neshat et al 2014 vulnerability aquifer

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ORIGINAL ARTICLE Estimating groundwater vulnerability to pollution using a modified DRASTIC model in the Kerman agricultural area, Iran Aminreza Neshat Biswajeet Pradhan Saied Pirasteh Helmi Zulhaidi Mohd Shafri Received: 14 February 2013 / Accepted: 20 July 2013 / Published online: 2 August 2013 Ó Springer-Verlag Berlin Heidelberg 2013 Abstract Groundwater contamination from intensive fertilizer application affects conservation areas in a plain. The DRASTIC model can be applied in the evaluation of groundwater vulnerability to such pollution. The main purpose of using the DRASTIC model is to map ground- water susceptibility to pollution in different areas. How- ever, this method has been used in various areas without modification, thereby disregarding the effects of pollution types and their characteristics. Thus, this technique must be standardized and be approved for applications in aquifers and particular types of pollution. In this study, the potential for the more accurate assessment of vulnerability to pol- lution is achieved by correcting the rates of the DRASTIC parameters. The new rates were calculated by identifying the relationships among the parameters with respect to the nitrate concentration in groundwater. The methodology was implemented in the Kerman plain in the southeastern region of Iran. The nitrate concentration in water from underground wells was tested and analyzed in 27 different locations. The measured nitrate concentrations were used to associate and correlate the pollution in the aquifer to the DRASTIC index. The Wilcoxon rank-sum nonparametric statistical test was applied to determine the relationship between the index and the measured pollution in Kerman plain. Also, the weights of the DRASTIC parameters were modified through the sensitivity analysis. Subsequently, the rates and weights were computed. The results of the study revealed that the modified DRASTIC model performs more efficiently than the traditional method for nonpoint source pollution, particularly in agricultural areas. The regression coefficients showed that the relationship between the vul- nerability index and the nitrate concentration was 82 % after modification and 44 % before modification. This comparison indicated that the results of the modified DRASTIC of this region are better than those of the ori- ginal method. Keywords Modified DRASTIC GIS Groundwater Hydrogeology Sensitivity analysis Kerman plain Vulnerability Introduction Groundwater is an important and prominent resource in most countries, particularly for those in arid and semi-arid areas. Water quality has been given more emphasis in groundwater management (Pradhan 2009; Ayazi et al. 2010; Manap et al. 2012, 2013). Aquifers are usually unconfined and highly permeable, thereby causing their high susceptibility to surface contamination (Javadi et al. 2011a, b). The potential groundwater pollution by human activities at or near the surface has been considered the primary basis for the management of this major resource by implementing preventive policies. The introduction of potential contaminants to a location on top of an aquifer at a specified position in an under- ground system is defined as groundwater vulnerability (National Research Council 1993). Vulnerability assess- ment must be based on scientific, accurate, and objective A. Neshat B. Pradhan (&) H. Z. M. Shafri Department of Civil Engineering, Faculty of Engineering, University Putra Malaysia, 43400 Serdang, Selangor, Malaysia e-mail: [email protected]; [email protected]; [email protected] S. Pirasteh Department of Geography and Environmental Management, Faculty of Environment, University of Waterloo, Waterloo, Canada 123 Environ Earth Sci (2014) 71:3119–3131 DOI 10.1007/s12665-013-2690-7

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GROUNDWATER VULNERABILITY - DRASTIC

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  • ORIGINAL ARTICLE

    Estimating groundwater vulnerability to pollution usinga modified DRASTIC model in the Kerman agricultural area, Iran

    Aminreza Neshat Biswajeet Pradhan

    Saied Pirasteh Helmi Zulhaidi Mohd Shafri

    Received: 14 February 2013 / Accepted: 20 July 2013 / Published online: 2 August 2013

    Springer-Verlag Berlin Heidelberg 2013

    Abstract Groundwater contamination from intensive

    fertilizer application affects conservation areas in a plain.

