process considerations for changing times

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Ron Latimer, PE Process Considerations for Changing Times: Process optimization and doing more with less

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Ron Latimer, PE

Process Considerations for Changing Times:

Process optimization and doing more with less

Process Optimization Approach

Extensive field work to thoroughly investigate and

understand plants and operations issues

Calibrate whole plant process model

Influent

Filtrate

Anaerobic Anoxic 1 Anoxic 2 Aerobic 1

Aerobic 2 Aerobic 3

Effluent

Dewatered Sludge

Filtrate

Sec Clarifier

Alum

Tert Alum

Post Anoxic Reair

Methanol

Primary Clarifier

Anaerobic Digester

Whole Plant Process Simulators

Whole Plant Simulations – BioWin, GPS-X

Steady State and Dynamic Modeling

Powerful tool with PROPER CALIBRATION and

APPLICATION

Mason Farm WWTP, OWASA North

Carolina

14.5 mgd WWTP (7.5 mgd current ADF)

Field sampling and BioWin model application to optimization

Process converted to step feed at zero cost to optimize use of influent

carbon

Nov 2008 –

May 2010

June 2010 –

Oct 2012

%

Reduced

Cost

($/gallon)

Annual

Savings

48% Alum (gpd) 915 671 27% $0.66 $59,000

25% Sodium

Hydroxide (gpd)1,360 535 61% $0.74 $223,000

20% Acetic Acid (gpd) 622 438 30% $1.08 $73,000

Total Annual Savings - - $355,000

Challenge: Increase Plant Capacity by 25%

with No New Basins and Meet TN of 5.6 mg/L

Existing 20 mgd secondary treatment facility

Project Goals:

Plant rerate to 25 mgd AADF

Effluent total nitrogen (TN) goal = 5.6 mg/L

TMDL based

NO NEW BASINS

Minimize capital

and operating

costs

Existing plant

to remain in service

Screens

Primary Clarifiers

Aeration Basins 5-8

Aeration Basins 1-4

Secondary Clarifiers

Sludge Holding Tanks

Disinfection and Reuse Filters

Approach: Model Calibration, Full Scale Pilot,

Model Verified and Design Further Optimized

Special sampling, BioWin model calibration

Full scale test different nitrogen removal configurations

determined using model

Model further calibrated from pilot, used model to

further optimize design

Solution: Innovative Hybrid Step

Feed Design with Internal Recycle

Zone DO Control – maximize

nitrification, minimize carryover

Internal Recycle

Pump – fully utilize

anoxic capacity

Step Feed – optimize influent carbon

use, wet weather

60%Q

40%Q

4,000 mg/L 3,600

mg/L

Solution: Modified Aeration Basins

Results: TN < 4 mg/L,

Exceeds the 5.6 mg/L Goal

0

2

4

6

8

10

12

14

16

18

12/18/08 2/26/09 5/7/09 7/16/09 9/24/09 12/3/09 2/11/10 4/22/10 7/1/10 9/9/10

Co

nc

(m

g/L

)Arlington East WRF - Secondary Effluent Nitrogen

30 per. Mov. Avg. (NO3-N + NO2-N) 30 per. Mov. Avg. (TKN) 30 per. Mov. Avg. (TN)

