zeitschrift für naturforschung / b / 26 (1971) · 3.0 germany license. on 01.01.2015 it is planned...

BAND 26 b ZEITSCHRIFT FÜR NATURFORSCHUNG 1971

Contents

C o n t e n t s of N u m b e r 1 N o t e s

O r i g i n a l C o m m u n i c a t i o n s

Inorganic and Organic Chemistry G. HAGELE, Application of 220 MHz Protonreso-nance-Spectroscopy for Conformation-Analysis . 1 W . M Ü L L E R , H . S C H Ä F E R and A . W E I S S , Struc-ture of the Pases Ca2LiSi3 and Ca2LiGe3 . . 5 0 . A . K U N Z E , 0 . G . M A L A N , P . A . B Ü G E R a n d W. FINK, The Influence of Sulfoxylates on the Photoconductivity of Chemically Deposited Lead Sulfide Layers 8 P . P R A S H A R and J . P . T A N D O N , Studies in Nio-bium (V) - S c h i f f Base Complexes . . . . 11 H . C . H E I N R I C H , E . E . G A B B E , a n d D . H . W H A N G , Physical and Biological Half-Life of Radio-chemically Pure 59Fe 13 J . C S O N K A - H O R V A I , A . D A V I D , G . H O R V Ä T H , and G . N Ä R A Y - S Z A B Ö , Rotational Isomerism in Bis- [p- (3-Methyl-butyloxy) -phenyl] -thiourea . . 21 T H . G H E O R G H I U and K . O E T T E , The Effect of Stereoisomeric Structure on Retention Time in Gas Liquid Chromatography of Per-O-trimethyl-silyl Derivatives of Pentoses and Hexoses . . . 24 L . P O H L and R . S T E I N S T R Ä S S E R , On the Existence of Nematic secondary Structures 26 K . K . B A N E R J I , P . N A T H , a n d G . V . B A K O R E ,

Kinetics of the Oxidation of methyl n-propyl ketone by manganese (III) sulphate . . . . 30 A . M A T S U O , M . N A K A Y A M A , Y . I S H I D A , a n d S .

H A Y A S H I , Isolation of Nonacosan-10-ol and Cupa-rene from the Liverwort, Bazzania pompeana . 32

Biochemistry, Biophysics and Biology J . J A C O B and A . Z E M A N , Urapygial Gland Fat of Fulmar 33 K . P O L L O W and B . P O L L O W , Oxidative and Re-ductive Interrelations between Oestrogens and Androgens in Rats Liver Slices 40 H . - G . L Ö F F L E R , F . S C H N E I D E R , a n d H . W E N C K , Kinetics of the Reaction of Papain with Bromo-acetamide 43 D . H I E D E M A N N - V A N W Y K a n d C . G A M I N I K A N -

N A N G A R A , Localization of Ferredoxin in the Thy-lakoid Membrane with Immunological Methods . 46 H.-E. B U C H W A L D and C H . W O L F F , Further Evi-dence for Carotenoids Engaged in a Metastable State in Photosynthesis 51 F. L E I B E N G U T H , Concerning Pleiotropism of wh and el Locus in Habrobracon juglandis . . . 54

Inorganic and Organic Chemistry W . S T R O H M E I E R a n d W . R E H D E R - S T I R N W E I S S , Reaction Rate r of the Catalytic Hydrogenation of Unsaturated Compounds M with RhX (CO) L2

as a Function of the Ligands X and L . . . . 61 A. M E W I S and H.-U. S C H U S T E R , The Structure of the Phases LiCo2Ge and LiNi2Sn 62 G. H E C K M A N N and E. F L U C K , Solubility and Chemical Shift of 31P Nuclear Resonance of white Phosphorus in Certain Solvents 63 A. M U C K and F . P E T R U , Preparation and IR-Spectra of Trisphosphito-yttrium-Acid, H 3 [Y(HP0 3 ) 3 ] 64 K . S E P P E L T and W . S U N D E R M A Y E R , N-Halogen-imidosulphuroxidifluorides, X - N S O F 2 . . . . 65 E . K O E R N E R V O N G U S T O R F , Z . P F A J F E R , a n d F . - W . G R E V E L S , Photochemical Preparation of Butadiene Iron Tricarbonyl and its Transforma-tion to bis-Butadiene Iron Monocarbonyl . . 66 F . F E H E R , F . M A L C H A R E K , a n d K . G L I N K A , S y n -thesis of Bis (chlormercapto) -benzoles . . . . 67 H. A. B R U N E and H. P. W O L F F , About the De-pendence of Substituents on Carbonyl-Vibratio-nal-Frequencies in Alkyl-substituated Iron-tri-carbonyls 68

Biochemistry, Biophysics and Biology K . N . S H I V A R A M , H . S T E G E M A N N , R . S I E P M A N N , and H. BOSER, Appearance and Disappearance of Phosphorylases in Potatoes 69 R. H A L F E N B E R G and G. S T E I N , About the Red Pigment of the Cottonbug Dysdercus intermedins Dist 71

C o n t e n t s of N u m b e r 2


Inorganic and Organic Chemistry R. A P P E L and E. L A S S M A N N , On the Reaction of Iminophosphoranes with SF4 73 H. W . R O E S K Y and G. R E M M E R S , N-Tribromo-phosphaza-compounds 75 H . G . B I E D E R M A N N , G . R O S S M A N N , a n d K . E .

S C H W A R Z H A N S , IR- and NMR-Spectra of Pseudo-Octahedral Cobalt (II)- and Nickel (II)-Com-plexes 78 A. S C H M I D P E T E R and H. R O S S K N E C H T , PH-phos-phine imines and biphosphine imines . . . . 81 H . - H . P E R K A M P U S , P . M Ü L L E R , a n d J . K N O P , Dipole-Moments of Phenanthrolines . . . . 83 R . S T E I N S T R Ä S S E R and L . P O H L , L O W Melting Nematic Eutectics 87

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IV CONTENTS

G . M Ü L L E R , G . B E Z O L D , W . D I E T E R L E , a n d G . SIEBKE, Amine-Exchange and Carbon-Alkylation 92 R . F . A B D U L L A , S . K . L A H I R I , T . A . C R A B B , a n d R. CAHILL, Morpholines-(III) : Some Further Aspects of the Cyclodehydrohalogenation of (ü-[N-(aryl-A7- (halogenoacyl) ] -aminoacetophenones . 95 W. B R O S E R and H. F L E I S C H H A U E R , Investigations of Equilibria on Basic Triphenylmethane-dyes in Methanol 99

Biochemistry, Biophysics and Biology

C. W O E N C K H A U S and D. S C H E R R , Investigations on Complex Formation of Dehydrogenases with Coenzyme Analogues 106 A . Z H E L E V A , L B U B E V A - I V A N O V A , a n d L . S . S P A S S O V , On the Structure of Peuarenarine, a New Coumarin from Peucedanum Arenarium . 113 D . Z I R W E R , B . B E C K E R , E . B U D E R , W . S C H Ä L I K E , and R. WETZEL, Comparative Studies on Hydra-tion Dependent Changes of DNA Secondary Structure of isolated DNA, Isolated Nucleo-histone and DNA in Situ 115 R. E. B R O C K M A N and S. S. B R O D Y , Photoreac-tions and Complex Formation of Retinal Mono-layers at a Water-Air Interface 119 D. F. H Ü L S E R and M. F. R A J E W S K Y , Autoradio-graphy with the Electron Microscope: Differen-tial Sensitivity of Photographic Emulsions for Tri-tium 125 J. KIEFER, The Sparing Effect of UV- and X-ray-dose-fractionation in Starved Diploid Yeast . . 129 S. S. BRODY, Interactions of Chlorophyll Mono-layers with Electron Donors and Acceptors . . 134 E. C A B E L A and H. A L T M A N N , Determination of Irradiation Effects on the Thymidine Kinase Ac-tivities within a Cell-Cycle of Synchronously Growing Chlorella 141 K . D O S E and L . Z A K I , The Peroxidase and Cata-latic Activity of Hemoproteinoids 144 G. RENGER, The Acceleration of the Deactivation Reactions in the Watersplitting System by Cer-tain Chemicals 149 C H . H I N T Z E - P O D U F A L , The Juvenile Hormone-like Effect of Farnesol Derivatives on the Pupal Development of Cerura vinula L 154 U. L Ü T T G E and E. B A L L , Light-Independent Un-coupler-Sensitive Ion Uptake by Green and by Pale Cells of Variegated Leaves of Higher Plants in Relation to Protein Content and Chloroplast Integrity 158

N o t e s

Inorganic and Organic Chemistry D . K U M M E R and J . F U R R ^ R , [Si(CH3)2]2Fe2-(CO) 7 , a Stereochemical^ Nonrigid Compound with Three Bridging Groups 162 E . L I N D N E R and U. K U N Z E , The Behaviour of Tetraorganostannanes Towards Aqueous Sulfur-dioxide 164 A. S T U H R and H . J A C O B S , The Crystal Structure of Na[Yb(NH 2 ) 4 ] 165

