sme1- metallic materials

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      Materials and sheet2

    SMEInitiative

    Content of presentation

    " Materials properties

    " Constraints on materials

    " Surface #nis!es

    " coatings"  $oining

    " Corrosion testing

    " Mec!anical testing

    " Macroscopic e%amination

    " Microscopic e%amination

    " &on'destructive e%amination

    " (ailure analysis

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      Materials and sheet3

    SMEInitiative

    Materials Properties

    " Strengt!

    " Elastic modulus

    " (atigue

    " (racture toug!ness

    " Creep

    " Micro'yielding

    " Coe)cient of t!ermale%pansion and coe)cient ofmoisture e%pansion

    " Stress corrosion

    " Corrosion fatigue

    " *ydrogen em+rittlement

    " ,ear and fretting

    " Surface #nis!es- Anodising

    - Conversion 

    - pic.ling/etc!ing- mec!anical

    " Coatings- !ard

    - +arriers

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      Materials and sheet4

    SMEInitiative

    Metallic Materials used in space

    " 0ig!t metals1 suc! as +eryllium1 magnesium1 aluminium andtitanium and t!eir alloys

    " Steels1 suc! as lo2'alloy1 tool1 corrosion resistant1 precipitation!arda+le1 and maraging

    " &ic.el and nic.el +ase alloys1 including pure nic.el1 Monelalloys1 Inconel alloys1 and ot!er nic.el' and co+ald'+asesuperalloys

    " Refractory metals1 principally nio+ium and moly+denum

    " Copper'+ase alloys1 including pure coppers1 +eryllium coppers1

    +ron3es and +rasses" Precious metals

    " ,elding1 +ra3ing and soldering alloys

    " 4arious plating alloys

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      Materials and sheet5

    SMEInitiative

    Materials Properties cont55

    " (racture Toug!ness-  T!e fracture toug!ness is a measure of t!e

    damage tolerance of a material containing

    initial 6a2s or crac.s5 T!e fracture toug!nessin metallic materials is descri+ed +y t!e plain

    strain value of t!e critical stress intensity

    factor5 T!e fracture toug!ness depends on t!eenvironment5 7ic is t!e plain strain criticalstress intensity factor5 7iscc plain strain criticalstress intensity factor for a speci#edenvironment in 2!ic! environmentally induced

    crac. gro2t! occurs5

    " For homogeneous materials the Kic or

    Kiscc shall be measured according toECSS- Q- 70- 45.

    " Metallic materials for use in corrosiesurface enironments shall be tested for

    fracture toughness under re!resentatieconditions

     Typical su+critical crac. propagation rateversus stress intensity relations!ip5 Stressintensity 71 is de#ned as 78Aσ√9πC/;1 2!ere σ is t!e total tensile stress1 C is t!e crac. lengt!1and A and are geometrical constants

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      Materials and sheet

    SMEInitiative

    Materials Properties cont55

    " Coe)cient of t!ermal e%pansion andcoe)cient of moisture e%pansion

    -  T!e di

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      Materials and sheet!

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    Materials Properties cont55

    " Mec!anical contact surface e

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      Materials and sheet"

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    Materials Properties cont55

    " Stress Corrosion Crac.ing- Stress corrosion may+e de#ned as t!e com+ined action of sustained tensile stress and

    corrosion t!at may lead to t!e premature failure of materials5 Certain materials are moresuscepti+le t!an ot!ers5 If a suscepti+le material is placed in a corrosive environmentunder tension of su)cient magnitude1 and t!e duration of service is su)cient to permit

    t!e initiation and gro2t! of crac.s1 failure 2ill occur at a stress lo2er t!an t!at 2!ic! t!ematerial 2ould normally +e e%pected to 2it!stand5 T!e corrosive environment need not+e severe in terms of general corrosive attac.5

    - Service failures due to stress corrosion are freuently encountered in cases 2!ere t!esurfaces of t!e failed parts are not visi+ly corroded in a general sense5

    - If failure is to +e avoided1 t!e total tensile strengt! in service must +e maintained at a

    safe level5 T!ere is no a+solute t!res!old stress for stress corrosion1 +ut comparativestress'corrosion t!res!olds can +e determined for materials su+jected to controlled

    conditions of test5 Estimates of t!e stress'corrosion t!res!old for a speci#c service

    application must +e determined for eac! alloy and !eat treatment1 using a test piece1stressing procedure and corrosive environment t!at are appropriate for t!e intended

    service5

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      Materials and sheet#

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    Materials Properties cont55

