nan ya nylon 6 engineering plastics

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NAN YA NYLON 6 Engineering Plastics Flame Retardant.High Toughness.Heat Resistant. Impact Resistant.Moldability.Low Warpage

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Page 1: NAN YA NYLON 6 Engineering Plastics

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NAN YA NYLON 6 Engineering PlasticsFlame Retardant.High Toughness.Heat Resistant.

Impact Resistant.Moldability.Low Warpage

Page 2: NAN YA NYLON 6 Engineering Plastics

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IntroductionAs Nylon is a semi-crystalline amido, it can easily form hydrogen bonds with

water molecules, and therefore it has higher moisture absorption than most

resins. If Nylon particles absorb too much moisture, it will cause issues during

the drying process before production and defects in the molding product.

Surface deficiencies in the silver bars or air bubbles will cause a decrease in

quality and the inferior material may not be recycled or reused. Hence, the

pre-production drying process is the most crucial step in Nylon processing.

NAN YA NYLON 6 Engineering Plastics Characteristics1. High toughness and excellent impact resistance.

2. Abrasion resistant and self-lubricating.

3. Good heat resistance, flame retardants, self-extinguishing.

4. Air barrier properties, excellent chemical resistance.

5. Suitable for products that require strength, precision, anti-heat deflection.

Page 3: NAN YA NYLON 6 Engineering Plastics

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From the above properties, it can be observed that the NAN YA NYLON 6 has a wide range of applications as listed below:

NAN YA NYLON 6

APPLICATIONS

Electrical and Electronics

Home appliance external casings, home appliance connector plugs, hair dryer air outlets, circuit breakers, farming tool external casings, external casings of heaters, external casing of fans, and circuit relay external casings.

Automotive Industry

Car handles, door handles, and bicycle brake handles, bicycle rims, and pedals.

Other Industries

Gears, fan blades, reel shafts, fasteners, and external casings of motors.

Others Racket braces, racquet frames, skates bases, connectors and luggage wheels.

Page 4: NAN YA NYLON 6 Engineering Plastics

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Moisture Content (Moisture absorption time after opening package)

Drying Temperature

(℃ )

Drying Time(hrs)

0.2~0.3%(3~8hrs) 80 2~40.3~0.6%(8~24hrs) 80 4~80.6~2.0%(24hrs above) 80 8~24

Graph 1: Drying time and Temperature Test

Graph 2: Drying time, Temperature and Moisture Content Test

◆ Drying Before Nylon is molded, the Nylon plastic particles should be dried to a moisture content of less than 0.2%. When moisture content exceeds 0.2%, jet surfaces will be formed on product surfaces and spoil the exterior appearance. The relations between drying times, temperature and drying hours of NAN YA FR-NYLON 6 are provided below.1. Recommended NAN YA FR-NYLON 6 drying temperature is 80℃ . When temperature is below 80℃ , drying results are not optimal, while at temperatures over 100℃ , drying results are optimal but improper operations will lead to yellowing or inferior product quality, so extra caution must be taken. The relations between drying temperature, drying time and moisture content of NAN YA FR-NYLON 6 ordinary grade (2110) are as provided.2. From the table below, it can be seen that ordinary material with a moisture content below 0.5% can be dried at 80℃ for 4 hours but if moisture content reaches 0.6%, the drying will require 80℃ for 8~24 hours. So when sealing the remaining materials, the package should be sealed tightly to prevent absorption of moisture and drying issues.

PHYSICAL PROPERTIES

0 1 2 3 4 5 6

Drying time (hrs)

0 2 4 6 8

0

0.1

0.2

0.3

0.4

Material: 2110 Drying conditions: 80℃Drying Method: Hot air Drying

FR-NYLON6

0

0.2

0.4

0.6

0.8

Constant temperature constant moisture (23℃ 50%RH)Indoor natural moisture absorption

2110

65℃

100℃

Water-absorbent Particles (%

)W

ater-absorbent Particles (%)

Drying time (hrs)

Page 5: NAN YA NYLON 6 Engineering Plastics

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Graph 3: Reinforced grade test

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3. Graphs 3 and 4 are natural moisture absorption

tests on NAN YA NYLON 6 ordinary grade (2110)

and NAN YA NYLON 6 fiber reinforced grade

(2210G6). The tests allow an understanding of

the relations between moisture absorption rate and

moisture absorption days of NYLON 6 ordinary

grade and fiber reinforced grade under natural

absorption conditions.