Biochemistry, Biophysics and Biology A . W A C K E R , H . F E L L E R , P . C H A N D R A , a n d T . K . R. REDDY, Effect of Adenosine-(3',5')-monophos-phate on the Inhibition of Dark Repair by Caf-feine 166 K. K. G A U R I , W . R Ü G E R , and A. W A C K E R , Photo-chemistry and Photobiology of 5-Ethyl- and 5-Propyldeoxyuridine 167 W . K R Ü G E R and S T . S C H N I T Z L E R , Growth of Zajdela Ascites Hepatoma Cells in Vivo Fol-lowing Treatment with Trypsin and Pronase in Vitro 169 I . I S H I Y A M A , A . T A K A T S U , G . U H L E N B R U C K , U . R E I F E N B E R G , S T . S C H N I T Z L E R , a n d 0 . P R O K O P , Serological Behaviour of an "incomplete" and "superagglutinating" Anti-A from the Snail Helix pomatia 171 A . M . L E S E N E Y , J . F O N T , R . B O U R R I L O N , I . S P R E N G E R , R . V O I G T M A N N , a n d G . U H L E N B R U C K , Erythroagglutinating Properties of Some Myo-genic Lectins 172 P. L. SCHELL, Construction of a Stopped-Flow Apparatus for Short Time Pulse-Incubation of Microorganisms and Cell Suspensions . . . 174 U. H. EHLING, Reproductive Capacity of Female Mice after Inhibition of DNA-Synthesis . . . 175 T H . G Ü N T H E R and F. D O R N , The Intracellular Mg Ion Activity in Different Mammal Cells . 176 G. THROM, Electrical Conductance and Action Potential in the Relative Refractory Period . . 178



Inorganic and Organic Chemistry H.-P. STOCK, Formation of Complexes of Molyb-date IV with Periodate-Ions in Aqueous Solutions 179 S . 0 . G R I M , E . F . D A V I D O F F , a n d T . J . M A R K S , Preparation and 31P Shifts of Some Quaternary Phosphonium Salts 184 J . D E L V E N T H A L and W . K U C H E N , On the Know-ledge of Organophosphorus Compounds, XIII. Some New Derivatives of 2.2-Bis(hydroxymethyl)-I.3-propandiol (Pentaerythrit) 190 W . S T R O H M E I E R a n d W . R E H D E R - S T I R N W E I S S , Mechanism of Catalytic Hydrogenation of Dime-thyl-Maleate and 1-Heptene with RhH(CO)(P03)3

in Toluene 193 J. LILIE, Pulsradiolytic Investigations of the Oxy-dative Ring Scission of Furan, Thiophen and Pyr-rol 197 H . M A U S E R and U. H E Z E L , Kinetical Analysis by Formal Integration Theoretical Principles and their Applications to Spectrophotometric Studies of Photoisomerization of Azobenzene . . . . 203 E . G I L B E R T , G . W A G N E R , a n d D . S C H U L T E - F R O H -LINDE, Photochemistry of 5-Iodouracil in Aqueous Solution in Presence of Oxygen and Methanol . 209 W . V O E L T E R , G . J U N G , E . B R E I T M E I E R , a n d E . BAYER, 13C-NMR Chemical Shifts of Amino Acids and Peptides 213

CONTENTS IX

H. A . BRUNE, G. HORLBECK, and U.-I . ZÄHORSZKY, Bis(cyclobutadienyl-irontrioarbonyl) . . . . 222 KL. KRETZSCHMAR and W . JAENICKE, Polaro-graphic Examination of the System Folic Acid — Dihydrofolic Acid — Tetrahydrofolic Acid . 225 Biochemistry, Biophysics and Biology H. EGGE, H . OCKENFELS, H. THOMAS, and F. ZIL-LIKEN, Mass Spectra of 1-Dimethylaminonaph-thalene-5-Sulfonyl Derivatives of Some Metaboli-tes of Catecholamines 229 W . HENNIG, W . KUNZ, B. SCHNIEDERS, and K . WILLIAMS, Analysis of the RNA Fractions of Mouse Liver: Comparison of the Extraction Me-thods of K i r b y and G e o r g i e v . . . . 235 G. GABELLA, Glial Cells in the Myenteric Plexus 244 M. BOLL, Effect of Proteolytic and Lipolytic Enzymes on the Electron Transport Particle Frac-tion of Rhodospirillum rubrum. II. Phospho-lipases 246 A. HACK and W . KLINGMÜLLER, Effects of Os-motic Shock and Triton Treatment on Sorbose Transport in Neurospora 250 W. FRANK, Deficiency of C2-Fragments in the Metabolism of Embryonic Rat Cells in Culture . 255 J. STAUFF and H. FUHR, Chemiluminescence from the Action of Singlet Oxygen on Chlorophyll a and some other Luminescing Sub-stances 260 F.-C. CZYGAN and W . EICHENBERGER, Fatty Acids of Esters of Secondary Carotenoids from Ankistrodesmus braunii (Naegeli) Collins (Chlo-rophyta, Chlorococcales) 264

N o t e s Inorganic and Organic Chemistry A . MÜLLER, N . WEINSTOCK, B. KREBS, B. BUSS, and A. FERWANAH, Preparation, Properties and Crystal Structure of K3 (WOS3) Cl 268 H. DREESKAMP and K. HILDENBRAND, 'H-nmr-Investigation of the Intramolecular Ligand Ex-change in Dimethylfluorphosphorane . . . . 269 H. P. STOCK, Remarks about the Formation of Na-Isopolymolybdates in Aqueous Solutions, In-fluenced by the Presence of NaCl 271

Biochemistry, Biophysics and Biology R. L. BRAHMACHARY, P. K . TAPASWI, and D GHOSAL, Further Investigations on Transcription in Limnaea (Mollusc) H. W. TIFFE, Dependence of Fluorescent Inten sity on the Intensity of Incident Light . . H. W . TIFFE and L. ZELLES, Fluorescence Mea surement of Tradescantia Pollen after u.v. Ra diation Damage

271

273

274

C o n t e n t s of N u m b e r 4 O r i g i n a l C o m m u n i c a t i o n s Inorganic and Organic Chemistry P. DVORAK, Binding by Hexacyanoferrates (II) of Thallium (I) 277

G. HECKMANN and E. FLUCK, 3 1 P N M R Investi-gations of the Behaviour of White Phosphorus in Some Organic Solvents 282 H. J. KAISER, H. G. V. FREYBERG, and A. DOIWA, Contact Potential and Heterogenous Catalysis . 292 K. -H. LINKE, R. TAUBERT, K . BISTER, W . BOR-NATSCH, and B. J. LIEM, Contributions to the Chemistry of Hydrazine and its Derivatives XXIII. Reactions of Barium Hydrazide 296 H. HOFFMANN and U. NICKEL, Formation Mecha-nism of Ni-(II)-a- and -/Miydroxyglutarate-Com-plexes 299 E. MÜLLER, E. LANGER, H. JÄKLE, H . MUHM, W . HOPPE, R. GRAZIANI, A . GIEREN and F. BRAN-DEL, New Syntheses with Transition Metal Com-plexes, X. The Structure of a new Rhodium-complex 305 P. KOURIM, W . BORS, and D. SCHULTE-FROLINDE, y-Radiolysis of Aqueous Solutions of 5-Bromo-2'-deoxyuridine in Presence of Oxygen I Identifica-tion of Products 308 P. KOURIM, W . BORS, and D. SCHULTE-FROLINDE, y-Radiolysis of Aqueous Solutions of 5-Bromo-2'-deoxyuridine in Presence of Oxygen II G-Values of Products and Comparison with the Radiolysis of the Aglycone 312 A . FONTANA, F. M . VERONESE, and E. B o c c u ' , Covalent Binding of Polypeptides to Sulfonium Resins 314 K. K. BANERJI, P. NATH , and G. V . BAKORE, Mechanism of the Oxidation of Methyl n-Propyl Ketone by Manganese (III) Sulphate . . . . 318 A. SYAMAL, Monosodium Derivatives of Aceto-acetanilide and Benzoylacetanilide 320 Biochemistry, Biophysics and Biology U. FROMMER and V. ULLRICH, Hydroxylation of Aliphatic Compounds by Liver Microsomes. III. Model Hydroxylation Reactions 322 G. F. STÄRK and L. JAENICKE, On the Metabolic Regulation in Eucaryotes: The Ribonucleic Acid-Ribonucleases System in Saccharomyces cere-visiae 328 W . STEGLICH, F. ESSER, and I. PILS, Pigments of Fungi, VI. Helveticone, a Bovinone Type Ben-zoquinone Derivative from Chroogomphus helve-ticus and Ch. rutilus 336 J. BERÜTER and E. STÄDLER, A n Oviposition Sti-mulant for the Carrot Rust Fly from Carrot Leaves 339 H. BÖHME, S. REIMER, and A . TREBST, The Ef-fect of Dibromothymoquinone, and Antagonist of Plastoquinone, on Non Cyclic and Cyclic Elec-tron Flow Systems in Isolated Chloroplasts . . 341 H. M. EMRICH, Optical Measurements of the Rapid pH-Change in the Visual Process during the Metarhodopsin I-II Reaction 352 R. MENZEL and G. LANGE, Ultrastructural Vari-ations during Light Adaptation in the Complex Eye of Formica polyctena 357 D. M . GOLDENBERG and M . LANGNER, Direct and Abscopal Antitumor Action of Local Hyper-thermia 359

