tetra tech - final site assessment report for frank ... · this report summarizes the findings of...

LUCAS STAMPS PROJECT MANAGER

July 20, 2016

Ms. Verneta Simon

On-Scene Coordinator

U.S. Environmental Protection Agency, Region 5

77 W. Jackson Blvd.

Chicago, IL 60604

Subject: Final Site Assessment Report for Frank Foundry Off-Site Areas

EPA Contract No. EP-S5-09-05

EPA Technical Direction Document (TDD) No. S05-0001-1507-204

Document Tracking No.: 0957

Dear Ms. Simon:

Tetra Tech, Inc. (Tetra Tech) is submitting this final site assessment report summarizing the work

conducted at properties adjacent to the former Frank Foundry site on February 18 and March 30, 2016.

This report summarizes the findings of the field activities conducted in off-site areas around the site.

The findings from previous site assessment activities conducted on the former Frank Foundry property

were presented in a previous report.

If you have any questions regarding this report, please contact me at (317) 797-2420 or at

[email protected].

Respectfully,

Lucas Stamps

Project Manager

FINAL

SITE ASSESSMENT REPORT

FRANK FOUNDRY OFF-SITE AREAS

2008 E 8th

STREET

MUNCIE, DELAWARE COUNTY, INDIANA

U.S. Environmental Protection Agency

Emergency Response Branch

Region 5

77 W Jackson Blvd.

Chicago, IL 60604

Submitted by

Tetra Tech, Inc.

1 S. Wacker Dr. Ste. 3700

Chicago, IL 60606

EPA Contract No. EP-S5-09-05

Technical Direction Document No. S05-0001-1507-204

Document Tracking No.: 0957

July 20, 2016

Prepared by

Lucas Stamps

Project Manager

Approved by

John Dirgo

START QC Reviewer

Frank Foundry Off-Site Areas Tetra Tech, Inc.

Final Site Assessment Report TDD No.: S05-0001-1507-204

July 20, 2016 i

CONTENTS

Section Page

1.0 INTRODUCTION ............................................................................................................................ 1 2.0 SITE BACKGROUND ..................................................................................................................... 1 3.0 FIELD INVESTIGATION ............................................................................................................... 2

3.1 SOIL SAMPLING ACTIVITIES ................................................................................................. 2 4.0 SOIL ANALYTICAL RESULTS ..................................................................................................... 3 5.0 POTENTIAL THREATS TO HUMAN HEALTH AND THE ENVIRONMENT .......................... 3

Appendix

A FIGURES

1 – SITE LOCATION MAP

2 – SITE MAP SHOWING OFF-SITE AREAS

3 – XRF SCREENING LOCATIONS

4 – LEAD ANALYTICAL RESULTS NORTH

5 – LEAD ANALYTICAL RESULTS SOUTH

B PHOTOGRAPHIC DOCUMENTATION LOG

C ANALYTICAL RESULTS TABLE

D LABORATORY ANALYTICAL REPORTS AND DATA VALIDATION REPORT



July 20, 2016 1

1.0 INTRODUCTION

Under Superfund Technical Assessment and Response Team (START) Contract No. EP-S5-09-05,

Technical Direction Document (TDD) No. S05-0001-1507-204, the U.S. Environmental Protection

Agency (EPA) tasked Tetra Tech, Inc. (Tetra Tech) with performing additional soil sampling as part of

the site assessment at the former Frank Foundry in Muncie, Delaware County, Indiana (Figure 1). EPA

requested that Tetra Tech collect soil samples from properties surrounding the former foundry. The

purpose of the sampling was to delineate the extent of off-site soil contamination from the foundry. Tetra

Tech also collected written and photographic documentation of site conditions and evaluated the potential

of imminent and substantial threats to human health and welfare or the environment. Under the direction

of On-Scene Coordinator (OSC) Verneta Simon, Tetra Tech START conducted the site assessment

activities on February 18 and March 30, 2016.

This site assessment report is organized into the following sections:

Introduction – provides a brief description of the objectives and scope of site assessment.

Site Background – describes the site and its history.

Field Investigation – discusses the methods and procedures used during the site assessment.

Analytical Results – presents the analytical results for the samples collected during the site

assessment.

Potential Threats to Human Health and the Environment – identifies the conditions at the site that

warrant a removal action under the National Oil and Hazardous Substances Pollution

Contingency Plan (NCP).

In addition, this site assessment report contains four appendices. Appendix A provides the figures for this

report. Appendix B provides the photographic documentation log of conditions during the site

assessment. Appendix C provides a table that summarizes laboratory analytical results. The laboratory

analytical reports and data validation reports for samples collected during the site assessment are included

in Appendix D.

2.0 SITE BACKGROUND

The former Frank Foundry is located at 2008 East 8th Street in Muncie, Delaware County, Indiana

(Appendix A, Figure 1). The geographic coordinates of the site are 40.181825 degrees north latitude and

85.363352 degrees west longitude. The site is located in a mixed residential and commercial area

(Appendix A, Figure 2). The outer fences of the site are largely intact; however, many breaches have

been made by vandals and other trespassers. Most of the buildings have been demolished; however, two



July 20, 2016 2

partially demolished structures remain on site. Large debris piles of bricks, wood, metal, and rubbish

were present on the site at the time of site assessment activities. A previous owner relocated materials at

the site and moved additional materials onto the site.

Previous investigators conducted an asbestos inspection and soil investigation of the site. At the time of

the asbestos inspection, buildings were largely intact and the interior walls and roofs were present on

many of the buildings now demolished. A subsequent inspection conducted by the City of Muncie

identified jagged and broken pieces of Category II non-friable asbestos transite materials reported as

friable. The soil investigation determined that on-site soil contained elevated levels of lead and arsenic.

A nonprofit organization, Farmished, has obtained ownership of the property. Farmished is planning to

use the property to educate the local public and provide charitable services by building raised gardens to

grow and sell fresh produce to local businesses and the public. In addition, Farmished plans to launch a

compost program. According to the current owner, subsequent vandalism and theft of structural beams

caused an on-site building to require demolition.

In August 2015, Tetra Tech START completed a site assessment on the former Frank Foundry property,

which documented threats to human health and the environment due to asbestos containing material

(ACM) and lead in soil above EPA screening levels.

Due to uncertainty of the property boundaries during the time when the foundry was in operation, OSC

Simon requested Tetra Tech START’s support in collecting soil samples from properties surrounding the

former foundry.

3.0 FIELD INVESTIGATION

EPA obtained access agreements for properties of interest, and on February 18 and March 30, 2016, EPA

and Tetra Tech START conducted soil sampling activities. Four different properties were sampled during

each sampling event. Each of the properties sampled was adjacent to the former Frank Foundry property.

3.1 SOIL SAMPLING ACTIVITIES

Tetra Tech START collected surface soil samples under the direction of EPA OSC Simon. Samples were

collected to a depth of approximately 1 foot below ground surface (bgs) using a hand auger. At

residential properties, a composite sample was collected in both the front and back yard, where possible.

An additional composite sample was collected from the garden, if present. One property, an

approximately 2-acre open field with a playground open to the public, was sampled in a 50-foot grid

pattern. Samples were placed in plastic bags and screened with a Niton XL3t X-ray fluorescence (XRF)



July 20, 2016 3

analyzer. At EPA OSC Simon’s discretion, samples were then either collected into laboratory supplied

containers or returned to the locations where they were collected. Each soil sample that was collected for

laboratory analysis was labeled, placed in a cooler with ice, and shipped to CT Laboratories in Baraboo,

Wisconsin under chain-of-custody. Samples were analyzed for selected metals, which included the eight

Resource Conservation and Recovery Act (RCRA) metals, as well as the 15 additional metals shown in

Appendix C.

4.0 SOIL ANALYTICAL RESULTS

During the site assessment, Tetra Tech START collected soil samples from off-site properties adjacent to

the former Frank Foundry site. The samples were collected to determine the presence of metals

contamination, and whether contamination poses imminent and substantial threats to public health or

welfare of the United States or the environment. The results are summarized in the data summary tables

provided in Appendix C. Because most of the properties were residential, the soil sample results were

compared to EPA’s Removal Management Levels (RML) for residential soil at target cancer risk of 10-4

for carcinogens and hazard quotient (HQ) of 3 for non-carcinogens.

A total of 54 locations in properties adjacent to the former foundry were screened with an XRF analyzer

(Appendix A, Figure 3). Of these 54 locations, none screened above the EPA RML of 400 milligrams per

kilogram (mg/kg) for lead in soil. Based on screening results, the OSC determined which samples were

submitted to the laboratory for analysis. In general, samples that were in areas of interest or that screened

above 100 mg/kg were submitted to the laboratory. A total of 24 samples were submitted for laboratory

analysis. No metals exceeded the EPA RMLs in any sample. The highest result for lead was 259 mg/kg

in sample FF-SS18-160218. Sampling locations and lead results are shown in Appendix A, Figures 4 and

5. Laboratory analytical results are summarized in Appendix C. The laboratory analytical reports and

data validation reports are included in Appendix D.

5.0 POTENTIAL THREATS TO HUMAN HEALTH AND THE ENVIRONMENT

Factors to be considered in determining the appropriateness of a potential removal action at a site are

discussed in the NCP and 40 CFR 300.415(b) (2). No threat factors are applicable to the properties that

are presented in this report. As a result of this assessment, Tetra Tech START recommends that removal

activities be focused on the former Frank Foundry property only, and not surrounding off-site properties.

APPENDIX A

FIGURES

1 – SITE LOCATION MAP

2 – SITE MAP SHOWING OFF-SITE AREAS

3 – XRF SCREENING LOCATIONS

4 – LEAD ANALYTICAL RESULTS NORTH

5 – LEAD ANALYTICAL RESULTS SOUTH

±

Date Saved: 7/1/2016

Frank Foundry Site2008 East 8th Street

Muncie, Delaware County, Indiana

Figure 1

Prepared For: EPA Prepared By: Tetra Tech, Inc.

Site Location Map

EPA Contract No.: EP-S5-13-01 TDD No.: S05-0001-1507-204

1,000 0 1,000

Feet

Source: USGS 7.5 Minute DRG Topographic Map

Coordinate System: NAD 27 UTM Zone 16

Legend

Site Boundary

Muncie East QuadrangleSection 14, Township 20N, Range 10E

SITE

Indiana

Maintenance Shop/Compressor Building

Former Foundry

Cleaning and Shipping

Storage

Core Finishing

Core Making Department

Factory Building

Off-Site Areas

8th St

7th St

Sh

iple

y S

t

5th St

Rib

ble

Av

e

6th St

Br o

the

r ton

St

Mo

ck

Av

e

6th St


Date Saved: 6/27/2016 EPA Contract No.: EP-S5-13-01 TDD No.: S05-0001-1507-204

Source: 2011-2013 Indiana Orthophotography

Coordinate System: Indiana State Plane

±100 0 100

Feet

Legend

Approximate Site Boundary

Off-Site Areas

Indiana

Frank Foundry Site2008 East 8th Street


Figure 2

Site Map Showing Off-Site Areas

FIGURE 3: XRF SCREENING LOCATIONS

HAS BEEN REDACTED – ONE PAGE

CONTAINS POTENTIAL PERSONALLY-IDENTIFYING INFORMATION

Off-Site Areas

63

189 259

127

10898.9 98.8

91.834.759.6

100

104

58.3

71.4

1918 16

12

11 10 09 06

0504030201

6th St

5th St

Mo

ck

Av

e

Bro

the

rto

n S

t

Wa

l lin

g A

ve

15

Frank Foundry ER Site2008 East 8th Street


Figure 4

Lead Analytical Results North


Date Saved: 7/7/2016 EPA Contract No.: EP-S5-13-01 TDD No.: S05-0001-1507-204

Source: 2011-2013 Indiana Orthophotography

Coordinate System: Indiana State Plane

±50 0 50

Feet

Legend

Sample Point

Lead In Soil (ppm)

Approximate Site Boundary

Off-Site Areas

Indiana

189

FIGURE 5: LEAD ANALYTICAL RESULTS SOUTH

HAS BEEN REDACTED – ONE PAGE

CONTAINS POTENTIAL PERSONALLY-IDENTIFYING INFORMATION

APPENDIX B

PHOTOGRAPHIC DOCUMENTATION LOG

Photographic Documentation Log

Client: U.S. Environmental Protection Agency Region 5 Prepared By: Tetra Tech, Inc.

Site Name: Frank Foundry Site TDD: S05-0001-1507-204

Location: Muncie, Delaware County, Indiana

Page 1

Photograph: 1

Direction: South

Date: 2/18/16

Photographer:

Keith Hughes

Description:

START using a hand

auger to collect a soil

sample.

Photograph: 2

Direction: N/A

Date: 2/18/16

Photographer:

Keith Hughes

Description:

START screening a soil

sample with an XRF

analyzer.





Page 2

Photograph: 3

Direction: N/A

Date: 2/18/16

Photographer:

Keith Hughes

Description:

START collects a soil

sample for laboratory

submission.

Photograph: 4

Direction: South

Date: 2/18/16

Photographer:

Keith Hughes

Description:

START analyzes the

surface of a soil pile

using an XRF analyzer.





Page 3

Photograph: 5

Direction: North

Date: 2/18/16

Photographer:

Lucas Stamps

Description:

One property that was

sampled contained a

rehabilitation facility.

Photograph: 6

Direction: East

Date: 2/18/16

Photographer:

Lucas Stamps

Description:

A former foundry-

owned property now

contains a playground

that is accessible to the

public.





Page 4

Photograph: 7

Direction: East

Date: 3/30/16

Photographer:

Lucas Stamps

Description:

Photograph of one of

the gardens that

START sampled during

the assessment.

Photograph: 8

Direction: North

Date: 3/30/16

Photographer:

Lucas Stamps

Description:

Photograph of the

former alley located

adjacent to the foundry

property. Asphalt was

prevalent below grade.





Page 5

Photograph: 9

Direction: East

Date: 3/30/16

Photographer:

Lucas Stamps

Description:

Former entrance to the

foundry.

Photograph: 10

Direction: North

Date: 3/30/16

Photographer:

Lucas Stamps

Description:

Building that was

previously used for

foundry administration.

APPENDIX C

ANALYTICAL RESULTS TABLE

Table 1

Soil Analytical Results

Frank Foundry Off-Site Areas


Sample IDFF-SS01-

160218

FF-SS02-

160218

FF-SS03-

160218

FF-SS04-

160218

FF-SS05-

160218

Units ResultsJ-

ResultsJ-

Aluminum 230,000 mg/kg 11,600 8,960 9,290 3,200 8,850

Antimony 94 mg/kg 1.2 1.1 0.95 0.75 1.4

Arsenic 68 mg/kg 11.3 12.4 10.4 7.4 10.8

Barium 46,000 mg/kg 79.5 89.2 87.9 66 83

Beryllium 470 mg/kg 0.6 0.68 0.65 1.2 0.81

Cadmium 210 mg/kg ND ND ND 0.016 0.021

Calcium NL mg/kg 3,580 3,320 3,410 3,270 8,340

Chromium NL mg/kg 18.9 14.6 17.6 7 14

Cobalt 70 mg/kg 8.1 8.1 8.8 5.9 8.3

Copper 9,400 mg/kg 21.5 19.2 20.6 21.2 26.6

Iron 160,000 mg/kg 24,200 18,400 19,600 13,600 22,300

Lead 400 mg/kg 59.6 63 71.4 34.7 91.8

Magnesium NL mg/kg 2,630 2,000 2,160 545 4,080

Manganese 5,500 mg/kg 415 642 700 129 553

Mercury 33 mg/kg 0.052 0.036 0.04 0.033 0.053

Nickel 4,600 mg/kg 18.4 13.7 14.5 18.3 19.2

Potassium NL mg/kg 1,360 1,190 1,220 744 1,440

Selenium 1,200 mg/kg 1.1 2.8 1.3 0.96 1.2

Silver 1,200 mg/kg 0.027 0.15 0.13 ND 0.077

Sodium NL mg/kg 24.9 24.7 21.5 47.5 44.1

Thallium 2.3 mg/kg ND 1.5 ND ND ND

Vanadium 1,200 mg/kg 31 25.8 26 18.3 24.8

Zinc 70,000 mg/kg 100 108 109 64.5 142

Notes:

Bold = Exceeds EPA RML J+ = Value may be biased high

EPA = Environmental Protection Agency J- = Value may be biased low

HQ = Hazard Quotient mg/kg = milligrams per kilogram

RML = Removal Management Level ND = Not Detected

ID = Identification NL = Not Listed

J = Value is approximate TCR = Target Cancer Risk

Analyte

EPA RML

(TCR = 10-4

&

HQ = 3)

Residential Soil

Table 1




Sample ID

Units

Aluminum 230,000 mg/kg

Antimony 94 mg/kg

Arsenic 68 mg/kg

Barium 46,000 mg/kg

Beryllium 470 mg/kg

Cadmium 210 mg/kg

Calcium NL mg/kg

Chromium NL mg/kg

Cobalt 70 mg/kg

Copper 9,400 mg/kg

Iron 160,000 mg/kg

Lead 400 mg/kg

Magnesium NL mg/kg

Manganese 5,500 mg/kg

Mercury 33 mg/kg

Nickel 4,600 mg/kg

Potassium NL mg/kg

Selenium 1,200 mg/kg

Silver 1,200 mg/kg

Sodium NL mg/kg

Thallium 2.3 mg/kg

Vanadium 1,200 mg/kg

Zinc 70,000 mg/kg

Notes:

Bold = Exceeds EPA RML

EPA = Environmental Protection Agency

HQ = Hazard Quotient

RML = Removal Management Level

ID = Identification

J = Value is approximate

Analyte

EPA RML

(TCR = 10-4

&

HQ = 3)

