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SDMS DocID 251753
SCOPE OF WORK TECHNICAL IMPRACTIBILITY (TI) EVALUATION
AND FIELD WORK FOR HYDRAULIC
CONTAINMENT SYSTEM DESIGN
HOWS CORNER SUPERFUND SITE PLYMOUTH MAINE
SEPTEMBER 2003
Prepared by
WOODARDampCURRAN Engineering bull Science bull Operations
WOODARD amp CURRAN INC 41 Hutchins Drive Portland ME 04102 (207)774-2112
CORPORATE OFFICES Maine Massachusetts N e w Hampshire Connecticut Florida
Engineering bull Science bull Operations operational offices throughout the us
October 10 2003
William P Lovely Jr Remedial Project Manager USEPA - New England Region 1 Congress Street Suite 1100 (HBT) Boston MA 02114-2023
Subject Hows Corner Superfund Site Plymouth Maine Transmittal of Scope of Work - Technical Impracticability Evaluation and Field Work for Hydraulic Containment System Design
Dear Bill
Three copies of the Final Scope of Work (SOW) for Technical Impracticability Evaluation and Field Work for Hydraulic Containment System Design are enclosed Three paper copies of the report are also being provided to MEDEP today
Please contact me at 1-800-426-4262 if you have any questions about the enclosed SOW Bill we appreciate your continued efforts in working with us to bring this project to a successful completion
Sincerely
WOODARD amp CURRAN INC
n^f
Thomas R Eschner Senior Project Manager
Enclosures
cc Claudia B Sait MEDEP (3 copies) David P Littell Pierce Atwood (1 copy) Jim Rawson General Electric (1 copy) Kristin Larson Skadded Arps Slate Meather amp Flom (1 copy)
41 Hutchins Drive i Portland Maine 04102 i 207-774-2112 i 207-774-6635 (Fax) i 1-800-426-4262 i wwwwoodardcurrancom
TABLE OF CONTENTS
SECTION NO TITLE PAGE NO
10 INTRODUCTION 1
20 SITE DESCRIPTION AND INVESTIGATION HISTORY 3
30 INVESTIGATION TECHNICAL APPROACH 6 31 INVESTIGATIVE APPROACH 6
311 Task 1 - Project Planning 7 312 Task 2 - Field Investigation 7 313 Task 3 - TI Evaluation and Reporting 19
40 SCHEDULE 22
50 ACRONYMS 24
LIST OF FIGURES
FIGURE NO TITLE PAGE NO
Figure 1-1 Site Locus Plan 2 Figure 2-1 Site Plan Detail 4 Figure 3-1 Proposed Well Locations 10 Figure 4-1 Proposed Project Schedule 23
LIST OF TABLES
TABLE NO TITLE PAGE NO
Table 3-1 Rationale for Proposed Well Locations 11
TISOW WOODARD amp CURRAN TOC-I September 302003 20564309
10 INTRODUCTION
The purpose of this scope of work (SOW) is to provide an overview of the tasks proposed in response to
United States Environmental Protection Agency (USEPA) guidance and site-specific requirements for the
Technical Impracticability (TI) Evaluation of the West SiteHows Corner Superfund Site (Site) as well as
an overview of a pumping test to support design of the hydraulic containment system selected in the
Interim Record of Decision (ROD) for the Non Source-Area Groundwater at the Site (USEPA 2002)
Details of the site characterization activities described in this SOW will be provided in the three
subsequent major project-planning documents that will be produced after agreement is reached on scope
and content of the SOW
bull Work Plan
bull Health and Safety Plan (HASP)
bull Quality Assurance Project Plan (QAPP)-Including the Sampling and Analysis Plan
(SAP)
The Site is located in Plymouth Maine as depicted in Figure 1-1 The Potentially Responsible Party
Group (the PRP Group) for the Site has been asked to implement additional site characterization to
address data gaps identified by the USEPA (USEPA 2003) so that a final ROD can be issued for the Site
In addition the data developed from the pumping test described in this SOW will be used to evaluate the
number and spacing of wells for development of the hydraulic containment system design This SOW
specifies the approach proposed by the PRP Group to (1) improve the understanding of groundwater
movement including solute transport in the fractured bedrock aquifer (2) establish the limits of the TI
zone at the Site and (3) provide information that will assist in designing the hydraulic containment
system specified in the Interim ROD
This SOW is organized into four Sections Section 2 presents a brief Site description and history
followed by a discussion of the Site Conceptual Model that was previously developed for the Site based
on existing data Section 3 presents the proposed technical approach to the investigation including
rationale for well locations and investigation techniques as well as a pumping test that will be used to
assist in development of the hydraulic containment system design that will be conducted pursuant to the
authority of the Administrative Order by Consent (AOC) for the Remedial Design (RD) Details
regarding the development of the hydraulic containment system will be presented in the Remedial Design
Work Plan Section 4 presents the overall schedule for implementing this TI SOW including the
pumping test and completing the TI Evaluation Report
TISOW WOODARDampCURRAN 1 September 302003 20564309
I I1 J1 - ^
i i i KA ^$^ c E I I F L Ti M O U T H
C -j--MlI e ^P
I
I Source USGS Topographic 75-minute Series Quadrangles
Plymouth ME 1982 and Dixmont ME 1982 bull MAINR
c Figure 1-1 Quadrangle Location Site Location Map
Hows Corner Superfund Site c Plymouth Maine 4000
WOODARDampCURRAN 99503716risiteloc
I
bull 20 SITE DESCRIPTION AND INVESTIGATION HISTORY
The Site is located in east-central Maine in the town of Plymouth The Site includes a 17-acre parcel of
land owned by George West and is comprised of Operable Unit One (Non-source Area Groundwater) and
the Source Area Groundwater as generally depicted on Figure 2-1 Mr West used a small two-acre
portion of the site to operate a waste oil facility from 1965 to 1980 During investigations conducted by
the Maine Department of Environmental Protection (MEDEP) in the early 1990s a fence was placed
ft around this 2-acre portion of the Site This fenced area is referred to in the RIFS and the Interim ROD as
the Source Area (Figure 2-1) Source Area Groundwater however is defined in the ROD as
d groundwater with total volatile organic compound (VOC) concentration equal to or greater than 10 parts
per million (ppm) and may exist outside the 2-acre fenced area
m From October 1999 to May 2001 the PRP Group with oversight by USEPA and MEDEP conducted a
Remedial Investigation (RI) to determine the nature and extent of contamination to characterize the fate
and transport of contaminants and to assess the potential risks that the contamination poses to both
human health and the environment The findings of the RI show that VOCs in groundwater and
polychlorinated biphenyls (PCBs) in soil within the fenced area of the Site were present at concentrations
exceeding the target risk levels of 105 carcinogenic risk or a Hazard Index of 1 for non-carcinogenic risk
In addition modeling of Site groundwater shows that groundwater flows radially away from the source
area and discharges to the surface in many spring-fed ponds and to the surface on the flanks of the hill
bull Under current conditions contamination from the Site has reached its maximum extent This
groundwater plume consists of both Source Area Groundwater which is defined as groundwater where
total VOC concentrations are greater than or equal to 10 ppm and Non-Source Area Groundwater which
is groundwater containing total VOC concentrations below 10 ppm (USEPA 2002) (see Figure 2-1) A
(0 detailed description of the distribution and extent of groundwater contamination at the Site is provided in
sections 40 and 50 of the RI Report
4 In July 2002 the PRP Group with oversight by USEPA and MEDEP completed a Feasibility Study (FS)
to develop and evaluate a range of remedial alternatives to address potential risks to human health and the
environment that were identified during the RI for the non-source area groundwater
TISOW WOODARD amp CURRAN 3 September 302003 20564309
NonmdashSource Area Groundwater
Source Atea Groundirater
17mdashAcre George West Property
_bdquoVOCugllppm
0
| n r nA
= Volatile Orgamc Compound _ = Microgram per Liter
= Parts per Million
300 600
FEET
Notes 1 Shaded areas based on Maximum Extent of total VOCs j n e | t h e r D e c e m b e r 1 9 9 9 P r e _ R 0 D o r J u n e 2 0 0 0 Supplemental Sampling Events
2 Source Area Groundwater is defined as groundwater with total VOC concentration equal to or greater than 10000 ugl (10 ppm) Extent of Source Area Groundwater plume inferred east of 2-Acre Fenced Area
3 Non Source Area Groundwater is defined as groundwater with total VOC concentrations less then 10000 ugl (10ppm)
Figure 2-1 Site Plan Detail
Hows Corner Superfund Site Plymouth Maine
WOODARD ampCURRAN Engineering bull Science Operations
205643wipsite sowu2-1A
0
Soil within the fenced area of the Site that presented a human health risk was excavated during pilot
testing for the FS and disposed of off-site The three remedial alternatives evaluated in the FS (WampC
bull 2002) were
bull No further Action
lt$ bull Limited Action and
bull Hydraulic Containment
$t As stated in Section 40 of the FS the possible presence of a remnant dense non-aqueous phase liquid
(DNAPL) source within the groundwater plume raises the question as to whether or not complete
restoration of the aquifer can be achieved in a reasonable period of time (eg less than 100 years)
Because of the uncertainties associated with the groundwater recharge rate the mass of DNAPL in
^ Source Area Groundwater the fractional organic carbon (foe) in the bedrock and the tetrachloroethene
(PCE) organic carbon partitioning coefficient (Koc) the restoration potential of both Source Area and
^ Non-Source Area Groundwater could not be assessed within a reasonable degree of scientific certainty in
the FS
The Interim ROD for Operable Unit One Non-Source Area Groundwater (USEPA 2002) was completed
in September 2002 The remedy selected in the Interim ROD consisted of
bull Installation of groundwater extraction and treatment system to contain Source Area Groundwater
bull Monitoring of surface water sediments and Non-Source Area Groundwater to measure the
progress of natural attenuation toward meeting Applicable or Relevant and Appropriate
Requirements (ARARs)
^9 bull Residential well monitoring with a public water contingency
bull Institutional Controls to prevent use of both Source and Non-Source Area Groundwater and
( i bull Five-year Reviews
4) Following completion of the FS Report and preparation of the Interim ROD for Operable Unit One
USEPA requested that further site characterization be completed to assist in making a determination
Jsect concerning the feasibility of attaining ARARs within a reasonable time Section 3 of this SOW outlines
the tasks proposed by the PRP Group to address the requirement for additional Site data necessary for a
pound TI evaluation and containment system design
TISOW WOODARD amp CURRAN 5 September 302003 20564309
bull 30 INVESTIGATION TECHNICAL APPROACH
On behalf of the PRP Group Woodard amp Curran (WampC) has developed a proposed SOW in response to
bull USEPAs request for additional field tasks to further refine the cleanup times presented in the 2002
