the varner groupcdn.varner.eu/global/varner/csr/downloads_csr/thevarnergroups...the varner group...

TThhee VVaarrnneerr GGrroouuppSSUUPPPPLLIIEERR RREEQQUUIIRREEMMEENNTTSS MMAANNUUAALL

PPaarrtt IIIIII..CChheemmiiccaall SSuubbssttaanncceess

NNoovveemmbbeerr 22001111

Supplier Requirements Manual – version 01.2011 - Copyright © CSR, The Varner Group, Norway 2011 2

Companies within the Varner Group

BIK BOK

CARLINGS

CUBUS

DRESSMANN

DRESSMANN XL

SOLO

URBAN

VIVIKES

VOLT

WEARHOUSE

WOW


INDEXIII. CHEMICAL SUBSTANCES

3.1 Safe handling of chemical substances

3.2 List of restricted substances

3.3 List of restricted substances - Packaging

3.4 Chemical Testing

3.5 Chemical Certificate

Last up-dated November 11


3.1 Safe handling of chemical substances

Environmental measures shall be taken throughout the production chain. Chemical substances and preparations shall be carefully managed and the use of chemicals in the production of goods to the Varner Group is clearly regulated.

List of all chemicals used in the productionAll suppliers to the Varner Group shall establish and maintain a list of all chemical substances used in the production process and maintenance. Upon request, suppliers shall submit the list to the CSR department and/or to auditors performing a social audit according to the Varner Group Code of Conduct. The list shall include the name of the chemical product, the purpose/area of use and a reference to a Material Safety Data Sheet (MSDS).

Written policy Suppliers shall have a written procedure for the procurement, storage, handling and use of chemicals include guidelines on safe handling and use of different chemicals, with specific emphasis on hazardous chemicals. Suppliers shall in addition appoint a responsible person in charge of implementing measures in accordance with these regulations.

Competence and Training Suppliers must ensure that the risk associated with each chemical substance is assessed, understood and communicated to all employees. Employees that procure, store, handle and use chemicals must have the right competence and be sufficiently trained; records from training shall be kept.

Storage Supplier shall prevent chemicals from leaking to air, ground and water. Chemical storage areas require specific design and equipment such as construction materials, lighting, ventilation and fire extinguishers. It shall include first aid and eyewash equipment. Additional requirements apply to chemicals that are classified as flammable or combustible liquids. Storage of liquid chemicals shall be free of drainage holes and protected by sills.

Hazardous Waste DisposalSupplier shall have a policy for disposing hazardous waste materials. Hazardous waste must not be allowed to accumulate and hazardous waste collection must be arranged through certified firms. The frequency of collection is dependent upon the type and amount of waste generated. Supplier shall keep a record of all waste collections.


3.2 List of restricted substances

Being able to offer our customers products without harmful chemicals is crucial. The list of restricted substances constitutes an essential part of the Varner Group Requirements Manual. It includes substances commonly found in apparel, accessories and packaging.

The list of restricted substances applies to all our suppliers and their sub-contractors. All dye houses, printing facilities, suppliers of raw materials or chemicals, laundries, tanneries or main production factories ought to follow our requirements.

Table 1 provides a quick review of the major restricted substances and the risk level associated with each substance for different product descriptions/compositions. Table 2 & 3 are extensive lists. Those lists the maximum concentration value allowed according to the Varner Group regulations for every restricted substance.

Tables explanation

For every substance, the list states the identification number (CAS No) according to Chemical Abstract Services. The ++ sign means that there may be several substances and CAS numbers covered by the specification. Stated numbers are examples of substances covered.

The list also gives the test methods that must be used for chemical analysis.

Symbols:

Legal restrictions within Norway and/or the EU that regulate the use of the substance exist. A fact sheet explaining the harmful health and environmental effects of the substance, its main use,

legal regulations and standard test methods is available (contact the CSR-department for details).


Table 1 – Summary of the major restricted substances and the risk level associated with each of them for different product compositions

Product Description / Composition

Tex

tiles

-N

atur

al F

iber

s

Tex

tiles

-Sy

nthe

tic F

iber

s

Tex

tiles

-Bl

end

Fibe

rs

Pla

stic

s, ru

bber

pro

duct

s

Coa

ting,

Prin

ts

Lea

ther

M

etal

Par

ts /

Jew

elle

ry

Allergenic Disperse Dyes

APEO

Azo Dyes

Cancerogenic Dyes

Chlorinated Organic Carriers

Chlorinated paraffins

Chlorinated Phenols - PCP

Chromium VI

Dimethyl Fumarate - DMFu

Extractable Heavy Metals

Flame Retardants *

Formaldehyde

Isocyanates

Nickel

Organic Solvents

Organotin Compounds

PAHs

PCB & PCT

Pesticides

PFOA & PFOS **

Phthalates

PVC

Quaternary Ammonium Salts

Total Cadmium

Total Lead

The risk level associated with the chemical substance is very high The risk level associated with the chemical substance is high.

* If treated with flame retardants** If treated with water-repellent finishing


Table 2–Extensive list of restricted substances Apparel/ Accessories/ Footwear

Please note, unless otherwise is stipulated in the Restricted Substances List, all suppliers are required to follow the EU regulatory framework for Chemicals.

FAMILY OF CHEMICAL SUBSTANCES CAS No Test Methods Varner requirements

Children< 3 yrs

Adults &Children >3 yrs

ALKYLPHENOL ETHOXYLATES

ALKYLPHENOL ETHOXYLATES (APEO)Nonionic tensides. May be used in detergents and cleaning agents.Nonylphenol ethoxylates(NPEO; nonylphenol polyethylene glycol ether; nonylphenoxy polyethoxy ethanol)

Nonylphenol (decomposition product)

26027-38-39016-45-9

++

25154-52-3

Solvent extraction followed by GC-

MS or LC-MS

Limit value 100 mg/kg for each

Octylphenol ethoxylates

Octylphenol (decomposition product)((1,1,3,3-Tetramethylbutyl)-phenol)

9063-89-2++

27193-28-8α-Sulfo-omega-(nonylphenoxy)-poly(oxy-1,2-ethanediyl) ammonium salt

9051-57-4

α-[4-(1,1,3,3-Tetramethylbutyl)phenyl]-omega-hydroxy-poly(oxy-1,2-ethanediyl)