Residential Soil

FF-SS06-

160218

FF-SS09-

160218

FF-SS10-

160218

FF-SS11-

160218

FF-SS12-

160218

ResultsJ-

ResultsJ-

10,100 8,460 7,910 7,820 10,900

1.4 1.3 0.96 ND 1.1

10.8 11.1 10 11.4 12.9

87.4 102 115 138 141

0.66 0.67 0.55 1.7 0.82

ND ND ND 0.61 0.26

10,900 3,710 2,490 8,600 42,900

14.9 13.6 12.7 11.4 18.4

7.1 9.1 7.2 7.1 8

26.2 22.6 16.7 39.1 25.6

21,800 18,600 17,900 ND 23,700

98.8 108 58.3 98.9 127

5,400 2,030 1,620 2,020 23,700

479 873 709 357 458

0.047 0.1 0.037 0.043 0.039

16.7 15 12.1 18.1 22.7

1,550 1,520 1,220 798 1,420

0.94 1.4 1.3 ND 0.74

0.081 0.16 0.14 0.24 0.092

41.4 22.7 14.4 262 89.1

ND 0.14 ND 0.23 ND

26.3 23.8 22.8 24.9 25.4

136 188 112 213 177

J+ = Value may be biased high

J- = Value may be biased low

mg/kg = milligrams per kilogram

ND = Not Detected

NL = Not Listed

TCR = Target Cancer Risk

Table 1




Sample ID

Units


Antimony 94 mg/kg

Arsenic 68 mg/kg

Barium 46,000 mg/kg

Beryllium 470 mg/kg

Cadmium 210 mg/kg

Calcium NL mg/kg

Chromium NL mg/kg

Cobalt 70 mg/kg

Copper 9,400 mg/kg

Iron 160,000 mg/kg

Lead 400 mg/kg

Magnesium NL mg/kg


Mercury 33 mg/kg

Nickel 4,600 mg/kg

Potassium NL mg/kg


Silver 1,200 mg/kg

Sodium NL mg/kg

Thallium 2.3 mg/kg


Zinc 70,000 mg/kg

Notes:





ID = Identification


Analyte

EPA RML

(TCR = 10-4

&

HQ = 3)

Residential Soil

FF-SS15-

160218

FF-SS16-

160218

FF-SS18-

160218

FF-SS19-

160218

ResultsJ-

Results

9,720 9,100 8,970 10,700

1.2 1.3 0.95 2.5

12.2 12.5 13 13.8

109 86.4 309 155

0.68 0.66 0.74 0.94

ND ND 0.51 0.21

4,480 6,000 5,460 16,800

15.9 16.9 29.3 17

8.7 7.7 8.8 8

25.6 26.1 37.3 36.6

23,800 22,300 21,500 23,300

104 100 259 189

2,890 3,720 3,150 9,510

707 704 733 595

0.11 0.088 0.05 0.076

18.7 17.5 17.1 21.8

1,390 1,050 1,040 1,860

1.2 0.98 1.1 1.5

0.14 0.19 0.15 0.12

27.3 26.8 29.8 54.7

ND ND ND ND

25.8 27.2 25.3 28.4

169 140 252 258




ND = Not Detected

NL = Not Listed


Table 1




Sample ID

Units


Antimony 94 mg/kg

Arsenic 68 mg/kg

Barium 46,000 mg/kg

Beryllium 470 mg/kg

Cadmium 210 mg/kg

Calcium NL mg/kg

Chromium NL mg/kg

Cobalt 70 mg/kg

Copper 9,400 mg/kg

Iron 160,000 mg/kg

Lead 400 mg/kg

Magnesium NL mg/kg


Mercury 33 mg/kg

Nickel 4,600 mg/kg

Potassium NL mg/kg


Silver 1,200 mg/kg

Sodium NL mg/kg

Thallium 2.3 mg/kg


Zinc 70,000 mg/kg

Notes:





ID = Identification


Analyte

EPA RML

(TCR = 10-4

&

HQ = 3)

Residential Soil

FF-

ALLEY 1-

160330

FF-

BACK COMP-

160330

FF-

GARDEN

COMP-

160330

FF-

FRONT

COMP-

160330

Results Results

1,060 8,230 8,580 7,720

0.35J

2.2 4.1 2

11.7 13.8 15.3 13.3

14.1 166 196 123

0.055 0.45 0.66 0.34

0.16 0.57 0.99 0.41

181,000 13,000 17,600 11,400

13.3 17.3 18.1 14.2

0.95 6.7 6.1 7.6

13.7 34.5 43.1 26.3

2,950 14,800 14,400 13,100

49.1 145 239 133

111,000 7,610 9,340 6,970

154 546 441 588

ND 0.15 0.22 0.11

3.3 17.3 16.8 14.6

412 1,160 1,300 1,070

0.61J+

1.1J+

1.6 2

ND 0.064J

0.19 ND

197 48.1 80.2 49.2

ND ND ND ND

3.4 21.3 21.7 20.4

37.3 241 351 242




ND = Not Detected

NL = Not Listed


Table 1




Sample ID

Units


Antimony 94 mg/kg

Arsenic 68 mg/kg

Barium 46,000 mg/kg

Beryllium 470 mg/kg

Cadmium 210 mg/kg

Calcium NL mg/kg

Chromium NL mg/kg

Cobalt 70 mg/kg

Copper 9,400 mg/kg

Iron 160,000 mg/kg

Lead 400 mg/kg

Magnesium NL mg/kg


Mercury 33 mg/kg

Nickel 4,600 mg/kg

Potassium NL mg/kg


Silver 1,200 mg/kg

Sodium NL mg/kg

Thallium 2.3 mg/kg


Zinc 70,000 mg/kg

Notes:





ID = Identification


Analyte

EPA RML

(TCR = 10-4

&

HQ = 3)

Residential Soil

FF-

GARDEN

COMP-

160330

FF-

ALLEY 2-

160330

FF-

YARD

COMP-

160330

FF-

BACK COMP-

160330

Results Results

7,730 1,080 9,150 8,550

1.2 0.8J

0.7J

1.6

10.7 3J+

12.4 15.7

95.8 45.4J

104 178

0.36 0.057 0.42 0.35

0.35 0.3J-

0.35 1.1

21,300 167,000 69,900 29,700

12.7 6.5J-

14.8 20.2

6 0.93J-

7.7 7.7

25.3 13.8J-

25.4 51

13,100 3,300 14,700 18,300

77.6 71.6J-

42.7 182

12,600 99,600 22,400 10,200

386 156J

314 539

0.099 ND 0.14 0.19

15.5 7.5J-

21.7 17.8

1,230 336 1,620 1,520

1J+

0.47J+

1J+

1.3J+

0.028J

0.033J-

ND 0.076J

52.1 234 83.9 74

ND ND ND ND

19.4 3.3 21.4 20.9

130 74J

107 325




ND = Not Detected

NL = Not Listed


Table 1




Sample ID

Units


Antimony 94 mg/kg

Arsenic 68 mg/kg

Barium 46,000 mg/kg

Beryllium 470 mg/kg

Cadmium 210 mg/kg

Calcium NL mg/kg

Chromium NL mg/kg

Cobalt 70 mg/kg

Copper 9,400 mg/kg

Iron 160,000 mg/kg

Lead 400 mg/kg

Magnesium NL mg/kg


Mercury 33 mg/kg

Nickel 4,600 mg/kg

Potassium NL mg/kg


Silver 1,200 mg/kg

Sodium NL mg/kg

Thallium 2.3 mg/kg


Zinc 70,000 mg/kg

Notes:





ID = Identification


Analyte

EPA RML

(TCR = 10-4

&

HQ = 3)

Residential Soil

FF- BACK

GRAB-160330

FF- FRONT

COMP-160330

Results

6,010 8,500

1.8 1.5

10.4 16.5

128 141

0.42 0.42

0.8 0.35

91,600 14,900

12.7 15.4

4.4 7.6

32.7 25.6

11,200 13,600

186 104

53,000 9,180

331 574

0.1 0.14

12.5 16.2

1,020 892

1.2J+

1.4

0.11J

ND

147 42.8

ND ND

15.5 21.6

254 194




ND = Not Detected

NL = Not Listed


APPENDIX D

LABORATORY ANALYTICAL REPORTS AND DATA VALIDATION REPORTS

CT Laboratories LLC • 1230 Lange Court • Baraboo, WI 53913 • 608-356-2760 www.ctlaboratories.com

ANALYTICAL REPORT

This report at a minimum contains the following information: • Analytical Report of Test Results • Description of QC Qualifiers • Chain of Custody (copy) • Quality Control Summary • Case Narrative (if applicable) • Correspondence with Client (if applicable) This report has been specifically prepared to satisfy project or program requirements. These results are in compliance with NELAC requirements for parameters where accreditation is required or available, unless otherwise noted in the case narrative.

117985 - Page 1 of 39

ANALYTICAL REPORT

LUCAS STAMPS

INDIANAPOLIS, IN 46239

Purchase Order #: 13-09-035

Project Name: FRANK FOUNDRY

Contract #: 2827

Folder #: 117985

1611 SOUTH FRANKLIN ROAD

Date Received: 04/01/2016

Arrival Temperature: 3.9

Report Date: 04/11/2016

QEPI

Reprint Date:

Page 1 of 12

1230 Lange Court • Baraboo, WI 53913 • 608-356-2760

www.ctlaboratories.com

Project #: 1507-204

Project Phase:

04/11/2016

CT LAB#: 702557

Result Units DL DODLOQ

RL DF Qualifier PrepDate/Time

AnalysisDate/Time

Analyst Method

Sampled: 03/30/2016 1120

Analyte

Sample Description: FF- ALLEY 1-160330

DODLOD

Client Sample #:

Inorganic Results

%89.7 4/5/16 JJFSolids, Percent 13:200.1 EPA 8000C0.1 1.000.10.1

Metals Results

mg/kg1060 4/6/16 NAHAluminum 04/04/2016 09:00 17:40 ^0.27 EPA 6010C0.13 1.000.270.045

mg/kg0.35 4/6/16 NAHAntimony 04/04/2016 09:00 17:40 ^J0.89 EPA 6010C0.45 1.000.890.14

mg/kg11.7 4/6/16 NAHArsenic 04/04/2016 09:00 17:40 ^0.89 EPA 6010C0.45 1.000.890.14

mg/kg14.1 4/6/16 NAHBarium 04/04/2016 09:00 17:40 ^0.056 EPA 6010C0.028 1.000.0560.010

mg/kg0.055 4/6/16 NAHBeryllium 04/04/2016 09:00 17:40 ^0.045 EPA 6010C0.013 1.000.0450.0045

mg/kg0.16 4/6/16 NAHCadmium 04/04/2016 09:00 17:40 ^0.045 EPA 6010C0.022 1.000.0450.0067

mg/kg181000 4/7/16 NAHCalcium 04/04/2016 09:00 14:54 ^16 EPA 6010C7.8 10.00162.7

mg/kg13.3 4/6/16 NAHChromium 04/04/2016 09:00 17:40 ^0.16 EPA 6010C0.078 1.000.160.026

mg/kg0.95 4/6/16 NAHCobalt 04/04/2016 09:00 17:40 ^0.27 EPA 6010C0.13 1.000.270.045

mg/kg13.7 4/6/16 NAHCopper 04/04/2016 09:00 17:40 ^0.45 EPA 6010C0.22 1.000.450.078

mg/kg2950 4/6/16 NAHIron 04/04/2016 09:00 17:40 ^2.0 EPA 6010C1.0 1.002.00.33

mg/kg49.1 4/6/16 NAHLead 04/04/2016 09:00 17:40 ^0.28 EPA 6010C0.14 1.000.280.045

mg/kg111000 4/7/16 NAHMagnesium 04/04/2016 09:00 14:54 ^8.9 EPA 6010C4.5 10.008.91.6

mg/kg154 4/6/16 NAHManganese 04/04/2016 09:00 17:40 ^0.17 EPA 6010C0.084 1.000.170.028

Unless specifically stated to the contrary, soil/sediment/sludge sample results reported on a Dry Weight Basis

117985 - Page 2 of 39

of 12Project Name: FRANK FOUNDRY

Contract #: 2827 Folder #: 117985

Project #: 1507-204

QEPI

Project Phase:

CT LAB#: 702557



AnalysisDate/Time

Analyst Method

Sampled: 03/30/2016 1120

Analyte


DODLOD

Client Sample #:

mg/kg3.3 4/6/16 NAHNickel 04/04/2016 09:00 17:40 ^0.13 EPA 6010C0.067 1.000.130.023

mg/kg0.61 B 4/6/16 NAHSelenium 04/04/2016 09:00 17:40 ^0.45 EPA 6010C0.22 1.000.450.067

mg/kg<0.019 4/6/16 NAHSilver 04/04/2016 09:00 17:40 Û0.11 EPA 6010C0.056 1.000.110.019

mg/kg<0.089 4/6/16 NAHThallium 04/04/2016 09:00 17:40 Û0.54 EPA 6010C0.27 1.000.540.089

mg/kg3.4 4/6/16 NAHVanadium 04/04/2016 09:00 17:40 ^0.089 EPA 6010C0.045 1.000.0890.013

mg/kg37.3 4/6/16 NAHZinc 04/04/2016 09:00 17:40 ^0.33 EPA 6010C0.17 1.000.330.056

mg/kg412 4/6/16 MDSPotassium 04/04/2016 09:00 10:47 ^74 EPA 6010C37 1.007412

mg/kg197 4/6/16 MDSSodium 04/04/2016 09:00 10:47 ^27 EPA 6010C13 1.00274.5

mg/kg<0.0024 4/8/16 LJFMercury 04/07/2016 10:30 09:44 Û0.0096 EPA 7471B0.0048 1.000.00960.0024

CT LAB#: 702558



AnalysisDate/Time

Analyst Method

Sampled: 03/30/2016 1145

Analyte

Sample Description: FF- BACK COMP-160330

DODLOD

Client Sample #:

Inorganic Results


Metals Results


mg/kg2.2 4/6/16 NAHAntimony 04/04/2016 09:00 17:47 ^1.1 EPA 6010C0.55 1.001.10.18


mg/kg166 4/6/16 NAHBarium 04/04/2016 09:00 17:47 ^0.068 EPA 6010C0.034 1.000.0680.012



mg/kg13000 4/6/16 NAHCalcium 04/04/2016 09:00 17:47 ^1.9 EPA 6010C0.96 1.001.90.33





117985 - Page 3 of 39



Project #: 1507-204

QEPI

Project Phase:

CT LAB#: 702558



AnalysisDate/Time

Analyst Method

Sampled: 03/30/2016 1145

Analyte


DODLOD

Client Sample #:


mg/kg145 4/6/16 NAHLead 04/04/2016 09:00 17:47 ^0.34 EPA 6010C0.17 1.000.340.055





mg/kg0.064 4/6/16 NAHSilver 04/04/2016 09:00 17:47 ^J0.14 EPA 6010C0.068 1.000.140.023



mg/kg241 4/6/16 NAHZinc 04/04/2016 09:00 17:47 ^0.41 EPA 6010C0.20 1.000.410.068


mg/kg48.1 4/6/16 MDSSodium 04/04/2016 09:00 10:50 ^33 EPA 6010C16 1.00335.5

mg/kg0.15 4/8/16 LJFMercury 04/07/2016 10:30 09:51 ^0.012 EPA 7471B0.0059 1.000.0120.0029

CT LAB#: 702559



AnalysisDate/Time

Analyst Method

Sampled: 03/30/2016 1152

Analyte

Sample Description: FF- GARDEN COMP-160330

DODLOD

Client Sample #:

Inorganic Results


Metals Results








117985 - Page 4 of 39



Project #: 1507-204

QEPI

Project Phase:

CT LAB#: 702559



AnalysisDate/Time

Analyst Method

Sampled: 03/30/2016 1152

Analyte


DODLOD

Client Sample #:











mg/kg0.19 4/6/16 NAHSilver 04/04/2016 09:00 17:53 ^0.14 EPA 6010C0.069 1.000.140.024







CT LAB#: 702560



AnalysisDate/Time

Analyst Method

Sampled: 03/30/2016 1200

Analyte

Sample Description: FF- FRONT COMP-160330

DODLOD

Client Sample #:

Inorganic Results


Metals Results




117985 - Page 5 of 39



Project #: 1507-204

QEPI

Project Phase:

CT LAB#: 702560



AnalysisDate/Time

Analyst Method

Sampled: 03/30/2016 1200

Analyte


DODLOD

Client Sample #:














mg/kg2.0 4/6/16 NAHSelenium 04/04/2016 09:00 18:00 ^0.57 EPA 6010C0.28 1.000.570.085








CT LAB#: 702561



AnalysisDate/Time

Analyst Method

Sampled: 03/30/2016 1215

Analyte


DODLOD

Client Sample #:

Inorganic Results



117985 - Page 6 of 39



Project #: 1507-204

QEPI

Project Phase:

CT LAB#: 702561



AnalysisDate/Time

Analyst Method

Sampled: 03/30/2016 1215

Analyte


DODLOD

Client Sample #:

Metals Results

























117985 - Page 7 of 39



Project #: 1507-204

QEPI

Project Phase:

CT LAB#: 702562



AnalysisDate/Time

Analyst Method

Sampled: 03/30/2016 1230

Analyte


DODLOD

Client Sample #:

