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Sheet MetalMSDS

Commercial Sheet Metal MSDS

Trade Name Manufacturer Page #

3M Silicone Lubricant 3M 2

440 Tape Alum/Grey Tremco 10

55-010 Breeze Eggshell Latex-White General Paint 16

ABC Super 90 Dry Chemical Strike First Corporation 19

All Season Windshield Washer Fluid Recochem 23

Argon Airgas Inc. 31

Black Spray Paint The Fastners Group 37

Can Dry Absorbent Absorbent Products 42

Cantesco Premium Anti-Spatter Concentrate Cantesco 45

Carbon and Alloy Steels Various Manufacturers 51

Duro Dyne Solvent Based Adhesive Duro Dyne 53

Emery Cloth Medium Grit 3M 57

Fantastik Original All Purpose Cleaner S.C. Johnson 68

Hardcast Foil Grip 1403-181BFX Carlisle 76

Hardcast Duct Seal 321 Carlisle 81

Industrial Hydraulic Oil Boss Lubricants 87

Linacoustic RC Duct Liner Johns Manville 89

Lubriplate Wheel Bearing Grease Lubriplate Lubricants 96

Microlite XG Johns Manville 102

Mineral Wool Insulation Roxul 108

Oil Based Floor Sweep Floor Sweep 115

Powdered Chalk Starrett 116

Propane Superior Propane 125

PROtack Water Based Duct Liner Adhesive Ductmate Industries 127

SPRAYON Zinc Rich Cold Galvanizing Compound The Sherwin-Williams Company 129

Unfaced Fiber Glass Insulation Johns Manville 135

United Duct Sealer Water Based McGill AirSeal 141

Used Oil Various Manufacturers 146

UVEX Clear Lens Cleaner Uvex 156

Vulkem 801 Gray-5 Gal Tremco 157

Xirtec 5 GRY Low Voc Cement for PVC Pipe IPS Corporation 164

Xylene Imperial Oil 166

MATERIAL SAFETY DATA SHEET 3M(TM) Silicone Lubricant 07/12/13

_________________________________________________________________________________________________Page 1 of 8

Material Safety Data Sheet

Copyright, 2013, 3M Company All rights reserved. Copying and/or downloading of this information for the purpose of properly

utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is

obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit

thereon.

SECTION 1: PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME: 3M(TM) Silicone Lubricant

MANUFACTURER: 3M

DIVISION: Industrial Adhesives and Tapes Division

ADDRESS: 3M Center, St. Paul, MN 55144-1000

EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)

Issue Date: 07/12/13

Supercedes Date: 08/04/10

Document Group: 05-6937-6

Product Use:

Limitations on Use: Sale and use severely restricted due to high VOC in CT, DE, ME,

MD, NH, NJ, NY, PA, RI, VA, DC, in CA per R-1168.

Intended Use: Industrial use

SECTION 2: INGREDIENTS

Ingredient C.A.S. No. % by WtISOBUTANE 75-28-5 70 - 80

HEPTANE 142-82-5 15 - 25

POLY(DIMETHYLSILOXANE) 63148-62-9 3 - 7

SECTION 3: HAZARDS IDENTIFICATION

3.1 EMERGENCY OVERVIEW

Odor, Color, Grade: in aerosol, transparent, very slight odor

General Physical Form: Liquid

Immediate health, physical, and environmental hazards: Closed containers exposed to heat from fire may build pressure and

explode. Extremely flammable liquid and vapor. Vapors may travel long distances along the ground or floor to an ignition source and

flash back. May cause target organ effects. May cause frostbite.

3.2 POTENTIAL HEALTH EFFECTS


_________________________________________________________________________________________________Page 2 of 8

Eye Contact:

Frostbite: Signs/symptoms may include intense pain, clouding of the cornea, redness, swelling, and blindness.

Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision.

Skin Contact:

Frostbite: Signs/symptoms may include intense pain, discoloration of skin, and tissue destruction.

Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, and itching.

Inhalation:

Upper Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose

and throat pain.

Intentional concentration and inhalation may be harmful or fatal.

May be absorbed following inhalation and cause target organ effects.

Ingestion:

Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, nausea, diarrhea and vomiting.

Target Organ Effects:

Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea,

slowed reaction time, slurred speech, giddiness, and unconsciousness.

SECTION 4: FIRST AID MEASURES

4.1 FIRST AID PROCEDURES

The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are

followed.

Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention.

Skin Contact: Wash affected area with soap and water. If signs/symptoms develop, get medical attention.

Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention.

If Swallowed: Do not induce vomiting. Give victim two glasses of water. Never give anything by mouth to an unconscious

person. Get immediate medical attention.

SECTION 5: FIRE FIGHTING MEASURES

5.1 FLAMMABLE PROPERTIES

Autoignition temperature No Data Available

Flash Point -50 ºF [Test Method: Tagliabue Closed Cup] [Details:

CONDITIONS: Propellant]

Flammable Limits(LEL) Approximately 1.5 % volume

Flammable Limits(UEL) Approximately 8 % volume

5.2 EXTINGUISHING MEDIAUse fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide).


_________________________________________________________________________________________________Page 3 of 8

5.3 PROTECTION OF FIRE FIGHTERS

Special Fire Fighting Procedures: Water may not effectively extinguish fire; however, it should be used to keep fire-exposed

containers and surfaces cool and prevent explosive rupture. Wear full protective equipment (Bunker Gear) and a self-contained

breathing apparatus (SCBA).

Unusual Fire and Explosion Hazards: Closed containers exposed to heat from fire may build pressure and explode. Extremely

flammable liquid and vapor. Vapors may travel long distances along the ground or floor to an ignition source and flash back.

Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition

information.

SECTION 6: ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures

If possible, seal leaking container. Place leaking containers in a well-ventilated area, preferably an operating exhaust hood, or if

necessary outdoors on an impermeable surface until appropriate packaging for the leaking container or its contents is available.

Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Remove all

ignition sources such as flames, smoking materials, and electrical spark sources. Use only non-sparking tools. Ventilate the area with

fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with

good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill

area to burn or explode. Remember, adding an absorbent material does not remove a toxic, corrosivity or flammability hazard.

6.2. Environmental precautions

For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. Collect the resulting residue

containing solution. Place in a metal container approved for transportation by appropriate authorities. Dispose of collected material

as soon as possible.

Clean-up methods

Refer to other sections of this MSDS for information regarding physical and health hazards, respiratory protection, ventilation, and

personal protective equipment. Call 3M-HELPS line (1-800-364-3577) for more information on handling and managing the spill.

Contain spill. Cover spill area with a fire-extinguishing foam. An aqueous film forming foam (AFFF) is recommended. Working

from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material.

Mix in sufficient absorbent until it appears dry. Collect as much of the spilled material as possible using non-sparking tools. Clean up

residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow

safety precautions on the solvent label and MSDS. Seal the container.

In the event of a release of this material, the user should determine if the release qualifies as reportable according to

local, state, and federal regulations.

SECTION 7: HANDLING AND STORAGE

7.1 HANDLINGDo not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Keep away from heat,

sparks, open flame, pilot lights and other sources of ignition. Ground containers securely when transferring contents. Wear low static

or properly grounded shoes. Do not pierce or burn container, even after use. No smoking while handling this material. Do not spray

near flames or sources of ignition. Avoid breathing of vapors, mists or spray. Avoid static discharge. Avoid eye contact with vapors,

mists, or spray. Keep out of the reach of children. Avoid contact with oxidizing agents.

7.2 STORAGEStore away from acids. Store away from heat. Store out of direct sunlight. Keep container tightly closed. Store away from oxidizing


_________________________________________________________________________________________________Page 4 of 8

agents.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 ENGINEERING CONTROLSUse with appropriate local exhaust ventilation. Use with functioning spray booth or local exhaust. Do not use in a confined area or

areas with little or no air movement. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to

below Occupational Exposure Limits and/or control mist, vapor, or spray. If ventilation is not adequate, use respiratory protection

equipment. Do not use in a confined area or areas with little or no air movement. If exhaust ventilation is not adequate, use

appropriate respiratory protection. Provide ventilation adequate to control vapor concentrations below recommended exposure limits

and/or control spray or mist.

8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)

8.2.1 Eye/Face ProtectionAvoid eye contact with vapors, mists, or spray.

The following eye protection(s) are recommended: Safety Glasses with side shields

.

8.2.2 Skin Protection

Not applicable. Wear insulated gloves to protect against frostbite.

Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with

your glove and/or protective clothing manufacturer for selection of appropriate compatible materials.

Gloves made from the following material(s) are recommended: Nitrile Rubber

.

8.2.3 Respiratory Protection

Avoid breathing of vapors, mists or spray.

An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full

respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce

inhalation exposure:

Half facepiece or full facepiece air-purifying respirator suitable for organic vapors

For questions about suitability for a specific application, consult with your respirator manufacturer.

8.2.4 Prevention of Swallowing

Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Not applicable.

8.3 EXPOSURE GUIDELINES

Ingredient Authority Type Limit Additional InformationHEPTANE ACGIH TWA 400 ppm

HEPTANE ACGIH STEL 500 ppm

HEPTANE OSHA TWA 2000 mg/m3

ISOBUTANE ACGIH STEL 1000 ppm

SOURCE OF EXPOSURE LIMIT DATA:

ACGIH: American Conference of Governmental Industrial Hygienists

CMRG: Chemical Manufacturer Recommended Guideline

OSHA: Occupational Safety and Health Administration

AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL)


_________________________________________________________________________________________________Page 5 of 8

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

Odor, Color, Grade: in aerosol, transparent, very slight odor

General Physical Form: Liquid

Autoignition temperature No Data Available

Flash Point -50 ºF [Test Method: Tagliabue Closed Cup] [Details:

CONDITIONS: Propellant]

Flammable Limits(LEL) Approximately 1.5 % volume

Flammable Limits(UEL) Approximately 8 % volume

Boiling Point No Data Available

Density 0.64 g/ml

Vapor Density 2.97 [Ref Std: AIR=1]

Specific Gravity 0.640 [Ref Std: WATER=1]

pH Not Applicable

Melting point No Data Available

Solubility in Water Nil

Evaporation rate 1.90 [Ref Std: WATER=1]

Hazardous Air Pollutants 0 % weight [Test Method: Calculated]

Volatile Organic Compounds Approximately 565 g/l [Test Method: calculated SCAQMD rule

443.1] [Details: low solids less exempts]

Volatile Organic Compounds <=5.06 lb/gal [Test Method: calculated SCAQMD rule 443.1]

[Details: low solids less exempts]

Kow - Oct/Water partition coef No Data Available

Percent volatile Approximately 95 % weight

VOC Less H2O & Exempt Solvents <=94.7 % [Test Method: calculated per CARB title 2]

Viscosity Not Applicable

Solids Content 0 %

SECTION 10: STABILITY AND REACTIVITY

Stability: Stable.

Materials and Conditions to Avoid:

10.1 Conditions to avoid

Heat

10.2 Materials to avoid

Strong oxidizing agents

Hazardous Polymerization: Hazardous polymerization will not occur.

Hazardous Decomposition or By-Products

Substance ConditionCarbon monoxide During Combustion

Carbon dioxide During Combustion


_________________________________________________________________________________________________Page 6 of 8

SECTION 11: TOXICOLOGICAL INFORMATION

Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its

components.

SECTION 12: ECOLOGICAL INFORMATION

ECOTOXICOLOGICAL INFORMATION

Not determined.

CHEMICAL FATE INFORMATION

Not determined.

SECTION 13: DISPOSAL CONSIDERATIONS

Waste Disposal Method: Incinerate in a permitted hazardous waste incinerator. Facility must be capable of handling aerosol cans.

As a disposal alternative, dispose of waste product in a permitted hazardous waste facility.

Dispose of empty product containers in a sanitary landfill.

RECYCLE EMPTY AEROSOL CONTAINERS WHERE AVAILABLE.

EPA Hazardous Waste Number (RCRA): D001 (Ignitable)

Since regulations vary, consult applicable regulations or authorities before disposal.

SECTION 14:TRANSPORT INFORMATION

ID Number(s):

62-4678-0930-7, 62-4678-0931-5, 62-4678-4930-3, 62-4678-4935-2, 78-8033-2219-3

For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501.

SECTION 15: REGULATORY INFORMATION

US FEDERAL REGULATIONSContact 3M for more information.

311/312 Hazard Categories:

Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - No

STATE REGULATIONSContact 3M for more information.

CHEMICAL INVENTORIESThe components of this product are in compliance with the chemical notification requirements of TSCA.

All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS),

or are exempt polymers whose monomers are listed on EINECS. Contact 3M for more information.


_________________________________________________________________________________________________Page 7 of 8

INTERNATIONAL REGULATIONSContact 3M for more information.

This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.

SECTION 16: OTHER INFORMATION

NFPA Hazard ClassificationHealth: 2 Flammability: 4 Reactivity: 0 Special Hazards: None

Aerosol Storage Code: 3

National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are

presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the

inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to

be generated in significant quantities.

Revision Changes:

Section 1: Product use information was modified.

Section 16: Disclaimer (second paragraph) was modified.

Section 10: Hazardous decomposition or by-products table was modified.

Section 8: Respiratory protection - recommended respirators information was modified.

Section 8: Respiratory protection - recommended respirators was modified.

Section 14: Transportation legal text was modified.

Section 15: Inventories information was modified.

Section 9: Density information was modified.

Section 9: Vapor density value was modified.

Section 9: Boiling point information was modified.

Section 5: Flammable limits (UE) information was modified.

Section 5: Flammable limits (LEL) information was modified.

Section 5: Autoignition temperature information was modified.

Section 5: Flash point information was modified.

Section 9: Property description for required properties was modified.

Section 9: Property description for optional properties was modified.

Section 9: Specific gravity information was modified.

Section 9: pH information was modified.

Section 9: Melting point information was modified.

Section 9: Solubility in water text was modified.

Section 8: Respiratory protection - recommended respirators guide was modified.

Section 9: Flash point information was modified.

Section 9: Flammable limits (LEL) information was modified.

Section 9: Flammable limits (UEL) information was modified.

Section 9: Autoignition temperature information was modified.

Section 2: Ingredient table was modified.

Section 8: Exposure guidelines ingredient information was modified.

Section 6: 6.2. Environmental precautions heading was modified.

Section 6: 6.1. Personal precautions, protective equipment and emergency procedures heading was modified.

Section 16: Web address was added.

Section 1: Address was added.

Copyright was added.

Company logo was added.

Telephone header was added.

Company Telephone was added.

Section 1: Emergency phone information was added.


_________________________________________________________________________________________________Page 8 of 8

Section 1: Emergency phone information was deleted.

Company Logo was deleted.

Copyright was deleted.

Section 16: Web address heading was deleted.

Section 1: Address line 1 was deleted.

Section 1: Address line 2 was deleted.

Section 8: Respiratory protection - recommended respirators punctuation was deleted.

Section 15: TSCA section 12[b] text was deleted.

Section 15: TSCA section 12[b] information was deleted.

DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M

MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY

OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF

TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of

use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely

within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a

particular purpose and suitable for user's method of use or application.

3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may

have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy.

In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M

3M USA MSDSs are available at www.3M.com

SECTI ON 1 - PRODUCT I NFORMATI ON

Product I dent if ier : 55-010 BREEZE EGGSHELL LATEX-WHI TE

Product Use: Protect ive Coat ing

Manufacturer 's Nam e: General Paint Corp. Supplier 's Nam e: General Paint Corp.

St reet Address: 950 Raym ur Ave St reet Address: 950 Raym ur Ave

City: Vancouver Province: BC City: Vancouver Province: BC

Posta l Code: V6A 3L5

Em ergency Phone: (604) 253-4022

Posta l Code: V6A 3L5

Em ergency Phone: (604) 253-4022

SECTI ON 2 - HAZARD OUS I NGREDI ENTS

Hazardous I ngredients( Specif ic )

% CAS Num ber

LD 5 0 of I ngredient ( Specify

species,route)

LC 5 0 of I ngredient ( Specify

species)

TI TANI UM DI OXI DE 14 - 16 13463-67-7 NOT AVAI LABLE NOT AVAI LABLE

PROPYLENE GLYCOL 2.29 - 2.31 57-55-6 20000 MG/ KG(ORAL, RAT)

NOT AVAI LABLE

SECTI ON 3 - PHYSI CAL DATA

Physica l Sta te: Liquid

Odour and Appearance: liquid with a slight am m onia smell

Coat ing VOC( gm / l) : 128

Odour Threshold( ppm ) : Not Available

Specif ic Gravity: 1.31

Vapor Density( a ir= 1 ) : Not Available

Vapor Pressure( m m Hg) : Not Available

Evaporat ion Rate: Not Available

Boiling Point ( º C ) : Greater than 100° C

Freezing Point ( º C ) : Less than 0° C

pH: 8.5-9.5

Coeff icient of W ater / Oil Dist r ibut ion: Not Available

SECTI ON 4 - FI RE AN D EXPLOSI ON DATA

Flam m abilit y: No I f yes, Under w hich Condit ions? Not Applicable

Means of Ext inct ion: Alcohol foam, Carbon dioxide, Dry chem ical powder, Polym er foam

Flashpoint and Method: "Not Applicable

Upper Flam m able Lt ( % by Volum e) : Not Applicable

Low er Flam m able Lt ( % by Volum e) : Not Applicable

Autoignit ion Tem perature: Not Applicable

Explosion Data - Sensit ivit y to I m pact : No

Explosion Data - Sensit ivit y to Stat ic discharges: No

Hazardous Com bust ion Pdts: carbon m onoxide, carbon dioxide, acrid, irr itant fum es (com ponents not specified) , calcium oxide, aldehydes, nit rogen oxides, sulfur oxides, m agnesium oxide, amm onium nit rate, nit rogen, nit rogen dioxide

SECTI ON 5 - REACTI VI TY DATA

Chem ica l Stabilit y: Stable I f Yes, Under w hich Condit ions? Not Applicable

I ncom pat ibilit y w ith other substances: Yes

I f yes, w hich ones? St rong Acids St rong Oxidizing agents St rong Bases

React ivit y, and under w hat condit ions? heat , ignit ion sources, nit r ic acid, dichlorohydrant ion, heat , sparks, or other ignit ion sources, generat ion of dust , tem peratures above 320° c

Hazardous Decom posit ion Products: oxides of nit rogen, acetaldehyde, acet ic acid, am monia, carbon dioxide, aldehydes, hydrogen

SECTI ON 6 - TOXI COLOGI CAL PROPERTI ES

Route of Ent ry

Skin Contact : Yes Absorpt ion: Yes

Eye Contact : Yes

I nhalat ion: Yes I ngest ion: Yes

Effects to Acute exposure to Product : I nsufficient Data

Effects to Chronic exposure to Product : PROPYLENE GLYCOL has been known to cause LACTI C ACI DOSIS.

Exposure Lim its ( Value,Units,By) TI TANI UM DI OXI DE: 10 m g/ m 3 ACGI H PROPYLENE GLYCOL: 10 mg/ m3 AI HA

I r r itancy ( if yes, expla in)

Sensit izat ion ( if yes, expla in) Carcinogenicit y ( if yes, expla in) TI TANI UM DI OXI DE is possibly carcinogenic to hum ans(2B) by I ARC.

Reproduct ive Tox icit y ( if yes, expla in) Teratogenicit y ( if yes, expla in)

Mutagenicit y ( if yes, expla in) Synergist ic Products ( if yes, expla in)

SECTI ON 7 - PREVENTI VE MEASURES

Personal Protect ive Equipm ent

Gloves: No Respira tor : Yes

Eye: No Footw ear : No

Clothing: No

Other : No

I f checked, specify t ype: Respirator: NI OSH APPROVED

Engineer ing cont rols ( specify such as vent ila t ion, enclosed process) : Use m echanical vent ilat ion to reduce exposure, ground all equipm ent and avoid exposure to open flames or sparks.

Leak and Spill Procedure: Wear adequate protect ive equipment and elim inate all ignit ion sources. Contain spill with absorbant m aterial and place in a suitable covered and labeled container for disposal.

W aste Disposal: Check with Federal, Provincial and local governm ent regulat ions and requirem ents for disposal.

Handling Procedures and Equipm ent : Use in a well vent ilated area. Do not use with incompat ible substances and keep away from heat and all ignit ion sources. Use grounded and non-sparking equipm ent only.

Storage Requirem ents: Store in a cool, well vent ilated area out of direct sunlight . Store away from heat and all ignit ion sources. Storage facilit y should be m anufactured out of fire resistant m aterials.

Specia l Shipping I nform at ion: None Required

SECTI ON 8 - FI RST AI D MEASURES

I nhalat ion: Rem ove to fresh air . Get m edical help if there is any breathing difficulty.

I ngest ion: Do not induce vom it ing unless directed by a physician. I f conscious and alert , give two glasses of water. Seek m edical at tent ion im m ediately.

Skin Contact : Rem ove Contam inated clothing ( including shoes) and wash before reuse. Flush with large am ounts of soap and water. I f irr itat ion persists, seek m edical at tent ion.

Eye Contact : Flush eyes with large am ounts of lukewarm water for 20 m inutes, while holding eyelids open or unt il ir r itat ion subsides. I f ir r itat ion persist , get m edical at tent ion.

SECTI ON 9 - PREPARATI ON I NFORMATI ON

Prepared by: General Paint Technical Dept

Phone: (604) 253-3131

Preparat ion Date: Jul 03, 2012

MATERIAL SAFETY DATA SHEET PAGE 1 OF 4

DATE PREPARED: JUNE 01/06

REVISED: April 2/2012

SECTION: 1 MANUFACTURER: PRODUCT IDENTIFICATION

Strike First Corporation ABC SUPER 90 DRY CHEMICAL

c/o Steel Fire Equipment Multi-Purpose Dry Chemical

150 Superior Blvd. Fire Extinguisher

Mississuaga, ON

L5T 2L2

Phone: 1-905-564-1500

EMERGENCY PHONE:Canutec: 1-613-996-6666

SECTION: 2 HAZARDOUS INGREDIENTS

% *ACGIH *OSHA

mg/m3 mg/m3 OTHER

CHEMICAL NAME CAS # W/W TLV STEL PEL STEL IDLH

Mono Ammonium Phosphate 7722-76-1 95*

Mica 12001-26-2 <3 3 NE 3 NE NE NE

Attaclay 8031-18-3 <3 NE NE NE NE NE NE

Silicone Oil 63148-57-2 <1 NE NE NE NE NE NE

Calcium Carbonate 471-34-1 <1 NE NE NE NE NE NE

Silica 112926-00-8 <1 2 NE 6 NE NE NE

Yellow Pigment 5468-75-7 <1 NE NE NE NE NE NE

*ACGIH TLV for particulars, not otherwise classified = 10; OSHA PEL for particulars not otherwise

regulated, Total dust =15 Respirable fraction 5.

NE = Not established

SECTION :3 PHYSICAL DAT A

BOILING POINT Not applicable

VAPOR PRESSURE Not applicable

VAPOR DENSITY Not applicable

SOLUBILITY IN WATER Not soluble. Water repellent coating.

SPECIFIC GRAVITY Approximately 0.88

PERCENT VOLATILE BY Not applicable

VOLUME

EVAPORATION RATE Not applicable

pH: (10% solution) Approximately 9-10

APPEARANCE & This material is a finely divided yellow

COLOR powder.


MANUFACTURER: Strike First Corporation

PRODUCT IDENTIFICATION: ABC DRY CHEMICAL FIRE EXTINGUISHER

SECTION: 4 FIRE AND EXPLOSION DAT A

FLASH POINT Not applicable

FLAMMABLE LIMITS Lower (LEL) Not applicable

Upper (LEL) Not applicable

EXTINGUISHING MEDIA None This product is a fire extinguishing

agent.

SPECIAL FIREFIGHTING Incipient fire responders should wear eye

PROCEDURES protection. Structural fire fighters must

wear Self-Contained Breathing Apparatus

and full protective equipment.

SECTION: 5 HEALTH HAZARD DAT A

THRESHOLD LIMIT VALUE *ACGIH TLV for particulars, Not otherwise

classified = 10

OSHA PEL For particulars not otherwise regulated;

Total Dust =15, Respirable Fraction 5.

EFFECTS OF OVEREXPOSURE

Acute This extinguishing material presents only

a slight risk of causing acute health

effects. If such effects occur, they will be in

the form of mild irritation of the skin, nose, or

throat and moderate irritation of the eyes.

If ingested, this product may cause an

upset stomach.

Chronic This product is not known to cause

chronic illnesses or diseases.

EMERGENCY FIRST-AID PROCEDURES

SKIN EXPOSURE If spilled on skin, immediately begin

decontamination with running water.

Remove exposed or contaminated clothing,

taking care not to contaminate eyes. If

reddening or irritation occurs, victim and

rescuers must seek immediate medical

attention.

EYE EXPOSURE If chemical is splashed in eyes, open

victim's eyes while under gentle running

water. Use sufficient force to open eyelids.

Have victim "roll" eyes. Minimum flushing

is for 15 minutes.




SECTION: 5 EMERGENCY FIRST-AID PROCEDURES

INHALATION If chemical is inhaled, remove victim to

fresh air. If necessary, use artificial

respiration to support vital functions. If

reddening or irritation occurs, victim and

rescuers must seek immediate medical

attention.

SECTION: 6 REACTIVITY DATA

STABILITY Stable

INCOMPATIBILITY Strong acids. Reacts violently with lithium.

HAZARDOUS Carbon monoxide and carbon dioxide

DECOMPOSITION PRODUCT

HAZARDOUS Will not occur

POLYMERIZATION

SECTION: 7 SPILL OR LEAK PROCEDURES

SMALL SPILLS Sweep up the spilled solid and place all

spill residue in a double plastic bag and

seal.

LARGE SPILLS If it is determined that exposure guidelines

for nuisance particulates - 10 mg/m3

(total particulates) or 5 mg/m3 (respirable

particulates) is exceeded use Level C:

triple gloves (rubber gloves with nitrile gloves,

over latex gloves), chemically resistant

suit and boots, hard hat, and air purifying

respirator with a HEPA filter.

Sweep or vacuum.

Dispose of in accordance with Federal,Provincial and local hazardous waste disposal regulations.




SECTION: 8 SPECIAL PROTECTION INFORMATION

RESPIRATORY Respiratory protection is not expected to

PROTECTION be needed. Maintain airborne contaminant

concentrations below guidelines for

nuisance particulates: (see Section 5)

VENTILATION Use with adequate ventilation. Use a

mechanical fan or vent area to outside.

PROTECTIVE GLOVES Wear rubber gloves for routine industrial

use.

EYE PROTECTION Safety glasses.

OTHER PROTECTIVE Use body protection appropriate for task.

EQUIPMENT:

SECTION: 9 SPECIAL PRECAUTION S

PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE

All employees who handle this material should be trained to handle it

safety. Avoid breathing dusts generated by this product.

Avoid getting chemicals ON YOU or IN YOU.

OTHER PRECAUTIONS: None

SECTION: 10 TRANSPORTATION

Hazard Class or Division: Fire Extinguisher, Class 2.2

UN 1044

For additional information contact Strike First Corporation

No harm to the environment is expected from this preparation

Fire extinguishers are designed and produced for the specific purpose of providing a safe and efficientsafety tool to be used only in the fighting of fires. Improper or careless use may cause severe bodily

injury and/or property damage.

Contents are under pressure which is necessary to deliver the contained extinguishing agent to the fire

source.

- Contents under pressure. Do not puncture, incinerate or discharge into another person's face.

- Do not store at high temperatures above 120 degrees Farenheit or 49 degrees Celcius.

- Keep away from children.

- Avoid inhaling the extinguishing agent. Avoid inhaling smoke and fumes - all fires release toxic

substances that are hamful. DO NOT remain in a closed area after use: evacuate the area

immediately and ventilate thoroughly before re-entering.

- Although extinguishing agents are non toxic when used properly, contact with them may cause

irritation to eyes, nose, throat and other allergic symptoms.

Windshield Washer -45°C PC purple

Not available.

Not available.

Not available.

Mixture.

WIP-35404PC

Consumer products: Windshield de-icing fluid.

Recochem Inc.Communications and RegulatoryAffairs Department(905) 878-5544

Recochem Inc.850 Montee de LiesseMontreal, Quebec514-341-3550

Class B-2: Flammable liquidClass D-1B: Material causing immediate and serious toxic effects (Toxic).Class D-2A: Material causing other toxic effects (Very toxic).Class D-2B: Material causing other toxic effects (Toxic).

Material Safety Data SheetWHMIS (Pictograms) WHMIS (Classification) Personal protective equipment

Section 1. Product and Company IdentificationProductname /Trade name

Synonym

Chemical family

Chemical formula

Manufacturer/Supplier

Material uses

AssociatedProduct’s ItemCode

CAS #

In case ofemergency

Print date

Validation date 04/05/2011.

04/05/2011.

Extremely hazardous by the following route of exposure: of ingestion. Hazardous by the following route of exposure: ofinhalation. Slightly hazardous by the following route of exposure: of skin contact (irritant, permeator), of eye contact(irritant). Non-sensitizer to skin. Severe over-exposure can result in death.

Acute exposure to methanol, either through ingestion or breathing high airborne concentrations can result insymptoms appearing between 40 minutes and 72 hours after exposure. Symptoms and signs are usually limited toCNS, eyes and gastrointestinal tract. Because of the initial CNS’s effects of headache, vertigo, lethargy andconfusion, there may be an impression of ethanol intoxication. Blurred vision, decreased acuity and photophobia arecommon complaints. Treatment with ipecac or lavage is indicated in any patient presenting within two hours ofingestion. A profound metabolic acidosis occurs in severe poisoning and serum bicarbonate levels are a moreaccurate measure of severity than serum methanol levels. Treatment protocols are available from most majorhospitals and early collaboration with appropriate hospitals is recommended.

Section 2. Hazards identification

Potential Acute HealthEffects

Note to Physician

Emergency Overview

No known significant effects or critical hazards. Avoid prolonged contact with eyes, skin and clothing.

WARNING!

NOT EXPECTED TO PRODUCE SIGNIFICANT ADVERSE HEALTH EFFECTS WHEN THE RECOMMENDEDINSTRUCTIONS FOR USE ARE FOLLOWED.

See section 11 for more detailed information on health effects and symptoms.

Section 3. Composition, information on ingredients

There are no ingredients present which, within the current knowledge of the supplier and in theconcentrations applicable, are classified as hazardous to health or the environment and hence requirereporting in this section.

Canada

Name CAS number Conc. (% w/w)Methanol 67-56-1 40 - 50

Continued on next page

All Season Windshield Washer 15-408H52

Apr. 05 2011

Apr. 05 2011

Windshield Washer -45°C PCpurpl e

Page: 2/8Validated on 04/05/2011.

Wash out mouth with water. Remove dentures if any. Move exposed person to fresh air. Keep person warm and atrest. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink.Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do soby medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Getmedical attention if symptoms occur. Never give anything by mouth to an unconscious person. If unconscious, placein recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as acollar, tie, belt or waistband.

