year 2 annual group report daly waters project

NATURAL RESOURCES EXPLORATION PTY LTD Natural Resources Exploration Pty Ltd Nicole Munro, Natural Resources Exploration Pty Ltd EL27877, EL27878 and EL27879 Nutwood Downs, Kalala, Shenandoah

Year 2 Annual Group Report Daly Waters Project GR214

Annual Group Technical Report Cooper, S.A.

SD53‐14, SE53‐01, SE53‐02

5564, 5565, 5665, 5666 NRE_NT2012: DW (Group x3) – 2nd Annual Group Report Base metals, diamonds and phosphate 23 October 2012

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.YEAR 2

ANNUAL GROUP REPORT

14/09/2011 to 13/09/2012DALY WATERS PROJECT

Title Holder

Operator

Tenement Manager Tenements

Tenement Names

Report Title

Type of Report

Author

Map 250k

Map 100k Company Reference Target Commodities

Date of Report

Contact Details NATURAL RESOURCES EXPLORATION PTY. LTD.

PO Box 9235, Gold Coast Mail Centre, QLD 9726

Level 8 Corporate Centre, 2 Corporate Ct, Bundall QLD

Tel: (07) 5644 5500 Fax: (07) 5528 4558

Email: [email protected]

Contents 1. ABSTRACT & INTRODUCTION .................................................................................................................. 4

2. TENEMENT AND LOCATION ..................................................................................................................... 4

3. GEOLOGY ................................................................................................................................................. 5

4. PREVIOUS FIRST YEAR PERIOD EXPLORATION ......................................................................................... 6

4.1 REVIEW OF HISTORICAL EXPLORATION ............................................................................................. 6

4.2 HISTORICAL WATER BORE CHIP SAMPLING ...................................................................................... 6

4.3 RECONNAISSANCE SITE VISIT ............................................................................................................. 6

5. CURRENT PERIOD EXPLORATION ............................................................................................................. 7

5.1 STRATIGRAPHIC DIAMOND CORE DRILLING ...................................................................................... 7

5.2 DOWNHOLE GEOPHYSICS ................................................................................................................ 11

5.3 DIAMOND EXPLORATION SAMPLING .............................................................................................. 12

6. CONCLUSIONS AND RECOMMENDATIONS ........................................................................................... 13

7. REFERENCES ........................................................................................................................................... 15

Figures

Figure 1. ........................................................................................................................................................ 5

Figure 2. ........................................................................................................................................................ 7

Figure 4. ........................................................................................................................................................ 8

Figure 3. ........................................................................................................................................................ 9

Figure 5. ...................................................................................................................................................... 10

Figure 6. ...................................................................................................................................................... 11

Tables

Table 1. ......................................................................................................................................................... 5

APPENDICES

1. Drill collar details (digital file attached) 2. Drill down hole orientation survey data (digital file attached) 3. Drilling Operations report by Drillwise 4. Drill lithology log (digital file attached) 5. Drilling magnetic susceptibility data (digital file attached) 6. Drilling relative density data (digital file attached) 7. Palynological examination report by L. Storian 8. Drill core portable XRF analysis data (digital file attached) 9. Petrological examination of drill samples by B.J. Barron. 10. Zonge downhole geophysics Operations report by S. Mann. 11. Downhole interpretation report by D. Tucker. 12. Diamond exploration sample details (digital file attached) 13. Diamond sample DMS processing details 14. Heavy mineral data sheet by Diatech. 15. Microprobe data on grains from diamond exploration samples (digital file attached)

1. ABSTRACT & INTRODUCTION

This report details all the exploration within EL27877, EL27878 and EL27879 which constitutes

the Daly Waters Project, for the second annual period ending 16 September 2012. The licences

are held by Natural Resources Exploration Pty Ltd and the target commodities are base metals,

diamonds, and phosphate. The dominant activity was the drilling of a 317.2m diamond cored

hole with associated downhole geophysics, measurements and sampling. This drilling was in

collaboration with the Northern territory Government. The drill hole was completed to test

the stratigraphy over the Daly Water Arch structural feature as no exploration has been

previously undertaken within EL27878 area, and the only historical drilling are water bores

with limited available data.

The single drillhole has confirmed the stratigraphy in an area and shown the Proterozoic rocks

to be at around 139 metres depth at this location. Further work is required but initial

observations are they are Proterozoic McArthur Group equivalents. Evidence of sulphide has

been observed including chalcopyrite. Geophysics has shown the region is suitable for electrical

based exploration and a potential target has been generated.

Nine heave mineral surface samples (total 144.77 kg) were also collected and processed during

the reporting period for diamond exploration. The diamond exploration samples were negative

for kimberlite indicators but the extreme wide spacing make this limited sampling inconclusive

at this stage.

2. TENEMENT AND LOCATION The Daly Waters Project consisting of EL27877, EL27878 and EL27879 is located in the central

north of the Northern Territory, approximately 500 kilometres southeast of Darwin. The

township of Daly Waters is situated within an excised portion of the EL27878. EL27905 was

formerly part of the project, but this licence was surrendered effective 21 August 2012. As a

separate Final Report (Munro, 2012) has been lodged activity within this licence is not discussed

further. Full details on the licences are in Table 1. Approved for Annual Group Technical

Reporting has been granted by the Department. All coordinates and maps in this report are

shown in GDA94, Zone 53 datum.

The Stuart, Buchanan and Carpentaria Highways intersect the project area and numerous minor

roads and unpaved tracks cross the tenures. The southern EL27079 is on the eastern side of the

Daly Waters SE53-01 1:250,000 map sheet. EL27878 covers the corners of Hodgson Downs

(SD53-14), Tanumbirini (SE53-02), Larrimah (SD53-13) and Daly Waters (SE53-01) 1:250,000 map

sheets. The eastern licence EL27877 crosses the southern boundary of Hodgson Downs

(SD53-14) and the northern boundary of the Tanumbirini (SE53-02) map sheets (Figure 1).

Licence Name Sub-blocks km2 Status Grant

Date

Expiry

Date

EL27877 Nutwood Downs 290 958 Granted 27/7/2010 26/7/2016

EL27878 Kalala 495 1628 Granted 15/9/2010 16/9/2016

EL27879 Shenandoah 475 1564 Granted 3/8/2010 2/8/2016

EL27905 Black Springs 155 511 Surrendered 15/9/2010 21/8/2012

Table 1. Daly Waters Project license details.

Figure 1. Exploration Index and Location map for Daly Waters Project. The location of drill

hole NDW12-01 is shown as well as all heavy mineral samples (red square are loam, red circle

are stream samples). Insert map shows 1:250,000 map sheets and license locations.

3. GEOLOGY

The Daly Waters Project tenements are located in the central region of the Mesozoic Dunmarra

Basin, an un-metamorphosed intracratonic basin unconformably part of the Neoproterozoic-

Palaeozoic overlying the Georgina, Wiso and Daly Basins and Palaeoproterozoic-

Mesoproterozoic sedimentary rocks of the McArthur Basin. The Dunmarra Basin is largely

unmetamorphosed and attains a maximum thickness of ~100 meters. No mineral occurrences

are known but potential is thought to exist for diamondiferous kimberlite pipes, phosphates,

base metals and uranium.

The surface geology consists mainly of poorly exposed Tertiary sands and Cretaceous Mullaman

Beds. The last published regional geological overview of the area was in 1969 (Brown, 1969)

4. PREVIOUS FIRST YEAR PERIOD EXPLORATION Main activity during the first annual period was the evaluation of historical exploration activity

and analysis of historical water hole drill chip samples.

4.1 REVIEW OF HISTORICAL EXPLORATION

An extensive review of historic exploration over its Daly Waters Project was conducted. The

earliest exploration on record dates back to 1971 by Comalco which explored for bauxite. Much

of the exploration since this time was for diamonds with a number of companies such as CRA

Exploration Limited, AOG Minerals, Ashton Mining Ltd, De Beers Australia Exploration,

Diamond Mines Australia and Aberfoyle Exploration. A full listing of the available open file

reports as provided in the First Annual Report (Devencorn, 2011).

Significantly no mineral exploration drilling has been completed within current exploration

licenses. Surface sampling for diamonds is restricted to the eastern part of current EL27877 by

Stockdale Prospecting Ltd, CRA Exploration Pty Ltd and Ashton Mining Ltd. A few chromites

were reported but as not microprobe data is available for the grains it is not possible to

speculate on their significance.

The main area of the current licenses has not been sampled at all possibly due to perceived thick

cover (Carpentaria Basin). But the amount of cover is depends on age of the sediments and age

of kimberlite. The kimberlite will be at the depth corresponding to is age in the local

stratigraphic column.

4.2 HISTORICAL WATER BORE CHIP SAMPLING

Selected historical water bore chip samples stored at the Northern Territory Geological Survey

were assayed for a range of metals. A total of thirty water bore chip samples were examined

from the current license area and anomalous levels of zinc, copper, lead and arsenic were

observed. Full details are in First Annual Report (Devencorn, 2011).

4.3 RECONNAISSANCE SITE VISIT

In August 2011 NRE conducted an initial site visit and reconnaissance program around

EL27878, Kalala. Meetings with the landowners were conducted and proposed drill hole

locations were ground inspected to assess their geological and accessibility conditions. NRE

further discussed all foreseen future drill holes with the landowners and the proposed access

to those drill holes along fence lines and existing tracks

Figure 2. Historical diamond indicator sampling. Yellow diamond shapes are diamonds,

smaller ones are microdiamonds, the small orange diamonds are chromites, red circles are

pyrope, and small grey squares are negative samples. Standard 1:100,000 map sheets are

shown.

5. CURRENT PERIOD EXPLORATION

5.1 STRATIGRAPHIC DIAMOND CORE DRILLING

An application was successful for a Drilling Collaboration in respect of EL27878 with the

Northern Territory Government. Under this program, NRE designed three stratigraphic holes

to be drilled. Due to time and budget constraints, only one drill hole NDW12-01 was completed.

The single drill hole was completed by Drillwise Pty Ltd based in Gibson, WA. The initial drill rig

was track mounted, but as this rig was not satisfactory this was replaced with a truck mounted rig

at 210.6m without pulling the rods. The hole was commenced on the 16 May 2012 and the

total depth reached on 7 June 2012 at which point the hole was abandoned. Two crews

worked double shifts over most of the period. The rig was released on the 12 June are failed

attempts to recover the drill rods, and after lowering the polypipe for the geophysics survey.

The hole NDW12-01 was rock rolled to competent ground at 1.4m. No sample was recovered

from this interval. The remaining entire hole from 1.4 to total depth 317.2m was HQ diamond

cored. Drilling was considered exceptionally challenging due to a number of different ground

conditions. A large number of days were lost due to mechanical issues. The core was halved on

site using a diamond saw.

Figure 4. Magnetic Susceptibility down hole.

The location of the hole collar was determined by a Garmin GPSmap 76cs handheld G P S set to

Averaging Mode (one second reading interval) over a 6 hours duration. Location determined

was; Easting (GDA94) 327,000mE; Northing (GDA94) 8,204,914mN; Elevation 210m; UTM Zone

53

The estimated accuracy of the hole collar is within one metre horizontal. A steel plate placed

over the buried collar would enable the collar to be located again with metal detector if

required. Location is shown in Figure 1 and details in Appendix 1.

5.1.1 Downhole Orientation Survey

The orientation of the drillhole was surveyed ever 50 metres down the hole with a Multishot

camera. Overall the hole was very straight and vertical. All magnetic intensity readings by the

survey probe (except the last reading at 300m depth) showed excellent correlation with

expected magnetic field strength (~48000nT) indicating little disturbance to magnetic azimuth.

As the final dip angle was only 0.9 degree from vertical at 300 metres, any slight disturbance of

the azimuth at this depth is not considered significant. See Appendix 2.

5.1.2 Palynological sampling

One s a m p l e from the drilling have been submitted for palynological examination to L.

Stoian from the Geological Survey of South Australia. The sample was from a thin (~1cm) mafic

clay unit (see Figure 3) at 38.4m depth, just above the unconformity with the underlying

limestone.

Figure 3. Thin band of black mudstone (~38.3m) just above dated sample. Scale in cm, top is

up.

The sample is not rich in pollen, spore or dinoflagellate cysts, with only a few taxa counted.

Modern and recent pollen grains were identified including Eucalypthus spathulatha, Casuarina

and Malvacipollis spp. Wood cuticles and phytoliths are present in moderate

frequencies. Marine microplankton include dinoflagellate cysts: Tectatodinium spp.,

Ataxiodinium confusum, Hystrichokolpoma rigaudiae, Apteodinium spp. The majority of the

dinoflagellate cysts are of Neogene age, more likely Late Miocene -Early Pliocene. The unit is

likely to be deposited under neritic marine conditions.

The support of Liliana Stoian, and the Geological Survey of South Australia, Resources and

Energy Group, DMITRE, is appreciated with this work.

5.1.3 Magnetic Susceptibility

The magnetic susceptibility was measured at approximately one metre intervals on

competent sections of the core. The instrument used was a Terraplus KT-10

Magnetic Susceptibility Meter set for HQ core diameter automatic correction. Sensitivity of

this instrument is 0.001x10-3 SI Units. Three readings were recorded on each core piece and the

average determined. All data is provided in Appendix 5. Figure 4 shows the average magnetic

susceptibility down the entire hole.

5.1.4 Petrographic description

Four initial samples were dispatched to consulting petrologist Dr B.J. Barron in Sydney for

detailed descriptions. The small fragments of half core were collected from various intervals to

confirm lithology. The full report is provided in Appendix 9

Two samples were from the limestone formation (138.38m and 134.32m). The first had a with

a mottled texture, the other with fine vugs. Both were confirmed as calcite rich limestone

sediments with little preserved texture. Two samples from the Proterozoic possible McArthur

Group equivalents were examined. At 230.5m the lithology is mudstone, possible lacustrine, and

262.0m depth is finely laminated claystone with possible fossil burrows.

5.1.5 Relative Density

The Relative Density (related to water) was determined on site at around one metre intervals

on suitable competent pieces of whole core. The method employed involved weighing the

core sample on a piece of wire in air, then submerged in water. The scale used was a generic

fishing digital scale of unknown accuracy (likely error could be up to 50g).

Figure 5. Chalcopyrite along near vertical fractures at 260.3m depth. Up hole is right, scale in

mm.

5.1.6 XRF drill core analysis

XRF multi-element analysis was conducted using a Delta X Premium Hand-held XRF (HHXRF)

with Rh anode and 30mm2 Silicon Drift Detector (SDD) over the entire length of hole at

regular intervals. The HHXRF was set to 3 Beam in Soil Mode with capture time of 60 seconds

per beam for a total of 180 seconds analysis time per sample. Measurements were taken

approximately every 1m from start of core (1.4m) to a depth of 12m, then every 5m interval

from 15m depth to end of hole (317.18m). Samples were selected and analyzed directly in the

metal core trays after previously cleaning with water.

XRF analysis was also completed on two sulphide coatings visible along fractures, confirming

one was pyrite and the other chalcopyrite. All data is provided in Appendix 8.

5.1.7 Drill Site Rehabilitation

Following completion of the downhole geophysics the polypipe within the hole was cut around

40cm below surface, sealed, and a thick metal cap placed on top. Soil was then placed back in

the hole over the metal cap. The sumps were then back filled and the original soil spread and

leveled over the site. Figure 6 shows the rehabilitation job completed using equipment and

personnel from Kalala Station.

Figure 6. Rehabilitated drillhole site NDW12-01. Drill sumps were on the right.

5.2 DOWNHOLE GEOPHYSICS

It was anticipated that both downhole TEM and IP dipole-dipole array would be completed to

the full depth of the drillhole. Due to a stuck drill rod string and the caved material above

blocking the hole, only the top half the hole was available for the TEM survey and as the hole

was dry and lined with PVC pipe no IP dipole-dipole could be completed. Full specifications

are provided in the Appendix 10 and interpretation in Appendix 11. The digital data has

previously been submitted (29 June 2012) as part of 'Drilling Collaboration Report Daly Waters

Project' report.

5.2.1 Downhole Transient Electromagnetic Survey

Downhole TEM survey using double 200m square loop centre over the hole, and the TEM sensor

lowered from 2 metres to 152 metres with readings every 5 metres. In conjunction two 200

square loops conventional TEM was completed to compare with and supplement the down

hole TEM.

5.2.2 Downhole Induced Polarisation Survey

Due to the stuck drill rod string down the hole, and the caving collapse of material above the

string the only practical IP survey that could be completed was a Mise a la Masse style survey.

A total of 77 stations were recorded on the surface over an area 400 metres east-west and

160 metres north-south at 40 metre intervals centred over the hole. The in-hole excitation

point was at 156 metres within hole NDW12-01.

5.3 DIAMOND EXPLORATION SAMPLING

During May-June 2011 the diamond exploration activity included surface loam deflation scraps

and stream sediment sampling for heavy mineral kimberlite indicator minerals (Figure 2).

5.3.1 Diamond Indicator Surface sampling

A total of nine (9) samples (144.77 kg total) were collected across the licences. Seven samples

were stream and two were loam sample scapes. These samples were sent to Diatech Heavy

Mineral Services in Perth. One sample, DW12-05 was lost in transit and not included. The

samples are all one standard bag each (around 10L), of minus 1.0 mm material screened on site.

Full sample details, including location coordinates, are provided in Appendix 12. Locations

were determined by handheld Garmin MapGPS 76cs GPS set in averaging mode during the

entire sampling collection time (around half an hour). All of the surface sampling activities

completed have been very low impact and only little rehabilitation at the time of collection has

been required. All stream samples were collected from un-cemented basal sediments in

natural trap sites within the active part of the current drainage. No disturbance to any rock

formations were required.

After the initial DMS concentration at Nagrom (Appendix 13) the concentrates were subject to

further TBE concentration and magnetic separation at Diatech before final visual observation.

Full details on the sample processing and results are provided in Appendix 13 and 14. No

kimberlitic or diamond indicators were observed. A number of grains were selected for

microprobe to confirm their mineralogy and all are not of further interest.

Trace gahnite (zinc spinel) was recovered with DW12-01 just south of Daly Waters, and a few

grains further to the south into EL27879. The number of gahnite grains recovered is decreasing

to the south. No gahnite was recovered in the northeast area of the project (EL27877)

5.3.2 Grain Microprobe Analyses

The selected indicator grains from Diatech were sent to Microbeam Services in Melbourne for

standard microprobe analyses. The grains were mounted in a round epoxy block which is then

grinded in diamond paste till the equatorial section of each grain is exposed and highly polished.

The core of the 27 selected grains were analysed using a Cameca SX50 Electron Microprobe

with four vertical Wavelength Dispersive Spectrometers (WDS). The electron beam accelerating

voltage was 15kV, and beam current 35/25nA. Counting times for all elements is 20 seconds

peak, and with 10 seconds on two backgrounds on either side of the peak position. Detection

limits for all elements better than 0.05 elemental weight percent except for Zn which is 0.09

elemental weight percent.

A lot of the grains were weathered and porous which hindered the quality of the analyses.

Grains identified as garnets were almandine, with minor pyrope components. The single garnet

from sample DW12-01 also had minor (15.6%) gossular component. Other grains were

confirmed as corundum, clinopyroxene and maybe amphibole, all of no further interest to

diamond exploration. The 14 gahnite grains were consistent in their chemistry with average

31.7% ZnO and 56.3% Al2O3 and 3.4% MgO. Full details are contained within Appendix 15.

6. CONCLUSIONS AND RECOMMENDATIONS In an area with little previous drilling the single drill hole has provided valuable information on

the stratigraphy and has shown the Proterozoic rocks to be at around 139 metres depth.

Further work is required but initial observations are the Proterozoic are McArthur Group

equivalents. Evidence of sulphide has been observed including chalcopyrite. The palynological

studies of the sediments that overlie limestone show that they are not from the Carpentaria

Basin (Jurassic- Cetaceous) as expected as the examination indicates a late Miocene-Early

Pliocene age. The anticipated Antrium Plateau Volcanics were not intersected above the

Proterozoic

The sequence intersected would appear transparent in a magnetic survey with no significant

magnetic units measured. The weak magnetic susceptibility readings do have a high correlation

with the observed lithology.

Geological study of the drillhole shows that pyrite was observed within the McArthur sediments

(Figure 5), as well in the Tindell Limestone near the base. A thin film of chalcopyrite was

confirmed at 260.4 metres along a fracture plane. It is significant these were along factures as

this implies mobilisation of sulphides. Minor pyrite was seen along some of the bedding planes

with within the dark grey McAthur sediments.

The hole intersected shallow marine fine sands to clay sediments of likely Late Miocene -Early

Pliocene age to 38.8 metres, overlying Devonian limestone. This limestone unconformably

overlies shallow dipping likely McArthur Basin shales with contact at 139.2 metres depth.

The TEM results did not detect large conducting and chargeable mineralised bodies either

intersecting or as near misses to the drill hole NDW12-01 above an estimated 150 metres depth.

The results also indicated that the shallow part of sediments surveyed at NDW12-01 is

essentially transparent to the type of electromagnetic signals used in mineral exploration. Also,

importantly, there is an absence of the often troublesome 'conductive overburden'

experienced elsewhere in Australia. If these conditions are widespread in this area of the

Carpentaria Basin, the TEM method is practical for large scale surveys seeking to explore

beneath these sediments to look in the basement for electrically detectable ore-bodies like for

instance HYC and Tennant Creek. Such surveys would use a heavy duty system with large loops

energised by high currents and with longer recording times.

The Induced Polarisation results recorded Self potential Apparent Chargeability and Potential

values (similar to Apparent Resistivity) anomalies around the drill hole NDW12-01. The SP

anomalies appear sinuous reminiscent of channels and it is believed that these are caused by

variations in the relatively shallow sediments, probably the top 50 metres. A locus of high

values 80 metres east of the drill hole warrant follow up.

The source of the Apparent Chargeability and Potential values anomalies are typical of a large

disseminated sulphide body. The depth is approximately 150 metres plus. These anomalies

warrant further investigation including drilling.

Because operational matters prevented direct access to the deeper sulphides intersected

by the drill hole NDW12-01, the direct characteristics of these remain untested by the downhole

IP method. If exploration continues in this locality, the sources of the deep and shallow IP

anomalies should be followed up.

To focus drilling for ore-bodies in this area, consideration is being to gravity traversing across

the Daly Waters Arch and airborne magnetic surveying over the tenements, to pin down the

basement depth and structural morphology in more detail.

7. REFERENCES Brown, M.C., 1969. Daly Waters Northern Territory 1:250,000 Geological Series Explanatory

Notes, Sheet SE53-1. Bureau of Mineral Resources, Geology and Geophysics, Canberra.

Devencorn, B., 2011. Year 1 Annual Group Report Daly Waters Project. Unpublished report

by Natural Resources Exploration Pty Ltd [submitted to NTGS]

Munro, N., 2012. Combined Report Year 2 Annual and Final, Black Springs EL27905.

Unpublished report by Natural Resources Exploration Pty Ltd [submitted to NTGS]

Stoian, L.M., 2012. Palynological analysis and dating of one sample from stratigraphic drillhole

NDW12-01, Daly Waters, Northern Territory. Unpublished report Geological Survey

of South Australia, Resources and Energy Group, DMITRE.