    The DRASTIC model can be applied in the evaluation of

    groundwater vulnerability to such pollution. The main

    purpose of using the DRASTIC model is to map ground-

    water susceptibility to pollution in different areas. How-

    ever, this method has been used in various areas without

    modification, thereby disregarding the effects of pollution

    types and their characteristics. Thus, this technique must be

    standardized and be approved for applications in aquifers

    and particular types of pollution. In this study, the potential

    for the more accurate assessment of vulnerability to pol-

    lution is achieved by correcting the rates of the DRASTIC

    parameters. The new rates were calculated by identifying

    the relationships among the parameters with respect to the

    nitrate concentration in groundwater. The methodology

    was implemented in the Kerman plain in the southeastern

    region of Iran. The nitrate concentration in water from

    underground wells was tested and analyzed in 27 different

    locations. The measured nitrate concentrations were used

    to associate and correlate the pollution in the aquifer to the

    DRASTIC index. The Wilcoxon rank-sum nonparametric

    statistical test was applied to determine the relationship

    between the index and the measured pollution in Kerman

    plain. Also, the weights of the DRASTIC parameters were

    modified through the sensitivity analysis. Subsequently, the

    rates and weights were computed. The results of the study

    revealed that the modified DRASTIC model performs more

    efficiently than the traditional method for nonpoint source

    pollution, particularly in agricultural areas. The regression

    coefficients showed that the relationship between the vul-

    nerability index and the nitrate concentration was 82 %

    after modification and 44 % before modification. This

    comparison indicated that the results of the modified

    DRASTIC of this region are better than those of the ori-

    ginal method.

    Keywords Modified DRASTIC GIS Groundwater Hydrogeology Sensitivity analysis Kerman plain Vulnerability

    Introduction

    Groundwater is an important and prominent resource in

    most countries, particularly for those in arid and semi-arid

    areas. Water quality has been given more emphasis in

    groundwater management (Pradhan 2009; Ayazi et al.

    2010; Manap et al. 2012, 2013). Aquifers are usually

    unconfined and highly permeable, thereby causing their

    high susceptibility to surface contamination (Javadi et al.

    2011a, b). The potential groundwater pollution by human

    activities at or near the surface has been considered the

    primary basis for the management of this major resource by

    implementing preventive policies.

    The introduction of potential contaminants to a location

    on top of an aquifer at a specified position in an under-

    ground system is defined as groundwater vulnerability

    (National Research Council 1993). Vulnerability assess-

    ment must be based on scientific, accurate, and objective

    A. Neshat B. Pradhan (&) H. Z. M. ShafriDepartment of Civil Engineering, Faculty of Engineering,

    University Putra Malaysia, 43400 Serdang, Selangor, Malaysia

    e-mail: [email protected]; [email protected];

    [email protected]

    S. Pirasteh

    Department of Geography and Environmental Management,

    Faculty of Environment, University of Waterloo, Waterloo,

    Canada

    123

    Environ Earth Sci (2014) 71:31193131

    DOI 10.1007/s12665-013-2690-7

  • evidence. Various methods have been introduced to esti-

    mate groundwater vulnerability with high accuracy (Javadi

    et al. 2011a, b). In most cases, these procedures consist of

    analytical tools intended to correlate groundwater con-

    tamination with land activities. There are three categories

    of assessment processes and procedures: the process-based

    simulation models, the statistical methods (Harbaugh et al.

    2000), and the overlay and index methods (Dixon 2004).

    Process-based models generally require a large amount

    of primary and secondary data to apply the mathematical

    models for creating the principal tool. Such methods seem

    more complex and difficult to use on a regional scale.

    Statistical methods use data on the known areal contami-

    nant distribution and describe the contamination potential

    for a specified geographical region using the available data

    in the regions of interest (National Research Council 1993).

    Overlay and index methods emphasize the combination

    of different regional maps by allocating a numerical index.

    Both methods are easy to apply in geographic information

    systems (GIS), particularly on a regional scale. Therefore,

    these techniques are the most popular methods used in

    vulnerability evaluation. The most widely used among

    these techniques include GOD (Foster 1987), IRISH (Daly

    and Drew 1999), AVI (van Stemproot et al. 1993), and

    DRASTIC (Aller et al. 1987). DRASTIC is widely applied

    in various countries, including the USA (Plymale and

    Angle 2002; Fritch et al. 2000; Shukla et al. 2000), China

    (Yuan et al. 2006; Huan et al. 2012; Yin et al. 2012),

    Jordan (Naqa et al. 2006), Morocco (Ettazarini 2006), Iran

    (Javadi et al. 2011a, b), Palestine (Mimi et al. 2012),

    Tunisia (Saidi et al. 2010, 2011), and Portugal (Pacheco

    and Sanches Fernandes 2012).