Immediately flush eyes with plenty of water for at least 20 minutes, occasionally lifting the upper and lower eyelids.Check for and remove any contact lenses. Get medical attention if irritation occurs.

Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention ifsymptoms occur. Wash clothing before reuse. Clean shoes thoroughly before reuse.

Move exposed person to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or ifrespiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Get medical attention ifsymptoms occur. If unconscious, place in recovery position and get medical attention immediately. Maintain an openairway. Loosen tight clothing such as a collar, tie, belt or waistband.

Section 4. First aid measuresEye contact

Skin contact

Inhalation

Ingestion

Notes to physician See section 2Contact poison treatment specialist immediately if large quantities have been ingested orinhaled.

No specific data.

Use an extinguishing agent suitable for the surrounding fire.

Explosive in the form of vapor when exposed to heat or flame. Vapor may travel considerable distance to source ofignition and flash back. When heated to decomposition, it emits acrid smoke and irritating fumes.

Highly flammable liquid and vapor.

Section 5. Fire-fighting measuresProducts of combustion

Fire-fighting media andinstructions

Fire Hazards

Explosion Hazards

Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble.Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposalcontainer. Dispose of via a licensed waste disposal contractor.

Stop leak if without risk. Move containers from spill area. Prevent entry into sewers, water courses, basements orconfined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillagewith non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in containerfor disposal according to local regulations (see section 13). Dispose of via a licensed waste disposal contractor.Note: see section 1 for emergency contact information and section 13 for waste disposal.

Section 6. Accidental release measuresSmall spill and leak

Large spill and leak


Apr. 05 2011 All Season Windshield Washer



Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool andwell-ventilated area, away from incompatible materials (see section 10) and food and drink. Keep container tightlyclosed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept uprightto prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmentalcontamination.

Put on appropriate personal protective equipment (see section 8). Eating, drinking and smoking should be prohibitedin areas where this material is handled, stored and processed. Workers should wash hands and face before eating,drinking and smoking.

Section 7. Handling and StorageHandling

Storage

Section 8. Exposure controls/personal protectionEngineering controls

Personal protection

Eyes

Body

Respiratory

Hands

Product name Exposure limitsUnited States

Methanol ACGIH TLV (United States, 1/2008). Absorbed through skin. TWA: 200 ppm 8 hour(s). TWA: 262 mg/m³ 8 hour(s). STEL: 250 ppm 15 minute(s). STEL: 328 mg/m³ 15 minute(s).OSHA PEL 1989 (United States, 3/1989). Absorbed through skin. TWA: 200 ppm 8 hour(s). TWA: 260 mg/m³ 8 hour(s). STEL: 250 ppm 15 minute(s). STEL: 325 mg/m³ 15 minute(s).NIOSH REL (United States, 6/2008). Absorbed through skin. TWA: 200 ppm 10 hour(s). TWA: 260 mg/m³ 10 hour(s).

No special ventilation requirements. Good general ventilation should be sufficient tocontrol worker exposure to airborne contaminants. If this product contains ingredientswith exposure limits, use process enclosures, local exhaust ventilation or otherengineering controls to keep worker exposure below any recommended or statutorylimits.

Safety eyewear complying with an approved standard should be used when a riskassessment indicates this is necessary to avoid exposure to liquid splashes, mists ordusts. Recommended: splash goggles

Personal protective equipment for the body should be selected based on the task beingperformed and the risks involved and should be approved by a specialist before handlingthis product.

Use a properly fitted, air-purifying or air-fed respirator complying with an approvedstandard if a risk assessment indicates this is necessary. Respirator selection must bebased on known or anticipated exposure levels, the hazards of the product and the safeworking limits of the selected respirator.

Chemical-resistant, impervious gloves complying with an approved standard should beworn at all times when handling chemical products if a risk assessment indicates this isnecessary. >8 hours (breakthrough time): nitrile rubber





Canada

STEL: 250 ppm 15 minute(s). STEL: 325 mg/m³ 15 minute(s).OSHA PEL (United States, 11/2006). TWA: 200 ppm 8 hour(s). TWA: 260 mg/m³ 8 hour(s).OSHA (United States, 2003). TWA: 200 ppm 8 hour(s). TWA: 260 mg/m³ 8 hour(s).

[1]Absorbed through skin.

Methanol US ACGIH 1/2008 200 262 - 250 328 - - - - [1]AB 6/2008 200 262 - 250 328 - - - - [1]BC 6/2008 200 - - 250 - - - - - [1]ON 6/2008 200 260 - 250 325 - - - - [1]QC 6/2008 200 262 - 250 328 - - - - [1]

Ingredient List name ppm mg/m³ Other ppm mg/m³ Other ppm mg/m³ Other Notations

CeilingSTEL (15 mins)TWA (8 hours)Occupational exposure limits

Not available.Boiling/condensationpoint

Liquid.

Not available.

8 to 11

Not available.

0.9 to 0.97

<1.11 [Air = 1]

<12.8 kPa (<96 mm Hg)

Soluble in water.

Not available.

Not available.

Alcohol. [Slight]

Not available.

Purple.

Lower: 6%Upper: 36%

Closed cup: 28°C (82.4°F) [Tagliabue.]

385°C (725°F)

May be combustible at high temperature.

Slightly flammable in the presence of the following materials or conditions: open flames, sparks and static dischargeand heat.Non-flammable in the presence of the following materials or conditions: shocks and mechanical impacts.Explosive in the form of vapor when exposed to heat or flame. Vapor may travel considerable distance to source ofignition and flash back. When heated to decomposition, it emits acrid smoke and irritating fumes.

2.1 compared to Butyl acetate.

Not available.

Section 9. Physical and chemical propertiesPhysical State andAppearance

Molecular weight

pH

Odour

Taste

Colour

Relative density

Vapor pressure

Vapour Density

Volatility

OdourThreshold

Viscosity

Solubility

The product is:

Auto-ignition temperature

Flash point

Flammable limits

Fire hazards in thepresence of varioussubstances

Evaporationrate

Melting/freezing point

VOC content OtherProperties

Not available.Not available.





The product is stable. Under normal conditions of storage and use, hazardous polymerization will not occur.

Slightly reactive or incompatible with the following materials: oxidizing materials, acids and alkalis.

Not available.

Section 10. Stability and reactivityStability

Conditions of instability

Incompatibility withvarious substances

Hazardous decompositionproducts

Under normal conditions of storage and use, hazardous decomposition products shouldnot be produced.

Acute toxicityProduct/ingredient name Result Species Dose Exposure

Chronic toxicity

Carcinogenicity

MutagenicityConclusion/Summary :

TeratogenicityConclusion/Summary :

Reproductive ToxicityConclusion/Summary :

ClassificationProduct/ingredient name ACGIH EPA NIOSH NTPIARC OSHA

Section 11. Toxicological Information

Canada

Methanol LC50 Inhalation Gas. Rat 64000 ppm 4 hoursLD50 Dermal Rabbit 15800 mg/kg -LD50 Dermal Rabbit 15840 mg/kg -LD50 Oral Rat 5600 mg/kg -LD50 Oral Rat 5600 mg/kg -

Methanol A5 4 - - - None.

Not available.

Not available.

Not available.

Conclusion/Summary Not available.

Conclusion/Summary Not available.

Conclusion/Summary May be fatal or cause blindness if swallowed.





Section 12. Ecological informationFor accidental discharges into the environment, see Section 6:"Accidental Release Measures" for suggestedinstructions.

Canada:

Aquatic ecotoxicity

Conclusion/Summary :Biodegradability

Conclusion/Summary : Not available.

Product/ingredient name Result Species ExposureMethanol Acute LC50 2500000 ug/L Marine water Crustaceans - Crangon crangon -

Adult48 hours

Acute LC50 3289 to 4395 mg/L Freshwater

Daphnia - Daphnia magna -Neonate - <24 hours

48 hours

Acute LC50 >100000 ug/L Fresh water Fish - Pimephales promelas -Juvenile (Fledgling, Hatchling,Weanling) - 0.2 to 0.5 g

96 hours

Not available.

Ecotoxicity No known significant effects or critical hazards.

The generation of waste should be avoided or minimized wherever possible. Dispose of surplus and non-recyclableproducts via a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at alltimes comply with the requirements of environmental protection and waste disposal legislation and any regional localauthority requirements. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains andsewers.

Waste information

Section 13. Disposal considerations

Disposal should be in accordance with applicable regional, national and local laws and regulations.

In containers of 450L or less, this product meets the requirementsfor exemption under TDG regulation special provisions, part 1,section 1.36b: Class 3, Flammable liquids: Alcohol Exemption.

No placard (handling and hazard label) required.

Section 14. Transport information

Proper Shipping Name(Canada) TDG

Special provisions

Not applicable.

Not applicable.

Class

Subsidiary class

Canada TDG Classification

Windshield washer antifreeze, Alcohol exempt.

Not applicable.

Not applicable.

UN number

Packing Group





Class

Not a pollutant.

Class 3: Flammable liquid.

Special provisions In containers of 5 L (5Kg) capacity or less this product is classifiedas a "Consumer Commodity" under DOT regulations.

Proper Shipping Name(United States) DOT

Alcohols, n.o.s. (Methanol)

Class 3: Flammable liquid.

Alcohols, n.o.s. (Methanol)

Marine pollutant

Proper Shipping NameIMDG

No placard (handling and hazard label) required.

Special provisions Emergency schedules (EmS)3-06

RemarksIn a means of containment of 5 L capacity or less this product isclassified as a "Limited Quantity".

-Subsidiary class

-Subsidiary class

International AirTransport Association(IATA)

For air shipment classification and associated regulations, please refer to the latest edition ofIATA Dangerous Goods Regulations.

Class

United States DOT (Classification)

IMDG Classification

III

UN 1987UN number

Packing Group

UN 1987

III

UN number

Packing Group

Not regulated.

U.S.A. Regulatory Lists

Section 15. Regulatory information

HCS Classification(U.S.A.)

Class B-2: Flammable liquidClass D-1B: Material causing immediate and serious toxic effects(Toxic).Class D-2A: Material causing other toxic effects (Very toxic).Class D-2B: Material causing other toxic effects (Toxic).

WHMIS Classification(Canada)

This product and/ or all of its components are on the TSCA inventory list.

This product and/ or all of its components are on the DSL.Canada DomesticSubstances List (DSL)Status





2

3

0

B

03

2

Hazardous MaterialInformation System(U.S.A.)

National FireProtectionAssociation(U.S.A.)

Health

Specific hazard

Reactivity

FlammabilityHealth

Flammability

Reactivity

Personal protection

Section 16. Other information

Validated and verified by Compliance and Technical Information Manager on 04/05/2011ph.# 905-878-5544.

Printed 04/05/2011.

Notice to readerTo the best of our knowledge, the informati on contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever fo rthe accuracy or completeness of the information contained herein.Final deter mination of suitability of any material is the sole responsibility of th e user. All materials may present unknown ha zards and should be used with caution. Although certainhazards are described herein, we cannot guarantee that these are the only hazards that exist.

MSDS are available at www.recochem.com


Apr. 05 2011 Apr. 05 2011

Argon

001004

Synthetic/Analytical chemistry.

5/6/2013.


Product nameAIRGAS INC., on behalf of its subsidiaries259 North Radnor-Chester RoadSuite 100Radnor, PA 19087-52831-610-687-5253

Product use

MSDS #Date ofPreparation/RevisionIn case of emergency

Section 1. Chemical product and company identification

Argon

:

::

:

Supplier

1-866-734-3438

Synonym : argon, compressed; Cryogenic Liquid Argon, Liquid Argon:

:

Inhalation

Emergency overview

Section 2. Hazards identification

Routes of entryPotential acute health effects

Acts as a simple asphyxiant.

Contact with rapidly expanding gas may cause burns or frostbite. Contact with cryogenicliquid can cause frostbite and cryogenic burns.

Ingestion is not a normal route of exposure for gases. Contact with cryogenic liquid cancause frostbite and cryogenic burns.

Contact with rapidly expanding gas may cause burns or frostbite. Contact with cryogenicliquid can cause frostbite and cryogenic burns.

Eyes

Skin

InhalationIngestion

Physical state Gas. [COLORLESS, ODORLESS INERT GAS OR LIQUID]

See toxicological information (Section 11)

WARNING!GAS:CONTENTS UNDER PRESURE.Do not puncture or incinerate container.Can cause rapid suffocation.May cause severe frostbite.LIQUID:Extremely cold liquid and gas under pressure.Can cause rapid suffocation.May cause severe frostbite.

Do not puncture or incinerate container.

::

:

:

:

::

Medical conditionsaggravated by over-exposure

Acute or chronic respiratory conditions may be aggravated by overexposure to this gas.:

Contact with rapidly expanding gases or liquids can cause frostbite.

Argon 7440-37-1 100 Oxygen Depletion [Asphyxiant]

Section 3. Composition, Information on IngredientsName % Volume Exposure limitsCAS number

Page: 1/6Build 1.1

Argon

As this product is a gas, refer to the inhalation section.

Check for and remove any contact lenses. Immediately flush eyes with plenty of waterfor at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medicalattention immediately.None expected.

Move exposed person to fresh air. If not breathing, if breathing is irregular or ifrespiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attentionimmediately.

Section 4. First aid measures

Eye contact

Skin contact

Inhalation

Ingestion

:

:

:

:

No action shall be taken involving any personal risk or without suitable training.If it is suspected that fumes are still present,the rescuer should wear an appropriate mask or self-contained breathing apparatus.It may be dangerous to the personproviding aid to give mouth-to-mouth resuscitation.

Frostbite : Try to warm up the frozen tissues and seek medical attention.

Non-flammable.No specific data.Use an extinguishing agent suitable for the surrounding fire.

Section 5. Fire-fighting measuresFlammability of the productProducts of combustionFire-fighting media andinstructions

Apply water from a safe distance to cool container and protect surrounding area. Ifinvolved in fire, shut off flow immediately if it can be done without risk.Contains gas under pressure. In a fire or if heated, a pressure increase will occur andthe container may burst or explode.

Special protectiveequipment for fire-fighters

Fire-fighters should wear appropriate protective equipment and self-contained breathingapparatus (SCBA) with a full face-piece operated in positive pressure mode.

:::

:

Immediately contact emergency personnel. Keep unnecessary personnel away. Usesuitable protective equipment (section 8). Shut off gas supply if this can be done safely.Isolate area until gas has dispersed.

Immediately contact emergency personnel. Stop leak if without risk. Note: see section 1for emergency contact information and section 13 for waste disposal.

Environmental precautions

Section 6. Accidental release measures

: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drainsand sewers.

Personal precautions :

Methods for cleaning up :

Cylinders should be stored upright, with valve protection cap in place, and firmly securedto prevent falling or being knocked over. Cylinder temperatures should not exceed 52 °C(125 °F).For additional information concerning storage and handling refer to Compressed GasAssociation pamphlets P-1 Safe Handling of Compressed Gases in Containers and P-12 Safe Handling of Cryogenic Liquids available from the Compressed Gas Association,Inc.

High pressure gas. Do not puncture or incinerate container. Use equipment rated forcylinder pressure. Close valve after each use and when empty. Protect cylinders fromphysical damage; do not drag, roll, slide, or drop. Use a suitable hand truck for cylindermovement. Never allow any unprotected part of the body to touch uninsulated pipes or vessels thatcontain cryogenic liquids. Prevent entrapment of liquid in closed systems or pipingwithout pressure relief devices. Some materials may become brittle at low temperaturesand will easily fracture.

Section 7. Handling and storageHandling

Storage

:

:

Page: 2/6Build 1.1

Argon

Use only with adequate ventilation. Use process enclosures, local exhaust ventilation orother engineering controls to keep worker exposure to airborne contaminants below anyrecommended or statutory limits.

argon Oxygen Depletion [Asphyxiant]

Section 8. Exposure controls/personal protectionEngineering controls

Product name

Use a properly fitted, air-purifying or air-fed respirator complying with an approvedstandard if a risk assessment indicates this is necessary. Respirator selection must bebased on known or anticipated exposure levels, the hazards of the product and the safeworking limits of the selected respirator.

Safety eyewear complying with an approved standard should be used when a riskassessment indicates this is necessary to avoid exposure to liquid splashes, mists ordusts.

Personal protective equipment for the body should be selected based on the task beingperformed and the risks involved and should be approved by a specialist before handlingthis product.

Personal protectionEyes

Skin

Respiratory

Consult local authorities for acceptable exposure limits.

:

:

:

:

Personal protection in caseof a large spill

: Self-contained breathing apparatus (SCBA) should be used to avoid inhalation of theproduct.

Chemical-resistant, impervious gloves complying with an approved standard should beworn at all times when handling chemical products if a risk assessment indicates this isnecessary.

Hands :The applicable standards are (US) 29 CFR 1910.134 and (Canada) Z94.4-93

When working with cryogenic liquids, wear a full face shield.

Insulated gloves suitable for low temperatures

-185.7°C (-302.3°F)-189.2°C (-308.6°F)

1.38 (Air = 1). Liquid Density@BP: 87 lb/ft3 (1393 kg/m3)-122.4°C (-188.3°F)

39.95 g/mole

Boiling/condensation pointMelting/freezing point

Section 9. Physical and chemical propertiesMolecular weight

Critical temperatureVapor density

ArMolecular formula::::::

Specific Volume (ft 3/lb) : 9.70874Gas Density (lb/ft 3) : 0.103

The product is stable.

Under normal conditions of storage and use, hazardous polymerization will not occur.

Under normal conditions of storage and use, hazardous decomposition products shouldnot be produced.

Section 10. Stability and reactivityStability and reactivityHazardous decompositionproductsHazardous polymerization

::

:

Section 11. Toxicological information

Specific effectsCarcinogenic effects No known significant effects or critical hazards.Mutagenic effects No known significant effects or critical hazards.Reproduction toxicity No known significant effects or critical hazards.

No specific information is available in our database regarding the other toxic effects ofthis material to humans.

Other toxic effects onhumans

:Toxicity data

:::

Page: 3/6Build 1.1

Argon

Section 12. Ecological information

Environmental fate : Not available.Environmental hazards : No known significant effects or critical hazards.Toxicity to the environment : Not available.

Aquatic ecotoxicityNot available.

Section 13. Disposal considerationsProduct removed from the cylinder must be disposed of in accordance with appropriate Federal, State, localregulation.Return cylinders with residual product to Airgas, Inc.Do not dispose of locally.

Section 14. Transport information

2.2 LimitedquantityYes.

PackaginginstructionPassengeraircraftQuantitylimitation:75 kg

Cargo aircraftQuantitylimitation:150 kg

DOT Classification

TDG Classification 2.2

ARGON,COMPRESSED

Argon, refrigeratedliquid

UN1006

UN1951

ARGON,COMPRESSED


Regulatoryinformation

UN number Proper shippingname

Class Packing group Label Additionalinformation

UN1006

UN1951

ExplosiveLimit andLimitedQuantityIndex0.125

PassengerCarryingRoad or RailIndex75

Specialprovisions42

MexicoClassification

UN1006

UN1951

ARGON,COMPRESSED


2.2 -

Not applicable (gas).



“Refer to CFR 49 (or authority having jurisdiction) to determine the information required for shipment of theproduct.”

Page: 4/6Build 1.1

Argon

Section 15. Regulatory information

U.S. Federal regulations

Connecticut Carcinogen Reporting: This material is not listed.Connecticut Hazardous Material Survey: This material is not listed.Florida substances: This material is not listed.Illinois Chemical Safety Act: This material is not listed.Illinois Toxic Substances Disclosure to Employee Act: This material is not listed.Louisiana Reporting: This material is not listed.Louisiana Spill: This material is not listed.Massachusetts Spill: This material is not listed.Massachusetts Substances: This material is listed.Michigan Critical Material: This material is not listed.Minnesota Hazardous Substances: This material is not listed.New Jersey Hazardous Substances: This material is listed.New Jersey Spill: This material is not listed.New Jersey Toxic Catastrophe Prevention Act: This material is not listed.New York Acutely Hazardous Substances: This material is not listed.New York Toxic Chemical Release Reporting: This material is not listed.Pennsylvania RTK Hazardous Substances: This material is listed.Rhode Island Hazardous Substances: This material is not listed.

TSCA 8(a) IUR: argonUnited States inventory (TSCA 8b): This material is listed or exempted.

Clean Water Act (CWA) 307: No products were found.Clean Water Act (CWA) 311: No products were found.

Clean Air Act (CAA) 112 regulated flammable substances: No products were found.Clean Air Act (CAA) 112 regulated toxic substances: No products were found.

State regulations

CEPA Toxic substances: This material is not listed.Canadian ARET: This material is not listed.Canadian NPRI: This material is not listed.Alberta Designated Substances: This material is not listed.Ontario Designated Substances: This material is not listed.Quebec Designated Substances: This material is not listed.

WHMIS (Canada) Class A: Compressed gas.

SARA 302/304/311/312 extremely hazardous substances: No products were found.SARA 302/304 emergency planning and notification: No products were found.SARA 302/304/311/312 hazardous chemicals: argonSARA 311/312 MSDS distribution - chemical inventory - hazard identification:argon: Sudden release of pressure

:

:

:

Canada

United States

Section 16. Other information

GAS:CONTENTS UNDER PRESURE.Do not puncture or incinerate container.Can cause rapid suffocation.May cause severe frostbite.LIQUID:Extremely cold liquid and gas under pressure.Can cause rapid suffocation.May cause severe frostbite.

Label requirements :

Label requirements : Class A: Compressed gas.

United States

Canada

Page: 5/6Build 1.1

Argon

3

0

0C

SA0

03Health

Special

Instability

Flammability

Health

Fire hazardReactivity

Personal protection

Notice to readerTo the best of our knowledge, the information contained herein is accurate. However, neither the above-namedsupplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of theinformation contained herein.Final determination of suitability of any material is the sole responsibility of the user. All materials may presentunknown hazards and should be used with caution. Although certain hazards are described herein, we cannotguarantee that these are the only hazards that exist.

SA0

00

National Fire ProtectionAssociation (U.S.A.)

Health

Special

Instability

Flammability:

liquid:

liquid:

Hazardous MaterialInformation System (U.S.A.)

0

0

0

Health

FlammabilityPhysical hazards

:

Page: 6/6Build 1.1

of 5

HMIS CodesHealth 2*

Flammability 3Reactivity 0

DATE OF PREPARATIONFeb 3, 2012

MATERIAL SAFETY DATA SHEET

E11902 00

SECTION 1 — PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NUMBERE119

PRODUCT NAMESpray Paint, Flat Black

MANUFACTURER'S NAMEMfd. for: J2 PRODUCTS54 Audia Court, Unit 2AConcord, ON L4K 3N4

Telephone Numbers and WebsitesProduct Information (905) 699-9410

Regulatory Information (216) 566-2902Medical Emergency (216) 566-2917

Transportation Emergency * (800) 424-9300for Chemical Emergency ONLY (spill, leak, fire, exposure, or accident)*

SECTION 2 — COMPOSITION/INFORMATION ON INGREDIENTS

% by Weight CAS Number Ingredient Units Vapor Pressure14 74-98-6 Propane

ACGIH TLV 2500 PPM 760 mmOSHA PEL 1000 PPM

13 106-97-8 ButaneACGIH TLV 800 PPM 760 mmOSHA PEL 800 PPM

16 108-88-3 TolueneACGIH TLV 20 PPM 22 mmOSHA PEL 100 ppm (Skin)OSHA PEL 150 ppm (Skin) STEL

36 67-64-1 AcetoneACGIH TLV 500 PPM 180 mmACGIH TLV 750 PPM STELOSHA PEL 1000 PPM

3 763-69-9 Ethyl 3-EthoxypropionateACGIH TLV Not Available 1.11 mmOSHA PEL Not Available

7 14807-96-6 TalcACGIH TLV 2 mg/m3 as Resp. DustOSHA PEL 2 mg/m3 as Resp. Dust

1 471-34-1 Calcium CarbonateACGIH TLV 10 mg/m3 as DustOSHA PEL 15 mg/m3 Total DustOSHA PEL 5 mg/m3 Respirable Fraction

0.4 1333-86-4 Carbon BlackACGIH TLV 3.5 MG/M3OSHA PEL 3.5 MG/M3

SECTION 3 — HAZARDS IDENTIFICATION

ROUTES OF EXPOSUREINHALATION of vapor or spray mist.EYE or SKIN contact with the product, vapor or spray mist.

EFFECTS OF OVEREXPOSUREEYES: Irritation.SKIN: Prolonged or repeated exposure may cause irritation.

INHALATION: Irritation of the upper respiratory system.

E119

page 2 of 5

UEL12.8

LEL1.0

FLASH POINTPropellant < 0 °F

May cause nervous system depression. Extreme overexposure may result in unconsciousness and possibly death.Prolonged overexposure to hazardous ingredients in Section 2 may cause adverse chronic effects to the following organs or systems:

the liverthe urinary systemthe cardiovascular systemthe reproductive system

SIGNS AND SYMPTOMS OF OVEREXPOSUREHeadache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists.Redness and itching or burning sensation may indicate eye or excessive skin exposure.

MEDICAL CONDITIONS AGGRAVATED BY EXPOSURENone generally recognized.

CANCER INFORMATIONFor complete discussion of toxicology data refer to Section 11.

SECTION 4 — FIRST AID MEASURES

EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention.SKIN: Wash affected area thoroughly with soap and water.

Remove contaminated clothing and launder before re-use.INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet.

INGESTION: Do not induce vomiting. Get medical attention immediately.

SECTION 5 — FIRE FIGHTING MEASURES

EXTINGUISHING MEDIACarbon Dioxide, Dry Chemical, Foam

UNUSUAL FIRE AND EXPLOSION HAZARDSContainers may explode when exposed to extreme heat.Application to hot surfaces requires special precautions.During emergency conditions overexposure to decomposition products may cause a health hazard. Symptoms may not be immediately

apparent. Obtain medical attention.SPECIAL FIRE FIGHTING PROCEDURES

Full protective equipment including self-contained breathing apparatus should be used.Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure

build-up and possible autoignition or explosion when exposed to extreme heat.

SECTION 6 — ACCIDENTAL RELEASE MEASURES

STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLEDRemove all sources of ignition. Ventilate the area.Remove with inert absorbent.

SECTION 7 — HANDLING AND STORAGE

STORAGE CATEGORYNot Available

PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGEKeep away from heat, sparks, and open flame. Vapors will accumulate readily and may ignite explosively.During use and until all vapors are gone: Keep area ventilated - Do not smoke - Extinguish all flames, pilot lights, and heaters - Turn off

stoves, electric tools and appliances, and any other sources of ignition.Consult NFPA Code. Use approved Bonding and Grounding procedures.Contents under pressure. Do not puncture, incinerate, or expose to temperature above 120F. Heat from sunlight, radiators, stoves, hot water,

and other heat sources could cause container to burst. Do not take internally. Keep out of the reach of children.

SECTION 8 — EXPOSURE CONTROLS/PERSONAL PROTECTION

PRECAUTIONS TO BE TAKEN IN USEUse only with adequate ventilation.Avoid contact with skin and eyes. Avoid breathing vapor and spray mist.Wash hands after using.This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels

only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts areACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction).

VENTILATIONLocal exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits.

Refer to OSHA Standards 1910.94, 1910.107, 1910.108.

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page 3 of 5

RESPIRATORY PROTECTIONIf personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator

approved by NIOSH/MSHA for protection against materials in Section 2.When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this

product, underlying paint, or the abrasive.PROTECTIVE GLOVES

None required for normal application of aerosol products where minimal skin contact is expected. For long or repeated contact, wear chemicalresistant gloves.

EYE PROTECTIONWear safety spectacles with unperforated sideshields.

OTHER PRECAUTIONSIntentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal.

SECTION 9 — PHYSICAL AND CHEMICAL PROPERTIES

PRODUCT WEIGHT 6.41 lb/gal 768 g/lSPECIFIC GRAVITY 0.77

BOILING POINT <0 - 342 °F <-18 - 172 °CMELTING POINT Not Available

VOLATILE VOLUME 92%EVAPORATION RATE Faster than ether

VAPOR DENSITY Heavier than airSOLUBILITY IN WATER N.A.

pH 7.0VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged)

Volatile Weight 47.26% Less Water and Federally Exempt Solvents

SECTION 10 — STABILITY AND REACTIVITY

STABILITY — StableCONDITIONS TO AVOID

None known.INCOMPATIBILITY

None known.HAZARDOUS DECOMPOSITION PRODUCTS

By fire: Carbon Dioxide, Carbon MonoxideHAZARDOUS POLYMERIZATION

Will not occur

SECTION 11 — TOXICOLOGICAL INFORMATION

CHRONIC HEALTH HAZARDSReports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage.Carbon Black is classified by IARC as possibly carcinogenic to humans (group 2B) based on experimental animal data, however, there is

insufficient evidence in humans for its carcinogenicity.

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page 4 of 5

TOXICOLOGY DATACAS No. Ingredient Name74-98-6 Propane

LC50 RAT 4HR Not AvailableLD50 RAT Not Available

106-97-8 ButaneLC50 RAT 4HR Not AvailableLD50 RAT Not Available

108-88-3 TolueneLC50 RAT 4HR 4000 ppmLD50 RAT 5000 mg/kg

67-64-1 AcetoneLC50 RAT 4HR Not AvailableLD50 RAT 5800 mg/kg

763-69-9 Ethyl 3-EthoxypropionateLC50 RAT 4HR Not AvailableLD50 RAT 5000 mg/kg

14807-96-6 TalcLC50 RAT 4HR Not AvailableLD50 RAT Not Available

471-34-1 Calcium CarbonateLC50 RAT 4HR Not AvailableLD50 RAT Not Available

1333-86-4 Carbon BlackLC50 RAT 4HR Not AvailableLD50 RAT Not Available

SECTION 12 — ECOLOGICAL INFORMATION

ECOTOXICOLOGICAL INFORMATIONNo data available.

SECTION 13 — DISPOSAL CONSIDERATIONS

WASTE DISPOSAL METHODWaste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261.Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers.Do not incinerate. Depressurize container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution.

SECTION 14 — TRANSPORT INFORMATION

Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shippingdescription for a particular mode of transport (ocean, air, etc.), does not indicate that the product is packaged suitably for that mode oftransport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the soleresponsibility of the person offering the product for transport.

US Ground (DOT)May be classed as Consumer Commodity, ORM-DUN1950, AEROSOLS, 2.1, LIMITED QUANTITY, (ERG#126)

Canada (TDG)May be classed as Consumer Commodity, ORM-DUN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, (ERG#126)

IMOMay be shipped as Limited QuantityUN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, EmS F-D, S-U, ADR (D)

IATA/ICAOUN1950, AEROSOLS, FLAMMABLE, 2.1, LIMITED QUANTITY

SECTION 15 — REGULATORY INFORMATION

SARA 313 SUPPLIER NOTIFICATION(40 CFR 372.65C)CAS No. CHEMICAL/COMPOUND % by WT % Element108-88-3 Toluene 16TSCA CERTIFICATION

All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory.

