L1033928 GBRI/09V PPE 4085053 1257/17

3 litres

BANNER MAXX ll is an emulsifiable concentrate formulation containing 162 g/l propiconazole

A broad spectrum foliar fungicide with systemic properties for control of Dollar Spot (Sclerotinia homoeocarpa), Fusarium Patch (Microdochium nivale) and Anthracnose (Colletotrichum graminicola) on stadium pitches, bowling greens, golf greens, golf tees and golf fairways.

The (COSHH) Control of Substances Hazardous to Health Regulations may apply to the use of this product at work. (UK only)

Product names marked ® or ™ , the ALLIANCE FRAMEthe SYNGENTA Logo and the PURPOSE ICON are Trademarks of a Syngenta Group Company

BANNER MAXX IIDangerHarmful if swallowed.Toxic to aquatic life with long lasting effects.Keep out of reach of childrenDo not eat, drink or smoke when using this product.IF SWALLOWED: Call a POISON CENTRE or doctor/physician if you feel unwell.Rinse mouth.Collect spillage.Dispose of contents/container to a licensed hazardous-waste disposal contractor or collection site except for triple rinsed empty clean containers which can be disposed of as non-hazardous waste.To avoid risks to human health and the environment comply with the instructions for use.Contains propiconazole. May cause an allergic reaction. MAPP 18038

PCS No. 05461

This product label is compliant with the CPA Voluntary Initiative (VI) guidance. (UK only)

Approval Holder and Marketing Company (UK) Marketing Company (Ireland)

Syngenta UK LimitedCPC 4, Capital Park, Fulbourn, Cambridge CB21 5XETel: Cambridge (01223) 883400

Syngenta Ireland LimitedBlock 6, Cleaboy Business Park, Old Kilmeaden Road, Waterford, IrelandTel: (051) 377203

PROTECT FROM FROST

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IMPORTANT INFORMATIONFOR USE ONLY AS A HORTICULTURAL FUNGICIDE.

For use on:

Crops Maximum individual dose (product/ha)

Maximum number of treatments

Maximum total dose (product/ha)

Stadium pitches, bowling greens, golf greens, golf tees

3.0 litres 2 per year* 6.0 litres

Golf fairways 3.0 litres 1 per year 3.0 litres

Other specific restrictions: * A minimum interval of 14 days should be observed between applications

READ THE LABEL BEFORE USE. USING THIS PRODUCT IN A MANNER THAT IS INCONSISTENT WITH THE LABEL MAY BE AN OFFENCE. FOLLOW THE CODE OF PRACTICE FOR USING PLANT PROTECTION PRODUCTS

SAFETY PRECAUTIONS(a) Operator protection (COSHH applies to UK only)Engineering controls of operator exposure must be used where reasonably practicable in addition to the following personal protective equipment:OPERATORS MUST WEAR SUITABLE PROTECTIVE CLOTHING (COVERALLS) AND SUITABLE PROTECTIVE GLOVES when applying by hand-held equipment.OPERATORS MUST WEAR SUITABLE PROTECTIVE GLOVES when handling the concentrate or contaminated surfaces.However, engineering controls may replace personal protective equipment if a COSHH assessment shows they provide an equal or higher standard of protection.DO NOT BREATHE SPRAY.WASH ALL PROTECTIVE CLOTHING thoroughly after use especially the insides of gloves.WASH SPLASHES from skin or eyes immediately.WASH HANDS AND EXPOSED SKIN before eating and drinking and after work

(b) Environmental protection Do not contaminate water with the product or its container. Do not clean application equipment near surface water. Avoid contamination via drains from farmyards and roads.RISK TO NON-TARGET INSECTS OR OTHER ARTHROPODS. See Directions for use.

(c) Storage and disposalKEEP IN ORIGINAL CONTAINER, tightly closed in a safe placeRINSE CONTAINER THOROUGHLY by using an integrated pressure rinsing device or manually rinsing three times. Add washings to sprayer at time of filling and dispose of safely.

L1033929 GBRI/09V PPE 4085056 1257/17

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This leaflet is part of the approved Product Label.

DIRECTIONS FOR USEIMPORTANT: This information is approved as part of the Product Label. All instructions within this section must be carefully read in order to obtain safe and successful use of this product.

