8^ej5^ · table of contents section no. . ____ titl_ e . _, ... "•-... . .. r page no. 1.0...

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REVISION 2

SAMPLING AND ANALYSIS PLAN f

FOR REMEDIAL INVESTIGATION/FEASIBILITY STUDY

FIRST PIEDMONT ROCK QUARRY/ROUTE 719 SITE

PITTSYLVANIA COUNTY, VIRGINIA

July 15, 1988

(Revised September 2, 1988)

S&ME3500 B Regency Park

P.O. Box 1308Gary, North Carolina 27512

(919) 481-0397

flR300l56

TABLE OF CONTENTS

Section No. . _ _ _ _ _ Title . _, ... " • - . . . . .. r Page No.

1.0 INTRODUCTION 1

1.1 PURPOSE . 11.2 SITE LOCATION AND OVERVIEW ; 21.3 ~~ PREVIOUS INVESTIGATIONS 4

i _ _ _2.0 GENERAL SITE CONDITIONS 1

2.1 ———.INTRODUCTION 12.2 "" " "" ENVIRONMENTAL SETTING" " """". 12.2.1 _ _ Geology 12.2.2 Soils 22.2.3 ....... -^Ground JJater _ . . . - - . . . i. : , 22.2.4 Surface Water . ; 3

.2.3 SITE HISTORY - , 42.4 ... SUMMARY OF WASTE DISPOSAL 5

; 3.0 FIELD PROCEDURES 1

3.1 TOPOGRAPHIC SURVEY _ : 13.1.1 Introduction 13.1.2 Base Maps/Aerial Photography 13.1.3 Data Collection Points 23.2 PIEZOMETER INSTALLATION PROCEDURES 23.2.1 --—Introduction j 23.2.2 Field Equipment 33,2,3 Installation Procedures • 33.3 WATER LEVEL MEASUREMENT PROCEDURES, £3.3.1 "" "Introduction " 43.3.2 Field Equipment 53.4.3 Water Level Measurements

in Piezometers and Wells , ' 53.4 GEOPHYSICAL SURVEYS 63.4.1 Resistivity Method ''_"-',' 63.4.2 Magnetic Method 73.4.3 Fracture Approximation 113.5 --- --SOURCE AREA SAMPLING . 123.5.1 VlWaste Pile Sampling 123.5.1.1 --— Field Equipment - 133.5.1.2 -. .Waste Pile Sampling Procedure 133.5.2 Drum Sampling 153.5.2.1 Drum Sampling Field Equipment 153.5.2.2 Drum Sampling Procedure 163.5.3 _... =Leachate/Sediment Sampling 173.5.3.1 -__ Field Equipment - ... 173.5.3.2 Leachate Sampling Procedure 173.5.3.3 _ .- . . _ Leachate.-Sediinent Sampling

Procedure ; 183.5.4 Pond Sampling 183,5.4.1 ._... --—— _Introduction . i 183.5.4.2 , -— -_: "Field Equipment " " -" -"f 19 fl R 3 0 0 I 5 73.5-4.3 Pond Sampling Procedure -- - - . 193.5.5 :. -_::-"--T-~-"Analyticar"Plan ' ' " 20

c

Section No. Title ___ Page No.

3.6 BOREHOLE SAMPLING 203.6.1 Purpose 203.6.2 _ Field Equipment 213.6.3 "Soil Boring Samples - 213.6.4 Diabase Dike Core Sampling 233.6.5 Analytical Plan 233.7 BOREHOLE GEOPHYSICS 243.7.1 Purpose 243.7.2 Equipment 253.7.3 Procedure 263.8 TEST PIT SAMPLING 27

[1 3.8.1 Introduction 27[ j 3 . S . 2 Field Equipment 27

3.8.3 Sampling Procedure 28D 3 . 9 MONITOR WELL INSTALLATION 29

3.9.1 Introduction 29.3.9.2 Field Equipment 303.9.3 Monitor Well Installation

C Procedure 343.10 MONITOR WELL SAMPLING 343 . 10 . 1 Introduction 34

0 3 . 1 0 . 2 Field Sampling Equipment 343.10.3 Well Evacuation and Sampling

Procedure 370 3 . 1 0 . 4 Ground Water Analytical Plan 37

3.11 SURFACE WATER AND SEDIMENT 373 . 11 . 1 Introduction 373.11.2 Field Equipment ~ 37

C 3 . 1 1 . 3 Surface Water Sampling Procedure • 383.11.4 Sediment Sampling Procedure 3p3.11.5 "Surface-Water and Sediment

E Analytical Plan 393.12 SOIL SAMPLING 403.12.1 Purpose 40

P 3.12.2 Field Equipment 40L 3.12.3 Soil Sampling Procedure ' 41" 3.12.4 Analytical Plan 44

3.13 SAMPLE CONTAINERS, PRESERVATION ANDE SHIPPING , 44

3.13.1 Typical Sampling Procedures 443.13.2 Sample Concentration Designation 44

C 3 . 1 3 . 3 Sample Containers & Preservation 453.13.4 Sample Shipping 453.13.4.1 Environmental Sample Shipping 45

KI 3.13,4.2 Hazardous Sample Shipping 47B 3.14 INSTRUMENT CALIBRATION 48

4.0 DATA MANAGEMENT PLAN 1

LL

4,1 GENERAL DOCUMENTATION PROCEDURE 14.2 Field/Laboratory Documentation 14.2.1 Field Log Books 24.2.3 Sample Tags 4

,AR300I58

Section No. ... Title__...... .... ...... . , . , . . _ ! Page No

4.2.3 Chain-pf-Custody Record . .' ! 4. \ 4.2.4 Monitoring Well Data-sheet 4

4.2.5 _ •- - - Monitoring Well Schematics '.. " 54.2.6 test Pit Records '- 54.3 --OTHER RELATED DATA 54.3.1 Meeting Summaries, Telephone,

Conversations, and Computations— . -- — and General notes , 5

4.3.2 Illustrations, Computations, and1 -1 ~ —other Engineering Documents 6

4.3.3 Progress Reports 64.3.4 RI Reports 6

5.0 INITIAL PROJECT SCHEDULE 1

U 6.0 DECONTAMINATION PROCEDURES 1t u t . . . - - |

r,. .. 6.1 DECONTAMINATION AREA 1: i 6.2 DECONTAMINATION PROCEDURES" 2LJ - - . . . . . _ • : ;

7.0 SITE MANAGEMENT PLAN 1r1 . ;J 7.1 - - -FIELD PERSONNEL 1

7.2. SITE SECURITY AND ACCESS 1

APPENDIX

A. Random Soil Sampling ProgramB. Headspace Analysis ProcedureC. FormsD. Sample Bottles, Preservation, and Cleaning Procedures

AR30'0!59

LIST OF FIGURES

Figure No, Title __.;

1-1 Site Location Map

1-2 Site Map

«, 3-1 Site Map Showing Geophysical Survey Locations

3-2 Grid Location Map

3-3 Source Area Sampling Locations

3-4 Schematic Drawing of Overburden and Bedrock" Monitor Well Construction

3-5 Soil Sampling GridIP nu __

I I 3-6 Typical Sampling ProceduresU

7-1 Project Chain of Authority

E

, ' AR300I60

LIST OF TABLESRevised September 2, 1988

Table No. ..Title „ _ .." ._... ; . , . . . .

3-1 ______"."! Sampling and AnalyticalSchedule

3-2 _-. Laboratory Analytical Procedures

3-3 ..._._.. Sampling Containers. Preservatives, and.... .. Holding Times ...',

p — 3-4 ; —List of Critical Spare Parts for Field| • " Equipment

6-1 ._.... _ .Decontamination Procedures

AR30016

FPRQ SAP Section 1S&HE Project No. 4112-88-900 Page 1 of 4

Revision No. 2July 15, 1988Revised September 2, 1988

1.0 INTRODUCTION

^ 1.1 PURPOSE

The Sampling and Analysis Plan (SAP) provides the procedures andi-' • protocols for performing sampling, monitoring well Installation andt *

cheaical analysis for work . activities during the Remedial

U Investigation/Feasibility Study (RI/FS) for the First Piedmont Rock

p ' Quarry/Route 719 (FPROJ Site located in Plttsylvania County, Virginia.

,Th!s document addresses all tasks to be implemented according to the RI/FS

j| Work Plan as amended by the Addendum (BCM, 1987). hereinafter referred to

as the RI/FS Work Plan.

U The Saispllng and Analysis Plan has been prepared to provide written

p procedures and protocols to be followed by S&ME, Industrial &

Environmental Analysts, Inc. (IEA) and other subcontractors while

performing the site investigation. The procedures and protocols were

developed using EPA guidance documents, ASTM procedures, and other

iii standard procedure references. All laboratory procedures will be in

ri accordance with the most recent Contract Laboratory Program (CLP)

Statement of Work (SOW) (Organics - 10/86 with 7/87 revision; Inorganics -

I 7/87). The protocols specified In the Sampling and Analysis Plan and In

the Quality Assurance Project Plan take precedence over all other project

m documents.

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FPRQ SAP . . . _ _ ; . .... ,:. _ ... .... Secti.on 1S&ME Project No. 4112-88-900 Page la of 4


The field investigation to be conducted at the FPRQ site will. ._ _.._.__ _ _ _ _ _ _ __!_•, _. .. • -;. ;. +:. .

: " . " " jdelineate the nature, presence, and quantity of any hazardous substances

which may have a negative affect upon the "local, environment. The Sampling

and Analysis Plan details S&ME's approach _ to the investigation and

provides detailed protocols that will be followed for sample collection in

AR300i63

C

FPRQ SAP Section 13&ME Project No. 4112-88-900 Page 2 of 4

Revision No. 2July 15, 1988

each of the environmental matrices at the site. The data collected by the

procedures presented herein and the quality assurance and quality control

procedures discussed In the Quality Assurance Project Plan (QAPjP) will

L* provide accurate data to make a determination on the existence of a

; problem. The Health and Safety Plan (HASP) specifies procedures to

assure that site activities will be conducted in such a manner that healthr[j and safety of project personnel vill be maintained. Employees working at

the site will receive site specific safety training at the site prior to

entering into site activities in accordance with the site Health and

Safety Plan. This meeting will cover employees right to know, site

operations, required levels of protection, personnel protective equipment,

decontamination and emergency procedures.

1.2 SITE LOCATION AND OVERVIEW >

The FPRQ site Is located at 79° 21' 05" north Latitude and 36° 39'

55* west Longitude, in Plttsylvania County, Virginia, off Route 719 and

north of Danville, Virginia as shown in Figure 1-1. The site Is bordered

by Route 719 and the community of Beaver Park to the south, Lawless Creek

to the west, and wooded areas to the north and east. A number of

residential homes are also located just south and east of Route 719.

Based on the U.S. Geological Survey (USGS), Blairs, Virginia Quadrangle of

1964 (photorevised In 1983), approximately 50 residences are located

within a one-half mile radius of the site, mostly towards the south-east.

The FPRQ site occupies approximately 4 acres and is presently

I

L AR300161+

FPRQ SAP Section 1S&ME Project No. 4112-88-900 Page 3 of 4


iinactive. Of the 4 acres, approximately 2 to 2.5 acres have been

- - - --;.;- - - - - - - - - = - - ;:..;----.-; -;,;;:..; • - ~ . ...... .-». 4 - - - - - - -landfilled. A generalized site map is shown on Figure 1-2.

- xhe property (approximately 182 acres) on which the subject site Is

located is owned by Mr. and Mrs. Richard Lacey Compton of Blairs,

Virginia. First Piedmont Corporation (FPC), located in Chatham, Virginia,. . . . . . . - . - . - . . . ,

and owned by Ben Davenport, leased the 4 acre parcel designated as First

Piedmont Rock Quarry from March 13, 1970 to July 11, 1972.

The subject site was, by lease, to be used as a "depository for;industrial refuse". The FPC disposed of approximately 15,000 gallons of

liquid waste consisting of solvents, carbon black, and detergents

generated during "floor and solvent cleaning operations" by Goodyear Tire

and Rubber Company. Additional wastes were contributed by Corning Glassi

Works and by Universal Leaf. The alleged wastes consisted of cardboard,

glass, paper, pallets, tires, rubber, elastomer compounds& tobacco stems,

putrescible wastes, and various silicate compounds with traces of lead" i

oxide generated during glass manufacturing. Disposal was approved by the

Pittsylvania County Health Department.

In 1972, a fire erupted at the site. First Piedmont Corporation

believes that the fire was ignited by spontaneous combustion of wood,i

tires and other solid materials. Subsequently FPC, transferred disposal

operations to another location. The FPRQ was then inspected by the

Virginia State Health Department and a closure order was issued. Disposal

operations were terminated in July 1972, and the site was subsequently

covered with 1 to 2 feet of clayey soils.

In June 1981, Goodyear Tire and Rubber Company nbtified FPC that some

i

: ... . ..:,,.. __fi.R3001 65

FPRQ SA? Section 1SSHE Project No. 4112-88-900 Page 4 of 4


of the waste which was generated at its Danville, Virginia plant and

deposited in the quarry contained hazardous substances. Subsequently, First

Piedmont Corporation filed a "Notification of Hazardous Waste Site" form

with EPA on June 5, 1981, listing "solvents" as one of the general types of

wastes disposed,

>; 1.3 PREVIOUS INVESTIGATIONSJ:

Several investigation and sampling efforts have been conducted at the

-a sife by the TJ. S. EPA (FIT and TAT contract investigations), the

"5 Pittsylvania-Canvllle Health Department, and by both First Piedmontsi

Corporation and Corning. The data collected during these Investigations

i indicated elevated levels of .organic compounds and metals In the ground

water, surface water, and sediments both on site and off site. The^3 r

*& analytical results from the previous sampling episodes Indicated, with a

E h i g h degree of confidence, the presence of chromium, lead, and zinc.-

However, the presence of the organic compounds detected (e.g. 4-methyl-2f«r;: pentanone, 1,1,1-trichloroethane, fluorotrichloroethane, tetrachloroethene,

bls(2-ethylhexl) phthalate, fluorotrichlorome thane, and aniline) was

kt qualified and Is questionable. V

i* Based on the evaluation of the data from these Investigations, it was

concluded that the data were not adequate to define the site conditions.

§ The data were, however, used to develop the scope of work for the RI.

(1R300I66



.... ... ._._..._ _2.-0-GENERAL SITE CONDITIONS

2.1 INTRODUCTION

The site conditions and history prior to initiation of the RI were

presented In the Work Plan. _ The site description includes the

environmental setting as well as a summary of the site history and results

of the previous investigations.

2.2 ENVIRONMENTAL SETTING

2.2,1 Geology ._. :....___.. ....... ;

The FPRQ site is situated in the uplands of the Piedmont Province

(PIttsylvania County Soil Survey). The site is underlain by the Shelton

Formation which primarily consists of granite gneiss, quartz schist, andi

quartzite. Geology and Ground Water Resources of Pittsvlvanla and Halifax

Counties. (LeGrand, 1960) indicates that the fractured granite gneissi

extends to depths of 200 to 300 feet, with the presence of a saprolitic

layer that may (based upon casing depths in the granite gneiss formation)

extend up to 60 feet In depth. The depth to bedrock.In the area is highly

variable, with rock outcrops existing throughout.

LeGrand (1985) has identified the existence of a diabase dike, a

naturally occurring formation, situated between the quarry and the Beaver

Park community on the south side of the quarry. This structure, according

SR3bOi67

FPRQ SAP Section 2SSME Project No. 4112-88-900 . " Page 2 of 5


to LeGrand, probably does not constitute a physical discontinuity to ground

water flow (aquifer discontinuity).

Soils in the area surrounding the FPRQ site are of the Cecil Series.

