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SUPPLEMENTARY REPORT-II EIA/RRA FOR RESIDUE UP-GRADATION AND DISTILLATE YIELD IMPROVEMENT PROJECT WITH 11.0 MMTPA CRUDE PROCESSING AT MATHURA REFINERY OF M/S INDIAN OIL CORPORATION LTD MATHURA REPORT NO. A257-SR-II-1741-1301 MARCH 2015 This report is prepared for M/s IOCL, Mathura refinery and it is for use by M/s IOCL, Mathura Refinery or their assigned representatives / organizations only. The matter contained in the report is confidential.

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SUPPLEMENTARY REPORT-II

EIA/RRA FOR RESIDUE UP-GRADATION AND DISTILLATE YIELD IMPROVEMENT PROJECT WITH

11.0 MMTPA CRUDE PROCESSING AT

MATHURA REFINERY OF

M/S INDIAN OIL CORPORATION LTD MATHURA

REPORT NO. A257-SR-II-1741-1301 MARCH 2015

This report is prepared for M/s IOCL, Mathura refinery and it is for use by M/s IOCL, Mathura Refinery or

their assigned representatives / organizations only. The matter contained in the report is confidential.

1

RESIDUE UP-GRADATION AND DISTILLATE YIELD

IMPROVEMENT PROJECT WITH 11.0 MMTPA CRUDE

PROCESSING AT MATHURA REFINERY OF

M/S INDIAN OIL CORPORATION LTD

Document No.

A257-SR-II-1741-1301

Rev. No. 0

Page 1 of 146

Template No. 5-0000-0001-T2 Rev. 1 Copyrights EIL – All rights reserved

The project “Residue Up-Gradation and Distillate Yield Improvement Project with 11.0 MMPTA

Crude Processing at Mathura Refinery of M/s Indian Oil Corporation Ltd, Mathura” was

considered for Environment Clearance in 18th Reconstituted EAC meeting where 11 nos. of

additional clarifications were sought and published vide Minutes of Meeting. A supplementary

report coving all the 11 points in comprehensive manner was prepared and submitted to MoEF

on 5th Sept’14.

During 24th Reconstituted EAC meeting on 29th Sept’14, the proposed expansion project was re-

considered and the committee reviewed the various details submitted for the clarifications of the

11 nos. points. The EAC further desired to submit additional information for following 3 nos. of

points, published vide Minutes of Meeting.

In compliance to the desired information, Mathura Refinery, IOC is submitting the

supplementary report-II. Summary of the compliance of the three points is as under and detailed

clarification is given in the report.

S.N. Action point Compliance

1. One month data for Methane and

Non-Methane Data to be reanalyzed

Sampling at 15 nos. of locations from where the

baseline data was collected w.r.t Methane and

Non-Methane hydrocarbons for one month and

samples were analyzed for the same between

4th Nov’14 to 4thDec’14. Detailed report is

enclosed as Annexure-I

2. Maximum Predicted Impact due to

SO2 emissions to be ascertained

and modeling developed for SO2 to

be corrected with CPCB data

Detailed report is enclosed as Annexure-II

3. Item wise details along with time

bound action plan for ESR during

construction period to be prepared

and submitted.

Detailed report is enclosed as Annexure-III

2

RESIDUE UP-GRADATION AND DISTILLATE YIELD

IMPROVEMENT PROJECT WITH 11.0 MMTPA CRUDE

PROCESSING AT MATHURA REFINERY OF

M/S INDIAN OIL CORPORATION LTD

Document No.

A257-SR-II-1741-1301

Template No. 5-0000-0001-T2 Rev. 1 Copyrights EIL – All rights reserved

Annexure-I

Point – 1 : One month data for Methane and Non-Methane Data to be reanalyzed

Detailed survey was carried out in a study area of 25 km radius around Mathura Refinery to

establish base line quality of ambient air. Air samples were collected at 15 locations and have

been re-analyzed for methane hydrocarbons and non methane hydrocarbons as per the

suggestions given by EAC.

A brief description on the sampling locations is as follows:

1. Barari:-

The place is situated in SE direction and at a distance of 2.5 km from the centre of the refinery.

The sample point chosen in this place is a Government school and it is surrounded by vegetable

market area and it is also adjacent to national highway passing through the Mathura Refinery.

Fig. 1.0 shows some pictures taken while taking samples in Barari village

2. Dhanateja:-

The place is situated in SE direction and at a distance of 0.3 km from the centre of the Refinery.

