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SRI S. RAMASAMY NAIDU MEMORIAL COLLEGE

(An Autonomous Institution Re-accredited with ‘A’ Grade by NAAC)

SATTUR- 626203

M.Sc. CHEMISTRY

SYLLABUS AND REGULATIONS

UNDER

CHOICE BASED CREDIT SYSTEM (CBCS)

(Effective from the academic year 2014 – 2015)

SRNMC Syllabus

Objectives

To enable the students

1. To gain knowledge on the basic and advanced level aspects in the different

disciplines of chemistry.

2. To get an exposure to the basics in Nano chemistry and biochemistry.

3. To gain knowledge on the basic and advanced level experimental techniques.

4. To get an exposure on some current trends in chemistry.

5. To assist the students in finding employment opportunities in the field of

Chemical Industries.

Eligibility for Admission

B.Sc. degree with chemistry as the core subject and physics as one of the allied

subjects; the other allied subject may be any one of the following: Mathematics, Botany, and

Zoology.

Duration of the Course

The duration of the course shall be two academic years comprising four semesters

with two semesters in each academic year.

Courses of Study

1. Core subjects

2. Major elective subjects

Credits

The term ‘credit’ refers to the weightage given to the course, usually in relation to the

instructional hours assigned to it. The total credits. required for completing Master of Science

in Chemistry is 90. The particulars of the credits for individual components and courses are

placed on Table-1.

Scheme of Examination

It is presented on Table-2

SRNMC Syllabus

Pattern of the Question Paper

Theory

Part A

Ten questions (Multiple choice) 10 x 1 = 10 marks

Two questions from each Unit

Part B

Five questions (either or type) 5 x 7 = 35 marks

One question from each Unit

Part C

Three questions (out of five) 3 x 10 = 30 marks

One question from each unit

---------------

Total 75 Marks

---------------

Evaluation:

The performance of the student is evaluated in terms of percentage of marks with a

provision for conversion to grade points. Evaluation for each course shall be done by a

continuous internal assessment by the concerned course teacher as well as by an end semester

examination which will be written type examination of 3 hours duration and will be

consolidated at the end of the course. The ratio of marks to be allotted to continuous internal

assessment and to end semester examination is 25:75 (i.e. Internal 25 Marks and external 75

Marks)

The components of continuous internal assessment are:

Two tests and their average 15 Marks

Seminar/Group Discussion 5 Marks

Assignment 5 Marks

Total 25 Marks

SRNMC Syllabus

Passing Minimum

A) Theory

1. 50% of the aggregate (External+ Internal)

2. No separate pass minimum for Internal

3. 34 Marks out of 75 is the pass minimum for the External.

B) Practical

1. 50% of the aggregate (External+ Internal)

2. No separate pass minimum for Internal

3. 27 Marks out of 60 is the pass minimum for the External.

C) Project

1. 50% of the aggregate (Project Evaluation + Viva Voce+ Internal)

2. No separate pass minimum for internal.

3. 27 marks out of 60 is the pass minimum for the External.

SRNMC Syllabus

M.Sc (CHEMISTRY)

Table -1: Course pattern

(With effect from the academic year 2014 – 2015)

S.No

Semester

I

II

III

IV

V

Total

Hours

Total

Credits

No of

Courses

1

I

Core

6(5)

Core

6(5)

Core

6(4)

Elective

6(4)

Practical

6(4)

30

22

5

2

II

Core

6(5)

Core

6(5)

Core

6(4)

Elective

6(4)

Practical

6(4)

30

22

5

3

III

Core

6(5)

Core

6(5)

Core

6(5)

Elective

6(4)

Practical

6(4)

30

23

5

4

IV

Core

6(5)

Core

6(5)

Core

6(5)

Elective

6(4)

Project

6(4)

30

23

5

TOTAL

120

90

20

SRNMC Syllabus

M.Sc (CHEMISTRY)

Table -2: Course details and scheme of examinations

(With effect from the academic year 2014 – 2015)

Sem Title of the Paper Hrs

per

week

Credit

Exam

hrs.

Marks Total

Int Ext

I

Organic Chemistry I - Organic

Reaction Mechanism And

Stereochemistry

6 5 3 25 75 100

Inorganic Chemistry I –

Periodic properties and solid

state chemistry 6 5 3 25 75 100

Physical Chemistry I –

Thermodynamics and

Electrochemistry

6 4 3 25 75 100

Major elective: (Any one)

1)Medicinal Chemistry

2) Biochemistry

6

4

3

25

75

100

Practical – I Inorganic

Chemistry

6

4

6

40

60

100

II

Organic Chemistry II –

Organic Reaction Mechanism

And Reagents

6 5 3 25 75 100

Inorganic Chemistry II -

Coordination and Bioinorganic

Chemistry.

6 5 3 25 75 100

Physical Chemistry II -

Quantum Catalysis and Nano

Chemistry.

6 4 3 25 75 100

Major Elective: (Any one)

1)Analytical Chemistry

2)Industrial Chemistry

6 4 3 25 75 100

Practical – II

Organic Chemistry 6 4 6 40 60 100

SRNMC Syllabus

III

Organic Chemistry III -

Organic Spectroscopy and

Natural products

6 5 3 25 75 100

Inorganic Chemistry III -

Inorganic Spectroscopy and

Nano Chemistry

6 5 3 25 75 100

Physical Chemistry III -

Group Theory and Molecular

Spectroscopy

6 5 3 25 75 100

Major elective: (Any one)

1) Computer Applications

2) Environmental chemistry

6 4 3 25 75 100

Practical III

Physical chemistry 6 4 6 40 60 100

IV

Organic Chemistry IV -

Biomolecules, Rearrangements

and Synthetic Methods.

6 5 3 25 75 100

Inorganic Chemistry IV -

Nuclear and Organometallic

Chemistry.

6 5 3 25 75 100

Physical Chemistry IV -

Chemical Kinetics , Surface and

Photo Chemistry

6 5 3 25 75 100

Major Elective: (Any one)

1) Introduction to Nano Science

2) Polymer Chemistry

6 4 3 25 75 100

1) Project

2) Review of recent aspects of

Chemistry

Viva Voce

6 4 6 40 40

20 100

SRNMC Syllabus

SRI S.RAMASAMY NAIDU MEMORIAL COLLEGE


SATTUR-626 203.

Department of Chemistry

(For those who joining in 2014-2015 and after)

SYLLABUS

Programme : M.Sc., Chemistry Subject Code :

Semester : I No. of Hours allotted : 6 / week

Subject : Paper I No. of Credits : 5

Title of the Paper : ORGANIC CHEMISTRY - I

ORGANIC REACTION MECHANISM AND STEREOCHEMISTRY

Objectives

To enable the Students

To learn the fundamentals of reaction mechanism.

To understanding the basic concept of stereochemistry.

To understand the concept of conformational analysis.

To know the concept of nucleophilic substitution and elimination.

Unit-I Introduction to Reaction Mechanism

Reaction intermediates – free radicals, carbenes, nitrenes, carbanions, carbocations –

Formation and stability of reaction intermediates - Methods of determination of reaction

mechanism - kinetic and thermodynamic control of chemical reaction. Kinetic and non

kinetic methods for determining organic mechanism – Principle of microscopic reversibility-

Energy profile diagram – Hammond postulate.

Electron displacement

Inductive and field effects, bond energies , delocalised bonds, cross conjugation –

Rules of resonance effect- Steric inhibition of resonance- Hyperconjugation- Hydrogen

bonding – Addition compounds – EDA complexes and inclusion compounds.

Unit –II Stereochemistry –I

Symmetry elements and points group classification- Concept of chirality, conditions

for chirality – Relationship between substrate symmetry and chirality . Projection formulae –

Wedge ,Fischer , Sawhorse and Newmann. Optical isomerism due to centre of chirality.

Molecules with one streogenic centre (chiral centre ) and molecules with more than one chiral

centre – properties of enantiomers and diastereoisomers – erythro and threo nomenclature –

.Cahn Ingold Prelog system of designation of configuration

Geometrical isomerism : E-Z nomenclature- determination of configuration of

geometrical isomers using physical and chemical methods – stereoisomerism in monocyclic

compounds (upto six membered ring )

Unit III Stereochemistry II

Prochirality and prosteroisomerism, enantiotopic and diastereotopic ligand and faces

and their nomenclature- pro-R and pro- S and Re and Si faces. Stereospecfic and

SRNMC Syllabus

stereoselective reactions. Asymmetric synthesis,Cram and prelog rules. Optical isomerism

due to axial chirality- biphenyl, Allenes and spiranes . Molecules with planar chirality –

paracyclophanes, trans-cyclooctene and ansa compounds.

Unit IV Conformational analysis

Configuration and Conformation –Conformation of ethane and n- butane-

conformational analysis – stereoelectronic and steric factors -conformation of simple acyclic

compounds-conformation of monosubtituted and disubstituted cyclohexanes –correlation of

the conformation of acyclic and cyclic systems with their physical and chemical properties

– conformational free energy – Curtin- Hammett principle- Quantitative treatment of Mobile

system-Eliel- Ro equation –conformations and reactivity of cyclohexanones

Unit -V Aliphatic Nucleophilic Substitution

Nucleophilicity and basicity – SN1 and SN2 mechanisms – Effect of substrate

structure, Effect of the attacking nucleophile , Effect of the leaving group – Effect of the

reaction medium, Ambident nucleophiles , ambident substrates , Neighbouring group

participation by π and σ bonds – SNi mechanism –– Nucleophilic substitution at allylic and a

vinylic carbon.

Aliphatic electrophilic substitution

Electrophilic substitution at saturated carbon – SE1,SE2,SEi mechanism.

Elimination :

Elimination - E1,E2 and E1CB mechanism – stereochemistry of Elimination –

orientation of the double bond– Effect of changes in the substrates base, leaving group and

medium on E1, E2, and E1CB reactions – elimination Vs substitution – pyrolytic cis

eliminations – Bredts rule .

Text book(s):

Text book-1

Title of the book : Advanced organic chemistry

Name of the Author : Jerry March

Publisher : Wiley and Sons Pvt Ltd

Edition/Year : 4/2007

Text book-2

Title of the book : Stereochemistry conformation and Mechanism

Name of the Author : P.S.Kalsi

Publisher : New age international publishers


Text book-3

Title of the book : Organic chemistry Vol-II

Name of the Author : I.L.Finar

Publisher : ELBS Longmann

Edition/Year : 5 /1975

Unit –I (From text book –1)

Chapter – 1 (Page No.17-19, 23-25)

Chapter – 2 (Page No.26-38, 68-69)

Chapter – 3 (Page No.75-91)

Chapter – 5 (Page No. 165-204)

SRNMC Syllabus


Unit –II (From text book –2)

Chapter – 1 (Page No.17 - 62)

(From text book –3)

Chapter – 4 (Page No. 170 -181, 197 -209)

Unit –III (From Text Book-2)

Chapter 1(Page No 84-130)

Unit –IV (From Text Book-2)

Chapter 4 (Page No 219-252)

(From Text Book-1)

Chapter 4 (Page No 107-108,138-149,150-164)

Unit –V (From text book –1)

Chapter 10(Page No.293-307,312-369)



Reference books:

Reference Book-1

Title of the book : Guide book to Mechanism in Organic chemistry

Name of the Author : Peter Sykes

Publisher : Orient Longman,

Edition/Year : 6/ 1984

Reference Book-2

Title of the book : Organic chemistry,

Names of the Author : R.T.Morrison and R.N. Boyd,

Publisher : Prentice, Hall,

Edition/Year : 6 /1995,

Reference Book-3

Title of the book : Stereochemistry of Organic compound Principles and Application,,

Name of the Author : D.Nasipuri

Publisher : wiley eastern Ltd


Reference Book-4

Title of the book : Stereo chemistry of carbon compounds,

Name of the Author : E.l.Eliel

Publisher : McGraw Hill

Edition/Year : 1 / (2008)

Prepared by :

Signature :

SRNMC Syllabus



SATTUR-626 203.



SYLLABUS

Programme : M.Sc ., Chemistry Subject Code :

Semester : I No. of Hours allotted: 6 / week

Subject : Paper II No of Credits : 5

Title of the Paper : INORGANIC CHEMISTRY – I

PERIODIC PROPERITIES AND SOLID STATE CHEMISTRY

Objectives:

To enable the Students to

Apply molecular orbital theory to the poly atomic molecules

Know about Bond properties , Ionic bonding and the concepts of solid state chemistry

Interrelate the structure poly-silicates and poly-acids with their properties

Unit I : Nature of chemical bonds:

Covalent bond: Hybridisation – Calculation of S and P characters – Bent’s rule-

M.O.theory; LCAO approximation – application of MOT to heteronuclear diatomic

molecules like NO, CO and triatomic molecule BeH2 – concept of multicentered bond as

applied to electron deficient molecules like diborane – VSEPR theory.