These soils consist of well-drained, gently sloping to moderately steep

I soils that have a domlnantly clayey subsoil. These soils are

> characteristically acidic in nature (pH ranging from 4 to 5) and are formed

froa weathered felsic bedrock and granite.

<T The topography of the FPRQ site has been significantly modified as a«

result of the use of the site as a rock quarry. The east floor of thenU quarry Is approximately 65 feet below the eastern rim.

fs The vest and east sides are granite walls, while the southern and

northern sides consist of slumped soils, mine debris, arfd deposited fill

R and wastes. Water is ponded near the base of the granite walls, and the

ponds have been designated as the North and South Ponds. Bedrock (granite)

ijj Is exposed at the land surface in some places at the site, and overlain by

I? as much as 15 to 20 feet of soft weathered granite and residual soil in

other places at the site. Landfilling activities have elevated the

I northern edge of the quarry equal to the surrounding topography. The lip

of the quarry is bounded on four sides by scrub vegetation and trees.

t 2.2.3 Ground Water •Ground water in the vicinity of the site occurs in the lower soils and

saprolltic area and the upper region of granite/gneiss bedrock. Shallow

I flR300!68

FPRQ S A P _ _ _ _ _ _ _ _ _ _ Section 2S&ME Project No. 4112-88-900 .- Page 3 of 5

- = . . = . . = . . - „ Revision N o . 2July 15, 1988

iground water tends to flow along the saprolitic zone and In a direction

which follows topography. This propensity for shallow ground water flow toii

parallel surface drainage defines several small aquifers isolated from each

other by topographic highs (LeGrand, 1985). Although no site specifici

information is available, LeGrand states that the shallow flow of ground

water is presumably northwest towards Lawless Creek.•"- - " " " ' "7~ -———- - :

The occurrence of ground water In bedrock is controlled by fractures,

most of which occur at a depth of less than 150 feet. Much of the ground

water Is in the upper 30 feet of the bedrock. Fractures In the granite of

J t h i s region often times exhibit two general orientations. The primary.

fractures tend to be vertical (or nearly so). Conversely, secondary

fractures tend to be concentric with relation to the center of the granitei

mass, which on a site specific scale are essentially horizontal. These

fracture patterns complicate the signature of.the aquifefr, and therefore... . . i

the difficulty of tracking contaminant migration is compounded.

Ground water is used as a potable water source for local residents

along State Route 719 in the Beaver Park community south and southeast of

the site. These water supply wells are reported to have an average depth

of 40 feet_ L ...._... .-._

2.2.4 Surface Water . . . . . " . . . . . . _ _ t ._.

The FPRQ site Is situated approximately 1,400 feet east of Lawlessj

Creek. Lawless Creek flows southwesterly and discharges into Fall Creek

which Is the main drainage basin for the area. Eventually Fall Creek

drains. Into the Dan River, approximately 12 miles .southeast of the site.

flR'300169

FPRQ SAP Section 2S&HE Project No. 4112-88-900 , Page 4 of 5

., Revision No. 2July 15, 1988

According to the Virginia Game and Inland Fish Commission, Lawless and Fall

Creeks are classified as warm water streams and are inhabited by a variety

"* of fish species which include sunflsh, bluegills, catfish, and possibly

white suckers. They are not: state-stocked trout streams. In addition,

conversations with local property owners have indicated that Lawless Creeki-

is utilized for recreational activities and that children wade and play In

J the creek, within 1 mile (downstream) of the site.

1

~* 2.3 SITE HISTORY

;f Richard Lacey Compton and Mae Milan Compton purchased the present*d

* 182.19 acre property, of which the CFS site Is a portion, on July 3, 1963.nij Mae Hilan Compton's interest' In the property passed to her husband,

T? Richard, upon her death in 1965. Mr. Compton is the sole owner of the site

property, and was the sole owner at the time disposal operations were**tI ' taking place.y

By lease dated March 13, 1970, Richard L. Compton and Lois H. Compton,

la his wife (Mr. Compton re-married), leased approximately 4 acres containing

j'c the subject site to the First Piedmont Corporation. The lease stipulated

that the site would be used as a landfill by FPC. By memo dated March 12,

1970, C.D. Bryant. Jr., of FPC Informed the residents near the site that

the quarry would be used to dispose of Industrial wastes from the Goodyear

fe Rubber and Tire Co. In Danville. Wastes, originating from the Corning

?r Glass Works and Universal Leaf were also disposed of at the site. In

addition, due to a lack of security around the site, uncontrolled dumping

at the site could also have occurred.

flR300!70

FPRQ SAP Section 2S&ME Project No. 4112-88-900 , Page 5 of 5


In its June 5, 1981 "Notification of' Hazardous Waste Site", FPC

Informed EPA that solvents in small quantities were disposed of at theisite, notably from the Goodyear Tire and Rubber Co. of Danville, Virginia.

2.4 SUMMARY OF WASTE DISPOSAL

The results of sampling events conducted at the CFS site have indicated

the presence of a number of heavy metals In soils, surface waters and

sediments, ground water, and source areas (I.e., drums). Contaminants

detected to date Include inorganics and organics including chromium, lead,

zinc, arsenic, barium, iron, magnesium, manganese, 4-methyl-2-pentanone,

1,1,1-trichloroethane, phthalates, as well as a number of other organic

species. As mentioned previously In Section 1.3, the data package Is

suspect due to a number of considerations and is not considered validi

overall. . - ^

flR3

i



3.0 FIELD PROCEDURES

The proposed field activities include the surveying, piezometer

Installation, water level measurements, geophysical surveys, source area

sampling, borehole sampling, borehole geophysics, test pit sampling,

monitor well installation and sampling, surface water and sediment

sampling and soil sampling. The sampling and measurement procedures for

each of the environmental media are presented in this section . All

activities will be carried out In accord with the specific requirements

stated In both the HASP and In the QAPjP.•

3.1 TOPOGRAPHIC SURVEY

3.1.1

Surveying control will be provided throughout the project. All

surveying work will be performed by the licensed land surveying firm of

Dewberry & Davis.

3.1.2 Base Haps/Aerial Photography

The areal extent of the study area will be defined on two base maps

with appropriate topographic resolution to define pertinent features. Two

base maps will be developed:

o Topographic map for the ten-acre area at a scale of 1" - 100' andcontour Interval of two feet.

BR300I72


Revision No. 2July 15. 1988

o Topographic map for 100-acre area at a Scale of 1" - 100' andcontour Interval of five feet. ' |

i

The topographic maps will be developed from aerial photographs with a

scale of approximately 1" - 100', Ground control, along with the metes

and boundary survey, will be performed by Dewberry & Davis.

3.1.3 Data Collection Points . , . .( .

• All data collection points Including monitoring wells, piezometers,

surface-water stations, geophysical profiles, etc. will be surveyed. S&MEr

staff __ will first locate all points on a working field map. All points

will then be surveyed by Dewberry & Davis to the nearest 0 . 1-foot

horizontal and nearest 0.1-foot vertical. Monitor wells will be surveyed

to the nearest 0.01-foot vertical.

3.2 PIEZOMETER INSTALLATION PROCEDURES

3.2.1 Introduction . .. . _ ,

Piezometers will be installed to provide water level data sufficient

to map the ground water potentiometric surface and determine the

dlrection(s) of ground water movement at the FPRQ site. The piezometers

will be installed for water level measurement use only and will not be

used for any other sampling purpose.

SR300I73

c



3.2.2 Field Equipment

The piezometers will be installed using'a hollow stem auger drilling

machine to advance the borehole. Soil samples will be collected using a

split barrel sampler.

The additional field equipment ~to be used during the piezometerr -

Installation will Include the following:

H o OVA or HNu Model PID/FIDlj o Field Log Book

- o Water level probeo Sample bottles for physical soil samples, sample tagso Camera and filmo Appropriate personal safety equipment

3.2.3 Installation Procedures

The borehole at each piezometer location will be drilled using hollow

stem augers, if possible with nominal 3.5 inch I.D. and 6.25 Inch O.D.

The augerlng procedure and soil sample collection will follow the standard

procedures In ASTM *D-1556. The split barrel soil samples will be

collected at five foot Intervals and described in the field by the site

geologist. The samples will be classified using to the Unified Soil

Classification System in accordance with ASTM D-2488. A portion of the

sample from each split barrel will be placed In a sample bottle and

retained for confirmatory description, if necessary. Monitoring of the

breathing zone will be conducted with an OVA or HNu at least every five

feet of drllllng.

The auger cuttings and split barrel samples will b& observed for

moisture content to determine the approximate water table depth. The

borehole will be extended approximately ten feet below the field

determined water table depth.

flR300l7l*

cc

FPRQ SAP Section 3S&ME Project No. 4112-88-900 page 4 of 50


The piezometer will be constructed using Schedule 40, PVC well casing

and screen with flush threaded joints. The well screen will be a ten foot. . - - . . . . _ . ••-:-. ..... |

length of PVC wi_th__Q.010 inch machine sawed slots.

. _ _The auger flights will be removed from the borehole prior to

- - Installing the piezometer materials. The piezometer screen will be

' positioned such that approximately five feet of the screen Interval• ' ; - • • • - . - . ' : | • . •

extends below the approximate water table. The annular space around the- - - - - - - - - -—- ^ ^ ^ ^ - --;-- --;-... _- _ ; . ___ - - - f - -j- -

f well screen will be _ filled with coarse well saxi4. The well sand will.** - - - - r

extend one to two feet above the top of the screen. Clean, potable water

____ _ £rOm an off site, approved source will be introduced into the piezometer

^ during emplacement of the well sand to wash the formation materials from

the screen interval.

A one to two foot thick bentonite pellet seal will be placed on top of

the sand. The remainder of the annular space will be filled with cement

grout to land surface, A four Inch diameter steel, protective casing with

a lockable cap will be set into the grout at land surface.

The piezometers will be developed by bailing to remove formation

materials from inside the well screen.

The _ land surface and piezometer measuring point elevation will be

surveyed to 0.01 foot (vertical) as part of the site survey activities.

3.3 WATER LEVEL MEASUREMENT PROCEDURES

3.3.1 Introduction ~ .. ........... ,., -i

During the RI field Investigation water; level, measurements will be-- - - - - . - f

made in the piezometers and monitoring wells and may also be made in the

^300/75

SAP Section 3S&HE Project No. 4112-88-900 Page 5 of 50


*™ti off site drinking water wells. The procedures to be followed for making

water level measurements Is discussed in the following sections.

•« 3.3.2 Field Equipment

*"" The water levels will be measured using an Actat electric water level

; probe or similar device. The following equipment will be used:i -i

n o Water Level Probefj o Field Log Book

. o Tape aeasurep, o Deionlzed water in spray bottlej j o Isopropyl alcohol In spray bottle" , o OVA and HNu FID/PID

o Appropriate personal safety equipment .......

3.3.3 Water Level Measurements In Piezometers and Wells

|| Water level measurements will be obtained by the following procedure:

|:; 1. Unlock protective casing cap and set aside.f-

2. Remove well "or piezometer cap, monitor breathing zone with OVA orn HNu.

3. Locate measuring point narked on the inner casing.

y 4. Using a previously decontaminated water level probe, flush againwith distilled water, lower probe carefully Into the piezometer

_, until the probe contacts the water surface.

•* 5. When the water level probe alarm sounds, mark the cable and readthe water level from the nearest measurement increments on the

F water level probe cable.

6, Record the piezometer Identification, water level to the nearestm 0.01 foot, time, date and any unusual observation andm Identification of the observer.

7. Retrieve the water level probe from the piezometer "and replaceJ both Inner and protective cover caps, locking the outer•* protective cover.

P 8. Decon the water level probe In preparation for the next readingk» by:

fiR300176



1) Rinsing with distilled water2) .Rinsing with isopropyl alcohol3) Flushing with distilled water4) Allow to air dry

3.4 GEOPHYSICAL SURVEYS . ,i

3.4.1 Resistivity Hethod iSurface resistivity will be conducted along two lines at approximate

right angles over the landfill and surrounding area (Figure 3-1). The

purpose of the survey is to determine the overburden thickness and depths

to the ground water surface and bedrock. ,A Bison Model 2390 Earth

Resistivity System, with the Bison Offset Sounding System "Boss" shall be

used to conduct vertical electric soundings (VES) , measuring apparent. iresistivity utilizing an offset Wenner electrode array.

In general, resistivity Is determined with the use of four electrodes

placed along ah azimuth. A known electrical current is Introduced intoi - >

the ground via the outer electrodes. As a result of ; the current flow, the

potential difference between the two Inner electrodes Is measured. With1 !

both current and the potential difference known, the apparent resistivity

is determined. ;

Using the Wenner array, electrodes are placed along a line equidistanti

from each other. Once the reading Is taken, the electrodes are either

moved to another station, maintaining the same electrode spacing for thei

purpose of profiling, or increased in equal distances over the same

station, thus Increasing the depth of Investigation for sounding

purposes. Resistivity profiles are plotted on straight graph paper

AR300I77



showing lateral variations along the line . For soundings , data are

plotted on log- log paper and the curve from this plot is then matched to a,

type curve. Froa this plot, the number of layers, and their corresponding

thicknesses and resistivity may be determined.

Weimor soundings using the Boss will be conducted along the two lines

at 40 foot intervals. These stations will be staked prior to the actual

survey. Procedures for the resistivity survey will be as follows;

Follow "Operating Instructions" for "Basic Measurements", beginning on page 21 of the Instruction manual.

00 Set up the offset sounding system at standard spacings of 1/2, 1,2, 4, 8, 16 and 32 meters.

« o Connect the Boss to the resistivity unit.

*"* ' o Check to see that the system Is operational. Make corrections asnecessary.n

La o If sufficient current Is not -supplied, check to see thatelectrodes are properly driven into ground, or If water is needed

n to lower surface resistivity. Hake corrections as necessary.

o Obtain readings starting with electrode spacing of 1/2 meters.

|| o Record current and potential difference values.

o Continue sounding, Increasing the electrode separation.

fla o Record data for each spacing at the location-

Pi o Move unit to next station.

n 3.4.2 Magnetic Method

•* Identification of areas of the landfill possibly containing burled

F drums, and the location of the referenced diabase dike will be conducted

[ AR300178



with a Geometries Model 856 AX Proton Precession Magnetometer equipped

with a gradlometer.

Both total field measurements and the vertical magnetic gradient will

be measured for better resolution of magnetic anomalies. To cover the

area of concern, the grid shown on Figure 3-1 will be used. To

sufficiently detect any subtle anomalies produced from buried metal with

an anticipated maximum depth of 65 feet, the sample density will consist

of ten foot centers over the grid. In all, a total of 21 survey lines

(A-A'/U-U') will be conducted.

Stakes will be placed along the borders of the grid at ten foot

Intervals and at: 50 foot centers within the grid. All stakes will be

labelled in respect to their coordinate position.

Upon completion of staking, the field crew will lay out a fiberglassj

engineers tape along an approximate NW-SE direction, beginning between

stakes A-A'. The site geophysicist shall then conduct t£ie magnetometerj

survey beginning at station A-0._ It j&_ important that the person

conducting the survey wear as little metal (watches, steel toed boots,

etc.) as possible during this Investigation, since these items can produce. . . ........ . . . . . . . i

fluctuations in the magnetic field as much as ten gammas and could mask

any anomalies created by drums buried at depths previously mentioned. To

eliminate other Interferences caused by surface irregularities (scrap

metal, etc.) the magnetic sensors will be placed on an aluminum staff, oneisensor will be on top of the staff at 8-feet, the lower sensor will be one

fiR300179

FPRQ SAP Section 3S&KE Project No. 4112-88-900 page 9 of 50


meter lower. The site geophysiclst will note any ferrous objects at or

near the surface which may influence the readings.