Appendix 1

H0002 Version 4

H0003 Date_generated 28-Jun-12

H0004 Reporting_period_end_date 28-Jun-12

H0005 State NT

H0100 Tenement_no EL27878

H0101 Tenement_holder Natural Resoucses Exploration Pty Ltd

H0102 Project_name Daly Waters

H0106 Tenement_operator NRE Operations Pty Ltd

H0150 250K_map_sheet_number SE53-01

H0151 100K_map_sheet_number 5565

H0200 Start_date_of_data_acquisition 1-May-12

H0201 End_date_of_data_acquisition 28-Jun-12

H0202 Template_format SL1

H0203 Number_of_data_records 1

H0204 Date_of_metadata_update 28-Jun-12

H0300 Location_data_file Daly_Waters_Combined_2012A_02_Drill_Collar.txt


H0302 Downhole_lithology_data_file Daly_Waters_Combined_2012A_03_Drill_Lithology.txt

H0303 Downhole_geochem_data_file Daly_Waters_Combined_2012A_04_Drill_Geochem.txt

H0304 Downhole_survey_data_file Daly_Waters_Combined_2012A_05_Drill_Survey.txt

H0308 File-Verfication_listing Daly_Waters_Combined_2012A_10_File_Listing.txt

H0314 Magsusc_data_file Daly_Waters_Combined_2012A_06_Dill_MagSusc.txt

H0318 Drill Relative_density Daly_Waters_Combined_2012A_07_Drill_density.txt

H0401 Drill_contractor Drillwise Pty Ltd

H0402 Description HQ diamond core drillhole collar

H0500 Feature_located Hole collar

H0501 Geodetic_datum GDA94

H0502 Vertical_datum AHD

H0503 Projection UTM

H0530 Coordinate_system Projected

H0531 Projection_Zone 53

H0532 Surveying_instrument Garmin 76sc in average mode (>6 hours)

H0533 Surveying_company Orogenic Exploration Pty Ltd

H1000 Hole_ID Xcoordinate Ycoordinate Zcoordinate Maxdepth Collar_azimuth Collar_Inclination Start_date End_date

H1001 metres metres metres metres degrees_true degrees H1004 1 1 2 0.1 0.5 0.2 D

EOF

NDW12‐01 327000 8204914 210 317.2 0 ‐90 16/05/2012 13/06/2012

Appendix 2

H0002 Version 4



H0005 State NT


H0101 Tenement_holder Natural Resources Exploration Pty Ltd







H0202 Template_format DS1











H0532 Surveying_instrument Multi shot

H0533 Surveying_company Drillwise Pty Ltd

H1000 Drillhole Survey_date Depth Azimuth_Mag Azimuth_True Dip Mag_Intensity Temperature H1001 Metres Degree Degree Degree nT C H1004 0.1 0.5 0.5 0.2 1 0.5

D NDW12‐01 18/05/2012 50.0 230.3 234.3 ‐89.9 47967 D NDW12‐01 25/05/2012 99.6 260.9 264.9 ‐89.8 47778 18

D NDW12‐01 27/05/2012 149.6 348.6 352.6 ‐89.9 48142 D NDW12‐01 30/05/2012 200.0 225.9 229.9 ‐89.8 48154 D NDW12‐01 2/06/2012 250.0 277.4 281.4 ‐89.8 48580 D

EOF

NDW12‐01 5/06/2012 300.0 222.4 226.4 ‐89.1 86133 26

Appendix 3

Drillwise pty Ltd Exploration Solutions Monday, 11 June 2012

Daly Waters Report 2012

Hole ID: NDW12-01

Diamond Drilling Program commence on Wednesday 16th May 2012

0-50 Metres

• Rock Rolled to competent ground at 1.4m

• Drilled soft broken ground

• Silting problems started to occur around 35m

• Lost water return around 46m (tried to condition hole but only lasted a couple metres)

50-100 Metres

• Ground started to pressurized through the loss of water and returning further up the

rod string

• Rods kept locking up in this zone • Ream HWT down to 51m to stop zone from caving in and pressurizing, whilst

reaming there was now a cavity from 29m to 41m. This cavity was not there whilst drilling

HQ

• Hole was completely dry thus constantly pulling rods out to grease due to rod chatter

in a dry hole

• Drilled broken with clay zones through out

• Constantly waiting on water as bore was inadequate to service our need to condition

and drill due to no water return

100-150 Metres

• Hole was still dry at this stage thus the constant need to pull out and grease rod string

but grease was being wiped away by wall in a matter of hours

• Constant change in ground condition from broken ground to clay and mud zones

• Drilled swelling Clay zones and rods keep locking up



150-200 Metres

• Drilled very broken ground and large patches of swelling clay zones causing heaps of

dramas with core loss and drop core in barrel and down hole thus changed over to HQ3 to

eliminate problems

• Drilled mud stone and didn‟t like any weight on this zone as it will suffocate bit face

and cause very short runs.





200-250 Metres

• Drilled mud stone and didn‟t like any weight on this zone as it will suffocate bit face and cause very short runs, core kept dropping into barrel and in hole





250-300 Metres

• Hole was silting up and tried constantly to condition hole but kept re occurring





• Hole started to cave in

• Unable to put weight on drill string as it would still just plug off upon anything more

than free spin and bog in

300- 310.4 Metres E.O.H

• Hole caving in from above causing silting problems, High Torque and rods bogging

in the hole

• Due to high torque and Bogging from cave-in, Rods keep separating

Strong possibility that the complete rod string will be a right off (approx $40,000 plus transport) Each rod to be tested at end of job. • Constantly waiting on water as bore was inadequate to service our need to condition




Note: Waiting on water was the biggest unproductive time spent throughout this program

causing anywhere from 1.5 to 4 hour delays every day thus un-enabling us to successfully

condition and flush hole out effectively.

The major cavity that occurred after drilling HQ was at 29 – 41 metres (12) was a major

factor prior to casing that section of. This has occurred in various other sections in the hole to

cause all the constant silting and cave in throughout the program.

Exceptionally challenging drilling

Barry Mckinlay

Operations Manager

DRILLWISE

Drillwise Pty Ltd Mob: 0400006631 • Email: [email protected] • Mail: PO Box 75, Gibson WA 6448

mailto:[email protected]

Appendix 4

H0002 Version 4



H0005 State NT


H0101 Tenement_holder Natural Resources Exploration Pty Ltd







H0202 Template_format DL1



H0300 Downhole_lithology_data_file EL27878_2012_Drill_03_LithoLogs.txt

H0301 Location_data_file EL27878_2012_Drill_02_DrillCollars.txt

H0302 Downhole_lithology_data_file EL27878_2012_Drill_03_LithoLogs.txt

H0303 Downhole_geochem_data_file EL27878_2012_Drill_04_DownholeGeochem.txt

H0304 Downhole_survey_data_file EL27878_2012_Drill_05_Downhole_Survey.txt

H0308 File-Verfication_listing EL27878_2012_Drill_10_File_Listing.txt

H0314 Magsusc_data_file EL27878_2012_Drill_06_MagSusc.txt

H0318 Drill Relative_density EL27878_2012_Drill_07_Relative_density.txt

H1000

H1001

H1004

D

Drillhole

NDW12‐01

Depth_from Depth_to Descriton

Metres Metres

0.1 0.1

0.0 15.0 Cream fine sandy sanstone, clay cemented bands common near surface

D

D

D

D

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

15.0 16.0 Orange‐red fine‐medium sands

16.0 20.8 Cream fine sandy sitlstone

20.8 24.0 Red‐orange fine‐medium sandstone

24.0 38.8 Crean silty clays, minor thin (<1cm) mafic carbonaceous clay bands near base.

D

D

D

D

D

D

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

38.8 54.1 Cream limstone

54.1 61.0 Light brown limestone, minor sandy texture

61.0 69.6 Light cream limestone, massive with mottled appearance

69.6 72.5 Pale redish silt clay limestone

72.5 139.2 Cream limestone, banded, motttled, horizontal beding, minor pyrite at base along fractures

139.2 141.0 Disturped unconfority suface, fragments of limestone within mostly distrubed shale fragments

D

D D

EOF

NDW12‐01

NDW12‐01

NDW12‐01

141.0 235.0 Mauve siltstone, dip 30 degrees, laminated, soft sediment defomation features common

235.0 291.6 Pale to darker grey, dip 25‐30 degrees, laminated, soft sediment defomation features common

291.6 317.2 Mauve‐grey laminated shale, 25‐20 degree dip, soft sediment deformation features common, trace sulphides on fractures.

Appendix 5

H0002

H0003

H0004

H0005

H0100

H0101

H0102

H0106

H0150

H0151

H0200

H0201

H0202

H0203

H0204

H0300

H0301

H0302

H0303

H0304

H0308

H0314

H0318

H0532

H0533

H0602

H0701

Version Date_generated

Reporting_period_end_date

State

Tenement_no

Tenement_holder

Project_name

Tenement_operator

250K_map_sheet_number


Start_date_of_data_acquisition

End_date_of_data_acquisition

Template_format

Number_of_data_records

Date_of_metadata_update

Magsusc_data_file

Location_data_file

Downhole_lithology_data_file

Downhole_geochem_data_file

Downhole_survey_data_file

File-Verfication_listing

Magsusc_data_file Drill

Relative_density

Survey_Instrument

Survey_Compnay

Sample_type

Sample_Preparation_details

4

28-Jun-12

28-Jun-12

NT

EL27878

Natural Resources Exploration Pty Ltd

Daly Waters

NRE Operations Pty Ltd

SE53-01

5565

1-May-12

28-Jun-12

DS1

216

28-Jun-12

Daly_Waters_Combined_2012A_06_Dill_MagSusc.txt

Daly_Waters_Combined_2012A_02_Drill_Collar.txt

Daly_Waters_Combined_2012A_03_Drill_Lithology.txt

Daly_Waters_Combined_2012A_04_Drill_Geochem.txt

Daly_Waters_Combined_2012A_05_Drill_Survey.txt

Daly_Waters_Combined_2012A_10_File_Listing.txt


Daly_Waters_Combined_2012A_07_Drill_density.txt

KT-10

Orogenic Exploration Pty Ltd

Drill core surface

Core cleaned with water

H1000 Drillhole Depth_From Depth_to MAGSUS_1 MAGSUS_2 MAGSUS_3 MAGSUS_AVG H1001 metres metres x10‐3 SI x10‐3 SI x10‐3 SI x10‐3 SI H1004 0.01 0.01 0.001 0.001 0.001 0.001