VI CONTENTS

N o t e s

Inorganic and Organic Chemistry W . STROHMEIER and R. ENDRES, Reaction Rate and Kinetic of H2 Uptake by Homogeneous Hy-drogenation Catalysts RhXL3 362 H. HARTL, W . FREIWALD, W . SCHILLER, and J. FUCHS, Crystal Data of New Polytungstates . 364 E. BIRKHOLZ, J. FUCHS, W . SCHILLER, and H. -P. STOCK, The Polytungstate Y, a Decatungstate . 365 E. NIECKE, H. THAMM, and 0 . GLEMSER, Fluoro-cyclotriphosphazenes of the Type P3N3F5X (X = C H 3 , C H C H O , S C H 3 , S C 6 H 5 , O C H 3 , O C 2 H 5 ,

OC6H5) . " 366 B. A. BILAL and C. REICHMUTH, Separation of the Actinides by Means of Countercurrent Elec-trolysis 368 A. V . PANDEY and M . L. MITTAL , Amperometric Study on the Complexes of Zn (II), Cd (II) and Hg (II) 369 P. ROTH , H. SCHÄFER, and A . WEISS, On New Thiotellurites: (NH4)2TeS3-2 H 2 0 , K3TeS4 and Rb3TeS4 371 S. L. SPASSOV, N. M. MOLLOV , and I. C. IVANOV, Rotational Barrier of the Formyl Group in Leon-tiformine 373 H. I. JOSCHEK, The Photolytic Reaction of A-Chloroisobutyraldehyde with Cyclohexene . . 374

Biochemistry, Biophysics and Biology W . STEGLICH, 1. PILZ, and A . BRESINSKY, Pig-ments of Fungi, VII. Identification and Chemo-taxonomic Evaluation of Pulvinic Acids in Rhizo-pogon (Gasteromycetes) 376 B. JOHANNES, H. BRZEZINKA, and H. BUDZIKIE-WICZ, Photosynthesis in Green Plants VI. Isola-tion of Diatoxanthin from Euglena gracilis . . 377 W . MENKE and E. SCHÖLZEL, Molecular Weight of Polypeptides of the Thylakoid Membrane . 378



Inorganic and Organic Chemistry C. GOSWAMI and K. K. BANERJI, Kinetics of the Oxidation of Aliphatic Aldehydes by Chromic Acid 383 A. ZWIERZAK and R. GRAMZE, Organophosphorus Esters If. Novel Approach to the Synthesis of S-Alkyl Phosphorothioates 386 H.-J. LA ROCHE, H. SIMON, M . KELLNER, and H. GÜNTHER, Biochemical Synthesis of Stereo-specifically Hydrogen Labelled Compounds in a Preparative Scale III. Preparation of [2,3-H] (2R,3R)-Carbonic Acids and Derivatives by Fer-mentation or Exchange with Clostridium kluyveri 389 B. G. CHATTERJEE and N. L. NYSS, Studies on Lactams 395 N. BODOR, J. SCHWARTZ, and N. TRINAJSTIC, SCFMO Study of the Tautomerism of Anilino-Thiazole and Related Compounds 400

Biochemistry, Biophysics and Biology D. WALB , M . LOOS, and U. HADDING, In Vitro Studies on the Mode of Action and Differences to Heparin Anticomplementary Effect of a Semi-synthetic Pentosan-Polysulfo-Ester 403 W. KLINGMÜLLER, Cellular Components Specifi-cally Labeled during Sorbose Stimulation of Su-gar Transport in Neurospora 409 R. AVERDUNK, The Effect of the Proliferation Inhibition Factor from the Culture of Stimulated Human Lymphocytes on a Permanent Cell Strain 414 B. VLCEK, A . REIF, and B. SEIDLOVÄ, Evidence of the Participation of Deoxycholate in Cancer Immunity 419 J. HÖLZL and H. WAGNER, A Method for Pre-paring Radioactive Labeled Phosphatides Using Soybeans in-Vivo 425 A . RADUNZ, G. H. SCHMID, and W . MENKE, Anti-bodies to Chlorophyll and their Reactions with Chloroplast Preparations 435 K. AUGSTEN and J. GÜTTNER, Influence of Benz-imidazole-mustard-derivatives on the Osmotic Haemolysis in Mice 447 M . HAVRÄNEK and K. VERES, A Simple Method of Preparation of Labelled Peptides Possessing Antibiotic Properties 451 P. SCHLECHT, Dielectric Studies of Aggregation Phenomena with Separated a and ß Chains of Human Hemoglobin 453 H. STIEVE and CHR. WIRTH , The Ion-dependence of the Receptor Potential of the Visual Cell of the Crayfish 457 H. RICHTER and U. SLEYTER, Fat Extraction at — 78 °C: Demonstration by Freeze-Etching . . 470

N o t e s

Inorganic and Organic Chemistry H. ALPER, Reaction of Group VI Metal Carbo-nyls with Diphenyliodonium Salts 474 R. STEUDEL, The Structure of the CC13 Radical . 475 H. P. FRITZ and G. HIERL, ^ - n . m . r . Spectra of 1-(2-aminoethyl) aziridine Complexes . . . . 476 G. FRITZ, P. BÖTTINGER, and N. BRAUNAGEL, Reactions of Si- and C chlorinated 1,3,5-Trisila-cyclohexanes and 1,3-Disilacyclopentenes with CH3MgCl and LiCH3 478 G. FRITZ, R . RIEKENS, T. GÜNTHER, and M . BERNDT, Reactions of (Cl3Si)oCCl2 and (F3Si)2CCl2 with CH3MgCl and CH3Li . . . 480 H. G. BIEDERMANN, G. ROSSMANN, and K. E. SCHWARZHANS, Saccharin as a Complexligand . 480 H. G. BIEDERMANN, P. K . BURKERT, and K . E. SCHWARZHANS, Anomalous Magnetic Behavior of Pyrazine-bridged Cobalt (II)-Complexes . . . 482 A . MÜLLER and I. BÖSCHEN, X -Ray Data of Some Amminemetaltetraoxometallates . . . 483

Biochemistry, Biophysics and Biology G. HORSTMANN, The Development of Pigment Granula in the Eyes of Ephestia kuehniella Z. . 484

CONTENTS VII

EL-SAYED EL-HIFNAWI , On the Ultrastructure of the Antennal Gland of Polyxenus lagurus (L.) (Diplopoda) 486 M . HAUSER and J. ROSENKRANZ, The Frog 's Rod Outer Segment Observed by the Negative Staining Technique 487 G. v . SENGBUSCH and H, STIEVE, Flash Photo-lysis of Rhodopsin. I. Measurements on Bovine Rod Outer Segments 488 J. B. HARBORNE and CH . A . WILLIAMS, A N e w Class of Flavone Pigments in the Palmae . . . 490



Inorganic and Organic Chemistry H . N Ö T H , H . SCHÄFER, and G. SCHMID, Metal Boron Compounds, XII. Diphenylboryl and Di-bromoboryl Stannanes 497 F. WEIGEL and N. TER MEER, Thermal Decompo-sition of Americium (III)-oxalate, -formiate, and -carbonate 504 N . WIBERG and WAN-CHUL JOO, Bis (trimethyl-silyl)-diazene- Reduction with Lithium . . . 512 K . MOEDRITZER , Multicomponent-Redistribution Equilibria in Mixtures of Methylsilanes and Me- * thylgermanes 517 H. BOCK and W. Fuss, Half-Wave Reduction Potentials of Boron Substituted Benzene Deriva-tives 525 E. FUNCK , A . JUNGERMANN, J. KAISER, and F. A . SCHRÖDER, IR-Spectroscopic and X-Ray Struc-tural Investigation of 2,4-Pentandionato-Lithium (Li-acac) Single Crystals 528 H . G. BIEDERMANN and K . E. SCHWARZHANS, Pseudo Octahedral Cobalt (II) and Nickel (II) Complexes with Guayacole, Vanilline and Iso-vanilline as Chelate Ligands 531 W . MÜLLER, H . SCHÄFER, and A. WEISS, On the Phases CaLiSi2 and CaLiGe2 534 J. SIEGEL, TH. PERROS, and H.-L. KRAUSS, Pre-paration and Thermal Decomposition of Tetra-ra-Propylammonium-Hexafluoroplatinate(IV) . . 537 S. KEMMLER-SACK and I. HOFELICH, O n B a P r 0 3

and BaTb03 539 L. J. ANGHILERI and E. S. MILLER, T h e Hydro-lysis of Sodium Polyphosphates 543 G. ZUNDEL and J. MUEHLINGHAUS, Proton Dis-persion Forces and Continuous Energy Level Distribution of Protons in the Hydrogen Bonds of Semiprotonated Poly-L-histidine and with Mo-del Substances 546 W . PIES and A . WEISS, Studies of the Substituent Effect in Aromatic Systems by Chlorine Nuclear Quadrupole Resonance (35C1-NQR). Chloranili-nium Salts, [Cl^C6H5 - ; cNH3®]Xe with X e = C l 0 , Br®, etc 555 F. DALL'ACQUA, S. MARCIANI , L. C IAVATTA, and G. RODIGHIERO, Formation of Inter-Strand Cross-Linkings in the Photoreactions between Furocoumarins and DNA 561