GENERAL INFORMATION BANNER MAXX II is an emulsifiable concentrate formulation containing 162 g/l propiconazole.

Propiconazole is rapidly absorbed by the assimilating parts of the plant, mostly within one hour of treatment. It is transported acropetally (upwards) in the xylem. This systemic translocation contributes to good distribution of the active ingredient within the plant tissue.

Propiconazole is a member of the DMI-fungicides group (demethylation inhibitors) These materials act on the fungal pathogen inside the plant at the stage of first haustoria formation and stop disease development by interfering with sterol biosynthesis in fungal cell membranes.Propiconazole has protective, curative and eradicant activity, although best results will be achieved when BANNER MAXX II is applied when the disease is still in the early stages of development. It is recommended that application begins when conditions are favourable for disease infection and at the very beginning of disease symptom expression.

RESTRICTIONSPrevent spray drift on to surrounding areasThe best available application equipment which minimises off-target drift should be used to reduce effects on non-target insects or other arthropods.DO NOT apply to turf under heat or moisture stress

For applications by vehicle mounted/drawn hydraulic boom sprayer, avoid spraying within 5m of unmanaged land (including rough grassland) to reduce effects on non-target insects or other arthropods.

DISEASES CONTROLLEDBANNER MAXX II is a systemic fungicide for the control of the following diseases in managed amenity turf and amenity grassland:

STADIUM PITCHES, BOWLING GREENS, GOLF GREENS, GOLF TEES (2 applications)• Dollar Spot (Sclerotinia homeocarpa) - Control• Fusarium Patch (Microdochium nivale) - Control• Anthracnose (Colletotrichum graminicola) *– Moderate control

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GOLF FAIRWAYS (one application)• Dollar Spot (Sclerotinia homeocarpa) - Reduction• Fusarium Patch (Microdochium nivale) – Moderate control• Anthracnose (Colletotrichum graminicola) *– Moderate control

* As a QUALIFIED MINOR USE RECOMMENDATION, evidence of effectiveness against Anthracnose (Colletotrichum graminicola) disease is limited.

For optimum turf quality and disease control, use BANNER MAXX II in conjunction with turf management practices that promote good plant health.

Correct identification of the disease(s) is essential in selecting the most appropriate control measures.

CROP SPECIFIC INFORMATION Begin applications when conditions are favourable for disease infection, at the very beginning of disease symptom expression.

Crop ToleranceWhen used as recommended, BANNER MAXX ll is well tolerated by all common turf grass species.

Rates of UseApply 3 litres BANNER MAXX II per hectare in 200-400 litres water per hectare.

For spot treatments, use 30 ml BANNER MAXX II per 4-10 litres water per hectare.

TimingApply in a preventative spray programme of 2 sprays per season for stadium pitches, bowling greens, golf greens, golf tees, starting when conditions become favourable for disease development. Apply 1 spray per season to golf fairways starting when conditions become favourable for disease development.

Apply 3 litres of BANNER MAXX II per hectare, with a maximum of two sprays with a minimum 14 day spray interval.

RESISTANCE MANAGEMENT In order to minimise the likelihood of the development of resistance, it is recommended that BANNER MAXX II should be used in a programme with products of different chemical groups.

Use BANNER MAXX II in a disease control programme, alternating treatments with other fungicides having different modes of action e.g. chlorothalonil-based products

BANNER MAXX II contains propiconazole, a SBI fungicide, applications should be made in accordance with the FRAG-UK guidelines.

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Apply BANNER MAXX II at full recommended rates. Utilize management practices, which encourage healthy turf and reduce turf stress.

APPLICATION

VOLUME OF WATER AND SPRAYING

BANNER MAXX II may be applied through tractor mounted boom sprayers and hand-held knapsack sprayers. Application equipment should be calibrated before use.

BANNER MAXX II is recommended to be applied in 200-400 litres water/ha with all application methods.

MIXING AND SPRAYINGTractor-mounted/trailed sprayers: Make sure the sprayer is set to give an even application at the correct volume and an even deposit. Half fill the spray tank with the required volume of clean water and start agitation. Add the required amount of BANNER MAXX II to the spray tank. Agitate the mixture thoroughly before use and continue agitation during spraying. Thoroughly wash all spray equipment with water immediately after use.