1&2 online 3&4 online5&6 online

7&8 online

Construction SubstantiallyComplete

Monthly Avg TN: June 2010 - 3.8 mg/LJuly 2010 - 3.9 mg/L

August 2010 - 3.4 mg/LSeptember 2010 - 3.9 mg/L

Lesson Learned: Modeling and Full Scale

Testing Allows Optimization of Existing

Infrastructure

An innovative and cost effective solution

Achieved rerating from 20 to 25 mgd and TN removal to

5.6 mg/L with no additional basin volume

Estimated savings versus more conventional approach

– $10 million

Neuse River WWTP Uses Process Models to

Improve Effectiveness of Design

New Requirements

Expansion to from 60 to 75 mgd

TN = 2.7 mg/L

TP = 1 mg/L

Challenges

Rerate existing bioreactors

No new aeration basin volume

Energy and chemical cost

reduction

Existing Plant Rerated to 75 mgd

Raw INF

Grit + PI Channel

Prim Clar

AX 1 AX 2Aerobic 1 Aerobic 2 Aerobic 3 Aerobic 4

Post AX ReairML Channel

Sec Clar

Effluent

RAS Channel

Methanol

TWAS

Filtrate

Primary Sludge

WWTP Sludge

Alum Tert

Alum

Extensive Special Sampling and BioWin Model Calibration

Full Scale Verification

Secondary Clarifier Stress Testing CFD Model Calibration

SolutionModeling verified rerate feasible

Optimized seasonal swing zone operations

Optimized zone DO control and NH3 based DO control

Deoxygenation zone for NRCY and 2nd anoxic zone

Full scale testing verified

Existing BNR Basins OK for 75 mgd

Saves $20 Million

Combined BioWin Modeling, Stress Testing, Secondary Clarifier CFD

Modeling and Full Scale Verification

F. Wayne Hill WRC, Gwinnett Co, GA

Parameter Units

F. Wayne

Hill

Limits

Flow mgd 60

cBOD5 mg/L --

TSS mg/L 3

COD mg/L 18

Ammonia-N mg/L 0.4

Total Phosphorus mg/L 0.08

Turbidity ntu 0.5

DO mg/L 7

Fecal Coliform #/100 2

Capacity Crisis – Consultant – Your

60 mgd Plant is Really Only a 30 mgd PlantIndividual Unit Process Capacity - Maximum Month

With Yellow River Sludge

44.0

33.2

56.8

42.2

29.1 31.0

43.7

22.2

56.8

33

15.3

38.4

0

10

20

30

40

50

60

70

PrimaryClarifiers

BRB SecondaryClarifiers

Blowers TWASCentrifuges

AnaerobicDigesters

Unit Process / Scenario

Cap

acit

y (

mg

d)

50% PC Eff. 20% PC Eff.

Year

Raw Influent Concentrations

cBOD,

mg/L

COD,

mg/L

TSS,

mg/L

NH3,

mg/LTP, mg/L

2004 182 609 430 24.8 7.6

2005 237 1021 940 25.6 7.3

2006 252 715 575 25.6 7.5

2007 297 1170 1391 28.6 9.6

2008 277 1211 1186 30.6 9.4

Detailed Process Study

Detailed field work, sampling, and BioWin calibration

Extremely poor historical sampling

Loads far overestimated

Primary clarifiers that “don’t work”

Simple operational changes

Low cost canopy baffle installed

– Now work

BRB 1-4 - A1 BRB 1-4 - A2 BRB 1-4 - B1 BRB 1-4 - B2 BRB 1-4 - C5+C6 BRB 1-4- C8 BRB 1-4- DBRB 1-4- C1+C2BRB 1-4 - C3+C4 BRB 1-4- C7

Grit tank

BRB 1-4- E

BRB 5-10- A1BRB 5-10- A2 BRB 5-10- B1 BRB 5-10- B2 BRB 5-10- C5+C6 BRB 5-10- C8BRB 5-10- C1+C2BRB 5-10- C3+C4 BRB 5-10- C7

Mg(OH)2

Mixed Liquor Metal Salt

Anaerobic Digesters

Dewatered Sludge

Grit

Tertiary Clarifier Metal Salt

Combined Filter Effluent - Pre O3 Infl

Tertiary Caustic

Sec Scum

Bioreactor21

COD Influent1

Installed Canopy Baffle Drastically Improves

Performance in Side By Side

Before After

Primary Clarifier % TSS Removal

Primary 9 – Baffle Installed 48%

Primary 10 – As Is 31%

Primary Clarifier Optimization for capacity

-50%

-40%

-30%

-20%

-10%

0%

10%

20%

30%

40%

50%

60%

70%

80%

90%

7/1/09 7/31/09 8/30/09 9/29/09 10/29/09 11/28/09 12/28/09 1/27/10 2/26/10

Pri

ma

ry C

lari

fie

r %

TS

S R

em

ova

l

Primary % TSS Removal 7 per. Mov. Avg. (Primary % TSS Removal)