Unit II : Atomic Properties

Ionic radii - covalent radii – Vander Waals Radius – bond length, bond order, bond

energy bond polarity – partial ionic character of covalent bonds – electronegativity – electron

affinity –Lattice energy-Born-Lande equation-Born Haber cycle-Covalent character in ionic

compounds- different types of electrostatic interactions-hydrogen bonding.

Unit III : Solid state chemistry – I

Elements of crystallography-space lattice-Unit cell-Crystal system-X ray

diffraction-Bragg’s equation-Bragg’s method-Rotation crystal method and powder method

of x-ray diffraction -Evaluation of unit cell dimensions-Structure of typical lattice such

Ceasium chloride,Zinc blende, Wurzite, Rutile, Fluorite, antifluorite, perovskite, covalent

crystal as diamond and graphite.

Unit IV : Solid state chemistry II

Dislocation in solids- point defects- colour centers – Free electron and band theories

– Types of solids – super conductivity – High temperature super conductors – Types of

semiconductors – Thermo electric power and Hall effect. Photo voltaic effect - Semi

conductors in solar energy conversions.

SRNMC Syllabus

Unit V : Inorganic Chains- Rings and Cages

Silicates: Various silicate , structures – structure property correlation – Silicones

Poly acids: Classification-Structure of isopoly acids : polymolybdate, polyvanadate

and polytungstate – heteropolyacids : preparation and structures 12, 9 and 6 heteropoly

acids Phosphazenes and poly Phosphonitrilic compounds – Polymeric sulphur nitride

(Polythiazyl) Cage compounds: Nomenclature of Boranes and carboranes – Wade’s rule –

Styx number – preparation and structures of B4H10,C2B10H12, (B12 H12) 2-

- borazine

Text books

Text Book- 1

Title of the book : Selected Topics in Inorganic Chemistry

Name of the Author : Wahid U.Malik

Publisher : S.Chand and Company Ltd.


Text Book- 2

Title of the book : Principles of Inorganic Chemistry

Name of the Author : B.R.Puri and L.R.Sharma,

Publisher : Milestone Publishers,New Delhi 2008.


Unit-I (From Text Book-1)

Chapter - 5 (Page No 154 to 199)

Unit II to V (From Text Book-2)


Chapter - 4 (Page No 131 to 135, 179 to 183)




Appendix I (Page No1114 to1126)

Reference Books

Reference Book-1

Title of the book : Inorganic Chemistry.

Name of the Author : James E. Huheey , Ellen A. Keitler and Richard L. Keitler,

Publisher : Harper Collins College Publishers


Reference Book-2

Title of the book : An Introduction to Inorganic Chemistry

Name of the Author : K.F.Purcell and J.C Koltz

Publisher : W.B. Saunders Company, Philadelphia,


Reference Book-3

Title of the book : Introduction to solids

Name of the Author : Azaroff

Publisher : Tata Mc Graw Hill Publishing House,New Delhi


Prepared by :

Signature :

SRNMC Syllabus



SATTUR-626 203.



SYLLABUS

Programme : M.Sc .Chemistry Subject Code :

Semester : I No. of Hours allotted: 6 / week

Subject : Core - Paper III No. of Credits : 4

Title of the Paper : PHYSICAL CHEMISTRY – I

THERMODYNAMICS AND ELECTROCHEMISTRY

Objectives


To understand the importance and significance of thermodynamics and the principle

of chemical equilibrium.

To acquire an insight into phase rule.

To understand the principles of quantum chemistry.

To know about the importance and significance of electrochemistry and its

applications.

UNIT-I Chemical Thermodynamics

Second law of thermodynamics, concept of entropy. Gibbs-Helmholtz equation,

Maxwell relations and thermodynamic equation of state. Partial molar quantities - Chemical

potential, its variation with temperature and pressure, Gibbs Duhem equation. Experimental

determinations of fugacity of real gases and its determination (Graphical,from state

equation,approximate and generalised methods).Third law of thermodynamics – Absolute

entropies, determinations of absolute entropies, exception to third law, and Unattainability

of absolute zero.

UNIT-II Chemical and Phase Equilibria

Thermodynamic derivation of the law of mass action, van’t Hoff’s reaction

isotherm. Variation of equilibrium constant with temperature. standard reaction free

energy, its calculation from thermochemical and electrochemical data. de Donder’s concept

of degree of advancement of a reaction.

Gibbs phase rule - its thermodynamic derivation. Application of phase rule to

three component systems - systems composed of two solids and a liquid- Formation of one

pair, two pairs and three pairs of partially miscible liquids.

UNIT – III Basic Principles of Quantum Mechanics

Planck’s explanation about black- body radiation,de-Broglie’s concept of matter

waves, Compton effect , Heisenberg’s uncertainty principle. Postulates of quantum

mechanics. Operators : Linear operators -methods of getting the following quantum

mechanical operators - position, momentum, kinetic energy, potential energy, total energy,

angular momentum, raising and lowering and spin angular momentum.

SRNMC Syllabus

Hermicity and proving the quantum mechanical operators are Hermetian.

Commutator algebra-evaluation of commutators - vanishing and non-vanishing commutators.

Eigen function and Eigen value, Expansion theorem. Orthogonality and normalization of

wave functions.

UNIT-IV Electrochemistry - I

Theory of electrolytic conductance – inter ionic attraction , ionic atmosphere ,

thickness of ionic atmosphere. Debye Huckel - Onsager conductance equation – its derivation

and experimental verification , deviations and modifications-Debye Falkenhagen and Wein

effects. Mean ionic activity and activity coefficients of strong electrolytes. The role of

electrodes – the electrochemical potential . Types of electrodes – gas / inert metal electrode ,

ion / insoluble salt / metal electrode, Oxidation-reduction electrode.

Types of cells-Electrochemical cells – Electrochemical cell reactions. Determination

of EMF of cells. Liquid junction potential. Nernst equation. Applications of EMF

measurements- determination of equilibrium constant, PH, solubility product.

Potentiometric titrations.

UNIT-V Electrochemistry – II

The electrical double layer and zeta potential. Perrin, Gouy-Chapmen and Stern

models.Over potential, Butler-Volmer equation - Tafel equation. Hydrogen over voltage.

current-potential curves- voltametry,polarography and cyclic voltametry.

Application of electrochemical processes- Power generation and storage. Fuel cells –

storage batteries and dry cells. Corrosion and Passivity - Principles of inhibition of corrosion-

photo electrochemistry and electro chemiluminescence.

Text books

Text book-1

Title of the book : Principles of Physical chemistry

Name of the Author : B.R.Puri, L.R.Sharma,M.S.Pathania

Publication : Vishal publishing Co,New Delhi.

Edition/ year : 45 /2012

Text Book- 2

Title of the book : Advanced Physical chemistry

Name of the Author : Gurdeep Raj

Publisher : Goel Publishing Co.Meerut.


Text Book- 3

Title of the book : Introductory Quantum chemistry

Name of the Author : A.K.Chandra

Publisher : Tata McGraw –Hill Publishing Company Limited,New Delhi.


Text Book- 4

Title of the book : An Introduction to Electrochemistry

Name of the Author : S.Glasstone

Publisher : East West Press (P) Ltd.


SRNMC Syllabus

Unit-I (From Text Book-1) Chapter – 14 (Page No.517-541,546-549)

Unit-II (From Text Book-1)

Chapter – 16 (Page No.564-573,581-582)

(From Text Book-2)

Chapter – 18 (Page No.1050-1052, 1054-1056, 1079-1083, 1085-1088)

Unit- III (From Text Book-1)

Chapter -1(Page No.23-25, 32-36)

(From Text Book-3)

Chapter -1(Page No.1-7)


Unit-IV(From Text Book-1)

Chapter – 22 (Page No.770-829,845-850,867-887)

(From Text Book-4)


Unit-V (From Text Book-1)

Chapter – 24 (Page No.845-851,867-873)

Reference Books

Reference Book-1

Title of the book : Thermodynamics for chemists

Name of the Author : S.Glasstone

Publisher : East West Press (P) Ltd,New Delhi.


Reference Book-2

Title of the book : Thermodynamics

Name of the Author : J.Rajaram and J.C. Kuriakose

Publisher : Shoban Lal Nagin, Chand & Co, New Delhi.


Reference Book-3


Name of the Author : D.N. Bajpai

Publisher : S.Chand &Company Ltd, New Delhi.


Reference Book-4

Title of the book : Electrochemistry

Name of the Author : B.K. Sharma

Publisher : Goel Publishing House,Meerut.


Prepared by :

Signature :

SRNMC Syllabus

SRI S.RAMASAMY NAIDU MEMORIAL COLLEGE (An Autonomous Institution Re-accredited with ‘A’ Grade by NAAC)

SATTUR-626 203.



SYLLABUS



Subject : Paper IV Major Elective – I (a) No of Credits : 4

Title of the Paper : MEDICINAL CHEMISTRY

Objectives

To enable the learners to

1. Know the fundamentals of Medicinal Chemistry.

2. Understand the concept of chemotherapy

Unit-I Fundamentals of Medicinal chemistry

Definitions of Medicinal Chemistry, Pharmacology and molecular pharmacology,

pharmacodynamics, pharmacophore,pharmacodynamics agents-- Structure Activity

Relationship (QSAR) – Hanschapproach –account of physiological effects by hydroxyl,

aldehyde,ketone,acidic,nitro,nitrite,nitrile groups and unsaturation - drug receptors –

streochemical consideration - mechanism of drug action on enzymes,gene function,biological

membranes.

Unit-II Medicinally useful antibiotics

Classification of antibiotics-Structural features and SAR of the following antibiotics-

penicillin G, cephalosphorin and their semisynthetic analogs (β-lactam), streptomycin(amino

glycoside), terramycin (tetracycline), erythromycin(macrolide) , chloramphenicol and

Rifamycin.

Unit-III Chemotherapeutic agents

Antineoplasticagents: Classification, synthesis and Assay of Cyclophosphamide,

Ifosfamide, Clorambucil, Busulfan, Decarbazine, Methotrexate, Azathioprine, 6-

Mercaptopurine, 5-fluorouracil and cisplatin,

Antituberculardrugs: Classification, Synthesis and Assay of Isoniazid, Rifampicin,

Pyrazinamine, Ethambutol, Thiacetazone, paraaminosalicylic acid and Ethionamide.

Antimalarialdrugs: Classification, synthesis and assay of Chloroquin. Primaquine,

Amaodiaquine, Mefloquine, Progunail Pyrimethamine,

Diuretics:Classification, Synthesis and Assay of Fursemide, Acetazolamide,

Chlorothiazide.

Unit-IV

Antihypertensivedrugs: Nifedipine, Captopril, Hydralazine, Sodiumnitroprusside,

clonidine, methyldopa and guanothidine

Antihistamines: H1-Antagonists - Pheniramine, Chlorpheniramine,

Diphenyhydramine,Mepyramine and Promethazine. H2-Antagonists - Cimetidine,Ranitidine

and fomotidine.

SRNMC Syllabus

Unit-V

Analgesic&Antipyreticdrug-Classification- narcotic &Non-narcotic analgesics:

Aspirin, sodiumsalicylate, paracetamol, phenylbutazone, oxyphenylbutazone, ibuprofen,

Mephenamic acid, Diclofenac sodium.

CNS Stimulant drugs: Amphetamine, Caffeine, Theobromine, Theophylline,

Nikethamide,Methyl phenidate (structure and uses only)

CNS Depressent drugs: Phenelazine, Imipramine, Amitriptyline, Desipramine

Text books

Text Book- 1

Title of the book : Pharmaceutical chemistry-organic

Name of the Author : G.R.Chatwal

Publisher : Himalaya Publishing House


Text Book- 2

Title of the book : A Textbook of Pharmaceutical Chemistry

Name of the Author : Jayashree Ghosh

Publisher : S.Chand& Company Ltd


Text Book- 3

Title of the book : Medicinal chemistry

Name of the Author : G.R.Chatwal



Text Book- 4

Title of the book : Text book of Pharmaceutical Organic chemistry

Name of the Author : Mohammad Ali

Publisher : CBS Publichers & distributors



Chapter – 1 (Page No. 5-7)

Chapter – 3 (Page No. 41-45, 50-56, 62, 63)

Chapter – 5 (Pages No. 94-97)


Chapter-23 (Page No.242-265)

Unit-III (From Text Book- 3)

Chapter-31 (Page No 316-333,283 to291, 264 to271)

Unit-IV (From Text Book- 3)

Chapter-19(Page No 214 to224)



(From Text Book-4)


SRNMC Syllabus

Reference Books

Reference Book-1 Title of the book : Medicinal Chemistry

Name of the Author : Kar.Ashutosh

Publisher : New age international publishing house


Reference Book-2

Title of the book : Introductory Medicinal Chemistry..