The sampling location chosen in this location is very nearer to the Refinery’s flare and it is also

surrounded by lot of cattle dung. The people live in this place use cattle dung to decorate their

houses and also as a fuel. Fig. 1.1 shows some pictures taken while taking samples in

Dhanateja village.

3. Chhadgaon:-

The place is situated in SW direction and at a distance of 0.9 km from the centre of the Refinery.

The sampling location here chosen in this village is adjacent to the local village road and the

location is surrounded by Paddy cultivation. Fig. 1.2 shows some pictures taken while taking

samples in chhadgaon village.

4. Bhainsa:-

The place is situated in NW direction and at a distance of 0.7 km from the centre of the

Refinery. The sampling location is chosen in this village is a house and it is just behind the

Refinery. Fig. 1.3 shows some pictures taken while taking samples in Bhainsa village.

5. Naglagyasi:-

The place is situated in NE direction and at a distance of 1.3 km from the centre of

Refinery. Sample has been taken from a local house in the village and the place surrounded by

open place which is not under cultivation and lot of cattle dung. Fig. 1.4 shows some pictures

taken while taking samples in Naglagyasi village.

3

RESIDUE UP-GRADATION AND DISTILLATE YIELD

IMPROVEMENT PROJECT WITH 11.0 MMTPA CRUDE

PROCESSING AT MATHURA REFINERY OF

M/S INDIAN OIL CORPORATION LTD

Document No.

A257-SR-II-1741-1301

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6. Sikandra:-

The place is situated in SE direction and at a distance of 30.4 km from the centre of Refinery.

Sample point is very nearer to the vegetable market located in the place. Fig. 1.5 shows some

pictures taken while taking samples in Barari village. Fig. 1.5 shows some pictures taken while

taking samples in Sikandra village.

7. SwarnaJayanti Hospital:-

The place is situated in NW direction and at a distance of 5.1 km from the centre of the

Refinery. The hospital is located adjacent to the national highway. The hospital is three storied

building and sampling has taken from first floor of the building. During sampling it has been

confirmed that free flow of air is taking place at the sampling point. Fig. 1.6 shows some pictures

taken while taking samples in S.J. Hospital.

8. Gokul:-

The place is situated in NE direction and at a distance of 3.9 km from the centre of Refinery.

The sample has been taken from a house located in the village. Fig. 1.6 shows some pictures

taken while taking samples in Gokul.

9. Kosikhurd:-

The place is situated in NW direction and at a distance of 6.9 km from the centre of Refinery.

The sample has been taken in a Petrol pump located there. Fig. 1.7 shows some pictures taken

while taking samples in Kosikhurd village.

10. Jagina:-

The place is situated in SW direction and at a distance of 15.2 km from the centre of Refinery.

The sample has been taken in a house located in the village. Fig. 1.8 shows some pictures

taken while taking samples in Jagina village.

11. Bad:-

The place is situated in N direction and at a distance of 1.6 km from the centre of the Refinery.

The sampling location is nearer to the national highway and the place has lot of paddy area

under cultivation.

12. Nawada:-

The place is situated in N direction and at a distance of 5.6 km from the centre of the Refinery.

A temple has been chosen as a sampling point, decided based on the availability of electricity.

The place consists of lot of open area and farmers are cultivating vegetables in the open place.

13. Fareh:-

The place is situated in SE direction and at a distance of 6.5 km from the centre of Refinery

Sample has been taken from a local electric substation and the place is covered with lot of

trees.

4

RESIDUE UP-GRADATION AND DISTILLATE YIELD

IMPROVEMENT PROJECT WITH 11.0 MMTPA CRUDE

PROCESSING AT MATHURA REFINERY OF

M/S INDIAN OIL CORPORATION LTD

Document No.

A257-SR-II-1741-1301

Template No. 5-0000-0001-T2 Rev. 1 Copyrights EIL – All rights reserved

14. Mangrawl:-

The place is situated in SE direction and at a distance of 18.0 km from the centre of Refinery.

Sample has taken from the office therein. The place has lot of vegetation and diversified both

plant and animal species.

15. Guruteg Bahadur Colony:-

The place is situated in SE direction and at a distance of 33.6 km from the centre of Refinery.

Here also the sampling point is nearer to the local vegetable market.

Table 1.0 Pictures taken while taking samples in the study area

Fig 1.0 Pictures taken at Barari Village

Fig 1.1 Pictures taken at Dhanateja Village

Fig 1.2 Pictures taken at chhadgaon Village

5

RESIDUE UP-GRADATION AND DISTILLATE YIELD

IMPROVEMENT PROJECT WITH 11.0 MMTPA CRUDE

PROCESSING AT MATHURA REFINERY OF

M/S INDIAN OIL CORPORATION LTD

Document No.