Interim ROD for this site This approach has been designed to evaluate the following additional data
lt9 needs identified by USEPA to refine cleanup times
4t bull Aquifer hydraulic conductivity
bull Aquifer porosity (matrix and bulk) and
H bull Partitioning of contaminants to the bedrock
^ The data from these additional field tasks will also be used by USEPA to define the TI zone for the Final
ROD and assist the PRPs in developing the design for the hydraulic containment system for the Source
j Area Groundwater which is being conducted under the authority of the RD AOC Details regarding
development of the hydraulic containment system will be presented in the Remedial Design Work Plan
The proposed TI SOW is based on information available during its preparation and may be amended
subject to USEPA approval as additional information regarding subsurface conditions becomes available
during the field investigation The following section describes the overall field investigation approach A
comprehensive presentation of each task in the field investigation will be provided in the Sampling and
bull Analysis Plan (SAP) which will be amended following approval of a final scope of work
bull0 31 Investigative Approach
j The work proposed to meet the additional data requirements stated by USEPA consists of the three
primary tasks described below and further outlined as subtasks Brief descriptions of each task are
presented in the subsections that follow
Task 1 - Project Planning
Task 2 - Field Investigation
Task 3 - TI Evaluation and Reporting
WOODARD amp CURRAN 6 September 302003 20564309
311 Task 1 - Project Planning
Project planning is the first task and includes the following five subtasks
bull Finalize the SOW
bull Prepare work plan
bull Revise existing site-specific Quality Assurance Project Plan (QAPP) Sampling and Analysis
Plan (SAP) and Health and Safety Plan (HASP) and
bull Secure subcontractor contracts
bull Mobilize to the Site and establish a field office
In order to finalize the SOW for this TI evaluation it is anticipated that a minimum of one meeting will
occur between the PRP Group USEPA MEDEP and WampC Once the SOW is finalized the QAPP
SAP and HASP (the Plans) will be revised to incorporate necessary modifications to reflect the agreed-
upon work methods and technology The SAP will be modified to include a detailed plan for the
additional field activities Once the Plans have been revised and the Work Plan prepared they will be
submitted to USEPA for review USEPA comments will be incorporated into the plans and final
approved plans will be issued
After final plans have been issued WampC will negotiate contracts with subcontractors for certain field
activities including boring and monitoring well installation geophysical survey packer testing and
investigation-derived waste (IDW) storage and disposal It is anticipated that a second meeting between
the parties may be needed prior to the commencement of the field activities
Because of the duration of the field activities described in this SOW and the need for on-site evaluation of
field results in order to make program decisions during the investigation WampC will mobilize a trailer to
the Site to serve as a field office The trailer will be equipped with telephone and fax machine
312 Task 2 - Field Investigation
The field investigation task will include the following subtasks
bull Subtask 1 - Boring installation
bull Subtask 2 - Borehole geophysics
TISOW
WOODARDampCURRAN 7 September 302003 20564309
0
0 bull Subtask 3 - Packer testing
bull Subtask 4 - Sampling and analysis
bull bull Subtask 5 - Monitoring well installation
bull Subtask 5 - Pumping test and
bull Subtask 6 - Tracer test
Each of the subtasks is summarized below however a comprehensive discussion of these subtasks and
associated methodologies will be provided in the SAP
Subtask 1 - Boring Installation
j Information obtained during the installation of the new borings will be used in the evaluation of the
aquifer hydraulic conductivity and the analysis of other aquifer properties (eg porosity fracture
frequency) For this subtask it is anticipated that one angled boring will be completed to a depth of 150
feet (ft) below ground surface (bgs) One additional angled boring and four new vertical bedrock borings
will be completed to depths of approximately 100 ft bgs This depth is consistent with the depth
evaluated in the RI and will allow evaluation of bedrock and groundwater properties to depths below the
transition from less competent to more competent bedrock (approximately 50 to 80 ft bgs)
m One additional vertical boring will be installed to a depth of 100 ft bgs as the pumping well location for
bull the pumping test The pumping well location will be based on the results of field work conducted prior to
its installation The proposed drilling program is designed to enhance understanding of the flow system
by aligning new boring locations with existing wells to characterize hydraulic properties of the fracture
network and bulk bedrock Furthermore the program allows for additional characterization of
M contamination in the Source Area groundwater The rationale for the boring locations is summarized in
Table 3-1 and the proposed locations of the borings are depicted on Figure 3-1 Actual locations may
M vary depending on field conditions and accessibility
jlt The drilling protocol employed during installation of both the angled and the vertical wells will allow for
evaluation of the potential presence of DNAPL in the rock and the need for modifications to the drilling
method if DNAPL is detected If sheen or product is observed in the return water core or cuttings from a
boring an interface probe may be employed to determine whether a NAPL is present in the boring
Based on the presence of DNAPL the boring may be terminated at a shallower depth than planned the
J TISOW 4 1 WOODARD amp CURRAN 8 September 302003
20564309
location may be abandoned or other practices may be employed to reduce the potential for causing
downward migration of DNAPL The protocol will be described in the Work Plan and the SAP
Angled Borings Two angled borings will be installed using air-hammer drilling methods The first
angled boring (AW-201) will be installed to a depth of 150 ft bgs in the vicinity of existing well MWshy
106 northeast of and outside of the source area and within the dissolved phase groundwater plume This
well will be angled from the surface toward the southeast at depth in order to intersect as many northwest-
dipping near-vertical fractures as possible The angle of this boring will be approximately 30deg to 40deg
from the vertical resulting in a surface projection of approximately 84 to 126 ft and total length of
approximately 173 to 195 ft The second angled boring (AW-202) will be installed to a depth of 100 ft
bgs in the vicinity of the existing MW-2 well cluster within the source area This well also will be angled
from the surface toward the southeast at depth in order to intersect near-vertical fractures The angle of
this boring will be approximately 30deg to 40deg from the vertical resulting in a surface projection of
approximately 58 to 84 ft and total length of approximately 115 to 130 ft
m
4
sect
i
TISOW WOODARD amp CURRAN 9 September 302003 20564309
Table 3-1
Rationale for Proposed Well Locations
Hows Corner Technical Impracticability Evaluation and Field work for Hydraulic Containment System Design
Well Identification
AW-201
AW-202
MW-203
MW-204
MW-205
MW-206
PW-207
Boring Orientation
Angled
Angled
Vertical
Vertical
Vertical
Vertical
Vertical
Minimum Boring Diameter (inches)
4
4
4
4
4
4
6
Drilling Method
Air Hammer
Air Hammer
Coring
Air Hammer
Air Hammer
Air Hammer
Core Air Hammer Over -drilling
Source Area Non-Source Area
Non-Source Area
Source Area
Non-Source Area
Non-Source Area
Source Area
Source Area
Source Area
Rationale for Boring
bull Intercept near-vertical fractures to understand subsurface geology bull Aid in iting MW-203 bull Intercept near-vertical fractures to understand subsurface geology bull Aid in siting PW-201 (Pumping well) bull ion of contamination bull 1 future monitoring location bull Potential reinjection well for hydraulic containment system bull Core for matrix diffusion evaluation bullbullbullbull Ibullbullbullbull 1bullbullbullbull 1bullbull bull 1
tion point for pumping test tion point in tracer test ion of contamination
future monitoring location tion point for pumping test tion point in tracer test ion of contamination
future monitoring location tion point for pumping test tion point in tracer test ion of contamination
future monitoring location tion point for pumping test
test well extraction well
bull Core for matrix diffusion evaluation bull i point for tracer test
TISOW September 30 2003 WOODARD amp CURRAN 20564309
MW-105D MW-5B
Primary Bedding Secondary Cleavage
Tertsry Fracturing
NOTE A total of 60 observations warn made rtrtjs roprtraont tticopy number of obsafvatk noted wtthln each azimutha) segment
MW-1 1 3D euro MW-205
2 AcreSource
Fenced-^ Area i
MW-103D MW-103S
17-Acre Property Boundary
MW-104D MW-1041 bull
MW-104S
Legend Figure 3-1 J Proposed Monitoring Well Proposed Well Locations
o- Site Property Boundary bull^bullProposed Pumping Well Hows Corner Superfund Site -xmdashx- Source Area Plymouth Maine
^ ^Proposed Angled Well bullamp Existing Monitoring Well bullWDODARDampCURRAN
Englnoortng bull Science bull Operations 205643wipsite-8OlaquoAx-opt-1-2-u3-1D
bull During the installation of each angled boring observations will be made regarding water gainloss
drilling rate and bit behavior to assess the depth of potential fractures In addition water levels will be
9 measured in nearby borings using either hand measurements data loggers or both to evaluate
connectivity between locations A change in water level in a nearby boring will indicate a hydraulic
at connection between the borings Borehole geophysics will also be performed on the borings (See Subtask
2 below) Information from each angled boring will be used to site an adjacent vertical well (MW-203
^ and PW-207) so that it intercepts a fracture observed in the angled boring
^ Vertical Borings Two of the vertical borings will be completed with rotary diamond coring to
approximately 100 ft bgs These borings will be adjacent to the angled borings described above One of
^ the cored borings (MW-203) will be located near MW-106 outside of the source area within the
dissolved-phase groundwater plume (see Figure 3-1) The other cored boring (PW-207) will be the
pumping well which is anticipated to be located within the source area in the vicinity of the existing
MW-2 well cluster Coring will allow data collection for several purposes including direct observation
of bedrock for determination of the nature of the rock matrix determination of the location and nature of
fractures and the degree of fracturing comparison with geophysical logs (Subtask 2) to verify