Hand-held and knapsack sprayers: Half fill the spray tank with clean water and add the required quantity of BANNER MAXX II to the tank. Complete filling, mix thoroughly and use immediately.

Thoroughly wash all spraying equipment immediately after use.

Wash out containers thoroughly, preferably using an integrated pressure rinsing device, or manually rinse three times. Add washings to the sprayer at the time of filling. Complete filling to the required volume and continue to agitate throughout the spraying operation.

Do not leave the spray liquid in the sprayer for long periods (such as during meal breaks or overnight). Make up only the amount of spray required for immediate use.

AFTER SPRAYINGThoroughly wash out sprayer according to manufacturer’s guidelines and dispose of washings and clean containers according to DEFRA Code of Practice and local water authority guidelines.

This product is to be used only in accordance with the recommendations and instructions given on the labels provided with this pack.

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Section 6 of the Health and Safety at Work ActAdditional Product Safety Information

(This section does not form part of the product label under the Control of Pesticides Regulations 1986.)

The product label provides information on a specific pesticidal use of the product; do not use otherwise, unless you have assessed any potential hazard involved, the safety measures required and that the particular use has ‘extensions of use’ approval or is otherwise permitted under the Control of Pesticides Regulations.

The information on this label is based on the best available information including data from test results.

Safety Data Sheet

SECTION 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING1.1 Product identifierTrade name: BANNER MAXX IIDesign code: A6780LProduct Registration number: MAPP 18038, PCS No. 05461

1.2 Relevant identified uses of the substance or mixture and uses advised againstUse Fungicide

1.3 Details of the supplier of the safety data sheet CompanyCompany: Syngenta UK Limited CPC4, Capital Park Fulbourn, Cambridge CB21 5XE United KingdomTelephone: +44 (0) 1223 883400Telefax: +44 (0) 1223 882195E-mail address: customer.services@syngenta.com

Marketing Company: Syngenta Ireland Limited Block 6, Cleaboy Business Park, Old Kilmeaden Road, Waterford, IrelandTelephone: +44 (051) 377203

1.4 Emergency telephone number Emergency telephone number +44 1484 538444

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SECTION 2. HAZARDS IDENTIFICATION2.1 Classification of the substance or mixtureClassification (REGULATION (EC) No 1272/2008)Acute toxicity, Category 4 H302: Harmful if swallowed.Chronic aquatic toxicity, Category 2 H411: Toxic to aquatic life with long lasting effects.2.2 Label elementsLabelling: Regulation (EC) No. 1272/2008

Hazard pictograms

Signal Word WarningHazard Statements

H302H411

Harmful if swallowed.Toxic to aquatic life with long lasting effects.

Supplemental Hazard Statements

EUH401

EUH208

To avoid risks to human health and the environ-ment, comply with the instructions for use.Contains propiconazole. May produce an allergic reaction.

Precautionary Statements

Prevention:P264 Wash skin thoroughly after handling.P270 Do not eat, drink or smoke when using this product.Response:P301+P312 +P330

IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth.

P391 Collect spillage.Disposal:P501 Dispose of contents/ container to an approved

waste disposal plant.

Hazardous components which must be listed on the label:• propiconazole

Precautionary statements:P501 Dispose of contents/container to a licensed hazardous-waste disposal con-tractor or collection site except for empty triple rinsed clean containers which can be disposed of as non-hazardous waste.

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2.3 Other hazardsThis substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS3.2 MixturesHazardous components

Chemical Name CAS-No. EC-No. Index-No. Registration number

Classification Concentration (% w/w)

propiconazole 60207-90-1262-104-4613-205-00-0

Acute Tox. 4; H302Skin Sens. 1; H317Aquatic Acute 1; H400Aquatic Chronic 1; H410

>= 10 - < 20

propylene carbonate

108-32-7203-572-1607-194-00-101-2119537232-48

Eye Irrit. 2; H319 >= 3 - < 10

For explanation of abbreviations see section 16.

