vapour and dry air to be perfect gases,

    the humidity ratio is given by:

    ! Substituting the values of gas constants of water vapour and air Rvand Rain the

    above equation; the humidity ratio is given by:

    ! For a given barometric pressure pt, given the DBT, we can find the saturated

    vapour pressure psatfrom the thermodynamic property tables on steam. Thenusing the above equation, we can find the humidity ratio at saturated conditions,

    Wsat.

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    2. Properties of moist air

    ! If unsaturated moist air is cooled at constant pressure, then the temperature

    at which the moisture in the air begins to condenseis known as dew-point

    temperature (DPT)of air. An approximate equation for dew-point

    temperature is given by:

    ! Note: From its definition, the dew point temperature is the saturation

    temperature corresponding to the vapour pressure of water vapour, it can

    also be obtained from steam tables or using the equation of saturated vapour

    pressure.

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    2. Properties of moist air

    ! The degree of saturationis the ratio of the humidity ratio W to the humidity

    ratio of a saturated mixture Wsat the same temperature and pressure:

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    2. Properties of moist air

    ! The enthalpyof moist air is the sum of the enthalpy of the dry air and the

    enthalpy of the water vapour. Enthalpy values are always based on some

    reference value. For moist air, the enthalpy of dry air is given a zero value at

    0oC, and for water vapour the enthalpy of saturated water is taken as zero at

    0oC. The enthalpy of moist air is given by:

    ! The unit of h is kJ/kg of dry air. Substituting the approximate values of cpand

    hg, we obtain:

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    2. Properties of moist air

    ! From the equation for enthalpy of moist air, the humid specific heatof moist

    air can be written as:

    ! Since (W.cpw) is very small compared to the first term, for all practical

    purposes, the humid specific heat of moist air, cpmcan be taken as 1.0216 kJ/

    kg dry air.K

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    2. Properties of moist air

    ! Specific volumeis defined as the number of cubic meters of moist air per

    kilogram of dry air. From perfect gas equation since the volumes occupied by

    the individual substances are the same, the specific volume is also equal to

    the number of cubic meters of dry air per kilogram of dry air:

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    Example 1

    On a particular day the weather forecast states that the dry bulb temperature

    is 37oC, while the relative humidity is 50% and the barometric pressure is

    101.325 kPa. Find the humidity ratio and enthalpy of moist air on this day.

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    Example 1 (solution)

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    3. Wet-bulb temperature

    ! The thermodynamic state of moist air is uniquely fixed if the barometric pressure and

    two other independent properties are known. As such, at a given barometric pressure,

    the state of moist air can be determined by measuring any two independent properties.

    ! One of them could be the dry-bulb temperature (DBT), as the measurement of this

    temperature is fairly simple and accurate. The accurate measurement of otherindependent parameters such as humidity ratio is very di"cult in practice.

    ! Since the measurement of temperature is easier, it would be convenient if the other

    independent parameter is also a temperature. The dew-point temperature (DPT) can be

    considered, but it is observed that accurate measurement of DPT is di"cult.

    ! In this context, a new independent temperature parameter called the wet-bulb

    temperature (WBT)is defined. Compared to DPT, it is easier to measure the WBT

    of moist air. Thus knowing the DBT and WBT from measurements, it is possible to

    find the other properties of moist air.

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    3. Wet-bulb temperature

    ! If the percentage saturation of an air sample

    is less than 100, i.e. it is less than saturated,

    and it comes into contact with water at the

    same temperature, there will be a di#erence

    in vapour pressures.

    ! As a result, some of the water will evaporate.

    The latent heat required for this change of

    state will be drawn from the sensible heat of

    the water, which will be slightly cooled.

    ! This drop in the water temperature provides

    a temperature di#erence, and a thermal

    balance will be reached where the flow of

    sensible heat from the air to the water

    provides the latent heat to evaporate a part

    of it.

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    3. Wet-bulb temperature

    ! The e#ect can be observed and

    measured by using two similar

    thermometers, one of which has its

    bulb enclosed in a wet wick. The

    drier the air passing over them, the

    greater will be the rate of evaporationfrom the wick and the greater the

    di#erence between the two readings

    (DBT and WBT). The di#erence

    between the two temp is termed wet

    bulb depression.

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    3. Wet-bulb temperature

    ! In brief, WBT is the temperature measured by ordinary

    thermometer when its bulb is covered with wet cloth and

    exposed to air

    ! The sling psychrometer is widely used for measurements

    involving room air or other applications where the air

    velocity inside the room is small.

