remedial bureau d 625 broadway 12th ... - nys dec...

ExxonMobil Environmental Services Company 400 Kingsland Avenue Brooklyn, New York 11222

MC0172.0030Y030.2014/ML

June 27, 2012

New York State Department of Environmental Conservation Division of Environmental Remediation Remedial Bureau D 625 Broadway 12th Floor Albany, New York 12233-7013

Attention: Mr. A. Joseph White

Re: Discharge Monitoring Report – May 2012 SPDES Permit No. NY-0267724 ExxonMobil Greenpoint Petroleum Remediation Project Greenpoint, Brooklyn, New York

Dear Mr. White:

ExxonMobil Oil Corporation is submitting this Discharge Monitoring Report (DMR) for the On-Site Free-Product Recovery System (RCS) and the Off-Site Free-Product Recovery System (ORS) for the month of May 2012, in accordance with the requirements of the New York State Department of Environmental Conservation (NYSDEC) State Pollution Discharge Elimination System (SPDES) Permit, No. NY-0267724. All results indicate no exceedances, as described below.

The RCS effluent was sampled on May 8, 2012 for the monthly DMR (Outfall 01A), with the RCS operating at a flow rate of approximately 351 gallons per minute (gpm). The average operational flow rate for the period of May 1, 2012 through May 31, 2012 was approximately 304 gpm. The total amount of flow treated and discharged by the RCS during this reporting period was approximately 12,454,095 gallons, of which, approximately 1,445,222 gallons were conveyed from the BP remedial system and approximately 8,272,009 gallons were conveyed from six ORS recovery wells (formerly known as the Off-Site wells). The RCS effluent sample results indicate no exceedances of either discharge quality or flow limits for the parameters specified in the monthly DMR (Outfall 01A).

The Outfall 001 discharge was sampled on May 8, 2012 for the monthly DMR (Outfall 001), at a flow rate of approximately 800 gpm; the RCS flow was approximately 351 gpm and the in-ground oil / water separator flow was approximately 449 gpm at the time of sampling. The total amount of flow treated and conveyed to Outfall 001 during this reporting period was approximately 13,371,416 gallons, of which approximately 917,321 gallons were conveyed from the in-ground oil / water separator and approximately 12,454,095 gallons were conveyed from the RCS. The Outfall 001 discharge sample results indicate no exceedances of either discharge quality or flow limits for the parameters specified in the monthly DMR (Outfall 001).

Mr. A. Joseph White June 27, 2012

MC0172.0030Y030.2014/ML

Summaries of the DMR analytical results for Outfall 01A and Outfall 001 are provided in Tables 1 and 2. A summary of the analytical results for additional parameters detected is provided in Table 3. The RCS laboratory analytical data are provided in Attachment 1. RCS photographs of the discharge point and receiving water taken in May 2012 are enclosed in Attachment 2. Based on visual inspections of the discharge location performed by RCS operations personnel on a periodic basis, the RCS discharge is in compliance with the narrative water quality standard for turbidity (NYCRR Title 6, Chapter X, Part 703.2). The DMR forms for Outfalls 001 and 01A are provided in Attachment 3.

On January 17, 2012, the RCS effluent and stormwater treatment processes were temporarily modified, in accordance with the RCS Bag Filter Pilot Study Work Plan (RCS Bag Filter Pilot Study), dated October 24, 2011, and approved by the NYSDEC on November 23, 2011. The approved RCS Bag Filter Pilot Study activities have continued throughout the month of May 2012. The analytical results from the RCS effluent samples collected in May 2012 continue to indicate no exceedances of discharge quality for the parameters specified for SPDES permitted Outfalls 01A and Outfall 001 during the RCS Bag Filter Pilot Study.

In accordance with the Sewer Installation Contingency and Monitoring Plan submitted by Roux Associates on October 6, 2011, the operation of a temporary construction dewatering treatment system associated with the sewer IRM activities initiated operation on October 13, 2011 and operated through December 12, 2011. The temporary treatment system was temporarily shut down on December 12, 2011 and initiated operation again on April 20, 2012. The temporary treatment system continued to operate throughout May 2012. The analytical results from the temporary treatment system effluent indicate no exceedances of discharge quality for the parameters specified for SPDES permitted Outfalls 01A.

On May 30, 2012, the RCS air stripper units began operating in a six-tray configuration in accordance with the RCS/ORS Air Stripper Implementation Plan, dated May 9, 2012. A sample was taken of the RCS influent and effluent within 20 minutes of the initial startup following the switch to the six-tray configuration. An additional sample was taken on May 31, 2012. The analytical results from the RCS effluent samples collected in May 2012 indicate no exceedances of discharge quality for the parameters specified for SPDES permitted Outfall 01A.

The ORS was sampled on May 8, 2012 for the monthly DMR (Outfall 002), with the ORS operating at a flow rate of approximately 305 gpm. The average operational flow rate for the period of May 1, 2012 through May 31, 2012 was approximately 387 gpm. The total amount of flow treated and discharged by the ORS during this reporting period was approximately 16,944,594 gallons. The ORS sample results indicate no exceedances of either the discharge quality or flow limits for the parameters specified in the monthly DMR (Outfall 002).

A summary of the DMR analytical results for Outfall 002 is provided in Table 4. A summary of the analytical results of additional parameters detected is provided in Table 5. The laboratory analytical data are provided in Attachment 1. Photographs of the discharge point and receiving water taken in May 2012 are enclosed in Attachment 2. Based on visual inspections of the discharge location performed by ORS operations personnel at the time of the sample collection,

Mr. A. Joseph White June 27, 2012

MC0172.0030Y030.2014/ML

the ORS discharge is in compliance with the narrative water quality standard for turbidity (NYCRR Title 6, Chapter X, Part 703.2). The DMR forms for Outfall 002 are provided in Attachment 3.

Should there be any questions or comments on this submission, please do not hesitate to contact me at 718.404.0652.

Sincerely,

Steve P. Trifiletti Project Manager

Attachments

cc: Regional Water Engineer (NYSDEC Region 2) – Long Island City, NY NYSDEC (Division of Water, Bureau of Water Compliance Programs) – Albany, NY [Attachment 3 Only] Justin Kennedy, Roux Associates, Inc.

Table 1. May 2012 Outfall 01A Discharge Monitoring Results Summary, Former ExxonMobil Brooklyn Terminal ExxonMobil Greenpoint Petroleum Remediation Project, Greenpoint, Brooklyn, New York

Discharge Loading (lbs / Day)

Parameter Daily Max Units Type RCS - Influent RCS - BP Influent RCS - Effluent RCS - AS Effluent

Flow 0.932 MGD DL -- -- 0.51 NA --

pH7 6.5 - 8.5 S.U. DL 6.96 7.04 7.74 NA --

Oil & Grease 15 mg/L DL 1.7 5.1 1.5 6.32715 11.8%

Total Suspended Solids 40 mg/L DL 9.6 27.6 10.8 45.55549 --

Settleable Solids 0.1 mL/L DL <0.10 <0.10 <0.10 <0.42181 --

1,1-Dichloroethane 10 µg/L DL 1 <1 <1 <0.00422 --

1,2-Dichloroethane 10 µg/L DL <1 <1 <1 <0.00422 --

Benzene 10 µg/L DL 220 58 2 0.00844 99.1%

Copper 95 µg/L DL <0.94 <0.94 <0.94 <0.00397 --

Ethylbenzene 5 µg/L DL 14 46 <0.8 <0.00337 >94.3%

Mercury Monitor µg/L -- <0.026 <0.026 <0.026 <0.00011 --

Methyl-tert-butyl ether 50 µg/L AL-I 18 22 5 0.02109 72.2%

Naphthalene 20 µg/L AL-I 4 46 3 0.01265 25.0%

Phenols Monitor µg/L -- <15 25 <15 <0.06327 --

Tetrachloroethylene 10 µg/L DL 78 <1 <1 <0.00422 >98.7%

Toluene 5 µg/L DL 12 3 <0.8 <0.00337 >93.3%

Trichloroethylene 10 µg/L DL 61 2 <1 <0.00422 >98.4%

Vinyl chloride 10 µg/L DL 3 <2 <2 <0.00844 >33.3%

Xylenes (Total) 10 µg/L DL 36 67 <0.9 <0.00380 >97.5%

Notes:1. mg/L - milligrams per Liter, µg/L - micrograms per Liter, mL/L - milliliters per Liter, MGD - million gallons per day2. NTU - Nephelometric Turbidity Unit3. NA - Not Applicable4. NM - Not Measured5. S.U. - Standard Unit6. NS - Not Sampled7. The pH was measured in the field at the time of sampling.8. "RCS - Influent" includes the untreated process water from the ExxonMobil recovery wells and BP's treatment system.9. "RCS - BP Influent" includes the untreated process water from the BP treatment system.10. "RCS - Effluent" includes the process water that has been treated and discharged by the air strippers.11. DL - Discharge Limit12. AL-1 - Action Limit Type I13. "RCS - Effluent" concentrations (highlighted column) are those that are used for comparison with the effluent discharge limits and action limits.14. The maximum daily flow is reported as the flow at the time of sampling.15. Outfall 01A was sampled on May 8, 2012.

SPDES Number: NY-0267724

Laboratory Analytical Method SummaryConstituent MethodVOCs (BTEX, TCE, etc.): EPA Method 624MTBE EPA Method 8260SVOCs (Naphthalene): EPA Method 625Oil & Grease EPA Method 1664AMetals (Copper, Iron, etc.): EPA Method 200.7Mercury EPA Method 245.1

*Copies of all laboratory chain of custody reports are maintained in files at the Roux Associates, Inc. office, located at 209 Shafter Street, Islandia, New York

Outfall 01A Discharge Limitations Results

EstimatedPercent Removal

ROUX ASSOCIATES, INC. 1 of 1 MC0172.0030Y030.2014/WKB

Table 2. May 2012 Outfall 001 Discharge Monitoring Results Summary, Former ExxonMobil Brooklyn Terminal ExxonMobil Greenpoint Petroleum Remediation Project, Greenpoint, Brooklyn, New York

ResultsDischarge Loading

(lbs / Day)Parameter Daily Max Units Type Outfall 001 Discharge Outfall 001 Discharge

Flow Monitor MGD -- 1.15 NA

pH7 6.5 - 8.5 S.U. DL 7.87 NA

Oil & Grease 15 mg/L DL 1.8 17.30503

Total Suspended Solids 40 mg/L DL 20.4 196.12368

System Turbidity7

(Influent / Discharge Pipe) Monitor NTU -- 44.2 NA

Turbidity7

(Receiving Water Background) Monitor NTU -- 12.3 NA

Notes:1. mg/L - milligrams per Liter, µg/L - micrograms per Liter, mL/L - milliliters per Liter, MGD - million gallons per day2. NTU - Nephelometric Turbidity Unit3. NA - Not Applicable4. NM - Not Measured5. S.U. - Standard Unit6. NS - Not Sampled7. pH, Turbidity, and System Turbidity were measured in the field.8. "Outfall 001 Discharge" includes stormwater and RCS - Effluent discharge.9. DL - Discharge Limit10. AL-1 - Action Limit Type I11. The maximum daily flow is reported as the flow at the time of sampling.12. Outfall 001 was sampled on May 8, 2012.


Laboratory Analytical Method SummaryConstituent MethodOil & Grease EPA Method 1664A

Outfall 001 Discharge Limitations

* Copies of all laboratory chain of custody reports are maintained in files at the Roux Associates, Inc. office, located at 209 Shafter Street, Islandia, New York


Table 3. May 2012 Outfall 01A Summary of Additional Detections, Former ExxonMobil Brooklyn Terminal ExxonMobil Greenpoint Petroleum Remediation Project, Greenpoint, Brooklyn, New York


Parameter Units RCS - Influent RCS - BP Influent RCS - Effluent RCS - AS Effluent

Flow MGD -- -- 0.51 NA --

Acenaphthene µg/L 5 11 4 0.01687 20.0%

Anthracene µg/L 0.7 5 0.5 0.00211 28.6%

Chrysene µg/L 0.4 3 0.3 0.00127 25.0%

2,4-Dimethylphenol µg/L 2 <3 1 0.00422 50.0%

Fluoranthene µg/L 0.6 <3 0.5 0.00211 16.7%

Fluorene µg/L 3 14 2 0.00844 33.3%

Phenanthrene µg/L 5 37 4 0.01687 20.0%

Pyrene µg/L 0.9 8 0.8 0.00337 11.1%

Notes:1. mg/L - milligrams per Liter, µg/L - micrograms per Liter, mL/L - milliliters per Liter, MGD - million gallons per day2. NTU - Nephelometric Turbidity Unit3. NA - Not Applicable4. NM - Not Measured5. S.U. - Standard Unit6. NS - Sample not analyzed for this parameter; analysis not required by permit7. "RCS - Influent" includes the untreated process water from the ExxonMobil recovery wells and BP's treatment system.8. "RCS - BP Influent" includes the untreated process water from the BP treatment system.9. "RCS - Effluent" includes the process water that has been treated and discharged by the air strippers.10. DL - Discharge Limit11. AL-1 - Action Limit Type I12. "RCS - Effluent" concentrations (highlighted column) are those that are used for comparison with the effluent discharge limits and action limits.13. The maximum daily flow is reported as the flow at the time of sampling.14. Outfall 01A was sampled on May 8, 2012.


Laboratory Analytical Method SummaryConstituent MethodVOCs (BTEX, TCE, ect.): EPA Method 624SVOCs: EPA Method 625


Outfall 01A Results



Table 4. May 2012 Outfall 002 Discharge Monitoring Results Summary, Off-Site Free-Product Recovery System ExxonMobil Greenpoint Petroleum Remediation Project, Greenpoint, Brooklyn, New York

Discharge Loading

(lbs / Day)

Parameter Daily Max Units Type OSS - Influent OSS - Effluent Effluent

Flow 0.62 MGD DL -- 0.44 NA --

pH 6.5 - 8.5 S.U. DL 6.86 7.65 NA --

Oil & Grease 15 mg/L DL 2.0 <1.4 <5.13142 --

Total Suspended Solids 40 mg/L DL 28.8 7.2 26.39017 75.0%

System Turbidity(Influent / Discharge Pipe)

Monitor NTU -- 4.5 21.2 NA --

Turbidity (Receiving Water) Monitor NTU -- -- 10.2 NA --

Settleable Solids 0.1 mL/L DL <0.10 <0.10 <0.36653 --

1,1-Dichloroethane 10 µg/L DL 3 <1 <0.00367 >66.7%

1,2-Dichloroethane 10 µg/L DL <2 <1 <0.00367 >50.0%

Benzene 40 µg/L DL 710 <0.9 <0.00330 >99.9%

Copper 95 µg/L DL 7.3 2.4 0.00880 67.1%

Ethylbenzene 5 µg/L DL 46 <0.8 <0.00293 >98.3%

Mercury Monitor µg/L -- <0.026 <0.026 <0.00010 --

Methyl-tert-butyl ether 90 µg/L AL-I 61 13 0.04765 78.7%

Naphthalene 40 µg/L AL-I 23 <0.2 <0.00073 >99.1%

Phenols Monitor µg/L -- 21 <15 <0.05498 >28.6%

Tetrachloroethylene 10 µg/L DL 270 <1 <0.00367 >99.6%

Toluene 10 µg/L DL 64 <0.8 <0.00293 >98.8%

Trichloroethylene 20 µg/L DL 360 <1 <0.00367 >99.7%

Vinyl chloride 10 µg/L DL 29 <2 <0.00733 >93.1%

Xylenes 20 µg/L DL 210 <0.9 <0.00330 >99.6%

Notes:1. mg/L - milligrams per Liter, µg/L - micrograms per Liter, mL/L - milliliters per Liter, MGD - million gallons per day2. NTU - Nephelometric Turbidity Unit3. NA - Not Applicable4. NM - Not Measured5. S.U. - Standard Unit6. NS - Not Sampled7. pH and Turbidity were measured in the field at the time of sampling.8. "OSS - Effluent" includes the treated Off-Site System effluent to be discharged at Outfall 002.9. "OSS - Influent" includes the untreated process water from the recovery wells to be treated by the Off-Site System.10. DL-Discharge Limit11. AL-1 - Action Limit Type I12. Effluent concentrations (highlighted column) are those that are used for comparison with the effluent discharge limits and action limits.13. The maximum daily flow is reported as the flow at the time of sampling.14. Outfall 002 was sampled on May 8, 2012.


Laboratory Analytical Method SummaryConstituent MethodVOCs (BTEX, TCE, etc.): EPA Method 624MTBE EPA Method 8260SVOCs (Naphthalene): EPA Method 625Oil & Grease EPA Method 1664AMetals (Copper, Iron, etc.): EPA Method 200.7Mercury EPA Method 245.1


Outfall 002 Discharge Limitations Results



Table 5. May 2012 Outfall 002 Summary of Additional Detections, Off-Site Free-Product Recovery System ExxonMobil Greenpoint Petroleum Remediation Project, Greenpoint, Brooklyn, New York


Parameter Units OSS - Influent OSS - Effluent Effluent

Flow MGD -- 0.44 NA --

cis-1,2-Dichloroethene µg/L 320 2 0.007330603 99.38%

2-Chloronaphthalene µg/L 0.2 0.2 0.00073306 --

2,4-Dimethylphenol µg/L 0.8 0.7 0.002565711 12.50%

Notes:1. mg/L - milligrams per Liter, µg/L - micrograms per Liter, mL/L - milliliters per Liter, MGD - million gallons per day2. NTU - Nephelometric Turbidity Unit3. NA - Not Applicable4. NM - Not Measured5. S.U. - Standard Unit6. NS - Not Sampled7. "OSS - Effluent" includes the treated Off-Site System effluent to be discharged at Outfall 002.8. "OSS - Influent" includes the untreated process water from the recovery wells to be treated by the Off-Site System.9. AL-1 - Action Limit Type I10. Effluent concentrations (highlighted column) are those that are used for comparison with the effluent discharge limits and action limits.11. The maximum daily flow is reported as the flow at the time of sampling.12. Outfall 002 was sampled on May 8, 2012.


Laboratory Analytical Method SummaryConstituent MethodVOCs (BTEX, TCE, etc.): EPA Method 624SVOCs: EPA Method 625

Outfall 002 Results


* Copies of all laboratory chain of custody reports are maintained in files at the Roux Associates, Inc. office, located at 209 Shafter Street, Islandia, New York


ROUX ASSOCIATES, INC. MC0172.0030Y030.2014/AT-CV

ATTACHMENT 1

Laboratory Analytical Data (Provided on CD in Bound Report)

ANALYTICAL RESULTS

Prepared by:

Lancaster Laboratories 2425 New Holland Pike

Lancaster, PA 17605-2425

Prepared for:

ExxonMobil Refining & Supply 38 Varick Street

Brooklyn NY 11222

May 18, 2012

Project: Greenpoint Project

Submittal Date: 05/09/2012 Group Number: 1307584 PO Number: 4514664449

Release Number: TRIFILETTI State of Sample Origin: NY

Client Sample Description Lancaster Labs (LLI) # RCS-Influent Grab Water 6644911 RCS-Effluent Grab Water 6644912 RCS-Inground OWS Effluent Grab Water 6644913 RCS-BP Influent Grab Water 6644914 Outfall 001 Grab Water 6644915 Receiving Water-001 Grab Water 6644916 QAQC_TB Water 6644917 The specific methodologies used in obtaining the enclosed analytical results are indicated on the Laboratory Sample Analysis Record. ELECTRONIC COPY TO

Roux Associates, Inc. Attn: Michael Ritorto

Respectfully Submitted,

(717) 556-7250

of 4

LLI Sample # WW 6644911LLI Group # 1307584 Account # 13438

Sample Description: RCS-Influent Grab Water S2010L4647 Greenpoint, NY XOM Brooklyn Terminal Project Name: Greenpoint Project

Collected: 05/08/2012 10:00 by MS

Submitted: 05/09/2012 09:25

ExxonMobil Refining & Supply

Reported: 05/18/2012 17:58

38 Varick StreetBrooklyn NY 11222

RCS-I As Received Limit of Quantitation

As ReceivedMethod Detection Limit* As Received

ResultAnalysis Name CAS NumberDilutionFactor

CAT No.

ug/l ug/lug/lGC/MS Volatiles EPA 624N.D. 1107-02-8 10371 10 50 Acrolein N.D. 1107-13-1 10371 10 50 Acrylonitrile 220 171-43-2 10371 0.9 5 Benzene N.D. 175-27-4 10371 0.7 5 Bromodichloromethane N.D. 175-25-2 10371 0.8 5 Bromoform N.D. 174-83-9 10371 2 5 Bromomethane N.D. 156-23-5 10371 1 5 Carbon Tetrachloride N.D. 1108-90-7 10371 0.8 5 Chlorobenzene N.D. 175-00-3 10371 2 5 Chloroethane N.D. 1110-75-8 10371 2 10 2-Chloroethyl Vinyl Ether

2-Chloroethyl vinyl ether may not be recovered if acid was used to preserve this sample.

N.D. 167-66-3 10371 1 5 Chloroform N.D. 174-87-3 10371 2 5 Chloromethane N.D. 1124-48-1 10371 1 5 Dibromochloromethane N.D. 195-50-1 10371 1 5 1,2-Dichlorobenzene N.D. 1541-73-1 10371 1 5 1,3-Dichlorobenzene N.D. 1106-46-7 10371 1 5 1,4-Dichlorobenzene N.D. 175-71-8 10371 2 5 Dichlorodifluoromethane 1 J 175-34-3 10371 1 5 1,1-Dichloroethane N.D. 1107-06-2 10371 1 5 1,2-Dichloroethane 2 J 175-35-4 10371 0.9 5 1,1-Dichloroethene 41 1156-59-2 10371 1 5 cis-1,2-Dichloroethene 3 J 1156-60-5 10371 1 5 trans-1,2-Dichloroethene N.D. 178-87-5 10371 1 5 1,2-Dichloropropane N.D. 110061-01-510371 1 5 cis-1,3-Dichloropropene N.D. 110061-02-610371 0.6 5 trans-1,3-Dichloropropene 14 1100-41-4 10371 0.8 5 Ethylbenzene N.D. 175-09-2 10371 2 5 Methylene Chloride N.D. 179-34-5 10371 1 5 1,1,2,2-Tetrachloroethane 78 1127-18-4 10371 1 5 Tetrachloroethene 12 1108-88-3 10371 0.8 5 Toluene N.D. 171-55-6 10371 1 5 1,1,1-Trichloroethane N.D. 179-00-5 10371 1 5 1,1,2-Trichloroethane 61 179-01-6 10371 1 5 Trichloroethene N.D. 175-69-4 10371 2 5 Trichlorofluoromethane 3 J 175-01-4 10371 2 5 Vinyl Chloride 36 11330-20-7 10371 0.9 5 Xylene (total)

ug/l ug/lug/lGC/MS Volatiles SW-846 8260B 18 11634-04-4 10943 0.5 1 Methyl Tertiary Butyl Ether

ug/l ug/lug/lGC/MS Semivolatiles EPA 6255 183-32-9 10334 0.3 5 Acenaphthene N.D. 1208-96-8 10334 0.3 5 Acenaphthylene 0.7 J 1120-12-7 10334 0.2 5 Anthracene N.D. 192-87-5 10334 20 59 Benzidine 0.4 J 156-55-3 10334 0.2 5 Benzo(a)anthracene N.D. 150-32-8 10334 0.3 5 Benzo(a)pyrene

*=This limit was used in the evaluation of the final result

of 4



Collected: 05/08/2012 10:00 by MS

Submitted: 05/09/2012 09:25


Reported: 05/18/2012 17:58





CAT No.

ug/l ug/lug/lGC/MS Semivolatiles EPA 625N.D. 1205-99-2 10334 0.3 5 Benzo(b)fluoranthene N.D. 1191-24-2 10334 0.2 5 Benzo(g,h,i)perylene N.D. 1207-08-9 10334 0.3 5 Benzo(k)fluoranthene N.D. 1101-55-3 10334 0.3 5 4-Bromophenyl-phenylether N.D. 185-68-7 10334 0.8 5 Butylbenzylphthalate N.D. 184-74-2 10334 0.5 5 Di-n-butylphthalate N.D. 159-50-7 10334 0.3 5 4-Chloro-3-methylphenol N.D. 1106-47-8 10334 0.3 5 4-Chloroaniline N.D. 1111-91-1 10334 0.5 5 bis(2-Chloroethoxy)methane N.D. 1111-44-4 10334 0.4 5 bis(2-Chloroethyl)ether N.D. 139638-32-910334 0.3 5 bis(2-Chloroisopropyl)ether N.D. 191-58-7 10334 0.2 5 2-Chloronaphthalene N.D. 195-57-8 10334 0.3 5 2-Chlorophenol N.D. 17005-72-3 10334 0.3 5 4-Chlorophenyl-phenylether 0.4 J 1218-01-9 10334 0.2 5 Chrysene N.D. 153-70-3 10334 0.4 5 Dibenz(a,h)anthracene N.D. 195-50-1 10334 0.3 5 1,2-Dichlorobenzene N.D. 1541-73-1 10334 0.3 5 1,3-Dichlorobenzene N.D. 1106-46-7 10334 0.3 5 1,4-Dichlorobenzene N.D. 191-94-1 10334 0.8 5 3,3'-Dichlorobenzidine N.D. 1120-83-2 10334 0.3 5 2,4-Dichlorophenol N.D. 184-66-2 10334 0.3 5 Diethylphthalate 2 J 1105-67-9 10334 0.3 5 2,4-Dimethylphenol N.D. 1131-11-3 10334 1 5 Dimethylphthalate N.D. 1534-52-1 10334 4 15 4,6-Dinitro-2-methylphenol N.D. 151-28-5 10334 10 29 2,4-Dinitrophenol N.D. 1121-14-2 10334 0.4 5 2,4-Dinitrotoluene N.D. 1606-20-2 10334 0.3 5 2,6-Dinitrotoluene N.D. 1122-66-7 10334 0.2 5 1,2-Diphenylhydrazine N.D. 1117-81-7 10334 1 5 bis(2-Ethylhexyl)phthalate 0.6 J 1206-44-0 10334 0.3 5 Fluoranthene 3 J 186-73-7 10334 0.3 5 Fluorene N.D. 1118-74-1 10334 1 5 Hexachlorobenzene N.D. 187-68-3 10334 0.8 5 Hexachlorobutadiene N.D. 177-47-4 10334 2 15 Hexachlorocyclopentadiene N.D. 167-72-1 10334 0.4 5 Hexachloroethane N.D. 1193-39-5 10334 0.3 5 Indeno(1,2,3-cd)pyrene N.D. 178-59-1 10334 0.3 5 Isophorone 4 J 191-20-3 10334 0.2 5 Naphthalene N.D. 198-95-3 10334 0.5 5 Nitrobenzene N.D. 188-75-5 10334 0.4 5 2-Nitrophenol N.D. 1100-02-7 10334 5 10 4-Nitrophenol N.D. 162-75-9 10334 2 5 N-Nitrosodimethylamine N.D. 1621-64-7 10334 0.4 5 N-Nitroso-di-n-propylamine N.D. 186-30-6 10334 0.3 5 N-Nitrosodiphenylamine N.D. 1117-84-0 10334 0.5 5 Di-n-octylphthalate N.D. 187-86-5 10334 3 15 Pentachlorophenol 5 185-01-8 10334 0.2 5 Phenanthrene 3 J 1108-95-2 10334 0.4 5 Phenol 0.9 J 1129-00-0 10334 0.2 5 Pyrene


of 4



Collected: 05/08/2012 10:00 by MS

Submitted: 05/09/2012 09:25


Reported: 05/18/2012 17:58





CAT No.

ug/l ug/lug/lGC/MS Semivolatiles EPA 625N.D. 1120-82-1 10334 0.3 5 1,2,4-Trichlorobenzene N.D. 188-06-2 10334 0.7 5 2,4,6-Trichlorophenol

ug/l ug/lug/lMetals EPA 200.7 rev 4.4 224,000 17440-70-2 01750 70.5 200 Calcium N.D. 17440-50-8 07053 0.94 10.0 Copper 5,990 17439-89-6 01754 14.1 200 Iron 3,620 17439-96-5 07058 0.44 5.0 Manganese

ug/l ug/lug/lEPA 245.1 rev 3 N.D. 17439-97-6 00259 0.026 0.20 Mercury

ug/l ug/lug/lWet Chemistry EPA 300.0 1,180,000 50016887-00-600224 100,000 200,000 Chloride

ug/l ug/lug/lEPA 420.4 N.D. 1n.a. 00434 15 40 Phenols (water)

ug/l ug/lug/lEPA 1664A 1,700 J 1n.a. 08079 1,400 5,000 HEM (oil & grease)

N T U N T UN T UEPA 180.1 (1993) 36.6 1n.a. 00279 0.090 0.30 Turbidity

ug/l ug/lug/lSM20 2540 D 9,600 J 1n.a. 00206 3,000 12,000 Total Suspended Solids

ml/l/hr ml/l/hrml/l/hrSM20 2540 F N.D. 1n.a. 00215 0.10 0.10 Settleable Solids

Sufficient sample volume was not available to perform a duplicate for thisanalysis.

Std. Units Std. UnitsStd. UnitsSM20 4500 H/B 6.9 1n.a. 00200 0.010 0.010 pH

General Sample CommentsState of New York Certification No. 10670 All QC is compliant unless otherwise noted. Please refer to the Quality Control Summary for overall QC performance data and associated samples.


of 4



Collected: 05/08/2012 10:00 by MS

Submitted: 05/09/2012 09:25


Reported: 05/18/2012 17:58


RCS-I

Method Analysis Name CAT No.