    Despite its popularity, the DRASTIC method has some

    disadvantages. The DRASTIC model consists of seven

    hydrogeologic factors: depth of water, net recharge, aquifer

    media, soil media, topography (slope), impact of vadose

    zone, and hydraulic conductivity of the aquifer.

    This approach primarily uses the seven parameters to

    compute for the vulnerability index. Each parameter is

    allocated specific weights and rating values, as shown in

    Table 1 (Aller et al. 1987). The DRASTIC model is con-

    sidered one of the best index models for vulnerability map-

    ping since it was first introduced by Aller et al. (1985, 1987).

    This technique disregards the effects of regional character-

    istics. Therefore, uniform weights and rating values are used.

    Moreover, this method does not use a standard validation test

    for the aquifer. Thus, several researchers have continued to

    develop this model using different methods. Some of the

    notable studies include those by Secunda et al. (1998),

    Melloul and Collin (1998), Zhou et al. (1999), Thirumalai-

    vasan et al. (2003), Dixon (2005), Antonakos and Lambrakis

    (2007), Bojorquez-Tapia et al. (2009), Ckakraborty et al.

    (2007), Denny et al. (2007), Hamza et al. (2007), Leone et al.

    (2009), Nobre et al. (2007), Pathak and Hiratsuka (2011),

    Remesan and Panda (2008), Saidi et al. (2011), and Hailin

    et al. (2011). Several groups attempted to correlate the vul-

    nerability index using chemical or contaminant parameters

    (Kalinski et al. 1994; Rupert 1999; McLay et al. 2001).

    Certain index methods modified the DRASTIC model by

    varying the factors and respective weights or by incorpo-

    rating alternative data on human activities, such as land use

    and contaminant loading. Al-Hanbali and Kondoh (2008)

    combined a human activity impact index derived from land

    use or cover data using the DRASTIC model. Their work

    demonstrated that human activities affect the groundwater

    quality and increase the risk of pollution in the Dead Sea

    groundwater basin in Jordan.

    The existing literature reports a limited number of studies

    on groundwater vulnerability from specific contamination

    sources based on GIS and index methods. This lack of

    information may be due to the previous definition of

    groundwater vulnerability for nonpoint sources. However,

    the existing index methods may still be useful in evaluating

    the risk of groundwater pollution in local and larger scales

    when it is combined with site-specific information, such as

    the hydrogeology and contamination history (Alexander

    et al. 1986). Recent studies have attempted to correlate the

    vulnerability index with chemical or contaminant parame-

    ters (Kalinski et al. 1994; Rupert 1999; McLay et al. 2001),

    whereas others correlate the nearby land to its vulnerability.

    However, the rates or weights of the DRASTIC model could

    not be used efficiently in these investigations.

    Nitrate is not naturally found in surface groundwater. This

    compound is considered a good indicator of contaminant

    movement from the surface to groundwater, particularly in

    land allocated for agricultural use (Javadi et al. 2011a, b).

    Carvalho (2009) conducted pollution risk assessment by

    integrating DRASTIC results with nitrate concentrations.

    Subsequently, other researchers used nitrate to modify

    DRASTIC (Panagopoulos et al. 2006; Javadi et al. 2011a, b).

    Pacheco and Sanches Fernandes (2012) used nitrates to

    perform a correspondence analysis. Panagopoulos et al.

    (2006) and Javadi et al. (2011a, b) calibrated the model using

    nitrate before a correlation coefficient was obtained to

    describe the relationship of the vulnerability index and

    nitrate concentration. In the current study, the rate of

    DRASTIC parameters was calibrated for the study area by

    measuring the nitrate concentration of groundwater. The

    relationship between the vulnerability indicators and the

    parameters was statistically analyzed to calibrate the rates

    using the Wilcoxon rank-sum nonparametric statistical test

    (Wilcoxon 1945). In addition, the single-parameter sensi-

    tivity analysis was applied to compute the effective weight of

    each parameter in the Kerman plain.

    The main contribution of this research compared with

    previously published literature in Javadi et al. (2011a, b) is

    3120 Environ Earth Sci (2014) 71:31193131

    123

  • the use of two nitrate samples in the same month, which

    makes more accurate correlation. Apart from that, the area

    of interest in this study is the Kerman plain which is

    located in the southeastern part of Iran. The Kerman plain

    is located in arid and semiarid regions, with groundwater as

    its only water source because of the scarcity of surface

    water. Moreover, the Kerman plain experiences heavy

    pumping of groundwater, which becomes a serious prob-

    lem because it continuously lowers the water table. The

    majority of the study area is covered with agricultural

    lands, and the application of fertilizers is a common

    practice. The DRASTIC model can be used to demonstrate

    the application of the proposed method and to provide a

    basis for its environmental management.