A minlnum of two total field readings per station will be measured to

„, check reproduciblllty. A one gamma or less variation between readings

will be considered sufficient. Data will be stored in the computer memory

of the magnetometer for later retrieval. Three gradient readings perE .

station will be collected and recorded. To check for magnetic drift, the

0 first station In each of the survey lines shall be reoccupied immediately. _

after all sites in that line have been recorded. The survey crew will

*-J> then move the tape to the next line and resume the survey. At least three

f* times each day the total field and gradient will be measured at anL

established base station to evaluate magnetic field changes and possibleC -

Instrument drift. 'Once all the lines are completed, field data will be plotted on a siterLi map and inspected for anomalous results. It Is anticipated that the high

p Iron content In drums will present a higher than normal total magnetic

field and gradient (position or negative depending on orientation of

I object to the magnetic field and gradiotneter). However, variations in the

size, shape, orientation, and number of drums, as well as their depth of

» burial will effect the signature of the anomaly. Therefore, any

I" anomalously 'high' or 'low' areas shall be identified as possible burled

drum sites. These areas will be staked and flagged for later

M investigation.

A review of the magnetic survey procedures are as follows:

Lo ' Stake grid at ten foot Intervals along border of study area.

i /SR300180

FPRQ SAP —- - Section 3S&ME Project No. 4112-88-900 Page 10 of 50


. ; io Label end points of profile lines beginning with A-A' and

continue in alphabetical order, ending with line U-U'.

o Stake interior of grid based on 50 foot centers.

o Lay out in an approximate Ntf-SE direction the fiberglassengineers tape,

o Place magnetic sensor on top of the 8-foot aluminum staff.

o Begin survey at station A-0.

o Obtain a minimum two field readings per station, If valuesreproduce to within 1.gamma, store second reading.

O_ Obtain gradient readings and record.

o If anomalous data are found, decrease spacing to 5-feet adjacentto station.

o Move to ne'xt station repeat previous step.

o When profile line has been completed, go back to first station Inprofile, obtain readings similar to other data.

o Record series of numbers that magnetometer has assigned toprofile stations.

_.„,_.. -_ __...._. ^ .... ,_„... ...— ....--- . -. ~ \~ f.o Move to next'profile, repeat previous steps.

o When all profiles have been completed, the readings stored in themagnetometer will be retrieved and recorded.

o The data will be plotted on a base map and contoured to defineanomalous areas.

- -Delineation of the diabase dike will also be done with this method.i

As the approximate location of the dike will be determined from the

geological survey, profile lines of about 200 to 300 feet In length will

be surveyed at sufficient intervals to delineate, the dike. Sample

intervals for the jp gnetic profiles will be between one and ten feet, the

closer spacings will be used near the apex of the magnetic anomaly.

AR300I8I

FPRQ SAP Section 3S&ME Project No. 4112-88-900 page 11 of 50


Profiles can be used to determine the location of the dike and the dip

direction. A minimum of four profile lines will be conducted. Survey

procedures are the same as the survey conducted to search for landfill

__ anomalies.

3.4.3 Fracture Approximation

Location of vertical fractures- at the proposed monitoring well

] locations will be done using electromagnetic techniques. The ABEM Wadl

_, (substituted "for the Geonics EM-34-3XL) will be used to Identify

-a approximate fracture locations. The scope of this effort may be modified

"* based on the results of the geological survey (Subtask 2.2).

A 100 foot X 100 foot area with a grid on 10 foot centers will be

:! established around each proposed well location (Figure 3-2). Stakes will

be labelled and placed along grid borders and at 20 foot centers within

-* the grid for later reference. Readings In ohm-meters wlj.1 be collected

^ at each station. At least three readings per day will be collected at a

base station to check for VLF or Instrument drift. Manufacturer

j calibration procedures will be followed.

The data will be recorded and plotted on a site map. These data will

-s then be contoured to help identify areas of relative low resistivity (high

* conductivity) believed to be associated with fluid filled fractures.

Procedures for the terrain conductivity will be as follows:

& o Stake two opposing 100-foot border lines of the six areas ofconcern at ten foot Intervals, label stakes.

fiR300182

FPRQ SAP L, -,-" _ ___ ...,. Section 3S&ME Project No. 4112-88-900 Page 12 of 50

Revision No. 2— - ; -77; -" _ Juty 15, 1988

Revised September 2, 1988

o Stake Interior grid at ten foot centers.

o Set up ABEM Wadi in accordance with the operational manual.

o Set VLF frequency and scale range.

o Lay out fiberglass tape across stake (100' on both sides).

o Obtain re_adlng.nId o Record value.

3.5 SOURCE AREA SAMPLING

The source area sampling is comprised of sampling waste materials,

residues, and leachate streams to determine the constituents present in

the waste material on the FPRQ site. The sampling activities will include

pond sampling, leachate seep and contaminated sediment sampling, drum

samplirtg, and carbon black pile sampling. The sampling locations proposedi: *

in the work plan are shown on Figure 3-3.

The samples collected will be analyzed for the complete Target

Compound List (TCL) and Target Analyte List (TAL). These parameters are

listed in Appendix A of the QAPP. Samples will be analyzed in accordance

with the current CLP-SOW for Routine Analytical Services (RAS). Available

data indicate that all samples will probably be low to medium

concentration; therefore, Special Analytical Services (SAS) should not be

required either In the field or laboratory. The data obtained from this

sampling will be used to select: the target parameters for the analyses Ini

Phase II of the Rt. The sampling and analytical program for Phases I and

II"activities are summarized on Table 3-1.

AR300I83

FPRQ SAP Section 3S&ME Project No. 4112-88-900 Page 12a of 50


' Revised September 2, 1988

; , 3.5.1 gaste Pile Sampling

p The Identified waste pile is the carbon black pile located outside the

quarry area. The pile will be sampled at a minimum of four points to

(ic

t

provide a. composite sample representative of the pile contents.



3.5.1.1 Field Equipment The carbon ,black waste pile will be sampled

using a sample trier and/or a bucket hand auger. The following field

equipment will be used: i .

o Sample triero Bucket hand augero Stainless steel spoons and spatulaso Sample bottles, lab qleanedo OVA or HNu FID/PIDo Field log booko ~ Camera and filmo Sample seals & tags

. o Chain-of-custody formo Appropriate personal safety equipmento Cooler and iceo Wheel barrow, if needed, to carry coolero Plastic bagso Aluminum foil & pans

Section 3.13 and Appendix D present the required sample bottles,

preservatives, holding times and laboratory bottle cleaning procedures for

all sampling efforts.

3.5.1.2 Waste Pile Sampling Procedure The waste, pile will be sampledI

using either the sample trier or the Jjucket hand auger. The sampling

method will be field determined and will follow the! following applicable

procedure for either the trier or auger:

Sample Trier _. .__i

1. Select representative sample locations. i2. ...Insert the decontaminated trier Into the material to be sample at

a 0 to 45° angle from horizontal. This orientationminimizes the spillage of sample from the sample trier.Extraction of samples might require tilting of the containers.

AR300185'



3. Rotate the trier once or twice to cut a core of material.

4. Slowly withdraw the trier, making sure that the slot Is facingupward.

5 , Place proportioned sample volume directly into bottle forvolatile analysis.

6, Empty trier Into foil lined pan for compositing the sampler foranalysis.

*7. Transfer the sample into the container using the spoon or

!•"> spatula .u 8. Repeat the sampling at four or more points.T

! 9. Place contaminated sampling trier in the plastic bag.,-k

Soil AugerF*wa 1. Select representative sample locations.

ni 2. Attach the decontaminated bucket and handle to an extension rod.

3. Begin turning the auger with a. clockwise motion and continueuntil the desired sampling depth Is obtained.

-* 4. Remove auger and place proportioned sample volumg directly intobottle for /volatile analysis.

'?hi 5. Transfer the remaining sample into a suitable container, using a

cleaned stainless steel spoon or trowel for compositing.

j 6. Repeat sampling at four or more points.

f 7. Place composited sample in lab supplied container.

-* 8. Cap the sample container attach the label, place in doubleplastic bag and affix custody seal. Record all pertinent data In

H the field log book, complete the sample analysis request form,t and complete a chain- of -custody record before taking the next

.e .

Preserve and/or place on ice If required.

AR300I86



3.5.2 Drum Sampling

A number of drums, potentially containing waste materials, have been

•.tdentified....w_ii.lili^___t^____lan^_il]t._area_.in the quarry. Two of the exposed

„...._. .....__ drums will be sampled to provide data for the characterization of the site

: ' contaminants. The drums to be sampled will be jointly selected by S&ME

and EPA personnel based on representativeness, safety and sampling* i • - - - - !

feasibility. The sampling of drummed waste materials poses a greater

j J safety risk than the other sampling procedures, therefore, extra care will

j— - • - be taken during the drum sampling. The primary hazard expected is drums

^ with the contents under pressure. The drums will be visually inspected

ft for bulging ends or sides and will not be opened if these conditions arey - . . , - -present. The area Immediately around each drum being sampled will also be

monitored with an OVA or HNu. and an oscygen/explosimeter during sampling.

3.5.2.1 Drum Sampling Field Equipment The equipment needed for the

drum will be determined after the drums to be sampled are selected. The

following equipment may be used:

o Sample containerso Field log booko Sample analysis request forms \o Chaln-of-custody forms ,o Seals for legal sample securityo Sample labelso Non-sparking bung opener (brass or beryllium)o Spray paint to mark drumso Exploslmeter and Oxygen level monitoro OVA or HNu FID/PID . _ . . . . , |

flR300I87



o Absorbent padso Sample triero Open tube samplero Stainless steel spoono Appropriate personal safety equipmento Camera and filmo Plastic bags for contaminated itemso Cooler & Iceo Wheel Barrow

3.5.2.2 Drum. Sampling Procedure The exact sampling technique for the

drums will be determined in the field. Sampling may include the following

procedures:

y o Conduct a general site survey visually and with the OVA or HNuand the explosimeter.

11 o Examine the physical, condition of the drum to determine if thedrum has bulging ends or side, leaks, etc. Photograph drum Inundisturbed state. Record In field log book pertinent data about

[' drum and markings.

o The drum will have to be upright for sampling. It may beI? necessary to move the drum and turn it upright for sampling.

o Mark the drum identification number on the side of the drum usingJHH the spray paint.

cThe drum will be opened after allowing time for the contents tosettle (If the drum was moved). The site manager will againevaluate the drum and determine If the drum will be opened. Thesampling team will be positioned upwind from the drum to minimizeexposure to vapors. The drum will be opened using a non-sparkingbung wrench. The opening will proceed slowly allowing anyaccumulated gases to vent. - - =.

Use an OVA or HNu to quantify the vapors venting from the drum.Record readings in the field log book.

flRSOO I

o Collect sample and transfer to the sample container.

o Cap the sample containers, ?e_al___and attach label. Record allpertinent data in the field log book.

o Place sample In Iced cooler.

o Complete the chain-of-custody record and proceed to next sample. .= -location.

3.5.3 Leachate/Sedlment Sampling

Sampling of leachate streams and soil and sediment contaminated by

leachate will be conducted as part of the source area sampling to identify

the waste constituents In the landfill area. . '.

3.5.3.1 Field Equipment The following field equipment will be used to

collect the leachate and sediment samples.

o Stainless steel beakero Stainless steel trowels and spoonso Sample bottles, as required, lab cleanedo Aluminum foil and panso Polyethylene sheetingo Field log booko Camera and filmo Sample sealso Sample labelso Chain-of-custody formso OVA or HNu PID/FIDo Appropriate personal safety equipment

3.5.3.2 Leachate Sampling Procedure

Dip the sample from the flow channel by slowly lowering thebeaker into the leachate. Care will be tak<?n not to disturb thebottom sediments.

AR300I89



o If the flow is low and the beaker cannot be easily filled, asmall hole will be excavated Into the stream bottom into whichthe beaker will be lowered. The sample will not be collecteduntil the sediments disturbed during digging the hole havesettled. The leachate sample will be collected from the upstreamleachate flowing into the hole. Care will be taken to notdisturb the bottom sediments.

o Fill the sample bottles by slowly pouring the leachate from thebeaker into the sample bottles. If additional leachate isrequired to complete filling the sample bottles, additionalstaples will be collected from the same location, and filling ofthe bottles will be staggered such that each bottle contains thesane relative mixture.

o Cap sample containers, seal, complete and attach sample tag,place In plastic bag, record all pertinent data Into field logbook.

o Place samples in Iced cooler.

3.5.3.3 Leachste Sediment Sampling Procedure

o Scan the sample area with the OVA or HNu to quantify the presenceof organic vapors. Record readings in the field log book.

o Excavate the sample losing the stainless steel spoons or trowel.Place the sample material directly Into the sample bottle forvolatile analysis.

o Mix the remaining sample in an aluminum foil pan using a cleanspoon and transfer to the other sample bottles.

o Cap sample containers, seal, complete sample tag, place Inplastic bag record all pertinent data in field log book,photograph site. Complete chain-of-custody record beforecollecting another sample. ........

o Place samples Into iced cooler.

3.5.4 Pond Sampling _

3.5.4.1 Introduction Liquids in the pond areas within the landfill area

will be sampled using a stainless steel beaker attached to an extension

pole. The pond samples will be used to determine if leachate from the

SR300I90

L.-:


Revision No. 1• - - -^-• = - ''- • : July 15, 1988

ilandfill materials has contaminated the water In the ponds.

3.5.4.2 Field Equipment The field equipment for the pond liquid, _. _. _. .. . .= = .., ~. .=- —— - - - -- — - i •sampling will be as follows: - - - .____._.._. .

o Field meters (pH, temperature, dissolved oxygen, conductivity).. o Stainless steel beaker

o Extension pole and strap to attach beaker: o Sample containers as required, lab cleaned

j o Field log book _. o Polyethelene sheeting

- o Camera and filmo Chain- of -custody formso_ .._ Saupie sealso Sample labels

C o O V A o r H N u FID/PIDo Appropriate personal safety equipment

3.5.4.3 Pond __ Sampling Procedure The pond liquid sample will be

collected by dipping the liquid from the selected location using the

stainless steel beaker attached to the extension pole. Care will be taken

to select a sampling location that will not place the sampling team in

danger of falling into the impoundment. If the pond banks are steep the

sample collector will be on a lifeline.i

The sampling equipment will be decontaminated a,t the designated site

decon area, wrapped in aluminum foil with the shiny side out and carried

to the sampling location.

The following procedures will be followed to collect the pond samples.

o Spread the polyethelene sheeting on the .ground at a convenientlocation near the pond. The sampling equipment will be assembledo n t h e sheeting. ' ' - _ . ' .

o Remove aluminum foil from sampling equipment and assemble.

M3Q019



Collect sample for volatile analysis directly Into bottle ifpossible.

Collect the sample by slowly lowering the beaker attached to theextension pole into the water. The beaker will be lowered toapproximately the mid point in the water column. Care will betaken to not disturb the bottom sediments In the pond.

Fill the sample bottles by slowly pouring the water from thebeaker. If additional water Is required to complete filling thesample bottles additional samples will be collected from theapproximate same location and filling of the bottles will bestaggered such that each contains the same relative mixture.

Cap saurple containers, seal, complete and attach the sample tag,record all pertinent data Into field log book.

Place samples in iced cooler. iCollect sample for measurement of field parameters. Measure theparameters (pH, temperature, dissolved oxygen, conductivity)using the procedures specified for the equipment.

3.5.5 Analytical Plan >'1f* All the samples collected during the source area sampling will be

analyzed for the complete XCL and TAL as shown in Table 3 -1. TheTJ.49 analytical procedures will be in accordance with tKe'most recent CLP-SOW.