    " Stress corrosion- Stress Corrosion Crac.ing 9SCC;1 de#ned as t!e com+ined action of a sustained tensile

    stress and corrosion1 can cause t!e premature failure of metals5 T!e metallic

    components proposed for use in most spacecrafts must +e screened to prevent failuresresulting from SCC5

    - =nly t!ose products found to possess a !ig! resistance to stress'corrosion crac.ing may!ave unrestricted usage in structural applications5

    - Materials intended for structural applications and li.ely to +e e%posed to a long'termterrestrial storage or 6o2n on t!e Space Transportation System1 fracture critical items1 allparts used or associated 2it! t!e fa+rication of launc! ve!icles s!all possess a !ig!

    resistance to stress'corrosion crac.ing5

    - Structural products of a metallic nature s!all +e selected from t!e preferred list in Ta+le I

    of ECSS' >' ?@' B5

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      Materials and sheet1$

    SMEInitiative

    Materials Properties cont55

    Specimen orientation and fracture plane identi#cation5 01 lengt!1 longitudinal1 principal directionof metal 2or.ing 9rolling1 e%trusion1 a%is of forging; T1 2idt!1longtransverse grain direction S1 t!ic.ness1 s!orttransverse grain direction C1 c!ord ofcylindrical cross section R1 radius of cylindrical cross section5 (irst letter: normal to t!e fractureplane 9loading direction; second letter: direction of crac. propagation in fracture plane5

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      Materials and sheet11

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    Materials Properties cont55

    " SCC ta+le I- Materials t!at testing and e%perience !ave s!o2n to possess !ig! resistance to stress'

    corrosion crac.ing5 T!eir use is given reference5

    " SCC ta+le II- Alloys and tempers listed in ta+le II are moderately resistant to stress' corrosion

    crac.ing5 T!ey s!ould +e considered for use only in cases 2!ere a suita+le alloy cannot+e found in Ta+le I5

    " SCC ta+le III- Materials listed in ta+le III !ave found to +e !ig!ly suscepti+le to stress' corrosion

    crac.ing5 T!ey s!ould +e considered for use only in applications 2!ere it can +edemonstrated conclusively t!at t!e pro+a+ility of stress corrosion is remote +ecause of

    lo2 sustained tensile stress 92!atever its origin; in critical grain directions1 suita+leprotective measures or an innocuous environment5

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      Materials and sheet12

    SMEInitiative

    Constraints on materials

    "  Temperature

    " 4acuum

    "  T!ermal cycling

    " C!emical 9corrosion;

    " alvanic compati+ility

    " Atomic o%ygen" Moisture a+sorption/desorption

    " (luid compati+ility

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      Materials and sheet13

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    Constraints on materials1 cont55

    "  Temperature-  T!e range of temperatures e%perienced 2ill play a large part in t!e materials selection5

    E%tremes are illustrated +y t!e e%amples of cryogenic tan.s and t!ermal protectionsystems for re'entry applications5 Temperatures +elo2 room temperature generallycause an increase in strengt! properties1 !o2ever t!e ductility decreases5 Ductility and

    strengt! may increase or decrease at temperatures a+ove room temperature5 T!isc!ange depends on many factors1 suc! as temperature and time of e%posure5

    - Materials s!all +e compati+le 2it! t!e t!ermal environment to 2!ic! t!ey are e%posed5

    - Passage t!roug! transition temperatures 9e5g51 +rittle'ductile transitions or glasstransition temperatures including t!e e

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      Materials and sheet14

    SMEInitiative

    Constraints on materials cont55

    "  T!ermal cycling-  T!ermal cycling can induce t!ermal stresses and due to t!e di

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      Materials and sheet15

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    Constraints on materials cont55

    " alvanic compati+ility- If t2o or more dissimilar materials are in direct electrical contact in a corrosive solution

    or atmosp!ere galvanic corrosion mig!t occur5 T!e less resistant material +ecomes t!eanode and t!e more resistant t!e cat!ode5 T!e cat!odic material corrodes very little ornot at all1 2!ile t!e corrosion of t!e anodic material is greatly en!anced5

    "Material com!atibilities shall be selected in accordance 'ith ECSS- Q-70-7()" Ma*imum !otential di$erences shall be in accordance 'ith ECSS- Q-70-7()

    - In t!e construction of a satellite1 t2o metals t!at form a compati+le couple may !ave to