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Template No. 5-0000-0001-T2 Rev. 1 Copyrights EIL – All rights reserved

Fig 1.3 Pictures taken at Bhainsa Village

Fig 1.4 Pictures taken at Naglagyasi Village

Fig 1.5 Pictures taken at Sikandra Village

Fig 1.6 Pictures taken at Swarna Jayanti Hospital

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RESIDUE UP-GRADATION AND DISTILLATE YIELD

IMPROVEMENT PROJECT WITH 11.0 MMTPA CRUDE

PROCESSING AT MATHURA REFINERY OF

M/S INDIAN OIL CORPORATION LTD

Document No.

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Template No. 5-0000-0001-T2 Rev. 1 Copyrights EIL – All rights reserved

Accordingly, air samples were again collected in the month of November 2014 and were

analysed for methane hydrocarbons and non-methane hydrocarbons.

The methods used for determining Methane & Non-Methane Hydrocarbons in 25 kms radius

vicinity of Mathura Refinery during the data collection are tabulated below in Table-1.1

Table-1.1 Methodologies Adopted in Assessing Methane and Non-Methane Hydrocarbons

S.No. Parameter Method

1. Methane Hydrocarbons Gas Chromatography with FID as detector

detector 2. Non Methane Hydrocarbons Gas Chromatography with FID as detector

Fig 1.6 Pictures taken at Gokul

Fig 1.7 Pictures taken at Kosikhurd Village

Fig 1.8 Pictures taken at Jagina Village

7

RESIDUE UP-GRADATION AND DISTILLATE YIELD

IMPROVEMENT PROJECT WITH 11.0 MMTPA CRUDE

PROCESSING AT MATHURA REFINERY OF

M/S INDIAN OIL CORPORATION LTD

Document No.

A257-SR-II-1741-1301

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As per the directions of EAC, one month continuous monitoring of Methane & Non-Methane

Hydrocarbons both were carried out in November-2014 in the same locations where initial

monitoring was carried out during baseline data collection for subject expansion project. The

laboratory results have shown that none of the sampling location in the study area contains the

presence of Methane and Non-Methane hydrocarbons (Results obtained from the laboratory are

attached herewith). Table 1.2 shows the comparison of data obtained in the month of May with

the current analysis.

Table1.2 Monitoring data for Methane and Non-Methane hydrocarbons

SN Location

Month of Sampling

Methane Hydrocarbons (ppm) Non-Methane Hydrocarbons (ppm)

January -2013 (During baseline

data collection) (A)

December-2014 (B)

January -2013 (During baseline

data collection) (C)

December -2014 (D)

1 Dhanateja 0.115 < 0.1 0.32 < 0.1

2 Bad < 0.1 < 0.1 0.16 < 0.1

3 Bhainsa < 0.1 < 0.1 0.16 < 0.1

4 Barari < 0.1 < 0.1 < 0.1 < 0.1

5 S.J Hospital < 0.1 < 0.1 0.22 < 0.1

6 Chaadgoan < 0.1 < 0.1 < 0.1 < 0.1

7 Gokul < 0.1 < 0.1 < 0.1 < 0.1

8 Fareh < 0.1 < 0.1 0.17 < 0.1

9 Mangrawl < 0.1 < 0.1 < 0.1 < 0.1

10 Jagina < 0.1 < 0.1 < 0.1 < 0.1

11 Nawada < 0.1 < 0.1 < 0.1 < 0.1

12 Kosikhurd < 0.1 < 0.1 < 0.1 < 0.1

13 Naglagayasi < 0.1 < 0.1 0.25 < 0.1

14 Sikandra < 0.1 < 0.1 < 0.1 < 0.1

15 Guruteg Bahudur Colony

< 0.1 < 0.1 < 0.1 < 0.1

VOC Control, Emission and Monitoring:

In petroleum complexes, the release of volatile organic compounds (VOCs) to air depends on

the products handled at the plant and may include acetaldehyde, acetone, benzene, toluene,

and xylene. VOC emissions are mostly fugitive and depend upon the production processes,

material handling and effluent treatment procedures, equipment maintenance, and climatic

conditions.

These fugitive emissions originate from the static and dynamic compressor joints and seals

used in flanges, pumps, valve packings and connection joints to the atmosphere like sampling,

relief valves, etc.

8

RESIDUE UP-GRADATION AND DISTILLATE YIELD

IMPROVEMENT PROJECT WITH 11.0 MMTPA CRUDE

PROCESSING AT MATHURA REFINERY OF

M/S INDIAN OIL CORPORATION LTD

Document No.