interpretation of the logs and collection of core samples for analysis (Subtask 4)
The remaining borings will be located east of the 2-acre fenced area within or near the periphery of the
source area and will be sited to align approximately with existing wells based on the known fracture
orientations at the Site (MW-204 and MW-205) or with new wells based on the known fracture
pound orientations at the Site (MW-206) Data from these locations in conjunction with the other borings
installed as part of this TI SOW and the existing wells will be used in the interpretation of the pumping
^ test (Subtask 6) and tracer test (Subtask 7) In addition these three borings will further delineate
contamination and provide potential monitoring locations for long-term monitoring Each of these
^ borings will be advanced to approximately 100 ft bgs with a minimum four-inch diameter air hammer
^ During the installation of each boring observations will be made regarding water gainloss drilling rate
and bit behavior to assess the depth of potential fractures In addition water levels will be measured in
nearby borings using either hand measurements data loggers or both to evaluate connectivity between
locations A change in water level in a nearby boring will indicate a hydraulic connection between the
TISOW WOODARD amp CURRAN 12 September 302003 20564309
borings Borehole geophysics and packer testing will also be performed on the borings (See Subtasks 2
and 3 below)
Drilling water will be containerized on site and treated through granular activated carbon (GAC) Treated
water will be analyzed to verify that PCB and VOC concentrations have been reduced to below ARARs
prior to discharge to the ground surface Cuttings will be spread on the ground surface at the site
consistent with the Remedial Investigation work plan
It is anticipated that up to 10 core samples from each cored boring (total of 20 cores) will be collected and
submitted to an off-site laboratory for analyses of porosity (matrix and bulk) permeability bulk density
and fraction of organic carbon (f^) using methods described in Subtask 4
Subtask 2 - Borehole Geophysics
To supplement information on fracture location and connectivity obtained during boring advancement a
borehole geophysical survey will be conducted on the newly installed bedrock borings to evaluate the
nature and orientation of water bearing fractures in the borings The survey will be performed at the
completion of the angled borings and again at the completion of the vertical borings The information
obtained during the survey may be used to identify the location of subsequent boring(s) by refining the
understanding of the depth aperture and orientation of bedrock fractures The following measurements
are proposed for the new borings caliper fluid temperature fluid resistivity and acoustic televiewer
(ATV) Single-point resistively and 16 inch normal measurements will also be made in the first two
borings installed and the data will be compared to data from the other geophysical logs to determine if
the measurements confirm and significantly improve the interpretation regarding the presence of water-
bearing fractures If the measurements are applicable to identification of fractures they may be included
in lieu of other geophysical logs in the remainder of the borings
Subtask 3 - Packer Testing
To further refine information on the aquifer hydraulic conductivity the hydraulic connection between
fractures in the borings will be evaluated during packer testing of vertical borings The data will be used
to estimate the hydraulic conductivity of specific fractures and fracture zones The packer testing will be
performed after the vertical borings have been installed and the borehole geophysical survey completed
TISOW WOODARD amp CURRAN 13 September 30 2003 20564309
bull
m
M
Drilling observations and information from borehole geophysics will be used to identify specific fractures
below the water table that are capable of transmitting water Prior to water injection for hydraulic
conductivity and fracture connectivity testing groundwater samples will be collected at selected intervals
for analysis of VOCs (See Subtask 4) Sampling intervals will be selected based on drilling observations
and logging results that indicate water is moving into or out of the borehole or that fractures exist to
promote water movement such as rapid increase in the amount of water returned rapid change in
temperature or highly fractured interval
^
^
bull
f$
Double packer testing will be performed at selected intervals within each newly installed boring It is
anticipated that up to six intervals per well will be tested for a maximum of 24 intervals and that for each
interval the test will include an approximate 15-minute injection of potable water at four progressively
increasing pressures Packer spacing is anticipated to be 10 ft however spacing may vary so that packers
are not located in potential fracture zones identified using information from rock cores drilling
observations and borehole geophysics The tests at an individual interval will be terminated if it appears
that the interval is not accepting water Care will be taken to minimize over-pumping or over-
pressurizing of the fractures The flow rate will be measured to evaluate the characteristics of the
fracture Water levels in adjacent borings will be measured during the packer testing to determine if a
hydraulic connection exists between the borings Water generated during packer testing will be
containerized on site and treated through GAC Treated water will be analyzed to verify that PCB and
VOC concentrations have been reduced to below ARARs prior to discharge to the ground surface
4 Subtask 4 Sampling and Analysis
~d
^
Rock and groundwater samples will be collected during the field program for laboratory analysis The
results of the analyses will be used to help refine the distribution of the plume and to estimate bedrock
properties These analyses will be used in conjunction with existing data during the TI evaluation to
refine cleanup times and establish the limits of the TI zone
As described in Subtask 1 it is anticipated that up to 10 core samples from each cored boring (total of 20
core samples) will be collected and submitted to an off-site laboratory for analyses of porosity (matrix and
bulk) permeability bulk density and fraction of organic carbon (f^) using existing industry methods
Subject to further evaluation of industry methods Woodard amp Curran proposes that porosity
TISOW WOODARD amp CURRAN20564309
14 September 302003
permeability and density will be measured using methods in the American Petroleum Institutes API RPshy
40 Fraction of organic carbon (f^) will be measured using either the LECO TOC method or Walkey-
Black method The LECO TOC method is a standard method in the petroleum industry and involves the
direct combustion of a ground rock sample The Walkey-Black method is a commonly used USEPA-
approved chemical oxidation method for determination of foe in soils In addition either method could be
used if a sample were scraped from a fracture surface To develop a reasonable range of f for Site
bedrock up to five samples will be selected from each boring from the unfractured matrix and up to five
from the fracture surfaces In addition Woodard amp Curran will evaluate the appropriateness of selecting
rock samples from a subset of the core samples from areas near fractures as well as from non-fractured
areas and submitting the samples for VOC analysis following methanol extraction
Results from these analyses will be used in conjunction with groundwater contaminant concentrations to
evaluate the significance of diffusion of contamination from the bedrock matrix in both the Source Area
and the Non-Source Area Although matrix diffusion likely is a significant factor in the determination of
cleanup times within the Source Area the potential applicability of matrix diffusion in the Non-Source
Area is not known These core analyses may provide evidence to assist in developing an estimate
through calculations of the effect of matrix diffusion on cleanup times
As noted in Subtask 3 prior to injection of water during packer testing groundwater samples will be
collected at selected intervals for analysis of volatile organic compounds (VOCs) Up to a total of 20
groundwater samples plus appropriate quality control samples will be collected from the newly installed
borings The samples will be submitted to an off-site laboratory for analysis Analytical results will be
validated in accordance with USEPA protocol and the data will be managed in WampCs existing
groundwater sampling analytical database for this site
Up to 21 existing monitoring wells from within or nearby the 17-acre property plus four new wells once
constructed will be sampled using low-flow techniques and submitted to an off-site laboratory for VOC
analysis Analytical results will be validated in accordance with USEPA protocol and the data will be
managed in WampCs existing groundwater sampling analytical database for this site
TISOW WOODARD amp CURRAN 15 September 302003 20564309
Subtask 5 - Monitoring Well Installation
Although it is anticipated that the newly installed borings will be left as open holes for tracer testing and
for pumping tests monitoring wells will be installed and developed in the newly installed borings unless
the USEPA MEDEP and PRP Group determine that the location is inappropriate for such use The
monitoring wells will be constructed of two-inch schedule 40 PVC screen and riser Screen intervals will
be selected based on the location of fractures identified during drilling geophysical logging and packer
testing A sand pack will be placed around the screen and will extend from approximately two ft below
the screen to approximately two ft above the screen
Subtask 6 - Pumping Test
WampC will conduct a single constant discharge pumping test to evaluate hydraulic properties of the
aquifer It is anticipated that the test will be conducted in a new pumping well in the vicinity of the
existing MW-2 well cluster within the source area Data from the pumping test will be used in
conjunction with other data from the investigation to improve the understanding of groundwater
movement and contaminant transport in the Source and Non-Source areas The results of the pumping
test will be used to refine the Site conceptual model as well as in the design of the hydraulic containment
system that is being constructed under the authority of the AOC for the RD
The groundwater pumping test will include the following components (1) Pumping test setup (2) Pretest
monitoring (3) Constant Discharge Pumping Test (4) Post-test monitoring and (5) Data Analysis
Pumping Test Setup In support of the groundwater pumping test WampC will install a pumping well
(PW-207) and procure and install the required groundwater extraction treatment and storage equipment at
the Site The well will be cored and over drilled to allow construction of a 4-inch well The location will