Inorganic Results


Metals Results

mg/kg1080 M 4/6/16 NAHAluminum 04/04/2016 09:00 18:12 ^0.26 EPA 6010C0.13 1.000.260.044

mg/kg0.80 Y 4/6/16 NAHAntimony 04/04/2016 09:00 18:12 ^J0.88 EPA 6010C0.44 1.000.880.14


mg/kg45.4 Y,M 4/6/16 NAHBarium 04/04/2016 09:00 18:12 ^0.055 EPA 6010C0.028 1.000.0550.0099


mg/kg0.30 M 4/6/16 NAHCadmium 04/04/2016 09:00 18:12 ^0.044 EPA 6010C0.022 1.000.0440.0066


mg/kg6.5 Y 4/6/16 NAHChromium 04/04/2016 09:00 18:12 ^0.15 EPA 6010C0.077 1.000.150.025


mg/kg13.8 Y 4/6/16 NAHCopper 04/04/2016 09:00 18:12 ^0.44 EPA 6010C0.22 1.000.440.077

mg/kg3300 M 4/6/16 NAHIron 04/04/2016 09:00 18:12 ^2.0 EPA 6010C0.99 1.002.00.33

mg/kg71.6 Y 4/6/16 NAHLead 04/04/2016 09:00 18:12 ^0.28 EPA 6010C0.14 1.000.280.044


mg/kg156 Y,M 4/6/16 NAHManganese 04/04/2016 09:00 18:12 ^0.17 EPA 6010C0.083 1.000.170.028

mg/kg7.5 Y,M 4/6/16 NAHNickel 04/04/2016 09:00 18:12 ^0.13 EPA 6010C0.066 1.000.130.023


mg/kg0.033 M,Y 4/6/16 NAHSilver 04/04/2016 09:00 18:12 ^J0.11 EPA 6010C0.055 1.000.110.019

mg/kg<0.088 M 4/6/16 NAHThallium 04/04/2016 09:00 18:12 ^U0.53 EPA 6010C0.26 1.000.530.088


mg/kg74.0 M 4/6/16 NAHZinc 04/04/2016 09:00 18:12 ^0.33 EPA 6010C0.17 1.000.330.055



mg/kg<0.0024 M 4/8/16 LJFMercury 04/07/2016 10:30 09:59 ^U0.0096 EPA 7471B0.0049 1.000.00960.0024


117985 - Page 8 of 39



Project #: 1507-204

QEPI

Project Phase:

CT LAB#: 702563



AnalysisDate/Time

Analyst Method

Sampled: 03/30/2016 1240

Analyte

Sample Description: FF- YARD COMP-160330

DODLOD

Client Sample #:

Inorganic Results


Metals Results

























117985 - Page 9 of 39



Project #: 1507-204

QEPI

Project Phase:

CT LAB#: 702564



AnalysisDate/Time

Analyst Method

Sampled: 03/30/2016 1323

Analyte


DODLOD

Client Sample #:

Inorganic Results


Metals Results

























117985 - Page 10 of 39



Project #: 1507-204

QEPI

Project Phase:

CT LAB#: 702565



AnalysisDate/Time

Analyst Method

Sampled: 03/30/2016 1334

Analyte

Sample Description: FF- BACK GRAB-160330

DODLOD

Client Sample #:

Inorganic Results


Metals Results













mg/kg53000 4/7/16 NAHMagnesium 04/04/2016 09:00 16:03 ^11 EPA 6010C5.4 10.00111.9












117985 - Page 11 of 39



Project #: 1507-204

QEPI

Project Phase:

CT LAB#: 702566



AnalysisDate/Time

Analyst Method

Sampled: 03/30/2016 1345

Analyte


DODLOD

Client Sample #:

Inorganic Results


Metals Results

























117985 - Page 12 of 39

Notes: ^ Indicates the laboratory is NELAP accredited for this analyte by the indicated matrix and method. DL (detection limit), LOD (limit of detection), loq (limit of quantitation) as defined by most recent DOD QSM version.

Submitted by:

DescriptionCodeQC Qualifiers

B Analyte detected in the associated Method Blank.C Toxicity present in BOD sample.D Diluted Out.E Safe, No Total Coliform detected.F Unsafe, Total Coliform detected, no E. Coli detected.G Unsafe, Total Coliform detected and E. Coli detected.H Holding time exceeded.I BOD incubator temperature was outside acceptance limits during test period.J Estimated value.L Significant peaks were detected outside the chromatographic window.M Matrix spike and/or Matrix Spike Duplicate recovery outside acceptance limits.N Insufficient BOD oxygen depletion.O Complete BOD oxygen depletion.P Concentration of analyte differs more than 40% between primary and confirmation analysis.Q Laboratory Control Sample outside acceptance limits.R See Narrative at end of report.S Surrogate standard recovery outside acceptance limits due to apparent matrix effects.T Sample received with improper preservation or temperature.U Analyte concentration was below detection limit.V Raised Quantitation or Reporting Limit due to limited sample amount or dilution for matrix background interference.W Sample amount received was below program minimum.X Analyte exceeded calibration range.Y Replicate/Duplicate precision outside acceptance limits.Z Specified calibration criteria was not met.

Current CT Laboratories Certifications

Kansas NELAP ID# E-10368Kentucky ID# 0023ISO/IEC 17025-2005 A2LA Cert # 3806.01North Carolina ID# 674Wisconsin (WDNR) Chemistry ID# 157066030Wisconsin (DATCP) Bacteriology ID# 105-289DoD-ELAP A2LA 3806.01GA EPD Stipulation ID E871111, Expires AnnuallyLouisiana ID # 115843Virginia ID# 7608Illinois NELAP ID # 002413Wisconsin (WOSB) ID# WI-5499-WBEMaryland ID# 344

All samples were received intact and properly preserved unless otherwise noted. The results reported relate only to the samples tested. This report shall not be reproduced, except in full, without written approval of this laboratory. The Chain of Custody is attached.

This report has been specifically prepared to satisfy project or program requirements. These results are in compliance with NELAC requirements for the parameters where accreditation is required or available, unless noted in the case narrative.

117985 - Page 13 of 39

117985 - Page 14 of 39

117985 - Page 15 of 39

117985 - Page 16 of 39

1230 Lange Court • Baraboo , W I 53913 • 608 -356-2760

www.ctlabor atories .com

QC SUMMARY REPORT

QEPI Project Name: FRANK FOUNDRY

Project Number: 1507-204SDG #: 0 Folder #: 117985

Duplicate

04/05/2016Analytical Run #: Analysis Date:13:20Analysis Time:704308JJF

CTLab #:Analyst:

Prep Batch #:

702562Parent Sample #:Prep Date/Time:

SOILMatrix:

Prep Analyst:

RPD Limit

SpikeAmount Added

Analyte Units % Recovery

Control Limits

RPDQualifier(s)QCsample result

Parent sample result

124516Method: SW8000C

Solids, Percent % 1 890.2 89.5

Date Printed: 04/11/2016

CTLaboratories LLC 1230 Lange Court • Baraboo, WI 53913 • 608-356-2760


117985 - Page 17 of 39



Duplicate

04/06/2016Analytical Run #: Analysis Date:18:26Analysis Time:702893

56598

NAHCTLab #:

Analyst:

Prep Batch #:


SOIL

LJF

Matrix:

Prep Analyst:

RPD Limit

SpikeAmount Added


Control Limits



124544Method: SW601004/04/201609:00

Aluminum mg/kg 9.6 1 201070 1080Antimony mg/kg 32 34 200.57 0.80Arsenic mg/kg 32 14 202.6 3.0Barium mg/kg 2.0 22 2036.4 45.4Beryllium mg/kg 1.60 7 200.061 0.057Cadmium mg/kg 1.60 31 200.22 0.30Calcium mg/kg 56 2 20171000 167000Chromium mg/kg 5.6 22 205.2 6.5Cobalt mg/kg 9.6 4 200.89 0.93Copper mg/kg 16.0 24 2010.8 13.8Iron mg/kg 72 2 203220 3300Lead mg/kg 10.0 26 2055.3 71.6Magnesium mg/kg 32 2 20102000 99600Manganese mg/kg 6.0 32 20113 156Nickel mg/kg 4.8 86 203.0 7.5Selenium mg/kg 16 19 200.39 0.47Silver mg/kg U 4.0 200 200.0192 0.033Thallium mg/kg U 19 0 200.0903 <0.0903Vanadium mg/kg 3.2 3 203.4 3.3Zinc mg/kg 12.0 4 2071.1 74.0




117985 - Page 18 of 39



Lab Control Spike Soil


56598

NAHCTLab #:

Analyst:

Prep Batch #:

Parent Sample #:Prep Date/Time:

SOLID

LJF

Matrix:

Prep Analyst:

RPD Limit

SpikeAmount Added


Control Limits



124544Method: SW601004/04/201609:00

Aluminum mg/kg 97 12097.3 80 ---100Antimony mg/kg 101 12025.3 80 ---25.0Arsenic mg/kg 98 12098.0 80 ---100Barium mg/kg 106 120106 80 ---100Beryllium mg/kg 96 1202.4 80 ---2.5Cadmium mg/kg 88 1202.2 80 ---2.5Calcium mg/kg 90 1204500 80 ---5000Chromium mg/kg 97 1209.7 80 ---10.0Cobalt mg/kg 97 12024.3 80 ---25.0Copper mg/kg 98 12012.3 80 ---12.5Iron mg/kg 99 12049.3 80 ---50.0Lead mg/kg 93 12023.3 80 ---25.0Magnesium mg/kg 93 1202320 80 ---2500Manganese mg/kg 84 12021.1 80 ---25.0Nickel mg/kg 94 12023.6 80 ---25.0Selenium mg/kg 95 12094.8 80 ---100Silver mg/kg 84 1202.1 75 ---2.5Thallium mg/kg 90 12090.3 80 ---100Vanadium mg/kg 100 12025.0 80 ---25.0Zinc mg/kg 98 12024.6 80 ---25.0




117985 - Page 19 of 39



Method Blank Soil


56598

NAHCTLab #:

Analyst:

Prep Batch #:


SOLID

LJF

Matrix:

Prep Analyst:

RPD Limit

SpikeAmount Added


Control Limits



124544Method: SW601004/04/201609:00

Aluminum mg/kg 0.120.30 0Antimony mg/kg U 0.400.13 0Arsenic mg/kg U 0.400.13 0Barium mg/kg U 0.0250.009 0Beryllium mg/kg U 0.0200.004 0Cadmium mg/kg U 0.0200.006 0Calcium mg/kg 0.7012.9 0Chromium mg/kg U 0.1250.023 0Cobalt mg/kg U 0.120.04 0Copper mg/kg U 0.200.07 0Iron mg/kg 0.90.91 0Lead mg/kg U 0.1250.04 0Magnesium mg/kg 0.406.0 0Manganese mg/kg 0.0750.052 0Nickel mg/kg U 0.0600.021 0Selenium mg/kg 0.200.14 0Silver mg/kg U 0.0500.017 0Thallium mg/kg U 0.240.08 0Vanadium mg/kg U 0.0400.012 0Zinc mg/kg U 0.150.05 0




117985 - Page 20 of 39



Matrix Spike Duplicate Soil


56598

NAHCTLab #:

Analyst:

Prep Batch #:


SOIL

LJF

Matrix:

Prep Analyst:

RPD Limit

SpikeAmount Added


Control Limits



124544Method: SW601004/04/201609:00

Aluminum mg/kg 144 120 8 201240 1080 80 ---111Antimony mg/kg 82 120 36 2023.5 0.80 80 ---27.8Arsenic mg/kg 113 120 13 20128 3.0 80 ---111Barium mg/kg 114 120 2 20172 45.4 80 ---111Beryllium mg/kg 80 120 7 202.3 0.057 80 ---2.8Cadmium mg/kg 68 120 8 202.2 0.30 80 ---2.8Calcium mg/kg 72 120 2 20171000 167000 80 ---5560Chromium mg/kg 80 120 6 2015.4 6.5 80 ---11.1Cobalt mg/kg 78 120 11 2022.5 0.93 80 ---27.8Copper mg/kg 80 120 7 2024.9 13.8 80 ---13.9Iron mg/kg 0 120 11 203250 3300 80 ---55.6Lead mg/kg 120 120 17 20105 71.6 80 ---27.8Magnesium mg/kg 122 120 2 20103000 99600 80 ---2780Manganese mg/kg 0 120 13 20151 156 80 ---27.8Nickel mg/kg 56 120 5 2023.1 7.5 80 ---27.8Selenium mg/kg 98 120 15 20109 0.47 80 ---111Silver mg/kg 70 125 23 202.0 0.033 75 ---2.8Thallium mg/kg 66 120 14 2073.4 BDL 80 ---111Vanadium mg/kg 103 120 7 2032.0 3.3 80 ---27.8Zinc mg/kg 155 120 22 20117 74.0 80 ---27.8




117985 - Page 21 of 39



Matrix Spike Soil


56598

NAHCTLab #:

Analyst:

Prep Batch #:


SOIL

LJF

Matrix:

Prep Analyst:

RPD Limit

SpikeAmount Added


Control Limits



124544Method: SW601004/04/201609:00

Aluminum mg/kg 71 1201160 1080 80 ---113Antimony mg/kg 119 12034.6 0.80 80 ---28.4Arsenic mg/kg 129 120149 3.0 80 ---113Barium mg/kg 118 120179 45.4 80 ---113Beryllium mg/kg 87 1202.5 0.057 80 ---2.8Cadmium mg/kg 75 1202.4 0.30 80 ---2.8Calcium mg/kg 71 120171000 167000 80 ---5670Chromium mg/kg 74 12014.9 6.5 80 ---11.3Cobalt mg/kg 87 12025.7 0.93 80 ---28.4Copper mg/kg 70 12023.7 13.8 80 ---14.2Iron mg/kg 0 1202980 3300 80 ---56.7Lead mg/kg 67 12090.5 71.6 80 ---28.4Magnesium mg/kg 155 120104000 99600 80 ---2840Manganese mg/kg 0 120136 156 80 ---28.4Nickel mg/kg 61 12024.8 7.5 80 ---28.4Selenium mg/kg 114 120129 0.47 80 ---113Silver mg/kg 88 1252.5 0.033 75 ---2.8Thallium mg/kg 76 12085.9 BDL 80 ---113Vanadium mg/kg 111 12034.9 3.3 80 ---28.4Zinc mg/kg 75 12095.3 74.0 80 ---28.4




117985 - Page 22 of 39



Duplicate


56598

MDSCTLab #:

Analyst:

Prep Batch #:


SOIL

LJF

Matrix:

Prep Analyst:

RPD Limit

SpikeAmount Added


Control Limits



124545Method: SW601004/04/201609:00

Potassium mg/kg 2.64 18 20403 336




117985 - Page 23 of 39



Duplicate


56598

MDSCTLab #:

Analyst:

Prep Batch #:


SOIL

LJF

Matrix:

Prep Analyst:

RPD Limit

SpikeAmount Added


Control Limits



124545Method: SW601004/04/201609:00

Sodium mg/kg 0.96 8 20215 234




117985 - Page 24 of 39





56598

MDSCTLab #:

Analyst:

Prep Batch #:


SOLID

LJF

Matrix:

Prep Analyst:

RPD Limit

SpikeAmount Added


Control Limits



124545Method: SW601004/04/201609:00

Potassium mg/kg 94 1202360 80 ---2500




117985 - Page 25 of 39





56598

MDSCTLab #:

Analyst:

Prep Batch #:


SOLID

LJF

Matrix:

Prep Analyst:

RPD Limit

SpikeAmount Added


Control Limits



124545Method: SW601004/04/201609:00

Sodium mg/kg 89 1202220 80 ---2500




117985 - Page 26 of 39



Method Blank Soil


56598

MDSCTLab #:

Analyst:

Prep Batch #:


SOLID

LJF

Matrix:

Prep Analyst:

RPD Limit

SpikeAmount Added


Control Limits



124545Method: SW601004/04/201609:00

Potassium mg/kg U 3311 0




117985 - Page 27 of 39



Method Blank Soil


56598

MDSCTLab #:

Analyst:

Prep Batch #:


SOLID

LJF

Matrix:

Prep Analyst:

RPD Limit

SpikeAmount Added


Control Limits



124545Method: SW601004/04/201609:00

Sodium mg/kg U 124 0




117985 - Page 28 of 39





56598

MDSCTLab #:

Analyst:

Prep Batch #:


SOIL

LJF

Matrix:

Prep Analyst:

RPD Limit

SpikeAmount Added


Control Limits



124545Method: SW601004/04/201609:00

Potassium mg/kg 114 120 3 203500 336 80 ---2780




117985 - Page 29 of 39





56598

MDSCTLab #:

Analyst:

Prep Batch #:


SOIL

LJF

Matrix:

Prep Analyst:

RPD Limit

SpikeAmount Added


Control Limits



124545Method: SW601004/04/201609:00

Sodium mg/kg 97 120 1 202920 234 80 ---2780




117985 - Page 30 of 39



Matrix Spike Soil


56598

MDSCTLab #:

Analyst:

Prep Batch #:


SOIL

LJF

Matrix:

Prep Analyst:

RPD Limit

SpikeAmount Added


Control Limits



124545Method: SW601004/04/201609:00

Potassium mg/kg 110 1203460 336 80 ---2840




117985 - Page 31 of 39



Matrix Spike Soil


56598

MDSCTLab #:

Analyst:

Prep Batch #:


SOIL

LJF

Matrix:

Prep Analyst:

RPD Limit

SpikeAmount Added


Control Limits



124545Method: SW601004/04/201609:00

Sodium mg/kg 98 1203010 234 80 ---2840




117985 - Page 32 of 39



Duplicate


56616

LJFCTLab #:

Analyst:

Prep Batch #:


SOIL

LJF

Matrix:

Prep Analyst:

RPD Limit

SpikeAmount Added


Control Limits



124632Method: SW7471B04/07/201610:30

Mercury mg/kg 0.20 200 200.0041 <0.00256




117985 - Page 33 of 39





56616

LJFCTLab #:

Analyst:

Prep Batch #:


SOLID

LJF

Matrix:

Prep Analyst:

RPD Limit

SpikeAmount Added


Control Limits



124632Method: SW7471B04/07/201610:30

Mercury mg/kg 116 1200.096 80 ---0.083




117985 - Page 34 of 39



Method Blank Soil


56616

LJFCTLab #:

Analyst:

Prep Batch #:


SOLID

LJF

Matrix:

Prep Analyst:

RPD Limit

SpikeAmount Added


Control Limits



124632Method: SW7471B04/07/201610:30

Mercury mg/kg U 004150.0021 0




117985 - Page 35 of 39





56616

LJFCTLab #:

Analyst:

Prep Batch #:


SOIL

LJF

Matrix:

Prep Analyst:

RPD Limit

SpikeAmount Added


Control Limits



124632Method: SW7471B04/07/201610:30

Mercury mg/kg 120 120 195 200.12 BDL 80 ---0.10




117985 - Page 36 of 39



Matrix Spike Soil


56616

LJFCTLab #:

Analyst:

Prep Batch #:


SOIL

LJF

Matrix:

Prep Analyst:

RPD Limit

SpikeAmount Added


Control Limits



124632Method: SW7471B04/07/201610:30

Mercury mg/kg U 1 1200.00256 BDL 80 ---0.10




117985 - Page 37 of 39

117985

Sample Condition Report Folder #: 117985 Print Date / Time: 04/01/2016 13:44 Client: QEPI Received Date / Time / By: 04/01/2016 1220 JLS Project Name: FRANK FOUNDRY Log-In Date / Time / By: 04/01/2016 1341 BNA Project Phase: Project #: 1507-204 PM: BMS Coolers: 5518 Temperature: 3.9 C On Ice: Y Custody Seals Present : Y COC Present:? Y Complete? Y Seal Intact? Y Numbers: SIGNED AND DATED Ship Method: FED EX EXPRESS Tracking Number: 874833617021 Adequate Packaging: Y Temp Blank Enclosed? Y Notes: THE SAMPLES WERE RECEIVED IN GOOD CONDITION ON ICE. ONE CUSTODY SEAL PRESENT AND INTACT, DATED 03/31/2016 AND SIGNED. ___________________________________________________________________________________________________________ Sample ID / Description Container Type Cond. Code pH OK?/Filtered? Tests _________________________________________________________________________________________________________ 702557 FF- ALLEY 1-160330 SOLIDS 1 / %SOL,HG,ICP,K,NA Total # of Containers of Type ( SOLIDS ) = 1 ___________________________________________________________________________________________________________ Sample ID / Description Container Type Cond. Code pH OK?/Filtered? Tests _________________________________________________________________________________________________________ 702558 FF- BACK COMP-160330 SOLIDS 1 / %SOL,HG,ICP,K,NA Total # of Containers of Type ( SOLIDS ) = 1 ___________________________________________________________________________________________________________ Sample ID / Description Container Type Cond. Code pH OK?/Filtered? Tests _________________________________________________________________________________________________________ 702559 FF- GARDEN COMP-160330 SOLIDS 1 / %SOL,HG,ICP,K,NA Total # of Containers of Type ( SOLIDS ) = 1 ___________________________________________________________________________________________________________ Sample ID / Description Container Type Cond. Code pH OK?/Filtered? Tests _________________________________________________________________________________________________________ 702560 FF- FRONT COMP-160330 SOLIDS 1 / %SOL,HG,ICP,K,NA Total # of Containers of Type ( SOLIDS ) = 1 ___________________________________________________________________________________________________________ Sample ID / Description Container Type Cond. Code pH OK?/Filtered? Tests _________________________________________________________________________________________________________ 702561 FF- GARDEN COMP-160330 SOLIDS 1 / %SOL,HG,ICP,K,NA Total # of Containers of Type ( SOLIDS ) = 1

117985 - Page 38 of 39

117985

___________________________________________________________________________________________________________ Sample ID / Description Container Type Cond. Code pH OK?/Filtered? Tests _________________________________________________________________________________________________________ 702562 FF- ALLEY 2-160330 SOLIDS 1 / %SOL,HG,ICP,K,NA Total # of Containers of Type ( SOLIDS ) = 1 ___________________________________________________________________________________________________________ Sample ID / Description Container Type Cond. Code pH OK?/Filtered? Tests _________________________________________________________________________________________________________ 702563 FF- YARD COMP-160330 SOLIDS 1 / %SOL,HG,ICP,K,NA Total # of Containers of Type ( SOLIDS ) = 1 ___________________________________________________________________________________________________________ Sample ID / Description Container Type Cond. Code pH OK?/Filtered? Tests _________________________________________________________________________________________________________ 702564 FF- BACK COMP-160330 SOLIDS 1 / %SOL,HG,ICP,K,NA Total # of Containers of Type ( SOLIDS ) = 1 ___________________________________________________________________________________________________________ Sample ID / Description Container Type Cond. Code pH OK?/Filtered? Tests _________________________________________________________________________________________________________ 702565 FF- BACK GRAB-160330 SOLIDS 1 / %SOL,HG,ICP,K,NA Total # of Containers of Type ( SOLIDS ) = 1 ___________________________________________________________________________________________________________ Sample ID / Description Container Type Cond. Code pH OK?/Filtered? Tests _________________________________________________________________________________________________________ 702566 FF- FRONT COMP-160330 SOLIDS 1 / %SOL,HG,ICP,K,NA Total # of Containers of Type ( SOLIDS ) = 1 ___________________________________________________________________________________________________________ Condition Code Condition Description 1 Sample Received OK

117985 - Page 39 of 39

CT Laboratories LLC • 1230 Lange Court • Baraboo, WI 53913 • 608-356-2760 www.ctlaboratories.com

ANALYTICAL REPORT

This report at a minimum contains the following information: • Analytical Report of Test Results • Description of QC Qualifiers • Chain of Custody (copy) • Quality Control Summary • Case Narrative (if applicable) • Correspondence with Client (if applicable) This report has been specifically prepared to satisfy project or program requirements. These results are in compliance with NELAC requirements for parameters where accreditation is required or available, unless otherwise noted in the case narrative.

117164 - Page 1 of 46

ANALYTICAL REPORT

KEITH HUGHES

INDIANAPOLIS, IN 46239

Purchase Order #: 1507-204

Project Name: FRANK FOUNDRY

Contract #: 2827

Folder #: 117164

1611 SOUTH FRANKLIN ROAD

Date Received: 2/23/2016

Arrival Temperature: 7.0

Report Date: 3/2/2016

QEPI

Reprint Date:

Page 1 of 18

1230 Lange Court • Baraboo, WI 53913 • 608-356-2760


Project #: 1507-204

Project Phase:

3/2/2016

CT LAB#: 690926



AnalysisDate/Time

Analyst Method

Sampled: 2/18/2016 1100

Analyte

Sample Description: FF-SS01-160218

DODLOD

Client Sample #:

Inorganic Results


Metals Results

mg/kg11600 M 2/24/16 NAHAluminum 2/24/2016 08:00 20:15 ^0.34 EPA 6010C0.17 1.000.340.057





mg/kg<0.0085 M 2/24/16 NAHCadmium 2/24/2016 08:00 20:15 ^U0.057 EPA 6010C0.028 1.000.0570.0085

mg/kg3580 B,M 2/24/16 NAHCalcium 2/24/2016 08:00 20:15 ^2.0 EPA 6010C0.99 1.002.00.34

mg/kg18.9 M 2/24/16 NAHChromium 2/24/2016 08:00 20:15 ^0.20 EPA 6010C0.099 1.000.200.033

mg/kg8.1 M 2/24/16 NAHCobalt 2/24/2016 08:00 20:15 ^0.34 EPA 6010C0.17 1.000.340.057

mg/kg21.5 M 2/24/16 NAHCopper 2/24/2016 08:00 20:15 ^0.57 EPA 6010C0.28 1.000.570.099

mg/kg24200 B,M 2/24/16 NAHIron 2/24/2016 08:00 20:15 ^2.6 EPA 6010C1.3 1.002.60.43

mg/kg59.6 M 2/24/16 NAHLead 2/24/2016 08:00 20:15 ^0.35 EPA 6010C0.18 1.000.350.057

mg/kg2630 B,M 2/24/16 NAHMagnesium 2/24/2016 08:00 20:15 ^1.1 EPA 6010C0.57 1.001.10.20

mg/kg415 M 2/24/16 NAHManganese 2/24/2016 08:00 20:15 ^0.21 EPA 6010C0.11 1.000.210.035


117164 - Page 2 of 46



Project #: 1507-204

QEPI

Project Phase:

CT LAB#: 690926



AnalysisDate/Time

Analyst Method

Sampled: 2/18/2016 1100

Analyte


DODLOD

Client Sample #:

mg/kg18.4 M 2/24/16 NAHNickel 2/24/2016 08:00 20:15 ^0.17 EPA 6010C0.085 1.000.170.030

mg/kg1.1 B,M 2/24/16 NAHSelenium 2/24/2016 08:00 20:15 ^0.57 EPA 6010C0.28 1.000.570.085

mg/kg0.027 M 2/24/16 NAHSilver 2/24/2016 08:00 20:15 ^J0.14 EPA 6010C0.071 1.000.140.024

mg/kg<0.11 M 2/24/16 NAHThallium 2/24/2016 08:00 20:15 ^U0.68 EPA 6010C0.34 1.000.680.11

mg/kg31.0 M 2/24/16 NAHVanadium 2/24/2016 08:00 20:15 ^0.11 EPA 6010C0.057 1.000.110.017

mg/kg100 M 2/24/16 NAHZinc 2/24/2016 08:00 20:15 ^0.43 EPA 6010C0.21 1.000.430.071


mg/kg24.9 2/25/16 MDSSodium 2/24/2016 08:00 09:06 ^J34 EPA 6010C17 1.00345.7


CT LAB#: 690927



AnalysisDate/Time

Analyst Method

Sampled: 2/18/2016 1107

Analyte


DODLOD

Client Sample #:

Inorganic Results


Metals Results

mg/kg8960 B 2/24/16 NAHAluminum 2/24/2016 08:00 21:11 ^0.37 EPA 6010C0.18 1.000.370.061





mg/kg<0.0092 2/24/16 NAHCadmium 2/24/2016 08:00 21:11 ^U0.061 EPA 6010C0.031 1.000.0610.0092

mg/kg3320 B 2/24/16 NAHCalcium 2/24/2016 08:00 21:11 ^2.2 EPA 6010C1.1 1.002.20.37





117164 - Page 3 of 46



Project #: 1507-204

QEPI

Project Phase:

CT LAB#: 690927



AnalysisDate/Time

Analyst Method

Sampled: 2/18/2016 1107

Analyte


DODLOD

Client Sample #:

mg/kg18400 B 2/24/16 NAHIron 2/24/2016 08:00 21:11 ^2.8 EPA 6010C1.4 1.002.80.46


mg/kg2000 B 2/24/16 NAHMagnesium 2/24/2016 08:00 21:11 ^1.2 EPA 6010C0.61 1.001.20.22





mg/kg1.5 2/24/16 NAHThallium 2/24/2016 08:00 21:11 ^0.74 EPA 6010C0.37 1.000.740.12






CT LAB#: 690928



AnalysisDate/Time

Analyst Method

Sampled: 2/18/2016 1112

Analyte


DODLOD

Client Sample #:

Inorganic Results


Metals Results








117164 - Page 4 of 46



Project #: 1507-204

QEPI

Project Phase:

CT LAB#: 690928



AnalysisDate/Time

Analyst Method

Sampled: 2/18/2016 1112

Analyte


DODLOD

Client Sample #:


















CT LAB#: 690929



AnalysisDate/Time

Analyst Method

Sampled: 2/18/2016 1115

Analyte


DODLOD

Client Sample #:

Inorganic Results


Metals Results




117164 - Page 5 of 46



Project #: 1507-204

QEPI

Project Phase:

CT LAB#: 690929



AnalysisDate/Time

Analyst Method

Sampled: 2/18/2016 1115

Analyte


DODLOD

Client Sample #:




mg/kg0.016 2/24/16 NAHCadmium 2/24/2016 08:00 21:24 ^J0.059 EPA 6010C0.029 1.000.0590.0088














mg/kg64.5 2/24/16 NAHZinc 2/24/2016 08:00 21:24 ^0.44 EPA 6010C0.22 1.000.440.074




CT LAB#: 690930



AnalysisDate/Time

Analyst Method

Sampled: 2/18/2016 1120

Analyte


DODLOD

Client Sample #:

Inorganic Results



117164 - Page 6 of 46



Project #: 1507-204

QEPI

Project Phase:

CT LAB#: 690930



AnalysisDate/Time

Analyst Method

Sampled: 2/18/2016 1120

Analyte


DODLOD

Client Sample #:

Metals Results






mg/kg0.021 2/24/16 NAHCadmium 2/24/2016 08:00 21:31 ^J0.058 EPA 6010C0.029 1.000.0580.0087



















117164 - Page 7 of 46



Project #: 1507-204

QEPI

Project Phase:

CT LAB#: 690931



AnalysisDate/Time

Analyst Method

Sampled: 2/18/2016 1130

Analyte


DODLOD

Client Sample #:

Inorganic Results


Metals Results

























117164 - Page 8 of 46



Project #: 1507-204

QEPI

Project Phase:

CT LAB#: 690932



AnalysisDate/Time

Analyst Method

Sampled: 2/18/2016 1152

Analyte


DODLOD

Client Sample #:

Inorganic Results


Metals Results


















mg/kg0.14 2/24/16 NAHThallium 2/24/2016 08:00 21:44 ^J0.73 EPA 6010C0.37 1.000.730.12







117164 - Page 9 of 46



Project #: 1507-204

QEPI

Project Phase:

CT LAB#: 690933



AnalysisDate/Time

Analyst Method

Sampled: 2/18/2016 1152

Analyte

Sample Description: FF-SS09D-160218

DODLOD

Client Sample #:

Inorganic Results


Metals Results

























117164 - Page 10 of 46



Project #: 1507-204

QEPI

Project Phase:

CT LAB#: 690934



AnalysisDate/Time

Analyst Method

Sampled: 2/18/2016 1200

Analyte


DODLOD

Client Sample #:

Inorganic Results


Metals Results

























117164 - Page 11 of 46



Project #: 1507-204

QEPI

Project Phase:

CT LAB#: 690935



AnalysisDate/Time

Analyst Method

Sampled: 2/18/2016 1205

Analyte


DODLOD

Client Sample #:

Inorganic Results


Metals Results


mg/kg<0.16 2/24/16 NAHAntimony 2/24/2016 08:00 22:21 Û1.0 EPA 6010C0.50 1.001.00.16









mg/kg<0.38 B 2/24/16 NAHIron 2/24/2016 08:00 22:21 Û2.3 EPA 6010C1.1 1.002.30.38





mg/kg<0.075 2/24/16 NAHSelenium 2/24/2016 08:00 22:21 Û0.50 EPA 6010C0.25 1.000.500.075


mg/kg0.23 2/24/16 NAHThallium 2/24/2016 08:00 22:21 ^J0.60 EPA 6010C0.30 1.000.600.10







117164 - Page 12 of 46



Project #: 1507-204

QEPI

Project Phase:

CT LAB#: 690936



AnalysisDate/Time

Analyst Method

Sampled: 2/18/2016 1209

Analyte


DODLOD

Client Sample #:

Inorganic Results


Metals Results


mg/kg1.1 B 2/24/16 NAHAntimony 2/24/2016 08:00 22:28 ^1.0 EPA 6010C0.52 1.001.00.17























117164 - Page 13 of 46



Project #: 1507-204

QEPI

Project Phase:

CT LAB#: 690937



AnalysisDate/Time

Analyst Method

Sampled: 2/18/2016 1245

Analyte


DODLOD

Client Sample #:

Inorganic Results


Metals Results

























117164 - Page 14 of 46



Project #: 1507-204

QEPI

Project Phase:

CT LAB#: 690941



AnalysisDate/Time

Analyst Method

Sampled: 2/18/2016 1245

Analyte

Sample Description: FF-SS15D-160218

DODLOD

Client Sample #:

Inorganic Results


Metals Results

























117164 - Page 15 of 46



Project #: 1507-204

QEPI

Project Phase:

CT LAB#: 690942



AnalysisDate/Time

Analyst Method

Sampled: 2/18/2016 1255

Analyte


DODLOD

Client Sample #:

Inorganic Results


Metals Results

























117164 - Page 16 of 46



Project #: 1507-204

QEPI

Project Phase:

CT LAB#: 690943



AnalysisDate/Time

Analyst Method

Sampled: 2/18/2016 1310

Analyte


DODLOD

Client Sample #:

Inorganic Results


Metals Results

























117164 - Page 17 of 46



Project #: 1507-204

QEPI

Project Phase:

CT LAB#: 690944



AnalysisDate/Time

Analyst Method

Sampled: 2/18/2016 1315

Analyte


DODLOD

Client Sample #:

Inorganic Results


Metals Results

























117164 - Page 18 of 46

Notes: ^ Indicates the laboratory is NELAP accredited for this analyte by the indicated matrix and method. DL (detection limit), LOD (limit of detection), loq (limit of quantitation) as defined by most recent DOD QSM version.