E119

page 5 of 5

SECTION 16 — OTHER INFORMATION

This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and theMSDS contains all of the information required by the CPR.

The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or otheradditives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make nowarranties, express or implied, and assume no liability in connection with any use of this information.


1 Of 3

SECTION I - PRODUCT IDENTIFICATION AND USE

PRODUCT IDENTIFIER CAN DRY SUPREME ABSORBENT

MANUFACTURER'S NAME Absorbent Products Ltd

STREET ADDRESS 724 East Sarcee St. 4 - extreme

CITY/PROVINCE Kamloops, BC 3 - high

POSTAL CODE V2H 1E7 2 - moderate

EMERGENCY TELEPHONE NUMBER: 1-800-667-0336 1 - slight

CHEMICAL NAME: Diatomaceous Earth 0 - insignificant

TRADE NAME: CAN DRY ABSORBENT NFPA HAZARD RATING:

CHEMICAL FAMILY: Silica Health - 1, Flammability - 0, Reactivity - 1

MATERIAL USE: Industrial Absorbent

SECTION II - HAZARDOUS INGREDIENTS OF MATERIAL

HAZARDOUS INGREDIENTS % CAS NUMBER OR OSHA PEL LD50/ /LC 50

UN NUMBER OR (ACGIH TLV) SPECIES AND ROUTE

NA NUMBER

100% 61790-53-2 see below N/av.

Free Crystalline Silica <1% 14808-60-7 see below N/av.

or Silica, quartz

SECTION III - PHYSICAL DATA FOR MATERIAL

PHYSICAL STATE solid ODOR AND APPEARANCE No odor, Buff / grey granules

VAPOR PRESSURE (mm Hg) N/ap. DENSITY (20 degrees Celcius) 35lb\cu. ft. +/- 5

VAPOR DENSITY (Air = 1) N/ap. SOLUBILITY IN WATER Insoluble, forms

SPECIFIC GRAVITY (Water=1) 2.0 colloidal suspension

FREEZING POINT N/ap. pH 5.5 - 6.5

BOILING POINT N/ap. slightly acidic in water

SECTION IV - FIRE AND EXPLOSION DATA

FLAMMABILITY (IF YES, UNDER WHICH CONDITIONS?) YES

NO X

MEANS OF EXTINCTION N/ap. SPECIAL PROCEDURES N/ap.

FLASHPOINT AND METHOD N/ap. UPPER FLAMMABILITY LIMIT (% BY VOLUME) N/ap.

AUTOIGNITION TEMPERATURE N/ap. LOWER FLAMMABILITY LIMIT (% BY VOLUME) N/ap.

HAZARDOUS COMBUSTION PRODUCTS N/ap.

EXPLOSION DATA:

SENSITIVITY IMPACT No SENSITIVITY TO STATIC DISCHARGE No

For sampling silica dusts refer to NIOSH Analytical Method 7500 or OSHA method ID 142

Abbreviations used on this Material Safety Data Sheet:

N/av. = Not available, N/ap. = Not applicable, ppm = parts per million, TLV = Threshold Limit Value.

NFPA Hazard Rating: 4-Extreme, 3-High, 2-Moderate, 1-Slight, 0-None, X-Blank

Naturally Occuring Diatomaceous

Earth

(Typical Analysis = 67% Silicon

Dioxide)

0

1 1

.

0

1 1

.

0

1 1

.

0

1 1

.


2 Of 3

MATERIAL IDENTIFIER: CAN DRY SUPREME ABSORBENT

SECTION V - HEALTH HAZARDS

Permissible Exposure Limits: OSHA PEL ACGIH OHS OHS STEL

(for airborne, nuisance dusts) 8 hr TWA TLV 8 hr TWA

Diatomaceous earth

Total dust 15 mg/m3

Not detected 4 mg/m3

n/a

Respirable dust 5 mg/m3

Not detected 1.5 mg/m3

n/a

Crystalline quartz (respirable) 0.1 mg/m3

0.1 mg/m3

0.025mg/m3

n/a

SECTION VI - REACTIVITY DATA

CHEMICAL STABILITY (IF NO, YES X

UNDER WHICH CONDITIONS) NO

INCOMPATIBILITY WITH OTHER SUBSTANCES YES X Hydrofluoric acid - silica may react violently

(IF YES, WHICH ONES) NO

REACTIVITY, AND UNDER WHAT CONDITIONS N/ap.

HAZARDOUS DECOMPOSITION PRODUCTS N/ap.

SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE

PERSONAL PROTECTIVE EQUIPMENT

GLOVES (SPECIFY) Not needed under normal conditions of use.

RESPIRATOR (SPECIFY) Avoid breathing dust. Use respirators approved NIOSH/OSHA for silica bearing dust.

EYE (SPECIFY) Use protective goggles in high dust conditions.

FOOTWEAR (SPECIFY) As required on jobsite.

Routes of Exposure and Effects:

Inhalation: Acute (short term) exposure to dust levels exceeding the PEL may cause irritation of respiratory tract resulting in a dry cough. Chronic (long term) exposure to

crystalline free silica contained by airborne diatomaceous earth dust where levels are higher than TLV's may lead to the development of silicosis or other respiratory problems.

Persistent dry cough, throat irritation and labored breathing on exertion are symptomatic. exposure may aggravate existing upper respiratory tract diseases such as asthma,

bronchitis or emphysema.

Eyes: Irritant.

Skin: Possible drying results in dermatitis.

Ingestion: No adverse effects.

Bureau of Mines or NIOSH approved respirators for protection against pneumoconiosis producing dusts recommended when dust is present. If the dust concentration is less

than ten (10) times the Permissible Exposure Limit (PEL) use quarter or half mask respirator with replacement dust filter or single use dust respirator with valve. If dust

concentration is greater than ten (10) times and less than one hundred (100) times the PEL use full faceplate respirator with replaceable dust filter; if greater than one hundred

(100) and less than two hundred (200) times the PEL use power air purifying (positive pressure) respirator with replaceable filter; if greater than two hundred (200) times the

PEL use type C, automatic-air respirator, continuous flow type (positive pressure), with full facepiece, head or helmet.

EFFECTS OF CHRONIC EXPOSURE TO PRODUCT

Exposure to quantities of crystalline silica dust, in the forms of quartz, cristobalite or tridymite, may be present in airborne dust. If the concentration levels are in excess of th

OSHA Permissible Limit (PEL-TWA 8hrs) of 0.05mg/m3 or the ACGIH Threshold Limit Value (TLV) of 0.05mg/m3, the crystalline silica is a known cause of silicosis, a

progressive, sometimes fatal, lung disease. From the International Agency for Research on Cancer (IARC), a 1997 review of "Crystalline Silica Inhaled in the Form of Quart

or Cristobalite" coded Monograph 68 concluded that Amorphous Silica is not classifiable to its carcinogenicity to humans (Group 3)


3 Of 3

MATERIAL IDENTIFIER: CAN DRY SUPREME ABSORBENT

SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE CONTINUED

CLOTHING (SPECIFY) Wear coveralls in high dust conditions.

ENGINEERING CONTROLS (SPECIFY, E.G. VENTILATION, ENCLOSED PROCESS)

Local - control within recommended TLV/PEL, mechanical filtration to minimize dust. Refer to ACGIH publication "Industrial

Ventilation" or similar publications for design of ventilation systems.

LEAK AND SPILL PROCEDURE

Vacuum clean spillage, wet sweep or wash away. Avoid creating dust.

WASTE DISPOSAL

Dispose of in accordance with local, state and federal regulations.

HANDLING PROCEDURES

Avoid creating dust. Repair or properly dispose of broken bags. Use wet process or enclosed handling.

STORAGE REQUIREMENTS

Store in a dry place to maintain product quality. Keep containers closed and in good condition. Repair damaged containers.

SPECIAL SHIPPING INFORMATION

None

SECTION VIII - FIRST AID MEASURES

SPECIFIC MEASURES

Inhalation: Remove victim to fresh air. If breathing has stopped, a trained person should perform artificial respiration.

Acute inhalation can cause dryness of the nasal passage and congestion of the upper respiratory tract.

Ingestion: Do not induce vomiting. Short-term exposure not considered harmful. Drink generous amounts of water to

reduce bulk and drying effects.

Eye: Wash with generous quantities of water. Consult physician if irritation persists. May cause irritation or inflammation.

Skin contact: Remove contaminated clothing. Wash with soap and water until clean. Use moisture renewing lotions

if dryness occurs. Not absorbed by the skin. May cause dryness.

SECTION IX - DEPARTMENT OF TRANSPORTATION

HAZARDOUS MATERIALS DESCRIPTION: None IDENTIFICATION NUMBER: None

TECHNICAL NAME: None LABEL(S) REQUIRED: None

HAZARDOUS CLASS: None

SECTION X - ENVIRONMENTAL DATA

SECTION XI - PREPARATION DATE OF MSDS

PREPARED BY: PHONE NUMBER DATE

Quality Control Staff, Absorbent Products Ltd. 1-800-667-0336 May, 2013

All information presented herein is believed to be accurate; however, it is the user's responsibility to determine in advance of need that the information is current and suitable for their circumstances. No warranty or guarantee, expressed

or implied is made by Absorbent Products Ltd., as to the information, or as to the safety, toxicity or the effect of this product.

EMERGENCY PLANNING AND COMMUNITY RIGHT TO KNOW INFORMATION

This product contains no toxic chemicals subject to the reporting requirements of section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40

CFR Part 372 (SARA 313 - Toxic Chemical Release Reporting).

EPA SARA 311/312 Hazard Classification: This product is considered hazardous under OSHA and SARA Title III, Section 301. Category: Chronic Health.

CERCLA Section 103: This product is not subject to CERCLA reporting requirements as it is sold. Refer to CERCLA regulations to determine if used product mixed with

other chemicals or materials may be reportable. Many states have more stringent release reporting requirements. Reports spills required under federal, state and local

regulations.

EPZ Toxic Substance Control Act (TSCA): All of the ingredients are listed on the TSCA Chemical Substances Inventory.

DOT Marine Pollutants: This product does not contain Marine Pollutants as defined in 49 CFR 171.8.

/6

Safety Data Sheetacc. to OSHA HCS

Printing date 10/07/2013 Reviewed on 10/07/2013

36.0.12

1 Identification of the substance/mixture and of the company/undertaking

· Trade name: CANTESCO ® PREMIUM ANTI-SPATTER- CONCENTRATE

· Article number: ENVIROSPAT, ES-16-P, ES-16-T, ES-1G, ES-5G, ES-DR, ES-4L, ES-20L· MSDS Number: 00104-CA-EN· UPC bar code(s):

699913-10250, 699913-10255, 699913-10260,699913-10265, 699913-10270

· Relevant identified uses of the substance:PREVENTS SPATTER BUILD UPIN WELDING APPLICATIONS

· Manufacturer/Supplier:WWW.CANTESCO.COM

USA ADDRESS :

KEMPER SYSTEM AMERICA, INC1200 NORTH AMERICA DR,WEST SENECA, NY 14224PH (716) 693-8206FAX (716) 558-2969

CANADIAN ADDRESS :

KEMPER SYSTEM CANADA13 - 5200 DIXIE ROADMISSISSAUGA, ON L4W 1E4PH (905) 624-5463FAX (905) 624-2840

· Information department:Tel: (716) 558-2971 ext. 228www.cantesco.com

· Emergency telephone number:ChemTrec (800) 424-9300Canada only: CANUTEC (Call collect) (613) 996-6666

2 Hazards identification

· Classification of the substance or mixture:The product is not classified according to the Globally Harmonized System (GHS).

· Information concerning particular hazards for human and environment:The product does not have to be labelled due to the calculation procedure of international guidelines.

· Classification system:The classification was made according to the latest editions of international substances lists, and expanded uponfrom company and literature data.

· NFPA ratings (scale 0 - 4):

00

0

Health = 0Fire = 0Reactivity = 0

CA

(Contd. on page 2)

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Trade name: CANTESCO ® PREMIUM ANTI-SPATTER- CONCENTRATE

(Contd. of page 1)

36.0.12

3 Composition/information on ingredients

· Chemical characterization: Mixtures· Description: Mixture of the substances listed below with nonhazardous additions.

· Dangerous components:

68412-54-4 Polyoxyethylene (9) nonylphenylether, branched

Acute Tox. 3, H301; Skin Irrit. 2, H315; Eye Irrit. 2A, H319

1-<3%

112-80-1 oleic acid, pure

Skin Irrit. 2, H315; Eye Irrit. 2A, H319; STOT SE 3, H335

≤1%

· Additional information: Exact concentrations are being withheld as trade secrets.

4 First aid measures

· General information: No special measures required.· After inhalation: Supply fresh air; consult doctor in case of complaints.· After skin contact: Generally the product does not irritate the skin.· After eye contact: Rinse opened eye for several minutes under running water.· After swallowing: If symptoms persist consult doctor.· Most important symptoms and effects, both acute and delayed: No further relevant information available.· Indication of any immediate medical attention and special treatment needed:

No further relevant information available.

5 Firefighting measures

· Suitable extinguishing agents:CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.

· Special hazards arising from the substance or mixture: No further relevant information available.· Protective equipment: No special measures required.

6 Accidental release measures

· Personal precautions, protective equipment and emergency procedures: Not required.· Environmental precautions: Dilute with plenty of water.· Methods and material for containment and cleaning up:

Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).· Reference to other sections:

No dangerous substances are released.See Section 7 for information on safe handling.See Section 8 for information on personal protection equipment.See Section 13 for disposal information.

7 Handling and storage

· Handling· Precautions for safe handling: No special measures required.· Information about protection against explosions and fires: No special measures required.· Storage· Requirements to be met by storerooms and receptacles: No special requirements.· Information about storage in one common storage facility: Not required.

(Contd. on page 3)

CA

/6




(Contd. of page 2)

36.0.12

· Further information about storage conditions: None.· Specific end use(s): No further relevant information available.

8 Exposure controls/personal protection

· Additional information about design of technical systems: No further data; see item 7.· Components with limit values that require monitoring at the workplace:

The product does not contain any relevant quantities of materials with critical values that have to be monitored atthe workplace.

· Additional information: The lists that were valid during the creation were used as basis.· Personal protective equipment· General protective and hygienic measures:

The usual precautionary measures for handling chemicals should be followed.· Breathing equipment: Not required.· Protection of hands:

The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation

· Material of gloves:The selection of the suitable gloves does not only depend on the material, but also on further marks of quality andvaries from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance ofthe glove material can not be calculated in advance and has therefore to be checked prior to the application.

· Eye protection: Goggles recommended during refilling.

9 Physical and chemical properties

· Form: Liquid· Color: Light beige· Odor: Mild· Odour threshold: Not determined.

· pH-value at 20 °C: 7

· Change in condition

Melting point/Melting range: 0 °C

Boiling point/Boiling range: 100 °C

· Flash point: Not applicable.

· Flammability (solid, gaseous): Not applicable.

· Ignition temperature:

Decomposition temperature: Not determined.

· Auto igniting: Product is not selfigniting.

· Danger of explosion: Product does not present an explosion hazard.

· Explosion limits

Lower: Not determined.

Upper: Not determined.

· Vapor pressure at 20 °C: 23 hPa

· Density at 20 °C: 1 g/cm³· Relative density: Not determined.

(Contd. on page 4)

CA

/6




(Contd. of page 3)

36.0.12

· Vapour density at 20 °C: .610 (AIR=1)· Evaporation rate at 20 °C: 1 (BA=1)

· Solubility in / Miscibility with

Water: Fully miscible.

· Partition coefficient (n-octanol/water): Not determined.

· Viscosity:

Dynamic: Not determined.

Kinematic: Not determined.

· Solvent content:

Organic solvents: 0.0 %

Solids content: 22.0 %· Other information No further relevant information available.

10 Stability and reactivity

· Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.· Possibility of hazardous reactions: No dangerous reactions known.· Conditions to avoid: No further relevant information available.· Incompatible materials: No further relevant information available.· Hazardous decomposition products: No dangerous decomposition products known.

11 Toxicological information

· Information on toxicological effects:· Acute toxicity· Primary irritant effect· on the skin: No irritant effect.· on the eye: No irritating effect.· Sensitization: No sensitizing effects known.· Additional toxicological information:

The product is not subject to classification according to internally approved calculation methods for preparations:When used and handled according to specifications, the product does not have any harmful effects according toour experience and the information provided to us.

· Carcinogenic categories

· IARC (International Agency for Research on Cancer)

102-71-6 2,2',2''-nitrilotriethanol 3

· NTP (National Toxicology Program)

None of the ingredients is listed.

12 Ecological information

· Aquatic toxicity: No further relevant information available.· Persistence and degradability: No further relevant information available.· Behavior in environmental systems· Bioaccumulative potential: No further relevant information available.· Mobility in soil: No further relevant information available.

(Contd. on page 5)

CA

/6




(Contd. of page 4)

36.0.12

· Other adverse effects: No further relevant information available.

13 Disposal considerations

· Waste treatment methods· Recommendation: Smaller quantities can be disposed of with household waste.

· Uncleaned packagings· Recommendation:

Place in a sealed container and label as waste. Place in a safe area, and comply with all federal, state, provincialand local regulations for disposal.

· Recommended cleansing agent: Water, if necessary with cleansing agents.

14 Transport information

· UN-Number· DOT, TDG, ADN, IMDG, IATA Not Available

· UN proper shipping name· DOT, TDG, ADN, IMDG, IATA Not Available

· Transport hazard class(es)

· DOT, TDG, ADN, IMDG, IATA· Class Not Available

· Packing group· DOT, TDG, IMDG, IATA Not Available

· Environmental hazards:· Marine pollutant: No

· Special precautions for user: Not applicable.

· Transport in bulk according to Annex II of

MARPOL73/78 and the IBC Code: Not applicable.

· UN "Model Regulation": -

15 Regulatory information

· Safety, health and environmental regulations/legislation specific for the substance or mixture· Sara

· Section 355 (extremely hazardous substances):


· Section 313 (Specific toxic chemical listings):


· TSCA (Toxic Substances Control Act):

All ingredients are listed.

· Proposition 65

· Chemicals known to cause cancer:


(Contd. on page 6)

CA

/6




(Contd. of page 5)

36.0.12

· Chemicals known to cause reproductive toxicity for females:


· Chemicals known to cause reproductive toxicity for males:


· Chemicals known to cause developmental toxicity:


· Carcinogenic categories

· EPA (Environmental Protection Agency):


· TLV (Threshold Limit Value established by ACGIH):


· NIOSH-Ca (National Institute for Occupational Safety and Health):


· OSHA-Ca (Occupational Safety & Health Administration):


· Canadian substance listings

· Canadian Domestic Substances List (DSL):

All ingredients are listed.

· Canadian Ingredient Disclosure list (limit 0.1%):


· Canadian Ingredient Disclosure list (limit 1%):

112-80-1 oleic acid, pure

16 Other information

This MSDS format meets ANSI Z400.1-1998, OSHA 1910.1200 and WHMIS requirements. Kemper SystemAmerica, Inc. provides the information contained herein in good faith but makes no representation as to itscomprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionaryhandling of the material by a properly trained person using this product. Product use and conditions of use arebeyond the control of Kemper System America, Inc. Warranty of materials is limited to test results of productperformance as detailed in certificates of compliance. Interpretation of test results is the responsibility of end-user.No other warranties, expressed or implied, are made. Kemper System America, Inc is an ISO 9001:2008registered company.

· Department issuing MSDS: Product safety department· Contact: Stephen Nowicki· Abbreviations and acronyms:

IMDG: International Maritime Code for Dangerous Goods

DOT: US Department of Transportation

IATA: International Air Transport Association

ACGIH: American Conference of Governmental Industrial Hygienists

NFPA: National Fire Protection Association (USA)

CA

Contractors Steel Company MATERIAL SAFETY DATA SHEET P.O. Box 3364 Livonia, Michigan 48150 (734) 464 4000 / Fax (734) 452 3939

(This product may contain chemicals subject to reporting requirements of section 313, Emergency Planning and Community Right To Know Act of 1986 and of 40CFR72)

Revision: March 12, 2013 Section 1 - Product Identification

Manufacturers Name: VARIOUS Product Name / Trade Name Carbon and Alloy Steels ( Bar ( Hot rolled- Round, Square, Strip, Flat )( Cold Finished - Round, Square, Flat )( Angle - Bar size, Structural )( Channel - Bar, Structural, Junior )( Beam - Standard I, Wide Flange & H, Junior )( Sheet - Hot rolled ) ( Plate - Floor, Abrasion Resisting )( Pipe )( Tubing - Square, Rectangular )( Expanded Metal - Standard, Flattened ) ( Bar size Tees) (Grating - Standard, Bar, Stair tread, Catwalk, Grip strut ) ( Molded Cover Bar ) ( Re rod )( Threaded Rod )( Rail) ( Structural Tees )) Galvanized ( Sheet, Round, Angle, Channel ) Section 2 - Ingredients

Components CAS# % Weight (1) ACGIH TLV (mg/m3) (Threshold limit value) (2) OSHA PEL (mg/m3) (Permissible exposure limit)

Base Metal Iron (Fe) 7439-89-6 balance 5 Oxide dust/fume 10 Oxide dust/fume

Alloying Elements

Aluminum (Al) 7429-90-5 0-.15 10

5

Dust

Fume

15

5

Dust

Respirable fraction

Antimony (Sb) 7440-36-0 < 1 .5 As Antimony .5 As Antimony

Arsenic As) 7440-38-2 < 1 .01 as Arsenic (A1 Carcinogen) .01 as Arsenic

Beryllium (Be) 7440-41-7 < 1 .002 as Beryllium (A1 Carcinogen) .002 as Beryllium

Boron (B) 7440-42-8 < 1 10 Oxide dust 15 Oxide dust

Cadmium (Cd) 7440-43-9 < 1 .01

.002

as Cadmium (A2 Carcinogen)

Respirable fraction

.005

.0025

as Cadmium

as Cadmium (action level)

Calcium (Ca) 1305-78-8 0-1 2 Oxide dust 5 Oxide dust

Carbon (C) 7440-4-0 .003-.1.1 not established not established

Chromium (Cr) 7440-47-3 .01-1 .5 Metal 1 Metal

Cobalt (Co) 7440-48-4 < 1 .02 as Cobalt (A3 Carcinogen) .1 Metal/Dust/Fume

Copper (Cu) 7440-50-8 .04-1 1

.2

Dust

Fume

1

.1

Dust

Fume

Lead Pb) 7439-92-1 0.-0.9 .05 Dust / Fume (A3 Carcinogen) .05 Dust / Fume

Magnesium (Mg) 7439-95-4 0-1 Not established Not established

Manganese (Mn) 7439-96-5 0.2-2 0.2 Elemental Mn and Inorg compounds 5 Fume (ceiling)

Molybdenum (Mo) 7439-98-7 0.01-0.8 10 Insoluble compounds 15 Insoluble compounds

Niobium (Nb) 7440-03-1 0-1 Not established

Nickel (Ni) 7440-02-0 0.01-1 1.5 Metal 1 Metal and insoluble compounds

Nitrogen (N) 7727-37-9 < 1 simple Asphyxiant simple Asphyxiant

Phosphorus (P) 7723-14-0 0-1 0.1 Phosphorus 0.1 Phosphorus

Selenium (Se) 7782-49-2 < 1 0.2 Selenium 0.2 Selenium

Silicon (Si) 7440-21-3 0-3 10 Dust 15 Dust

Sulfur (S) 7446-09-5 0-1 5.2

13

Sulfur dioxide

Sulfur dioxide (STEL)

13 Sulfur dioxide

Tin (Sn) 7723-14-0 0-1 2 Metal, oxide and organic compounds 2 Inorganic compounds

Titanium (Ti) 7440-32-6 0-1 Not established Not established

Tungsten (W) 7440-33-7 0-1 5

10

Insoluble compounds as W

Insoluble compounds as W (STEL)

not Established

Vanadium (V) 7440-62-2 0-1 0.05 Oxide Dust/Fume 0.5

0.1

Oxide dust (ceiling)

Oxide Fume (ceiling)

Zinc (Zn) 7440-66-6 0.-.05 10

5

10

Oxide dust

Oxide fume

Oxide fume (STEL)

5

10

Oxide fume

Oxide dust

(1) % of alloying material varies with grade of material. (2) ACGIH Threshold Limit Value. (NOTE: No OSHA PEL’s or ACGIH TLV’s exist for steel. Various grades of steel will contain different combinations of these elements and/or trace elements..

Section 3 - Physical Data

Material is (at normal conditions)

Solid

Appearance and Odor (Carbon) Gray-Black metallic, Odorless (Galvanized) Silver or Bluish white

Melting Point (Base Metal)>2500o F

420o C (Galvanized)

Specific Gravity

approximately 7

Boiling Point (Galvanized) 908o C Vapor pressure (mm Hg.)Galvanized 1 mmHg 487o C Vapor Density (Air = 1)

No information Found (NIF)

Evaporation Rate

NIF

pH N/A Solubility in water(% by weight) N/A Percent Volatile by Volume (%) N/A

Section 4 - Fire and Explosion Data

Extinguishing Media ( Base Metal) N/A (Galvanized) CO2 Dry Powder extinguisher - Do not use water Special Fire Fighting Procedures Steel products in the solid state present no fire or explosion hazard

Unusual Fire and Explosion Hazards Zinc oxide fume Flash Point (method used) Auto ignition (solid zinc in oxygen) 908o C Special fire fighting procedures Self - contained breathing apparatus Section 5 - Reactivity Data

Stability Stable Incompatibility (Materials to Avoid) Reacts with strong acids to produce Hydrogen gas(Galvanized)Avoid contact with acids and Alkalis

Conditions to avoid N/A Hazardous Decomposition Products Zinc forms zinc oxide fumes at boiling point Metallic dust or fumes may be produced during welding, burning, grinding and machining

6-2hri3.doc Revision 03/12/13

Section 6 - Health Hazard Data Note: Steel products in their natural state do not present an inhalation, ingestion or contact hazard. However, operations such as Burning, Welding, Sawing, Brazing, Grinding and Machining may release fumes and/or dusts which may present health hazards if TLV’s are exceeded. The major exposure hazard is inhalation. Effects of overexposure to fumes and dust are as follows:

ACUTE: Excessive inhalation of metallic fumes and dust may result in irritation of eyes, nose, and throat. High concentrations of fumes and dust of iron-oxide, manganese, and zinc may result in metal fume fever. Typical symptoms last from 12 to 48 hours and consist of a metallic taste in the mouth, dryness and irritation of the throat, chills and fever

CHRONIC: Chronic health effects (including cancer) have been associated with the fumes and dusts of individual component metals, and welding fumes as a general category have been listed by IARC as a carcinogen. See conditions listed opposite the element: Iron (Fe) siderosis, a benign pneumoconiosis, symptoms may include chronic bronchitis, emphysema, and shortness of breath, breathing fumes may result in metal

fume fever. Penetration of iron particles into the skin or eye may cause an exogenous or ocular siderosis. Ingestion overexposures may affect the

gastrointestinal, nervous, hematopoietic system and the liver

Aluminum (Al) breathing fumes may result in metal fume fever

Antimony (Sb) breathing fumes may result in metal fume fever

Arsenic As) breathing fumes may result in metal fume fever

Beryllium (Be) breathing fumes may result in metal fume fever

No chronic debilitating symptoms indicated

Bismuth no information available

Boron (B) breathing fumes may result in metal fume fever, Primary target organs are the lung and kidney. Because of its cumulative nature, chronic cadmium

poisoning can cause serious disease which takes many years to develop and may continue to progress despite cessation of exposure. Progression of the

disease may not reflect current exposure conditions. It is also capable of causing a painful osteomalacia called “Itai-Itai” in postmenopausal women, and

has caused developmental effects and/or reproductive effects in male / female animals. Cadmium is a listed carcinogen.

Cadmium (Cd) No information available

Calcium (Ca) No chronic debilitating symptoms indicated

Carbon (C) breathing fumes may result in metal fume fever. Prolonged and repeated overexposure to dust or fumes may cause skin ulcers, nasal irritation and

ulceration, kidney damage and cancer of the respiratory system. Is listed as a carcinogen

Chromium (Cr) breathing fumes may result in metal fume fever

Cobalt (Co) Dust and fume can irritate the eyes, nose and throat causing coughing, wheezing, nosebleeds, ulcers and metal fume fever. Other effects from repeated

inhalation include a metallic or sweet taste, discoloration of skin, teeth or hair, and allergic skin reaction.

Copper (Cu) breathing fumes may result in metal fume fever, Lead can accumulate in the body. Consequently, exposure to fumes or dust may produce signs of

polyneuritis, diminished vision and peripheral neuropathy, such as tingling and loss of feeling in fingers, arms and legs. Lead is a known reproductive

and developmental toxin. It is also associated with central nervous system disorders, anemia, kidney disfunction and neurobehavioral abnormalities. The

brain is a major target organ. Lead is a listed carcinogen

Lead Pb) breathing fumes may result in metal fume fever

Magnesium (Mg) breathing fumes may result in metal fume fever, Bronchitis,and pneumonitis. A variety of neurological symptoms including muscle spasms, gait

disturbances, tremors, and psychoses.

Manganese (Mn) No information available

Molybdenum Mo) No chronic debilitating symptoms indicated

Niobium (Nb) breathing fumes may result in metal fume fever, Prolonged and repeated contact may cause sensitization dermatitis. Inhalation has caused lung damage

as well as sinus, nasal and lung cancer in lab animals. Nickel is a listed carcinogen.

Nickel (Ni) No information available

Nitrogen (N) Necrosis of the mandible

Phosphorus (P) breathing fumes may result in metal fume fever

Selenium (Se) No chronic debilitating symptoms indicated

Silicon (Si) (as sulfur dioxide) Edema of the lungs

Sulfur (S) breathing fumes may result in metal fume fever

Tin (Sn) No information available

Titanium (Ti) No information available

Tungsten (W) The major target for vanadium pentoxide toxicity is the respiratory tract. Fumes or dust can cause severe eye and respiratory irritation and systemic

effects. Emphysema, pneumonia, Chronic bronchitis, green tongue, conjunctivitis, pharyngitis, rhinitis, rales, chronic productive cough, tightness of the

chest, and allergic reactions have been reported following overexposure.