    ! It consists of two thermometers mounted side by side

    and fitted in a frame with a handle for whirling the

    device through air. The required air circulation (~ 3 to 5

    m/s) over the sensing bulbs is obtained by whirling the

    psychrometer (~ 300 RPM). Readings are taken when

    both the thermometers show steady-state readings.

    ! In the aspirated psychrometer, the thermometers remain

    stationary, and a small fan, blower or syringe moves the air

    across the thermometer bulbs.

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    4. Adiabatic saturation

    ! Adiabatic saturation temperature- temperature at which water, by

    evaporating into air, can bring the air to saturation at the same temperature

    adiabatically.

    ! An adiabatic saturator is a device using which one can measure theoretically

    the adiabatic saturation temperature of air.

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    4. Adiabatic saturation

    An adiabatic saturation device has

    liquid water at the adiabatic

    saturation temperature T2is

    evaporated at a rate mwinto a moist

    air stream flowing at a rate of

    mda(1 + W) through the duct. Thusconservation of mass applied

    separately to both dry air and water

    components yields

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    4. Adiabatic saturation

    ! Above equation maybe used to solve for the upstream (ambient) humidity

    ratio.

    ! Note: da = dry air; wv = water vapour

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    5. Psychrometric chart

    ! A Psychrometric chart graphically represents the thermodynamic properties

    of moist air.

    ! Standard psychrometric charts are bounded by the DBT line (x-axis) and the

    vapour pressure or humidity ratio (y-axis). The left hand side of the

    psychrometric chart is bounded by the saturation line.

    ! Psychrometric charts are readily available for standard barometric pressure of

    101.325 kPa at sea level and for normal temperatures (0-50oC).

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    5. Psychrometric chart

    R R

    ASHRAE PSYCHROMETRIC CHART NO.1NORMAL TEMPERATURE

    BAROMETRIC PRESSURE: 29.921 INCHES OF MERCURY

    Copyright 1992

    AMERICAN SOCIETY OF HEATING, REFRIGERATING AND AIR-CONDITIONING ENGINEERS, INC.

    SEA LEVEL

    10 15 20 25

    30

    35

    40

    45

    50

    55

    55

    60

    60

    ENTHALPY - BTU PER POUND OF DRY AIR

    15

    20

    25

    30

    35

    40

    45

    50

    ENTH

    ALPY

    -BT

    UPER

    POUND

    OFDR

    YAIR

    SATU

    RATIONTE

    MPE

    RATUR

    E-F

    35

    40

    45

    50

    55

    60

    65

    70

    75

    80

    85

    90

    95

    100

    105

    110

    115

    120

    DRYBULBTEMPERATURE-F

    .002

    .004

    .006

    .008

    .010

    .012

    .014

    .016

    .018

    .020

    .022

    .024

    .026

    .028

    10%RELATIVEHU

    MIDITY

    20%

    30%

    40%

    50%

    60%

    70%

    80%

    90%

    35

    3540

    4045

    45 50

    50 55

    55 60

    60

    65

    65

    70

    70

    75

    75

    80

    80

    85WETBULBTEMPERATURE-F

    85

    90

    12.5

    13.0

    13.5

    14.0

    VOLUME-CU.FT.PERLB.DRYAIR

    14.5

    15.0

    HUMIDITYRATIO-POUNDSMOISTUREPERPOUND

    DRYAIR

    0

    1.0 1.0

    :-

    2.0

    4.0

    8.0

    -8.0-4

    .0-2

    .0-1

    .0

    -0.5-0

    .4-0.3-0

    .2-0.1

    0.

    10

    .2

    0.3

    0.4

    0.5

    0.6

    0.8

    -2000

    -1000

    0

    500

    1000

    1500

    2000

    3000

    5000

    - ::

    SENSIBL E HEAT Qs

    TOTAL HEAT Qt

    ENTHALPY

    HUMIDITY RATIO

    Dh

    DW

    R R

    ASHRAE PSYCHROMETRIC CHART NO.1NORMAL TEMPERATURE

    BAROMETRIC PRESSURE: 29.921 INCHES OF MERCURY

    Copyright 1992

    AMERICAN SOCIETY OF HEATING, REFRIGERATING AND AIR-CONDITIONING ENGINEERS, INC.

    SEA LEVEL

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    Example 2

    Temperature in a room is 25C. If the wet-bulb temperature is 20C, find

    the RH, dew point, humidity ratio, specific volume and specific enthalpy at

    that state.

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    6. Psychrometric processes

    ! Sensible heating or cooling

    ! a psychrometric process that

    involves the increase or decrease

    of air temperature without

    changing its humidity ratio.