be in the vicinity of the MW-2 well cluster and be based upon results of the angled bedrock boring AWshy
202 The equipment will include but not be limited to
bull Down well pump plumbing and appurtances
bull Two (2) 20000 frac tanks
bull Groundwater transfer pumps and controls
bull Settlingaerationsand filtration treatment processes for the treatment of inorganics (if needed) and
nsow WOODARD amp CURRAN 16 September 302003 20564309
bull Granular activated carbon units for the treatment of dissolved organics in the groundwater
The groundwater treatment process will include the following processes 1) an oxidation and filtration
step to remove the inorganics from the groundwater and GAC units to treat the organic contaminants in
the extracted groundwater
Pretest Monitoring Prior to initiation of pumping WampC will monitor water levels in existing wells and
newly installed borings adjacent to the pumping well using a combination of hand measurements and data
loggers to develop an understanding of the piezometric surface under unstressed conditions The wells
proposed for water-level monitoring will be described in the work plan In addition all gauges
transducers flow meters and other equipment used in conducting the pumping tests shall be calibrated
before use
Constant Discharge Pumping Test The pumping test will be conducted in the source area using
newly-installed pumping well PW-207 It is anticipated that the test will be conducted at a pumping rate
of approximately 2 gallons per minute (gpm) for a period of 2 to 3 days however a higher or lower rate
may be shown to be appropriate based on the drilling and packer testing conducted during boring
installation Woodard amp Curran proposes to conduct this test using a vacuum-enhanced recovery system
(VERS) as described in the ROD so that the water level is not lowered appreciably in the vicinity of the
pumping well to prevent the potential migration of NAPLs to deeper bedrock zones The appropriateness
and feasibility of the VERS for the pumping test will be determined by field testing or literature
evaluation prior to completion of the Work Plan Because of the short duration of this test it is not
anticipated that stability of water levels will be reached in observation wells The test will however
provide information to estimate hydraulic conductivity and bedrock storage During the test the water
levels in the pumping well and selected monitoring wells will be logged continuously via down well data
loggers It is anticipated that water levels in approximately 24 wells will be measured using hand
measurements and data loggers
Groundwater extracted during the pumping test will be stored temporarily in an on-site frac tank prior to
on-site treatment and disposal
TISOW WOODARD amp CURRAN 17 September 302003 20564309
Post-Test Monitoring After the pump is turned off in the pumping well water levels will continue to be
monitored using hand measurements and data loggers until they have returned to within 10 of the preshy
test levels For planning purposes this has been estimated to be two weeks
Data Analysis Data collected during the pumping test will be analyzed with Aquifer Win32 Results of
the pumping test will be summarized in the summary data package for the TI Evaluation and the results
will also be used in the design of the hydraulic containment system specified in the Interim ROD that is
being conducted under the authority of the AOC for the RD Detail regarding use of the pumping test
data in hydraulic system design will be provided in the Remedial Design Work Plan
Subtask 7 - Tracer Test
WampC will conduct a tracer test using a conservative tracer to evaluate fracture connectivity porosity
dispersivity and matrix diffusion of the bedrock aquifer in both the Source Area and Non-Source Area
To increase the potential for success of this test results of the pumping test evaluation will be used to
revise the tracer test plan proposed here as necessary Following rebound of water levels after
completion of the pumping test WampC will initiate a single natural gradient tracer test The test will
consist of injecting a tracer into well PW-207 in the source area (Figure 3-1) for up to five days and
monitoring the tracers arrival in nearby wells Borehole geophysics core evaluation and packer testing
will be used to select the specific injection depth(s) in the well
A Tracer Test Work Plan will be completed prior to initiation of injection to determine the type quantity
and concentration of tracer based on the distance between the injection well and the monitoring wells A
conservative tracer that is one that is not preferentially adsorbed to rock or organic matter will be
selected for the tracer test Tracer injection equipment including tanks and flow-regulating and metering
equipment and pumps will be used to mix the tracer at the surface prior to injection Fractures may be
packered in the injection well and tracer solution will be injected at a rate determined during preparation
of the Tracer Test Work Plan During injection the potentiometric surface of the aquifer will be
monitored to verify that the potentiometric surface remains relatively constant during the injection
process
nsow WOODARD amp CURRAN 18 September 302003 20564309
Prior to injection of the tracer background concentration will be established by collecting samples from
up to six wells in the area of the tracer test and analyzing them for the tracer using an appropriate
analytical method Following injection of the tracer solutions the concentration of the tracer in
downgradient wells and borings will be measured A monitoring network will be established using nearby
monitoring wells Downhole probes will be installed in six new and existing wells near the injection well
to be identified in the work plan first to determine the background tracer concentrations and then to
monitor for the presence of the tracer upon initiation of the test Measurements will be collected at
periodic intervals to be determined based on the results of packer testing If an increase in tracer
concentration is detected or at a minimum on a weekly basis a water sample will be collected using low
flow sampling methodologies and analyzed in an off-site laboratory to evaluate the concentration of the
tracer The concentration of the tracer will be recorded Monitoring of the tracer concentration will
continue throughout the duration of the test The tracer will be allowed to flow with groundwater for one
month or until detected in wells in the vicinity of MW-106 whichever is shorter
313 Task 3 - TI Evaluation and Reporting
The TI Evaluation and reporting task includes the following five subtasks
bull Data evaluation
bull Summary data package
bull Draft TI Evaluation
bull Meetings with PRP Group and USEPA and
bull Revise and finalize TI Evaluation
As the subtasks of the field investigation are completed the data will be evaluated for the purpose of
addressing the data gaps identified by USEPA Specifically the data will be used to further refine the
cleanup times for non-source area groundwater presented in the Interim ROD
The data obtained during the field investigation will be reduced and evaluated and a summary data
package will be prepared that will include a discussion of the field activities completed and presentation
of the data It is anticipated that up to two meetings with USEPA will be necessary before the data
evaluation and summary report are completed
TISOW WOODARDampCURRAN 19 September 302003 20564309
Data collected during the pumping test will be analyzed with Aquifer Win32 Results will be summarized
in the summary data package and will also be presented as part of the RD submittals
Following submittal of the summary data package the TI evaluation will be prepared In accordance with
EPA guidance (1993) the TI waiver evaluation document will address the following topics
1 Specific ARARS or media cleanup standards for which TI determination is sought This section of the
TI Evaluation will identify the specific contaminants for which the TI determination is sought Based on
information available to date a waiver may be appropriate for pesticides PCBs chlorinated organic
compounds and other site-related contaminants that upon evaluation will not attain ARARs in a
reasonable period of time
2 Spatial area over which the TI waiver will apply The purpose of the additional site investigation
outlined in this SOW is to obtain the data necessary to further refine cleanup times presented in the
Interim ROD to determine what portions of the Site will not be expected to reach ARARs within a
reasonable time Consistent with TI guidance (USEPA 1993) the TI evaluation will specify the
horizontal and vertical extent of the area for which TI determination is sought Groundwater
concentration data from the RI and the TI SOW will be used to refine the distribution of the plume Data
from the drilling geophysical logging packer testing and pumping and tracer tests will be used to refine
the Site conceptual model and the cleanup times that will serve as the basis for establishing the scope and
nature of the TI zone
3 Conceptual Model The conceptual model forms the technical core of the TI Waiver Evaluation since
it provides basis for understanding of the restoration potential of the site The conceptual model outlines
the physical and hydrogeological constraints that hinder remediation or removal of Site contaminants and
it is the extent of these constraints rather than restoration timeframe alone that USEPA will use to
evaluate the necessity of the TI waiver of ARARs The conceptual model is the link between restoration
potential and restoration timeframe since it explains why proposed technologies are unlikely to work
either at all or within the desired 100-year timeframe
The Site conceptual model is not a mathematical model however as the result of the extensive modeling
and investigations of the site WampC has a strong understanding of the complex bedrock and overburden
TISOW WOODARDampCURRAN 20 September 302003 20564309
groundwater system beneath this site This understanding has been presented previously in both the RI
report and the FS and will be refined based on the TI SOW as necessary and summarized in the TI
Waiver Evaluation with specific attention to the physical and hydrogeological constraints on remediation
In particular the Site conceptual model will be reviewed in light of the new geologic data from drilling
logging and packer testing and the new hydrogeologic data obtained from the pumping test and tracer test
and will be revised to incorporate the new understanding
4 An evaluation of the restoration potential of the site This section will consist of a several components
It will present a systematic review of the technologies potentially capable of remediating the site given
the physical and hydrogeological constraints identified in the site model The newly acquired data will