9002-93-1

Other alkylphenol ethoxylates ++

BIOCIDES / PESTICIDES / FUNGICIDES

BIOCIDES / PESTICIDES / FUNGICIDES Biocides/Pesticides are used in the production of natural fibers like cotton, ramie, flax, wool etc. to protect against insects, fungus, plants etc. 2,4,5-T 93-76-5

Solvent Extractionfollowed by

GC-MS

Totalcontent

should not exceed

0,5 mg/kg

Total content

should not exceed 1

mg/kg

2,4-D 94-75-7Azinophosmethyl 86-50-0Azinophosethyl 2642-71-9Aldrine 309-00-2Bromophos-ethyl 4824-78-6Captafol 2425-06-1Carbaryl(1-Naphthalenol methylcarbamate)

63-25-2

Chlordane 57-74-9Chlordimeform(N'-(4-Chloro-2-methylphenyl)-N,N-dimethyl-methanimidamide)

6164-98-3

Chlordecone(Kepone)

143-50-0

Chlorfenvinphos 470-90-6Chlorobenzilate 510-15-6Coumaphos 56-72-4Cyfluthrin 68359-37-5Cyhalothrin 91465-08-6

Cypermethrin 52315-07-8DEF 78-48-8Deltamethrin 52918-63-5



Children< 3 yrs


BIOCIDES / PESTICES / FUNGICIDES

BIOCIDES / PESTICES / FUNGICIDES (contrinue)Biocides/Pesticides are used in the production of natural fibers like cotton, ramie, flax, wool etc. to protect against insects, fungus, plants etc. DDD(1,1-Dichloro-2,2-bis(p-chlorophenyl)ethane; dichloro-diphenyl-dichloroethane; 1,1'-(2,2-dichloroethylidene)bis[4-chlorobenzene)

53-19-072-54-8

Solvent Extraction followed by

GC-MS

Totalcontent

should not exceed 0,5

mg/kg

Totalcontent

should not exceed 1

mg/kg

DDEDichloro-diphenyl-dichloro ethylene

3424-82-672-55-9

DDT(Dichloro-diphenyl-trichloroethane; 1,1'-(2,2,2-trichloroethylidene)bis[4-chlorobenzene],

50-29-3789-02-6

Diazinon 333-41-5

Dichlorprop 120-36-5Dicrotophos 141-66-2

Dieldrin 60-57-1

Dimethoate 60-51-1Dinozeb and its salts 88-85-7Endosufan, α 959-98-8Endosulfan, β 33213-65-9Endrine 72-20-8Esfenvalerate 66230-04-4Fenvalerate 51630-58-1Heptachlor 76-44-8Heptachloroepoxide 1024-57-3Hexabromo-1,1'-biphenyl(BP-6)

36355-01-8

Hexachlorobenzene 118-74-1α-Hexachlorocyclohexane 319-84-6β-Hexachlorocyclohexane 319-85-7δ-Hexachlorocyclohexane 319-86-8Isodrine 465-73-6Isothiazolinones (sensitizing)

2-Octyl-2H-isothiazol-3-one (octhilinone (ISO))

5-chloro-2-methyl-2H-isothiazol-3-one2-methyl-2H-isothiazol-3-one

26530-20-126172-55-42682-20-4

Kelevane 4234-79-1Kepone 143-50-0Lindane(γ-HCH, including mixtures of isomers of HCH (BHC))

58-89-9 608-73-1

Malathion 121-75-5MCPA 94-74-6MCPB 94-81-5Mecoprop (MCPP) 93-65-2Methamidophos 10265-92-6Methoxychlor 72-43-5



Children< 3 yrs


BIOCIDES / PESTICES / FUNGICIDES

BIOCIDES / PESTICES / FUNGICIDES (contrinue)Biocides/Pesticides are used in the production of natural fibers like cotton, ramie, flax, wool etc. to protect against insects, fungus, plants etc. Methylbromide 74-83-9

Solvent Extractionfollowed by

GC-MS

Total content


mg/kg

Total content


mg/kg

Mirex 2385-85-5

Monocrotophos 6923-22-4

Parathion 56-38-2

Quinalphos 13593-03-8

Parathion-methyl 298-00-0

Perthane (Ethylene) 72-56-0Phosdrin/ Mevinphos 7786-34-7Strobane 8001-50-1Telodrin (Isobenzan) 297-78-9Toxaphene 8001-35-2

Triffluralin 1582-09-8

CHLORINATED BENZENES, TOLUENES, NAPHTALENES & XYLENES

CHLORINATED BENZENES, TOLUENES, NAPHTALENES & XYLENESLegal regulationsChlorinated naphthalenes ++


GC-MS

Total content should not exceed 1 mg/kg

Chlorinated xylenes ++Chlorotoluenes(Chloromethylbenzenes)

o-Chlorotoluene

++

95-49-8Dichlorobenzenes

1,2-Dichlorobenzene1,3-Dichlorobenzene1,4-DichlorobenzeneDichloromethylbenzene

++95-50-1

541-73-1106-46-798-87-3

Dichlorotoluenes

2,6-Dichlorotoluene2,4-Dichlorotoluene3,4-Dichlorotoluene

29797-40-8 ++

118-69-495-73-895-75-0

Hexachlorobenzenes 118-74-1++

Monochlorobenzene 108-90-7Pentachlorobenzenes 608-93-5

++Pentachlorotoluenes 877-11-2

++Tetrachlorobenzenes ++Tetrachlorotoluenes ++Trichlorobenzenes

1,2,4-Trichlorobenzene1,2,3-Trichlorobenzene

12002-48-1 ++

120-82-187-61-6

Trichlorotoluenes(Trichloromethylbenzenes)

++



Children< 3 yrs


CHLORINATED BENZENES, TOLUENES, NAPHTALENES & XYLENESCHLORINATED BENZENES, TOLUENES, NAPHTALENES & XYLENES (Other – no legal regulations)C3-Alkylbenzenes

1,2,4-Trimethylbenzene++

95-63-6


GC-MS

Total content should not exceed 1 mg/kg

C4-AlkylbenzenesButylbenzene

++104-51-8

68411-44-9Biphenyl 92-52-42-Chlorophenol(o-Chlorophenol)

95-57-8

1,1'-Oxybis-benzene(Diphenyl oxide) 101-84-8

m-Phenylphenol([1,1'-Biphenyl]-ol; Hydroxybiphenyl)