A257-SR-II-1741-1301

Template No. 5-0000-0001-T2 Rev. 1 Copyrights EIL – All rights reserved

In order to minimize the fugitive emissions, the following measures will be taken:

Minimum number of flanges, valves, etc.

High grade gasket material for packing

Usage of state-of-the-art low leakage valves preferably with bellow seals

Usage of pumps with mechanical seals

Provisions of floating roof storage tanks

Provisions of double seal in some of storage tanks

Provision of seals in the drains and manholes

For VOC monitoring, recurring cost of Rs.14.00Lakh/annum has been estimated in the

operational phase of the project.

A regular Leak Detection and Repair (LDAR) program/survey is carried out within the refinery

complex annually. A summary of the procedure adopted is as follows:

The monitoring procedure, will be in compliance with ISO/DIS 14001, and uses a similar

procedure to that detailed in “Guidelines for Environmental Auditing—General Principles”,

AS/NZS ISO 14010 (Int) 1995.

The monitoring procedure for each of the operations is included:

A) Monitoring Preliminaries:-

i. Review of Process and Instrumentation Diagrams (P&IDs), Process Flow Diagrams (PFDs)

and other information

ii. For each facility P&IDs, PFDs and other information will be reviewed to identify all emission

points. Where appropriate screen or group those emissions points. For example:

Screening – Pressure safety valves (PSVs) are screened from further analysis as the

frequency of release is considered to be low and they are required for the safe operation of

the plant.

Grouping – Fugitive emissions of hydrocarbons (H/Cs) from vents are grouped as fugitive

emissions.

iii. Opening meeting

At each opening meeting an outline is given of the objective and the methodology to be used

for the monitoring. Requests are made for specific environmental documentation and

personnel.

B) Conduct the Audit

9

RESIDUE UP-GRADATION AND DISTILLATE YIELD

IMPROVEMENT PROJECT WITH 11.0 MMTPA CRUDE

PROCESSING AT MATHURA REFINERY OF

M/S INDIAN OIL CORPORATION LTD

Document No.

A257-SR-II-1741-1301

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i. Review Emission Points Detailed on the P&IDs

With the assistance of operations personnel the emission points identified in the P&ID will be

reviewed. From the P&IDs, it will be determined whether sampling needs to be undertaken

and what emission points should be sampled.

ii. Review Monitoring Undertaken to Date

Operations personnel will review environmental monitoring that may have been undertaken to

date and will obtain, where possible:

Fuel gas analysis, in particular the sulphur concentrations

Fuel gas flow rates (note: fuel gas flow rates will enable mass emission rates of emissions to

be determined.

iii. Undertake an Inspection of the Facility

iv. Inspection of the facility will verify the information supplied and to establish the ability or

otherwise, to undertake programmed sampling.

v. If required, Undertake Representative Sampling

Depending on monitoring undertaken to date, and the accessibility to sample point locations,

sampling of gaseous or liquid effluents will be undertaken, as deemed necessary.

C) Undertake a Close-Out Meeting with the Operations Personnel

Brief outline of the findings with regard to emission point identification, stream characterization

and mass emission rate determination will be provided.

Conclusion:

For Methane hydrocarbons, comparing the A and B data in Table 1.2, none of the locations

have shown the presence of Methane hydrocarbons except for data collected in village

Dhanateja. This might be due to escape of unburnt volatile gases from the Refinery Flare as the

location in very close proximity to the Refinery Flare.

For non-Methane hydrocarbons, on comparing C and D data in Table 1.2, there hasn’t been a

significant/considerable difference in the values reported in the locations where the presence of

non-methane hydrocarbons showed. The difference is not considerable and the difference might

have come due to the seasonal variations or during the analysis of the samples collected.

So, it may be finally concluded based on the re-analysis study that the study area around the

Mathura Refinery is free from the Methane and Non-methane hydrocarbons.

10

RESIDUE UP-GRADATION AND DISTILLATE YIELD

IMPROVEMENT PROJECT WITH 11.0 MMTPA CRUDE

PROCESSING AT MATHURA REFINERY OF

M/S INDIAN OIL CORPORATION LTD

Document No.

