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Topological transitions and singularities in fluids: Life of a Drop Manne Siegbahn Memorial Lecture, Oct. 18, 2007 During its brief existence, drop goes through many stages. Shape changes often accompanied by dynamic singularities*. *Dynamic singularities: infinitesimally small, very short time Test-bed for understanding broad class of phenomena.

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Page 1: Topological transitions and singularities in fluids: Life of a Drop Manne Siegbahn Memorial Lecture, Oct. 18, 2007 During its brief existence, drop goes

Topological transitions and singularities in fluids: Life of a Drop

Manne Siegbahn Memorial Lecture, Oct. 18, 2007

During its brief existence, drop goes through many stages.

Shape changes often accompanied by dynamic singularities*.*Dynamic singularities: infinitesimally small, very short time

Test-bed for understanding broad class of phenomena.

Page 2: Topological transitions and singularities in fluids: Life of a Drop Manne Siegbahn Memorial Lecture, Oct. 18, 2007 During its brief existence, drop goes

Topology changes - real transition

Neck radius 0 (curvature )

Pressure Cannot do simulation to get to other side of snapoff

?

Is there understanding for these transitions like that for thermodynamic phase transitions?

How do drops fall, break apart?

Page 3: Topological transitions and singularities in fluids: Life of a Drop Manne Siegbahn Memorial Lecture, Oct. 18, 2007 During its brief existence, drop goes

Similar behavior: Star formation

PILLARS OF CREATION IN STAR-FORMING REGION

Gas Pillars in M16 - Eagle NebulaHubble Space Telescope 4/1/95

Page 4: Topological transitions and singularities in fluids: Life of a Drop Manne Siegbahn Memorial Lecture, Oct. 18, 2007 During its brief existence, drop goes

Similar behavior: Breakup of bacteria colonies

Elena Budrene - Harvard

Dynamic singularities appear everywhere in physics -

celestial microscopic nuclear fission…

Page 5: Topological transitions and singularities in fluids: Life of a Drop Manne Siegbahn Memorial Lecture, Oct. 18, 2007 During its brief existence, drop goes

Who Did It

Experiment Theory/Simulation Osman Basaran Itai Cohen Michael Brenner Nathan Keim Pankaj Doshi Xiangdong Shi Jens Eggers Lei Xu Laura Schmidt Wendy Zhang

Funding: NSF

Page 6: Topological transitions and singularities in fluids: Life of a Drop Manne Siegbahn Memorial Lecture, Oct. 18, 2007 During its brief existence, drop goes

Birth and Childhood

A happy childhood!

Surface tension + gravity

Page 7: Topological transitions and singularities in fluids: Life of a Drop Manne Siegbahn Memorial Lecture, Oct. 18, 2007 During its brief existence, drop goes

Rayleigh-Plateau Instability

Surface area decreases if L 2 R.Unstable to perturbations.

Pressure greatest at minimum thickness liquid squeezed out.

L

R

Page 8: Topological transitions and singularities in fluids: Life of a Drop Manne Siegbahn Memorial Lecture, Oct. 18, 2007 During its brief existence, drop goes

Bolas Spider

Page 9: Topological transitions and singularities in fluids: Life of a Drop Manne Siegbahn Memorial Lecture, Oct. 18, 2007 During its brief existence, drop goes

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Midlife Crisis

Page 10: Topological transitions and singularities in fluids: Life of a Drop Manne Siegbahn Memorial Lecture, Oct. 18, 2007 During its brief existence, drop goes

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Midlife Crisis

Page 11: Topological transitions and singularities in fluids: Life of a Drop Manne Siegbahn Memorial Lecture, Oct. 18, 2007 During its brief existence, drop goes

Water into Air

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Singularity is same even though gravity points in opposite direction

Xiangdong Shi and Michael Brenner

Page 12: Topological transitions and singularities in fluids: Life of a Drop Manne Siegbahn Memorial Lecture, Oct. 18, 2007 During its brief existence, drop goes

Water Drops

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Page 13: Topological transitions and singularities in fluids: Life of a Drop Manne Siegbahn Memorial Lecture, Oct. 18, 2007 During its brief existence, drop goes

How to Think About Shapes: Scale invariance(borrowed from statistical mechanics)

Breakup radius smaller than any other length.Dynamics insensitive to all other lengths.

Flow depends only on shrinking radius.

Page 14: Topological transitions and singularities in fluids: Life of a Drop Manne Siegbahn Memorial Lecture, Oct. 18, 2007 During its brief existence, drop goes

How to Think About Shapes: Scale invariance(borrowed from statistical mechanics)

Breakup radius smaller than any other length.Dynamics insensitive to all other lengths.