3.6 BOREHOLE SAMPLING

3.6.1 Purpose

Boreholes will be advanced at each monitoring well location for the

purpose of determining the soil composition, depth to bedrock, water

elevation and for sampling.

Each borehole will be logged by the onslte geologist to determine soil

constituents and water level for screen placement. The geologist will

flR300192



retain and appropriately handle two samples from each borehole to be held

for possible laboratory analysis.

3.6.2 Field Equipment.. ... . _ _ _ . . . __...__ _ . :. i.

The following field equipment will be used, to collect the boreholesamples: - , _ . . . . . . . . ..„.. . .

P o Stainless steel spatula and spoons.jj o Sample bottles as required, lab cleaned

• o Aluminum foilp - o Field log book| o Sample seals

." o Sample labelso Chain-of-custody forms

P OVA or HNu PIP/FIDlai o Appropriate personal safety equipment

3.6.3 Soil Boring Samples , ,

Continuous soil samples will be collected in the uncons oil dated

overburden in the test borings and monitoring well installation boreholes

augered at the site. The continuous samples will be collected using

standard split barrel samplers and hollow stem augerlng procedure to auger

refusal. The steel split barrel sampler is two feet long, and has a

two-inch outside diameter (1 3/8-inch Inside jliameter). The split barreli

sampling will be conducted following the procedures specified in ASTM

D-1556, ..._.._._.. . : _ _ _ . " ;...:.

The soil samples will be described by the field geologist and

classified following the Unified Soil Classification Method Specified Ini

ASTM D-2488. The field description will also Include the sample color,: |

using the Munsell Color Chart, percentage content of', different grain size

•flR3.OD.193

FPRQ SAP Section 3SSHE Project No. 4112-88-900 Page 22 of 50


materials, visual moisture condition and any other description deemed

necessary. Each split barrel sample will be subjected to a headspacae

analysis as described in Appendix B. The field description will be

recorded on the Field Test Boring Record form shown in Appendix C.

Two samples of the continuous soil samples will be retained and

appropriately handled from each test boring for possible laboratory

analysis. The samples to be analyzed will be selected by the onslte.;- - ~~- . . . . . . .

geologist, based on visual observations, the OVA/HNu headspace analysis,

and stratlgraphic position. If there are no Indications of impacts, the

onslte geologist will select two samples at his discretion. If

significant lupacts are observed, additional samples may be retained for

laboratory analysis. At a minimum 10% of the retained samples will be

following procedure

submitted for analysis. The soil samples will be collected using the

o Remove split barrel sampler from drive rod; remove drive end andr* rod connection from sample tube, open tube carefully to minimizeti loss of sample.

*n o Scan soil length with OVA or HNu and record readings.

1-3 o Cut sample In approximate lengthwise halves using a clean,_ straight stainless steel spatula.

-a o Place one half of sample into sample bottle(s) for laboratoryanalysis .

^ o Place remaining half of sample in clean 1 pint jar, cap withaluminua foil and seal with ring lid or tape. This sample will

r.f be used for a field head space analysis using the procedures! ' shown In Appendix B .ki.

o Complete the physical description of the sample; prepare andattach sample tags; place sample for laboratory in cooler,

iflo Complete documentation in the field log book.

T*A-

FPRQ SAP I Section 3S&ME Project No. 4112-88-900 . Page 23 of 50

Revision No. 2July i.5, 1988Revised September 2, 1988

3.6.4 Diabase Dike Core Sample ;. . . . __. ._ .. . .... _ . .__ ...._— ___.. ._.___ ... ... j ......

A core sample of the unweathered part of the diabase dike located- - - - - - - - — — ----- - - - - I

between the site and the Beaver Park community will be collected and

analyzed for chromium by the extraction procedure to determine If the dike

may be the source of chromium previously found in the some community

wells. " " " " " ! . " . " .- |

The location for the diabase sample will be determined based on the:_ I

geological and geophysical surveys. After augerlng through the

unconsolidated sediments, the diabase dike will be.cored using the rock

coring procedures specified in ASTM D 2113-83. A.five foot continuous

core will be taken within or-through the dike. An unweathered portion ofi

the retrieved dike material will be selected for chemical analysis._ ' . - - -. ; ... j-. r . . , ; [.

The sample will^ consist of approximately 150 grams of >the unweathered

diabase. The core sample will be placed in a clean wide mouth sample

bottle for delivery to the laboratory.

The borehole samples selected for analysis (Table 3-1) will be placed!

in the appropriate sample containers {Section 3.13) at the time of

collection and labeled. The samples will be placed In coolers with ice

for preservation and shipping to the laboratory. A chain-of-custody. 1

record will be prepared for each lot of samples and will accompany the

samples to document the possession of the samples from the site to the

laboratory. " ."

flR3dOI95

FPRQ SAP Section 3S&HS Project No. 4112-88-900 Page 24 of 50


3.6.5 Analytical Plan

The borehole samples will be analyzed by IEA for selected parameters

from the TCL and TAL following CLP-SOW RAS procedures. The analytical

tests for the borehole samples will be selected after the completion of

Phase I of the RI.

The diabase rock" material from the core sample will be analyzed for

chronlum as a SAS following CLP protocol. SW-846 Method 1310 will be

used. The sample preparation and analytical procedure for this sample

will be as follows:

Collect approximately 150 grams of unweathered diabase rock fromcore barrel, place in-wide mouth sample bottle, seal and label.

/Ship the sample to the laboratory under chain-of-custodyprotocols.

>Analyze sample for chromium by extraction procedure toxiclty testmethod.

3.7 BOREHOLE GEOPHYSICS

3.7.1 Purpose

Upon completion of the drilling of each monitoring well, and prior to

screen placement, the borehole will be geophysically logged to obtain:

o Depth to bedrocko Location of bedrock fractureso Lithologlc changeso Conductivity changes

HR300196

FPRQ SAP Section 3S&ME Project No. 4112-88-900 Page 24a of 50

Revision No. 2.....:.•• : j'._. July 15> 19g8

...'.-..--..... -ii_ •-•:.--—- ;.-..:, _..;••-. _- T:- ..._ -.:::.______ Revised September 2r 1988

This information is needed to determine the geohydrologic parameters

of the site, potential flow and migration of contaminants from the

landfill, and to evaluate potential remedial alternatives for subsurface

contamination. The geophysical data will be used In comparison with the

boring logs to accurately define these parameters.

flR300197



Borehole geophysics will be conducted In the deep borings using the

following aethods:

o Temperature Loggingr- o Caliper Loggingi o Borehole Induction

. These logs will aid In the determination of fracture zones byj ,

1) measuring a temperature differential caused by the intrusion of water

Cflowing from the fractures, 2) gauging the competency of the formation,

based on changes in borehole diameter and 3) noting changes in electrical

conductivity produced from water bearing fractures. Acoustic logging in

n lieu of callper and borehole induction logging, will be performed If EPA

can coordinate logging by the USGS, the 5 7/8 inch borehole diameter Is

Ij sufficient and the logistics do not adversely effect the project schedule

~ or costs. To date no local contractors who perform acoustic logging have

** been Identified. >

ij3.7.2. Equipment

\2 The borehole logging will be conducted using the following tools and

P~ the respective methods of operation and use recommended by thee" manufacturer. - -

L o Temperature Tool - Log Master

P o Callper Tool - Log Master

o Borehole Induction Logger - Geonics LTD EM-39.

^ The temperature and callper tools are run on a truck mounted Log

* Master logging unit.

i fiR300i98L

FPRQ SAP .--.. —,...:. - - - - - -_,-._ Section 3S&ME Project No. 4112-88-900 page 26 of 50

Revision No, 2July 15, 1988

3.7.3 Procedure _ _____ ,

The three logs will be conducted in the deeper borings of the six well

clusters an4 _in the well adjacent to the fill area.

It is important that the tools and cable are decontaminated (Sectioni

6.0) between wells ensuring no cross-contamination between borings. The.—.— ...... ... . . -_ . . . . _ - - . . . .

decontamination procedure it as follows:

o Wash tool and cable with a phosphate-free soap and watersolution.

o Tap water rinse

__ _._ DI Water rinse

o Air dry .._._ .

o Wrap tool in aluminum foil (shiny side out)

Note: When logging a well, a technician may wipe the cable that hascome in contact with the boring with a towel soaked in soapysolution and then rinse with DI water as it is brought up.

After decontamination, the suite of logs will be run in the following

order: —^ " ------ ^ ^ _.._""..:

1. Temperature2. Borehole Induction (conductivity)3. Caliper

The logs will be conducted In this order as the temperature log

should be run when the water in the boring is least disturbed. The

borehole induction log will be run next, since disturbances In borehole

fluids may have some effect on the log. The caliper log will be run last- 'since it measures ~ "differences in the diameter of. the borehole and any

AR3.00I99

FPRQ SA? Section 3S&HE Project No. 4112-38-900 Page 27 of 50


j disturbances produced from previous logging will have little or no effect

on this log. - -I ' . -i Logging procedures are as follow:

r _ _ _ _ _ _ _ . _... . . _ . : _ _

o Set tripod over well I"1 • o Calibrate tools according to manufactures specifications

o Lower tool in well (make sure that unit is not turned on)[ o The caliper log must not "be attempted when lowering tool down! , well.

o When running temperature log, let tool set In bottom of hole to0 allow for thermal equilibrium, and to minimize instrumental

drift.. o Using counter, record bottom of boring in feet.o Run log coming up boring, line speed should be between 15-20 feet

per minute.o When log is finished, make sure that log height and actual well

depth agree.o Evaluate data quality, if necessary repeat loggingo Secure gear.o Decontaminate tool and cable.

C

C 3.8 TEST PIT SAMPLING

3.8.1 Introduction>

Test pits will "be installed within the landfill area to Identify the

waste materials. A minimum of two test pits will be dug to a depth of

five feet or less. Samples will be collected from the exposed layers of

waste materials other than household waste, trees, wood and construction

rubble. An OVA or HNu will be used to scan the exposed soils and waste

layers for organic vapor emissions.

3.8.2 Field Equipment

The field sampling equipment needed as follows:

^ o Stainless steel trowels and spoonso Aluminum foil

r

[i;

flR3Q0200



o Aluminum panso OVA or HNu PID/FID 'to Field log booko Camera and filmo Sample sealso Sample labelso Chain-of-custody formso Appropriate personal safety equipment

- " 3.8.3 Sampling Procedure .* * ' . . " ''.-'-...- . ' .- - - !

The rubber tired backhoe will be set up and readied for excavating at..._._,._ .__„. _.- , ... .--™ . -. - - - .. -,- ----- j

j J the desired test pit location. The area will be scanned with the OVA or

p HNu prior to excavation. The backhoe operator and sampling team will

*-* conduct this sampling with Level C Health and Safety Protection including

O protective clothing and full face respirator.L ' " . . . . . . . ,The test pits will be excavated us ing'a rubber tired backhoe. All

OSHA requirements will be strictly adhered to. If ;a;potentially dangerous

situation is encountered, the test pit will be backfilled and another site

selected. The backhoe will excavate the test pit In layers of one to two

feet at a time. The excavated material will be stockpiled adjacent to thei

pit. Upon completion of the sampling the excavated soil and waste

materials will be placed back into the test pit. iThe excavation will continue to the rock underlying the waste material

or a maximum of five feet. The test pit will be excavated a minimum of

two bucket widths wide or more to ensure stable slopes.

The sampling team will photograph and prepare a written description of

the materials exposed in the test pit. Each waste layer will be scanned

with an OVA/or HNu. The sampling procedure will follow the following

steps. '" " "_ . - . . _ . _ . . .-- . . _ =- ; -

I-AR30020

c

FPRQ SAP Section 3S&ME Project Ho. 4112-88-900 Page 29 of 50


o Scan the test pit location with the OVA or HNu PID/FID.

o Begin excavating the test pit with "the backhoe. The excavationwill proceed slowly with layers of one to two feet at a time.The field sampling team will observe the excavation process anddirect the backhoe operator.

o Upon completion of the excavation to the desired depth (maximum 5feet) the sampling team will record a detailed writtendescription of the materials exposed In the test pit includingburial depth and thickness of layers. A detailed photographicrecord will also be completed.

o Scan test pit walls with OVA or HNU

. o At each soil or waste zone to be sampled, a clean stainless steelspoon with be used to scrape and clean three areas on the surfaceof the zone. A clean spoon or trowel will then be used for eachof the cleaned areas to dig out a portion of the material. Aportion of each sample will be directly placed In a sample jarfor volatile analysis. Sample material from the three locationswill be then placed into a clean, aluminum foil pan. Thematerial will be mixed in the pan and the remaining samplebottles will be filled using a clean stainless steel spoon.

o Cap sample containers, seal, complete sample tag, recordinformation Into field log book.

o Place samples In iced cooler. >

Uo The sampling procedures will be repeated for each layer to besampled.

BTJ o Upon completion of sampling In the test pit, the backhoe will bef. i used to push the excavated material back Into the test pit.

r - 3.9 MONITOR WELL INSTALLATIONU

3.9.1 Introduction

^ The FPRQ work plan calls for the installation of six well pairs with a

03 well screened In the overburden, If saturated, and a well screened In the

bedrock. One additional well In the bedrock will be installed. If the

overburden Is absent or unsaturated, only one well may be installed. If

no water bearing zones are encountered, an alternate well location will be

c

flR300202

FPRQ SAP .- Section 3S&ME Project No. 4112-88-900 Page 30 of 50


selected. The approximate locations are given In the work plan. However,i

the specific locations will be selected^ in the field using the data fromi

the well siting analysis conducted during Phase I of the RI.i.-. ..=_= Tkg specific, purposes of the monitoring well network are as follows:

- --- -.. - . . .: - - ,

o Characterize the site aquifer systems;. . I

o Define the vertical and horizontal extent of the contaminantplume, if present;

o Monitor the contaminant concentrations;

o Determine the interconnection between the overburden and bedrockaquifers and the extent of interaquifer contaminant movement; and. . . . . . .-..=... __..._.-.. •- - j

o Estimate the rate of plume migration, if present.-- --" --- - -• -.- - - ' :3.9.2 Field Equipment : ,

The drilling equipment to be used for installation of the monitor

wells will include a hollow stem auger drilling machine, an air rotary

drilling machine, water truck, support vehicles, and the neaessary tools.i

The field geologist supervising the well installation will utilize the

following equipment. - - - . . - - - . r-j T :

o OVA or HNu PID/FID 'o Field log booko Water level probeo Sample jars for cuttingso Appropriate personal safety equipmento Camera ,

3.9.3 Monitor Wall Installation Procedure

In areas with overburden test borings will be completed using hollow

stem auger drilling techniques. Continuous split barrel samples will be

.-flR300203

r



collected In each test boring. The test borings will extend to auger

refusal. The procedures to be followed for* the test boring and sampling

are discussed In Section 3:6, Borehole Sampling. The test boring holes

will be converted to monitoring wells screened in the overburden and

weathered rock zone, if saturated. If problems are encountered in the

test boring, such as cave in or formation materials filling the hollow

stem, the test borings will be redrilled with the air rotary machine,I^»j temporary casing Installed and the monitor well constructed in the

p redrilled hole. If the overburden is unsaturated, the rotary rig will be

used to extend the borehole into bedrock following the procedures below.

|l The bedrock monitoring wells will be drilled using the air rotary

nethod. The air rotary machine will be used to drill an eleven-inch

[j diameter hole five feet into the bedrock. A six-inch diameter steel

p- casing will be set in the borehole and grouted into place. The grout will

be placed In the annular space around the six-Inch pipe* using a. tremie

[ p i p e and pumping the grout Into the hole from the bottom up. The tremiejj

pipe will be raised as the grout Is pumped into the hole. The grout will

y be allowed to set for at least twenty four hours before drilling Is

continued. No organic additives will be used in the grout or lubricating

agents.