Submitted by:

DescriptionCodeQC Qualifiers

B Analyte detected in the associated Method Blank.C Toxicity present in BOD sample.D Diluted Out.E Safe, No Total Coliform detected.F Unsafe, Total Coliform detected, no E. Coli detected.G Unsafe, Total Coliform detected and E. Coli detected.H Holding time exceeded.I BOD incubator temperature was outside acceptance limits during test period.J Estimated value.L Significant peaks were detected outside the chromatographic window.M Matrix spike and/or Matrix Spike Duplicate recovery outside acceptance limits.N Insufficient BOD oxygen depletion.O Complete BOD oxygen depletion.P Concentration of analyte differs more than 40% between primary and confirmation analysis.Q Laboratory Control Sample outside acceptance limits.R See Narrative at end of report.S Surrogate standard recovery outside acceptance limits due to apparent matrix effects.T Sample received with improper preservation or temperature.U Analyte concentration was below detection limit.V Raised Quantitation or Reporting Limit due to limited sample amount or dilution for matrix background interference.W Sample amount received was below program minimum.X Analyte exceeded calibration range.Y Replicate/Duplicate precision outside acceptance limits.Z Specified calibration criteria was not met.

Current CT Laboratories Certifications

Kansas NELAP ID# E-10368Kentucky ID# 0023ISO/IEC 17025-2005 A2LA Cert # 3806.01North Carolina ID# 674Wisconsin (WDNR) Chemistry ID# 157066030Wisconsin (DATCP) Bacteriology ID# 105-289DoD-ELAP A2LA 3806.01GA EPD Stipulation ID E871111, Expires AnnuallyLouisiana ID # 115843Virginia ID# 7608Illinois NELAP ID # 002413Wisconsin (WOSB) ID# WI-5499-WBEMaryland ID# 344

All samples were received intact and properly preserved unless otherwise noted. The results reported relate only to the samples tested. This report shall not be reproduced, except in full, without written approval of this laboratory. The Chain of Custody is attached.

This report has been specifically prepared to satisfy project or program requirements. These results are in compliance with NELAC requirements for the parameters where accreditation is required or available, unless noted in the case narrative.

117164 - Page 19 of 46

117164 - Page 20 of 46

117164 - Page 21 of 46

117164 - Page 22 of 46

1230 Lange Court • Baraboo , W I 53913 • 608 -356-2760

www.ctlabor atories .com

QC SUMMARY REPORT



Duplicate

2/24/2016Analytical Run #: Analysis Date:14:20Analysis Time:691511JJF

CTLab #:Analyst:

Prep Batch #:


SOILMatrix:

Prep Analyst:

RPD Limit

SpikeAmount Added


Control Limits



123478Method: SW8000C

Solids, Percent % 0 866.0 66.1




117164 - Page 23 of 46



Duplicate


56219

NAHCTLab #:

Analyst:

Prep Batch #:


SOIL

LJF

Matrix:

Prep Analyst:

RPD Limit

SpikeAmount Added


Control Limits



123482Method: SW601002/24/201608:00

Aluminum mg/kg 9.6 6 2010900 11600Antimony mg/kg 32 9 201.1 1.2Arsenic mg/kg 32 0 2011.3 11.3Barium mg/kg 2.0 3 2077.5 79.5Beryllium mg/kg 1.60 5 200.57 0.60Cadmium mg/kg U 1.60 0 200.00882 <0.00882Calcium mg/kg 56 0 203590 3580Chromium mg/kg 5.6 5 2018.0 18.9Cobalt mg/kg 9.6 4 208.4 8.1Copper mg/kg 16.0 4 2020.7 21.5Iron mg/kg 72 2 2023800 24200Lead mg/kg 10.0 7 2055.5 59.6Magnesium mg/kg 32 3 202550 2630Manganese mg/kg 6.0 2 20408 415Nickel mg/kg 4.8 4 2017.7 18.4Selenium mg/kg 16 10 201.0 1.1Silver mg/kg U 4.0 200 200.0250 0.027Thallium mg/kg U 19 0 200.118 <0.118Vanadium mg/kg 3.2 3 2030.0 31.0Zinc mg/kg 12.0 2 2098.1 100




117164 - Page 24 of 46





56219

NAHCTLab #:

Analyst:

Prep Batch #:


SOLID

LJF

Matrix:

Prep Analyst:

RPD Limit

SpikeAmount Added


Control Limits



123482Method: SW601002/24/201608:00

Aluminum mg/kg 94 12094.3 80 ---100Antimony mg/kg 95 12023.8 80 ---25.0Arsenic mg/kg 96 12096.0 80 ---100Barium mg/kg 93 12093.0 80 ---100Beryllium mg/kg 96 1202.4 80 ---2.5Cadmium mg/kg 92 1202.3 80 ---2.5Calcium mg/kg 91 1204530 80 ---5000Chromium mg/kg 91 1209.1 80 ---10.0Cobalt mg/kg 91 12022.8 80 ---25.0Copper mg/kg 90 12011.3 80 ---12.5Iron mg/kg 100 12050.0 80 ---50.0Lead mg/kg 88 12021.9 80 ---25.0Magnesium mg/kg 86 1202160 80 ---2500Manganese mg/kg 85 12021.2 80 ---25.0Nickel mg/kg 89 12022.3 80 ---25.0Selenium mg/kg 90 12090.3 80 ---100Silver mg/kg 88 1202.2 75 ---2.5Thallium mg/kg 84 12083.5 80 ---100Vanadium mg/kg 98 12024.4 80 ---25.0Zinc mg/kg 93 12023.2 80 ---25.0




117164 - Page 25 of 46



Method Blank Soil


56219

NAHCTLab #:

Analyst:

Prep Batch #:


SOLID

LJF

Matrix:

Prep Analyst:

RPD Limit

SpikeAmount Added


Control Limits



123482Method: SW601002/24/201608:00

Aluminum mg/kg 0.122.0 0Antimony mg/kg U 0.400.13 0Arsenic mg/kg 0.400.17 0Barium mg/kg 0.0250.019 0Beryllium mg/kg U 0.0200.004 0Cadmium mg/kg U 0.0200.006 0Calcium mg/kg 0.703.4 0Chromium mg/kg U 0.1250.023 0Cobalt mg/kg U 0.120.04 0Copper mg/kg U 0.200.07 0Iron mg/kg 0.91.4 0Lead mg/kg U 0.1250.04 0Magnesium mg/kg 0.401.0 0Manganese mg/kg 0.0750.061 0Nickel mg/kg U 0.0600.021 0Selenium mg/kg 0.200.091 0Silver mg/kg U 0.0500.017 0Thallium mg/kg U 0.240.08 0Vanadium mg/kg U 0.0400.012 0Zinc mg/kg 0.150.11 0




117164 - Page 26 of 46





56219

NAHCTLab #:

Analyst:

Prep Batch #:


SOIL

LJF

Matrix:

Prep Analyst:

RPD Limit

SpikeAmount Added


Control Limits



123482Method: SW601002/24/201608:00

Aluminum mg/kg 676 120 3 2012600 11600 80 ---148Antimony mg/kg 22 120 1 209.2 1.2 80 ---37.1Arsenic mg/kg 96 120 3 20154 11.3 80 ---148Barium mg/kg 97 120 0 20223 79.5 80 ---148Beryllium mg/kg 97 120 2 204.2 0.60 80 ---3.7Cadmium mg/kg 78 120 6 202.9 BDL 80 ---3.7Calcium mg/kg 88 120 2 2010100 3580 80 ---7420Chromium mg/kg 90 120 11 2032.2 18.9 80 ---14.8Cobalt mg/kg 83 120 0 2039.0 8.1 80 ---37.1Copper mg/kg 94 120 0 2039.0 21.5 80 ---18.6Iron mg/kg 0 120 4 2022900 24200 80 ---74.2Lead mg/kg 90 120 1 2093.1 59.6 80 ---37.1Magnesium mg/kg 86 120 3 205830 2630 80 ---3710Manganese mg/kg 62 120 9 20438 415 80 ---37.1Nickel mg/kg 87 120 0 2050.8 18.4 80 ---37.1Selenium mg/kg 86 120 5 20128 1.1 80 ---148Silver mg/kg 88 125 2 203.3 0.027 75 ---3.7Thallium mg/kg 82 120 6 20121 BDL 80 ---148Vanadium mg/kg 74 120 0 2058.3 31.0 80 ---37.1Zinc mg/kg 94 120 1 20135 100 80 ---37.1




117164 - Page 27 of 46



Matrix Spike Soil


56219

NAHCTLab #:

Analyst:

Prep Batch #:


SOIL

LJF

Matrix:

Prep Analyst:

RPD Limit

SpikeAmount Added


Control Limits



123482Method: SW601002/24/201608:00

Aluminum mg/kg 694 12012600 11600 80 ---144Antimony mg/kg 22 1209.0 1.2 80 ---36.0Arsenic mg/kg 93 120145 11.3 80 ---144Barium mg/kg 95 120216 79.5 80 ---144Beryllium mg/kg 94 1204.0 0.60 80 ---3.6Cadmium mg/kg 75 1202.7 BDL 80 ---3.6Calcium mg/kg 83 1209580 3580 80 ---7200Chromium mg/kg 110 12034.8 18.9 80 ---14.4Cobalt mg/kg 82 12037.8 8.1 80 ---36.0Copper mg/kg 91 12037.8 21.5 80 ---18.0Iron mg/kg 0 12023100 24200 80 ---72.0Lead mg/kg 88 12091.4 59.6 80 ---36.0Magnesium mg/kg 79 1205470 2630 80 ---3600Manganese mg/kg 136 120464 415 80 ---36.0Nickel mg/kg 86 12049.3 18.4 80 ---36.0Selenium mg/kg 81 120118 1.1 80 ---144Silver mg/kg 88 1253.2 0.027 75 ---3.6Thallium mg/kg 77 120111 BDL 80 ---144Vanadium mg/kg 71 12056.5 31.0 80 ---36.0Zinc mg/kg 92 120133 100 80 ---36.0




117164 - Page 28 of 46



Duplicate


56219

MDSCTLab #:

Analyst:

Prep Batch #:


SOIL

LJF

Matrix:

Prep Analyst:

RPD Limit

SpikeAmount Added


Control Limits



123483Method: SW601002/24/201608:00

Potassium mg/kg 2.64 10 201510 1360




117164 - Page 29 of 46



Duplicate


56219

MDSCTLab #:

Analyst:

Prep Batch #:


SOIL

LJF

Matrix:

Prep Analyst:

RPD Limit

SpikeAmount Added


Control Limits



123483Method: SW601002/24/201608:00

Sodium mg/kg 0.96 2 2024.5 24.9




117164 - Page 30 of 46





56219

MDSCTLab #:

Analyst:

Prep Batch #:


SOLID

LJF

Matrix:

Prep Analyst:

RPD Limit

SpikeAmount Added


Control Limits



123483Method: SW601002/24/201608:00

Potassium mg/kg 92 1202300 80 ---2500




117164 - Page 31 of 46





56219

MDSCTLab #:

Analyst:

Prep Batch #:


SOLID

LJF

Matrix:

Prep Analyst:

RPD Limit

SpikeAmount Added


Control Limits



123483Method: SW601002/24/201608:00

Sodium mg/kg 94 1202360 80 ---2500




117164 - Page 32 of 46



Method Blank Soil


56219

MDSCTLab #:

Analyst:

Prep Batch #:


SOLID

LJF

Matrix:

Prep Analyst:

RPD Limit

SpikeAmount Added


Control Limits



123483Method: SW601002/24/201608:00

Potassium mg/kg U 3311 0




117164 - Page 33 of 46



Method Blank Soil


56219

MDSCTLab #:

Analyst:

Prep Batch #:


SOLID

LJF

Matrix:

Prep Analyst:

RPD Limit

SpikeAmount Added


Control Limits



123483Method: SW601002/24/201608:00

Sodium mg/kg U 124 0




117164 - Page 34 of 46





56219

MDSCTLab #:

Analyst:

Prep Batch #:


SOIL

LJF

Matrix:

Prep Analyst:

RPD Limit

SpikeAmount Added


Control Limits



123483Method: SW601002/24/201608:00

Potassium mg/kg 86 120 1 204560 1360 80 ---3710




117164 - Page 35 of 46





56219

MDSCTLab #:

Analyst:

Prep Batch #:


SOIL

LJF

Matrix:

Prep Analyst:

RPD Limit

SpikeAmount Added


Control Limits



123483Method: SW601002/24/201608:00

Sodium mg/kg 98 120 0 203670 24.9 80 ---3710




117164 - Page 36 of 46



Matrix Spike Soil


56219

MDSCTLab #:

Analyst:

Prep Batch #:


SOIL

LJF

Matrix:

Prep Analyst:

RPD Limit

SpikeAmount Added


Control Limits



123483Method: SW601002/24/201608:00

Potassium mg/kg 86 1204460 1360 80 ---3600




117164 - Page 37 of 46



Matrix Spike Soil


56219

MDSCTLab #:

Analyst:

Prep Batch #:


SOIL

LJF

Matrix:

Prep Analyst:

RPD Limit

SpikeAmount Added


Control Limits



123483Method: SW601002/24/201608:00

Sodium mg/kg 98 1203560 24.9 80 ---3600




117164 - Page 38 of 46



Duplicate


56256

LJFCTLab #:

Analyst:

Prep Batch #:


SOIL

LJF

Matrix:

Prep Analyst:

RPD Limit

SpikeAmount Added


Control Limits



123573Method: SW7471B02/29/201610:00

Mercury mg/kg 0.20 4 200.054 0.052




117164 - Page 39 of 46





56256

LJFCTLab #:

Analyst:

Prep Batch #:


SOLID

LJF

Matrix:

Prep Analyst:

RPD Limit

SpikeAmount Added


Control Limits



123573Method: SW7471B02/29/201610:00

Mercury mg/kg 114 1200.095 80 ---0.083




117164 - Page 40 of 46



Method Blank Soil


56256

LJFCTLab #:

Analyst:

Prep Batch #:


SOLID

LJF

Matrix:

Prep Analyst:

RPD Limit

SpikeAmount Added


Control Limits



123573Method: SW7471B02/29/201610:00

Mercury mg/kg U 004150.0021 0




117164 - Page 41 of 46





56256

LJFCTLab #:

Analyst:

Prep Batch #:


SOIL

LJF

Matrix:

Prep Analyst:

RPD Limit

SpikeAmount Added


Control Limits



123573Method: SW7471B02/29/201610:00

Mercury mg/kg 107 120 2 200.18 0.052 80 ---0.12




117164 - Page 42 of 46



Matrix Spike Soil


56256

LJFCTLab #:

Analyst:

Prep Batch #:


SOIL

LJF

Matrix:

Prep Analyst:

RPD Limit

SpikeAmount Added


Control Limits



123573Method: SW7471B02/29/201610:00

Mercury mg/kg 107 1200.18 0.052 80 ---0.12




117164 - Page 43 of 46

117164

Sample Condition Report Folder #: 117164 Print Date / Time: 02/23/2016 11:24 Client: QEPI Received Date / Time / By: 02/23/2016 1035 CHB Project Name: FRANK FOUNDRY Log-In Date / Time / By: 02/23/2016 1124 JLS Project Phase: Project #: 1507-204 PM: BMS Coolers: 5357 Temperature: 7.0 C On Ice: N Custody Seals Present : Y COC Present:? N Complete? N Seal Intact? Y Numbers: DATED AND SIGNED Ship Method: FEDEX EXPRESS Tracking Number: 874833616231 Adequate Packaging: Y Temp Blank Enclosed? Y Notes: THE SAMPLES WERE RECEIVED IN GOOD CONDITION. NO ICE PRESENT, MELT WATER ONLY. NO COC IN COOLER. DJL CONTACTED CLIENT AND A COC WAS EMAILED. CLIENT ADVISED HE WANTED ALL TAL METALS, NOT THE ORIGINAL LIST GIVEN __________________________________________________________________________________________________________ Sample ID / Description Container Type Cond. Code pH OK?/Filtered? Tests _________________________________________________________________________________________________________ 690926 FF-SS01-160218 SOLIDS 1 / %SOL,HG,ICP,K,NA Total # of Containers of Type ( SOLIDS ) = 1 __________________________________________________________________________________________________________ Sample ID / Description Container Type Cond. Code pH OK?/Filtered? Tests _________________________________________________________________________________________________________ 690927 FF-SS02-160218 SOLIDS 1 / %SOL,HG,ICP,K,NA Total # of Containers of Type ( SOLIDS ) = 1 __________________________________________________________________________________________________________ Sample ID / Description Container Type Cond. Code pH OK?/Filtered? Tests _________________________________________________________________________________________________________ 690928 FF-SS03-160218 SOLIDS 1 / %SOL,HG,ICP,K,NA Total # of Containers of Type ( SOLIDS ) = 1 __________________________________________________________________________________________________________ Sample ID / Description Container Type Cond. Code pH OK?/Filtered? Tests _________________________________________________________________________________________________________ 690929 FF-SS04-160218 SOLIDS 1 / %SOL,HG,ICP,K,NA Total # of Containers of Type ( SOLIDS ) = 1 __________________________________________________________________________________________________________ Sample ID / Description Container Type Cond. Code pH OK?/Filtered? Tests _________________________________________________________________________________________________________ 690930 FF-SS05-160218 SOLIDS 1 / %SOL,HG,ICP,K,NA Total # of Containers of Type ( SOLIDS ) = 1