Name of the Author : J.B Taylor and P.D Kennewell

Publisher : Ellisworth publishers


Prepared by :

Signature :

SRNMC Syllabus



SATTUR-626 203.



SYLLABUS



Subject : Paper IV- Major Elective – I (b) No of Credits : 4

Title of the Paper : BIOCHEMISTRY

Objectives


To understand the biological role of enzymes in living organisms

To get a knowledge about the metabolism and genetic information.

Unit-I Enzymes

Classifications, nomenclature,properties of enzymes, some features of active sites of

enzymes, enzyme kinetics-Michaelis-Menton model-significance of Km and Vmax Values,

Enzyme inhibition-competitive and non-competitive.Allosteric interaction-Mechanism of

enzyme action .Lysozyme and carboxypeptidase.

Unit-II Generation and storage of Metabolic energy

Metabolism-basic concepts and design – glycolysis – citricacidcycle - oxidative

phosphorylation-pentose pathway and gluoneogenesis.

Glycogen and disaccharide metabolism, fatty acid metabolism –amino acid degradation

and urea cycle-photosynthesis.

Unit-III Information, Storage, transmission and expression of genetic information

DNA- structure and its replication: messenger RNA and transcription - genetic code

and gene - protein relationship-protein synthesis, control of gene expression-Eukaryotic

chromosomes, Recombinant DNA technology.

Unit-IV Bio-inorganic chemistry

Metalloproteins and enzymes-Blue copper proteins-copper proteins as

oxidases/reductases-Nickel containing enzymes-structure of DNA-types of nucleic acid

interactions-coordination, intercalation and hydrogen bonding-interactions of metal ions with

nucleic acid-redox chemistry. Hydrolytic chemistry-monitoring the DNA binding by UV, IR,

NMR and CV spectral techniques.

Unit-V Biophysical aspects

Electron transport and oxidative phosphorylation-Thermodynamic and kinetic

aspects-Photosynthesis-An overview-Photo system II-The light harvesting chlorophyll-

protein complexes of photo system II-Role of carotenoids in photosynthesis-The primary

electron donor of photo system II,P680-The stable primary electron acceptor QA and the

SRNMC Syllabus

secondary electron acceptor QB –The transient intermediate electron acceptor of photo

system II,pheophytin-Oxygen evolution-The role of manganese-The electron donor to P680+

-Charge recombination in photo system II-Photo system I-Light-harvesting chlorophyll-

protein complexes of photo system I-The primary electron donor of photo system I ,P700-The

primary electron acceptor Ao of photo system I- The intermediate electron acceptor A1 of

photo system I- Mobile electron carriers plastocynanin and ferredoxin NADP+ - reductase.

Text books

Text Book- 1

Title of the book : Fundamentals of Biochemistry

Name of the Author : J.L Jain

Publisher : S.Chand & company Limited


Text Book- 2

Title of the book : Bioinorganic Chemistry

Name of the Author : I.Bertini, H.B.Gray S.J.Leppard and J.S Valentine

Publisher : Viva Books Pvt Ltd..


Text Book- 3

Title of the book : Biochemistry

Name of the Author : A.L.Lehninger,

Publisher : CBS publishers



Chapter 16 (Page No 277-286,309-331)


Chapter 21(Page No 367-412,420-422)

Unit-III (From Text Book-3)


Unit IV (From Text Book -2)


Unit-V Study materials will be provided.

Reference Books Reference Book-1

Title of the book : Biochemistry

Name of the Author : B.D.Hames and N.M.Hooper

Publisher : Viva Books Ltd


Reference Book-2

Title of the book : Bio Chemistry,

Name of the Author : U.Sathiya narayana, U. Cakarapani

Publisher : Books and allied Pvt.ltd,Kolkata.


SRNMC Syllabus

Reference Book-3

Title of the book : Biochemistry,

Name of the Author : J.M. Berg, J.L.Tymoczko and L.Stryer,

Publisher : W.H.Freeman and company, New York


Reference Book-4


Name of the Author : K.F. Purcell and J.C. Koltz,

Publisher : W.B. Saunders Company, Philadelpha 1980


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Subject : Paper V Practical - I No. of Credits : 4

Title of the Paper : Inorganic Chemistry Practical

Objectives


To understand the principle for the estimation of binary mixture.

To apply the principle in the semi-micro analysis of an inorganic salt mixture.

To prepare the inorganic complexes

1. Semi-micro qualitative analysis: Analysis of mixtures containing one familiar and

one less familiar cations from the following W, Pb, Se, Mo, Cu, Cd, V, Mn, Ni, Co,

Zn, Ca, Ba, Sr, Li, Mg (insoluble and interfering an ion may be avoided).

2. Inorganic preparations: preparation of at least 5 inorganic complexes.

3. Quantitative analysis: separation and estimation of mixtures by volumetric and

gravimetric methods: some recommended mixtures are

i) Cu and Ni

ii) Fe and Ni

iii) Ca and Ba

iv) Cu and Zn

v) Fe and Cu

References

Reference Book-1

Title of the book : Vogel’s Text Book of Quantitative Chemical Analysis

Name of the Author : J. Bassett et al

Publisher : ELBS, Longmann, U.K


Reference Book-2

Title of the book : Inorganic Semi micro Qualitative Analysis

Name of the Author : V.V. Ramanujam

Publisher : The National Publishing Co, Chennai


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SYLLABUS

Programme : M.S., Chemistry Subject Code :

Semester : II No. of Hours allotted : 6 / week

Subject : Core Paper VI No of Credits : 5

Title of the Paper : ORGANIC CHEMISTRY – II

ORGANIC REACTION MEHANISM AND REAGENTS

Objectives

To enable the Students

To understand the aromatic character of organic compounds.

To learn the concept of addition to multiple bonds, aromatic eletrophilic & nucleophilic

substitution.

To understand the concept of oxidation and reduction.

Unit I Aromatic Character

Aromatic character in benzene , six membered rings , five , seven and eight

membered rings – other systems with aromatic sextets – Huckel’s rule – Craigs rule –

concept of homoaromaticity and antiaromaticity - systems with 2,4 and 10 electrons –

systems with more than10 electrons – Alternant and nonalternant hydrocarbons - Chemistry

of cyclopentadienyl anion –Fulvene, Azulene , Tropolones Sydnone and Annulenes

Novel ring system

Nomenclature of bicyclic and tricyclic systems- chemistry of adamantane, diamantane

(congressane), cubane and catenanes.

Unit II Addition to multiple bonds

Electrophilic, nucleophilic and free radical additions- addition to conjugated systems

– orientation of the addendum- stereo chemical factors in reactions like addition of hydrogen,

halogen, hydrogen halides, hypohalous acids, hydroboration, hydroxylation and epoxidation.

Addition to carbonyl groups –mechanism of Aldol condensation, Perkin reaction,

Knoevenagel reaction, Mannich reaction, Cannizaro reaction, Benzoin condensation, Claisen

ester condensation, Darzen’s reaction, Reformatsky reaction, Wittig reaction and Grignard

reaction.

Addition to α, β-Unsaturated carbonyl groups – addition of Grignard reagents to α, β-

unsaturated carbonyl compounds, Michael addition and Diels-Alder reaction .

Unit III Aromatic electrophilic substitution –orientation,reactivity and mechanism of

nitration , halogenation, Friedel-Craft’s reaction and sulphonation –partial rate factors-

SRNMC Syllabus

ortho/para ratio-Quantitative treatment of reactivity of the electrophile (the selectivity

relation) - Aromatic nucleophilic substitution reactions SNAr,SN1 and benzyne mechanisms.

Quantitative treatment of the effect of structure on reactivity – The Hammett

relationship- significance of reaction and substituent constants- application of the Hammett

equation in reaction mechanism – limitations and deviation.

Unit IV Oxidation and reduction

Mechanism and application of stereochemical aspect of the following oxidation –

reduction reactions: Oxidation reaction involving CrO3, SeO2, OsO4, LTA (lead tetra

acetate), PIA (periodic acid), NBS (N- bromosuccinimide), H2O2-Oppenauer oxidation.

Catalytic hydrogenation: reaction involving lithium aluminium hydride, tri isobutyl

aluminohydride, DIBAL, sodium borohydride, Birch reduction, Meerwein-Pondorf-Verley

reduction and hydroboration.

Unit V Reagents in organic synthesis and Free Radicals

Reagents: Gilman’s reagent (lithium dimethylcuprate), LDA (lithium

diisopropylamide), DCC (Dicyclohexylcarbodiimide), 1,3-dithiane,Woodward and Prevost

hydroxylation, Merrifield resin, Peterson’s synthesis and Baker’s yeast.

Free radicals: Formation, detection and stability of free radicals – free radical

reactions – halogenation, addition, oxidation, reduction and rearrangement reactions –

Barton, Sandmeyer, Gomberg, Bachmann, Ullmann, Pschorr and Hundsdiecker reactions.

Text books

Text Book- 1

Title of the book : Advanced Organic Chemistry,


Publisher : John Wiley & Sons


Text Book- 2

Title of the book : Organic reaction mechanism

Name of the Author : Raj K Bansal

Publisher : Tata Mc Graw-hill publishing company Ltd,Delhi


Text Book- 3

Title of the book : Reactions &Reagents,

Name of the Author : O.P.Agarwal

Publisher : Goel publishing house,


Text Book- 4 Title of the book : Reagents inOrganic synthesis

Name of the Author : O.P.Agarwal

Publisher : Geol publishing house,

Edition/Year : 43/2008.

Unit-I (From text book –1)

Chapter - 2 (Page No.40-67)

Chapter - 3 (Page No 91-93)


Chapter 13 (Page No.734-830)

Chapter 16 (Page No.920-22,973,945-951,954-955,969-970)

Chapter 19 (Page No.1233-1235)

SRNMC Syllabus

Chapter 10 (Page No.339-354,491-93)

Chapter 15 (Page No.795-97,839-852)

Unit-III (From Text Book-1) Chapter 12 (Page No.509-542)



Unit-IV (From Text Book-2) Chapter 14 (Page No 584-604)

(From Text Book-3)


Chapter 21 (Page No 853-860,866-890,903-909,926-929,931-933)


Chapter 20 (Page no.810-816)

Chapter 21(Page no.853-860,866,890,903-909,926-933)

(From Text Book-1)


Chapter 14 (Page no.689-699,715-716,723-724,730-732


Reference Books

Reference Book-1

Title of the book : Mechanism and Structure in Organic Chemistry,

Name of the Author : E.S. Gould,

Publisher : Henry Holt& Co.,New York ,


Reference Book-2

Title of the book : Reaction Mechanism and Reagents in Organic Chemistry,

Name of the Author : Gurdeep R Chatwal

Publisher : Himalaya publishing house, New Delhi


Reference Book-3

Title of the book : Guide book to Mechanism in Organic chemistry

Name of the Author : Peter Sykes

Publisher : Orient Longman,

Edition/Year : 6/ 1984

Reference Book-4

Title of the book : Organic chemistry,

Name of the Author : R.T.Morrison and R.N. Boyd,

Publisher : Prentice, Hall,

Edition/Year : 6 /1995,

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SYLLABUS



Subject : Core Paper VII No. of Credits : 5

Title of the Paper : INORGANIC CHEMISTRY – II

CO-ORDINATION AND BIOINORGANIC CHEMISTRY

Objectives

To have an insight into study of coordination compounds and their reactions

To have an understanding of role of inorganic metal complexes in living systems

Unit – I Coordination compounds

IUPAC Nomenclature of coordination compounds -isomerism in coordination

compounds. – stability constant – Factors affecting stability constant in solution –

Determination of stability constant – Spectrophotometry, polarographic and potentiometric

method.

Theories of bonding : VB – CFT- MO theories - Splitting of d- orbitals in oh,Td, and

square planar geometries – CFSE Calculation in terms of 10Dq - Factors affecting crystal

field splitting, spectro chemical series – Magnetic properties of transition metal complexes –

calculation of spin – only magnetic moments – quenching of orbital magnetic moments.

Unit – II Reaction Mechanism of Coordination compounds

Substitution reactions of octahedral complexes- Factors affecting reactivity octahedral of

complexes – labile – inert complexes – Mechanism of acid hydrolysis, base hydrolysis and

anation reactions Substitution reactions of square planar complexes – Factors affecting

reactivity of square planar complexes – The trans- effect and its applications– Electron

transfer reactions –– outer sphere and inner sphere electron transfer mechanisms-

complementary and non-complementary reactions

Unit – III Bio – Inorganic Chemistry – I

Porphyrin ring system – metalloporphyrins – hemogolobin and myoglobin structures

and work functions – synthetic oxygen carries – cyto chromes – structure and work functions

in respiration – chlorophyll – structure – photosynthetic sequence – iron sulphur proteins

[non – heme iron protein] – copper containing proteins – classification – blue copper proteins

– structure of blue copper electron transferases copper proteins as Oxidases – cytochrome C

oxidase

Unit – IV Bio – Inorganic Chemistry – II

Carboxypeptidase A : Structure, function – carbonic anhydrase – inhibition and

poisoning – Corin ring system – Vitamin B12 and B12 Coenzymes – in – vivo and in – vitro

nitrogen fixation – essential and trace elements in biological systems - metal ion toxicity

SRNMC Syllabus

Molecular mechanism of ion transport across the membrane – sodium and potassium ions

pumps – chelate therapy – cis platin.