SECTION 4. FIRST AID MEASURES4.1 Description of first aid measuresGeneral advice: Have the product container, label or Safety Data Sheet with you when calling the emergency number, a poison control center or physician, or going for treatment.If inhaled: Move the victim to fresh air. If breathing is irregular or stopped, administer artificial respiration. Keep patient warm and at rest. Call a physician or poison control centre immediately.In case of skin contact: Take off all contaminated clothing immediately. Wash off immediately with plenty of water. If skin irritation persists, call a physician.Wash contaminated clothing before re-use.In case of eye contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses. Immediate medical attention is required.If swallowed: If swallowed, seek medical advice immediately and show this container or label. Do NOT induce vomiting 4.2 Most important symptoms and effects, both acute and delayed Symptoms: No information available. 4.3 Indication of any immediate medical attention and special treatment neededTreatment: There is no specific antidote available. Treat symptomatically.

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SECTION 5. FIRE-FIGHTING MEASURES5.1 Extinguishing mediaSuitable extinguishing media:Extinguishing media - small firesUse water spray, alcohol-resistant foam, dry chemical or carbon dioxide.Extinguishing media - large firesAlcohol-resistant foam or Water sprayUnsuitable extinguishing media:Do not use a solid water stream as it may scatter and spread fire.5.2 Specific hazards arising from the substance or mixture Specific hazards during fire-fighting: As the product contains combustible organic components, fire will produce dense black smoke containing hazardous products of combustion (see section 10). Exposure to decomposition products may be a hazard to health.5.3 Advice for firefighters Special protective equipment for firefighters: Wear full protective clothing and self-contained breathing apparatus. Further information: Do not allow run-off from fire fighting to enter drains or water courses. Cool closed containers exposed to fire with water spray.

SECTION 6. ACCIDENTAL RELEASE MEASURES6.1 Personal precautions, protective equipment and emergency proceduresPersonal precautions: Refer to protective measures listed in sections 7 and 8.6.2 Environmental precautionsEnvironmental precautions: Prevent further leakage or spillage if safe to do so. Do not flush into surface water or sanitary sewer system. If the product contaminates rivers and lakes or drains inform respective authorities.6.3 Methods and materials for containment and cleaning upMethods for cleaning up: Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). Clean contaminated surface thoroughly. Clean with detergents. Avoid solvents. Retain and dispose of contaminated wash water.6.4 Reference to other sections For disposal considerations see section 13., Refer to protective measures listed in sections 7 and 8.

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SECTION 7. HANDLING AND STORAGE7.1 Precautions for safe handlingAdvice on safe handling: No special protective measures against fire required. Avoid contact with skin and eyes. When using do not eat, drink or smoke. For personal protection see section 8.7.2 Conditions for safe storage, including any incompatibilitiesRequirements for storage areas and containers: No special storage conditions required. Keep containers tightly closed in a dry, cool and well-ventilated place. Keep out of the reach of children. Keep away from food, drink and animal feedingstuffs.7.3 Specific end use(s)Specific use(s): For proper and safe use of this product, please refer to the approval conditions laid down on the product label.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION8.1 Control parametersOccupational Exposure Limits

Components CAS-No. Value type (Form of exposure)

Control parameters

Basis

propiconazole 60207-90-1 TWA 5 mg/m3 SYNGENTA

8.2 Exposure controls Engineering measuresContainment and/or segregation is the most reliable technical protection measure if exposure cannot be eliminated. The extent of these protection measures depends on the actual risks in use. Maintain air concentrations below occupational exposure standards. Where necessary, seek additional occupational hygiene advice.Personal protective equipmentEye protection: No special protective equipment required.Hand protectionRemarks: No special protective equipment required.Skin and body protection: No special protective equipment required. Select skin and body protection based on the physical job requirements.Respiratory protection: No personal respiratory protective equipment normally required. When workers are facing concentrations above the exposure limit they must use appropriate certified respirators.Protective measures: The use of technical measures should always have priority over the use of personal protective equipment. When selecting personal protective equipment, seek appropriate professional advice.

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SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES9.1 Information on basic physical and chemical properties

Appearance: Liquid Colour: light amberOdour: oilyOdour Threshold: No data availablepH: 4 - 8 Concentration: 1 %Flash-Point: > 230 °CEvaporation rate: No data availableLower explosion limit: No data availableUpper explosion limit: No data availableRelative vapour density: No data availableDensity: 1.13 g/cm3 (25 °C)Auto-ignition temperature: 370 °CDecomposition temperature: No data availableViscosity Viscosity, dynamic: 254 mPa.s (20 °C) 75 mPa.s (40 °C)Explosive Properties: Not explosiveOxidising properties: The substance or mixture is not classified as oxidizing.