    Study area

    The Kerman plain is an arid and semi-arid area; the

    majority of the study area is composed of agricultural land.

    Pistachio is the most economically important product in

    this region. The Kerman plain has an area of 978 km2 in

    the southeastern part of Iran (Fig. 1). The highest ground

    elevation in the area is 1,980 m, with the lowest point

    being 1,633 m above sea level. The average annual rainfall

    in the study area was 108.3 mm in 2011. The vadose zone

    consists of silt and clay, sand and gravel, or gravel and sand

    with silt. The aquifer medium is composed of marlstone

    and shale, silt and clay, massive sandstone, or sand and

    gravel. The total net recharge of the study area is 186.06

    million cubic meters per year (MCM per year). The max-

    imum electrical conductivity (EC) in this study area is

    3,880 lmoh/cm (micromhos per centimeter), and theaverage EC is 2,700 lmoh/cm. The minimum EC is1,100 lmoh/cm. In addition, the southeastern regions ofthe plain have the maximum EC. The geology of Kerman

    plain contains Cretaceous and Eocene conglomerates (PC),

    intrusive rocks (gp), Eocene and Neogene volcanism, and

    Neogene, or younger, sediments.

    Materials and methods

    Data and DRASTIC method

    The data used to obtain the hydrogeological parameters of

    the DRASTIC model are listed in Table 2. This method

    was established by the United States Environmental Pro-

    tection Agency (USEPA) to classify the pollution potential

    Table 1 Original DRASTIC weights and rating systems

    Depth to water (m) Recharge (mm) Topography

    (slope %)

    Conductivity (m/

    day)

    Aquifer media Vadose zone material Soil media

    Range Rating Range Rating Range Rating Range Rating Range Rating Range Rating Range Rating

    (01.5) 10 (050.8) 1 (02) 10 (0.044.1) 1 Massive shale 2 Confining

    layer

    1 Thin or

    absent

    10

    (1.54.6) 9 (50.8101.6) 3 (26) 9 (4.112.3) 2 Metamorphic/

    igneous

    3 Silt/clay 3 Gravel 10

    (4.69.1) 7 (101.6177.8) 6 (612) 5 (12.328.7) 4 Weathered

    metamorphic

    igneous

    4 Shale 3 Sand 9

    (9.115.2) 5 (177.8254) 8 (1218) 3 (28.741) 6 Limestone 3 Peat 8

    (15.222.8) 3 ([254) 9 ([18) 1 (4182) 8 Glacial till 5 Sandstone 6 Shrinkingclay

    7

    (22.830.4) 2 ([82) 10 Beddedsandstone,

    limestone

    6 Bedded

    limestone,

    sandstone

    6 Sandy loam 6

    ([30.4) 1 Loam 5

    Massive

    sandstone

    6 Sand and

    gravel

    6 Silty loam 4

    Massive

    limestone

    8 W. silt Clay loam 3

    Sand and gravel 8 Sand and

    gravel

    8 Muck 2

    Basalt 9 Basalt 9 No

    shrinking

    clay

    1

    Karsts

    limestone

    10 Karsts

    limestone

    10

    DRASTIC weight: 5 DRASTIC weight: 4 DRASTIC

    weight: 1

    DRASTIC weight: 3 DRASTIC weight: 3 DRASTIC weight: 5 DRASTIC weight: 2

    Source: Aller et al. (1987)

    Environ Earth Sci (2014) 71:31193131 3121

    123

  • of aquifers (Aller et al. 1987). Vulnerability to contami-

    nation is defined as a dimensionless index function of

    hydrogeological factors, contamination sources, and

    anthropogenic effects in any specific area (Plymale and

    Angle 2002). Groundwater vulnerability commonly refers

    to the potential contamination from nonpoint sources or

    distributed point sources of pollution, such as pesticides or

    nitrates from fertilizers in agricultural practices. Since the

    development of the DRASTIC model (Aller et al. 1987) for

    groundwater vulnerability assessment by USEPA in the

    late 1980s, this type of indexing method has become

    popular, and widely used in the US, and worldwide

    (Sinkevich et al. 2005; Werz and Hotzl 2007). The index

    consists of seven parameters with different weighting fac-

    tors and is calculated by

    V X7

    i1Wi Ri ; 1

    where V is the index value and Wi is the weighted coeffi-

    cient for parameter i, with an associated rating value of Ri.