Unit V

Acid – base systems: Acid – base definition: Bronsted – Lowry- Lux – flood-

Solvent system – Lewis Usanovich – generalized acid – base concept – steric effect on the

strength of acids and bases – HSAB concept – Symbiosis.

Oxidation and Reduction: Electrode potential and electromotive forces- application

of electrode potential in inorganic chemistry – determination of oxidizing or reducing power

of the element, feasibility of displacement reaction, determination of equilibrium constant.

Text books

Text Book- 1



Publisher : Milestone Publishers , New Delhi


Text Book- 2


Name of the Author : Wahid U.Malik et al



Text Book- 3

Title of the book : Concise Co-ordination Chemistry,

Name of the Author : R.Gopalan and V.Ramalingam,

Publisher : Vikas Publishing House PVT Ltd



Chapter 26 &27 (Page No 738 to755, 759 to 779)

Unit II (From Text Book 2) Chapter 15, 16 and 17 (Page No 510 to 550)

Unit III and IV (From Text Book 3)

Chapter 14 (Page No 313 to 328)

Unit V (From Text Book I)


(From Text book- 2)

Chapter – 22 (Page No. 658-660,684 -696,752)

Reference Books

Reference Book-1


Name of the Author : K.F. Purcell and J.C. Koltz,

Publisher : W.B. Saunders Company, Philadelpha 1980


Reference Book-2





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SYLLABUS

Programme : M.Sc. Chemistry Subject Code :


Subject : Core Paper VIII No. of Credits : 4

Title of the Paper : PHYSICAL CHEMISTRY - II

QUANTUM, CATALYSIS AND NANO CHEMISTRY

Objectives:

To apply the principles of quantum chemistry to simple systems, atomic and

molecular systems and to obtain their energies.

To understand the theory and applications of catalysis.

To know about the principles and instrumentation of nano chemistry.

UNIT : I Application of Quantum Mechanics to Simple Systems

Derivation of Schrodinger wave equation (SWE). Application of SWE to simple

systems - particle moving in one dimensional box, particle moving in a 3-D box- degeneracy

– distortion, particle moving in a ring, rigid rotator, simple harmonic oscillator. Radial

wave function and radial probability distribution function. Shapes of various atomic orbitals.

UNIT : II Approximation Methods in Quantum Mechanics

Need for approximation methods (variation and Perturbation methods).Time

independent perturbation theory. Perturbation corrections-first order correction. Schrodinger

equation for He atom. variation theorem- application to hydrogen and He atom. Hartee -

Fock Self Consistent Field (HFSCF) theory- application to He atom, HFSCF method of

many electron system. Electron spin and Pauli principle, anti symmetric nature of the wave

functions ,Slater rules , Born-Oppenheimer approximation. VB and MO theories of homo

nuclear diatomic molecules.

UNIT-III Statistical Thermodynamics

Aims of statistical thermodynamics, definitions of state of a system,ensembles

(micro, macro and grand canonical). Derivation of Boltzmann distribution law , Boltzmann-

Planck equation. Partition functions-thermodynamic properties from partition

functions,partition function and equilibrium constant. Quantum statistics –Fermi-Dirac and

Bose-Einstein statistics. Population inversion. Einstein’s and Debye’s theories of heat

capacities of solids. Nuclear spin statistics- ortho- and para- nuclear states-calculation of

residual entropy of H2 at 0 K in terms of ortho- and para- ratio.

UNIT:IV Catalysis

Catalysis-Types, characteristics and theory of catalysis. Hetrogeneous catalysis-

kinetics, retardation and effect of temperature. Classification of catalysis. Enzyme catalysis –

SRNMC Syllabus

characteristics, factors governing the rate of enzyme reaction. Mechanism of enzyme

catalysis (Michaelis Menten equation) , Lineweaver and Burk plot , Eadie’s plot

Acid–Base catalysis –Mechanism and its kinetics. Hammett and Bronsted equation ,

Acidity function. Langmuir – Heinshelwood and Langmuir – Rideal- mechanism . ARRT of

surface reactions – NH3 synthesis, hydrogenation of C2H4 and cracking of hydrocarbons.

UNIT : V Instrumentation in Nanochemistry:

Microscopic techniques for the characterization of nanomaterials – UV-Visible and

fluorescence spectroscopy AFM, SEM, TEM. X-ray diffraction and microanalysis

Text books

Text Book- 1

Title of the book : Introductory Quantum chemistry

Name of the Author : A.K.Chandra

Publisher : Tata McGraw –Hill Publishing Company Limited,New Delhi.


Text book-2





Text Book- 3



Publisher : Goel Publishing Co,Meerut.


Text Book- 4

Title of the book : Nano technology, basic science and emerging technologies

Name of the Author : Mick Wilson

Publisher : Overseas Press India Private Limited,New Delhi.


Unit- I & II (From Text Book-1)







Chapter – 25 (Page No.892-910,919-923)

Unit -IV (From text book 3)

Chapter-15(Page No.841-872)

Unit- V (From text book 4)

Chapter-2(Page No. 30-40)

SRNMC Syllabus

Reference Books

Reference Book-1

Title of the book : Quantum chemistry

Name of the Author : R.K.Prasad

Publisher : New Age International Publishers, New Delhi


Reference Book-2

Title of the book : Introduction to Nanotechnology

Name of the Author : Charles P.Poolee Jr. and Franck Owens,

Publisher : John-Wiley and Sons


Reference Book-3

Title of the book : Nano: the Essentials

Name of the Author : T.Pradeep

Publisher : Mc Graw-Hill Education, Delhi.


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Subject : Paper IX Major Elective –II -a No of Credits : 4

Title of the Paper : ANALYTICAL CHEMISTRY

Objectives


To learn the principle of electro analytical methods & spectroanalytical methods.

To gain knowledge on the basic concepts of error analysis

Unit-I: Precipitation Techniques

Introduction-properties of precipitates and precipitating reagents –colloidal

precipitates, Co-precipitation-post precipitation –precipitates from homogeneous solution –

surface adsorption –drying and ignition of precipitates –application of gravimetric methods

Unit-II: Error Analysis

Error analysis: Classification of errors-accuracy and precision-minimization of errors-

significant figures-significant figures in computation-statistical treatment of data: mean,

median, standard deviations, variance, relative standard deviation –spread, errors-standard

deviation of computed results-Student’s t-test-F-test-comparison of the means of two

samples-correlation and regression: linear regression (least square analysis).

Unit-III Electro analytical methods

Electro analytical techniques: Electrogravimetry, theory of eletrogravimetric analysis-

electrolytic separation and determination of metal ions.Coulometry: Electrolytic cell-working

electrodes-auxiliary electrode and reference electrode- coulometric titrations Voltammetry:

Cyclic Voltammetry - stripping, voltammetry - chronopoteniometry. Amperometry:

Amperometric titration.

Unit-IV: Thermoanalytical Methods

Thermal analysis, theory and principles of DTA and TGA- factors affecting the

position of DT and TG traces-application of DTA and TGA to the thermal behavior of the

following compounds-crystalline coppersulphate, calcium oxalate monohydrate, calcium

acetate monohydrate, zinc hexafluosilicate-complementary nature of DTA and TGA-

principle and application of DSC-determination of degree of conversion of high alumina

cement-purity determination-phase transition study –in forensic laboratory.

Unit-V: Spectroanalytical Methods

Colorimetry: Beer and Lambert’s law-terminology-condition for a satisfactory

colorimetric analysis-method of colour measurement or comparison-principles of

SRNMC Syllabus

colorimetric determinations of NH3, Cr, Cu, Fe, Mn-simultaneous spectrophotometer

determination of Cr and Mn.

Nephelometry and turbidimetry:principle-determination of sulphate and phosphate-

fluorimetry:principle-application of fluorimetry in the determination of Cd,Ca,and Zn and

determination of codeine and morphine in a mixture-flame spectrometry: theory-

interferences-AAS-applications in the determination of Mg+2

and Ca+2

in tap water ,V in

lubricating oil, trace lead in a ferrous alloy and trace elements in contaminated soil.

Text books

Text Book- 1

Title of the book : Elements of analytical chemistry

Name of the Author : R.Gopalan

Publisher : Sultan Chand & sons


Text Book- 2

Title of the book : Instrumental method of chemical analysis

Name of the Author : Gurdeep chatwal

Publisher : Himalaya publishing House



Chapter 9 (Page No 121 to134)




Chapter 10 (Page No 139 to 145,148 to 150)

(From Text Book-2)

Chapter 28 (Page No 2.541 to 2.545)

Unit-IV (From Text Book-2)




Chapter 13 to 16(Page No 2.389 to 2.398, 2.349 to 2.416, 2.367)

Reference Books

Reference Book-1,

Title of the book : Fundamentals of Analytical Chemistry,

Name of the Author : D.A.Skoog, D.M.West and F.J.Hollar

Publisher : Harcourt College Publishers,1


Reference Book-2 Title of the book : Instrumental Methods of Analysis

Name of the Author : H.H.Williard,L.L.Merritt and J.A.Dean

Publisher : East-West press New Delhi


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Subject : Paper IX -Major Elective –II (b) No of Credits : 4

Title of the Paper : INDUSTRIAL CHEMISTRY

Objectives


To understand the principle of chemical technology & to utilize the raw materials

in chemical industry

To get the awareness about the pollution and its control

Unit-I: Principles of Chemical Technology

Introduction: Basic principles of chemical industry -importance of chemical industry-

classification of technological processes-designing and modeling of chemical plants-unit

process and unit operations.

Basic requirements of industrial reactors-choice and selectivity of reactor basic

principles of homogeneous and heterogeneous processes and reactors with examples.

Unit-II: Raw Materials and Energy for Chemical Industry

Raw materials-Characteristics of raw materials and their resources- methods of raw

material concentration –integral utilization of raw materials

Energy for chemical industry-power and fuels-classification of fuels-coal-fuel gases

and liquid fuels-petroleum-cracking-chemical corrosion-types of corrosion and preventive

measures

Unit-III: Water Pollution and Its Control

Introduction – types of water –soft and hard water-softening of water– water

pollution – sources of water pollution – water pollutants – classification – physical, chemical

and biological – inorganic pollutants and toxic metals – organic pollutants – -pesticides and

fertilizers – suspended particles – water quality – ill effects of water pollutants – water

pollution control – water treatment – primary, secondary and tertiary treatment – desalination

– reverse osmosis – sewage and industrial waste water treatment.

Unit-IV: Small Scale Chemical Industries

Electro-thermal and electro-chemical industries: Electric furnace- classification - manufacture

of calcium carbide, yellow phosphorus and red phosphorus - Electrolytic manufacturing and

refining of aluminum - process and theory of electroplating.

Oils, fats and waxes:

Manufacturing of soyabean oil-Analysis of oils, fats and waxes- manufacture of

soap by batch process - detergent (cationic, anionic and non-ionic) – cosmetics (powder,

SRNMC Syllabus

cream, hair fixers) – manufacture of some industrially important chemicals like potassium

chlorate – metal powders.

.

Unit-V: Large Scale Chemical Industries

Manufacturing process-raw materials-composition and uses of products in Portland

cement-ceramics-plastics( Polyethylene, PVC)-- synthetic fibres (Nylon66, Nylon6,

Terylene) - natural Rubber- Refining of crude rubber - Vulcanisation of rubber and Synthetic

rubbers (BunaS, Neoprene)-fertilizers(Nitrogen and phosphate) Organic insecticides

(DDT,BHC)

Text books

Text Book- 1

Title of the book : ChemicalTechnology,Vol.1.

Name of the Author : 1.Mukhlyonov(ed.),

Publisher : Mir publication,Moscow


Text Book- 2

Title of the book : Enviromental Chemistry

Name of the Author : A.k.De

Publisher : New age International (P) Limited


Text book-3

Title of the book : Industrial chemistry

Name of the Author : B.K Sharma -

Publisher : Goel publishing house.