2015 = 65%

4 blowers to

2 blowers

Primary Clarifier optimization for increased gas

0

5,000

10,000

15,000

20,000

25,000

30,000

35,000

40,000

45,000

50,000

0

50

100

150

200

250

300

350

400

450

Au

g-0

8

Se

p-0

8

Oct-

08

No

v-0

8

De

c-0

8

Ja

n-0

9

Fe

b-0

9

Ma

r-0

9

Ap

r-0

9

Ma

y-0

9

Ju

n-0

9

Ju

l-0

9

Au

g-0

9

Se

p-0

9

Oct-

09

No

v-0

9

De

c-0

9

Ja

n-1

0

Fe

b-1

0

Lo

ad

ing

(pp

d)

Ga

s F

low

(sc

fm)

Digester Gas Production and Primary Sludge Loading

Digester Gas Flow Primary Sludge Loading

Digester Gas Flow - 30 Day Moving Average Primary Sludge Loading - 30 Day Moving Average

Modified Sampling and Whole Plant BioWin

Model Calibration Confirms True Loadings

Poor influent sampling and FOG/grease

Historical loads far overestimated

BioWin calibration and special sampling verified “true” loadings

much lower

Primary clarifiers now working well - Plant capacity maintained

ParameterOriginal

Design

Historical Avg.

(Prior to Data

Reconciliation)

Recommended

Values (After Data

Reconciliation)

COD, mg/L 476 1,030 635

BOD5, mg/L 200 266 284

TSS, mg/L 230 1,023 365

Ammonia Based DO Control

• Concept – use aerobic zone

ammonia (online probe/analyzer)

concentration to determine DO

setpoints

• Benefits: Minimize airflow/energy,

reduce supplemental carbon

• Allows stricter control of DO entering

anoxic zones and simultaneous

nitrification/denitrification (SNDN )

• Take advantage of extra aerobic volume to

do SNDN as well as endogenous

denitrification

Overview of Simultaneous Nitrification and

Denitrification (SNDN)

• SNDN is operating at low DO conditions to achieve

nitrification and denitrification in the same zone

• Denitrification can occur at low DO conditions in

aerobic zone

• Overall reduced need for purchased carbon/lower TN

• Requires higher SRTs and solids inventories

• Nitrification slows down at lower DO

• 20 mgd plant operating at a low DO concentration

would save ~ $80,000/year with diffused aeration

DO = 2 mg/L DO = 0.5 mg/L

Diffused Aeration $270,000 $190,000

Assumes $0.06/kW-hr

Ammonia Based DO/aeration control

Example control concept at

Tallahassee, FL Advanced

Wastewater Treatment Plant

• If NH3-N < 0.75 mg/L

– DO setpoint in Zone 2, 3 and 4 = 0.3 mg/L

• If NH3-N > 1.0 mg/L

– DO setpoint in Zone 2, 3 and 4 = 2.0 mg/L

Ammonia Based DO Control for SNDN

shows high savings potential

24 mgd VA plant

Goal is to save on supplemental

carbon costs and aeration

Savings up to $280,000/yr

75 mgd VA plant

• Goal is to save on supplemental

carbon costs and aeration

• 40% reduction in supplemental

carbon ($400K/yr)