92-69-3

Propylbenzene 103-65-1Tetrachloroethylene(Perchloroethylene)

127-18-4

1,2,3,4-Tetrahydro-naphthalene(Tetrahydronaphthalene; benzocyclohexane)

119-64-2

CHLORINATED & OTHER PHENOLS

CHLORINATED & OTHER PHENOLS

Chlorinated phenols, and salts and esters of these

++Not

detected(detection limit 0.05

mg/kgfor each)

Not detected, (detection limit 0.5 mg/kg

for each)

5-Chloro-2-(2,4-dichlorophenoxy)-phenol(Triclosan)

3380-34-5 Solvent Extraction followed by

GC-MSPentachlorophenol and its salts or esters(PCP)

87-86-5++

Textile: § 64 LFGB B82.02-8

Leather: BS EN ISO 17070

2-Phenylphenol [(1,1’-Biphenyl)-2-ol; o-phenylphenol; 2-biphenylol; 2-hydroxybiphenyl; OPP]

90-43-7

50 mg/kg

Tetrachlorophenol and its salts and esters TeCP

Including tetrachlorophenoxy compounds

25167-83-3935-95-558-90-2

4901-51-3++

Not detected

(detection limit 0.05

mg/kgfor each)

Not detected

(detection limit 0.5 mg/kg

for each)

CHLOROPARAFFINSCHLOROPARAFFINS

Medium-chained chlorinated paraffins, C14-C17(MCCPs)

85535-85-9GC-MS or

LC-MSNot detected

(detection limit 100 mg/ kgfor each)Short-chained chlorinated paraffins

(SCCPs; chloroalkanes; C10-13)85535-84-8



Children< 3 yrs


DIMETHYLFUMARATE

DIMETHYLFUMARATEDMFuDimethylfumarate(DMFu)

624-49-7Solvent Extraction

followed by GC-MS

Not detected(detection limit 0,1 mg/kg)

DYES

ACID DYESAcid dyes that are classified carcinogenic and/or sensitising/allergenic.C.I. Acid Black 48; C.I. 65 005(1,1'-Iminobis[4-amino-9,10-anthracenedione, sulfonated)

1328-24-1

DIN 54231Not detected

(detection limit 15 mg/kg for each)

C.I. Acid Black 194 61931-02-0C.i. Acid Blue 113; C.I. 26 360(8-(Phenylamino)-5-[[4-[(3-sulfophenyl)azo]-1-naphthalenyl]azo]-1-naphthalenesulfonic acid,disodium salt)

3351-05-1

C.I. Acid Orange 45; C.I. 22 195(3-Amino-4-[[4'-[[4-[[(4-methylphenyl)sulfonyl]oxy]phenyl]azo][1,1'-biphenyl]-4-yl]azo]-2,7-naphthalenedisulfonic acid, disodium salt)

2429-80-3

C.I. Acid Orange 156C.I. Acid Red 4; C.I. 14 710(4-Hydroxy-3-[(2-methoxyphenyl)azo]-1-naphthalenesulfonic acid, monosodium salt)

5858-39-9

C.I. Acid Red 5, disodium salt; C.I. 14 905(4-Hydroxy-3-[(2-methoxyphenyl)azo]-2,7-naphthalenedisulfonic acid, disodium salt)

5858-63-9

C.I. Acid Red 24; C.I. 16 140C.I. Acid Red 26; C.I. 16 150(4-[(2,4-Dimethylphenyl)azo]-3-hydroxy-2,7-naphthalenedisulfonic acid, disodium salt)

3761-53-3

C.I. Acid Red 73; C.I. 27 290(7-Hydroxy-8-[[4-(phenylazo)phenyl]azo]-1,3-naphthalenedisulfonic acid, disodium salt)

5413-75-2

C.I. Acid Red 85; C.I. 22 245(7-Hydroxy-8-[[4'-[[4-[[(4-methylphenyl)sulfonyl]oxy]phenyl]azo][1,1'-biphenyl]-4-yl]azo]-1,3-naphthalenedisulfonic acid, disodium salt)

3567-65-5

C.I. Acid Red 114; C.I. 23 635(8-[[3,3'-Dimethyl-4'-[[4-[[(4-methylphenyl)sulfonyl]oxy]phenyl]azo][1,1'-biphenyl]-4-yl]azo]-7-hydroxy-1,3-naphthalenedisulfonic acid, disodium salt)

6459-94-5



Children< 3 yrs


DYES

AZODYES Azodyes which, by reductive cleavage of one or more azo groups, may release one or more of the arylamines listed below, shall not be used in textile or leather articles which may come into direct and prolonged contact with the human skin or oral cavity.o-Aminoazotoluene 4-(o-tolyazo)-o-toluidine; 2-amino-azotoluene; C.I. Solvent Yellow 3; C.I. 11 160)

97-56-3

Textile:EN 1436-1/2:2003

Leather, metalsand plastics:CEN ISO/TS17234:2003

Not detected(detection limit 20 mg/kg

for each)

4-Aminobiphenyl 92-67-12-Amino-4-nitrotoluene(2-Methyl-5-nitro-benzenamine; 5-nitro-o-toluidine;6-methyl-3-nitroaniline; C.I. 37 105)

99-55-8

Benzidine (4,4'-Diaminodiphenyl) 92-87-54-Chloroaniline (p-Chloroaniline) 106-47-82-Chloro-4-nitroaniline 121-87-94-Chloro-o-toluidine 95-69-2p-Cresidine (6-Methoxymethylaniline) 120-71-82,4-Diaminoanisole (4-Methoxy-m-phenylenediamine)

615-05-4

4,4'-Diaminodiphenylmethane (4,4'-Methylenedianiline; MDA)

101-77-9

3,3'-Dichlorobenzidine 91-94-12,6-Dichloro-4-nitroaniline 99-30-93,3'-Dimethoxybenzidine (o-Dianisidine) 119-90-42,4-Dimethyl-benzenamine (2,4-Xylidine) 95-68-12,6-Dimethyl-benzenamine (2,6-Xylidine) 87-62-7Diphenylamine 122-39-42-Metoxybenzenamine (o-Anisidine) 90-04-04-Methyl-1,3-benzendiamine(2,4-Diaminotoluene; toluene-2,4-diamine)

95-80-7

4,4'-Methylenebis(2-chloro-benzenamine)(4,4'-Methylenebis(2-chloroaniline))

101-14-4

4,4'-Methylenebis-(2-methyl-benzenamine) (4,4'-Methylenedi-o-toluidine; 3,3'-dimethyl-4,4'-diaminobiphenylmethane)

838-88-0

2-Naphthylamine (β-Naphthylamine) 91-59-83-Nitro-p-toluidine (4-Methyl-3-nitroaniline; 4-methyl-3-nitro-benzenamine)

119-32-4

4,4'-Oxybis-benzenamine(4,4'-Oxydianiline; 4-aminophenyl ether)

101-80-4

4-(Phenylazo)-benzenamine(4-Aminoazobenzene; p-Aminoazobenzene; C.I.