AnalysisDate and Time

Batch#Trial# Dilution Factor

Analyst

Laboratory Sample Analysis Record

1Jason M Long05/15/2012 18:59 E121361AA1EPA 624 VOCs by 624 10371 1Kevin A Sposito05/11/2012 22:42 F121324AA1SW-846 8260B MTBE Only 8260B Water 10943 1Kevin A Sposito05/11/2012 22:42 F121324AA1SW-846 5030B GC/MS VOA Water Prep 01163 1Holly Berry05/14/2012 07:45 12130WAJ6251EPA 625 Method 625 10334 1Cynthia J

Salvatori 05/10/2012 08:30 12130WAJ6251EPA 625 625 Water Extraction 08108

1Joanne M Gates05/11/2012 13:28 1213057160071EPA 200.7 rev 4.4Calcium 01750 1Joanne M Gates05/11/2012 13:28 1213057160071EPA 200.7 rev 4.4Copper 07053 1Joanne M Gates05/11/2012 13:28 1213057160071EPA 200.7 rev 4.4Iron 01754 1Joanne M Gates05/11/2012 13:28 1213057160071EPA 200.7 rev 4.4Manganese 07058 1Parker D Lindstrom05/11/2012 15:20 1213157140011EPA 245.1 rev 3Mercury 00259

1James L Mertz05/10/2012 12:00 1213057160071EPA 200.7 rev 4.4EPA 600 ICP Digest (tot rec)

05716

1Nelli S Markaryan05/10/2012 17:50 1213157140011EPA 245.1 rev 3PW/WW Hg Digest 05714 500Clinton M Wilson05/16/2012 14:01 12136987121B1EPA 300.0 Chloride 00224 1K Robert

Caulfeild-James05/15/2012 08:28 12135113101A1EPA 420.4 Phenols (water) 00434

1Nancy J Shoop05/14/2012 10:10 12135113101A1EPA 420.4 Phenol Distillation (water) 00491

1Yolunder Y Bunch05/17/2012 08:12 12138807901A1EPA 1664A HEM (oil & grease) 08079 1Luz M Groff05/09/2012 20:45 12130027902B1EPA 180.1 (1993)Turbidity 00279 1Hannah M Royer05/11/2012 10:06 12132020602B1SM20 2540 D Total Suspended Solids 00206 1Luz M Groff05/09/2012 15:15 12130021501A1SM20 2540 F Settleable Solids 00215 1Luz M Groff05/09/2012 22:30 12130020003A1SM20 4500 H/B pH 00200


of 4


Sample Description: RCS-Effluent Grab Water S2010L4647 Greenpoint, NY XOM Brooklyn Terminal Project Name: Greenpoint Project

Collected: 05/08/2012 09:45 by MS

Submitted: 05/09/2012 09:25


Reported: 05/18/2012 17:58


RCS-E As Received Limit of Quantitation



CAT No.

ug/l ug/lug/lGC/MS Volatiles EPA 624N.D. 1107-02-8 10371 10 50 Acrolein N.D. 1107-13-1 10371 10 50 Acrylonitrile 2 J 171-43-2 10371 0.9 5 Benzene N.D. 175-27-4 10371 0.7 5 Bromodichloromethane N.D. 175-25-2 10371 0.8 5 Bromoform N.D. 174-83-9 10371 2 5 Bromomethane N.D. 156-23-5 10371 1 5 Carbon Tetrachloride N.D. 1108-90-7 10371 0.8 5 Chlorobenzene N.D. 175-00-3 10371 2 5 Chloroethane N.D. 1110-75-8 10371 2 10 2-Chloroethyl Vinyl Ether


N.D. 167-66-3 10371 1 5 Chloroform N.D. 174-87-3 10371 2 5 Chloromethane N.D. 1124-48-1 10371 1 5 Dibromochloromethane N.D. 195-50-1 10371 1 5 1,2-Dichlorobenzene N.D. 1541-73-1 10371 1 5 1,3-Dichlorobenzene N.D. 1106-46-7 10371 1 5 1,4-Dichlorobenzene N.D. 175-71-8 10371 2 5 Dichlorodifluoromethane N.D. 175-34-3 10371 1 5 1,1-Dichloroethane N.D. 1107-06-2 10371 1 5 1,2-Dichloroethane N.D. 175-35-4 10371 0.9 5 1,1-Dichloroethene N.D. 1156-59-2 10371 1 5 cis-1,2-Dichloroethene N.D. 1156-60-5 10371 1 5 trans-1,2-Dichloroethene N.D. 178-87-5 10371 1 5 1,2-Dichloropropane N.D. 110061-01-510371 1 5 cis-1,3-Dichloropropene N.D. 110061-02-610371 0.6 5 trans-1,3-Dichloropropene N.D. 1100-41-4 10371 0.8 5 Ethylbenzene N.D. 175-09-2 10371 2 5 Methylene Chloride N.D. 179-34-5 10371 1 5 1,1,2,2-Tetrachloroethane N.D. 1127-18-4 10371 1 5 Tetrachloroethene N.D. 1108-88-3 10371 0.8 5 Toluene N.D. 171-55-6 10371 1 5 1,1,1-Trichloroethane N.D. 179-00-5 10371 1 5 1,1,2-Trichloroethane N.D. 179-01-6 10371 1 5 Trichloroethene N.D. 175-69-4 10371 2 5 Trichlorofluoromethane N.D. 175-01-4 10371 2 5 Vinyl Chloride N.D. 11330-20-7 10371 0.9 5 Xylene (total)


ug/l ug/lug/lGC/MS Semivolatiles EPA 6254 J 183-32-9 10334 0.3 5 Acenaphthene N.D. 1208-96-8 10334 0.3 5 Acenaphthylene 0.5 J 1120-12-7 10334 0.2 5 Anthracene N.D. 192-87-5 10334 20 59 Benzidine N.D. 156-55-3 10334 0.2 5 Benzo(a)anthracene N.D. 150-32-8 10334 0.3 5 Benzo(a)pyrene


of 4



Collected: 05/08/2012 09:45 by MS

Submitted: 05/09/2012 09:25


Reported: 05/18/2012 17:58





CAT No.

ug/l ug/lug/lGC/MS Semivolatiles EPA 625N.D. 1205-99-2 10334 0.3 5 Benzo(b)fluoranthene N.D. 1191-24-2 10334 0.2 5 Benzo(g,h,i)perylene N.D. 1207-08-9 10334 0.3 5 Benzo(k)fluoranthene N.D. 1101-55-3 10334 0.3 5 4-Bromophenyl-phenylether N.D. 185-68-7 10334 0.8 5 Butylbenzylphthalate N.D. 184-74-2 10334 0.5 5 Di-n-butylphthalate N.D. 159-50-7 10334 0.3 5 4-Chloro-3-methylphenol N.D. 1106-47-8 10334 0.3 5 4-Chloroaniline N.D. 1111-91-1 10334 0.5 5 bis(2-Chloroethoxy)methane N.D. 1111-44-4 10334 0.4 5 bis(2-Chloroethyl)ether N.D. 139638-32-910334 0.3 5 bis(2-Chloroisopropyl)ether N.D. 191-58-7 10334 0.2 5 2-Chloronaphthalene N.D. 195-57-8 10334 0.3 5 2-Chlorophenol N.D. 17005-72-3 10334 0.3 5 4-Chlorophenyl-phenylether 0.3 J 1218-01-9 10334 0.2 5 Chrysene N.D. 153-70-3 10334 0.4 5 Dibenz(a,h)anthracene N.D. 195-50-1 10334 0.3 5 1,2-Dichlorobenzene N.D. 1541-73-1 10334 0.3 5 1,3-Dichlorobenzene N.D. 1106-46-7 10334 0.3 5 1,4-Dichlorobenzene N.D. 191-94-1 10334 0.8 5 3,3'-Dichlorobenzidine N.D. 1120-83-2 10334 0.3 5 2,4-Dichlorophenol N.D. 184-66-2 10334 0.3 5 Diethylphthalate 1 J 1105-67-9 10334 0.3 5 2,4-Dimethylphenol N.D. 1131-11-3 10334 1 5 Dimethylphthalate N.D. 1534-52-1 10334 4 15 4,6-Dinitro-2-methylphenol N.D. 151-28-5 10334 10 30 2,4-Dinitrophenol N.D. 1121-14-2 10334 0.4 5 2,4-Dinitrotoluene N.D. 1606-20-2 10334 0.3 5 2,6-Dinitrotoluene N.D. 1122-66-7 10334 0.2 5 1,2-Diphenylhydrazine N.D. 1117-81-7 10334 1 5 bis(2-Ethylhexyl)phthalate 0.5 J 1206-44-0 10334 0.3 5 Fluoranthene 2 J 186-73-7 10334 0.3 5 Fluorene N.D. 1118-74-1 10334 1 5 Hexachlorobenzene N.D. 187-68-3 10334 0.8 5 Hexachlorobutadiene N.D. 177-47-4 10334 2 15 Hexachlorocyclopentadiene N.D. 167-72-1 10334 0.4 5 Hexachloroethane N.D. 1193-39-5 10334 0.3 5 Indeno(1,2,3-cd)pyrene N.D. 178-59-1 10334 0.3 5 Isophorone 3 J 191-20-3 10334 0.2 5 Naphthalene N.D. 198-95-3 10334 0.5 5 Nitrobenzene N.D. 188-75-5 10334 0.4 5 2-Nitrophenol N.D. 1100-02-7 10334 5 10 4-Nitrophenol N.D. 162-75-9 10334 2 5 N-Nitrosodimethylamine N.D. 1621-64-7 10334 0.4 5 N-Nitroso-di-n-propylamine N.D. 186-30-6 10334 0.3 5 N-Nitrosodiphenylamine N.D. 1117-84-0 10334 0.5 5 Di-n-octylphthalate N.D. 187-86-5 10334 3 15 Pentachlorophenol 4 J 185-01-8 10334 0.2 5 Phenanthrene N.D. 1108-95-2 10334 0.4 5 Phenol 0.8 J 1129-00-0 10334 0.2 5 Pyrene


of 4



Collected: 05/08/2012 09:45 by MS

Submitted: 05/09/2012 09:25


Reported: 05/18/2012 17:58





CAT No.














of 4



Collected: 05/08/2012 09:45 by MS

Submitted: 05/09/2012 09:25


Reported: 05/18/2012 17:58


RCS-E




Analyst






05716






of 1


Sample Description: RCS-Inground OWS Effluent Grab Water S2010L4647 Greenpoint, NY XOM Brooklyn Terminal Project Name: Greenpoint Project

Collected: 05/08/2012 10:45 by MS

Submitted: 05/09/2012 09:25


Reported: 05/18/2012 17:58


RCS-O As Received Limit of Quantitation



CAT No.

ug/l ug/lug/lWet Chemistry EPA 300.0 393,000 10016887-00-600224 20,000 40,000 Chloride

ug/l ug/lug/lEPA 1664A N.D. 1n.a. 08079 1,400 5,000 HEM (oil & grease)


ug/l ug/lug/lSM20 2540 D 52,700 1n.a. 00206 5,000 20,000 Total Suspended Solids






Analyst


100Clinton M Wilson05/15/2012 19:57 12136987121B1EPA 300.0 Chloride 00224 1Yolunder Y Bunch05/17/2012 08:12 12138807901A1EPA 1664A HEM (oil & grease) 08079 4Luz M Groff05/09/2012 20:45 12130027902B1EPA 180.1 (1993)Turbidity 00279 1Hannah M Royer05/11/2012 10:06 12132020602B1SM20 2540 D Total Suspended Solids 00206 1Luz M Groff05/09/2012 22:30 12130020003A1SM20 4500 H/B pH 00200


of 4


Sample Description: RCS-BP Influent Grab Water S2010L4647 Greenpoint, NY XOM Brooklyn Terminal Project Name: Greenpoint Project

Collected: 05/08/2012 11:15 by MS

Submitted: 05/09/2012 09:25


Reported: 05/18/2012 17:58


RCS-B As Received Limit of Quantitation



CAT No.



N.D. 167-66-3 10371 1 5 Chloroform N.D. 174-87-3 10371 2 5 Chloromethane N.D. 1124-48-1 10371 1 5 Dibromochloromethane N.D. 195-50-1 10371 1 5 1,2-Dichlorobenzene N.D. 1541-73-1 10371 1 5 1,3-Dichlorobenzene N.D. 1106-46-7 10371 1 5 1,4-Dichlorobenzene N.D. 175-71-8 10371 2 5 Dichlorodifluoromethane N.D. 175-34-3 10371 1 5 1,1-Dichloroethane N.D. 1107-06-2 10371 1 5 1,2-Dichloroethane N.D. 175-35-4 10371 0.9 5 1,1-Dichloroethene 4 J 1156-59-2 10371 1 5 cis-1,2-Dichloroethene N.D. 1156-60-5 10371 1 5 trans-1,2-Dichloroethene N.D. 178-87-5 10371 1 5 1,2-Dichloropropane N.D. 110061-01-510371 1 5 cis-1,3-Dichloropropene N.D. 110061-02-610371 0.6 5 trans-1,3-Dichloropropene 46 1100-41-4 10371 0.8 5 Ethylbenzene N.D. 175-09-2 10371 2 5 Methylene Chloride N.D. 179-34-5 10371 1 5 1,1,2,2-Tetrachloroethane N.D. 1127-18-4 10371 1 5 Tetrachloroethene 3 J 1108-88-3 10371 0.8 5 Toluene N.D. 171-55-6 10371 1 5 1,1,1-Trichloroethane N.D. 179-00-5 10371 1 5 1,1,2-Trichloroethane 2 J 179-01-6 10371 1 5 Trichloroethene N.D. 175-69-4 10371 2 5 Trichlorofluoromethane N.D. 175-01-4 10371 2 5 Vinyl Chloride 67 11330-20-7 10371 0.9 5 Xylene (total)


ug/l ug/lug/lGC/MS Semivolatiles EPA 62511 J 1083-32-9 10334 3 50 Acenaphthene 3 J 10208-96-8 10334 3 50 Acenaphthylene 5 J 10120-12-7 10334 2 50 Anthracene N.D. 1092-87-5 10334 200 600 Benzidine N.D. 1056-55-3 10334 2 50 Benzo(a)anthracene N.D. 1050-32-8 10334 3 50 Benzo(a)pyrene


of 4



Collected: 05/08/2012 11:15 by MS

Submitted: 05/09/2012 09:25


Reported: 05/18/2012 17:58





CAT No.

ug/l ug/lug/lGC/MS Semivolatiles EPA 625N.D. 10205-99-2 10334 3 50 Benzo(b)fluoranthene N.D. 10191-24-2 10334 2 50 Benzo(g,h,i)perylene N.D. 10207-08-9 10334 3 50 Benzo(k)fluoranthene N.D. 10101-55-3 10334 3 50 4-Bromophenyl-phenylether N.D. 1085-68-7 10334 8 50 Butylbenzylphthalate N.D. 1084-74-2 10334 5 50 Di-n-butylphthalate N.D. 1059-50-7 10334 3 50 4-Chloro-3-methylphenol N.D. 10106-47-8 10334 3 50 4-Chloroaniline N.D. 10111-91-1 10334 5 50 bis(2-Chloroethoxy)methane N.D. 10111-44-4 10334 4 50 bis(2-Chloroethyl)ether N.D. 1039638-32-910334 3 50 bis(2-Chloroisopropyl)ether 2 J 1091-58-7 10334 2 50 2-Chloronaphthalene N.D. 1095-57-8 10334 3 50 2-Chlorophenol N.D. 107005-72-3 10334 3 50 4-Chlorophenyl-phenylether 3 J 10218-01-9 10334 2 50 Chrysene N.D. 1053-70-3 10334 4 50 Dibenz(a,h)anthracene N.D. 1095-50-1 10334 3 50 1,2-Dichlorobenzene N.D. 10541-73-1 10334 3 50 1,3-Dichlorobenzene N.D. 10106-46-7 10334 3 50 1,4-Dichlorobenzene N.D. 1091-94-1 10334 8 50 3,3'-Dichlorobenzidine N.D. 10120-83-2 10334 3 50 2,4-Dichlorophenol N.D. 1084-66-2 10334 3 50 Diethylphthalate N.D. 10105-67-9 10334 3 50 2,4-Dimethylphenol N.D. 10131-11-3 10334 10 50 Dimethylphthalate N.D. 10534-52-1 10334 40 150 4,6-Dinitro-2-methylphenol N.D. 1051-28-5 10334 100 300 2,4-Dinitrophenol N.D. 10121-14-2 10334 4 50 2,4-Dinitrotoluene N.D. 10606-20-2 10334 3 50 2,6-Dinitrotoluene N.D. 10122-66-7 10334 2 50 1,2-Diphenylhydrazine N.D. 10117-81-7 10334 10 50 bis(2-Ethylhexyl)phthalate N.D. 10206-44-0 10334 3 50 Fluoranthene 14 J 1086-73-7 10334 3 50 Fluorene N.D. 10118-74-1 10334 10 50 Hexachlorobenzene N.D. 1087-68-3 10334 8 50 Hexachlorobutadiene N.D. 1077-47-4 10334 20 150 Hexachlorocyclopentadiene N.D. 1067-72-1 10334 4 50 Hexachloroethane N.D. 10193-39-5 10334 3 50 Indeno(1,2,3-cd)pyrene N.D. 1078-59-1 10334 3 50 Isophorone 46 J 1091-20-3 10334 2 50 Naphthalene N.D. 1098-95-3 10334 5 50 Nitrobenzene N.D. 1088-75-5 10334 4 50 2-Nitrophenol N.D. 10100-02-7 10334 50 100 4-Nitrophenol N.D. 1062-75-9 10334 20 50 N-Nitrosodimethylamine N.D. 10621-64-7 10334 4 50 N-Nitroso-di-n-propylamine N.D. 1086-30-6 10334 3 50 N-Nitrosodiphenylamine N.D. 10117-84-0 10334 5 50 Di-n-octylphthalate N.D. 1087-86-5 10334 30 150 Pentachlorophenol 37 J 1085-01-8 10334 2 50 Phenanthrene N.D. 10108-95-2 10334 4 50 Phenol 8 J 10129-00-0 10334 2 50 Pyrene


of 4



Collected: 05/08/2012 11:15 by MS

Submitted: 05/09/2012 09:25


Reported: 05/18/2012 17:58





CAT No.

ug/l ug/lug/lGC/MS Semivolatiles EPA 625N.D. 10120-82-1 10334 3 50 1,2,4-Trichlorobenzene N.D. 1088-06-2 10334 7 50 2,4,6-Trichlorophenol



ug/l ug/lug/lWet Chemistry EPA 300.0 998,000 25016887-00-600224 50,000 100,000 Chloride

ug/l ug/lug/lEPA 420.4 25 J 1n.a. 00434 15 40 Phenols (water)

ug/l ug/lug/lEPA 1664A 5,100 1n.a. 08079 1,400 5,000 HEM (oil & grease)

N T U N T UN T UEPA 180.1 (1993) 119 4n.a. 00279 0.36 1.2 Turbidity







of 4



Collected: 05/08/2012 11:15 by MS

Submitted: 05/09/2012 09:25


Reported: 05/18/2012 17:58


RCS-B




Analyst






05716


Caulfeild-James05/15/2012 08:49 12135113101B1EPA 420.4 Phenols (water) 00434

1Nancy J Shoop05/14/2012 10:10 12135113101B1EPA 420.4 Phenol Distillation (water) 00491



of 1


Sample Description: Outfall 001 Grab Water S2010L4647 Greenpoint, NY XOM Brooklyn Terminal Project Name: Greenpoint Project

Collected: 05/08/2012 11:35 by MS

Submitted: 05/09/2012 09:25


Reported: 05/18/2012 17:58


O-001 As Received Limit of Quantitation



CAT No.

ug/l ug/lug/lWet Chemistry EPA 1664A 1,800 J 1n.a. 08079 1,400 5,000 HEM (oil & grease)








Analyst


1Yolunder Y Bunch05/17/2012 08:12 12138807901A1EPA 1664A HEM (oil & grease) 08079 1Luz M Groff05/09/2012 20:45 12130027902B1EPA 180.1 (1993)Turbidity 00279 1Hannah M Royer05/11/2012 10:06 12132020602B1SM20 2540 D Total Suspended Solids 00206 1Luz M Groff05/09/2012 22:30 12130020003A1SM20 4500 H/B pH 00200


of 1


Sample Description: Receiving Water-001 Grab Water S2010L4647 Greenpoint, NY XOM Brooklyn Terminal Project Name: Greenpoint Project

Collected: 05/08/2012 11:30 by MS

Submitted: 05/09/2012 09:25


Reported: 05/18/2012 17:58


RE001 As Received Limit of Quantitation



CAT No.

N T U N T UN T UWet Chemistry EPA 180.1 (1993) 1.9 1n.a. 00279 0.090 0.30 Turbidity







Analyst


1Luz M Groff05/09/2012 20:45 12130027902B1EPA 180.1 (1993)Turbidity 00279 1Hannah M Royer05/11/2012 10:06 12132020602B1SM20 2540 D Total Suspended Solids 00206 1Luz M Groff05/09/2012 22:30 12130020003A1SM20 4500 H/B pH 00200


of 2


Sample Description: QAQC_TB Water S2010L4647 Greenpoint, NY XOM Brooklyn Terminal Project Name: Greenpoint Project

Collected: 05/08/2012

Submitted: 05/09/2012 09:25


Reported: 05/18/2012 17:58


RE01T As Received Limit of Quantitation



CAT No.

ug/l ug/lug/lGC/MS Volatiles EPA 624N.D. 1107-02-8 10371 10 50 Acrolein N.D. 1107-13-1 10371 10 50 Acrylonitrile N.D. 171-43-2 10371 0.9 5 Benzene N.D. 175-27-4 10371 0.7 5 Bromodichloromethane N.D. 175-25-2 10371 0.8 5 Bromoform N.D. 174-83-9 10371 2 5 Bromomethane N.D. 156-23-5 10371 1 5 Carbon Tetrachloride N.D. 1108-90-7 10371 0.8 5 Chlorobenzene N.D. 175-00-3 10371 2 5 Chloroethane N.D. 1110-75-8 10371 2 10 2-Chloroethyl Vinyl Ether



ug/l ug/lug/lGC/MS Volatiles SW-846 8260B N.D. 11634-04-4 10943 0.5 1 Methyl Tertiary Butyl Ether



of 2




Submitted: 05/09/2012 09:25


Reported: 05/18/2012 17:58


RE01T




Analyst


1Jason M Long05/15/2012 20:33 E121361AA1EPA 624 VOCs by 624 10371 1Kevin A Sposito05/11/2012 19:26 F121324AA1SW-846 8260B MTBE Only 8260B Water 10943 1Kevin A Sposito05/11/2012 19:26 F121324AA1SW-846 5030B GC/MS VOA Water Prep 01163


of 7

Quality Control Summary Client Name: ExxonMobil Refining & Supply Group Number: 1307584 Reported: 05/18/12 at 05:58 PM

*- Outside of specification **-This limit was used in the evaluation of the final result for the blank (1) The result for one or both determinations was less than five times the LOQ. (2) The unspiked result was more than four times the spike added.

Matrix QC may not be reported if insufficient sample or site-specific QC samples were not submitted. In these situations, to demonstrate precision and accuracy at a batch level, a LCS/LCSD was performed, unless otherwise specified in the method. All Inorganic Initial Calibration and Continuing Calibration Blanks met acceptable method criteria unless otherwise noted on the Analysis Report.

Laboratory Compliance Quality Control

Blank Blank Blank Report LCS LCSD LCS/LCSD Analysis Name Result MDL** LOQ Units %REC %REC Limits RPD RPD Max Batch number: E121361AA Sample number(s): 6644911-6644912,6644914,6644917 Acrolein N.D. 10. 50 ug/l 92 53-126 Acrylonitrile N.D. 10. 50 ug/l 88 61-120 Benzene N.D. 0.9 5 ug/l 97 80-121 Bromodichloromethane N.D. 0.7 5 ug/l 91 76-123 Bromoform N.D. 0.8 5 ug/l 85 65-136 Bromomethane N.D. 2. 5 ug/l 92 55-122 Carbon Tetrachloride N.D. 1. 5 ug/l 91 72-128 Chlorobenzene N.D. 0.8 5 ug/l 90 79-120 Chloroethane N.D. 2. 5 ug/l 90 54-121 2-Chloroethyl Vinyl Ether N.D. 2. 10 ug/l 90 47-128 Chloroform N.D. 1. 5 ug/l 97 79-122 Chloromethane N.D. 2. 5 ug/l 92 63-135 Dibromochloromethane N.D. 1. 5 ug/l 88 74-121 1,2-Dichlorobenzene N.D. 1. 5 ug/l 93 78-125 1,3-Dichlorobenzene N.D. 1. 5 ug/l 90 78-124 1,4-Dichlorobenzene N.D. 1. 5 ug/l 92 78-124 Dichlorodifluoromethane N.D. 2. 5 ug/l 74 48-120 1,1-Dichloroethane N.D. 1. 5 ug/l 93 75-130 1,2-Dichloroethane N.D. 1. 5 ug/l 104 72-138 1,1-Dichloroethene N.D. 0.9 5 ug/l 94 71-136 cis-1,2-Dichloroethene N.D. 1. 5 ug/l 97 73-130 trans-1,2-Dichloroethene N.D. 1. 5 ug/l 91 73-131 1,2-Dichloropropane N.D. 1. 5 ug/l 94 78-121 cis-1,3-Dichloropropene N.D. 1. 5 ug/l 88 79-120 trans-1,3-Dichloropropene N.D. 0.6 5 ug/l 87 74-120 Ethylbenzene N.D. 0.8 5 ug/l 90 80-120 Methylene Chloride N.D. 2. 5 ug/l 96 71-132 1,1,2,2-Tetrachloroethane N.D. 1. 5 ug/l 94 75-121 Tetrachloroethene N.D. 1. 5 ug/l 89 77-127 Toluene N.D. 0.8 5 ug/l 90 80-120 1,1,1-Trichloroethane N.D. 1. 5 ug/l 92 74-127 1,1,2-Trichloroethane N.D. 1. 5 ug/l 97 80-120 Trichloroethene N.D. 1. 5 ug/l 94 80-120 Trichlorofluoromethane N.D. 2. 5 ug/l 97 55-136 Vinyl Chloride N.D. 2. 5 ug/l 88 56-121 Xylene (total) N.D. 0.9 5 ug/l 91 80-120

of 7



Blank Blank Blank Report LCS LCSD LCS/LCSD Analysis Name Result MDL** LOQ Units %REC %REC Limits RPD RPD Max Batch number: F121324AA Sample number(s): 6644911-6644912,6644914,6644917 Methyl Tertiary Butyl Ether N.D. 0.5 1 ug/l 80 68-121 Batch number: 12130WAJ625 Sample number(s): 6644911-6644912,6644914 Acenaphthene N.D. 0.3 5 ug/l 102 75-117 Acenaphthylene N.D. 0.3 5 ug/l 103 75-122 Anthracene N.D. 0.2 5 ug/l 103 75-116 Benzidine N.D. 20. 60 ug/l 34 16-104 Benzo(a)anthracene N.D. 0.2 5 ug/l 104 76-117 Benzo(a)pyrene N.D. 0.3 5 ug/l 105 69-143 Benzo(b)fluoranthene N.D. 0.3 5 ug/l 94 64-145 Benzo(g,h,i)perylene N.D. 0.2 5 ug/l 108 66-145 Benzo(k)fluoranthene N.D. 0.3 5 ug/l 115 66-145 4-Bromophenyl-phenylether N.D. 0.3 5 ug/l 106 80-112 Butylbenzylphthalate N.D. 0.8 5 ug/l 106 80-125 Di-n-butylphthalate N.D. 0.5 5 ug/l 105 76-120 4-Chloro-3-methylphenol N.D. 0.3 5 ug/l 109 75-113 4-Chloroaniline N.D. 0.3 5 ug/l 67 10-124 bis(2-Chloroethoxy)methane N.D. 0.5 5 ug/l 105 69-128 bis(2-Chloroethyl)ether N.D. 0.4 5 ug/l 102 72-114 bis(2-Chloroisopropyl)ether N.D. 0.3 5 ug/l 100 87-134 2-Chloronaphthalene N.D. 0.2 5 ug/l 93 57-112 2-Chlorophenol N.D. 0.3 5 ug/l 100 78-118 4-Chlorophenyl-phenylether N.D. 0.3 5 ug/l 103 76-115 Chrysene N.D. 0.2 5 ug/l 100 81-118 Dibenz(a,h)anthracene N.D. 0.4 5 ug/l 108 68-144 1,2-Dichlorobenzene N.D. 0.3 5 ug/l 94 73-111 1,3-Dichlorobenzene N.D. 0.3 5 ug/l 91 67-110 1,4-Dichlorobenzene N.D. 0.3 5 ug/l 92 68-111 3,3'-Dichlorobenzidine N.D. 0.8 5 ug/l 76 33-124 2,4-Dichlorophenol N.D. 0.3 5 ug/l 108 72-127 Diethylphthalate N.D. 0.3 5 ug/l 105 74-120 2,4-Dimethylphenol N.D. 0.3 5 ug/l 105 70-123 Dimethylphthalate N.D. 1. 5 ug/l 102 30-112 4,6-Dinitro-2-methylphenol N.D. 4. 15 ug/l 105 65-120 2,4-Dinitrophenol N.D. 10. 30 ug/l 103 64-140 2,4-Dinitrotoluene N.D. 0.4 5 ug/l 108 74-121 2,6-Dinitrotoluene N.D. 0.3 5 ug/l 103 80-115 1,2-Diphenylhydrazine N.D. 0.2 5 ug/l 106 75-114 bis(2-Ethylhexyl)phthalate N.D. 1. 5 ug/l 105 74-118 Fluoranthene N.D. 0.3 5 ug/l 106 86-119 Fluorene N.D. 0.3 5 ug/l 105 74-117 Hexachlorobenzene N.D. 1. 5 ug/l 104 75-114 Hexachlorobutadiene N.D. 0.8 5 ug/l 97 58-116 Hexachlorocyclopentadiene N.D. 2. 15 ug/l 80 38-133 Hexachloroethane N.D. 0.4 5 ug/l 89 61-113 Indeno(1,2,3-cd)pyrene N.D. 0.3 5 ug/l 105 67-143 Isophorone N.D. 0.3 5 ug/l 103 75-123 Naphthalene N.D. 0.2 5 ug/l 99 73-118 Nitrobenzene N.D. 0.5 5 ug/l 106 74-121

of 7



Blank Blank Blank Report LCS LCSD LCS/LCSD Analysis Name Result MDL** LOQ Units %REC %REC Limits RPD RPD Max 2-Nitrophenol N.D. 0.4 5 ug/l 107 77-120 4-Nitrophenol N.D. 5. 10 ug/l 50 27-80 N-Nitroso-di-n-propylamine N.D. 0.4 5 ug/l 98 68-114 N-Nitrosodimethylamine N.D. 2. 5 ug/l 63 44-81 N-Nitrosodiphenylamine N.D. 0.3 5 ug/l 105 84-135 Di-n-octylphthalate N.D. 0.5 5 ug/l 110 65-155 Pentachlorophenol N.D. 3. 15 ug/l 107 55-137 Phenanthrene N.D. 0.2 5 ug/l 103 77-113 Phenol N.D. 0.4 5 ug/l 57 26-71 Pyrene N.D. 0.2 5 ug/l 109 76-115 1,2,4-Trichlorobenzene N.D. 0.3 5 ug/l 97 70-119 2,4,6-Trichlorophenol N.D. 0.7 5 ug/l 104 83-120 Batch number: 121305716007 Sample number(s): 6644911-6644912,6644914 Calcium N.D. 70.5 200 ug/l 98 90-110 Copper N.D. 0.94 10.0 ug/l 100 90-110 Iron N.D. 14.1 200 ug/l 96 90-110 Manganese N.D. 0.44 5.0 ug/l 99 85-115 Batch number: 121315714001 Sample number(s): 6644911-6644912,6644914 Mercury N.D. 0.026 0.20 ug/l 98 85-115 Batch number: 12135113101A Sample number(s): 6644911-6644912 Phenols (water) N.D. 15. 40 ug/l 96 90-110 Batch number: 12135113101B Sample number(s): 6644914 Phenols (water) N.D. 15. 40 ug/l 96 90-110 Batch number: 12136987121B Sample number(s): 6644911-6644914 Chloride N.D. 200. 400 ug/l 101 90-110 Batch number: 12130020003A Sample number(s): 6644911-6644916 pH 100 99-101 Batch number: 12130021501A Sample number(s): 6644911-6644912,6644914 Settleable Solids N.D. 0.10 0.10 ml/l/hr Batch number: 12130027902B Sample number(s): 6644911-6644916 Turbidity 0.11 J 0.090 0.30 N T U 93 90-110 Batch number: 12132020602B Sample number(s): 6644911-6644916 Total Suspended Solids N.D. 3,000. 12,000 ug/l 89 91 79-107 1 10 Batch number: 12138807901A Sample number(s): 6644911-6644915 HEM (oil & grease) N.D. 1,400. 5,000 ug/l 93 84 78-114 10 16