    +e placed in close pro%imity to one anot!er5 Alt!oug! t!is may not cause anomalies ormalfunctions in t!e space environment1 it !as to +e +orne in mind t!at spacecraft often

    !ave to +e stored on eart! for considera+le periods of time and t!at during storage t!eymay inadvertently +e e%posed to environments 2!ere galvanic corrosion can ta.e place5In fact1 t!is is .no2n to !ave ta.en place on several occasions and it is for t!is reasont!at t!e Agency !as +een studying t!e dangers involved5

    " See also paragrap! a+out Corrosion

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      Materials and sheet1

    SMEInitiative

    Constraints on materials cont55

    " procedure- a simpli#ed procedure can +e used to estimate t!e

    compati+ility of a +imetallic couple +y ta.ing into

    account t!e di

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      Materials and sheet1!

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    Constraints on materials cont55

    " Atomic o%ygen- Spacecraft in lo2 eart! or+it 90E=; at altitudes of +et2een H@@ .m and ?@@ .m are

    e%posed to a 6u% of atomic o%ygen5 T!e 6u% level varies 2it! altitude1 velocity vector

    and solar activity5 T!e 6uence levels vary 2it! t!e duration of e%posure5

    " Moisture a+sorption/desorption-  T!e properties of composite materials are suscepti+le to c!anges induced +y t!e ta.e'up

    of moisture5 Moisture a+sorption occurs during production of components and launc! oft!e spacecraft1 desorption occurs in t!e space vacuum5

    " (luid compati+ility- In some occasions materials are in contact 2it! liuid o%ygen1 gaseous o%ygen or ot!er

    reactive 6uids or could come into contact 2it! suc! a 6uid during an emergency

    situation5

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      Materials and sheet1"

    SMEInitiative

    Interfaces 9surfaces1 layers;

    " Anodising

    " C!emical conversion

    " metallic coatings 9overlay and di

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      Materials and sheet1#

    SMEInitiative

    Surface #nis!es

    "  T!e surface #nis! of a component can in6uenceits mec!anical and environmental dura+ility5

    " Anodising 9c!romic1 sulp!uric1 sulp!uricJo%alic;- Anodising is an electrolytic process for t!ic.ening and sta+ilising o%ide #lms on +ase metals

    and anodising grade alloys5 It may +e used as a pre'treatment for painting and dying or as apassivation treatment for an electro'+rig!tened surface5

    - *ard anodised layers are 2ear resistant and dura+le5

    - lac. anodising 2it! co+alt sulp!ide and nic.el sulp!ide is used for controlling t!e optical

    properties of surfaces5

    " +igh solar absor!tance) high emmitnace

    -  T!e anodised layer is electrically non'conductive5

    -  T!e +at! constituents and process conditions may vary +et2een organisations5

    - Caution s!ould +e e%ercised in anodising very t!in products suc! as foils

    - Coatings are porous and needs sealing 9coating can release 2ater in vacuum;

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      Materials and sheet2$

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    Surface #nis!es1 cont55

    " C!emical conversion 9c!romate1 p!osp!ate; '- Commercial process 9alodine 1 irridite1 etc;

    - C!emical conversion depends upon t!e a+sorption of a protective metal o%ide #lm into

    an e%isting o%ide #lm +ut may include non'metals in some cases5- C!romating involves t!e formation of a mi%ed metal'c!romium o%ide #lm5 It !as a good

    corrosion resistance and an e%cellent +ond to su+seuent organic coatings5

    - P!osp!ating is primarily used as an underlayer for paint #nis!es5 It #nds little applicationfor corrosion protection5

    - C!emical conversion coatings can +e eit!er electrically conductive or non'conductive5

    -  Temporary corrosion protection only

    - simple and c!eap process

    - may +e applied +y immersion1 praying1 +rus!ing1 2iping or any ot!er 2etting met!od

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      Materials and sheet21

    SMEInitiative

    Coatings1 cont55

    " Metallic coatings 9overlay and di

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      Materials and sheet22

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    Coatings1 cont55

    evaporation

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      Materials and sheet23

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    Coating1 cont55

    ,ear

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      Materials and sheet24

    SMEInitiative

    Coating1 cont55

    " Moisture +arriers- Coatings can +e used to prevent moisture a+sorption or desorption of dimensionally sta+le

    structures or to prevent t!e release of organic volatiles 2!ic! could a

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      Materials and sheet25

    SMEInitiative

    Coating1 cont55

    " Depending on t!e design and service1 t!efollo2ing coatings are used:

    - Paints

    - p!osp!ate coatings

    - c!romate coatings- electroless nic.el

    - c!romium1 electroplated

    - o%ides and +lac. o%ide

    - nic.el/tin1 electroplated

    - tin/lead

    - electroless nic.el plus electroplated c!romium

    - vapour'deposited aluminium

    - metals1 suc! as gold1 silver1 palladium1 rodium

    - lu+rication coatings suc! as +raycoat grease

    - moly+denum disul#de

    - car+ides and nitrides or com+ination

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      Materials and sheet2

    SMEInitiative

     $oining

    " Mec!anical fastening

    " onding

    " Com+ined +onding and fastening

    " (usion1 including 2elding1 +ra3ing1 solderingand di

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      Materials and sheet2!

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     $oining cont55

    " olted joints- olts o

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      Materials and sheet2"

    SMEInitiative

     $oining cont55

    " (usion tec!niues can +e grouped as:- soldering

    - +ra3ing

    - 2elding1 including di

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      Materials and sheet2#

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     $oining cont55

    " Soldering- Soldering is commonly referred to as soft soldering in 2!ic! lo2 melting point alloys suc!

    as Tin'0ead or Indium +ased alloys are used5 Soldered joints are used for electrical andt!ermal conducting pat!s and for lo2 mec!anical strengt! joints5

    - Soldering s!all not +e used for structural applications unless revie2ed and approved +yt!e Customer5

    - See also ne%t session

    " ra3ing- ra3ing is preferred to soldering in t!ose cases 2!ere a strong joint1 2!ic! is !eat

    resistant is reuired5 As distinct from soft soldering +ra3ing usually refers to joining 2it!alloys of copper1 silver and 3inc

    " ,elding- &umerous 2elding tec!niues are availa+le5 In t!e aerospace industry t!e follo2ingtec!niues are often used:

    " ,ungsten nert as /, 'elding

    " 1lasma-2rc 'elding

    " Electron 3eam /E3 'elding ) laser 'elding

    " esistance 'elding /induction) s!ot) seam 'elding) i$usion 'elding

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      Materials and sheet3$

    SMEInitiative

    Corrosion Testing

    " eneral Corrosion

    " Stress Corrosion

    " imetallic Corrosion

    " Atomic =%ygen Corrosion

    " Red Plague Corrosion

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      Materials and sheet32

    SMEInitiative

    eneral corrosion testing

      Salt'spray'9foreground;and *umidity C!am+er'+ot! !ave temperatureand !umidity regulators

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      Materials and sheet33

    SMEInitiative

    Stress corrosion testing

       Test setup for t!e alternate immersion testingof specimens in a 5FG &aCl solution

    Al'0i stresscorrosion failure

     Testing acc5 to ESAPSS'@'??

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      Materials and sheet34

    SMEInitiative

    imetallic corrosion testing

       T!e +imetalliccorrosion +et2eent2o materials cantested in speci#cliuids and underany !umiditylevels5

       T!e current and

    voltage di

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      Materials and sheet35

    SMEInitiative

    Atomic =%ygen Corrosion

      Materials for use in spaceapplications in lo2 eart! or+itand e%posed to t!e !ostilecom+ination of atomic o%ygenand t!ermal cycling !ave to +e

    screened for t!eir suscepti+ilityto 2it!stand t!is environmentover very long periods

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      Materials and sheet3

    SMEInitiative

    Red plague testing

      Red plague testing 9Ant!ony and ro2n test; is performed according toESA PSS'@'?H@

       Test conditions: HL@ !rs at FO oC

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      Materials and sheet3!

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    Mec!anical Testing

    " *ardness testing

    "  Tensile Testing" Compression testing

    " (atigue testing

    " (racture Toug!ness

    "  T!ermal cycling

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      Materials and sheet3#

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    Mec!anical Testing cont55

       T!is euipment is more particularlydedicated to t!e testing of t!ermo'structural materials suc! as CMCmaterials5 It !as +een set up for

    measuring tensile properties fromam+ient temperature up to B@@oC

    under air5 Suc! a test is recognised to+e t!e most important for evaluatingmec!anical properties of CMC5