Solvent Yellow 1; C.I. 11 000)60-09-3

4,4'-Thiobis-benzenamine (4,4'-Thiodianiline) 139-65-1o-Tolidine (3,3’-Dimethylbenzidine) 119-93-7o-Toluidine(2-Methylbenzamine; 2-aminotoluene; 2-methylaniline)

95-53-4

2,4,5-Trimethyl-benzenamine(2,4,5-Trimethylaniline) 137-17-7



Children< 3 yrs


DYES

AZODYES (Blue colorant – mixture of the two substances)

Navy Blue 2-Naphthalenesulfonic acid, 4-hydroxy-3-((2-hydroxy-3,5-dinitrophenyl)azo)-7-((4-methoxyphenyl)amino)-,chromium complex

118685-33-9

Textile:EN 1436-1/2:2003

Leather, metals and plastics:CEN ISO/ TS 17234: 2003


for each)Trisodiumbis(6-(4-anisidino)-3-sulfonato-2(3,5-dinitro-2-oxidophenylazo)-1-naphtolato)chromate(1-)

Unknown

DYES

CATIONIC (BASIC) DYESCationic (basic) dyes that are classified carcinogenic and/or sensitising/allergenic.C.I. Basic Black 1



C.I. Basic Green 1; C.I. 42 040(Brilliant Green; [4-[4-(diethylamino)benzhydrylene]cyclohexa-2,5-dien-1-ylidene]diethylammonium hydrogen sulphate)

633-03-4

C.I. Basic Green 4; C.I. 42 000(Malachite green; N-[4-[[4-(dimethylamino)phenyl]phenylmethylene]-2,5-cyclohexadien-1-ylidene]-N-methyl-methanaminium chloride)

569-64-218015-76-4

C.I. Basic Red 9; C.I. 42 500(4-[(4-Aminophenyl)(4-imino-2,5-cyclohexadien-1-ylidene)methyl]-benzenamine monohydrochloride)

569-61-9 25620-78-4

C.I. Basic Red 12; C.I. 48 070(2-[3-(1,3-Dihydro-1,3,3-trimethyl-2H-indol-2-ylidene)-1-propenyl]-1,3,3-trimethyl-3H-indolium chloride)

6320-14-5

C.I. Basic Red 46(Sulfuric acid, dimethyl ester, compound with N-methyl-N-[4-[(1-methyl-1H-1,2,4-triazol-5-yl)azo]phenyl]benzylamine (1:1))

62163-53-5

C.I. Basic Red 46 (Astrazon red FBL) 12221-69-1C.I. Basic Violet 3; C.I. 42 555([4-[4,4'-bis(Dimethylamino)benzhydrylidene]cyclohexa-2,5-dien-1-ylidene]dimethylammonium chloride)

548-62-9

C.I. Basic Violet 14; C.I. 45 210(4-[(4-Aminophenyl)(4-imino-2,5-cyclohexadien-1-ylidene)methyl]-2-methyl-benzenamine) monohydrochloride)

632-99-5



Children< 3 yrs


DYES

DIRECT DYES (SUBSTANTIVE DYES)Direct dyes (substantive dyes) that are classified carcinogenic, teratogenic and/or sensitising/allergenic.C.I. Direct Black 38; C.I. 30 235(4-Amino-3-[[4'-[(2,4-diaminophenyl)azo][1,1'-biphenyl]-4-yl]azo]-5-hydroxy-6-(phenylazo)-2,7-naphthalenedisulfonic acid, disodium salt)

1937-37-7



C.I. Direct Blue 1; C.I. 24 410(6,6'-[(3,3'-Dimethoxy[1,1'-biphenyl]-4,4'-diyl)bis(azo)]bis[4-amino-5-hydroxy-1,3-naphthalenedisulfonic acid, tetrasodium salt)

2475-45-8 2610-05-1

C.I. Direct Blue 6; C.I. 22 610(3,3'-[[1,1'-Biphenyl]-4,4'-diylbis(azo)]bis[5-amino-4-hydroxy-2,7-naphthalenedisulfonic acid,tetrasodium salt)

2602-46-2

C.I. Direct Blue 15; C.I. 24 400(3,3'-[(3,3'-Dimethoxy[1,1'-biphenyl]-4,4'-diyl)bis(azo)]bis[5-amino-4-hydroxy-2,7-naphthalenedisulfonic acid, tetrasodium salt)

2429-74-5

C.I. Direct Blue 78; C.I. 34 200(2-[[4-[[4-[[1-Hydroxy-6-(phenylamino)-3-sulfo-2-naphthalenyl]azo]-1-naphthalenyl]azo]-6-sulfo-1-naphthalenyl]azo]-1,4-benzenedisulfonic acid,tetrasodium salt)

2503-73-3

C.I. Direct Brown 95; C.I. 30 145(Disodium-[5-[[4'-[[2,6-dihydroxy-3-[(2-hydroxy-5-sulfophenyl)azo]phenyl]azo][1,1'-biphenyl]-4-yl]azo]-2-hydroxybenzoato(4-)]-cuprate(2-))

16071-86-6

C.I. Direct Red 28; C.I. 22 120(3,3'-[[1,1'-Biphenyl]-4,4'-diylbis(azo)]bis[4-amino-1-naphthalenesulfonic acid, disodium salt)

573-58-0



Children< 3 yrs


DYES

DISPERSE DYESDisperse dyes that are classified carcinogenic and/or sensitising/allergenic.C.I. Disperse Black 1; C.I. 11 365(4-[(4-Aminophenyl)azo]-1-naphthalenamine)

6054-48-4



C.I. Disperse Black 2; C.I. 11 255(4-[(4-Aminophenyl)azo]-2-methoxy-5-methyl-benzenamine)