Vanadium (V) breathing fumes may result in metal fume fever, as vanadium pentoxide - Emphysema, pneumonia

Zinc (Zn) Gastrointestinal inflammation reported in animal studies

Carcinogen(N.T.P.) N/A Carcinogen(I.A.R.C.) N/A Medical conditions aggravated by exposure: Individuals with chronic respiratory disorders may be adversely affected by any fume or airborne particulate matter exposure Emergency Medical Procedures: Inhalation: Remove to fresh air, if condition continues, consult a physician. Eye Contact: Flush thoroughly with running water to remove particulate, obtain medical attention. Skin Contact: Remove particles by washing thoroughly with soap and water. Seek medical attention if condition persists. Ingestion: If significant amounts of metal are ingested, consult a physician

HMIS RATING - Health 0 Flammability 0 Reactivity 0 HMIS HAZARD INDEX - Minimal 0 Slight 1 Moderate 2 Serious 3 Severe 4Section 7 - Environmental Protection Spill or Leak procedures: Fine turnings and small chips should be swept or vacuumed. Scrap metal can be reclaimed for reuse. Waste Disposal Method: Used or unused product should be disposed of in accordance with Federal, State and Local disposal or discharge laws. Section 8 - Special Protection Information Respiratory Protection: An appropriate dust/mist/fume respirator should be used to avoid excessive inhalation of particulate. If exposure limits are reached or exceeded, use NIOSH approved equipment. Hands, Arms, and Body: Protective gloves should be worn as required for welding burning or handling operations. Eyes and Face: Face shields or goggles should be worn when grinding or cutting. Face shields should be worn when welding or cutting. Other Clothing and Equipment: As required depending on operations and safety codes

In welding, precautions should be taken for airborne contaminants which may originate from components of the welding rod. Arc or Spark generated when welding or burning could be a source of ignition for combustible and flammable materials

DISCLAIMER The information in this MSDS was obtained from sources which we believe are reliable, however, the information is provided without any representation or warranty, express or implied, regarding the accuracy or correctness. The conditions or methods of handling, storage, use and disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use, or disposal of the product.

6-2hri3.doc Revision 03/12/13

SAFETY DATA SHEET Prepared by Duro Dyne December 27, 2013

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Trade name: DURO DYNE SOLVENT BASED ADHESIVE

Product Identifier: RPG-1, RPG-5, RPG-55

Item #: 5047, 5048, 5049

Supplier Details: DURO DYNE CORPORATION

81 Spence Street

Bay Shore, NY 11706

Information Phone No: 800-899-3876

Emergency Phone No: 800-424-9300 (CHEMTREC)

2. HAZARD IDENTIFICATION

Permissible Exposure Level: 50 ppm

Threshold Limit Value: 50 ppm

Effects of Acute Overexposure:

Eyes: Can cause severe irritation, redness, tearing, blurred

vision.

Skin: Prolonged or repeated contact can cause moderate

irritation, defatting, dermatitis.

Breathing: Excessive inhalation or vapors can cause nasal and

respiratory irritation, central nervous system effects

including dizziness, weakness, fatigue, nausea, headache

and possible unconsciousness, and even death.

Swallowing: Can cause gastrointestinal irritation, nausea, vomiting and

diarrhea. Aspiration of material into the lungs can cause

chemical pneumonitis, which can be fatal.

Effects of Chronic Overexposure: Prolonged or repeated exposure to N-Hexane may damage

peripheral nerve tissue (that of the arms and legs) and

result in muscular weakness and loss of sensation in the

extremities (Peripheral Neuropathy). Methyl Ethyl Ketone

may potentate (shorten time of onset) peripheral

neuropathy caused by N-Hexane. Prolonged and repeated

inhalation of high levels of mixed isomers of Hexane

resulted kidney damage in male rats. The effects observed

are the same of those seen in male rats exposed to other

hydrocarbons. The mechanism by which these chemicals

cause the characteristics kidney toxicity is unique to the

male rat and the kidney effects are not expected to occur

in man. Overexposure to this material (or its components)

has been suggested as a cause of the following effects in

HEALTH 2

FLAMMABILITY 3

REACTIVITY 0

Page 1 of 4

2. HAZARD IDENTIFICATION continued

humans and may aggravate pre-existing disorders of these

organs, central nervous system, and visual impairment.

3. COMPOSITION/INFORMATION ON INGREDIENTS

PRINCIPAL HAZARDOUS

COMPONENTS

% BY

WEIGHT

CAS# THRESHOLD LIMIT

VALUE

Toluene 12.5% 108-88-3 100 ppm

Hexane 55.5% 110-54-3 50 ppm

These chemicals are subject to the reporting requirements of Section 313 of Sara Title III. OSHA, NTP

or IARC does not class the ingredients in this product as carcinogens. All ingredients in this product are

on the TSCA Inventory.

4. FIRST AID MEASURES

Skin: Thoroughly wash exposed area with soap and water.

Remove contaminated clothing. Launder contaminated

clothing before re-use.

Eyes: Flush with large amounts of water. Lifting upper and

lower lids occasionally, Get medical attention.

Ingested: Do not induce vomiting. Keep person warm, quiet and get

medical attention. Aspiration of material into the lungs

due to vomiting can cause chemical pneumonits, which

can be fatal.

Inhalation: If affected remove individual to fresh air. If breathing is

difficult, administer oxygen. If breathing has stopped give

artificial respiration. Keep person warm, quiet and get

medical attention.

Primary Routes of Entry: Inhalation, skin contact.

Effects of Chronic Overexposure: Prolonged or repeated exposure to N-Hexane may

Damage peripheral nerve tissue(that of the arms and

legs) and result in muscular weakness and loss of

sensation in the extremities (Peripheral Nauropathy).

Methyl Ethyl Ketone may potentate (shorten the time of

onset) peripheral neuropathy caused by N-Hexane.

Prolonged and repeated inhalation of high levels of

mixed isomers of Hexane resulted kidney damage in

male rats. The effects observed are the same of those

seen in male rats exposed to other hydrocarbons. The

mechanism by which these chemicals cause the

characteristic kidney toxicity is unique to the male rat

and the kidney effects are not expected to occur in man.

Overexposure to this material (or its components) has

been suggested as a cause of the following effects in

humans and may aggravate pre-existing disorders of

these organs, central nervous system, and visual

impairment.

Page 2 of 4

5. FIRE-FIGHTING MEASURES

Flash Point (Test Method): Tag closed cup. <0°F

Flammable Limits: LEL: 1.2%

UEL: 6.9%

Extinguishing Media: Foam, dry chemical CO2, water fog or spray.

Special Fire Fighting Procedures: Use air supplied breathing equipment for enclosed areas.

Avoid breathing of vapor or fumes.

Unusual Fire & Explosion Hazards: Heat may build up pressure in closed containers. Cool

with water spray.

6. ACCIDENTAL RELEASE MEASURES

Spill Response: Remove all ignition sources. Keep people away. Recover

liquid. Add absorbent sawdust, etc. Ventilate, wipe up.

Place in sealed containers.

7. HANDLING AND STORAGE

Hygienic Practices in Handling & Storage: Flammable mixture. Do not store near heat, sparks or

open flame. Use with adequate ventilation. Avoid

prolonged or repeated breathing of vapor or contact with

skin. Do not take internally, in an emergency call a

physician. Keep out of reach of children.

Do not store with strong oxidants like liquid chlorine or

concentrated oxygen.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Eye Protection: Splash goggles or safety glasses.

Skin Protection: Chemical resistant gloves.

Respiratory Protection (Specific Type): NIOSH approved dual cartridge respirator with cartridges

suitable for organic solvent vapor.

Ventilation Recommended: Adequate = to outdoors.

Other Protection: Eye wash, safety shower.

9. PHYSICAL AND CHEMICAL PROPERTIES

Boiling Point: 150°F

Specific Gravity (Water = 1): .77

Vapor Pressure (mmHg): 180

Percent Volatile: 68% by weight

Vapor Density (Air = 1): 3

Evaporation Rate (N-Butyl Aceate = 1): 8

Solubility in Water: Not Soluble.

Appearance & Odor: Amber colored syrup, mild odor.

Volatile Organic Content: 4.43 lbs/gal or 531 grams/liter

Page 3 of 4

10. STABILITY AND REACTIVITY

Stability: Stable

Conditions to Avoid: None

Incompatibility/Materials to Avoid: Strong oxidants like liquid chlorine.

Hazardous Polymerization: Will not occur.

Conditions to Avoid: None

Hazardous Decomposition of Products: If burned, fumes could contain oxides of carbon and

nitrogen.

11. TOXICOLOGICAL INFORMATION

No information available.

12. ECOLOGICAL INFORMATION

No information available.

13. DISPOSAL METHOD

Waste Disposal Method: Approved site. Obey local, state and federal regulations.

14. TRANSPORT INFORMATION Proper DOT Shipping Name: Adhesive Containing Flammable Liquid,3, PG II.

15. REGULATORY INFORMATION

Chemical Family: Solvent Based Adhesive

DOT Hazard Classification: UN 133

16. OTHER INFORMATION

Warning: This product contains chemicals known to the State of

California to cause cancer.

Do not store with strong oxidants like liquid chlorine or

concentrated oxygen.

Hazard Rating: Health: 2

Flammability: 3

Reactivity: 0

Date SDS Prepared: April 3, 2012

THE INFORMATION AND RECOMMENDATIONS SET FORTH HEREIN ARE BELIEVED TO BE ACCURATE. BECAUSE SOME

OF THE INFORMATION IS DERIVED FROM INFORMATION PROVIDED TO DURO DYNE CORPORATION FROM ITS

SUPPLIERS, DURO DYNE CORPORATION MAKES NO WARRANTY, EXPRESSED OR IMPLIED, REGARDING THE ACCURACY

OF THE DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF. SINCE THE USE OF THIS INFORMATION AND

THE CONDITIONS AND USE OF THIS PRODUCT ARE CONTROLLED BY THE USER, IT IS THE USER'S OBLIGATION TO

DETERMINE THE CONDITIONS OF SAFE USE OF THE PRODUCT. THE INFORMATION IS SUPPLIED FOR YOUR

INFORMATION AND CONSIDERATION AND DURO DYNE CORPORATION ASSUMES NO RESPONSIBILITY FOR USE OR

RELIANCE THEREON. IT IS THE RESPONSIBILITY OF THE USER OF DURO DYNE CORPORATION PRODUCTS TO COMPLY

WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL LAWS AND REGULATIONS.

Page 4 of 4

3M™ Abrasive Products, 011K, Emery Cloth Sheets, Medium, Coarse 03/11/14

__________________________________________________________________________________________ Page 1 of 11

Safety Data Sheet

Copyright,2014,3M Company.

All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is

allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from

3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.

Document Group: 25-0157-5 Version Number: 1.06

Issue Date: 03/11/14 Supercedes Date: 03/22/13

SECTION 1: Identification

1.1. Product identifier

3M™ Abrasive Products, 011K, Emery Cloth Sheets, Medium, Coarse

1.2. Recommended use and restrictions on use

Recommended useAbrasive Product

1.3. Supplier’s details

MANUFACTURER: 3M

DIVISION: Abrasive Systems Division

ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA

Telephone: 1-888-3M HELPS (1-888-364-3577)

1.4. Emergency telephone number

1-800-364-3577 or (651) 737-6501 (24 hours)

SECTION 2: Hazard identification

2.1. Hazard classificationNot classified as hazardous according to OSHA Hazard Communication Standard, 29 CFR 1910.1200.

2.2. Label elements

Signal wordNot applicable.

Symbols

Not applicable.

Pictograms

Not applicable.

Notes to Physician:

Not applicable

2.3. Hazards not otherwise classifiedNone.


__________________________________________________________________________________________ Page 2 of 11

48% of the mixture consists of ingredients of unknown acute oral toxicity.

SECTION 3: Composition/information on ingredients

Ingredient C.A.S. No. % by Wt

Aluminum Oxide Mineral (non-fibrous) 1344-28-1 15 - 30

Iron Oxide Mineral 1309-37-1 5 - 15

Limestone 1317-65-3 5 - 15

Silica 7631-86-9 1 - 2

Titanium Dioxide 13463-67-7 0.5 - 1.5

Quartz Silica 14808-60-7 0.001 - 0.25

Cured Resin Mixture 2 - 15

Cloth Backing Mixture 15 - 40

SECTION 4: First aid measures

4.1. Description of first aid measures

Inhalation: Remove person to fresh air. If you feel unwell, get medical attention.

Skin Contact:

Wash with soap and water. If signs/symptoms develop, get medical attention.

Eye Contact:

Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get

medical attention.

If Swallowed:

Rinse mouth. If you feel unwell, get medical attention.

4.2. Most important symptoms and effects, both acute and delayed

See Section 11.1. Information on toxicological effects.

4.3. Indication of any immediate medical attention and special treatment requiredNot applicable

SECTION 5: Fire-fighting measures

5.1. Suitable extinguishing media

In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish.

5.2. Special hazards arising from the substance or mixture

None inherent in this product.

Hazardous Decomposition or By-Products

Substance Condition

Carbon monoxide During Combustion

Carbon dioxide During Combustion

5.3. Special protective actions for fire-fighters

No unusual fire or explosion hazards are anticipated.


__________________________________________________________________________________________ Page 3 of 11

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Observe precautions from other sections.

6.2. Environmental precautions

Not applicable.

6.3. Methods and material for containment and cleaning upNot applicable.

SECTION 7: Handling and storage

7.1. Precautions for safe handlingFor industrial or professional use only. Avoid breathing of dust created by sanding, grinding or machining. Do not eat, drink

or smoke when using this product. Wash thoroughly after handling. Combustible dust may form by action of this product on

another material (substrate). Dust generated from the substrate during use of this product may be explosive if in sufficient

concentration with an ignition source. Dust deposits should not be allowed to accumulate on surfaces because of the potential

for secondary explosions.

7.2. Conditions for safe storage including any incompatibilities

No special storage requirements.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Occupational exposure limits

Ingredient C.A.S. No. Agency Limit type Additional Comments

Iron Oxide Mineral 1309-37-1 Amer Conf of

Gov. Indust.

Hyg.

TWA(respirable fraction):5

mg/m3

Iron Oxide Mineral 1309-37-1 US Dept of

Labor - OSHA

TWA(as fume):10 mg/m3

ROUGE 1309-37-1 US Dept of

Labor - OSHA

TWA(as total dust):15

mg/m3;TWA(respirable

fraction):5 mg/m3

Limestone 1317-65-3 US Dept of

Labor - OSHA



fraction):5 mg/m3

Aluminum Oxide Mineral (non-

fibrous)

1344-28-1 Chemical

Manufacturer

Rec Guid

TWA:1 fiber/cc

Aluminum Oxide Mineral (non-

fibrous)

1344-28-1 US Dept of

Labor - OSHA



fraction):5 mg/m3

Aluminum, insoluble compounds 1344-28-1 Amer Conf of

Gov. Indust.

Hyg.

TWA(respirable fraction):1

mg/m3

Titanium Dioxide 13463-67-7 Amer Conf of

Gov. Indust.

Hyg.

TWA:10 mg/m3


__________________________________________________________________________________________ Page 4 of 11

Titanium Dioxide 13463-67-7 Chemical

Manufacturer

Rec Guid

TWA(as respirable dust):5

mg/m3

Titanium Dioxide 13463-67-7 US Dept of

Labor - OSHA

TWA(as total dust):15 mg/m3

Quartz Silica 14808-60-7 Amer Conf of

Gov. Indust.

Hyg.

TWA(respirable

fraction):0.025 mg/m3

Quartz Silica 14808-60-7 US Dept of

Labor - OSHA

TWA concentration(as total

dust):0.3 mg/m3;TWA

concentration(respirable):0.1

mg/m3(2.4 millions of

particles/cu. ft.)

Silica 7631-86-9 Chemical

Manufacturer

Rec Guid

TWA(as respirable dust):3

mg/m3

SILICA, AMORPHOUS 7631-86-9 US Dept of

Labor - OSHA

TWA concentration:0.8

mg/m3;TWA:20 millions of

particles/cu. ft.Amer Conf of Gov. Indust. Hyg. : American Conference of Governmental Industrial Hygienists

American Indust. Hygiene Assoc : American Industrial Hygiene Association

Chemical Manufacturer Rec Guid : Chemical Manufacturer's Recommended Guidelines

US Dept of Labor - OSHA : United States Department of Labor - Occupational Safety and Health Administration

TWA: Time-Weighted-Average

STEL: Short Term Exposure Limit

CEIL: Ceiling

8.2. Exposure controls

8.2.1. Engineering controlsProvide appropriate local exhaust ventilation for sanding, grinding or machining. Use general dilution ventilation and/or

local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control

dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. Provide local exhaust at

process emission sources to control exposure near the source and to prevent the escape of dust into the work area. Ensure that

dust-handling systems (such as exhaust ducts, dust collectors, vessels, and processing equipment) are designed in a manner to

prevent the escape of dust into the work area (i.e., there is no leakage from the equipment).

8.2.2. Personal protective equipment (PPE)

Eye/face protection

To minimize the risk of injury to face and eyes, always wear eye and face protection when working at sanding or grinding

operations or when near such operations. Select and use eye/face protection to prevent contact based on the results of an

exposure assessment. The following eye/face protection(s) are recommended:

Safety Glasses with side shields

Skin/hand protectionWear appropriate gloves to minimize risk of injury to skin from contact with dust or physical abrasion from grinding or

sanding.

Respiratory protection

Assess exposure concentrations of all materials involved in the work process. Consider material being abraded when

determining the appropriate respiratory protection. Select and use appropriate respirators to prevent inhalation overexposure.

An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of

a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator


__________________________________________________________________________________________ Page 5 of 11

type(s) to reduce inhalation exposure:

Half facepiece or full facepiece air-purifying respirator suitable for particulates

For questions about suitability for a specific application, consult with your respirator manufacturer.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

General Physical Form: Solid

Odor, Color, Grade: Solid Abrasive Product

Odor threshold Not Applicable

pH Not Applicable

Melting point Not Applicable

Boiling Point Not Applicable

Flash Point Not Applicable

Evaporation rate Not Applicable

Flammability (solid, gas) Not Classified

Flammable Limits(LEL) Not Applicable

Flammable Limits(UEL) Not Applicable

Vapor Pressure Not Applicable

Vapor Density Not Applicable

Specific Gravity Not Applicable

Solubility In Water Not Applicable

Solubility- non-water Not Applicable

Partition coefficient: n-octanol/ water Not Applicable

Autoignition temperature Not Applicable

Decomposition temperature Not Applicable

Viscosity Not Applicable

SECTION 10: Stability and reactivity

10.1. Reactivity

This material is considered to be non reactive under normal use conditions.

10.2. Chemical stability

Stable.

10.3. Possibility of hazardous reactions

Hazardous polymerization will not occur.

10.4. Conditions to avoid

None known.

10.5. Incompatible materials

None known.


__________________________________________________________________________________________ Page 6 of 11

10.6. Hazardous decomposition products

Substance Condition

None known.

Refer to section 5.2 for hazardous decomposition products during combustion.

SECTION 11: Toxicological information

The information below may not be consistent with the material classification in Section 2 if specific ingredient

classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be

reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be

present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be

relevant to the material as a whole.

11.1. Information on Toxicological effects

Signs and Symptoms of Exposure

Based on test data and/or information on the components, this material may produce the following health effects:

Inhalation:Dust from grinding, sanding or machining may cause irritation of the respiratory system. Signs/symptoms may include cough,

sneezing, nasal discharge, headache, hoarseness, and nose and throat pain.

Skin Contact:Mechanical Skin irritation: Signs/symptoms may include abrasion, redness, pain, and itching.

Eye Contact:

Mechanical eye irritation: Signs/symptoms may include pain, redness, tearing and corneal abrasion.

Dust created by grinding, sanding, or machining may cause eye irritation. Signs/symptoms may include redness, swelling,

pain, tearing, and blurred or hazy vision.

Ingestion:

Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.

Carcinogenicity:

Ingredient C.A.S. No. Class Description Regulation

Quartz Silica 14808-60-7 Grp. 1: Carcinogenic to humans International Agency for Research on Cancer

SILICA, CRYS AIRRESP 14808-60-7 Known human carcinogen National Toxicology Program Carcinogens

Titanium Dioxide 13463-67-7 Grp. 2B: Possible human carc. International Agency for Research on Cancer

Additional Information:

This document covers only the 3M product. For complete assessment, when determining the degree of hazard, the material

being abraded must also be considered.

This product contains titanium dioxide and quartz (crystalline) silica. Cancer of the lungs has been associated with inhalation

of high levels of titanium dioxide in animal studies, and occupational exposure to inhaled quartz silica has been associated

with silicosis and lung cancer. No exposure to titanium dioxide or quartz silica is expected during the normal handling and

use of this product. Titanium dioxide and quartz silica were not detected when air sampling was conducted during simulated

use of similar products containing these substances. Therefore, the health effects associated with titanium dioxide and quartz

(crystalline) silica are not expected during the normal use of this product.

Toxicological Data


__________________________________________________________________________________________ Page 7 of 11

If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or

the data are not sufficient for classification.

Acute ToxicityName Route Species Value

Overall product Ingestion No data available; calculated ATE > 5,000 mg/kg

Aluminum Oxide Mineral (non-fibrous) Dermal LD50 estimated to be > 5,000 mg/kg

Aluminum Oxide Mineral (non-fibrous) Inhalation-

Dust/Mist

(4 hours)

Rat LC50 > 2.3 mg/l

Aluminum Oxide Mineral (non-fibrous) Ingestion Rat LD50 > 5,000 mg/kg

Limestone Dermal Rat LD50 > 2,000 mg/kg

Limestone Inhalation-

Dust/Mist

(4 hours)

Rat LC50 3.0 mg/l

Limestone Ingestion Rat LD50 6,450 mg/kg

Iron Oxide Mineral Dermal Not

available

LD50 3,100 mg/kg

Iron Oxide Mineral Ingestion Not

available

LD50 3,700 mg/kg

Silica Dermal Rabbit LD50 > 5,000 mg/kg

Silica Inhalation-

Dust/Mist

(4 hours)

Rat LC50 > 0.691 mg/l

Silica Ingestion Rat LD50 > 5,110 mg/kg

Titanium Dioxide Dermal Rabbit LD50 > 10,000 mg/kg

Titanium Dioxide Inhalation-

Dust/Mist

(4 hours)

Rat LC50 > 6.82 mg/l

Titanium Dioxide Ingestion Rat LD50 > 10,000 mg/kg

Quartz Silica Dermal LD50 estimated to be > 5,000 mg/kg

Quartz Silica Ingestion LD50 estimated to be > 5,000 mg/kg

ATE = acute toxicity estimate

Skin Corrosion/IrritationName Species Value

Aluminum Oxide Mineral (non-fibrous) Rabbit No significant irritation

Limestone Rabbit No significant irritation

Iron Oxide Mineral Rabbit No significant irritation

Silica Rabbit No significant irritation

Titanium Dioxide Rabbit No significant irritation

Quartz Silica No significant irritation

Serious Eye Damage/IrritationName Species Value

Aluminum Oxide Mineral (non-fibrous) Rabbit No significant irritation

Limestone Rabbit No significant irritation

Iron Oxide Mineral Rabbit No significant irritation

Silica Rabbit No significant irritation

Titanium Dioxide Rabbit No significant irritation

Skin SensitizationName Species Value

Iron Oxide Mineral Human Some positive data exist, but the data are not

sufficient for classification

Silica Human

and

animal

Not sensitizing

Titanium Dioxide Human

and

animal

Not sensitizing

Respiratory SensitizationName Species Value


__________________________________________________________________________________________ Page 8 of 11

Germ Cell MutagenicityName Route Value

Aluminum Oxide Mineral (non-fibrous) In Vitro Not mutagenic

Iron Oxide Mineral In Vitro Not mutagenic

Silica In Vitro Not mutagenic

Titanium Dioxide In Vitro Not mutagenic

Titanium Dioxide In vivo Not mutagenic

Quartz Silica In Vitro Some positive data exist, but the data are not


Quartz Silica In vivo Some positive data exist, but the data are not


CarcinogenicityName Route Species Value

Aluminum Oxide Mineral (non-fibrous) Inhalation Rat Not carcinogenic

Iron Oxide Mineral Inhalation Human Some positive data exist, but the data are not


Silica Not

Specified

Mouse Some positive data exist, but the data are not


Titanium Dioxide Ingestion Multiple

animal

species

Not carcinogenic

Titanium Dioxide Inhalation Rat Carcinogenic

Quartz Silica Inhalation Human

and

animal

Carcinogenic

Reproductive Toxicity

Reproductive and/or Developmental EffectsName Route Value Species Test Result Exposure

Duration

Limestone Ingestion Not toxic to development Rat NOAEL 625

mg/kg/day

premating &

during

gestation

Silica Ingestion Not toxic to female reproduction Rat NOAEL 509

mg/kg/day

1 generation

Silica Ingestion Not toxic to male reproduction Rat NOAEL 497

mg/kg/day

1 generation

Silica Ingestion Not toxic to development Rat NOAEL

1,350

mg/kg/day

during

organogenesi

s

Target Organ(s)

Specific Target Organ Toxicity - single exposureName Route Target Organ(s) Value Species Test Result Exposure

Duration

Limestone Inhalation respiratory system All data are negative Rat NOAEL

0.812 mg/l

90 minutes

Specific Target Organ Toxicity - repeated exposureName Route Target Organ(s) Value Species Test Result Exposure

Duration

Aluminum Oxide Mineral

(non-fibrous)

Inhalation pneumoconiosis |

pulmonary fibrosis

Some positive data exist, but the

data are not sufficient for

classification

Human NOAEL Not

available

occupational

exposure

Limestone Inhalation respiratory system Some positive data exist, but the


classification

Human NOAEL Not

available

occupational

exposure

Iron Oxide Mineral Inhalation pulmonary fibrosis |

pneumoconiosis

Some positive data exist, but the


Human NOAEL Not

available

occupational

exposure


__________________________________________________________________________________________ Page 9 of 11

classification

Silica Inhalation respiratory system |

silicosis

All data are negative Human NOAEL Not

available

occupational

exposure

Titanium Dioxide Inhalation respiratory system Some positive data exist, but the


classification

Rat LOAEL

0.010 mg/l

2 years

Titanium Dioxide Inhalation pulmonary fibrosis All data are negative Human NOAEL Not

available

occupational

exposure

Quartz Silica Inhalation silicosis Causes damage to organs

through prolonged or repeated

exposure

Human NOAEL Not

available

occupational

exposure

Aspiration HazardName Value

Please contact the address or phone number listed on the first page of the SDS for additional toxicological information

on this material and/or its components.

SECTION 12: Ecological information

Ecotoxicological information

Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material

and/or its components.

Chemical fate information

Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material

and/or its components.

SECTION 13: Disposal considerations

13.1. Disposal methods

Dispose of contents/ container in accordance with the local/regional/national/international regulations.

Prior to disposal, consult all applicable authorities and regulations to insure proper classification. The substrate that was

abraded must be considered as a factor in the disposal method for this product. Dispose of waste product in a permitted

industrial waste facility. As a disposal alternative, incinerate in a permitted waste incineration facility. Proper destruction

may require the use of additional fuel during incineration processes. If no other disposal options are available, waste product

may be placed in a landfill properly designed for industrial waste.

EPA Hazardous Waste Number (RCRA): Not regulated

SECTION 14: Transport Information

Not regulated per U.S. DOT, IATA or IMO.

These transportation classifications are provided as a customer service. As the shipper YOU remain responsible for

complying with all applicable laws and regulations, including proper transportation classification and packaging. 3M

transportation classifications are based on product formulation, packaging, 3M policies and 3M understanding of

applicable current regulations. 3M does not guarantee the accuracy of this classification information. This information

applies only to transportation classification and not the packaging, labeling, or marking requirements. The original 3M

package is certified for U.S. ground shipment only. If you are shipping by air or ocean, the package may not meet

applicable regulatory requirements.

SECTION 15: Regulatory information


__________________________________________________________________________________________ Page 10 of 11

15.1. US Federal RegulationsContact 3M for more information.

311/312 Hazard Categories:

Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - No Delayed Hazard - No

15.2. State RegulationsContact 3M for more information.

15.3. Chemical InventoriesThis product is an article as defined by TSCA regulations, and is exempt from TSCA Inventory listing requirements.

Contact 3M for more information.

15.4. International RegulationsContact 3M for more information.

This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.

SECTION 16: Other information

NFPA Hazard Classification

Health: 0 Flammability: 1 Instability: 0 Special Hazards: None

National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address

the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar

emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include

the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.

HMIS Hazard ClassificationHealth: 0 Flammability: 1 Physical Hazard: 0 Personal Protection: X - See PPE section.

Hazardous Material Identification System (HMIS® III) hazard ratings are designed to inform employees of chemical hazards

in the workplace. These ratings are based on the inherent properties of the material under expected conditions of normal use

and are not intended for use in emergency situations. HMIS® III ratings are to be used with a fully implemented HMIS® III

program. HMIS® is a registered mark of the American Coatings Association (ACA).

Document Group: 25-0157-5 Version Number: 1.06

Issue Date: 03/11/14 Supercedes Date: 03/22/13

DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES

NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY

OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR

USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable

for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product,

some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to

determine whether it is fit for a particular purpose and suitable for user's method of use or application.

3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer

may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness

or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available


__________________________________________________________________________________________ Page 11 of 11

directly from 3M

3M USA SDSs are available at www.3M.com


according to ANSI Z400.1- 2004 and 29 CFR 1910.1200

FANTASTIK® ORIGINAL DISINFECTANT ALL PURPOSE CLEANER

Version 3.0 Print Date 03/15/2013

Revision Date 02/25/2013 MSDS Number 350000004769

1/8

1. PRODUCT AND COMPANY IDENTIFICATION

Product information

Trade name : FANTASTIK® ORIGINAL DISINFECTANT ALL PURPOSE CLEANER

Use of the Substance/Mixture

: Hard Surface Cleaner

Company : S.C. Johnson and Son, Limited 1 Webster Street Brantford ON N3T 5R1

Emergency telephone number

: 24 Hour Transport & Medical Emergency Phone (866) 231-5406 24 Hour International Emergency Phone (952) 852-4647 24 Hour Canadian Transport Emergency Phone (CANUTEC) (613) 996-6666

2. HAZARDS IDENTIFICATION

Emergency Overview Appearance / Odor : yellow / liquid / pleasant

Immediate Concerns

: Caution CAUSES EYE IRRITATION. Avoid contact with skin, eyes and clothing.

Potential Health Effects Exposure routes : Eye, Skin, Inhalation, Ingestion.

Eyes : Causes:

Moderate eye irritation

Skin : Causes skin irritation.

Inhalation : No adverse effects expected when used as directed.

Ingestion : May cause irritation to mouth, throat and stomach. May cause abdominal discomfort.

Aggravated Medical Condition

: Persons with pre-existing skin disorders may be more susceptible to irritating effects.






2/8

3. COMPOSITION/INFORMATION ON INGREDIENTS

Hazardous chemicals present at or above reportable levels as defined by OSHA 29 CFR 1910.1200 or the Canadian Controlled Products Regulations are listed in this table:

Chemical Name CAS-No. Weight percent

Propylene glycol monobutyl ether

5131-66-8 1.00 - 5.00

Alkyl dimethyl benzyl ammonium chloride

68391-01-5 0.10 - 1.00

Alkyl dimethyl ethyl benzyl ammonium chloride (C12-14)

68956-79-6 0.10 - 1.00

For additional information on product ingredients, see www.whatsinsidescjohnson.com.

4. FIRST AID MEASURES

Eye contact : Remove contact lenses. Flush immediately with plenty of water for at least 15 to 20 minutes. Get medical attention if irritation develops and persists.