Flow depends only on shrinking radius.

But: Radius depends on flow (which depends on radius (which depends on flow(which depends on radius (which depends on flow

(which depends on radius (which depends on flow (which depends on radius(which depends on flow (which depends on radius(which depends on flow. . .

Self-similar structure: Blow up any part regain original.

Universal shapes

Page 15: Topological transitions and singularities in fluids: Life of a Drop Manne Siegbahn Memorial Lecture, Oct. 18, 2007 During its brief existence, drop goes

Similarity Solution

h(z,t) = f(t) H[(z-zo)/f(t)ß]

Similarity solutions same AT DIFFERENT TIMES with different magnifications along h and z.

Scaling determined by force balance at singularity.PDE ODE

z

h

Keller and Miksis (83); Eggers, RMP (97)

Page 16: Topological transitions and singularities in fluids: Life of a Drop Manne Siegbahn Memorial Lecture, Oct. 18, 2007 During its brief existence, drop goes

Unhappy drops are all unhappy in their own way

Explore different asymptotic regimes by tuning parameters.

Depends on: viscosity of inner fluid, viscosity ratio of fluids, (air is a fluid)density of inner fluid, density difference, surface tension, nozzle diameter, D

Page 17: Topological transitions and singularities in fluids: Life of a Drop Manne Siegbahn Memorial Lecture, Oct. 18, 2007 During its brief existence, drop goes

Scaling Profiles - Glycerol into Oil Stretching axes by different amounts at different times

produces master curve

Itai Cohen, Michael Brenner Jens Eggers, Wendy Zhang

= (z-zo)/f(t)ß

= h

(z,t)

/f(t)

Page 18: Topological transitions and singularities in fluids: Life of a Drop Manne Siegbahn Memorial Lecture, Oct. 18, 2007 During its brief existence, drop goes

Singularities tame non-linearity of Navier-Stokes Eqs.

Role of scale invariance -

borrowed from critical phenomena

Near singularity, dynamics insensitive to all other lengths

Emphasize what is Universal

But . . .

Page 19: Topological transitions and singularities in fluids: Life of a Drop Manne Siegbahn Memorial Lecture, Oct. 18, 2007 During its brief existence, drop goes

Water into OilNot so simple

Persistence of memory.

No similarity solution.

No universality!

Separation of scales but also of axial and

radial length scales.

I. Cohen, W. ZhangP. Doshi, O. BasaranP. Howell, M. Siegel

Page 20: Topological transitions and singularities in fluids: Life of a Drop Manne Siegbahn Memorial Lecture, Oct. 18, 2007 During its brief existence, drop goes

Water into OilContinued…

Viscosity of water begins to matter

creates very fine thread.

Page 21: Topological transitions and singularities in fluids: Life of a Drop Manne Siegbahn Memorial Lecture, Oct. 18, 2007 During its brief existence, drop goes

Remember water drop in air?

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Page 22: Topological transitions and singularities in fluids: Life of a Drop Manne Siegbahn Memorial Lecture, Oct. 18, 2007 During its brief existence, drop goes

Remember water drop in air?

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What about air drop in water (i.e., a bubble)?

N. Keim, W. Zhang

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Page 23: Topological transitions and singularities in fluids: Life of a Drop Manne Siegbahn Memorial Lecture, Oct. 18, 2007 During its brief existence, drop goes

Perturbations

N. Keim, W. Zhang

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slight nozzle tilt oblong nozzle

Page 24: Topological transitions and singularities in fluids: Life of a Drop Manne Siegbahn Memorial Lecture, Oct. 18, 2007 During its brief existence, drop goes

The drop falls splashes

Is splash interesting?Break-up localizes energy from the kinetic energy into

singular points as surface ruptures. How?