    The following physical parameters are included in the

    DRASTIC method:

    D Depth to water table from the soil surface

    R net recharge

    A Aquifer media

    S Soil media

    T Topography

    I Impact of the vadose zone media

    C Conductivity (hydraulics) of the aquifer

    Each of these hydrogeological factors is given a rating

    from 1 to 10, and the DRASTIC parameters are

    weighted from 1 to 5 according to their relative

    contribution to the potential contamination (Aller et al.

    1987). The resulting index is a relative measure of vul-

    nerability to contamination. Areas with a higher index

    value are more vulnerable, as compared with those with a

    lower index. The rates and weights of the original

    DRASTIC model parameters are presented by Aller et al.

    (1987). The seven layers of the DRASTIC model are pre-

    sented in Fig. 2.

    Fig. 1 Study area

    Table 2 Sources of data used for creation of hydro-geologicalparameter for DRASTIC method

    No data type Sources

    1. Hydrogelical data Meteorological Organization of

    Kerman

    2. Geology map Geological survey of IRAN

    3. Soil map Soil and water research Institute of

    Kerman

    4. Topography Water organizations of Kerman

    5. Wells Water organizations of Kerman

    6. Hydraulic

    conductivity

    Water organization of Kerman

    7. Geological profile Water organization of Kerman

    8. Groundwater balance

    of Kerman plain

    Water organization of Kerman

    9. Sample wells Surveyed in my study area and took two

    times samples using GSP technique

    3122 Environ Earth Sci (2014) 71:31193131

    123

  • Fig. 2 Seven layers of DRASTIC model (a depth of water, b recharge, c aquifer media, d soil, e topography (slope %), f impact of vadose zone,g hydraulic conductivity)

    Environ Earth Sci (2014) 71:31193131 3123

    123

  • DRASTIC data layers

    The assigned layers for the seven DRASTIC parameters

    were constructed in raster GIS, based on Table 1.

    Depth of water

    The water table depths were measured from 28 observation

    wells. The ArcGIS Geostatistical Analyst extension by

    Krigging interpolation was applied to interpolate the points

    and to develop the raster map with a pixel size of 100 m.

    Krigging was previously used to obtain significant results

    in groundwater level analysis (Kumar 2007; Gundogdu and

    Guney 2007; Theodossiou 1999). The methodology for

    groundwater vulnerability measures the water table depth

    from the surface as the parameter of interest. This param-

    eter represents the distance that a contaminant must travel

    from the surface to reach the groundwater. A deeper water

    level indicates a longer time for contamination (Aller et al.

    1987). The depths to the water levels for the Kerman plain

    are classified into three classes: 1523 m, 2330 m, and

    [30 m, with depth to water rates (Dr) of 3, 2, and 1,respectively. Given that the study area is located in arid and

    semi arid regions, two classes less than 30 m were defined

    to represent the area of irrigation return flow.

    Net recharge (R)

    The net recharge is considered the result of rainfall infil-

    tration, irrigation return flow, and absorption wells in the

    study area. The total net recharge was computed by the

    Kerrman Water Authorities.

    Aquifer media (A)

    Classification of this area was based on the drilling logs for

    each well. Two sections of the aquifer rock are basically

    composed of marl and conglomerate rocks in the southern

    regions and a small area in the northwestern region. The

    extensive sand deposits with a very low percentage of fine-

    grained material were identified as gravel and sand. Deposits of

    fine to coarse sand (fine-medium sand) extended across the

    northern and northeastern regions of the study area. Deposits of

    silt and clay were located exclusively in the middle region of

    the study area. According to Aller et al. (1987) and Rahman

    (2008), glacial till is a mixture of gravel, sand, silt, and clay.

    Soil media (S)

    The soil map of the Soil and Water Institute of Kerman was

    used. The soil media layer indicated the recharge rate that

    could infiltrate into the pollution. The soil map consists of

    clay loam, gravel, loam, non-shrinking and non-aggregated

    clay, sand, sandy loam, and silty loam. Aller et al. (1987)

    stated that the maximum rate belonged to gravel, sand, and

    sandy loam. Based on the observed soil media layer, sand

    with high permeability was located in the northern and

    southern regions of the study area.