30 mgd VA plant

• 47% reduction in supplemental

carbon, 10% reduction in energy

ANX 1ANX 2ANX 3ANX 4

AE

R 1

AER 2 AER 3

AER 4

Post-ANX1 Post-ANX2 Re-

AER

MeOH addition

AER 5

Operate at DO 0.5 mg/L

Operate at

DO 2.0 mg/L

Op

era

te a

t D

O 2

.0 m

g/L

Operate at

DO 0.8 mg/L

MR396

Example SNDN Pilot Using Ammonia-Based

DO Control to Reduce Carbon Demand

Control

Basin

Ammonia

setpoint

1.5 mg/L

Cell 5

aerated

REAERATIO

N

PRIMARY

ANOXIC /

ANAEROBIC

RAS

FERMENTATIO

N

AEROBIC2nd ANOXIC / AEROBIC

PRIMARY ANOXIC /

AEROBIC SWING

ANAEROBIC

30” AIR LEGEND:D.O. PROBE

FE/PDIT

MOV

Four Individual MOVs Control Airflow to SND

Pilot – Each Has Separate DO Setpoints

Optimized DO Control Strategy

• Zone 1 Cells 5-6

• Low DO – 0.5 mg/L

• High DO – 1.0 mg/L

• Zone 2 Cells 7-9

• Low DO – 0.75 mg/L

• High DO – 3.0 mg/L

• Zone 3 Cell 1

• Low DO – 1.9 mg/L

• High DO – 2.1 mg/L

• Zone 4 Cell 13

• 2.0 mg/L setpoint

Nitrification is Maintained and SNDN Tank

Performing Similarly Using 40% Less Carbon

SND Nitrate end

of AE zone cell 10

SND Nitrate (blue)

end of 2nd AX zone

cell 12

Ammonia

Cell 9

Control Nitrate (black)

end of 2nd AX zone cell 12

DO Profile in SNDN Train

DO

Zone 1

(red)

DO

Zone 2

(green)

Ammonia At End of Cell 9 Drops when Setpoint

is Lowered from 2.5 to 1.5 mg/L (as Expected)

0

0.5

1

1.5

2

2.5

3

3.5

4

7/25/15 0:00 7/30/15 0:00 8/4/15 0:00 8/9/15 0:00 8/14/15 0:00 8/19/15 0:00 8/24/15 0:00 8/29/15 0:00 9/3/15 0:00 9/8/15 0:00 9/13/15 0:00

Co

nce

ntr

atio

n (

mg

/L)

Time

Tank 11

Tank 11 Cell 9 Ammonia from probe (mg/L)

Setpoint

changes

Diffused aeration/mixing considerations

Diffused aeration also provides mixing of MLSS

The energy required to mix may exceed the

process oxygen demand

Results in excessive aeration, DO carryover to unaerated

zones and increased power costs

Inadequate mixing can lead to short circuiting, solids settling,

secondary P release, etc.

Poor Diffuser Taper and Underloaded Basins

result in Mixing Limited Conditions

0.0

0.5

1.0

1.5

2.0

2.5

3.0

3.5

4.0

4.5

DO

Co

nce

ntr

ation

(m

g/L

)

Excess

Dissolved

Oxygen

0

5

10

15

20

25

30

35

40

45

50

Co

nce

ntr

ation

(m

g/L

)

NH3-N NO3-N PO4-P

Fully Nitrified 1/3 through Aerobic Zone

~ $100,000/yr additional aeration at $0.10/kW-hr

Comparison of Mixing Technologies

Evaluated for a 56 mgd BNR Facility

HP/1,000

CFTotal HP1 Annual Cost@ $0.10/kW-

hr

Vertical Mixers 0.15 – 0.20 143 – 191 $93,000 – $125,000

Hyperboloid Mixers 0.10 – 0.15 96 - 143 $63,000 - $93,000

Jet Mixing 0.60 574 $375,000

Large - Bubble

Mixing0.10 – 0.15 96 - 143 $63,000 - $93,000

Fine Bubble

Diffusers0.302 – 0.52 287 – 487 $188,000 - $313,000

1Based on 956,000 CF of mixed volume2Based on 0.12 scfm/SF, 20 scfm/hp, 12 to 20 ft depth

Conclusion – We want to limit the occurrence of mixing limited conditions in aerobic zones since it is expensive to mix with diffused air.

Case Study – 15 mgd AWRRF Recently

Converted to ENR

Needs to meet TN < 5 and TP < 0.3 mg/L

Mixed zone provided just prior to post-anoxic zone

to reduce oxygen in NRCY and post anoxic zone

The Mixed Zone Provides Substantial

Denitrification prior to the Post-Anoxic

Providing a Mixed Zone upfront of the

Post Anoxic Zone Saves Money

Additional 1.5 mg/L TN reduction

230 gpd of supplemental carbon saved

$150,000 carbon savings, $17,000 additional energy

$300,000 additional construction cost to provide

mixers in 5 basins

Simple payback just over two years

Decoupling aeration and mixing for reduced

energy and effluent TN

Diffused aeration is an expensive way to mix reactors

Proper design, control & operation should limit the frequency of occurrence

The ability to decouple mixing from aeration can result in:

Decreased energy consumption

Decreased chemical usage

Decreased effluent nutrients

Decoupling aeration and mixing for reduced

energy and effluent TN

Providing separate mixing equipment in aerobic

zones (especially towards the end) can be cost-

effective

Vertical, hyperboloid and big-bubble mixers can be cost

effective and installed with diffused air

At a minimum, develop control strategies to allow

airflows to drop below minimum mixing

requirements, with occasional re-suspend cycles

Real-time Control of Nitrified Recycle Rate

to Optimize Denitrification

What is the nitrate concentration leaving

1st anoxic zone?

If > 1 mg/L, reduce NRCY; if < 0.5 mg/L

increase NRCY

Sidestream treatment can provide cost

effective N and P reduction

Sidestreams contribute:

■≥15 to 20% of the influent TN

■ ≥30% P load

Can often reuse existing infrastructure to

reduce costs

Thickening

Biological mainstream process

Anaerobic Digestion

DewateringSidestream

treatment

clarification

Biosolids

MR396

Sidestream N treatment -

Anammox/Deammonification

41

Ammonia oxidizing bacteria(AOB)

Anammox bacteria

Oxygen: ~63% theoretical savings Carbon: ~100% theoretical savings Achieve 80-90% TIN removal Sustainable, green technology

PaquesKruger/Veolia Demon

Recent Sidestream N Project Example

Cost in $/lbs N removed for SNR processes ranges from $0.50-

0.63 / lb N removed

Cost to remove nitrogen in the mainstream is about double

42

Technology$/lb N

Removed

Breakeven

Compared to

Mainstream

(years)

Demon New Tank $ 0.54 9

Kruger MBBR New Tank $ 0.63 11

Kruger IFAS New Tank $ 0.50 8

BNR Mainstream N Removal $ 1.03 -

Sidestream P treatment: Nutrient recovery helps

minimize nuisance struvite formation and reduce P

recycle

• Fluidized bed reactor or CSTR used for struvite recovery

• High quality, slow release fertilizer – revenue offsets costs

• Reduction in ferric/alum – payback on capital

Magnesium

Caustic

Centrate/Filtrate

Dryer

Effluent

Struvite

Dewatering

Sand (Procorp)

FBR80-90% P removal15-30% N removal

High NH3-N and PO4-P

MgNH4PO4•6 H2O

F. Wayne Hill WRC – Nutrient

Recovery Project

• Gwinnett County DWR

• 60 MGD advanced WWTP

• 0.08 mg/L TP effluent limit

• Bio-P and chemical trim

for P-removal

• Influent TP ~ 9 mg/L

Implementation of WASSTRIP™ concept at

FWH to minimize nuisance struvite production

Primary

Clarification3 Stage BNR

Secondary

Clarification

Rotary Drum

Thickening

Dewatering

Centrifuges

Ostara

Nutrient

Recovery

To Tertiary

TreatmentInfluent

WAS

Anaerobic

Digestion

RAS

P-Release Tank

Struvite

Pellets

PS

Filtrate EQ

Centrate

EQ

NaOH

MgCl2

Cake

Filtrate / Centrate

Nutrient

Recovery

Facility

Centrate

Pump

Station

Lower P and Mg content of sludge minimizes nuisance struvite formation from digester onwards

Release P and Mg from sludge

Send P, Mg rich sidestream to recovery process

Nutrient Recovery Facility –

WASSTRIP + Recovery startup in July 2015

Observations from last 4 months

• Producing about 1 ton

per day of slow release

fertilizer product

• Reduced main plant

chemical use

• Dewatered cake

increase from 22 to 24%

• 22 wet ton decrease in

sludge mass leaving

plant

15

16

17

18

19

20

21

22

23

24

25

26

27

28

Cak

e S

olid

s (%

TS)

Thank You!

Questions and Contact Information

Ron Latimer

Hazen and [email protected]