H . A . BRUNE, H . HÜTHER , and H. HANEBECK, The Proton Resonance Spectrum of 1,2-Diphenyl-cyclobutadiene-irontricarbonyl. An Investigation on Bonding Properties in Complex Stabilized Cy-clobutadiene 570 R. STEINSTRÄSSER and L. POHL, LOW Melting p-alkyl-p'-alkoxy- and p-alkyl-p'-acyloxy-azoben-zenes 577

Biochemistry, Biophysics and Biology H. FRITSCH , K . HAHLBROCK , and H. GRISEBACH, Biosynthesis of Cyanidin in Cell Suspension Cul-tures of Haplopappus gracilis 581 H. GIMMLER and M . AVRON , On the Mechanism of Bensoquinone Penetration and Photoreduction by Whole Cells 585 K. TEMPEL, On the Action of Folic Acid on De-oxyribonucleases of Mouse Kidney 589 R. AVERDUNK and E. Liss, The Significance of Glucose for the Growth of Yoshida Ascites Tu-mor Cells in Suspension Cultures 595 U. DENNHÖFER, Genetics and Chemistry of Eye Colour Mutations of the Mosquito Culex pipiens L. 599 B. HOLM and O. HEBY , Putrescine and Spermi-dine Changes in Heat-synchronized Tetrahymena Populations 604 G. FELLENBERG, Investigations Upon the Binding of Plant Growth Substances to Several Compo-nents of the Chromatin in vitro. I. Binding to DNA 607

N o t e s

Inorganic and Organic Chemistry M . SCHMIDT and E. KIEWERT , Triphenylboro-selenol — The First Representative of the "Boro-selenol"nSystem 613 F. FEHER and D. GRODAU , Synthesis of Bis (tri-phenylsilyltrisulfanyl) alkanes 614 W . STERZEL and W . - D . SCHNEE, Infrared Spec-trum and Structure of EuC03 615 H. BINDER, Concerning the Preparation of the Six Membered Ring Compound (NPC12) (NCH3) (BC12) (NCH3) (PC12) . . . 616 W . BROSER and U . BOLLERT , Substituent Effects upon the Basicity of some 1,1-disubstituated Hy-drazines 618

Biochemistry, Biophysics and Biology P. TUNMANN and H . A . KADRY , Occurrence of Bryononic Acid in the Root of Bryonia Dioica Jacq. XII 620 M . KANOE , H . BLOBEL, W . SCHAEG, and K . WENK, Partial Purification of Panton-Valentine-Leucozidin of Staphylococcus aureus . . . . 621 P. MUKHERJEE, On the Recovery of X-Irradiated Bacteria 622 F. SCHNEEWEISS and R. L'ORANGE , Continual Measurement of the Potassium Uptake of Cell-suspensions with an Ionselective Electrode . . 624 M . B. PRADAL, P. LOUISOT , and R. GOT , Effect of Triton X-100 on the Galactosyl-transferase Ac-tivity of Chide Embryo Cells 625

VIII CONTENTS

W. W. FRANKE, Cross-Bridges Between Intra-macronuclear Microtubules and Inner Nuclear Membrane 626



Inorganic and Organic Chemistry H. LACHMANN, H. MAUSER, F. SCHNEIDER, and H. WENCK, Kinetic Analysis of Model Reactions for Enzyme Catalysis using Kinetic Spectra, Ab-sorbance-difference Diagrams and Formal Inte-gration 629 J . GROBE and U. MÖLLER, N . M . R . Study of the System (CH3)3P/BF3 639 E. AMBERGER and H. SCHMIDT, The Nitrogen-Induced Lattice of Boron: I-Tetragonal Boron Nitride (B 1 2) 4B 2N 1 - 2 641 P. I. PAETZOLD, W . SCHEIBITZ, and E. SCHOLL, Preparation and Properties of 1,3,2-Dioxaboro-lanediones-(4,5) 646 J. EBELING, M. A . LEVA, H . STARY , and A . SCHMIDPETER, Phosphazene X L I I I . PH-Triaza-phosphorine 650 M . HERBERHOLD and H. BRABETZ, Transition Me-tal 7i-Complexes of Tetramethoxyethylene . . . 656 K. -H. TYTKO and 0 . GLEMSER, On the Mecha-nism for Polyanion Formation in Aqueous Solu-tion. The Condensation Mechanism for the For-mation of the Hexatungstate Ion [W6O1 0(OH)3]5 9

(Paratungstate A) 659 H. W . ROESKY and E. JANSSEN, Isocyanates and Related Compounds of Trimeric Phosphor-di-fluoronitride 679 W . BECK, K . SCHORPP, and K . H. STETTER, Reactions of Organic Radicals with Palladium and Platinum Complexes 684 J. BENSTED and S. P. VARMA, Infrared Spectro-scopic Studies of Calcium Sulphate heated to High Temperatures 690 H. BERGER, Solvolysis and Phosphorylating Acti-vity of Polyphosphate Esters 694 P. RENZ, Synthesis of 6',7'-Dimethyl-naphto-(2',3')-imidazole-4,5. A Convenient Method for the Preparation of the Intermediate 2,3-Dihy-droxy-6,7-dimethyl-naphtalene 701 F. DUTKA , A . F. MÄRTON , and P. VINKLER, Sub-stituent Effect on Reactivity of Alkyl Thiolacetates 703 F. VÖGTLE, M . ZUBER, and P. NEUMANN, Steric Interactions of Inner Atoms in Cyclic Com-pounds, 18. The Nitrile Group as an Intraanular Substituent 707

Biochemistry, Biophysics and Biology K. POLLOW and B. POLLOW, Characterization and Kinetics of the Microsomal Enzyme of Rat Placenta which Functions as a "Transhydro-genase" between Estradiol-17/? and Androstene-dione 710

K. PODUSKA, F. SORM, and K. SLÄMA, Natural and Synthetic Materials with Insect Hormone Activity. 9. Structure-Juvenile Activity Relation-ships in simple Peptides 719 P. R. LORENZ and J. W . AINSWORTH, Cell Cycle Analysis and Stimulation of Rat Kangaroo Cell (PtK2) after Pulse Labeling 722 K. LÜRSSEN, Localization of Protein Synthesis During Development of the Lamellar System of Greening Etioplasts 725

N o t e s

Inorganic and Organic Chemistry W . STROHMEIER and R. ENDRES, Reactivity of Hydrogenation Catalysts MC1(P$3)3 (M = Ir and Rh) 730 P. BUCK and R. NITSCHE, GaPS4 - A New Com-pound in the System Ga —P —S 731 R. DEMUTH, J. GROBE, and L. STEINER, A New Synthesis of Unsymmetrical Diphosphines and Arsinophosphines 731 E. LINDNER and H. -D. EBERT, Preparation and Properties of New Perfluoroacyldiarylphosphines 733 H. G. BIEDERMANN, P. K. BURKERT, K . E. SCHWARZHANS, and K . WICHMANN, Anomalous Magnetic Behaviour of (iV-Hydroxyphthalimido)-(acetato) -copper (II) 734 M . ZIEGLER and J. WEISS, The Crystal and Mole-cular Structure of [Cl2GeNCH3]3 735

Biochemistry, Biophysics and Biology K. -H. LINKE and K. SCHRÖDTER, Contributions to the Chemistry of Hydrazine and its Derivatives. XXVH. Formation of Hydrazine and Fixation of Nitrogen during Hydrolysis of Barium Nitride, Ba3N2 736 K. -H . LINKE, K . SCHRÖDTER, and M. KREBS, Con-tributions to the Chemistry of Hydrazine and its Derivatives. XXVIII. Condensation Reactions with Barium Nitride, Ba3N2 737 S. HUNECK, Constituents of Liverworts and Mos-ses, IX. Lunnularic Acid from Marchantia alpestris 738 A . HOLL , E. SCHULTE, and W . HOLL, Crossing over of Olfactory Fiber Bundles within the Ol-factory Bulb of Catfishes 739