The cuttings and water from the monitor well drilling will be

collected because of the potential contamination. The drilling site will

be covered with polyethylene sheeting on which the cuttings will be

collected. The sheeting will be extended approximately twenty feet down

slope from each well location and a collection sump will be constructed

and lined with the polyethylene. Any liquids generated during drilling

BR300201)

c



will flow down the sheeting and be collected in the sump. The liquids

will be bailed or pumped from the sump and placed in drums. A cuttings; °

deflector hood will be used to direct blown cuttings away from site

personnel. ,.,. V ,'-. - " .'.-..--, -,-=-_!--. -'-.--','- _zr.i_" """ • ----------- -••'•-- -~:'-_"-_ H

After the grout has set for 24 hours, the borehole into the bedrock

will be drilled by the air rotary method using a 5-7/8 Inch diametert -i.

bit. _= The drilling will continue until a water zone is encountered. If

the water zone is not encountered within fifty feet from the top of the

bedrock, drilling will be stopped pending a decision to continue drilling

or move to another location. The borehole In the bedrock will be drilled

using a minimal amount of potable water to cool the bit and control dust

in the borehole. Drilling will be stopped every five feet and the

borehole will be blown with air to determine if a water zone (fracture)

has been encountered. When a water zone is located, the borehole will be

drilled another ten feet. >

Upon completion of drilling the drill rods and bit will be removed

from the hole. After the water level in the borehole has stabilized, the

hole will be geophysically logged as described in Section 3,7 Borehole_ _ iGeophysics.

The monitoring wells will be constructed with two-inch diameter welli

casing and screen. It will be decided after the Phase I data has been

evaluated whether the casing and screen will be PVC or stainless steel.!

Stainless steel (304) will be used If volatile organics are identified asi

being of primary concern and PVC will be used if metals are of primary

concern-

flR300205

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FPRQ SAP Section 3SfiME Project No. 4112-88-900 Page 33 of 50


Well casing will be Installed In both the overburden and bedrock

wells. The bedrock wells will not be completed as open hole wells.

The wells will be Installed using ten feet of 0.010 inch slot size

well screen with a capped bottom. The annular area outside the well

screen will be filled with fine filter sand. The sand will be placed by

pumping through a treraie pipe extending to the bottom of the hole. The

well sand will extend one- to two-feet above the top of the well screen.

A one-to two-foot thick layer of bentonite pellets will be placed on top

of the sand by pumping through the tremie pipe. The remainder of .the

annular opening will be grouted to land surface by pumping grout from the

bottom of the opening upward using the tremie pipe. The tremie pipe will

be raised as the grout fills the hole. The bottom of the tremie pipe will

[j be kept below the grout level at all times. A four-inch diameter

f-7 protective casing with locfcable cap will be set into the grout to protect

the monitor well. A concrete pad will be constructc-d at the ground

p surface to facilitate drainage away from the well.

A schematic drawing showing the construction of the overburden and

{j. bedrock monitor wells is shown In Figure 3-4.

-•* After the grout has set up for 24 hours the wells will be developed a

until the sediment free water is obtained or the sediment content is no

j longer decreasing.

The well cuttings, drilling water and development water will be

H collected, placed In drums, and stored on site pending disposal.

-T The drilling equipment will be decontaminated upon arrival at the

site, between each well, and before leaving the site. The decontamination

JR300206

L


Revision No. 1— —— -- _ _ _ _ _ _ _ _ _ _ _ juiy 15. 1988

_•_ _ m __ .._. " r "— ' J_ i

procedure is discussed In Section 6.

The field geologist will have the following responsibilities duringi

well drilling and installation,i

. 1o Collect and describe formation cutting samples.

o Monitor air in borehole and air in working area with OVA or HNuat least every five feet of drilling.

! _ _o Maintain field log book and field records for: each well.io Make field determinations where applicable or contact task

coordinator or site manager when necessary.

o Document that the well drilling procedures and well constructionspecifications were followed.

...._. .. __.. . . . .._. —. —_—.-—.. ..._-._-.-fed

3.10 MONITOR WELL SAMPLING

3.10.1 Introduction

———The monitoring well installation plan for Phase II of the RI calls for

the installation of six shallow and deep wells nested together and one

additional deep well near the landfill. The monitoring wells will be

sampled one time during Phase II. ~ ":

3.10.2 Field Sampling Equipment _ ._ _ , . , - , ,

The field sampling equipment includes the equipment required for well

evacuation as well as the equipment required for the actual sampling.

o Water Level Probe - . _ ! ; _o Pneumatic Pump, discharge lines, control .box, nitrogen gas

cylinder and fittings '~ .o Portable pH metero Portable conductivity and temperature metero 55 gallon drumso Teflon bailers . . . . . . . . . - - - = -o Nylon line for bailers. . . . . . ; ,

AR73 00207



o Peristaltic pump, . o Backflush filter

o Sample container, as required, lab cleanedo OVA or HNu PID/FIDo Field log booko Sample seals

i . o Saraple labelso Chain-of-custody forms

[ - o Appropriate personal safety equipment

r% 3.10.3 Well Evacuation and Sampling Procedure

i--* The wells will Initially be evacuated to remove stagnant water, with

C p H , specific conductance and temperature recorded in the field and used as

a guide to Indicate when wells have stabilized and are ready fornjjj sampling. Generally, from three to five well volumes will be removed

prior to sampling.

" The purging will be performed using a pneumatic stainless steel and

[7 teflon puiap. The pump consists of a stainless steel body and fittings,Li • .

teflon ball check valves and polyethylene gas and water discharge fioses.

I.- Nitrogen will be used as the operating gas for the pump. The pump Is

designed such that water enters from the bottom; then nitrogen is pumped

ii under pressure through the nitrogen inlet hose, forcing the ball check

P valve at the bottom to close and discharge water through the discharge

hose. The pump is then cycled automatically either by electric orr?fe- nitrogen-operated timers at the ground surface.

The discharge hoses used during the well evacuation will be new

* polyethylene. The outside of the new hoses will be decontaminated and

r stored in new plastic garbage bags before use. The hose will be discarded

afteruse. AR300208l':

The well evacuation and sampling will be conducted using the following

procedure:

FPBLQ SAP Section 3S&ME Project No. 4112-88-900 Page 36 of 50


i

o Spread polyethylene sheeting, on ..ground near wellhead, placeevacuation and sampling equipment on sheeting.

io Unlock and remove protection cap, remove well cap, monitor

headspace with OVA or HNu measure water level, record In logbook. - !

o Calculate volume of standing water in the well by multiplying thefeet- of water in the well by 0.16 tq get 1 well volume ingallons. The volume to be evacuated will be approximately threeto --five times this volume. Record calculations In field logbook.

io Connect tubing to pump and lower into the well. Connect above

ground end of gas tubing to control unit.

o Begin pumping set pumping rate to minimize drawdown. The waterpumped from the well will be discharged into a 55 gallon drum forstorage until a disposal method is approved. The pH andconductivity will be measured frequently during the evacuation.Purging will continue until three consecutive readings of pH andspecific conductance Indicate stability. The three readings ofpH must be within 0.1 units. The conductance readings must agreewithin 10 percent. - However, if the values do not agree withinthe desired limits, then a maximum of 10 well volumes will be/removed .prior to sampling. A minimum of 3 well volumes will be'evacuated. The pump will be withdrawn prior to sampling.

*o Upon completion of the well evacuation the pump will be removed

from the well. - --- - •i

o The" well will then be sampled using a clean teflon bailer and newnylon cord. The bailer will be lowered slowly into the well andslowly into the water to minimize agitation. The first bailer ofwater will be wasted into the water collection drum. The samplebottles for organic analyses will be filled by pouring slowlyfrom the bailer Into the sample bottles. The volatile bottleswill be filled first.

o Samples for inorganic parameters will be filtered prior toplacement In the sample bottle. A decontaminated peristalticpump and backflush filtering apparatus will be used. The samplewill be pumped from a collection bottle through a 45 micronfilter Into the sample bottle. The first 250-500 ml of samplethrough the filter will not be used but wasted to the watercollection drum.

a Seal the sample bottles, complete sample tag and chain-of-custodyrecord and place sample bottles into iced cooler.

Complete recording data In field log book. The data. < |Ethe log book will Include, ..date, time, well nurafrer*, , samp Zingpersonnel, weather, depth to water, measured Indicator parametersduring purging, OVA readings, total well volumes removed.



o The well caps will be replaced, the well cap locked and thesampling team will proceed to the next well.

3.10.4 Ground Water Analytical Plan .

The Initial samples collected from the new monitoring wells will be

[" analyzed for the TCL and TAL parameters and selected water quality

parameters (Table 3-1). The proposed water quality parameters include

total dissolved solids, and major ions.

ti

c 3.11 SURFACE WATER AND SEDIMENT SAMPLINGF

M 3.11.1 Introduction

Surface-water and sediment samples will be collected from six

11 locations. The locations Include one leachate seep channel, two

Identified spring locations and three locations In Lawless Creek. This

f__, sampling' will be conducted to help define the contaminant pathways on and>

p off site. Flow measurements will also be made where possible, following

sampling.

U The saapling includes a low flow period sample .and a high flow period

sample following a precipitation event.

f" 3.11.2 Field Eoultment _

The following field equipment will be used to collect the surface

j|; water and sediment samples.

f o Stainless steel beaker and extension pole£} o Stainless steel trowels and spoons

o Sample bottles, as required, lab cleanedy o Portable pH, dissolved oxygen, temperature and conductivityi meters

flR3002!0


Revision No. 2, July 15, 1988

-- —— - - " -

o Aluminum foil & panso Polyethylene sheetingo Field log booko Camera and filmo Sample_seals : :_ro- Sample labels - - --- ---- -o__ __Chain-of-custody formso OVA or HNu PID/FIDo Appropriate personal safety equipment

-3-.l_L_3- Stir face-Water Sampling Procedure

Collect sample for volatile analysis directly from surface-water.If possible.

_ ____. . ....-..- . . —- --J

Assemble the beaker and extension rod

_Pip the sample from the flow channel by slowly lowering thebeaker into the water column. The beaker will be lowered to theapproximate mid point of the water column. Care will be takennot to disturb the bottom sediments.

If the flow Is low and the beaker cannot be easily filled, a/small hole will be excavated into the stream bottom Into which-the beaker will be lowered. The sample will not be collecteduntil the sediments disturbed during digging *the hole havesettled. The water sample will be collected from the upstreamwater flowing into the hole. Care will be taken to not disturbthe bottom sediments. ,

iFill the sample bottles by slowly pouring the water from thebeaker Into the sample bottles. If additional water Is requiredto complete filling the sample bottles, additional water will becollected from the same sample location. Addition sample will beplaced In each bottle of a sample set so that each has the samerelative mixture.

Cap sample containers, seal, complete and attach sample tag,record all pertinent data Into field log book.

. . , - . _ . . . . . . , . - , iPlace samples In iced cooler.

Collect sample for measurement at field parameters. Measure theparameters (pH, conductivity, dissolved oxygen and temperature)using procedures specified for equipment. Record readings Infield log book.

AR3002II

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FPRQ SAP _ Section 3S&ME Project No. 4112-88-900 Page 39 of 50


o Measure flow using appropriate method (i.e., flume , weir , orpygmy meter) .

3.11.4 Sediment Collection Procedure

The sediment samples will be collected from the bottom of the stream

channel at a point within five feet of the surface water sample location.

The sediment samples will be collected after the surface water samples are

collected.

o Select convenient location and place a double layer of aluminumfoil on ground.

o Collect sample for volatile analysis directly from media , Ifpossible.

o The stainless steel beaker attached to the extension pole will beused to scoop sediment from the bottom of the channel if thewater depth Is to great to allow use of a trowel. If the waterdepth is shallow, the sediment will be scooped from the bottom: using a trowel or spoon. The sediment will be placed on the' aluminum foil pan and mixed before filling the sample bottles .

>o Fill the appropriate sample bottles using a stainless steel spoon

to transfer the sediment Into the bottles

o Cap~ sample containers, seal, complete sample tag, record allpertinent data Into field log book, photograph site.

o Place samples into cooled sample chest.

3.11.5 S gfsee-ffater and Sediment Analytical PlanE'

The first round of surface-water and sediment samples will be analyzed

„. for all TGL and TAL parameters along with total dissolved solids, total

* suspended solids and major ions. The second round of samples will be

£" analyzed for a short list of Indicator compounds selected from all sitefe

data sources. Two second round water samples will be analyzed for the TCL

and TAL parameters to evaluate flow dependent variances.

SR3002I2

C



. _._.... ______ . . . . .. ... . _.. . . . . . .3.12 SOIL SAMPLING }

3.12.1 Purposei

The soil sampling will be conducted in areas determined to be

envircfnmentally sensitive or areas where contact with contaminants by the

public is most likely. The work plan specifies collecting samples from

1). a 50' by_50^ grid within the quarry area, 2). a 100' by 100' grid

within. 100' of the quarry edge; 3). sampling in the area of stressedivegetation northeast of the site; and 4). sampling downgradient from the

site. . ...... ...—.. _ - _ _ _ _ — . , -- - - -

The objective of the soil sampling is to determine which areas of soil

within the grid area may require, excavation for treatment or disposal andi

which areas may require covering to prevent direct contact.

ii3.12.2 Field Equipment . " . '

The field equipment required for collecting the soil samples will

Include the following:

o 100 foot tape measures - 2o 300 foot tape measures - 1o Compasso Pin Flags - 2 colorso Bucket hand augerso Aluminum or stainless steel-panso Aluminum foilo Stainless steel spoons and trowelso OVA or HNu PIDo Field log booko Sample seals —o Sample labelso Chain-of-custody formso Sample bottles, laboratory cleanedo Coolerso Wheel barrowo Shovelso Appropriate personal safety equipment

AR300213

FPRQ SAP .._ _ _ . . Section 3S&HE Project No. 4112-88-900 Page 41 of 50


3.12.3 Soli Sampling Procedure _

The soil samples will be collected from randomly selected areas within

each grid area and from areas of visibly distressed vegetation or visibly

^ Identifiable areas of concern. The samples will consist of the entire

soil column from the surface to the selected sample termination depth.

Appendix A presents further details on the random sampling procedure.

The Initial soil sampling activities for the site will be performed

Li utilizing the following criteria. These criteria have been established to

p fully Investigate the site soil conditions and prevent bias In the

stapling program.

ni i^ 1. Onslte 50' X 50' grid areas will be established as diagramed in

Figure 3-5.

Li. 2. Off site 100' X 100''grid areas will be established as diagramedIn Figure 3-5.

L"3. From each grid area, one sample may be collected from an area of

obvious contamination or vegetative stress and1* submitted foranalysis.

4. Each grid area will be subdivided into 25 sectors and numbered asdiagramed In Figure 3-5.

* fli 5. From the subdivided grid area two sample locations (two of the 25

sectors) will be selected by random number generation.

y 6. .Two samples from the randomly selected sectors will be collected,described Itthologically and logged into the project fieldbook.

„ The samples will be subjected to a headspace analysis utilizing. the HNu or OVA (Appendix B). The HNu or OVA scan results will be** logged in the project fieldbook.

§7. If one sample has an HNu or OVA reading 10 ppm above thebackground level, It will., .be submitted for analysis. If bothsamples have HNu or OVA readings 10 ppm above the background

r" level, the sample with the highest reading will be submitted for^ analysis,

3., 8. If neither sample collected randomly from a grid square indicatesHNu or OVA readings 10 ppm above background levels, both samples

w

I AR3002II.