PHYSICAL PROPERTIES

Hygroscopic (daily) days

0.000

0.250

0.500

0.750

1.000

1.250

1.500

1.750

2.000

0 5 10 15 20 25 30 35 40 45 50 55 60 65

2110

0.000

0.500

1.000

1.500

2.000

2.500

3.000

3.500

0 5 10 15 20 25 30 35 40 45 50 55 60 65

Constant temperature constantmoisture (23℃ 50%RH)Indoor natural moisture absorption

Constant temperature constant moisture (23℃ 50%RH)Indoor natural moisture absorption

2210G6Moisture content (%)

Moisture content (%)

Hygroscopic (daily) days

Graph 4: Ordinary grade test

Page 6: NAN YA NYLON 6 Engineering Plastics

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Models 2100 2110 2210G3 2210G6Drying Temperature ℃ 80 80 80 80

Drying Time Hrs 4 4 4 4Nozzle Temperature ℃ 235~245 240~250 250~260 250~265

Cylinder Temperature

Front ℃ 230~245 235~245 245~255 245~265Middle ℃ 225~240 230~240 235~245 240~255Rear section ℃ 220~230 225~235 225~240 230~245

Mold Temperature ℃ 60 60 80~90 80~90 Injection Pressure kg/cm2 400~800 400~800 500~1000 600~1500

Screw Rotation Speed rpm 100~160 100~160 100~120 100~120Injection Speed – Fast Fast Fast Fast

Molding Shrinkage(Test Thickness 3mm)

Flow % 1.4~1.8 1.2~1.6 0.3~0.7 0.2~0.3Vertical % 1.4~1.6 1.0~1.5 0.8~1.2 0.5~0.8

Models 2210GC 2210G9 2310 2512Drying Temperature ℃ 80 80 80 80

Drying Time Hrs 4 4 4 4Nozzle Temperature ℃ 265~275 265~275 240~250 240~255

Cylinder Temperature

Front ℃ 260~275 260~275 235~245 240~250Middle ℃ 255~265 255~265 225~235 230~245Rear section ℃ 245~255 245~255 220~230 225~235

Mold Temperature ℃ 100~110 100~110 60 60Injection Pressure kg/cm2 600~1800 600~1800 400~1000 500~1500

Screw Rotation Speed rpm 100~120 100~120 100~120 100~120Injection Speed – Fast Fast Fast Fast

Molding Shrinkage(Test Thickness 3mm)

Flow % 0.2~0.5 0.2~0.3 1.0~1.5 0.6~1.4Vertical % 0.3~0.6 0.4~0.6 1.0~1.5 0.5~1.2

Table 1: NAN YA FR-NYLON 6 Injection Reference Conditions

FR-NYLON 6

10

2

3

5

7

10

180 200 220 240 260 280

2

3

5

7

10( at 100sec-1 )

PE (MI= 0.35)

PE (MI= 2.1)

Melt Viscosity (poise)

Temperature (℃)

High Viscosity

Ordinary GradeHigh Viscosity

Ordinary Grade Medium Viscosity

Ordinary Grade Low Viscosity

◆ Molding Conditions

Table 1 lists the injection mold reference

conditions, including recommended cylinder

temperature settings, injection pressures,

and injection speeds. NAN YA FP-NYLON 6

has a wide range of molding conditions, easy

moldability and has a molding temperature

range of 220℃~270℃ (Resin temperature

refers to the direct temperature measurement

of resin from the injection nozzle), so the

product can be easily molded under the

recommended conditions.

PHYSICAL PROPERTIES

Graph 5: Relation of melt viscosity and temperature

Page 7: NAN YA NYLON 6 Engineering Plastics

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Graph 6: Influence of Injection pressure on flow length

Spiral Flow Test Thickness: 0.8mmMold Temperature: 50℃Cylinder Temperature: 230, 240, 250, 255℃

Graph 7: Influence of Injection pressure on flow length

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◆ Flowability Characteristics

1. Graphs 6 and 7 represent the relation

between injection pressure and flow

length for different product thicknesses

of NAN YA FR-NYLON 6 bulk models.