D NDW12‐01 1.80 1.95 0.047 0.048 0.042 0.046

D NDW12‐01 3.50 3.60 0.275 0.106 0.102 0.161 D NDW12‐01 4.30 4.40 0.078 0.098 0.185 0.120

D NDW12‐01 4.95 5.05 0.052 0.121 0.119 0.097 D NDW12‐01 5.90 6.10 0.126 0.117 0.128 0.124

D NDW12‐01 6.95 7.02 0.202 0.192 0.172 0.189

D NDW12‐01 7.94 8.07 0.255 0.266 0.242 0.254

D NDW12‐01 8.90 9.00 0.429 0.478 0.470 0.459

D NDW12‐01 9.95 10.02 0.121 0.123 0.127 0.124

D NDW12‐01 10.90 11.00 0.188 0.196 0.196 0.193

D NDW12‐01 23.90 24.00 0.016 0.018 0.018 0.017

D NDW12‐01 32.85 33.00 0.150 0.153 0.139 0.147

D NDW12‐01 36.20 36.30 0.227 0.224 0.223 0.225

D NDW12‐01 37.00 37.25 0.268 0.258 0.263 0.263 D NDW12‐01 38.00 38.10 0.162 0.149 0.136 0.149

D NDW12‐01 38.60 38.70 0.253 0.278 0.274 0.268

D NDW12‐01 39.20 39.30 0.008 0.010 0.013 0.010

D NDW12‐01 39.90 40.00 0.015 0.013 0.019 0.016

D NDW12‐01 41.95 42.05 0.012 0.021 0.016 0.016

D NDW12‐01 42.90 43.10 0.008 0.010 0.014 0.011

D NDW12‐01 43.90 44.00 0.021 0.018 0.014 0.018

D NDW12‐01 45.30 45.40 0.024 0.017 0.021 0.021

D NDW12‐01 47.00 47.15 0.010 0.015 0.007 0.011

D NDW12‐01 47.70 47.80 0.018 0.015 0.005 0.013

D NDW12‐01 49.90 50.00 0.013 0.015 0.016 0.015

D NDW12‐01 51.95 52.10 0.016 0.021 0.011 0.016 D NDW12‐01 53.85 54.00 0.093 0.061 0.058 0.071

D NDW12‐01 55.90 56.00 0.005 0.018 0.019 0.014

D NDW12‐01 57.90 58.00 0.055 0.058 0.100 0.071

D NDW12‐01 59.65 59.75 0.004 0.004 0.008 0.005

D NDW12‐01 60.90 61.00 0.010 0.010 0.009 0.010

D NDW12‐01 61.90 62.00 0.010 0.007 0.008 0.008

D

D

D

D

D

D

D

D

D

D

D

D

D

D

D

D

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

62.90

64.00

65.20

65.90

66.80

68.05

72.50

72.95

74.70

75.50

77.35

78.35

79.15

80.05

80.60

81.60

63.00

64.10

65.30

66.00

66.90

68.15

72.60

73.05

74.80

75.60

77.45

78.45

79.25

80.10

80.70

81.70

0.008

0.009

0.008

0.015

0.005

0.011

0.001

0.027

0.015

0.004

0.016

0.007

0.015

0.004

0.010

0.018

0.006

0.007

0.007

0.011

0.001

0.012

0.009

0.021

0.018

0.004

0.007

0.009

0.005

0.001

0.009

0.005

0.003

0.006

0.005

0.008

0.002

0.011

0.007

0.017

0.018

0.005

0.005

0.007

0.005

0.008

0.029

0.012

0.006

0.007

0.007

0.011

0.003

0.011

0.006

0.022

0.017

0.004

0.009

0.008

0.008

0.004

0.016

0.012

D NDW12‐01 82.55 82.65 0.010 0.004 0.008 0.007

D NDW12‐01 83.85 83.95 0.006 0.006 0.002 0.005

D NDW12‐01 84.90 85.00 0.005 0.010 0.007 0.007

D NDW12‐01 85.90 86.05 0.004 0.009 0.009 0.007

D NDW12‐01 88.20 88.30 0.014 0.005 0.008 0.009

D NDW12‐01 88.95 89.05 0.008 0.010 0.007 0.008 D NDW12‐01 90.95 91.05 0.008 0.004 0.001 0.004

D NDW12‐01 91.95 92.10 0.005 0.009 0.007 0.007

D NDW12‐01 93.95 94.00 0.002 0.005 0.005 0.004

D NDW12‐01 97.90 98.00 0.040 0.029 0.012 0.027

D NDW12‐01 99.95 100.05 0.005 0.004 0.004 0.004

D NDW12‐01 100.90 101.00 0.004 0.007 0.001 0.004

D NDW12‐01 102.60 102.75 0.012 0.006 0.009 0.009

D NDW12‐01 103.95 104.05 0.003 0.007 0.008 0.006

D NDW12‐01 105.60 105.75 0.002 0.002 0.001 0.002

D NDW12‐01 106.90 107.00 0.009 0.003 0.004 0.005

D NDW12‐01 108.80 108.95 0.010 0.002 0.005 0.006

D NDW12‐01 111.10 111.15 0.018 0.021 0.006 0.015 D NDW12‐01 111.65 111.75 0.030 0.041 0.025 0.032

D NDW12‐01 114.25 114.35 0.006 0.007 0.010 0.008

D NDW12‐01 116.30 116.45 0.011 0.006 0.010 0.009

D NDW12‐01 119.00 119.15 0.016 0.014 0.016 0.015

D NDW12‐01 124.00 124.10 0.013 0.002 0.002 0.006

D NDW12‐01 125.35 125.45 0.011 0.021 0.009 0.014

D NDW12‐01 126.60 126.70 0.027 0.026 0.033 0.029

D NDW12‐01 128.95 129.05 0.007 0.009 0.010 0.009

D NDW12‐01 130.95 131.05 0.044 0.041 0.049 0.045

D NDW12‐01 134.05 134.20 0.009 0.001 0.008 0.006

D NDW12‐01 136.15 136.30 0.003 0.004 0.002 0.003

D NDW12‐01 137.55 137.60 0.002 0.003 0.001 0.002 D NDW12‐01 137.70 137.80 0.007 0.015 0.009 0.010

D NDW12‐01 137.96 138.00 0.007 0.004 0.005 0.005

D NDW12‐01 138.45 138.55 0.003 0.002 0.002 0.002

D NDW12‐01 139.60 139.70 0.247 0.271 0.272 0.263

D NDW12‐01 139.85 140.00 0.150 0.167 0.175 0.164

D NDW12‐01 140.60 140.65 0.030 0.034 0.029 0.031

D NDW12‐01 141.00 141.10 0.222 0.207 0.217 0.215

D NDW12‐01 142.00 142.05 0.158 0.158 0.139 0.152

D NDW12‐01 143.00 143.10 0.107 0.053 0.050 0.070

D NDW12‐01 143.95 144.00 0.097 0.094 0.108 0.100

D NDW12‐01 144.90 144.95 0.131 0.123 0.127 0.127

D NDW12‐01 146.10 146.15 0.136 0.146 0.148 0.143 D NDW12‐01 146.95 147.05 0.105 0.110 0.114 0.110

D NDW12‐01 149.05 149.10 0.046 0.023 0.022 0.030

D NDW12‐01 150.60 150.70 0.139 0.128 0.127 0.131

D NDW12‐01 151.35 151.45 0.112 0.116 0.047 0.092

D

D

D

D

D

D

D

D

D

D

D

D

D

D

D

D

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

153.65

155.50

156.50

158.10

158.95

160.95

162.95

163.95

164.95

166.85

167.80

169.75

171.50

173.30

175.95

177.25

153.75

155.60

156.60

158.15

159.05

161.00

163.10

164.05

165.00

166.95

167.90

169.80

171.60

173.40

176.00

177.30

0.072

0.115

0.030

0.018

0.055

0.053

0.034

0.104

0.063

0.153

0.145

0.199

0.162

0.165

0.117

0.186

0.058

0.125

0.052

0.013

0.055

0.032

0.038

0.059

0.061

0.145

0.134

0.151

0.206

0.168

0.126

0.163

0.067

0.120

0.047

0.014

0.060

0.040

0.014

0.057

0.138

0.109

0.135

0.152

0.196

0.165

0.150

0.173

0.066

0.120

0.043

0.015

0.057

0.042

0.029

0.073

0.087

0.136

0.138

0.167

0.188

0.166

0.131

0.174

D NDW12‐01 178.20 178.40 0.250 0.228 0.226 0.235

D NDW12‐01 179.35 179.45 0.160 0.196 0.191 0.182

D NDW12‐01 182.90 183.00 0.221 0.226 0.219 0.222

D NDW12‐01 184.85 184.95 0.278 0.276 0.279 0.278

D NDW12‐01 187.20 187.35 0.256 0.306 0.293 0.285

D NDW12‐01 189.80 189.90 0.244 0.245 0.242 0.244 D NDW12‐01 190.95 191.05 0.305 0.307 0.293 0.302

D NDW12‐01 192.10 192.20 0.423 0.429 0.420 0.424

D NDW12‐01 193.75 193.85 0.380 0.375 0.376 0.377

D NDW12‐01 194.65 194.75 0.314 0.352 0.343 0.336

D NDW12‐01 196.00 196.10 0.242 0.257 0.265 0.255

D NDW12‐01 197.10 197.20 0.169 0.239 0.211 0.206

D NDW12‐01 198.00 198.10 0.273 0.250 0.250 0.258

D NDW12‐01 199.00 199.05 0.215 0.196 0.215 0.209

D NDW12‐01 200.10 200.20 0.171 0.176 0.170 0.172

D NDW12‐01 201.60 201.70 0.178 0.171 0.176 0.175

D NDW12‐01 203.05 203.15 0.161 0.175 0.178 0.171

D NDW12‐01 203.70 203.75 0.170 0.186 0.193 0.183 D NDW12‐01 205.50 205.60 0.021 0.051 0.042 0.038

D NDW12‐01 207.30 207.40 0.211 0.305 0.296 0.271

D NDW12‐01 209.00 209.10 0.233 0.224 0.227 0.228

D NDW12‐01 210.85 211.00 0.284 0.268 0.268 0.273

D NDW12‐01 211.95 212.05 0.297 0.273 0.261 0.277

D NDW12‐01 214.00 214.10 0.350 0.344 0.352 0.349

D NDW12‐01 215.90 216.00 0.285 0.262 0.272 0.273

D NDW12‐01 216.10 216.15 0.035 0.031 0.026 0.031

D NDW12‐01 217.95 218.00 0.237 0.246 0.248 0.244

D NDW12‐01 218.95 219.10 0.269 0.254 0.251 0.258

D NDW12‐01 220.70 220.78 0.378 0.389 0.437 0.401

D NDW12‐01 223.35 223.45 0.115 0.121 0.118 0.118 D NDW12‐01 224.25 224.40 0.374 0.377 0.370 0.374

D NDW12‐01 225.95 226.00 0.117 0.150 0.151 0.139

D NDW12‐01 227.40 227.50 0.106 0.124 0.145 0.125

D NDW12‐01 229.65 229.75 0.153 0.152 0.150 0.152

D NDW12‐01 232.40 232.50 0.212 0.211 0.222 0.215

D NDW12‐01 233.00 233.15 0.241 0.197 0.195 0.211

D NDW12‐01 233.90 234.00 0.198 0.203 0.203 0.201

D NDW12‐01 234.95 235.05 0.283 0.288 0.285 0.285

D NDW12‐01 235.95 236.05 0.168 0.168 0.166 0.167

D NDW12‐01 236.80 236.90 0.312 0.308 0.305 0.308

D NDW12‐01 238.05 238.15 0.159 0.142 0.147 0.149

D NDW12‐01 238.95 239.10 0.177 0.173 0.175 0.175 D NDW12‐01 240.05 240.15 0.205 0.206 0.196 0.202

D NDW12‐01 241.75 241.85 0.202 0.202 0.206 0.203

D NDW12‐01 242.05 242.10 0.104 0.095 0.036 0.078

D NDW12‐01 243.60 243.70 0.165 0.160 0.165 0.163

D

D

D

D

D

D

D

D

D

D

D

D

D

D

D

D

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

244.95

245.80

247.95

249.60

250.80

251.90

253.90

256.95

259.05

260.85

262.95

263.90

265.00

266.00

268.45

269.85

245.10

246.00

248.05

249.75

250.90

252.00

254.05

257.10

259.15

260.95

263.05

264.00

265.10

266.10

268.55

269.95

0.241

0.292

0.167

0.223

0.152

0.246

0.528

0.228

0.366

0.513

0.233

0.205

0.216

0.282

0.101

0.349

0.256

0.297

0.147

0.287

0.146

0.235

0.484

0.230

0.357

0.503

0.224

0.161

0.227

0.286

0.141

0.326

0.264

0.291

0.111

0.290

0.141

0.227

0.501

0.228

0.360

0.519

0.220

0.105

0.230

0.272

0.157

0.144

0.254

0.293

0.142

0.267

0.146

0.236

0.504

0.229

0.361

0.512

0.226

0.157

0.224

0.280

0.133

0.273

D NDW12‐01 271.45 271.55 0.718 0.482 0.671 0.624

D NDW12‐01 272.90 273.00 0.327 0.169 0.105 0.200

D NDW12‐01 273.85 273.95 0.303 0.331 0.316 0.317

D NDW12‐01 274.85 275.05 0.203 0.195 0.175 0.191

D NDW12‐01 276.90 277.00 0.229 0.164 0.162 0.185

D NDW12‐01 278.05 278.15 0.140 0.145 0.141 0.142 D NDW12‐01 279.40 279.50 1.550 1.600 1.530 1.560

D NDW12‐01 280.35 280.45 0.253 0.284 0.481 0.339

D NDW12‐01 281.25 281.35 0.308 0.244 0.557 0.370

D NDW12‐01 282.30 282.40 0.448 1.040 1.130 0.873

D NDW12‐01 283.50 283.60 1.670 1.430 1.650 1.583

D NDW12‐01 284.50 284.64 0.229 0.280 0.117 0.209

D NDW12‐01 285.20 285.30 1.340 1.230 0.728 1.099

D NDW12‐01 286.30 286.40 0.147 0.145 0.118 0.137

D NDW12‐01 287.60 287.70 0.606 0.177 0.308 0.364

D NDW12‐01 288.22 288.38 0.366 0.698 0.614 0.559

D NDW12‐01 289.43 289.52 0.194 0.397 0.385 0.325

D NDW12‐01 290.22 290.31 0.311 0.198 0.144 0.218 D NDW12‐01 291.60 291.70 0.249 0.194 0.238 0.227

D NDW12‐01 292.68 292.76 0.348 0.506 1.100 0.651

D NDW12‐01 293.25 293.39 0.379 0.318 0.317 0.338

D NDW12‐01 294.67 294.78 0.278 1.650 0.816 0.915

D NDW12‐01 295.60 295.70 0.266 0.168 0.263 0.232

D NDW12‐01 296.70 296.84 0.288 0.357 0.329 0.325

D NDW12‐01 297.60 297.72 0.236 0.249 0.186 0.224

D NDW12‐01 298.29 298.35 0.267 0.279 0.170 0.239

D NDW12‐01 299.30 299.39 0.301 0.444 0.398 0.381

D NDW12‐01 300.72 300.85 0.320 0.417 0.198 0.312

D NDW12‐01 301.42 301.60 0.208 0.282 0.336 0.275

D NDW12‐01 302.72 302.90 0.223 0.251 0.189 0.221 D NDW12‐01 303.60 303.71 0.234 0.208 0.197 0.213

D NDW12‐01 304.60 304.70 0.260 0.292 0.287 0.280

D NDW12‐01 305.75 305.84 0.407 0.386 0.408 0.400

D NDW12‐01 306.64 306.74 0.633 0.702 0.749 0.695

D NDW12‐01 307.70 307.77 0.313 0.246 0.380 0.313

D NDW12‐01 308.54 308.64 0.321 0.281 0.321 0.308

D NDW12‐01 309.55 309.63 0.288 0.216 0.262 0.255

D NDW12‐01 310.40 310.48 0.327 0.375 0.327 0.343

D NDW12‐01 311.40 311.49 0.219 0.196 0.164 0.193

D NDW12‐01 312.20 312.30 0.235 0.171 0.237 0.214

D NDW12‐01 313.55 313.62 0.096 0.109 0.115 0.107

D NDW12‐01 314.52 314.60 0.067 0.066 0.048 0.060 D NDW12‐01 315.13 315.24 0.197 0.228 0.323 0.249

D NDW12‐01 316.54 316.64 0.247 0.293 0.286 0.275

EOF

Appendix 6

H0002

H0003

H0004

H0005

H0100

H0101

H0102

H0106

H0150

H0151

H0200

H0201

H0202

H0203

H0204

H0300

H0301

H0302

H0303

H0304

H0308

H0314

H0318

H0532

H0533

H0602

Version Date_generated

Reporting_period_end_date

State

Tenement_no

Tenement_holder

Project_name

Tenement_operator



Start_date_of_data_acquisition

End_date_of_data_acquisition

Template_format

Number_of_data_records

Date_of_metadata_update

Drill Relative_density

Location_data_file

Downhole_lithology_data_file

Downhole_geochem_data_file

Downhole_survey_data_file

File-Verfication_listing

Magsusc_data_file

Drill Relative_density

Survey_Instrument

Survey_Compnay

Sample_type

4

28-Jun-12

28-Jun-12

NT

EL27878

Natural Resoruces Exploration Pty Ltd

Daly Waters


SE53-01

5565

1-May-12

28-Jun-12

DS1

204

28-Jun-12


Daly_Waters_Combined_2012A_02_Drill_Collar.txt

Daly_Waters_Combined_2012A_03_Drill_Lithology.txt

Daly_Waters_Combined_2012A_04_Drill_Geochem.txt

Daly_Waters_Combined_2012A_05_Drill_Survey.txt

Daly_Waters_Combined_2012A_10_File_Listing.txt



Generic fishing scales

Terra Search Pty Ltd

Drill core fragments

H1000 Drillhole Depth_From Depth_to DRY WEIGHT WET WEIGHT Realative Density H1001 metres metres kg kg To water H1004 0.01 0.01 0.05 0.05 D NDW12‐01 1.80 1.95 0.460 0.275 2.49

D NDW12‐01 3.50 3.60 0.210 0.125 2.47

D NDW12‐01 4.30 4.40 0.285 0.105 1.58

D NDW12‐01 4.95 5.05 0.325 0.185 2.32

D NDW12‐01 5.90 6.10 0.530 0.285 2.16 D NDW12‐01 6.95 7.02 0.155 0.080 2.07

D NDW12‐01 7.94 8.07 0.365 0.185 2.03

D NDW12‐01 8.90 9.00 0.260 0.140 2.17

D NDW12‐01 9.95 10.02 0.110 0.050 1.83

D NDW12‐01 10.90 11.00 0.255 0.115 1.82

D NDW12‐01 23.90 24.00 0.660 0.350 2.13

D NDW12‐01 32.85 33.00 0.590 0.305 2.07

D NDW12‐01 39.20 39.30 0.625 0.370 2.45

D NDW12‐01 39.90 40.00 0.525 0.325 2.63

D NDW12‐01 41.95 42.05 0.660 0.340 2.06

D NDW12‐01 42.90 43.10 0.780 0.495 2.74

D NDW12‐01 43.90 44.00 0.910 0.580 2.76 D NDW12‐01 45.30 45.40 0.905 0.570 2.70

D NDW12‐01 47.00 47.15 1.045 0.645 2.61

D NDW12‐01 47.70 47.80 0.600 0.380 2.73

D NDW12‐01 49.90 50.00 1.175 0.730 2.64

D NDW12‐01 51.95 52.10 0.940 0.530 2.29

D NDW12‐01 53.85 54.00 0.930 0.525 2.30

D NDW12‐01 61.90 62.00 0.675 0.405 2.50

D NDW12‐01 62.90 63.00 0.715 0.425 2.47

D NDW12‐01 64.00 64.10 0.745 0.440 2.44

D NDW12‐01 65.20 65.30 0.585 0.345 2.44

D NDW12‐01 65.90 66.00 0.600 0.395 2.93

D NDW12‐01 66.80 66.90 0.545 0.310 2.32 D NDW12‐01 68.05 68.15 0.480 0.275 2.34

D

D

D

D

D

D

D

D

D

D

D

D

D

D

D

D

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

72.50

72.95

74.70

75.50

77.35

78.35

79.15

80.05

80.60

81.60

82.55

83.85

84.90

85.90

88.20

88.95

72.60

73.05

74.80

75.60

77.45

78.45

79.25

80.10

80.70

81.70

82.65

83.95

85.00

86.05

88.30

89.05

0.665

0.490

0.650

0.565

0.390

0.795

0.530

0.270

0.430

0.625

0.865

0.710

0.560

0.865

0.740

0.725

0.385

0.275

0.375

0.335

0.220

0.405

0.255

0.140

0.240

0.370

0.515

0.425

0.345

0.540

0.455

0.435

2.38

2.28

2.36

2.46

2.29

2.04

1.93

2.08

2.26

2.45

2.47

2.49

2.60

2.66

2.60

2.50

D NDW12‐01 90.95 91.05 0.660 0.390 2.44

D NDW12‐01 91.95 92.10 0.985 0.575 2.40

D NDW12‐01 93.95 94.00 0.345 0.200 2.38

D NDW12‐01 97.90 98.00 0.540 0.315 2.40 D NDW12‐01 99.95 100.05 0.495 0.295 2.48

D NDW12‐01 100.90 101.00 0.585 0.350 2.49

D NDW12‐01 102.60 102.75 0.960 0.575 2.49

D NDW12‐01 103.95 104.05 0.610 0.370 2.54

D NDW12‐01 105.60 105.75 1.020 0.600 2.43

D NDW12‐01 106.90 107.00 0.600 0.355 2.45

D NDW12‐01 108.80 108.95 0.560 0.330 2.43

D NDW12‐01 111.10 111.15 0.535 0.300 2.28

D NDW12‐01 111.65 111.75 0.785 0.455 2.38

D NDW12‐01 114.25 114.35 0.555 0.310 2.27

D NDW12‐01 116.30 116.45 0.710 0.410 2.37

D NDW12‐01 119.00 119.15 0.895 0.545 2.56 D NDW12‐01 124.00 124.10 0.385 0.230 2.48

D NDW12‐01 125.35 125.45 0.795 0.470 2.45

D NDW12‐01 126.60 126.70 0.645 0.385 2.48

D NDW12‐01 128.95 129.05 0.705 0.430 2.56

D NDW12‐01 130.95 131.05 0.810 0.460 2.31

D NDW12‐01 134.05 134.20 1.080 0.665 2.60

D NDW12‐01 136.15 136.30 1.115 0.680 2.56

D NDW12‐01 137.55 137.60 0.445 0.270 2.54

D NDW12‐01 137.70 137.80 0.695 0.440 2.73

D NDW12‐01 137.96 138.00 0.335 0.210 2.68

D NDW12‐01 138.45 138.55 0.810 0.500 2.61

D NDW12‐01 139.60 139.70 0.630 0.355 2.29 D NDW12‐01 139.85 140.00 1.240 0.715 2.36

D NDW12‐01 140.60 140.65 0.425 0.245 2.36

D NDW12‐01 141.00 141.10 0.760 0.460 2.53

D NDW12‐01 142.00 142.05 0.580 0.355 2.58

D NDW12‐01 143.00 143.10 0.415 0.250 2.52

D NDW12‐01 143.95 144.00 0.375 0.225 2.50

D NDW12‐01 144.90 144.95 0.325 0.190 2.41

D NDW12‐01 146.10 146.15 0.475 0.285 2.50

D NDW12‐01 146.95 147.05 0.655 0.395 2.52

D NDW12‐01 149.05 149.10 0.290 0.175 2.52

D NDW12‐01 150.60 150.70 0.770 0.475 2.61

D NDW12‐01 151.35 151.45 0.635 0.390 2.59 D NDW12‐01 153.65 153.75 0.665 0.410 2.61

D NDW12‐01 155.50 155.60 0.730 0.455 2.65

D NDW12‐01 156.50 156.60 0.470 0.285 2.54

D

D

D

D

D

D

D

D

D

D

D

D

D

D

D

D

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

158.10

158.95

160.95

162.95

163.95

164.95

166.85

167.80

169.75

171.50

173.30

175.95

177.25

178.20

179.35

182.90

158.15

159.05

161.00

163.10

164.05

165.00

166.95

167.90

169.80

171.60

173.40

176.00

177.30

178.40

179.45

183.00

0.410

0.365

0.240

0.200

0.590

0.425

0.405

0.850

0.560

0.475

0.580

0.335

0.410

0.960

0.885

0.550

0.255

0.220

0.140

0.130

0.355

0.255

0.245

0.520

0.340

0.290

0.355

0.205

0.255

0.585

0.545

0.340

2.65

2.52

2.40

2.86

2.51

2.50

2.53

2.58

2.55

2.57

2.58

2.58

2.65

2.56

2.60

2.62

D NDW12‐01 184.85 184.95 0.660 0.405 2.59

D NDW12‐01 187.20 187.35 1.155 0.715 2.63

D NDW12‐01 189.80 189.90 0.670 0.410 2.58

D NDW12‐01 190.95 191.05 0.595 0.360 2.53 D NDW12‐01 192.10 192.20 0.815 0.500 2.59

D NDW12‐01 193.75 193.85 0.760 0.470 2.62

D NDW12‐01 194.65 194.75 0.510 0.310 2.55

D NDW12‐01 196.00 196.10 0.665 0.405 2.56

D NDW12‐01 197.10 197.20 0.705 0.435 2.61

D NDW12‐01 198.00 198.10 0.580 0.355 2.58

D NDW12‐01 199.00 199.05 0.415 0.255 2.59

D NDW12‐01 200.10 200.20 0.990 0.610 2.61

D NDW12‐01 201.60 201.70 0.580 0.355 2.58

D NDW12‐01 203.05 203.15 0.530 0.320 2.52

D NDW12‐01 203.70 203.75 0.495 0.305 2.61

D NDW12‐01 205.50 205.60 0.605 0.375 2.63 D NDW12‐01 207.30 207.40 0.625 0.385 2.60

D NDW12‐01 209.00 209.10 0.690 0.445 2.82

D NDW12‐01 210.85 211.00 0.745 0.465 2.66

D NDW12‐01 211.95 212.05 0.695 0.435 2.67

D NDW12‐01 214.00 214.10 0.675 0.415 2.60

D NDW12‐01 215.90 216.00 0.715 0.445 2.65

D NDW12‐01 223.35 223.45 0.610 0.370 2.54

D NDW12‐01 224.25 224.40 1.080 0.640 2.45

D NDW12‐01 225.95 226.00 0.335 0.210 2.68

D NDW12‐01 227.40 227.50 0.875 0.535 2.57

D NDW12‐01 229.65 229.75 0.510 0.315 2.62

D NDW12‐01 232.40 232.50 0.610 0.375 2.60 D NDW12‐01 233.00 233.15 0.855 0.525 2.59

D NDW12‐01 233.90 234.00 0.525 0.320 2.56

D NDW12‐01 234.95 235.05 0.395 0.250 2.72

D NDW12‐01 235.95 236.05 0.535 0.330 2.61

D NDW12‐01 236.80 236.90 0.670 0.415 2.63

D NDW12‐01 238.05 238.15 0.585 0.360 2.60

D NDW12‐01 238.95 239.10 0.675 0.415 2.60

D NDW12‐01 240.05 240.15 0.730 0.445 2.56

D NDW12‐01 241.75 241.85 0.700 0.430 2.59

D NDW12‐01 242.05 242.10 0.505 0.310 2.59

D NDW12‐01 243.60 243.70 0.800 0.490 2.58

D NDW12‐01 244.95 245.10 0.795 0.490 2.61 D NDW12‐01 245.80 246.00 1.280 0.790 2.61

D NDW12‐01 247.95 248.05 0.670 0.405 2.53

D NDW12‐01 249.60 249.75 1.110 0.685 2.61

D

D

D

D

D

D

D

D

D

D

D

D

D

D

D

D

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

NDW12‐01

250.80

251.90

253.90

256.95

259.05

260.85

262.95

263.90

265.00

266.00

268.45

269.85

271.45

272.90

273.85

274.85

250.90

252.00

254.05

257.10

259.15

260.95

263.05

264.00

265.10

266.10

268.55

269.95

271.55

273.00

273.95

275.05

0.725

0.830

0.685

0.620

0.730

0.770

0.585

0.485

0.895

0.775

0.680

0.690

0.960

0.690

0.895

1.110

0.445

0.505

0.420

0.385

0.455

0.475

0.355

0.300

0.540

0.475

0.420

0.420

0.590

0.425

0.585

0.690

2.59

2.55

2.58

2.64

2.65

2.61

2.54

2.62

2.52

2.58

2.62

2.56

2.59

2.60

2.89

2.64

D NDW12‐01 276.90 277.00 0.715 0.440 2.60

D NDW12‐01 278.05 278.15 0.645 0.395 2.58

D NDW12‐01 279.40 279.50 0.810 0.505 2.66

D NDW12‐01 280.35 280.45 0.820 0.510 2.65 D NDW12‐01 281.25 281.35 1.045 0.655 2.68

D NDW12‐01 282.30 282.40 0.700 0.435 2.64

D NDW12‐01 283.50 283.60 0.965 0.615 2.76

D NDW12‐01 284.50 284.64 1.175 0.730 2.64

D NDW12‐01 285.20 285.30 0.925 0.580 2.68

D NDW12‐01 286.30 286.40 0.685 0.425 2.63

D NDW12‐01 287.60 287.70 1.050 0.655 2.66

D NDW12‐01 288.22 288.38 1.069 0.655 2.58

D NDW12‐01 289.43 289.52 0.750 0.465 2.63

D NDW12‐01 290.22 290.31 0.675 0.420 2.65

D NDW12‐01 291.60 291.70 0.810 0.500 2.61

D NDW12‐01 292.68 292.76 0.695 0.440 2.73 D NDW12‐01 293.25 293.39 1.195 0.765 2.78

D NDW12‐01 294.67 294.78 0.955 0.635 2.98

D NDW12‐01 295.60 295.70 0.570 0.360 2.71

D NDW12‐01 296.70 296.84 1.155 0.730 2.72

D NDW12‐01 297.60 297.72 1.025 0.655 2.77

D NDW12‐01 298.29 298.35 0.785 0.500 2.75

D NDW12‐01 299.30 299.39 0.755 0.485 2.80

D NDW12‐01 300.72 300.85 1.320 0.855 2.84

D NDW12‐01 301.42 301.60 1.155 0.740 2.78

D NDW12‐01 302.72 302.90 1.470 0.935 2.75

D NDW12‐01 303.60 303.71 0.860 0.540 2.69

D NDW12‐01 304.60 304.70 0.810 0.510 2.70 D NDW12‐01 305.75 305.84 0.885 0.580 2.90

D NDW12‐01 306.64 306.74 0.805 0.510 2.73

D NDW12‐01 307.70 307.77 0.510 0.315 2.62

D NDW12‐01 308.54 308.64 0.865 0.560 2.84

D NDW12‐01 309.55 309.63 0.715 0.455 2.75

D NDW12‐01 310.40 310.48 0.660 0.420 2.75

D NDW12‐01 311.40 311.49 0.775 0.490 2.72

D NDW12‐01 312.20 312.30 0.965 0.610 2.72

D NDW12‐01 313.55 313.62 0.615 0.425 3.24

D NDW12‐01 314.52 314.60 0.585 0.360 2.60

D NDW12‐01 315.13 315.24 0.960 0.610 2.74

D NDW12‐01 316.54 316.64 0.990 0.665 3.05 EOF

Appendix 7

Palynological analysis and dating of one sample from stratigraphic drillhole

NDW12‐001, Daly Waters, Northen Territory

Author: Liliana M Stoian

One sample from NDW12‐001 stratigraphic drillhole, Daly Waters, has been submitted to Liliana Stoian, Senior Geoscientist, Geological Survey of South Australia for palynological analysis and dating.

The sample was collected by Steven Cooper, depth 38.5 to 38.6m, and represents a black clay layer sitting above an unconformity with underlying limestone, possible Devonian age. Sample size for palynological analysis is about 20‐30g.

Traditional palynological methods were employed including digesting in HCl and HF acids followed by heavy liquid separation (SPT – sodium polytungstate liquit at density 2). No much separation was observed after heavy liquid and all organic material was mounted on a slide using Eukit media. Palynomorph identification was undertaken by the author using a Zeiss Photomicroscope III.

Results

Fossil pollen of Malvacipollis diversus, Haloragacidites harrisii (Casuarina type) and Eucalyptus spathulata are present in very low frequencies. No other pollen grains were present. The palynofloras are difficult to correlate with any palynofloral zones developed in Australia due to lack of any key taxa and species diversity. Pollen of Eucalyptus spathulatha could come from modern eucalyptus species.

Marine microplankton is well represented and include the following taxa: Ataxiodinium confusum, Hystrichokolpoma rigaudiae, Tectatodinium pellitum, Bitectatodinium tepikiense, Apteodinium spp. Similar dinoflagellate cysts are known elsewhere from Neogene and Quaternary and their presence in the sample is associated with a marine event. Species of Bitectatodinium tepikiense and Tectatodinium pellitum are indicators of neritic to oceanic environment.

Sample also contain small amount of grass phytoliths (trapezoid, bilobate and fan shapes). Phytoliths are biogenic silica produced by many plants, very resistant to weathering and preserved in modern soil as well as in older sediments.

The sample does not contain any reworked palynomorphs.

Based on dinoflagellate cysts assemblages and correlation with similar assemblages found elsewhere, the sample is likely to be dated Late Miocene – Early Pliocene.