    Topography (T)

    Topography in the DRASTIC model displays the slope of

    the land surface. The topography was derived from the

    digital elevation model using a topographic map

    (1:25,000). The topography of the area was divided into

    five classes (Aller et al. 1987), which were mostly found in

    areas with slopes ranging from 0 to 2 % and from 2 to 6 %.

    Impact of the vadose zone (I)

    The impact of the vadose zone was classified based on the

    drilling logs for each well. The most significant part of the

    area included gravel and sand with silt and clay (1530 %)

    in the western region. A small section located in the

    northeastern region of the study area exclusively contains

    gravel and sand.

    Hydraulic conductivity (H)

    The hydraulic conductivity of the aquifer was computed

    according to the following equation: k Tb, where k is the

    hydraulic conductivity of the aquifer (m/s), T is the trans-

    missivity (m2/s), and b is the thickness of the aquifer (m).

    The hydraulic conductivity distribution map was generated

    using pumping test results and a geoelectrical study of the

    area. Regions with maximum hydraulic conductivity

    exhibited higher chances of distribution contamination.

    Hydraulic conductivity was derived by measurement, and

    the GIS-ArcView was applied to interpolate the hydraulic

    conductivity and create the raster layer. Hydraulic con-

    ductivity could be divided into three classes.

    All required layers were created; each layer was classified

    using the different rating scales The DRASTIC index was then

    determined by multiplying the obtained values with the weight

    factor. The obtained index was divided into seven groups

    (Aller et al. 1987). The vulnerability indices and the corre-

    sponding area percentages are presented in Figs. 3 and 4.

    Nitrate measurements

    The nitrate concentration was selected as the main

    parameter of the initial contamination to calibrate the

    DRASTIC model. A total of 27 agricultural wells were

    chosen for the analysis and sampling, with two nitrate

    samples obtained from each well. The first nitrate sample

    3124 Environ Earth Sci (2014) 71:31193131

    123

  • was obtained in May 2010 to calibrate the model, and the

    second nitrate sample was obtained in May 2011 to

    determine the correlation coefficient between the nitrate

    concentration and groundwater vulnerability. The May

    2011 samples were normalized before they were used. The

    exact location of each well was determined using global

    positioning system techniques.

    Calibration method

    The rates of DRASTIC were initially modified using the Wil-

    coxon rank-sum nonparametric statistical test. Subsequently,

    the modified DRASTIC was applied for sensitivity analysis.

    Nitrate was selected as the primary control parameter in the

    study. This parameter was used to change the DRASTIC rates.

    Nitrate is not naturally found in groundwater, but it usually

    enters via the surface. The Kerman plain is situated in an

    agricultural area where fertilizer use is common. Therefore, the

    nitrate concentration can be used as an indicator of the vul-

    nerability index to reflect the actual situation in the study area.

    The following conditions must be met when using nitrate to

    optimize the weights and rates: (1) the mean nitrate concen-

    tration should be an effect of the agricultural activities on the

    surface. (2) The distribution area should be relatively uniform.

    (3) Leaching of nitrate occurs because of recharges from the

    surface over a long period of time. To ensure the correlation

    between contamination and human activities, the vulnerability

    index would increase with the increasing nitrate concentration.

    Finally, the correlation between nitrate concentration and vul-

    nerability would illustrate the higher means vulnerability index.

    Agriculture is the primary activity in the selected study area,

    thereby ensuring that these basic conditions are satisfied (Pan-

    agopoulos et al. 2006; Javadi et al. 2011a, b). The Wilcoxon

    rank-sum nonparametric statistical test was used to modify the

    rates of the DRASTIC model. Sensitivity analysis was then

    applied to optimize the weights of the DRASTIC model.

