xible sensors for an indoor air quality sensor system

2
Fle Hanns- Abstrac Indoor a especial assures a sensor and imp capacito with CO 2 Key wor Flexible The sen sensor ( gas sens ca. 10 p layers. A 50 μm t thin film cleanroo wafer ha Pi-foil-su glass - line/spac The hum cellulose solving exible se -Erik Endres 1 1 Fraunhofer 2 Fraunhofe ct: air quality m ly for highly the optimum r system me edimetric se ors (rh, CO 2 ) 2 measureme rds: indoor a e sensors an nsor system (meander, ca sors (IDC, lin pF) coated w All the senso hick PI foil s m process (1 om for MEM andling subs ubstrate with rough sur ce to 6 μm. midity senso e acetate but of CAB in ensors 1 , Klaus Ros r EMFT, Han h er ISC, Neun monitoring a sealed pass m compromis easuring tem ensors [1]. A demonstrat ent [2]. air quality, CO nd system consists of a. 4 k) and ne/space 6 μ with chemical ors are man substrate us 150 nm Au) MS-technolog strate. The c a – compar rface limits or is an IDC tyrate layer n an appro Fig. 1. Photo for an i e 2 , Katja Sch nsastr. 27d, 8 hanns-erik.en erplatz 2, 97 nd control a ive buildings e between a mperature, re first system es the proof O 2 sensor, g a temperat d two capacit μm, capacitan active polym nufactured on ing a fine pi ) in the EM gy on 150m challenging u red to silicon the minim coated with (CAB) [3]. A opriate solv ography of the ndoor a herbaum 2 ,R 80686 Munic ndres@emft. 7082 Würzbu at home an s and electric a good air-qu lative humid on polymer f of principle as sensor, fo ture tive nce mer n a itch MFT mm use n or mum h a After vent mix sp se an are Th a h 3-a (In Th thi tem ne co foi ree e realized stru air quali Robert Faul 1 , ch, Germany, .fraunhofer.d urg, Germany nd in cars a cal driven ca uality and ene ity and CO 2 foil with Au- e and enhan oil mems xture the lay ray pistol on nsor foil the d formed a ea. he CO 2 senso heteropolysil aminopropyle ndicator) and he heating of n film heate mperature ca ath the se mpatible to Z l technology el production ctures on a 20 ity sens Waltraud He , www.emft.f de y, www.isc.fr are essentia rs. The dema ergy saving. concentratio -thin film res ces the capa yer was depo nto the surfa solution dro rough layer or consists o oxane layer e-trimethoxy d propyltrim the CO 2 sen er (meander a. 65 °C), w ensing IDC ZIF sockets w y is compati n processes. 00 mm sheet. sor syst ell 1 , Karlhein fraunhofer.de raunhofer.de al for energy and driven v This paper d on based on sistors and in ability of prio osited with a ace. After str ops dried imm with a large of an IDC co r (copolymer y¬siloxane methoxysiloxa nsor is realiz ca. 40 , o which is glue C. All conta with 1 mm p ible to futur tem nz Bock 1 e e y saving, ventilation describes resistive nterdigital or results a manual riking the mediately e surface ated with isation of - AMO ane) [4]. zed with a operating ed under- acts are pitch. The e reel to DOI 10.5162/IMCS2012/6.2.2 IMCS 2012 – The 14th International Meeting on Chemical Sensors 531

Upload: others

Post on 13-May-2022

2 views

Category:

Documents


0 download

TRANSCRIPT

Page 1: xible sensors for an indoor air quality sensor system

FleHanns-

AbstracIndoor aespecialassures a sensorand impcapacitowith CO2

Key wor

FlexibleThe sensensor (gas sensca. 10 players. A50 µm tthin filmcleanroowafer haPi-foil-suglass - line/spac

The humcellulosesolving

exible se-Erik Endres1

1 Fraunhofer

2 Fraunhofe

ct: air quality mly for highly the optimumr system meedimetric se

ors (rh, CO2)2 measureme

rds: indoor a

e sensors annsor system (meander, casors (IDC, lin

pF) coated wAll the sensohick PI foil s

m process (1om for MEMandling subsubstrate with

rough surce to 6 µm.

midity sensoe acetate but

of CAB in

ensors 1, Klaus Rosr EMFT, Han

her ISC, Neun

monitoring asealed pass

m compromiseasuring temensors [1]. A demonstratent [2].

air quality, CO

nd system consists of

a. 4 kΩ) andne/space 6 µ

with chemicalors are mansubstrate us150 nm Au)MS-technologstrate. The c a – comparrface limits

or is an IDCtyrate layer n an appro

Fig. 1. Photo

for an ie2, Katja Sch

nsastr. 27d, 8hanns-erik.enerplatz 2, 97

nd control aive buildingse between a

mperature, refirst system es the proof

O2 sensor, g

a temperatd two capacitµm, capacitan

active polymnufactured oning a fine pi) in the EMgy on 150mchallenging ured to silicon

the minim

coated with(CAB) [3]. Aopriate solv

ography of the

ndoor aherbaum2 ,R80686 [email protected] Würzbu

at home ans and electrica good air-qulative humid on polymer f of principle

as sensor, fo

ture tive nce mer n a itch

MFT mm use n or

mum

h a After vent

mixspseanare

Tha h3-a(InThthitemnecofoiree

e realized stru

air qualiRobert Faul1,ch, Germany,.fraunhofer.durg, Germany

nd in cars acal driven cauality and eneity and CO2foil with Au-

e and enhan

oil mems

xture the layray pistol onnsor foil the d formed a ea.