      A ceramic matri% compositespecimen is clamped into self'aligning

    2ater cooled grips5 It passes t!roug!a specially designed furnace a+le to!eat its cali+rated section to B@@oC5A !ig! temperature capacitive

    e%tensometer made of ceramicspro+es permit strain measurements5

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      Materials and sheet4$

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    Mec!anical Testing cont55

       T2o units1 specially designed according

    to to speci#cation ESA PSS'@'?@L1operate under vacuum5 T2o ot!er unitsoperate under atmosp!eric pressure5

     T!e !eating and cooling is provided +ynitrogen gas5

    =ne of t!e t2o systems fort!ermal cycling undervacuum 94MDI is s!o2n;5 T!esystem is provided 2it!vie2ing ports and electricfeed t!roug! connection5

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      Materials and sheet41

    SMEInitiative

    Macro/Microscopic E%amination

    " Macroscopic 9 Q?F;

    " 0ig!t microscopy

    " Confocal microscopy

    " Scanning Electron Microscopy

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      Materials and sheet42

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    Macroscopic E%amination

      Magni#cation %?F- 4isual Inspection

    - Stereo3oom

    - Scanning Electron Microscopy at lo2

    magni#cation

    - P!otograp!y   T!e diversity of samples su+mitted

    for failure analysis is illustrated +y

    t!is p!otograp!1 2!ic! featurespart of a defective spacecraft

    antenna1 a nic.el cadmium +atterycell1 detector electrodes1 printed

    circuit +oards1 fracture toug!nessspecimen1 part of a dip +ra3ed

    2aveguide1 sections t!roug! asolar army !ydrogen em+rittled

    springs and a composite structure

    designed to 2it!stand t!e impactof particles travelling at B@ .m/s5

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      Materials and sheet43

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    Microscopic E%amination cont55

    " 0ig!t Microscopy- metallurgical microscopy

    " =ptical Microscopes Reic!ertMe(H: magn5 Q to QF@@1 Itincludes: interferometer1polarised lig!t illumination1micro'!ardness tester Reic!ertMe(a: magn5 Q to F@@ Itincludes: polarised lig!t

    illumination1 dar. and +rig!t#eld illumination1 connection to

    Cleme% Image analyser 

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      Materials and sheet44

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    Microscopic E%amination cont55

      Confocal microscopy  Confocal microscopy allo2s t!e us to

    o+tain dept!'selective information on t!et!ree'dimensionial structure of amicroscopic o+ject5

      0EICA TCS &T 2it! microscopeDM'RQE and galvanometerdriven K'stage5

     T!e %/y resolution is @5O µm9(,*M; and a corresponding 3'resolution of +etter t!an @5F

    µm 9(,*M; at LOO nm

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      Materials and sheet45

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    Microscopic E%amination cont55

    " In many situations even greater

    magni#cations are useful5 T!iscapa+ility is provided +y t2o

    Scanning Electron Microscopes

    9SEM; 2!ic! can magnify to QH@@@@@ 2it! good resolution5 9$E=0

     T@@ and Cam+ridge SB@;5 T!egreat dept! of #eld of t!ese

    instruments and t!e large specimenc!am+er of one of t!ese SEMs !as

    made t!em particularly useful ine%amining roug! fracture surfaces

    to determine t!e cause of acomponent failure5

    " 4ie2 on Scanning ElectronMicroscope Cam+ridge SB@

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      Materials and sheet4

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    &on'Destructive E%amination

    " Scanning 0aser Acoustic Microscopy 9S0AM;

    " C' Mode Scanning Acoustic Microscopy 9C'SAM;

    " Radiograp!y 9in T=S'>C;

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      Materials and sheet4!

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    &on'Destructive E%amination cont55

       T!e Scanning 0aser Acoustic

    Microscopy 9S0AM; produces images of

    t!e internal structure of metals1

    ceramics and even +iological tissues1

    and t!ese are displayed in real time on

    a T4 monitor5

       T!e S0AM uses very !ig! freuency

    ultrasound in a transmission mode to

    produce images5 Acoustic 2aves aretransmitted into t!e +ottom face of t!e

    cell sample +y means of a distilled'

    2ater coupling medium5 sing t!is

    instrument it 2as possi+le to assess

    t!e uality of solar cell interconnectors

    for t!e Space Telescope5

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      Materials and sheet4"

    SMEInitiative

    (ailure Analysis

    " Under control of Material Review Board(MRB)