    Sensitivity analysis

    According to Babiker et al. (2005), Saidi et al. (2011), the

    applied weights for calculating the vulnerability index

    Fig. 3 Original vulnerabilitymap

    Fig. 4 The percentage of DRASTIC result

    Environ Earth Sci (2014) 71:31193131 3125

    123

  • could differ, depending on the study area. The impact of

    the weights of each parameter with their theoretical

    weights was compared using the single-parameter sensi-

    tivity analysis. In this study, the vulnerability index was

    calibrated using rate modification. The influence of the

    parameters in the index computation was evaluated using

    sensitivity analysis. To investigate for any improvement in

    the newly developed DRASTIC map, the nitrate distribu-

    tion was compared. The effective weight of each polygon

    is defined as

    W Pr Pw V 100; 2where W is the effective weight of each parameter and V is

    the overall vulnerability index. Pr and Pw are the rating

    value and weight of each parameter, respectively. The

    ArcGIS software was used to calculate all combinations of

    parameters and their weights. A total of 526 unique suba-

    reas were found in the study area; these subareas were

    considered in the statistical analysis of the results. The

    effective weight derived from the single-parameter sensi-

    tivity analysis is shown in Table 5. The depth to water

    displays the lowest effective weights (mean effective

    weight, 4.12 wt%) compared with the theoretical weights

    (21.74 wt%). The net recharge, aquifer media, and

    hydraulic conductivity had higher effective weights than

    the theoretical weights assigned by DRASTIC.

    Fig. 5 Original vulnerabilitymap and nitrate (NO3)

    concentration for study area

    Table 3 Correlation factors between nitrate concentration and ori-ginal vulnerability index

    Pearsons correlation

    coefficient (%)

    Number of

    data

    Factor

    100 27 Nitrate concentration

    44 DRASTIC index

    Fig. 6 Relationship of DRASTIC intrinsic vulnerability index andmodified DRASTIC to groundwater nitrates concentration for the

    Kerman plain

    3126 Environ Earth Sci (2014) 71:31193131

    123

  • Fig. 7 Modified DRASTICmap

    Table 4 Original and modifiedDRASTIC weighting rates

    based on nitrate concentration

    Depth to water table: nitrate

    concentration divided to six

    classes, not used for depth of

    water

    Factor Range Original rating Mean NO3 Modified rating

    Depth to groundwater 1523 3 No data 3

    2330 2 No data 2

    [30 1 No data 1Recharge (mm) 050.8 1 13.4 7.12

    50.8101.6 3 12.8 6.8

    101.6177.8 6 18.8 10

    Soil type Clay loam 3 15.13 8.1

    Gravel 10 No data 10

    Silty loam 4 13.34 7

    Loam 5 10 5.3

    Sandy loam 6 8.3 4.4

    Sand 9 18.83 10

    Non-shrinking 1 12 6.4

    Topography 02 10 13.13 2.5

    26 9 14.58 2.8

    612 5 11.59 2

    1218 3 53.2 10

    [18 1 No data 1Impact of vadose

    zone

    Silt/clay 3 19.6 10

    Sand and gravel 8 7.4 3.8

    Sand and gravel with silt and

    clay

    6 13 6.7

    Aquifer media Marlstone 2 15.4 9.1

    Silt and clay 5 17 10

    Sandstone 6 No data 6

    Gravel sand 8 13.6 7.9

    Environ Earth Sci (2014) 71:31193131 3127

    123

  • Results and discussion

    Result of index calibration and evaluation

    The difference between the original DRASTIC values and

    the nitrate concentration using a sample of 27 wells in May

    2010 is presented in Fig. 5. Pearsons correlation factor

    (Table 3) was applied to determine the correlation between

    the nitrate concentration and the DRASTIC values, as

    illustrated in Fig. 6. Pearsons correlation value was calcu-

    lated at 44 %. This value is relatively low, thereby indicating

    that the original vulnerability index must be changed to

    obtain a realistic assessment of the potential contamination

    in the study area. The highest nitrate concentration was

    correlated with the highest rate. Other weighting rates were

    linearly changed according to this relation. In the current

    method, the rates of the net recharge, aquifer media,

    hydraulic conductivity, impact of vadose zone, soil media,

    and topography were modified based on the mean nitrate

    concentration. The highest rate was assigned to the highest

    mean nitrate concentration, the lowest rate was assigned to

    the lowest mean concentration, and the remaining rates were

    linearly modified. This approach was applied to all layers, as

    shown in Table 4, and to the new weight of the modified

    DRASTIC model with sensitivity analysis. The new

    DRASTIC map was computed by applying the modified

    system, as shown in Fig. 7. The modified DRASTIC model

    concentration and the percentage of its results are shown in

    Fig. 8. The Pearsons correlation factor was computed for

    the modified DRASTIC model; its value was increased to

    82 % in the new model, as indicated in Table 5 and Fig. 6.

    The calibration results suggested that the modified

    DRASTIC model significantly affects the study area.