FPRQ SAP Section 3S&ME Project No. 4112-88-900 _ . . . . _ . _ _ _ _ _ _ _ _ Page 42 of 50


will be assigned sequential numbers, logged into the projectsampling notebook and stored for possible future analysisaccording to the random selection procedure.

9. From the samples collected, and not submitted for analysis basedP on visual observations or headspace analysis, a random number[ generation program will be utilized to select up to 10% of these

samples for laboratory analysis.. . . ...._.._._ . -~ - . - ---. - . ; .|

10. One biased background sample will be collected from the areasoutheast of the quarry and submitted for analysis.

O i l . Assuming that there are no areas of stressed vegetation, orobvious contamination, and none of the random samples meet theheadspace criteria, then a minimum of five samples, four random

p (10% of random sample population) andl one background, will bejj submitted for analysis. The maximum number of samples depends

upon observed impacts.n - - !

The grid overlying the site will be constructed be establishing a

baseline that transects the quarry. The baseline will be marked at 50'

Intervals and lateral lines will be laid perpendicular to the baseline

using a compass and tape measure. This process will continue until the 12

onslte 50' X 50' grid squares have been constructed. Following

establishing the onsite grid, the offsite 100' ,X 100' grid will be

extended to cover the remainder of the study area. - All grid corners willi

be marked with pin flags which will be labeled as grid corners.

The sample sectors of the grids will be established prior to sampling!

by measuring and marking the grid square as diagramed In Figure 3-5. The

sample sites which will have been previously generated, will be markedi

with pin flags of a different color than the grid squares. All sample

locations for all sample grids will be established prior to collecting anyi

samples, . " = . . . . . . . . .

The procedure for collecting the soil samples will be as follows:

AR300215



*• =• . - -

o Visually scan grid for areas of stressed vegetation or visiblycontaminated soil. Mark any of these areas with pin flag (secondcolor).

o Locate the randomly selected two additional locations within theP grid.1 ,

o The sample location will be cleared of surface litter such as, - grass, leaves, etc. by scraping with shovel or spoon.

o Remove aluminum foil covering from clean bucket hand auger anduse the hand auger to collect soil sample. The soil sample will

n consist of a composite of all the soil removed from the hole,therefore only one hand auger will be used for each sample,

Co The soil will be extracted from the auger bucket using thestainless steel spoons. The soil will be collected in a foil

- sample collection pan.0'

o The hand auger holes will be extended to a minimum depth of twofeet and a maximum depth of four feet.

CC

o The soil collected in the pan will be mixed using a stainlesssteel spoon following'collection of the volatile sample.

o Fill the sample bottles and the head space analysis bottle usinga new clean spoon.

o Cap and label the sample collection bottles. Cap and label thehead space analysis bottle.

o Conduct the head space analysis according to the procedure InP Appendix B.

o Place sample In cooler with ice.

ri o Complete field log book record.i_*

-„ o Proceed to next sample location and repeat procedure.LUpon completion of the soil sampling, the samples to be submitted to

m the laboratory for chemical analysis will be selected based on the

r* criteria discussed above. A chain-of-custody for these samples will beL prepared to accompany the shipment of the samples to the lab. The

rRR300216

FPRQ SAP . - - . - - . _ section 3S&ME Project No. 4112-88-900 Page 44 of 50


September 2, 1988

remaining samples will be placed in open top drums labelled, achieved and

stored in the fenced storage area pending disposal.

Any additional waste materials generated during the soil sampling will

also be placed In drums and stored in the fenced storage area.i

3.12,4 Analytical Plan . . . . . .

The analytical parameters for the soil samples will be determined upon

completion of the Phase I sampling and analysis (Table 3-1). The

-parameters will -consist of selected compounds identified during the TCL

and TAL analyses conducted during Phase I. The samples will fee analyzed

by IEA following EPA contract laboratory program analytical and QA/QC

procedures. - . _i

3.13 SAMPLE CONTAINERS, PRESERVATION AND SHIPPING >

3.13.1 Typical Sampling Procedures

The flow chart on Figure 3-6 outlines the typical sampling procedures

for use at the site during all sampling efforts. Specific samplingi

procedures are described under each task.

ii

3.13.2 Sample Concentration Designation

Low-Concentration SampleThe contaminant of highest concentration is present at less than10 parts per million (ppm). Examples include backgroundenvironmental samples.

Medium-Concentration SampleThe contaminant of highest concentration is present at a levelgreater than 10 ppm and less than 15 percent (150,000 ppm).Examples Include material onsite that is obviously weathered.

fiR300217



High-Concentration SampleAt least one contaminant is present at a level greater than 15percent. However, all samples collected to date have been low tomedium concentration.

3.13.3 Sample Containers And Preservation _ ,_

The saurple containers used for all samples collected will be provided

by the contract lab. The containers will be pre- cleaned following the

protocols outlined In lEA's standard operating procedures and Included as

part of Appendix D.

All samples will be containerized and preserved following the criteria

outlined in 40 CFR Part 136 . A chart listing sample parameters ,

container, preservative and maximuia holding time Is Included In Appendix

D.

Table 3-3 Is included to outline the project specific containers ,>

preservatives and holding times.

3.13.4 Sam-pie

Prior to shipping, samples will be stored In their shipping containers

either In the site trailer or a clean zone of the fenced compound. Due to

the proximity of the FPRQ site to the contract lab and the logistics of

mobilizing personnel to the site, all samples from the FPRQ site will be

directly transported by IEA or S&ME staff to the laboratory for analysis.

This procedure will eliminate the need for using public transportation or

private carriers for transporting samples. The laboratory will be called

AR300218

FPRQ SAP -—.„..-_,=-. ...... ——— -Sectjon 3S&ME Project No. 4112-88-900 Page 45a of 50


prior to sample delivery to confirm they can accept delivery and handle

will be lEA's samplethe samples appropriately. Mr. Gary Gilllland

custodian for this project.

All samples delivered to the lab will be labeled, packaged and handled

in accordance with the shipping protocols outlined in the following

sections.

3.13.4.1 Environmental Sample Shipping Low-concentration samples

are defined as environmental samples and should be

as follows

packaged for shipment

flR300219

FPRQ SAP Section 3S&KE Project No. 4112-88-900 Page 46 of 50


1. A sample tag Is attached to the sample bottle. Examples ofproperly completed sample tags are given In Appendix C.

2. All bottles, except the volatile organic analysis (VGA) vials,are taped closed with electrical tape (or other tape asappropriate). Evidence tape may be used for additional samplesecurity.

_3. Each sample bottle Is placed In a separate plastic bag, which isthen sealed. As much air as possible Is squeezed from the bagbefore sealing. Bags may be sealed with evidence tape foradditional security. . _

4. A cooler (such as a Coleman or other sturdy cooler) will used asa shipping container. In preparation for shipping samples, thedrain plug Is taped shut from the Inside and outside, and a largeplastic bag Is used as a liner for the cooler. Approximately 1

. inch of packing material, such as asbes tos - free vermiculite,perllte, or styrofoam beads, is placed In the bottom of theliner. Other commercially available shipping containers may beused.

5. The bottles are placed in the lined picnic cooler. Cardboardseparators may be placed between the bottles at the discretion ofthe shipper.

• - -6. Water samples for low or medium-level organics analysis and

low-level Inorganics analysis must be shipped > cooled to 4°Cwith Ice. " No ice is to be used in shipping inorganic low-levelsoil samples or medium/high-level water samples, or organichigh-level water or soil samples, or dioxin samples. Ice is notrequired in shipping soil samples, but may be utilized at the

f? option of the sampler. All cyanide samples, however, must be^ shipped cooled to 4°C.

, * 7. The lined cooler Is filled wi th packing material (such asasbestos-free veraicullte, perilite, or styrofoam beads), and the

*"* large Inner (garbage bag) liner Is taped shut. Sufficientpacking material should be used to prevent sample containers frommaking contact during shipment. Again, evidence tape may be

K- used.

p 8. The paperwork going to the laboratory is placed inside a plasticy hag. The bag Is sealed and taped to the inside of the cooler

lid. A copy of the COG form should be Included in the paperwork,, sent to the laboratory. Appendix C gives an example of a COG

fona. The laboratory should be notified or if the shipper^ suspects that the sample contains any other substance for which

the laboratory personnel should take safety precautions.

fiR3Q0220



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9 The cooler is closed and padlocked or taped shut with strappingtape. ' ;

10. At least two signed custody seals are placed on the cooler, oneon the front and one on the back. Additional seals may be usedif the sampler or shipper thinks more seals are necessary.

3.13.4.2 Hazardous Sample Shipping :i

Medium -and high-concentration samples are defined as hazardous. Only

source area samples may meet this criteria. Packaging of these samples

will be as follows: ;

1. A sample tag Is attached to the S£iinple bottle. Appendix Ccontains an example sample tag.

2 . All bottles , except the VGA vials , are taped closed withelectrical tape (or other tape as appropriate) . Evidence tapemay be used for additional security.

3. Each sample bottle is placed in a plastic bag, and the bag issealed. For medium- concentration water samples, each VGA vial iswrapped In a paper towel, and the two vials are placed in onehag. As much air as possible is squeezed frou* the bags beforesealing . "Evidence tape may be used to seal the bags foradditional security.

4. Each bottle Is placed in a separate paint can, the paint can isfilled with vermiculite, and the lid Is fixed to the can. Thelid must be sealed with metal clips or with filament or evidencetape; if clips are used, the manufacturer typically recommends

-six clips.

5. Arrows are placed on the can to indicate with end Is up.

6. The outside of each can must contain the property DOT shippingname and identification number of the sample. The Informationmay be placed on stickers or printed legibly. A liquid sample ofan uncertain nature . is shipped as a flammable liquid with theshipping name "FLAMMABLE LIQUID, N.O.S." and the Identificationnumber "1 1993." A solid sample of uncertain nature is shippedas a flammable solid with the shipping name "FLAMMABLE SOLID,N.O.S." and the Identification number nUKl325." If the nature ofthe sample is known, 49 CFR-171-177 Is consulted to determine theproper labelling and packing requirements.

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SAP Section 3S&ME Project No. 4112-88-900 " Page 48 of 50


7. The cans are placed upright in a cooler that has had its drainplug taped shut inside and out, and the cooler has been linedwith a garbage bag. Vermiculite is placed on the bottom. Twosizes of paint cans are used: half-gallon and gallon. Thehalf-gallon paint cans can be stored on top of each other;however, the gallon cans are too high In stack. The cooler Isfilled with vermlculite, and the liner Is taped shut.

8. The paperwork going to the laboratory Is placed inside a plasticbag and taped to the inside of the cooler lid. A copy of the COGfom, an example of which Is shown in Appendix C, should beincluded In the paperwork sent to the laboratory. The willsaopler keeps one copy of the COG form. The laboratory should benotified if the sample is suspected of containing any substancefor which laboratory personnel should take safety precautions.

9. The cooler is closed and sealed with strapping tape. At leasttwo custody seals are placed on the outside of the cooler (one onthe front and one on the back). More custody seals may be usedat the discretion of the sampler.

10. The following markings are placed on the top of the cooler.

o Proper shipping name (49 CFR 172.301o DOT Identification number (49 CFR 172.301)o Shipper's or consignee's name and address (49 CFR-172.306)o "This END UP" legibly written if shipment contains liquid

hazardous materials (49 CFK. 172.312. >

11. An arrow symbol(s) Indicating "This Way Up" should be placed onthe cooler in addition to the markings and labels describedabove.

Other commercially available shipping containers may be used. The site

manager will ascertain that the containers are appropriate to the type of

sample being shipped.

3.14 FIELD EQUIPMENT CALIBRATION

The following section Is a synopsis of field Instrumentation

calibration procedures which will be utilized during the Investigation of

the FPRQ. Each piece of field equipment will be calibrated as described

n PI •"> o n "n "" oA Ro 00. 2 2

FPRQ SAP "... .._. _ :.'.?'' Section 3S&ME Project No. 4112-88-900 Page 49 of 50


below and a log maintained to document the calibration performed. The

calibration log will be maintained by the site manager and stored In the

onsite office.

Portable pH meters will be checked before each use for mechanicaland electrical functions, weak batteries, and cracked or fouledelectrodes. The meter will be checked against two buffersolutions (at pH 4.0 and 7.0) before sampling each well. Thebuffer solution containers shall be refilled each day from freshsolution stock.

Temperature will be measured by the temperature probe of the pHmeter. The temperature probe will be calibrated weekly duringuse with a calibrated thermometer and the condition of the probechecked prior to each use.

o The specific .conductance meter will be checked for mechanical andelectrical function at each sample station and will be calibrateddaily as per the manufacturer's directions and specifications.The specific conductance meter will be checked against a standardsolution of NaCl, KC1 or other solution of known concentrationand adjusted for the temperature change.... __ _. ...........

o The dissolved oxygen meter will be checked prior to each use formechanical and electrical condition. The meter will becalibrated In air or as specified by the manufacturersrecommendation dally.

o The portable explosimer/oxygen meter will be checked each day forbattery charge. The oxygen sensor will be cleaned and/orreplaced as needed when the sensor becomes non-functional. Afunctional check will be performed by breathing on or placing ahand over the probe (oxygen meter) and/or using a calibration gas(explosimeter), per the manufacturer's recommendations.

o The HNu will have the battery, lamp, and fan checked before eachfield use. Isobutylene will- be used as a calibration gas toperiodically check the sensitivity of the lamp. The unit will bechecked with vapor from a magic marker daily. The probe will becleaned and/or replaced as needed.

o The organic vapor analyzer (OVA) will be checked before eachfield use. The battery charge, probe/side pack assembly leakagesand possible .cylinder leakages will be checked. A step-by-stepstart-up procedure from the instruction manual will be followedfor the OVA, and the OVA's response will be checked with vaporform a- magic marker. ™: The instrument will be calibrated weeklyusing manufacturer supplied calibration kit.

fiR30Q223

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Geophysical surveys will generate data that Is evaluated based onrelative differences or contrast rather than absolute values .Equipment will be maintained and checked daily for properoperation as per the manufacturers recommendation.

Equipment such as engineer's rules, surveyor's tapes and otherlinear measuring devices will be checked for conditions prior touse but will not be calibrated.

Acceptance and control limits for Instrument calibration will be set

based on the manufacturers recommendations and guidance. No measurementsn- will be made with an instrument that does not meet the control limitsLa

Table 3-4 presents a list of critical spare parts for field equipment.

SR30022li

FPRQ SAP Section 4S&ME Project No. 4112-88-900 . ]?age 1 of 6


4.0 DATA MANAGEMENT PLAN ,

4.1 GENERAL DOCUMENTATION PROCEDURES j

The field team will have at least one person who Is thoroughlyi

familiar with the appropriate documentation procedures. This person willi

personally perform, or directly oversee, the completion of the documents

which accompany the samples. The documentation tasks shall be performed

on a sample-by-sample basis throughout the day. However, shipping

containers and some paperwork can be prepared in advance for incoming

samples. _ _ _ _ _ _ .... . _ . . . .

One person on each sampling team will record the field data. All

field documents will be completed in indelible Ink and be legible.!

Corrections may be made by lining through the incorrect entry, adding the

correct Information and initialing the correction. If corrections cannoti

be made legibly, or if a document is damaged, it must be marked "void",

returned to the document coordinator, and noted in the field log book.

Reasons for major corrections will be noted In the lo'g book.

4.2 FIELD/LABORATORY DOCUMENTATION

Sample possession must be traceable from the time the sample is

collected, to its delivery to the IEA laboratory. In order to identify

4R300225

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the samples and manage the Information, samples will be numbered

sequentially In the following manner:

FP-001 A,B Ground water; monitoring well samples; A-shallowwells, B-deep wells.