Inorganic and Organic Chemistry 0 . E. RÖSSLER, A System Theoretic Model of Biogenesis 741 J. PEBLER and K . DEHNICKE, M ö s s b a u e r -and R a m a n - Spectra of Fe(02PF2)3 and Fe(02PCl2)3 747 R. STEUDEL Bond Properties of the Groups —SO-and - S e O - in Thionyl resp. Selenyl Compounds 750 H. BRUNNER and ST. LOSKOT, Substitution of NO-Bridges in [C5H5Co(NO)]2 by Three-Elec-tron-Ligands 757

CONTENTS IX

M . BAUDLER, P. JUNKES, and G. SADRI, The Be-haviour of P2I4 in Solution 759 I. Z. SIEMION and L. WILSCHOWITZ, The Race-mization of the Esters of N- (p-Nitrobenzylidene) -a-amino Acids 762 H. A . BRUNE, H. P. WOLFF, and H. HÜTHER, I,2 - Dimethyl-3,4-diisopropyl-cyclobutadiene-iron-tricarbonyl and Trimethyl-isopropyl-cyclobuta-diene-irontricarbonyl 765 B. G. CHATTERJEE, R. F. ABDULLA, and N. L. NYSS, Cyclodehydrohalogenation with Potassium Tertiary Butoxide in Dimethyl Sulfoxide . . . 771

Biochemistry, Biophysics and Biology R. TRESSL and F. DRAWERT, About the Biogenesis of Aroma-Substances in Plants and Fruits, XIIIth

Communication: Incorporation of 8-14C-Octanoic-acid in Banana and Strawberry Aroma-Substances 774 H. P. KRAUSE, H. PROBST, and FR. SCHNEIDER, Cell Division and Energy Dependent Metabolic Power of Ehrlich-Ascites-Tumor Cell Under Aero-bic and Anaerobic Conditions 780 E. SCHAUENSTEIN, R. RINDLER, R. SCHINDLER, M . TAUFER, and G. RUHENSTROTH-BAUER, In-fluence of 4-Hydroxypental on Oxygen Uptake and the SH Content of the Normal Rat Liver and the Hepatoma Induced by Diäthylnitrosamine . 788 P. MEINDL, G. BODO, J. LINDNER, and P. PALESE, Influence of 2-deoxy-2,3-dehydro-Ar-acetylneurami-nic Acid on Mycovirus-neuraminidases and the Replication of Influenca- and Newcastle-Disease Virus 792 KL. KOSCHEL, H. TÄUBER, and E. WECKER, The Inhibition of Cellular Protein Synthesis in HeLa Cells after Infection with Active and Inactivated Poliovirus 798 R. C. SRIVASTAVA and P. K. AVASTHI, A New Equation for Microbial Growth 804 P. BÖGER, Relationship of Transhydrogenase and Diaphorase Activity of Ferredoxin-NADP Re-ductase with Photosynthetic NADP Reduction . 807 L. E. BOCKSTAHLER, Incorporation of Uridine in Cleavage Stage Eggs of the Sea Urchin Para-centrotus Lividus 816 R. L. BRAHMACHARY, D. GHOSAL, and P. K . TAPASWI, Rhythmic Incorporation of P32 and C14-uracil in Early Mitotic Cycles of Limnaea (Mol-lusc) Eggs 822 W . MENKE and H.-G. RUPPEL, Molecular Weight, Size and Shape of Thylakoidmembrane Proteins 825 H. K. LICHTENTHALER, The Unequal Synthesis of the Lipophilic Plastidquinones in Sun- and Shade Leaves of Fagus silvatica L 832 H. HAGEDORN and H. WEINERT, Ultrastructural Studies of Saprolegnia monoica 843

N o t e s

Inorganic and Organic Chemistry H. MAUSER and H.-J. NIEMANN, Further Remarks on the Kinetic Analysis of Photoreactions Using Formal Integration 850

E. SCHWARZMANN, K . -H. OGNIBENI, and J. HAASE, Preparation and Properties of Tribasic Lead Sulfate 851 B. KREBS and S. POHL , Thiogermanates with Adamantane-Like Ge4S104 9 Ions 853 E. LINDNER and K . - M . MATEJCEK, Preparation and Properties of yr-Cyclopentadienyldicarbonyl-(diethyldithiophosphinato) molybdenum ( + 11) . 854 W . STEC, A . OKRUSZEK, and M . MIKOLAJCZYK, Stereochemistry of Oxidation of Thiophosphoryl Group in 1,3,2-Dioxaphosphorinans . . . . 855

Biochemistry, Biophysics and Biology F. KÖHLER and W . MEISE, Embryotoxicity of JV-Phthaloyl-DL-glutamine 857 R. HARDELAND, Differences in Regulation be-tween Rat Liver and Kidney Tyrosine Amino-transferases 858 N. RIEDER, Structure of M ü 11 e r's Vesicles of Loxodes magnus Stokes (Ciliata, olotricha) . . 859 A. SIPPEL, A Simple Law of Mortality Using but One Unknown Constant 859 G. v. SENGBUSCH and H. STIEVE, Flash Photo-lysis of Rhodopsin, II. Measurements on Rhodop-sin Digitonin Solutions and Fragments of Rod Outer Segments 861 H. G. HARDEBECK, Light Enhanced Decarboxy-lation of Indol-3-acetic Acid by Thermal Pro-teinoids 862



Inorganic and Organic Chemistry M . K . BACHLAUS, K . L. MENARIA, and P. NATH, Chelating Tendencies of some N- (2-Acyl-l, 3-Indandione) Tri Alkyl Ammonium Iodides . . 865 R. K . MEHTA, V . C. SINGHI, and R. K . GUPTA, Formation Constants of some Bivalent Metal Ion Chelates of iV-(2-hydroxy-l-naphthalidene) Anthra-nilic Acid ( S c h i f f Base) 867 M . P. BHUTRA and S. P. TANDON , Light Ab-sorption in Ar-Acetonyl Quinolinium Iodide . . 870 F. VÖGTLE and R. LICHTENTHALER, Steric Inter-actions of Inner Atoms in Cyclic Compounds, 19 New Heterocyclic [3,3] Metacyclophanes . . 872 F. SEELA, Actinomine and 4,6-Dimethyl-di-tert-butyl-actinomine-Model Compounds for Studies of the Actinomycin-DNA Interaction . . . . 875

Biochemistry, Biophysics and Biology W . FRIEDRICH and M . MOSKOPHIDIS, Further Ex-periments about the Reaction of Some Corrinoids with Carbon Monoxide and with Esters of Chloro-formic Acid 879 U. ZIMMERMANN and G. PILWAT, Influence of Ammonium Chloride and the Essential Amino Acids Histidine and Leucine upon the Stationary Distribution of Potassium in E. coli B 525 . . 887

VI CONTENTS

H. EGGE, U . MURAWSKI, W . CHATRANON , and F. ZILLIKEN, The Branched Chain Fatty Acids of Staphylococcus aureus, a Gas Chromatographic-Mass Spectrometric Analysis H. SCHÜSSLER, A Study of the Dry Thermal De-naturation of Ribonuclease H. A . W . SCHNEIDER, Porphyrinsynthesis in Iso-lated Particles from Tissue Cultures of Tobacco A. THANBICHLER, H. GILCK, and E. BECK, On the Catabolism of Hamamelose [2-C- (hydroxy-methyl) -D-ribose] I. The Oxidation of Hama-melose by Pseudomonas A. RADUNZ, Phosphatidyl Glycerol Antiserum and its Reactions with Chloroplasts I. RAU and L. H. GRIMME, The Influence of Dif-ferent s-Triazines on the Green Alga Ankistro-desmus braunii S. S. BRODY, Interactions Between Ferredoxin and Chlorophyll in a Monolayer System . K. KOSCHEL, Release of 51Chromium from La-beled HeLa-Cells after Infection by Poliovirus . K. BORGERT, E. WECKER, and K . KOSCHEL, Early Functions of Poliovirus. II. The RNA Re-plication of Hydroxylamine-inactivated Polio-viruses K. KOSCHEL and E. WECKER, Early Functions of Poliovirus. III. The Effect of Guanidine on Early Functions C. MIETENS and K. KOSCHEL, R N A Content and Antigenicity of Polioviruses before and after In-activation by Heating G. F. KOLAR and R. PREUSSMANN, Validity of a Linear Hammett Plot for the Stability of Some Carcinogenic l-Aryl-3,3-dimethyltriazenes in an Aqueous System K.-D. SPINDLER, The Influence of Light on the Egg-laying of the Copepod Cyclops ricinus . . G. HANSER, Explorations on Quantity of Vitamine B6 in the three Castes of Honey-Bee Apis melli-fera H. M . ROUSHDY and A . E. IMAM, Growth Rate Measurements in Gamma Irridiated Catfish . .