Appendix 8

H0002 Version 4



H0005 State NT


H0101 Tenement_holder NRE Operations Pty Ltd







H0202 Template_format DG1











H0602 Sample_type Cut drill core surface

H0701 Sample_Preparation_details Half HQ core cleaned with water

H0801 Assay_Company NRE Operations Pty Ltd

H0802 Assay_description Hand held DeltaX Premium XRF (HHXRF), 180 seconds per sample

H1000 Drillhole Depth Material XRF_Mode P P +/‐ S S +/‐ Cl Cl +/‐ K K +/‐ Ca Ca +/‐ Ti Ti +/‐ V V +/‐ Cr Cr +/‐ Mn Mn +/‐ Fe Fe +/‐ Co Co +/‐ Ni Ni +/‐ Cu Cu +/‐ Zn Zn +/‐ As As +/‐ Se Se +/‐ Rb Rb +/‐ Sr Sr +/‐ Zr Zr +/‐ Mo Mo +/‐ Ag Ag +/‐ Cd Cd +/‐ Sn Sn +/‐ Sb Sb +/‐ W W +/‐ Au Au +/‐ Hg Hg +/‐ Pb Pb +/‐ Bi Bi +/‐ Th Th +/‐ U U +/‐

H1001 Metre ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm

H1004 0.1

D NDW12‐01 1.4 Sediment Soil 1357 389 ‐65 199 ‐927 137 3042 88 644 46 10228 114 220 8 40 10 72 9 372465 1776 265 4 ‐761 12 20 4 281 5 41.4 2 ‐0.7 0.7 12.1 1.2 61.9 1.9 103 2 9.2 1.1 2 4 ‐5 5 40 9 11 10 10 4 ‐24 2 ‐12 2 ‐2 4 44 5 2.8 1.8 ‐9.8 1.8

D NDW12‐01 2.4 Sediment Soil 619 334 430 178 ‐565 134 3411 98 971 49 12382 134 165 7 123 9 48 8 164577 851 160 3 ‐456 10 31 4 246 5 30.4 1.6 ‐0.2 0.7 29.4 1.1 78 2 142 3 8.3 1.3 ‐2 5 ‐10 7 29 11 3 12 11 5 ‐9 2 5 2 23 2 ‐19 6 19 2 ‐1 2

D NDW12‐01 3 Sediment Soil 694 248 406 130 ‐493 85 4693 80 255 32 5848 56 279 5 171 7 ‐12 6 84983 296 33.6 1.3 ‐91 5 6 2 179 3 14.4 0.8 0.1 0.4 30.5 0.7 105.7 1.9 142 2 5.1 0.8 ‐3 3 ‐4 4 27 6 2 7 2 3 ‐3.7 1.4 ‐0.5 1.2 8.3 1.3 16 3 15.4 1.4 ‐3.2 1.2

D NDW12‐01 4 Sediment Soil 317 138 351 64 50 49 4273 58 454 24 4234 33 103 3 117 4 39 3 14694 57 7.7 0.5 ‐6 3 12 1.8 983 6 3.4 0.7 1 0.4 31.5 0.7 484 5 230 3 0.6 0.8 3 2 5 3 26 6 ‐6 6 ‐22 3 2.5 1.3 9.4 1.2 24.9 1.1 3 3 22.7 1.6 2.3 1.5

D NDW12‐01 5 Sediment Soil 556 180 5159 154 51 54 4999 65 9060 79 4159 34 101 3 99 4 84 4 19107 71 9.3 0.6 ‐16 3 11.5 1.8 210 3 4.3 0.7 0.4 0.4 28.2 0.6 372 5 189 2 3.1 0.8 3 2 ‐5 3 24 6 4 6 ‐1 2 ‐1.7 1.2 3.8 1.1 21.7 1.1 10 3 21.3 1.5 0.5 1.4

D NDW12‐01 6 Sediment Soil 106 226 2277 159 26 86 4250 86 3696 65 3446 41 59 4 56 5 13 5 30793 138 7.1 0.9 ‐31 5 18 3 320 4 5.9 0.7 ‐0.8 0.5 26.8 0.8 28.1 1.1 122 2 5.3 0.9 1 3 ‐7 5 34 8 3 9 ‐3 3 ‐0.2 1.6 3.4 1.4 2 1.1 ‐28 4 7.2 1.4 1.3 1.3

D NDW12‐01 7 Sediment Soil 1650 245 4394 180 ‐232 75 3117 62 4209 59 4396 42 390 5 463 8 159 6 59145 213 29.1 1.1 ‐63 5 101 3 333 4 8.6 0.8 0.3 0.4 16.7 0.7 613 8 157 2 4.2 0.8 1 3 ‐4 4 27 6 2 7 ‐7 3 ‐0.1 1.5 3.2 1.2 16.6 1.3 6 4 19 1.8 ‐5 1.7

D NDW12‐01 8 Sediment Soil 812 259 6848 224 136 88 3571 68 6669 79 4015 42 70 4 102 6 4 5 85184 304 33.4 1.3 ‐87 5 20 2 354 4 4.2 0.7 0.1 0.4 18.9 0.6 64.5 1.4 168 2 2 0.8 ‐5 3 ‐3 4 21 6 1 7 ‐4 3 ‐2.6 1.4 1.7 1.3 6.3 1.3 14 3 9.1 1.3 ‐0.7 1.2

D NDW12‐01 9 Sediment Soil 1298 395 11907 358 577 139 3531 86 12072 145 4084 55 118 5 163 9 ‐22 8 182481 690 55 2 ‐189 7 3 3 410 4 17.7 1.1 ‐0.2 0.5 15.4 0.8 32.7 1.1 207 3 4.9 0.9 ‐1 3 ‐8 4 19 7 8 8 0 3 ‐11.4 1.7 ‐4.8 1.5 ‐11.3 2 37 4 6.3 1.5 ‐2.2 1.4

D NDW12‐01 10 Sediment Soil 484 250 4455 192 324 90 3036 64 5813 73 3935 41 69 4 119 6 20 5 84730 302 28.2 1.3 ‐75 5 8 2 111 2 7.7 0.8 ‐0.1 0.4 15.6 0.6 49.3 1.2 229 3 3.9 0.9 ‐6 3 ‐15 4 34 7 4 7 2 3 ‐4.6 1.4 1.3 1.3 5.2 1.3 18 3 13.1 1.4 ‐1.7 1.1

D NDW12‐01 11 Sediment Soil 113 217 4661 182 379 80 2605 57 5325 67 3232 34 83 3 114 5 9 5 48760 175 16.7 1 ‐51 4 18 2 66.3 1.7 8.8 0.7 0.1 0.4 17.7 0.6 63.6 1.4 169 2 3.5 0.8 0 3 ‐6 4 30 6 5 7 3 2 ‐3.5 1.3 ‐0.9 1.1 14.4 1.1 3 3 13.7 1.4 ‐1.3 1.1

D NDW12‐01 12 Sediment Soil ‐38 143 135 65 125 57 3520 59 ‐67 21 3675 34 60 3 66 4 8 3 20139 77 9.1 0.6 ‐28 4 6.7 1.8 47.6 1.5 4.5 0.7 ‐0.4 0.4 22.9 0.6 83.5 1.5 227 3 1.2 0.8 5 3 2 4 17 6 ‐11 7 3 2 ‐0.1 1.3 1.3 1 19.4 1 ‐7 3 13.7 1.3 ‐0.8 1

D NDW12‐01 15 Sediment Soil ‐447 109 105 50 462 49 616 27 ‐268 14 1755 18 21.5 1.7 21 2 ‐1 3 8192 36 ‐1.3 0.3 11 3 9 1.6 10.2 0.9 0.7 0.5 0.3 0.3 2.2 0.4 13.4 0.5 32.8 0.7 ‐0.1 0.5 3 2 ‐3 3 10 5 11 6 14.6 2 ‐2.9 1.1 1 1 7.7 0.8 11 3 2.4 0.8 0.9 0.8

D NDW12‐01 20 Sediment Soil ‐323 125 2054 98 763 55 1168 33 2440 37 1511 17 17.8 1.6 24 2 0 3 6883 32 ‐0.6 0.3 13 3 6.5 1.6 196 2 0.8 0.5 0 0.3 5.8 0.4 22.1 0.7 28.2 0.6 1.9 0.5 1 2 ‐1 3 18 6 ‐8 6 ‐2 2 0.8 1.1 1.9 0.9 5.6 0.8 ‐1 3 2.4 0.9 ‐0.2 0.8

D NDW12‐01 25 Sediment Soil 584 114 116 39 81 32 198 18 ‐213 13 313 7 4.5 0.8 1.9 1.7 ‐6 2 835 9 0.1 0.1 18 3 6.5 1.5 7.4 0.7 ‐1.1 0.4 0.7 0.3 0.6 0.3 6.7 0.4 29.5 0.6 ‐0.2 0.5 0 2 2 3 12 5 6 6 2.3 1.7 1.2 1 ‐0.3 0.8 2.8 0.6 16 2 1.7 0.8 1.1 0.7

D NDW12‐01 30 Sediment Soil 348 205 242 97 ‐94 80 38183 335 470 52 6338 59 80 4 77 5 135 5 26883 117 8.9 0.8 21 5 50 3 84 2 4.1 0.7 ‐0.2 0.5 191.9 1.6 24.1 1 277 4 ‐0.7 1.1 ‐2 3 ‐16 5 20 8 ‐6 9 5 3 ‐0.1 1.6 6.1 1.4 9.3 1.2 ‐21 4 26 1.9 10.4 1.9

D NDW12‐01 35 Sediment Soil 161 285 190 140 ‐308 120 35569 435 574 69 3646 54 62 5 60 7 258 9 26948 155 8.7 1.1 31 7 7 3 10 3 5.1 0.9 0.4 0.6 188 2 23.3 1.2 124 3 3.1 1.2 1 4 ‐3 6 23 10 ‐16 12 7 4 ‐2 2 7.2 1.9 2 1.5 ‐45 5 17 2 3 2

D NDW12‐01 40 Sediment Soil ‐300 636 1405 196 831 91 2517 61 345229 2162 296 9 13.8 1.3 ‐6 2 647 8 4632 27 ‐0.1 0.3 27 4 8.2 1.8 172 2 ‐0.4 0.5 0.2 0.4 2.9 0.4 32.2 0.9 3 0.4 ‐0.7 0.5 3 3 ‐1 4 33 6 5 7 ‐1 2 1.8 1.2 0.8 1 3.5 0.8 11 3 1.6 0.9 0 0.9

D NDW12‐01 45 Sediment Soil 189 616 1130 190 325 87 11108 126 287850 1904 693 13 11.3 1.5 2 3 393 6 6332 35 1.9 0.4 18 4 15 2 369 4 1.2 0.5 0.7 0.4 22.9 0.6 34.1 1 15.6 0.6 0.2 0.6 0 3 ‐3 4 25 7 8 8 ‐8 3 3 1.4 3.5 1.2 3.5 0.9 ‐8 3 3.6 1.1 1.5 1.1

D NDW12‐01 50 Sediment Soil 972 662 651 193 1261 99 2186 61 338882 2213 205 7 4.9 1.1 ‐9 2 381 6 2247 18 1.3 0.2 18 4 47 2 61.5 1.8 0.6 0.5 ‐0.3 0.4 4.9 0.5 32.6 1 2.7 0.4 ‐0.2 0.5 ‐3 3 ‐7 4 16 7 6 8 ‐7 2 6.3 1.4 3.7 1.1 2.5 0.8 5 3 2 1 1 1

D NDW12‐01 55 Sediment Soil 182 685 539 199 1262 102 842 51 363690 2392 258 8 2.7 1.1 3 2 378 6 4040 26 0.6 0.3 11 4 8.8 1.9 736 6 0.9 0.6 0.1 0.4 1 0.4 28.5 0.9 0.7 0.4 0.1 0.5 3 3 ‐3 4 10 7 ‐6 8 ‐14 3 3 1.3 5.4 1.2 7.6 0.9 ‐7 3 2.6 1 ‐0.5 0.9

D NDW12‐01 60 Sediment Soil 337 533 434 160 636 86 20671 189 211961 1402 953 16 16.4 1.7 5 3 261 5 8249 39 3.3 0.4 66 4 19.5 2 102.1 2 1.8 0.6 1.9 0.4 40.7 0.7 75.1 1.5 35.2 0.8 ‐1.7 0.6 ‐2 3 ‐2 4 18 6 18 7 ‐1 2 2.1 1.3 2.2 1.1 13.4 0.9 30 3 4.4 1.1 2.5 1.1

D NDW12‐01 65 Sediment Soil ‐1169 1098 3526 340 2533 154 2691 84 818588 5812 432 11 8.6 1.4 4 3 118 4 3478 26 ‐1.3 0.3 39 5 15 2 208 3 1.2 0.6 1.7 0.5 2.6 0.5 92.2 2 5.7 0.6 ‐1.2 0.6 6 3 ‐2 5 29 7 ‐11 8 ‐5 3 8.6 1.6 3.5 1.3 2.9 0.9 0 4 0.1 1.2 3.5 1.3

D NDW12‐01 70 Sediment Soil 6133 1051 4104 327 993 135 7629 118 704729 5001 1849 25 13 2 12 3 127 5 12126 61 0.1 0.5 39 5 135 3 145 3 3.2 0.7 1.3 0.5 14.4 0.6 101 2 14.4 0.7 ‐0.5 0.7 0 3 4 4 31 7 7 8 ‐4 3 8.9 1.6 2.9 1.4 13.1 1.1 2 4 2.1 1.2 3.5 1.3

D NDW12‐01 75 Sediment Soil ‐443 435 1368 150 211 71 25976 208 161128 997 1782 21 34 2 38 3 207 5 9692 44 1.8 0.4 28 4 16.6 1.9 175 2 1.7 0.5 1.1 0.4 72.2 0.9 65.9 1.3 53.9 1 0.1 0.6 3 3 ‐8 4 20 6 ‐1 7 0 2 0.9 1.3 4.6 1.1 1.8 0.8 1 3 8.1 1.1 3.8 1.2

D NDW12‐01 80 Sediment Soil ‐1916 656 529 192 2447 109 541 45 387382 2398 127 6 2 0.9 ‐4 2 116 4 1281 13 ‐0.1 0.2 24 3 9.8 1.8 51.7 1.6 0 0.5 0 0.4 1.6 0.4 55.5 1.2 0.9 0.4 0 0.5 ‐1 3 ‐2 4 29 6 ‐2 7 ‐5 2 5.1 1.3 2.4 1 8.9 0.9 5 3 ‐0.5 0.9 0.2 0.9

D NDW12‐01 85 Sediment Soil 1375 971 1413 282 1510 127 2028 71 707371 4714 43 4 1.8 0.9 ‐2 2 55 3 308 7 0.5 0.1 31 4 15 2 25.9 1.6 0.2 0.6 1.6 0.4 2.2 0.5 110 2 2.7 0.5 0.7 0.6 0 3 ‐13 4 26 7 24 8 ‐4 2 5.9 1.5 5.4 1.2 13 1 5 3 3.1 1.2 4.2 1.3

D NDW12‐01 90 Sediment Soil 1617 1137 1373 326 1492 144 2812 85 885324 6199 53 5 2.4 1 2 2 17 3 323 8 0.6 0.1 22 4 18 2 ‐1.9 1.3 0.3 0.6 1.3 0.5 2 0.5 79.1 1.8 5.4 0.6 1.2 0.6 0 3 9 5 31 7 4 8 ‐7 3 8.2 1.6 6.7 1.3 6.5 1 2 3 3.1 1.2 1.7 1.2

D NDW12‐01 95 Sediment Soil 1555 1194 2200 352 2640 166 2246 87 843650 6386 138 7 3.2 1.2 8 3 35 4 1224 16 0.3 0.2 3 4 13 2 226 4 0.1 0.7 0.7 0.5 3.2 0.5 115 3 3.5 0.6 ‐0.3 0.7 ‐2 4 ‐9 5 19 8 8 9 ‐2 3 5.7 1.6 5.2 1.4 9.1 1.1 ‐8 4 3.4 1.4 2.9 1.5

D NDW12‐01 100 Sediment Soil ‐164 988 3712 313 13922 242 2907 80 690108 4772 150 8 1.3 1.2 0 3 70 4 8998 48 3.5 0.5 11 4 14 2 81 2 2.9 0.7 1.7 0.5 3 0.5 111 2 2.7 0.6 0.2 0.6 ‐1 3 ‐4 4 23 7 7 8 ‐3 3 6.5 1.6 4 1.4 17.6 1.1 7 3 3.3 1.2 0.4 1.2

D NDW12‐01 105 Sediment Soil ‐1167 1053 1114 305 2592 150 3729 90 757396 5367 117 6 3.1 1.1 ‐3 2 60 4 816 12 0 0.2 23 4 17 2 70 2 ‐0.1 0.6 1.1 0.5 1.8 0.5 57.9 1.5 3 0.5 ‐0.2 0.6 1 3 ‐13 5 32 8 ‐1 8 ‐8 3 8.6 1.6 7.7 1.3 7.2 1 2 3 2.5 1.2 2.7 1.2

D NDW12‐01 110 Sediment Soil 119 892 809 256 230 106 574 57 622817 4083 33 4 2.6 0.9 1 2 32 3 282 7 0.4 0.1 29 4 11 2 22.9 1.5 ‐0.2 0.5 1.2 0.4 0.4 0.5 124 2 1.8 0.5 0.1 0.6 1 3 ‐8 4 17 7 ‐9 8 ‐2 3 7.1 1.5 4.2 1.2 4.4 0.9 1 3 2.1 1.2 2.8 1.3

D NDW12‐01 115 Sediment Soil 756 419 893 130 1104 70 433 32 172920 988 29 3 2.9 0.7 6.9 2 153 4 645 9 0.3 0.1 25 3 13 1.7 18 1.1 0.5 0.4 0.3 0.3 0.2 0.4 19.7 0.7 1.2 0.3 0.6 0.5 5 3 ‐2 4 32 6 9 7 ‐2.5 2 3.7 1.2 3.8 1 2.1 0.7 7 3 0.3 0.8 1.2 0.8

D NDW12‐01 125 Sediment Soil ‐745 1201 168 337 205 143 1813 85 841826 6481 54 6 2.5 1.2 1 3 1035 13 2490 24 0.4 0.3 7 5 17 3 ‐31.3 1.2 2.5 0.7 1.3 0.5 1.4 0.6 76.2 1.9 3.5 0.6 ‐0.2 0.7 ‐2 4 ‐14 5 26 8 17 9 ‐4 3 7 1.7 4.4 1.4 6.4 1.1 ‐8 4 4.6 1.4 3.3 1.4

D NDW12‐01 130 Sediment Soil ‐153 980 1761 291 283 119 7175 110 696043 4754 473 12 8.3 1.5 5 3 818 10 6880 39 1.7 0.4 30 4 13 2 34.3 1.7 1.1 0.8 0.8 0.5 12 0.6 113 2 19.5 0.8 0.2 0.6 1 3 0 4 20 7 2 8 0 3 7.7 1.6 3.8 1.3 27.7 1.2 1 3 5.6 1.3 2.3 1.3

D NDW12‐01 135 Sediment Soil 1688 1161 1812 337 2962 161 1374 76 904932 6401 540 12 0.9 1.3 4 3 442 7 1785 18 0.7 0.2 32 5 94 3 64 2 1.6 0.9 0.8 0.5 2.3 0.5 274 5 2.5 0.8 1.7 0.7 ‐1 3 1 5 23 8 5 9 ‐7 3 9.1 1.6 6.2 1.3 42.9 1.5 ‐5 4 5.6 1.5 1.7 1.6

D NDW12‐01 140 Sediment Soil 704 218 3213 151 ‐154 66 25445 212 7478 84 3177 32 79 3 33 4 82 4 38263 139 17.3 0.9 0 4 23 2 463 4 7 0.6 0.5 0.4 171.4 1.4 77 1.5 97.8 1.5 2.8 0.7 1 3 ‐1 4 19 6 12 7 ‐5 3 ‐1 1.4 7 1.3 1.8 1 4 3 16.9 1.4 6 1.5

D NDW12‐01 145 Sediment Soil ‐245 225 215 113 ‐98 94 32346 341 1261 63 3356 43 97 4 45 5 41 5 22527 116 7.8 0.9 ‐14 5 11 3 ‐34.3 1.4 14.5 0.9 0 0.6 207.4 2 282 5 101 2 5.3 1 ‐3 4 ‐8 5 31 9 24 10 2 3 ‐1.3 1.8 5.9 1.6 1.9 1.3 ‐37 5 15 2 2 2

D NDW12‐01 150 Sediment Soil ‐317 144 430 74 ‐61 50 30475 223 1868 46 1888 21 75 2 55 3 40 3 11556 49 2.1 0.4 16 3 10.3 1.8 274 3 4.5 0.5 0.1 0.4 133.8 1.1 65.1 1.3 61.9 1.1 2.7 0.6 3 3 ‐3 4 21 6 0 7 ‐3 2 1.4 1.3 7.4 1.1 1.5 0.8 ‐7 3 9.5 1.1 2.1 1.2

D NDW12‐01 155 Sediment Soil ‐21 171 1462 108 ‐58 59 25712 204 2944 53 3380 32 91 3 62 4 50 4 28288 105 14.8 0.7 ‐15 4 22 2 17.7 1.2 6.8 0.7 0.4 0.4 162.1 1.3 493 6 131.3 2 1.2 0.8 1 3 ‐2 4 15 6 3 7 4 2 ‐1.7 1.3 5.9 1.2 9.4 1 2 3 20.7 1.7 2 1.8

D NDW12‐01 160 Sediment Soil ‐130 164 2604 124 78 62 15820 139 3590 52 5984 46 75 3 51 4 23 3 21019 79 10 0.6 ‐11 4 125 3 93.2 1.9 14.6 0.7 1.3 0.4 80.3 0.9 320 4 147 2 2.6 0.7 2 3 ‐7 4 25 6 11 7 3 2 ‐0.8 1.3 7.5 1.2 5.5 0.9 ‐4 3 22 1.5 ‐0.2 1.4

D NDW12‐01 165 Sediment Soil ‐221 151 1275 95 ‐112 53 31912 240 2690 53 3317 30 83 3 67 3 45 3 7297 38 4.5 0.4 6 4 10 2 10.4 1.2 30.4 0.9 4.1 0.5 252.3 1.8 1067 13 119 2 2.2 0.8 3 3 ‐4 4 22 6 9 7 6 3 ‐1.3 1.5 6.6 1.2 9.1 1.1 ‐20 4 27 2 1 2

D NDW12‐01 170 Sediment Soil 563 235 5297 193 ‐171 73 27046 238 8784 99 3458 36 72 3 75 5 128 5 35078 134 15.8 0.9 30 5 24 2 407 4 5.8 0.6 0.5 0.4 164.5 1.4 145 2 118.3 1.9 2.5 0.8 3 3 6 4 31 7 ‐1 8 ‐1 3 ‐2.2 1.4 5.2 1.3 0.8 1 ‐4 3 15.5 1.5 1.9 1.5

D NDW12‐01 175 Sediment Soil 1622 325 1316 139 1742 103 21010 202 40466 317 2817 32 96 3 38 5 624 9 39723 153 15.6 0.9 75 5 29 2 244 3 2.6 0.7 0.3 0.4 101 1.1 132 2 94.9 1.7 6.2 0.8 ‐4 3 ‐2 4 32 7 0 8 11 3 1.1 1.5 3.6 1.4 15 1.1 45 3 13 1.4 3.7 1.5

D NDW12‐01 180 Sediment Soil 296 199 1968 130 ‐294 63 15834 149 2863 52 2328 27 32 3 8 4 156 5 46194 164 24 0.9 38 5 22 2 64.2 1.7 2 0.6 0.8 0.4 81.7 0.9 38.6 1 96.1 1.5 ‐0.2 0.7 0 3 ‐8 4 23 6 7 7 2 2 ‐1.5 1.3 5.1 1.2 0 0.9 16 3 10.3 1.2 ‐0.4 1.1

D NDW12‐01 185 Sediment Soil 601 222 470 111 ‐289 76 45838 359 2177 61 5406 49 106 4 86 5 140 5 50735 187 22.1 1 ‐21 5 39 2 163 3 5.7 0.7 0.3 0.4 289.7 1.9 79.7 1.6 137 2 1.9 0.8 ‐1 3 ‐10 4 30 7 ‐5 8 2 3 0.1 1.5 6.8 1.3 ‐0.3 1.1 2 4 27.3 1.7 3 1.7

D NDW12‐01 190 Sediment Soil ‐167 207 4468 178 ‐76 71 22765 210 7109 87 3680 38 65 3 56 4 90 5 22292 94 11.9 0.7 ‐14 4 97 3 577 5 5.6 0.6 0.6 0.4 174.1 1.5 57.9 1.4 166 3 1.8 0.9 0 3 2 4 22 7 1 8 ‐2 3 ‐1.7 1.4 8.8 1.4 0.8 1 ‐14 4 19.3 1.6 3.6 1.6

D NDW12‐01 195 Sediment Soil 336 199 1227 116 ‐331 66 34663 270 2211 54 4289 39 88 3 50 4 168 5 42515 152 19.8 0.9 ‐10 4 15 2 47.5 1.5 4.8 0.6 0 0.4 212.1 1.5 57.3 1.2 136.4 2 1.8 0.7 ‐3 3 ‐11 4 33 6 0 7 8 2 ‐1.2 1.4 4.6 1.2 1.2 1 8 3 22.6 1.4 ‐0.5 1.4

D NDW12‐01 200 Sediment Soil 339 186 225 88 ‐185 64 41594 312 856 49 4062 37 97 3 61 4 104 4 29138 108 13.9 0.7 ‐4 4 16.3 2 87.1 1.9 3.8 0.6 0 0.4 285.2 1.8 66 1.4 121.2 1.8 0.9 0.7 ‐3 3 ‐4 4 28 6 10 7 2 2 1.2 1.4 6.4 1.2 2.3 1 6 3 21.2 1.4 0.5 1.5

D NDW12‐01 205 Sediment Soil 79 226 1977 146 ‐309 79 44491 356 3574 70 5242 49 109 4 81 5 157 6 54053 201 25.4 1.1 ‐40 5 13 2 77.4 1.9 4.5 0.7 0.2 0.4 292.3 1.9 85.2 1.7 137 2 1 0.8 ‐4 3 ‐9 4 27 7 2 8 1 3 ‐1.8 1.5 6.4 1.3 ‐0.5 1.1 2 4 25.8 1.6 3 1.7

D NDW12‐01 210 Sediment Soil 282 189 656 99 ‐206 67 49482 365 1415 55 5518 47 124 4 88 4 147 5 26693 104 15.4 0.7 1 4 11 2 43 1.6 4.6 0.6 0.7 0.4 343 2 72 1.5 156 2 0.9 0.8 ‐1 3 ‐7 4 31 7 0 7 5 3 1.2 1.5 7.2 1.3 2 1.1 ‐11 4 30.3 1.7 3.3 1.7