FP-101 Soils (100 series); test borings, hand augers soilsamples

FP-201 Sediments (200 series); sediment samples, andgravel-pack sand

-FP-301 Surface water (300 series); normal and wet weathersamples and decontamination and drilling supplywater.

FP-401 Source Area Samples (400 series); test pits, wastepiles, drums, leachate streams, and pond samples.

FP-501 A,B Borehole samples (500 series); overburden samplesi from monitor well boreholes.

FP-601 Diabase dike core sample (600 series>.

FP-701 A,B Test pit samples (700 series), A-Aqueous; B-Solid.

Duplicates, spikes and blanks will be incorporated Into the appropriate

category and numbered consecutively. Splits will be labeled with the same

sample number and marked with the letter "A" designating it as a split.

To provide documentation and quality control, the following records and

forms will be used: Examples of the forms are contained In Appendix C.

r 4.2.1 Field Log Books

Permanently bound field notebooks will be used to provide the means of

f recording data and activities performed at the site. They will-be field

survey books or equivalent. Entries will-be described In as much detail as

£ flR300226


_____ ..__ _ Revision No. 2July 15, 1988

practical. Each notebook will be identified by the project-specific

document number. The cover of each notebook will bear:

o The name of the person or organization to whom the book isassigned _ _ _.. .__

io -Project name and number

o Book number

o Start date and

o End date

At the beginning of each entry, the date, start time, weather, field

personnel present, and level of personal protection being used during a

specific activity will be recorded.

The names of visitors to the site and the purpose of their visit will

also be recorded in the field notebook by the Site Manager.- .-_.- . . ... ._.,. . . ..... _ . .__ .... _..._...._j.._.. . ^

All measurements " made and samples collected will be recorded. All

entries will be made in indelible ink and no erasures will be made.iIf an incorrect entry Is made, the information will be crossed out

* iwith a single strike mark and initialed by the, person making the

correction. Wherever a sample Is collected or a measurement made, ai

detailed description of the sampling location shall be recorded. All

equipment used to make measurements will be recorded. All notes shall be

objective and factual: no personal comments shall be recorded.

Each team member Is responsible for maintaining security for his/her

field notebook. Only the person to whom the notebook Is assigned shall

write in that notebook.

AR300227

FPRQ SAP _____ Section 4S&HE Project No. 4112-88-900 Page 4 of 6


Saiaples will be collected following the procedures documented in this

plan. The equipment used to collect samples will be noted, along with the

tine of saiapllng, sample description, depth at which the sample was

1 collected, and volume and number of containers obtained. In addition, the

cooler nuatber Into which the samples are placed in the field will bei

recorded. Duplicates, which will receive an entirely separate sample

Pj | nuniber, will be noted under the sample description. All directions from

this plan will be noted In detail

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4.2.3

Sample tags will be similar to the EPA Identification tags. All

Information will be filled .out and the tags will be attached to each

sanple container.

>

4.2.3 Chsln-of-Custody Record

The chain-of-custody record will contain a summary of the contents of

the shipment , dates , times , sample numbers and signatures for the

transferral of the samples.

I' 4.2.4 Honltorlng ffell Data SheetL

The monitoring well data sheet will provide a convenient format for

y recording water levels, information to determine the water volume to be

purged from the well prior to sampling, and other pertinent data. Data

** which must be obtained from each well includes:

o Well location and. Identification numberso Depth to water

flR300228



o Total well deptho Standing water heighto Volume of the standing water column

4.2.5 Monitoring Well Schematics iThe monitoring well schematic will provide a summary of pertinent

monitoring well Information including: date drilled, drilling method,

observing geologist, well depth, screen depth and construction technique.

A modified version of this will be incorporated into the formal report.

i4.2.6 Test Pit Records . . ,

The test pit records will provide a summary of pertinent information

recorded during test pit excavation including: date excavated, sampling

personnel, llthologic and strategraphic Information, samples taken and

observations relating to artificial conditions. A fin_al version will

appear in the formal report.

4.3 OTHER RELATED DATA " ^ •

Other related presentation and sources of data will include

Illustrations, graphs, meeting summaries, audit reports and the RI

reports.. These data will be kept in a locked cabinet unless in use._ . . _ _ . _ • _ • _ • _ — " - " - - - - - - !

iI

4.3.1 Meeting Summaries, telephone conversations, and general notes

These will be recorded in the* field notebooks, along with the date,____ i

time and names of personnel Involved. Meetings can be project and/or

safety related. — •— - -- - ; : ,

flR300229

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7.TRQ SAP Section 4S&ME Project No. 4112-88-900 Page 6 of 6


4.3.2 Illustrations. Computations. and Other Engineering Documents

Original Illustrations and graphics will be Initialed and dated by the

person originating the document. A second person will check these

documents for completeness and needed corrections.

4.3.3 Progress Reports

These will be written periodically by the Site Manager to include:

nuraber of test pits excavated, number of samples taken, number of

monitoring wells Installed, deviation from approved field and laboratory

methods, any advice or guidance dealing with quality control for field and

laboratory activities, and questionable practices or procedures noted in

the field or laboratory. These reports will be directed to the Project

Manager for comment and/or action.

>

4.3.4 Bl Resorts

The Phase I and Phase II reports shall be written at the end of each

phase and completed after all analyses for samples collected In that phase

have been evaluated. As discussed In the Work Plan, the report will

consolidate and summarize data and document the site evaluation.

Approximately 20 copies of the draft report and 30 copies of the final

report will be made available. Once the final report has been accepted,

one copy of the final report will be kept and placed In a locked file

cabinet.

AR300230

iflk



5.0 INITIAL PROJECT SCHEDULE

i " the schedule for the FPRQ RI/FS is shown on Figure 6-1 of the Work

Plan, and is amplified on Figure 5-1 of- this document. The graphicP - :j I schedule on Figure 5-1 anticipated final approval of the project plans by• - * . _ . - . . _ . - - — . . . .

.August 1, 1988. Final approval of the plans was not received until August

£-1 ---- 17, 1988. Consequently, the schedule of tasks and project deliverables is

p extended In accordance with the schedule, Figure 6-1, in the Work Plan.LJi ' "' - .. - ;

Delivery dates In the Consent Order are determined by reference to the

number of months allowed In the Work Plan schedule for the task,

subsequent to approval of the Project Plans. Nevertheless, EPA has

approved', and Respondents have instructed, S&ME to begin work on Tasks 2.0i >

and 3.0 prior to the final approval of the project plans, and the parties

have cooperated In planning the schedule of other tasks In anticipation of

approval. These tasks may in fact be accomplished . earlier than indicated

on the extended schedule,

flR'30023

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FPRQ SAP Section 6S&KE Project No. 4112-88-900 Page 1 of 2


SECTION 6

DECONTAMINATION PROCEDURES

S. 1 DECONTAMINATION AREA

A designated area for equipment and personal decontamination will be

established adjacent to the site entry point. Decontamination areas will

be established for large equipment, (e.g. auger drill machine, backhoe)

sampling equipment and tools and personnel. The areas will be adjacent but

separate because of the differences in decontamination procedures. Both

decontamination areas will be bermed to prohibit uncontrolled change.

The decontamination area for the large equipment will consist of a

flat, cleared area covered with a double layer of 20 mil polyethylene

sheeting. A hole will be excavated in one corner of the pad in which the

cleaning liquids will be collected. The liquids will be bailed or pumped>

from the pit and stored in drums pending disposal.

The decontamination area for the sampling equipment and tools will be

located adjacent to the large equipment decontamination area to provide0 accessibility for both areas to the steam cleaner. This area will be a 20

nil polyethylene lined area with a liquid collection sump. The liquids

collected In the sump will be bailed or pumped into drums for storage

pending disposal. The area will be constructed large enough to accommodate

racks for holding tools, tubs containing the cleaning solutions and if

necessary a work bench.

I . ftR30Q232

FPRQ SAP Section 6S&ME Project No. 4112-88-900 I'age 2 of 2


The personnel decontamination area will also be a 20 mil polyethylene

lined area constructed adjacent to the equipment cleaning area.

6.2 DECONTAMINATION PROCEDURES

The decontamination procedures for each of the work activities and

equipment are shown on Table 6-1. A copy of the Table will be posted at

the decontamination area for reference.

. Health and safety precautions will be followed during the cleaning

procedures to minimize contact with potential contaminants on the

equipment. Breathing protection will be utilized daring the steam cleaning

procedures to minimize exposure to contaminants volatilized.during thei

steam cleaning.

SR3Q0233

r"



SECTION 7

SITE MANAGEMENT PLAN

7.1 FIELD PERSONNEL

The SSME personnel on site during the field sampling activities will

be under the supervision of the S&ME Site Manager and the S&ME Health and

Safety Officer or designate. The chain of command from the Site Manager

to the EPA priiaary contact will be through the designated S&ME Project

Contact. The chain of command with the individual identified is shown in

Figure 7-1.

Mr. James Wren, Responder' s Committee Chairman, Is the principal

representative for the Respojiders. The Responders have designated Mr.

Ernest Parker, Jr., P.E. of S&ME as the Site Coordinator for the

Responders pursuant to the Consent Order. Mr. Parker is Ey&ME's principal

project coordinator and is responsible for day-to-day communications with

the EPA's Site Coordinator.

7.2 SITE SECURITY AND ACCESS

Security on the FPRQ site will be established by constructing a fence

around the site and posting appropriate warning signs. A separate storage

area will also be constructed by enclosing a designated area with fencing

to provide security for samples, equipment and waste materials generated.

flR30023tt


Revision No. 2July 15, 1988ii

All fence gates, store boxes and doors will be locked when not being

directly used and when no personnel are present on site.i

Access to the site will _be controlled by the Site Manager (W.

Robertson) and the Respondent Coordinator (J. Wren). All personnel

entering the site will be approved by the Site Manager and the Site Health

and Safety Officer (or his designee). The Site Manager will maintain ai

daily site entry log. The entry log will Include the name, affiliation,

time of entry and time of exit for all individuals on the site.

•flR.300235

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FPRQ SAP . __ . .Section 6S&HE Project No. 4112-88-900 Page 1 of 2


SECTION 6

DECONTAMINATION PROCEDURES

I 6.1 DECONTAMINATION AREA

A designated area for equipment and personal decontamination will be

established adjacent to the site entry point. Decontamination areas will

j , be established for large equipment, (e.g. auger drill machine, backhoe)lj

sampling equipment and tools and personnel. The areas will be adjacent butf * -L separate because of the differences In decontamination procedures. Both

r

»* decontamination areas will be bermed to prohibit uncontrolled change.

The decontamination area for the large equipment will consist of a

j flat, cleared area covered with a double layer of 20 mil polyethylene

sheeting. A hole will be excavated in one corner of the pad in which theL""1 . . . — - ; - -

cleaning liquids will be collected. The liquids will be bailed or pumped

. , from the pit and stored In drums pending disposal.

"* The decontamination area for the sampling equipment and tools will be

f located adjacent to the large equipment decontamination area to provide

accessibility for both areas to the steam cleaner. This area will be a 20

L nil polyethylene lined area with a. liquid collection sump. The liquids

I-. collected in the sump will be bailed or pumped Into drums for storage1

pending disposal. The area will be constructed large enough to accommodate

lit racks for holding tools, tubs containing the cleaning solutions and if

necessary a work bench.

flR300239

FPRQ SAP ___ Section 6S&ME Project No. 4112-88-900 Page 2 of 2


The personnel decontamination area will also be a 20 mil polyethylene

lined area constructed adjacent to the equipment cleaning area.

6.2 DECONTAMINATION PROCEDURES

The decontamination procedures for each of the work activities and...._.__.__._._. .._ . ___. ... ! . .

equipment are shown on Table 6-1. A copy of the Table will be posted at

the decontamination area for reference.

Health and safety precautions will be folio

procedures to minimize contact with potential

equipment. Breathing protection will be utilized du

procedures to minimize exposure to contaminants

steam cleaning.

. . . . _ . _

wed during the cleaning

contaminants on the

ring the steam cleaning

volatilized during the

AR3002itO

FPRQ SAP Section 7S&ME Project No. 4112-88-900 _'~" Page 1 of 2


SECTION 7

SITE MANAGEMENT PLAN

7.1 FIELD PERSONNEL

The S&ME personnel on site during the field sampling activities will

be under the supervision of the S&ME Site Manager and the S&ME Health andi t[ ; Safety Officer or designate. The chain of command from the Site Manager

7™> to the EPA primary contact will be through the designated S&ME Project

Contact. The chain of command with the individual identified is shown In

P Figure 7-1. _la-

Mr. James Wren, Responder's Committee Chairman, Is the principalr»[__ representative for the Responders. The Responders have designated Mr.

l - Ernest Parker, Jr., P.E. of S&ME as the Site Coordinator for the. - ,

Responders pursuant to the Consent Order. Mr. Parker is S&ME's principal

j project coordinator and is responsible for day-to-day communications with

the EPA's Site Coordinator.

*- 7.2 SITS SECURITY AND ACCESSJ ' ' ~

Security on the FPRQ site will be established by constructing a fence

. around the site and posting appropriate warning signs. A separate storageto*

area will also be constructed by enclosing a designated area with fencing

K; to provide security for samples, equipment and waste materials generated.

fto

FPRQ SAP _ --Section?S&ME Project No. 4112-88-900 Page 2 of 2

Revision No. 2July 151 1988

All fence gates, store boxes and doors will be locked when not being

directly used and when no personnel are present on site.

Access to the slte _ will J?e controlled by the Site Manager (W.

Robertson) and the Respondent Coordinator (J. Wren). All personnel

entering the site wilf be approved by the Site Manager and the Site Health--._ ---— --.- - ———- . .__i——— . . I

and Safety Officer (or his designee). The Site Manager will maintain a

daily site entry log. The entry log will include the name, affiliation,!

time of entry and time of exit for all individuals on the site.

AR3Q0242

L

L

FIGURES

BR3002143

FIRST PIEDMONT ROCKQUARRY SITE

oaoCDco

SITE LOCATfON MAP

jlPROJECT11 FIRST PIEDMONT ROCKII QUARRY

DANVILLE, VA. S&ME SCALE: .N.T. s.JOB NO' 4H2-86-90rC

FIG. No:±!

HK3HBJOOFQUARRY

COMMUNrTY OF BEAVER PARK

PROJECTFIRST PIEDMONT ROCK

DANVILLE, VA.

LO_3-CNJ

SITE MAP

S&MEQUARRY T zasr »»».— FIG. N0".±i

SCALE: ^T-5-JOB NO'. 4112-88-90.10

"fSI

nLi

L

TOMETERRE

EXPLANATION:

• PROPOSED MONITOR WELL LOCATIONS *-v

j ABEM Wadi" 'Grid'JiocatloHS

Graphic Scale in FeetContour Interval is 20* ._" .

GRID LOCATION MAP

'I PROJECTi\ FIRST PIEDMONT ROCK

QUARRYDANVILLE, VA.

.SCALE: AS SHOWNJOB NO! 41 1 2 -68-901 B

FIG.A .tS00

f!fa-I

CCMMUNfTY OF BEAVER PARK

NOfTTH(NOT TO SCALE)

Reference: Fig. 4-3 in Work PlanSOURCE AREA SAMPLE LOCATIONS

SOURCE AREA SAMPLING LOCATIONScn-3-ooCDCD


, QUARRYDANVILLE, VA". S&ME SCALE: _N. T. s.