Sample Matrix Quality Control

of 7



Unspiked (UNSPK) = the sample used in conjunction with the matrix spike Background (BKG) = the sample used in conjunction with the duplicate MS MSD MS/MSD RPD BKG DUP DUP Dup RPD Analysis Name %REC %REC Limits RPD MAX Conc Conc RPD Max___ Batch number: E121361AA Sample number(s): 6644911-6644912,6644914,6644917 UNSPK: P644875 Acrolein 99 98 40-128 1 30 Acrylonitrile 101 99 58-124 2 30 Benzene 111 113 83-132 2 30 Bromodichloromethane 96 100 78-128 4 30 Bromoform 91 90 59-129 1 30 Bromomethane 94 95 52-134 1 30 Carbon Tetrachloride 105 108 76-147 4 30 Chlorobenzene 102 102 82-121 1 30 Chloroethane 94 98 50-140 4 30 2-Chloroethyl Vinyl Ether 0* 0* 10-172 0 30 Chloroform 106 106 82-132 0 30 Chloromethane 94 97 50-140 3 30 Dibromochloromethane 96 95 72-128 0 30 1,2-Dichlorobenzene 101 101 79-126 0 30 1,3-Dichlorobenzene 103 101 79-126 1 30 1,4-Dichlorobenzene 101 102 79-126 0 30 Dichlorodifluoromethane 88 88 42-132 0 30 1,1-Dichloroethane 109 110 79-141 1 30 1,2-Dichloroethane 111 114 65-146 2 30 1,1-Dichloroethene 112 112 75-153 1 30 cis-1,2-Dichloroethene 107 109 81-134 2 30 trans-1,2-Dichloroethene 109 108 74-144 1 30 1,2-Dichloropropane 101 104 77-130 3 30 cis-1,3-Dichloropropene 95 96 74-113 2 30 trans-1,3-Dichloropropene 95 95 69-116 0 30 Ethylbenzene 105 105 82-124 1 30 Methylene Chloride 104 105 65-148 1 30 1,1,2,2-Tetrachloroethane 102 102 73-121 0 30 Tetrachloroethene 106 107 78-136 1 30 Toluene 105 107 84-123 2 30 1,1,1-Trichloroethane 107 109 83-137 2 30 1,1,2-Trichloroethane 104 104 85-121 0 30 Trichloroethene 110 114 86-131 4 30 Trichlorofluoromethane 108 111 62-152 2 30 Vinyl Chloride 96 98 60-137 3 30 Xylene (total) 105 106 79-130 1 30 Batch number: F121324AA Sample number(s): 6644911-6644912,6644914,6644917 UNSPK: P645368 Methyl Tertiary Butyl Ether 79 79 72-126 0 30 Batch number: 12130WAJ625 Sample number(s): 6644911-6644912,6644914 UNSPK: P644993 Acenaphthene 99 96 74-112 3 30 Acenaphthylene 101 98 75-119 4 30 Anthracene 102 99 89-115 3 30 Benzidine 29 31 20-98 11 30

of 7




Unspiked (UNSPK) = the sample used in conjunction with the matrix spike Background (BKG) = the sample used in conjunction with the duplicate MS MSD MS/MSD RPD BKG DUP DUP Dup RPD Analysis Name %REC %REC Limits RPD MAX Conc Conc RPD Max___ Benzo(a)anthracene 103 101 78-126 4 30 Benzo(a)pyrene 103 99 70-121 2 30 Benzo(b)fluoranthene 94 99 61-146 11 30 Benzo(g,h,i)perylene 108 103 74-129 1 30 Benzo(k)fluoranthene 115 96 61-145 11 30 4-Bromophenyl-phenylether 104 102 74-109 5 30 Butylbenzylphthalate 110 107 74-117 3 30 Di-n-butylphthalate 104 101 68-115 3 30 4-Chloro-3-methylphenol 37* 41* 54-126 16 30 4-Chloroaniline 68 64 10-110 0 30 bis(2-Chloroethoxy)methane 109 104 73-130 2 30 bis(2-Chloroethyl)ether 99 97 76-107 4 30 bis(2-Chloroisopropyl)ether 100 98 85-114 4 30 2-Chloronaphthalene 88 86 53-117 4 30 2-Chlorophenol 3* 4* 81-99 24 30 4-Chlorophenyl-phenylether 99 96 87-116 3 30 Chrysene 100 96 78-125 2 30 Dibenz(a,h)anthracene 111 103 79-125 2 30 1,2-Dichlorobenzene 91 92 81-113 7 30 1,3-Dichlorobenzene 91 92 80-111 7 30 1,4-Dichlorobenzene 91 92 80-113 6 30 3,3'-Dichlorobenzidine 72 73 32-116 8 30 2,4-Dichlorophenol 4* 5* 77-98 15 30 Diethylphthalate 101 97 69-110 2 30 2,4-Dimethylphenol 99 97 71-102 4 30 Dimethylphthalate 98 96 37-142 4 30 4,6-Dinitro-2-methylphenol 109 106 57-139 3 30 2,4-Dinitrophenol 108* 102 10-107 0 30 2,4-Dinitrotoluene 102 99 79-107 4 30 2,6-Dinitrotoluene 101 98 83-107 3 30 1,2-Diphenylhydrazine 107 105 78-117 4 30 bis(2-Ethylhexyl)phthalate 109 105 86-128 2 30 Fluoranthene 101 100 69-119 5 30 Fluorene 101 98 74-109 3 30 Hexachlorobenzene 105 102 68-110 3 30 Hexachlorobutadiene 101 99 62-125 4 30 Hexachlorocyclopentadiene 97 99 36-146 8 30 Hexachloroethane 91 92 65-110 7 30 Indeno(1,2,3-cd)pyrene 107 101 79-124 0 30 Isophorone 105 101 84-107 2 30 Naphthalene 102 99 69-106 3 30 Nitrobenzene 109 105 75-109 3 30 2-Nitrophenol 20* 16* 66-120 16 30 4-Nitrophenol 33 30 10-88 3 30 N-Nitroso-di-n-propylamine 96 94 74-110 4 30 N-Nitrosodimethylamine 68 68 38-98 6 30

of 7




Unspiked (UNSPK) = the sample used in conjunction with the matrix spike Background (BKG) = the sample used in conjunction with the duplicate MS MSD MS/MSD RPD BKG DUP DUP Dup RPD Analysis Name %REC %REC Limits RPD MAX Conc Conc RPD Max___ N-Nitrosodiphenylamine 105 104 84-142 6 30 Di-n-octylphthalate 117 112 67-155 2 30 Pentachlorophenol 17* 18* 21-110 11 30 Phenanthrene 101 99 88-116 4 30 Phenol 6* 12 10-80 66* 30 Pyrene 111 108 82-113 4 30 1,2,4-Trichlorobenzene 102 99 73-113 3 30 2,4,6-Trichlorophenol 5* 4* 73-110 6 30 Batch number: 121305716007 Sample number(s): 6644911-6644912,6644914 UNSPK: P645748 BKG: P645748 Calcium 856 (2) 81-118 4,770,000 4,630,000 3 20 Copper 104 86-122 30.9 J 29.9 J 3 (1) 20 Iron 90 70-130 225 223 1 (1) 20 Manganese 96 70-130 125 123 1 20 Batch number: 121315714001 Sample number(s): 6644911-6644912,6644914 UNSPK: P644875 BKG: P644875 Mercury 96 80-120 N.D. N.D. 0 (1) 20 Batch number: 12135113101A Sample number(s): 6644911-6644912 UNSPK: 6644912 Phenols (water) 94 101 90-110 7* 6 Batch number: 12135113101B Sample number(s): 6644914 UNSPK: 6644914 Phenols (water) 94 91 90-110 4 6 Batch number: 12136987121B Sample number(s): 6644911-6644914 UNSPK: P643361 BKG: P643361 Chloride 113* 90-110 98,500 101,000 2 (1) 20 Batch number: 12130020003A Sample number(s): 6644911-6644916 BKG: P644906 pH 7.3 7.3 0 3 Batch number: 12130027902B Sample number(s): 6644911-6644916 BKG: P644902 Turbidity 8.7 8.6 1 3 Batch number: 12132020602B Sample number(s): 6644911-6644916 BKG: P645901 Total Suspended Solids N.D. N.D. 0 (1) 20

Surrogate Quality Control

Surrogate recoveries which are outside of the QC window are confirmed unless attributed to dilution or otherwise noted on the Analysis Report. Analysis Name: VOCs by 624 Batch number: E121361AA

of 7




1,2-Dichloroethane-d4 Fluorobenzene 4-Bromofluorobenzene ________________________________________________________________________________________________________________ 6644911 101 103 100 6644912 104 102 101 6644914 105 103 97 6644917 103 101 98 Blank 104 103 93 LCS 105 104 97 MS 102 103 101 MSD 102 104 101 ________________________________________________________________________________________________________________ Limits: 76-114 80-120 86-115 Analysis Name: BTEX + MTBE 8260B Water Batch number: F121324AA Dibromofluoromethane 1,2-Dichloroethane-d4 Toluene-d8 4-Bromofluorobenzene ________________________________________________________________________________________________________________ 6644911 92 97 99 97 6644912 93 98 98 95 6644914 90 98 99 96 6644917 93 101 98 91 Blank 94 102 98 89 LCS 92 99 97 96 MS 92 102 98 97 MSD 93 103 98 97 ________________________________________________________________________________________________________________ Limits: 80-116 77-113 80-113 78-113 Analysis Name: Method 625 Batch number: 12130WAJ625 Nitrobenzene-d5 2-Fluorobiphenyl Terphenyl-d14 Phenol-d6 2-Fluorophenol 2,4,6-Tribromophenol ________________________________________________________________________________________________________________ 6644911 96 99 89 58 63 99 6644912 101 98 87 57 58 88 6644914 109 113 112 64 71 104 Blank 101 100 95 46 65 99 LCS 102 100 99 51 70 105 MS 106 99 102 7* 4* 4* MSD 105 100 103 8* 4* 4* ________________________________________________________________________________________________________________ Limits: 56-120 62-121 56-119 10-72 10-114 36-140

Case Narrative

Project Name: Greenpoint ProjectLLI Group #: 1307584

General Comments:

See the Laboratory Sample Analysis Record section of the Analysis Report for the method references.

All QC met criteria unless otherwise noted in an Analysis Specific Comment below. Refer to the QC Summary for specific values and acceptance criteria.

Project specific QC samples are not included in this data set

Matrix QC may not be reported if site-specific QC samples were not submitted. In these situations, to demonstrate precision and accuracy at a batch level, a LCS/LCSD was performed, unless otherwise specified in the method.

Surrogate recoveries (if applicable) which are outside of the QC window are confirmed unless attributed to a dilution or otherwise noted in an Analysis Specific Comment below.

The samples were received at the appropriate temperature and in accordance with the chain of custody unless otherwise noted.

Analysis Specific Comments:

EPA 624, GC/MS VolatilesBatch #: E121361AA (Sample number(s): 6644911-6644912, 6644914, 6644917 UNSPK: P644875)

The recovery(ies) for the following analyte(s) in the MS and/or MSD was outside the acceptance window: 2-Chloroethyl Vinyl Ether

EPA 625, GC/MS SemivolatilesBatch #: 12130WAJ625 (Sample number(s): 6644911-6644912, 6644914 UNSPK: P644993)

The recovery(ies) for the following analyte(s) in the MS and/or MSD was outside the acceptance window: 2-Chlorophenol, 2,4-Dichlorophenol, 2-Nitrophenol, 4-Chloro-3-methylphenol, Pentachlorophenol, 2,4,6-Trichlorophenol, 2,4-Dinitrophenol, Phenol

The relative percent difference(s) for the following analyte(s) in the MS/MSD were outside outside acceptance windows: Phenol

The recovery(ies) for one or more surrogates were outside of the QC window for sample(s) MS, MSD

EPA 300.0, Wet ChemistryBatch #: 12136987121B (Sample number(s): 6644911-6644914 UNSPK: P643361 BKG: P643361)

The recovery(ies) for the following analyte(s) in the MS was outside the acceptance window: Chloride

v 1.8.8 5/18/2012 6:02:19PM

EPA 420.4, Wet ChemistryBatch #: 12135113101A (Sample number(s): 6644911-6644912 UNSPK: 6644912)

The relative percent difference(s) for the following analyte(s) in the MS/MSD were outside outside acceptance windows: Phenols (water)

SM20 2540 F, Wet Chemistry

Sample #s: 6644911, 6644912, 6644914Sufficient sample volume was not available to perform a duplicate for thisanalysis.

v 1.8.8 5/18/2012 6:02:19PM

Explanation of Symbols and Abbreviations

The following defines common symbols and abbreviations used in reporting technical data: RL Reporting Limit BMQL Below Minimum Quantitation Level N.D. none detected MPN Most Probable Number TNTC Too Numerous To Count CP Units cobalt-chloroplatinate units IU International Units NTU nephelometric turbidity units umhos/cm micromhos/cm ng nanogram(s) C degrees Celsius F degrees Fahrenheit meq milliequivalents lb. pound(s) g gram(s) kg kilogram(s) µg microgram(s) mg milligram(s) mL milliliter(s) L liter(s) m3 cubic meter(s) µL microliter(s) pg/L picogram/liter

< less than - The number following the sign is the limit of quantitation, the smallest amount of analyte which can be reliably determined using this specific test.

> greater than

ppm parts per million - One ppm is equivalent to one milligram per kilogram (mg/kg), or one gram per million grams. For aqueous liquids, ppm is usually taken to be equivalent to milligrams per liter (mg/l), because one liter of water has a weight very close to a kilogram. For gases or vapors, one ppm is equivalent to one microliter of gas per liter of gas.

ppb parts per billion

Dry weight Results printed under this heading have been adjusted for moisture content. This increases the analyte weight basis concentration to approximate the value present in a similar sample without moisture. All other results are reported

on an as-received basis. Data Qualifiers: C – result confirmed by reanalysis.

J - estimated value – The result is ≥ the Method Detection Limit (MDL) and < the Limit of Quantitation (LOQ).

U.S. EPA CLP Data Qualifiers:

Organic Qualifiers Inorganic Qualifiers A TIC is a possible aldol-condensation product B Value is <CRDL, but ≥IDL B Analyte was also detected in the blank E Estimated due to interference C Pesticide result confirmed by GC/MS M Duplicate injection precision not met D Compound quantitated on a diluted sample N Spike sample not within control limits E Concentration exceeds the calibration range of S Method of standard additions (MSA) used the instrument for calculation N Presumptive evidence of a compound (TICs only) U Compound was not detected P Concentration difference between primary and W Post digestion spike out of control limits confirmation columns >25% * Duplicate analysis not within control limits U Compound was not detected + Correlation coefficient for MSA <0.995 X,Y,Z Defined in case narrative

Analytical test results meet all requirements of NELAC unless otherwise noted under the individual analysis.

Measurement uncertainty values, as applicable, are available upon request.

Tests results relate only to the sample tested. Clients should be aware that a critical step in a chemical or microbiological analysis is the collection of the sample. Unless the sample analyzed is truly representative of the bulk of material involved, the test results will be meaningless. If you have questions regarding the proper techniques of collecting samples, please contact us. We cannot be held responsible for sample integrity, however, unless sampling has been performed by a member of our staff. This report shall not be reproduced except in full, without the written approval of the laboratory.

Times are local to the area of activity. Parameters listed in the 40 CFR part 136 Table II as “analyze immediately” are not performed within 15 minutes.

WARRANTY AND LIMITS OF LIABILITY - In accepting analytical work, we warrant the accuracy of test results for the sample as submitted. THE FOREGOING EXPRESS WARRANTY IS EXCLUSIVE AND IS GIVEN IN LIEU OF ALL OTHER WARRANTIES, EXPRESSED OR IMPLIED. WE DISCLAIM ANY OTHER WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING A WARRANTY OF FITNESS FOR PARTICULAR PURPOSE AND WARRANTY OF MERCHANTABILITY. IN NO EVENT SHALL LANCASTER LABORATORIES BE LIABLE FOR INDIRECT, SPECIAL, CONSEQUENTIAL, OR INCIDENTAL DAMAGES INCLUDING, BUT NOT LIMITED TO, DAMAGES FOR LOSS OF PROFIT OR GOODWILL REGARDLESS OF (A) THE NEGLIGENCE (EITHER SOLE OR CONCURRENT) OF LANCASTER LABORATORIES AND (B) WHETHER LANCASTER LABORATORIES HAS BEEN INFORMED OF THE POSSIBILITY OF SUCH DAMAGES. We accept no legal responsibility for the purposes for which the client uses the test results. No purchase order or other order for work shall be accepted by Lancaster Laboratories which includes any conditions that vary from the Standard Terms and Conditions, and Lancaster hereby objects to any conflicting terms contained in any acceptance or order submitted by client.

3768.08

ANALYTICAL RESULTS

Prepared by:



Prepared for:


Brooklyn NY 11222

May 18, 2012




Client Sample Description Lancaster Labs (LLI) # OSS-Influent Grab Water 6644874 OSS-Effluent Grab Water 6644875 Receiving Water-002 Grab Water 6644876 QAQC_TB Water 6644877 The specific methodologies used in obtaining the enclosed analytical results are indicated on the Laboratory Sample Analysis Record. ELECTRONIC COPY TO



(717) 556-7250

of 4


Sample Description: OSS-Influent Grab Water S2010L4647 Greenpoint, NY XOM Brooklyn Terminal Project Name: Greenpoint Project

Collected: 05/08/2012 10:00 by BC

Submitted: 05/09/2012 09:25


Reported: 05/18/2012 17:56


OSS-I As Received Limit of Quantitation



CAT No.

ug/l ug/lug/lGC/MS Volatiles EPA 624N.D. 2107-02-8 10371 20 100 Acrolein N.D. 2107-13-1 10371 20 100 Acrylonitrile 710 2071-43-2 10371 18 100 Benzene N.D. 275-27-4 10371 1 10 Bromodichloromethane N.D. 275-25-2 10371 2 10 Bromoform N.D. 274-83-9 10371 4 10 Bromomethane N.D. 256-23-5 10371 2 10 Carbon Tetrachloride N.D. 2108-90-7 10371 2 10 Chlorobenzene 38 275-00-3 10371 4 10 Chloroethane N.D. 2110-75-8 10371 4 20 2-Chloroethyl Vinyl Ether


N.D. 267-66-3 10371 2 10 Chloroform N.D. 274-87-3 10371 4 10 Chloromethane N.D. 2124-48-1 10371 2 10 Dibromochloromethane N.D. 295-50-1 10371 2 10 1,2-Dichlorobenzene N.D. 2541-73-1 10371 2 10 1,3-Dichlorobenzene N.D. 2106-46-7 10371 2 10 1,4-Dichlorobenzene N.D. 275-71-8 10371 4 10 Dichlorodifluoromethane 3 J 275-34-3 10371 2 10 1,1-Dichloroethane N.D. 2107-06-2 10371 2 10 1,2-Dichloroethane 2 J 275-35-4 10371 2 10 1,1-Dichloroethene 320 2156-59-2 10371 2 10 cis-1,2-Dichloroethene 17 2156-60-5 10371 2 10 trans-1,2-Dichloroethene N.D. 278-87-5 10371 2 10 1,2-Dichloropropane N.D. 210061-01-510371 2 10 cis-1,3-Dichloropropene N.D. 210061-02-610371 1 10 trans-1,3-Dichloropropene 46 2100-41-4 10371 2 10 Ethylbenzene N.D. 275-09-2 10371 4 10 Methylene Chloride N.D. 279-34-5 10371 2 10 1,1,2,2-Tetrachloroethane 270 2127-18-4 10371 2 10 Tetrachloroethene 64 2108-88-3 10371 2 10 Toluene N.D. 271-55-6 10371 2 10 1,1,1-Trichloroethane N.D. 279-00-5 10371 2 10 1,1,2-Trichloroethane 360 279-01-6 10371 2 10 Trichloroethene N.D. 275-69-4 10371 4 10 Trichlorofluoromethane 29 275-01-4 10371 4 10 Vinyl Chloride 210 21330-20-7 10371 2 10 Xylene (total)


ug/l ug/lug/lGC/MS Semivolatiles EPA 6252 J 183-32-9 10334 0.3 5 Acenaphthene N.D. 1208-96-8 10334 0.3 5 Acenaphthylene N.D. 1120-12-7 10334 0.2 5 Anthracene N.D. 192-87-5 10334 19 57 Benzidine N.D. 156-55-3 10334 0.2 5 Benzo(a)anthracene N.D. 150-32-8 10334 0.3 5 Benzo(a)pyrene


of 4



Collected: 05/08/2012 10:00 by BC

Submitted: 05/09/2012 09:25


Reported: 05/18/2012 17:56





CAT No.

ug/l ug/lug/lGC/MS Semivolatiles EPA 625N.D. 1205-99-2 10334 0.3 5 Benzo(b)fluoranthene N.D. 1191-24-2 10334 0.2 5 Benzo(g,h,i)perylene N.D. 1207-08-9 10334 0.3 5 Benzo(k)fluoranthene N.D. 1101-55-3 10334 0.3 5 4-Bromophenyl-phenylether N.D. 185-68-7 10334 0.8 5 Butylbenzylphthalate N.D. 184-74-2 10334 0.5 5 Di-n-butylphthalate N.D. 159-50-7 10334 0.3 5 4-Chloro-3-methylphenol N.D. 1106-47-8 10334 0.3 5 4-Chloroaniline N.D. 1111-91-1 10334 0.5 5 bis(2-Chloroethoxy)methane N.D. 1111-44-4 10334 0.4 5 bis(2-Chloroethyl)ether N.D. 139638-32-910334 0.3 5 bis(2-Chloroisopropyl)ether 0.2 J 191-58-7 10334 0.2 5 2-Chloronaphthalene N.D. 195-57-8 10334 0.3 5 2-Chlorophenol N.D. 17005-72-3 10334 0.3 5 4-Chlorophenyl-phenylether N.D. 1218-01-9 10334 0.2 5 Chrysene N.D. 153-70-3 10334 0.4 5 Dibenz(a,h)anthracene N.D. 195-50-1 10334 0.3 5 1,2-Dichlorobenzene N.D. 1541-73-1 10334 0.3 5 1,3-Dichlorobenzene N.D. 1106-46-7 10334 0.3 5 1,4-Dichlorobenzene N.D. 191-94-1 10334 0.8 5 3,3'-Dichlorobenzidine N.D. 1120-83-2 10334 0.3 5 2,4-Dichlorophenol N.D. 184-66-2 10334 0.3 5 Diethylphthalate 0.8 J 1105-67-9 10334 0.3 5 2,4-Dimethylphenol N.D. 1131-11-3 10334 1 5 Dimethylphthalate N.D. 1534-52-1 10334 4 14 4,6-Dinitro-2-methylphenol N.D. 151-28-5 10334 10 29 2,4-Dinitrophenol N.D. 1121-14-2 10334 0.4 5 2,4-Dinitrotoluene N.D. 1606-20-2 10334 0.3 5 2,6-Dinitrotoluene N.D. 1122-66-7 10334 0.2 5 1,2-Diphenylhydrazine 1 J 1117-81-7 10334 1 5 bis(2-Ethylhexyl)phthalate N.D. 1206-44-0 10334 0.3 5 Fluoranthene 0.5 J 186-73-7 10334 0.3 5 Fluorene N.D. 1118-74-1 10334 1 5 Hexachlorobenzene N.D. 187-68-3 10334 0.8 5 Hexachlorobutadiene N.D. 177-47-4 10334 2 14 Hexachlorocyclopentadiene N.D. 167-72-1 10334 0.4 5 Hexachloroethane N.D. 1193-39-5 10334 0.3 5 Indeno(1,2,3-cd)pyrene N.D. 178-59-1 10334 0.3 5 Isophorone 23 191-20-3 10334 0.2 5 Naphthalene N.D. 198-95-3 10334 0.5 5 Nitrobenzene 0.5 J 188-75-5 10334 0.4 5 2-Nitrophenol N.D. 1100-02-7 10334 5 10 4-Nitrophenol N.D. 162-75-9 10334 2 5 N-Nitrosodimethylamine N.D. 1621-64-7 10334 0.4 5 N-Nitroso-di-n-propylamine N.D. 186-30-6 10334 0.3 5 N-Nitrosodiphenylamine N.D. 1117-84-0 10334 0.5 5 Di-n-octylphthalate N.D. 187-86-5 10334 3 14 Pentachlorophenol 0.5 J 185-01-8 10334 0.2 5 Phenanthrene 7 1108-95-2 10334 0.4 5 Phenol N.D. 1129-00-0 10334 0.2 5 Pyrene


of 4



Collected: 05/08/2012 10:00 by BC

Submitted: 05/09/2012 09:25


Reported: 05/18/2012 17:56





CAT No.


ug/l ug/lug/lMetals EPA 200.7 rev 4.4 199,000 17440-70-2 01750 70.5 200 Calcium 7.3 J 17440-50-8 07053 0.94 10.0 Copper 11,500 17439-89-6 01754 14.1 200 Iron 3,090 17439-96-5 07058 0.44 5.0 Manganese



ug/l ug/lug/lEPA 420.4 21 J 1n.a. 00434 15 40 Phenols (water)









of 4



Collected: 05/08/2012 10:00 by BC

Submitted: 05/09/2012 09:25


Reported: 05/18/2012 17:56


OSS-I




Analyst


2Jason M Long05/15/2012 16:37 E121361AA1EPA 624 VOCs by 624 10371 20Jason M Long05/15/2012 17:01 E121361AA1EPA 624 VOCs by 624 10371 1Kevin A Sposito05/11/2012 21:58 F121324AA1SW-846 8260B MTBE Only 8260B Water 10943 1Kevin A Sposito05/11/2012 21:58 F121324AA1SW-846 5030B GC/MS VOA Water Prep 01163 1Holly Berry05/14/2012 06:55 12130WAJ6251EPA 625 Method 625 10334 1Cynthia J




05716




1Yolunder Y Bunch05/17/2012 08:12 12138807901A1EPA 1664A HEM (oil & grease) 08079 4Luz M Groff05/09/2012 20:45 12130027902A1EPA 180.1 (1993)Turbidity 00279 1Hannah M Royer05/11/2012 10:06 12132020602A1SM20 2540 D Total Suspended Solids 00206 1Luz M Groff05/09/2012 15:15 12130021501A1SM20 2540 F Settleable Solids 00215 1Luz M Groff05/09/2012 21:45 12130020002A1SM20 4500 H/B pH 00200


of 4


Sample Description: OSS-Effluent Grab Water S2010L4647 Greenpoint, NY XOM Brooklyn Terminal Project Name: Greenpoint Project

Collected: 05/08/2012 09:30 by BC

Submitted: 05/09/2012 09:25


Reported: 05/18/2012 17:56


OSS-E As Received Limit of Quantitation



CAT No.