D NDW12‐01 215 Sediment Soil 329 194 2348 137 ‐34 70 12323 134 2421 50 4809 45 443 6 39 5 154 5 22769 94 11.2 0.7 19 4 55 3 435 4 66.5 1.1 0.4 0.5 70.1 1 266 4 215 3 1.9 0.9 2 3 0 4 34 7 ‐8 8 ‐8 3 7.6 1.8 7.3 1.4 2.8 1 ‐5 4 18.9 1.7 4.8 1.7

D NDW12‐01 220 Sediment Soil 187 192 1008 110 ‐151 67 36498 279 1809 52 4266 39 83 3 50 4 164 5 37590 135 16.8 0.8 ‐2 4 9.6 1.9 352 4 3 0.6 0.2 0.4 249.7 1.6 30.2 0.9 132.9 1.9 1.9 0.7 0 3 ‐3 4 20 6 4 7 ‐5 3 0.7 1.4 7.1 1.2 2.6 1 6 3 20.5 1.4 ‐1.1 1.4

D NDW12‐01 225 Sediment Soil 265 159 359 76 ‐134 54 35221 252 785 42 3746 32 95 3 78 4 104 4 17159 67 7.8 0.6 14 4 11.6 1.9 39.3 1.4 3.6 0.6 ‐0.1 0.4 274.9 1.7 65.4 1.3 148 2 1.4 0.7 ‐1 3 ‐8 4 19 6 ‐2 7 5 2 1.3 1.3 8.4 1.2 1.3 0.9 ‐6 3 24.6 1.4 3.3 1.5

D NDW12‐01 230 Sediment Soil ‐153 272 1008 155 ‐391 96 54555 504 4725 94 2448 36 44 4 ‐25 5 184 7 68192 291 28.2 1.4 ‐59 6 16 3 21.7 1.8 13.4 0.9 0.5 0.6 293 2 54.9 1.6 278 4 3.3 1.2 ‐3 3 ‐6 5 35 8 12 9 10 3 ‐2.9 1.8 6.4 1.6 ‐3 1.4 1 5 43 2 8 2

D NDW12‐01 235 Sediment Soil 554 171 1232 97 ‐72 55 33736 243 2473 51 3132 29 122 3 105 4 109 4 18599 72 8.6 0.6 8 4 14.6 1.9 45.9 1.4 3.4 0.6 0.1 0.4 281 1.7 65 1.3 117.2 1.7 1.4 0.7 ‐1 3 ‐6 4 28 6 9 7 2 2 0.7 1.3 5.8 1.1 3.2 0.9 ‐7 3 19.8 1.3 0.8 1.4

D NDW12‐01 240 Sediment Soil 91 196 392 98 ‐274 70 36399 312 1414 55 4031 41 94 4 59 4 145 5 21315 92 9.8 0.7 16 5 86 3 54.3 1.9 2.9 0.6 0.1 0.5 288.1 2 47.5 1.2 152 2 1.3 0.8 0 3 ‐1 4 37 7 1 8 5 3 1.5 1.5 7.5 1.4 1.9 1.1 ‐6 4 26.7 1.6 1.7 1.6

D NDW12‐01 245 Sediment Soil 193 189 1246 113 ‐214 68 33726 262 1480 49 6324 52 85 4 78 4 143 5 34518 127 16.4 0.8 ‐12 4 280 4 152 2 3 0.6 ‐0.2 0.4 265 1.7 44.2 1.1 130.4 1.9 0.7 0.7 5 3 0 4 30 6 ‐1 7 4 3 ‐0.5 1.4 7.2 1.3 1 1 ‐5 3 23.2 1.5 1.8 1.5

D NDW12‐01 250 Sediment Soil 39 191 561 102 ‐219 68 23574 213 1348 47 3309 35 60 3 46 4 135 5 31409 124 13.9 0.8 ‐10 4 31 2 196 3 2.5 0.6 ‐0.2 0.4 188.9 1.5 47.6 1.2 118.3 1.9 0.2 0.8 ‐5 3 ‐11 4 33 7 ‐8 8 6 3 0.2 1.5 5.7 1.3 2.6 1 ‐6 4 19.3 1.5 3.4 1.5

D NDW12‐01 255 Sediment Soil 587 221 519 114 ‐13 79 29755 249 2016 53 5121 47 90 4 58 5 249 6 60069 217 28.3 1.1 ‐40 5 40 2 315 4 2 0.6 0.5 0.4 211.5 1.6 47.9 1.2 179 3 0.8 0.8 0 3 0 4 36 6 7 7 1 3 ‐1.1 1.4 5.8 1.3 ‐0.3 1.1 13 4 21.4 1.5 1.5 1.5

D NDW12‐01 260 Sediment Soil 135 173 350 85 ‐50 64 31505 246 1480 48 5118 43 106 3 82 4 209 5 21160 84 8.9 0.6 ‐1 4 19 2 205 3 3.7 0.6 ‐0.6 0.4 267.4 1.7 104.5 1.9 163 2 2.7 0.8 0 3 ‐3 4 30 6 8 7 3 3 0.2 1.4 7.2 1.3 1.6 1 ‐16 4 29.5 1.6 3.7 1.6

D NDW12‐01 265 Sediment Soil ‐141 186 948 109 980 88 33103 267 1579 51 7228 59 102 4 83 5 343 6 30409 118 14.5 0.8 ‐17 4 162 3 292 3 2.9 0.7 0.1 0.4 258.4 1.8 117 2 148 2 0.7 0.8 2 3 ‐9 4 34 7 ‐5 7 4 3 ‐0.4 1.4 7.1 1.3 7.6 1.1 ‐3 4 28.9 1.7 3.3 1.7

D NDW12‐01 270 Sediment Soil 209 169 216 80 ‐101 60 32300 241 1257 45 4464 38 104 3 81 4 579 7 24940 93 8.5 0.7 14 4 31 2 76.6 1.7 3.7 0.6 0.1 0.4 244.8 1.6 127 2 144.2 2 0.8 0.7 0 3 2 4 36 6 6 7 5 2 ‐0.3 1.3 5.9 1.2 7.6 1 0 3 28.4 1.5 0.9 1.5

D NDW12‐01 275 Sediment Soil 13 146 332 72 ‐93 52 28150 206 510 37 4264 35 89 3 87 4 405 6 15392 60 7.8 0.5 19 4 40 2 127 2 10.3 0.7 0.6 0.4 204.7 1.4 140 2 154 2 1.2 0.7 3 2 ‐5 3 25 6 ‐5 6 1 2 1.8 1.3 7.4 1.1 9.8 1 2 3 23.9 1.4 4.9 1.4

D NDW12‐01 280 Sediment Soil ‐548 182 96 87 ‐85 80 31038 307 1257 58 3976 45 108 4 96 5 92 5 6923 43 3.3 0.4 32 5 17 2 160 3 3.6 0.8 0.5 0.5 258 2 191 3 123 2 1.6 0.9 5 3 ‐3 5 33 8 9 9 ‐4 3 5.1 1.7 8 1.5 17.6 1.4 ‐26 4 30.9 2 8 2

D NDW12‐01 285 Sediment Soil 608 306 894 173 995 128 26059 267 1098 55 7756 78 107 5 56 7 3403 32 166558 652 36 2 ‐73 7 ‐3 3 517 5 14 1.1 ‐0.1 0.5 128.3 1.4 217 4 123 2 3 0.9 ‐3 3 ‐5 4 37 7 17 8 9 4 ‐11.2 1.8 3.9 1.8 ‐4.8 1.9 22 4 26.1 1.9 0.7 1.8

D NDW12‐01 290 Sediment Soil 52 162 360 80 ‐105 60 33240 245 1246 45 5852 46 132 3 133 4 546 7 19473 75 9.5 0.6 14 4 31 2 1343 7 4.3 0.8 1.4 0.4 245.1 1.6 290 4 152 2 0.4 0.7 2 2 ‐5 4 28 6 12 7 ‐22 3 2.6 1.4 14 1.4 32.6 1.3 2 3 31.9 1.6 0.9 1.6

D NDW12‐01 295 Sediment Soil 166 277 142 140 ‐633 103 33893 358 768 61 5782 66 113 5 67 7 61 7 62559 292 21.9 1.4 ‐46 6 3 3 22 2 5.5 1 ‐0.7 0.6 217 2 251 5 128 3 3.3 1.1 ‐1 4 ‐6 6 31 9 8 10 2 3 ‐2.2 1.9 7.8 1.7 23.1 1.7 ‐15 5 30 2 8 2

D NDW12‐01 300 Sediment Soil 319 192 476 98 ‐250 71 28333 239 665 44 7148 59 112 4 85 5 55 4 30700 119 14.5 0.8 ‐26 4 55 3 95 2 3.7 0.8 ‐1 0.4 201 1.5 295 4 166 2 0.9 0.8 4 3 1 4 36 7 ‐6 7 4 3 1.3 1.5 5.3 1.3 30 1.3 ‐10 4 27.9 1.8 3.8 1.8

D NDW12‐01 305 Sediment Soil 675 260 993 146 330 104 21254 229 826 50 5268 57 93 4 55 6 101 6 89470 384 25.1 1.6 ‐97 6 0 3 148 3 4.5 1 ‐0.6 0.6 127.6 1.5 231 4 361 6 4.1 1.3 6 3 ‐1 5 29 8 20 9 0 3 ‐4 1.8 2.9 1.6 15.3 1.6 ‐13 5 22 2 3 2

D NDW12‐01 310 Sediment Soil 131 192 184 93 ‐359 71 24012 216 838 44 7218 61 118 4 100 5 60 5 32603 130 13.9 0.9 ‐22 4 7 2 58.1 1.8 5.1 0.9 0.8 0.5 170.2 1.5 379 5 216 3 3.4 1 0 3 ‐4 4 31 7 ‐3 8 5 3 ‐0.4 1.5 6.8 1.4 31.7 1.4 ‐19 4 39 2 4 1.9

D NDW12‐01 315 Sediment Soil 76 183 216 86 ‐220 68 35951 292 1646 54 5922 52 119 4 133 5 77 4 20188 84 9.9 0.7 24 4 9 2 92 2 5.5 0.9 1 0.5 225.7 1.7 644 8 214 3 1.8 0.9 7 3 ‐11 4 35 7 ‐4 7 7 3 ‐0.1 1.5 4.9 1.3 33.9 1.4 ‐12 4 39 2 5 2

D NDW12‐01 317.18 Sediment Soil 168 162 278 79 ‐60 57 16850 146 694 35 3656 33 78 3 151 5 23 4 31259 115 14 0.8 ‐33 4 68 2 158 2 3.1 0.7 ‐0.3 0.4 95.9 1 491 6 478 6 ‐0.4 1.1 2 3 ‐6 4 20 6 2 7 3 2 ‐2.2 1.4 3.6 1.2 20.9 1.2 0 4 29.1 2 6.8 1.8

D NDW12‐01 260.4 Sulphide Soil 33781 2372 626151 13945 3356 646 9107 328 3090 155 5784 168 ‐43 14 ‐48 25 120 26 827581 7021 215 10 ‐929 35 334445 2836 237 54 ‐71 5 0 2 65 3 30 2 31 2 25.8 1.8 ‐16 7 ‐27 11 190 20 23 22 5 14 ‐6 6 ‐40 7 237 9 ‐9 14 ‐11 5 ‐28 4

D NDW12‐01 260.4 Sulphide Mining 1653.4 0 0 0 0 0 0 0 219009 0 791.6 0 0 0 198986 0 217.9 0 0 0 19.1 0 0 0 0 0 358 0 548.6 0 778.7 0 0 0 22.2 0 23.7 0

D NDW12‐01 307.3 Sulphide Soil 22407 1541 728663 10760 ‐1685 396 2794 130 3036 99 702 56 ‐115 7 ‐227 14 2094 38 939822 6842 137 9 ‐631 26 ‐77 7 409 9 521 7 2.1 1.6 ‐21 2 19.2 1.9 22.9 1.7 113 4 0 6 ‐19 9 42 15 23 17 ‐3 10 ‐44 7 ‐23 5 ‐23 8 65 9 ‐6 3 ‐21 3

EOF

Appendix 9

DR B.J. BARRON Petrologist ABN: 49 121 890 594

7 Fairview Avenue ST IVES NSW 2075

AUSTRALIA Tel/Fax: (02) 9449.5839

e-mail: [email protected]

Our ref: N11/12/1708

Your ref: Email 19 June 2012.

Detailed petrological examination of four drill core samples

from a stratigraphic drill hole near Daly Waters NT.

Report No: N11/12/1708 29 July, 2012

For: NRE Operations Pty Ltd

Dr B.J. Barron

Consulting Petrologist

mailto:[email protected]

Sample No. NDW12-01 138.38m

Rock Type Deposit of (?hydrothermal) carbonate (mainly calcite)

comprising poorly defined subparallel layers of undeformed

partly clouded crystals of variable grain size. Accessory

pyrite is present.

Hand Specimen A compact (non-friable) fine grained mid grey (-brown) drill

core sample containing some moderately coarse grains that are well cleaved. The

sample is spongy containing 10% to 20% of small voids. In some domains these occur

in subparallel narrow layers. The sample reacts strongly with cold dilute HCl indicating

abundant calcite.

Thin Section This sample is a deposit of undeformed (?hydrothermal)

carbonate (mainly calcite – see reaction with cold dilute HCl above). The rock is almost

monomineralic and comprises poorly defined subparallel layers of partly clouded

crystals with a variable grain size from less than 0.2 mm (fine sand size) up to crystals

that are optically continuous and more than 4 mm long. An average grain size is about 1

mm.

The carbonate grains mainly have irregular shapes and are

mutually interlocking. The rock contains about 20% of small voids, many of which

show subhedral projections of calcite crystals into the voids. Some carbonate crystals

may comprise two types of carbonate, since coarse host crystals contain abundant

inclusions of a fine grained ?second carbonate with subhedral rhombic shapes

suggesting ?dolomite (or ankerite etc.).

In some elongate interstitial domains are patches of pale

brown, strongly clouded carbonate that could represent an iron-bearing carbonate. This

carbonate is present only in accessory proportions.

The rock is cut by numerous very narrow (less than 0.2 mm

across), subparallel but branching veinlets of late carbonate that is clear of dusty

inclusions. These carbonate veinlets are subparallel to the poorly defined layering.

NRE Operations Pty Ltd Dr B.J. Barron

Jul-12 Petrologist

Small spongy and irregular opaque deposits (rarely more

than 1 cm long) also are accessory. Examination in reflected light suggests they are

possibly ?pyrite. Some penetrate along branching mutual grain boundaries and fractures

in the carbonate.

This sample may be identified as a deposit of

(?hydrothermal) carbonate (mainly calcite) comprising poorly defined subparallel layers

of undeformed partly clouded crystals of variable grain size. Accessory pyrite is present.


Rock Type Extremely fine grained calcite-rich ?calcrete containing

poorly defined irregular outlines of angular lithic fragments.

It most likely represents a deposit of exceptionally fine

grained, reworked (?aeolian) and recrystallised microfossil

clasts.

HandSpecimen A compact (non-friable) fine grained, mottled pale grey and

very pale grey sample, in which pale grey material could represent ?irregular fragments.

Some of the latter could contain very fine sand sized ?clasts. Both fractions react very

strongly with cold dilute HCl indicating calcite.

Thin Section This sample has undertone intense, extremely fine grained

alteration to almost monomineralic carbonate. The carbonate is calcite (see strong

reaction with cold dilute HCl above), which has an average grain size of about 0.03 mm.

Nevertheless, there are poorly preserved outlines of possible lithic fragments that have a

variable size, and reflect those defined in the hand specimen. The largest of these in the

present section reaches nearly 4 mm long.

Although the fragments are now exceptionally fine grained

calcite, they also contain irregularly disseminated, very fine grained (rarely more than

0.02 mm) translucent to near opaque granules that partly define abundant rounded and


Jul-12 Petrologist

cuspate small shapes (mainly less than 0.05 mm) that could represent broken

?microfossil remains.

The rock contains small patches (mainly less than 1 mm

across) of poorly crystallised subradial chalcedony. Some patches are intergrown with

minor cherty quartz. Most are also intergrown with small patches of fine grained

carbonate. Sparse voids and veinlets are partly coated with translucent red-brown

hematite and are partly filled with coarser grained granular carbonate. This reaches 0.6

mm grain size in the present section.

This sample most likely represents a deposit of exceptionally

fine grained, reworked (?aeolian) and recrystallised microfossil clasts and may be

identified as extremely fine grained calcite-rich calcrete containing poorly defined

irregular outlines of angular lithic fragments.


Rock Type Exceptionally fine grained claystone deposit with

compaction layering. Dusty oxides once could have been

iron-bearing carbonate. It is most likely a shallow lake

deposit.

Hand Specimen A friable, mid red-brown ?hematite-rich finely laminated

sample, containing sparsely disseminated small pale grey spots. These are less than 1

mm diameter. The sample lacks reaction with cold dilute HCl and therefore lacks

calcite. The sample is not magnetic.

Thin Section This sample is a deposit of finely laminated ?compaction

foliated claystone that is crowded with small opaque ?oxide granules and partly stained

by red-brown hematite dust. It comprises almost equally abundant lensed narrow

domains, some of which have irregular shapes and reach more than 5 mm long but only

0.5 mm thick, of very fine grained low birefringent clay ± birefringent ?smectite clay

that is little-stained by patchy red-brown hematite. The elongate lensed domains are set


Jul-12 Petrologist

in host rock that is also clay-rich (possibly mainly smectite clay), stained by red-brown

hematite dust. The latter contain relatively more abundant opaque granules.

Also present are sparse elongate „spots‟ of clouded

birefringent clay, some of which have subhedral shapes and may replace crystal sites.

These domains also contain relatively few opaque granules compared with the host

rock.

The sample contains sparse subhedral opaque ?oxide crystal

sites up to about 0.2 mm that account for about 3% to 5% of the present section area.

Very rare small angular grains (mainly less than 0.06 mm grain size) are quartz. These

are present only in one domain and may be secondary.

This rock lacks recognisable relict texture but is not a normal

sediment. It could represent an exceptionally fine grained claystone deposit with

compaction layering. Dusty oxides once could have been iron-bearing carbonate. It is

most likely a shallow lake deposit.

Sample No. NDW12-01 262m

Rock Type Fine grained, very finely laminated sparsely silty claystone.

The sample contains a structure interpreted as a micro-

?worm burrow.

Hand Specimen A fine grained, very finely laminated mid-grey, fairly

compact (not friable) drill core sample, containing visible small reflective ?detrital mica

flakes parallel to layering (?bedding).

ThinSection Unlike the previous sample, the present rock retains a clear

clastic sedimentary texture and is sparsely silty claystone.

Silt sized (<0.05mm) detritus is angular and dominated by

thin mica flakes, a few of which are bent and deformed. Angular quartz is slightly


Jul-12 Petrologist

subordinate. The detritus accounts for less than 10% of the present section area, and has

a somewhat patchy distribution.

Mica flakes are strictly parallel to a compaction foliation and

mainly are less than 0.15 mm long but less than 0.01 mm thick. They are dominated by

birefringent ?„sericite‟ and few are pale brown to almost colourless pleochroic micas

that are most likely degraded biotite. Also present are sparse similar sized thin

carbonaceous flakes.

The micas account for about 5% to 7% of the section area.

Accessory detritus comprises mid green tourmaline, small green chlorite flakes, apatite,

zircon and small opaque oxide grains.

The recognisable fine grained detritus is set throughout an

abundant rock matrix of very fine grained wispy birefringent ?‟illite-smectite‟ clay,

wispy flakes of which rarely exceed 0.03 mm long. The abundant flakes define a

?compaction foliation direction and are subparallel to the larger wispy detrital mica

flakes.

A disrupted irregular domain more than 3 mm long and up to

0.5 mm across, is oriented normal to the layering. This could represent a micro- ?worm

burrow. Several of these structures are present.

This sample may be identified as fine grained, very finely

laminated sparsely silty claystone. The sample contains a structure interpreted as a

micro- ?worm burrow.


Jul-12 Petrologist

Appendix 10

Zonge Engineering and Research Organization (Australia) Pty Ltd

Daly Waters

Mise-a-la-masse and

Down-Hole Transient Electromagnetic

Surveys

Logistics Report

for

NRE Operations

Compiled by:

S.Mann

Report No: 967 Date : June 2012

Zonge Engineering & Research Organization (Australia) Pty Ltd

39 Raglan Avenue Edwardstown SA 5039

Tel +61 8 83710020 Fax +61 8 83710080

CONTENTS

1. SUMMARY.................................................................................................................. 1

2. INSTRUMENTATION and SURVEY PARAMETERS ............................................. 2

3. PRODUCTION ISSUES .............................................................................................. 4

4. PRODUCTION SUMMARY ....................................................................................... 4

5. DATA PROCESSING.................................................................................................. 5

6. EXPLANATION OF FILES ........................................................................................ 6

TABLES

Table 1 Job 967 Data Summary .......................................................................................... 3

APPENDICES

APPENDIX I

Job 967 Summary

APPENDIX II

Plots of DHEM data and “surface” resistivity inversion model

APPENDIX III

Plots of MALM data

APPENDIX IV

Plots of coincident loop sounding resistivity inversion model

1. SUMMARY

In May and June 2012, Zonge Engineering and Research Organization (Zonge) mobilised

a two-person geophysical field crew to the Daly Waters Prospect in the Northern Territory

to conduct Down-Hole Induced Polarisation (DHIP) and Down-Hole ElectroMagnetic

(DHEM) surveys for NRE Operations.

The crew initially mobilised on the 25th

of May however due to drilling on hole NDW12-

01 not being completed the crew demobilised on the 30th

of May back to Adelaide. The

crew re-mobilised on the 10th

of June and completed DHEM, Mise-a-la-masse (MALM)

and coincident loop EM surveying before final demobilisation on the 16th

of June. Much

of the DHEM and all of the DHIP surveying planned could not be performed due to the

hole being blocked by abandoned drill string at approximately 156m from surface.

Survey planning and interpretation of data was performed by David Tucker of Gawler

Geoscience.

Data quality and repeatability were monitored throughout the course of the survey which

ensured that the best possible data were acquired given local conditions and time

constraints.

1

2. INSTRUMENTATION and SURVEY PARAMETERS

A Zonge multipurpose GDP-32II

receiver was used to take all of the MALM data for this

project. MALM data were recorded in pole-pole mode using non-polarisable porous pots

filled with copper sulphate as receiver electrodes. Data were acquired in time domain at a

frequency of 0.125hz allowing acquisition of potential voltage (Vp), self-potential (SP)

and chargeability (Mx).

MALM transmitted fields were generated with a Zonge ZT-30 geophysical transmitter

connected to electrodes on the surface some distance from the hole and the second placed

down the hole at approximately 156m from surface. Synchronisation was controlled via a

Zonge XMT-32 transmitter controller.

An EMIT Smartem V receiver and controller were used to acquire data and control the

Zonge ZT-30 transmitter respectively for the DHEM and EM sounding acquisition. For

DHEM acquisition a Geonics BH43-3D coil probe was used with data recorded on each

X, Y and Z components at a frequency of 2.083 Hz. Readings were taken at 5 metre

intervals between 2-152 metres from surface. Source fields were produced using a 2-turn

200x200 metre transmitter loop. Coincident loop EM soundings were acquired at two locations separated by 200 metres

near NDW12-01. Readings were taken using a 1.25 Hz frequency using a single turn 200

metre transmitter and receiver loop.