N o t e s

Inorganic and Organic Chemistry H. G. BIEDERMANN, P. K . BURKERT, and K . E. SCHWARZHANS, XH-Wide Line NMR Investigation of Bis (salicylaldehydato) - (pyridazine) -Cobalt (II) L. HOLLECK and G. KAZEMIFARD, The Influence of Tetraalkylammonium Ions on the Polarogra-phie Reduction of Diazoaminobenzenes (Tria-zenes) R. B. HÖRHAMMER, A . E. SCHWARTING, and J. M. EDWARDS, The Structure of Dehydrodecodine G. HALBACH and W . WINKLER, Flaconoids in the Fruits of the Genus Silybum eburneum

Biochemistry, Biophysics and Biology G. SCHULTZ, Flavonol Glycosides in Flowers of Trifolium pannonicum L

B. JANISTYN, W . BARZ , and R. POHL, Degradation of 2',4,4',6'-Tetrahydroxychalcone-2'-/?-D-gluco-side by Callus Suspension Cultures of Pisum sad-

893 vum L 973

901 C o n t e n t s of N u m b e r 10

903 O r i g i n a l C o m m u n i c a t i o n s

Inorganic and Organic Chemistry H. W . ROESKY and M . DIETL, The Preparation of S4N3CI Derivatives 977 W . WOLFSBERGER, H. H. PICKEL, and H. SCHMID-

G^G BAUR, Phosphinimino-phosphines by Desilylation of iV-silyl-phosphinimines 979 G. HECKMANN and E. FLUCK, Chemical Shifts of

9 1 9 the 31P-NMR-Multiples of Tetraphosphorus Tri-sulfide in Some Solvents 982 K. WIEGHARDT, The Crystal Structure of Di-/z-hydroxy-bis [aquotriamminecobalt (III) ] -nitrates-hydrate 987

9 2 9 h . BEHRENS, H. -D. FEILNER, E. LINDNER, and D. UHLIG, About the Insertion of Group II Metals into the Metal Metal Bond of Binuclear Carbo-nylmetalates 990

9 3 4 G. SCHMID and L. WEBER, Reactions on Diboryl-amine Palladium Complexes 994 H. L. NIGAM and U. C. SRIVASTAVA, K-Absorp-

940 tion Spectral Investigations on Some Cobalt Complexes Involving Sulphur-Ligands . . . 997 KL. KRETZSCHMAR and W . JAENICKE, The Redox

945 Mechanism of the System Folic Acid-Dehydro-folic Acid-Tetrahydrofolic Acid, II . . . . 999 E. MÜLLER, A . SEGLITZ, and KL.-P. ZELLER, Mass Spectrometric Investigations with a,a'-Bis-acety-

950 lenic ketones 1003 N. ZAMBELLI and N. TRINAJSTIC, Theoretical

953 Study of Furotropones ' 1007

Biochemistry, Biophysics and Biology 9 5 6 R. VOIGT, H . WENCK, and F. SCHNEIDER, Kine-

tics of the Reaction of 2,4-dinitro-l-fluorobenzene 962 with Imidazole-, SH- and Imidazole-SH-com-

pounds 1010 H. F. KÜHNLE and P. RENZ, Biosynthesis of 5,6-Dimethylbenzimidazole Precursors-Function of 6,7-Dimethyl-8-ribityllumazine 1017 G. FISCHER and W . ALBERT, A Biological Active Peptide in the Skin of Lampreys (Eudontomyzon

968 danfordi vladykovi) 1021 A. MATSUO, M . NAKAYAMA , and SH. HAYASHI, Aromatic Esters from the Liverwort, Isotachis japonica 1023

9 6 9 G. ARCAYA , M . E. PANTOJA, M . PIEBER, C. ROMERO, and J. C. TOHÄ , Molecular Interaction

970 of L-Tryptophan with Bases, Ribonucleosides and DNA 1026

971 W . W . FRANKE, D. J. MORRE, B. DEUMLING, R. D. CHEETHAM, J. KARTENBECK, E.-D. JARASCH, and H.-W. ZENTGRAF, Synthesis and Turnover of Membrane Proteins in Rat Liver: An Examina-

972 tion of the Membrane Flow Hypothesis . . . 1 0 3 1

CONTENTS IX

W. GERLICH, Determination of Particle Size by Gel Chromatography with Sepharose 6B . . 1040 D . F. HÜLSER and W . FRANK , Stimulation of Embryonic Rat Cells in Culture by a Protein Fraction Isolated from Fetal Calf Serum. I: Elec-trophysiological Measurements at the Cell Sur-face Membranes 1045 H . VON NICOLAI , R. DRZENIEK, and F. ZILLIKEN, Kinetic and Chemical Experiments about the De-cay of Di-7V-acetylneuraminosyl-lacto-iV-tetraose by Neuraminidases of Myxoviruses and Vibrio cholerae 1049 D. HIEDEMANN-VAN WYK , On a Glycolipopeptide from Chloroplasts and its Serological Properties 1052 E. WEBER and H. SCHNEIDER, Species Specific Mating Calls in Discoglossus pictus Otth, 1837 and Discoglossus sardus Tschudi, 1837 (Disco-glossidae, Anura) 1055 G. KAHL, Synthesis of rRNA, tRNA and Other RNA-species Concomitant with Polyribosome Formation in Aging Potato Tuber Slices . . . 1058 G. KAHL, Activation of Protein Synthesis in Aging Potato Tuber Slices 1064

N o t e s

Inorganic and Organic Chemistry H . BÜRGER and J. CICHON , R a m a n and Infra-red Spectra of H3SiBr and D3SiBr 1068 E. SCHWARZHANS and R. BIRKENBERG, Concer-ning the Structure of Hydrogen Analogues of Tungsten Bronces 1069 D. SELLMAN, Reactions in Complex-bounded Li-gands. III. Hydrazine and Bridging Ligand in Neural Complexes of Chromium and Tungsten . 1070 F. FEHER and H. KULUS, On a Direct Preparation of ^-substituted Cyclic Sulfur-nitrogen-com-pounds from Sulfur and Azido Formates . . . 1071 N . SINGH and H . P. LATSCHA, Glyoxychloroiso-cyanate 1072 R. BLACHNIK and B. GATHER , The System CuoTe — AsoTea 1073 V . KRÄMER and R. NITSCHE, I n 4 B i 2 S 9 , a N e w Compound in the System In2S3 —Bi2S3 . . . 1074

Biochemistry, Biophysics and Biology P. L. SCHELL, Uptake of Polynucleotides by Mouse Ascites Tumor Cells i(X) pH-Dependent Uptake of Synthetic Homoribopolymers . . . 1074 R. G O T H and M . F. RAJEWSKY, Ethylation of Guanine-./V-7 in the Nucleic Acids of Rat Embryos and Liver by Ethylnitrosourea 1076 W. KRÜGER, Relationship Between Content of iV-acetylneuraminic Acid and Tumor Age in the Zajdela Ascites Hepatoma 1078 R. BINGÖL, W . SCHAEG, and H. BLOBEL, N o PenicilloyLsubstitution during Reaction of Peni-cillinase from Staphylococcus aureus with Peni-cillin G 1080 W . MEISE and F. KÖHLER, Embryotoxic Activity of TV-Phthaloyl-DL-isoglutamine 1081

H. KOTHBAUER and H. SCHENKEL-BRUNNER, Haemagglutinins in Snails. A Discussion of their Biological Function 1082 N. KLEMM, Monoamine-containing Cell Elements in the Stomatogastric Nervous System and in the Corpora cardiaca of Schistocerca gregaria Forsk. (Insecta, Orthoptera) 1085 A . BRESINSKY and R . BACHMANN , Formation of Pulvinic Acids by Hygrophoropsis aurantiaca (Paxillaceae-Boletales) in Vitro 1086



Inorganic and Organic Chemistry S. KEMMLER-SACK and I. WALL , On B a 3 C a U 2 0 9

and Ba3SrU209 1089 J. R. BARD and J. O. WEAR , A n E S R Study of Mn(II) Complexes in Water-Methanol Mixed Solvents 1091 H. D. LUTZ and H. HAEUSELER, Preparation of Metal Sulphites from Organic Solvents. IR-Spec-tra of Metal Salts of Naphthenic Acid . . . . 1096 W. LOHMANN, Charge-Transfer Interactions of Aliphatic .Amino Acids with Metal Ions . . . 1098 K. DEHNICKE and H . LEIMEISTER, The Vibra-tional Spectrum of Trichloroisocyanuric Acid, (CINCO) 3 1101 R. KÖSTER and K . - D . ASMUS, The Reduction of Carbon Tetrachloride by Hydrated Electrons, H-Atoms, and Reducing Radicals 1104 R. KÖSTER and K . - D . ASMUS, The Reaction of Chlorinated Ethylenes with Hydrated Electrons and OH-Radicals in Aqueous Solution . . . . 1108 H. STERK and G. KOLLENZ , EHT-model l Calcula-tions at Pyrrole- and Furane-diones . . . . 1 1 1 6 M. SCHÖNESHÖFER, Pulse Radiolysis of the Tro-pylium-ion, Tropylcarbinol and Tropilidene in Aqueous Solution 1120 H. JUNEK and F. FROSCH, Rearrangements of Coumarins, Caused by an Intermediate Cleavage of the Lactone 1124 S. MARCIANI , F. DALL'ACQUA , L. GUELFI, and D. VEDALDI, Photoreactivity (365 nm) of Some Coumarins and 4',5'-dihydro-furocoumarins with Nucleic Acids 1129 S. A. I. Rizvi and T. SULTANA, Microdetermina-tion of Nodososide and Related Compounds Using Ceric Sulphate as Oxidizing Agent 1137 RIAZ F. ABDULLA and A . N. BANNERJI, Morpho-lines- (IV) 1140