    " Collection of +ac.ground data

    "visual e%amination" selection1 identi#cation1 preservation of specimens

    " macroscopic e%amination and analysis

    " microscopic e%amination and analysis

    " metallograp!ic sections e%amination

    " failure mec!anism" c!emical analysis

    " simulated testing

    " report

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      Materials and sheet4#

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    Materials Properties

    anne% cont55

    " Corrosion fatigue- Corrosion fatigue indicates crac. formation and propagation caused +y t!e e

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      Materials and sheet5$

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    Materials Propertiesanne% cont55

    " Strengt!- Spacecraft design covers t!e survival of t!e structure under t!e 2orst feasi+le

    com+ination of mec!anical and t!ermal loads5 All events of t!e complete lifetime of t!espacecraft are addressed +y t!is design5 T!e strengt! of a material is !ig!ly dependant

    on t!e direction as 2ell as on t!e sign of t!e applied load1 e5g51 a%ial tensile1 transversecompressive1 and ot!ers5

    "  !ositie margin of safet# and shall include) if a!!licable) #ield load anal#sis)ultimate load anal#sis and buc"ing load anal#sis

    " Elastic modulus-  T!e elastic modulus de#ned as t!e ratio +et2een t!e unia%ial stress and t!e strain 9e5g51 oungNs modulus1 compressive modulus1 s!ear modulus; is for metals and alloys 2ea.ly

    dependant on !eat'treatment and orientation5 *o2ever1 for #+re reinforced materials1t!e elastic modulus depends on t!e #+re orientation5

    " For com!osites the re6uired elastic modulus shall be eried.

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      Materials and sheet51

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    Materials Propertiesanne% cont55

    " (atigue- (atigue fracture can form in components 2!ic! are su+jected to alternating stresses5

     T!ese stresses may lie far +elo2 t!e allo2ed static strengt! of t!e material5

    "For com!onents e*!eriencing alternating stresses) demonstration of thedegradation of material !ro!erties oer the com!lete mission

    " (racture toug!ness-  T!e fracture toug!ness is a measure of t!e damage tolerance of a material containing

    initial 6a2s or crac.s5 T!e fracture toug!ness in metallic materials is descri+ed +y t!e

    plain strain value of t!e critical stress intensity factor5 T!e fracture toug!ness dependson t!e environment5 7ic is t!e plain strain critical stress intensity factor5 7iscc plain strain

    critical stress intensity factor for a speci#ed environment in 2!ic! environmentallyinduced crac. gro2t! occurs5

    " Metallic materials for use in corrosie surface enironments shall be tested for

    fracture toughness under re!resentatie conditions

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      Materials and sheet52

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    Materials Properties anne% cont55

    " Creep- Creep is a time'dependant deformation of a material under an applied load5 It usually

    occurs at elevated temperature1 alt!oug! some materials creep at room temperature5 Ifpermitted to continue inde#nitely1 creep terminates in rupture5 E%trapolations from simple

    to comple% stress'temperature'time conditions are di)cult5" ,esting under re!resentatie serice conditions is necessar# 'hen cree! is li"el# to

    occur.

    " Micro'yielding- Some materials may e%!i+it residual strain after mec!anical loading5 T!e micro'yield is t!e

    force to +e applied to get a residual strain of %@'B m/m along t!e tensile or compressionloading direction5 In general1 t!e most severe mec!anical loading occurs during launc!5

    " 8here dimensional stabilit# re6uirements hae to be met) micro-#ielding shall beassessed.

    " 8hen it is li"el# to occur) testing and anal#sis in relation 'ith the mechanical loading

    during the life c#cle of the hard'are shall be !erformed.

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      Materials and sheet54

    SMEInitiative

    Stress Corrosion Crac.ing1 cont

    Mean +rea.ing stress versus e%posure time for s!orttransverse 5Hmm 9@5 HFin5; diam aluminium alloy?@?F tension specimens tested according to ASTM LL at various e%posure stress levels5 Eac! pointrepresents an average of #ve specimens5

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      Materials and sheet55

    SMEInitiative

    Stress Corrosion Crac.ing1 cont55

    E

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      Materials and sheet5

    SMEInitiative

    SCC Ta+le I ' Steel Alloys

      Alloy  Car%on steel&1$$$ series'