The raw data from each day was downloaded every evening from the receiver's internal

memory to a laptop computer before being sent to Zonge‟s Adelaide office. Final

processing, plotting and modelling were completed in Zonge's Adelaide office.

2

Table 1 Job 967 Data Summary

Method

Line

Start

station local

Finish

station local

Start station UTM

mE/mN

Finish station UTM

mE/mN

Station Spacing

(m)

Number

of Stations

Line/Hole length**

Line

Completion Date

Coincident loop EM

‐

324350

326350

326477/8206235

326289/8206165

200

2

200m

12/06/2012

DHEM

NDW12

‐01

2m

152m

XCOLLAR:327000.0 YCOLLAR:8204913.0

ZCOLLAR:212.0 2m

XCOLLAR:327000.0 YCOLLAR:8204913.0

ZCOLLAR:212.0 152m

5m

31

152m

14/06/2012

MALM

3

400

0

327200/8205040

326800/8205040

40

11

400

15/06/2012

MALM

4

400

0

327200/8205000

326800/8205000

40

11

400

15/06/2012

MALM

5

400

0

327200/8204960

326800/8204960

40

11

400

14/06/2012

MALM

6

400

0

327200/8204920

326800/8204920

40

11

400

14/06/2012

MALM

7

400

0

327200/8204880

326800/8204880

40

11

400

15/06/2012

MALM

8

400

0

327200/8204840

326800/8204840

40

11

400

15/06/2012

MALM

9

400

0

327200/8204800

326800/8204800

40

11

400

15/06/2012

3

3. PRODUCTION ISSUES

Substantial delays occurred during the survey due to delays in the completion and casing

of the hole, during this time the crew were on standby. The planned down-hole surveying

was only possible to a limited degree due to the reduced access resulting from the stuck

drill string from 156 metres and below.

As a result of the limited opportunity for down-hole surveying alternative techniques to

better utilise the hole and understand subsurface electrical structure were performed.

No safety related incidents occurred during completion of the survey. Detailed information on daily production may be found on the accompanying disc under

"Production Reports". Additional information about safety issues may be found on the

same disc under "Safety _Documentation".

4. PRODUCTION SUMMARY

Appendix I provides a Summary of the Production of Job 967. More detailed information

on daily production may be found on the accompanying disc under "Production Reports".

4

5. DATA PROCESSING

The quality of each block of raw DHEM, MALM and MLEM data was examined before

being averaged to create a single record for each receiving station. Data points that were

considered of poor quality were skipped before averaging each station‟s data.

DHEM data were edited and reviewed using EMIT‟s Agent99 software before primary

field rotations to produce rotation corrected A, U and V components for output. Resulting

rotated A, U, V data are presented in Apendix II where both log and linear signal

magnitude scales are presented. A single resistivity sounding inversion model of vertical

component (A/Z) coil data was performed on data acquired at 2m below surface in

NDW12-01 as a proxy surface in-loop reading. It should be noted however that the

proximity of the 4x4 vehicle and winch used in surveying may have had an undesired

effect on this sounding and resulting modelled resistivities.

Mise-a-la-masse data were edited as per above and imported into an excel spreadsheet

(NDW12-MALM.xlsx) within which the apparent resistivities were calculated. Apparent

resistivity calculations were performed assuming a point source at 156 metres down-hole,

the coordinates of the remote transmitter and receiver electrodes were taken into account

in the apparent resistivity calculations. The location of the remote transmitter and receiver

electrodes are recorded in the 967_MALM.stn file accompanying this report.

Chargeability values are “Newmont Chargeability” values recorded by the GDP receiver

and reflect an integration of decay window magnitudes over the 450-1100ms after

transmitter turnoff. Potential voltage and self potential values as plotted in Appendix III

are averages of those recorded by the receiver.

Coincident loop EM data were reviewed using EMIT‟s Agent99 software before being

output and imported into Zonge‟s STEMINV software for 1D inversion. 1D resistivity

sounding profiles over depth are presented in Appendix IV. It is possible that the

remarkably low resistivities modelled for sounding 324350 are the result of SPM effects

commonly seen in coincident loop EM data.

All raw and processed data, location data and documents associated with this survey are

presented on the accompanying disc.

5

6. EXPLANATION OF FILES

Digital data is provided on CD along with paper plots of the data. Data from each surveyed line are placed

in the following directory structure on the accompanying CD: Processed_Data\line#. File formats

are explained below:

*.PDF Adobe Acrobat Portable Document File containing plot files and report

*.DAT Edited and averaged IP and resistivity data from TQIP software; Data from

SmarTem receiver

*.RAW the edited raw data downloaded from the GDP-32ii

*.MDB TQIP database containing IP data

*.KML Google Earth coordinate file

*.STN Station coordinate file

*.PNG Graphic plot of resulting data

6

APPENDIX I Job

967 Summary

Prod Hours Misc Hours Equipment Hire

2

(2

(2

(2

Z

on

ge

Mobilisation from Adelaide to Alice Springs - Collect Gear.

Mobilisation from Alice Springs to Tennant Creek

Crew mobe to Daly aters - Standby.

Crew initial site recon, grid out Misse A La Masse survey.

Crew initial site recon, grid out Misse A La Masse survey.

Pack up and drive to Tennant Creek.

Drive Tennant Creek to Alice Springs, store and freight equipment

Travel Alice Springs to Adelaide

Travel Adelaide to Daly aters

Standby due to blocked hole

Set up EM loop

Taking data 12-01

Taking data 12-01

Taking data 12-01

De-mobe from Daly aters to Darwin

Freight equipment - De-mobe to Adelaide

TOTAL

2

(2

(2

(2

Sub

Rate

Billable

Zonge Engineering & Research Organization (Aust) Pty Ltd JOB HOURS SUMMARY

Job No.:

Client:

Project Name: Summary Sheet:

967

NRE Operations

Daly Waters

1 of 1

Date:

By:

25th May, 2012

L McDonald / L Hennessy

24/06/2012

APPENDIX II

Plots of DHEM data and “surface” resistivity inversion model

Kaw A

+-e--+-&-- +-e--+-&-- +-e--+-&-- +-e--+-+-e-- +-e--+-+-e-- 30 40 50 60 70 75 80 85 90 95

1000000-r----r--- ----.----,----,----,----.-----.----r----r----.----.----,----,----,----.-----.----r----r--- ----.----,----,----.----.----..---.-----r----.----r-----

100000

2. 1000

100

10

0.1 0

·0.1

Depth (metres)

Raw U Component

125 130 135 140 146 150

10 -;---,;---,--- ----.----.---,----.--- ----.----.---;----;----;----;----.---,----;----;----;----;---;----;----;----;----.---.----.----;---,;---,----

-

100

10+-+ 1----+

0

-0.1

-1 +-;<:== 10

-100

-

·10000--+-e--+-e--+--+-e+ -++ --+ --+-e--+-e--+-e--+-e--+--++ --+ --+-e--+-e--+-e--+-e--+--++ -++ --+-e--+-e--+-e---

0 10 15 20 25 30 35 40 50 55 60 70 75 80 85 Depth (metres)

90 95 100 105 110 115 120 125 130 135 140 146 150

Kaw A

0 10 15 20 25 30 35 40 50 60 70 75 80 85

Depth (metres) 90 95 100 105 110 115 120 125 130 135 140 146 150

A

"'

"'

200000

15000

:>= 2- 100000 c: 0

5oooo Q)

0:

as 0

-50000

0 5 10 15 20 25 30 35 40 46 50 55 60 65 70 75 80 85 Depth (metres)

90 95 100 105 110 115 120 125 130 135 140 146 150

Raw UComponent

4000

-:> 2- Q)

"c:' a. Q)

0:

2000

0

,:::;;:::_

/"---.. /

5-"

:r- - -

::;: -2000 v

w

-4000 St

0 5 10 15 20 25 30 35 40 46 50 55 60 65 70 75 80 85 Depth (metres)

Raw VComponent

1000

90 95 100 105 110 115 120 125 130 135 140 146 150

-:> 2- 0

/"'-.....

"'-----r-/ / :::;

·---.- - Q)

"c:' """ / v v.a

-,

-.

:

0 a. Q)

0: ::;: w

-1000 I "

/ ;--::.

-2000

0 5 10 15 20 25 30 35 40 46 50 55 60 65 70 75 80 85 Depth (metres)

90 95 100 105 110 115 120 125 130 135 140 146 150

-

DHEM "Surface" model resistivities

0.00

·100.00

·200.00

·300.00

·400.00

·500.00

·600.00

APPENDIX III

Plots of MALM data

8207000

8206500

8206000

8205500

8205000

8204500

8204000

8203500

213.5

212.5

211.5

210.5

209.5

208.5

207.5

206.5

205.5

204.5

203.5

SRTM Elevations

325500 326000 326500 327000 327500 328000

327050 327100 3271 327200

327050 327100 327150 327200

2

-5

----0

25 50 75

metres

Mise-a-la-masse Survey

Hole NDW12-01: Potential Voltage Data (mV)

by Zonge Engineering Australia June 2012

327100 3271 327200

326800 326850 326900 326950 327050 327100 327150 327200

2.877 4.487 6.301 8.226 10.522 14.412 23.768

2

-5

----0

25 50

metres

I I I I II Mise-a-la-masse Survey

75 Hole NDW12-01: Apparent Resistivity Data (Ohm/m)


326850 326950 3271 327200

326800 326850 326900 326950 000

6.443 7.627 8.464 9.221 10.049 12.365 17.552

2

-5

----0

25 50 75

metres


Hole NDW12-01: Newmont Chargeability Data (ms)


326850 326950 327200

1;;E

2

-5

----0

25 50 75

metres


Hole NDW12-01: Self Potential Data (mV)


APPENDIX IV

Plots of coincident loop sounding resistivity inversion model

e

; (

I

/ I / "" I

- sta tio ,324350 Model

! \ Resis ivites

,!:

- sta tio 1 326350 Model

Resiti ities

'1\

\ \

1\

Apparent ResJ.st•vlty

Appendix 11

Downhole Geophysics in Drillhole NSW12-01

June 2012

CHARACTERISTICS AND INTERPRETATION OF DOWNHOLE GEOPHYSICS AT

DRILLHOLE NDW12-01 DALY WATERS PROJECT NORTHERN TERRITORY EL27878

MAY-JUNE 2012

Figure 1: Location of drillhole NDW12-01 Daly Waters (after Steve Cooper).

Prepared by Gawler Geoscience for

Natural Resources Exploration Operations Pty Ltd

Author:

David H Tucker PhD, MAusIMM, MASEG, MGSA

Effective Date: 27 June 2012

Gawler Geoscience Report Number: NRE_DHT_0301

Gawler Geoscience Report Date: 27 June 2012

1:250,000 Sheet Name: Daly Waters

1:250,000 Sheet Number: SE53-01

Title: EL27878

Author: Dr David H Tucker

Page 1 of 30


June 2012

1. Executive Summary A downhole geophysics program was undertaken in drillhole NDW12-01 by Zonge

Engineering Pty Ltd (Zonge) for NRE Operations Pty Ltd (NRE) from 27 May 27 to 16 June

16 2012. The geophysics program was supervised by Dr David H Tucker of Gawler

Geoscience (Geoscience).

The aim of the program was twofold:

1. To measure electrical characteristics of the geological section, and

2. To search around the hole for conductive and chargeable mineralisation.

The geophysics was undertaken within the Geophysics and Drilling Collaborations program.

Table 1: Summary of geophysical methods used and interpretation.

Geophysical Method

Outcome

Interpretation

Induced Polarisation dipole-dipole array in hole (1 metre electrode spacings).

Not conducted. Open hole situation water filled situation not available (lined with PVC pipe)

n.a.

Induced Polarisation Mise-a-la- masse with excitation point downhole.

Conducted. Electrode located at

156m at bottom of PVC in available part of drillhole (sulphides recognised in drill core at approx 183 and approx 240 metres depth were not directly accessible).

A Chargeable conducting zone lies in northwest of gridded area. Not closed by survey. Source estimated to lie approx 150+ metres. Possible disseminated sulphides. Also SP indicates sinuous anomalies interpreted as shallow channels less than 50 metres deep.

TEM in hole with multiple surface loops used for excitation.

Conducted. Twin 200 m loop used: and 2m -152 m of hole successfully surveyed at 5 metre stations

Flat response. No off-hole conductors recognised. Sounding models indicate 1-D geo-electric section of: from surface Apparent Resistivities of approx 10-20 Ohm.metres, rising to approx 500

Ohm.metres at approx 140 metres depth. Then falling off with

increasing depth.

TEM remote from hole for reference purposes.

Conducted. 200m coincident loops. Two stations observed, edge on edge.

Sounding models indicate 1-D geo- electric section of: from surface Apparent Resistivities of approx 40- 50 Ohm.metres, rising to approx 160 Ohm.metres at approx 230

metres depth. Then falling off with increasing depth.

The hole was drilled with HQ rods to 317.2 metres depth by Drillwise Pty Ltd (Drillwise). A

complete HQ drill string was abandoned in the hole from approximately 167.1 metres to TD.

PVC was run for 156 metres and only this upper section was open geophysics probes.

There was a blockage to probes below this.

A Mise a la masse IP survey was conducted on a grid 400 metres East-west by 160 metres

North-south. There was no sulphide zone directly accessible, therefore an excitation

electrode for the work was located at 156 metres in NDW12-01 at the bottom of the hole as

only option. The remote current and receiver electrodes were located approximately 650

Page 2 of 30


June 2012

metres to the South and to the North respectively. Voltage and induced polarisation

measurements were made on a grid with stations 40 metres apart.

Anomalous IP results were recorded in Self potential, Voltages, Apparent Chargeability and

are evident in Apparent Resistivity estimates calculated from the values. There are two kinds

of anomaly patterns: those detected by Self Potential are sinuous and reminiscent of

channels in sediments; those detected in Apparent Chargeability, Voltages and Apparent

Resistivity are more elliptical in character and are not closed off in the North. Both kinds

extend at least 200 metres past the drillhole and out of the surveyed area.

The depth to the sources of the sinuous anomalies is estimated at less than 50 metres.

Sources may be sulphides or more likely clays in shallow channels.

The depth to the more elliptical anomalies is estimated at 150+ meters. The geological

source of the anomalies is not known. The source is likely to be disseminated sulphides.

Both kinds should be followed up.

Downhole TEM readings were acquired at 5 metre depth intervals from 2 to 152 metres

using an energised dual 200 metre square loop centred over the drill collar.

Results indicate that the downhole TEM survey did not detect significant conducting bodies

either intersecting the drillhole, or within the reach of the excitation footprint of the 200 metre

loop. It is believed that this footprint amounts approximately to a cylinder of rock 200 metres

across and extending from the surface to 150 metres.

The abandoned drill rods which lie in the hole approximately 10-15 metres directly below the

deepest station with the TEM probe were not clearly detected, probably because of poor

coupling. Their influence appears to be weak.

The implication for exploration of the TEM results available from this survey is that bothe IP

and TEM electrical geophysics methods could be useful for deep exploration for conductive

ore-bodies in this area. For this purpose, large loops and high current strengths and large

dipoles and high currents should be considered.

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June 2012

Table of Contents

1. Executive Summary........................................................................................... 2

2. Introduction........................................................................................................ 7

3. Drillhole Characteristics ................................................................................... 8

4. Regional Context ............................................................................................... 9

5. Transient Electromagnetic Survey ................................................................. 10

5.1. Equipment and layout for downhole TEM survey............................................. 10

5.2. Results and interpretation for downhole TEM .................................................. 15

5.3. Moving loops layout for surface TEM sounding survey .................................. 20

5.4. Results and interpretation for surface TEM sounding survey ......................... 20

6. Induced Polarisation survey ........................................................................... 22

6.1. Equipment and layout......................................................................................... 22

6.2. IP Results and interpretation ............................................................................. 26

7. Conclusions and Recommendations............................................................. 29

8. Bibliography..................................................................................................... 30

List of Figures

Figure 1: Location of drillhole NDW12-01 Daly Waters (after Steve Cooper)......................... 1

Figure 2: Daly Waters geophysics location grid reference map for both IP Mise-a-la-masse

and Downhole TEM survey and TEM sounding survey. GDA 94 (map modified after

Mann, 2012)................................................................................................................... 7

Figure 3: Schematic diagram of downhole TEM receiver setup. The probe is overall 2.4

metres long, the bottom part comprising a solid weight. The sensor is located mid

length........................................................................................................................... 11

Figure 4: TEM Transmitter site, operator with equipment including insulated cables in

foreground, connected to the 200m square loop. ......................................................... 12

Figure 5: Live wire warning sign; generator and transmitter located 25 metres down the road.

.................................................................................................................................... 12

Figure 6: Zonge ZT-30 TEM Transmitter indicates 120.1 volts at 0.56 amperes is being fed

into the loop. ................................................................................................................ 13

Figure 7: TEM Receiver layout (refer to the previous schematic diagram); note tripod directly

over PVC protruding from drillhole; 4 conductor cable extends across to winch on back

of truck; receiving equipment is located beside truck on right....................................... 13

Figure 8: Connecting TEM probe sections; winch on truck at left. Geophysicist holding

vertical probe has a gas burner in his right hand and is heating black shrink wrap over

screwed joints to minimise water entry and unravelling in operation............................. 14

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June 2012

Figure 9: Complete TEM receiver probe: Geonics BH43-3D. .............................................. 14

Figure 10: EMIT Smartem V receiver and Zonge controller in operation to acquire data,

connected to the downhole TEM probe via the winch cable. ........................................ 15

Figure 11: TEM results for A, U and V components. Vertical scale units are microvolts per

ampere and horizontal scale units are metres. ............................................................. 16

Figure 12: DHEM 2 metres. Decay curve for channels 1-33 Time constant fit over early

channels 2 to 7 i.e. within the red lines (Tau= 0.11ms)................................................. 17

Figure 13: DHEM 2 metres. Decay curves channels 1-33. Power curve fit for channels 7-

21 (Power = -2.72). .................................................................................................. 17

Figure 14: DHEM 2metres. Decay curves for Channels 1-33. Power curve fit for channels

23-33 (power = -0.90). ................................................................................................. 18

Figure 15: DHEM 2 metres. Decay curves for channels 1-33. Alternative Time constant

curve fit for channels 23-33 (Tau=44.6ms). .................................................................. 18

Figure 16: DHEM NDW12-01 surface model resistivities (after Zonge). One dimensional

section is shown alongside. Note that the part below the abandoned drill rods may be

unreliable. .................................................................................................................... 19

Figure 17: 1-D model resistivities for Coincident Loop TEM : corresponding first pass model

1-D geo-electric section. .............................................................................................. 20

Figure 18: Schematic of IP current electrode and transmitter layout.................................... 23

Figure 19: Lowering copper electrode to bottom on hole on rope, with current supplying

cable taped on at 5 metre intervals. ............................................................................. 23

Figure 20: IP Transmitter set up at hole; Honda generator, Zonge receiver. ....................... 24

Figure 21: IP Infinity current insertion porous pot. ............................................................... 24

Figure 22: Digging hole, filling with water and agitating to create mud slurry suitable for pot at

grid point. ..................................................................................................................... 25

Figure 23: Zonge Multipurpose GDP-3211 IP receiver at field station, local earthing pot shown;

roving field pot at a grid point (not shown) is connected by long red wire which is visible

snaking off past operator in the centre of picture. .............................................. 25

Figure 24: Self potential. This is the natural Voltaic response of the ground with the power

source switched off. The drillhole lies at the very centre of the grid. Note the sinuous

character reminiscent of channels. Note also the very high (pink) responses centred 80

metres East of NDW12-01. .......................................................................................... 27

Figure 25: Apparent Chargeability. The drillhole and current injection point lies at the centre

of the grid. High vales, such as those in the northern part of the grid commonly indicate

disseminated sulphides................................................................................................ 27

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June 2012

Figure 26: Potential data. The drillhole and current injection point lies at the centre of the

grid. Note the Potential low in the NW of the grid. ........................................................ 28

Figure 27: Apparent Resistivity Data. Note the intense Potential low in the NW of the grid. 28

List of Tables

Table 1: Summary of geophysical methods used and interpretation...................................... 2

Table 2: Drillhole NDW12-01 Location. ................................................................................. 8

Table 3: NDW12-01 Drillhole Characteristics. ....................................................................... 8

Table 4: Smartem V sampling windows (milliseconds). ....................................................... 10

Table 5 : First pass model 1-D geo-electric section at NDW12-01....................................... 21

Page 6 of 30


June 2012

2. Introduction A downhole geophysics program was undertaken in drillhole NDW12-01 by Zonge

Engineering Pty Ltd (Zonge) for NRE Operations Pty Ltd (NRE) from 27 May to 16 June

2012. The geophysics program was supervised by Dr David H Tucker of Gawler Geoscience

(Geoscience).

The aim of the geophysics program was twofold:

1. To measure electrical characteristics of the geological section encountered in the

hole, and

2. To search around the hole for conductive and chargeable mineralisation.

The geophysics was undertaken within the Geophysics and Drilling Collaborations program.

This logistics of the field operations is illustrated in this report by pictures taken in the field by

the author. Various diagrams produced by the author and by Zonge are included to present

the results and interpretation. A location map is shown as Figure 2 below.

Figure 2: Daly Waters geophysics location grid reference map for both IP Mise-a-la-masse and Downhole

TEM survey and TEM sounding survey. GDA 94 (map modified after Mann, 2012).

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June 2012

3. Drillhole Characteristics Drillhole NDW12-01 is located in EL27878 approx 10km Northwest of Daly Waters at

coordinates shown in Table 2.

Table 2: Drillhole NDW12-01 Location.

Drillhole East_WGS84 North_WGS84 Elevation_m UTM_Zone Depth_m Dip_angle

NDW12-01 327,000 8204914 210 53 317.2 -90

The hole was drilled with HQ rods to a surveyed total depth (TD) of 317.2 metres. Of this,

approximately 156 metres was open and available for geophysics. Below that, the hole was

not accessible due to an intervening blockage, likely comprised of collapsed rock and mud.

A schematic of the situation is shown in Table 3.

To prevent collapse, the top 156 metres was lined with 48mm internal diameter PVC pipe

opened at the bottom. The installation method used was to glue and run down the six metre

long PVC pipes within the HQ drill string to the bottom of the hole. When at TD, the HQ rods

were withdrawn, leaving the PVC in situ.

Before undertaking geophysical surveys a heavy ‘dummy’ weight, approximately one meter

long, was lowered on a rope to test the characteristics of the pipe and the blockage. The

dummy would not pass beyond the bottom of the PVC and raising a few metres and

dropping a few metres did not help.

From 167.1 metres to total depth (TD) the drillhole contained a stuck string of HQ drill.

The water table was estimated by drillers to lie at approximately 140 metres below surface.

Table 3: NDW12-01 Drillhole Characteristics.

Hole depth range

HQ rods recovered (m)

HQ rods remaining in hole (m)

PVC depth range (m) open for geophysics

Blockage (m)

0

to

317.2

0

to

168

0 to

~156

~156 to

167.1

~167.1

to

317.2

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June 2012

4. Regional Context The geology of the locality is recognised as Karumba Basin sediments overlying Carpentaria

Basin sediments overlying probable Georgina Basin sediments and these in turn overlying

possible McArthur Basin metasediments and/or Tennant Creek rocks (Warramunga Group).

A regional map is included as Figure 1.

There is no known on-line open file summary available of electrical characteristics of

sediments in this area and in particular there is no known geo-electric section available.

Electrical data may exist within company reports (Roger Clifton pers. comm.) but was not

pursued here.