9.2 Other InformationSurface tension: 39.3 mN/m, 0.1 %, 20 °C

SECTION 10. STABILITY AND REACTIVITY10.1 ReactivityNone reasonably foreseeable.10.2 Chemical stabilityStable under normal conditions.10.3 Possibility of hazardous reactionsHazardous reactions: No dangerous reaction known under conditions of normal use.10.4 Conditions to avoidConditions to avoid: No decomposition if used as directed.10.5 Incompatible materialsMaterials to avoid: None known.10.6 Hazardous decomposition productsCombustion or thermal decomposition will evolve toxic and irritant vapours.

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SECTION 11. TOXICOLOGICAL INFORMATION11.1 Information on toxicological effectsAcute toxicityProduct:Acute oral toxicity: LD50 (Rat, female): 1,750 mg/kgAcute inhalation toxicity: LC50 (Rat, male and female): > 2.55 mg/l Exposure time: 4 h Test atmosphere: dust/mist Assessment: The substance or mixture has no acute inhalation toxicityAcute dermal toxicity: LD50 (Rat, male and female): > 5,000 mg/kgComponents:propiconazole:Acute oral toxicity: LD50 (Rat, male and female): 1,517 mg/kgAcute inhalation toxicity: LC50 (Rat, male and female): > 5,800 mg/m3 Exposure time: 4 h Test atmosphere: dust/mistAcute dermal toxicity: LD50 (Rat, male and female): > 4,000 mg/kg Assessment: The substance or mixture has no acute dermal toxicitypropylene carbonate:Acute dermal toxicity: LD50 (Rabbit, male): > 2,000 mg/kg Assessment: The substance or mixture has no acute dermal toxicity

Skin corrosion/irritationProduct:Species: RabbitResult: No skin irritationComponents:propiconazole:Species: RabbitResult: No skin irritationpropylene carbonate:Species: RabbitResult: No skin irritation

Serious eye damage/eye irritationProduct:Species: RabbitResult: No eye irritation

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Components:propiconazole:Species: RabbitResult: No eye irritationpropylene carbonate:Species: RabbitResult: irritating

Respiratory or skin sensitisationProduct:Test Type: Buehler TestSpecies: Guinea pigResult: Did not cause sensitisation on laboratory animals.Components:propiconazole:Species: Guinea pigResult: May cause sensitisation by skin contact.propylene carbonate:Species: manResult: Did not cause sensitisation on laboratory animals.

Germ cell mutagenicityComponents:propiconazole:Germ cell mutagenicity - Assessment: Animal testing did not show any mutagenic effects.propylene carbonate:Germ cell mutagenicity - Assessment: Animal testing did not show any mutagenic effects., Tests on bacterial or mammalian cell cultures did not show mutagenic effects.

CarcinogenicityComponents:propiconazole:Carcinogenicity - Assessment: Animal testing did not show any carcinogenic effects.propylene carbonate:Carcinogenicity - Assessment: Not classifiable as a human carcinogen.

Reproductive toxicityComponents:propiconazole:Reproductive toxicity - Assessment: Animal testing did not show any effects on fertility., No toxicity to reproduction

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propylene carbonate:Reproductive toxicity - Assessment: No toxicity to reproductionNo evidence of adverse effects on sexual function and fertility, or on development, based on animal experiments.

Repeated dose toxicityComponents:propiconazole:Remarks: No adverse effect has been observed in chronic toxicity tests.

SECTION 12. ECOLOGICAL INFORMATION12.1 ToxicityProduct:Toxicity to fish:LC50 (Oncorhynchus mykiss (rainbow trout)): 25 mg/lExposure time: 96 hRemarks: Based on test results obtained with similar product.LC50 (Lepomis macrochirus (Bluegill sunfish)): 36 mg/lExposure time: 96 hRemarks: Based on test results obtained with similar product.Toxicity to daphnia and other aquatic invertebrates:EC50 (Daphnia magna (Water flea)): 8.5 mg/lExposure time: 48 hRemarks: Based on test results obtained with similar product.Toxicity to algae:ErC50 (Pseudokirchneriella subcapitata (green algae)): 44 mg/lExposure time: 96 hRemarks: Based on test results obtained with similar product.NOEC (Pseudokirchneriella subcapitata (green algae)): 0.46 mg/lEnd point: Growth rateExposure time: 96 hRemarks: Based on test results obtained with similar product.Components:propiconazole:Toxicity to fish:LC50 (Oncorhynchus mykiss (rainbow trout)): 4.3 mg/lExposure time: 96 hToxicity to daphnia and other aquatic invertebrates:EC50 (Daphnia magna Straus): 10.2 mg/lExposure time: 48 hEC50 (Americamysis bahia (Mysid shrimp)): 0.51 mg/lExposure time: 96 h