    (o) allo* steel&413$+434$ etc'  &E' DAC+ ,-11

    Msic )ire&ASTM 22"'  ,.-"$ steel

    ,.-13$ steel

    ,.-14$ steel

    1$#5 srin0 steel

    3$$ series stainless steel&nsensitised'24$$ series erritic stainless steel

      21--# stainless steel

    Carenter 2$ C% Stainless steel

    Carenter 2$$ C%-3 stainless steel

    A2" stainless steel

    AM35$ stainless steel

    AM355 stainless steel

    Alar 32 stainless steel

    Csto 45$ stainless steel

      Csto 455 stainless steel15-5 P, stainless steel

    P, 14-" Mo stainless steel  P, 15-! Mo stainless steel

    1!-! P, stainless steel

     itronic 33 &3'  &E' Mara0in0 steel MAA( 612

    Condition

    7elo) 125 80/29 &1"$ 8si' :TS

    7elo) 125 80/29 &1"$ 8si' :TS &1'

    7elo) 14" 80/29 &21$ 8si' :TS

    cold dra)n

    Qenched and teered

    Qenched and teered

    Qenched and teered

    Qenched and teered

    AllAll

    All

    All

    All

    All

    SCT 1$$$&4' and a%ove

    SCT 1$$$ and a%ove

    ,1$$$ &5' and a%ove

    ,1$$$ and a%ove

    ,1$$$ and a%ove

    ,1$$$ and a%ove

    C,#$$ and S,#5$ and a%ove &+!'

    C,#$$

    C,#$$

    All

    All

    1' A sall n%er o la%orator* ailres o

    seciens ct ro late ore than 2

    inches thic8 have %een o%served at !5;

    *ield+ even )ithin this ltiate stren0th

    ran0e< The se o thic8 late shold

    thereore %e avoided in a corrosive

    environent )hen sstained tensile stress

    in the short transverse direction is

    e=ected<2' >ncldin0 )eldents o 3$4(+ 31(+

    321 and 34!<

    3' >ncldin0 )eldents<

    4' SCT 1$$$ ? s%-@ero coolin0 and

    teerin0 at 53"B1!9C &1$$$'

    5' ,1$$$ ? hardened a%ove 53"C &1$$$'

    ' C,#$$ ? cold )or8ed and a0ed at

    4"$C &1$$$9'

    !' S,#5$ ? soltion treated and

    teered at 51$C $'

    &E' ESA classiication - not in ASA

    MSC-SPEC-522A

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      Materials and sheet5!

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     SCC Ta+le I ' &ic.el Alloys

      Allo*

      ,astello* C

    ,astello* 6

    >ncolo* "$$

    >ncolo* #$1

    >ncolo* #$3>nconel $$ &3'

      >nconel 25

    >nconel !1" &3'

    >nconel 6-!5$

    Monel -5$$

     iSan -C #$2

    ene 41

    :nite 212

    asalo*

    3' >ncldin0 )eldents

      Condition

      All

      All

      All

    All

     All

      Annealed

    Annealed

    All

    All

    All

      All

      All

      All

      All

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      Materials and sheet5"

    SMEInitiative

    SCC Ta+le I ' Aluminium Alloys

    Alloy,

    Wrought(1,2)

      Allo*+ 1$$$ series

    2$11

    2$24+ rod %ar

    221#

    &E' 241#

    &E' 21"

    3$$$ series5$$$ series

    $$$ series &E'!$2$

    !$4#

    !14#

    !$5$

    !$!5

    !4!5

    Condition

    All

    T"

    T"

    T+ T"

    T"

    T+ T"

    All

    All &4+5'

    All

    T &'

    T!3

    T!3

    T!3

    T!3

    T!3

    Cast (3)

    355

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      Materials and sheet5#

    SMEInitiative

    SCC Ta+le I ' Copper Alloys/ Misc5 Alloys

    CDA no (1)

      11$

      1!$

    1!2

    1#4

    1#5

    23$

    422

    443

    51$

    521

    1#

    1#

    ""

    !$

    !25

    2"$+524+$

      32+55+!$5

      !1$+!15

      &E'#1!+ &E'#3!

     

    Condition (% cold rolled) (2)

    3!

    AT+ ,T &3'

    AT+ ,T &3'

    3!

    #$

    4$

    3!

    1$

    3!

    3!