provide an improved understanding of bedrock hydraulic properties that will allow a more Site-specific
evaluation of technologies The review of technologies will also include review of innovative
technologies and will evaluate whether existing remedial technologies or strategies would be capable of
achieving groundwater restoration at the site in a reasonable timeframe The section reference the FS and
will summarize the alternative remedies considered in the FS focusing on the ability of each to restore
groundwater in a reasonable timeframe It will also include a discussion of the selected hydraulic
containment system in light of the data gathered from the pumping test conducted in conjunction with the
TI SOW
Based on the Batch Flushing Model and using the agreed upon koc data from the RI as well as data from
this TI SOW including the f data collected as part of Subtask 4 a restoration timeframe analysis will be
conducted Following completion of the timeframe analysis and consideration of the results of drilling
rock and water analyses and pumping and tracer test a determination will be made regarding the Source
Area and the portion of the Non-Source Area VOC plume that will not attain ARARs in a reasonable
time
TISOW WOODARD amp CURRAN 21 September 302003 20564309
40 SCHEDULE
A proposed project schedule is included with this plan as Figure 4-1 This schedule is included for
discussion purposes and will be modified as necessary once the final scope of work as been approved by
all parties and the field work activities are coordinated with the subcontractors
TISOW WOODARD amp CURRAN 22 September 302003 20564309
ID
2
3
4
5
6
7 a i 10
11
12
13
14
15
16
17
16
19
20
21
22
24
25
26
27
26
29
30
31
32
Task Name
Project Meeting with EPA
Finalize SOW
Prepare Work Plans QAPP HASP Revision
Submit Work Plans for EPA Approval
Project Meeting with EPA
Revisions to work plans
Submit final work plans
Subcontractor Contracts
Project Meeting wEPA
Field Investigation
Site Mobilization
Install Borings
Borehole Geophysics
Packer Testing amp Collect GW Samples
Pumping Test
Tracer Test
Test setup
Injection
Monitoring
Data Reporting
InstallDevelop Wells
Data Evaluation
Prepare Data Package
Data Package Submittal to EPA
Draft Tl Evaluation Repon
Draft Tl Evaluation Report Submttal to EPA
EPA ReviewComment on Tl Evaluation ReF
Project Meeting wEPA
Revisions to Tl Evaluation Report
Submit Final Tl Evaluation Report
Start
Wed 070903
Thu 071003
Fri 101003
Mon 120103
Mon 121503
Mon 122903
Mon 011204
Tue 011304
Thu 021904
Fri 032104
Fri 032604
Fri 040204
Fri 041604
Fri 042304
Thu 050604
Wed 060204
Wed 060204
Wed 060904
Wed 060904
Wed 062304
Wed 070704
Wed 042804
Wed 062304
Mon 080204
Mon 070504
Tue 082404
Wed 082504
Wed 091504
Thu 0916AM
Thu 093004
Finish
Wed 070903
Fri 1OtO7u3
Fri 112803
Fri 122603
Mon 121503
Fri 010904
Mon 011204
Mon 012604
Thu 021904
Tue 071304
Thu 040104
Thu 042204
Tue 042704
Wed 050504
Tue 052504
Tue 071304
Tue 060804
Tue 061504
Tue 070604
Tue 071304
Fri 070904
Tue 072004
Fri 073004
Mon 080204
Mon 082304
Tue 082404
Tue 091404
Wed 091504
Wed 082904
Thu 093004
FIGURE 4-1 DRAFT HOWS CORNER SUPERFUND SITE
Tl EVALUATION amp RELD WORK FOR HYDRAUUC CONTAINMENT SYSTEM DESIGN PROPOSED PROJECT SCHEDULE
2003 2004 Mav |
Jun | Jul
ltamp i
Aug
i
Sen Oct I Nov Dec Jan Feb I Mar
ii i i
k ^tr 1
1V i
I t bull ^
I
ta^M bull bull M W
l LgtH^HBKLii LJ Mi
I
bull bull raquo bull laquo^ 0930
Task Progress I^MLHHHI^LB Summary ^^^^^^^^f External Tasks M B WMMM Deadline ^7 Project Hows Comer Schedule6A bull bull bull 1 UData Fri 101003 Split Milestone ^ Project Summary ^f^KKKKKK^^ External Milestone ^
Pagei
50 ACRONYMS
AOC Administrative Order by Consent
ARARs Applicable or Relevant and Appropriate Requirements
ATV acoustic televiewer
bgs below ground surface
CERCLA Comprehensive Environmental Resource and Conservation Liability Act
DNAPL Dense Non-Aqueous Phase Liquid
GAC granular activated carbon
gpm gallons per minute
HASP Health and Safety Plan
row investigation-derived waste
MCL Maximum Containment Level
MEDEP Maine Department of Environmental Protection
MEG Maine Enforcement Guideline
mgkg milligrams per kilogram
Hg kg micrograms per kilogram
NCP National Contingency Plan
PCB polychlorinated biphenyl
PID photo ionization detector
ppm parts per million
PRP Potentially Responsible Party
TISOW WOODARD amp CURRAN 24 September 302003 20564309
QAPP Quality Assurance Project Plan
QAQC Quality AssuranceQuality Control
RA Remedial Action
RAO Remedial Action Objective
RCRA Resource Conservation and Recovery Act
RD Remedial Design
RIFS Remedial InvestigationFeasibility Study
ROD Record of Decision
SAP Sampling and Analysis Plan
SOW Statement of Work
TAL target analyte list
TI Technical Impracticability
USEPA United State Environmental Protection Agency
VOCs volatile organic compounds
WampC Woodard amp Curran Inc
TISOW WOODARD amp CURRAN 25 September 302003 20564309
REFERENCES
Everts CJ RS Kanwar (1994) Evaluation of Rhodamine WT as an adsorbed tracer in an agricultural
soil J Hydrology 153 53-70
Kasnavia T D Vu DA Sabatini (1999) Fluorescent dye and media properties affecting sorption and
tracer selection Groundwater 37 376-381
Ptak T G Schmid (1996) Dual-tracer transport experiments in a physically and chemically
heterogeneous porous aquifer effective transport parameters and spatial variability J Hydrology
183 117-138
Sabatini DA T A Austin (1991) Characteristics of Rhodamine WT and fluorescein as adsorbing
ground-water tracers Ground Water 29 341-349
Trudgill ST (1987) Soil water dye tracing with special reference to the use of Rhodamanie WT
Lissamine FF and Amino G acid Hydrological Processes 1 149-170
US Environmental Protection Agency (USEPA) 1993 Guidance for Evaluating the Technical
Impracticability of Ground-Water Restoration - Interim Final Office of Solid Waste and
Emergency Response Washington DC Directive 92342-25 September 1993
US Environmental Protection Agency (USEPA) 2002 Interim Record of Decision Summary shy
Operable Unit One Non-Source Area Groundwater West SiteHows Corner Superfund Site
Plymouth Maine EPA Region 1 September 2002
US Environmental Protection Agency (USEPA) 2003 Proposed Scope of Work West SiteHows
Corner Superfund Site Plymouth Maine EPA Region 1 4 pages September 2002
Vasudevan D RL Fimmen AB Francisco (2001) Tracer-grade Rhodamine WT Structure of
constituent isomers and their sorption behavior Environ Sci Technol 35 4089-4096
nsow WOODARD amp CURRAN 26 September 30 2003 20564309
Woodard amp Curran Inc (WampC) 2002 Final Feasibility Study Report - Non-Source Area Groundwater
Hows Comer Superfund Site Plymouth Maine July 2002
TISOW WOODARD amp CURRAN 27 September 302003 20564309
f
m WOODARD amp CURRAN Maine Massachusetts New Hampshire Connecticut Florida Illinois Operational offices across the US 1-800-426-4262 wwwwoodardcurrancom
i
CORPORATE OFFICES Maine Massachusetts N e w Hampshire Connecticut Florida
Engineering bull Science bull Operations operational offices throughout the us
October 10 2003
William P Lovely Jr Remedial Project Manager USEPA - New England Region 1 Congress Street Suite 1100 (HBT) Boston MA 02114-2023
Subject Hows Corner Superfund Site Plymouth Maine Transmittal of Scope of Work - Technical Impracticability Evaluation and Field Work for Hydraulic Containment System Design
Dear Bill
Three copies of the Final Scope of Work (SOW) for Technical Impracticability Evaluation and Field Work for Hydraulic Containment System Design are enclosed Three paper copies of the report are also being provided to MEDEP today
Please contact me at 1-800-426-4262 if you have any questions about the enclosed SOW Bill we appreciate your continued efforts in working with us to bring this project to a successful completion
Sincerely
WOODARD amp CURRAN INC
n^f
Thomas R Eschner Senior Project Manager
Enclosures
cc Claudia B Sait MEDEP (3 copies) David P Littell Pierce Atwood (1 copy) Jim Rawson General Electric (1 copy) Kristin Larson Skadded Arps Slate Meather amp Flom (1 copy)
41 Hutchins Drive i Portland Maine 04102 i 207-774-2112 i 207-774-6635 (Fax) i 1-800-426-4262 i wwwwoodardcurrancom
TABLE OF CONTENTS
SECTION NO TITLE PAGE NO
10 INTRODUCTION 1
20 SITE DESCRIPTION AND INVESTIGATION HISTORY 3
30 INVESTIGATION TECHNICAL APPROACH 6 31 INVESTIGATIVE APPROACH 6
311 Task 1 - Project Planning 7 312 Task 2 - Field Investigation 7 313 Task 3 - TI Evaluation and Reporting 19
40 SCHEDULE 22
50 ACRONYMS 24
LIST OF FIGURES
FIGURE NO TITLE PAGE NO
Figure 1-1 Site Locus Plan 2 Figure 2-1 Site Plan Detail 4 Figure 3-1 Proposed Well Locations 10 Figure 4-1 Proposed Project Schedule 23
LIST OF TABLES
TABLE NO TITLE PAGE NO
Table 3-1 Rationale for Proposed Well Locations 11
TISOW WOODARD amp CURRAN TOC-I September 302003 20564309
10 INTRODUCTION
The purpose of this scope of work (SOW) is to provide an overview of the tasks proposed in response to
United States Environmental Protection Agency (USEPA) guidance and site-specific requirements for the
Technical Impracticability (TI) Evaluation of the West SiteHows Corner Superfund Site (Site) as well as
an overview of a pumping test to support design of the hydraulic containment system selected in the
Interim Record of Decision (ROD) for the Non Source-Area Groundwater at the Site (USEPA 2002)
Details of the site characterization activities described in this SOW will be provided in the three
subsequent major project-planning documents that will be produced after agreement is reached on scope
and content of the SOW
bull Work Plan
bull Health and Safety Plan (HASP)
bull Quality Assurance Project Plan (QAPP)-Including the Sampling and Analysis Plan
(SAP)
The Site is located in Plymouth Maine as depicted in Figure 1-1 The Potentially Responsible Party
Group (the PRP Group) for the Site has been asked to implement additional site characterization to
address data gaps identified by the USEPA (USEPA 2003) so that a final ROD can be issued for the Site
In addition the data developed from the pumping test described in this SOW will be used to evaluate the
number and spacing of wells for development of the hydraulic containment system design This SOW
specifies the approach proposed by the PRP Group to (1) improve the understanding of groundwater
movement including solute transport in the fractured bedrock aquifer (2) establish the limits of the TI
zone at the Site and (3) provide information that will assist in designing the hydraulic containment
system specified in the Interim ROD
This SOW is organized into four Sections Section 2 presents a brief Site description and history
followed by a discussion of the Site Conceptual Model that was previously developed for the Site based
on existing data Section 3 presents the proposed technical approach to the investigation including
rationale for well locations and investigation techniques as well as a pumping test that will be used to
assist in development of the hydraulic containment system design that will be conducted pursuant to the
authority of the Administrative Order by Consent (AOC) for the Remedial Design (RD) Details