N.D. 167-66-3 10371 1 5 Chloroform N.D. 174-87-3 10371 2 5 Chloromethane N.D. 1124-48-1 10371 1 5 Dibromochloromethane N.D. 195-50-1 10371 1 5 1,2-Dichlorobenzene N.D. 1541-73-1 10371 1 5 1,3-Dichlorobenzene N.D. 1106-46-7 10371 1 5 1,4-Dichlorobenzene N.D. 175-71-8 10371 2 5 Dichlorodifluoromethane N.D. 175-34-3 10371 1 5 1,1-Dichloroethane N.D. 1107-06-2 10371 1 5 1,2-Dichloroethane N.D. 175-35-4 10371 0.9 5 1,1-Dichloroethene 2 J 1156-59-2 10371 1 5 cis-1,2-Dichloroethene N.D. 1156-60-5 10371 1 5 trans-1,2-Dichloroethene N.D. 178-87-5 10371 1 5 1,2-Dichloropropane N.D. 110061-01-510371 1 5 cis-1,3-Dichloropropene N.D. 110061-02-610371 0.6 5 trans-1,3-Dichloropropene N.D. 1100-41-4 10371 0.8 5 Ethylbenzene N.D. 175-09-2 10371 2 5 Methylene Chloride N.D. 179-34-5 10371 1 5 1,1,2,2-Tetrachloroethane N.D. 1127-18-4 10371 1 5 Tetrachloroethene N.D. 1108-88-3 10371 0.8 5 Toluene N.D. 171-55-6 10371 1 5 1,1,1-Trichloroethane N.D. 179-00-5 10371 1 5 1,1,2-Trichloroethane N.D. 179-01-6 10371 1 5 Trichloroethene N.D. 175-69-4 10371 2 5 Trichlorofluoromethane N.D. 175-01-4 10371 2 5 Vinyl Chloride N.D. 11330-20-7 10371 0.9 5 Xylene (total)


ug/l ug/lug/lGC/MS Semivolatiles EPA 625N.D. 183-32-9 10334 0.3 5 Acenaphthene N.D. 1208-96-8 10334 0.3 5 Acenaphthylene N.D. 1120-12-7 10334 0.2 5 Anthracene N.D. 192-87-5 10334 20 59 Benzidine N.D. 156-55-3 10334 0.2 5 Benzo(a)anthracene N.D. 150-32-8 10334 0.3 5 Benzo(a)pyrene


of 4



Collected: 05/08/2012 09:30 by BC

Submitted: 05/09/2012 09:25


Reported: 05/18/2012 17:56





CAT No.

ug/l ug/lug/lGC/MS Semivolatiles EPA 625N.D. 1205-99-2 10334 0.3 5 Benzo(b)fluoranthene N.D. 1191-24-2 10334 0.2 5 Benzo(g,h,i)perylene N.D. 1207-08-9 10334 0.3 5 Benzo(k)fluoranthene N.D. 1101-55-3 10334 0.3 5 4-Bromophenyl-phenylether N.D. 185-68-7 10334 0.8 5 Butylbenzylphthalate N.D. 184-74-2 10334 0.5 5 Di-n-butylphthalate N.D. 159-50-7 10334 0.3 5 4-Chloro-3-methylphenol N.D. 1106-47-8 10334 0.3 5 4-Chloroaniline N.D. 1111-91-1 10334 0.5 5 bis(2-Chloroethoxy)methane N.D. 1111-44-4 10334 0.4 5 bis(2-Chloroethyl)ether N.D. 139638-32-910334 0.3 5 bis(2-Chloroisopropyl)ether 0.2 J 191-58-7 10334 0.2 5 2-Chloronaphthalene N.D. 195-57-8 10334 0.3 5 2-Chlorophenol N.D. 17005-72-3 10334 0.3 5 4-Chlorophenyl-phenylether N.D. 1218-01-9 10334 0.2 5 Chrysene N.D. 153-70-3 10334 0.4 5 Dibenz(a,h)anthracene N.D. 195-50-1 10334 0.3 5 1,2-Dichlorobenzene N.D. 1541-73-1 10334 0.3 5 1,3-Dichlorobenzene N.D. 1106-46-7 10334 0.3 5 1,4-Dichlorobenzene N.D. 191-94-1 10334 0.8 5 3,3'-Dichlorobenzidine N.D. 1120-83-2 10334 0.3 5 2,4-Dichlorophenol N.D. 184-66-2 10334 0.3 5 Diethylphthalate 0.7 J 1105-67-9 10334 0.3 5 2,4-Dimethylphenol N.D. 1131-11-3 10334 1 5 Dimethylphthalate N.D. 1534-52-1 10334 4 15 4,6-Dinitro-2-methylphenol N.D. 151-28-5 10334 10 29 2,4-Dinitrophenol N.D. 1121-14-2 10334 0.4 5 2,4-Dinitrotoluene N.D. 1606-20-2 10334 0.3 5 2,6-Dinitrotoluene N.D. 1122-66-7 10334 0.2 5 1,2-Diphenylhydrazine N.D. 1117-81-7 10334 1 5 bis(2-Ethylhexyl)phthalate N.D. 1206-44-0 10334 0.3 5 Fluoranthene N.D. 186-73-7 10334 0.3 5 Fluorene N.D. 1118-74-1 10334 1 5 Hexachlorobenzene N.D. 187-68-3 10334 0.8 5 Hexachlorobutadiene N.D. 177-47-4 10334 2 15 Hexachlorocyclopentadiene N.D. 167-72-1 10334 0.4 5 Hexachloroethane N.D. 1193-39-5 10334 0.3 5 Indeno(1,2,3-cd)pyrene N.D. 178-59-1 10334 0.3 5 Isophorone N.D. 191-20-3 10334 0.2 5 Naphthalene N.D. 198-95-3 10334 0.5 5 Nitrobenzene N.D. 188-75-5 10334 0.4 5 2-Nitrophenol N.D. 1100-02-7 10334 5 10 4-Nitrophenol N.D. 162-75-9 10334 2 5 N-Nitrosodimethylamine N.D. 1621-64-7 10334 0.4 5 N-Nitroso-di-n-propylamine N.D. 186-30-6 10334 0.3 5 N-Nitrosodiphenylamine N.D. 1117-84-0 10334 0.5 5 Di-n-octylphthalate N.D. 187-86-5 10334 3 15 Pentachlorophenol N.D. 185-01-8 10334 0.2 5 Phenanthrene N.D. 1108-95-2 10334 0.4 5 Phenol N.D. 1129-00-0 10334 0.2 5 Pyrene


of 4



Collected: 05/08/2012 09:30 by BC

Submitted: 05/09/2012 09:25


Reported: 05/18/2012 17:56





CAT No.














of 4



Collected: 05/08/2012 09:30 by BC

Submitted: 05/09/2012 09:25


Reported: 05/18/2012 17:56


OSS-E




Analyst






05716




1Yolunder Y Bunch05/17/2012 08:12 12138807901A1EPA 1664A HEM (oil & grease) 08079 1Luz M Groff05/09/2012 20:45 12130027902A1EPA 180.1 (1993)Turbidity 00279 1Hannah M Royer05/11/2012 10:06 12132020602A1SM20 2540 D Total Suspended Solids 00206 1Luz M Groff05/09/2012 15:15 12130021501A1SM20 2540 F Settleable Solids 00215 1Luz M Groff05/09/2012 21:45 12130020002B1SM20 4500 H/B pH 00200


of 1


Sample Description: Receiving Water-002 Grab Water S2010L4647 Greenpoint, NY XOM Brooklyn Terminal Project Name: Greenpoint Project

Collected: 05/08/2012 10:30 by BC

Submitted: 05/09/2012 09:25


Reported: 05/18/2012 17:56


RE002 As Received Limit of Quantitation



CAT No.

N T U N T UN T UWet Chemistry EPA 180.1 (1993) 11.4 1n.a. 00279 0.090 0.30 Turbidity







Analyst


1Luz M Groff05/09/2012 20:45 12130027902A1EPA 180.1 (1993)Turbidity 00279 1Hannah M Royer05/11/2012 10:06 12132020602A1SM20 2540 D Total Suspended Solids 00206 1Luz M Groff05/09/2012 21:45 12130020002B1SM20 4500 H/B pH 00200


of 2




Submitted: 05/09/2012 09:25


Reported: 05/18/2012 17:56


002-T As Received Limit of Quantitation



CAT No.







of 2




Submitted: 05/09/2012 09:25


Reported: 05/18/2012 17:56


002-T




Analyst


1Jason M Long05/15/2012 18:35 E121361AA1EPA 624 VOCs by 624 10371 1Kevin A Sposito05/11/2012 19:05 F121324AA1SW-846 8260B MTBE Only 8260B Water 10943 1Kevin A Sposito05/11/2012 19:05 F121324AA1SW-846 5030B GC/MS VOA Water Prep 01163


of 7





Blank Blank Blank Report LCS LCSD LCS/LCSD Analysis Name Result MDL** LOQ Units %REC %REC Limits RPD RPD Max Batch number: E121361AA Sample number(s): 6644874-6644875,6644877 Acrolein N.D. 10. 50 ug/l 92 53-126 Acrylonitrile N.D. 10. 50 ug/l 88 61-120 Benzene N.D. 0.9 5 ug/l 97 80-121 Bromodichloromethane N.D. 0.7 5 ug/l 91 76-123 Bromoform N.D. 0.8 5 ug/l 85 65-136 Bromomethane N.D. 2. 5 ug/l 92 55-122 Carbon Tetrachloride N.D. 1. 5 ug/l 91 72-128 Chlorobenzene N.D. 0.8 5 ug/l 90 79-120 Chloroethane N.D. 2. 5 ug/l 90 54-121 2-Chloroethyl Vinyl Ether N.D. 2. 10 ug/l 90 47-128 Chloroform N.D. 1. 5 ug/l 97 79-122 Chloromethane N.D. 2. 5 ug/l 92 63-135 Dibromochloromethane N.D. 1. 5 ug/l 88 74-121 1,2-Dichlorobenzene N.D. 1. 5 ug/l 93 78-125 1,3-Dichlorobenzene N.D. 1. 5 ug/l 90 78-124 1,4-Dichlorobenzene N.D. 1. 5 ug/l 92 78-124 Dichlorodifluoromethane N.D. 2. 5 ug/l 74 48-120 1,1-Dichloroethane N.D. 1. 5 ug/l 93 75-130 1,2-Dichloroethane N.D. 1. 5 ug/l 104 72-138 1,1-Dichloroethene N.D. 0.9 5 ug/l 94 71-136 cis-1,2-Dichloroethene N.D. 1. 5 ug/l 97 73-130 trans-1,2-Dichloroethene N.D. 1. 5 ug/l 91 73-131 1,2-Dichloropropane N.D. 1. 5 ug/l 94 78-121 cis-1,3-Dichloropropene N.D. 1. 5 ug/l 88 79-120 trans-1,3-Dichloropropene N.D. 0.6 5 ug/l 87 74-120 Ethylbenzene N.D. 0.8 5 ug/l 90 80-120 Methylene Chloride N.D. 2. 5 ug/l 96 71-132 1,1,2,2-Tetrachloroethane N.D. 1. 5 ug/l 94 75-121 Tetrachloroethene N.D. 1. 5 ug/l 89 77-127 Toluene N.D. 0.8 5 ug/l 90 80-120 1,1,1-Trichloroethane N.D. 1. 5 ug/l 92 74-127 1,1,2-Trichloroethane N.D. 1. 5 ug/l 97 80-120 Trichloroethene N.D. 1. 5 ug/l 94 80-120 Trichlorofluoromethane N.D. 2. 5 ug/l 97 55-136 Vinyl Chloride N.D. 2. 5 ug/l 88 56-121 Xylene (total) N.D. 0.9 5 ug/l 91 80-120

of 7



Blank Blank Blank Report LCS LCSD LCS/LCSD Analysis Name Result MDL** LOQ Units %REC %REC Limits RPD RPD Max Batch number: F121324AA Sample number(s): 6644874-6644875,6644877 Methyl Tertiary Butyl Ether N.D. 0.5 1 ug/l 80 68-121 Batch number: 12130WAJ625 Sample number(s): 6644874-6644875 Acenaphthene N.D. 0.3 5 ug/l 102 75-117 Acenaphthylene N.D. 0.3 5 ug/l 103 75-122 Anthracene N.D. 0.2 5 ug/l 103 75-116 Benzidine N.D. 20. 60 ug/l 34 16-104 Benzo(a)anthracene N.D. 0.2 5 ug/l 104 76-117 Benzo(a)pyrene N.D. 0.3 5 ug/l 105 69-143 Benzo(b)fluoranthene N.D. 0.3 5 ug/l 94 64-145 Benzo(g,h,i)perylene N.D. 0.2 5 ug/l 108 66-145 Benzo(k)fluoranthene N.D. 0.3 5 ug/l 115 66-145 4-Bromophenyl-phenylether N.D. 0.3 5 ug/l 106 80-112 Butylbenzylphthalate N.D. 0.8 5 ug/l 106 80-125 Di-n-butylphthalate N.D. 0.5 5 ug/l 105 76-120 4-Chloro-3-methylphenol N.D. 0.3 5 ug/l 109 75-113 4-Chloroaniline N.D. 0.3 5 ug/l 67 10-124 bis(2-Chloroethoxy)methane N.D. 0.5 5 ug/l 105 69-128 bis(2-Chloroethyl)ether N.D. 0.4 5 ug/l 102 72-114 bis(2-Chloroisopropyl)ether N.D. 0.3 5 ug/l 100 87-134 2-Chloronaphthalene N.D. 0.2 5 ug/l 93 57-112 2-Chlorophenol N.D. 0.3 5 ug/l 100 78-118 4-Chlorophenyl-phenylether N.D. 0.3 5 ug/l 103 76-115 Chrysene N.D. 0.2 5 ug/l 100 81-118 Dibenz(a,h)anthracene N.D. 0.4 5 ug/l 108 68-144 1,2-Dichlorobenzene N.D. 0.3 5 ug/l 94 73-111 1,3-Dichlorobenzene N.D. 0.3 5 ug/l 91 67-110 1,4-Dichlorobenzene N.D. 0.3 5 ug/l 92 68-111 3,3'-Dichlorobenzidine N.D. 0.8 5 ug/l 76 33-124 2,4-Dichlorophenol N.D. 0.3 5 ug/l 108 72-127 Diethylphthalate N.D. 0.3 5 ug/l 105 74-120 2,4-Dimethylphenol N.D. 0.3 5 ug/l 105 70-123 Dimethylphthalate N.D. 1. 5 ug/l 102 30-112 4,6-Dinitro-2-methylphenol N.D. 4. 15 ug/l 105 65-120 2,4-Dinitrophenol N.D. 10. 30 ug/l 103 64-140 2,4-Dinitrotoluene N.D. 0.4 5 ug/l 108 74-121 2,6-Dinitrotoluene N.D. 0.3 5 ug/l 103 80-115 1,2-Diphenylhydrazine N.D. 0.2 5 ug/l 106 75-114 bis(2-Ethylhexyl)phthalate N.D. 1. 5 ug/l 105 74-118 Fluoranthene N.D. 0.3 5 ug/l 106 86-119 Fluorene N.D. 0.3 5 ug/l 105 74-117 Hexachlorobenzene N.D. 1. 5 ug/l 104 75-114 Hexachlorobutadiene N.D. 0.8 5 ug/l 97 58-116 Hexachlorocyclopentadiene N.D. 2. 15 ug/l 80 38-133 Hexachloroethane N.D. 0.4 5 ug/l 89 61-113 Indeno(1,2,3-cd)pyrene N.D. 0.3 5 ug/l 105 67-143 Isophorone N.D. 0.3 5 ug/l 103 75-123 Naphthalene N.D. 0.2 5 ug/l 99 73-118 Nitrobenzene N.D. 0.5 5 ug/l 106 74-121

of 7



Blank Blank Blank Report LCS LCSD LCS/LCSD Analysis Name Result MDL** LOQ Units %REC %REC Limits RPD RPD Max 2-Nitrophenol N.D. 0.4 5 ug/l 107 77-120 4-Nitrophenol N.D. 5. 10 ug/l 50 27-80 N-Nitroso-di-n-propylamine N.D. 0.4 5 ug/l 98 68-114 N-Nitrosodimethylamine N.D. 2. 5 ug/l 63 44-81 N-Nitrosodiphenylamine N.D. 0.3 5 ug/l 105 84-135 Di-n-octylphthalate N.D. 0.5 5 ug/l 110 65-155 Pentachlorophenol N.D. 3. 15 ug/l 107 55-137 Phenanthrene N.D. 0.2 5 ug/l 103 77-113 Phenol N.D. 0.4 5 ug/l 57 26-71 Pyrene N.D. 0.2 5 ug/l 109 76-115 1,2,4-Trichlorobenzene N.D. 0.3 5 ug/l 97 70-119 2,4,6-Trichlorophenol N.D. 0.7 5 ug/l 104 83-120 Batch number: 121305716007 Sample number(s): 6644874-6644875 Calcium N.D. 70.5 200 ug/l 98 90-110 Copper N.D. 0.94 10.0 ug/l 100 90-110 Iron N.D. 14.1 200 ug/l 96 90-110 Manganese N.D. 0.44 5.0 ug/l 99 85-115 Batch number: 121315714001 Sample number(s): 6644874-6644875 Mercury N.D. 0.026 0.20 ug/l 98 85-115 Batch number: 12135113101A Sample number(s): 6644874-6644875 Phenols (water) N.D. 15. 40 ug/l 96 90-110 Batch number: 12136987121B Sample number(s): 6644874-6644875 Chloride N.D. 200. 400 ug/l 101 90-110 Batch number: 12130020002A Sample number(s): 6644874 pH 100 99-101 Batch number: 12130020002B Sample number(s): 6644875-6644876 pH 100 99-101 Batch number: 12130021501A Sample number(s): 6644874-6644875 Settleable Solids N.D. 0.10 0.10 ml/l/hr Batch number: 12130027902A Sample number(s): 6644874-6644876 Turbidity 0.11 J 0.090 0.30 N T U 93 90-110 Batch number: 12132020602A Sample number(s): 6644874-6644876 Total Suspended Solids N.D. 3,000. 12,000 ug/l 89 91 79-107 1 10 Batch number: 12138807901A Sample number(s): 6644874-6644875 HEM (oil & grease) N.D. 1,400. 5,000 ug/l 93 84 78-114 10 16


of 7



Unspiked (UNSPK) = the sample used in conjunction with the matrix spike Background (BKG) = the sample used in conjunction with the duplicate MS MSD MS/MSD RPD BKG DUP DUP Dup RPD Analysis Name %REC %REC Limits RPD MAX Conc Conc RPD Max___ Batch number: E121361AA Sample number(s): 6644874-6644875,6644877 UNSPK: 6644875 Acrolein 99 98 40-128 1 30 Acrylonitrile 101 99 58-124 2 30 Benzene 111 113 83-132 2 30 Bromodichloromethane 96 100 78-128 4 30 Bromoform 91 90 59-129 1 30 Bromomethane 94 95 52-134 1 30 Carbon Tetrachloride 105 108 76-147 4 30 Chlorobenzene 102 102 82-121 1 30 Chloroethane 94 98 50-140 4 30 2-Chloroethyl Vinyl Ether 0* 0* 10-172 0 30 Chloroform 106 106 82-132 0 30 Chloromethane 94 97 50-140 3 30 Dibromochloromethane 96 95 72-128 0 30 1,2-Dichlorobenzene 101 101 79-126 0 30 1,3-Dichlorobenzene 103 101 79-126 1 30 1,4-Dichlorobenzene 101 102 79-126 0 30 Dichlorodifluoromethane 88 88 42-132 0 30 1,1-Dichloroethane 109 110 79-141 1 30 1,2-Dichloroethane 111 114 65-146 2 30 1,1-Dichloroethene 112 112 75-153 1 30 cis-1,2-Dichloroethene 107 109 81-134 2 30 trans-1,2-Dichloroethene 109 108 74-144 1 30 1,2-Dichloropropane 101 104 77-130 3 30 cis-1,3-Dichloropropene 95 96 74-113 2 30 trans-1,3-Dichloropropene 95 95 69-116 0 30 Ethylbenzene 105 105 82-124 1 30 Methylene Chloride 104 105 65-148 1 30 1,1,2,2-Tetrachloroethane 102 102 73-121 0 30 Tetrachloroethene 106 107 78-136 1 30 Toluene 105 107 84-123 2 30 1,1,1-Trichloroethane 107 109 83-137 2 30 1,1,2-Trichloroethane 104 104 85-121 0 30 Trichloroethene 110 114 86-131 4 30 Trichlorofluoromethane 108 111 62-152 2 30 Vinyl Chloride 96 98 60-137 3 30 Xylene (total) 105 106 79-130 1 30 Batch number: F121324AA Sample number(s): 6644874-6644875,6644877 UNSPK: P645368 Methyl Tertiary Butyl Ether 79 79 72-126 0 30 Batch number: 12130WAJ625 Sample number(s): 6644874-6644875 UNSPK: P644993 Acenaphthene 99 96 74-112 3 30 Acenaphthylene 101 98 75-119 4 30 Anthracene 102 99 89-115 3 30 Benzidine 29 31 20-98 11 30

of 7




Unspiked (UNSPK) = the sample used in conjunction with the matrix spike Background (BKG) = the sample used in conjunction with the duplicate MS MSD MS/MSD RPD BKG DUP DUP Dup RPD Analysis Name %REC %REC Limits RPD MAX Conc Conc RPD Max___ Benzo(a)anthracene 103 101 78-126 4 30 Benzo(a)pyrene 103 99 70-121 2 30 Benzo(b)fluoranthene 94 99 61-146 11 30 Benzo(g,h,i)perylene 108 103 74-129 1 30 Benzo(k)fluoranthene 115 96 61-145 11 30 4-Bromophenyl-phenylether 104 102 74-109 5 30 Butylbenzylphthalate 110 107 74-117 3 30 Di-n-butylphthalate 104 101 68-115 3 30 4-Chloro-3-methylphenol 37* 41* 54-126 16 30 4-Chloroaniline 68 64 10-110 0 30 bis(2-Chloroethoxy)methane 109 104 73-130 2 30 bis(2-Chloroethyl)ether 99 97 76-107 4 30 bis(2-Chloroisopropyl)ether 100 98 85-114 4 30 2-Chloronaphthalene 88 86 53-117 4 30 2-Chlorophenol 3* 4* 81-99 24 30 4-Chlorophenyl-phenylether 99 96 87-116 3 30 Chrysene 100 96 78-125 2 30 Dibenz(a,h)anthracene 111 103 79-125 2 30 1,2-Dichlorobenzene 91 92 81-113 7 30 1,3-Dichlorobenzene 91 92 80-111 7 30 1,4-Dichlorobenzene 91 92 80-113 6 30 3,3'-Dichlorobenzidine 72 73 32-116 8 30 2,4-Dichlorophenol 4* 5* 77-98 15 30 Diethylphthalate 101 97 69-110 2 30 2,4-Dimethylphenol 99 97 71-102 4 30 Dimethylphthalate 98 96 37-142 4 30 4,6-Dinitro-2-methylphenol 109 106 57-139 3 30 2,4-Dinitrophenol 108* 102 10-107 0 30 2,4-Dinitrotoluene 102 99 79-107 4 30 2,6-Dinitrotoluene 101 98 83-107 3 30 1,2-Diphenylhydrazine 107 105 78-117 4 30 bis(2-Ethylhexyl)phthalate 109 105 86-128 2 30 Fluoranthene 101 100 69-119 5 30 Fluorene 101 98 74-109 3 30 Hexachlorobenzene 105 102 68-110 3 30 Hexachlorobutadiene 101 99 62-125 4 30 Hexachlorocyclopentadiene 97 99 36-146 8 30 Hexachloroethane 91 92 65-110 7 30 Indeno(1,2,3-cd)pyrene 107 101 79-124 0 30 Isophorone 105 101 84-107 2 30 Naphthalene 102 99 69-106 3 30 Nitrobenzene 109 105 75-109 3 30 2-Nitrophenol 20* 16* 66-120 16 30 4-Nitrophenol 33 30 10-88 3 30 N-Nitroso-di-n-propylamine 96 94 74-110 4 30 N-Nitrosodimethylamine 68 68 38-98 6 30

of 7




Unspiked (UNSPK) = the sample used in conjunction with the matrix spike Background (BKG) = the sample used in conjunction with the duplicate MS MSD MS/MSD RPD BKG DUP DUP Dup RPD Analysis Name %REC %REC Limits RPD MAX Conc Conc RPD Max___ N-Nitrosodiphenylamine 105 104 84-142 6 30 Di-n-octylphthalate 117 112 67-155 2 30 Pentachlorophenol 17* 18* 21-110 11 30 Phenanthrene 101 99 88-116 4 30 Phenol 6* 12 10-80 66* 30 Pyrene 111 108 82-113 4 30 1,2,4-Trichlorobenzene 102 99 73-113 3 30 2,4,6-Trichlorophenol 5* 4* 73-110 6 30 Batch number: 121305716007 Sample number(s): 6644874-6644875 UNSPK: P645748 BKG: P645748 Calcium 856 (2) 81-118 4,770,000 4,630,000 3 20 Copper 104 86-122 30.9 J 29.9 J 3 (1) 20 Iron 90 70-130 225 223 1 (1) 20 Manganese 96 70-130 125 123 1 20 Batch number: 121315714001 Sample number(s): 6644874-6644875 UNSPK: 6644875 BKG: 6644875 Mercury 96 80-120 N.D. N.D. 0 (1) 20 Batch number: 12135113101A Sample number(s): 6644874-6644875 UNSPK: P644912 Phenols (water) 94 101 90-110 7* 6 Batch number: 12136987121B Sample number(s): 6644874-6644875 UNSPK: P643361 BKG: P643361 Chloride 113* 90-110 98,500 101,000 2 (1) 20 Batch number: 12130020002A Sample number(s): 6644874 BKG: P644720 pH 7.7 7.6 0 3 Batch number: 12130020002B Sample number(s): 6644875-6644876 BKG: 6644875 pH 8.2 8.2 0 3 Batch number: 12130027902A Sample number(s): 6644874-6644876 BKG: 6644875 Turbidity 14.0 13.3 5* 3 Batch number: 12132020602A Sample number(s): 6644874-6644876 BKG: P644993 Total Suspended Solids 27,600 27,200 1 (1) 20


Surrogate recoveries which are outside of the QC window are confirmed unless attributed to dilution or otherwise noted on the Analysis Report. Analysis Name: VOCs by 624 Batch number: E121361AA

of 7




1,2-Dichloroethane-d4 Fluorobenzene 4-Bromofluorobenzene ________________________________________________________________________________________________________________ 6644874 105 103 101 6644875 103 103 97 6644877 104 102 96 Blank 104 103 93 LCS 105 104 97 MS 102 103 101 MSD 102 104 101 ________________________________________________________________________________________________________________ Limits: 76-114 80-120 86-115 Analysis Name: BTEX + MTBE 8260B Water Batch number: F121324AA Dibromofluoromethane 1,2-Dichloroethane-d4 Toluene-d8 4-Bromofluorobenzene ________________________________________________________________________________________________________________ 6644874 93 99 98 95 6644875 94 103 98 92 6644877 93 101 98 91 Blank 94 102 98 89 LCS 92 99 97 96 MS 92 102 98 97 MSD 93 103 98 97 ________________________________________________________________________________________________________________ Limits: 80-116 77-113 80-113 78-113 Analysis Name: Method 625 Batch number: 12130WAJ625 Nitrobenzene-d5 2-Fluorobiphenyl Terphenyl-d14 Phenol-d6 2-Fluorophenol 2,4,6-Tribromophenol ________________________________________________________________________________________________________________ 6644874 94 97 95 61 68 102 6644875 105 101 97 59 61 67 Blank 101 100 95 46 65 99 LCS 102 100 99 51 70 105 MS 106 99 102 7* 4* 4* MSD 105 100 103 8* 4* 4* ________________________________________________________________________________________________________________ Limits: 56-120 62-121 56-119 10-72 10-114 36-140

Case Narrative


General Comments:








EPA 624, GC/MS VolatilesBatch #: E121361AA (Sample number(s): 6644874-6644875, 6644877 UNSPK: 6644875)


EPA 625, GC/MS SemivolatilesBatch #: 12130WAJ625 (Sample number(s): 6644874-6644875 UNSPK: P644993)

The recovery(ies) for the following analyte(s) in the MS and/or MSD was outside the acceptance window: 2-Chlorophenol, 2,4-Dichlorophenol, 2-Nitrophenol, 4-Chloro-3-methylphenol, Pentachlorophenol, 2,4,6-Trichlorophenol, 2,4-Dinitrophenol, Phenol

The relative percent difference(s) for the following analyte(s) in the MS/MSD were outside outside acceptance windows: Phenol

The recovery(ies) for one or more surrogates were outside of the QC window for sample(s) MS, MSD



v 1.8.8 5/18/2012 5:59:08PM

EPA 420.4, Wet ChemistryBatch #: 12135113101A (Sample number(s): 6644874-6644875 UNSPK: P644912)

The relative percent difference(s) for the following analyte(s) in the MS/MSD were outside outside acceptance windows: Phenols (water)

EPA 180.1 (1993), Wet ChemistryBatch #: 12130027902A (Sample number(s): 6644874-6644876 BKG: 6644875)

The duplicate RPD for the following analyte(s) exceeded the acceptance window: Turbidity


Sample #s: 6644874, 6644875Sufficient sample volume was not available to perform a duplicate for thisanalysis.

v 1.8.8 5/18/2012 5:59:08PM




> greater than













3768.08

ANALYTICAL RESULTS

Prepared by:



Prepared for:


Brooklyn NY 11222

May 22, 2012




Client Sample Description Lancaster Labs (LLI) # RCS-Before Carbon Grab Air 6646694 RCS-Lead Carbon Grab Air 6646695 RCS-Lag Carbon Grab Air 6646696 The specific methodologies used in obtaining the enclosed analytical results are indicated on the Laboratory Sample Analysis Record. ELECTRONIC COPY TO



(717) 556-7250

of 2

LLI Sample # AQ 6646694LLI Group # 1307951 Account # 13438

Sample Description: RCS-Before Carbon Grab Air S2010L4647 Greenpoint, NY Summa #185 XOM Brooklyn Terminal Project Name: Greenpoint Project

Collected: 05/08/2012 11:46 by MS

Submitted: 05/10/2012 09:20


Reported: 05/22/2012 18:13


CAT No. DFCAS NumberAnalysis Name As Received

Final Result MDLAs Received Final Result MDL

ppb(v)ppb(v) ug/m3ug/m3Volatiles in Air EPA TO-15 0.503.5 8.3 167-64-1 05298 1.2Acetone 4.01,000 3,200 2071-43-2 05298 13Benzene 0.50N.D. N.D. 1100-44-7 05298 2.6Benzyl chloride

The stated QC limits are advisory only until sufficient data pointscan be obtained to calculate statistical limits.