Biochemistry, Biophysics and Biology V . ROSSBACH, FR. SCHNEIDER, and H. WENCK, Synthesis and Properties of Unsymmetrical Di-ketopiperazines of Cysteine 1144 J. HÖLZL and H. WAGNER , Studies of the In-corporation of an Intraduodenal Applied 14C/ 32P-Polyen-Phosphatidylcholine into the Liver Rats and its Excretion in the Bile 1151

XII CONTENTS

E. RIEDEL and E. WAMSIEDLER, Biochemical In-vestigations of Experimental Chronic Epileptic Animals 1158 R. KIMMICH, Nuclear Magnetic Relaxation Spec-troscopy in Solutions of Bovine Hemoglobin . 1168 W . HAEHNEL, G. DÖRING, and H. T. W ITT , On the Reaction between Chlorophyll-ai and its Pri-mary Electron Donors in Photosynthesis . . . 1 1 7 1 L. DITTES, I. RISSLAND, and H. MÖHR , On the Regulation of Enzyme Levels (phenylalanine am-monia-Lyase) in Different Organs of a Plant (Sinapis alba L.) 1175 F. KOENIG, Concentration of Some Lipids in the Chloroplasts of Zea mays and Anthirrhinum majus 1180 E. WOLLENWEBER, M.-L. BOUILLANT, PH. LEBRE-TON, and K. EGGER, Rare Flavonoid-aglycones in the Lipophil Excretion of Alnus glutinosa . . 1188

N o t e s

Inorganic and Organic Chemistry F. FEHER and R. LÜPSCHEN, Contributions to the Chemistry of Sulfur, 111. New Synthesis of Phe-nyl-substituted Cyclic Silicon-sulfur Compounds . 1191 H. SEIDEL and R. MEYN, The Synthesis of Li 2 CS 3 . 1192 H. SEIDEL and R. LEMOR, The Compound Tl2Cu(C03)2 1193 K. GORZNY, Synthesis of Pentachlorobutadien-phosphonates 1193

Biochemistry, Biophysics and Biology U. SCHREIBER, R. BAUER, and U. F. FRANCK, Chlorophyll Fluorescence Induction in Scene-desmus at Oxygen Deficiency 1195 J. A. SCHMIDT, Results of Microbiological and Biochemical Researches Concerning the Resis-tance of Peronospora in Tobacco. III. . . . 1197 I. ISHIYAMA and G. UHLENBRUCK, On the Nature of the Anti-Dextran Activity of the Helix pomatia „Anti-A" Agglutinin 1198 M . VOLM and K . WAYSS, No Influence of Partial Hepatectomy on the Survival Rate of Rats Bearing W a 1 k e r - Carcinosarcoma . . . . 1199 H. DIRINGER, Lipoamidase Activity in Virus In-duced Tumours and in the Corresponding Nor-mal Tissue 1201 A. SIPPEL, Relationship between Dose and Effect . 1202



Inorganic and Organic Chemistry H. LINGMANN and K. -H. LINKE, The Reaction of Hydrazine and 1,2-Dimethylhydrazine with Di-chlorodisulfane 1207 D. JAHR, K . L. SCHWARZHANS, D. NÖTHE , and P. K. BURKERT, Metal Complexes of Paramagne-tic Salicylaldimine and Thiosemicarbazone Li-gands 1210

W . MASSA and W . RÜDORFF, On a- and /?-Li3MeF6

Compounds 1216 G. PAUSEWANG, Preparation and Crystallogra-phic Data of the Compounds A2NbOF5 and A2Mo02F4 (A = Rb, Cs, NH4) 1218 H. BRUNNER and H.-D. SCHINDLER, Mechanism of Triphenylphosphine Exchange and Racemisa-tion in Optically Active Mn-Complexes . . . 1220 J. BESENHARD and H. P. FRITZ, Investigation of the Behaviour of Graphite Electrodes in Non-aqueous Electrolytes 1225 S. KEMMLER-SACK and I. WALL , On Perowskite Phases in the Systems BaO —SE203 —U02,a: III The Solid Solutions Ba2La0i67UO5i5 — Ba2La0,67U1>33O6 1229 H. W . ROESKY aijd 0 . PETERSEN, Phosphorus-and Sulfurhydrazine-Compounds 1232 L. KLASINC and J. V. KNOP , Furan and Thio-phene Analogs of Phenanthrene. A Theoretical Study of the Absorption Spectra of Benzodifurans, benzodithiophenes and Thienobenzofurans . . . 1235 U. MURAWSKI, H. EGGE, and F. ZILLIKEN, Mass Spectra of Synthetic Methylene- and Non-Methy-lene-Interrupted cis-ds-Methyl-Octadecadienoates as Their Tetra-O-Trimethylsilylether . . . . 1 2 4 1 W . v. BROCKE, E. REINHARD, G. NICHOLSON, and W. A. KÖNIG, The Occurence of 3-(l ' , l ' -di-methylallyl) -scopoletin in Tissue Cultures of Ruta graveolens 1252 Biochemistry, Biophysics and Biology G. CAPORALE, F. DALL'ACQUA, A . CAPOZZI, S. MARCIANI, and R. CROCCO, Studies on the Bio-synthesis of Some Furocoumarins Present in Ruta graveolens 1256 I. SCHLIE and L. JAENICKE, Tetrazolium-Bioauto-graphy of Pteroylglutamic Acid Conjugates . . 1260 H. ECKSTEIN, Acid-Soluble Deoxynucleotides and DNA Synthesis in Growing Yeast After X-Irra-diation, I. Diphenylamine Positive Material in Synchronized and Asynchronously Growing Cells 1266 M . METZLER, K . H. DAHM, D. MEYER, and H. ROLLER, On the Biosynthesis of Juvenile Hor-mone in the Adult Cecropia Moth 1270 E. STEUDLE and U. ZIMMERMANN, Cell Turgor Pressure and Selective Ion Transport of Chaeto-morpha linum 1276 P. G. POPOV , L. I. VALEVA-DIMITROVA, and A . A. HADJIOLOV, Effect of Irradiation on the Bio-synthesis of Liver Ribonucleic acids in Intact and Adrenalectomized Rats 1282 R. K. SINHA and D. N. MISRA, Studies on the Secondary Structure of Intraphage T-7 DNA . 1288 F. W. TISCHENDORF, Paraproteins and Normal Immunoglobulins of the Lambda Type: Immuno-chemical Differentiation and Classification . . 1292 E. STEUDLE and U. ZIMMERMANN, Hydraulic Conductivity of Valonia utricularis 1302 H. STIEVE, H. BOLLMANN-FISCHER, and B. BRAUN, The Significance of Metabolic Energy and the Ion Pump for the Receptor Potential of the Cray-fish Photoreceptor Cell 1311

CONTENTS/BOOK REVIEWS XIII

CHR. C. KRISCHER, Derivation of the Photo-electric Efficiency of Photoreceptors and a Me-thod of Extracellular Measurement of Nerve Cur-rent 1322 CHR. C. KRISCHER, The Photo-electric Efficiency of the Median and the Lateral Photoreceptor of the Barnacle Balanus eburneus 1326 F. J. FEHRENBACH, Identity of Streptolysin-0 and NAD-Glycohydrolase (EC 3.2.2.5) . . . 1336 V. H. MORALES and E. GARCIA-GIRALT, Immuno-suppressive Action in Vitro by a Bovine Spleen Extract 1339 D. SCHWAB, Electron Microscopic Study on Intracellular Microorganisms in Foraminifera . 1341 J. JACOB and A . ZEMAN, The Uropygial Gland Fat of the Coot (Fulica atra) 1344 J. JACOB and A . ZEMAN, The Uropygial Gland Fats of the Greenfinch, Bullfinch and the Linnet . 1352 S. HUNECK, KL. SCHREIBER, G. SNATZKE, and H.-W. FEHLHABER, Miriquidic Acid, a New Depside from Lecidea lilienstroemii and Lecidea leucophaea 1357