A257-SR-II-1741-1301

Template No. 5-0000-0001-T2 Rev. 1 Copyrights EIL – All rights reserved

Annexure-II

Point – 2 : Maximum Predicted Impact due to SO2 emissions to be ascertained and modeling to be developed for SO2 to be correlated with CPCB data Mathura Refinery was established with utmost care for environment after having done the first

ever scientific study for assessment of impact on environment prior to commissioning of the

Refinery (Environmental Impact Assessment) during 1975-77 by the Expert Committee under

the Chairman of Dr. S. Varadrajan, the then Chairman & MD, Indian Petrochemical Corporation

Ltd. The study covered (a) the pollutant levels prevailing in the Agra Region by NEERI and (b)

Dispersion of Pollutants from refinery by IMD and Teeneco of Italy. The study involved

determination of Sulphur Dioxide at various distances from refinery site under different

Meteorological conditions. The committee recommended a limit of1000 kg /hr Sulphur dioxide

emission from refinery stacks and predicted that the impact of about 1-2µg/Nm3 at Agra Region

and 0.3 µg/Nm3 at Bharatpur region in 1975.

Mathura Refinery was commissioned in 1982 with a permission of 1000 kg/hr sulphur dioxide

emission from refinery stacks. In Oct’1993, under the directive of the Hon’ble Supreme Court,

coveted institute for Environment, NEERI carried out detailed study for the reduction of SO2

emissions from the refinery. The study recommended short term and long terms steps for

reduction of the SO2 from the limit of 1000 kg/hr to 450 kg/hr. The reduction in sulphur dioxide

emission level over a period of time is as under:

Prescribe limit (Kg/hr) Actual values (Kg/hr) Remarks

1000 (Mar-Sep)

700 (Oct-Feb)

530-600

360-450

Use of Natural Gas

commenced Dec’96

450 (entire year) 300-380 2000 onwards

The various recommendations given by NEERI and in-house projects were implemented during

1995-2000 in order to bring down the SO2 emission below level of 450 kg/hr. Major ones are

given as under

a) Low Sulphur crude processing: Processing of low Sulphur crude (40% of the total crude

processed) viz. Bombay High and Nigerian Crude.

b) Use of clean fuel in furnaces: Since, Dec’96, Natural Gas is used in furnaces to meet major

heating requirement. Approx 60% of total energy need is met by Natural Gas. Refinery Fuel Gas

is used after de-sulphurization to reduce H2S less than 100 ppmv. Low sulphur Liquid fuel

(Finance oil) having ‘S’ less than 1% is used. It reduces both SO2 emission as well as

particulate matter emission.

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RESIDUE UP-GRADATION AND DISTILLATE YIELD

IMPROVEMENT PROJECT WITH 11.0 MMTPA CRUDE

PROCESSING AT MATHURA REFINERY OF

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Document No.

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c) Sulphur Recovery Units: New SRU units with 99% + sulphur recovery was installed and

commissioned in 1999. In 2005, Tail Gas Treatment Unit was installed and commissioned to

achieve more than 99.5% sulphur recovery. In 2010, one new SRU was commissioned to have

a provision one unit always as a hot stand-by.

d) Hydro Cracker Unit –Hydrocracker unit was commissioned to produce BS-III & IV grade

automobile fuel. OHCU also provided hydro-processed feed to FCC. Presently, 30% FCC feed

in hydro-processed (OHCU Bottom) which significantly decreased SO2 emission from FCC unit.

e) Tall chimneys: For better dispersion of pollutants in atmosphere so that the Ground Level

Concentrations are kept at the minimum tall chimneys are provided in furnaces. All units are

having stacks ranging upto 90 meters.

f) Creation of Pollution Sink (Green Belt): As Green cover acts as a natural sink to pollutants,

Mathura Refinery has done extensive tree plantation within the refinery & township area as well

as far flung areas since inception. Till date, more than 2.89 lakhs trees planted around Agra &

Mathura region to convert refinery operations carbon neutral.

Since starting, SO2 emission from refinery was maintained always below the prescribed limit.

The plot below represents emissions for over past 30 years:

SO2 Monitoring Activities by Refinery: To measure the SO2 concentration in the ambient air

and keep track on the impact on surroundings, Mathura Refinery has established 4 continuous

monitoring stations outside the refinery.

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RESIDUE UP-GRADATION AND DISTILLATE YIELD

IMPROVEMENT PROJECT WITH 11.0 MMTPA CRUDE

PROCESSING AT MATHURA REFINERY OF

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Document No.

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1. Farah : Downwind direction. (10 KM far from refinery)

2. Keetham : Downwind direction. Situated within premises of Soor Sarovar Pakshi Vihar. (27 KM

from refinery)

3. Sikandra: Downwind direction. Situated within premises of Archaeological monument of

sikandra (Tomb of Akbar). (37 KM from refinery)

4. Bharatpur: Cross wind direction. Situation within premises of Keoladeo Ghana National Park.

(40 KM from refinery)

The above four monitoring stations are equipped with sophisticated instruments from M/s

Thermo-USA make SOx analyzers and are in operation since 1981 even before inception of

refinery in 1982.