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Toxicity to algae:ErC50 (Pseudokirchneriella subcapitata (green algae)): 8.9 mg/lExposure time: 96 hNOEC (Pseudokirchneriella subcapitata (green algae)): 0.13 mg/lEnd point: Growth rateExposure time: 96 hM-Factor (Acute aquatic toxicity): 1Toxicity to microorganisms:EC50 (activated sludge): > 100 mg/lExposure time: 3 hToxicity to fish (Chronic toxicity):NOEC: 0.068 mg/lExposure time: 95 dSpecies: Cyprinodon variegatus (sheepshead minnow)Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity):NOEC: 0.11 mg/lExposure time: 28 dSpecies: Americamysis bahia (Mysid shrimp)M-Factor (Chronic aquatic toxicity): 1Ecotoxicology AssessmentAcute aquatic toxicity: Very toxic to aquatic life.

12.2 Persistence and degradabilityComponents:propiconazole:Biodegradability: Result: Not readily biodegradable.propylene carbonate:Biodegradability: Result: Readily biodegradable.

12.3 Bioaccumulative potentialComponents:propiconazole:Bioaccumulation: Remarks: Low to medium mobility in soil.Partition coefficient: n-octanol/water: log Pow: 3.72 (25 °C)

12.4 Mobility in soilComponents:propiconazole:Distribution among environmental compartments: Remarks: Low to medium mobility in soil.Stability in soil: Dissipation time: 66 - 170 dPercentage dissipation: 50 % (DT50)Remarks: Product is not persistent.

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12.5 Results of PBT and vPvB assessmentProduct:Assessment: This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.Components:propiconazole:Assessment: This substance is not considered to be persistent, bioaccumulating and toxic (PBT). This substance is not considered to be very persistent and very bioaccumulating (vPvB).propylene carbonate:Assessment: This substance is not considered to be persistent, bioaccumulating and toxic (PBT). This substance is not considered to be very persistent and very bioaccumulating (vPvB).

12.6 Other adverse effectsNo data available

SECTION 13. DISPOSAL CONSIDERATIONS 13.1 Waste treatment methodsProduct: Do not contaminate ponds, waterways or ditches with chemical or used container. Do not dispose of waste into sewer. Where possible recycling is preferred to disposal or incineration. If recycling is not practicable, dispose of in compliance with local regulations.Contaminated packaging: Empty remaining contents. Triple rinse containers. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not re-use empty containers.Waste Code: uncleaned packagings150110, packaging containing residues of or contaminated by dangerous substances

SECTION 14. TRANSPORT INFORMATION 14.1 UN number ADN: UN 3082 ADR: UN 3082 RID: UN 3082 IMDG: UN 3082 IATA: UN 3082

14.2 UN proper shipping name ADN: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (PROPICONAZOLE)

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ADR: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (PROPICONAZOLE) RID: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (PROPICONAZOLE) IMDG: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (PROPICONAZOLE) IATA: Environmentally hazardous substance, liquid, n.o.s. (PROPICONAZOLE)

14.3 Transport hazard class(es) ADN: 9 ADR: 9 RID: 9 IMDG: 9 IATA: 9

14.4 Packing group ADN Packing group: III Classification Code: M6 Hazard Identification Number: 90 Labels: 9 ADR Packing group: III Classification Code: M6 Hazard Identification Number: 90 Labels: 9 Tunnel restriction code: (-) RID Packing group: III Classification Code: M6 Hazard Identification Number: 90 Labels: 9 IMDG Packing group: III Labels: 9 EmS Code: F-A, S-F IATA (Cargo) Packing instruction (cargo aircraft): 964 Packing instruction (LQ): Y964 Packing group: III Labels: Miscellaneous