Coronal splash

Lei Xu, Wendy Zhang

Page 25: Topological transitions and singularities in fluids: Life of a Drop Manne Siegbahn Memorial Lecture, Oct. 18, 2007 During its brief existence, drop goes

Drop splashes

Drop of alcohol hitting smooth, dry slide

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Lei Xu, Wendy Zhang

Page 26: Topological transitions and singularities in fluids: Life of a Drop Manne Siegbahn Memorial Lecture, Oct. 18, 2007 During its brief existence, drop goes

Drop splashes

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atmospheric pressure 1/3 atmospheric pressure

(Mt. Everest)

Lei Xu, Wendy Zhang

Page 27: Topological transitions and singularities in fluids: Life of a Drop Manne Siegbahn Memorial Lecture, Oct. 18, 2007 During its brief existence, drop goes

0

2

4

6

8

0 20 40 60 80 100

V0

(m/s

)

PT (kPa)

Non Monotonic (in all cases)

Splash

No Splash

Impact Velocity vs. Threshold Pressure

Non-monotonic

Lei Xu, Wendy Zhang

Page 28: Topological transitions and singularities in fluids: Life of a Drop Manne Siegbahn Memorial Lecture, Oct. 18, 2007 During its brief existence, drop goes

Singularity during splash

t0 Vexp (t - t0)-0.5

Drop rim expands infinitely rapidly at moment of impact.

Page 29: Topological transitions and singularities in fluids: Life of a Drop Manne Siegbahn Memorial Lecture, Oct. 18, 2007 During its brief existence, drop goes

At high viscosity, does air matter?

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Lei Xu, Casey Stevens, Nathan Keim

5 cSt

High pressure

Low pressure

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Page 30: Topological transitions and singularities in fluids: Life of a Drop Manne Siegbahn Memorial Lecture, Oct. 18, 2007 During its brief existence, drop goes

At high viscosity, does air matter?

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are needed to see this picture.

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10 cSt

100 kPa

43 kPa

Air still matters.

Does compressibility?

Page 31: Topological transitions and singularities in fluids: Life of a Drop Manne Siegbahn Memorial Lecture, Oct. 18, 2007 During its brief existence, drop goes

1000 cSt

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Page 32: Topological transitions and singularities in fluids: Life of a Drop Manne Siegbahn Memorial Lecture, Oct. 18, 2007 During its brief existence, drop goes

Last stage of the drop: What remains?

Why are drops always ring-shaped?

Page 33: Topological transitions and singularities in fluids: Life of a Drop Manne Siegbahn Memorial Lecture, Oct. 18, 2007 During its brief existence, drop goes

Black

Page 34: Topological transitions and singularities in fluids: Life of a Drop Manne Siegbahn Memorial Lecture, Oct. 18, 2007 During its brief existence, drop goes

How does evaporation bring everything to edge?

Drop pinned at contact line

Analogy with Electrostatics

(steady state diffusion)

vapor saturated at surface

Equations for potential of a charged conductor:at points, electric field (evaporation rate) diverges.

Page 35: Topological transitions and singularities in fluids: Life of a Drop Manne Siegbahn Memorial Lecture, Oct. 18, 2007 During its brief existence, drop goes

Every stage of drop’s life arouses astonishment. Ideas used to treat singularities appear in different variations - from

thermodynamic to topological transitions

A great idea “is like a phantom ocean beating upon the shores of human life in successive waves of specialization.”

A. N. Whitehead

Surprises and beauty await us… even in the most familiar phenomena!

Page 36: Topological transitions and singularities in fluids: Life of a Drop Manne Siegbahn Memorial Lecture, Oct. 18, 2007 During its brief existence, drop goes

END

Page 37: Topological transitions and singularities in fluids: Life of a Drop Manne Siegbahn Memorial Lecture, Oct. 18, 2007 During its brief existence, drop goes

Navier-Stokes Equation

[v/t + (v . )]v = -P + 2v + F

inertial terms = internal pressure + viscous force + body force

+ Incompressibility Equation

+ Laplace pressure equation for surface

Page 38: Topological transitions and singularities in fluids: Life of a Drop Manne Siegbahn Memorial Lecture, Oct. 18, 2007 During its brief existence, drop goes

Remember water drop in air?

QuickTime™ and aPhoto - JPEG decompressor

are needed to see this picture.

N. Keim, W. Zhang

Singularity sensitive to small perturbations - remembers axial asymmetry

slight nozzle tilt

What about air drop in water (i.e., a bubble)?