6232-57-1

C.I. Disperse Blue 1; C.I. 64 500(1,4,5,8-Tetraamino-9,10-anthracenedione)

2475-45-8

C.I. Disperse Blue 3; C.I. 61 505(1-[(2-Hydroxyethyl)amino]-4-(methylamino)-9,10-anthracenedione)

2475-46-9

C.I. Disperse Blue 7; C.I. 62 500(1,4-Dihydroxy-5,8-bis[(2-hydroxyethyl)amino]-9,10-anthracenedione)

3179-90-6

C.I. Disperse Blue 26; C.I. 63 305(1,5-Dihydroxy-4,8-bis(methylamino)-9,10-anthracenedione)

3860-63-7

C.I. Disperse Blue 35(1-Amino-4,5-dihydroxy-8-(methylamino)-9,10-anthracenedione)

12222-75-2 56524-77-7

C.I. Disperse Blue 102 12222-97-8C.I. Disperse Blue 106; C.I. 111 935(2-[Ethyl[3-methyl-4-[(5-nitro-2-thiazolyl)azo]phenyl]amino]-ethanol)

12223-01-768516-81-4

C.I. Disperse Blue 124; C.I. 111 938(2-[Ethyl[3-methyl-4-[(5-nitro-2-thiazolyl)azo]phenyl]amino]-ethanol acetate (ester))

61951-51-715141-18-1

C.I. Disperse Brown 1; C.I. 11 152(C.I. Disperse Orange 46; 2,2'-[[3-chloro-4-[(2,6-dichloro-4-nitrophenyl)azo]phenyl]imino]bis-ethanol)

23355-64-8

C.I. Disperse Orange 1; C.I. 11 080(4-[(4-Nitrophenyl)azo]-N-phenyl-benzenamine)

2581-69-3

C.I. Disperse Orange 3; C.I. 11 005(4-[(4-Nitrophenyl)azo]-benzenamine)

730-40-5

C.I. Disperse Orange 11; C.I. 60 700(1-Amino-2-methyl-9,10-anthracenedione)

82-28-0

C.I. Disperse Orange 13; C.I. 26 080(4-[[4-(Phenylazo)-1-naphthalenyl]azo]-phenol; C.I. Solvent Orange 52)

6273-10-7

C.I. Disperse Orange 37; C.I. 11 132(C.I. Disperse Orange 76)

12223-33-5

C.I. Disperse Orange 37/59/76 (3-[[4-[(2,6-Dichloro-4-nitrophenyl)azo]phenyl]ethylamino]propanenitrile

13301-61-6

C.I. Disperse Orange 76 51811-42-8C.I. Disperse Orange 149 85136-74-9



Children< 3 yrs


DYES

DISPERSE DYES (continue)Disperse dyes that are classified carcinogenic and/or sensitising/allergenic.C.I. Disperse Red 1; C.I. 11 110(2-[Ethyl[4-[(4-nitrophenyl)azo]phenyl]amino]-ethanol)

2872-52-8



C.I. Disperse Red 7; C.I. 11 150(2,2'-[[3-Chloro-4-[(4-nitrophenyl)azo]phenyl]imino]bis-ethanol)

4540-00-5

C.I. Disperse Red 11; C.I. 62 015(1,4-Diamino-2-methoxy-9,10-anthracenedione)

2872-48-2

C.I. Disperse Red 17; C.I. 11 210(2,2'-[[3-Methyl-4-[(4-nitrophenyl)azo]phenyl]imino]bis-ethanol)

3179-89-3

C.I. Disperse Yellow 1; C.I. 10 345(4-[(2,4-Dinitrophenyl)amino]-phenol)

119-15-3

C.I. Disperse Yellow 3; C.I. 11 855(N-[4-[(2-Hydroxy-5-methylphenyl)azo]phenyl]-acetamide)

2832-40-8

C.I. Disperse Yellow 9; C.I. 10 375(N-(2,4-Dinitrophenyl)-1,4-benzenediamine)

6373-73-5

C.I. Disperse Yellow 23; C.I. 26 070(4-[[4-(Phenylazo)phenyl]azo]-phenol)

6250-23-3

C.I. Disperse Yellow 39 12236-29-2C.I. Disperse Yellow 49 54824-37-2C.I. Disperse Yellow 54(2-(3-Hydroxy-2-quinolinyl)-1H-indene-1,3(2H)-dione)

7576-65-0

DYESOTHER DYES Dyes that are classified carcinogenic, teratogenic and/or sensitising/allergenic.1,4-Bensenediamine(p-Phenylenediamine;diaminobenzene;PPDA;C.I. 76 060)

106-50-3


(detection limit 15 mg/kg for each)N,N-Dimethyl-4-/(phenylazo)-benzenamine

(4-Dimethylaminoazobenzene;C.I. Solvent Yellow 2;C.I. 11 020)

60-11-7



Children< 3 yrs


FLAME RETARDANTS

BROMINATED FLAME RETARDANTS

1,1'-(1-Methylethylidene)bis[3,5-dibromo-4-(2,3-dibromopropoxy)]benzene (1,1'-(Isopropylidene)bis[3,5-dibromo-4-(2,3-dibromopropoxy)benzene]; BDBPT)

21850-44-2

Solvent Extraction

followed by GS-MS or LC-MS

Not detected(detection limit 5 mg/kg for

each)

bis(2-Ehylhexyl)-tetrabromophthalate (Phthalic acid, tetrabromo-, di(2-ethylhexyl) ester; BEHTBP)

26040-51-7

1,2-bis(2,4,6-Tribromophenoxy)ethane(1,1'-[ethane-1,2-diylbisoxy]bis[2,4,6-tribromobenzene]; 1,1'-[1,2-ethanediylbis(oxy)]bis[2,4,6-tribromobenzene];

37853-59-1

1,1'-(Ethane-1,2-diyl)bis[2,3,4,5,6-pentabromobenzene] (Decabromodiphenylethane; 1,2-Bis(2,3,4,5,6-pentabromophenyl)ethane; DBDPE)

84852-53-9

2,3-Dibromo-1-propanol-hydrogenphosphate(bis(2,3-Dibromopropyl)phosohate)

5412-25-9

2,2-bis(Bromomethyl)-1,3-propanediol (Dibromoneopentyl glycol)