    4$ 7 hase'

    4$ 7 hase'

    4$

    5$

    5$+ annealed

    $$

    $

    $

    Alloy

    7er*lli+ S-2$$C

    ,S 25 &($5'

    ,S 1""

    MP35

    Titani 3Al-2

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      Materials and sheet$

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    SCC Ta+le II ' Steel Alloys/Miscellaneous alloys

      Alloy

      Car%on steel &1$$$ series'

      (o)-allo* steel &413$+434$ etc'

     itronic 32

     itronic $

    4$$ series artensitic stainless steel &e=cet 44$'

    P, 13-" Mo stainless steel

    15-5 P, stainless steel1!-4 P, stainless steel

    Condition

    1225 to 13!$ MPa :TS

    1225 to 13!$ MPa :TS

    All

    All

    &1'

    All

    7elo) ,1$$$ &2'

    All

     1' Teerin0 %et)een 3!$ and $$C shold %e avoided %ecase corrosion and stress-corrosion resistance is lo)ered<

     2' ,1$$$ ? hardened a%ove 53"C &1$$$'<

    Alloy

    Ma0nesi AF317

    Ma0nesi F$A

    Ma0nesi &E' F3

    Condition

    All

    All

    All

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      Materials and sheet1

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    SCC Ta+le II ' Aluminium Alloys91H;

      Alloy, wrough

      2$24 rod+ %ar+ e=trsion

      2$24 late+ e=trsions

      2124 late

      2$4" late

      4$32

    5$"3

      5$"

    545!$$1

    &E' !$1$

    !$4#

      !$5$

      !$!5

      !1!5

    !4!5

    !1!"

    &E' ssian Al-(i 142$+ 1421

    Condition

    T+ T2

    T"

    T"

    T"

    T

    All &3'

    All &3'

    All &3'

    T!5+ T!

    T!4

    T!

    T!4+ T!

    T! T!4+

    T!

    T!

    T!

    soln< treatGa0e

    Alloy, cast

    31#+ alini

    allo*s< These allo*s are not recoended or hi0h-teeratre alications<

    C &15$' and a%ove<

    &E' ESA classiication - not in ASA MSC-SPEC-522A<

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      Materials and sheet2

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    SCC Ta+le III ' Steel Alloys

     Alloy

     Car%on steel&1$$$ series'

    (o) allo* steel&413$+434$ etc'

     &E' DAC+ ,-11steel

     44$C stainless steel

    1" i Mara0in0 steel+ 2$$ 0rade

    1" i Mara0in0 steel+ 25$ 0rade

    1" i Mara0in0 steel+ 3$$ 0rade

    1" i Mara0in0 steel+ 35$ 0rade

    AM 35$ stainless steel

    AM 355 stainless steel

    Csto 455 stainless steel

    P, 15-! Mo stainless steel

    1!-! P, stainless steel C,#$$

     &E' ovar

    Condition

    A%ove 13!$ Ma :TS

    A%ove 13!$ Ma :TS

    A%ove 13!$ Ma :TS

    All

    A0ed at #$$

    A0ed at #$$

    A0ed at #$$

    A0ed at #$$

    7elo) SCT 1$$$

    7elo) SCT 1$$$

    7elo) ,1$$$

    All e=cet C,#$$

    All e=cet C,#$$

    All

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      Materials and sheet3

    SMEInitiative

     SCC Ta+le III ' Aluminium Alloys

    Alloy, Wrought (1,2)

    2$11

    2$14

    2$1!

    2$24

    2$24 or0in0s

    2$24 Plate

    &E' Al-(i 2$"$

    &E' 21"!$$1

    !$$5

    &E' !$2$

    !$3#

    !$!5

    !1!5

    !$!#

    !1!"

    !4!5&E' Al-(i "$#$

    &E' 7S (#3

    &E' ssian Al-(i 1441+ 14$

    Condition

    T3+ T4

    All

    All

    T3+ T4

    T+ T2+ T"

    T2

    T"

    T3+ T4

    T

    All

    eldents

    All

    T

    T

    T

    T

    T

    All

    T

    All

    Condition

     T

     T

     T4

     T

     As cast

    Alloy

    2#5

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    SMEInitiative

     SCC Ta+le III ' Copper Alloys/ Magnesium alloys

    CDA no (1)

    2$

    353

    443

    !2

    "!

    !2

    !

    !!$

    !"2

    1' Coer Develoent

     Association allo* n%er 

     2' atin0 %ased on listed

    conditions onl*

    Condition (% cold rolled) (2)

    5$

    5$

    4$

    5$+ annealed

    1$+ 4$

    A+ 25+ 5$

    3"

    3"+ 5$+ annealed

    5$

     Alloy Condition

     Ma0nesi AF17 All

     Ma0nesi AF"$A All

     Ma0nesi E54 All

     Ma0nesi FCM!11 All