separation and identification of cations - periodni.com + fe(cn)4-6 sno2-2 ass3-, aso-, sns2-,...

1
www.periodni.com Cd Pb Cr Ba K 1550 °C 520 °C 300 °C 1560 °C 1450 °C 1540 °C 2+ 2+ + 2+ 2+ 3+ 2+ 3+ 5+ 3+ 5+ 2+ 4+ 2+ 3+ 3+ 3+ 2+ 2+ 2+ 2+ 2+ 2+ 2+ 2+ + + + Pb , Ag , Hg , Hg , Bi , Cu , Cd , As , As , Sb , Sb , Sn , Sn , Fe , Fe , Cr , Al , Co , Ni , Mn , Zn , Ba , Sr , Ca , Mg , Na , K , NH 2 4 2+ 2+ 3+ 2+ 3+ 5+ 3+ 5+ 2+ 4+ 2+ 3+ 3+ 3+ 2+ 2+ 2+ 2+ 2+ 2+ 2+ 2+ + + + Hg , Bi , Cu , Cd , As , As , Sb , Sb , Sn , Sn , Fe , Fe , Cr , Al , Co , Ni , Mn , Zn , Ba , Sr , Ca , Mg , Na , K , NH 4 2+ 3+ 3+ 3+ 2+ 2+ 2+ 2+ 2+ 2+ 2+ 2+ + + + Fe , Fe , Cr , Al , Co , Ni , Mn , Zn , Ba , Sr , Ca , Mg , Na , K , NH 4 2+ 2+ 2+ 2+ 2+ 2+ 2+ 2+ + + + Co , Ni , Mn , Zn , Ba , Sr , Ca , Mg , Na , K , NH 4 2+ 2+ 2+ 2+ + + + Ba , Sr , Ca , Mg , Na , K , NH 4 HgO·Hg(NH ) 22 J. Meija et al, Atomic weights of the elements 2013, Pure Appl. Chem., 88, 265-291 (2016) 4.0026 2 20.180 10 14.007 7 18 17 18.998 9 15.999 8 12.011 6 C 10.81 B 5 Al 13 Si 14 P 15 S 16 He Ne N Ar Cl F O IVA VA VIA VIIA VIIIA 13 14 15 16 17 18 IIIA 1 2 3 4 5 6 7 1.008 1 6.94 Li 3 9.0122 Be 4 22.990 Na 11 24.305 Mg 12 39.098 K 19 40.078 Ca 20 85.468 Rb 37 87.62 Sr 38 132.91 Cs 55 137.33 Ba 56 (223) Fr 87 (226) Ra 88 H IA IIA 1 2 138.91 La 57 174.97 Lu 71 140.12 Ce 58 140.91 Pr 59 144.24 Nd 60 (145) 61 150.36 Sm 62 151.96 Eu 63 157.25 Gd 64 158.93 Tb 65 162.50 Dy 66 164.93 Ho 67 167.26 Er 68 168.93 Tm 69 173.05 Yb 70 Pm (227) Ac 89 232.04 Th 90 231.04 Pa 91 238.03 U 92 (262) 103 (237) 93 (244) 94 (243) 95 (247) 96 (247) 97 (251) 98 (252) 99 (257) 100 (258) 101 (259) 102 Lr Np Pu Am Cm Bk Cf Es Fm Md No 44.956 Sc 21 88.906 Y 39 IIIB 3 Tc Bh Rf Db Hs Mt 39.948 35.45 83.798 36 131.29 54 (222) 86 26.982 28.085 30.974 32.06 47.867 Ti 22 50.942 V 23 51.996 Cr 24 54.938 Mn 25 55.845 Fe 26 58.933 Co 27 58.693 Ni 28 63.546 Cu 29 65.38 Zn 30 69.723 Ga 31 72.64 Ge 32 74.922 As 33 78.971 Se 34 79.904 35 91.224 Zr 40 92.906 Nb 41 95.95 Mo 42 178.49 Hf 72 180.95 Ta 73 183.84 W 74 (98) 43 126.90 I 53 101.07 Ru 44 102.91 Rh 45 106.42 Pd 46 107.87 Ag 47 112.41 Cd 48 186.21 Re 75 190.23 Os 76 192.22 Ir 77 195.08 Pt 78 196.97 Au 79 200.59 Hg 80 204.38 Tl 81 207.2 Pb 82 208.98 Bi 83 (209) Po 84 (210) At 85 114.82 In 