Remarks : The stations – Farah & Sikandra are located adjacent to the National Highway – 2.

Concentration of SO2 in & around Taj from CPCB and other sources: CPCB has

established 05 numbers of monitoring stations in Agra including one at Taj Mahal under NAMP.

The following table (Source-CPCB website) gives the concentration of SO2 at Taj Mahal. The

level is consistently below the 10 µg/Nm3 well below Annual Average Standard 20 µg/Nm3of as

per 2009 notification.

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RESIDUE UP-GRADATION AND DISTILLATE YIELD

IMPROVEMENT PROJECT WITH 11.0 MMTPA CRUDE

PROCESSING AT MATHURA REFINERY OF

M/S INDIAN OIL CORPORATION LTD

Document No.

A257-SR-II-1741-1301

Template No. 5-0000-0001-T2 Rev. 1 Copyrights EIL – All rights reserved

Source : www.cpcb.nic.in

http://cpcb.nic.in/agra_data.php

Proposed Expansion Project and Impact on SO2 emissions: With the proposed expansion

with 90% High Sulphur Crude processing and lesser sulphur in products, the SO2 emission shall

be maintained within 450 m3/hr with following measures:

1- Reduce in liquid fuel and maximizing gaseous fuel (Fuel gas and Natural Gas)

2- Use of fuel oil with ‘S’ content < 0.6%

3- Installation of SRU’s with minimum 99.5% efficiency

4- Hydro finished feed to FCCU

The comparison of various sources of SO2 emission is as under:

Crude T"put Units 8 MMTPA 11 MMTPA

Thermal SOX Kg/Hr 218 99

SRU SOX Kg/Hr 134 258

FCC SOX Kg/Hr 98 94

Total Kg/Hr 450 450

The SO2and NOx emission in Basecase of 8 MMTPA and Expansion case of 11 MMTPA case

are tabulated below in Table 1 and Table-2 respectively:

CPCB Taj Mahal Station

2.01.14 BDL

07.01.14 5

12.01.14 BDL

28.01.14 BDL

02.03.14 BDL

25.03.14 BDL

01.05.14 6

20.05.14 BDL

05.06.14 BDL

16.06.14 BDL

23.06.14 BDL

02.07.14 BDL

23.07.14 7

12.08.14 4

24.08.14 BDL

01.09.14 BDL

06.09.14 BDL

24.09.14 BDL

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RESIDUE UP-GRADATION AND DISTILLATE YIELD

IMPROVEMENT PROJECT WITH 11.0 MMTPA CRUDE

PROCESSING AT MATHURA REFINERY OF

M/S INDIAN OIL CORPORATION LTD

Document No.

A257-SR-II-1741-1301

Template No. 5-0000-0001-T2 Rev. 1 Copyrights EIL – All rights reserved

Table- 1- BASECASE (8 MMTPA) –SO2& NOx Emission Data

Stack Characteristic Fuel Consumption (MT/D)

SO2 Emission

NOx Emission

Units Height

(m) Dia (m)

Temp (C)