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IATA (Passenger) Packing instruction (passenger aircraft): 964 Packing instruction (LQ): Y964 Packing group: III Labels: Miscellaneous

14.5 Environmental hazards ADN Environmentally hazardous: yes ADR Environmentally hazardous: yes RID Environmentally hazardous: yes IMDG Marine pollutant: yes IATA (Passenger) Marine pollutant: yes IATA (Cargo) Marine pollutant: yes

14.6 Special precautions for user Not applicable

14.7 Transport in bulk according to Annex II of Marpol and the IBC Code Not applicable for product as supplied.

SECTION 15. REGULATORY INFORMATION15.1 Safety, health and environmental regulation/legislation specific for the substance or mixtureSeveso III: Directive 2012/18/EU of the European Parliament and of the Council on the control of major-accident hazards involving dangerous substances.

Quantity 1 Quantity 2 E2 ENVIRONMENTAL HAZARDS 200 t 500 t

Other regulations: Take note of Directive 98/24/EC on the protection of the health and safety of workers from the risks related to chemical agents at work. Use plant protection products safely. Always read the label and product information before use.

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15.2 Chemical safety assessment A Chemical Safety Assessment is not required for this substance when it is used in the specified applications.

SECTION 16. OTHER INFORMATIONFull text of H-StatementsH302: Harmful if swallowed.H317: May cause an allergic skin reaction.H319: Causes serious eye irritation.H400: Very toxic to aquatic life.H410: Very toxic to aquatic life with long lasting effects.

Full text of other abbreviationsAcute Tox.: Acute toxicityAquatic Acute: Acute aquatic toxicityAquatic Chronic: Chronic aquatic toxicityEye Irrit.: Eye irritationSkin Sens.: Skin sensitisation

ADN - European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways; ADR - European Agreement concerning the International Carriage of Dangerous Goods by Road; AICS - Australian Inventory of Chemical Substances; ASTM - American Society for the Testing of Materials; bw - Body weight; CLP - Classification Labelling Packaging Regulation; Regulation (EC) No 1272/2008; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the German Institute for Standardisation; DSL - Domestic Substances List (Canada); ECHA - European Chemicals Agency; EC-Number - European Community number; ECx - Concentration associated with x% response; ELx - Loading rate associated with x% response; EmS - Emergency Schedule; ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with x% growth rate response; GHS - Globally Harmonized System; GLP - Good Laboratory Practice; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; IBC - International Code for the Construction and Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory concentration; ICAO - International Civil Aviation Organization; IECSC - Inventory of Existing Chemical Substances in China; IMDG - International Maritime Dangerous Goods; IMO - International Maritime Organization; ISHL - Industrial Safety and Health Law (Japan); ISO - International Organisation for Standardization; KECI - Korea Existing Chemicals Inventory; LC50 - Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test population (Median Lethal Dose); MARPOL - International Convention for the Prevention of Pollution from Ships; n.o.s.

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- Not Otherwise Specified; NO(A)EC - No Observed (Adverse) Effect Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable Effect Loading Rate; NZIoC - New Zealand Inventory of Chemicals; OECD - Organization for Economic Co-operation and Development; OPPTS - Office of Chemical Safety and Pollution Prevention; PBT - Persistent, Bioaccumulative and Toxic substance; PICCS - Philippines Inventory of Chemicals and Chemical Substances; (Q)SAR - (Quantitative) Structure Activity Relationship; REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the Council concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals; RID - Regulations concerning the International Carriage of Dangerous Goods by Rail; SADT - Self-Accelerating Decomposition Temperature; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Substance Inventory; TSCA - Toxic Substances Control Act (United States); UN - United Nations; UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods; vPvB - Very Persistent and Very Bioaccumulative

Further informationClassification of the mixture: Classification procedure:Acute Tox. 4 H302 On basis of test data.Aquatic Chronic 2 H411 On basis of test data.

The information provided in this Safety Data Sheet is correct to the best of our knowledge, infor-mation and belief at the date of its publication. The information given is designed only as a guid-ance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.

Product names are a trademark or registered trademark of a Syngenta Group Company.

SPECIMEN -

2017

TO DATE