49 118.71 Sn 50 121.76 Sb 51 127.60 Te 52 Kr Xe Rn Br IVB VB VIB VIIB IB IIB VIIIB 5 4 6 7 8 9 10 11 12 (272) 107 (267) 104 (268) 105 Sg (271) 106 (277) 108 (276) 109 (281) Ds 110 (280) Rg 111 (285) Cn 112 Fl 113 (287) 114 115 (291) Lv 116 117 118 Np Fr Ra Pm Ac Lr Np Pu Am Cm Bk Cf Es Fm Md No Tc Bh Rf Db Hs Mt Po At Rn Sg Ds Rg Cn Fl Lv Np Nh Nh (285) Mc (289) Mc Ts (294) Og (294) Ts Og PERIODIC TABLE OF THE ELEMENTS Downloads Online calculators Periodic table of the elements Copyright Eni Generali , Split © 2005-2017 c Faculty of Chemistry and Technology, , CROATIA PERIODIC TABLE OF THE ELEMENTS 2+ 2+ + 2+ 2+ 3+ 2+ 3+ 5+ 3+ 5+ 2+ 4+ 2+ 3+ 3+ 3+ 2+ 2+ 2+ 2+ 2+ 2+ 2+ 2+ + + + Pb , Ag , Hg , Hg , Bi , Cu , Cd , As , As , Sb , Sb , Sn , Sn , Fe , Fe , Cr , Al , Co , Ni , Mn , Zn , Ba , Sr , Ca , Mg , Na , K , NH 2 4 2+ 2+ 3+ 2+ 3+ 5+ 3+ 5+ 2+ 4+ 2+ 3+ 3+ 3+ 2+ 2+ 2+ 2+ 2+ 2+ 2+ 2+ + + + Hg , Bi , Cu , Cd , As , As , Sb , Sb , Sn , Sn , Fe , Fe , Cr , Al , Co , Ni , Mn , Zn , Ba , Sr , Ca , Mg , Na , K , NH 4 2+ 3+ 3+ 3+ 2+ 2+ 2+ 2+ 2+ 2+ 2+ 2+ + + + Fe , Fe , Cr , Al , Co , Ni , Mn , Zn , Ba , Sr , Ca , Mg , Na , K , NH 4 2+ 2+ 2+ 2+ 2+ 2+ 2+ 2+ + + + Co , Ni , Mn , Zn , Ba , Sr , Ca , Mg , Na , K , NH 4 2+ 2+ 2+ 2+ + + + Ba , Sr , Ca , Mg , Na , K , NH 4 3+ 2+ Sb , Sn NaNO + rhodamine B 2 Zn-uranyl acetate HCl + HgCl 2 Sb S 2 3 Sb S 2 5 SnS 2 2- - CrO , Al(OH) 4 4 HAc + Pb(Ac) 2 NH Cl 4 NH SCN 4 Fe(OH) 3 brown ppt. PRECIPITATE MnS pink ppt. ZnS white ppt. CoS black ppt. NiS black ppt. CoS black ppt. NiS black ppt. 2+ 2+ Co , Ni 2+ 2+ Mn , Zn MnO 2 brown ppt. HNO + NaBiO 3 3 HCl (conc.) orange ppt. orange ppt. yellow ppt. yellow ppt. yellow ppt. brown ppt. HNO 3 (conc.) NH 3 (conc.) 0 Hg Cl + Hg 2 2 grey precipitate HNO + HO 3 2 2 (6 mol/L) (3 %) HCl (0.5 mol/L) NaOH + HO 2 2 (6 mol/L) (3 %) (NH ) C O 42 2 4 + + Na , K , + NH 4 PbCl 2 white ppt. AgCl white ppt. Hg Cl 2 2 white ppt. AgCl white ppt. Hg Cl 2 2 white ppt. 2+ Pb + Ag(NH ) 32 PRECIPITATE HgS CuS CdS yellow ppt. Bi S 2 3 As S 2 3 yellow ppt. As S 2 5 yellow ppt. Sb S 2 3 orange ppt. Sb S 2 5 orange ppt. SnS brown ppt. SnS 2 yellow ppt. KOH (3 mol/L) HCl (3 mol/L) HCl (6 mol/L) II a subgroup II b subgroup HgS CuS black ppt. CdS yellow ppt. Bi S 2 3 brown ppt. HNO 3 (3 mol/L) HNO 3 (conc.) Hg(NO ) ·2HgS 32 Bi(OH) 3 NH 3 (conc.) NH 3 (conc.) 3+ 2+ 2+ Bi , Cu , Cd 2+ 2+ Cu(NH ) , Cd(NH ) 34 34 KCN + H S 2 4- HAc + Fe(CN) 6 2- SnO 2 3- - 2- 2- 3- - AsS , AsO , SnS , SnO , SbS , SbO 4 2 3 3 4 2 As S 2 3 As S 2 5 As S 2 3 As S 2 5 SnS PRECIPITATE NH Cl + NH OH 4 4 (NH ) PO 42 4 (0.5 mol/L) + NH 3 (conc.) PRECIPITATE NaOH + HO 2 2 (6 mol/L) (3 %) Fe(OH) 3 brown ppt. Cr(OH) 3 grey-green p. Ba (PO ) 3 42 white ppt. Ca (PO ) 3 42 white ppt. Sr (PO ) 3 42 white ppt. MgNH PO 4 4 white ppt. Ca (PO ) 3 42 white ppt. Sr (PO ) 3 42 white ppt. MgNH PO 4 4 white ppt. 2+ 2+ 2+ Sr , Ca , Mg 2+ 2+ Ca , Mg 2+ Mg Na Co(NO ) 3 26 NaOH + quinalizarine PRECIPITATE - Zn(OH) 3 HS 2 HO 2 (100 °C) K Cr O 2 2 7 Determined in the original solution Al(OH) 3 white ppt. SOLUTION ORIGINAL SOLUTION SOLUTION SOLUTION SOLUTION SOLUTION FLAME COLORING FLAME COLORING NH SCN 4 + amyl alcohol yellow ppt. yellow ppt. HNO 3 (conc.) NaAc + AgNO 3 white ppt. black ppt. HNO + HCl 3 (1:3) SnCl 2 Cu Fe(CN) 2 6 reddish brown ppt. 0 Bi brown precipitate CdS yellow precipitate AgCl white precipitate Sb-rhodamine pinkish-red coloration 4+ Sn grey ppt. Hg Cl 2 2 PbCrO 4 yellow precipitate 0 HgNH Cl + Hg 2 black precipitate black ppt. black ppt. brown ppt. black ppt. PbCrO 4 yellow precipitate Al(OH) 3 white precipitate 2+ Fe(SCN) blood red coloration ZnS white precipitate Ni-dimethylglyoxime red precipitate 2- Co(SCN) 4 deep blue coloration + dimethylglyoxime NH 3 (3 mol/L) - MnO 4 violet coloration BaCrO 4 yellow precipitate SrSO 4 white precipitate CH COOH 3 (conc.) K CrO 2 4 CH COOH 3 (conc.) (NH ) SO 42 4 CaC O 2 4 white precipitate Mg-quinalizarine blue coloration Na-uranyl acetate pale yellow precipitate K Co(NO ) 3 26 yellow precipitate Barium apple green Strontium crimson red Calcium brick red Sodium yellow Potassium violet Lower reduction zone Lower oxidation zone Higher reduction zone Higher oxidation zone (melting zone) Qualitative inorganic analysis SEPARATION AND IDENTIFICATION OF CATIONS SEPARATION AND IDENTIFICATION OF CATIONS Separate the clear liquid from the precipitate Test tubes Bunsen burner Heating in the water bath Ag AsO 3 4 chocolate brown ppt. Nessler's reagent yellow to brown ppt. HgO·Hg(NH ) 22 HS 2 (in acidic medium) (in basic medium) HS 2