regarding the development of the hydraulic containment system will be presented in the Remedial Design
Work Plan Section 4 presents the overall schedule for implementing this TI SOW including the
pumping test and completing the TI Evaluation Report
TISOW WOODARDampCURRAN 1 September 302003 20564309
I I1 J1 - ^
i i i KA ^$^ c E I I F L Ti M O U T H
C -j--MlI e ^P
I
I Source USGS Topographic 75-minute Series Quadrangles
Plymouth ME 1982 and Dixmont ME 1982 bull MAINR
c Figure 1-1 Quadrangle Location Site Location Map
Hows Corner Superfund Site c Plymouth Maine 4000
WOODARDampCURRAN 99503716risiteloc
I
bull 20 SITE DESCRIPTION AND INVESTIGATION HISTORY
The Site is located in east-central Maine in the town of Plymouth The Site includes a 17-acre parcel of
land owned by George West and is comprised of Operable Unit One (Non-source Area Groundwater) and
the Source Area Groundwater as generally depicted on Figure 2-1 Mr West used a small two-acre
portion of the site to operate a waste oil facility from 1965 to 1980 During investigations conducted by
the Maine Department of Environmental Protection (MEDEP) in the early 1990s a fence was placed
ft around this 2-acre portion of the Site This fenced area is referred to in the RIFS and the Interim ROD as
the Source Area (Figure 2-1) Source Area Groundwater however is defined in the ROD as
d groundwater with total volatile organic compound (VOC) concentration equal to or greater than 10 parts
per million (ppm) and may exist outside the 2-acre fenced area
m From October 1999 to May 2001 the PRP Group with oversight by USEPA and MEDEP conducted a
Remedial Investigation (RI) to determine the nature and extent of contamination to characterize the fate
and transport of contaminants and to assess the potential risks that the contamination poses to both
human health and the environment The findings of the RI show that VOCs in groundwater and
polychlorinated biphenyls (PCBs) in soil within the fenced area of the Site were present at concentrations
exceeding the target risk levels of 105 carcinogenic risk or a Hazard Index of 1 for non-carcinogenic risk
In addition modeling of Site groundwater shows that groundwater flows radially away from the source
area and discharges to the surface in many spring-fed ponds and to the surface on the flanks of the hill
bull Under current conditions contamination from the Site has reached its maximum extent This
groundwater plume consists of both Source Area Groundwater which is defined as groundwater where
total VOC concentrations are greater than or equal to 10 ppm and Non-Source Area Groundwater which
is groundwater containing total VOC concentrations below 10 ppm (USEPA 2002) (see Figure 2-1) A
(0 detailed description of the distribution and extent of groundwater contamination at the Site is provided in
sections 40 and 50 of the RI Report
4 In July 2002 the PRP Group with oversight by USEPA and MEDEP completed a Feasibility Study (FS)
to develop and evaluate a range of remedial alternatives to address potential risks to human health and the
environment that were identified during the RI for the non-source area groundwater
TISOW WOODARD amp CURRAN 3 September 302003 20564309
NonmdashSource Area Groundwater
Source Atea Groundirater
17mdashAcre George West Property
_bdquoVOCugllppm
0
| n r nA
= Volatile Orgamc Compound _ = Microgram per Liter
= Parts per Million
300 600
FEET
Notes 1 Shaded areas based on Maximum Extent of total VOCs j n e | t h e r D e c e m b e r 1 9 9 9 P r e _ R 0 D o r J u n e 2 0 0 0 Supplemental Sampling Events
2 Source Area Groundwater is defined as groundwater with total VOC concentration equal to or greater than 10000 ugl (10 ppm) Extent of Source Area Groundwater plume inferred east of 2-Acre Fenced Area
3 Non Source Area Groundwater is defined as groundwater with total VOC concentrations less then 10000 ugl (10ppm)
Figure 2-1 Site Plan Detail
Hows Corner Superfund Site Plymouth Maine
WOODARD ampCURRAN Engineering bull Science Operations
205643wipsite sowu2-1A
0
Soil within the fenced area of the Site that presented a human health risk was excavated during pilot
testing for the FS and disposed of off-site The three remedial alternatives evaluated in the FS (WampC
bull 2002) were
bull No further Action
lt$ bull Limited Action and
bull Hydraulic Containment
$t As stated in Section 40 of the FS the possible presence of a remnant dense non-aqueous phase liquid
(DNAPL) source within the groundwater plume raises the question as to whether or not complete
restoration of the aquifer can be achieved in a reasonable period of time (eg less than 100 years)
Because of the uncertainties associated with the groundwater recharge rate the mass of DNAPL in
^ Source Area Groundwater the fractional organic carbon (foe) in the bedrock and the tetrachloroethene
(PCE) organic carbon partitioning coefficient (Koc) the restoration potential of both Source Area and
^ Non-Source Area Groundwater could not be assessed within a reasonable degree of scientific certainty in
the FS
The Interim ROD for Operable Unit One Non-Source Area Groundwater (USEPA 2002) was completed
in September 2002 The remedy selected in the Interim ROD consisted of
bull Installation of groundwater extraction and treatment system to contain Source Area Groundwater
bull Monitoring of surface water sediments and Non-Source Area Groundwater to measure the
progress of natural attenuation toward meeting Applicable or Relevant and Appropriate
Requirements (ARARs)
^9 bull Residential well monitoring with a public water contingency
bull Institutional Controls to prevent use of both Source and Non-Source Area Groundwater and
( i bull Five-year Reviews
4) Following completion of the FS Report and preparation of the Interim ROD for Operable Unit One
USEPA requested that further site characterization be completed to assist in making a determination
Jsect concerning the feasibility of attaining ARARs within a reasonable time Section 3 of this SOW outlines
the tasks proposed by the PRP Group to address the requirement for additional Site data necessary for a
pound TI evaluation and containment system design
TISOW WOODARD amp CURRAN 5 September 302003 20564309
bull 30 INVESTIGATION TECHNICAL APPROACH
On behalf of the PRP Group Woodard amp Curran (WampC) has developed a proposed SOW in response to
bull USEPAs request for additional field tasks to further refine the cleanup times presented in the 2002
Interim ROD for this site This approach has been designed to evaluate the following additional data
lt9 needs identified by USEPA to refine cleanup times
4t bull Aquifer hydraulic conductivity
bull Aquifer porosity (matrix and bulk) and
H bull Partitioning of contaminants to the bedrock
^ The data from these additional field tasks will also be used by USEPA to define the TI zone for the Final
ROD and assist the PRPs in developing the design for the hydraulic containment system for the Source
j Area Groundwater which is being conducted under the authority of the RD AOC Details regarding
development of the hydraulic containment system will be presented in the Remedial Design Work Plan
The proposed TI SOW is based on information available during its preparation and may be amended
subject to USEPA approval as additional information regarding subsurface conditions becomes available
during the field investigation The following section describes the overall field investigation approach A
comprehensive presentation of each task in the field investigation will be provided in the Sampling and
bull Analysis Plan (SAP) which will be amended following approval of a final scope of work
bull0 31 Investigative Approach
j The work proposed to meet the additional data requirements stated by USEPA consists of the three
primary tasks described below and further outlined as subtasks Brief descriptions of each task are
presented in the subsections that follow
Task 1 - Project Planning
Task 2 - Field Investigation
Task 3 - TI Evaluation and Reporting
WOODARD amp CURRAN 6 September 302003 20564309
311 Task 1 - Project Planning
Project planning is the first task and includes the following five subtasks
bull Finalize the SOW
bull Prepare work plan
bull Revise existing site-specific Quality Assurance Project Plan (QAPP) Sampling and Analysis
Plan (SAP) and Health and Safety Plan (HASP) and
bull Secure subcontractor contracts
bull Mobilize to the Site and establish a field office
In order to finalize the SOW for this TI evaluation it is anticipated that a minimum of one meeting will
occur between the PRP Group USEPA MEDEP and WampC Once the SOW is finalized the QAPP
SAP and HASP (the Plans) will be revised to incorporate necessary modifications to reflect the agreed-
upon work methods and technology The SAP will be modified to include a detailed plan for the
additional field activities Once the Plans have been revised and the Work Plan prepared they will be
submitted to USEPA for review USEPA comments will be incorporated into the plans and final
approved plans will be issued
After final plans have been issued WampC will negotiate contracts with subcontractors for certain field
activities including boring and monitoring well installation geophysical survey packer testing and
investigation-derived waste (IDW) storage and disposal It is anticipated that a second meeting between
the parties may be needed prior to the commencement of the field activities
Because of the duration of the field activities described in this SOW and the need for on-site evaluation of
field results in order to make program decisions during the investigation WampC will mobilize a trailer to
the Site to serve as a field office The trailer will be equipped with telephone and fax machine
312 Task 2 - Field Investigation
The field investigation task will include the following subtasks
bull Subtask 1 - Boring installation
bull Subtask 2 - Borehole geophysics
TISOW
WOODARDampCURRAN 7 September 302003 20564309
0
0 bull Subtask 3 - Packer testing
bull Subtask 4 - Sampling and analysis
bull bull Subtask 5 - Monitoring well installation
bull Subtask 5 - Pumping test and
bull Subtask 6 - Tracer test
Each of the subtasks is summarized below however a comprehensive discussion of these subtasks and
associated methodologies will be provided in the SAP
Subtask 1 - Boring Installation
j Information obtained during the installation of the new borings will be used in the evaluation of the
aquifer hydraulic conductivity and the analysis of other aquifer properties (eg porosity fracture
frequency) For this subtask it is anticipated that one angled boring will be completed to a depth of 150
feet (ft) below ground surface (bgs) One additional angled boring and four new vertical bedrock borings
will be completed to depths of approximately 100 ft bgs This depth is consistent with the depth
evaluated in the RI and will allow evaluation of bedrock and groundwater properties to depths below the