The regional gravity for Australia, available on the AGSO website and NT website, indicates

that the drillhole is located on a regional Bouguer anomaly high anomaly. This is named the

Daly River arch. This ‘arch’ is a narrow, 10-20km wide North-south striking gravity anomaly

which extends for more than a hundred kilometres, and is of regional significance. The

anomaly morphology, and in particular its marginal gradients, is generally poorly defined by

the 11 km spaced helicopter gravity stations and rare detailed road traverses. One such road

traverse, which extends East-west along the Borraloola Highway and also the Buchanan

Highway, gives some indication. The Buchanan Highway gradient indicates a steeply dipping

density contact, probably a fault on the west side. The depth to the source of the gravity

anomalies has not been modelled and is not known.

There is only weak correspondence between aeromagnetic patterns and the North-south

gravity anomaly high, perhaps indicating that they have different sources. Several estimates

to magnetic basement made by the author (from the low quality regional aeromagnetic data

within the area of EL27878) lie in the range 300-600 metres. The dominant magnetic pattern

indicates a 30km wide suite of approximately 305 degree bearing narrow linear anomalies

through and beyond the EL27878. These responses are typical of dyke swarms intruding

faults. It is speculated they are attributable to magnetic Antrim Plateau Volcanics. Vague

pattern breaks, probably attributable to faults, strike through the EL27878 past drillhole

NDW12-01 on a strike of 020 degrees.

In conclusion, it is likely that the Daly River arch gravity anomaly is caused by a narrow sliver

of higher density basement forming a topographic high, perhaps bounded by steeply dipping

faults. An analogy with the Emu Fault and the localisation of the HYC ore body is relevant.

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June 2012

5. Transient Electromagnetic Survey 5.1. Equipment and layout for downhole TEM survey

The downhole TEM survey as undertaken required an energising loop to be laid out on the

surface and for readings to be taken at intervals down the drillhole. A schematic diagram of

the set up is shown in Figure 3. A set of pictures taken in the field by the author to illustrate

the work is included in this report (Figures 4 to 10).

A full description of the operational procedures and digital copy of the results are included in

Zonge’s logistics report (Mann, 2012).


Zonge ZT-30 transmitter, which was supplied with power from a Honda 3 KVa generator, for

the downhole TEM acquisition.

The downhole probe was a Geonics BH43-3D coil probe with data recorded on each X, Y

and Z component a a frequency of 2.083 Hz. The system used 33 time windows from 0.14

to 141 milliseconds and these are provided in the following table (Table 4).

Table 4: Smartem V sampling windows (milliseconds).

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June 2012

A conventional, square, dual loop was chosen for this survey, with 200 metres per side,

oriented North-south East-west and with the hole at the geometric centre. Such a loop would

couple with a flat conductor intersecting or lying close to the hole. In operation the current

through the loop is governed by the wire resistance and the transmitter capacity and in this

instance was 0.56 amperes.

The loops were laid through light scrub, which did not require cut lines.

Readings were taken in the hole with the probe lowered in 5 metre stops, with the sensor

location of the probe starting 2 metres below surface and extending to 152 metres below

surface.

An option considered, but not adopted because the hole was not open to its full depth, and

the results did not warrant further work, was to lay out several other adjacent loops cornered

on the hole to search for extensions of any conductors away from the hole.

Figure 3: Schematic diagram of downhole TEM receiver setup. The probe is overall 2.4 metres long, the bottom part comprising a solid weight. The sensor is located mid length.

Page 11 of 30


June 2012

Figure 4: TEM Transmitter site, operator with equipment including insulated cables in foreground, connected to the 200m square loop.

Figure 5: Live wire warning sign; generator and transmitter located 25 metres down the road.

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June 2012

Figure 6: Zonge ZT-30 TEM Transmitter indicates 120.1 volts at 0.56 amperes is being fed into the loop.

Figure 7: TEM Receiver layout (refer to the previous schematic diagram); note tripod directly over PVC protruding from drillhole; 4 conductor cable extends across to winch on back of truck; receiving equipment is located beside truck on right.

Page 13 of 30


June 2012

Figure 8: Connecting TEM probe sections; winch on truck at left. Geophysicist holding vertical probe has a gas burner in his right hand and is heating black shrink wrap over screwed joints to minimise water entry and unravelling in operation.

Figure 9: Complete TEM receiver probe: Geonics BH43-3D.

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June 2012

Figure 10: EMIT Smartem V receiver and Zonge controller in operation to acquire data, connected to the downhole TEM probe via the winch cable.

5.2. Results and interpretation for downhole TEM

The data obtained by the TEM downhole survey were processed by Zonge in Adelaide and

plotted profiles of these results are shown below (Figure 11).

The plot shows three sets of profiles. The ‘A’ component is axial to the hole and because the

hole is vertical, is also a vertical vector component.

The ‘U’ component and ‘V’ components are North and South vector components. These

latter components can be useful if conductive mineralisation is encountered and can give an

indication of direction of extensions to such.

The units used for the TEM results are microvolts per ampere of current flowing in the loop

and are thus normalised: the scale used in the diagram is logarithmic: horizontal units are

metres from surface, with surface at the left.

The A component shows a very smooth and essentially flat set of profiles. There are no

strong obvious anomalies as might be expected if significant conductors were present

intersecting the hole (confirming what is known from the geological logging).

On close inspection, the early time channels in the A component results show a gentle rise

in amplitude from surface to peak at approximately 35 metres depth. Below approximately

75 metres, there is a very slight and gentle rise in amplitude of all channels towards the

bottom of the set of observations. It is suspected that this may represent a response from

the drill rods.

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June 2012

Close inspection of the U component and V component shown here shows weak inflections

at approximately 10-15 metres, 60-65 metres 100-105 metres and 110-115 metres. These

do not show corresponding anomalies in the A component. There is a weak correspondence

with geologically observed unconformities: as such, the inflections may indicate weak

conductivity changes associated with these unconformities.

Figure 11: TEM results for A, U and V components. Vertical scale units are microvolts per ampere and horizontal scale units are metres.

To illustrate the characteristics of the TEM data, decay curve plots are included here for the

33 channel sample taken at the two metre depth point, i.e. for the shallowest sample of the

drillhole and for which the geometry is best understood. Curve fits of two types are applied

where appropriate: power curve fits and time constant fits (Figures 12-15).

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June 2012

Figure 12: DHEM 2 metres. Decay curve for channels 1-33 Time constant fit over early channels 2 to 7 i.e. within the red lines (Tau= 0.11ms).

Figure 13: DHEM 2 metres. Decay curves channels 1-33. Power curve fit for channels 7-21 (Power =

-2.72).

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June 2012

Figure 14: DHEM 2metres. Decay curves for Channels 1-33. Power curve fit for channels 23-33 (power = -0.90).

Figure 15: DHEM 2 metres. Decay curves for channels 1-33. Alternative Time constant curve fit for channels 23-33 (Tau=44.6ms).

A one dimensional inversion was run by Zonge on this shallowest observation dataset at two

metres depth and the result is shown in Figure 16: the drillhole data were treated as a

surface observation for the purpose of comparison with moving loop values discussed

below. This approach provided a result equivalent to a depth sounding which is normally

only possible for each station of a moving loop configuration TEM survey. As such, the

drillhole result can be directly compared to moving loop data.

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June 2012

Figure 16: DHEM NDW12-01 surface model resistivities (after Zonge). One dimensional section is shown alongside. Note that the part below the abandoned drill rods may be unreliable.

The smooth sounding model probably indicates a three layer case applies as indicated in the

1-D sketch above (Figure 16). The figure shows corresponding geological notes alongside.

It is noted that the estimated 20 ohm metre section to approximately 40 metres corresponds

approximately with an unconformity noted in drill core at approximately 39 metres.

Below that porous limestone was encountered in drillcore to a disconformity at approximately

140 metres which is also approximately the water table: this depth corresponds to the peak

values calculated in the resistivity model of 500 ohm metres.

Below 140 metres in the sounding model the resistivities drop off to a minimum at

approximately 400 metres.

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June 2012

5.3. Moving loops layout for surface TEM sounding survey

Two surface TEM soundings were taken using coincident 200 metre loops at a location

approximately 1.5 kilometres Northwest from drillhole NDW12-01 (see Figure 2).


Zonge ZT-30 transmitter supplied with power from a Honda 3 KVa generator for the

downhole EM sounding acquisition.

5.4. Results and interpretation for surface TEM sounding survey

A one dimensional inversion model of apparent resistivities run on the data by Zonge is

included here (Figure 17). It indicates a three or possibly four layer model applies at this

location.

Figure 17: 1-D model resistivities for Coincident Loop TEM : corresponding first pass model 1-D geo- electric section.

From surface to approximately 50 metres depth resistivities peak at approximately 55-60

ohm metes; from 50 metres to approximately 130 metres values drop to approximately 40-55

Page 20 of 30


June 2012

ohm metres and from 130 metres to approximately 300 metres approach a maximum of 160-

200 ohm metres.

Table 5 : First pass model 1-D geo-electric section at NDW12-01.

Model Depth Range (metres (approximate))

Model Apparent Resistivity Range (Ohm metres)

Geological Interpretation

~00 – ~50 55-60 Dry-moist soils and sediments

~50 - ~130 40-50 Moist sediments

~130 - ~300 160-200 Wet sediments

~300+ Assymtotes to 2 Unreliable

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June 2012

6. Induced Polarisation survey 6.1. Equipment and layout

To investigate the Apparent Resistivity and Chargeability characteristics of the geological

section in this drillhole, and in particular of the intersections of sulphides encountered at 183

and 240 metres, it was planned to run an Induced Polarisation survey using a small dipole-

dipole array (one metre ‘a’ spacing and ‘n=1’). Such a survey requires a water-filled open

hole. Because the available hole was not water-filled, this option was not possible to

implement.

A secondary plan, to run a Mise a la Masse style of survey (Mudge, 2004: Hauck, 1970) to

test for possible extensions of any significant sulphides encountered and identify any ‘near

misses’, was finally run in modified form. The survey layout is indicated in Figure 2 in the

Introduction. The layout at the drillhole is shown in Figure 18. Operational pictures taken by

the author are included as Figures 19 to 23.

The equipment used included a Zonge multipurpose GDP-3211 receiver recorded in pole-

pole mode using non polarisable porous pots filled with copper sulphate as receiver

electrodes. Data were acquired in time domain at a frequency of 0.125hz allowing

acquisition of potential voltage 9Vp), self-potential (SP) and chargeability (Mx).

Transmitted fields were generated with a Zonge ZT-30 geophysical transmitter connected to

electrodes on the surface some distance from the hole and the second placed down the hole

at approximately 156m from surface. Synchronisation was controlled by a Zonge XMT-32

transmitter controller.

Ideally this kind of test calls for the current electrode to be planted directly within each zone of

mineralisation. However, because the known sulphide sections were in the blocked-off part

of the hole, it was only practical to do the next best and plant the current electrode at the

deepest point reachable and use this as a current injection point. By this means, the survey

in effect can search above the current injection point.

Induced Polarisation readings were obtained at 40 metre stations on a grid of overall

dimensions 400 metres East-west by 160 metres North-south centred on the drill collar. The

in-hole excitation point consisted of a one metre length of 25mm copper rod at 156 metres

depth presumably located in mud. Approximately two kilograms of copper sulphate in water

were poured into the drill pipe to improve conductive contact with surrounding rock. A

second electrode for current input was located as an infinity point approximately 650 metres

to the South. Readings were taken at moving porous pots located at grid points and at an

infinity point located approximately 650 metres to the North.

Page 22 of 30


June 2012

Figure 18: Schematic of IP current electrode and transmitter layout.

Figure 19: Lowering copper electrode to bottom on hole on rope, with current supplying cable taped on at 5 metre intervals.

Page 23 of 30


June 2012

Figure 20: IP Transmitter set up at hole; Honda generator, Zonge receiver.

Figure 21: IP Infinity current insertion porous pot.

Page 24 of 30


June 2012

Figure 22: Digging hole, filling with water and agitating to create mud slurry suitable for pot at grid point.

Figure 23: Zonge Multipurpose GDP-3211

IP receiver at field station, local earthing pot shown; roving field pot at a grid point (not shown) is connected by long red wire which is visible snaking off past operator in the centre of picture.

Page 25 of 30


June 2012

6.2. IP Results and interpretation

Four plots of results are included here: Self Potential, Apparent Chargeability, Potential, and

Apparent Resistivity (Figures 24 to 27). The grid extends 160 metres North-south and 400

metres East-west and the drillhole and the current injection point lie beneath the geographic

centre of the grid.

Anomalous IP results were recorded in each of the Self Potential, Apparent Chargeability

and Potential. Anomalies and Potential and in Apparent Chargeability are essentially linear

in pattern, have an overall East-west strike and extend at least 200 metres past the drillhole

and out of the surveyed area.

Surprisingly high values of Apparent Chargeability (up to 35 milliseconds in the pink area of

Figure 25) were recorded in the Northwest of the grid. This corresponds approximately to an

area low in Potential low (blue values Figure 26), which in turn allows calculation of Apparent

Resistivity low values marked as deep purple (Figure 27). Such correspondence of high

values of Apparent Chargeability and Low Apparent Resistivity is often associated with

sulphides.

It is notable that in each of these set of responses there is no obvious concentric pattern of

contours around the drillhole. Rather we see a half closed concentric pattern in Apparent

Chargeability centred some 150 metres or more to the Northwest of the drillhole. This is an

unusual and key result. This may indicate that the IP method didn’t connect with significant

conductive or chargeable bodies close to the current injection point, i.e. at 156 metres.

Rather, the IP connected with a separate body at least 150 metres away and below the

Chargeability high. Estimated depth to the source is approximately 150 metres plus.

It is recommended that the anomalies are followed up.

The Self Potential is a measure of natural voltaic response of an area, and a high zone can

indicate oxidising sulphides beneath. In the area around NDW12-01 the higher responses in

Self Potential, as indicated by the pink coloration in the figure, lie in sinuous patterns over

the grid, different from the other responses. This suggests a different kind of source from

what is observed in the Potential and Apparent Chargeability. The sinuous patterns are

suggestive of channels in a floodplain. These responses may indicate variations in clay

content of shallow channels at less than 50 metres depth. The highest results as evidenced

by three stations are centred approximately 80 metres East of the drillhole.

The geological source of the anomalies is uncertain. Sulphides are possible: alternatively

clays are also possible.

Page 26 of 30


June 2012

Figure 24: Self potential. This is the natural Voltaic response of the ground with the power source switched off. The drillhole lies at the very centre of the grid. Note the sinuous character reminiscent of channels. Note also the very high (pink) responses centred 80 metres East of NDW12-01.

Figure 25: Apparent Chargeability. The drillhole and current injection point lies at the centre of the grid. High vales, such as those in the northern part of the grid commonly indicate disseminated sulphides.

Page 27 of 30


June 2012

Figure 26: Potential data. The drillhole and current injection point lies at the centre of the grid. Note the Potential low in the NW of the grid.

Figure 27: Apparent Resistivity Data. Note the intense Potential low in the NW of the grid.

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June 2012

7. Conclusions and Recommendations 1. Conclusion TEM: Because NDW12-01 was blocked halfway down and essentially

dry, testing of geophysical characteristics of the rocks intersected by the drill was

limited in scope.

2. Conclusion: TEM: The TEM results did not detect large conducting and chargeable

mineralised bodies either intersecting or as near misses to the drillhole NDW12-01

above an estimated 150 metres depth.

3. Conclusion TEM: Implications for future exploration. The TEM results indicate that

the shallow part of sediments surveyed at NDW12-01 are essentially transparent to

the type of electromagnetic signals used in mineral exploration. Also, importantly,

there is an absence of the often troublesome ‘conductive overburden’ experienced

elsewhere in Australia.

4. Recommendation TEM: If these conditions are widespread in this area of the

Carpentaria Basin, the TEM method is practical for large scale surveys seeking to

explore beneath these sediments to look in the basement for electrically detectable

ore-bodies like for instance HYC and Tennant Creek. Such surveys would use a

heavy duty system with large loops energised by high currents and with longer

recording times.

5. Conclusion IP: The Induced Polarisation results recorded Self potential Apparent

Chargeability and Potential values (similar to Apparent Resistivity) anomalies around

the drillhole NDW12-01. The SP anomalies appear sinuous reminiscent of channels

and it is believed that these are caused by variations in the relatively shallow

sediments, probably the top 50 metres. A locus of high values 80 metres east of the

drillhole warrant follow up.

6. Conclusion IP: Implications for exploration. The source of the Apparent Chargeability

and Potential values anomalies are typical of a large disseminated sulphide body.

The depth is approximately 150 metres plus. These anomalies warrant further

investigation including drilling.

7. Conclusion IP: Because operational matters prevented direct access to the deeper

sulphides intersected by the drillhole NDW12-01, the direct characteristics of these

remain untested by the downhole IP method,

8. Recommendation IP: If exploration continues in this locality, the sources of the deep

and shallow IP anomalies should be followed up.

9. Recommendation General: To focus drilling for ore-bodies in this area, consideration

should be given to gravity traversing across the Daly River arch and airborne

magnetic surveying over the tenements, to pin down the basement depth and

structural morphology.

Page 29 of 30


June 2012

8. Bibliography

Hauck III, A.M., 1970. A reconnaissance downhole induced polarisation and resistivity

survey method. McPhar Geophysics Limited. Presnted at the S.E.G. Annual meeting. New

Orleans, Louisiana. November 1970.

Mann, S.T., 2012. Daly Waters down-hole Induced Polarisation and down-hole Transient

Electromagnetic Surveys. Logistics report for NRE Operations. Zonge Engineering Pty Ltd.

Report No 967. June 2012.

Mudge, S.T., 2004. Radial Resistivity/IP surveys using a downhole current electrode.

Exploration Geophysics (2004) 35, 186-193.

Tucker, D.H., 2012. Characteristics and interpretation of downhole geophysics at drillhole

NDW12-01 Daly Waters Project Northern Territory EL27878 May-June 2012. Report

prepared by Gawler Geoscience for Natural Resources Exploration Operations Pty Ltd.

Vigar, A.J., 2011. Review and Exploration Recommendation of the Daly Waters project

Northern Territory EL27905, El27877 & El27879. Prepared by Mining Associates Pty Limited

for Natural Resources Exploration Pty Ltd.

End

Page 30 of 30

Appendix 12

H0002 Version 4 H0003 Date_generated 15/10/2012 H0004 Reporting_period_end_date 30/9/2012 H0005 State NT H0100 Tenement_no EL27877 EL27878 EL27879

H0101 Tenement_holder Natural Resouc es Exploration Pty Ltd

H0102 Project_name Daly Waters H0106 Tenement_operator Natural Resouc es Exploration Pty Ltd

H0150 250K_map_sheet_number SD53‐14 SE53‐01 SE53‐02

H0151 100K_map_sheet_number 5564 5565 5665 5666

H0200 Start_date_of_data_acquisition 1/5/2012 H0201 End_date_of_data_acquisition 31/7/2012 H0202 Template_format SG1 H0203 Number_of_data_records 9 H0204 Date_of_metadata_update 15/10/2012 H0300 Location_data_file Daly_Waters_Combined_2012A_08_HM_Sample_details.txt H0318 Grain_microprobe_data Daly_Waters_Combined_2012A_09_Grain_probe.txt H0500 Feature_located Surface_location H0501 Geodetic_datum GDA94 H0502 Vertical_datum AHD H0503 Projection UTM H0530 Coordinate_system Projected H0531 Projection_zone 53 H0532 Surveying_instrument Garmin 75cs GPS Averaged Position H0533 Surveying_company Orogenic Exploration Pty Ltd H0600 Sample_code Stream Loam H0601 Sample_type Stream sediment Loam deflation scap H0602 Sample_description 10L (one bag) screened ‐1.0mm on site H0701 Sample_preparation_details Wet/dry screen 0.3‐0.8mm, DMS heavy liquid seperate, magnetic separate, TBE seperation, observe H0702 Job_no 12042 H0801 Assay_company Diatech, Perth H1000 SAMPLE Collection_date TYPE Xcoordinate Ycoordinate Zcoordinate Map_100k WEIGHT LICENCE RATING LOCATION COMMENTS

H1001 metres metres metres kg H1004 2 2 5 0.001

D DW12‐01 25/05/2012 Stream 326192 8200147 232 5565 18.213 EL27878 Medium Daly Waters Creek, 400m S of road xing, near west bank Fine gravel, rounded pisoliths, below tree roots, sitstone base

D DW12‐02 25/05/2012 Loam 332551 8145209 235 5564 21.368 EL27879 Poor W of western Stuart Highway fence, 1.9km N of Hayfield turnoff Fine rounded pisoliths, coarse sands on silty base

D DW12‐03 25/05/2012 Stream 327611 8180625 256 5565 13.39 EL27879 Medium W of Stuart Highway, 5.8km ESE of McGorrery Pond Angular limestone/siltstone fragments between large boulders

D DW12‐04 26/05/2012 Loam 335020 8184850 252 5565 15.39 EL27879 Poor 5.4km east along fence from Midges Bore Rounded pisoliths concentrations on hard silty base, south side fence

D DW12‐06 26/05/2012 Stream 377434 8230160 223 5665 12.599 EL27877 Medium NW trib of Hodgon River, N of track xing on bend Sub to Rounded limestone & siltstone fine gravel race on bend, clay base

D DW12‐07 28/05/2012 Stream 382613 8228040 189 5665 14.936 EL27877 Poor NW trib of Hodgon River, N of track xing Rounded Fe stained pebbles, poor trap around limestone blocks, edge channe

D DW12‐08 28/05/2012 Stream 388765 8227327 183 5665 14.338 EL27877 Poor West branch Brumby Creek, 40m downstream N of track xing Fine subrounded gravel behind tree roots

D DW12‐09 28/05/2012 Stream 385474 8227830 185 5665 18.667 EL27877 Excellent West branch Hodgson River, 20m downstream N of track xing Fine Fe‐stained fine gravel in siltstone bedrock crevices

D DW12‐10 7/06/2012 Stream 363234 8232073 211 5666 15.868 EL27878 Good Strangways River, 40m E upstream of track xing Rounded Fe stained pisoliths in potholes, behind roots on clay base

EOF

Appendix 13

Nagrom Metallurgical Report


A.C.N. 008 868 335

A.B.N. 55 008 868 335

T: 08 9399 3934

F: 08 9497 1415

PO Box 66

Kelmscott WA 6991

49 Owen Road,

Kelmscott WA 6111

Level 8 Corporate Center

2 Corporate Court

BUNDALL QLD 4217

Diamond DMS Testwork

Nagrom Batch Number: T1054

Diatech Job Number: 12042

August 21 2012

DIAMOND

PYROPE

KIMBERLITIC CR SPINEL

Metallurgical Testing – Assay Laboratory – Pilot Plant Fabrication – Mineral Processing

NRE Operations Pty Ltd Sample Summary Report Date: August 21 2012

SAMPLE

Received Net Mass (Dry)

+1.2mm Net Mass (Wet)

+0.3mm Net Mass (Wet)

‐0.3mm Net Mass (Wet)

‐1.2+0.3mm DMS Sinks Net Mass (Dry)

‐1.2+0.3mm TBE Sinks Net Mass (Dry)

g g g g g g

DW12 ‐ 01

18203.2

126.3

16506.4

5831.3

219.7

170.5 DW12 ‐ 02 21341.1 105.3 15444.1 9949.0 100.7 32.5

DW12 ‐ 03 13372.4 104.4 8449.4 9072.4 74.8 58.2

DW12 ‐ 04 15372.1 37.2 2012.3 17613.0 82.2 21.9

DW12 ‐ 05 ‐ ‐ ‐ ‐ ‐ ‐

DW12 ‐ 06 12490.2 225.7 9633.7 7484.1 1780.6 1779.4

DW12 ‐ 07 14925.1 124.9 11547.4 8219.0 4245.6 4242.4

DW12 ‐ 08 14339.1 74.7 8880.6 10744.8 1269.1 1120.2

DW12 ‐ 09 18631.8 988.8 18622.7 3827.7 6747.5 6744.3

DW12 ‐ 10 15823.1 1021.7 16203.0 5510.9 836.9 688.9

Note:

Sample DW12‐05 arrived with the bag broken and no sample remaining.

