the semi-classical approximation for pedestrians an...
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The Semi-classical Approximation for Pedestriansan elementary introduction
Uzy Smilansky
Department of Physics of Complex Systems, The Weizmann Institute of Science, Rehovot, ILSchool of Mathematics Cardiff University, Cardiff, Wales, UK
Abstract These lectures are intended to introduce the Semi ClassicalApproximation and some of its intricacies in a consistent andtransparent way. The main topics to be covered are • The semi classical approximation for the quantum evolution operator.• Uniform approximations• Semi-classical spectral theory: • The trace formula and some of its applications. (For systems in 1-d)
It is hoped that the ideas and tools presented here will provide asolid jumping-board for further studies and applications .
“Putting quantum flesh on classical bones”
(W.H. Miller)
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a) The buckyball carbon-70;b) The pancake-shaped biomolecule tetraphenylporphyrin (TPP) C44 H30 N4 ; c) The fluorinated fullerene C60 F48 . (atomic mass of 1632 units )
Probing the limits of the quantum worldM. Arndt, K. Hornberger, and A. Zeilinger , Physics World (March 2005) 35-40
Motivation (For Physicists) :
A two slits experiment with heavy moleculesThe correspondence principle in action!
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Motivation (For Mathematicians)
1. Singular perturbation theory:
The Schroedinger equation:
¹h ! 0?
2. Oscillatory integralsRdx ei f (x )=¹h
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Books Richard P. Feynman and Albert R. Hibb:Quantum Mechanics and Path Integrals(McGraw-Hill, New York, 1965).L. S. Schulman: Techniques and Applications of Path Integration, (Wiley -Interscience Monographs and Texts in Physics and Astronomy, NY, 1981) David J. Tannor: Introduction to Quantum Mechanics –A time dependent perspective.(University Science Books, 2007)
/www.weizmann.ac.il/chemphys/tannor/Bookhttp://
Bibliography
ArticlesToo many to be listed.These lectures are based on my papers with S. Levit, K. Moehring and David Brink.To download: http://www.weizmann.ac.il/complex/uzy/publications.html # 26,27,29,30,38,39,41,47
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Preliminaries: Classical vs Quantum evolution
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Feynman Path Integral representation The Democracy of Paths:
t’’
q’
t’
q’’
q(t)
Richard P. Feynman and Albert R. Hibbs, Quantum Mechanics and Path Integrals(McGraw-Hill, New York, 1965).
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± =TN
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Back to the propagator and the path integral
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Note: The boundary conditions do not determine a classical path uniquely! (examples below) However, there is no conflict with the uncertainty principle: the path is notprescribed by the simultaneous values of the position and the momentum.
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V(q)
qq’ q’’
Tmax
Example: Several trajectories which satisfy the same boundary conditions.
Tmax : If t”-t’>Tmax direct transition becomes classically forbidden
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Now that we have identified the classical trajectory (trajectories) as the saddle points we should compute the pre-exponential factor in the SPA for the path-integral. An elegant way to do this is offered if the path integral is defined in a different way.
The path expansion representation of the path integral
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Classical bones: dynamics (trajectory), action, stability Quantum flesh : transition amplitude, interference, the quantum scale: ~
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q(t’’; p’)
p’
q’’
dp=2¼h / dq’’
p’i p’2
Classical transition probability
dq’’
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t
caustics
Classically forbidden domain
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End of section I
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Appendix
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