0.20N.D. N.D. 175-27-4 05298 1.3Bromodichloromethane 0.50N.D. N.D. 1593-60-2 05298 2.2Bromoethene 0.20N.D. N.D. 175-25-2 05298 2.1Bromoform 0.20N.D. N.D. 174-83-9 05298 0.78Bromomethane 0.50N.D. N.D. 1106-99-0 05298 1.11,3-Butadiene 0.504.2 13 175-65-0 05298 1.5tert-Butyl Alcohol 0.50N.D. N.D. 175-15-0 05298 1.6Carbon Disulfide 0.20N.D. N.D. 156-23-5 05298 1.3Carbon Tetrachloride 0.201.1 4.9 1108-90-7 05298 0.92Chlorobenzene 0.201.8 4.8 175-00-3 05298 0.53Chloroethane 0.20N.D. N.D. 167-66-3 05298 0.98Chloroform 0.20N.D. N.D. 174-87-3 05298 0.41Chloromethane 0.20N.D. N.D. 1107-05-1 05298 0.633-Chloropropene 0.20N.D. N.D. 195-49-8 05298 1.02-Chlorotoluene 4.0220 760 20110-82-7 05298 14Cyclohexane 0.20N.D. N.D. 1124-48-1 05298 1.7Dibromochloromethane 0.20N.D. N.D. 1106-93-4 05298 1.51,2-Dibromoethane 0.200.55 J 3.3 J 1541-73-1 05298 1.2m-Dichlorobenzene 0.200.60 J 3.6 J 195-50-1 05298 1.2o-Dichlorobenzene 0.200.62 J 3.7 J 1106-46-7 05298 1.2p-Dichlorobenzene 0.200.52 J 2.6 J 175-71-8 05298 0.99Dichlorodifluoromethane 0.204.3 17 175-34-3 05298 0.811,1-Dichloroethane 0.2013 53 1107-06-2 05298 0.811,2-Dichloroethane 0.204.1 16 175-35-4 05298 0.791,1-Dichloroethene 4.0150 610 20156-59-2 05298 16cis-1,2-Dichloroethene 0.209.7 38 1156-60-5 05298 0.79trans-1,2-Dichloroethene 0.20N.D. N.D. 178-87-5 05298 0.921,2-Dichloropropane 0.20N.D. N.D. 110061-01-505298 0.91cis-1,3-Dichloropropene 0.20N.D. N.D. 110061-02-605298 0.91trans-1,3-Dichloropropene 0.50N.D. N.D. 1123-91-1 05298 1.81,4-Dioxane 0.50N.D. N.D. 164-17-5 05298 0.94Ethanol

The QC window for ethanol is advisory due to the erratic performance of the analyte using this method.

0.50N.D. N.D. 1141-78-6 05298 1.8Ethyl Acetate 0.2037 160 1100-41-4 05298 0.87Ethylbenzene 0.2011 55 1622-96-8 05298 0.984-Ethyltoluene 0.50N.D. N.D. 176-13-1 05298 3.8Freon 113 0.20N.D. N.D. 176-14-2 05298 1.4Freon 114 0.2013 53 1142-82-5 05298 0.82Heptane 0.50N.D. N.D. 187-68-3 05298 5.3Hexachlorobutadiene 0.2019 68 1110-54-3 05298 0.70Hexane 0.50N.D. N.D. 1591-78-6 05298 2.02-Hexanone 0.50N.D. N.D. 167-63-0 05298 1.2Isopropyl Alcohol 0.500.79 J 2.3 J 178-93-3 05298 1.5Methyl Ethyl Ketone 0.50N.D. N.D. 1108-10-1 05298 2.0Methyl Isobutyl Ketone 0.20N.D. N.D. 180-62-6 05298 0.82Methyl Methacrylate

of 2


Sample Description: RCS-Before Carbon Grab Air S2010L4647 Greenpoint, NY Summa #185 XOM Brooklyn Terminal Project Name: Greenpoint Project

Collected: 05/08/2012 11:46 by MS

Submitted: 05/10/2012 09:20


Reported: 05/22/2012 18:13




ppb(v)ppb(v) ug/m3ug/m3Volatiles in Air EPA TO-15 4.057 210 201634-04-4 05298 14Methyl t-Butyl Ether 0.200.54 J 1.9 J 175-09-2 05298 0.69Methylene Chloride 0.204.2 7.2 1115-07-1 05298 0.34Propene 0.200.86 J 3.6 J 1100-42-5 05298 0.85Styrene 0.20N.D. N.D. 179-34-5 05298 1.41,1,2,2-Tetrachloroethane 4.0210 1,500 20127-18-4 05298 27Tetrachloroethene 0.20N.D. N.D. 1109-99-9 05298 0.59Tetrahydrofuran 0.2050 190 1108-88-3 05298 0.75Toluene 0.50N.D. N.D. 1120-82-1 05298 3.71,2,4-Trichlorobenzene 0.200.56 J 3.0 J 171-55-6 05298 1.11,1,1-Trichloroethane 0.20N.D. N.D. 179-00-5 05298 1.11,1,2-Trichloroethane 4.0180 980 2079-01-6 05298 21Trichloroethene 0.200.23 J 1.3 J 175-69-4 05298 1.1Trichlorofluoromethane 0.2016 74 1540-84-1 05298 0.932,2,4-Trimethyl Pentane 4.067 330 2095-63-6 05298 201,2,4-Trimethylbenzene 4.042 210 20108-67-8 05298 201,3,5-Trimethylbenzene 0.50N.D. N.D. 1108-05-4 05298 1.8Vinyl Acetate 0.2018 45 175-01-4 05298 0.51Vinyl Chloride 4.0100 450 20179601-23-105298 17m/p-Xylene 0.2019 83 195-47-6 05298 0.87o-Xylene 4.0120 530 201330-20-7 05298 17Xylene (total)

MDL = Method Detection Limit





Analyst


1Michael A Ziegler05/21/2012 16:28 A1214030AB1EPA TO-15 TO 15 VOA Ext. List 05298 20Michael A Ziegler05/21/2012 18:57 A1214030AB1EPA TO-15 TO 15 VOA Ext. List 05298

of 2


Sample Description: RCS-Lead Carbon Grab Air S2010L4647 Greenpoint, NY Summa #69 XOM Brooklyn Terminal Project Name: Greenpoint Project

Collected: 05/08/2012 11:50 by MS

Submitted: 05/10/2012 09:20


Reported: 05/22/2012 18:13




ppb(v)ppb(v) ug/m3ug/m3Volatiles in Air EPA TO-15 0.5012 30 167-64-1 05298 1.2Acetone 0.2014 46 171-43-2 05298 0.64Benzene 0.50N.D. N.D. 1100-44-7 05298 2.6Benzyl chloride


0.20N.D. N.D. 175-27-4 05298 1.3Bromodichloromethane 0.50N.D. N.D. 1593-60-2 05298 2.2Bromoethene 0.20N.D. N.D. 175-25-2 05298 2.1Bromoform 0.20N.D. N.D. 174-83-9 05298 0.78Bromomethane 0.50N.D. N.D. 1106-99-0 05298 1.11,3-Butadiene 0.50N.D. N.D. 175-65-0 05298 1.5tert-Butyl Alcohol 0.50N.D. N.D. 175-15-0 05298 1.6Carbon Disulfide 0.20N.D. N.D. 156-23-5 05298 1.3Carbon Tetrachloride 0.20N.D. N.D. 1108-90-7 05298 0.92Chlorobenzene 0.201.1 3.0 175-00-3 05298 0.53Chloroethane 0.200.46 J 2.3 J 167-66-3 05298 0.98Chloroform 0.20N.D. N.D. 174-87-3 05298 0.41Chloromethane 0.20N.D. N.D. 1107-05-1 05298 0.633-Chloropropene 0.20N.D. N.D. 195-49-8 05298 1.02-Chlorotoluene 0.206.0 21 1110-82-7 05298 0.69Cyclohexane 0.20N.D. N.D. 1124-48-1 05298 1.7Dibromochloromethane 0.20N.D. N.D. 1106-93-4 05298 1.51,2-Dibromoethane 0.20N.D. N.D. 1541-73-1 05298 1.2m-Dichlorobenzene 0.20N.D. N.D. 195-50-1 05298 1.2o-Dichlorobenzene 0.20N.D. N.D. 1106-46-7 05298 1.2p-Dichlorobenzene 0.200.70 J 3.5 J 175-71-8 05298 0.99Dichlorodifluoromethane 0.201.9 7.7 175-34-3 05298 0.811,1-Dichloroethane 0.20N.D. N.D. 1107-06-2 05298 0.811,2-Dichloroethane 0.203.0 12 175-35-4 05298 0.791,1-Dichloroethene 0.2062 240 1156-59-2 05298 0.79cis-1,2-Dichloroethene 0.204.0 16 1156-60-5 05298 0.79trans-1,2-Dichloroethene 0.20N.D. N.D. 178-87-5 05298 0.921,2-Dichloropropane 0.20N.D. N.D. 110061-01-505298 0.91cis-1,3-Dichloropropene 0.20N.D. N.D. 110061-02-605298 0.91trans-1,3-Dichloropropene 0.50N.D. N.D. 1123-91-1 05298 1.81,4-Dioxane 0.502.0 3.7 164-17-5 05298 0.94Ethanol


0.50N.D. N.D. 1141-78-6 05298 1.8Ethyl Acetate 0.20N.D. N.D. 1100-41-4 05298 0.87Ethylbenzene 0.20N.D. N.D. 1622-96-8 05298 0.984-Ethyltoluene 0.50N.D. N.D. 176-13-1 05298 3.8Freon 113 0.20N.D. N.D. 176-14-2 05298 1.4Freon 114 0.200.48 J 1.9 J 1142-82-5 05298 0.82Heptane 0.50N.D. N.D. 187-68-3 05298 5.3Hexachlorobutadiene 0.200.48 J 1.7 J 1110-54-3 05298 0.70Hexane 0.50N.D. N.D. 1591-78-6 05298 2.02-Hexanone 0.50N.D. N.D. 167-63-0 05298 1.2Isopropyl Alcohol 0.501.3 J 3.8 J 178-93-3 05298 1.5Methyl Ethyl Ketone 0.50N.D. N.D. 1108-10-1 05298 2.0Methyl Isobutyl Ketone 0.20N.D. N.D. 180-62-6 05298 0.82Methyl Methacrylate

of 2


Sample Description: RCS-Lead Carbon Grab Air S2010L4647 Greenpoint, NY Summa #69 XOM Brooklyn Terminal Project Name: Greenpoint Project

Collected: 05/08/2012 11:50 by MS

Submitted: 05/10/2012 09:20


Reported: 05/22/2012 18:13




ppb(v)ppb(v) ug/m3ug/m3Volatiles in Air EPA TO-15 0.201.3 4.7 11634-04-4 05298 0.72Methyl t-Butyl Ether 0.203.1 11 175-09-2 05298 0.69Methylene Chloride 0.202.7 4.6 1115-07-1 05298 0.34Propene 0.20N.D. N.D. 1100-42-5 05298 0.85Styrene 0.20N.D. N.D. 179-34-5 05298 1.41,1,2,2-Tetrachloroethane 0.20N.D. N.D. 1127-18-4 05298 1.4Tetrachloroethene 0.20N.D. N.D. 1109-99-9 05298 0.59Tetrahydrofuran 0.200.51 J 1.9 J 1108-88-3 05298 0.75Toluene 0.50N.D. N.D. 1120-82-1 05298 3.71,2,4-Trichlorobenzene 0.20N.D. N.D. 171-55-6 05298 1.11,1,1-Trichloroethane 0.20N.D. N.D. 179-00-5 05298 1.11,1,2-Trichloroethane 0.203.0 16 179-01-6 05298 1.1Trichloroethene 0.200.65 J 3.6 J 175-69-4 05298 1.1Trichlorofluoromethane 0.20N.D. N.D. 1540-84-1 05298 0.932,2,4-Trimethyl Pentane 0.200.24 J 1.2 J 195-63-6 05298 0.981,2,4-Trimethylbenzene 0.20N.D. N.D. 1108-67-8 05298 0.981,3,5-Trimethylbenzene 0.50N.D. N.D. 1108-05-4 05298 1.8Vinyl Acetate 0.2012 30 175-01-4 05298 0.51Vinyl Chloride 0.200.27 J 1.2 J 1179601-23-105298 0.87m/p-Xylene 0.20N.D. N.D. 195-47-6 05298 0.87o-Xylene 0.200.27 J 1.2 J 11330-20-7 05298 0.87Xylene (total)






Analyst


1Michael A Ziegler05/21/2012 19:39 A1214030AB1EPA TO-15 TO 15 VOA Ext. List 05298

of 2


Sample Description: RCS-Lag Carbon Grab Air S2010L4647 Greenpoint, NY Summa #140 XOM Brooklyn Terminal Project Name: Greenpoint Project

Collected: 05/08/2012 11:52 by MS

Submitted: 05/10/2012 09:20


Reported: 05/22/2012 18:13




ppb(v)ppb(v) ug/m3ug/m3Volatiles in Air EPA TO-15 0.509.0 21 167-64-1 05298 1.2Acetone 0.200.42 J 1.3 J 171-43-2 05298 0.64Benzene 0.50N.D. N.D. 1100-44-7 05298 2.6Benzyl chloride


0.20N.D. N.D. 175-27-4 05298 1.3Bromodichloromethane 0.50N.D. N.D. 1593-60-2 05298 2.2Bromoethene 0.20N.D. N.D. 175-25-2 05298 2.1Bromoform 0.20N.D. N.D. 174-83-9 05298 0.78Bromomethane 0.50N.D. N.D. 1106-99-0 05298 1.11,3-Butadiene 0.50N.D. N.D. 175-65-0 05298 1.5tert-Butyl Alcohol 0.50N.D. N.D. 175-15-0 05298 1.6Carbon Disulfide 0.20N.D. N.D. 156-23-5 05298 1.3Carbon Tetrachloride 0.20N.D. N.D. 1108-90-7 05298 0.92Chlorobenzene 0.201.5 3.9 175-00-3 05298 0.53Chloroethane 0.20N.D. N.D. 167-66-3 05298 0.98Chloroform 0.20N.D. N.D. 174-87-3 05298 0.41Chloromethane 0.20N.D. N.D. 1107-05-1 05298 0.633-Chloropropene 0.20N.D. N.D. 195-49-8 05298 1.02-Chlorotoluene 0.20N.D. N.D. 1110-82-7 05298 0.69Cyclohexane 0.20N.D. N.D. 1124-48-1 05298 1.7Dibromochloromethane 0.20N.D. N.D. 1106-93-4 05298 1.51,2-Dibromoethane 0.200.38 J 2.3 J 1541-73-1 05298 1.2m-Dichlorobenzene 0.200.40 J 2.4 J 195-50-1 05298 1.2o-Dichlorobenzene 0.200.44 J 2.6 J 1106-46-7 05298 1.2p-Dichlorobenzene 0.200.41 J 2.0 J 175-71-8 05298 0.99Dichlorodifluoromethane 0.20N.D. N.D. 175-34-3 05298 0.811,1-Dichloroethane 0.20N.D. N.D. 1107-06-2 05298 0.811,2-Dichloroethane 0.200.24 J 0.94 J 175-35-4 05298 0.791,1-Dichloroethene 0.200.54 J 2.1 J 1156-59-2 05298 0.79cis-1,2-Dichloroethene 0.20N.D. N.D. 1156-60-5 05298 0.79trans-1,2-Dichloroethene 0.20N.D. N.D. 178-87-5 05298 0.921,2-Dichloropropane 0.20N.D. N.D. 110061-01-505298 0.91cis-1,3-Dichloropropene 0.20N.D. N.D. 110061-02-605298 0.91trans-1,3-Dichloropropene 0.50N.D. N.D. 1123-91-1 05298 1.81,4-Dioxane 0.50N.D. N.D. 164-17-5 05298 0.94Ethanol


0.50N.D. N.D. 1141-78-6 05298 1.8Ethyl Acetate 0.200.38 J 1.6 J 1100-41-4 05298 0.87Ethylbenzene 0.200.31 J 1.5 J 1622-96-8 05298 0.984-Ethyltoluene 0.50N.D. N.D. 176-13-1 05298 3.8Freon 113 0.20N.D. N.D. 176-14-2 05298 1.4Freon 114 0.20N.D. N.D. 1142-82-5 05298 0.82Heptane 0.50N.D. N.D. 187-68-3 05298 5.3Hexachlorobutadiene 0.20N.D. N.D. 1110-54-3 05298 0.70Hexane 0.50N.D. N.D. 1591-78-6 05298 2.02-Hexanone 0.50N.D. N.D. 167-63-0 05298 1.2Isopropyl Alcohol 0.500.59 J 1.7 J 178-93-3 05298 1.5Methyl Ethyl Ketone 0.50N.D. N.D. 1108-10-1 05298 2.0Methyl Isobutyl Ketone 0.20N.D. N.D. 180-62-6 05298 0.82Methyl Methacrylate

of 2


Sample Description: RCS-Lag Carbon Grab Air S2010L4647 Greenpoint, NY Summa #140 XOM Brooklyn Terminal Project Name: Greenpoint Project

Collected: 05/08/2012 11:52 by MS

Submitted: 05/10/2012 09:20


Reported: 05/22/2012 18:13




ppb(v)ppb(v) ug/m3ug/m3Volatiles in Air EPA TO-15 0.20N.D. N.D. 11634-04-4 05298 0.72Methyl t-Butyl Ether 0.200.33 J 1.2 J 175-09-2 05298 0.69Methylene Chloride 0.203.1 5.4 1115-07-1 05298 0.34Propene 0.200.23 J 0.97 J 1100-42-5 05298 0.85Styrene 0.20N.D. N.D. 179-34-5 05298 1.41,1,2,2-Tetrachloroethane 0.200.28 J 1.9 J 1127-18-4 05298 1.4Tetrachloroethene 0.20N.D. N.D. 1109-99-9 05298 0.59Tetrahydrofuran 0.200.28 J 1.0 J 1108-88-3 05298 0.75Toluene 0.50N.D. N.D. 1120-82-1 05298 3.71,2,4-Trichlorobenzene 0.20N.D. N.D. 171-55-6 05298 1.11,1,1-Trichloroethane 0.20N.D. N.D. 179-00-5 05298 1.11,1,2-Trichloroethane 0.20N.D. N.D. 179-01-6 05298 1.1Trichloroethene 0.20N.D. N.D. 175-69-4 05298 1.1Trichlorofluoromethane 0.20N.D. N.D. 1540-84-1 05298 0.932,2,4-Trimethyl Pentane 0.200.58 J 2.9 J 195-63-6 05298 0.981,2,4-Trimethylbenzene 0.200.37 J 1.8 J 1108-67-8 05298 0.981,3,5-Trimethylbenzene 0.50N.D. N.D. 1108-05-4 05298 1.8Vinyl Acetate 0.2016 40 175-01-4 05298 0.51Vinyl Chloride 0.200.98 J 4.2 J 1179601-23-105298 0.87m/p-Xylene 0.200.64 J 2.8 J 195-47-6 05298 0.87o-Xylene 0.201.6 7.0 11330-20-7 05298 0.87Xylene (total)






Analyst


1Michael A Ziegler05/21/2012 17:55 A1214030AB1EPA TO-15 TO 15 VOA Ext. List 05298

of 2


*- Outside of specification (1) The result for one or both determinations was less than five times the LOQ. (2) The unspiked result was more than four times the spike added.



Blank Blank Report LCS LCSD LCS/LCSD Analysis Name Result MDL Units %REC %REC Limits RPD RPD Max Batch number: A1214030AB Sample number(s): 6646694-6646696 Acetone N.D. 1.2 ug/m3 106 107 67-138 2 25 Benzene N.D. 0.64 ug/m3 105 111 70-130 5 25 Benzyl chloride N.D. 2.6 ug/m3 63* 72 70-130 13 25 Bromodichloromethane N.D. 1.3 ug/m3 107 117 70-138 8 25 Bromoethene N.D. 2.2 ug/m3 Bromoform N.D. 2.1 ug/m3 101 112 71-150 10 25 Bromomethane N.D. 0.78 ug/m3 85 93 70-130 9 25 1,3-Butadiene N.D. 1.1 ug/m3 79 83 60-135 6 25 tert-Butyl Alcohol N.D. 1.5 ug/m3 Carbon Disulfide N.D. 1.6 ug/m3 70 73 56-106 4 25 Carbon Tetrachloride N.D. 1.3 ug/m3 97 100 70-130 3 25 Chlorobenzene N.D. 0.92 ug/m3 94 103 70-130 9 25 Chloroethane N.D. 0.53 ug/m3 93 98 71-129 6 25 Chloroform N.D. 0.98 ug/m3 99 105 70-130 6 25 Chloromethane N.D. 0.41 ug/m3 81 86 58-129 6 25 3-Chloropropene N.D. 0.63 ug/m3 2-Chlorotoluene N.D. 1.0 ug/m3 Cyclohexane N.D. 0.69 ug/m3 90 94 61-122 4 25 Dibromochloromethane N.D. 1.7 ug/m3 97 105 68-138 8 25 1,2-Dibromoethane N.D. 1.5 ug/m3 98 107 71-135 10 25 m-Dichlorobenzene N.D. 1.2 ug/m3 104 110 68-136 6 25 o-Dichlorobenzene N.D. 1.2 ug/m3 109 120 71-143 10 25 p-Dichlorobenzene N.D. 1.2 ug/m3 105 118 67-140 12 25 Dichlorodifluoromethane N.D. 0.99 ug/m3 86 91 72-140 6 25 1,1-Dichloroethane N.D. 0.81 ug/m3 100 104 66-126 4 25 1,2-Dichloroethane N.D. 0.81 ug/m3 110 117 70-130 6 25 1,1-Dichloroethene N.D. 0.79 ug/m3 81 85 64-117 5 25 cis-1,2-Dichloroethene N.D. 0.79 ug/m3 96 103 69-120 7 25 trans-1,2-Dichloroethene N.D. 0.79 ug/m3 88 93 67-121 5 25 1,2-Dichloropropane N.D. 0.92 ug/m3 102 109 70-130 6 25 cis-1,3-Dichloropropene N.D. 0.91 ug/m3 105 110 67-134 4 25 trans-1,3-Dichloropropene N.D. 0.91 ug/m3 96 106 67-134 9 25 1,4-Dioxane N.D. 1.8 ug/m3 134 130 45-182 3 25 Ethanol N.D. 0.94 ug/m3 199* 193* 70-130 3 25 Ethyl Acetate N.D. 1.8 ug/m3 117 121 63-130 3 25 Ethylbenzene N.D. 0.87 ug/m3 94 104 70-130 10 25 4-Ethyltoluene N.D. 0.98 ug/m3 97 108 69-135 11 25

of 2



Blank Blank Report LCS LCSD LCS/LCSD Analysis Name Result MDL Units %REC %REC Limits RPD RPD Max Freon 113 N.D. 3.8 ug/m3 91 96 67-115 5 25 Freon 114 N.D. 1.4 ug/m3 78 82 66-120 6 25 Heptane N.D. 0.82 ug/m3 98 104 60-125 6 25 Hexachlorobutadiene N.D. 5.3 ug/m3 98 105 54-155 7 25 Hexane N.D. 0.70 ug/m3 91 95 62-120 4 25 2-Hexanone N.D. 2.0 ug/m3 127 133 54-166 5 25 Isopropyl Alcohol N.D. 1.2 ug/m3 121 118 70-130 3 25 Methyl Ethyl Ketone N.D. 1.5 ug/m3 109 113 66-129 3 25 Methyl Isobutyl Ketone N.D. 2.0 ug/m3 123 130 61-145 5 25 Methyl Methacrylate N.D. 0.82 ug/m3 118 122 66-139 3 25 Methyl t-Butyl Ether N.D. 0.72 ug/m3 93 95 64-124 3 25 Methylene Chloride N.D. 0.69 ug/m3 90 94 70-130 5 25 Propene N.D. 0.34 ug/m3 67 72 47-117 8 25 Styrene N.D. 0.85 ug/m3 98 107 70-139 9 25 1,1,2,2-Tetrachloroethane N.D. 1.4 ug/m3 105 114 67-145 8 25 Tetrachloroethene N.D. 1.4 ug/m3 95 105 70-130 9 25 Tetrahydrofuran N.D. 0.59 ug/m3 105 108 56-140 3 25 Toluene N.D. 0.75 ug/m3 96 103 70-130 7 25 1,2,4-Trichlorobenzene N.D. 3.7 ug/m3 119 127 45-182 7 25 1,1,1-Trichloroethane N.D. 1.1 ug/m3 103 107 70-130 4 25 1,1,2-Trichloroethane N.D. 1.1 ug/m3 98 105 68-128 7 25 Trichloroethene N.D. 1.1 ug/m3 106 116 70-130 9 25 Trichlorofluoromethane N.D. 1.1 ug/m3 87 97 70-130 12 25 2,2,4-Trimethyl Pentane N.D. 0.93 ug/m3 1,2,4-Trimethylbenzene N.D. 0.98 ug/m3 102 112 69-138 9 25 1,3,5-Trimethylbenzene N.D. 0.98 ug/m3 98 107 71-142 9 25 Vinyl Acetate N.D. 1.8 ug/m3 112 115 61-150 2 25 Vinyl Chloride N.D. 0.51 ug/m3 84 93 70-130 11 25 m/p-Xylene N.D. 0.87 ug/m3 98 105 70-130 6 25 o-Xylene N.D. 0.87 ug/m3 99 108 70-130 9 25 Xylene (total) N.D. 0.87 ug/m3 98 106 70-130 7 25

Case Narrative


General Comments:








EPA TO-15, Volatiles in AirBatch #: A1214030AB (Sample number(s): 6646694-6646696)

The recovery(ies) for the following analyte(s) in the LCS and/or LCSD exceeded the acceptance window indicating a positive bias: Ethanol

The recovery(ies) for the following analyte(s) in the LCS and/or LCSD were below the acceptance window: Benzyl Chloride

v 1.8.8 5/22/2012 6:15:19PM




> greater than













3768.08

ANALYTICAL RESULTS

Prepared by:



Prepared for:


Brooklyn NY 11222

May 29, 2012




Client Sample Description Lancaster Labs (LLI) # ORS AS INFLUENT Composite Air 6660446 SVE INFLUENT Grab Air 6660447 SVE COMBINED INFLUENT Composite Air 6660448 FLAME OX EFFLUENT Composite Air 6660449 The specific methodologies used in obtaining the enclosed analytical results are indicated on the Laboratory Sample Analysis Record. ELECTRONIC COPY TO



(717) 556-7250

of 2


Sample Description: ORS AS INFLUENT Composite Air S2010L4647 Greenpoint, NY Summa #146 XOM Brooklyn Terminal Project Name: Greenpoint Project

Collected: 05/08/2012 13:40 by BC

Submitted: 05/22/2012 09:30


Reported: 05/29/2012 18:48


through 05/08/2012 14:40



ppb(v)ppb(v) ug/m3ug/m3Volatiles in Air EPA TO-15 50660 1,600 10067-64-1 05298 120Acetone 201,300 4,200 10071-43-2 05298 64Benzene 50N.D. N.D. 100100-44-7 05298 260Benzyl chloride