transition from less competent to more competent bedrock (approximately 50 to 80 ft bgs)
m One additional vertical boring will be installed to a depth of 100 ft bgs as the pumping well location for
bull the pumping test The pumping well location will be based on the results of field work conducted prior to
its installation The proposed drilling program is designed to enhance understanding of the flow system
by aligning new boring locations with existing wells to characterize hydraulic properties of the fracture
network and bulk bedrock Furthermore the program allows for additional characterization of
M contamination in the Source Area groundwater The rationale for the boring locations is summarized in
Table 3-1 and the proposed locations of the borings are depicted on Figure 3-1 Actual locations may
M vary depending on field conditions and accessibility
jlt The drilling protocol employed during installation of both the angled and the vertical wells will allow for
evaluation of the potential presence of DNAPL in the rock and the need for modifications to the drilling
method if DNAPL is detected If sheen or product is observed in the return water core or cuttings from a
boring an interface probe may be employed to determine whether a NAPL is present in the boring
Based on the presence of DNAPL the boring may be terminated at a shallower depth than planned the
J TISOW 4 1 WOODARD amp CURRAN 8 September 302003
20564309
location may be abandoned or other practices may be employed to reduce the potential for causing
downward migration of DNAPL The protocol will be described in the Work Plan and the SAP
Angled Borings Two angled borings will be installed using air-hammer drilling methods The first
angled boring (AW-201) will be installed to a depth of 150 ft bgs in the vicinity of existing well MWshy
106 northeast of and outside of the source area and within the dissolved phase groundwater plume This
well will be angled from the surface toward the southeast at depth in order to intersect as many northwest-
dipping near-vertical fractures as possible The angle of this boring will be approximately 30deg to 40deg
from the vertical resulting in a surface projection of approximately 84 to 126 ft and total length of
approximately 173 to 195 ft The second angled boring (AW-202) will be installed to a depth of 100 ft
bgs in the vicinity of the existing MW-2 well cluster within the source area This well also will be angled
from the surface toward the southeast at depth in order to intersect near-vertical fractures The angle of
this boring will be approximately 30deg to 40deg from the vertical resulting in a surface projection of
approximately 58 to 84 ft and total length of approximately 115 to 130 ft
m
4
sect
i
TISOW WOODARD amp CURRAN 9 September 302003 20564309
Table 3-1
Rationale for Proposed Well Locations
Hows Corner Technical Impracticability Evaluation and Field work for Hydraulic Containment System Design
Well Identification
AW-201
AW-202
MW-203
MW-204
MW-205
MW-206
PW-207
Boring Orientation
Angled
Angled
Vertical
Vertical
Vertical
Vertical
Vertical
Minimum Boring Diameter (inches)
4
4
4
4
4
4
6
Drilling Method
Air Hammer
Air Hammer
Coring
Air Hammer
Air Hammer
Air Hammer
Core Air Hammer Over -drilling
Source Area Non-Source Area
Non-Source Area
Source Area
Non-Source Area
Non-Source Area
Source Area
Source Area
Source Area
Rationale for Boring
bull Intercept near-vertical fractures to understand subsurface geology bull Aid in iting MW-203 bull Intercept near-vertical fractures to understand subsurface geology bull Aid in siting PW-201 (Pumping well) bull ion of contamination bull 1 future monitoring location bull Potential reinjection well for hydraulic containment system bull Core for matrix diffusion evaluation bullbullbullbull Ibullbullbullbull 1bullbullbullbull 1bullbull bull 1
tion point for pumping test tion point in tracer test ion of contamination
future monitoring location tion point for pumping test tion point in tracer test ion of contamination
future monitoring location tion point for pumping test tion point in tracer test ion of contamination
future monitoring location tion point for pumping test
test well extraction well
bull Core for matrix diffusion evaluation bull i point for tracer test
TISOW September 30 2003 WOODARD amp CURRAN 20564309
MW-105D MW-5B
Primary Bedding Secondary Cleavage
Tertsry Fracturing
NOTE A total of 60 observations warn made rtrtjs roprtraont tticopy number of obsafvatk noted wtthln each azimutha) segment
MW-1 1 3D euro MW-205
2 AcreSource
Fenced-^ Area i
MW-103D MW-103S
17-Acre Property Boundary
MW-104D MW-1041 bull
MW-104S
Legend Figure 3-1 J Proposed Monitoring Well Proposed Well Locations
o- Site Property Boundary bull^bullProposed Pumping Well Hows Corner Superfund Site -xmdashx- Source Area Plymouth Maine
^ ^Proposed Angled Well bullamp Existing Monitoring Well bullWDODARDampCURRAN
Englnoortng bull Science bull Operations 205643wipsite-8OlaquoAx-opt-1-2-u3-1D
bull During the installation of each angled boring observations will be made regarding water gainloss
drilling rate and bit behavior to assess the depth of potential fractures In addition water levels will be
9 measured in nearby borings using either hand measurements data loggers or both to evaluate
connectivity between locations A change in water level in a nearby boring will indicate a hydraulic
at connection between the borings Borehole geophysics will also be performed on the borings (See Subtask
2 below) Information from each angled boring will be used to site an adjacent vertical well (MW-203
^ and PW-207) so that it intercepts a fracture observed in the angled boring
^ Vertical Borings Two of the vertical borings will be completed with rotary diamond coring to
approximately 100 ft bgs These borings will be adjacent to the angled borings described above One of
^ the cored borings (MW-203) will be located near MW-106 outside of the source area within the
dissolved-phase groundwater plume (see Figure 3-1) The other cored boring (PW-207) will be the
pumping well which is anticipated to be located within the source area in the vicinity of the existing
MW-2 well cluster Coring will allow data collection for several purposes including direct observation
of bedrock for determination of the nature of the rock matrix determination of the location and nature of
fractures and the degree of fracturing comparison with geophysical logs (Subtask 2) to verify
interpretation of the logs and collection of core samples for analysis (Subtask 4)
The remaining borings will be located east of the 2-acre fenced area within or near the periphery of the
source area and will be sited to align approximately with existing wells based on the known fracture
orientations at the Site (MW-204 and MW-205) or with new wells based on the known fracture
pound orientations at the Site (MW-206) Data from these locations in conjunction with the other borings
installed as part of this TI SOW and the existing wells will be used in the interpretation of the pumping
^ test (Subtask 6) and tracer test (Subtask 7) In addition these three borings will further delineate
contamination and provide potential monitoring locations for long-term monitoring Each of these
^ borings will be advanced to approximately 100 ft bgs with a minimum four-inch diameter air hammer
^ During the installation of each boring observations will be made regarding water gainloss drilling rate
and bit behavior to assess the depth of potential fractures In addition water levels will be measured in
nearby borings using either hand measurements data loggers or both to evaluate connectivity between
locations A change in water level in a nearby boring will indicate a hydraulic connection between the
TISOW WOODARD amp CURRAN 12 September 302003 20564309
borings Borehole geophysics and packer testing will also be performed on the borings (See Subtasks 2
and 3 below)
Drilling water will be containerized on site and treated through granular activated carbon (GAC) Treated
water will be analyzed to verify that PCB and VOC concentrations have been reduced to below ARARs
prior to discharge to the ground surface Cuttings will be spread on the ground surface at the site
consistent with the Remedial Investigation work plan
It is anticipated that up to 10 core samples from each cored boring (total of 20 cores) will be collected and
submitted to an off-site laboratory for analyses of porosity (matrix and bulk) permeability bulk density
and fraction of organic carbon (f^) using methods described in Subtask 4
Subtask 2 - Borehole Geophysics
To supplement information on fracture location and connectivity obtained during boring advancement a
borehole geophysical survey will be conducted on the newly installed bedrock borings to evaluate the
nature and orientation of water bearing fractures in the borings The survey will be performed at the
completion of the angled borings and again at the completion of the vertical borings The information
obtained during the survey may be used to identify the location of subsequent boring(s) by refining the
understanding of the depth aperture and orientation of bedrock fractures The following measurements
are proposed for the new borings caliper fluid temperature fluid resistivity and acoustic televiewer
(ATV) Single-point resistively and 16 inch normal measurements will also be made in the first two
borings installed and the data will be compared to data from the other geophysical logs to determine if
the measurements confirm and significantly improve the interpretation regarding the presence of water-
bearing fractures If the measurements are applicable to identification of fractures they may be included
in lieu of other geophysical logs in the remainder of the borings
Subtask 3 - Packer Testing
To further refine information on the aquifer hydraulic conductivity the hydraulic connection between
fractures in the borings will be evaluated during packer testing of vertical borings The data will be used
to estimate the hydraulic conductivity of specific fractures and fracture zones The packer testing will be
performed after the vertical borings have been installed and the borehole geophysical survey completed
TISOW WOODARD amp CURRAN 13 September 30 2003 20564309
bull
m
M
Drilling observations and information from borehole geophysics will be used to identify specific fractures
below the water table that are capable of transmitting water Prior to water injection for hydraulic
conductivity and fracture connectivity testing groundwater samples will be collected at selected intervals
for analysis of VOCs (See Subtask 4) Sampling intervals will be selected based on drilling observations
and logging results that indicate water is moving into or out of the borehole or that fractures exist to
promote water movement such as rapid increase in the amount of water returned rapid change in
temperature or highly fractured interval
^
^
bull
f$
Double packer testing will be performed at selected intervals within each newly installed boring It is