117164 - Page 44 of 46

117164

__________________________________________________________________________________________________________ Sample ID / Description Container Type Cond. Code pH OK?/Filtered? Tests _________________________________________________________________________________________________________ 690931 FF-SS06-160218 SOLIDS 1 / %SOL,HG,ICP,K,NA Total # of Containers of Type ( SOLIDS ) = 1 __________________________________________________________________________________________________________ Sample ID / Description Container Type Cond. Code pH OK?/Filtered? Tests _________________________________________________________________________________________________________ 690932 FF-SS09-160218 SOLIDS 1 / %SOL,HG,ICP,K,NA Total # of Containers of Type ( SOLIDS ) = 1 __________________________________________________________________________________________________________ Sample ID / Description Container Type Cond. Code pH OK?/Filtered? Tests _________________________________________________________________________________________________________ 690933 FF-SS09D-160218 SOLIDS 1 / %SOL,HG,ICP,K,NA Total # of Containers of Type ( SOLIDS ) = 1 __________________________________________________________________________________________________________ Sample ID / Description Container Type Cond. Code pH OK?/Filtered? Tests _________________________________________________________________________________________________________ 690934 FF-SS10-160218 SOLIDS 1 / %SOL,HG,ICP,K,NA Total # of Containers of Type ( SOLIDS ) = 1 __________________________________________________________________________________________________________ Sample ID / Description Container Type Cond. Code pH OK?/Filtered? Tests _________________________________________________________________________________________________________ 690935 FF-SS11-160218 SOLIDS 1 / %SOL,HG,ICP,K,NA Total # of Containers of Type ( SOLIDS ) = 1 __________________________________________________________________________________________________________ Sample ID / Description Container Type Cond. Code pH OK?/Filtered? Tests _________________________________________________________________________________________________________ 690936 FF-SS12-160218 SOLIDS 1 / %SOL,HG,ICP,K,NA Total # of Containers of Type ( SOLIDS ) = 1 __________________________________________________________________________________________________________ Sample ID / Description Container Type Cond. Code pH OK?/Filtered? Tests _________________________________________________________________________________________________________ 690937 FF-SS15-160218 SOLIDS 1 / %SOL,HG,ICP,K,NA Total # of Containers of Type ( SOLIDS ) = 1 __________________________________________________________________________________________________________ Sample ID / Description Container Type Cond. Code pH OK?/Filtered? Tests _________________________________________________________________________________________________________ 690941 FF-SS15D-160218 SOLIDS 1 / %SOL,HG,ICP,K,NA Total # of Containers of Type ( SOLIDS ) = 1 __________________________________________________________________________________________________________ Sample ID / Description Container Type Cond. Code pH OK?/Filtered? Tests

117164 - Page 45 of 46

117164

_________________________________________________________________________________________________________ 690942 FF-SS16-160218 SOLIDS 1 / %SOL,HG,ICP,K,NA Total # of Containers of Type ( SOLIDS ) = 1 __________________________________________________________________________________________________________ Sample ID / Description Container Type Cond. Code pH OK?/Filtered? Tests _________________________________________________________________________________________________________ 690943 FF-SS18-160218 SOLIDS 1 / %SOL,HG,ICP,K,NA Total # of Containers of Type ( SOLIDS ) = 1 __________________________________________________________________________________________________________ Sample ID / Description Container Type Cond. Code pH OK?/Filtered? Tests _________________________________________________________________________________________________________ 690944 FF-SS19-160218 SOLIDS 1 / %SOL,HG,ICP,K,NA Total # of Containers of Type ( SOLIDS ) = 1 __________________________________________________________________________________________________________ Condition Code Condition Description 1 Sample Received OK

117164 - Page 46 of 46

Tetra Tech, Inc.

1 South Wacker Dr. Suite 3700, Chicago, IL 60606

Tel 312.201.7479 | Fax 312.201.0031

www.tetratech.com

May 11, 2016

Ms. Verneta SimonOn-Scene CoordinatorU.S. Environmental Protection Agency Region 577 W. Jackson Blvd.Chicago, Illinois 60604

Subject: Data Validation ReportFrank Foundry - RSEPA Contract No. EP-S5-13-01Technical Direction Document No. S05-0001-1507-204Document Tracking No. 0741

Dear Ms. Simon:

Tetra Tech Inc. (Tetra Tech) submits this Data Validation Report for ten soil samples collected at theFrank Foundry – RS site. The samples were collected on March 30, 2016 and were analyzed for metalsby CT Laboratories LLC, Baraboo, Wisconsin. Tetra Tech received the last of the data on May 6, 2016.

Analytical data were evaluated in general accordance with the EPA National Functional Guidelines(NFG) for Inorganic Superfund Data Review (August 2014).

The data are acceptable and usable as qualified based on exceedances of established quality control (QC)criteria discussed in the data validation report.

If you have any questions regarding this data validation report, please call me at (662) 681-5727.

Sincerely,

Jessica A. VickersSTART Chemist

Enclosurecc: Kevin Scott, Tetra Tech Program Manager

Lucas Stamps, Tetra Tech Project ManagerTDD File

ATTACHMENT 1

DATA VALIDATION REPORTCT LABORATORIES LLC REPORT NO. 117985

DATA VALIDATION CHECKLIST – STAGE 2AEPA REGION 5 START CONTRACT

Page 1 of 4

Site Name Frank Foundry - RSTDD No. 0001-1507-204

Document Tracking No. 0741

Data Reviewer(signature and date) May 6, 2016

Technical Reviewer(signature and date) May 9, 2016

Laboratory Report No. 117985 Laboratory CT Laboratories LLC, Baraboo, Wisconsin

Analyses Metals by EPA SW-846 Methods 6010C and 7471B

Samples 10 Soil samples

Field Duplicate Pairs None

Field Blanks None

INTRODUCTION

This checklist summarizes the Stage 2A validation performed on the subject laboratory report, in accordance with the Environmental ProtectionAgency (EPA) Guidance for Labeling Externally Validated Laboratory Analytical Data for Superfund Use (January 2009). Analytical data wereevaluated in general accordance with the EPA National Functional Guidelines (NFG) for Inorganic Superfund Data Review (August 2014).

OVERALL EVALUATION

No rejection of results were required for this data set. The data are acceptable and usable as qualified based on any exceedances of establishedquality control (QC) criteria discussed in this validation.

Data completeness:

WithinCriteria

Exceedance/Notes

Y

Sample preservation, receipt, and holding times:

WithinCriteria

Exceedance/Notes

Y


Page 2 of 4

Method blanks:

WithinCriteria

Exceedance/Notes

N

Method blank for analytical run No. 124544 contained aluminum, calcium, iron, magnesium, manganese, and selenium above theDL. The selenium results for samples FF- BACK COMP-160330, FF- BACK GRAB-160330, FF- ALLEY 1-160330,FF- BACK COMP-160330, FF- ALLEY 2-160330, FF- GARDEN COMP-160330, and FF- YARD COMP-160330 wereless than ten times the associated blank concentration and qualified as estimated with a possible high bias (J+). No furtherqualifications were required because the associated results were greater than ten times the associated blank concentrations.

Field blanks:

WithinCriteria

Exceedance/Notes

NA

MS/MSD:

WithinCriteria

Exceedance/Notes

N

FF- ALLEY 2-160330: The MS and/or MSD recoveries were below control limits for cadmium, calcium, chromium, cobalt,copper, iron, lead, manganese, mercury, nickel, silver, and thallium; and above control limits for arsenic and magnesium. Foraluminum and zinc, the MSD recovery was above and the MS recovery was below control criteria. The relative percent differenceswere above control limits for antimony, mercury, silver, and zinc. No qualifications were required for aluminum, calcium, iron,magnesium, and manganese because the parent result was greater than four times the associated spike amount. The arsenicresult was qualified as estimated with a possible high bias (J+); the cadmium, chromium, cobalt, copper, lead, mercury, nickel,silver, and thallium results were qualified as estimated with a possible low bias (J-/UJ); and the antimony and zinc results werequalified as estimated (J).

Post digestion spikes:

WithinCriteria

Exceedance/Notes

NA


Page 3 of 4

Serial dilutions:

WithinCriteria

Exceedance/Notes

NA

Laboratory duplicates:

WithinCriteria

Exceedance/Notes

NFF- ALLEY 2-160330: Laboratory duplicate results exceeded control criteria for antimony, barium, cadmium, chromium,copper, lead, manganese, and nickel. The associated results were qualified as estimated (J), unless previously qualified due toMS/MSD exceedances.

Field duplicates:

WithinCriteria

Exceedance/Notes

NA

LCS/LCSD:

WithinCriteria

Exceedance/Notes

Y

Sample dilutions:

WithinCriteria

Exceedance/Notes

N10x: calcium and magnesium for FF- ALLEY 1-160330, FF- BACK GRAB-160330, and FF- ALLEY 2-160330

10x: calcium for FF- YARD COMP-160330


Page 4 of 4

Re-extraction and reanalysis:

WithinCriteria

Exceedance/Notes

Y

MDLs/RLs:

WithinCriteria

Exceedance/Notes

Y Results above the detection limit (DL) and below the reporting limit (RL) were reported as estimated concentrations (J).

Other [specify]:

WithinCriteria

Exceedance/Notes

NA

Overall Qualifications:

See results summary pages attached for changes to the laboratory qualifiers based upon this validation. The following is a list of qualifiers anddefinitions that may be used for the validation of this data package:

J The analyte was positively identified; the associated value is the approximate concentration of the analyte in the sample.

J+The analyte was positively identified; the associated value is the approximate concentration of the analyte in the sample and may bebiased high.

J-The analyte was positively identified; the associated value is the approximate concentration of the analyte in the sample and may bebiased low.

NJThe analysis indicates the presence of an analyte that has been “tentatively identified” and the associated value is the approximateconcentration of the analyte in the sample.

RThe sample result is rejected as unusable due to serious deficiencies in one or more quality control criteria. The analyte may or may notbe present in the sample.

U The analyte was analyzed for, but was not detected at or above the associated value (reporting limit).

UJThe analyte was analyzed for, but was not detected at or above the associated value (reporting limit), which is considered approximatedue to deficiencies in one or more quality control criteria.

FRANK FOUNDRY SOIL ANALYTICAL SUMMARY

CT LABORATORIES REPORT NO. 117985

Sample Number Analyte Result Lab_Qual MDL RL Dilution_Factor Units Val_Result Val_Qual