Skin contact : Wash off immediately with plenty of water. Remove contaminated clothing and shoes. Get medical attention if irritation develops and persists. Wash clothing before reuse. Thoroughly clean shoes before reuse.

Inhalation : No special requirements

Ingestion : If swallowed, DO NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention immediately.

5. FIREFIGHTING MEASURES

Suitable extinguishing media

: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

Specific hazards during firefighting

: Container may melt and leak in heat of fire.

Further information : Fight fire with normal precautions from a reasonable distance.

Standard procedure for chemical fires. Wear full protective clothing and positive pressure self-contained breathing apparatus.






3/8

Flash point : Note: no data available

Lower explosion limit : Note: no data available

Upper explosion limit : Note: no data available


Personal precautions : No special precautions required.

Environmental precautions : Outside of normal use, avoid release to the environment.

Methods for cleaning up : Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. Dike large spills. Clean residue from spill site.

7. HANDLING AND STORAGE

Handling

Advice on safe handling : Avoid contact with skin, eyes and clothing. For personal protection see section 8. Use only as directed. KEEP OUT OF REACH OF CHILDREN AND PETS.

Advice on protection against fire and explosion

: Normal measures for preventive fire protection.

Storage

Requirements for storage areas and containers

: Keep container closed when not in use. Keep in a dry, cool and well-ventilated place.






4/8

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Occupational Exposure Limits

ACGIH or OSHA exposure limits have not been established for this product or reportable ingredients unless noted in the table above. Occupational Exposure Limits

Components CAS-No. mg/m3

ppm

Non-standard

units

Basis

Ethyl alcohol 64-17-5 -

1,000 ppm

-

ACGIH STEL

Occupational Exposure Limits

Personal protective equipment

Respiratory protection

No personal respiratory protective equipment normally required.

Hand protection

: If prolonged or repeated contact is possible: Wear suitable gloves.

Eye protection

Safety glasses with side-shields

Skin and body protection

: No special requirements.

Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Wash thoroughly after handling.

9. PHYSICAL AND CHEMICAL PROPERTIES

Form : liquid

Color : yellow

Odor : pleasant

pH : 11.8 - 12.4

Melting point : no data available

Boiling point : no data available

Freezing point : no data available






5/8

Flash point : no data available

Evapouration rate : no data available

Auto-ignition temperature : no data available

Lower explosion limit : no data available

Upper explosion limit : no data available

Vapour pressure : 17.5 mmHg

Density : 1.01 g/cm3 similar to water

Water solubility : completely soluble

Partition coefficient: n-octanol/water

: no data available

Viscosity, dynamic : no data available

Relative vapour density : no data available

Volatile Organic Compounds Total VOC (wt. %)*

: 3 % - additional exemptions may apply *as defined by US Federal and State Consumer Product Regulations

10. STABILITY AND REACTIVITY

Conditions to avoid : Direct sources of heat.

Materials to avoid : Strong acids

Hazardous decomposition products

: Thermal decomposition can lead to release of irritating gases and vapours.

Thermal decomposition : Note: no data available

Hazardous reactions : Stable under recommended storage conditions.

11. TOXICOLOGICAL INFORMATION

Acute oral toxicity : LD50 Measured > 5,000 mg/kg






6/8

Acute inhalation toxicity : no data available Acute dermal toxicity : LD50

Measured > 5,000 mg/kg

Chronic effects Carcinogenicity : no data available

Mutagenicity : None Anticipated Reproductive effects : no data available

Teratogenicity : no data available

Sensitisation : no data available


Ecotoxicity effects : no data available

13. DISPOSAL CONSIDERATIONS

Observe all applicable Federal, Provincial and State regulations and Local/Municipal ordinances regarding disposal. Consumer may discard empty container in trash, or recycle where facilities exist.

14. TRANSPORT INFORMATION

Please refer to the Bill of Lading/receiving documents for up-to-date shipping information. Land transport

U.S. DOT and Canadian TDG Surface Transportation: Proper shipping name not regulated Class: None. UN/ID No.: None. Packaging group None. Sea transport

IMDG: Proper shipping name not regulated






7/8

Class: None. UN/ID No.: None. Packaging group None. Air transport

ICAO/IATA:

Proper shipping name not regulated Class: None. UN/ID No.: None. Packaging group None.


California Prop. 65 : This product is not subject to the reporting requirements under California's Proposition 65.

Canada Regulations : This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations.


HMIS Ratings

Health 2

Flammability 0

Reactivity 0

NFPA Ratings

Health 2

Fire 0

Reactivity 0

Special -

This information is being provided in accordance with Occupational Safety and Health Administration (OSHA) and Canada’s Workplace Hazard Material Information System (WHMIS) regulations. The information supplied is designed for workplaces where product use and frequency of exposure exceeds that established for the labeled consumer use. Further information






8/8

This document has been prepared using data from sources considered to be technically reliable. It does not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein. Actual conditions of use are beyond the seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations.

Prepared by: SC Johnson Global Safety Assessment & Regulatory Affairs (GSARA)

Issued: 1 February 2014

Supersedes: 1 March 2011

DuctSeal 321 Page 1 of 6


______________________________________________________________________________________

1. PRODUCT AND COMPANY IDENTIFICATION

Product Name: DuctSeal 321

Synonyms: Water-Based Mastic

Manufacturer/Supplier Carlisle HVAC Products 900 Hensley Lane Wylie, TX 75098

Internet Address: http://www.carlisleHVAC.com Fax Number: (972) 442-0076

Phone NumbersMedical Emergency:

CHEMTREC (USA): (800) 424-9300

CHEMTREC (International): MSDS Assistance: (972) 442-6545 Fax On Demand: NA Technical Assistance: (888) 229-2199 Customer Service: (888) 229-0199

______________________________________________________________________________________

2. COMPONENT INFORMATION

Component CAS No. Percent Range Hazardous in Blend

Methanol 67-56-1 0.5 – 3.45

This product is not hazardous according OSHA 29 CFR 1910.1200.

Hazards:

Flammable/Combustible No

Acute

Toxin

No Chronic

Toxin

No Carcinogen No

Pressure No Reactive No Exposure Limit Target Organ Other

2A. OTHER INGREDIENTS Greater than 3%

Component CAS No.

Latex Co-polymer 24937-78-8

Calcium Carbonate 1317-65-3

Clay 1332-58-7

Chlorinated Paraffin 63449-39-8

_________________________________________________________________________________

3. HAZARDS IDENTIFICATION

Emergency and Hazards Overview:

May cause moderate irritation to eyes. May be harmful if swallowed. Read and understand all health and

safety information on the product label and Material Safety Data Sheet before use.

Ratings

Health 1 Flammability 0 Reactivity 0

Primary Route of Exposure: Skin x Inhalation x Eye x Ingestion x

Health Effect Information

Eye Contact: May cause eye irritation if wiped or rubbed into eyes.

Skin Contact: May cause mild skin irritation on prolonged or repeated contact.

Inhalation: Breathing high concentrations of vapors may cause nausea & irritation of nose, throat, &

respiratory tract. Respiratory symptoms associated with pre-existing lung disorders may be

aggravated by exposure to this material.

Ingestion: Ingestion of large quantity may cause initial central nervous system stimulation, followed by

depression.




Medical Conditions Aggravated by Exposure: Prolonged exposure to vapors could aggravate

pre-existing disorders in lungs, kidney and liver.

4. FIRST AID INFORMATION

Eye Contact: Flush with water for 15 minutes. Get medical attention immediately.

Skin Contact: Wipe off and wash skin with soap and water. Promptly remove contaminated clothing and

wash before reuse.

Inhalation: Remove to fresh air. If breathing has stopped, start artificial respiration. Oxygen may be

administered. Consult physician immediately

Ingestion: Do not induce vomiting unless directed to do so by a physician. Consult a physician

immediately.

Notes to Physician: This product contains ethylene glycol, Hexahydro-1, 3,5-triethyl-s-triazine (not in a

reportable amount).

5. FIRES AND EXPLOSION INFORMATION

Flammable Properties

Flash Point: No flash to boiling Test Method: Closed cup

Flame extension: NA Test Method: NA

Flammable Limits in Air

Upper Percent: NA Lower Percent: NA

Auto ignition Temperature: NA Test Method: NA

NFPA Classification: H 1 F 0 R 0

Extinguishing Media: CO2, foam, dry chemical or water spray.

Fire Fighting Measures Special Fire Fighting Procedures and Equipment: Firemen must wear full-face air-supplied masks and

full protective clothing.

Unusual Fire and Explosion Conditions: This product is not sensitive to physical shock or static

discharge. Exposure of closed container to temperatures above the boiling point could cause

pressure buildup and container rupture.

Hazardous Combustion By-Products: CO, CO2, unburned hydrocarbons, or nitrous oxides.




______________________________________________________________________________________


Personnel Safeguards: Evacuate non-essential personnel to safe areas. Clean-up responders should wear

proper protective clothing and gloves before entering the affected area.

Regulatory Notifications: Certain component of this product is defined as hazardous according to U.S.

EPA. Spill reporting requirements and reportable quantities vary by region.

Consult all applicable state and local regulations. For Canada, observe all

precautions noted above.

Containment and Clean up: Prevent product from entering drinking water supplies or streams. Observe

above precautions, collect liquid with inert, noncombustible material and

remove for disposal.

7. HANDLING AND STORAGE INFORMATION

Handling: Normal use condition doesn’t produce respirable Silica. However, sanding, grinding, and

burning might release respirable Silica. Keep out of reach of children. Launder contaminated

clothing. Wash hands with soap and water after use, especially before eating or drinking.

Storage: Store in a dry, well ventilated environment away from heat, above 35 deg F and below 110 deg F.

Keep containers closed when not in use. Do not pressurize, cut weld or grind containers.

Empty Container Warnings

Drums: Drums may be reused after wash.

Plastic: Plastic containers may be reused after wash.

______________________________________________________________________________________

8. EXPOSURE CONTROLS / PERSONAL PROTECTION INFORMATION

Exposure Limits and Guidelines

Component CAS No. Exposure Limit

Methanol 67-56-1 200 ppm OSHA PEL

200 ppm ACGIH TWA, 250 ppm STEL

Personal Protective Equipment

Eye/Face Protection: Wear safety goggles or face shield. Contact lenses should not be worn.

Skin Protection: Use protective rubber gloves (Hycron, neoprene, or nitrile).

Respiratory Protection: Provide adequate ventilation to maintain vapors below PEL/TWA. If vapor

levels are exceeded, use NIOSH approved respirator, both during and

immediately after application, until vapor levels are below limits.

Personal Hygiene: Avoid rubbing eyes during handling. Use good personal hygiene practices to avoid

incidental ingestion.

Engineering Controls / Work Practices

Ventilation: Provide local exhaust or area ventilation to maintain concentration of vapors below

PEL/TWA.

Other: Source of clean water should be available in the work area for flushing eyes and skin. Wash

thoroughly with soap and water after use and before eating.




______________________________________________________________________________________

9. PHYSICAL AND CHEMICAL PROPERTIES??

Appearance: Gray Mastic Vapor Pressure: 17 mm Hg @ 20ºC

Odor: Typical latex with slight ammonia odor Vapor Density (air=1): <air

Physical state: Mastic Percent Volatile by Weight: 28-32

pH: 8.4 – 9.5 Volatile Organic Content: 93 g/l (according

to SCAQMD calculation)

DOT Corrosivity: NA Molecular Weight: NA

Boiling Point: 212ºF Average Carbon Number: NA

Melting Point: NA Viscosity @ 77 F: >300 K cps

Specific Gravity: 1.34-1.41

Pour Point: NA

Solubility in Water: Miscible with water

Octanol / Water Coefficient: Log Kow = NA

______________________________________________________________________________________

10. STABILITY AND REACTIVITY INFORMATION

Chemical Stability: Stable

Conditions to Avoid: Avoid extreme heat, fire and temperature.

Incompatible Materials to Avoid: Avoid strong acids, strong oxidizers.

______________________________________________________________________________________

11. TOXICOLOGICAL INFORMATION (will only print available data)

Primary Eye Irritation: Irritating

Primary Skin Irritation: NA

Acute Dermal Toxicity: Product toxicity has not been determined.

Subacute Dermal Toxicity: NA

Dermal Sensitization: NA

Inhalation Toxicity: Product toxicity has not been determined.

Inhalation Sensitization: NA

Oral Toxicity: Product toxicity has not been determined.

Mutagenicity: NA

Carcinogenicity: NA

Reproductive Toxicity: Product toxicity has not been determined.

Teratogenicity: NA

Immunotoxicity: NA

Neurotoxicity: NA

No other toxicological information available

______________________________________________________________________________________


Aquatic Toxicity: Not known

Terrestrial Toxicity: Not known

Chemical Fate and Transport: Not known

No other ecological information available

______________________________________________________________________________________

13. DISPOSAL INFORMATION

Regulatory Information: Consult all regulations (federal, state, provincial, local etc.) or a qualified waste

disposal firm when characterizing waste for disposal.




Waste Disposal Methods: Recover free liquid. Absorb residue and dispose of according to local, state and

Federal EPA regulation. Empty container: may contain explosive vapors. Do

Not cut, puncture or weld on or nearby.

______________________________________________________________________________________

14. TRANSPORTATION INFORMATION

U.S. Department of Transportation (DOT) Highway / Rail: Not regulated by DOT

International Highway (Transportation of Dangerous Goods-TDG): Not regulated

International Ocean (International Maritime Dangerous Goods – IMDG): Not regulated

International Air (International Air Transportation Authority – IATA): Not regulated

The DOT description is provided to assist in the proper shipping classification of this product and

may not be suitable for all shipping descriptions.

Other: No other information available

______________________________________________________________________________


Regulatory Lists

U.S. TSCA Inventory: All components of this material are on the US TSCA Inventory or exempt from

listing on the TSCA Inventory.

Sara Section 313: This product contains the following Sara, Title III, Section 313 Chemicals:

Chemical CAS Number Percent in Product

Methanol 67-56-1 0.5 – 3.45

IARC Group: NA

Regulatory Lists Searched

This product contains a mixture of one or more components found on the following State List at or above

OSHA de minimis quantities

Health & Safety: NA

Environmental: NA

International: NA

State: FL, MA, MN, PA, NJ, WA

National Inventories: NA

SARA 311 / 312 Categories (For the chemicals above)

Acute: Yes Chronic: Yes Fire: Yes Pressure: No Reactive: No

Regulated: No

California Proposition 65 Information: Warning! None in the list

Canadian WHMIS Classification

Methanol




Class: Class B2 and D2B

This product has been classified in accordance with hazard criteria of the Controlled Products

Regulations (CPR). This MSDS contains all the information required by the CPR.

Canadian Environmental Protection Act (CEPA) All reportable chemical substance is listed on the Domestic Substances List (DSL) or otherwise complies

with CEPA new substance notification requirements.

National Pollution Release Inventory (NPRI)

This product contains the following chemical subject to the reporting requirements of the CEPA

subsection 16(1), NPRI.

Chemical CAS Number Percent in Product

Methanol 67-56-1 0.5 – 3.45

Other Regulations: No other information available.

______________________________________________________________________________________


Health and Environmental Label Language

All ingredients contained in this product are included on the US EPA Toxic Substances Control Act

(TSCA) inventory or exempt from listing on the TSCA inventory. All ingredients contained in this

product comply with the requirements of the Canadian Environmental Protection Act (CEPA) and are

listed on the Domestic Substance List (DSL) or Non-Domestic Substance List (NDSL)

MSDS Revisions Previous Version Date: 1 March 2011

Section

Old Information:

New Information:

Prepared By: R&D Department Date: 1 February 2014

Disclaimer of Warranty: The information contained herein is based upon data and information available

to us, and reflects our best professional judgment. This product may be formulated in part with

components purchased from other companies. In many instances, especially when proprietary or trade

secret materials are used, CCWI Company must rely upon the hazard evaluation of such components

submitted by that product’s manufacturer or importer. No warranty of merchantability, fitness for any use,

or any other warranty is expressed or implied regarding the accuracy of such data or information. The

results to be obtained from the use thereof, or that any such use does not infringe any patent, since the

information contained herein may be applied under conditions of use beyond our control and with which

we may be unfamiliar, we do not assume responsibility for the results of such application. This information

is furnished upon the condition that the person receiving it shall make his own determination of the

suitability of the material for his particular use.

Boss Lubricants: Material Safety Data Sheet Issue Date: January 1, 2012

Ventilation Procedure: Normal shop ventilation adequate

Product Information Product Trade Name: Boss Industrial Hydraulic Oils

Transportation: Emergency Phone Number

(CHEMTREC): (800) 424-9300

Chemical Name:

Petroleum Oil Blend

NFPA Code:

Health: 0 Fire: 1 Reactivity: 0

Glove protection:

Eye protection:

Other Protection:

Oil impervious gloves recommended

Not usually required, but goggles

recommended

None required

HMIS System: Health: 0 Flamability: 1 Reactivity:

0 5. PHYSICAL DATA Vapour Pressure: >1mm Hg

Specific Gravity: <1.00 @ 15.5 C

1. HAZARDOUS INGREDIENTS

This material is not known to contain any chemical listed as a

carcinogen or suspected carcinogen by OSHA, IARC or the

National Toxiology Program (NIP) at a concentration greater than

0.1%.

Contains refined petroleum oil and selected additives.

This material is non-carcinogenic as defined by OSHA, IARC,

or NIP

2. FIRE AND EXPLOSION HAZARDS

Water Solubility: Slight

Percent Volatile: Not determined

Vapour Density: Not determined

Evaporation Rate: Not determined

Odor: Mild hydrocarbon odor

Appearance: Amber liquid.

6. STABILITY

Stability: Stable

Incompatibility: Oxidizing agents

Polymerization: Will not occur

Flash point, C:

Upper Flammable Limit:

Lower Flammable Limit:

Extinguishing Media:

216- 246

Not determined

Not determined

CO2 dry chemical: foam: water

spray: water fog

Thermal Decomposition: Oxides of carbon, nitrogen,

phosphorus, and hydrogen

sulfide.

Special Firefighting Procedures: Cool containers with H2O and

remove from fire exposure

Unusual fire & Explosion Hazards: Empty containers could contain

flammable vapours

3. HEALTH HAZARD DATA

Oral Toxicity:

Minimal hazard. Oral toxicity greater than 5,000

mg/kg

7. SPILL OR LEAK PROCEDURES Spill Procedures: Wear chemical splash goggles

Wear rubber boots

Prevent entry into sewers and waterways. Pickup free

liquid for recycle/disposal

Absorb small amounts of inert material for disposal

Waste Disposal: Disposal should be in compliance with federal, provincial

and local laws

Eye Irritation: May be an eye irritant

Skin Irritation: Possible redness may result from prolonged exposure.

Other: Unknown

TLV: 5 mg/m3 as oil mist

Emergency First Aid Procedures:

8. SPECIAL PRECAUTIONS

Special Precautions: Launder contaminated clothing before reuse.

Wash skin thoroughly after handling. Avoid

prolonged contact

Skin:

Eye:

Inhalation:

Oral:

Additional:

Wash with soap

Flush with large amounts of water. If irritation

persists, get medical attention

Remove to fresh air. See physician if irritation

persists

Call physician. Do not induce vomiting

None

9. TRANSPORTATION AND LABELING

DOT Proper Shipping Name: Not applicable

DOT Hazard Class: Not applicable

4. SPECIAL PROTECTION INFORMATION

10. OTHER REGULATORY INFORMATION

BOSS INDUSTRIAL HYDRAULIC OILS

Boss Lubricants: Material Safety Data Sheet

SARA SEC

313

SUPPLIER

NOTIFICATIONS

This product contains the following toxic chemical, subject to the reporting requirements of sec 313 of the energy planning and community

right-to-know act of 1986 and of 40CFR372.

CAS# CHEMICAL NAME %WEIGHT

Available

This information must be included in all MSDS’s that are copied and distributed for this material.

The information presented herein has been compiled from sources considered to be dependable, and is accurate to the best of BOSS

LUBRICANT’S knowledge; however, BOSS makes no warranty whatsoever, expressed or implied, of merchantability or fitness for the

particular purpose, regarding the accuracy of such date or the results to be obtained from the use thereof. BOSS LUBRICANTS assumes no

responsibility for injury to recipient or to third persons or for any damage to any property and recipient assumes all such risks.

11. January 1, 2011

Prepared by: Technical Services

Boss Lubricants Ltd.

112, 6303 30th street S.E.

Calgary, Alberta

T2C 1R4

(800) 844-9457

BOSS INDUSTRIAL HYDRAULIC OILS

Material Name: Fiberglass Wool Commercial and Industrial

Insulation, Antimony-free Safety Data Sheet

ID: 1077

____________________________________________________________ Page 1 of 7 Issue Date: 01/11/2013 Revision: 1.0002

Section 1 - Product and Company Identification Hazard Label WARNING label Company Information Johns Manville Telephone: 303-978-2000 8:00AM-5:00PM M-F Insulation Systems Internet Address: http://www.jm.com P.O. Box 5108 Emergency: 800-424-9300 (Chemtrec, In English) Denver, CO 80127 USA Trade Names: 800 Series Spin Glas® Board, unfaced Insul-SHIELD® Coated Black 1000 Series Spin Glas® Board Linacoustic® RC Duct Liner PM Micromat Rx™ Blended Blowing Wool Fabrication Board

Permacote® Linacoustic® (Types:Standard, HP and R-300) Precipitator Spin Glas®

Hullboard (Incombustible) Spin Glas® HTB 26 & 23 Hullinsul® Fiber Glass Board R Series Microlite® (Plain) Incombustible Microlite® Spin Glas® HTB 26 & 23 Use: Lining sheet metal ducts in AC, heating and ventilation systems

Section 2 - Hazards Identification Emergency Overview

Inhalation of excessive amounts of dust from the product may cause temporary upper respiratory irritation and/or congestion--remove individual to fresh air. In high temperature applications, treatment, curing, or in geographic areas of high heat and humidity, this product may release gases irritating to the eyes, nose and throat.

Inhalation Temporary mechanical irritation may occur upon exposure to dust or fibers released from cutting this product. Irritation of the upper respiratory tract, coughing, and congestion may occur in extreme exposures. Severe irritation of the mouth, nose, and throat, as well as signs of central nervous system depression (drowsiness, dizziness, headache), may occur upon inhalation of vapors or gases.

Skin Temporary irritation (itching) or redness may occur.

Ingestion This product is not intended to be ingested (eaten). If ingested, it may cause temporary irritation to the gastrointestinal (digestive) tract.

Eyes Temporary irritation (itching) or redness may occur.

Ears Temporary irritation (itching) or redness may occur.

Primary Routes of Entry (Exposure) Eyes, skin, inhalation (breathing dust and fibers) and ingestion.

Target Organs Nose (nasal passages), throat, lungs, skin, eyes

Medical Conditions Aggravated by Exposure Pre-existing chronic respiratory, skin, or eye diseases or conditions.

Section 3 - Composition/Information on Ingredients

CAS # Component Percent Not Applicable Continuous Filament Glass Fiber 0-12 Not Applicable Fiber Glass Wool 65-85 Not Available Urea extended phenol-formaldehyde binder (cured) 10-18 NA Acrylic Coating 0-10 1333-86-4 Carbon black, bound (present in black products only) <1

Material Name: Fiberglass Wool Commercial and Industrial Insulation, Antimony-free Safety Data Sheet ID: 1077


50-00-0 Formaldehyde <1 Component Information

Formaldehyde may be released by partial hydrolysis of the urea formaldehyde polymer.

General Product Description Fibrous glass blankets or boards with glass mat facing or coating.

Section 4 - First Aid Measures First Aid: Inhalation

If dust is inhaled in excess of exposure limits referenced in section 8 of this safety data sheet, remove individual to fresh air. Drink water to clear throat, and blow nose to remove dust. A saline spray in the nose may help clear any fibers.

First Aid: Skin Wash gently with soap and water to remove dust and fibers. Alternatively, fibers can be removed from the skin by use of ordinary masking or wrapping tape. Should irritation persist, seek medical attention.

First Aid: Ingestion Rinse mouth with water to remove dust and fibers and drink plenty of water to help reduce irritation. If irritation persists, seek medical attention.

First Aid: Eyes Do not rub or scratch eyes. Dust particles may cause the eye to be scratched. Flush eyes with large amounts of water until irritation subsides. If irritation persists, seek medical attention.

First Aid: Ears Wash exposed skin with soap and water. If irritation develops in the inner ear, seek medical attention.

First Aid: Notes to Physician Dust from the product may cause mechanical irritation of the eyes, skin, and upper respiratory tract. Treat symptomatically. Irritating gases may be released under conditions of high heat or humidity. At high levels, these could cause severe upper respiratory and eye irritation. Formaldehyde gas is a skin and respiratory sensitizer. Treatment should be directed toward removing the source of irritation with symptomatic treatment as necessary.

Section 5 - Fire Fighting Measures Flash Point: Not applicable Method Used: Not applicable Upper Flammable Limit (UFL): Not applicable Lower Flammable Limit (LFL): Not applicable Auto Ignition: Not determined Flammability Classification: Not determined Rate of Burning: Not determined General Fire Hazards

There is no potential for spontaneous fire or explosion. Inorganic glass fibers are naturally non-combustible and non-flammable.

Extinguishing Media Carbon dioxide (CO2), water, water fog, dry chemical.

Fire Fighting Equipment/Instructions No special procedures are expected to be necessary for this product. Normal fire fighting procedures should be followed to avoid inhalation of smoke and gases.

Section 6 - Accidental Release Measures Clean-Up Procedures

Pick up large pieces. Vacuum dusts. If sweeping is necessary, use a dust suppressant such as water. Do not dry sweep dust accumulation. These procedures will help to minimize potential exposures.

Section 7 - Handling and Storage Handling Procedures

Use protective equipment as described in Section 8 of this safety data sheet when handling uncontained material. Handle in accordance with good industrial hygiene and safety practices.

Storage Procedures Warehouse storage should be in accordance with package directions, if any. Material should be kept clean, dry, and in original packaging.



Section 8 - Exposure Controls / Personal Protection The Occupational Safety and Health Administration (OSHA) has not adopted specific occupational exposure standards for fiber glass. Fiber glass is treated as a nuisance dust and is regulated by OSHA as a particulate not otherwise regulated (total dust) shown in CFR 1910.1000 Table Z-3. Respirable fraction 5 mg/m3 Total dust 15 mg/m3 JM has adopted the fiber glass industry voluntary Product Stewardship Program (PSP), formerly the NAIMA-OSHA Health and Safety Partnership Program (HSPP). Under the PSP, JM recommends that exposures be limited to the voluntary concentration of 1 f/cc TWA for fibers longer than 5 microns with a diameter less than 3 microns. This will help minimize potential irritation effects. The PSP also includes the PPE recommendations described below. Formaldehyde (50-00-0)

OSHA: 0.75 ppm TWA 0.5 ppm Action Level; 0.75 ppm TWA; 2 ppm STEL (Irritant and potential cancer hazard - see 29 CFR 1910.1048) 3 ppm TWA (unless specified in 1910.1048)

ACGIH: 0.3 ppm Ceiling Carbon black, bound (present in black products only) (1333-86-4)

OSHA: 3.5 mg/m3 TWA 3.5 mg/m3 TWA

ACGIH: 3.5 mg/m3 TWA

PERSONAL PROTECTIVE EQUIPMENT Personal Protective Equipment: Eyes/Face

Safety glasses with side shields are recommended to keep dust out of the eyes. Personal Protective Equipment: Ears

Use ear protection (earplugs, hood, or earmuffs) to prevent airborne dust or fibers from entering the ear, if necessary. Personal Protective Equipment: Skin

Leather or cotton gloves should be worn to protect against mechanical abrasion. See also Personal Protective Equipment: General, below.

Personal Protective Equipment: Respiratory A NIOSH-approved respirator should be used if ventilation is unavailable, or is inadequate for keeping levels below the applicable exposure limits referenced in Section 8 of this SDS.

Ventilation In fixed manufacturing settings, local exhaust ventilation should be provided at areas of cutting, milling or other processing to remove airborne dust and fibers.

Personal Protective Equipment: General Wear a cap, a loose-fitting, long-sleeved shirt and long pants to protect skin from irritation. Exposed skin areas should be washed with soap and water after handling or working with fiber glass. Clothing should be washed separately from other clothes, and the washer should be rinsed thoroughly (run empty for a complete wash cycle). This will reduce the chances of fiber glass being transferred to other clothing.

Section 9 - Physical & Chemical Properties

Appearance: Fibrous glass blankets or boards with glass mat facing or coating with glass mat facing.

Odor: Mild resin odor

Physical State: Solid pH: Not applicable Vapor Pressure: Not applicable Vapor Density: Not applicable

Boiling Point: Not applicable Melting Point: >704ºC/1300ºF Solubility (H2O): Nil Specific Gravity: Variable

VOC: Not determined



Section 10 - Stability & Reactivity Information Stability

These products are not reactive. Hazardous Decomposition

May form carbon dioxide and carbon monoxide. Hazardous Polymerization

Will not occur.

Section 11 - Toxicological Information Acute Toxicity A: General Product Information

If dust evolves from this product during use it may cause temporary mechanical irritation or scratchiness of the throat and/or itching of the eyes and skin. Exposure to formaldehyde may cause eye and upper respiratory irritation, and possible respiratory or skin sensitization (allergy). If sensitization occurs, subsequent exposures to formaldehyde may worsen asthma or other respiratory problems, and cause allergic-type reactions.

B: Component Analysis - LD50/LC50 Formaldehyde (50-00-0) Inhalation LC50 Rat: 0.578 mg/L/4H; Oral LD50 Rat:500 mg/kg Carbon black, bound (present in black products only) (1333-86-4) Oral LD50 Rat: >15400 mg/kg; Dermal LD50 Rabbit:>3 g/kg

Carcinogenicity A: General Product Information

Exposure to formaldehyde has been associated with the development of nasopharyngeal cancer in laboratory animals and humans. Formaldehyde has been classified as a known human carcinogen, Group 1, by the International Agency for Research on Cancer (IARC). OSHA specifically regulates formaldehyde under 29 CFR 1910.1048.

B: Component Carcinogenicity Fiber glass wool

NTP: Not listed. IARC: Group 3 - Not Classifiable (IARC Monograph 81 [2002] (listed under Man-made mineral fibres),

Monograph 43 [1988]) Formaldehyde (50-00-0)

ACGIH: A2 - Suspected Human Carcinogen OSHA: 0.5 ppm Action Level; 0.75 ppm TWA; 2 ppm STEL (Irritant and potential cancer hazard - see 29

CFR 1910.1048) NTP: Known to Cause Cancer

IARC: Group 1 - Known Human Carcinogen Carbon black, bound (present in black products only) (1333-86-4)

ACGIH: A4 - Not Classifiable as a Human Carcinogen IARC: Group 2B - Possibly Carcinogenic to Humans (IARC Monograph 93 [in preparation], Monograph

65 [1996])

Chronic Toxicity Continuous Filament Glass Fiber: No chronic health effects are known to be associated with exposure to continuous filament fiber glass. Results from epidemiologic studies have not shown any increases in respiratory disease or cancer. The International Agency for Research on Cancer (IARC) has classified continuous filament fiber glass as a Group 3 substance, not classifiable as to its carcinogenicity to humans. Because of the large diameter of continuous filament fibers, these products are not considered respirable.