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Page 1: Separation and identification of cations - periodni.com + Fe(CN)4-6 SnO2-2 AsS3-, AsO-, SnS2-, SnO2-, SbS3-, SbO- ... SEPARATION AND IDENTIFICATION OF CATIONS Separate the clear liquid

www.periodni.com

Cd

Pb

Cr

BaK

1550 °C

520 °C

300 °C

1560 °C

1450 °C

1540 °C2+2+ + 2+ 2+ 3+ 2+ 3+ 5+ 3+ 5+ 2+ 4+ 2+ 3+ 3+ 3+ 2+ 2+ 2+ 2+ 2+ 2+ 2+ 2+ + + +Pb , Ag , Hg , Hg , Bi , Cu , Cd , As , As , Sb , Sb , Sn , Sn , Fe , Fe , Cr , Al , Co , Ni , Mn , Zn , Ba , Sr , Ca , Mg , Na , K , NH2 4

2+2+ 3+ 2+ 3+ 5+ 3+ 5+ 2+ 4+ 2+ 3+ 3+ 3+ 2+ 2+ 2+ 2+ 2+ 2+ 2+ 2+ + + +Hg , Bi , Cu , Cd , As , As , Sb , Sb , Sn , Sn , Fe , Fe , Cr , Al , Co , Ni , Mn , Zn , Ba , Sr , Ca , Mg , Na , K , NH4

2+ 3+ 3+ 3+ 2+ 2+ 2+ 2+ 2+ 2+ 2+ 2+ + + +Fe , Fe , Cr , Al , Co , Ni , Mn , Zn , Ba , Sr , Ca , Mg , Na , K , NH4

2+ 2+ 2+ 2+ 2+ 2+ 2+ 2+ + + +Co , Ni , Mn , Zn , Ba , Sr , Ca , Mg , Na , K , NH4

2+ 2+ 2+ 2+ + + +Ba , Sr , Ca , Mg , Na , K , NH4

HgO·Hg(NH )2 2

J. Meija et al, Atomic weights of the elements 2013, Pure Appl. Chem., 88, 265-291 (2016)

4.0026

2

20.180

10

14.007

7

1817

18.998

9

15.999

8

12.011

6

C10.81

B5

Al13

Si14

P15

S16

He

NeN

ArCl

FO

IVA VA VIA VIIA

VIIIA

13 14 15 16 17

18

IIIA

1

2

3

4

5

6

7

1.008

1

6.94

Li3

9.0122

Be4

22.990

Na11

24.305

Mg12

39.098

K19

40.078

Ca20

85.468

Rb37

87.62

Sr38

132.91

Cs55

137.33

Ba56

(223)

Fr87

(226)

Ra88

H

IA

IIA

1

2

138.91

La57

174.97

Lu71

140.12

Ce58

140.91

Pr59

144.24

Nd60

(145)

61

150.36

Sm62

151.96

Eu63

157.25

Gd64

158.93

Tb65

162.50

Dy66

164.93

Ho67

167.26

Er68

168.93

Tm69

173.05

Yb70

Pm

(227)

Ac89

232.04

Th90

231.04

Pa91

238.03

U92

(262)

103

(237)

93

(244)

94

(243)

95

(247)

96

(247)

97

(251)

98

(252)

99

(257)

100

(258)

101

(259)

102

LrNp Pu Am Cm Bk Cf Es Fm Md No

44.956

Sc21

88.906

Y39

IIIB3

Tc

BhRf Db Hs Mt

39.94835.45

83.798

36

131.29

54

(222)

86

26.982 28.085 30.974 32.06

47.867

Ti22

50.942

V23

51.996

Cr24

54.938

Mn25

55.845

Fe26

58.933

Co27

58.693

Ni28

63.546

Cu29

65.38

Zn30

69.723

Ga31

72.64

Ge32

74.922

As33

78.971

Se34

79.904

35

91.224

Zr40

92.906

Nb41

95.95

Mo42

178.49

Hf72

180.95

Ta73

183.84

W74

(98)