JOB NO". 4VI2-88-90IC

FIG. NO: _?if____

Overburden BedrockMonitoring Well - "". __ Monitoring Well

Lockable.•Protective1

• $f\&Q

SurficialSoils

T

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or PVC

c —— 1.0' Seal ofBentonite ^

SAPROLITE —

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CDLOCXI

SCHEMATIC DRAWING OF OVERBURDEN ANDBEDROCK MONITOR WELL CONSTRUCTION


QUARRYDANVILLE, VA. S&ME SCALE: **.T. s.

JOB NO: 4II2-883-9QI CFIG. NO". 3"4

V———J

TYPICAL SAMPLING PROCEDURES

Project Team Decides What Samples to Collect Which Analyses to Perform.and Idemifki the Low*. Medium-, end High-Concentration Samples

CLP Coordinator (or Team Leader) CompiUi Analytical Needsand Determines Bottles Required

1CLP Coordinator (or Equipment Manager) Orders Bottles from Laiboratoratory I

I______,SefiM-.es Are Collected (and Filtered if Necettaryl [

j Equipment Manager Orders Preservatives

i4TAL SAMPLES*

r

HAZARDOUS SAMPLES **

IProper Preservative* Art Adcled Tesn Placed on Bottles* • I

Tag* Placed on Bottle*t

Bottles Placed In Plastic 8*fl

Bottle t Placed In Plastic Bag I

tBottles Placed in Paint Cm

BotUes Placed In Cooler Can Fitted with Vtrmlculitt

. Separator* Ptaead In Cooler.1 IctAddrf

Can Sealed with Tape or Clips j

._• tCooler Fill*d with V«rmkutiti

I

Cert Properly Labeted

Paperwork Taped to Inside Top" "*" of Cooler

±

1Canj Pot in Cooler

Cooler Filled with Vtrmlcullt*

Cooler Staled with Tape andCustody Seals Paperwork Taped to lni.de Top

of Cooler

Cooler Properly Labeled

±Samples Shipped (Regular Akblll)

Cooler Sealed with Tape andCustody Seats

Cooler Properly Labeled

* Low concentration** Medium, high, and dloxtn concentration

SampUt Shipped (RestrictedAnkle Alrb.II)

CvJinC\JCD

DC•d

PROJEC^FIRST PIEDMONT ROCK

QUARRYDANVILLE, VA.

fw.WestinghouseSCALE: . N/AJOB NO: 4IIZ-88-900FIG. NO: 3-6___

EPA PRIMARY CONTACT

RESPONDERS COMMITTEE CHAIRMANJL 0. WREN

SSME SITE COORDINATORERNEST F. PARKER, JR., P. E.

IPROJECT MANAGER

JAN F. SASSAMAN, Ph. D.

S&ME SITE MANAGERWILLIAM B. ROBERTSON

SITE ACTIVITY MANAGERS

PROJECT CHAIN OF AUTHORITY

HEALTH S SAFETY OFFICERBARBARA FOSTER, R. N.

(OR DESIGNEE)

COLO

CDOOor


QUARRYDANVILLE, VA. S&ME SCALE: NX A.

JOB NO*. 4112-88-901'C

FIG. NO: 7-r

4---

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AR300259

TABLE 3-2Laboratory Analytical Procedures

2 - • • _ _ _ _Sample Group ;;;.; . , _ '__~ ~ '.'.=..~=: ~,.. '.~"_7 :~:.-J:-_Z.... Method of Analysis

SOURCE AREA SAMPLES . - ' - - \(ponds, drum contents, leachate, seep sediment) CLP-RAS3

BOREHOLE SAMPLES _-.....______ _ ...-.:: .....-__-- " ,- - . -CLP-RAS3

DIABASE DIKE CORE _ _ _ _ _ _ _ _ _ CLP-SAS4 SW846 #1310

j , Chromium

H TEST PIT SAMPLES " " " : ^CLP-RAS3

i

P " OTJND WATER " ™ - "~ ~" _ " . _._ : CLP-RAS3|j _. __._...__.__..__.._ . _ .. . .

H SURFACE WATER CLP-RAS3u ;

SEDIMENTS CLP-RAS3

SOIL ------ CLP-RAS3- / - ------ --- -:-- ----- - -- - ---- ---- -'-- \

1. All analyses will be performed in accordance with the motet recentCLP-SOW; Organics 10/86 with 7/87 revision and inorganics 7/87.Quantitation limits will be as specified in the CLP-SOW.i

2, See Table 3-1 for parameters to be analyzed.

3. CLP-RAS * Contract Laboratory Program - Routine Analytical Services.

4. CLP-SAS - Contract Laboratory Program - Special Analytical Services.

AR300260

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I

TABLE 3-4

List of Critical Spare Parts for Field Equipment

OVA: Cup filters #510318-1Exhaust filters | 510116-1

__ Ignitors 510451-1_ __ Diaphragms CR007KK

Calibration Gas Kit , CR009UYFuel \ Hydrogen UHP Grade

HNU: Lamp cleaner 101 500Calibration Gas Kit 101-350

pH Buffer solutions 4.01, 7.41 & 10.4' Potassium chloride \ Fisher 50-P-138

_____ ___ Batteries 9 volt/AAProbe , Fisher 13-620-97

.._=..,.. . -..-. ... _ _ , - . , _ .. .^ or equivalent

Conductivity Batteries _ ...... : . . AA/9 voltStandardization solution

D.O. Meter Spare membrane kit ;- , YSI 5776Batteries

jCamera L Film 35 mm 100-400 ASA/ Batteries Size AA

flR300262

TABLE 6-1Decontamination Procedures(Posted at Decon Area)

Work ActivitiesXIterns Level of Protection Decontamination Procedures

Drilling equipment, B, C or D 1) Steam cleanbackhoe, and large D if reading <5 ppm 2) Scrub off any clinging grime/dirtpieces of equipment C if readings <50 ppm 4) Tap water rinse

B if readings >50 ppm 5) Deionized water rinser •j Well screen and D 1) Steam clean* • casing 2) Alconox solution

3) Tap water rinsef 4) Deionized water rinseI „ _ 5) Wrap in new plastic sheeting

Field Equipment, D or C 1) Alconox solutionBailers, spoons, D if reading <5 ppm 2) Tap water rinsebuckets, pujsps, C if reading >5 ppm 3) Isopropyl alcohol rinsewater level probes, 4) Deionized water rinsepH meter, D.O. meter, 5) Wrap in aluminum foilconductivity meter (shiny side out) - if possible)and thermometers - , ___ . _

Outside of hoses D 1) Alconox solution2) Tap water rinse3) Deionized water rinse4) Place in large plastic

bags (double bag) and seal

Boots, gloves D 1) Alconox solution - usemasks, etc., and brush on bootsother personal equipment 2) Steam rain suit (if

applicable)3) Tap water rinse4) Bag up disposable gloves,

cartridges, tyveks, etc.(triple bag for disposalin sanitary landfill)

Readings are taken with an OVA or HNu, initially, to determine the level ofprotection required - readings must be above background

ccc

SR300263

APPENDIX "A

Random Soil Sampling Program

APPENDIX ARandom Soil Sampling Program

For soil sampling a total of 12-50 feet by 50 feet grid areas will be

established within the quarry. A total of nine 100 feet by 100 feet grid

areas will be established within 100 feet of the quarry. Each grid area

t will be divided Into 25 sectors (10 feet by 10 feet) for the onslte grid

areas and 20 feet by 20 feet for the off site grid areas. The sectors

• ' within each grid area wilL be numbered sequential from 1 to 25 beginning

[ with the sector in the northwest corner and proceeding to the southeast*•-

coraer. A random number generating program will be used to select twop . — .\ numbers between 1 and 25 (two sectors per grid area) for sampling. These*—• _

randon samples are In addition to the distressed vegetation/disturbed area

*•* biased sampling.

After the selection of the random samples to be submitted for analysis

based on the headspace analysis or observation of impacts the remainingr - . . . . . . . .[ random samples (up to 42 or two per grid area) will be sequentially*-• *

numbered. The random number generating program will again be used to

" select 10% of the total random sample population for analysis.

C

r

flR300265

- - -- _APPENDIX B

Head Space Analysis Procedure

^300266

HEAD SPACE ANALYSES PROCEDURE

I During drilling and sampling operations, an organic vapor analyzer

(OVA) will be used to determine levels of volatile organics. Selected

i split spoons samples, will be placed in a clean glass jar, filling the jar

f approximately to 3/4 total volume. The jar will then be covered by a

sheet of alurainum foil, and exposed to ambient conditions for

j approximately five ainutes allowing time for volatlzatlon. The remaining

sample will be placed In a clean glass jar, sealed labelled and placed in[ | . . . . . .*•* a cooler. Following the elapsed time, the sampling tube on the OVA is

P Inserted through the foil and the organic concentration measured.

cci;

I

APPENDIX C

Forms

n.

1.S

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Q

SUHO" NO

Protect Co-3*

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e

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o*

.... .

.. -

..

. _

_ __J

Preservative:Yes O No t 1

ANALYSES

800 AntonsSolids (isaoositss*COO. TOC. NutrientsPhenolicsMcrcwyMetalsCyanideOil and GreaseO.ganics GO'MSP.ionty PoHuiantsVotalilc O»panicsPcsiiddcsPCB

Rcmaiks:

>

Tag No Wb S J»nplo (Ju

11843

r

SAMPLE IDS.TIFICATION TAG

flR300269

c

k.-

CHAIN OF CUSTODY RECORD '__SR30027Q

BOREHOLE LOG

PftOJECT________________________________ Borehole ID :LOCATION.PROJECT KOT —————————————————I——————- L°"ed by:

LOCATION: DRILLER: START INODATE:

GROUND ELEV-: RIG:TIHE:

TOTAL DEPTH: BIT(S):COKPLETEO AS:

BOREHOLE DIAK.: FLUID:DEPTH

0 -

S -

10"

is -

20 -

SAKPLE

REC0VR

ft.

N

VAL

HKu

PPM

•

%

GAS

•

•

SYKS0L

C0HPL

MATERIAL DESCRIPTIONS AND COHHEKTS

•>

•

i:

c

Westinghouse

UELL/PROBEWELL/PROBE CONSTRUCTION SUMMARY

ELEVATION:PROJECT_LOCATION __________________ TOP OF RISER! ._PROJECT NO.____________________ TOP OF PROT. CASING:PERSONNEL____________________ LOCATION OR COORDS:

DRILLING SUMMARY:TOTAL DEPTH:__BOREHOLE DIAMETER:

DRILLER:

RIO: -——————————————————— CASING:BITtS): _____________________

DRILLING FLUID:

SURFACE CASING:

vat DESIGN:BASIC: GEOLOGIC LOO__GEOPHYS. LOG__.CASING STRING(S): C-CASING / S=SCREEN

CASING: ———— —— DEVELOPMENT SUMMARY:

SCREEN:

CENTRALIZERS:

FILTER MATERIAL:

AKKULAR SEAL:

CEMENT:OTHER:

CONSTRUCTION TIME LOG:

TASKDRILLING:

GEOPHYSICALLOGGING:

FILTER

DEVELOPMENT:OTHER:Filter._

Safcrelft

STARTDATE TIME

FINISHDATE TIME

COMMENTS;

W) Westinghouse

L

[

L

S&METEST PIT LOG

JOB NAME________.___________________. JOB NO.

SUBJECT____________________... SHEET NO..

RECORDED 8Y_______________________ DATE-

SAMPLING TEAM_________________________ WEATHER.

TEST PIT NO..______________________ LOCATION,

CLIENT/REGULATORY REPRESENTATIVES ON SITE

I—I-

ELEV.FT.

-

-

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-

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-

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DEPTHFT.0.0

-1.0

-2.0 -

-3.0 _

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-8.0 -

-9.0 -

10. O

DESCRIPTION OF SOILS/STRATASAMPLE

NO,

>

TYPE

-

-

-

-

REMARKS

•

»ADD.T.ONAL REMARKS ——————————————;————————~- fl H 3 0 ffZ 7 3

-. -

LI ... _____ _.__ .: APPENDIX D

[" """" ~ " Sample Bottles, Preservation[_, . . . . . . . an4- Cleaning Procedures

SR3002TV

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kav« «( *MV*na.

S&MEPROJECT ____ __ __ ________ ____________ NO". 4112-88-900

First Piedmont Rock Quarry

M

. NO: D-]

•

SOP for Cleaning Inorganic Bottfes

Title: Cleaning Inorganic Bottles

Scope: This operating procedure will cover the method of cleaning bottles for inorganicsamples. ....... — _ -

Purpose: The purpose of this procedure is to ensure that bottles are free of contamination forsampling use by IEA customers-

Procedure: _ " :I

1) Wash bottles and caps in hot water with laboratory detergent.

2) Rinse both with 10 % 12% (nitric acid).

3) Rinse three times with ddonizcd water.

4) Invert bottles and dry in contaminant free area.

5) Cap bottles. - • __ !

6) Store in contaminant free area.

7) Each month, an inorganic sample bottle is filled with DI water. The water is thentested for Total Solids. If the result is < 4 mg/L, the glassware is considered dean.The result must be recorded in the Inorganic glassware logbook. It is theresponsibility of the Inorganic Lab Supervisor to enter the result in the logbook.

SOP for Cleaning Volatiles Vials and Bottles

Title: Cleaning Volatiles Vials and Bottles

Scope: This operating procedure will cover the method of cleaning vials and bottles forvolatiles samples.

Purpose;" The purpose of this procedure is to ensure r.hat vials and bottles are free ofcontamination for sampling use by IEA customers.

Procedures:I

1) Wash vials, bottles. Teflon® liners, septa, and caps in hot tap water withlaboratory detergent

i2) Rinse all items with deionized water. ;3 ) " Ovcndryatl25°C. - - - - - - - - - - i

4) Allow all vials, bottles, liners and septa to cool in an enclosed contaminantfree environment. . . . . . . . .

5) Seal vials and bottles with liners or septa as app f a§; &<J]tKin/b5b.. . i .

6) Store vials and bottles in a contaminant free area.

7) Each month, a vial is filled with organic free water and the water issubsequently transferred to a volumetric flask. The water is then analyzdd.fororganic contaminants. The result must be recorded in the volatile organicglassware logbook by the GC7MS department supervisor.

SOP for Cleaning Organic Bottles

Title: Cleaning Organic Bottles

Scope: This operating procedure will cover the method of cleaning bottles for organicsamples,

Purpose: The purpose of this procedure is to ensure that bottles arc free of contamination forsampling use by IEA customers.

Procedures:1) Wash bottles and caps in hot water with laboratory detergent.

2) Rinse three times with tap water.

3) Rinse three times with deionized water.

[ 4) Rinse with methanoL

5) Invert bottles and dry in contaminant free area. _ _ _ . . .

i 6) Ctpbotdcs.i

7) Store in contaminant fiee area.

8} Each month, an organic sample bottle must be filled with organic free water.**• The water is then extracted and analyzed for the presence of organic

contaminants. The result must be listed in the organic glassware logbook.[ The GC/MS department supervisor is responsible for entering the result inI thelogbook. -

SOP for Cleaning Metals Bottles

i. Title: Cleaning Metals Bottles

[ S c o p e : This operating procedure will cover the method of cleaning bottles for metalssamples.

Purpose: The purpose of this procedure is to ensure that bottles are free of contamination for* sampling use by IEA. customers.L

Procedure:*^ 1} Wash bottles and caps in hot water with laboratory detergent

-.. 2) Rinse both with 10 %HN03 (nitric acid).

3) Rinse three times with deionized water.

4) Invert bottles and dry in contaminant free area.

** " 5) Cap bottles.

6) Store in contaminant free area. _

7} Each month, a sample bottle for metals analysis is filled with DI water. The water isthen transferred to a beaker and analyzed for the RCRA metajs. The result must beentered in the metals glassware logbook by the Metals S$>$vgoQ 0277