20N.D. N.D. 10075-27-4 05298 130Bromodichloromethane 50N.D. N.D. 100593-60-2 05298 220Bromoethene 20N.D. N.D. 10075-25-2 05298 210Bromoform 20N.D. N.D. 10074-83-9 05298 78Bromomethane 50N.D. N.D. 100106-99-0 05298 1101,3-Butadiene 50N.D. N.D. 10075-65-0 05298 150tert-Butyl Alcohol 50180 550 10075-15-0 05298 160Carbon Disulfide 20N.D. N.D. 10056-23-5 05298 130Carbon Tetrachloride 20N.D. N.D. 100108-90-7 05298 92Chlorobenzene 20230 600 10075-00-3 05298 53Chloroethane 20N.D. N.D. 10067-66-3 05298 98Chloroform 20N.D. N.D. 10074-87-3 05298 41Chloromethane 20N.D. N.D. 100107-05-1 05298 633-Chloropropene 20N.D. N.D. 10095-49-8 05298 1002-Chlorotoluene 20360 1,200 100110-82-7 05298 69Cyclohexane 20N.D. N.D. 100124-48-1 05298 170Dibromochloromethane 20N.D. N.D. 100106-93-4 05298 1501,2-Dibromoethane 20N.D. N.D. 100541-73-1 05298 120m-Dichlorobenzene 20N.D. N.D. 10095-50-1 05298 120o-Dichlorobenzene 20N.D. N.D. 100106-46-7 05298 120p-Dichlorobenzene 20N.D. N.D. 10075-71-8 05298 99Dichlorodifluoromethane 20N.D. N.D. 10075-34-3 05298 811,1-Dichloroethane 20N.D. N.D. 100107-06-2 05298 811,2-Dichloroethane 20N.D. N.D. 10075-35-4 05298 791,1-Dichloroethene 20890 3,500 100156-59-2 05298 79cis-1,2-Dichloroethene 2053 J 210 J 100156-60-5 05298 79trans-1,2-Dichloroethene 20N.D. N.D. 10078-87-5 05298 921,2-Dichloropropane 20N.D. N.D. 10010061-01-505298 91cis-1,3-Dichloropropene 20N.D. N.D. 10010061-02-605298 91trans-1,3-Dichloropropene 50N.D. N.D. 100123-91-1 05298 1801,4-Dioxane 50760 1,400 10064-17-5 05298 94Ethanol


50N.D. N.D. 100141-78-6 05298 180Ethyl Acetate 20120 510 100100-41-4 05298 87Ethylbenzene 2033 J 160 J 100622-96-8 05298 984-Ethyltoluene 50N.D. N.D. 10076-13-1 05298 380Freon 113 20N.D. N.D. 10076-14-2 05298 140Freon 114 2086 J 350 J 100142-82-5 05298 82Heptane 50N.D. N.D. 10087-68-3 05298 530Hexachlorobutadiene 20150 530 100110-54-3 05298 70Hexane 50N.D. N.D. 100591-78-6 05298 2002-Hexanone 50320 790 10067-63-0 05298 120Isopropyl Alcohol 50N.D. N.D. 10078-93-3 05298 150Methyl Ethyl Ketone 50N.D. N.D. 100108-10-1 05298 200Methyl Isobutyl Ketone 20460 1,900 10080-62-6 05298 82Methyl Methacrylate

of 2


Sample Description: ORS AS INFLUENT Composite Air S2010L4647 Greenpoint, NY Summa #146 XOM Brooklyn Terminal Project Name: Greenpoint Project

Collected: 05/08/2012 13:40 by BC

Submitted: 05/22/2012 09:30


Reported: 05/29/2012 18:48


through 05/08/2012 14:40



ppb(v)ppb(v) ug/m3ug/m3Volatiles in Air EPA TO-15 20170 600 1001634-04-4 05298 72Methyl t-Butyl Ether 20110 400 10075-09-2 05298 69Methylene Chloride 2029 J 49 J 100115-07-1 05298 34Propene 20160 660 100100-42-5 05298 85Styrene 20N.D. N.D. 10079-34-5 05298 1401,1,2,2-Tetrachloroethane 2061 J 420 J 100127-18-4 05298 140Tetrachloroethene 20N.D. N.D. 100109-99-9 05298 59Tetrahydrofuran 20160 590 100108-88-3 05298 75Toluene 50N.D. N.D. 100120-82-1 05298 3701,2,4-Trichlorobenzene 20N.D. N.D. 10071-55-6 05298 1101,1,1-Trichloroethane 20N.D. N.D. 10079-00-5 05298 1101,1,2-Trichloroethane 20370 2,000 10079-01-6 05298 110Trichloroethene 20N.D. N.D. 10075-69-4 05298 110Trichlorofluoromethane 20470 2,200 100540-84-1 05298 932,2,4-Trimethyl Pentane 20110 520 10095-63-6 05298 981,2,4-Trimethylbenzene 2046 J 230 J 100108-67-8 05298 981,3,5-Trimethylbenzene 50N.D. N.D. 100108-05-4 05298 180Vinyl Acetate 20190 500 10075-01-4 05298 51Vinyl Chloride 20120 530 100179601-23-105298 87m/p-Xylene 2038 J 160 J 10095-47-6 05298 87o-Xylene 20160 690 1001330-20-7 05298 87Xylene (total)

Reporting limits were raised due to interference from the sample matrix.






Analyst


100Michael A Ziegler05/24/2012 03:18 C1214330AB1EPA TO-15 TO 15 VOA Ext. List 05298

of 1


Sample Description: SVE INFLUENT Grab Air S2010L4647 Greenpoint, NY Summa #880 XOM Brooklyn Terminal Project Name: Greenpoint Project

Collected: 05/08/2012 13:30 by BC

Submitted: 05/22/2012 09:30


Reported: 05/29/2012 18:48




mg/m3mg/m3 ppm(v)ppm(v)Volatiles in Air EPA 18 mod/EPA 25 mod

390 30 271-43-2 07090 1Benzene 190 40 2106-97-8 07090 0.6Butane 39,800 15,000 2n.a. 07090 4C1-C10 Hydrocarbons as methane 17,900 12,000 2n.a. 07090 2C2-C10 Hydrocarbons as methane 0.2N.D. N.D. 274-84-0 07090 0.2Ethane 310 3 2100-41-4 07090 0.8Ethylbenzene 1300 100 2110-54-3 07090 0.4Hexane 302,300 3,600 4074-82-8 07090 40Methane 2420 140 2109-66-0 07090 0.6Pentane 0.71 J 0.6 J 274-98-6 07090 0.4Propane 620 6 2108-88-3 07090 2Toluene 6100 20 21330-20-7 07090 1Xylene (total)






Analyst


2Florida A Cimino05/22/2012 17:30 M121441ZA1EPA 18 mod/EPA 25 mod

BTEX plus Aliphatics 07090



of 1


Sample Description: SVE COMBINED INFLUENT Composite Air S2010L4647 Greenpoint, NY Summa #1022 XOM Brooklyn Terminal Project Name: Greenpoint Project

Collected: 05/08/2012 13:35 by BC

Submitted: 05/22/2012 09:30


Reported: 05/29/2012 18:48


through 05/08/2012 14:35



mg/m3mg/m3 ppm(v)ppm(v)Volatiles in Air EPA 18 mod/EPA 25 mod

330 10 271-43-2 07090 1Benzene 140 20 2106-97-8 07090 0.6Butane 33,700 5,700 2n.a. 07090 4C1-C10 Hydrocarbons as methane 12,700 4,100 2n.a. 07090 2C2-C10 Hydrocarbons as methane 0.2N.D. N.D. 274-84-0 07090 0.2Ethane 3N.D. N.D. 2100-41-4 07090 0.8Ethylbenzene 1100 40 2110-54-3 07090 0.4Hexane 101,100 1,700 2074-82-8 07090 20Methane 2200 60 2109-66-0 07090 0.6Pentane 0.7N.D. N.D. 274-98-6 07090 0.4Propane 6N.D. N.D. 2108-88-3 07090 2Toluene 6N.D. N.D. 21330-20-7 07090 1Xylene (total)






Analyst






of 2


Sample Description: FLAME OX EFFLUENT Composite Air S2010L4647 Greenpoint, NY Summa #516 XOM Brooklyn Terminal Project Name: Greenpoint Project

Collected: 05/08/2012 17:48 by BC

Submitted: 05/22/2012 09:30


Reported: 05/29/2012 18:48


through 05/08/2012 18:48



ppb(v)ppb(v) ug/m3ug/m3Volatiles in Air EPA TO-15 5.096 230 1067-64-1 05298 12Acetone 2.06.1 J 19 J 1071-43-2 05298 6.4Benzene 5.0N.D. N.D. 10100-44-7 05298 26Benzyl chloride


2.0N.D. N.D. 1075-27-4 05298 13Bromodichloromethane 5.0N.D. N.D. 10593-60-2 05298 22Bromoethene 2.0N.D. N.D. 1075-25-2 05298 21Bromoform 2.0N.D. N.D. 1074-83-9 05298 7.8Bromomethane 5.0N.D. N.D. 10106-99-0 05298 111,3-Butadiene 5.07.4 J 22 J 1075-65-0 05298 15tert-Butyl Alcohol 5.0N.D. N.D. 1075-15-0 05298 16Carbon Disulfide 2.0N.D. N.D. 1056-23-5 05298 13Carbon Tetrachloride 2.0N.D. N.D. 10108-90-7 05298 9.2Chlorobenzene 2.017 44 1075-00-3 05298 5.3Chloroethane 2.0N.D. N.D. 1067-66-3 05298 9.8Chloroform 2.018 38 1074-87-3 05298 4.1Chloromethane 2.0N.D. N.D. 10107-05-1 05298 6.33-Chloropropene 2.0N.D. N.D. 1095-49-8 05298 102-Chlorotoluene 2.045 160 10110-82-7 05298 6.9Cyclohexane 2.0N.D. N.D. 10124-48-1 05298 17Dibromochloromethane 2.0N.D. N.D. 10106-93-4 05298 151,2-Dibromoethane 2.0N.D. N.D. 10541-73-1 05298 12m-Dichlorobenzene 2.0N.D. N.D. 1095-50-1 05298 12o-Dichlorobenzene 2.0N.D. N.D. 10106-46-7 05298 12p-Dichlorobenzene 2.0N.D. N.D. 1075-71-8 05298 9.9Dichlorodifluoromethane 2.0N.D. N.D. 1075-34-3 05298 8.11,1-Dichloroethane 2.02.6 J 11 J 10107-06-2 05298 8.11,2-Dichloroethane 2.0N.D. N.D. 1075-35-4 05298 7.91,1-Dichloroethene 2.03.7 J 15 J 10156-59-2 05298 7.9cis-1,2-Dichloroethene 2.0N.D. N.D. 10156-60-5 05298 7.9trans-1,2-Dichloroethene 2.0N.D. N.D. 1078-87-5 05298 9.21,2-Dichloropropane 2.0N.D. N.D. 1010061-01-505298 9.1cis-1,3-Dichloropropene 2.0N.D. N.D. 1010061-02-605298 9.1trans-1,3-Dichloropropene 5.0N.D. N.D. 10123-91-1 05298 181,4-Dioxane 5.07.3 J 14 J 1064-17-5 05298 9.4Ethanol


5.0N.D. N.D. 10141-78-6 05298 18Ethyl Acetate 2.0N.D. N.D. 10100-41-4 05298 8.7Ethylbenzene 2.0N.D. N.D. 10622-96-8 05298 9.84-Ethyltoluene 5.0N.D. N.D. 1076-13-1 05298 38Freon 113 2.0N.D. N.D. 1076-14-2 05298 14Freon 114 2.042 170 10142-82-5 05298 8.2Heptane 5.0N.D. N.D. 1087-68-3 05298 53Hexachlorobutadiene 2.0250 880 10110-54-3 05298 7.0Hexane 5.0N.D. N.D. 10591-78-6 05298 202-Hexanone 5.0N.D. N.D. 1067-63-0 05298 12Isopropyl Alcohol 5.0N.D. N.D. 1078-93-3 05298 15Methyl Ethyl Ketone 5.0N.D. N.D. 10108-10-1 05298 20Methyl Isobutyl Ketone 2.0N.D. N.D. 1080-62-6 05298 8.2Methyl Methacrylate

of 2


Sample Description: FLAME OX EFFLUENT Composite Air S2010L4647 Greenpoint, NY Summa #516 XOM Brooklyn Terminal Project Name: Greenpoint Project

Collected: 05/08/2012 17:48 by BC

Submitted: 05/22/2012 09:30


Reported: 05/29/2012 18:48


through 05/08/2012 18:48



ppb(v)ppb(v) ug/m3ug/m3Volatiles in Air EPA TO-15 2.0N.D. N.D. 101634-04-4 05298 7.2Methyl t-Butyl Ether 2.015 52 1075-09-2 05298 6.9Methylene Chloride 2.017 29 10115-07-1 05298 3.4Propene 2.0N.D. N.D. 10100-42-5 05298 8.5Styrene 2.0N.D. N.D. 1079-34-5 05298 141,1,2,2-Tetrachloroethane 2.0270 1,800 10127-18-4 05298 14Tetrachloroethene 2.08.7 J 26 J 10109-99-9 05298 5.9Tetrahydrofuran 2.0N.D. N.D. 10108-88-3 05298 7.5Toluene 5.0N.D. N.D. 10120-82-1 05298 371,2,4-Trichlorobenzene 2.0N.D. N.D. 1071-55-6 05298 111,1,1-Trichloroethane 2.0N.D. N.D. 1079-00-5 05298 111,1,2-Trichloroethane 2.036 190 1079-01-6 05298 11Trichloroethene 2.0N.D. N.D. 1075-69-4 05298 11Trichlorofluoromethane 2.03.5 J 16 J 10540-84-1 05298 9.32,2,4-Trimethyl Pentane 2.0N.D. N.D. 1095-63-6 05298 9.81,2,4-Trimethylbenzene 2.0N.D. N.D. 10108-67-8 05298 9.81,3,5-Trimethylbenzene 5.0N.D. N.D. 10108-05-4 05298 18Vinyl Acetate 2.0N.D. N.D. 1075-01-4 05298 5.1Vinyl Chloride 2.0N.D. N.D. 10179601-23-105298 8.7m/p-Xylene 2.0N.D. N.D. 1095-47-6 05298 8.7o-Xylene 2.0N.D. N.D. 101330-20-7 05298 8.7Xylene (total)

Reporting limits were raised due to interference from the sample matrix.






Analyst


10Michael A Ziegler05/24/2012 10:22 C1214330AB1EPA TO-15 TO 15 VOA Ext. List 05298

of 3





Blank Blank Report LCS LCSD LCS/LCSD Analysis Name Result MDL Units %REC %REC Limits RPD RPD Max Batch number: C1214330AB Sample number(s): 6660446,6660449 Acetone N.D. 1.2 ug/m3 114 114 67-138 0 25 Benzene N.D. 0.64 ug/m3 99 97 70-130 2 25 Benzyl chloride N.D. 2.6 ug/m3 67* 67* 70-130 1 25 Bromodichloromethane N.D. 1.3 ug/m3 105 103 70-138 2 25 Bromoethene N.D. 2.2 ug/m3 Bromoform N.D. 2.1 ug/m3 115 115 71-150 1 25 Bromomethane N.D. 0.78 ug/m3 91 91 70-130 0 25 1,3-Butadiene N.D. 1.1 ug/m3 89 90 60-135 1 25 tert-Butyl Alcohol N.D. 1.5 ug/m3 Carbon Disulfide N.D. 1.6 ug/m3 71 72 56-106 1 25 Carbon Tetrachloride N.D. 1.3 ug/m3 99 100 70-130 1 25 Chlorobenzene N.D. 0.92 ug/m3 97 98 70-130 1 25 Chloroethane N.D. 0.53 ug/m3 93 94 71-129 0 25 Chloroform N.D. 0.98 ug/m3 95 95 70-130 0 25 Chloromethane N.D. 0.41 ug/m3 95 97 58-129 2 25 3-Chloropropene N.D. 0.63 ug/m3 2-Chlorotoluene N.D. 1.0 ug/m3 Cyclohexane N.D. 0.69 ug/m3 86 87 61-122 1 25 Dibromochloromethane N.D. 1.7 ug/m3 104 104 68-138 0 25 1,2-Dibromoethane N.D. 1.5 ug/m3 105 106 71-135 1 25 m-Dichlorobenzene N.D. 1.2 ug/m3 100 102 68-136 2 25 o-Dichlorobenzene N.D. 1.2 ug/m3 103 104 71-143 1 25 p-Dichlorobenzene N.D. 1.2 ug/m3 102 103 67-140 1 25 Dichlorodifluoromethane N.D. 0.99 ug/m3 95 98 72-140 2 25 1,1-Dichloroethane N.D. 0.81 ug/m3 99 97 66-126 2 25 1,2-Dichloroethane N.D. 0.81 ug/m3 107 107 70-130 0 25 1,1-Dichloroethene N.D. 0.79 ug/m3 84 86 64-117 2 25 cis-1,2-Dichloroethene N.D. 0.79 ug/m3 96 95 69-120 1 25 trans-1,2-Dichloroethene N.D. 0.79 ug/m3 94 95 67-121 1 25 1,2-Dichloropropane N.D. 0.92 ug/m3 97 95 70-130 2 25 cis-1,3-Dichloropropene N.D. 0.91 ug/m3 97 96 67-134 1 25 trans-1,3-Dichloropropene N.D. 0.91 ug/m3 103 103 67-134 0 25 1,4-Dioxane N.D. 1.8 ug/m3 63 94 45-182 39* 25 Ethanol N.D. 0.94 ug/m3 155* 157* 70-130 2 25 Ethyl Acetate N.D. 1.8 ug/m3 90 91 63-130 1 25 Ethylbenzene N.D. 0.87 ug/m3 102 103 70-130 0 25 4-Ethyltoluene N.D. 0.98 ug/m3 98 99 69-135 1 25

of 3



Blank Blank Report LCS LCSD LCS/LCSD Analysis Name Result MDL Units %REC %REC Limits RPD RPD Max Freon 113 N.D. 3.8 ug/m3 86 86 67-115 0 25 Freon 114 N.D. 1.4 ug/m3 83 84 66-120 1 25 Heptane N.D. 0.82 ug/m3 105 104 60-125 0 25 Hexachlorobutadiene N.D. 5.3 ug/m3 105 107 54-155 2 25 Hexane N.D. 0.70 ug/m3 91 90 62-120 1 25 2-Hexanone N.D. 2.0 ug/m3 114 115 54-166 1 25 Isopropyl Alcohol N.D. 1.2 ug/m3 98 108 70-130 10 25 Methyl Ethyl Ketone N.D. 1.5 ug/m3 96 95 66-129 1 25 Methyl Isobutyl Ketone N.D. 2.0 ug/m3 110 109 61-145 1 25 Methyl Methacrylate N.D. 0.82 ug/m3 100 98 66-139 2 25 Methyl t-Butyl Ether N.D. 0.72 ug/m3 93 91 64-124 2 25 Methylene Chloride N.D. 0.69 ug/m3 88 87 70-130 0 25 Propene N.D. 0.34 ug/m3 82 88 47-117 6 25 Styrene N.D. 0.85 ug/m3 103 102 70-139 1 25 1,1,2,2-Tetrachloroethane N.D. 1.4 ug/m3 122 121 67-145 1 25 Tetrachloroethene N.D. 1.4 ug/m3 92 93 70-130 1 25 Tetrahydrofuran N.D. 0.59 ug/m3 103 107 56-140 4 25 Toluene N.D. 0.75 ug/m3 102 102 70-130 0 25 1,2,4-Trichlorobenzene N.D. 3.7 ug/m3 111 113 45-182 2 25 1,1,1-Trichloroethane N.D. 1.1 ug/m3 98 97 70-130 0 25 1,1,2-Trichloroethane N.D. 1.1 ug/m3 112 112 68-128 0 25 Trichloroethene N.D. 1.1 ug/m3 89 88 70-130 0 25 Trichlorofluoromethane N.D. 1.1 ug/m3 95 98 70-130 3 25 2,2,4-Trimethyl Pentane N.D. 0.93 ug/m3 1,2,4-Trimethylbenzene N.D. 0.98 ug/m3 101 102 69-138 1 25 1,3,5-Trimethylbenzene N.D. 0.98 ug/m3 102 103 71-142 1 25 Vinyl Acetate N.D. 1.8 ug/m3 117 113 61-150 4 25 Vinyl Chloride N.D. 0.51 ug/m3 97 98 70-130 1 25 m/p-Xylene N.D. 0.87 ug/m3 105 105 70-130 0 25 o-Xylene N.D. 0.87 ug/m3 106 106 70-130 0 25 Xylene (total) N.D. 0.87 ug/m3 105 105 70-130 0 25 Batch number: M121441ZA Sample number(s): 6660447-6660448 Benzene N.D. 0.8 ppm(v) 94 93 67-111 1 30 Butane N.D. 0.3 ppm(v) C1-C10 Hydrocarbons as methane N.D. 7. ppm(v) C2-C10 Hydrocarbons as methane N.D. 5. ppm(v) Ethane N.D. 0.1 ppm(v) Ethylbenzene N.D. 0.7 ppm(v) 103 102 46-141 1 30 Hexane N.D. 0.2 ppm(v) Methane N.D. 2. ppm(v) Pentane N.D. 0.3 ppm(v) Propane N.D. 0.2 ppm(v) Toluene N.D. 0.8 ppm(v) 82 85 55-120 3 30 Xylene (total) N.D. 0.7 ppm(v) 92 94 46-139 2 30

of 3



Case Narrative


General Comments:








EPA TO-15, Volatiles in AirBatch #: C1214330AB (Sample number(s): 6660446, 6660449)

The recovery(ies) for the following analyte(s) in the LCS and/or LCSD exceeded the acceptance window indicating a positive bias: Ethanol

The recovery(ies) for the following analyte(s) in the LCS and/or LCSD were below the acceptance window: Benzyl Chloride

The relative percent difference(s) for the following analyte(s) in the LCS/LCSD were outside acceptance windows: 1,4-Dioxane

Sample #s: 6660446, 6660449Reporting limits were raised due to interference from the sample matrix.

v 1.8.8 5/29/2012 6:50:32PM




> greater than













3768.08

ANALYTICAL RESULTS

Prepared by:



Prepared for:


Brooklyn NY 11222

June 13, 2012




Client Sample Description Lancaster Labs (LLI) # RCS-Influent Grab Water 6672205 RCS-Effluent Grab Water 6672206 QAQC_TB Water 6672207 The specific methodologies used in obtaining the enclosed analytical results are indicated on the Laboratory Sample Analysis Record. ELECTRONIC COPY TO



(717) 556-7250

of 4



Collected: 05/30/2012 11:32 by MS

Submitted: 05/31/2012 09:45


Reported: 06/13/2012 13:25


RCSIN As Received Limit of Quantitation



CAT No.





ug/l ug/lug/lGC/MS Semivolatiles EPA 6255 J 183-32-9 10334 0.3 5 Acenaphthene N.D. 1208-96-8 10334 0.3 5 Acenaphthylene N.D. 1120-12-7 10334 0.2 5 Anthracene N.D. 192-87-5 10334 19 57 Benzidine 0.2 J 156-55-3 10334 0.2 5 Benzo(a)anthracene N.D. 150-32-8 10334 0.3 5 Benzo(a)pyrene


of 4



Collected: 05/30/2012 11:32 by MS

Submitted: 05/31/2012 09:45


Reported: 06/13/2012 13:25





CAT No.

ug/l ug/lug/lGC/MS Semivolatiles EPA 625N.D. 1205-99-2 10334 0.3 5 Benzo(b)fluoranthene N.D. 1191-24-2 10334 0.2 5 Benzo(g,h,i)perylene N.D. 1207-08-9 10334 0.3 5 Benzo(k)fluoranthene N.D. 1101-55-3 10334 0.3 5 4-Bromophenyl-phenylether N.D. 185-68-7 10334 0.8 5 Butylbenzylphthalate N.D. 184-74-2 10334 0.5 5 Di-n-butylphthalate N.D. 159-50-7 10334 0.3 5 4-Chloro-3-methylphenol N.D. 1106-47-8 10334 0.3 5 4-Chloroaniline N.D. 1111-91-1 10334 0.5 5 bis(2-Chloroethoxy)methane N.D. 1111-44-4 10334 0.4 5 bis(2-Chloroethyl)ether N.D. 139638-32-910334 0.3 5 bis(2-Chloroisopropyl)ether N.D. 191-58-7 10334 0.2 5 2-Chloronaphthalene N.D. 195-57-8 10334 0.3 5 2-Chlorophenol N.D. 17005-72-3 10334 0.3 5 4-Chlorophenyl-phenylether N.D. 1218-01-9 10334 0.2 5 Chrysene N.D. 153-70-3 10334 0.4 5 Dibenz(a,h)anthracene N.D. 195-50-1 10334 0.3 5 1,2-Dichlorobenzene N.D. 1541-73-1 10334 0.3 5 1,3-Dichlorobenzene N.D. 1106-46-7 10334 0.3 5 1,4-Dichlorobenzene N.D. 191-94-1 10334 0.8 5 3,3'-Dichlorobenzidine N.D. 1120-83-2 10334 0.3 5 2,4-Dichlorophenol N.D. 184-66-2 10334 0.3 5 Diethylphthalate N.D. 1105-67-9 10334 0.3 5 2,4-Dimethylphenol N.D. 1131-11-3 10334 0.9 5 Dimethylphthalate N.D. 1534-52-1 10334 4 14 4,6-Dinitro-2-methylphenol N.D. 151-28-5 10334 9 28 2,4-Dinitrophenol N.D. 1121-14-2 10334 0.4 5 2,4-Dinitrotoluene N.D. 1606-20-2 10334 0.3 5 2,6-Dinitrotoluene N.D. 1122-66-7 10334 0.2 5 1,2-Diphenylhydrazine N.D. 1117-81-7 10334 0.9 5 bis(2-Ethylhexyl)phthalate 0.4 J 1206-44-0 10334 0.3 5 Fluoranthene 2 J 186-73-7 10334 0.3 5 Fluorene N.D. 1118-74-1 10334 0.9 5 Hexachlorobenzene N.D. 187-68-3 10334 0.8 5 Hexachlorobutadiene N.D. 177-47-4 10334 2 14 Hexachlorocyclopentadiene N.D. 167-72-1 10334 0.4 5 Hexachloroethane N.D. 1193-39-5 10334 0.3 5 Indeno(1,2,3-cd)pyrene N.D. 178-59-1 10334 0.3 5 Isophorone 3 J 191-20-3 10334 0.2 5 Naphthalene N.D. 198-95-3 10334 0.5 5 Nitrobenzene N.D. 188-75-5 10334 0.4 5 2-Nitrophenol N.D. 1100-02-7 10334 5 9 4-Nitrophenol N.D. 162-75-9 10334 2 5 N-Nitrosodimethylamine N.D. 1621-64-7 10334 0.4 5 N-Nitroso-di-n-propylamine N.D. 186-30-6 10334 0.3 5 N-Nitrosodiphenylamine N.D. 1117-84-0 10334 0.5 5 Di-n-octylphthalate N.D. 187-86-5 10334 3 14 Pentachlorophenol 3 J 185-01-8 10334 0.2 5 Phenanthrene 0.4 J 1108-95-2 10334 0.4 5 Phenol 0.3 J 1129-00-0 10334 0.2 5 Pyrene


of 4



Collected: 05/30/2012 11:32 by MS

Submitted: 05/31/2012 09:45


Reported: 06/13/2012 13:25





CAT No.


The LCS and/or LCSD recoveries are outside the stated QC windowbut within the marginal exceedance allowance of +/- 4 standard deviations as defined in the NELAC Standards. The following analytes are accepted based on this allowance: bis(2-chloroisopropyl)ether The laboratory did not receive sufficient sample volume to perform the method QC requirement for MS/MSD or MS/DUP analysis.