43

126.90

I53

101.07

Ru44

102.91

Rh45

106.42

Pd46

107.87

Ag47

112.41

Cd48

186.21

Re75

190.23

Os76

192.22

Ir77

195.08

Pt78

196.97

Au79

200.59

Hg80

204.38

Tl81

207.2

Pb82

208.98

Bi83

(209)

Po84

(210)

At85

114.82

In49

118.71

Sn50

121.76

Sb51

127.60

Te52

Kr

Xe

Rn

Br

IVB VB VIB VIIB IB IIBVIIIB

54 6 7 8 9 10 11 12

(272)

107

(267)

104

(268)

105

Sg(271)

106

(277)

108

(276)

109

(281)

Ds110

(280)

Rg111

(285)

Cn112

Fl113

(287)

114 115

(291)

Lv116 117 118

NpFr Ra

Pm

Ac LrNp Pu Am Cm Bk Cf Es Fm Md No

Tc

BhRf Db Hs Mt

Po At Rn

Sg Ds Rg Cn Fl LvNp NhNh(285)

Mc(289)

Mc Ts(294)

Og(294)

Ts Og

P E R I O D I C TA B L E O F T H E E L E M E N T S

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Online calculators

Periodic table of the elements

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P E R I O D I C TA B L E O F T H E E L E M E N T S

2+2+ + 2+ 2+ 3+ 2+ 3+ 5+ 3+ 5+ 2+ 4+ 2+ 3+ 3+ 3+ 2+ 2+ 2+ 2+ 2+ 2+ 2+ 2+ + + +Pb , Ag , Hg , Hg , Bi , Cu , Cd , As , As , Sb , Sb , Sn , Sn , Fe , Fe , Cr , Al , Co , Ni , Mn , Zn , Ba , Sr , Ca , Mg , Na , K , NH2 4

2+2+ 3+ 2+ 3+ 5+ 3+ 5+ 2+ 4+ 2+ 3+ 3+ 3+ 2+ 2+ 2+ 2+ 2+ 2+ 2+ 2+ + + +Hg , Bi , Cu , Cd , As , As , Sb , Sb , Sn , Sn , Fe , Fe , Cr , Al , Co , Ni , Mn , Zn , Ba , Sr , Ca , Mg , Na , K , NH4

2+ 3+ 3+ 3+ 2+ 2+ 2+ 2+ 2+ 2+ 2+ 2+ + + +Fe , Fe , Cr , Al , Co , Ni , Mn , Zn , Ba , Sr , Ca , Mg , Na , K , NH4

2+ 2+ 2+ 2+ 2+ 2+ 2+ 2+ + + +Co , Ni , Mn , Zn , Ba , Sr , Ca , Mg , Na , K , NH4

2+ 2+ 2+ 2+ + + +Ba , Sr , Ca , Mg , Na , K , NH4

3+ 2+Sb , Sn

NaNO + rhodamine B2

Zn-uranyl acetate

HCl + HgCl2

Sb S2 3 Sb S2 5SnS2

2- -CrO , Al(OH)4 4

HAc + Pb(Ac) 2 NH Cl4

NH SCN4

Fe(OH)3

brown ppt.

PRECIPITATE

MnSpink ppt.

ZnSwhite ppt.

CoSblack ppt.

NiSblack ppt.

CoS

black ppt.

NiS

black ppt.

2+ 2+Co , Ni

2+ 2+Mn , Zn

MnO2

brown ppt.

HNO + NaBiO3 3

HCl (conc.)

orange ppt. orange ppt.yellow ppt.yellow ppt. yellow ppt. brown ppt.

HNO3 (conc.)

NH3 (conc.)

0Hg Cl + Hg2 2

grey precipitate

HNO + H O 3 2 2 (6 mol/L) (3 %) HCl (0.5 mol/L)

NaOH + H O 2 2(6 mol/L) (3 %)

(NH ) C O4 2 2 4

+ +Na , K , +NH4

PbCl2white ppt.

AgClwhite ppt.

Hg Cl2 2

white ppt.

AgCl

white ppt.

Hg Cl2 2

white ppt.

2+Pb

+Ag(NH )3 2

PRECIPITATE

HgS CuS CdSyellow ppt.

Bi S2 3 As S2 3

yellow ppt.