FF- BACK COMP-160330 Aluminum 8550 0.057 0.34 1 mg/kg 8550

FF- BACK COMP-160330 Antimony 1.6 0.19 1.1 1 mg/kg 1.6

FF- BACK COMP-160330 Arsenic 15.7 0.19 1.1 1 mg/kg 15.7

FF- BACK COMP-160330 Barium 178 0.013 0.072 1 mg/kg 178

FF- BACK COMP-160330 Beryllium 0.35 0.0057 0.057 1 mg/kg 0.35

FF- BACK COMP-160330 Cadmium 1.1 0.0086 0.057 1 mg/kg 1.1

FF- BACK COMP-160330 Calcium 29700 0.34 2.0 1 mg/kg 29700

FF- BACK COMP-160330 Chromium 20.2 0.033 0.20 1 mg/kg 20.2

FF- BACK COMP-160330 Cobalt 7.7 0.057 0.34 1 mg/kg 7.7

FF- BACK COMP-160330 Copper 51.0 0.10 0.57 1 mg/kg 51.0

FF- BACK COMP-160330 Iron 18300 0.43 2.6 1 mg/kg 18300

FF- BACK COMP-160330 Lead 182 0.057 0.36 1 mg/kg 182

FF- BACK COMP-160330 Magnesium 10200 0.20 1.1 1 mg/kg 10200

FF- BACK COMP-160330 Manganese 539 0.036 0.22 1 mg/kg 539

FF- BACK COMP-160330 Mercury 0.19 0.0029 0.012 1 mg/kg 0.19

FF- BACK COMP-160330 Nickel 17.8 0.030 0.17 1 mg/kg 17.8

FF- BACK COMP-160330 Potassium 1520 16 95 1 mg/kg 1520

FF- BACK COMP-160330 Selenium 1.3 B 0.086 0.57 1 mg/kg 1.3 J+

FF- BACK COMP-160330 Silver 0.076 J 0.024 0.14 1 mg/kg 0.076 J

FF- BACK COMP-160330 Sodium 74.0 5.7 34 1 mg/kg 74.0

FF- BACK COMP-160330 Solids, Percent 71.4 1 0.1 1 PERCENT 71.4

FF- BACK COMP-160330 Thallium 0 U 0.11 0.69 1 mg/kg 0.69 U

FF- BACK COMP-160330 Vanadium 20.9 0.017 0.11 1 mg/kg 20.9

FF- BACK COMP-160330 Zinc 325 0.072 0.43 1 mg/kg 325

FF- BACK GRAB-160330 Aluminum 6010 0.054 0.32 1 mg/kg 6010

FF- BACK GRAB-160330 Antimony 1.8 0.18 1.1 1 mg/kg 1.8

FF- BACK GRAB-160330 Arsenic 10.4 0.18 1.1 1 mg/kg 10.4

FF- BACK GRAB-160330 Barium 128 0.012 0.068 1 mg/kg 128

FF- BACK GRAB-160330 Beryllium 0.42 0.0054 0.054 1 mg/kg 0.42

FF- BACK GRAB-160330 Cadmium 0.80 0.0081 0.054 1 mg/kg 0.80

FF- BACK GRAB-160330 Calcium 91600 3.2 19 10 mg/kg 91600

FF- BACK GRAB-160330 Chromium 12.7 0.031 0.19 1 mg/kg 12.7

FF- BACK GRAB-160330 Cobalt 4.4 0.054 0.32 1 mg/kg 4.4

Page 1 of 8




FF- BACK GRAB-160330 Copper 32.7 0.095 0.54 1 mg/kg 32.7

FF- BACK GRAB-160330 Iron 11200 0.41 2.4 1 mg/kg 11200

FF- BACK GRAB-160330 Lead 186 0.054 0.34 1 mg/kg 186

FF- BACK GRAB-160330 Magnesium 53000 1.9 11 10 mg/kg 53000

FF- BACK GRAB-160330 Manganese 331 0.034 0.20 1 mg/kg 331

FF- BACK GRAB-160330 Mercury 0.10 0.0030 0.012 1 mg/kg 0.10

FF- BACK GRAB-160330 Nickel 12.5 0.028 0.16 1 mg/kg 12.5

FF- BACK GRAB-160330 Potassium 1020 15 89 1 mg/kg 1020

FF- BACK GRAB-160330 Selenium 1.2 B 0.081 0.54 1 mg/kg 1.2 J+

FF- BACK GRAB-160330 Silver 0.11 J 0.023 0.14 1 mg/kg 0.11 J

FF- BACK GRAB-160330 Sodium 147 5.4 32 1 mg/kg 147

FF- BACK GRAB-160330 Solids, Percent 75.9 1 0.1 1 PERCENT 75.9

FF- BACK GRAB-160330 Thallium 0 U 0.11 0.65 1 mg/kg 0.65 U

FF- BACK GRAB-160330 Vanadium 15.5 0.016 0.11 1 mg/kg 15.5

FF- BACK GRAB-160330 Zinc 254 0.068 0.41 1 mg/kg 254

FF- FRONT COMP-160330 Aluminum 8500 0.052 0.31 1 mg/kg 8500

FF- FRONT COMP-160330 Antimony 1.5 0.17 1.0 1 mg/kg 1.5

FF- FRONT COMP-160330 Arsenic 16.5 0.17 1.0 1 mg/kg 16.5

FF- FRONT COMP-160330 Barium 141 0.012 0.065 1 mg/kg 141

FF- FRONT COMP-160330 Beryllium 0.42 0.0052 0.052 1 mg/kg 0.42

FF- FRONT COMP-160330 Cadmium 0.35 0.0078 0.052 1 mg/kg 0.35

FF- FRONT COMP-160330 Calcium 14900 0.31 1.8 1 mg/kg 14900

FF- FRONT COMP-160330 Chromium 15.4 0.030 0.18 1 mg/kg 15.4

FF- FRONT COMP-160330 Cobalt 7.6 0.052 0.31 1 mg/kg 7.6

FF- FRONT COMP-160330 Copper 25.6 0.091 0.52 1 mg/kg 25.6

FF- FRONT COMP-160330 Iron 13600 0.39 2.3 1 mg/kg 13600

FF- FRONT COMP-160330 Lead 104 0.052 0.32 1 mg/kg 104

FF- FRONT COMP-160330 Magnesium 9180 0.18 1.0 1 mg/kg 9180

FF- FRONT COMP-160330 Manganese 574 0.032 0.19 1 mg/kg 574

FF- FRONT COMP-160330 Mercury 0.14 0.0028 0.011 1 mg/kg 0.14

FF- FRONT COMP-160330 Nickel 16.2 0.027 0.16 1 mg/kg 16.2

FF- FRONT COMP-160330 Potassium 892 14 86 1 mg/kg 892

FF- FRONT COMP-160330 Selenium 1.4 B 0.078 0.52 1 mg/kg 1.4

Page 2 of 8




FF- FRONT COMP-160330 Silver 0 U 0.022 0.13 1 mg/kg 0.13 U

FF- FRONT COMP-160330 Sodium 42.8 5.2 31 1 mg/kg 42.8

FF- FRONT COMP-160330 Solids, Percent 76.3 1 0.1 1 PERCENT 76.3

FF- FRONT COMP-160330 Thallium 0 U 0.10 0.62 1 mg/kg 0.62 U

FF- FRONT COMP-160330 Vanadium 21.6 0.016 0.10 1 mg/kg 21.6

FF- FRONT COMP-160330 Zinc 194 0.065 0.39 1 mg/kg 194

FF- ALLEY 1-160330 Aluminum 1060 0.045 0.27 1 mg/kg 1060

FF- ALLEY 1-160330 Antimony 0.35 J 0.14 0.89 1 mg/kg 0.35 J

FF- ALLEY 1-160330 Arsenic 11.7 0.14 0.89 1 mg/kg 11.7

FF- ALLEY 1-160330 Barium 14.1 0.010 0.056 1 mg/kg 14.1

FF- ALLEY 1-160330 Beryllium 0.055 0.0045 0.045 1 mg/kg 0.055

FF- ALLEY 1-160330 Cadmium 0.16 0.0067 0.045 1 mg/kg 0.16

FF- ALLEY 1-160330 Calcium 181000 2.7 16 10 mg/kg 181000

FF- ALLEY 1-160330 Chromium 13.3 0.026 0.16 1 mg/kg 13.3

FF- ALLEY 1-160330 Cobalt 0.95 0.045 0.27 1 mg/kg 0.95

FF- ALLEY 1-160330 Copper 13.7 0.078 0.45 1 mg/kg 13.7

FF- ALLEY 1-160330 Iron 2950 0.33 2.0 1 mg/kg 2950

FF- ALLEY 1-160330 Lead 49.1 0.045 0.28 1 mg/kg 49.1

FF- ALLEY 1-160330 Magnesium 111000 1.6 8.9 10 mg/kg 111000

FF- ALLEY 1-160330 Manganese 154 0.028 0.17 1 mg/kg 154

FF- ALLEY 1-160330 Mercury 0 U 0.0024 0.0096 1 mg/kg 0.0096 U

FF- ALLEY 1-160330 Nickel 3.3 0.023 0.13 1 mg/kg 3.3

FF- ALLEY 1-160330 Potassium 412 12 74 1 mg/kg 412

FF- ALLEY 1-160330 Selenium 0.61 B 0.067 0.45 1 mg/kg 0.61 J+

FF- ALLEY 1-160330 Silver 0 U 0.019 0.11 1 mg/kg 0.11 U

FF- ALLEY 1-160330 Sodium 197 4.5 27 1 mg/kg 197

FF- ALLEY 1-160330 Solids, Percent 89.7 1 0.1 1 PERCENT 89.7

FF- ALLEY 1-160330 Thallium 0 U 0.089 0.54 1 mg/kg 0.54 U

FF- ALLEY 1-160330 Vanadium 3.4 0.013 0.089 1 mg/kg 3.4

FF- ALLEY 1-160330 Zinc 37.3 0.056 0.33 1 mg/kg 37.3

FF- BACK COMP-160330 Aluminum 8230 0.055 0.33 1 mg/kg 8230

FF- BACK COMP-160330 Antimony 2.2 0.18 1.1 1 mg/kg 2.2

FF- BACK COMP-160330 Arsenic 13.8 0.18 1.1 1 mg/kg 13.8

Page 3 of 8




FF- BACK COMP-160330 Barium 166 0.012 0.068 1 mg/kg 166

FF- BACK COMP-160330 Beryllium 0.45 0.0055 0.055 1 mg/kg 0.45

FF- BACK COMP-160330 Cadmium 0.57 0.0082 0.055 1 mg/kg 0.57

FF- BACK COMP-160330 Calcium 13000 0.33 1.9 1 mg/kg 13000

FF- BACK COMP-160330 Chromium 17.3 0.031 0.19 1 mg/kg 17.3

FF- BACK COMP-160330 Cobalt 6.7 0.055 0.33 1 mg/kg 6.7

FF- BACK COMP-160330 Copper 34.5 0.096 0.55 1 mg/kg 34.5

FF- BACK COMP-160330 Iron 14800 0.41 2.5 1 mg/kg 14800

FF- BACK COMP-160330 Lead 145 0.055 0.34 1 mg/kg 145

FF- BACK COMP-160330 Magnesium 7610 0.19 1.1 1 mg/kg 7610

FF- BACK COMP-160330 Manganese 546 0.034 0.20 1 mg/kg 546

FF- BACK COMP-160330 Mercury 0.15 0.0029 0.012 1 mg/kg 0.15

FF- BACK COMP-160330 Nickel 17.3 0.029 0.16 1 mg/kg 17.3

FF- BACK COMP-160330 Potassium 1160 15 90 1 mg/kg 1160

FF- BACK COMP-160330 Selenium 1.1 B 0.082 0.55 1 mg/kg 1.1 J+

FF- BACK COMP-160330 Silver 0.064 J 0.023 0.14 1 mg/kg 0.064 J

FF- BACK COMP-160330 Sodium 48.1 5.5 33 1 mg/kg 48.1

FF- BACK COMP-160330 Solids, Percent 75.1 1 0.1 1 PERCENT 75.1

FF- BACK COMP-160330 Thallium 0 U 0.11 0.66 1 mg/kg 0.66 U

FF- BACK COMP-160330 Vanadium 21.3 0.016 0.11 1 mg/kg 21.3

FF- BACK COMP-160330 Zinc 241 0.068 0.41 1 mg/kg 241

FF- FRONT COMP-160330 Aluminum 7720 0.057 0.34 1 mg/kg 7720

FF- FRONT COMP-160330 Antimony 2.0 0.18 1.1 1 mg/kg 2.0

FF- FRONT COMP-160330 Arsenic 13.3 0.18 1.1 1 mg/kg 13.3

FF- FRONT COMP-160330 Barium 123 0.013 0.071 1 mg/kg 123

FF- FRONT COMP-160330 Beryllium 0.34 0.0057 0.057 1 mg/kg 0.34

FF- FRONT COMP-160330 Cadmium 0.41 0.0085 0.057 1 mg/kg 0.41

FF- FRONT COMP-160330 Calcium 11400 0.34 2.0 1 mg/kg 11400

FF- FRONT COMP-160330 Chromium 14.2 0.033 0.20 1 mg/kg 14.2

FF- FRONT COMP-160330 Cobalt 7.6 0.057 0.34 1 mg/kg 7.6

FF- FRONT COMP-160330 Copper 26.3 0.099 0.57 1 mg/kg 26.3

FF- FRONT COMP-160330 Iron 13100 0.42 2.5 1 mg/kg 13100

FF- FRONT COMP-160330 Lead 133 0.057 0.35 1 mg/kg 133

Page 4 of 8




FF- FRONT COMP-160330 Magnesium 6970 0.20 1.1 1 mg/kg 6970

FF- FRONT COMP-160330 Manganese 588 0.035 0.21 1 mg/kg 588

FF- FRONT COMP-160330 Mercury 0.11 0.0031 0.012 1 mg/kg 0.11

FF- FRONT COMP-160330 Nickel 14.6 0.030 0.17 1 mg/kg 14.6

FF- FRONT COMP-160330 Potassium 1070 16 93 1 mg/kg 1070

FF- FRONT COMP-160330 Selenium 2.0 0.085 0.57 1 mg/kg 2.0

FF- FRONT COMP-160330 Silver 0 U 0.024 0.14 1 mg/kg 0.14 U

FF- FRONT COMP-160330 Sodium 49.2 5.7 34 1 mg/kg 49.2

FF- FRONT COMP-160330 Solids, Percent 71.7 1 0.1 1 PERCENT 71.7

FF- FRONT COMP-160330 Thallium 0 U 0.11 0.68 1 mg/kg 0.68 U

FF- FRONT COMP-160330 Vanadium 20.4 0.017 0.11 1 mg/kg 20.4

FF- FRONT COMP-160330 Zinc 242 0.071 0.42 1 mg/kg 242

FF- GARDEN COMP-160330 Aluminum 8580 0.056 0.33 1 mg/kg 8580

FF- GARDEN COMP-160330 Antimony 4.1 0.18 1.1 1 mg/kg 4.1

FF- GARDEN COMP-160330 Arsenic 15.3 0.18 1.1 1 mg/kg 15.3

FF- GARDEN COMP-160330 Barium 196 0.013 0.069 1 mg/kg 196

FF- GARDEN COMP-160330 Beryllium 0.66 0.0056 0.056 1 mg/kg 0.66

FF- GARDEN COMP-160330 Cadmium 0.99 0.0083 0.056 1 mg/kg 0.99

FF- GARDEN COMP-160330 Calcium 17600 0.33 1.9 1 mg/kg 17600

FF- GARDEN COMP-160330 Chromium 18.1 0.032 0.19 1 mg/kg 18.1

FF- GARDEN COMP-160330 Cobalt 6.1 0.056 0.33 1 mg/kg 6.1

FF- GARDEN COMP-160330 Copper 43.1 0.097 0.56 1 mg/kg 43.1

FF- GARDEN COMP-160330 Iron 14400 0.42 2.5 1 mg/kg 14400

FF- GARDEN COMP-160330 Lead 239 0.056 0.35 1 mg/kg 239

FF- GARDEN COMP-160330 Magnesium 9340 0.19 1.1 1 mg/kg 9340

FF- GARDEN COMP-160330 Manganese 441 0.035 0.21 1 mg/kg 441

FF- GARDEN COMP-160330 Mercury 0.22 0.0030 0.012 1 mg/kg 0.22

FF- GARDEN COMP-160330 Nickel 16.8 0.029 0.17 1 mg/kg 16.8

FF- GARDEN COMP-160330 Potassium 1300 15 92 1 mg/kg 1300

FF- GARDEN COMP-160330 Selenium 1.6 B 0.083 0.56 1 mg/kg 1.6

FF- GARDEN COMP-160330 Silver 0.19 0.024 0.14 1 mg/kg 0.19

FF- GARDEN COMP-160330 Sodium 80.2 5.6 33 1 mg/kg 80.2

FF- GARDEN COMP-160330 Solids, Percent 74.6 1 0.1 1 PERCENT 74.6

Page 5 of 8




FF- GARDEN COMP-160330 Thallium 0 U 0.11 0.67 1 mg/kg 0.67 U

FF- GARDEN COMP-160330 Vanadium 21.7 0.017 0.11 1 mg/kg 21.7

FF- GARDEN COMP-160330 Zinc 351 0.069 0.42 1 mg/kg 351

FF- ALLEY 2-160330 Aluminum 1080 M 0.044 0.26 1 mg/kg 1080

FF- ALLEY 2-160330 Antimony 0.80 JY 0.14 0.88 1 mg/kg 0.80 J

FF- ALLEY 2-160330 Arsenic 3.0 0.14 0.88 1 mg/kg 3.0 J+

FF- ALLEY 2-160330 Barium 45.4 Y,M 0.0099 0.055 1 mg/kg 45.4 J

FF- ALLEY 2-160330 Beryllium 0.057 0.0044 0.044 1 mg/kg 0.057

FF- ALLEY 2-160330 Cadmium 0.30 M 0.0066 0.044 1 mg/kg 0.30 J-

FF- ALLEY 2-160330 Calcium 167000 2.6 15 10 mg/kg 167000

FF- ALLEY 2-160330 Chromium 6.5 Y 0.025 0.15 1 mg/kg 6.5 J-

FF- ALLEY 2-160330 Cobalt 0.93 0.044 0.26 1 mg/kg 0.93 J-

FF- ALLEY 2-160330 Copper 13.8 Y 0.077 0.44 1 mg/kg 13.8 J-

FF- ALLEY 2-160330 Iron 3300 M 0.33 2.0 1 mg/kg 3300

FF- ALLEY 2-160330 Lead 71.6 Y 0.044 0.28 1 mg/kg 71.6 J-

FF- ALLEY 2-160330 Magnesium 99600 1.5 8.8 10 mg/kg 99600

FF- ALLEY 2-160330 Manganese 156 Y,M 0.028 0.17 1 mg/kg 156 J

FF- ALLEY 2-160330 Mercury 0 UM 0.0024 0.0096 1 mg/kg 0.0096 UJ

FF- ALLEY 2-160330 Nickel 7.5 Y,M 0.023 0.13 1 mg/kg 7.5 J-

FF- ALLEY 2-160330 Potassium 336 12 73 1 mg/kg 336

FF- ALLEY 2-160330 Selenium 0.47 B 0.066 0.44 1 mg/kg 0.47 J+

FF- ALLEY 2-160330 Silver 0.033 JM,Y 0.019 0.11 1 mg/kg 0.033 J-

FF- ALLEY 2-160330 Sodium 234 4.4 26 1 mg/kg 234

FF- ALLEY 2-160330 Solids, Percent 89.5 1 0.1 1 PERCENT 89.5

FF- ALLEY 2-160330 Thallium 0 UM 0.088 0.53 1 mg/kg 0.53 UJ

FF- ALLEY 2-160330 Vanadium 3.3 0.013 0.088 1 mg/kg 3.3

FF- ALLEY 2-160330 Zinc 74.0 M 0.055 0.33 1 mg/kg 74.0 J

FF- GARDEN COMP-160330 Aluminum 7730 0.050 0.30 1 mg/kg 7730

FF- GARDEN COMP-160330 Antimony 1.2 0.16 1.0 1 mg/kg 1.2

FF- GARDEN COMP-160330 Arsenic 10.7 0.16 1.0 1 mg/kg 10.7

FF- GARDEN COMP-160330 Barium 95.8 0.011 0.063 1 mg/kg 95.8

FF- GARDEN COMP-160330 Beryllium 0.36 0.0050 0.050 1 mg/kg 0.36

FF- GARDEN COMP-160330 Cadmium 0.35 0.0075 0.050 1 mg/kg 0.35

Page 6 of 8




FF- GARDEN COMP-160330 Calcium 21300 0.30 1.8 1 mg/kg 21300

FF- GARDEN COMP-160330 Chromium 12.7 0.029 0.18 1 mg/kg 12.7

FF- GARDEN COMP-160330 Cobalt 6.0 0.050 0.30 1 mg/kg 6.0

FF- GARDEN COMP-160330 Copper 25.3 0.088 0.50 1 mg/kg 25.3

FF- GARDEN COMP-160330 Iron 13100 0.38 2.3 1 mg/kg 13100

FF- GARDEN COMP-160330 Lead 77.6 0.050 0.31 1 mg/kg 77.6

FF- GARDEN COMP-160330 Magnesium 12600 0.18 1.0 1 mg/kg 12600

FF- GARDEN COMP-160330 Manganese 386 0.031 0.19 1 mg/kg 386

FF- GARDEN COMP-160330 Mercury 0.099 0.0028 0.011 1 mg/kg 0.099

FF- GARDEN COMP-160330 Nickel 15.5 0.026 0.15 1 mg/kg 15.5

FF- GARDEN COMP-160330 Potassium 1230 14 83 1 mg/kg 1230

FF- GARDEN COMP-160330 Selenium 1.0 B 0.075 0.50 1 mg/kg 1.0 J+

FF- GARDEN COMP-160330 Silver 0.028 J 0.021 0.13 1 mg/kg 0.028 J

FF- GARDEN COMP-160330 Sodium 52.1 5.0 30 1 mg/kg 52.1

FF- GARDEN COMP-160330 Solids, Percent 79.6 1 0.1 1 PERCENT 79.6

FF- GARDEN COMP-160330 Thallium 0 U 0.10 0.60 1 mg/kg 0.60 U

FF- GARDEN COMP-160330 Vanadium 19.4 0.015 0.10 1 mg/kg 19.4

FF- GARDEN COMP-160330 Zinc 130 0.063 0.38 1 mg/kg 130

FF- YARD COMP-160330 Aluminum 9150 0.051 0.30 1 mg/kg 9150

FF- YARD COMP-160330 Antimony 0.70 J 0.16 1.0 1 mg/kg 0.70 J

FF- YARD COMP-160330 Arsenic 12.4 0.16 1.0 1 mg/kg 12.4

FF- YARD COMP-160330 Barium 104 0.011 0.063 1 mg/kg 104

FF- YARD COMP-160330 Beryllium 0.42 0.0051 0.051 1 mg/kg 0.42

FF- YARD COMP-160330 Cadmium 0.35 0.0076 0.051 1 mg/kg 0.35

FF- YARD COMP-160330 Calcium 69900 3.0 18 10 mg/kg 69900

FF- YARD COMP-160330 Chromium 14.8 0.029 0.18 1 mg/kg 14.8

FF- YARD COMP-160330 Cobalt 7.7 0.051 0.30 1 mg/kg 7.7

FF- YARD COMP-160330 Copper 25.4 0.089 0.51 1 mg/kg 25.4

FF- YARD COMP-160330 Iron 14700 0.38 2.3 1 mg/kg 14700

FF- YARD COMP-160330 Lead 42.7 0.051 0.32 1 mg/kg 42.7

FF- YARD COMP-160330 Magnesium 22400 0.18 1.0 1 mg/kg 22400

FF- YARD COMP-160330 Manganese 314 0.032 0.19 1 mg/kg 314

FF- YARD COMP-160330 Mercury 0.14 0.0027 0.011 1 mg/kg 0.14

Page 7 of 8




FF- YARD COMP-160330 Nickel 21.7 0.027 0.15 1 mg/kg 21.7

FF- YARD COMP-160330 Potassium 1620 14 84 1 mg/kg 1620

FF- YARD COMP-160330 Selenium 1.0 B 0.076 0.51 1 mg/kg 1.0 J+

FF- YARD COMP-160330 Silver 0 U 0.022 0.13 1 mg/kg 0.13 U

FF- YARD COMP-160330 Sodium 83.9 5.1 30 1 mg/kg 83.9

FF- YARD COMP-160330 Solids, Percent 78.6 1 0.1 1 PERCENT 78.6

FF- YARD COMP-160330 Thallium 0 U 0.10 0.61 1 mg/kg 0.61 U

FF- YARD COMP-160330 Vanadium 21.4 0.015 0.10 1 mg/kg 21.4

FF- YARD COMP-160330 Zinc 107 0.063 0.38 1 mg/kg 107

Page 8 of 8

Tetra Tech, Inc.