The laboratory did not receive sufficient sample volume to performthe method QC requirement for MS/DUP analysis.



of 4



Collected: 05/30/2012 11:32 by MS

Submitted: 05/31/2012 09:45


Reported: 06/13/2012 13:25


RCSIN





Analyst


1Lauren C Temple06/05/2012 16:13 M121571AA1EPA 624 VOCs by 624 10371 1Daniel H Heller06/04/2012 12:42 D121562AA1SW-846 8260B MTBE Only 8260B Water 10943 1Daniel H Heller06/04/2012 12:42 D121562AA1SW-846 5030B GC/MS VOA Water Prep 01163 1Matthew S Woods06/04/2012 17:04 12153WAB6251EPA 625 Method 625 10334 1David S Schrum06/01/2012 13:00 12153WAB6251EPA 625 625 Water Extraction 08108 1Joanne M Gates06/06/2012 09:19 1215757160011EPA 200.7 rev 4.4 Calcium 01750 1Joanne M Gates06/06/2012 09:19 1215757160011EPA 200.7 rev 4.4 Copper 07053 1Joanne M Gates06/06/2012 09:19 1215757160011EPA 200.7 rev 4.4 Iron 01754 1Joanne M Gates06/06/2012 09:19 1215757160011EPA 200.7 rev 4.4 Manganese 07058 1Damary Valentin06/04/2012 07:26 1215357140011EPA 245.1 rev 3 Mercury 00259 1Annamaria

Stipkovits06/05/2012 22:00 1215757160011EPA 200.7 rev 4.4 EPA 600 ICP Digest (tot

rec) 05716

1Nelli S Markaryan06/01/2012 18:07 1215357140011EPA 245.1 rev 3 PW/WW Hg Digest 05714 500Clinton M Wilson06/07/2012 17:12 12159987121B2EPA 300.0 Chloride 00224 1Venia B McFadden06/06/2012 17:00 12158113101A1EPA 420.4 Phenols (water) 00434 1Nancy J Shoop06/06/2012 09:50 12158113101A1EPA 420.4 Phenol Distillation

(water) 00491

1Yolunder Y Bunch06/11/2012 08:35 12163807901A1EPA 1664A HEM (oil & grease) 08079 1Susan A Engle05/31/2012 12:15 12152027903A1EPA 180.1 (1993) Turbidity 00279 1Susan A Engle06/04/2012 11:45 12156020601A1SM20 2540 D Total Suspended Solids 00206 1Luz M Groff05/31/2012 17:00 12152021501A1SM20 2540 F Settleable Solids 00215 1Susan A Engle06/08/2012 12:45 12160002201A1SM20 4500 H/B pH 12152


of 4



Collected: 05/30/2012 12:15 by MS

Submitted: 05/31/2012 09:45


Reported: 06/13/2012 13:25


RCSEF As Received Limit of Quantitation



CAT No.







of 4



Collected: 05/30/2012 12:15 by MS

Submitted: 05/31/2012 09:45


Reported: 06/13/2012 13:25





CAT No.

ug/l ug/lug/lGC/MS Semivolatiles EPA 625N.D. 1205-99-2 10334 0.3 5 Benzo(b)fluoranthene N.D. 1191-24-2 10334 0.2 5 Benzo(g,h,i)perylene N.D. 1207-08-9 10334 0.3 5 Benzo(k)fluoranthene N.D. 1101-55-3 10334 0.3 5 4-Bromophenyl-phenylether N.D. 185-68-7 10334 0.8 5 Butylbenzylphthalate N.D. 184-74-2 10334 0.5 5 Di-n-butylphthalate N.D. 159-50-7 10334 0.3 5 4-Chloro-3-methylphenol N.D. 1106-47-8 10334 0.3 5 4-Chloroaniline N.D. 1111-91-1 10334 0.5 5 bis(2-Chloroethoxy)methane N.D. 1111-44-4 10334 0.4 5 bis(2-Chloroethyl)ether N.D. 139638-32-910334 0.3 5 bis(2-Chloroisopropyl)ether N.D. 191-58-7 10334 0.2 5 2-Chloronaphthalene N.D. 195-57-8 10334 0.3 5 2-Chlorophenol N.D. 17005-72-3 10334 0.3 5 4-Chlorophenyl-phenylether N.D. 1218-01-9 10334 0.2 5 Chrysene N.D. 153-70-3 10334 0.4 5 Dibenz(a,h)anthracene N.D. 195-50-1 10334 0.3 5 1,2-Dichlorobenzene N.D. 1541-73-1 10334 0.3 5 1,3-Dichlorobenzene N.D. 1106-46-7 10334 0.3 5 1,4-Dichlorobenzene N.D. 191-94-1 10334 0.8 5 3,3'-Dichlorobenzidine N.D. 1120-83-2 10334 0.3 5 2,4-Dichlorophenol N.D. 184-66-2 10334 0.3 5 Diethylphthalate N.D. 1105-67-9 10334 0.3 5 2,4-Dimethylphenol N.D. 1131-11-3 10334 1 5 Dimethylphthalate N.D. 1534-52-1 10334 4 15 4,6-Dinitro-2-methylphenol N.D. 151-28-5 10334 10 30 2,4-Dinitrophenol N.D. 1121-14-2 10334 0.4 5 2,4-Dinitrotoluene N.D. 1606-20-2 10334 0.3 5 2,6-Dinitrotoluene N.D. 1122-66-7 10334 0.2 5 1,2-Diphenylhydrazine N.D. 1117-81-7 10334 1 5 bis(2-Ethylhexyl)phthalate 0.4 J 1206-44-0 10334 0.3 5 Fluoranthene 2 J 186-73-7 10334 0.3 5 Fluorene N.D. 1118-74-1 10334 1 5 Hexachlorobenzene N.D. 187-68-3 10334 0.8 5 Hexachlorobutadiene N.D. 177-47-4 10334 2 15 Hexachlorocyclopentadiene N.D. 167-72-1 10334 0.4 5 Hexachloroethane N.D. 1193-39-5 10334 0.3 5 Indeno(1,2,3-cd)pyrene N.D. 178-59-1 10334 0.3 5 Isophorone 1 J 191-20-3 10334 0.2 5 Naphthalene N.D. 198-95-3 10334 0.5 5 Nitrobenzene N.D. 188-75-5 10334 0.4 5 2-Nitrophenol N.D. 1100-02-7 10334 5 10 4-Nitrophenol N.D. 162-75-9 10334 2 5 N-Nitrosodimethylamine N.D. 1621-64-7 10334 0.4 5 N-Nitroso-di-n-propylamine N.D. 186-30-6 10334 0.3 5 N-Nitrosodiphenylamine N.D. 1117-84-0 10334 0.5 5 Di-n-octylphthalate N.D. 187-86-5 10334 3 15 Pentachlorophenol 4 J 185-01-8 10334 0.2 5 Phenanthrene N.D. 1108-95-2 10334 0.4 5 Phenol 0.4 J 1129-00-0 10334 0.2 5 Pyrene


of 4



Collected: 05/30/2012 12:15 by MS

Submitted: 05/31/2012 09:45


Reported: 06/13/2012 13:25





CAT No.


The LCS and/or LCSD recoveries are outside the stated QC windowbut within the marginal exceedance allowance of +/- 4 standard deviations as defined in the NELAC Standards. The following analytes are accepted based on this allowance: bis(2-chloroisopropyl)ether The laboratory did not receive sufficient sample volume to perform the method QC requirement for MS/MSD or MS/DUP analysis.












of 4



Collected: 05/30/2012 12:15 by MS

Submitted: 05/31/2012 09:45


Reported: 06/13/2012 13:25


RCSEF





Analyst


1Lauren C Temple06/05/2012 16:39 M121571AA1EPA 624 VOCs by 624 10371 1Daniel H Heller06/04/2012 13:51 D121562AA1SW-846 8260B MTBE Only 8260B Water 10943 1Daniel H Heller06/04/2012 13:51 D121562AA1SW-846 5030B GC/MS VOA Water Prep 01163 1Matthew S Woods06/04/2012 17:35 12153WAB6251EPA 625 Method 625 10334 1David S Schrum06/01/2012 13:00 12153WAB6251EPA 625 625 Water Extraction 08108 1Joanne M Gates06/06/2012 09:23 1215757160011EPA 200.7 rev 4.4 Calcium 01750 1Joanne M Gates06/06/2012 09:23 1215757160011EPA 200.7 rev 4.4 Copper 07053 1Joanne M Gates06/06/2012 09:23 1215757160011EPA 200.7 rev 4.4 Iron 01754 1Joanne M Gates06/06/2012 09:23 1215757160011EPA 200.7 rev 4.4 Manganese 07058 1Damary Valentin06/04/2012 07:28 1215357140011EPA 245.1 rev 3 Mercury 00259 1Annamaria


rec) 05716


(water) 00491

1Yolunder Y Bunch06/11/2012 08:35 12163807901A1EPA 1664A HEM (oil & grease) 08079 1Susan A Engle05/31/2012 12:15 12152027903A1EPA 180.1 (1993) Turbidity 00279 1Susan A Engle06/04/2012 11:45 12156020601A1SM20 2540 D Total Suspended Solids 00206 1Luz M Groff05/31/2012 17:00 12152021501A1SM20 2540 F Settleable Solids 00215 1Susan A Engle06/08/2012 12:53 12160002201A1SM20 4500 H/B pH 12152


of 2




Submitted: 05/31/2012 09:45


Reported: 06/13/2012 13:25


RCSTB As Received Limit of Quantitation



CAT No.







of 2




Submitted: 05/31/2012 09:45


Reported: 06/13/2012 13:25


RCSTB




Analyst


1Lauren C Temple06/05/2012 17:05 M121571AA1EPA 624 VOCs by 624 10371 1Daniel H Heller06/04/2012 12:19 D121562AA1SW-846 8260B MTBE Only 8260B Water 10943 1Daniel H Heller06/04/2012 12:19 D121562AA1SW-846 5030B GC/MS VOA Water Prep 01163


of 6





Blank Blank Blank Report LCS LCSD LCS/LCSD Analysis Name Result MDL** LOQ Units %REC %REC Limits RPD RPD Max Batch number: D121562AA Sample number(s): 6672205-6672207 Methyl Tertiary Butyl Ether N.D. 0.5 1 ug/l 93 68-121 Batch number: M121571AA Sample number(s): 6672205-6672207 Acrolein N.D. 10. 50 ug/l 71 53-126 Acrylonitrile N.D. 10. 50 ug/l 73 61-120 Benzene N.D. 0.9 5 ug/l 94 80-121 Bromodichloromethane N.D. 0.7 5 ug/l 92 76-123 Bromoform N.D. 0.8 5 ug/l 93 65-136 Bromomethane N.D. 2. 5 ug/l 82 55-122 Carbon Tetrachloride N.D. 1. 5 ug/l 96 72-128 Chlorobenzene N.D. 0.8 5 ug/l 100 79-120 Chloroethane N.D. 2. 5 ug/l 79 54-121 2-Chloroethyl Vinyl Ether N.D. 2. 10 ug/l 87 47-128 Chloroform N.D. 1. 5 ug/l 92 79-122 Chloromethane N.D. 2. 5 ug/l 83 63-135 Dibromochloromethane N.D. 1. 5 ug/l 97 74-121 1,2-Dichlorobenzene N.D. 1. 5 ug/l 100 78-125 1,3-Dichlorobenzene N.D. 1. 5 ug/l 100 78-124 1,4-Dichlorobenzene N.D. 1. 5 ug/l 99 78-124 Dichlorodifluoromethane N.D. 2. 5 ug/l 89 48-120 1,1-Dichloroethane N.D. 1. 5 ug/l 90 75-130 1,2-Dichloroethane N.D. 1. 5 ug/l 94 72-138 1,1-Dichloroethene N.D. 0.9 5 ug/l 92 71-136 cis-1,2-Dichloroethene N.D. 1. 5 ug/l 92 73-130 trans-1,2-Dichloroethene N.D. 1. 5 ug/l 93 73-131 1,2-Dichloropropane N.D. 1. 5 ug/l 93 78-121 cis-1,3-Dichloropropene N.D. 1. 5 ug/l 98 79-120 trans-1,3-Dichloropropene N.D. 0.6 5 ug/l 91 74-120 Ethylbenzene N.D. 0.8 5 ug/l 100 80-120 Methylene Chloride N.D. 2. 5 ug/l 89 71-132 1,1,2,2-Tetrachloroethane N.D. 1. 5 ug/l 91 75-121 Tetrachloroethene N.D. 1. 5 ug/l 109 77-127 Toluene N.D. 0.8 5 ug/l 102 80-120 1,1,1-Trichloroethane N.D. 1. 5 ug/l 94 74-127 1,1,2-Trichloroethane N.D. 1. 5 ug/l 99 80-120 Trichloroethene N.D. 1. 5 ug/l 96 80-120 Trichlorofluoromethane N.D. 2. 5 ug/l 96 55-136

of 6



Blank Blank Blank Report LCS LCSD LCS/LCSD Analysis Name Result MDL** LOQ Units %REC %REC Limits RPD RPD Max Vinyl Chloride N.D. 2. 5 ug/l 87 56-121 Xylene (total) N.D. 0.9 5 ug/l 103 80-120 Batch number: 12153WAB625 Sample number(s): 6672205-6672206 Acenaphthene N.D. 0.3 5 ug/l 99 100 75-117 1 30 Acenaphthylene N.D. 0.3 5 ug/l 102 98 75-122 4 30 Anthracene N.D. 0.2 5 ug/l 90 95 75-116 6 30 Benzidine N.D. 20. 60 ug/l 54 49 16-104 10 30 Benzo(a)anthracene N.D. 0.2 5 ug/l 105 103 76-117 2 30 Benzo(a)pyrene N.D. 0.3 5 ug/l 98 103 69-143 5 30 Benzo(b)fluoranthene N.D. 0.3 5 ug/l 101 97 64-145 3 30 Benzo(g,h,i)perylene N.D. 0.2 5 ug/l 101 100 66-145 1 30 Benzo(k)fluoranthene N.D. 0.3 5 ug/l 92 92 66-145 0 30 4-Bromophenyl-phenylether N.D. 0.3 5 ug/l 99 101 80-112 2 30 Butylbenzylphthalate N.D. 0.8 5 ug/l 99 104 80-125 5 30 Di-n-butylphthalate N.D. 0.5 5 ug/l 94 96 76-120 2 30 4-Chloro-3-methylphenol N.D. 0.3 5 ug/l 112 107 75-113 4 30 4-Chloroaniline N.D. 0.3 5 ug/l 102 90 10-124 12 30 bis(2-Chloroethoxy)methane N.D. 0.5 5 ug/l 114 112 69-128 1 30 bis(2-Chloroethyl)ether N.D. 0.4 5 ug/l 96 101 72-114 5 30 bis(2-Chloroisopropyl)ether N.D. 0.3 5 ug/l 85* 88 87-134 4 30 2-Chloronaphthalene N.D. 0.2 5 ug/l 97 79 57-112 21 30 2-Chlorophenol N.D. 0.3 5 ug/l 88 93 78-118 5 30 4-Chlorophenyl-phenylether N.D. 0.3 5 ug/l 102 106 76-115 4 30 Chrysene N.D. 0.2 5 ug/l 92 93 81-118 1 30 Dibenz(a,h)anthracene N.D. 0.4 5 ug/l 99 100 68-144 1 30 1,2-Dichlorobenzene N.D. 0.3 5 ug/l 90 96 73-111 7 30 1,3-Dichlorobenzene N.D. 0.3 5 ug/l 89 99 67-110 10 30 1,4-Dichlorobenzene N.D. 0.3 5 ug/l 90 97 68-111 7 30 3,3'-Dichlorobenzidine N.D. 0.8 5 ug/l 91 78 33-124 16 30 2,4-Dichlorophenol N.D. 0.3 5 ug/l 105 106 72-127 1 30 Diethylphthalate N.D. 0.3 5 ug/l 102 98 74-120 4 30 2,4-Dimethylphenol N.D. 0.3 5 ug/l 99 102 70-123 3 30 Dimethylphthalate N.D. 1. 5 ug/l 94 92 30-112 3 30 4,6-Dinitro-2-methylphenol N.D. 4. 15 ug/l 86 85 65-120 1 30 2,4-Dinitrophenol N.D. 10. 30 ug/l 92 85 64-140 7 30 2,4-Dinitrotoluene N.D. 0.4 5 ug/l 105 104 74-121 1 30 2,6-Dinitrotoluene N.D. 0.3 5 ug/l 108 104 80-115 4 30 1,2-Diphenylhydrazine N.D. 0.2 5 ug/l 88 89 75-114 0 30 bis(2-Ethylhexyl)phthalate N.D. 1. 5 ug/l 106 107 74-118 1 30 Fluoranthene N.D. 0.3 5 ug/l 90 92 86-119 2 30 Fluorene N.D. 0.3 5 ug/l 106 107 74-117 0 30 Hexachlorobenzene N.D. 1. 5 ug/l 88 87 75-114 1 30 Hexachlorobutadiene N.D. 0.8 5 ug/l 105 104 58-116 1 30 Hexachlorocyclopentadiene N.D. 2. 15 ug/l 93 82 38-133 12 30 Hexachloroethane N.D. 0.4 5 ug/l 86 92 61-113 7 30 Indeno(1,2,3-cd)pyrene N.D. 0.3 5 ug/l 103 103 67-143 0 30 Isophorone N.D. 0.3 5 ug/l 109 104 75-123 5 30 Naphthalene N.D. 0.2 5 ug/l 99 99 73-118 0 30 Nitrobenzene N.D. 0.5 5 ug/l 95 96 74-121 1 30

of 6



Blank Blank Blank Report LCS LCSD LCS/LCSD Analysis Name Result MDL** LOQ Units %REC %REC Limits RPD RPD Max 2-Nitrophenol N.D. 0.4 5 ug/l 97 102 77-120 4 30 4-Nitrophenol N.D. 5. 10 ug/l 53 54 27-80 1 30 N-Nitroso-di-n-propylamine N.D. 0.4 5 ug/l 96 100 68-114 4 30 N-Nitrosodimethylamine N.D. 2. 5 ug/l 62 63 44-81 2 30 N-Nitrosodiphenylamine N.D. 0.3 5 ug/l 93 92 84-135 1 30 Di-n-octylphthalate N.D. 0.5 5 ug/l 98 102 65-155 4 30 Pentachlorophenol N.D. 3. 15 ug/l 103 106 55-137 2 30 Phenanthrene N.D. 0.2 5 ug/l 89 93 77-113 5 30 Phenol N.D. 0.4 5 ug/l 47 53 26-71 12 30 Pyrene N.D. 0.2 5 ug/l 93 96 76-115 4 30 1,2,4-Trichlorobenzene N.D. 0.3 5 ug/l 97 99 70-119 2 30 2,4,6-Trichlorophenol N.D. 0.7 5 ug/l 104 99 83-120 5 30 Batch number: 121535714001 Sample number(s): 6672205-6672206 Mercury N.D. 0.026 0.20 ug/l 105 85-115 Batch number: 121575716001 Sample number(s): 6672205-6672206 Calcium N.D. 70.5 200 ug/l 99 90-110 Copper N.D. 0.94 10.0 ug/l 101 90-110 Iron N.D. 14.1 200 ug/l 101 90-110 Manganese N.D. 0.44 5.0 ug/l 102 85-115 Batch number: 12158113101A Sample number(s): 6672205-6672206 Phenols (water) N.D. 15. 40 ug/l 98 90-110 Batch number: 12159987121B Sample number(s): 6672205-6672206 Chloride N.D. 200. 400 ug/l 100 90-110 Batch number: 12152021501A Sample number(s): 6672205-6672206 Settleable Solids N.D. 0.10 0.10 ml/l/hr Batch number: 12152027903A Sample number(s): 6672205-6672206 Turbidity 0.12 J 0.090 0.30 N T U 99 90-110 Batch number: 12156020601A Sample number(s): 6672205-6672206 Total Suspended Solids N.D. 3,000. 12,000 ug/l 92 79-107 Batch number: 12160002201A Sample number(s): 6672205-6672206 pH 101 99-103 Batch number: 12163807901A Sample number(s): 6672205-6672206 HEM (oil & grease) 1,600

J 1,400. 5,000 ug/l 90 78 78-114 14 16


of 6



Unspiked (UNSPK) = the sample used in conjunction with the matrix spike Background (BKG) = the sample used in conjunction with the duplicate MS MSD MS/MSD RPD BKG DUP DUP Dup RPD Analysis Name %REC %REC Limits RPD MAX Conc Conc RPD Max___ Batch number: D121562AA Sample number(s): 6672205-6672207 UNSPK: 6672205 Methyl Tertiary Butyl Ether 87 78 72-126 5 30 Batch number: M121571AA Sample number(s): 6672205-6672207 UNSPK: P671833 Acrolein 73 73 40-128 0 30 Acrylonitrile 74 74 58-124 0 30 Benzene 93 89 83-132 2 30 Bromodichloromethane 101 97 78-128 4 30 Bromoform 97 96 59-129 1 30 Bromomethane 97 92 52-134 5 30 Carbon Tetrachloride 111 112 76-147 1 30 Chlorobenzene 103 103 82-121 0 30 Chloroethane 91 88 50-140 3 30 2-Chloroethyl Vinyl Ether 0* 0* 10-172 0 30 Chloroform 101 99 82-132 2 30 Chloromethane 99 101 50-140 1 30 Dibromochloromethane 100 100 72-128 0 30 1,2-Dichlorobenzene 104 104 79-126 1 30 1,3-Dichlorobenzene 104 102 79-126 1 30 1,4-Dichlorobenzene 106 104 79-126 2 30 Dichlorodifluoromethane 109 111 42-132 1 30 1,1-Dichloroethane 98 94 79-141 4 30 1,2-Dichloroethane 104 101 65-146 3 30 1,1-Dichloroethene 104 106 75-153 2 30 cis-1,2-Dichloroethene 96 95 81-134 1 30 trans-1,2-Dichloroethene 101 99 74-144 2 30 1,2-Dichloropropane 98 95 77-130 3 30 cis-1,3-Dichloropropene 99 98 74-113 2 30 trans-1,3-Dichloropropene 103 98 69-116 5 30 Ethylbenzene 107 104 82-124 3 30 Methylene Chloride 94 95 65-148 2 30 1,1,2,2-Tetrachloroethane 94 92 73-121 1 30 Tetrachloroethene 108 110 78-136 1 30 Toluene 108 105 84-123 3 30 1,1,1-Trichloroethane 105 106 83-137 1 30 1,1,2-Trichloroethane 100 95 85-121 4 30 Trichloroethene 107 104 86-131 3 30 Trichlorofluoromethane 116 117 62-152 1 30 Vinyl Chloride 104 104 60-137 0 30 Xylene (total) 109 107 79-130 2 30 Batch number: 121535714001 Sample number(s): 6672205-6672206 UNSPK: P671150 BKG: P671150 Mercury 108 80-120 N.D. 0.027 J 200* (1) 20 Batch number: 121575716001 Sample number(s): 6672205-6672206 UNSPK: P676002 BKG: P676002 Calcium 1185 81-118 4,470,000 4,400,000 2 20

of 6




Unspiked (UNSPK) = the sample used in conjunction with the matrix spike Background (BKG) = the sample used in conjunction with the duplicate MS MSD MS/MSD RPD BKG DUP DUP Dup RPD Analysis Name %REC %REC Limits RPD MAX Conc Conc RPD Max___

(2) Copper 111 86-122 N.D. N.D. 0 (1) 20 Iron 90 70-130 276 262 5 (1) 20 Manganese 91 70-130 180 175 3 20 Batch number: 12158113101A Sample number(s): 6672205-6672206 UNSPK: P671150 Phenols (water) 95 94 90-110 1 6 Batch number: 12159987121B Sample number(s): 6672205-6672206 UNSPK: P671150 BKG: P671150 Chloride 111* 90-110 720,000 732,000 2 (1) 20 Batch number: 12152027903A Sample number(s): 6672205-6672206 BKG: P672176 Turbidity 3.9 5.0 24* 3 Batch number: 12156020601A Sample number(s): 6672205-6672206 BKG: P672678 Total Suspended Solids 814,000 790,000 3 20 Batch number: 12160002201A Sample number(s): 6672205-6672206 BKG: 6672205 pH 7.5 7.5 0 3


Surrogate recoveries which are outside of the QC window are confirmed unless attributed to dilution or otherwise noted on the Analysis Report. Analysis Name: BTEX + MTBE 8260B Water Batch number: D121562AA Dibromofluoromethane 1,2-Dichloroethane-d4 Toluene-d8 4-Bromofluorobenzene ________________________________________________________________________________________________________________ 6672205 96 91 101 107 6672206 99 99 101 102 6672207 101 95 101 99 Blank 100 99 101 97 LCS 100 98 101 107 MS 94 94 101 109 MSD 96 93 103 111 ________________________________________________________________________________________________________________ Limits: 80-116 77-113 80-113 78-113 Analysis Name: VOCs by 624 Batch number: M121571AA 1,2-Dichloroethane-d4 Fluorobenzene 4-Bromofluorobenzene ________________________________________________________________________________________________________________

of 6




6672205 97 101 103 6672206 97 101 104 6672207 99 98 101 Blank 98 99 101 LCS 99 100 103 MS 100 101 103 MSD 99 103 103 ________________________________________________________________________________________________________________ Limits: 76-114 80-120 86-115 Analysis Name: Method 625 Batch number: 12153WAB625 Nitrobenzene-d5 2-Fluorobiphenyl Terphenyl-d14 Phenol-d6 2-Fluorophenol 2,4,6-Tribromophenol ________________________________________________________________________________________________________________ 6672205 70 73 51* 14 3* 9* 6672206 86 81 55* 8* 3* 11* Blank 86 89 62 46 68 87 LCS 92 87 77 43 60 93 LCSD 91 84 76 47 64 91 ________________________________________________________________________________________________________________ Limits: 56-120 62-121 56-119 10-72 10-114 36-140

Case Narrative


General Comments:








EPA 624, GC/MS VolatilesBatch #: M121571AA (Sample number(s): 6672205-6672207 UNSPK: P671833)


EPA 625, GC/MS SemivolatilesBatch #: 12153WAB625 (Sample number(s): 6672205-6672206)

The recovery(ies) for the following analyte(s) in the LCS and/or LCSD were below the acceptance window: bis(2-Chloroisopropyl)ether

The recovery(ies) for one or more surrogates were outside of the QC window for sample(s) 6672205, 6672206

v 1.8.8 6/13/2012 1:28:17PM

Sample #s: 6672205The LCS and/or LCSD recoveries are outside the stated QC windowbut within the marginal exceedance allowance of +/- 4 standarddeviations as defined in the NELAC Standards. The followinganalytes are accepted based on this allowance:bis(2-chloroisopropyl)etherThe laboratory did not receive sufficient sample volume to perform

the method QC requirement for MS/MSD or MS/DUP analysis.

Sample #s: 6672206The LCS and/or LCSD recoveries are outside the stated QC windowbut within the marginal exceedance allowance of +/- 4 standarddeviations as defined in the NELAC Standards. The followinganalytes are accepted based on this allowance:bis(2-chloroisopropyl)etherThe laboratory did not receive sufficient sample volume to performthe method QC requirement for MS/MSD or MS/DUP analysis.

EPA 200.7 rev 4.4, MetalsBatch #: 121575716001 (Sample number(s): 6672205-6672206 UNSPK: P676002 BKG: P676002)

The recovery(ies) for the following analyte(s) in the MS was outside the acceptance window: Calcium

EPA 245.1 rev 3, MetalsBatch #: 121535714001 (Sample number(s): 6672205-6672206 UNSPK: P671150 BKG: P671150)

The duplicate RPD for the following analyte(s) exceeded the acceptance window: Mercury



EPA 180.1 (1993), Wet ChemistryBatch #: 12152027903A (Sample number(s): 6672205-6672206 BKG: P672176)

The duplicate RPD for the following analyte(s) exceeded the acceptance window: Turbidity


Sample #s: 6672205, 6672206The laboratory did not receive sufficient sample volume to perform

the method QC requirement for MS/DUP analysis.

v 1.8.8 6/13/2012 1:28:17PM




> greater than













3768.08

ANALYTICAL RESULTS

Prepared by:



Prepared for:


Brooklyn NY 11222

June 13, 2012




Client Sample Description Lancaster Labs (LLI) # RCS-Influent Grab Water 6673891 RCS-Effluent Grab Water 6673892 QAQC_TB Water 6673893 The specific methodologies used in obtaining the enclosed analytical results are indicated on the Laboratory Sample Analysis Record. ELECTRONIC COPY TO



(717) 556-7250

of 4



Collected: 05/31/2012 10:30 by MS

Submitted: 06/01/2012 09:25


Reported: 06/13/2012 12:10


IN-RC As Received Limit of Quantitation



CAT No.





ug/l ug/lug/lGC/MS Semivolatiles EPA 6256 183-32-9 10334 0.3 5 Acenaphthene N.D. 1208-96-8 10334 0.3 5 Acenaphthylene 0.3 J 1120-12-7 10334 0.2 5 Anthracene N.D. 192-87-5 10334 19 57 Benzidine N.D. 156-55-3 10334 0.2 5 Benzo(a)anthracene N.D. 150-32-8 10334 0.3 5 Benzo(a)pyrene


of 4



Collected: 05/31/2012 10:30 by MS

Submitted: 06/01/2012 09:25


Reported: 06/13/2012 12:10





CAT No.

ug/l ug/lug/lGC/MS Semivolatiles EPA 625N.D. 1205-99-2 10334 0.3 5 Benzo(b)fluoranthene N.D. 1191-24-2 10334 0.2 5 Benzo(g,h,i)perylene N.D. 1207-08-9 10334 0.3 5 Benzo(k)fluoranthene N.D. 1101-55-3 10334 0.3 5 4-Bromophenyl-phenylether N.D. 185-68-7 10334 0.8 5 Butylbenzylphthalate N.D. 184-74-2 10334 0.5 5 Di-n-butylphthalate N.D. 159-50-7 10334 0.3 5 4-Chloro-3-methylphenol N.D. 1106-47-8 10334 0.3 5 4-Chloroaniline N.D. 1111-91-1 10334 0.5 5 bis(2-Chloroethoxy)methane N.D. 1111-44-4 10334 0.4 5 bis(2-Chloroethyl)ether N.D. 139638-32-910334 0.3 5 bis(2-Chloroisopropyl)ether N.D. 191-58-7 10334 0.2 5 2-Chloronaphthalene N.D. 195-57-8 10334 0.3 5 2-Chlorophenol N.D. 17005-72-3 10334 0.3 5 4-Chlorophenyl-phenylether N.D. 1218-01-9 10334 0.2 5 Chrysene N.D. 153-70-3 10334 0.4 5 Dibenz(a,h)anthracene N.D. 195-50-1 10334 0.3 5 1,2-Dichlorobenzene N.D. 1541-73-1 10334 0.3 5 1,3-Dichlorobenzene N.D. 1106-46-7 10334 0.3 5 1,4-Dichlorobenzene N.D. 191-94-1 10334 0.8 5 3,3'-Dichlorobenzidine N.D. 1120-83-2 10334 0.3 5 2,4-Dichlorophenol N.D. 184-66-2 10334 0.3 5 Diethylphthalate N.D. 1105-67-9 10334 0.3 5 2,4-Dimethylphenol N.D. 1131-11-3 10334 0.9 5 Dimethylphthalate N.D. 1534-52-1 10334 4 14 4,6-Dinitro-2-methylphenol N.D. 151-28-5 10334 9 28 2,4-Dinitrophenol 1 J 1121-14-2 10334 0.4 5 2,4-Dinitrotoluene N.D. 1606-20-2 10334 0.3 5 2,6-Dinitrotoluene N.D. 1122-66-7 10334 0.2 5 1,2-Diphenylhydrazine N.D. 1117-81-7 10334 0.9 5 bis(2-Ethylhexyl)phthalate 0.5 J 1206-44-0 10334 0.3 5 Fluoranthene 4 J 186-73-7 10334 0.3 5 Fluorene N.D. 1118-74-1 10334 0.9 5 Hexachlorobenzene N.D. 187-68-3 10334 0.8 5 Hexachlorobutadiene N.D. 177-47-4 10334 2 14 Hexachlorocyclopentadiene N.D. 167-72-1 10334 0.4 5 Hexachloroethane N.D. 1193-39-5 10334 0.3 5 Indeno(1,2,3-cd)pyrene N.D. 178-59-1 10334 0.3 5 Isophorone 3 J 191-20-3 10334 0.2 5 Naphthalene N.D. 198-95-3 10334 0.5 5 Nitrobenzene N.D. 188-75-5 10334 0.4 5 2-Nitrophenol N.D. 1100-02-7 10334 5 9 4-Nitrophenol N.D. 162-75-9 10334 2 5 N-Nitrosodimethylamine N.D. 1621-64-7 10334 0.4 5 N-Nitroso-di-n-propylamine N.D. 186-30-6 10334 0.3 5 N-Nitrosodiphenylamine N.D. 1117-84-0 10334 0.5 5 Di-n-octylphthalate N.D. 187-86-5 10334 3 14 Pentachlorophenol 4 J 185-01-8 10334 0.2 5 Phenanthrene N.D. 1108-95-2 10334 0.4 5 Phenol 0.5 J 1129-00-0 10334 0.2 5 Pyrene


of 4



Collected: 05/31/2012 10:30 by MS

Submitted: 06/01/2012 09:25


Reported: 06/13/2012 12:10





CAT No.