Fiber Glass Wool (non-durable glass fibers): In October 2001, IARC classified fiber glass wool as Group 3, "not classifiable as to its carcinogenicity to humans." The 2001 decision was based on current human and animal research that shows no association between inhalation exposure to dust from fiber glass wool and the development of respiratory disease In 2011, the National Toxicology Program (NTP, a component of the United States Department of Health and Human Services) issued its 12th Report on Carcinogens (Report). The Report makes clear that any glass fibers that have been successfully assessed in an animal study and shown no cancer hazard are NOT among those “certain” fibers and NOT listed in the Report. The glass fibers comprising the products on this MSDS have either been successfully assessed by appropriate animal protocols and / or have modeled Kdis values such that they are considered non-durable and the current human and animal research that shows no association between inhalation exposure to dust from fiber glass wool and the development of respiratory disease is applicable to these fibers.

Section 12 - Ecological Information Ecotoxicity A: General Product Information

No data available for this product. B: Component Analysis - Ecotoxicity - Aquatic Toxicity

Formaldehyde (50-00-0) 96 Hr LC50 Pimephales promelas: 24.1 mg/L [flow-through]; 96 Hr LC50 Lepomis macrochirus: 0.10 mg/L [flow-through]; 96 Hr LC50 Brachydanio rerio: 41 mg/L [static] 5 min EC50 Photobacterium phosphoreum: 9.0 mg/L; 15 min EC50 Photobacterium phosphoreum: 7.26 mg/L; 25 min EC50 Photobacterium phosphoreum: 6.81 mg/L; 30 min EC50 Photobacterium phosphoreum: 16.5 mg/L; 1 Hr EC50 Vibrio harveyi: 1.2 mg/L; 5 Hr EC50 Vibrio harveyi: 3.7 mg/L; 72 Hr EC50 Colpoda aspera: 5.39 mg/L 96 Hr EC50 water flea: 20 mg/L; 48 Hr EC50 Daphnia magna: 2 mg/L Carbon black, bound (present in black products only) (1333-86-4) 24 Hr EC50 Daphnia magna: >5600 mg/L

Section 13 - Disposal Considerations US EPA Waste Number & Descriptions General Product Information

This product is not expected to be a hazardous waste when it is disposed of according to the U.S. Environmental Protection Agency (EPA) under Resource Conservation and Recovery Act (RCRA) regulations. Product characterization after use is recommended to ensure proper disposal under federal and/or state requirements.

Disposal Instructions Dispose of waste material according to Local, State, Federal, and Provincial Environmental Regulations.

Section 14 - Transport Information International Transport Regulations

These products are not classified as dangerous goods according to international transport regulations.

Section 15 - Regulatory Information US Federal Regulations A: General Product Information

SARA 311/312: This product is not classified as hazardous under SARA 311/312. B: Component Analysis

This material contains one or more of the following chemicals required to be identified under SARA Section 302 (40 CFR 355 Appendix A), SARA Section 313 (40 CFR 372.65) and/or CERCLA (40 CFR 302.4). Formaldehyde (50-00-0)

SARA 302: 500 lb TPQ SARA 313: 0.1 % de minimis concentration

CERCLA: 100 lb final RQ; 45.4 kg final RQ



State Regulations A: General Product Information

The glass fibers in this product are not known to be regulated. Other state regulations may apply. Check individual state requirements. WARNING: This product contains a substance known to the state of California to cause cancer: Methyl Carbamate (trace) 598-55-0 present in mat facer

B: Component Analysis - State The following components appear on one or more of the following state hazardous substances lists:

Component CAS # CA FL MA MN NJ PA Fiber Glass Wool (¹related to Glass, fibrous or dust) (²related to Fibrous glass)

Not Applicable

Yes¹ No Yes² No Yes² Yes²

Fiber Glass Wool (¹related to Mineral wool fiber) (²related to Fibrous glass)

Not Applicable

Yes¹ No Yes¹ Yes Yes² Yes¹

Formaldehyde 50-00-0 Yes No Yes Yes Yes Yes Carbon black, bound (present in black products only)

1333-86-4 Yes No Yes Yes Yes Yes

The following statement(s) are provided under the California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): WARNING! This product contains a chemical known to the state of California to cause cancer. A: TSCA Status

This product and its components are listed on the TSCA 8(b) inventory.

B: Component Analysis - Inventory Component CAS # TSCA DSL EINECS Fiber Glass Wool Not Applicable No No No Fiber Glass Wool Not Applicable Yes Yes Yes Formaldehyde 50-00-0 Yes Yes Yes Carbon black, bound (present in black products only) 1333-86-4 Yes Yes Yes

International Regulations A: General Product Information

These products are considered articles under both U.S. and international product regulations and as such, these products do not require registration or notification on the various country-specific inventories.

B: Component Analysis - WHMIS IDL The following components are identified under the Canadian Hazardous Products Act Ingredient Disclosure List:

Component CAS # Minimum Concentration Fiber Glass Wool Not Applicable 1 % (related to Fibrous glass) Formaldehyde 50-00-0 0.1 %

WHMIS Classification

Controlled Product Classification: D2A This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations. This SDS contains all the information required by the Controlled Products Regulations.

Section 16 - Other Information Other Information

Prepared for: Johns Manville Insulation Systems P. O. Box 5108 Denver, CO USA 80217-5108 Prepared by:



Johns Manville Technical Center P.O. Box 625005 Littleton, CO USA 80162-5005 The information herein is presented in good faith and believed to be accurate as of the effective date given. However, no warranty, expressed or implied, is given. It is the buyer's responsibility to ensure that its activities comply with Federal, State or provincial, and local laws.

Date MSDS # Reason 09/30/08 09/3/2011 01/11/2013

1077-1.0000 1077-1.0001 1077-1.0002

New SDS for new product. Regulatory update. Trade name and toxicological update in section 11.

End of Sheet 1077


Material Name: Mineral Wool Insulation

Page 1 of 7 Issue Date: September 20th, 2013 Replaces Issue: November 16, 2010

1. Identification:

1.1 Product Generic Name: Mineral Wool Insulation 1.2 Product Use: Commercial, Industrial, Residential, and Marine Insulation

1.3 Products:

AFB®, CAVITYROCK®, COMFORTBATT®, COMFORTBOARDTM, CONROCK, CURTAINROCK®, DRAINBOARD®, ENERWRAP®, FABROCKTM, FIREWALL®, MONOBOARD®, RHM®, RHT®, ROCKBOARD®, ROCKFILLTM, ROXUL

Plus, SAFE®, SAFE’n’SOUND®1, STURDIROCK®, TECHTON 1200®, TECHTON 1200® MARINE, TOPROCK®

1.4 Company Address: ROXUL Inc. 420 Bronte St. S. Suite 105 Milton, Ontario Canada L9T 0H9 1.5 Web Site: www.roxul.com 1.6 If further information is required, please call or fax ROXUL Inc. Telephone: 1-800-265-6878 or 905-878-8474 Fax: 905-878-8077 1. SAFE’n’SOUND® is a registered Trademark used under license by ROXUL Inc.

2. Information on Ingredients:

Ingredient Name

CAS Number %

Mineral Fiber

RN 65997-17-3 94-99

Cured Urea Extended Phenolic Formaldehyde Binder

25104-55-6 1-6

3. Hazards Identification:

3.1 Appearance and Odor: Grey, green, brown fibrous batt, blanket, preformed pipe or board. 3.2 Emergency Overview: Acrid smoke may be generated during a fire. Exposure to dust may be irritating to the eyes, nose and throat.

3.3 Potential Health Effects: 3.3.1 Inhalation: Temporary mechanical irritation of the upper respiratory tract (scratchy throat, coughing,

congestion) may result from exposures to dusts and fibers in excess of applicable exposure limits. 3.3.2 Skin Contact: Dusts and fibers may cause temporary mechanical irritation (itching) or redness to the

skin. 3.3.3 Eye Contact: Dusts and fibers may cause temporary mechanical irritation (itching) or redness to the

eyes.

3.3.4 Ingestion: Ingestion of this product is unlikely and not intended under normal conditions of use. Ingestion of this product may cause gastrointestinal irritation.

3.3.5 Existing Medical Conditions: Pre-existing chronic eye, skin and respiratory conditions may temporarily worsen due to exposure to dusts and fibers.




4. First-Aid Measures:

4.1 Inhalation: If irritation occurs, remove the affected person to fresh air. Drink water, and blow nose, to clear dusts and fibers from throat and nose. If irritation persists, consult a physician.

4.2 Skin: If irritation occurs, do not rub or scratch. Rinse under running water prior to washing with mild soap

and water. Use a washcloth to help remove fibers. If irritation persists, consult a physician. 4.3 Eyes: If irritation occurs, flush eyes with plenty of water for at least 15 minutes. Do not rub the eyes. Consult a

physician if irritation persists. 4.4 Ingestion: Ingestion of this product is unlikely and not intended under normal conditions of use. If it does

occur, rinse mouth with plenty of water to help remove dust and fibers, and drink plenty of water to help reduce potential gastrointestinal irritation. Do not induce vomiting unless directed to do so by a physician.

5. Fire-Fighting Measures:

The products are non-combustible and do not pose a fire hazard. However, packaging material may burn. 5.1. Suitable extinguishing media: Water, foam, carbon dioxide or dry powder

5.2 Extinguishing media which must not be used for safety reasons: None 5.3 Combustion products: Carbon dioxide, carbon monoxide and trace gases 5.4 Special protective equipment for fire-fighters: Observe normal fire fighting procedures 5.5 Flash point: None Flash Point Method Used: Not Applicable Upper Flammable Lower Flammable Limit (UFL): Not Applicable Limit: Not Applicable Autoignition: Not Applicable Explosive Properties: Not Applicable

6. Accidental Release Measures:

6.1 Containment Procedures: Pick up large pieces and scoop up dusts and fibers after they have settled out of air. These materials will disperse and settle along the bottom of waterways and ponds. It cannot easily be removed once it is waterborne, but is considered non-hazardous in water.

6.2 Cleanup Procedures: Use OSHA-recommended work practices and protective equipment as described in

Section 8 of this Material Safety Data Sheet. Avoid generating airborne dusts and fibers during cleanup. Do not use compressed air. Vacuum dusts and fibers. Place material in an appropriate container for disposal as non-hazardous waste.

6.3 Response Procedures: Isolate area. Keep unnecessary personnel away. If dry methods or compressed air are

used to collect dusts and fibers, all personnel in the area should wear OSHA-approved protective equipment (see Section 8 of this Material Safety Data Sheet).




7. Handling and Storage:

7.1 General Precautions:

- Utilize OSHA-recommended work practices and protective equipment when using the products (see Section 8 of this Material Safety Data Sheet).

7.2 Handling:

- Unpack material at application site to avoid unnecessary handling of product. - Keep work areas clean. Avoid unnecessary handling of scrap material and debris by placing such materials

in suitable containers, which should be kept as close to the work area as possible. - Ensure good ventilation. Local exhaust ventilation may be required if the method of use produces dust

levels which exceed applicable exposure limits (see Section 8 of this Material Safety Data Sheet). - Avoid excessive eye and skin contact with dusts and fibers. - Use recommended cleanup procedures to avoid buildup of dusts and fibers in the work area.

7.3 Storage: - Keep material in original packaging until it is to be used. - Store material to protect against adverse conditions including precipitation.

8. Exposure Controls/Personal Protection: 8.1 Exposure Guidelines: 8.1.1 General Product Information: Follow all applicable exposure limits. Local regulations may apply. Roxul

recommends that users of the products adhere to the OSHA-recommended PEL of 1 f/cc TWA (fibers

longer than 5 m with diameters less than 3 m). This recommended PEL, together with recommended work practices and personal protective equipment, were adopted in a Health and Safety Partnership Program (HSPP) agreement in 1999 between OSHA and the North American Insulation Manufacturers Association (NAIMA), of which Roxul is a member. Adherence to the OSHA-recommended PEL, work practices and protective equipment in the HSPP is expected to provide appropriate protection against all inhalation-related health risks that may be associated with exposures to mineral wool fibers (ACGIH 1997; NAIMA 1999; OSHA 1999; National Research Council 2000, IARC 2001), and to minimize eye and skin irritation.

8.1.2 Component Exposure Limits:

Source Legal or Recommended Exposure Limit Exposure

OSHA 1 f/cc TWA (recommended) Synthetic Vitreous Fibers, > 5 m

length, < 3 m diameter

ACGIH 1 f/cc TWA (threshold limit value – TLV) Synthetic Vitreous Fibers, > 5 m

length, < 3 m diameter

OSHA 15 mg/m3 TWA-PEL (total particulate) 5 mg/m3 TWA-PEL (respirable particulate)

Inert dust and particulates not otherwise regulated

ACGIH 10 mg/m3 TWA-TLV (inhalable particulate) 3 mg/m3 TWA-TLV (respirable particulate)

Particulates not otherwise classified, containing no asbestos and <1% crystalline silica




8.2 Equipment and Work Practices: Follow OSHA-recommended equipment and work practices. A complete copy of these practices can be obtained from Roxul Inc. (see Section 1 of this Material Safety Data Sheet), and is available on the OSHA website (http://www.osha.gov/SLTC/syntheticmineralfibers). 8.2.1 Follow OSHA-recommended safe handling practices listed in Section 7.2 above. 8.2.2 Where feasible, general dilution ventilation or local exhaust ventilation should be used as necessary to

maintain exposures below applicable exposure limits. Dust collection systems should be used in cutting or machining operations and may be needed when using power tools.

8.2.3 Follow OSHA-recommended work practices when fabricating, installing or removing product.

8.3 Personal Protective Equipment:: 8.3.1 Respiratory:

8.3.1.1 General: In poorly ventilated areas when dusty conditions exist and/or dust levels exceed applicable exposure

limits, wear a NIOSH certified dust respirator with an efficiency rating of N95 or higher. Use disposable face masks complying with NIOSH respirator standards, such as a 3M Model 8210 (or 8710) (3M Model 9900 in high humidity environments) or equivalent. For exposures up to five times the established exposure limits use a quarter-mask respirator, rated N95 or higher; and for exposures up to ten times the established exposure limits use a half-mask respirator (e.g. MSA’s DM-11, Racal’s Delta N95, 3M’s 8210), rated N95 or higher. For exposures up to 50 times the established exposure limits use a full-face respirator, rated N99 or higher.

8.3.1.2 Specific Operations: In poorly ventilated areas when dusty conditions exist and/or dust levels exceed applicable exposure

limits, wear a NIOSH certified dust respirator with an efficiency rating of N95 or higher, such as a 3M Model 8210 (or 8710) (3M Model 9900 in high humidity environments) or equivalent, when fabricating, installing or removing product.

8.3.2 Skin:

Wear loose fitting, long sleeved and long-legged clothing to prevent irritation. A head cover is also recommended, especially when working with material overhead. The use of suitable gloves is also recommended. Skin irritation cannot occur if there is no contact with the skin. Do not tape sleeves or pants at wrists or ankles. Remove fibers from the work clothes, before leaving work to reduce potential skin irritation. If working in a very dusty environment it is advisable to shower and change clothes

8.3.3 Eyes/Face:

Wear safety goggles or safety glasses with side shields.

9. Physical and Chemical Properties:

9.1 Appearance: Grey, green fibrous batt or board

9.2 State: Solid

9.3 Odor: May have slight resin odour

9.4 Boiling point:: n.a.

9.5 Melting point: Approximately 2150 F (1177 C)

9.6 Vapour pressure: n.a.

9.7 Vapour Density: n.a.

9.8 Specific Gravity: n.a.

9.9 Evaporation Rate: n.a.

9.10 Freezing Point: n.a.

9.11 Viscosity: n.a.

9.12 Solubility: Insoluble (H2O)

9.13 Partition coefficient: n.a.

n.a. = not applicable




10. Stability and Reactivity:

10.1 Stability: Stable 10.2 Reactivity: Not reactive 10.3 Thermal decomposition products: Primary combustion products of the cured urea extended phenolic formaldehyde binder, when heated above

390 F (200 C), are carbon monoxide, carbon dioxide, ammonia, water and trace amounts of formaldehyde. Other undetermined compounds could be released in trace quantities. Emission usually only occurs during the first heating. The released gases may be irritating to the eyes, nose and throat during initial heat-up. Use appropriate respirators (air supplied) particularly in tightly confined or poorly ventilated areas during initial heat-up.

10.4 Hazardous Polymerization: Will not occur 10.5 Incompatible Materials: This product reacts with hydrofluoric acid.

11. Toxicological Information:

11.1 Acute Toxicity:

Coarse fibers and dust from mineral wool products can cause temporary mechanical irritation (itching, redness) of the skin, and of the mucous membranes in the eyes and in the upper respiratory tract (nose and throat). The itching and possible inflammation are a mechanical reaction to dust and coarse fibers (of more than about 5 µm in diameter), and are not damaging in the way chemical irritants may be. They generally abate within a short time after the end of exposure. When products are handled continually, the skin itching generally diminishes.

11.2 Chronic Toxicity:

11.2.1 Summary: In October 2001, IARC completed a re-evaluation of respirable mineral wool fibers and classified them in Group 3 (not classifiable as to their carcinogenicity to humans). A summary of the most important scientific studies appears below:

11.2.2 Human Data:

11.2.2.1 The possible carcinogenic effects of exposure to mineral wool fibers has been evaluated in a number of

epidemiological (human) studies. Most of this research, including large long-tem studies of mineral wool production workers in the U.S. and Europe, has been sponsored or supported by the North American and International thermal insulation industries, including Roxul Inc. Published reports of the early results of these studies identified significantly elevated rates of respiratory cancer in several subcohorts of the worker populations under evaluation (e.g., Simonato et al. 1987; Enterline et al. 1987). However, the studies had several methodological limitations, including failure to control for confounding exposures to other possible causes of the elevated cancer risk, including tobacco use and occupational exposures to recognized carcinogens such as asbestos. For these reasons, the authors of these reports did not interpret the results as establishing an association between exposure to mineral wool fibers and an increased risk of cancer. Several of these earlier reports formed part of the basis for IARC’s previous classification of mineral wool fibers in Group 2B (possibly carcinogenic to humans) (IARC 1987).

11.2.2.2 Follow-up studies, including case-control studies designed to exclude the contribution of confounding

exposures to the cancer experience of the study populations, found no evidence that mineral wool fibers are associated with an increased cancer risk (Marsh et al. 1996; Wong, et al. 1991; Kjaerheim et al. 2001). In announcing the new Group 3 classification for mineral wool fibers, IARC stated: “Epidemiologic studies published during the 15 years since the previous IARC Monographs review of these fibers in 1988 provide no evidence of increased risks of lung cancer or of mesothelioma (cancer of the lining of the body cavities) from occupational exposures during manufacture of these materials” (IARC 2001).

11.2.3 Animal Data:

11.2.3.1 Several studies of intraperitoneal injection of high doses of mineral wool fibers have produced

significant increases in the incidence of mesothelioma (IARC 2002). The intraperitoneal injection studies formed part of the basis for IARC’s previous (IARC 1987) Group 2B classification for mineral wool fibers. Leading scientists agree that intraperitoneal injection studies (i.e., surgical implantation or injection into the chest or abdomen) are the least relevant type of animal study for evaluating




potential human risk for fiber exposures, because such studies bypass the animals’ natural defense mechanisms and involve a type and pattern of exposure (implantation of a high dose early in life) that does not mimic human patterns of exposure (inhalation of much lower doses over a lifetime) (National Research Council 2000).

11.2.3.2 A well-designed long-term inhalation study in rats exposed to mineral wool fibers found no significant

increase in lung tumor incidence, and no mesotheliomas (IARC 2002). Likewise, in two intratracheal instillation studies of mineral wool fibers, no significant increase in the incidence of lung tumors or mesotheliomas was found (IARC 2002). Inhalation studies are regarded as the most relevant type of animal data for evaluating potential human risk, and intratracheal instillation studies, while less relevant, are considered valuable for the initial screening of fibrous compounds (National Research Council 2000). Thus, evaluating all the available animal studies in conjunction with the human data,

IARC’s most recent review finds “inadequate evidence overall for any cancer risk” from mineral wool fibers (IARC 2001).

11.3 Evaluations of Potential Carcinogenicity:

Source Classification Description

IARC Group 3 Not Classifiable as a Human Carcinogen

ACGIH Group A3 Confirmed Animal Carcinogen with Unknown Relevance to Humans

12. Ecological Information:

12.1 Ecotoxicity: No data available for the products. The products are stable, are not expected to cause harm to

animals, plants or fish, and have no other known adverse environmental effects. 12.2 Environmental Fate: No data available for the products.

13. Disposal Considerations: 13.1 US EPA Waste Number & Descriptions:

13.1.1 General Product Information: The products, as supplied, are not expected to be a characteristic hazardous waste under RCRA if discarded.

13.1.2 EPA Waste Numbers: No EPA Waste Numbers are applicable for this product's components. 13.2 Disposal Instructions: Product is not considered a hazardous waste. Dispose of waste material according to

Federal, State, Provincial, and Local environmental regulations.

14. Transport Information: 14.1 General: No special precautions.

14.2 US DOT Information: This product is not classified as a hazardous material for transport.

15. Regulatory Information: 15.1 U.S. Regulations: 15.1.1 Toxic Substances Control Act (TSCA): All components in this product are listed, as required, on the US

EPA TSCA inventory, or are not required to be listed

15.1.2 CERCLA: Includes mineral fiber emissions from facilities manufacturing or processing glass rock or slag fibers (or other mineral derived fibers) of average diameter 1 micrometer or less; Statutory RQ = 1 pound (.454 kg); no final RQ is being assigned to the generic or broad class (related to Fine mineral fibers).




15.1.3 Clean Air Act: Mineral wool fiber appears on the Clean Air Act-1990 Hazardous Air Pollutants List. 15.2 State and Local Regulations: State, Provincial, and Local regulations not identified in this Material Safety Data

Sheet may apply. 15.3 WHMIS: The products have been classified in accordance with the hazard criteria of the Controlled Product

Regulations and this Material Safety Data Sheet contains all the information required by the Controlled Product Regulations

15.3.1: WHMIS IDL: No components are listed on the IDL

15.3.2: WHMIS Classification: No components are classified as controlled products.

16. Further Information:

16.1 Potential Health Effects:

IARC Monograph Man-made Vitreous Fibres, press release October 2001 Safety in the Use of Mineral and Synthetic Fibers, Occupational Safety and Health Series. International Labor Office (ILO).

Information about “Health and Safety Research on Rock- and Slag-wool” can be obtained from the North American Insulation Manufacturers Association (NAIMA), 44 Canal Center Plaza, Suite 310, Alexandria, VA 22314, USA). Home-page: http://www.naima.org

16.2 Key/Legend:

ACGIH = American Conference of Governmental Industrial Hygienists; CAA = Clean Air Act; CAS = Chemical Abstracts Service; CERCLA = Comprehensive Environmental Response, Compensation and Liability Act; DOT = Department of Transportation; EPA = Environmental Protection Agency; HMIS = Hazardous Material Identification System; HSPP = Health and Safety Partnership Program; IARC = International Agency for Research on Cancer; MSDS = Material Safety Data Sheet; NAIMA = North American Insulation Manufacturers Association; NFPA = National Fire Protection Association; NIOSH = National Institute for Occupational Safety and Health; OSHA = Occupational Safety and Health Administration; PEL = Permissible Exposure Limit; RCRA = Resource Conservation and Recovery Act; RQ = Reportable Quantity; SVF = synthetic vitreous fibers; TSCA = Toxic Substances Control Act; TWA = time-weighted average; WHMIS = Workplace Hazardous Materials Information System.

16.3 References: Complete citations, or copies, of all references cited in this Material Safety Data Sheet can be

obtained from Roxul Inc. (see Section 1). 16.4 Accuracy: The information contained herein is based upon data considered to be accurate. However, no

warranty is expressed or implied regarding the accuracy of these data, the results to be obtained from the use thereof, or that any such use will not infringe upon any patent. This information is furnished as a guide only and upon the condition that the person receiving it shall make tests to determine the accuracy and suitability for his or her own purpose.

http://www.naima.org/

(Effective Date January 1, 2014)

MATERIAL SAFETY DATA SHEETManufacturer’s Data: Floor Sweep, Inc. Telephone : 704-596-4570

4239 Joe Street Fax : 704-596-5588

Charlotte, N.C. 28206 Contact: Robin D. Garner

I. Product Identification

Oil Base :Sweeping compound (Intended use on concrete or non-waxed surfaces)

Wax Base : Sweeping compound (Intended use on resilient tile,linoleum,terazzo)

Ingredients : Trade Secret, Info withheld per OSHA (CFR 1910.1200)

II. Hazardous Components No known hazardous components per 29 CFR 1910.1200

NFPA Codes: Health code: 1, Flammability: 1, Reactivity: 0, Personal protection: N/A

III. Physical and Chemical Characteristics Volatility and Solubility : Nil

Appearance : Oil Base - Green with Pine Scent

Wax Base - Red with Pine Scent

IV. Fire and Explosion Data Flashpoint : Greater than 350 degrees F

The compounds should be stored away from fire sources. If ignited by

exposure to high temperatures, treat as sawdust fire and extinguish with

CO2 or Foam. Considered Stable: Will not flash spontaneously.

V. Health Hazard Data First Aid Procedures : The products require no respiratory or other forms of

protective equipment as there is little or no effects form overexposure. If

irritation occurs, wash irritated area with soap and water.

VI. Environmental Protection Sweep up and dispose utilizing permitted industrial waste disposal site. Not considered

EPA hazardous waste.

VII. Other Data : Instructions for use, and Shelf Life Data Products should be applied to floor surface and swept up immediately as surface

could become slippery if applied for extended periods of time.

Shelf Life : Products should be used within 6 months from date of purchase.

MSDS-Propane-32003-2 (01/14) Side 1 of 2


SECTION 1 – PRODUCT INFORMATION

Product Name: Propane

Trade Name: LPG (Liquefied Petroleum Gas), LP-Gas

Chemical Formula: C3H8

WHMIS Classification Class A – Compressed Gas

Class B, Division 1 – Flammable G

Supplier: Superior Propane

A Division of Superior Plus LP

1111 - 49th Avenue N.E.

Calgary, AB T2E 8V2

Business: (403) 730-7500

24-Hour

Emergency Contact: Canutec (613) 996-6666

Application and Use: Propane is commonly used as a fuel for heating, cooking, automobiles, forklift trucks, crop drying and welding

and cutting operations. Propane is used in industry as a refrigerant, solvent and as a chemical feedstock.

SECTION 2 – HAZARDOUS INGREDIENTS

COMPONENTS

CAS No

% VOLUME (v/v)

LD 50 (RAT, ORAL)

Propane 74-98-6 90% -99% Not Applicable

Propylene

E thane

Butane and heavier hydro carbons

Occupational Exposure Limit:

115-07-1

74-84-0

106-97-8

0% - 5%

0% - 5%

0% - 2.5%

Not Applicable

Not Applicable

Not Applicable

Based upon animal test data, the acute toxicity of this product is expected to be inhalation: 4 hour LC50 = 280,000 ppm (Rat)

Note: Composition is typical for HD-5 Propane per The Canadian General Standard Board CGSB 3.14 National Standard of Canada.

Exact composition will vary from shipment to shipment.

SECTION 3 – CHEMICAL AND PHYSICAL DATA

Form: Liquid and vapour while

stored under pressure

Boiling Point: -42°C @ 1 atm

Freezing Point: -188°C

Evaporation Rate: Rapid (Gas at normal ambient conditions)

Vapour Pressure: 1435 kPa (maximum) @ 37.8°C

Vapour Density: 1.52 (Air = 1)

Coefficient of Water/Oil Distribution: Not available

pH: Not available

Solubility in Water: Slight, 6.1% by volume @ 17.8°C

Specific Gravity: 0.51 (water = 1)

Appearance/Odour: Colourless liquid and vapour while stored

under pressure. Colourless and odourless

gas in natural state at any concentration.

Commercial propane has an odourant

added, ethyl mercaptan, which has an

odour similar to boiling cabbage.

Odour Threshold: 4800 ppm

With proper handling, transportation and storage, adding a chemical odourant such as ethyl mercaptan has proven to be a very

effective warning device, but all odourants have certain limitations. The effectiveness of the odourant may be diminished by a person’s sense of smell, by competing odours and by oxidation which may cause a potentially dangerous situation.

SECTION 4 – FIRE OR EXPLOSION HAZARD

Flash Point: -103.4°C

Method: Closed cup

Flammable Limits: Lower 2.4%, Upper 9.5%

Auto Ignition Temperature: 432 °C

Hazardous Combustion Products: Carbon monoxide can be

produced when primary air and secondary air are while

combustion is taking place.

Fire and Explosive Hazards: Explosive air - vapour allowed to

leak to atmosphere.

Sensitivity to Impact: No

Sensitivity to Static Discharge: Yes

SECTION 5 – REACTIVITY DATA

Conditions to Avoid: Keep separate from oxidizing agents.

Gas explodes spontaneously when mixed with chloride dioxide.

Incompatibility: Remove sources of ignition and observe distance

requirements for storage tanks from combustible

Fire Extinguishing Precautions: Use water spray to cool exposed

cylinders or tanks. Do not extinguish fire unless the source of the

escaping gas that is fueling the fire can be turned off.

Fire can be extinguished with carbon dioxide and/or dry chemical

(BC). Container metal shells require cooling with water to prevent

impingement and the weakening of metal.

If sufficient water is not available to protect the container shell from

weakening, the area will be required to be evacuated.

If gas has not ignited, liquid or vapour may be dispersed by water

spray or flooding.

Special Fire Fighting Equipment: Protective clothing, hose monitors,

fog nozzles, self-contained breathing apparatus material, drains and

openings to building

Hazardous Decomposition Products: Deficient primary and

secondary air can produce carbon monoxide.

Hazardous Polymerization: Will not occur.

MSDS-Propane-32003-2 (01/14) Side 2 of 2

SECTION 6 – TOXICOLOGICAL PROPERTIES OF MATERIAL

Routes of Entry: Skin Contact, Eye Contact, Inhalation

Inhalation: Simple asphyxiant. No effect at concentrations of

10,000 ppm (peak exposures). Higher concentrations may cause

central nervous system disorder and/or damage. Lack of oxygen

may cause dizziness, loss of coordination, weakness, fatigue,

euphoria, mental confusion, blurred vision, convulsions, breathing

failure, coma and death. Breathing high vapour concentrations

(saturated vapours) for a few minutes may be fatal. Saturated

vapours may be encountered in confined spaces and/or under

conditions of poor ventilation. Avoid breathing vapours or mist.

Skin and Eye Contact: Exposure to vapourizing liquid may cause

frostbite (cold burns) and permanent eye damage.