    ! example: Moist air passing over a

    room space heater

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    Example 3

    ! Find RH and wet-bulb temp of the post-heated air.

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    Example 3 (solution)

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    6. Psychrometric processes

    ! Heating and humidifying

    ! a psychrometric process that

    involves the simultaneous

    increase of dry-bulb temp and

    humidity ratio of the air.

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    Example 4

    2.5 m3of lumber is being dried at 60C dry-bulb temperature and 52C

    wet-bulb temperature. The drying rate of the lumber is 12.5 kg of water per

    hour. If outside air is at 27C dry-bulb temperature and 80% relative

    humidity, how much outside air is needed per minute to carry away the

    evaporated moisture?

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    Example 4 (solution)

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    6. Psychrometric processes

    ! Cooling and dehumidifying

    ! a psychrometric process that

    involves the removal of water from

    the air as the air temp drops

    below the dew-point temp.

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    Example 5

    Moist air at 50C dry-bulb temperature and 32% relative humidity enters

    the cooling coil of a dehumidification kiln heat pump system and is cooled

    to a temperature of 18C. If the drying rate of 6 m3of lumber is 4 kg/hour,

    determine the kW of refrigeration required.

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    Example 5 (solution)

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    6. Psychrometric processes

    ! Adiabatic / evaporative cooling

    ! a psychrometric process that

    involves the cooling or air without

    heat loss or gain.

    ! sensible heat lost by the air is

    converted to latent heat in the

    added water vapour.

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    Example 6

    Referring to the figure, air at state point 1 (65C DBT and 57C WBT)

    experiences a temperature drop of 3C as it passes through the 1.2 m

    wide stack of lumber. Determine the properties of the air at state point 2

    and compare them with those at state point 1. If the air is flowing at a rate

    of 2 ms-1, determine the drying rate, assuming that the volume of the stack

    of 2.5 cm thick lumber is 2.5 m3

    . The stack is 1.2 m wide x 3.6 m long, andthe boards are separated by stickers 3.8 cm wide x 1.9 cm thick that are

    spaced 0.6 m apart.

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    Example 6 (solution)

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    6. Pyschrometric processes

    ! Adiabatic mixing of moist stream air

    ! a psychrometric process that

    involves no heat loss or gain

    during the mixing of two air

    streams.

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    Example 7

    0.2 kg/s of moist air at 45C (DBT) and 10% RH is mixed with 0.3 kg/s of

    moist air at 25C and a humidity ratio of 0.018 kgw/kgda in an adiabatic

    mixing chamber. After mixing, the mixed air is heated to a final

    temperature of 40C using a heater. Find the temperature and relative

    humidity of air after mixing. Find the heat transfer rate in the heater and

    relative humidity of air at the exit of heater. Assume the barometricpressure to be 1 atm.

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    Example 7 (solution)

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    Example 8

    Hot, humid outdoor air is drawn into the system with a volumetric flow rate V1= 100

    cfm (0.0472 m3/s). The temperature of the outdoor air is T1= 95oF (35oC) and it has

    relative humidity $1= 0.7. In order to provide a comfortable environment, the air

    must be both cooled and dehumidified. The air passes over a chilled water coil inorder to dehumidify it. The air exits the chilled water coil at T2= 45oF (7.2oC). The air

    then passes over a steam coil in order to reheat it to a comfortable temperature. The

    air exits the steam coil at T3= 65oF (18.3oC).

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    Example 8

    (a) What is the humidity ratio of the air entering the chilled water coil?

    (b) What is the mass flow rate of dry air entering the chilled water coil?

    (c) At what temperature does condensation begin as the air flows through chilled

    water coil?

    (d) What is the humidity ratio of the air leaving the chilled water coil?

    (e) What is the volumetric flow rate of condensate that forms on the chilled water

    coil?(f) What is the relative humidity of the air leaving the steam coil that is provided to

    the conditioned space?

    (g) What are the rates of heat transfer to the chilled water in the chilled water coil

    and from the steam in the steam coil?

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    Example 8 (solution)

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    Example 8 (solution)

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    Example 9

    Moist air at 60oF (15.6oC) DBT and 20% RH enters a heater and humidifier at

    the rate of 1600 cfm (0.755 m3/s), Heating of the air is followed by adiabatic

    humidification so that it leaves at 115oF (46.1oC) DBT and a RH of 30%.

    Saturated water vapour at 212oF (100oC) is injected. Determined the required

    heat transfer rate and mass flow rate of water vapour.

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    Example 9 (solution)