N o t e s

Inorganic and Organic Chemistry J. KRÄTSMÄR-SMOGROVIÖ, J. SOKOLIK, N . ZRU-BÄKOVÄ, and SURKA, The Structure and Pro-perties of Cupric 2-Furancarboxylate Trihydrate 1365 JIRI KOHOUT , M . QUASTLEROVÄ-HVASTIJOVÄ, and M . KOHÜTOVÄ , Cyanato-Copper (II) Com-plex with Organic Ligands V, The Magnetic Mo-ments and the Structure of Some Cyanato-Cop-per (II) Complexes with Ligands from the Aniline Group 1366 J. FLECKENSTEIN, S. KEMMLER-SACK, and W . RÜDORFF, On Two New Alkali-uranium-oxidfluo-rides with Uranium in Two Oxidation States . 1367 E. SCHWARZMANN and E. FELLWOCK, Characte-rization of Goldaquoxide and Goldoxide . . . 1369 K. -H. LINKE and D. SKUPIN, Synthesis of Diethyl 1,1- (cycloheptasulf anyl) hydrazine -2,2-dicarboxy-late 1371 W . RÖMERMANN, A . RÖMER, and H. BUDZIKIE-WICZ, Colouring of N-free Esters by D r a g e n -d o r f f s Reagent 1372 M . MIKOLAJCZYK and J. DRABOWICZ, Magnetic Nonequivalence in Chlorosulphinyl Compounds . 1372

Biochemistry, Biophysics and Biology R. VOIGTMANN and G. UHLENBRUCK, Purification of a Pseudo-Cholinesterase from the Haemo-lymph of Helix pomatia 1374 S. P. BILLA and K . BAHADUR, Isolation and Iden-tification of a Phospholipid 1376 D. MISHRA and B. SAMAL, Interaction of Benz-imidazole and Nickel in Delaying the Senescence of Detached Rice Leaves 1377 J. HAHN and 0 . MARTINI, Insulin of Turkey (Meleagris gallopavo) — Evidence for High Bio-logical Activity Compared to Beef Insulin . . 1378

H. KINDL and H. RUIS, Subcellular Distribution of p-Hydroxybenzoic Acid Formation in Castor Bean Endosperm 1379 W . VOELTER, G. JUNG, E. BREITMAIER, W . KÖ-NIG, D. GUPTA, and G. BREITMAIER, Isolation of Oxindole from Children's Urine 1380 M . R. HEBLE, S. NARAYANASWAMI, and M . S. CHADHA, 24-Methylenecholesterol in Tissue Cul-tures of Holarrhena antidysenterica 1382 P. MUKHERJEE, Studies on the Recovery of X-Ir-radiated Bacteria 1383 W . SCHEID and H. TRAUT , On the Nature of Achromatic Lesions ("Gaps") Induced by X-Rays in Chromosomes of Vicia faba 1384 F. ROMER, Changes in the Integument During the First Larval Instar of Gryllus bimaculatus (Saltatoria) 1386 N. WILBERT and G. HELLER, The Microscopical Structure of Tachysoma pellionella (Müller-Stein,, 1859) (Ciliate, Hypotricha)) . . . . 1389 W. NAGL, Partial Change by Phytohormones of Root Tip Mitoses to Endomitoses 1390

B o o k Reviews

G. N. AGRIOS, Plant Pathology (J. E. Wheeler) . 1206 I. ASIMOV, Grünes Licht für das Leben (A. Trebst) 976 A. M . BARRET and J. T. DINGLE, Tissue Pro-teinase (R. Zwilling) 1395 R. B. CLAYTON, Methods in Enzymology, Vol. 15 (H. Grisebach) 380 E. T. DEGENS and D. A. Ross, Hot Brines and Recent Heavy Metal Deposits in the Red Sea (R. German) 740 G. DOEBEL, Das Weltall und seine Entdeckung (H. Haffner) 864 G. DOEBEL, Dem roten Planeten auf der Spur (K. Walter) 1087 W. EBING, Gaschromatographie der Pflanzen-schutzmittel (R. Franck) 493 0 . EICHLER, A . FARA, H. HERKEN U. A . D. WELCH, Handbuch der experimentellen Pharma-kologie, Band X X V I (H. Uehleke) 975 W. ERNST, Erdbebenvorhersage (R. German) . 1392 G. FELS, Der Organismus (H. Bothe) . . . . 382 H. P. FIEDLER, Lexikon der Hilfsstoffe für Phar-mazie, Kosmetik und angrenzende Gebiete (E. Graf) 1088 H. FRIESER, G. HAASE U. E. KLEIN, Grundlagen der photographischen Prozesse mit Silberhalo-geniden, Band 1, 2 und 3 (W. Bahnmüller) . . 1204 D. GERLACH, Botanische Mikrotechneik (P. Bö-ger) 276 W . GERLACH und M . LIST, Gib Schiff und Segel für Himmel und Luft (E. Mundinger) . . . . 1395 R. M . GILBERT and N. S. SHUTERLAND, Ani-mal Discrimination Learning (E. Curio) . . . 1393 W. B. GRATZER, Readings in Molecular Biology (R. Knippers) 493

X I V BOOK REVIEWS

U . HAMANN und G. WAGENITZ , Bibliographie zur Flora von Mitteleuropa (K. Mägdefrau) . . . 494 H. E. HESS, E. LANDOLT und R. HIRZEL, Flora der Schweiz und angrenzender Gebiete, Band 1 und 2 (K. Mägdefrau) 1394 F. R. JEVONS, Biochemie des Lebens (J. Schwenn) 1395 P. JORDAN, A . LOMBARD und J. BUDELT, Bild der Wissenschaft. Die Architektur der Erde (K. Daubert) 495 B. KATZ, „Nerv, Muskel und Synapse" (D. Heuser) 627 W. R. KLEMM, Animal Electroencephalography (Kl. Vetter) 627 W . LAUX, W . SICKER und D. BLUMENBACH, Bi-bliographie der Pflanzenschutz-Literatur, Band 4 (W. Bartels) 976 W. LEITHE, The Analysis of Air Pollutants (J. Sander) 381 V. G. MÖLLENSTEDT and K. H. GAUKLER, V T H International Congress on X-Ray Optics and Mi-croanalysis (D. Stöffler) 627 E. MÜLLER, Methoden der organischen Chemie (Houben-Weyl), Band V / l a Kohlenwasserstoffe Teil 1, Alkane, Cycloalkane (V. Schumacher) . 72 E. MÜLLER, Methoden der organischen Chemie (Houben-Weyl), Band XIII/4: Metallorganische Verbindungen von AI, Ga, In, Ti (R. Schmutz-ler) 380 E. MÜLLER, Methoden der organischen Chemie (Houben-Weyl), Band V / l c Kohlenwasserstoffe Teil 3 (V. Schumacher) 491 E. MÜLLER, H. MEERWEIN und K . ZIEGLER, Me-thoden der organischen Chemie, Band XIII/1, Metallorganische Verbindungen Li, Na, K, Rb, Cs, Ag, Au (H. Schmidbaur) 863 A . NIEDERWIESER u. G. PATAKI, Progress in Thin-Layer Chromatography and Related Me-thods, Vol. I (H. Tschesche) 1205 A. NOWOTNY, Basic Exercises in Immunochemi-stry (Kl.-U. Hartmann) 493 G. PATAKI, Techniques of Thin-Layer Chromato-graphy in Amino Acid and Peptide Chemistry (H. Tschesche) 1204 G. N. RAMACHANDRAN and R. SRINIVASAN, Fou-rier methods in crystallography (E. Mandelkow) 740

H.-J. REHM, Industrielle Mikrobiologie (E. Mun-dinger) D. W . RIBBONS, J. F. WIESSNER, and J. SCHULTZ, Nucleic Acid-protein Interactions and Nucleic Acid Synthesis in Viral Infection (R. Knippers) H. RÖPKE und J. J. RIEMANN, Analog-Computer in Chemie und Biologie (M. Graef) . . . . B. ROSEN, Tables Interneationales des Constances Selectionnees 17. Donnees Spectroscopiques rela-tives aux Molecules Diatomiques — International Tables of Selected Constants 17. Spectroscopic Data relative to Diatomic Molecules (H. Rau) . J. SEIBL, Massenspektrometrie (W. Oettmeier) . SIEMENS A.G., Rechenzentrum (M. Graef) . . G. SCHIMMEL und W . VOGELL, Methodensamm-lung der Elektronenmikroskopie, Lfg. 1 und 2 (M. V. Nermut) P. SCHOPFER, Experimente zur Pflanzenphysiolo-gie (P. BÖGER) R. SCHULZE, Strahlenkunde der Erde (R. Mühl-eisen) F. SNELL, J. WOLKEN, G. J. IVERSON, and J. LAM, Physical Principles of Biological Membranes (P. Dancker) H. I. SHUVAL, Developments in Water Quality Research (J. Sander) 72 R. Y . STANIER, M . DODOROFF, and E. A . ADEL-BERG, General Microbiology (R. Knippers) . . E. TEUSCHER, Pharmakognosie I und II (E. Rein-hard) H. WAGNER and L. HÖRHAMMER, Pharmacognosy and Phytochemistry (H. Grisebach) R. WEGELER, Chemie der Pflanzenschutz- und Schädlingsbekämpfungsmittel, Band 2 (R.Diercks) D. H. M. WOOLLAM, Advances in Teratology (B Ostertag) W. WÜST, Die Brutvögel Mitteleuropas (E Schütz) W. ZIMMERMANN, Geschichte der Pflanzen (U Hamann)

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M . F. RAJEWSKY, H. Friedrich-Freksa zum 65. Ge-burtstag 178a

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