Text book-4

Title of the book : Outlines of Chemical Technology

Name of the Author : M.Gopala Rao Drydens

Publisher : East-West Press


Text Book- 5

Title of the book : Polymer Science

Name of the Author : V.R.Gowarikar, N.V.Viswanathan and Jayadev Sreedher, “

Publisher : Wiley Eastern Ltd., New Delhi



Chapter 2 (Page No 20-25,68-89)

Chapter 3 (Page No90-118)



(From textbook -4)

Chapter 1 (Page No 10 - 30)


Chapter 7(Page no.287-307,316-320)

SRNMC Syllabus

(From Text Book - 2)

Chapter 12(Page no292-295)

Unit-III (From Text Book - 2)

Chapter -9 &10 (Page No. 170-267)

Unit-IV (From Text Book - 3)

Chapter - 40 (Page No. 1153-1155, 1169-1171, 1176-1178, 1184-1186, 1296-1298,

1305-1306)

Chapter - 48 (Page No.1340-1343)

Unit-V (From Text Book- 5 )


Reference Books

Reference Book-1

Title of the book : Industrial chemistry

Name of the Author : B.K Sharma

Publisher : Goel publishing house.


Reference Book-2

Title of the book : Chemical process industries

Name of the Author : R.Norris shreve & J.A.Brink

Publisher : McGraw Hill


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Subject : Paper X Practical - II No of Credits : 4

Title of the Paper : ORGANIC CHEMISTRY PRACTICAL

Objectives


To estimate the organic compounds quantitatively & prepare organic compounds by

two stage preparation

To separate and analyse the given organic mixture into two different components

Separation and analysis of two component mixtures. Identification of the

components and preparation of solid derivative.

Quantitative analysis:

a. Estimation of glucose by Bertrand method

b. Estimation of glycine.

c. Estimation of Ascorbic Acid.

d. Estimation of Acetone

Organic preparations: (only for class work)

About 5 (five) two stage preparations:

a. p-Nitroaniline from acetanilide

b. Anthranilic acid from phthalimide

c. m-Nitrobenzoic acid from methyl benzoate

d. Benzanilide from benzophenone.

e. Acetylsalicylic acid from salicylic acid

SRNMC Syllabus

Reference books:

Reference books - 1

Title of the book : Practical Organic Chemistry

Name of the Author : A.I. Vogel

Publisher : ELBS

Edition/Year : 3 / 1975

Reference book -2

Title of the book : Practical organic Chemistry

Name of the Author : S.P.Bhutani,Aruna Chhikara

Publisher : Ane Books Pvt.Ltd.,


Reference book -3

Title of the book : Organic Chemistry Lab Manual

Names of the Author : Gnapragasam and Ramamoorthy

Publisher : S.Viswanathan


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Semester : III No. of Hours allotted : 6/ week

Subject : Core Paper XI No of Credits : 5

Title of the Paper : ORGANIC CHEMISTRY - III

ORGANIC SPECTROSCOPY AND NATURAL PRODUCTS

Objectives

To understanding the principle of UV, IR and Mass spectroscopy and their application

in organic chemistry.

To apply 1H NMR and

13C NMR methods in elucidating the structure and

identification of organic molecules.

To apply the principle of ORD and CD in elucidating the structure of organic

molecules.

To study the application of chromatographic techniques.

To know the chemistry of alkaloids, steroids and antibiotics.

UNIT: I UV, IR and Mass Spectroscopy

UV Spectroscopy Principle- absorption spectra of conjugated dienes - unsaturated

carbonyl compounds –Woodward- Fieser rules, Scott’s rules-aromatic carbonyls.

IR Spectroscopy: Molecular vibrations – vibrational frequency-factors influencing

group frequencies –quantitative studies.

Mass Spectrometry: Principle –type of ions –base peak – parent ion, metastable and

isotopic peaks –nitrogen rule– fragmentation- general rules-pattern of fragmentation for

compounds such as hydrocarbons, amines, alcohols, ketones, acids, phenols and nitro

compounds – McLafferty rearrangement – Retro Diels –Alder reaction.

UNIT :II 1H NMR spectroscopy: Origin of NMR spectra – chemical shift – Chemical shift

parameters, Internal standards , Factors affecting chemical shifts, Anisotropic effect – spin-

spin coupling – coupling constant – first and second order spectra – spin-spin splitting –

influence of stereochemical factors on chemical shift of protons – simplification of complex

spectra – deuterium substitution – spin decoupling –double resonance –Spin decopling and

spin tickling - shift reagents - Lanthanide shift Reagents , Chiral resolving reagents - nuclear

overhauser Effect – CIDNP – NMR concept of aromaticity.

Unit: III 13

C NMR spectroscopy: Natural abundance –H decoupling- Off-resonance

decoupling –line intensities–chemical shift equivalence-elementary study of alpha, beta and

SRNMC Syllabus

gamma effects-hybridisation of carbon- calculation of chemical shifts for aromatic and

aliphatic compounds ,DEPT 13

C spectra -13

C correlation spectroscopy- COSY, HETCOR,

NOESY and Inadequate.

Application: Application of Spectral studies to characterize the organic compounds

UNIT: IV Chiral, optical techniques and vitamins:

ORD and CD-principle-Cotton effect-type of ORD curves-α-haloketone rule-octant

rule-applications to determine the configuration and conformation of simple monocyclic and

bicyclic ketones-comparison of ORD and CD.

Vitamins : Introduction,classification - Structure and synthesis of vitamins

A,B1,B2,B6,C, D2 and H

UNIT : V Steroids and Alkaloids

Steroids: Classification – complete chemistry and stereochemistry of cholesterol,

male sex harmones – androsterone and testosterone – female sex harmones –

oestrone,equilenin, progesterone and lanosterol

Alkaloids: General methods of structural determination – Hofmann, Emde and Von

Braun degradations. Structure and synthesis of quinine, morphine(synthesis not required),

lysergic acid and reserpine.

Text books

Text Book- 1

Title of the book : Organic Spectroscopy Principles and application,

Name of the Author : Jag Mohan

Publisher : Narosa publishing house

Edition/Year : 2/2004,

Text Book- 2

Title of the book : The Chemistry of Organic Natural Products

Name of the Author : Gurdeep Chatwal- Vol II

Publisher : Himalaya publishing House Mumbai.


Text Book- 3





Text Book- 4

Title of the book : Chemistry of Organic Natural Products

Name of the Author : Gurdeep Chatwal- Vol I

Publisher : Himalaya publishing House Mumbai.



Chapter 2 (Page no. 18 - 51, 28-95)

Chapter 3 (Page no. 119-124,137-154)

Chapter 5 (Page no. 340-341,358-374)

SRNMC Syllabus


Chapter 4 (Page no. 187- 197,203 – 256, 269 – 288, 296 - 306)


Chapter 4 (Page no.307 - 326)

Unit-IV (From Text Book-1) Chapter 6 (Page no.473-481)

Chapter 5 (Page no.440-445,457-460)




Chapter 17 (Page No. 843-845,848-851,855-862)


Chapter 1 (Page No.8-9, 99-109,132-142, 146-158)


Chapter 4(Page no.327-361,385-413,418,419-422)

(From Text Book-4)

Chapter 3(Page no.3.1-3.4, 3.6-3.17, 3.66-3.76, 3.89-3.97, 3.109-3.117, 3.123-3.126)

Reference Books

Reference Book-1

Title of the book : Application of Absorption Spectroscopy

Name of the Author : John R.Dyer,

Publisher : Prentice-Hall

Edition/Year : 1987

Reference Book-2

Title of the book : Organic Spectroscopy,

Name of the Author : William Kemp,



Reference Book-3

Title of the book : Spectrometric Identification of Organic Compounds

Name of the Author : Robert M. Silverstein, Francis Webster

Publisher : John Wiley &Sons Ind


Reference Book-4

Title of the book : The Chemistry of Steroids ,

Name of the Author : W.Klyne

Publisher : Reinhold

Edition/Year : 1953

Reference Book-5

Title of the book : ORD and CD in Chemistry and Biochemistry

Name of the Author : P. Crabbe

Publisher : Academic Press,

Edition/Year : 1972

Prepared by :

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SYLLABUS


Semester : III No. of Hours allotted : 6 / week

Subject : Paper -XII No of Credits : 5

Title of the Paper : INORGANIC CHEMISTRY III

INORGANIC SPECTROSCOPY AND NANOCHEMISTRY

Objectives:


to have an in depth study of spectral applications to the structural elucidation of

inorganic compounds.

to have an exposure to the nano technology

to understand the concept of molecular rearrangements reaction in coordination

complexes.

Unit : I Electronic Spectra of Transition Metal Complexes and Photochemistry:

d-d transition- charge transfer transition.-selection rules – mechanism of

breakdown of selection rules- bandwidths and shapes- Jahn Teller effect –Orgel diagram –

Tanabo - sugano diagram- evaluation of 10Dq and β for octahedral and tetrahedral complexes

of d2,d

3,d

7 and d

8 configurations-photochemistry – photo redox and substitution reactions in

Co(III) and Cr(III) complexes.

Unit : II Application of Spectroscopy to the Study of Inorganic Compounds:

Mossbauer Spectroscopy:

Mossbauer effect- resonance absorption-Doppler effect-Doppler velocity –isomer

shift-magnetic hyperfine splitting-application of Mossbauer spectroscopy in the study of iron

and tin complexes.

NMR Spectroscopy: 31

P,19

F and 15

N – NMR – introduction –application in structural

problem-evaluation of rate constants –monitoring the course of reaction –NMR of fluxional

molecules –NMR of paramagnetic molecules- contact shifts and shift reagents.

ESR Spectroscopy: Principle –presentation of the spectrum –hyperfine splitting- evaluation

of g values –factors affecting the magnitude of g –values-Zero field splitting –Kramer's

degeneracy---application of ESR in the study of transition of metal complex

UNIT : III Nanochemistry-I

Basic idea of nanoscience–Dimensional control in nano structures-,1D,2D and 3D

nano structures , synthesis of nano materials -chemical method, sol gel -Chemical vapour

deposition- Ball milling-plasma Arcing- electrodeposition- Thermolysis

SRNMC Syllabus

Applications of nano materials- Insulation material-machine tools-high power

magnets-motor vehicle and Aircrafts

UNIT : IV Nanochemistry-II

Carbon nanotubes: structure and characterization of single walled carbon nano

tubes-properties and applications of nano tubes.

Nano Shells: Introduction-types - properites and applications (Ion slective film gold

nanoshell for Blood Immunoassay and cancer Detection and thearpy,Gold nanoshells for

enhancing the Raman scattering.)

Nano polymers: Conductive polymer and Block copolymer.

Future applications: Microelectro mechanical system-Robot-Ageless material-NP coating-

Environmental applications.

UNIT :V Molecular Rearrangements and Reaction of Coordinated Ligands:

Molecular rearrangement of four coordinated complex- six coordinated

complexes-reaction at coordinated ligands- reaction due to metal ion polarization of

coordinated ligands-hydrolysis of amino acid ester and amides and of peptides- Aldol

condensation-imine formation, hydrolysis and substituent exchange – the template effect and

macro cyclic ligands.

Text books

Text Book- 1



Publisher : Milestone Publishers , New Delhi


Text Book- 2

Title of the book : Introduction to Nanotechnology

Name of the Author : Charles P.Poolee Jr. and Franck Owens,

Publisher : John-Wiley and Sons


Text Book- 3



Publisher : Tata Mc Graw-Hill Education,Delhi.


Text Book- 4

Title of the book : NanoTechnology


Publisher : Overseas Press India Private Limited


Text Book-5

Title of the book : An Introduction to Inorganic Chemistry.

Name of the Author : K.F. Purcell and J.C Koltz ,

Publisher : W.B Saunders company,


SRNMC Syllabus

Text Book-6

Title of the book : .Spectroscopy

Name of the Author : B.K Sharma

Publisher : Geol Publishing House, Meerut



Chapter 29 (Page No 822 to 838,872 to 876)


Chapter 14 (Page No 737 to761)




Chapter 5 and 11 (5.4.1 to 5.4.5, 5.5.1 to 5.5.6 , 11.4.1 )

(From Text Book -3)


(From Text Book -4)

Chapter 9 (9.1 to 9.9)

Unit V (From Text Book -5)

Chapter (Page No 757 to 791)

Reference Books

Reference Book-1





Reference Book-2

Title of the book : Physical Methods in Chemistry

Name of the Author : R.S.Drago

Publisher : W.B.Saunder company, London


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SYLLABUS

Programme : M.Sc. Chemistry Subject Code :


Subject : Core Paper XIII No. of Credits : 5

Title of the Paper : PHYSICAL CHEMISTRY – III

GROUP THEORY AND MOLECULAR SPECTROSCOPY

Objectives

To enable the learners to

To have an idea of symmetries of molecules and their fundamental concepts.

To apply the group theory to spectroscopy and molecular problems.

To get an insight into the principles of molecular spectroscopy.

To get a clear idea about various spectroscopic technique and their applications.

UNIT-I Group Theory

Molecular symmetry elements and symmetry operations. Matrix algebra- types of

matrices, matrix representation for symmetry operations (E,Cn,Sn,i, σ) and transformation

matrices. Group-definition and properties of a group, subgroup, isomorphic group and

classes. Group multiplication table for c2v and c3v point groups . Representation of a group -

reducible and irreducible representations.