The laboratory did not receive sufficient sample volume to performthe method QC requirement for MS/MSD or MS/DUP analysis.


ug/l ug/lug/lEPA 245.1 rev 3 0.027 J 17439-97-6 00259 0.026 0.20 Mercury











of 4



Collected: 05/31/2012 10:30 by MS

Submitted: 06/01/2012 09:25


Reported: 06/13/2012 12:10


IN-RC




Analyst


1Lauren C Temple06/06/2012 02:43 M121572AA1EPA 624 VOCs by 624 10371 1Kelly E Keller06/05/2012 20:40 F121574AA1SW-846 8260B MTBE Only 8260B Water 10943 1Kelly E Keller06/05/2012 20:40 F121574AA1SW-846 5030B GC/MS VOA Water Prep 01163 1Linda M

Hartenstine06/05/2012 10:41 12154WAG6251EPA 625 Method 625 10334

1Nicholas W Shroyer06/04/2012 18:00 12154WAG6251EPA 625 625 Water Extraction 08108

1John P Hook06/07/2012 20:30 1215757160031EPA 200.7 rev 4.4 Calcium 01750 1John P Hook06/07/2012 20:30 1215757160031EPA 200.7 rev 4.4 Copper 07053 1John P Hook06/07/2012 20:30 1215757160031EPA 200.7 rev 4.4 Iron 01754 1John P Hook06/07/2012 20:30 1215757160031EPA 200.7 rev 4.4 Manganese 07058 1Damary Valentin06/05/2012 08:10 1215657140031EPA 245.1 rev 3 Mercury 00259 1Annamaria


rec) 05716


(water) 00491

1Yolunder Y Bunch06/12/2012 08:12 12164807901A1EPA 1664A HEM (oil & grease) 08079 2Luz M Groff06/01/2012 20:20 12153027902A1EPA 180.1 (1993) Turbidity 00279 1Susan A Engle06/05/2012 07:39 12157020601A1SM20 2540 D Total Suspended Solids 00206 1Luz M Groff06/01/2012 17:00 12153021501A1SM20 2540 F Settleable Solids 00215 1Kenneth A Bell06/05/2012 20:49 12157006003A1SM20 4500 H/B pH 12152


of 4



Collected: 05/31/2012 10:55 by MS

Submitted: 06/01/2012 09:25


Reported: 06/13/2012 12:10


EF-RC As Received Limit of Quantitation



CAT No.







of 4



Collected: 05/31/2012 10:55 by MS

Submitted: 06/01/2012 09:25


Reported: 06/13/2012 12:10





CAT No.

ug/l ug/lug/lGC/MS Semivolatiles EPA 625N.D. 1205-99-2 10334 0.3 5 Benzo(b)fluoranthene N.D. 1191-24-2 10334 0.2 5 Benzo(g,h,i)perylene N.D. 1207-08-9 10334 0.3 5 Benzo(k)fluoranthene N.D. 1101-55-3 10334 0.3 5 4-Bromophenyl-phenylether N.D. 185-68-7 10334 0.8 5 Butylbenzylphthalate N.D. 184-74-2 10334 0.5 5 Di-n-butylphthalate N.D. 159-50-7 10334 0.3 5 4-Chloro-3-methylphenol N.D. 1106-47-8 10334 0.3 5 4-Chloroaniline N.D. 1111-91-1 10334 0.5 5 bis(2-Chloroethoxy)methane N.D. 1111-44-4 10334 0.4 5 bis(2-Chloroethyl)ether N.D. 139638-32-910334 0.3 5 bis(2-Chloroisopropyl)ether N.D. 191-58-7 10334 0.2 5 2-Chloronaphthalene N.D. 195-57-8 10334 0.3 5 2-Chlorophenol N.D. 17005-72-3 10334 0.3 5 4-Chlorophenyl-phenylether N.D. 1218-01-9 10334 0.2 5 Chrysene N.D. 153-70-3 10334 0.4 5 Dibenz(a,h)anthracene N.D. 195-50-1 10334 0.3 5 1,2-Dichlorobenzene N.D. 1541-73-1 10334 0.3 5 1,3-Dichlorobenzene N.D. 1106-46-7 10334 0.3 5 1,4-Dichlorobenzene N.D. 191-94-1 10334 0.8 5 3,3'-Dichlorobenzidine N.D. 1120-83-2 10334 0.3 5 2,4-Dichlorophenol N.D. 184-66-2 10334 0.3 5 Diethylphthalate N.D. 1105-67-9 10334 0.3 5 2,4-Dimethylphenol N.D. 1131-11-3 10334 0.9 5 Dimethylphthalate N.D. 1534-52-1 10334 4 14 4,6-Dinitro-2-methylphenol N.D. 151-28-5 10334 9 28 2,4-Dinitrophenol N.D. 1121-14-2 10334 0.4 5 2,4-Dinitrotoluene N.D. 1606-20-2 10334 0.3 5 2,6-Dinitrotoluene N.D. 1122-66-7 10334 0.2 5 1,2-Diphenylhydrazine N.D. 1117-81-7 10334 0.9 5 bis(2-Ethylhexyl)phthalate 0.4 J 1206-44-0 10334 0.3 5 Fluoranthene 2 J 186-73-7 10334 0.3 5 Fluorene N.D. 1118-74-1 10334 0.9 5 Hexachlorobenzene N.D. 187-68-3 10334 0.8 5 Hexachlorobutadiene N.D. 177-47-4 10334 2 14 Hexachlorocyclopentadiene N.D. 167-72-1 10334 0.4 5 Hexachloroethane N.D. 1193-39-5 10334 0.3 5 Indeno(1,2,3-cd)pyrene N.D. 178-59-1 10334 0.3 5 Isophorone 1 J 191-20-3 10334 0.2 5 Naphthalene N.D. 198-95-3 10334 0.5 5 Nitrobenzene N.D. 188-75-5 10334 0.4 5 2-Nitrophenol N.D. 1100-02-7 10334 5 9 4-Nitrophenol N.D. 162-75-9 10334 2 5 N-Nitrosodimethylamine N.D. 1621-64-7 10334 0.4 5 N-Nitroso-di-n-propylamine N.D. 186-30-6 10334 0.3 5 N-Nitrosodiphenylamine N.D. 1117-84-0 10334 0.5 5 Di-n-octylphthalate N.D. 187-86-5 10334 3 14 Pentachlorophenol 3 J 185-01-8 10334 0.2 5 Phenanthrene N.D. 1108-95-2 10334 0.4 5 Phenol 0.3 J 1129-00-0 10334 0.2 5 Pyrene


of 4



Collected: 05/31/2012 10:55 by MS

Submitted: 06/01/2012 09:25


Reported: 06/13/2012 12:10





CAT No.


The laboratory did not receive sufficient sample volume to performthe method QC requirement for MS/MSD or MS/DUP analysis.


ug/l ug/lug/lEPA 245.1 rev 3 0.027 J 17439-97-6 00259 0.026 0.20 Mercury











of 4



Collected: 05/31/2012 10:55 by MS

Submitted: 06/01/2012 09:25


Reported: 06/13/2012 12:10


EF-RC




Analyst


1Lauren C Temple06/06/2012 03:08 M121572AA1EPA 624 VOCs by 624 10371 1Kelly E Keller06/05/2012 19:34 F121574AA1SW-846 8260B MTBE Only 8260B Water 10943 1Kelly E Keller06/05/2012 19:34 F121574AA1SW-846 5030B GC/MS VOA Water Prep 01163 1Linda M

Hartenstine06/05/2012 11:13 12154WAG6251EPA 625 Method 625 10334

1Nicholas W Shroyer06/04/2012 18:00 12154WAG6251EPA 625 625 Water Extraction 08108

1John P Hook06/07/2012 20:34 1215757160031EPA 200.7 rev 4.4 Calcium 01750 1John P Hook06/07/2012 20:34 1215757160031EPA 200.7 rev 4.4 Copper 07053 1John P Hook06/07/2012 20:34 1215757160031EPA 200.7 rev 4.4 Iron 01754 1John P Hook06/07/2012 20:34 1215757160031EPA 200.7 rev 4.4 Manganese 07058 1Damary Valentin06/05/2012 08:12 1215657140031EPA 245.1 rev 3 Mercury 00259 1Annamaria


rec) 05716


(water) 00491

1Yolunder Y Bunch06/12/2012 08:12 12164807901A1EPA 1664A HEM (oil & grease) 08079 1Luz M Groff06/01/2012 20:20 12153027902A1EPA 180.1 (1993) Turbidity 00279 1Susan A Engle06/05/2012 07:39 12157020601A1SM20 2540 D Total Suspended Solids 00206 1Luz M Groff06/01/2012 17:00 12153021501A1SM20 2540 F Settleable Solids 00215 1Kenneth A Bell06/05/2012 20:59 12157006003A1SM20 4500 H/B pH 12152


of 2




Submitted: 06/01/2012 09:25


Reported: 06/13/2012 12:10


TB-RC As Received Limit of Quantitation



CAT No.







of 2




Submitted: 06/01/2012 09:25


Reported: 06/13/2012 12:10


TB-RC




Analyst


1Lauren C Temple06/06/2012 03:34 M121572AA1EPA 624 VOCs by 624 10371 1Kelly E Keller06/05/2012 21:02 F121574AA1SW-846 8260B MTBE Only 8260B Water 10943 1Kelly E Keller06/05/2012 21:02 F121574AA1SW-846 5030B GC/MS VOA Water Prep 01163


of 6





Blank Blank Blank Report LCS LCSD LCS/LCSD Analysis Name Result MDL** LOQ Units %REC %REC Limits RPD RPD Max Batch number: F121574AA Sample number(s): 6673891-6673893 Methyl Tertiary Butyl Ether N.D. 0.5 1 ug/l 78 68-121 Batch number: M121572AA Sample number(s): 6673891-6673893 Acrolein N.D. 10. 50 ug/l 78 53-126 Acrylonitrile N.D. 10. 50 ug/l 79 61-120 Benzene N.D. 0.9 5 ug/l 93 80-121 Bromodichloromethane N.D. 0.7 5 ug/l 93 76-123 Bromoform N.D. 0.8 5 ug/l 91 65-136 Bromomethane N.D. 2. 5 ug/l 85 55-122 Carbon Tetrachloride N.D. 1. 5 ug/l 97 72-128 Chlorobenzene N.D. 0.8 5 ug/l 96 79-120 Chloroethane N.D. 2. 5 ug/l 82 54-121 2-Chloroethyl Vinyl Ether N.D. 2. 10 ug/l 82 47-128 Chloroform N.D. 1. 5 ug/l 89 79-122 Chloromethane N.D. 2. 5 ug/l 90 63-135 Dibromochloromethane N.D. 1. 5 ug/l 95 74-121 1,2-Dichlorobenzene N.D. 1. 5 ug/l 96 78-125 1,3-Dichlorobenzene N.D. 1. 5 ug/l 97 78-124 1,4-Dichlorobenzene N.D. 1. 5 ug/l 96 78-124 Dichlorodifluoromethane N.D. 2. 5 ug/l 94 48-120 1,1-Dichloroethane N.D. 1. 5 ug/l 92 75-130 1,2-Dichloroethane N.D. 1. 5 ug/l 95 72-138 1,1-Dichloroethene N.D. 0.9 5 ug/l 98 71-136 cis-1,2-Dichloroethene N.D. 1. 5 ug/l 94 73-130 trans-1,2-Dichloroethene N.D. 1. 5 ug/l 93 73-131 1,2-Dichloropropane N.D. 1. 5 ug/l 90 78-121 cis-1,3-Dichloropropene N.D. 1. 5 ug/l 95 79-120 trans-1,3-Dichloropropene N.D. 0.6 5 ug/l 97 74-120 Ethylbenzene N.D. 0.8 5 ug/l 96 80-120 Methylene Chloride N.D. 2. 5 ug/l 92 71-132 1,1,2,2-Tetrachloroethane N.D. 1. 5 ug/l 91 75-121 Tetrachloroethene N.D. 1. 5 ug/l 104 77-127 Toluene N.D. 0.8 5 ug/l 98 80-120 1,1,1-Trichloroethane N.D. 1. 5 ug/l 93 74-127 1,1,2-Trichloroethane N.D. 1. 5 ug/l 95 80-120 Trichloroethene N.D. 1. 5 ug/l 94 80-120 Trichlorofluoromethane N.D. 2. 5 ug/l 104 55-136

of 6



Blank Blank Blank Report LCS LCSD LCS/LCSD Analysis Name Result MDL** LOQ Units %REC %REC Limits RPD RPD Max Vinyl Chloride N.D. 2. 5 ug/l 95 56-121 Xylene (total) N.D. 0.9 5 ug/l 99 80-120 Batch number: 12154WAG625 Sample number(s): 6673891-6673892 Acenaphthene N.D. 0.3 5 ug/l 98 97 75-117 2 30 Acenaphthylene N.D. 0.3 5 ug/l 97 95 75-122 2 30 Anthracene N.D. 0.2 5 ug/l 90 90 75-116 1 30 Benzidine N.D. 20. 60 ug/l 45 45 16-104 1 30 Benzo(a)anthracene N.D. 0.2 5 ug/l 107 102 76-117 4 30 Benzo(a)pyrene N.D. 0.3 5 ug/l 100 99 69-143 1 30 Benzo(b)fluoranthene N.D. 0.3 5 ug/l 100 99 64-145 0 30 Benzo(g,h,i)perylene N.D. 0.2 5 ug/l 109 110 66-145 0 30 Benzo(k)fluoranthene N.D. 0.3 5 ug/l 94 96 66-145 2 30 4-Bromophenyl-phenylether N.D. 0.3 5 ug/l 105 104 80-112 1 30 Butylbenzylphthalate N.D. 0.8 5 ug/l 101 103 80-125 2 30 Di-n-butylphthalate N.D. 0.5 5 ug/l 97 96 76-120 1 30 4-Chloro-3-methylphenol N.D. 0.3 5 ug/l 97 104 75-113 7 30 4-Chloroaniline N.D. 0.3 5 ug/l 97 94 10-124 3 30 bis(2-Chloroethoxy)methane N.D. 0.5 5 ug/l 109 107 69-128 2 30 bis(2-Chloroethyl)ether N.D. 0.4 5 ug/l 100 100 72-114 1 30 bis(2-Chloroisopropyl)ether N.D. 0.3 5 ug/l 87 88 87-134 1 30 2-Chloronaphthalene N.D. 0.2 5 ug/l 97 73 57-112 28 30 2-Chlorophenol N.D. 0.3 5 ug/l 92 99 78-118 7 30 4-Chlorophenyl-phenylether N.D. 0.3 5 ug/l 102 99 76-115 3 30 Chrysene N.D. 0.2 5 ug/l 92 93 81-118 1 30 Dibenz(a,h)anthracene N.D. 0.4 5 ug/l 107 104 68-144 3 30 1,2-Dichlorobenzene N.D. 0.3 5 ug/l 91 93 73-111 2 30 1,3-Dichlorobenzene N.D. 0.3 5 ug/l 87 90 67-110 3 30 1,4-Dichlorobenzene N.D. 0.3 5 ug/l 91 95 68-111 4 30 3,3'-Dichlorobenzidine N.D. 0.8 5 ug/l 86 81 33-124 5 30 2,4-Dichlorophenol N.D. 0.3 5 ug/l 100 102 72-127 2 30 Diethylphthalate N.D. 0.3 5 ug/l 98 95 74-120 3 30 2,4-Dimethylphenol N.D. 0.3 5 ug/l 99 97 70-123 3 30 Dimethylphthalate N.D. 1. 5 ug/l 83 84 30-112 1 30 4,6-Dinitro-2-methylphenol N.D. 4. 15 ug/l 84 86 65-120 2 30 2,4-Dinitrophenol N.D. 10. 30 ug/l 85 89 64-140 5 30 2,4-Dinitrotoluene N.D. 0.4 5 ug/l 102 101 74-121 1 30 2,6-Dinitrotoluene N.D. 0.3 5 ug/l 96 97 80-115 1 30 1,2-Diphenylhydrazine N.D. 0.2 5 ug/l 89 88 75-114 1 30 bis(2-Ethylhexyl)phthalate N.D. 1. 5 ug/l 108 105 74-118 3 30 Fluoranthene N.D. 0.3 5 ug/l 98 89 86-119 9 30 Fluorene N.D. 0.3 5 ug/l 103 102 74-117 2 30 Hexachlorobenzene N.D. 1. 5 ug/l 88 89 75-114 1 30 Hexachlorobutadiene N.D. 0.8 5 ug/l 95 95 58-116 0 30 Hexachlorocyclopentadiene N.D. 2. 15 ug/l 86 88 38-133 3 30 Hexachloroethane N.D. 0.4 5 ug/l 84 89 61-113 6 30 Indeno(1,2,3-cd)pyrene N.D. 0.3 5 ug/l 110 108 67-143 2 30 Isophorone N.D. 0.3 5 ug/l 105 99 75-123 6 30 Naphthalene N.D. 0.2 5 ug/l 94 97 73-118 3 30 Nitrobenzene N.D. 0.5 5 ug/l 95 95 74-121 0 30

of 6



Blank Blank Blank Report LCS LCSD LCS/LCSD Analysis Name Result MDL** LOQ Units %REC %REC Limits RPD RPD Max 2-Nitrophenol N.D. 0.4 5 ug/l 102 105 77-120 3 30 4-Nitrophenol N.D. 5. 10 ug/l 45 49 27-80 9 30 N-Nitroso-di-n-propylamine N.D. 0.4 5 ug/l 103 101 68-114 2 30 N-Nitrosodimethylamine N.D. 2. 5 ug/l 55 63 44-81 14 30 N-Nitrosodiphenylamine N.D. 0.3 5 ug/l 91 90 84-135 1 30 Di-n-octylphthalate N.D. 0.5 5 ug/l 101 102 65-155 1 30 Pentachlorophenol N.D. 3. 15 ug/l 108 107 55-137 1 30 Phenanthrene N.D. 0.2 5 ug/l 93 91 77-113 1 30 Phenol N.D. 0.4 5 ug/l 47 51 26-71 9 30 Pyrene N.D. 0.2 5 ug/l 96 96 76-115 1 30 1,2,4-Trichlorobenzene N.D. 0.3 5 ug/l 93 92 70-119 0 30 2,4,6-Trichlorophenol N.D. 0.7 5 ug/l 99 96 83-120 3 30 Batch number: 121565714003 Sample number(s): 6673891-6673892 Mercury N.D. 0.026 0.20 ug/l 112 85-115 Batch number: 121575716003 Sample number(s): 6673891-6673892 Calcium N.D. 70.5 200 ug/l 96 90-110 Copper N.D. 0.94 10.0 ug/l 100 90-110 Iron N.D. 14.1 200 ug/l 96 90-110 Manganese N.D. 0.44 5.0 ug/l 100 85-115 Batch number: 12158113101A Sample number(s): 6673891-6673892 Phenols (water) N.D. 15. 40 ug/l 98 90-110 Batch number: 12159987121B Sample number(s): 6673891-6673892 Chloride N.D. 200. 400 ug/l 100 90-110 Batch number: 12153021501A Sample number(s): 6673891-6673892 Settleable Solids N.D. 0.10 0.10 ml/l/hr Batch number: 12153027902A Sample number(s): 6673891-6673892 Turbidity 0.11 J 0.090 0.30 N T U 93 90-110 Batch number: 12157006003A Sample number(s): 6673891-6673892 pH 100 99-103 Batch number: 12157020601A Sample number(s): 6673891-6673892 Total Suspended Solids N.D. 3,000. 12,000 ug/l 87 79-107 Batch number: 12164807901A Sample number(s): 6673891-6673892 HEM (oil & grease) N.D. 1,400. 5,000 ug/l 96 93 78-114 3 16


Unspiked (UNSPK) = the sample used in conjunction with the matrix spike Background (BKG) = the sample used in conjunction with the duplicate

of 6



MS MSD MS/MSD RPD BKG DUP DUP Dup RPD Analysis Name %REC %REC Limits RPD MAX Conc Conc RPD Max___ Batch number: F121574AA Sample number(s): 6673891-6673893 UNSPK: 6673892 Methyl Tertiary Butyl Ether 79 80 72-126 1 30 Batch number: M121572AA Sample number(s): 6673891-6673893 UNSPK: P672616 Acrolein 77 76 40-128 0 30 Acrylonitrile 79 80 58-124 1 30 Benzene 103 102 83-132 1 30 Bromodichloromethane 99 100 78-128 0 30 Bromoform 91 95 59-129 4 30 Bromomethane 93 94 52-134 2 30 Carbon Tetrachloride 112 110 76-147 1 30 Chlorobenzene 101 101 82-121 1 30 Chloroethane 90 88 50-140 2 30 2-Chloroethyl Vinyl Ether 0* 0* 10-172 0 30 Chloroform 100 98 82-132 2 30 Chloromethane 104 102 50-140 2 30 Dibromochloromethane 98 98 72-128 0 30 1,2-Dichlorobenzene 101 102 79-126 1 30 1,3-Dichlorobenzene 102 103 79-126 1 30 1,4-Dichlorobenzene 102 102 79-126 0 30 Dichlorodifluoromethane 111 106 42-132 5 30 1,1-Dichloroethane 103 105 79-141 1 30 1,2-Dichloroethane 101 101 65-146 0 30 1,1-Dichloroethene 109 111 75-153 2 30 cis-1,2-Dichloroethene 104 103 81-134 1 30 trans-1,2-Dichloroethene 108 107 74-144 1 30 1,2-Dichloropropane 97 98 77-130 1 30 cis-1,3-Dichloropropene 93 95 74-113 2 30 trans-1,3-Dichloropropene 89 89 69-116 0 30 Ethylbenzene 103 103 82-124 0 30 Methylene Chloride 101 103 65-148 2 30 1,1,2,2-Tetrachloroethane 90 93 73-121 3 30 Tetrachloroethene 114 114 78-136 1 30 Toluene 103 103 84-123 0 30 1,1,1-Trichloroethane 105 106 83-137 1 30 1,1,2-Trichloroethane 98 97 85-121 1 30 Trichloroethene 108 109 86-131 1 30 Trichlorofluoromethane 123 117 62-152 5 30 Vinyl Chloride 111 107 60-137 4 30 Xylene (total) 105 106 79-130 1 30 Batch number: 121565714003 Sample number(s): 6673891-6673892 UNSPK: P673905 BKG: P673905 Mercury 113 80-120 N.D. 0.026 J 200* (1) 20 Batch number: 121575716003 Sample number(s): 6673891-6673892 UNSPK: P675617 BKG: P675617 Calcium 39 (2) 81-118 94,900 94,000 1 20 Copper 100 86-122 N.D. N.D. 0 (1) 20 Iron 97 70-130 N.D. N.D. 0 (1) 20 Manganese 100 70-130 8.1 8.0 1 (1) 20

of 6




Unspiked (UNSPK) = the sample used in conjunction with the matrix spike Background (BKG) = the sample used in conjunction with the duplicate MS MSD MS/MSD RPD BKG DUP DUP Dup RPD Analysis Name %REC %REC Limits RPD MAX Conc Conc RPD Max___ Batch number: 12158113101A Sample number(s): 6673891-6673892 UNSPK: P671150 Phenols (water) 95 94 90-110 1 6 Batch number: 12159987121B Sample number(s): 6673891-6673892 UNSPK: P671150 BKG: P671150 Chloride 111* 90-110 720,000 732,000 2 (1) 20 Batch number: 12153027902A Sample number(s): 6673891-6673892 BKG: 6673891 Turbidity 44.8 45.6 2 3 Batch number: 12157006003A Sample number(s): 6673891-6673892 BKG: P674734 pH 7.8 7.8 0 3 Batch number: 12157020601A Sample number(s): 6673891-6673892 BKG: P673902 Total Suspended Solids 144,000 149,000 3 (1) 20


Surrogate recoveries which are outside of the QC window are confirmed unless attributed to dilution or otherwise noted on the Analysis Report. Analysis Name: BTEX + MTBE 8260B Water Batch number: F121574AA Dibromofluoromethane 1,2-Dichloroethane-d4 Toluene-d8 4-Bromofluorobenzene ________________________________________________________________________________________________________________ 6673891 97 103 97 93 6673892 99 106 97 90 6673893 101 105 96 86 Blank 102 106 97 85 LCS 95 103 95 97 MS 96 104 96 95 MSD 96 101 98 95 ________________________________________________________________________________________________________________ Limits: 80-116 77-113 80-113 78-113 Analysis Name: VOCs by 624 Batch number: M121572AA 1,2-Dichloroethane-d4 Fluorobenzene 4-Bromofluorobenzene ________________________________________________________________________________________________________________ 6673891 96 100 100 6673892 101 100 105 6673893 100 99 105 Blank 97 99 104

of 6




LCS 103 101 104 MS 103 102 104 MSD 102 104 105 ________________________________________________________________________________________________________________ Limits: 76-114 80-120 86-115 Analysis Name: Method 625 Batch number: 12154WAG625 Nitrobenzene-d5 2-Fluorobiphenyl Terphenyl-d14 Phenol-d6 2-Fluorophenol 2,4,6-Tribromophenol ________________________________________________________________________________________________________________ 6673891 87 84 59 10 3* 7* 6673892 89 87 60 7* 3* 10* Blank 85 84 63 37 58 79 LCS 90 87 78 41 59 93 LCSD 90 82 73 48 67 87 ________________________________________________________________________________________________________________ Limits: 56-120 62-121 56-119 10-72 10-114 36-140

Case Narrative


General Comments:








EPA 624, GC/MS VolatilesBatch #: M121572AA (Sample number(s): 6673891-6673893 UNSPK: P672616)


EPA 625, GC/MS SemivolatilesBatch #: 12154WAG625 (Sample number(s): 6673891-6673892)

The recovery(ies) for one or more surrogates were outside of the QC window for sample(s) 6673891, 6673892

Sample #s: 6673891, 6673892The laboratory did not receive sufficient sample volume to performthe method QC requirement for MS/MSD or MS/DUP analysis.

EPA 200.7 rev 4.4, MetalsBatch #: 121575716003 (Sample number(s): 6673891-6673892 UNSPK: P675617 BKG: P675617)

The recovery(ies) for the following analyte(s) in the MS was outside the acceptance window: Calcium

EPA 245.1 rev 3, MetalsBatch #: 121565714003 (Sample number(s): 6673891-6673892 UNSPK: P673905 BKG: P673905)

The duplicate RPD for the following analyte(s) exceeded the acceptance window: Mercury

v 1.8.8 6/13/2012 12:13:44PM




Sample #s: 6673891, 6673892The laboratory did not receive sufficient sample volume to perform

the method QC requirement for MS/DUP analysis.

v 1.8.8 6/13/2012 12:13:44PM




> greater than













3768.08


ATTACHMENT 2

Photographs of Discharge Points and Receiving Water

ROUX ASSOCIATES, INC. MC0172.0030Y030.2014/AT2– 1 –

Photograph 1: Former Brooklyn Terminal RCS outfall and receiving water in May 2012(SPDES Permit No. NY-0267724, Outfall Number 001)

Photograph 2: Former Brooklyn Terminal RCS outfall and receiving water in May 2012(SPDES Permit No. NY-0267724, Outfall Number 001)

Photos = 4.25 x 5.67

ROUX ASSOCIATES, INC. MC0172.0030Y030.2014/AT2– 2 –

Photograph 3: Off-Site System outfall and receiving water in May 2012(SPDES Permit No. NY-0267724, Outfall Number 002)

Photograph 4: Off-Site System outfall and receiving water in May 2012(SPDES Permit No. NY-0267724, Outfall Number 002)


ATTACHMENT 3

Discharge Monitoring Report Forms

remedial bureau d 625 broadway 12th ... - nys dec...

Documents