Ingestion: Not considered to be a hazard.

SECTION 7 – PREVENTATIVE MEASURES

Acute Exposure: Contact with Liquefied Petroleum Gas may cause

frostbite or cold burns. Propane acts as a simple asphyxiant as oxygen

content in air is displaced by the propane. At increasing

concentration levels, propane may cause dizziness, headaches, loss of

coordination, fatigue, unconsciousness and death.

Chronic Exposure: No reported effects from long term low level

exposure.

Sensitization to Product: Not known to be a sensitizer.

Occupational Exposure Limits: American Conference of

Governmental Industrial Hygienists (ACGIH) lists as a simple

asphyxiant.

ACGIH TLV: 1000 ppm

Carcinogenicity, Reproductive Toxicity, Teratogenicity,

Mutagenicity: No effects reported.

Other Toxicological Effects: None

Eyes: Safety glasses or chemical goggles are recommended when transferring product.

Skin: Insulated gloves required if contact with liquid or liquid cooled equipment is expected. Wear gloves and long

sleeves when transferring product.

Inhalation: Where concentration in air would reduce the oxygen level below 18% air or exceed occupational exposure limits

in section 6, self-contained breathing apparatus is required.

Ventilation: Use in well-ventilated areas. Use with explosion proof mechanical ventilation in confined spaces or poorly

ventilated areas.

SECTION 8 – EMERGENCY AND FIRST AID PROCEDURES

Eyes: Should eye contact with liquid occur, flush eyes with lukewarm water for 15 minutes. Obtain immediate

medical care.

Skin: In case of Cold Burn from contact with liquid, immediately place affected area in lukewarm water and keep at this

temperature until circulation returns. If fingers or hands are frostbitten, have the victim hold his hand next to his body such

as under the armpit. Obtain immediate medical care.

Ingestion: None considered necessary.

Inhalation: Remove person to fresh air. If breathing is difficult or has stopped, administer artificial respiration. Obtain immediate

medical care.

Spill or Leak: Eliminate leak if possible. Eliminate source of ignition. Ensure cylinder is upright. Disperse vapours with hose streams

using fog nozzles. Monitor low areas as propane is heavier than air and can settle into low areas. Remain upwind of leak.

Keep people away. Prevent vapour and/or liquid from entering into sewers, basements or confined areas.

SECTION 9 – TRANSPORTATION, HANDLING AND STORAGE

• Transport and store cylinders and tanks secured in an

upright position in a ventilated space away from ignition

sources (so the pressure relief valve is in contact with

the vapour space of the cylinder or tank).

• Cylinders that are not in use must have the valves in the

closed position and be equipped with a protective cap or guard.

Transportation of Dangerous Goods (TDG)

TDG Classification: Flammable Gas 2.1

AARR SECTION 10 – PREP ATION INFORMATION

• Do not store with oxidizing agents, oxygen, or chlorine

cylinders.

• Empty cylinders and tanks may contain product residue.

Do not pressurize, cut, heat or weld empty containers.

• Transport, handle and store according to applicable federal

and provincial codes and regulations.

TDG Shipping Name: Liquefied Petroleum Gas (Propane)

PIN Number: UN1075

Prepared by: Superior Propane

Health Safety and Environment Team

Telephone: (403) 730-7500

Revision: January 17, 2014

Supersedes: January 17, 2011

The information contained herein is believed to be accurate. It is provided independently of any sale of the product. It is not intended to

constitute performance information concerning the product. No express warranty, implied warranty of merchantability or fitness for a particular

purpose is made with respect to the product information contained herein.

MATERIAL SAFETY DATA SHEET ISSUE DATE: 5/4/98

REVISED DATE: 6/22/12 Supersedes: Any Previous M.S.D.S. On This Product

EMERGENCY PHONE NUMBER: CHEM-TEL, INC. 1-800-255-3924

I. IDENTIFICATION

PRODUCT NAME: PROtack/PROtack HV DUCTMATE INDUSTRIES, INC. PRODUCT CLASS: Water Based Duct Liner Adhesive 210 5th St. Charleroi, PA 15022

II. HAZARDOUS INGREDIENTS REPORTING REQUIREMENTS: OSHA Hazard Communication Standard (29CFR1910.1200) hazard class………………….….None EPA SARA Title III Section 312 (40CFR370) hazard class……………………………………..None EPA SARA Title III Section 313 (40CFR372) toxic chemicals above “de minimis” level are….None CALIFORNIA PROP 65 substances listed by the State of California under the “Safe Drinking Water and Toxic Enforcement Act of 1986”. No such substances are present in reportable amounts for occupational exposure as per OSHA’s approval of the California Hazard Communication Standard, Federal Register, page 31159 ff, 6 June 1997.

III. PHYSICAL DATA APPEARANCE: Grey Liquid SOLUBILITY IN WATER: Dilutable BOILING POINT: 100 C / 212 F WEIGHT PER GALLON: 9.5 .2 lbs./gallon VOLATILE BY WEIGHT: 60% 2% (Water) VAPOR DENSITY: Heavier than Air. EVAPORATION RATE: Slower than Ether. ODOR: Mild PHYSICAL STATE: Liquid Ph: 8 to 9.5 VOC CONTENT: 40 g/L EPA Method 24

IV. HEALTH AND FIRST AID CAUTION: May cause discomfort in eyes. Prolonged or repeated contact with skin may cause dryness. IN EYES: Flush with water for 15 minutes. ON SKIN: Wash with soap and water. INGESTED: Seek medical attention. INHALATION: No effects expected. If difficulty breathing occurs remove to fresh air and consult physician.

V. FIRE AND EXPLOSION HAZARD DATA FLAMMABILITY CLASS (OSHA/NFPA): None. FLASH POINT: >212 F PM Closed Cup EXTINGUISHING MEDIA: Water or dry type extinguisher. UNUSUAL FIRE HAZARD: Containers may burst when exposed to extreme heat. FIRE FIGHTING PROCEDURES: Firemen should wear equipment to protect against noxious fumes. Self contained breathing apparatus may be needed. PRODUCT OF COMBUSTION: May yield Carbon Monoxide and/or Carbon Dioxide.

VI. SPILL OR LEAK PROCEDURES Dike area to prevent spill from spreading. Collect spilled material in salvage container. Small amounts may be absorbed into appropriate absorbents. Prevent spill from entering sewers, drains, and waterways. Dispose of product in accordance with applicable local, state, and federal regulations.

VII. SPECIAL PROTECTION VENTILATION: Provide sufficient ventilation to maintain constant fresh air in workplace. EYE PROTECTION: Use safety goggles when splash potential exists. HAND PROTECTION: Protective impervious gloves are recommended. OTHER: A clean source of water should be available for washing eyes and skin.

VIII. TRANSPORTATION INFORMATION Non-flammable, as a Latex compound U.S.A.: Regulation by the following: DOT, IMO, ICAD/IATA: None Canada: Regulation by the following: DSL, WHMIS: None European: EEC SYMBOL: None EEC Classification, Packaging and Labeling of Dangerous Substances: None TSCA 12(b) Export Notification Requirement: TSCA 12(b) Export Notification Requirement: All components of this product are either listed on the U.S. Toxic Substances Control Act (TSCA) inventory of chemicals or are otherwise compliant with TSCA regulations. Acrylic Acid residual monomer CAS# 79-10-7

IX. REACTIVITY DATA STABILITY: Stable under normal conditions of handling and use. INCOMPATIBILITY: Products may react violently with products that react with water. HAZARDOUS DECOMPOSITION: Fumes produced when heated to decomposition may include: oxides of carbon, nitrogen, and sulfur along with hydrocarbon residues. HAZARDOUS POLYMERIZATION: Will not occur.

X. SPECIAL PRECAUTIONS HANDLING AND STORAGE: Store in tightly closed containers, at temperatures 45 F to 90 F. Guard against inhalation of excess vapors, ingestion, and contact with skin and eyes. Change soiled workclothes frequently. Clean hands after handling. Precautions also apply to emptied containers. Keep containers away from extreme heat and cold. Prevent from freezing, but if product is allowed to freeze, thaw completely before use. This information is taken from sources or based upon data believed to be reliable; however, DUCTMATE INDUSTRIES, INC. makes no warranty as to the absolute correctness or sufficiency of any of the foregoing or that additional or other measures may not be required under particular conditions. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist, as all materials may present unknown health hazards.

199/6-12

Revision 9/13; MSDS Form No. 81451 - Page 1 of 10

USED OIL MATERIAL SAFETY DATA SHEET

SECTION 1: PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: USED OIL SYNONYMS: Waste oil; Used lubricating oil; Oil and water mixture PRODUCT PART NUMBER(S): Not applicable. PRODUCT USE: Oil or water mixture for re-refining or reprocessing.

If this product is used in combination with other products, refer to the Material Safety Data Sheets for those products.

24-HOUR EMERGENCY PHONE NUMBERS These numbers are for MEDICAL AND TRANSPORTATION (SPILL): emergency use only. If you desire non-emergency 1-800-468-1760 product information, please call a phone number listed below. MANUFACTURER/ SUPPLIER: Safety-Kleen Systems, Inc.

2600 North Central Expressway Suite 400 Richardson, Texas 75080 USA 1-800-669-5740 www.safety-kleen.com

TECHNICAL INFORMATION: 1-800-669-5740 Press 1 then 1 then Extension 7500 MSDS FORM NUMBER: 81451 ISSUE: September 15, 2013 ORIGINAL ISSUE: January 15, 1990 SUPERSEDES: September 15, 2010 PREPARED BY: Product MSDS Coordinator APPROVED BY: MSDS Task Force



SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS

OSHA PEL ACGIH TLV®

WT% NAME SYNONYM CAS NO. TWA STEL TWA STEL LDa LCb 80 to 100 Lubricating oils, used Used oil 70514-12-4 N. Av. N. Av. N. Av. N. Av. N. Av. N. Av. 0 to 20* Water/solids N. Av. N. Av. N. Av. N. Av. N. Av. N. Av. N. Av. N. Av. 0 to 10* Hydrocarbon solvents.

May include gasoline, diesel fuel, jet fuel, mineral spirits, etc.

N. Av. N. Av. N. Av. N. Av. N. Av. N. Av. N. Av. N. Av.

0 to 1.5* Metals.

May include lead, iron, zinc, copper, chromium, arsenic, nickel, and others: each below 1.0 WT%.


0 to 1.0* Polynuclear aromatics.

May include naphthalene, fluoranthene, phenanthrene, pyrene, and others: each below 0.3 WT%.


0 to 0.5* Chlorinated solvents. N. Av. N. Av. N. Av. N. Av. N. Av. N. Av. N. Av. N. Av.

N.Av. = Not Available *Even though the concentration range does not fall under the ranges prescribed by WHMIS, this is the actual range which varies with each batch of the product.

aOral-Rat LD50 (mg/kg)

bInhalation-Rat LC50

SECTION 3: HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW APPEARANCE Liquid, black and viscous (thick), petroleum odor. WARNING! PHYSICAL HAZARDS Combustible liquid. HEALTH HAZARDS May be harmful if inhaled. May be harmful if absorbed through skin. May be harmful or fatal if swallowed. May irritate the respiratory tract (nose, throat, and lungs), eyes, and skin. Suspect cancer hazard. Contains material which can cause cancer. Risk of cancer depends

on duration and level of exposure. Contains material which can cause birth defects. Contains material which can cause central nervous system damage. ENVIRONMENTAL HAZARDS Product may be toxic to fish, plants, wildlife, and/or domestic animals.



POTENTIAL HEALTH EFFECTS Effects may vary depending on material composition. Typical effects may include: INHALATION High concentrations of vapor or mist may be harmful if inhaled. High (BREATHING): concentrations of vapor or mist may irritate the respiratory tract (nose, throat,

and lungs). High concentrations of vapor or mist may cause nausea, vomiting, headaches, dizziness, loss of coordination, numbness, and other central nervous system effects. Massive acute overexposure may cause rapid central nervous system depression, sudden collapse, coma, and/or death.

EYES: May cause irritation. SKIN: May cause irritation. Product may be absorbed through the skin and cause

harm as noted under INHALATION (BREATHING). INGESTION May be harmful or fatal if swallowed. May cause throat irritation, (SWALLOWING): nausea, vomiting, and central nervous system effects as noted under

INHALATION (BREATHING). Breathing product into the lungs during ingestion or vomiting may cause lung injury and possible death.

MEDICAL CONDITIONS Individuals with pre-existing cardiovascular, liver, kidney, AGGRAVATED BY respiratory tract (nose, throat, and lungs), central nervous EXPOSURE: system, eye, and/or skin disorders may have increased

susceptibility to the effects of exposure. CHRONIC: Prolonged or repeated inhalation may cause oil pneumonia, lung tissue

inflammation, fibrous tissue formation, and/or toxic effects as noted under INHALATION (BREATHING). Prolonged or repeated eye contact may cause inflammation of the membrane lining the eyelids and covering the eyeball (conjunctivitis). Prolonged or repeated skin contact may cause drying, cracking, redness, itching, and/or swelling (dermatitis).

CANCER This product contains mineral oils, untreated or mildly treated, which can INFORMATION: cause cancer. This product may contain hydrocarbon and chlorinated

solvents; metals, and polynuclear aromatics which can cause cancer. Risk of cancer depends on duration and level of exposure. For more information, see SECTION 11: CARCINOGENICITY.

POTENTIAL ENVIRONMENTAL EFFECTS Product may be toxic to fish, plants, wildlife, and/or domestic animals. Also see SECTION 12: ECOLOGICAL INFORMATION.



SECTION 4: FIRST AID MEASURES

INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing (BREATHING) is difficult, give oxygen. Oxygen should only be administered by qualified

personnel. Someone should stay with victim. Get medical attention if breathing difficulty persists.

EYES: If irritation or redness from exposure to vapor develops, move away from

exposure into fresh air. Upon contact, immediately flush eyes with plenty of lukewarm water, holding eyelids apart, for 15 minutes. Get medical attention.

SKIN: Remove affected clothing and shoes. Wash skin thoroughly with soap and

water. Get medical attention if irritation or pain develops or persists. INGESTION: Do NOT induce vomiting. Immediately get medical attention. Call (SWALLOWING) 1-800-468-1760 for additional information. If spontaneous vomiting occurs,

keep head below hips to avoid breathing the product into the lungs. Never give anything to an unconscious person by mouth.

NOTE TO Treat symptomatically and supportively. Treatment may vary with condition PHYSICIANS: of victim and specifics of incident. Call 1-800-468-1760 for additional

information.

SECTION 5: FIRE FIGHTING MEASURES

FLASH POINT: >200°F (93°C) (minimum) Pensky-Martens Closed Cup FLAMMABLE LIMITS IN AIR: Not available. AUTOIGNITION TEMPERATURE: Not available. HAZARDOUS COMBUSTION Decomposition and combustion materials may be toxic. PRODUCTS: Burning may produce phosgene gas, nitrogen oxides, carbon

monoxide, and unidentified organic compounds. CONDITIONS OF FLAMMABILITY: Heat, sparks, or flame. Product may burn but does not ignite readily. EXTINGUISHING MEDIA: Use carbon dioxide, regular foam, dry chemical, water spray,

or water fog.



NFPA 704 HAZARD This information is intended solely for the use by individuals IDENTIFICATION: trained in this system.

FIRE FIGHTING Keep storage containers cool with water spray. INSTRUCTIONS: A positive-pressure, self-contained breathing apparatus

(SCBA) and full-body protective equipment are required for fire emergencies.

FIRE AND Heated containers may rupture. “Empty” containers may EXPLOSION HAZARDS: retain residue and can be dangerous. Product is not sensitive

to mechanical impact. Product may be sensitive to static discharge, which could result in fire or explosion.

SECTION 6: ACCIDENTAL RELEASE MEASURES

Remove all ignition sources. Do not touch or walk through spilled product. Stop leak if you can do it without risk. Wear protective equipment and provide engineering controls as specified in SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION. Isolate hazard area. Keep unnecessary and unprotected personnel from entering. Ventilate area and avoid breathing vapor or mist. A vapor suppressing foam may be used to reduce vapors. Contain spill away from surface waters and sewers. Contain spill as a liquid for possible recovery, or sorb with compatible sorbent material and shovel with a clean, sparkproof tool into a sealable container for disposal. Additionally, for large spills: Water spray may reduce vapor, but may not prevent ignition in closed spaces. Dike far ahead of liquid spill for collection and later disposal. There may be specific federal regulatory reporting requirements associated with spills, leaks, or releases of this product. Also see SECTION 15: REGULATORY INFORMATION.

1 01

0

FIRE HAZARD (RED)

REACTIVITY (YELLOW)

HEALTH HAZARD (BLUE)

SPECIFIC HAZARD (WHITE)



SECTION 7: HANDLING AND STORAGE

HANDLING: Keep away from heat, sparks, or flame. Where flammable mixtures may be

present, equipment safe for such locations should be used. Use clean, sparkproof tools and explosion-proof equipment. When transferring product, storage tanks, tanker trucks, and rail tank cars should be grounded and bonded. Do not breathe vapor or mist. Use in a well ventilated area. Avoid contact with eyes, skin, clothing, and shoes. Do not smoke while using this product.

SHIPPING AND Keep container tightly closed when not in use and during transport. Do not STORING: pressurize, cut, weld, braze, solder, drill, or grind containers. Keep

containers away from heat, flame, sparks, static electricity, or other sources of ignition. Empty product containers may retain product residue and can be dangerous. See SECTION 14: TRANSPORT INFORMATION for Packing Group information.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

ENGINEERING Use general ventilation, process enclosures, local exhaust ventilation, or CONTROLS: other engineering controls to control air-borne levels. Where explosive

mixtures may be present, equipment safe for such locations should be used.

PERSONAL PROTECTIVE EQUIPMENT RESPIRATORY A respiratory protection program which meets USA’s OSHA General PROTECTION: Industry Standard 29 CFR 1910.134 or Canada’s CSA Standard

Z94.4-M1982 requirements must be followed whenever workplace conditions warrant a respirator’s use. Consult a qualified Industrial Hygienist or Safety Professional for respirator selection guidance.

EYE Wearing chemical goggles is recommended. PROTECTION: Contact lens may be worn with eye protection. SKIN Where prolonged or repeated skin contact is likely, wear neoprene, PROTECTION: nitrile (4 mil minimum), PVC (polyvinyl chloride), or equivalent protective gloves; wearing natural rubber or equivalent gloves is not recommended. When product is heated and skin contact is likely, wear

heat-insulating gloves, boots, and other protective clothing. To avoid prolonged or repeated contact with product where spills and

splashes are likely, wear appropriate chemical-resistant faceshield, boots, apron, whole body suits, or other protective clothing.



PERSONAL Wash thoroughly with soap and water after handling product and before HYGIENE: eating, drinking, or using tobacco products. Clean affected clothing, shoes,

and protective equipment before reuse. Discard affected clothing, shoes, and/or protective equipment if they cannot be thoroughly cleaned. Discard leather articles, such as shoes, saturated with the product.

OTHER Where spills and splashes are likely, facilities storing or using this product PROTECTIVE should be equipped with an emergency eyewash and shower, both EQUIPMENT: equipped with clean water, in the immediate work area.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE, APPEARANCE, AND ODOR: Liquid, black and viscous (thick), petroleum odor. ODOR THRESHOLD: Not available. MOLECULAR WEIGHT: Not applicable.

SPECIFIC GRAVITY: 0.8 to 1.0 at 60°F (15.6°C) (water = 1) DENSITY: 6.7 to 8.3 LB/US gal (800 to 1000 g/l) (approximately) VAPOR DENSITY: greater than 1 (air = 1) (based on kerosene)

VAPOR PRESSURE: Not available. BOILING POINT: Not available. FREEZING/MELTING POINT: Not available. pH: Not applicable. EVAPORATION RATE: less than 1 (butyl acetate = 1) SOLUBILITY IN WATER: Slight.

FLASH POINT: >200°F (93°C) (minimum) Pensky-Martens Closed Cup FLAMMABLE LIMITS IN AIR: Not available. AUTOIGNITION TEMPERATURE: Not available.



SECTION 10: STABILITY AND REACTIVITY

STABILITY: Stable under normal temperatures and pressures. Avoid heat, sparks, or

flame. INCOMPATIBILITY: Avoid acids, alkalies, oxidizing agents, reducing agents, reactive

halogens, or reactive metals. REACTIVITY: Polymerization is not known to occur under normal temperatures and

pressures. Not reactive with water. HAZARDOUS DECOMPOSITION None under normal temperatures and pressures. Also see PRODUCTS: SECTION 5: HAZARDOUS COMBUSTION PRODUCTS.

SECTION 11: TOXICOLOGICAL INFORMATION SENSITIZATION: Based on best current information, there may be known human

sensitization associated with this product. MUTAGENICITY: Based on best current information, there may be mutagenicity

associated with this product. CARCINOGENICITY: Mineral oils, untreated or mildly treated are listed by IARC as a known

carcinogen. Mineral oils, untreated or mildly treated are classified by NTP as having limited evidence of carcinogenicity in humans or sufficient evidence of carcinogenicity in experimental animals.

There may be hydrocarbon and chlorinated solvents; metals, and polynuclear aromatics present in this product which are listed by OSHA as known carcinogens. There may be hydrocarbon and chlorinated solvents; metals, and polynuclear aromatics present in this product which are listed by IARC as known, probable, or possible carcinogens. There may be hydrocarbon and chlorinated solvents; metals, and polynuclear aromatics present in this product which are classified by NTP as known carcinogens or as having limited evidence of carcinogenicity in humans or sufficient evidence of carcinogenicity in experimental animals. There may be hydrocarbon and chlorinated solvents; metals, and polynuclear aromatics present in this product which are recognized by ACGIH as confirmed or suspected human carcinogens. Also see SECTION 3: CANCER INFORMATION.



REPRODUCTIVE Based on best current information, there may be reproductive TOXICITY: toxicity associated with this product. TERATOGENICITY: Based on best current information, there may be teratogenicity

associated with this product. TOXICOLOGICALLY SYNERGISTIC Based on best current information, there may be toxicologically PRODUCT(S): synergistic products associated with this product.

SECTION 12: ECOLOGICAL INFORMATION ECOTOXICITY: Not available. OCTANOL/WATER PARTITION COEFFICIENT: Not available. VOLATILE ORGANIC Not available. COMPOUNDS: As per 40 CFR Part 51.100(s).

SECTION 13: DISPOSAL CONSIDERATIONS Dispose in accordance with federal, state, provincial, and local regulations. Regulations may also apply to empty containers. The responsibility for proper waste disposal lies with the owner of the waste. Contact Safety-Kleen regarding proper recycling or disposal.

SECTION 14: TRANSPORT INFORMATION DOT: Not regulated. TDG: Not regulated. EMERGENCY RESPONSE Not applicable. GUIDE NUMBER: Reference North American Emergency Response Guidebook

SECTION 15: REGULATORY INFORMATION USA REGULATIONS Based on the ingredient(s) listed in SECTION 2, this product does not SARA SECTIONS contain any "extremely hazardous substances" listed pursuant to Title III 302 AND 304: of the Superfund Amendments and Reauthorization Act of 1986 (SARA)

Section 302 or Section 304 as identified in 40 CFR Part 355, Appendix A and B.



SARA SECTIONS This product poses the following physical and health hazards as 311 AND 312: defined in 40 CFR Part 370 and is subject to the requirements of

sections 311 and 312 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA):

Immediate (Acute) Health Hazard Delayed (Chronic) Health Hazard

SARA SECTION This product may contain "toxic" chemicals subject to the requirements 313: of section 313 of Title III of the Superfund Amendments and

Reauthorization Act of 1986 (SARA) and 40 CFR Part 372. CERCLA: This product may contain “hazardous substances” listed pursuant to

Comprehensive Environmental Response, Compensation and Liability Act of 1980 (CERCLA) in 40 CFR Part 302, Table 302.4.

TSCA: Not available. CALIFORNIA: This product is not for sale or use in the State of California. CANADIAN REGULATIONS WHMIS: Not regulated CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA): Not available.

SECTION 16: OTHER INFORMATION REVISION INFORMATION: Regulatory review. Update to Section 1. LABEL/OTHER INFORMATION: Not available. User assumes all risks incident to the use of this product. To the best of our knowledge, the information contained herein is accurate. However, Safety-Kleen assumes no liability whatsoever for the accuracy or completeness of the information contained herein. No representations or warranties, either express or implied, of merchantability, fitness for a particular purpose or of any other nature are made hereunder with respect to information or the product to which information refers. The data contained on this sheet apply to the product as supplied to the user.

MATERIAL SAFETY DATA SHEET HMIS RATINGS: HEALTH:1, FLAMMABITY:0, REACTIVITY:0

Identity: Uvex Clear Lens Cleaner - # S461, S463, S464, S467

Section I

Manufacturer: Uvex Safety, Inc. Emergency Telephone: 401-232-1200

Address: 900 Douglas Pike Information Telephone: 800-343-3411

Smithfield, RI 02917 Date Prepared: 04/23/12

Section II - Hazardous Ingredients/Identity Information

Hazardous Components (Specific Chemical Identity; Common Name(s))

OSHA PEL 1

ACGIH TLV 1

Other limits recommended

% (optional)

Ethylene Glycol Mono Butyl Ether #111-76-2 25 PPM TWA (SKIN)

25 PPM TWA (SKIN)

N/A <6%

Section III - Physical/Chemical Characteristics

Boiling Point: 212° F (100° C) SpecificGravity (H2O=1): 0.98 at 77° F (25° C)

Vapor Pressure (mm Hg.): � 22 mm Hg at 70° F (20° C) Melting Point: N/A

Vapor Density (Air = 1) : NOT DETERMINED Evaporation Rate (Butyl Acetate = 1): < 1

Solubility in Water: 100%

Appearance and Odor: CLEAR TINTED LIQUID WITH A SLIGHT ODOR.

Section IV - Fire and Explosion Hazard Data

Flash Point (Method Used): >212°F Flammable Limits: NOTFLAMMABLE UNDER NORMAL CONDITIONS OF STORAGE & USE.

LEL: N/A UEL: N/A

Extinguishing Media: 1. WATER FOG OR SPRAY, 2. CARBON DIOXIDE (CO2), 3. DRY CHEMICAL, 4. CLASS B EXTINGUISHERS

Special Fire Fighting Procedures: KEEP FIRE EXPOSED CONTAINERS COOL. WEAR SELF-CONTAINED BREATHING APPARATUS (SCBA) AND FULL PROTECTIVE EQUIPMENT.

Unusual Fire and Explosion Hazards: N/A

Section V - Reactivity Data

Stability Unstable: NOStable: YES

Conditions to Avoid: DO NOT FREEZE, STORE IN COOL AREA.AVOID IGNITION SOURCES.

Incompatibility (Materials to Avoid): STRONG ACIDS, ALKALIES, AND OXIDIZERS.

Hazardous Decomposition or Byproducts: NONE

Hazardous Polymerization

May Occur: NOWill Not Occur: YES

Conditions to Avoid: NONE

Section VI - Health Hazard Data Route(s) of Entry: Inhalation? YES Skin? NO Ingestion? YES

Health Hazards (Acute and Chronic):. EYE CONTACT: IN SOME CASES EYE IRRITATION MAY OCCUR. IMMEDIATELY FLUSH WITH A WATER OR EYEWASH SOLUTION AND CONSULT A PHYSICIAN. IN SOME CASES SKIN CONTACT MAY CAUSE IRRITATION, IMMEDIATELY FLUSH WITH SOAP AND WATER, REMOVE CONTAMINATED CLOTHING AND CONSULT A PHYSICIAN. INGESTION: GASTRIC IRRITATION AND VOMITING. DO NOT INDUCE VOMITING, GIVE PLENTY OF WATER AND CONSULT A PHYSICIAN. PREVENT ASPIRATION OF VOMITED MATERIAL INDUCED BY INGESTION OF PRODUCT.

Carcinogenicity: NTP? NO IARC Monographs? NO OSHA Regulated? NO

Signs and Symptoms of Exposure: EYE, SKIN OR GASTRIC IRRITATION, NAUSEA, DIZZINESS, HEADACHE.

Medical Conditions Generally Aggravated by Exposure: NONE KNOWN

Emergency First Aid Procedures: SEEK MEDICAL ATTENTION IF LARGE QUANTITIES ARE SWALLOWED. WASH EXPOSED SKIN THOROUGHLY WITH SOAP & WATER. FLUSH EXPOSED EYES WITH WATER OR EYEWASH SOLUTION FOR AT LEAST 15 MINUTES. SEEK MEDICAL ATTENTION IN ALL CASES.

Section VII - Precautions for Safe Handling and UseSteps to Be Taken in Case Material is Released or Spilled: IN CASE OF LARGE SPILLS WEAR PROTECTIVE CLOTHING, NEOPRENE GLOVES AND CHEMICAL SPLASH GOGGLES.

Waste Disposal Method: ABSORB WITH SAND OR INERT MATERIAL. THEN REMOVE AND A DISPOSE OF ABSORBED MATERIAL IN AN APPROPRIATE MANNER.

Precautions to Be Taken in Handling and Storing: AVOID SKIN & EYE CONTACT. AVOID INHALATION AND INGESTION. WEAR PROTECTIVE CLOTHING, GLOVES AND SAFETY GLASSES WHEN A LARGE SPILL OR SPLASH HAZARD EXISTS. HANDLE AND STORE IN A WELL-VENTILATED AND COOL AREA.

Other Precautions: DO NOT FREEZE. STORE IN A COOL, WELL-VENTILATED AREA.

Section VIII - Control MeasuresVentilation Local Exhaust: GENERAL AIR CIRCULATION SUFFICIENT FOR NORMAL PRODUCT USE. Special: N/A

Mechanical: ADEQUATE VENTILATION Other: N/A

Protective Gloves: NONE REQUIRED FOR NORMAL PRODUCT USE. Eye Protection: NONE REQUIRED FOR NORMAL PRODUCT USE.

Other Protective Clothing: NONE REQUIRED FOR NORMAL PRODUCT USE.

Work Hygienic Practices: ALWAYS FOLLOW SAFE WORK PRACTICES.