3296-90-0

Hexabromocyclododecane and all diastereoisomers (HBCDD)

25637-99-4134237-51-7134237-50-6134237-52-8

3194-55-6Pentabromodiphenylether(pentaBDE)

32534-81-9

Polybrominated biphenyls(PBB)

59536-65-1

Octabromodiphenylether(octaBDE)

32536-52-0

1,1'-Oxybis(2,3,4,5,6-pentabromo)-benzene(deca-Bromodiphenylether; dekaBDE)

1163-19-5

2-Ethylhexyl-2,3,4,5-tetrabromobenzoate(TBB)

183658-27-7

Tetrabromobisphenol A (TBBP-A) 79-94-72,4,6-Tribromophenol (TBP) 118-79-6Tris-(2,3-dibromopropyl)-phosphate(TRIS; TrisBP)

126-72-7



Children< 3 yrs


FLAME RETARDANTS

OTHER FLAME RETARDANTS

Compounds of antimonyAntimony trioxide

++1309-64-4


GS-MS or LC-MS

Not detected(detection limit 5 mg/kg for

each)

1,3-Dichloro-2-propanol-phosphate (3:1)(Tris(1,3-dichloro-2-propyl)-phosphate; TDCP)

13674-87-8

Paraffin waxes and hydrocarbon waxes, chlorinated

63449-39-8

Phosphoric acid tris(2-methylphenyl)-ester(Tri-o-toly- phosphate; tri-o-cresyl-phosphate)

78-30-8

Potassium hexafluorotitanate 16919-27-0Potassium hexafluorozirconate 16923-95-8Triphenyl phosphate(TPhP; phosphoric acid, triphenyl ester)

115-86-6

Tris-(aziridinyl)-phosphinoxide(TEPA)

5455-55-1

Tris(2-chloroethyl)-phosphate(2-Chloro-ethanol, phosphate (3:1); TCEP)

115-96-8

FORMALDEHYDE

FORMALDEHYDE Used in finishing treatment and sundry Formaldehyde 50-00-0

++

Textile:EN ISO 14184: 1

Leather:DIN ISO 17226-2

Not detected

(detection limit 16 mg/kg)

75 mg/kg(in direct contact with skin)

300 mg/kg(with no direct contact with skin)

ISOCYANATESISOCYANATES

Diphenylmethane diisocyanate (MDI)(MDI, 4,4'-methylenediphenyl diisocyanate)

101-68-826447-40-55873-54-1

EN ISO 10283Not detected

(Detection limit 10 mg/kg for each)

Hexamethylene diisocyanate (HDI) 822-06-0Isophorone diisocyanate (IPDI, 3-isocyanatomethyl-3,5,5-trimethylcyclohexyl isocyanate)

4098-71-9

Tetramethylxylene diisocyanate (TMXDI, 1,3-bis(1-isocyanato-1-methylethyl)benzene)

2778-42-9

Toluene-2,4-diisocyanate(TDI; 2,4-diisocyanato-1-methyl-benzene)

584-84-991-08-7

26471-62-5



Children< 3 yrs


METAL & METAL COMPOUNDS

EXTRACTABLE HEAVY-METALSUsed in finishing treatment and sundry Antimony and antimony compounds 7440-36-0

++

Extraction with artificial sweat

solution (EN ISO 105 E04 by ICP-OES or

ICP-MS)

5 mg/kg 30 ,0 mg/kg

Arsenic and arsenic compounds 7440-38-2++

0,20 mg/kg 1,0 mg/kg

Barium and barium compounds (readily soluble) 7440-39-3++ 10 mg/kg

Cadmium and cadmium compounds 7440-43-9 ++

0.10 mg/kg

Chromium(III) and its salts 7440-47-3 ++

1 mg/kg 2 mg/kg

Chromium(VI) and its salts

Potassium dichromateSodium dichromate

Sodium chromatePotassium chromateAmmonium dichromateStrontium chromate

7440-47-3 18540-29-9

++7778-50-9

7789-12-0 / 10588-01-97775-11-37789-00-67789-09-57789-06-2

Under detection limit(less than 0.5 mg/kg)

Cobalt and cobalt compounds

Cobalt dichlorideCobalt(II) sulphateCobalt(II) dinitrateCobalt(II) carbonateCobalt(II) diacetate

7440-48-4++

7646-79-910124-43-310141-05-6

513-79-171-48-7

1,0 mg/kg 4,0 mg/kg

Copper and copper compounds 7440-50-8++

25,0 mg/kg 50,0 mg/kg

Lead, lead alloys and lead compounds Lead chromate Lead chromate molybdate sulphate red Lead sulfochromate yellow Lead hydrogen arsenate

7439-92-1++

7758-97-612656-85-81344-37-27784-40-9

0,2 mg/kg 1,0 mg/kg

Mercury and mercury compounds 7439-97-6++

0.02 mg/kg

Nickel and nickel compounds 7440-02-0 ++

1,0 mg/kg 4,0 mg/kg

Silver ion 7440-22-4++

0,10 mg/kg

Tin and inorganic tin compounds 7440-31-5++

4 mg/kg

Zinc and zinc compounds 7440-66-6++ 60 mg/kg



Children< 3 yrs



TOTAL HEAVY-METALS

Antimony and antimony compounds7440-36-0 ICP-MS

Polyester:260 mg/kg

Cadmium and cadmium compounds 7440-36-0++

EN 112250 mg/kg 75 mg/kg

Chromium(VI) and its salts

Potassium dichromateSodium dichromate

7440-47-318540-29-9

++7778-50-9

10588-01-9

Leather:DIN EN ISO 17075

Not detected(detection limit 3 mg/kg)

Lead, lead alloys and lead compounds 7439-92-1++

US EPA 3051/ 3052

45 mg/kg 90 mg/kg


NICKELMetal accessories

Nickel and nickel compounds

7440-02-0 ++

For coated item: EN 1811 +EN 12472

Non coated item: EN 1811

<0,5 µg/cm²/weekArticles in skin contact

<0,2 µg/cm²/week(pierced part)

MISCELLANOUS

MISCELLANOUS

Acrylamide(2-Propenamide)

79-06-1

Declaration of non-use

Shall not be used in the production

Anthracene oil 90640-80-5

Anthracene oil, anthracene paste 90640-81-6Anthracene oil, anthracene paste, anthracene fraction