he CO2 sensoheteropolysilaminopropyle

ndicator) andhe heating of n film heatemperature caath the sempatible to Zl technologyel production

ctures on a 20

ity sens Waltraud He, www.emft.f

de y, www.isc.fr

are essentiars. The demaergy saving. concentratio

-thin film resces the capa

yer was deponto the surfasolution drorough layer

or consists ooxane layer e-trimethoxyd propyltrimthe CO2 sen

er (meander a. 65 °C), wensing IDCZIF sockets wy is compatin processes.

00 mm sheet.

sor systHell1, Karlhein

fraunhofer.de

raunhofer.de

al for energyand driven vThis paper d

on based onsistors and inability of prio

osited with aace. After strops dried imm

with a large

of an IDC cor (copolymery¬siloxane methoxysiloxansor is realiz

ca. 40 Ω, owhich is glueC. All conta

with 1 mm pible to futur

tem nz Bock1

e

e

y saving, ventilation describes resistive

nterdigital or results

a manual riking the mediately e surface

ated with isation of - AMO

ane) [4]. zed with a operating ed under-acts are pitch. The e reel to

DOI 10.5162/IMCS2012/6.2.2

IMCS 2012 – The 14th International Meeting on Chemical Sensors 531

Page 2: xible sensors for an indoor air quality sensor system

Experimental After manufacturing the sensors were tested, separated using a laser process and coated with the active layers. The test of the thin film resistors was performed on a heated chuck. The gas sensors were coated and afterwards characterized within the Fraunhofer EMFT gas measuring unit [5] whereby a specific mechanical adapter was constructed and fabricated to interface the measurement system.

Results Characterization of the temperature sensor and the heater element is a reproducible TCR of 1630 ppm. The humidity sensors show a nearly linear humidity response within the indoor humidity range (slope 0.23 pf / 10 % rh), fig. 2.

Fig. 2. Calibration curve of the humidity sensor (lin. response, no sensitivity to CO2)

Also the CO2 sensors show a reproducible, nonlinear response to CO2 with a detection range from natural CO2 (ca. 400 ppm) up to 5000 ppm (ca. 50 fF / 1000 ppm CO2) fig. 3.

60 120 180 240 30011,55p

11,60p

11,65p

11,70p

11,75p

capa

cita

nce

[F]

time [min]

0100020003000

12000

13000

14000

15000

CO

2 [p

pm]

Fig. 3: Typical CO2 calibration curve (T = 25 °C, 50 % rh).

The cross sensitivity of the CO2 Sensor to humidity, caused by humidity adsorption of the layer and the substrate can be compensated numerically using a nonlinear formula [6].

Conclusion The feasibility for indoor air climate sensors, based on foil substrates fabricated in the MEMS technology of Fraunhofer EMFT was investigated Several sensor characterization measurements are executed. The experiments show the possibility to develop a fully flexible indoor air quality sensor system with a minimum lifetime of 6 months. All sensors are compatible to the measuring capability of integrated circuits available on the market.

Acknowledgements This work was financed by the European Commission within the FP7 Strep-ICT- INTERFLEX GA: 247710.

References [1] Endres, H.-E.:Air quality measurement and

management. In: Gassmann, O.: Sensors in intelligent buildings Weinheim: Wiley-VCH, 2001, S.85-102(Sensors applications 2), DOI:10.1002/3527600302.ch2c)

[2] Oprea A. et al., Temperature, humidity and gas sensors integrated on plastic foil for low power applications, Sensors and Actuators B 140 (2009), pp 227-232, DOI:10.1016/j.snb.2009.04.019.

[3] Oprea A. et al., Capacitive humidity sensors on flexible RFID labels, Sensors and Actuators B132 (2008),pp 404-410, DOI:10.1016/j.snb.2007.10.010..

[4] Stegmeier S. et al.: Sensing mechanism of room temperature CO2 sensors based on primary amino groups, Sensors and Actuators B154(2011), pp. 270-276, DOI: 10.1016/j.snb.2010.01.022.

[5] Endres, H.-E. et al.: A test system for gas sensors, Sensors and Actuators. B23(1995),pp.163-172

[6] Endres, H.-E. et al.:A capacitive CO2 sensor system with suppression of the humidity interference. Sensors and Actuators. B57(1999), pp.83-87, DOI:10.1016/S0925-4005(99)00060-X)

10 20 30 40 50 6016,6

16,8

17,0

17,2

17,4

17,6

17,8

Cap

acita

nce

[pF]

rel. humidity [%]

DOI 10.5162/IMCS2012/6.2.2

IMCS 2012 – The 14th International Meeting on Chemical Sensors 532