As S2 5

yellow ppt.

Sb S2 3

orange ppt.

Sb S2 5

orange ppt.

SnSbrown ppt.

SnS2

yellow ppt.

KOH (3 mol/L)

HCl (3 mol/L)

HCl (6 mol/L)

II a subgroup II b subgroup

HgS CuS

black ppt.

CdS

yellow ppt.

Bi S2 3

brown ppt.

HNO3 (3 mol/L)

HNO3 (conc.)

Hg(NO ) ·2HgS3 2

Bi(OH)3

NH3 (conc.)

NH3 (conc.)

3+ 2+ 2+Bi , Cu , Cd

2+ 2+Cu(NH ) , Cd(NH )3 4 3 4

KCN + H S24-HAc + Fe(CN)6

2-SnO2

3- - 2- 2- 3- -AsS , AsO , SnS , SnO , SbS , SbO4 2 3 3 4 2

As S2 3 As S2 5

As S2 3 As S2 5 SnS

PRECIPITATE

NH Cl + NH OH4 4

(NH ) PO4 2 4 (0.5 mol/L) + NH3 (conc.)

PRECIPITATE

NaOH + H O 2 2(6 mol/L) (3 %)

Fe(OH)3

brown ppt.

Cr(OH)3

grey-green p.

Ba (PO )3 4 2

white ppt.

Ca (PO )3 4 2

white ppt.

Sr (PO )3 4 2

white ppt.

MgNH PO4 4

white ppt.

Ca (PO )3 4 2

white ppt.

Sr (PO )3 4 2

white ppt.

MgNH PO4 4

white ppt.

2+ 2+ 2+Sr , Ca , Mg

2+ 2+Ca , Mg

2+Mg

Na Co(NO )3 2 6

NaOH + quinalizarine

PRECIPITATE

-Zn(OH)3

H S2

H O 2 (100 °C)

K Cr O2 2 7

Dete

rmin

ed in

the o

rigin

al s

olu

tion

Al(OH)3

white ppt.

SOLUTION

O R I G I N A L S O L U T I O N

SOLUTION

SOLUTION

SOLUTION

SOLUTION

FLAME COLORINGFLAME COLORING

NH SCN4

+ amyl alcohol

yellow ppt. yellow ppt.

HNO3 (conc.)

NaAc + AgNO3

white ppt.

black ppt.

HNO + HCl 3 (1:3)

SnCl2

Cu Fe(CN)2 6

reddish brown ppt.

0Bi

brown precipitate

CdSyellow precipitate

AgCl

white precipitate

Sb-rhodamine

pinkish-red coloration

4+Sngrey ppt. Hg Cl2 2

PbCrO4yellow precipitate

0HgNH Cl + Hg2

black precipitate

black ppt.

black ppt. brown ppt. black ppt.

PbCrO4yellow precipitate

Al(OH)3white precipitate

2+Fe(SCN)blood red coloration

ZnSwhite precipitate

Ni-dimethylglyoxime

red precipitate

2-Co(SCN)4deep blue coloration

+ dimethylglyoxime

NH3 (3 mol/L)

-MnO4

violet coloration

BaCrO4yellow precipitate

SrSO4white precipitate

CH COOH3 (conc.)

K CrO2 4

CH COOH3 (conc.)

(NH ) SO4 2 4

CaC O2 4white precipitate

Mg-quinalizarine

blue coloration

Na-uranyl acetatepale yellow precipitate

K Co(NO )3 2 6yellow precipitate

Bariumapple green

Strontiumcrimson red

Calciumbrick red

Sodiumyellow

Potassiumviolet

Lower reduction zone

Lower oxidation zone

Higher reduction zone

Higher oxidation zone(melting zone)

Qualitative inorganic analysis

SEPARATION AND IDENTIFICATION OF CATIONSSEPARATION AND IDENTIFICATION OF CATIONS

Separate the clear liquid from the precipitate

Test tubes

Bunsen burner

Heating in the water bath

Ag AsO3 4

chocolate brown ppt.

Nessler's reagent yellow to brown ppt.

HgO·Hg(NH )2 2

H S2(in acidic medium)

(in basic medium)

H S2