91995-15-2

Anthracene oil, anthracene paste,distn. lights 91995-17-4

Anthracene oil, anthracene-low 90640-82-7

Bisphenol-A(BPA)

80-05-7Solvent extraction

followed by GC-MS

Not detected(detection limit

1 mg/kg for textile and5 mg/kg for plastics)

Boric acid 10043-35-311113-50-1



Diarsenic pentaoxide 1303-28-2Diethylenetriaminepentaacetic-acid sodium salt(DTPA)

140-01-2

2,4-Dinitrotoluene 121-14-2Disodium tetraborate, anhydrous 1330-43-4

12179-04-31303-96-4



Children< 3 yrs


MISCELLANOUS

MISCELLANOUS

Ethylenediaminetetraacetic-acid(EDTA)

60-00-4



Linear alkydbenzene sulfonates(LAS)

++

N-Butylbenzenesulfonamide 3622-84-2Nicotine 54-11-5

65-30-54-Nitrobenzenamine(p-Nitroaniline; C.I. Azoic Diazo Component 37; C.I. 37035)

100-01-6

Nitrobenzene 98-95-3Octamethylcyclotetrasiloxane 556-67-2

ORGANIC SOLVENTS

ORGANIC SOLVENTS Used in several production processesBenzene 71-43-2

Headspace GC-MS or solventextraction

Not detected (detection limit 1 mg/kg

for each)

Carbon tetrachloride(Tetrachloromethane)

56-23-5

Chloroform(Trichloromethane)

67-66-3

4-Chloro-3-methyl-phenol(p-Chloro-m-cresol)

59-50-7

Cyclohexane 110-82-7Cyclohexanone 108-94-11,1-Dichloroethene(Vinylidene chloride)

75-35-4

N,N-Dimethylformamide(Dimethylformamide)

68-12-2 30 mg/kg

2-Ethoxyethanol(Ethylene glycol monoethyl ether)

110-80-5

Not detected (detection limit 1 mg/kg

for each)

Ethoxyethanol acetate (2-Ethoxyethyl acetate; ethylglycol acetate)

111-15-9

Hexachlorobutadiene(1,1,2,3,4,4-Hexachloro-1,3-butadiene) 87-68-3

2-Methoxyethanol;(Ethylene glycol monomethyl ether) 109-86-4

2-Methoxyethanol acetate;(2-Methoxyethyl acetate;methylglycol acetate) 110-49-6

Methyl ethyl ketone (MEK) 78-93-3n-Hexane 110-54-3N-Methylpyrrodine (NMP) 872-50-4N,N-dimethylacetamide(Dimethylacetamide)

127-19-5

1,1'-Oxybis-2-propanol 110-98-5Pentachloroethane 76-01-7Phenol 108-95-2Tetrachloroethane(Perchloroethylene;1,1,2,2-tetrachloroethylene) 127-18-4



Children< 3 yrs


ORGANIC SOLVENTS

ORGANIC SOLVENTS Used in several production processes1,1,1,2-Tetrachloroethane 630-20-6

Headspace GC-MS or solventextraction


for each)

1,1,2,2-Tetrachloroethane 79-34-51,1,1-Trichloroethane 71-55-61,1,2-Trichloroethane 79-00-5Tricolorethylene (TCE) 79-01-6Toluene 108-88-3Xylene 1330-20-7

ORGANOCHLORINESORGANOCHLORINES .Dichloro[(dichlorophenyl)methyl]methylbenzene, mixture of isomers

76253-60-6Extraction

followed by GC-MS or

LC-MS

Total0,5 mg/kg

Total1 mg/kg

Polychlorinated biphenyls(PCB)

1336-36-3++

Polychlorinated terphenyls(PCT)

61788-33-8++

ORGANOTIN COMPOUNDS

ORGANOTIN COMPOUNDS …

Dibutyltin (DBT) and dibutyltin compounds ++

ISO 17353 analysis with

GC-MS

0.5 mg/kgfor each

1,0 mg/kgfor each

Dioctyltin (DOT) and dioctyltin compounds 15231-44-4870-08-6

++Hexabutyldistannoxane(Tributyltinoxide; bis(tributyltin)-oxide; TBTO)

56-35-9

Monobutyltin (MBT) compounds ++Monooctyltin (MOT) compounds ++Tetrabutyltin (Tetrabutylstannane; tetra-n-butyltin; TeBT)

1461-25-2

Tetrabutyl tin compounds ++Tetraoctyltin 3590-84-9Tribytyltin (TBT) and tributyltin compounds(Tributylstannane; tributyltin hydride)

688-73-3 56573-85-4

++Tricyclohexyltin (TCyHT) compounds ++Tricyclohexyltin hydroxide 1321-70-5Trioctylstannane(Trioctyltin; TOT)

869-59-0++

Triphenyltin (TPhT) and triphenyltin compounds 668-34-8 ++

Tripropyltin; (TPT)



Children< 3 yrs


PERFLUORATED HYDROCARBONS

PERFLUORATED HYDROCARBONS

Perfluorooctane-carboxylic acid (PFOA) and PFOA compounds

335-67-13825-26-1335-95-5

2395-00-8335-93-3335-66-0376-27-2

3108-24-5++

Solvent extraction, LC-MS

analysis

1 µg/m²for each

Perfluorooctane-sulphonate (PFOS) and PFOS related compounds(Perfluorooctanyl-sulphonates with the formula C8F17SO2X where X = OH, metallic salt, halogenide, amide, and other derivates including polymers)

++

PHTHALATES

PHTHALATES Mainly used as plasticisers in PVC prints but may also be used as carriers.Butylbenzylphthalate(BBP) 85-68-7

ISO 15777analysis with

GC-MS orLC-MS

Not detected(detection

limit 50 mg/kg for

each phthalate)

100 mg/kg for each

phthalate

Total content of all

phthalate should not exceed 500

mg/kg

Dibutylphthalate(DBP)

84-74-2

Diethylphthalate(DEP) Carrier

84-66-2

Di(2-ethylhexyl)-phthalate(DEHP)

117-81-7

Di-iso-butylphthalate(DIBP) 84-69-5

Diisodecylphthalate(DIDP)

26761-40-0 68515-49-1

Di-iso-nonylphthalate(DINP)

28553-12-0 68515-48-0

Dimethylphthalate(DMP)

131-11-3

Di-n-octylphthalate(DNOP)