Page 39: Topological transitions and singularities in fluids: Life of a Drop Manne Siegbahn Memorial Lecture, Oct. 18, 2007 During its brief existence, drop goes

Memory of all initial amplitudes

Modes oscillate: an() e i cn ln

n=3

Laura Schmidt & Wendy Zhang Nathan Keim

Page 40: Topological transitions and singularities in fluids: Life of a Drop Manne Siegbahn Memorial Lecture, Oct. 18, 2007 During its brief existence, drop goes

SF6

V0 vs. PT for different gases

0

2

4

6

8

0 20 40 60 80 100

airHeKr

V0

(m/s

)

PT (kPa)

SF6

Page 41: Topological transitions and singularities in fluids: Life of a Drop Manne Siegbahn Memorial Lecture, Oct. 18, 2007 During its brief existence, drop goes

Data Collapse for Different GasesV

0 (m

/s)

0

2

4

6

8

0 20 40 60 80 100

air He Kr SF6

√M PT (arb. unit)

Page 42: Topological transitions and singularities in fluids: Life of a Drop Manne Siegbahn Memorial Lecture, Oct. 18, 2007 During its brief existence, drop goes

Model

V0

Ved

Destabilizing stress: G ~ G CG Ve

~ P M/kT √kT/M √RV0/2t

Stabilizing stress: L = /d = / √Lt

The ratio of G and L determines splashing:

G /L ~ 1 at threshold

Page 43: Topological transitions and singularities in fluids: Life of a Drop Manne Siegbahn Memorial Lecture, Oct. 18, 2007 During its brief existence, drop goes

Different liquid viscosities

PT (kPa)

0

2

4

6

8

0 20 40 60 80 100

methanolethanol2-propanol

V0

(m/s

)

Page 44: Topological transitions and singularities in fluids: Life of a Drop Manne Siegbahn Memorial Lecture, Oct. 18, 2007 During its brief existence, drop goes

Threshold values of G/L all liquids, gases and velocities

G

ΣL

= γMPT •RV0

2kT•

ν L

σ

V0(m/s)

G/ L

0

0.2

0.4

0.6

0.8

1

0 2 4 6 8

Turn over V0

Page 45: Topological transitions and singularities in fluids: Life of a Drop Manne Siegbahn Memorial Lecture, Oct. 18, 2007 During its brief existence, drop goes

Glycerol/water

100 x viscosity of water

Page 46: Topological transitions and singularities in fluids: Life of a Drop Manne Siegbahn Memorial Lecture, Oct. 18, 2007 During its brief existence, drop goes

Glycerol/water

Xiangdong Shi, Michael Brenner

Page 47: Topological transitions and singularities in fluids: Life of a Drop Manne Siegbahn Memorial Lecture, Oct. 18, 2007 During its brief existence, drop goes

Glycerol/water

Xiangdong Shi, Michael Brenner

Page 48: Topological transitions and singularities in fluids: Life of a Drop Manne Siegbahn Memorial Lecture, Oct. 18, 2007 During its brief existence, drop goes

Scaling for different

Page 49: Topological transitions and singularities in fluids: Life of a Drop Manne Siegbahn Memorial Lecture, Oct. 18, 2007 During its brief existence, drop goes

Atmospheric pressure (100kPa)

Page 50: Topological transitions and singularities in fluids: Life of a Drop Manne Siegbahn Memorial Lecture, Oct. 18, 2007 During its brief existence, drop goes

Reduced pressure (17kPa)

Page 51: Topological transitions and singularities in fluids: Life of a Drop Manne Siegbahn Memorial Lecture, Oct. 18, 2007 During its brief existence, drop goes

“I am an old man now and when I die and go to Heaven there are two matters on which I hope for enlightenment. One is quantum electrodynamics, and the other is turbulent motion of fluids. And about the former I am really rather optimistic.” Sir Horace Lamb (1932)

Dynamic singularities appear everywhere in physics - from celestial to microscopic to nuclear fission…

Page 52: Topological transitions and singularities in fluids: Life of a Drop Manne Siegbahn Memorial Lecture, Oct. 18, 2007 During its brief existence, drop goes

Water falling in air

NOT like cartoon!

2 snapoffs:

Top Bottom

Xiangdong ShiMichael Brenner

Page 53: Topological transitions and singularities in fluids: Life of a Drop Manne Siegbahn Memorial Lecture, Oct. 18, 2007 During its brief existence, drop goes

As it evaporates, what remains?

Page 54: Topological transitions and singularities in fluids: Life of a Drop Manne Siegbahn Memorial Lecture, Oct. 18, 2007 During its brief existence, drop goes

Data collapse of different liquids in high-velocity regime in air

V0 (

m/s

)

PT √L (arb. units)

0

2

4

6

8

0 20 40 60 80 100

methonalethanol2-propanol

Page 55: Topological transitions and singularities in fluids: Life of a Drop Manne Siegbahn Memorial Lecture, Oct. 18, 2007 During its brief existence, drop goes

Physical constants of gases

gas He Air Kr SF6

Molecular

Weight

(Dalton)4 29 83.8 146

Dynamic viscosity

(Pa s)20 18.6 25.6 15.3