teoria do campo cristalino 1_2019.pdf · ex.:cd 1s 22s 2 62p6 103s 3p 4s2 3d 4p6 4d10 ex.:cd2+ 1s...
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![Page 1: Teoria do Campo Cristalino 1_2019.pdf · Ex.:Cd 1s 22s 2 62p6 103s 3p 4s2 3d 4p6 4d10 Ex.:Cd2+ 1s 22s 2p6 2 3s 103p6 4s2 3d 4p6 5s2 4d10 Por exemplo, considere o cádmio, que no estado](https://reader033.vdocuments.us/reader033/viewer/2022041907/5e640ee16b3d651ae0280815/html5/thumbnails/1.jpg)
Teoria do Campo
Cristalino Aula 1
![Page 2: Teoria do Campo Cristalino 1_2019.pdf · Ex.:Cd 1s 22s 2 62p6 103s 3p 4s2 3d 4p6 4d10 Ex.:Cd2+ 1s 22s 2p6 2 3s 103p6 4s2 3d 4p6 5s2 4d10 Por exemplo, considere o cádmio, que no estado](https://reader033.vdocuments.us/reader033/viewer/2022041907/5e640ee16b3d651ae0280815/html5/thumbnails/2.jpg)
![Page 3: Teoria do Campo Cristalino 1_2019.pdf · Ex.:Cd 1s 22s 2 62p6 103s 3p 4s2 3d 4p6 4d10 Ex.:Cd2+ 1s 22s 2p6 2 3s 103p6 4s2 3d 4p6 5s2 4d10 Por exemplo, considere o cádmio, que no estado](https://reader033.vdocuments.us/reader033/viewer/2022041907/5e640ee16b3d651ae0280815/html5/thumbnails/3.jpg)
![Page 4: Teoria do Campo Cristalino 1_2019.pdf · Ex.:Cd 1s 22s 2 62p6 103s 3p 4s2 3d 4p6 4d10 Ex.:Cd2+ 1s 22s 2p6 2 3s 103p6 4s2 3d 4p6 5s2 4d10 Por exemplo, considere o cádmio, que no estado](https://reader033.vdocuments.us/reader033/viewer/2022041907/5e640ee16b3d651ae0280815/html5/thumbnails/4.jpg)
Ex.:Cd
1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 4d10
Ex.:Cd2+
1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s2 4d10
Por exemplo, considere o cádmio, que no estado fundamental possui 48 elétrons
![Page 5: Teoria do Campo Cristalino 1_2019.pdf · Ex.:Cd 1s 22s 2 62p6 103s 3p 4s2 3d 4p6 4d10 Ex.:Cd2+ 1s 22s 2p6 2 3s 103p6 4s2 3d 4p6 5s2 4d10 Por exemplo, considere o cádmio, que no estado](https://reader033.vdocuments.us/reader033/viewer/2022041907/5e640ee16b3d651ae0280815/html5/thumbnails/5.jpg)
![Page 6: Teoria do Campo Cristalino 1_2019.pdf · Ex.:Cd 1s 22s 2 62p6 103s 3p 4s2 3d 4p6 4d10 Ex.:Cd2+ 1s 22s 2p6 2 3s 103p6 4s2 3d 4p6 5s2 4d10 Por exemplo, considere o cádmio, que no estado](https://reader033.vdocuments.us/reader033/viewer/2022041907/5e640ee16b3d651ae0280815/html5/thumbnails/6.jpg)
Forma dos orbitais d:
![Page 7: Teoria do Campo Cristalino 1_2019.pdf · Ex.:Cd 1s 22s 2 62p6 103s 3p 4s2 3d 4p6 4d10 Ex.:Cd2+ 1s 22s 2p6 2 3s 103p6 4s2 3d 4p6 5s2 4d10 Por exemplo, considere o cádmio, que no estado](https://reader033.vdocuments.us/reader033/viewer/2022041907/5e640ee16b3d651ae0280815/html5/thumbnails/7.jpg)
dz2 é o somatório da combinação linear entre:
![Page 8: Teoria do Campo Cristalino 1_2019.pdf · Ex.:Cd 1s 22s 2 62p6 103s 3p 4s2 3d 4p6 4d10 Ex.:Cd2+ 1s 22s 2p6 2 3s 103p6 4s2 3d 4p6 5s2 4d10 Por exemplo, considere o cádmio, que no estado](https://reader033.vdocuments.us/reader033/viewer/2022041907/5e640ee16b3d651ae0280815/html5/thumbnails/8.jpg)
Campo Cristalino octaédrico
![Page 9: Teoria do Campo Cristalino 1_2019.pdf · Ex.:Cd 1s 22s 2 62p6 103s 3p 4s2 3d 4p6 4d10 Ex.:Cd2+ 1s 22s 2p6 2 3s 103p6 4s2 3d 4p6 5s2 4d10 Por exemplo, considere o cádmio, que no estado](https://reader033.vdocuments.us/reader033/viewer/2022041907/5e640ee16b3d651ae0280815/html5/thumbnails/9.jpg)
![Page 10: Teoria do Campo Cristalino 1_2019.pdf · Ex.:Cd 1s 22s 2 62p6 103s 3p 4s2 3d 4p6 4d10 Ex.:Cd2+ 1s 22s 2p6 2 3s 103p6 4s2 3d 4p6 5s2 4d10 Por exemplo, considere o cádmio, que no estado](https://reader033.vdocuments.us/reader033/viewer/2022041907/5e640ee16b3d651ae0280815/html5/thumbnails/10.jpg)
![Page 11: Teoria do Campo Cristalino 1_2019.pdf · Ex.:Cd 1s 22s 2 62p6 103s 3p 4s2 3d 4p6 4d10 Ex.:Cd2+ 1s 22s 2p6 2 3s 103p6 4s2 3d 4p6 5s2 4d10 Por exemplo, considere o cádmio, que no estado](https://reader033.vdocuments.us/reader033/viewer/2022041907/5e640ee16b3d651ae0280815/html5/thumbnails/11.jpg)
![Page 12: Teoria do Campo Cristalino 1_2019.pdf · Ex.:Cd 1s 22s 2 62p6 103s 3p 4s2 3d 4p6 4d10 Ex.:Cd2+ 1s 22s 2p6 2 3s 103p6 4s2 3d 4p6 5s2 4d10 Por exemplo, considere o cádmio, que no estado](https://reader033.vdocuments.us/reader033/viewer/2022041907/5e640ee16b3d651ae0280815/html5/thumbnails/12.jpg)
![Page 13: Teoria do Campo Cristalino 1_2019.pdf · Ex.:Cd 1s 22s 2 62p6 103s 3p 4s2 3d 4p6 4d10 Ex.:Cd2+ 1s 22s 2p6 2 3s 103p6 4s2 3d 4p6 5s2 4d10 Por exemplo, considere o cádmio, que no estado](https://reader033.vdocuments.us/reader033/viewer/2022041907/5e640ee16b3d651ae0280815/html5/thumbnails/13.jpg)
![Page 14: Teoria do Campo Cristalino 1_2019.pdf · Ex.:Cd 1s 22s 2 62p6 103s 3p 4s2 3d 4p6 4d10 Ex.:Cd2+ 1s 22s 2p6 2 3s 103p6 4s2 3d 4p6 5s2 4d10 Por exemplo, considere o cádmio, que no estado](https://reader033.vdocuments.us/reader033/viewer/2022041907/5e640ee16b3d651ae0280815/html5/thumbnails/14.jpg)