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    When do scientific theories change?

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    Democritus develops the idea of atoms

    460 B.C.

    he pounded up materials until he had reduced

    them to smaller and smaller particles which

    he called

    ATOMA

    (greek for indivisible)

    Were Democritus tiny particles really undividable?

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    The Greeks believed

    that all matter was made from 4 elements

    Aristotle (384-322 BC)Fire is NOT matter! What form of energy is fire?

    WRONG

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    1803 John Dalton

    EXPERIMENTAL OBSERVATIONS

    Combined elements to form compounds

    Observed that the ratio of elements in acompound was always the same

    element + element = compound

    Magnesium + oxygen = magnesium oxide

    10 grams + 6.58 grams = 16.58 grams

    1000 grams + 658 grams = 1,658 grams

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    1803 John Dalton

    Theory (model)

    All matter is made of particles that

    cant be divided ATOMS

    An ATOM is like a solid sphere

    Elements are made of 1 type of atom

    Compounds contain more than 1 kind

    of atom

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    1897 JJ Thompson

    EXPERIMENTAL OBSERVATIONS

    Negatively charged beam attracted to a

    positive plate (magnet)

    ELECTRON

    Sealed tube filled with gas

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    JJ THOMSON

    Theory (model)

    Negative(-) particles are a part of the atom

    Since the atom as a whole, is neutral, there must also be

    positive (+) matter within the atom

    Chocolate Chip IceCream Model

    Chips are negativeparticles

    Ice cream is positivematter

    1897

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    1911 Ernest Rutherford

    oversaw Geiger and Marsden carrying out his

    famous gold foil experiment.

    they fired Helium nuclei (also called alpha

    particles) at a very, very thin piece of gold

    foil(only a few atoms thick).

    They predicted that the alpha particles

    would pass right through the foil.

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    1911 Ernest Rutherford

    Experimental Observations

    They found that most

    of the alpha particles

    passed through the foil.

    However, about 1 in10,000 were deflectedhttp://regentsprep.org/Regents/physics/phys05/catomodel/ruther.htm

    http://regentsprep.org/Regents/physics/phys05/catomodel/ruther.htmhttp://regentsprep.org/Regents/physics/phys05/catomodel/ruther.htm
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    1911 Ernest Rutherford

    Theory (model)

    Alpha particle deflection

    was caused by a dense

    nucleus

    the positive chargein an

    atom are concentrated in

    the nucleus

    Predicted result

    Actual result

    What do the blue circles on the diagram represent?

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    1913 Niels Bohr

    studied under Rutherford at the

    Victoria University in Manchester.

    Bohr refined Rutherford's idea by

    adding that the electrons were in

    orbits.like planets orbiting the

    sun.

    Link to Niels Bohrs paper on Atoms and Molecules

    http://dbhs.wvusd.k12.ca.us/webdocs/Chem-History/Bohr/Bohr-1913a.html

    http://dbhs.wvusd.k12.ca.us/webdocs/Chem-History/Bohr/Bohr-1913a.htmlhttp://dbhs.wvusd.k12.ca.us/webdocs/Chem-History/Bohr/Bohr-1913a.htmlhttp://dbhs.wvusd.k12.ca.us/webdocs/Chem-History/Bohr/Bohr-1913a.htmlhttp://dbhs.wvusd.k12.ca.us/webdocs/Chem-History/Bohr/Bohr-1913a.htmlhttp://dbhs.wvusd.k12.ca.us/webdocs/Chem-History/Bohr/Bohr-1913a.htmlhttp://dbhs.wvusd.k12.ca.us/webdocs/Chem-History/Bohr/Bohr-1913a.html
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    Bohr Model

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    Modified

    Bohr Model of a

    helium atom

    ++

    -

    -

    proton

    electron neutron

    shell

    (energy level)

    Electrons travel

    around the nucleuslike planets aroundthe sun.

    In 1932, James Chadwick confirms the existence of neutrons on in the nucleus of atoms.

    What is different about this model compared to the previous slide?

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    1926 Erwin Schrodinger

    Schrodingers Cat: a thoughtexperiment.

    Use mathematics to describethe motion and locations ofelectrons.

    Electron Cloud Model of theatom was developed as aresult of Schrodingers workwith mathematical probability.

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    Electron Cloud Model

    This model shows theprobability (likelihood) offinding an electron.

    The cloud model represents

    a sort of history of where anelectron has been and whereit is going.

    Imagine if the electron left

    a trace of where it was. Thecollection of traces wouldbegin to resemble a cloud.

    Where are we most likely to find

    an electron within this atom?

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    Scientific Theory May Change

    As scientists have made new observations of matter,their understanding of the atom changed.

    Scientists must be open to new evidence. A scientific

    theory does not represent truth but instead our bestunderstanding.

    Does the statement above mean that the scientistswho have studied the atom were wrong?

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    MORE ON ATOMS

    Actual picture of atoms. Kinda looks like

    solid spheres from this perspective.

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    Energy LevelsElectrons that are closer to

    the nucleus have less

    energy.

    When electrons are in their

    lowest energy levelsthey

    are in their ground state

    When an electron absorbsenough energy, it may move

    to a higher energy

    levelexcited state

    When an electronreturns to its ground

    state

    light may be released

    from the atom

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    Isotopes

    The same atomswith different

    numbers of

    neutrons.

    How can you

    determine the

    mass number of

    an atom?

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    ATOMIC STRUCTURE

    What is the atomic number of

    the atom shown above?

    What is its mass number?

    17

    35

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    ATOMIC STRUCTURE

    Particle

    proton

    neutron

    electron

    Charge

    + charge

    - charge

    No charge

    1

    1

    1/1837

    Mass

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    SUMMARY

    1. The Atomic Numberof an atom =number of

    protons in the nucleus.

    2. The Mass Numberof an atom =number of

    Protons + Neutrons in the nucleus.

    3. The number of Protons =Number of Electrons.

    4. Electrons orbit the nucleus in shells(levels).

    5. Electrons can move between levels as energy isabsorbed or emitted.