Great Orthogonality theorem. construction of a character tables-C2V, C3V , C4V, C2h

and D2d. Standard reduction formula. Direct product – definition and its applications.

UNIT-II Application of Group Theory to Spectroscopy and Molecular Problems

Definition of molecular vibration, symmetry of normal mode analysis to

water,formaldehyde, ammonia, trans-N2F2 and ethylene molecule.Selection rules for IR and

Raman spectra.Selection rules for electronic transition in simple molecules like ethylene,

formaldehyde and benzene.

Group theory applied to hybridization (BCl3,PCl5 and CH4) .Simplication for

molecular orbital calculation- SALC procedure - HMO theory and delocalisation energy for

cyclopropenyl,butadiene and benzene systems.

UNIT-III Molecular Spectroscopy-I

Electromagnetic spectrum. Types of molecular energies. Absorption and emission of

radiation. Einstein’s coefficient-induced emission and absorption. Rotational spectra of rigid

diatomic molecules-isotope effect in rotational spectra. Informations derived from rotational

spectra.

Infrared spectroscopy. Vibrational energy of diatomic molecule-infrared selection

rules-diatomic vibrating rotator. Vibrations of polyatomic molecules - overtone, combination

and difference bands. Concept of group frequencies - coupling interaction. Fermi resonance-

Fourier transforms infrared spectroscopy.

SRNMC Syllabus

UNIT-IV Molecular Spectroscopy-II

Raman spectroscopy. Theories of Raman scattering Rotational and vibrational Raman

spectra. Mutual exclusion principle. Laser Raman spectra. Electronic spectra of diatomic and

polyatomic molecules. Intensity of vibrational electronic spectra - Franck Condon principle -

rotational fine structure of electronic vibrational spectra. Fortrat parabola. Dissociation and

predissociation spectra.

NQR : Principles and applications –quadruple moment and electrical field, nuclear

quadruple resonance, nuclear quadruple coupling in atoms and molecules. Identification of

ionic character and hybridization.

UNIT-V Spin Resonance Spectroscopy

NMR : Magnetic properties of nuclei. Resonance condition - NMR instrumentation -

Relaxation processes - chemical shift – spin-spin splitting, relaxation times, line shape and

line width experimental techniques - double resonance technique, ENDOR, Nuclear

Overhauser effect, FT-NMR spectroscopy. Lanthanide shift reagents.

ESR : principles of ESR –Hyperfine structure-ESR spectra of free radicals in solution

–Anisotropic systems. Systems in triplet state - Zero field splitting in ESR and Krammer’s

degeneracy.

Text books

Text Book- 1

Title of the book : Symmetry and spectroscopy of molecules

Name of the Author : K. Veera Reeddy

Publisher : New Age International Publishers


Text Book- 2

Title of the book : Group Theory in Chemistry

Name of the Author : V.Ramakrishnan and M.S. Gopinathan

Publisher : Vishal Publications


Text Book- 3

Title of the book : Fundamentals of molecular spectroscopy

Name of the Author : Colin N. Banwell and Elaine M.McCash

Publisher : Tata McGraw- Hill Publishing Company Limited


Text Book- 4

Title of the book : Instrumental methods of chemical analysis

Name of the Author : Gurdeep R. Chatwal



Unit I (From Text book 1)





SRNMC Syllabus

Unit II (From Text book 1)


(From Text Book 2)


Unit III & IV (From Text book 3)

Chapter-2&3(Page No. 31-98)


(From Text book 4)

Chapter-4(Page No. 2.83-2.99)

Unit V (From Text book 3)

Chapter-7 (Page No. 199-219)

(From Text book 4)



Reference Books

Reference Book-1

Title of the book : Group Theory and its applications to chemistry

Name of the Author : K.V.Raman

Publisher : Tata McGraw- Hill Publishing company limited


Reference Book-2

Title of the book : Chemical applications of Group Theory

Name of the Author : F.A. Cotton

Publisher : John Wiley & Sons,New york


Reference Book-3

Title of the book : A Simple approach to group theory in chemistry

Name of the Author : S. Swarnalakshmi,T. Saroja,R.M.Ezhilarasi

Publisher : Universities Press Private Ltd


Reference Book-4

Title of the book : Molecular structure and spectroscopy

Name of the Author : G.Aruldhas

Publisher : PHI Learning (P) Limited, New Delhi


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Subject : Paper XIV - Major Elective III (a) No of Credits : 4

Title of the Paper : COMPUTER APPLICATIONS

Objectives:

To study the basic concepts of VB and its application in chemistry.

To know about basic concepts of internet.

UNIT: 1 Basic Concept of VB

Introduction to visual basic-the integrated development environment-the menu bar,tool

bar,the project explorer,the tool box,the properties of window,the form designer,the form lay

out,the immediate window,the elements of the interface-programming an application

common properties,common methods and common events-customising the environment.

Working with Forms: The appearance of form – the start up form – loading, showing

and hiding forms – elementary concepts of drag and drop operations.

Basic active X controls : Elementary concepts of Text Box control, the List Box and

ComboBox controls.

Variables – declaring variables – variable types – strings, numeric and data variables-

scope and life forms of variables – constants.

UNIT: II The Language Forms And Basic Active Controls

Control flow statements: If… Then and If… Then…Else. Loop statements: DO…

Loop, For…Next and While – Wend – nested control statement – the Exit statement. Arrays:

Declaring arrays – specifying arrays – multi dimensional arrays. Procedures: Subroutines,

functions, calling procedures – arrangements – arguments passing mechanism – using

optional arguments – functions returning arrays.

UNIT:III Applications of VB in Chemistry

Writing Simple programs in Chemistry :

1. Calculation of molecular weight of organic compound,

2. Ionic strength of an electrolyte,

3. Different velocities of a gas,

4. NMR frequency values of nuclei,

5. Average rate constant,

6. Unit cell dimensions,

7. Thermodynamic parameters,

8. Reduced mass,

SRNMC Syllabus

9. Empirical formula of an organic compound containing C,H and O,

10. Normality, molality and molarity of a solution,

11. Half life period of a radioactive material,

12. Surface tension and

13. Temperature in Kelvin scale into Celsius and vice-versa.

Practical : (Class work only)

Construcion of programs in VB language, compiling, debugging and making

executive files, printing the output.

Running Simple VB programs in Chemistry to calculate/ determine the above

problems.

UNIT: IV Basic Concepts Of Communications Systems

Communication systems: Satellites – RADAR – optical fibers – advantages and

disadvantages – ISDN – distributed systems – advantages and disadvantages.

Telecommunications: analog and digital signals – types and needs of modulations –

MODEMS – Telecommunication software.

Computer networks: An overview – communication processors – protocols –

network architecture.

Practicals (Class work only)

1. Salient features of Windows and MS Word for typing texts and equations in Chemistry

– tabular columns – advanced concepts.

2. Basic concept of creating and accessing databases using MS Access.

3. Significance of Chemdraw – drawing chemical structures and pasting them in the text.

UNIT : V Basic Concepts of Internet and Applications in Chemistry

Internet: History of internet – the working way of internet – getting connected to internet –

internet protocols – internet addressing –domain names- internet services.

www: Web Pages – home Pages – web browsers – search engines – internet chat – chatting

on web.

E-mail : Introduction – working way – mailing basics – e-mail ethics – advantages and

disadvantages – creating e-mail – receiving and sending e-mails.

Internet : characterisation – advantages – drawbacks – need for internet – extranet.

Applications of internet in Chemistry : Websites in Literature survey in chemistry

– popular websites in chemistry – data bases in chemistry - URLS – WAIS – downloading

the attachment / PDF files – opening ,browsing and searching a website literature searching

online.

Practicals (Class work only) :

1. Creating e-mail id,sending and receiving e- mail, attachment files, PDF files.Opening,

browsing and searching a website – down loading– literature survey in chemistry –

online searching.

Unit I To V: Study material will be provided

SRNMC Syllabus

Reference Books

Reference Book-1

Title of the book : Mastering Visual Basic 6

Name of the Author : Evangelos Petroutsos

Publisher : BPB Publication


Reference Book-2

Title of the book : Visual Basic 6 Super Bible

Name of the Author : David Jung, Pierre Boutqukin, John D. Conley III, Loren Eidahl

Publisher : First Indian Edition, Techmedia, New Delhi, 1999.


Reference Book-3

Title of the book : Visual Basic 6.

Name of the Author : Gary Cornell,

Publisher : Tata-McGraw Hill, New Delhi

Edition/Year : 1998

Prepared by :

Signature :

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SYLLABUS


Semester : III No. of Hours allotted : 6/week

Subject : Paper XIV Major Elective III- (b) No of Credits : 4

Title of the Paper : ENVIRONMENTAL CHEMISTRY

Objectives:

To learn about pollutions and its types.

To know the sources and control measures of various pollution.

UNIT: I Introduction and Classification

Introduction –Environmental science-Environmental chemistry-Ecology-

Definition-Eco-System-Cycling of minerals elements and gases –Phosphate cycle- Carbon

cycle- -Nitrogen Cycle-Hydrological cycle-Environment segments- pollution and its types:

Air pollution- water pollution- soil pollution- radioactive pollution-thermal pollution-noise

pollution- marine pollution- and its effects and control- remedial measures.

UNIT: II Analysis of Pollutant

Neutron Activation Analysis-Anodic Stripping Voltametry-Atomic Absorption

Spectrophotometry-X-Ray Florescence-non-dispersive Infrared spectrometry-Fourier

transform Infrared spectroscopy- chemiluminescence-gas chromatography-High performance

Liquid chromatography-Iom selective Electrode.

UNIT: III Air Pollution

Introduction – sources of air pollution – air pollutants – classification and effects of air

pollutants – oxides of nitrogen,sulphur and carbon- acid rain-effects and control-hydrogen

sulphide – effects and control- carbon mono oxide – effects and control- photochemical smog

– effects and control – fly ash – effects and control – green house effect – global warming –

effects and control – ozone layer – ozone depletion – cholorofluoro carbons – effects and

control.

UNIT : IV Soil Pollution

Introduction –types of soil – soil pollution types – sources of soil pollution-

fertilizers and pesticides – radioactive pollutants – soil wastes – soil sediments as pollutant-

indicators of soil pollution – soil erosion – treatment of soil pollutants – treatment of solid

wastes – thermal methods – land filling – composting – land protection – remedial measures

for soil pollution

UNIT : V Industrial pollution & Chemical Toxicology

Introduction-causes of industrial pollution–thermal power plants-nuclear power

reactors-fertilizers and chemical industry-pulp and paper industries – agro based industries-

cement industry. Toxic chemicals in the environment – biochemical effects of arsenic,

cadmium, lead, mercury and cyanide- bio-ware agents.

SRNMC Syllabus

Text books

Text Book- 1

Title of the book : Environmental Chemistry,

Name of the Author : A.K De,

Publisher : New age International Pvt.Ltd.,Delhi


Text Book- 2

Title of the book : Environmental chemistry

Name of the Author : B.K.Sharma

Publisher : Goel Publishing House




Unit II (From Text book -1)


Unit III (From Text book -2)

Chapter 4 &5 (Page No 69-129)

Unit- IV (From Text Book-2)

Chapter -1 (Page No. 33-34)

Chapter -2(Page No 47-55,62-64)

Chapter-3 (Page No 75-80)

Unit V (From text book -1) Chapter 9 (Page No 110-120,122 -124,129, 130)

Reference Book

Title of the book : Environmental Chemistry,

Name of the Author : B.K Sharma and H.Kaur,

Publisher : Krishna Prakashan, Meerut

Edition/Year : /1997

Prepared by :

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Subject : Paper XV PRACTICAL III No of Credits : 4

Title of the Paper : CONDUCTOMETRIC, POTENTIOMETRIC TITRATIONS,

KINETICS AND ADSORPTION

Objectives:

To know about the practical applications of conductometry.

To appreciate the application of potentiometric technique in the quantitative analysis.

To understand the concepts of adsorption and Chemical kinetics by carrying out

experiments.

I. Conductometric Experiments

i. Double displacement & acid base titrations

a) NH4Cl-NaOH-Mixture of CH3COOH &HCl.

b) NH4Cl- NaOH- Mixture of NH4Cl &HCl.

ii.Precipitation tiltration

a) Na2CO3-Pb(NO3)2 – Na2CO3

b) b) K2SO4 – BaCl2 – K2SO4.

iii. Determination of dissociation constant of weak acids.

II Adsorption Experiments

Adsorption of oxalic acid/ Acetic acid on charcoal.

III Kinetic Experiments

i. Kinetics of alkaline hydrolysis of ester by conductometric method

ii. Perdisulphate and iodide ion reaction: Study of primary salt effect and

determination of concentration of given KNO3.