FO FG NG kg/hr Burner Type

kg/hr

CDU 80 6.5 180 149 127 0.2 121.54 LOW NOX 50.6

VDU 60 3.35 180 37 32 0.1 30.38 LOW NOX 12.6

VBU-I 60 2.1 250 15 22 0.0 12.56 LOW NOX 6.1

VBU-II 60 2.1 250 15 22 0.0 12.56 LOW NOX 6.1

FCCU-CH 60 1.75 300 23 37 0.1 18.65 NORMAL 9.6

BBU 40 2.36 165 0 4 0.0 0.04 LOW NOX 0.5

TGTU 62 1.12 190 0 0 3.2 0.00 LOW NOX 0.2

CCRU-I 67 2.15 150 0 50 0.1 0.53 LOW NOX 5.5

CCRU-II 66 2.23 190 0 29 0.0 0.31 LOW NOX 3.2

DHDS 44 1.52 185 0 12 0.0 0.13 LOW NOX 1.3

DHDT 60 1.42 173 0 0 0.0 0.00 LOW NOX 0.0

OHCU-I 41 1.47 200 0 12 0.0 0.12 LOW NOX 1.3

OHCU-II 41 2.1 200 0 23 0.1 0.25 LOW NOX 2.6

HGU-I 60 2.95 200 0 0 62.9 0.08 LOW NOX 3.4

HGU-II (PDS) 60 1.4 190 0 0 0.0 0.00 LOW NOX 0.0

HGU-II 60 2.25 145 0 0 96.6 0.12 LOW NOX 5.2

MSQ 60 0.9 230 0 4 0.0 0.05 LOW NOX 0.5

Prime-G 60 0.8 210 0 4 0.0 0.04 LOW NOX 0.4

TPS Boiler 116 4.5 110 25 0 259 20.90 LOW NOX 20.2

GT-I 60 3.5 120 0 0 216.0 0.27 LOW NOX 11.6

GT-II 60 3.5 120 0 0 216.0 0.27 LOW NOX 11.6

GT-III 60 3.5 120 0 0 216.0 0.27 LOW NOX 11.6

FLARE 95 5.3 1000 0 0 0.0 0.00 - 0.0

FCC-CO-Boiler 80 2.5 275 0 0 0 97.50 - 13.0

SRU-A, B, C, D 62 0.8 270 0 7 0 133.41 NORMAL 0.03

TOTAL

264.4 385.0 1070.4 450.00

177.12

Table- 2 - 11 MMTPA case – SO2 & NOx emission data

Stack Characteristic

Fuel Consumption (MT/Day)

SO2 Emission

NOx Emission

Height

(m) Dia (m)

Temp (C) FO FG NG kg/hr Burner Type

kg/hr

CDU 80.0 6.5 180.0 80.0 255.2 53.3 36.1 LOW NOX 50.5

VDU 60.0 3.4 180.0 6.4 49.8 53.1 3.2 LOW NOX 9.9

VBU-I 60.0 2.1 250.0 0.0 0.0 0.0 0.0 LOW NOX 0.0

VBU-II 60.0 2.1 250.0 0.0 0.0 0.0 0.0 LOW NOX 0.0

FCCU-CH 60.0 1.8 300.0 10.7 46.7 18.1 5.0 NORMAL 8.7

BBU 40.0 2.4 165.0 0.0 25.0 0.0 0.3 LOW NOX 2.7

TGTU 62.0 1.1 190.0 0.0 0.0 3.24 0.0 LOW NOX 0.2

CCRU-I 67.0 2.2 150.0 0.0 65.2 0.1 0.7 LOW NOX 7.1

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RESIDUE UP-GRADATION AND DISTILLATE YIELD

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PROCESSING AT MATHURA REFINERY OF

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Document No.