    Nitrate is important to obtain better results in the vulner-

    ability map, considering that most of the lands in the

    Kerman plain are agricultural. The new rates and weights

    of the modified DRASTIC map indicated that 41.34 % of

    the area belonged to the very high and high vulnerability

    class. The percentage for this class was 50.09 % before the

    modification. The percentages for the moderate class

    before and after modification were 30.81 and 39.85 %,

    respectively. The low and very low classes covered 19.09

    and 18.81 %, before and after the application of the new

    rates, respectively. These results clarified the effect of

    modification. In addition, maps were compared to show the

    spatial distribution of the index before and after modifi-

    cation, as shown in Fig. 9. The result indicated that

    45.72 % of the results had a similar class, but 54.28 %

    belonged to a different class, thereby verifying the effec-

    tiveness of the proposed method. The first nitrate test in

    2010 was applied to calibrate the DRASTIC model and to

    create the modified DRASTIC model. The second nitrate

    test was used to compute for the correlation factor. The

    application of the new rates and weights to the layers

    clarified the effect of the modification. The region of higher

    vulnerability in both maps is situated around the boundary

    of the study area, which is mainly composed of highly

    permeable sand and gravel. In the modified DRASTIC

    model, the vulnerability increases in the center of the

    Kerman plain because of agricultural activities (Table 6).

    Fig. 8 Percentage of modified DRASTIC result

    Table 5 Single-parametersensitivity analysis on modified

    DRASTIC

    Parameter DRASTIC weight Theoretical weight (%) Effective weight (%)

    Minimum Mean Maximum SD

    D 5 21.74 2.91 4.12 10.49 1.47

    R 4 17.39 14.20 22.47 31.01 4.54

    A 3 13.04 12.33 17.52 26.09 2.99

    S 2 8.70 4.73 9.49 18.35 3.05

    T 1 4.35 0.61 2.34 8.93 2.14

    I 5 21.74 10.71 23.37 35.71 6.40

    C 3 13.04 10.47 15.83 23.81 3.42

    3128 Environ Earth Sci (2014) 71:31193131

    123

  • Conclusion

    The Kerman plain is located in an arid and semi-arid

    region. With groundwater as the only water source in the

    area, the evaluation of groundwater quality is crucial. The

    increased pumping rates from the water table and the

    decreased rainfall in the area accounted for the assessed

    groundwater vulnerability in the area.

    Applying the DRASTIC model in this region usually

    provides a satisfactory assessment of the intrinsic vulner-

    ability of groundwater to pollution. In addition, the

    majority of the area consists of agricultural land where

    inorganic fertilizers are commonly used. Thus, the nitrate

    concentrations in the groundwater are primarily due to the

    leaching of nitrate from the soil surface layers to the

    groundwater. Given the abovementioned considerations,

    the original DRASTIC algorithm required calibration and

    modification to obtain more accurate results. Thus, we

    developed and applied the modified DRASTIC model. The

    correlation factor between the nitrate concentrations and

    the original vulnerability index was evaluated at 44 %,

    whereas the correlation factor between the nitrate con-

    centrations and the modified DRASTIC model was calcu-

    lated at 82 %. These results indicated that the modified

    DRASTIC model could provide better results, as compared

    with the original DRASTIC model. An advantage of the

    modified DRASTIC model is its flexibility for adjusting the

    rates and weights of the said model.

    The modified DRASTIC model in this study is recom-

    mended for evaluating groundwater vulnerability to pol-

    lution in agricultural lands with extensive use of nitrates.

    The conditions of a specific area significantly influence the

    type of modifications to be applied in the DRASTIC model.

    The DRASTIC weights can be varied to improve the model

    in this study.

    Acknowledgments The authors would like to thank Saman Javadiand Mohsen Dadras for their valuable contribution in this manuscript.

    Thanks to three anonymous reviewers for their helpful reviews which

    helped us to improve the quality of the earlier version of the

    manuscript.

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    Estimating groundwater vulnerability to pollution using a modified DRASTIC model in the Kerman agricultural area, IranAbstractIntroductionStudy area

    Materials and methodsData and DRASTIC methodDRASTIC data layersDepth of waterNet recharge (R)Aquifer media (A)Soil media (S)Topography (T)Impact of the vadose zone (I)Hydraulic conductivity (H)

    Nitrate measurementsCalibration method

    Sensitivity analysisResults and discussionResult of index calibration and evaluation

    ConclusionAcknowledgmentsReferences