IV Potentiometric methods

i. Precipitation titration : Ag vs halide mixture

ii. Redox titrations : a)permanganate vs iodide ion

b)ceric ammonium sulphate vs ferrous ion

iii. Determination of dissociation constant of weak acids and pH of

buffer solutions

iii. Determination of solubility product of sparingly soluble salts.

SRNMC Syllabus

Reference Books:

Reference Book-1

Title of the book : Advanced Practical Physical Chemistry

Name of the Author : J.B. Yadav

Publisher : Goel Publications, Meerut


Reference Book-2

Title of the book : Practical physical Chemistry

Name of the Author : B.Viswanathan

Publisher : Vivas Book private limited


Prepared by :

Signature :

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SYLLABUS


Semester : IV No. of Hours allotted : 6/week

Subject : Paper XVI No of Credits : 5

Title of the Paper : ORGANIC CHEMISTRY -IV

BIOMOLECULES, REARRANGEMENTS AND SYNTHETIC METHODS

Objectives:

To know about the chemistry of carbohydrates and proteins and terpenoids.

To understanding the fundamental concept of photochemistry and free radicals

To know about the various types of molecular rearrangements

To get insight into the principle of green chemistry

To know the synthetic utility of reagents

UNIT: I Carbohydrates, Amino Acids, Proteins & Terpenoids:

Carbohydrates: Methods used for determination of ring size – structure elucidation of

maltose, lactose and cellobiose - A brief study of starch and cellulose(structure only)

Amino Acids and Proteins: Aminoacids - Peptides - Classification of proteins –

denaturation – structure of (primary, secondary, tertiary and quaternary) peptides– Chemistry

of glutathione and oxytocin

Terpenoids: Classification of terpenoids – structure , stereochemistry and synthesis

of α- pinene, zingiberene and squalene.

UNIT :II Photochemistry, Pericyclic Reactions & Free Radicals

Basic principles of photochemistry-Jablonskii diagram –Norrish- I and Norrish-II type

reactions – Paterno-buchi reaction – photochemistry of olefins and dienes –cis, trans

isomersisation - photosensitization - photoreduction.

Pericyclic reactions:Conservation of orbital symmetry – electrocyclic reactions –

cyclo addition reactions and sigmatropic rearrangements –applications of correlation diagram

approach(butadiene and hexatriene), Frontier molecular approach, Huckel-Mobius approach

to the above reactions.

Free radicals: Formation, detection and stability of free radicals – free radical

reactions – halogenation, addition, oxidation, reduction and rearrangement reactions –

Barton, Sandmeyer, Gomberg, Bachmann, Ullmann, Pschorr and Hundsdiecker reactions.

UNIT :III Molecular Rearrangements

Mechanism of the following rearrangement reactions: Wagner – Meerwein,Pinacol,

Demjanov, Beckmann, Hofmann, Curtius, Wolff, Baeyer-Villeger, Stevens, Sommelet-

SRNMC Syllabus

Hauser, Favorskii, Benzil-benzilic acid, Claisen, Cope, Fries, Dienone-phenol and Benzidine

rearrangement, Photo Fries rearrangements.

UNIT :IV Green Chemistry

Twelve basic principles of green chemistry, atom economy, planning a green

synthesis(green starting materials,green catalyst(any two)and reagents (any two),green

solvents –applications of supercritical fluids ,ionic liquids and water – solvent free

techniques-Phase transfer catalyst and its application in green synthesis(any three).

Non-conventional microwave heating -interaction of microwave radiation with the material-

difference between conventional heating and microwave heating. -applications and

advantages of microwave heating over conventional heating.

UNIT: V Planning synthesis and Synthetic Methods

Planning a synthesis-Relay approach and convergent approach to total synthesis-Retro

synthetic analysis of simple organic compounds-functional group inter conversions-use of

activating and blocking groups in synthesis-stereo selective problems of geometrical and

optical isomerism-steric crowding-Transition metal complexes in organic chemistry-

Homogeneous hydrogenation-Regioselectivity-Diastereoselectivity-Enantioselectivity-

Umpolung synthesis-Robinson annelation –A schematic analysis of the total synthesis of the

following compounds: trans -9-methyl -1-decalone and 2,4- dimethyl-2-hydroxy pentanoic

acid, Isonootkatone

Text books

Text Book- 1

Title of the book : Organic chemistry of Natural products vol I

Name of the Author : Gurdeep R.chatwal

Publisher : Himalaya publishing housing,Mumbai.


Text Book- 2

Title of the book : Reaction Mechanism in Organic Chemistry,

Name of the Author : S.M .Mukherji and Singh

Publisher : Macmillan India Ltd


Text Book- 3

Title of the book : New trends in Green chemistry,

Name of the Author : V.K Ahluwalia ,and M.Kidwai,

Publisher : Anamaya publishing house, New Delhi.

Edition/Year : 2004

Text Book- 4

Title of the book : Organic Synthesis,

Name of the Author : R.E. Ireland,

Publisher : Prentice-Hall of India Pvt. Ltd ,


SRNMC Syllabus

Text book-5





Text Book- 6

Title of the book : Organic chemistry of Natural products vol II

Name of the Author : Gurdeep R.chatwal

Publisher : Himalaya publishing housing,Mumbai.


Unit-I (From Text Book-1) Chapter 1 (Page No 1.46 to 1.53, 1.115 to1.123)

Chapter 2 (Page No 2.62 to 2.93, 2.98 to 2.101)

(From Text Book-6) Chapter 1(Page No. 1.92 – 1.98, 1.128 -1.132, 1.147 -1.152)

(From text book –5) Chapter 7 (Page No328-333)


Chapter 17 (Page No. 843-845,848-851,855-862)





Chapter 18(Page No 1072-77, 1080-83, 1090-92, 1095-1140)

Unit-IV (From Text Book-3) Chapter 1&2 (Page No 1-4)






Unit-V (From Text Book-4) Chapter 2 (Page No 17-52)

Chapter 4 (Page No 55-56,81-87)

Reference Books

Reference Book-1

Title of the book : Organic Chemistry,Vol II ,




Reference Book-2

Title of the book : Green Chemistry(Environmental Friendly Alternatives)

Name of the Author : R.Sanghi and M.M. Srivastava,

Publisher : Narosa publishing House, New Delhi.


Reference Book-3

Title of the book : An introduction to Green Chemistry

Name of the Author : V.Kumar,

Publisher : Vishal publishing Co, New Delhi.

SRNMC Syllabus


Reference Book-4

Title of the book : Photochemistry and Pericyclic Reactions

Name of the Author : Jagdamba Singh and Jayasingh

Publisher : New age international (p) limited, New Delhi.


Reference Book - 5

Title of the book : Advanced Organic Chemistry,.


Publisher : John Wiley and Sons,


Prepared by :

Signature :

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SYLLABUS


Semester : IV No. of Hours allotted : 6 / week

Subject : Core Paper XVII No of Credits : 5

Title of the Paper : INORGANIC CHEMISTRY -IV

NUCLEAR AND ORGANOMETALLIC CHEMISTRY

Objectives:


to have a complete study of f-block elements.

to have an idea about various analytical techniques.

to learn principles and applications in nuclear chemistry.

Unit : I Structure of Nucleus and Radioactive Decay

Composition of the nucleus –nuclear Size, shape and density-Priniciple, radial

and magnetic quantum number’s-nuclear configuration-parity and its conservation-mass

defect and binding energy

Radioactive decay: Group displacement law –decay series –rate of disintegration -half life-

average life – secular and transient equilibria-theories of alpha decay, beta decay, gamma

emission, internal conversion and electron capture-Auger effect.

Unit : II Nuclear Fission and Fusion and Application of Radioactive Isotopes:

Bethe's notation of nuclear process - nuclear reaction energies (Q-values)-fission-

energy release in nuclear fission-mass distribution of fission products-theory of nuclear

fission-fissile and fertile isotopes –energy from nuclear fusion-thermonuclear reaction in

stars- Nuclear reactor--breeder reactor- waste disposal management.

Applications of radioactive isotopes: - chemical investigations-age determination-medical

field-agriculture-- analytical techniques.-biological effects of radiations.

Unit :III Actinides and Lanthanides: Chemistry of Lanthanides and Actinides;

Lanthanides –occurrence, extraction from monazite separation procedure - ion

exchange method - solvent extraction method. Physical and chemical properties-Electronic

configuration- common oxidation state-lanthanide contraction and its consequences-color of

lanthanides ions-magnetic properties of lanthanides-separation of actinide elements-

separation of Pu from fission products-electronic configuration- oxidation state-comparison

of lanthanides and actinides-position in the periodic table

SRNMC Syllabus

Unit :IV Electroanalytical and Spectra Analytical Methods:

Electro analytical Techniques:

Electrogravimetry: Theory of electrogravimetric analysis-electrolytic separation

and determination of metal ions. Coulometry- coulometric titrations. Voltametry: cyclic

voltammetry--Amperometry: Amperometric titrations.

Thermoanalytical Methods: Instrumentation and applications of thermogravimetry-

Differential Thermal Analysis and Differential Scanning calorimetry

Spectroanalytical Method: principle and applications of - Fluorimetry- nepheometry and

turbidimetry- and flame photometry –atomic absorptions spectroscopy and atomic

fluorescence spectroscopy.

Unit – V

Complexes of п- acceptor ligands:

Synthesis, structure and bonding in metal carbonyls, nitrosyls – Application of EAN

rule. Synthesis, properties, structure and bonding in Ferrocene, . Olefin and acetylene

complexes.

Catalysis using organometallic compounds

Oxidative addition – reductive elimination – insertion reaction Catalytic mechanism in

the following reactions :hydrogenation of olefins (Willkinson catalyst) - hydroformylation

(Oxoprocess) – acetic acid from ethanol – oxidation of alkenes to aldehydes and Ketones

(Wacker process) – olefin polymerization (Ziegler – Natta) – Cyclooligomerisation of

acetylenes (Reppe’s or Wilke’s catalysts) Olefin isomerisation using Ni Catalyst.

Text books

Text Book- 1

Title of the book : Essential of Nuclear Chemistry

Name of the Author : H.I .Arnikar

Publisher : Wiley Eastern Ltd.,New Delhi


Text Book- 2

Title of the book : Nuclear Chemistry

Name of the Author : U.N.Dash

Publisher : Sultan Chand and Sons, New Delhi

Edition/Year : I/1991

Text Book- 3


Name of the Author : Wahid U.Malik ,Tuli, Madan



Text Book- 4

Title of the book : Instrumental Methods of chemical Analysis

Name of the Author : Gurdeep R.Chatwal



Text Book- 5

Title of the book : Advanced Inorganic Chemistry Vol II

Name of the Author : Satya Prakash

Publisher : S.Chand & Company Ltd


SRNMC Syllabus

Text Book- 6

Title of the book : Concise Co-ordination Chemistry,

Name of the Author : R.Gopalan and V.Ramalingam,

Publisher : Vikas Publishing House Pvt Ltd


Unit I From Text book-2)

Chapter - 1(Section 1.5 to 1.6.4, 1.8.1, 1.8.2)

Chapter - 3 (Section 3.2 to3.3, 3.6.1, 3.6.2,)

Chapter - 5 (Page no 195 to 201,214 to 227)

Unit II (From Text book -1)

Chapter 5(Section 5.1 to 5.2.6, 5.7 to 5.7.3, 5.9 ,5.10)

Chapter 6 (Section6.2 ,6.3 6.9)

Chapter 7 (Section 7.8.1 ,7.11)

Chapter 10 (Section 10.7.1.10.7.3 to 10.7.6)


Chapter 9 and 10 (274 to 331)


Chapter 26 to29 (Page No 2.523 to 2.549)

Chapter 41 (Page No 2.701 ,2.719 to 2.738)

Chapter 13 to 16 (Page No 2.340 to 2.415)



(From Text Book-6)


Reference Books

Reference Book-1

Title of the book : Source Book on Atomic Energy

Name of the Author : S.Glasstone,

Publisher : Van Nostrand Reinhold Company, New York


Reference Book-2

Title of the book : Fundamentals of Analytical Chemistry,

Name of the Author : D.A .Skoog and D.M. West

Publisher : Harcourt college Publishers Philadelphia


Reference Book-3

Title of the book : Instrumental Methods of Analysis

Name of the Author : H.H..Willard, LL.Merritt and J.A.Dean,

Publisher : East- West press., New Delhi

Edition/Year : /1988

Reference Book-4

Title of the book : Analytical Chemistry –Instrumental Techniques

Name of the Author : Mahinder Singh

Publisher : Dominant Publisher and Distributors, New Delhi


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SRNMC Syllabus

SRI S.RAMASAMY NAIDU MEMORIAL COLLEGE (An Autonomous Institution Re-accredited with ‘A’ Grade by NAAC)

SATTUR-626 203.