PHYSICAL PROPERTIES

Spiral Flow Test Thickness: 2.0mmMold Temperature: 50℃Cylinder Temperature: 230, 240, 250, 255℃

2100

2210G6Well Flow Grade

2210G6

2210G9Well Flow Grade

2512

2210G7

2210G9

25

35

45

55

65

75

85

95

105

115

125

135

145

500 600 700 800 900 1000 1100 1200 1300 1400

NYLON 6

2100

2210G6Well Flow Grade

2210G6

2210G9Well Flow Grade

2512

2210G7

2210G9

110

160

210

260

310

360

410

460

510

560

610

660

500 600 700 800 900 1000 1100 1200 1300 1400

Injection Pressure (kg/cm2)

NYLON 6

Spiral Flow Length (mm)Spiral Flow Length (mm)

Injection Pressure (kg/cm2)

Page 8: NAN YA NYLON 6 Engineering Plastics

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PHYSICAL PROPERTIES

2. Graph 8 is the comparison of NAN YA NYLON 6 ordinarygrade(2110)andNANYANYLON6fiber reinforcedgrade(2210G6,2210G9)intheflowability of different thicknesses. For most plastic products, the thicknesswillhaveasignificantimpactontheflowability (L/t ratio, L: Flow Length, t: product thickness). From Graph8,bothNANYANYLON6ordinarygrade(2110) andNANYANYLON6fiberreinforcedgrade (2210G6, 2210G9) are tested for when product thickness is increased from 1mm to 3mm. Although theincreaseisonly2mm,theflowabilityshowsa significantchange.Thisiswhyproductdesigns should avoid uneven thicknesses.

3.Besidesaffectingflowability,productthicknesswill also affect product shrinkage. Products with larger thickness will have a larger shrinkage and require longer cooling time. Hence, in product designs, uneventhicknessshouldbeavoidedtoprevent warping of product. Graph 9 shows the relation of product thickness and product shrinkage of NAN YA NYLON 6 ordinary grade (2110) and NAN YA NYLON6fiberreinforcedgrade(2210GC).

Graph 8: Influence of Product Thickness on Flow Length

Graph 9: Relation of Product Shrinkage and Product Thickness

Molding Temperature2210 Ordinary Grade: 250℃2210GC: 270℃

Processing Conditions:Change Specs to 5mmChange time to 3 secChangepressureto75barInjectionpressure75barMold Temperature 40℃Cylinder Temperature:255, 250, 240, 235℃

0 1 2 3 4

0 0.2 0.4 0.6 0.8 1.0 1.2 1.4 1.6 1.8 2.0 2.2 0

2

4

6

8

Product Shrinkage (%)

Flow Length (%)

Product Thickness (mm)

Product Thickness (mm)

0

500

1000

1500

21002210G62210G9

2110 2210GC

21102210GC

NYLON 6

NYLON 6

Page 9: NAN YA NYLON 6 Engineering Plastics

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Reasons Contents

Heat ageing of materials and breaking of reinforcing materials

Heat stability agents, colorings or reinforcing material type, and quantity

Processing ConditionsPre-drying (Temperature and Time)Molding TemperatureMolding Cycle

Impurities Mold release agents, lubricants, dust, metallic powder, and other resins

USES OF RECYCLED MATERIAL

Currently, use of recycled materials in

molding plants is a common practice but

due to different requirements of product

quality, there are significant differences in

the blending of material. Most engineering

plastics demonstrate differences in physical

properties during recycling. The causes of

the differences can be summarized in

Table 2 on the right.

◆ Notes for using Recycled Materials

1. The recycled materials must be dried again.

2. The materials should be mixed evenly before processing.

3. Impurities should be avoided.

4. The processing temperature should be slightly reduced.

Table 2: Reasons for Decrease in Physical Properties of Engineering Plastics

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Page 10: NAN YA NYLON 6 Engineering Plastics

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PLASTICS 3RD DIV.·ENGINEERING PLASTICSADD: NO. 201, Dunhua N. Rd, Taipei CityTEL: 886-2-27122211 EXT. 5813~5814FAX: 886-2-27198661