Part #32-003108 Rev G

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IPEX GHS SAFETY DATA SHEETDate Revised: JUN 2013

Supersedes: JAN 2012

SECTION I - PRODUCT AND COMPANY IDENTIFICATION

XIRTEC 5 GRY Low VOC Cement for PVC Plastic Pipe

Low VOC Solvent Cement for PVC Plastic Pipe

IPEX Inc. MANUFACTURER: IPS Corporation

807 Pharmacy Avenue 17109 South Main Street, Gardena, CA 90248-3127

Scarborough, Ontario M1L 3K2, CAN P.O. Box 379, Gardena, CA 90247-0379

Tel. 1-310-898-3300

EMERGENCY: Transportation: CHEMTEL Tel. 800.255-3924, 813-248-0585 (International) Medical: CHEMTEL Tel. 800.255-3924, 813-248-0585 (International)

SECTION 2 - HAZARDS IDENTIFICATION

Acute Toxicity: Category 4 Acute Toxicity: None Known Flammable Liquid Category 2

Skin Irritation: Category 3 Chronic Toxicity: None Known

Skin Sensitization: NO

Eye:

GHS LABEL: Signal Word: WHMIS CLASSIFICATION: CLASS B, DIVISION 2

OR Danger

H225: Highly flammable liquid and vapor P210: Keep away from heat/sparks/open flames/hot surfaces – No smokingH319: Causes serious eye irritation P261: Avoid breathing dust/fume/gas/mist/vapors/spray

H332: Harmful if inhaled P280: Wear protective gloves/protective clothing/eye protection/face protection

H335: May cause respiratory irritation P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

H336: May cause drowsiness or dizziness P403+P233: Store in a well ventilated place. Keep container tightly closed

EUH019: May form explosive peroxides P501: Dispose of contents/container in accordance with local regulation

SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS CAS# EINECS # CONCENTRATION

Pre-registration Number % by Weight

Tetrahydrofuran (THF) 109-99-9 203-726-8 05-2116297729-22-0000 25 - 50

Methyl Ethyl Ketone (MEK) 78-93-3 201-159-0 05-2116297728-24-0000 5 - 36

Cyclohexanone 108-94-1 203-631-1 05-2116297718-25-0000 15 - 30

All of the constituents of this adhesive product are listed on the TSCA inventory of chemical substances maintained by the US EPA, or are exempt from that listing.

* Indicates this chemical is subject to the reporting requirements of Section 313 of the Emergency Planning and Community Right-to-Know Act of 1986 (40CFR372).

# indicates that this chemical is found on Proposition 65’s List of chemicals known to the State of California to cause cancer or reproductive toxicity.

SECTION 4 - FIRST AID MEASURES Contact with eyes: Flush eyes immediately with plenty of water for 15 minutes and seek medical advice immediately.

Skin contact: Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water. If irritation develops, seek medical advice.

Inhalation: Remove to fresh air. If breathing is stopped, give artificial respiration. If breathing is difficult, give oxygen. Seek medical advice.

Ingestion: Rinse mouth with water. Give 1 or 2 glasses of water or milk to dilute. Do not induce vomiting. Seek medical advice immediately.

SECTION 5 - FIREFIGHTING MEASURES Suitable Extinguishing Media: Dry chemical powder, carbon dioxide gas, foam, Halon, water fog. HMIS NFPA 0-Minimal

Unsuitable Extinguishing Media: Water spray or stream. Health 2 2 1-Slight

Exposure Hazards: Inhalation and dermal contact Flammability 3 3 2-Moderate

Combustion Products: Oxides of carbon, hydrogen chloride and smoke Reactivity 0 0 3-Serious

PPE B 4-Severe

Protection for Firefighters: Self-contained breathing apparatus or full-face positive pressure airline masks.

SECTION 6 - ACCIDENTAL RELEASE MEASURES Personal precautions: Keep away from heat, sparks and open flame.

Provide sufficient ventilation, use explosion-proof exhaust ventilation equipment or wear suitable respiratory protective equipment.

Prevent contact with skin or eyes (see section 8).

Environmental Precautions: Prevent product or liquids contaminated with product from entering sewers, drains, soil or open water course.

Methods for Cleaning up: Clean up with sand or other inert absorbent material. Transfer to a closable steel vessel.

Materials not to be used for clean up: Aluminum or plastic containers

SECTION 7 - HANDLING AND STORAGE Handling: Avoid breathing of vapor, avoid contact with eyes, skin and clothing.

Keep away from ignition sources, use only electrically grounded handling equipment and ensure adequate ventilation/fume exhaust hoods.

Do not eat, drink or smoke while handling.

Storage: Store in ventilated room or shade below 44°C (110°F) and away from direct sunlight.

Keep away from ignition sources and incompatible materials: caustics, ammonia, inorganic acids, chlorinated compounds, strong oxidizers and isocyanates.

Follow all precautionary information on container label, product bulletins and solvent cementing literature.

SECTION 8 - PRECAUTIONS TO CONTROL EXPOSURE / PERSONAL PROTECTIONEXPOSURE LIMITS: ACGIH TLV ACGIH STEL OSHA PEL OSHA STEL:

Tetrahydrofuran (THF) 50 ppm 100 ppm 200 ppm

Methyl Ethyl Ketone (MEK) 200 ppm 300 ppm 200 ppm

20 ppm 50 ppm 50 ppm

Engineering Controls: Use local exhaust as needed.

Monitoring: Maintain breathing zone airborne concentrations below exposure limits.

Personal Protective Equipment (PPE):

Eye Protection: Avoid contact with eyes, wear splash-proof chemical goggles, face shield, safety glasses (spectacles) with brow guards and side shields,etc. as may be appropriate for the exposure.

Skin Protection: Prevent contact with the skin as much as possible. Butyl rubber gloves should be used for frequent immersion.

Use of solvent-resistant gloves or solvent-resistant barrier cream should provide adequate protection when normal adhesive application

practices and procedures are used for making structural bonds.

Respiratory Protection: Prevent inhalation of the solvents. Use in a well-ventilated room. Open doors and/or windows to ensure airflow and air changes. Use localexhaust ventilation to remove airborne contaminants from employee breathing zone and to keep contaminants below levels listed above.

With normal use, the Exposure Limit Value will not usually be reached. When limits approached, use respiratory protection equipment.

Category 2B

Hazard Statements Precautionary Statements

REACH

Component

Cyclohexanone

XIRTEC 5 GRY Low VOC Cement for PVC Plastic Pipe

PRODUCT NAME:

PRODUCT USE:

SUPPLIER:

GHS CLASSIFICATION:

Health Environmental Physical

Filename: XIRTEC 5 GRY_LoVoc 6-13.xls Page 1 of 2 6/12/2013 9:34 AM

IPEX GHS SAFETY DATA SHEETDate Revised: JUN 2013

Supersedes: JAN 2012XIRTEC 5 GRY Low VOC Cement for PVC Plastic Pipe

SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES Appearance: Gray, medium syrupy liquid

Odor: Ketone Odor Threshold: 0.88 ppm (Cyclohexanone)

pH: Not Applicable

Melting/Freezing Point: -108.5°C (-163.3°F) Based on first melting component: THF Boiling Range: 66°C (151°F) to 156°C (313°F)

Boiling Point: 66°C (151°F) Based on first boiling component: THF Evaporation Rate: > 1.0 (BUAC = 1)

Flash Point: -20°C (-4°F) TCC based on THF Flammability: Category 2

Specific Gravity: 0.9611 @23°C ( 73°F) Flammability Limits: LEL: 1.1% based on Cyclohexanone

Solubility: Solvent portion soluble in water. Resin portion separates out. UEL: 11.8% based on THF

Partition Coefficient n-octanol/water: Not Available Vapor Pressure: 129 mm Hg @ 20°C (68°F)based on THF

Auto-ignition Temperature: 321°C (610°F) based on THF Vapor Density: >2 (Air = 1)

Decomposition Temperature: Not Applicable Other Data: Viscosity: Medium bodied

VOC Content: When applied as directed, per SCAQMD Rule 1168, Test Method 316A,VOC content is: < 510 g/l.

SECTION 10 - STABILITY AND REACTIVITY Stability: Stable

Hazardous decomposition products: None in normal use. When forced to burn, this product gives off oxides of carbon, hydrogen chloride and smoke.

Conditions to avoid: Keep away from heat, sparks, open flame and other ignition sources.

Incompatible Materials: Oxidizers, strong acids and bases, amines, ammonia

SECTION 11 - TOXICOLOGICAL INFORMATIONLikely Routes of Exposure: Inhalation, Eye and Skin Contact

Acute symptoms and effects:

Inhalation: Severe overexposure may result in nausea, dizziness, headache. Can cause drowsiness, irritation of eyes and nasal passages.

Eye Contact: Vapors slightly uncomfortable. Overexposure may result in severe eye injury with corneal or conjunctival inflammation on contact with the liquid.

Skin Contact: Liquid contact may remove natural skin oils resulting in skin irritation. Dermatitis may occur with prolonged contact.

Ingestion: May cause nausea, vomiting, diarrhea and mental sluggishness.

Chronic (long-term) effects: None known to humans

Toxicity: LD50 LC50

Tetrahydrofuran (THF) Oral: 2842 mg/kg (rat) Inhalation 3 hrs. 21,000 mg/m3 (rat)

Methyl Ethyl Ketone (MEK) Oral: 2737 mg/kg (rat), Dermal: 6480 mg/kg (rabbit) Inhalation 8 hrs. 23,500 mg/m3 (rat)

Cyclohexanone Oral: 1535 mg/kg (rat), Dermal: 948 mg/kg (rabbit) Inhalation 4 hrs. 8,000 PPM (rat)

SECTION 12 - ECOLOGICAL INFORMATION Ecotoxicity: None Known

Mobility: In normal use, emission of volatile organic compounds (VOC's) to the air takes place, typically at a rate of < 510 g/l.

Degradability: Biodegradable

Bioaccumulation: Minimal to none.

SECTION 13 - WASTE DISPOSAL CONSIDERATIONSFollow local and national regulations. Consult disposal expert.

SECTION 14 - TRANSPORT INFORMATION Proper Shipping Name: Adhesives

Hazard Class: 3

Secondary Risk: None DOT Limited Quantity: Up to 5L per inner packaging, 30 kg gross weight per package.

Identification Number: UN 1133 Consumer Commodity: Depending on packaging, these quantities may qualify under DOT as "ORM-D" .

Packing Group: PG II

Label Required: Class 3 Flammable Liquid

Marine Pollutant: NO TDG CLASS: FLAMMABLE LIQUID 3

SHIPPING NAME: ADHESIVES

UN NUMBER/PACKING GROUP: UN 1133, PG II

SECTION 15 - REGULATORY INFORMATION Precautionary Label Information: Highly Flammable, Irritant Ingredient Listings: USA TSCA, Europe EINECS, Canada DSL, Australia

Symbols: F, Xi AICS, Korea ECL/TCCL, Japan MITI (ENCS)

Risk Phrases: R11: Highly flammable.

R20: Harmful by inhalation. R66: Repeated exposure may cause skin dryness or cracking

R36/37: Irritating to eyes and respiratory system. R67: Vapors may cause drowsiness and dizziness

Safety Phrases: S9: Keep container in a well-ventilated place. S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

S16: Keep away from sources of ignition - No smoking. S33: Take precautionary measures against static discharges.

S25: Avoid contact with eyes. S46: If swallowed, seek medical advise immediately and show this container or label.

SECTION 16 - OTHER INFORMATION Specification Information: All ingredients are compliant with the requirements of the European

Department issuing data sheet: Safety Health & Environmental Affairs Directive on RoHS (Restriction of Hazardous Substances).

Training necessary: Yes, training in practices and procedures contained in product literature.

Reissue date / reason for reissue: 6/12/2013 / Updated GHS Standard Format

Intended Use of Product: Solvent Cement for PVC Plastic Pipe

This product is intended for use by skilled individuals at their own risk. The information contained herein is based on data considered accurate based on current state of

knowledge and experience. However, no warranty is expressed or implied regarding the accuracy of this data or the results to be obtained from the use thereof.

EXCEPTION for Ground Shipping

TDG INFORMATION

Synergistic Products

Not Established Not Established Not Established Not Established Not Established Not Established

Reproductive Effects Teratogenicity Mutagenicity Embryotoxicity Sensitization to Product

Filename: XIRTEC 5 GRY_LoVoc 6-13.xls Page 2 of 2 6/12/2013 9:34 AM

Product Name: XYLENE

Revision Date: 26 Feb 2013 Page 1 of 11

______________________________________________________________________________________________________________________


SECTION 1 PRODUCT AND COMPANY IDENTIFICATION PRODUCT

Product Name: XYLENE Product Description: Aromatic Hydrocarbon MSDS Number: 4562

Intended Use: Chemical feedstock, Solvent

COMPANY IDENTIFICATION

Supplier: IMPERIAL OIL CHEMICALS DIVISION 240 4th Avenue S.W. CALGARY, ALBERTA. T2P 3M9 Canada

24 Hour Environmental / Health Emergency Telephone

1-866-232-9563

Transportation Emergency Phone Number 1-866-232-9563 Product Technical Information 1-800-663-4109

SECTION 2 COMPOSITION / INFORMATION ON INGREDIENTS Reportable Hazardous Substance(s) or Complex Substance(s) Name CAS# Concentration* Acute Toxicity Mixed Xylenes 1330-20-7 100 % Oral Lethality: LD50 > 5000

mg/kg (Rat) Hazardous Constituent(s) Contained in Complex Substance(s) Name CAS# Concentration* Acute Toxicity ETHYL BENZENE 100-41-4 10 - 20% Inhalation Lethality: LC50

17.8 mg/l (Rat); Oral Lethality: LD50 3.5 g/kg (Rat)

* All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.

SECTION 3 HAZARDS IDENTIFICATION This material is considered to be hazardous according to regulatory guidelines (see (M)SDS Section 15). PHYSICAL/CHEMICAL EFFECTS

FLAMMABLE. In use, may form flammable/explosive vapour-air mixture. Material can release vapours that readily form flammable mixtures. Vapour accumulation could flash and/or explode if ignited. Material can accumulate static charges which may cause an ignition.

HEALTH EFFECTS

Irritating to skin. May cause cancer. May cause harm to the unborn child. If swallowed, may be aspirated and cause lung damage. May be irritating to the eyes, nose, throat, and lungs. Target Organs: Skin |



______________________________________________________________________________________________________________________

NFPA Hazard ID: Health: 2 Flammability: 3 Reactivity: 0 HMIS Hazard ID: Health: 2* Flammability: 3 Reactivity: 0 NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person.

SECTION 4 FIRST AID MEASURES

INHALATION

Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation.

SKIN CONTACT

Wash contact areas with soap and water. Remove contaminated clothing. Launder contaminated clothing before reuse.

EYE CONTACT

Flush thoroughly with water for at least 15 minutes. Get medical assistance. INGESTION

Seek immediate medical attention. Do not induce vomiting. NOTE TO PHYSICIAN

If ingested, material may be aspirated into the lungs and cause chemical pneumonitis. Treat appropriately. This light hydrocarbon material, or a component, may be associated with cardiac sensitisation following very high exposures (well above occupational exposure limits) or with concurrent exposure to high stress levels or heart-stimulating substances like epinephrine. Administration of such substances should be avoided.

SECTION 5 FIRE FIGHTING MEASURES

EXTINGUISHING MEDIA

Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight streams of water

FIRE FIGHTING

Fire Fighting Instructions: FLAMMABLE. Evacuate area. If a leak or spill has not ignited, use water spray to disperse the vapours and to protect personnel attempting to stop a leak. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Unusual Fire Hazards: Hazardous material. Firefighters should consider protective equipment indicated in Section 8.



______________________________________________________________________________________________________________________

Hazardous Combustion Products: Smoke, Fume, Incomplete combustion products, Oxides of carbon

FLAMMABILITY PROPERTIES

Flash Point [Method]: >23°C (73°F) [ASTM D-56] Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Autoignition Temperature: 432°C (810°F) - 528°C (982°F) [Technical literature]

SECTION 6 ACCIDENTAL RELEASE MEASURES

NOTIFICATION PROCEDURES

In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations.

PROTECTIVE MEASURES

Avoid contact with spilled material. Warn or evacuate occupants in surrounding and downwind areas if required, due to toxicity or flammability of the material. See Section 5 for fire fighting information. See the Hazard Identification Section for Significant Hazards. See Section 4 for First Aid Advice. See Section 8 for advice on the minimum requirements for personal protective equipment. Additional protective measures may be necessary, depending on the specific circumstances and/or the expert judgment of the emergency responders.

SPILL MANAGEMENT Land Spill: Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop leak if you can do so without risk. All equipment used when handling the product must be grounded. Do not touch or walk through spilled material. Prevent entry into waterways, sewer, basements or confined areas. A vapour-suppressing foam may be used to reduce vapour. Use clean non-sparking tools to collect absorbed material. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Large Spills: Water spray may reduce vapour, but may not prevent ignition in enclosed spaces. Recover by pumping or with suitable absorbent. Water Spill: Stop leak if you can do so without risk. Eliminate sources of ignition. Warn other shipping. If the Flash Point exceeds the Ambient Temperature by 10 deg C or more, use containment booms and remove from the surface by skimming or with suitable absorbents when conditions permit. If the Flash Point does not exceed the Ambient Air Temperature by at least 10C, use booms as a barrier to protect shorelines and allow material to evaporate. Seek the advice of a specialist before using dispersants. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken.

ENVIRONMENTAL PRECAUTIONS

Large Spills: Dyke far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas.

SECTION 7 HANDLING AND STORAGE

HANDLING

Avoid contact with skin. Avoid contact with eyes. Prevent exposure to ignition sources, for example use non-



______________________________________________________________________________________________________________________

sparking tools and explosion-proof equipment. Prevent small spills and leakage to avoid slip hazard. Material can accumulate static charges which may cause an electrical spark (ignition source). Use proper bonding and/or ground procedures. However, bonding and grounds may not eliminate the hazard from static accumulation. Consult local applicable standards for guidance. Additional references include American Petroleum Institute 2003 (Protection Against Ignitions Arising out of Static, Lightning and Stray Currents) or National Fire Protection Agency 77 (Recommended Practice on Static Electricity) or CENELEC CLC/TR 50404 (Electrostatics - Code of practice for the avoidance of hazards due to static electricity). Loading/Unloading Temperature: [Ambient] Transport Temperature: [Ambient] Transport Pressure: [Ambient] Static Accumulator: This material is a static accumulator. A liquid is typically considered a nonconductive, static accumulator if its conductivity is below 100 pS/m (100x10E-12 Siemens per meter) and is considered a semiconductive, static accumulator if its conductivity is below 10,000 pS/m. Whether a liquid is nonconductive or semiconductive, the precautions are the same. A number of factors, for example liquid temperature, presence of contaminants, anti-static additives and filtration can greatly influence the conductivity of a liquid.

STORAGE

Ample fire water supply should be available. A fixed sprinkler/deluge system is recommended. The container choice, for example storage vessel, may effect static accumulation and dissipation. Keep container closed. Handle containers with care. Open slowly in order to control possible pressure release. Store in a cool, well-ventilated area. Outside or detached storage preferred. Storage containers should be earthed and bonded. Fixed storage containers, transfer containers and associated equipment should be grounded and bonded to prevent accumulation of static charge. Storage Temperature: [Ambient] Storage Pressure: [Ambient] Suitable Containers/Packing: Tankers; Drums; Tank Trucks; Barges; Tank Cars Suitable Materials and Coatings (Chemical Compatibility): Carbon Steel; Polyester; Stainless Steel; Teflon Unsuitable Materials and Coatings: Natural Rubber; Butyl Rubber; Ethylene-proplyene-diene monomer (EPDM); Polystyrene; Polyethylene; Polypropylene; PVC; Polyvinyl Alcohol; Polyacrylonitrile; Compatibility with plastics will vary

SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION Substance Name Form Limit/Standard Note Source

ETHYL BENZENE TWA 20 ppm ACGIH

Mixed Xylenes Vapour. RCP - TWA

434 mg/m3 100 ppm Total Hydrocarbons

Supplier

Mixed Xylenes STEL 150 ppm ACGIH

Mixed Xylenes TWA 100 ppm ACGIH

NOTE: Limits/standards shown for guidance only. Follow applicable regulations. ENGINEERING CONTROLS



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The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider:

Adequate ventilation should be provided so that exposure limits are not exceeded. Use explosion-proof ventilation equipment.

PERSONAL PROTECTION

Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include:

Half-face filter respirator For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include:

Chemical resistant gloves are recommended. Eye Protection: If contact is likely, safety glasses with side shields are recommended. Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include:

Chemical/oil resistant clothing is recommended. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practise good housekeeping.

ENVIRONMENTAL CONTROLS

Comply with applicable environmental regulations limiting discharge to air, water and soil. Protect the environment by applying appropriate control measures to prevent or limit emissions.

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

Note: Physical and chemical properties are provided for safety, health and environmental considerations only and may not fully represent product specifications. Contact the Supplier for additional information. GENERAL INFORMATION

Physical State: Liquid Form: Clear



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Colour: Colourless

Odour: Aromatic

Odour Threshold: N/D

IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION

Relative Density (at 15 °C): 0.869 [Technical literature] Density (at 15 ºC): 870 kg/m³ (7.26 lbs/gal, 0.87 kg/dm³) [ISO 12185] Flash Point [Method]: >23°C (73°F) [ASTM D-56] Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Autoignition Temperature: 432°C (810°F) - 528°C (982°F) [Technical literature] Boiling Point / Range: 136°C (277°F) - 145°C (292°F) [Technical literature] Vapour Density (Air = 1): < 1 at 101 kPa [Technical literature] Vapour Pressure: 0.8 kPa (6 mm Hg) at 20ºC [Calculated] Evaporation Rate (n-butyl acetate = 1): 0.85 [In-house method] pH: N/D

Log Pow (n-Octanol/Water Partition Coefficient): 3.12 - 3.16 [Technical literature] Solubility in Water: Negligible

Viscosity: [N/D at 40 °C] | 0.79 cSt (0.79 mm2/sec) at 20°C [ASTM D7042] Oxidizing Properties: See Hazards Identification Section.

OTHER INFORMATION

Freezing Point: -54°C (-65°F) [Technical literature] Melting Point: -39°C (-39°F) [Technical literature] Pour Point: -95°C (-139°F) - 13°C (56°F) [Technical literature] Molecular Weight: 106 G/MOLE [Calculated] Hygroscopic: No Coefficient of Thermal Expansion: 0.00105 V/V/DEG C [Calculated] [In-house method] Decomposition Temperature: N/D

SECTION 10 STABILITY AND REACTIVITY

STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Avoid heat, sparks, open flames and other ignition sources. MATERIALS TO AVOID: Strong oxidizers

HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur.

SECTION 11 TOXICOLOGICAL INFORMATION

ACUTE TOXICITY

Route of Exposure Conclusion / Remarks

Inhalation

Toxicity (Rat): LC50 > 20 mg/l Minimally Toxic. Based on test data for the material.

Irritation: No end point data for material. Elevated temperatures or mechanical action may form vapours, mist, or fumes which may be irritating to the eyes, nose, throat, or lungs.

Ingestion



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Toxicity (Rat): LD50 > 3523 mg/kg Minimally Toxic. Based on test data for the material.

Skin

Toxicity (Rabbit): LD50 > 4200 mg/kg Minimally Toxic. Based on test data for the material.

Irritation: Data available. Irritating to the skin. Based on test data for the material.

Eye

Irritation: Data available. Moderately irritating to the eyes. Based on test data for structurally similar materials.

CHRONIC/OTHER EFFECTS For the product itself:

Vapour concentrations above recommended exposure levels are irritating to the eyes and the respiratory tract, may cause headaches and dizziness, are anaesthetic and may have other central nervous system effects. Small amounts of liquid aspirated into the lungs during ingestion or from vomiting may cause chemical pneumonitis or pulmonary edema. Very high exposure (confined spaces / abuse) to light hydrocarbons may result in abnormal heart rhythm (arrhythmias). Concurrent high stress levels and/or co-exposure to high levels of hydrocarbons (above occupational exposure limits), and to heart-stimulating substances like epinephrine, nasal decongestants, asthma drugs, or cardiovascular drugs may initiate arrhythmias. Contains: ETHYLBENZENE: Caused cancer in laboratory animal studies. The relevance of these findings to humans is uncertain. XYLENES: High exposures to xylenes in some animal studies have been reported to cause health effects on the developing embryo/fetus. These effects were often at levels toxic to the mother. The significance of these findings to humans has not been determined.

CMR Status:

Chemical Name CAS Number List Citations

ETHYL BENZENE 100-41-4 3, 4

Mixed Xylenes 1330-20-7 4

--REGULATORY LISTS SEARCHED-- 1 = IARC 1 3 = IARC 2B 5 = ACGIH A1 2 = IARC 2A 4 = ACGIH ALL 6 = ACGIH A2

SECTION 12 ECOLOGICAL INFORMATION

The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material -- Expected to be toxic to aquatic organisms. Material -- Not expected to demonstrate chronic toxicity to aquatic organisms. MOBILITY Material -- Highly volatile, will partition rapidly to air. Not expected to partition to sediment and wastewater

solids. PERSISTENCE AND DEGRADABILITY

Biodegradation:



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Material -- Expected to be readily biodegradable. Hydrolysis: Material -- Transformation due to hydrolysis not expected to be significant. Photolysis: Material -- Transformation due to photolysis not expected to be significant. Atmospheric Oxidation: Material -- Expected to degrade rapidly in air BIOACCUMULATION POTENTIAL Material -- Potential to bioaccumulate is low. OTHER ECOLOGICAL INFORMATION

VOC (EPA Method 24): 7.252 lbs/gal

SECTION 13 DISPOSAL CONSIDERATIONS

Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS

Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products.

REGULATORY DISPOSAL INFORMATION

Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH.

SECTION 14 TRANSPORT INFORMATION

LAND (TDG)

Proper Shipping Name: FLAMMABLE LIQUIDS, N.O.S. (Xylenes, Ethylbenzene) Hazard Class & Division: 3 UN Number: 1993 Packing Group: III Special Provisions: 16

LAND (DOT)

Proper Shipping Name: FLAMMABLE LIQUIDS, N.O.S. (Xylenes, Ethylbenzene ) Hazard Class & Division: 3 ID Number: 1993 Packing Group: III Product RQ: 100 LBS - Mixed Xylenes ERG Number: 128



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Label(s): 3 Transport Document Name: UN1993, FLAMMABLE LIQUIDS, N.O.S. (Xylenes, Ethylbenzene), 3, PG III

SEA (IMDG)

Proper Shipping Name: XYLENES Hazard Class & Division: 3 EMS Number: F-E, S-D UN Number: 1307 Packing Group: III Label(s): 3 Transport Document Name: UN1307, XYLENES, 3, PG III, (>23°C c.c.)

AIR (IATA)

Proper Shipping Name: XYLENES Hazard Class & Division: 3 UN Number: 1307 Packing Group: III Label(s) / Mark(s): 3 Transport Document Name: UN1307, XYLENES, 3, PG III

SECTION 15 REGULATORY INFORMATION

WHMIS Classification: Class B, Division 2: Flammable Liquids Class D, Division 2, Subdivision A: Very Toxic Material Class D, Division 2, Subdivision B: Toxic Material This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the (M)SDS contains all the information required by the Controlled Products Regulations. CEPA: All components of this material are either on the Canadian Domestic Substances List (DSL), exempt, or have been notified under CEPA. Complies with the following national/regional chemical inventory requirements: AICS, DSL, ENCS, IECSC, KECI, PICCS, TSCA

The Following Ingredients are Cited on the Lists Below:

Chemical Name CAS Number List Citations

ETHYL BENZENE 100-41-4 6

Mixed Xylenes 1330-20-7 6

--REGULATORY LISTS SEARCHED-- 1 = TSCA 4 3 = TSCA 5e 5 = TSCA 12b 2 = TSCA 5a2 4 = TSCA 6 6 = NPRI

SECTION 16 OTHER INFORMATION

N/D = Not determined, N/A = Not applicable



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THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Revision Changes: Section 06: Protective Measures was modified. Section 09: Boiling Point C(F) was modified. Section 09: Pour Point C(F) was modified. Section 09: Density - Header was modified. Section 09: Density kg/m3(lbs/gal) was modified. Section 08: Comply with applicable regulations phrase was modified. Section 09: Vapour Pressure was modified. Section 11: Inhalation Irritation Test Data was modified. Section 09: Relative Density - Header was modified. Section 09: Flash Point C(F) was modified. Section 09: Autoignition Temperature was modified. Section 09 Viscosity was modified. Section 09 Viscosity was modified. Section 14: Transport Document Name was modified. Section 15: National Chemical Inventory Listing was modified. Section 11: Additional Health Information was modified. Section 16: MSN,MAT ID was modified. Section 09: Freezing Point ºC(ºF) was modified. Section 09: Melting Point C(F) was modified. Composition: Component table was modified. Composition: Component table was modified. Section 08: Exposure Limits Table was modified. Section 15: Canadian List Citations Table was modified. Section 01: Company Contact Methods Sorted by Priority was modified. Section 11: Tox List Cited Table was modified. Section 16: CA Contains was added. Section 16: CA Contains - Header was added. ------------------------------------------------------------------------------------------------------------------- ---------------------------------- PRECAUTIONARY LABEL TEXT: Contains: Mixed Xylenes WHMIS Classification: Class B, Division 2: Flammable Liquids Class D, Division 2, Subdivision A: Very Toxic Material Class D, Division 2, Subdivision B: Toxic Material HEALTH HAZARDS Irritating to skin. May cause cancer. May cause harm to the unborn child. If swallowed, may be aspirated and cause lung damage. Target Organs: Skin | PHYSICAL HAZARDS In use, may form flammable/explosive vapour-air mixture. Material can accumulate static charges which may cause an ignition. FLAMMABLE. PRECAUTIONS Avoid contact with skin. Avoid contact with eyes. Prevent exposure to ignition sources, for example use non-sparking tools and explosion-proof equipment. Use proper bonding and/or earthing procedures.However, bonding and earthing may not eliminate the hazard from static accumulation.



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FIRST AID Eye: Flush thoroughly with water for at least 15 minutes. Get medical assistance. Oral: Seek immediate medical attention. Do not induce vomiting. Skin: Wash contact areas with soap and water. Remove contaminated clothing. Launder contaminated clothing before reuse. FIRE FIGHTING MEDIA Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. SPILL/LEAK Land Spill: Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop leak if you can do so without risk. Prevent entry into waterways, sewer, basements or confined areas. A vapour-suppressing foam may be used to reduce vapour. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Water Spill: Stop leak if you can do so without risk. Eliminate sources of ignition. Warn other shipping. Report spills as required to appropriate authorities. If the Flash Point exceeds the Ambient Temperature by 10 deg C or more, use containment booms and remove from the surface by skimming or with suitable absorbents when conditions permit. If the Flash Point does not exceed the Ambient Air Temperature by at least 10C, use booms as a barrier to protect shorelines and allow material to evaporate. Seek the advice of a specialist before using dispersants. ----------------------------------------------------------------------------------------------------------------------------------------------------- The information and recommendations contained herein are, to the best of Imperial Oil's knowledge and belief, accurate and reliable as of the date issued. Imperial Oil assumes no responsibility for accuracy of information unless the document is the most current available from an official Imperial Oil distribution system. The information and recommendations are offered for the user's consideration and examination, and it is the user's responsibility to satisfy itself that they are suitable and complete for its particular use. If buyer repackages this product, legal counsel should be consulted to insure proper health, safety and other necessary information is included on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, republication or retransmission of this document, in whole or in part, is not permitted. ----------------------------------------------------------------------------------------------------------------------------- ------------------------ DGN: 5004671 (1020902) ----------------------------------------------------------------------------------------------------------------------------------------------------- Copyright 2002 Imperial Oil Limited, All rights reserved Prepared by: Imperial Oil Limited, Solvents

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