117-84-0

1,2-Benzenedicarboxylic acid, di-C6-8branched alkyl esters, C7-rich(DIHP)

71888-89-6

1,2-Benzenedicarboxylic acid, di-C/-11-branched and linear alkyl esters(DHNUP)

68515-42-4



Children< 3 yrs


POLYCYCLIC COMPOUNDSPOLYCYCLIC AROMATIC HYDROCARBONS (PAH)

Acenaphtene 83-32-9

DIN/ ISO 18287 by GC-MS

Sum for all 16 PAHs shouldnot exceed 10.0 mg/kg

Acenaphthylene 208-96-8Anthracene 120-12-7

Benzo[a]anthracene 56-55-3Benzo[a]pyrene 50-32-8 1 mg/kg Benzo[b]fluoranthene 205-99-2

Sum for all 16 PAH shouldnot exceed 10.0 mg/kg

Benzo[ghi]perylene 191-24-2Benzo[k]fluoranthene 207-08-9Chrysene 218-01-9Dibenz[a,h]anthracene 53-70-3Fluoranthene 206-44-0Fluorene 86-73-7Indeno[1,2,3-cd]pyrene 193-39-5Napthalene 91-20-3Phenanthrene 85-01-8Pyrene 129-00-0

POLYVINYLCHLORIDE (PVC)POLYVINYLCHLORIDE (PVC)

Polyvinylchloride (PVC) 9002-86-2 Beilstein followed by

FTIRNot detectedPolyvinylidenchloride 9002-85-1

QUATERNARY AMMONIUM SALTS

QUATERNARY AMMONIUM SALTS Used as detergents, fabric softeners, biocides Bis(hydrogenated tallow alkyl)dimethylchloride (Bis(hydrogenated tallow)dimethyl ammonium-chloride; DHTDMAC)

61789-80-8



Bis(hydrogenated-tallow-alkyl)dimethylammoniumchloride (DTDMAC)

68783-78-8

Distearyl-dimethylammoniumchloride(DODMAC; DSDMAC)

107-64-2

OTHERpH VALUE

Clothing and textiles for babies or that come in direct contact with skin: pH 4,0-7,5

Clothing and textiles that do not come into direct contact with skin: pH 4,0-9,

Textile:ISO 3071

Leather:ISO 4045


Table 3 –Extensive list of restricted substances Packaging


PAPERPAPER

Formaldehyde 50-00-0++

EN 1541150 mg/kg

Metals, Total amount

Acid digestion, analysis by

ICP-AESand/or ICP-MS

Total content of allheavy metals should not

exceed 100 mg/kg

Cadmium 7440-43-9++

Lead 7439-92-1++

Chromium VI 7440-47-3++

Mercury 7439-97-6++

Perfluorooctane-carboxylic acid (PFOA) and PFOA compounds

335-67-13825-26-1335-95-5

2395-00-8335-93-3335-66-0376-27-2

3108-24-5++

Solvent extraction, LC-MS analysis 1 µg/m²

Perfluorooctane-sulphonate (PFOS) and PFOS related compounds(Perfluorooctanyl-sulphonates with the formula C8F17SO2X where X = OH, metallic salt, halogenide, amide, and other derivates including polymers)

++

Polyvinylchloride (PVC)9002-86-2

Beilstein followed by FTIR

Not detectedPolyvinylidenchloride

9002-85-1



PLASTICPLASTIC

Bisphenol A(BPA) 80-05-7

GC-MSNot detected

(detection limit 5 mg/kg)Dimethylformamide(DMF) 68-12-2

GC-MS 100 mg/kg

Isocyanates See list of Isocyanates in Table 2 ++ ISO 10283 Not detected

(detection limit 3 mg/kg)Metals, Total amount

Acid digestion, analysis by

ICP-AESand/or ICP-MS

Total content of allHeavy metals should not

exceed 100 mg/kg

Cadmium 7440-43-9++

Lead 7439-92-1++

Chromium VI 7440-47-3++

Mercury 7439-97-6++

Organotin Compounds See list of Organotin Compounds in Table 2 ++

ISO 17353by GC-MS 1 mg/kg for each

Phenols

Solvent extraction LC-MS

Not detected(detection limit 0,05 mg/kg)

Pentachlorophenol and its salts or esters 87-86-5 ++

5-Chloro-2-(2,4-dichlorophenoxy)-phenol(Triclosan)

3380-34-5

Tetrachlorophenol and its salts and esters

Including tetrachlorophenoxy compounds

25167-83-3935-95-558-90-2

4901-51-3++

2-Phenylphenol (OPP) 90-43-7 50 mg/kg

PhthalatesSee list Phthalates in Table 2 ++ GC-MS

50 mg/kgfor each phthalate

Polychlorinated Biphenyls(PCB)

1336-36-3Solvent extraction

followed byGC-MS

Total content of all should not exceed 0,5 mg/kgPolychlorinated Triphenyls

(PCT)61788-33-8

Polyvinylchloride(PVC) 9002-86-2

Beilstein followed by FTIR

Not detectedPolyvinylidenchloride 9002-85-1

3.4 Chemical Testing

A test report performed by an approved independent laboratory may be requested.

The Varner Group reserve the right to cancel orders, in whole or in part, and claim or take other action if products or tests do not comply with our chemical requirements. The buying department reserves the right to ask for additional documentation showing the requirements have been respected and random controls may be carried.

The following laboratories are approved for chemical testing:

BLC Leather Technology Centre Bureau Veritas (Global) High Street (Global) Intertek Labtest (Global) MTS (Global) SGS (Global) CMA Testing and Certification Laboratories (Hong Kong) Ekoteks (Turkey) UL-STR (India) Textile Testing International (Pakistan)


3.5 Chemical Certificate

The buying department reserve the right to ask for additional documentation showing the chemical requirements have been respected and random product quality controls may be carried out.

Suppliers may be asked to print out, complete and submit the below Chemical Certificate together with all pre-production samples in correct colours and artwork and enclose related test documentation.

Varner Group Chemical Certificate

Supplier

Buying Chain

Order number

Style

Date

SUPPLIER COMMITMENT

We hereby confirm that the present order comply with the Varner Group Chemical requirements. We confirm the products supplied do not contain any hazardous substances.

Name and Position

Supplier’s Signature

the varner groupcdn.varner.eu/global/varner/csr/downloads_csr/thevarnergroups...the varner group...

Documents