SYLLABUS



Subject : Core Paper XVIII No. of Credits : 5

Title of the Paper : PHYSICAL CHEMISTRY -IV CHEMICAL KINETICS, SURFACE AND PHOTOCHEMISTRY

Objectives:

To get themselves exposed to kinetics and mechanism.

To derive advance knowledge on solids and surface phenomena.

To learn concepts of non-equilibrium thermodynamics and bio-energetic.

To understand the fundamental concepts of photochemistry.

UNIT - I Chemical Kinetics I:

Collision theory, ARR theory, Chain reactions – general characteristics. Potential

energy surfaces. study of kinetics of chain reactions like H2-Br2 reaction, decomposition of

acetaldehyde and N2O5. Study of H2-O2 explosive reactions.

Unimolecular reaction rate theories – the simple Lindemann treatment,

Hishelwood’s theory, Rice, Ramsperger and Kassel(RRK) theory, Marcus theory or Rice,

Ramsperger, Kassel and Marcus (RRKM) theory, Slater’s theory. Principle of microscopic

reversibility and detailed balancing, Kinetic isotope effect. Reactions in solution – influence

of solvent dielectric constant, ionic strength (Bronsted- Bjerrum equation – primary and

secondary salt effects) and volume of activation.

UNIT- II Chemical Kinetics II

Fast reactions techniques – chemical relaxation methods, temperature and pressure

jump methods, ultrasonic absorption technique, reactions in flow system, continuous and

stopped flow, shock wave tube methods; chemical kinetics in crossed molecular beams, Flash

photolysis. Application of nmr and esr in the study of reaction kinetics.

UNIT - III Surface Chemistry

Introduction- adsorption of gases on solids- physisorption and chemisorptions,

adsorption isotherms- Freundlich, Langmuir, BET, and Temkin adsorption isotherms –

Surface tension-Gibbs adsorption isotherm-surface area determination–monolayer-

preparation of LB films – micelles - critical micellar concentration (CMC)-structure- reverse

micelles-micro emulsion. Application of photoelectron spectroscopy to the study of surface

reactions.

SRNMC Syllabus

UNIT - IV Biophysical Chemistry

Basic concept of non-equilibrium thermodynamics, Onsager reciprocal relationship

– Its application to biological systems. High energy metabolites – ATP and its role in

bioenergetic, transfer of potential and coupled reaction. Biological energy conversion in

catabolism and anabolism – Biophysical applications of Mossbauer effect, NMR imaging.

Applications of spin labeling in membrane research – Molecular recognition . An

introduction to supramolecular chemistry.

UNIT - V Photo- and Radiation Chemistry :

Physical properties of the electronically excited molecules – excited state dipole

moments, pKa and redox potentials –photo physical processes in electronically excited

molecules – Fluorescence, phosphorescence and other deactivating processes. Stern - Volmer

equation and its applications – electronic energy transfer mechanisms – photosensitization

and chemiluminescence, Experimental techniques in photochemistry – light sources –

chemical actinometry – elementary aspects of photosynthesis, photochemical conversion and

storage of solar energy. Radiation chemistry – source of high energy – interaction of high

energy radiation with matter – radiolysis of water -- mode of reactions of hydrated electrons –

OH and H. Experimental techniques of radiation chemistry- Dosimeter .

Text books

Text Book- 1

Title of the book : Chemical Kinetics

Name of the Author : K.J.Laidler

Publisher : Pearson Education Private Ltd, Delhi


Text Book- 2

Title of the book : Fast Reactions

Name of the Author : J.N.Bradley

Publisher : Clarendon Press Oxford

Edition/Year : 1975

Text Book- 3



Publisher : Goel Publishing Co,Meerut.


Text Book- 4

Title of the book : Fundamentals of Biochemistry

Name of the Author : J.N.Jain

Publisher : S.Chand & Company Ltd, New Delhi

Edition/year : 6 / 2005

Text Book- 5

Title of the book : Fundamentals of Photochemisty

Name of the Author : K.K. Rohatgi Mukherjee

Publisher : New age International (P) Limited


Text Book- 6

Title of the book : Essential of Nuclear chemistry

Name of the Author : H.J.Arnikar

Publisher : New Age International Publishers


SRNMC Syllabus






Unit-II (From Text book-2)






Unit-III (From Text book-3)

Chapter-16(Page No. 873-880, 882-894. 905-909)

Chapter-17(Page No. 952-954, 1017-1021, 1028-1030)

Unit-IV (From Text book-4)


Unit- V (From text book -5)

Chapter - 4 (Section 4.7 to 4.9)

Chapter - 5 (Section 5.1)

Chapter - 9 (Section 9.5)

Chapter -10 (Section 10.1)

(From text book -6)

Chapter -11 (Section 11.1 to 11.7.5)

Reference Books

Reference Book-1





Reference Book-2





Reference Book-3

Title of the book : Physical chemistry on Surfaces

Name of the Author : A.W.Adamson

Publisher : John Wiley &Sons, New York


Reference Book-4

Title of the book : Principles of Biochemistry

Name of the Author : A.L.Lehninger

Publisher : CBS Publication,New Delhi

Edition/year : /1984

Reference Book-5





Prepared by :

Signature :

SRNMC Syllabus



SATTUR-626 203.



SYLLABUS



Subject : Paper XIX Major Elective IV (a) No of Credits : 4

Title of the Paper : INTRODUCTION TO NANOSCIENCE

Objectives:

To understand the basic concept of nano science.

To study the synthesis and applications of nano chemistry.

To know about the characterization of nano materials.

UNIT: I General Introduction

Forms of Matter – Crystal structures –electronic properties of atoms and solids –

surface energy and surface tension – defining nanodimensional materials – 0D, 1D and 2D

nanostructures – size dependence of properties – special properties resulting from

nanodimensionality – potential use of nanomaterials.

UNIT: II Synthesis of nanomaterials

General approaches – nucleation process – sizes of the crystal – influence of

nucleation rate on the size of the crystal – chemical methods – Sol-gel techniques – control of

grain size – Co- precipitation - hydrolysis – nonochemical method – colloidal precipitation –

bottom up and top down approaches – kinetically confined synthesis of nanoparticles.

UNIT: III Principle and Instrumentation

Spectrophotometry, XRD, EXAFS, XPS, SEM, TEM, AFM – application to

nanomaterials characterization.

UNIT: IV Optical properties of nanomaterials

UV-Vis, IR absorption - photoluminescence and stimulated emission – nonlinear

optical mixing – photo conductivity - Magnetic properties: concepts of dia-, para-, and

Ferro-magnetism – exchange correlation – exchange interaction. Electrical properties:

electrical conductivity – Hall effect – charge carrier density – activation energy; electronic

properties – field emission properties.

UNIT: V Biological nanomaterials: sizes of building blocks – proteins – DNA double

nanowire – enzymes – protein synthesis – Micelles and vesicles – Biomimetic nanostructures

– Worm micelles and Vesicles from block copolymers.

Text books

Text Book- 1

Title of the book : Introduction to Nano Technology

Name of the Author : C.P.Poole

Publisher : John Wiley & Sons,INC.


SRNMC Syllabus

Text Book- 2



Publisher : Mc Graw-Hill Education,Delhi.


Text Book- 3

Title of the book : NanoTechnology


Publisher : Oversaes India pvt Ltd



Chapter-2 (Page No. 8-21)


Chapter -3 (Page No.56-70)


Chapter -2 (15-75)

Unit-IV&V (From Text Book-1)

Chapter - 4 (80-93)

Chapter -12 (310-329)

Reference Books

Reference Book-1

Title of the book : The Chemistry of Nano Materials

Name of the Author : C.N.R.Rao

Publisher : Wiley-VCH –Verlag Gmoh and co

Edition/Year : volumes 1and 2 /1980

Prepared by :

Signature :

SRNMC Syllabus



SATTUR-626 203.



SYLLABUS



Subject : Paper XIX Major Elective IV (b) No of Credits : 4

Title of the Paper : POLYMER CHEMISTRY

Objectives:

1. To understand the chemistry of polymerization.

2. To study about the utility of polymers in various field.

3. To know about the processing of polymers.

UNIT I: Classification of Polymers and Chemistry of Polymerisation

Classification of polymers: linear polymers,non-linear or branched

polymers,cross-linked polymers, homo chain hetero chain, homopolymers co-polymers block

polymers and graft polymers.

Chemistry of polymerisation: Types of polymerization – mechanism –

chain,growth,free radical,ionic,co-ordination, ring opening, metathetical,group transfer,

polyaddition and polycondensation polymerizations.

UNIT II : Individual Polymers

Individual polymers: Monomers required general methods of preparation, repeat

units and uses of the following polymers and resins - polyethylene, polystyrene,

polyacryloniltrile, polymethylmethacrylate, PVC, polytetra-fluoroethylene, ,polybutadienes

and polychloroprene, polyesters, polycarbonates, polyimides, polyamides (Kevlar),

polyurethanes, polyethylene, glycols,phenol-formaldehyde,urea- formaldehyde,melamine-

formaldehyde and epoxy resins.

UNIT III : Properties of Polymers

Intrinsic properties – processing properties – basic idea of isomerism of polymers –

configuration of polymer chain – geometrical structure - syndiotatic, isotatic and atatic

polymers. Glass transition temperature: Definition – factors affecting glass transition

temperature – relationships between glass transition temperature and (a) molecular weight,

(b) melting point and (c) plasticizer – importance of glass transition temperature – heat

distortion temperature. Molecular weight and size of polymers: Number average, weight

average, sedimentation and viscosity average molecular weights – molecular weights and

degree of polymerisation– poly dispersity – molecular weight distribution in polymers – size

of polymer molecules – kinetics of polymerization.

UNIT IV: Polymerisation Techniques, Degradation and Uses of Polymers

Polymerisation Techniques: Bulk, solution, suspension, emulsion, melt

condensation and interfacial polycondensation polymerizations. Degradation: Types of

degradation – thermal, mechanical, ultrasonic and photodegradation – photo stabilizers –

oxidative degradation – antioxidants – hydrolytic degradation. Uses of polymers in

electronics and biomedicine.

SRNMC Syllabus

UNIT V: Polymer Processing

Polymer processing: plastics (thermo and thermosetting), elastomers, fibres,

compounding, plasticizers, colorants, flame retardants. Compression and injection mouldings

– film extrusion and calendering – die casting and rotational casting- thermofoaming –

reinforcing.

Text books

Text Book- 1

Title of the book : Polymer Science

Name of the Author : V.R.Gowarikar, N.V.Viswanathan and Jayadev Sreedher,

Publisher : Wiley Eastern Ltd., New Delhi


Text Book- 2

Title of the book : Principles of Polymer science

Name of the Author : N.V.Sastry

Publisher : Narosa Publishing House


Unit-I (From Text Book-1) Chapter 1 (Page No 12-14)





Chapter 3 (Page no 86 to 97)

Chapter 6 (Page No150 to172)

Unit-IV (From Text Book-1)

Chapter - 2 (Page no 71-85)


Chapter-15 (Page No 462-466)

(From Text Book-2)

Chapter-5 (Page No.206-219,220-235)

Reference Books

Reference Book-1

Title of the book : Text book of polymer science

Name of the Author : F.W.Billmeyar

Publisher : JohnWiley and sons,New York


Reference Book-2

Title of the book : Text book of polymer chemistry

Name of the Author : B.K.Sharma

Publisher : Goel pub,House, Meerut.

Edition/Year : 1989

Reference Book-3

Title of the book : Text book of Introductory polymer chemistry

Name of the Author : G.S.Mistra

Publisher : New Age International pub, New Delhi

Edition/Year : 2005

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Signature :

SRNMC Syllabus



SATTUR – 626 203.


(For those who are joining in 2014-2015 and after)

SYLLABUS

Programme : M. Sc., Chemistry Subject Code :

Semester : IV No. of Hours allotted : 6 / Week

Subject : Core - Paper XX No. of Credits : 4

Title of the Paper - PROJECT

Objectives:

To develop the ability of the students to prepare a project.

To get clear idea about the new concepts in our field apart from the syllabus.

Regulations for the Project Report

Evaluation method for project:

Max Marks Credits

Internal External

Project report 40 40

Viva voce 20

Total 100 4

Internal examiners are the respective supervisors.

Viva Voce examination to be evaluated by the external examiner.

The report of the project must be in the prescribed form. It should be typed neatly in MS

word with the equation editor or using Latex. The font size of the letter should be 13 or

points with double space.

The format of the project report should have the following components.

First Page should contain:

Title of the project report.

Name of the candidate

Register number.

Name of the supervisor.

Address of the institution

Month & year of submission.

SRNMC Syllabus

Contents .

Declaration by candidate

Certificate by supervisor.

Acknowledgement

Preface

Chapter 1 - Preliminaries.

Other chapters.

References.

The number of Pages in the project may be 40 to 50.

Each Page should contain atleast 18 lines.

Four copies of the project report with spiral binding should be submitted.

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