A257-SR-II-1741-1301

Template No. 5-0000-0001-T2 Rev. 1 Copyrights EIL – All rights reserved

CCRU-II 65.8 2.2 190.0 0.0 37.5 0.1 0.4 LOW NOX 4.1

DHDS 44.0 1.5 185.0 0.0 16.7 0.1 0.2 LOW NOX 1.8

DHDT 60.0 1.4 173.0 0.0 9.3 9.3 0.1 LOW NOX 1.5

OHCU-I 41.0 1.5 200.0 0.0 12.0 0.0 0.1 LOW NOX 1.3

OHCU-II 41.1 2.1 200.0 0.0 24.3 0.1 0.3 LOW NOX 2.7

HGU-I 60.0 3.0 200.0 0.0 0.0 107.5 0.1 LOW NOX 5.8

HGU-II (PDS) 60.0 1.4 190.0 0.0 0.0 0.0 0.0 LOW NOX 0.0

HGU-II 60.0 2.3 145.0 0.0 0.0 110.3 0.1 LOW NOX 5.9

MSQ 60.0 0.9 230.0 0.0 5.7 0.0 0.1 LOW NOX 0.6

Prime-G 60 0.8 210 0.0 4.7 0.0 0.0 LOW NOX 0.5

TPS Boiler 116.0 4.5 110.0 9.8 0.0 99.6 4.2 LOW NOX 7.8

GT-I 60.0 3.5 120.0 0.0 0.0 216.0 0.3 LOW NOX 11.6

GT-II 60.0 3.5 120.0 0.0 0.0 216.0 0.3 LOW NOX 11.6

GT-III 60.0 3.5 120.0 0.0 0.0 216.0 0.3 LOW NOX 11.6

FLARE 95.0 5.3 1000.0 0.0 0.0 0.0 0.0 - 0.0

FCC-CO-Boiler 80.0 2.5 275.0 0.0 0.0 0.0 93.8 - 13.0

SRU- A, B, C, D 62.0 0.8 270.0 0.0 7.2 0.0 75.1 NORMAL 0.03

M-11 Stacks Proposed

SHU 60.0 * * 0.0 0.0 138.0 0.2 LOW NOX 7.4

New VDU 60.0 3.4 180.0 4.1 32.2 34.3 2.1 LOW NOX 6.4

OHCU-I new 41.0 2.5 200.0 0.0 54.5 0.1 0.6 LOW NOX 6.0

HGU-III 60.0 2.8 150.0 0.0 0.0 230.5 0.3 LOW NOX 12.4

New SRUs 60.0 0.78 270.0 0.0 21.7 0.0 225.2 LOW NOX 2.4

TGTU 62.0 0.80 190.0 0.0 0.0 9.7 0.0 LOW NOX 0.5

GT-V 60.0 3.5 120.0 0.0 0.0 386.5 0.5 LOW NOX 20.8

GT-VI 60.0 3.5 120.0 0.0 0.0 386.5 0.5 LOW NOX 20.8

TOTAL

111.0 668 2288 450.00 LOW NOX 235.73

Air Quality Prediction using ISCST3 MODEL in Agra City:-

There were 2 stations out of 15 stations, situated within Agra City and are about 25 KM away from Refinery to record the ground level concentration of pollutant. This baseline environmental data in the study period represents the emission level in existing scenario and includes the impact of the emissions from the existing facilities. The ground level concentration for SO2 was predicted in 50 KM radius using Industrial Source Complex Version 3, which is an AERMOD dispersion modeling program designed to estimate pollutant concentrations for simple, intermediate, or complex terrain.

In order to find any impact on Taj Mahal and TTZ zone, Air modeling is conducted for 50 kms radius from Mathura refinery and isopleth obtained is given below. The model shows that the air impact has already dissipated in this range itself and practically, there is no impact coming on

Taj Mahal. However, some minor impact of 5-6 g/m3 is noticed around 25 kms radius which further reduces towards Taj Mahal which is around 41 kms in south east direction from Mathura refinery.

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RESIDUE UP-GRADATION AND DISTILLATE YIELD

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PROCESSING AT MATHURA REFINERY OF

M/S INDIAN OIL CORPORATION LTD

Document No.

A257-SR-II-1741-1301

Template No. 5-0000-0001-T2 Rev. 1 Copyrights EIL – All rights reserved

Control of SO2 emissions: For control of SO2 emissions, SRUs, ARUs, TGTU, Palletizer and plantation activities have been suggested. For this activity, an amount of Rs. 112265.00 lakhs as capital cost and for additional plantation activities, recurring cost of Rs. 8.0 lakh/annum in addition to the capital cost has been estimated. Conclusion: Based on the Isopleth drawn for the capacity expansion, it has been concluded that the SO2 emissions resulting due to the capacity expansion is well within the limits as per the NAAQS for the study area of 25 km. When we examine the same for 50 km radius , the SO2 emissions has practically no effect on the Taj Mahal. Isopleth obtained for SO2 emissions in 50 kms radius from Mathura refinery including the location of Taj Mahal is shown in figure-1.9 below.

Fig.-1.9 - SO2 emission isopleths for 50 kms radius from Mathura Refinery

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RESIDUE UP-GRADATION AND DISTILLATE YIELD

IMPROVEMENT PROJECT WITH 11.0 MMTPA CRUDE

PROCESSING AT MATHURA REFINERY OF

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Document No.

A257-SR-II-1741-1301

Template No. 5-0000-0001-T2 Rev. 1 Copyrights EIL – All rights reserved

Annexure-III

Point – 3: Item-wise details along with time bound action plan for ESR (Enterprise Social Responsibility) for construction phase to be prepared and submitted As a part of Guidelines on Corporate Social Responsibility for Central Public Sector Enterprises,

dated 09.04.2010 from Ministry of Heavy Industries and Public Enterprises, IOCL, Mathura

Refinery has been implementing various projects in order to bring socio-economical progress in

the surrounding region.

Mathura Refinery undertakes these projects – short term and long term in consultation with

District Administration, request received from Gram Pradhans and based on the

recommendations of baseline survey for identified villages around the Refinery. The survey

focused on requirement of infrastructural facilities for schools like buildings, drainage, roads,

drinking water facility, provision of teaching aids/ equipments, library, table and chairs etc.

The Social Impact assessment study was carried out by Tata Institute of Social Science and

Engineers India Limited in 5 KM radius of Mathura Refinery as a part of EIA study for the

proposed capacity expansion project of Mathura Refinery. In the SIA study, focus areas for

social up-liftment have been identified as Medical and Health care, Clean Drinking, Sanitation,

Education, Infrastructure etc.

In compliance to the MoEF query, IOCL, Mathura Refinery shall be implementing project with

the cost of Rs 11.0 Crores during the 4 years of project construction phase in the aforesaid

areas for social up-liftment.

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