Nagrom Project Testwork T1054 - Natural Resources 21 August 2012.xlsx Page 2 of 5

% S

inks

NRE Operations Pty Ltd MicroDMS Operating Parameters Report Date: August 21 2012

PE Tracers

Relative Density (RD)

Added

Sinks

%

FeSi Grade

Feed Density

Overflow Density

Underflow Density

Cut Point

EPM

1mm g.cm‐3

No. No. g.cm‐3

g.cm‐3

g.cm‐3

Grey 2.70 10 0 0 270F 2.23 2.06 2.67 3.25 0.12

Green 2.80 10 0 0

Cream 2.90 10 0 0

Orange 3.00 10 0 0

Dark Pink 3.10 10 0 0

Violet 3.20 10 3 30

Yellow 3.30 10 7 70

Black 3.40 10 7 70

Blue 3.53 10 10 100

Synthetic Diamonds (~0.4mm) 20 20 100

100

75

50

MicroDMS Partition Curve

25

0 2.70 2.80 2.90 3.00 3.10 3.20 3.30 3.40 3.50 3.60

Tracer Relative Density (RD) g.cm‐3


Nagrom Statement of Certification

Sample Preparation and Analysis:

The testwork is conducted by experienced personnel at Nagrom’s Kelmscott metallurgical

laboratory under the supervision of a senior metallurgist.

A.C.N. 008 868 335

A.B.N. 55 008 868 335

T: 08 9399 3934 F: 08 9497 1415

PO Box 66 Kelmscott WA 6991

49 Owen Road, Kelmscott WA 6111

Process solids are assayed in‐house using fused bead/XRF methods where applicable otherwise

acid/fusion dilution followed by ICP‐MS methods are used.

Process solutions are assayed in‐house using ICP‐OES and ICP‐MS techniques. Ultratrace Laboratories are used to augment our services and provide external reference.

The reports will be signed on behalf of the General Manager and Executive Director of Nagrom (the

Mineral Processors).

Dr Slobodanka Vukcevic

For further information, contact: Slobodanka Vukcevic, Senior Metallurgist

Telephone: +61 8 9399 3934

Mobile: 0439 900 455

Information in the report relating to the metallurgical interpretation, analysis, mineral distribution

and recommendations has been compiled and checked by the Senior Metallurgist of Nagrom. Dr

Slobodanka Vukcevic has sufficient experience and expertise relevant to this type of test‐work

through her job experiences and education and she qualifies as a competent person in the field of

metallurgy. The Nagrom team including Slobodanka Vukcevic, Rick Murphy and Tony Wilkinson has a wide range

of metallurgical experiences in comminution, gravity separation, flotation, leaching, SX, IX,

precipitation, and settling from bench testing scale through to pilot plant scale for the development

of flow‐sheets or for solving process problems.

Mineral Processing - Metallurgical Testing - Circuitry Design - Equipment Supply


Appendix 14

Detailed Heavy Mineral Analysis Sample No:

DW12-01

Ph 61 8 9361 2596

Fx 61 8 9470 1504

Our Job No.: 12042

Disc No.: Overall Sample Assessment:

Your Project Code:

Negative

Northern Territory

Sample Type (as collected):

Sample Type (as received):

Stream Sediment

DMS Concentrate

Head Weight 18.21 kg

Wet Weight kg

Observed Sample Type: TBE Concentrate

Diamond Number of particles in each size fraction Total

mm +2.0 +1.2 +.8 +.4 +.3 +.25 +.20 +.10 particles Description of these particles

Key Minerals Number of particles in each size fraction

Assessment Wear Total

particles

No of particles

probed mm +2.0 +1.2 +.8 +.4 +.3 +.25 +.20 +.10

Other Minerals % Percentage of particles in each size fraction mm +2.0 +1.2 +.8 +.4 +.3 +.25 +.20 +.10 Wear Colour Angularity Lustre Transparency Form/Shape

Almandine

Tr HA

pale orange,

pale pink

subrounded glassy transparent DAF, hummocky, irregular

Anatase Tr HA blue-grey,

golden yellow

subrounded greasy translucent

to

transparent

tabular

Barite

Tr Tr

LA white, stained subrounded waxy translucent fine crystalline

aggregates

Corundum Tr Tr HA colourless, subrounded adamantin transparent irregular to subhedral,

blue, pink to e

subangular black inclusions common

Fe Oxide/Hydroxide 100 40

red-brown,

yellow-brown

rounded highly

polished

opaque pisolitic

Gahnite Tr HA aqua-green subrounded frosted translucent irregular

to rounded

Ilmenite Tr MA silvery-black subrounded dull to

submetallic

opaque altered

Kyanite Tr 5 MA colourless, Fe- subrounded pearly translucent bladed

Leucoxene

Tr Tr

stained, sky-

blue

HA blue-grey,

greenish-grey

to rounded

subrounded porcelain-

like,

polished

to

transparent

opaque smooth, irregular

Monazite

Tr HA

cream-yellow rounded resinous translucent irregular

Muscovite Tr Tr MA colourless subrounded pearly transparent rare flakes

Rutile Tr 20 HA black, silvery-

black

rounded submetallic subtransluc

ent

ovate, rolled

Staurolite Tr Tr MA honey-brown,

dark brown

subrounded glassy transparent irregular

Tourmaline 15 HA black-brown, subrounded glassy to translucent near spherical to ovate

brown to rounded frosted to

transparent

Zircon

TOTAL %

Tr 20 % % 100% 100%

% % %

HA pink,

colourless,

plum-pink

subrounded glassy transparent ovate, subhedral

to rounded

mm +2.0 +1.2 +.8 +.4 +.3 +.25 +.20 +.10

Final Conc Weight 35.97000 g Size Range -0.8+0.3 mm

Weight Observed 35.97000 g

Magnetic Fractions vs Size Fraction

All All All All All All


DW12-01

Ph 61 8 9361 2596

Fx 61 8 9470 1504

Our Job No.: 12042


Your Project Code:

Negative

Northern Territory

What Has Been Observed?

Technician: LF

Date Observed: 14-Aug-12

Comment about

this sample:

Report Printed: 28/08/2012 2:38:12 PM

mm +2.0 +1.2 +.8 +.4 +.3 +.25 +.20 +.10




NotMag All All


DW12-02

Ph 61 8 9361 2596

Fx 61 8 9470 1504

Our Job No.: 12042


Your Project Code:

Negative

Northern Territory



Stream Sediment

DMS Concentrate


Wet Weight kg






particles

No of particles

probed mm +2.0 +1.2 +.8 +.4 +.3 +.25 +.20 +.10


Almandine

Tr Tr

MA pink subrounded glassy transparent irregular

Corundum Tr Tr LA colourless/blue

, colourless

vitreous transparent tabular, blocky

Fe Oxide/Hydroxide 100 80 brown, red-

brown

subangular

to rounded

dull,

polished

opaque pisolites, irregular

Gahnite Tr HA dark green subrounded dull, glassy translucent

Ilmenite Tr MA black subrounded dull opaque irregular

Kyanite Tr Tr HA colourless,

pale blue

pearly transparent elongate, tabular

Leucoxene Tr 5 HA beige, grey polished opaque irregular

Rutile Tr 5 MA black, cherry

red

subrounded metallic opaque ovate

Tourmaline Tr Tr HA black-brown subrounded glassy opaque,

transparent

subhedral, irregular

Zircon Tr 10 HA colourless rounded dull, glassy transparent ovate, irregular

TOTAL % % % 100% 100% % % %


Technician: JED


Comment about

this sample:


mm +2.0 +1.2 +.8 +.4 +.3 +.25 +.20 +.10




NotMag All All


DW12-03

Ph 61 8 9361 2596

Fx 61 8 9470 1504

Our Job No.: 12042


Your Project Code:

Negative

Northern Territory



Stream Sediment

DMS Concentrate


Wet Weight kg






particles

No of particles

probed mm +2.0 +1.2 +.8 +.4 +.3 +.25 +.20 +.10


Almandine

Tr MA

pale pink subrounded glassy transparent irregular

Al-Spinel Tr MA pale green subrounded frosted translucent subhedral

Corundum Tr Tr LA colourless,

blue

subangular vitreous transparent tabular, subhedral

Fe Oxide/Hydroxide 100 98 brown subangular

to rounded

dull,

polished

opaque irregular, pisolites

Gahnite Tr MA green frosted,

glassy

translucent subhedral

Kyanite Tr Tr MA colourless pearly translucent elongate, tabular,

included

Leucoxene Tr HA beige, cream rounded polished opaque irregular

Rutile Tr 1 MA black, cherry

red


Staurolite Tr MA brown frosted,

glassy

translucent blocky, irregular

Tourmaline Tr Tr MA black-brown,

pale brown

subrounded glassy transparent

, opaque subhedral, irregular

Zircon Tr 1 LA colourless,

pink, plum

subangular,

subrounded

vitreous transparent subhedral, ovate

TOTAL % % % 100% 100% % % %


Technician: JED


Comment about

this sample:


mm +2.0 +1.2 +.8 +.4 +.3 +.25 +.20 +.10




NotMag All All


DW12-04

Ph 61 8 9361 2596

Fx 61 8 9470 1504

Our Job No.: 12042


Your Project Code:

Negative

Northern Territory



Stream Sediment

DMS Concentrate


Wet Weight kg






particles

No of particles

probed mm +2.0 +1.2 +.8 +.4 +.3 +.25 +.20 +.10


Corundum

Tr Tr

LA colourless,

blue

angular to

subangular

vitreous transparent tabular, irregular

Fe Oxide/Hydroxide 100 95 brown, tan angular to

rounded

dull opaque irregular

Gahnite Tr MA dark green glassy translucent subhedral

Ilmenite Tr MA black subrounded dull opaque irregular

Kyanite Tr Tr MA colourless pearly transparent elongate, included

Leucoxene Tr HA beige subrounded polished opaque irregular

Pyrite Tr MA brassy yellow subangular metallic opaque irregular

Rutile Tr Tr MA black, cherry-

red


Staurolite Tr MA orange-brown glassy translucent, irregular

opaque

Tourmaline Tr Tr MA black-brown subangular

to rounded

glassy translucent, subhedral, irregular

opaque

Zircon Tr 5 MA colourless,

pale peach

subrounded glassy transparent ovate

TOTAL % % % 100% 100% % % %


Technician: JED


Comment about

this sample:


mm +2.0 +1.2 +.8 +.4 +.3 +.25 +.20 +.10




All All 1/8 All All All


DW12-06

Ph 61 8 9361 2596

Fx 61 8 9470 1504

Our Job No.: 12042


Your Project Code:

Negative

Northern Territory



Stream Sediment

DMS Concentrate


Wet Weight kg






particles

No of particles

probed mm +2.0 +1.2 +.8 +.4 +.3 +.25 +.20 +.10


Barite

Tr Tr

LA white subangular frosted opaque,

translucent

tabular, granular

Corundum Tr Tr LA colourless,

blue

subangular vitreous transparent tabular, irregular

Fe Oxide/Hydroxide 100 100 brown, tan,

red-brown

subangular

to rounded

dull opaque irregular, pisolites

Ilmenite Tr Tr MA black dull metallic opaque irregular, tabular

Leucoxene Tr HA beige subrounded polished opaque irregular

Rutile Tr MA cherry-red,

black

metallic opaque irregular, ovate

Zircon Tr LA colourless glassy transparent ovate, subhedral

TOTAL % % % 100% 100% % % %


Technician: JED


Comment about

this sample:


mm +2.0 +1.2 +.8 +.4 +.3 +.25 +.20 +.10




All All None 1/2 None All


DW12-07

Ph 61 8 9361 2596

Fx 61 8 9470 1504

Our Job No.: 12042


Your Project Code:

Negative

Northern Territory



Stream Sediment

DMS Concentrate


Wet Weight kg






particles

No of particles

probed mm +2.0 +1.2 +.8 +.4 +.3 +.25 +.20 +.10


Barite

Tr Tr

LA white frosted translucent granular

Corundum Tr Tr LA pale/dark

blue,

colourless

angular vitreous transparent tabular, irregular,

included, subhedral


brown, tan,

red-brown

subangular

to rounded

dull to

polished

opaque irregular, pisolites

Ilmenite Tr MA black subrounded dull,

metallic

opaque irregular

Kyanite Tr Tr MA colourless pearly transparent blocky, elongate

Leucoxene Tr Tr HA beige, grey subrounded polished opaque irregular

Rutile Tr Tr MA black, cherry-

red

metallic translucent, elongate, ovate

opaque

Tourmaline Tr Tr MA black-brown subangular glassy,

frosted

opaque subhedral, blocky

Zircon Tr Tr MA colourless ovate, subhedral

TOTAL % % % 100% 100% % % %


Technician: JED


Comment about

this sample:


mm +2.0 +1.2 +.8 +.4 +.3 +.25 +.20 +.10




All All 1/4 All 1/4 All


DW12-08

Ph 61 8 9361 2596

Fx 61 8 9470 1504

Our Job No.: 12042


Your Project Code:

Negative

Northern Territory



Stream Sediment

DMS Concentrate


Wet Weight kg






particles

No of particles

probed mm +2.0 +1.2 +.8 +.4 +.3 +.25 +.20 +.10


Almandine

Tr HA

pale pink rounded glassy transparent irregular

Amphibole Tr LA pale bottle

green

subangular glassy transparent short lath, black

inclusions.

Barite Tr Tr LA white subangular dull translucent tabular

Corundum Tr HA colourless, subrounded glassy to transparent subhedral to irregular,

blue to

subangular frosted often with black inclusion


brick red,

mustard

yellow

rounded highly

polished

opaque pisolitic

Ilmenite

Tr MA

silvery black subrounded submetallic opaque rare

Leucoxene

Phosphate

Tr HA

Tr HA

beige, sage,

grey

cream/red

mottled

rounded porcelain-

like,

polished

rounded porcelain-

like, dull

opaque smooth, irregular

opaque irregular, flattened

Rutile

Tourmaline

Tr HA

Tr HA

black, silvery-

black

black-brown,

brown

rounded submetallic subtransluc

ent to

opaque

rounded frosted translucent

to

transparent

ovate, rolled

near spherical to ovate

Zircon

Tr HA

colourless rounded glassy transparent ovate to subhedral

TOTAL % % % 100% 100% % % %


Technician: LF


Comment about

this sample:


mm +2.0 +1.2 +.8 +.4 +.3 +.25 +.20 +.10




All All None 1/8 None All


DW12-09

Ph 61 8 9361 2596

Fx 61 8 9470 1504

Our Job No.: 12042


Your Project Code:

Negative

Northern Territory



Stream Sediment

DMS Concentrate


Wet Weight kg






particles

No of particles

probed mm +2.0 +1.2 +.8 +.4 +.3 +.25 +.20 +.10


Almandine

Tr HA

pale pink rounded glassy transparent irregular

Barite Tr Tr MA white,

colourless

subrounded frosted translucent

to opaque

irregular, blocky

Corundum Tr Tr MA blue, subrounded glassy transparent subhedral

colourless to

subangular ,

translucent

Fe Oxide/Hydroxide 100 100 brown, red-

brown, yellow-

brown

rounded dull opaque rolled

Ilmenite

Tr MA

silvery black subrounded metallic opaque subhedral/anhedral

Kyanite Tr Tr MA colourless subrounded glassy transparent bladed

Leucoxene Tr HA brown, grey-

blue

rounded polished opaque anhedral

Rutile Tr HA red, black rounded sub-metallic opaque anhedral

Zircon Tr HA colourless, pink rounded glassy transparent sub/anhedral

TOTAL % % % 100% 100% % % %


Technician: BJG


Comment about

this sample:


mm +2.0 +1.2 +.8 +.4 +.3 +.25 +.20 +.10




All All All All All All


DW12-10

Ph 61 8 9361 2596

Fx 61 8 9470 1504

Our Job No.: 12042


Your Project Code:

Negative

Northern Territory



Stream Sediment

DMS Concentrate


Wet Weight kg






particles

No of particles

probed mm +2.0 +1.2 +.8 +.4 +.3 +.25 +.20 +.10


Almandine

Tr Tr

LA pale pink angular glassy transparent irregular

Amphibole Tr MA green angular dull opaque elongate/blocky

Corundum Tr MA blue, subrounded glassy transparent sub/anhedral


colourless,

yellow

red-brown,

yellow-brown

to

subangular

angular,

subangular

,

translucent

dull opaque irregular

Ilmenite Tr MA silvery-black subrounded metallic opaque subhedral

Kyanite Tr LA colourless subangular vitreous transparent tabular

Leucoxene Tr HA brown, grey-

green

subrounded polished opaque subhedral/anhedral

Phosphate Tr HA orange rounded dull opaque rolled

Rutile Tr Tr HA cherry-red,

black

rounded,

subrounded

submetallic opaque rolled

Tourmaline Tr Tr HA black-brown rounded glassy translucent irregular

Zircon Tr HA colourless,

orange

rounded glassy transparent subhedral/ovate

TOTAL % % % 100% 100% % % %


Technician: BJG


Comment about

this sample:


Appendix 15

EL27877 EL27878

Natural Resouces Exploration Pty

Daly

Natural Resouces Exploration Pty

CPX GNT COR

Clinopyroxene Garnet Corundum

Microbeam Services,

H0802 Assay_description EMP Spot Electron microprobe anaylses, core of grain SAMPLE MinCode Notes Mount Sequence Size SiO2 TiO2 Na2O Al2O3 FeO MnO MgO CaO Cr2O3 Nb2O5 V2O3 NiO K2O ZnO Fe2O3 SumOxide

H1001 mm % % % % % % % % % % % % % % % %

H1002 EMP EMP EMP EMP EMP EMP EMP EMP EMP EMP EMP EMP EMP EMP EMP EMP

H1004 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.08 0.05 0.05 0.05 0.05 0.05 0.05

D DW12-01 COR Corundum OR230812A 41 0.3 0.03 0.01 0 98.39 0.16 0 0 0 0.18 0 0.01 0.02 0 0 0 98.82

D DW12-01 COR Corundum OR230812A 42 0.3 0.03 0.01 0 97.51 0.64 0.01 0 0.01 0.21 0.05 0.01 0.01 0 0 0 98.5

D DW12-01 COR Corundum OR230812A 43 0.3 0.02 0.04 0.01 97.93 0.25 0 0.01 0.01 0.12 0 0.03 0 0 0 0 98.41

D DW12-01 COR Corundum OR230812A 44 0.3 0.02 0.02 0.01 97.28 1.36 0 0 0.01 0.44 0.01 0 0 0 0.01 0 99.16

D DW12-01 GNT OR230812A 45 0.3 38.29 0.07 0.01 21.27 28.29 0.65 4.75 6.56 0.01 0 0.06 0 0 0 0.93 100.89

D DW12-01 SPL Gahnite OR230812A 46 0.3 0 0.01 57.96 0.58 0.07 5.74 0.02 0 0.02 0 0 0.01 29.88 5.89 100.19

D DW12-01 SPL Gahnite OR230812A 47 0.3 0.01 0 57.78 1.27 0.06 4.93 0.01 0.08 0.01 0.04 0 0 30.34 5.08 99.61

D DW12-01 SPL Gahnite OR230812A 48 0.3 0.02 0.01 57.06 2.54 0.2 4.39 0.01 0.14 0.05 0.03 0.01 0 29.71 5.54 99.71

D DW12-01 SPL Gahnite OR230812A 49 0.3 0.01 0 57.16 1.78 0.1 3.85 0.01 0 0 0.02 0.03 0 31.6 5.77 100.34

D DW12-01 SPL Gahnite OR230812A 50 0.3 0.02 0 56.22 4.2 0.09 2.16 0 0.2 0 0.02 0.01 0 31.68 5.36 99.98

D DW12-01 SPL Gahnite OR230812A 51 0.3 0 0 55.13 1.19 0.25 1.84 0 0 0 0.06 0 0 34.41 6.27 99.19

D DW12-01 SPL Gahnite OR230812A 52 0.3 0 0 56.6 3.71 0.02 3.74 0 0.25 0 0.04 0.01 0.01 29.97 5.99 100.35

D DW12-01 SPL Gahnite OR230812A 53 0.3 0.01 0 54.35 0 0.2 1.39 0 0.41 0.03 0.04 0.01 0.01 36.12 7.52 100.1

D DW12-01 SPL Gahnite OR230812A 54 0.3 0 0 55.99 4.21 0.11 2.18 0.01 0.13 0.04 0.07 0 0 31.56 6.08 100.38

D DW12-01 SPL Gahnite OR230812A 55 0.3 0 0.01 57.6 4.68 0.16 4.63 0 0 0.03 0.06 0.03 0.01 27.55 5 99.75

D DW12-02 SPL Gahnite OR230812A 56 0.3 0 0.03 55.56 4.87 0.31 1.95 0.01 0 0.03 0.03 0.02 0 31.44 5.8 100.07

D DW12-03 SPL Gahnite OR230812A 57 0.3 0 0.1 53.95 0 0.05 4.05 0 0.05 0 0.07 0 0 36.99 4.57 99.82

D DW12-03 SPL Gahnite OR230812A 58 0.3 0.02 0 58 3.29 0.11 5.36 0.01 0.04 0 0.01 0 0 27.97 5.46 100.28

D DW12-04 SPL Gahnite OR230812A 59 0.3 0 0 54.86 1.1 0.23 2.04 0 0.01 0 0.02 0 0 34.06 6.71 99.09

D DW12-08 CPX Pyx OR230812A 60 0.3 51.35 0.6 0.34 2.53 6.79 0.37 15.63 19.77 0.02 0.02 0.04 0.01 0 0.03 2.12 99.63

D DW12-08 CPX Pyx OR230812A 61 0.3 52.18 0.2 0.3 1.02 6.91 0.61 14.91 21.11 0.01 0 0.01 0 0 0.06 1.62 98.95

D DW12-09 GNT OR230812A 62 0.3 38.01 0.02 0 21.59 29.38 0.85 7.66 1.2 0.03 0 0.03 0.01 0.01 0.02 1.76 100.57

D DW12-09 GNT OR230812A 63 0.3 37.75 0.02 0 21.42 29.96 1.28 6.31 2.08 0 0.04 0.03 0.02 0 0 1.69 100.6

D DW12-09 GNT OR230812A 64 0.3 37.14 0.01 0.01 20.96 33.59 1.78 4.28 1.02 0.01 0.02 0 0.03 0 0 1.52 100.39

D DW12-10 AMPH Amph? OR230812A 65 0.3 53.33 0.76 0.2 2.61 12.5 0.24 14.76 13.04 0 0.06 0.08 0.02 0.1 0 0 97.71

D DW12-10 GNT OR230812A 66 0.3 37.52 0.04 0.03 21.2 29.39 0.93 7.21 1.18 0.02 0.01 0.04 0.03 0.01 0.04 1.99 99.66

D DW12-10 GNT OR230812A 67 0.3 38.28 0.01 0.01 21.68 25.78 0.64 9.98 1.09 0.06 0 0.03 0.05 0 0.08 1.99 99.68

EOF

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year 2 annual group report daly waters project

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