1 South Wacker Dr. Suite 3700, Chicago, IL 60606

Tel 312.201.7479 | Fax 312.201.0031

www.tetratech.com

March 29, 2016

Ms. Verneta SimonOn-Scene CoordinatorU.S. Environmental Protection Agency Region 577 W. Jackson Blvd.Chicago, Illinois 60604

Subject: Data Validation ReportFrank Foundry RAEPA Contract No. EP-S5-13-01Technical Direction Document No. S05-0001-1507-204Document Tracking No. 0632

Dear Ms. Simon:

Tetra Tech Inc. (Tetra Tech) is submitting this Data Validation Report for 16 soil samples collected at theFrank Foundry site. The samples were collected on February 18, 2016, and were analyzed for TargetAnalyte List metals by CT Laboratories LLC. Tetra Tech received the final data package on March 10,2016.

Analytical data were evaluated in general accordance with the EPA Contract Laboratory Program (CLP)National Functional Guidelines (NFG) for Superfund Inoganic Data Review (August 2014).

The data are acceptable and usable as qualified.

If you have any questions regarding this data validation report, please call me at (509) 688-5957.

Sincerely,

Deb KutsalSTART Chemist

Enclosurecc: Kevin Scott, Tetra Tech Program Manager

Keith Hughes, QEPI Project ManagerTDD File

ATTACHMENT 1

DATA VALIDATION REPORTSDG 117164


Page 1 of 5

Site Name Frank Foundry Removal SiteTDD No. 0001-1507-204

Document Tracking No. 0632

Data Reviewer(signature and date) March 21, 2016

Technical Reviewer(signature and date) 25 March 2016

Laboratory Report No. 117164 Laboratory CT Laboratories LLC

Analyses Metals by EPA SW6010C and EPA SW7471B

Samples 16 Soil samples

Field Duplicate Pairs FF-SS09-160218/FF-SS09D-160218 and FF-SS15-160218/FF-SS15D-160218

Field Blanks None

INTRODUCTION

This checklist summarizes the Stage 2A validation performed on the subject laboratory report, in accordance with the U.S. EnvironmentalProtection Agency (EPA) Guidance for Labeling Externally Validated Laboratory Analytical Data for Superfund Use (January 2009). Analytical datawere evaluated in general accordance with the EPA Contract Laboratory Program (CLP) National Functional Guidelines (NFG) for InorganicSuperfund Data Review (August 2014).

OVERALL EVALUATION

The data are acceptable and usable as qualified.

Data completeness:

WithinCriteria

Exceedance/Notes

Y

Sample preservation, receipt, and holding times:

WithinCriteria

Exceedance/Notes

NSamples were received at the laboratory on melted ice and at a temperature of 7 degrees Celsius (°C), above the recommended 6

°C, 5 days following collection. All results were qualified as estimated and possibly biased low (J-/UJ).


Page 2 of 5

Method blanks:

WithinCriteria

Exceedance/Notes

NMethod blank contained aluminum, arsenic, barium, calcium, iron, magnesium, manganese, selenium, and zinc below RLs. Most of

the associated sample results were greater than 10 times the concentrations in the blank, so were not qualified. The seleniumresult for sample FF-SS12-160218 was raised to the RL and qualified as not detected (U).

Field blanks:

WithinCriteria

Exceedance/Notes

NA No field blanks are included in the SDG.

MS/MSD:

WithinCriteria

Exceedance/Notes

N

The MS %Rs were below lower control limits for antimony, cadmium, iron, manganese, thallium, and vanadium, and above theupper control limit for aluminum and manganese.

No qualifications were required for antimony, cadmium, magnesium, thallium, and vanadium because the parent sample resultswere already qualified as estimated and possibly biased low (J-) because of the cooler receipt temperature issue previouslydiscussed.

No qualifications were required for aluminum, iron, or manganese because the amount in the parent sample was greater than fourtimes the amount spiked.


Page 3 of 5

Post digestion spikes:

WithinCriteria

Exceedance/Notes

NPost digestion spike (PDS) results were below the lower control limit for cadmium, magnesium, thallium, and vanadium.

Associated parent sample results were previously qualified as estimated with a possible low bias (J-) because of a coolertemperature issue discussed above, so no additional action was needed.

Serial dilutions:

WithinCriteria

Exceedance/Notes

NSerial dilution % differences exceeded the control limit for aluminum, barium, calcium, chromium, iron, magnesium, manganese,

nickel, vanadium, and zinc. The associated qualifications were overridden due to the cooler receipt temperature issuepreviously discussed.

Laboratory duplicates:

WithinCriteria

Exceedance/Notes

NLaboratory duplicate result exceeded control criteria for silver. The associated qualification was overridden due to the cooler

receipt temperature issue previously discussed.

Field duplicates:

WithinCriteria

Exceedance/Notes

YField duplicate pair FF-SS09-160218/FF-SS09D-160218 and FF-SS15-160218/FF-SS15D-160218 results were within the QC guidelinesof 25 relative percent difference (RPD) for results more than five times the RL and a difference below the RL for lowerconcentrations, using the RL for non-detect results.

LCS/LCSD:

WithinCriteria

Exceedance/Notes

Y


Page 4 of 5

Sample dilutions:

WithinCriteria

Exceedance/Notes

Y Sample FF-SS12-160218 underwent a 10x dilution for calcium, to bring it into calibration range.

Re-extraction and reanalysis:

WithinCriteria

Exceedance/Notes

NA

MDLs/RLs:

WithinCriteria

Exceedance/Notes

Y Results above the DL and below the RL were reported by the laboratory as estimated concentrations (J).

Other [specify]:

WithinCriteria

Exceedance/Notes

NA


Page 5 of 5

Overall Qualifications:

See results summary pages attached for changes to the laboratory qualifiers based upon this validation. The following is a list of qualifiers anddefinitions that may be used for the validation of this data package:

J The analyte was positively identified; the associated value is the approximate concentration of the analyte in the sample.

J+The analyte was positively identified; the associated value is the approximate concentration of the analyte in the sample and may bebiased high.

J-The analyte was positively identified; the associated value is the approximate concentration of the analyte in the sample and may bebiased low.

NJThe analysis indicates the presence of an analyte that has been “tentatively identified” and the associated value is the approximateconcentration of the analyte in the sample.

RThe sample result is rejected as unusable due to serious deficiencies in one or more quality control criteria. The analyte may or may notbe present in the sample.

U The analyte was analyzed for, but was not detected at or above the associated value (reporting limit).

UJThe analyte was analyzed for, but was not detected at or above the associated value (reporting limit), which is considered approximatedue to deficiencies in one or more quality control criteria.

Frank Foundry Soil Sample Results

CT Laboratories, 117164

Analyte Lab Qual Lab Sample ID Matrix Reporting Limit Lab Result Units Sample ID Val. Result Val. Qual

Solids, Percent 690926 Soil 0.1 69.1 PERCENT FF-SS01-160218 69.1

Aluminum M 690926 Soil 0.34 11600 mg/kg FF-SS01-160218 11600 J-

Antimony 690926 Soil 1.1 1.2 mg/kg FF-SS01-160218 1.2 J-

Arsenic 690926 Soil 1.1 11.3 mg/kg FF-SS01-160218 11.3 J-

Barium 690926 Soil 0.071 79.5 mg/kg FF-SS01-160218 79.5 J-

Beryllium 690926 Soil 0.057 0.60 mg/kg FF-SS01-160218 0.60 J-

Cadmium UM 690926 Soil 0.057 0 mg/kg FF-SS01-160218 0.057 UJ

Calcium B,M 690926 Soil 2.0 3580 mg/kg FF-SS01-160218 3580 J-

Chromium M 690926 Soil 0.20 18.9 mg/kg FF-SS01-160218 18.9 J-

Cobalt M 690926 Soil 0.34 8.1 mg/kg FF-SS01-160218 8.1 J-

Copper M 690926 Soil 0.57 21.5 mg/kg FF-SS01-160218 21.5 J-

Iron B,M 690926 Soil 2.6 24200 mg/kg FF-SS01-160218 24200 J-

Lead M 690926 Soil 0.35 59.6 mg/kg FF-SS01-160218 59.6 J-

Magnesium B,M 690926 Soil 1.1 2630 mg/kg FF-SS01-160218 2630 J-

Manganese M 690926 Soil 0.21 415 mg/kg FF-SS01-160218 415 J-

Mercury 690926 Soil 0.013 0.052 mg/kg FF-SS01-160218 0.052 J-

Nickel M 690926 Soil 0.17 18.4 mg/kg FF-SS01-160218 18.4 J-

Potassium 690926 Soil 94 1360 mg/kg FF-SS01-160218 1360 J-

Selenium B,M 690926 Soil 0.57 1.1 mg/kg FF-SS01-160218 1.1 J-

Silver JM 690926 Soil 0.14 0.027 mg/kg FF-SS01-160218 0.027 J-

Sodium J 690926 Soil 34 24.9 mg/kg FF-SS01-160218 24.9 J-

Thallium UM 690926 Soil 0.68 0 mg/kg FF-SS01-160218 0.68 UJ

Vanadium M 690926 Soil 0.11 31.0 mg/kg FF-SS01-160218 31.0 J-

Zinc M 690926 Soil 0.43 100 mg/kg FF-SS01-160218 100 J-


Aluminum B 690927 Soil 0.37 8960 mg/kg FF-SS02-160218 8960 J-

Antimony J 690927 Soil 1.2 1.1 mg/kg FF-SS02-160218 1.1 J-




Cadmium U 690927 Soil 0.061 0 mg/kg FF-SS02-160218 0.061 UJ

Calcium B 690927 Soil 2.2 3320 mg/kg FF-SS02-160218 3320 J-

Chromium 690927 Soil 0.22 14.6 mg/kg FF-SS02-160218 14.6 J-

Cobalt 690927 Soil 0.37 8.1 mg/kg FF-SS02-160218 8.1 J-

Copper 690927 Soil 0.61 19.2 mg/kg FF-SS02-160218 19.2 J-

Iron B 690927 Soil 2.8 18400 mg/kg FF-SS02-160218 18400 J-

Lead 690927 Soil 0.38 63.0 mg/kg FF-SS02-160218 63.0 J-

Magnesium B 690927 Soil 1.2 2000 mg/kg FF-SS02-160218 2000 J-

Manganese 690927 Soil 0.23 642 mg/kg FF-SS02-160218 642 J-


Nickel 690927 Soil 0.18 13.7 mg/kg FF-SS02-160218 13.7 J-


Selenium 690927 Soil 0.61 2.8 mg/kg FF-SS02-160218 2.8 J-

Silver 690927 Soil 0.15 0.15 mg/kg FF-SS02-160218 0.15 J-


Thallium 690927 Soil 0.74 1.5 mg/kg FF-SS02-160218 1.5 J-

Vanadium 690927 Soil 0.12 25.8 mg/kg FF-SS02-160218 25.8 J-

Zinc 690927 Soil 0.46 108 mg/kg FF-SS02-160218 108 J-













Page 1 of 7











Silver J 690928 Soil 0.14 0.13 mg/kg FF-SS03-160218 0.13 J-


Thallium U 690928 Soil 0.69 0 mg/kg FF-SS03-160218 0.69 UJ









Cadmium J 690929 Soil 0.059 0.016 mg/kg FF-SS04-160218 0.016 J-












Selenium B 690929 Soil 0.59 0.96 mg/kg FF-SS04-160218 0.96 J-

Silver U 690929 Soil 0.15 0 mg/kg FF-SS04-160218 0.15 UJ

Sodium 690929 Soil 35 47.5 mg/kg FF-SS04-160218 47.5 J-



Zinc 690929 Soil 0.44 64.5 mg/kg FF-SS04-160218 64.5 J-







Cadmium J 690930 Soil 0.058 0.021 mg/kg FF-SS05-160218 0.021 J-


















Page 2 of 7
































Barium 690932 Soil 0.076 102 mg/kg FF-SS09-160218 102 J-








Lead 690932 Soil 0.38 108 mg/kg FF-SS09-160218 108 J-









Thallium J 690932 Soil 0.73 0.14 mg/kg FF-SS09-160218 0.14 J-



Solids, Percent 690933 Soil 0.1 71.9 PERCENT FF-SS09D-160218 71.9

Aluminum B 690933 Soil 0.33 8510 mg/kg FF-SS09D-160218 8510 J-

Antimony 690933 Soil 1.1 1.4 mg/kg FF-SS09D-160218 1.4 J-

Arsenic 690933 Soil 1.1 11.5 mg/kg FF-SS09D-160218 11.5 J-

Barium 690933 Soil 0.069 98.9 mg/kg FF-SS09D-160218 98.9 J-

Beryllium 690933 Soil 0.055 0.67 mg/kg FF-SS09D-160218 0.67 J-

Cadmium U 690933 Soil 0.055 0 mg/kg FF-SS09D-160218 0.055 UJ

Calcium B 690933 Soil 1.9 3490 mg/kg FF-SS09D-160218 3490 J-

Chromium 690933 Soil 0.19 13.9 mg/kg FF-SS09D-160218 13.9 J-

Cobalt 690933 Soil 0.33 9.0 mg/kg FF-SS09D-160218 9.0 J-

Copper 690933 Soil 0.55 22.8 mg/kg FF-SS09D-160218 22.8 J-

Iron B 690933 Soil 2.5 19100 mg/kg FF-SS09D-160218 19100 J-

Page 3 of 7




Lead 690933 Soil 0.35 108 mg/kg FF-SS09D-160218 108 J-

Magnesium B 690933 Soil 1.1 2010 mg/kg FF-SS09D-160218 2010 J-

Manganese 690933 Soil 0.21 806 mg/kg FF-SS09D-160218 806 J-

Mercury 690933 Soil 0.012 0.12 mg/kg FF-SS09D-160218 0.12 J-

Nickel 690933 Soil 0.17 15.0 mg/kg FF-SS09D-160218 15.0 J-

Potassium 690933 Soil 91 1460 mg/kg FF-SS09D-160218 1460 J-

Selenium 690933 Soil 0.55 1.3 mg/kg FF-SS09D-160218 1.3 J-

Silver 690933 Soil 0.14 0.15 mg/kg FF-SS09D-160218 0.15 J-

Sodium J 690933 Soil 33 27.5 mg/kg FF-SS09D-160218 27.5 J-

Thallium U 690933 Soil 0.66 0 mg/kg FF-SS09D-160218 0.66 UJ

Vanadium 690933 Soil 0.11 23.3 mg/kg FF-SS09D-160218 23.3 J-

Zinc 690933 Soil 0.42 191 mg/kg FF-SS09D-160218 191 J-



























Antimony U 690935 Soil 1.0 0 mg/kg FF-SS11-160218 1.0 UJ




Cadmium 690935 Soil 0.050 0.61 mg/kg FF-SS11-160218 0.61 J-





Iron UB 690935 Soil 2.3 0 mg/kg FF-SS11-160218 2.3 UJ







Selenium U 690935 Soil 0.50 0 mg/kg FF-SS11-160218 0.50 UJ


Sodium 690935 Soil 30 262 mg/kg FF-SS11-160218 262 J-

Thallium J 690935 Soil 0.60 0.23 mg/kg FF-SS11-160218 0.23 J-



Page 4 of 7






Antimony B 690936 Soil 1.0 1.1 mg/kg FF-SS12-160218 1.1 J-





Calcium 690936 Soil 18 42900 mg/kg FF-SS12-160218 42900 J-











Selenium 690936 Soil 0.52 0.74 mg/kg FF-SS12-160218 0.74 UJ






























Solids, Percent 690941 Soil 0.1 78.5 PERCENT FF-SS15D-160218 78.5

Aluminum B 690941 Soil 0.30 8880 mg/kg FF-SS15D-160218 8880 J-

Antimony 690941 Soil 1.0 1.1 mg/kg FF-SS15D-160218 1.1 J-

Arsenic 690941 Soil 1.0 11.2 mg/kg FF-SS15D-160218 11.2 J-

Barium 690941 Soil 0.063 94.4 mg/kg FF-SS15D-160218 94.4 J-

Beryllium 690941 Soil 0.050 0.62 mg/kg FF-SS15D-160218 0.62 J-

Cadmium U 690941 Soil 0.050 0 mg/kg FF-SS15D-160218 0.050 UJ

Calcium B 690941 Soil 1.8 3920 mg/kg FF-SS15D-160218 3920 J-

Chromium 690941 Soil 0.18 14.8 mg/kg FF-SS15D-160218 14.8 J-

Cobalt 690941 Soil 0.30 7.7 mg/kg FF-SS15D-160218 7.7 J-

Copper 690941 Soil 0.50 23.6 mg/kg FF-SS15D-160218 23.6 J-

Iron B 690941 Soil 2.3 21400 mg/kg FF-SS15D-160218 21400 J-

Page 5 of 7




Lead 690941 Soil 0.31 102 mg/kg FF-SS15D-160218 102 J-

Magnesium B 690941 Soil 1.0 2440 mg/kg FF-SS15D-160218 2440 J-

Manganese 690941 Soil 0.19 624 mg/kg FF-SS15D-160218 624 J-

Mercury 690941 Soil 0.012 0.10 mg/kg FF-SS15D-160218 0.10 J-

Nickel 690941 Soil 0.15 16.6 mg/kg FF-SS15D-160218 16.6 J-

Potassium 690941 Soil 83 1290 mg/kg FF-SS15D-160218 1290 J-

Selenium 690941 Soil 0.50 1.2 mg/kg FF-SS15D-160218 1.2 J-

Silver 690941 Soil 0.13 0.13 mg/kg FF-SS15D-160218 0.13 J-

Sodium J 690941 Soil 30 24.2 mg/kg FF-SS15D-160218 24.2 J-

Thallium U 690941 Soil 0.60 0 mg/kg FF-SS15D-160218 0.60 UJ

Vanadium 690941 Soil 0.10 23.9 mg/kg FF-SS15D-160218 23.9 J-

Zinc 690941 Soil 0.38 160 mg/kg FF-SS15D-160218 160 J-

















































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