anticipated that up to six intervals per well will be tested for a maximum of 24 intervals and that for each
interval the test will include an approximate 15-minute injection of potable water at four progressively
increasing pressures Packer spacing is anticipated to be 10 ft however spacing may vary so that packers
are not located in potential fracture zones identified using information from rock cores drilling
observations and borehole geophysics The tests at an individual interval will be terminated if it appears
that the interval is not accepting water Care will be taken to minimize over-pumping or over-
pressurizing of the fractures The flow rate will be measured to evaluate the characteristics of the
fracture Water levels in adjacent borings will be measured during the packer testing to determine if a
hydraulic connection exists between the borings Water generated during packer testing will be
containerized on site and treated through GAC Treated water will be analyzed to verify that PCB and
VOC concentrations have been reduced to below ARARs prior to discharge to the ground surface
4 Subtask 4 Sampling and Analysis
~d
^
Rock and groundwater samples will be collected during the field program for laboratory analysis The
results of the analyses will be used to help refine the distribution of the plume and to estimate bedrock
properties These analyses will be used in conjunction with existing data during the TI evaluation to
refine cleanup times and establish the limits of the TI zone
As described in Subtask 1 it is anticipated that up to 10 core samples from each cored boring (total of 20
core samples) will be collected and submitted to an off-site laboratory for analyses of porosity (matrix and
bulk) permeability bulk density and fraction of organic carbon (f^) using existing industry methods
Subject to further evaluation of industry methods Woodard amp Curran proposes that porosity
TISOW WOODARD amp CURRAN20564309
14 September 302003
permeability and density will be measured using methods in the American Petroleum Institutes API RPshy
40 Fraction of organic carbon (f^) will be measured using either the LECO TOC method or Walkey-
Black method The LECO TOC method is a standard method in the petroleum industry and involves the
direct combustion of a ground rock sample The Walkey-Black method is a commonly used USEPA-
approved chemical oxidation method for determination of foe in soils In addition either method could be
used if a sample were scraped from a fracture surface To develop a reasonable range of f for Site
bedrock up to five samples will be selected from each boring from the unfractured matrix and up to five
from the fracture surfaces In addition Woodard amp Curran will evaluate the appropriateness of selecting
rock samples from a subset of the core samples from areas near fractures as well as from non-fractured
areas and submitting the samples for VOC analysis following methanol extraction
Results from these analyses will be used in conjunction with groundwater contaminant concentrations to
evaluate the significance of diffusion of contamination from the bedrock matrix in both the Source Area
and the Non-Source Area Although matrix diffusion likely is a significant factor in the determination of
cleanup times within the Source Area the potential applicability of matrix diffusion in the Non-Source
Area is not known These core analyses may provide evidence to assist in developing an estimate
through calculations of the effect of matrix diffusion on cleanup times
As noted in Subtask 3 prior to injection of water during packer testing groundwater samples will be
collected at selected intervals for analysis of volatile organic compounds (VOCs) Up to a total of 20
groundwater samples plus appropriate quality control samples will be collected from the newly installed
borings The samples will be submitted to an off-site laboratory for analysis Analytical results will be
validated in accordance with USEPA protocol and the data will be managed in WampCs existing
groundwater sampling analytical database for this site
Up to 21 existing monitoring wells from within or nearby the 17-acre property plus four new wells once
constructed will be sampled using low-flow techniques and submitted to an off-site laboratory for VOC
analysis Analytical results will be validated in accordance with USEPA protocol and the data will be
managed in WampCs existing groundwater sampling analytical database for this site
TISOW WOODARD amp CURRAN 15 September 302003 20564309
Subtask 5 - Monitoring Well Installation
Although it is anticipated that the newly installed borings will be left as open holes for tracer testing and
for pumping tests monitoring wells will be installed and developed in the newly installed borings unless
the USEPA MEDEP and PRP Group determine that the location is inappropriate for such use The
monitoring wells will be constructed of two-inch schedule 40 PVC screen and riser Screen intervals will
be selected based on the location of fractures identified during drilling geophysical logging and packer
testing A sand pack will be placed around the screen and will extend from approximately two ft below
the screen to approximately two ft above the screen
Subtask 6 - Pumping Test
WampC will conduct a single constant discharge pumping test to evaluate hydraulic properties of the
aquifer It is anticipated that the test will be conducted in a new pumping well in the vicinity of the
existing MW-2 well cluster within the source area Data from the pumping test will be used in
conjunction with other data from the investigation to improve the understanding of groundwater
movement and contaminant transport in the Source and Non-Source areas The results of the pumping
test will be used to refine the Site conceptual model as well as in the design of the hydraulic containment
system that is being constructed under the authority of the AOC for the RD
The groundwater pumping test will include the following components (1) Pumping test setup (2) Pretest
monitoring (3) Constant Discharge Pumping Test (4) Post-test monitoring and (5) Data Analysis
Pumping Test Setup In support of the groundwater pumping test WampC will install a pumping well
(PW-207) and procure and install the required groundwater extraction treatment and storage equipment at
the Site The well will be cored and over drilled to allow construction of a 4-inch well The location will
be in the vicinity of the MW-2 well cluster and be based upon results of the angled bedrock boring AWshy
202 The equipment will include but not be limited to
bull Down well pump plumbing and appurtances
bull Two (2) 20000 frac tanks
bull Groundwater transfer pumps and controls
bull Settlingaerationsand filtration treatment processes for the treatment of inorganics (if needed) and
nsow WOODARD amp CURRAN 16 September 302003 20564309
bull Granular activated carbon units for the treatment of dissolved organics in the groundwater
The groundwater treatment process will include the following processes 1) an oxidation and filtration
step to remove the inorganics from the groundwater and GAC units to treat the organic contaminants in
the extracted groundwater
Pretest Monitoring Prior to initiation of pumping WampC will monitor water levels in existing wells and
newly installed borings adjacent to the pumping well using a combination of hand measurements and data
loggers to develop an understanding of the piezometric surface under unstressed conditions The wells
proposed for water-level monitoring will be described in the work plan In addition all gauges
transducers flow meters and other equipment used in conducting the pumping tests shall be calibrated
before use
Constant Discharge Pumping Test The pumping test will be conducted in the source area using
newly-installed pumping well PW-207 It is anticipated that the test will be conducted at a pumping rate
of approximately 2 gallons per minute (gpm) for a period of 2 to 3 days however a higher or lower rate
may be shown to be appropriate based on the drilling and packer testing conducted during boring
installation Woodard amp Curran proposes to conduct this test using a vacuum-enhanced recovery system
(VERS) as described in the ROD so that the water level is not lowered appreciably in the vicinity of the
pumping well to prevent the potential migration of NAPLs to deeper bedrock zones The appropriateness
and feasibility of the VERS for the pumping test will be determined by field testing or literature
evaluation prior to completion of the Work Plan Because of the short duration of this test it is not
anticipated that stability of water levels will be reached in observation wells The test will however
provide information to estimate hydraulic conductivity and bedrock storage During the test the water
levels in the pumping well and selected monitoring wells will be logged continuously via down well data
loggers It is anticipated that water levels in approximately 24 wells will be measured using hand
measurements and data loggers
Groundwater extracted during the pumping test will be stored temporarily in an on-site frac tank prior to
on-site treatment and disposal
TISOW WOODARD amp CURRAN 17 September 302003 20564309
Post-Test Monitoring After the pump is turned off in the pumping well water levels will continue to be
monitored using hand measurements and data loggers until they have returned to within 10 of the preshy
test levels For planning purposes this has been estimated to be two weeks
Data Analysis Data collected during the pumping test will be analyzed with Aquifer Win32 Results of
the pumping test will be summarized in the summary data package for the TI Evaluation and the results
will also be used in the design of the hydraulic containment system specified in the Interim ROD that is
being conducted under the authority of the AOC for the RD Detail regarding use of the pumping test
data in hydraulic system design will be provided in the Remedial Design Work Plan
Subtask 7 - Tracer Test
WampC will conduct a tracer test using a conservative tracer to evaluate fracture connectivity porosity
dispersivity and matrix diffusion of the bedrock aquifer in both the Source Area and Non-Source Area
To increase the potential for success of this test results of the pumping test evaluation will be used to
revise the tracer test plan proposed here as necessary Following rebound of water levels after
completion of the pumping test WampC will initiate a single natural gradient tracer test The test will
consist of injecting a tracer into well PW-207 in the source area (Figure 3-1) for up to five days and
monitoring the tracers arrival in nearby wells Borehole geophysics core evaluation and packer testing
will be used to select the specific injection depth(s) in the well
A Tracer Test Work Plan will be completed prior to initiation of injection to determine the type quantity
and concentration of tracer based on the distance between the injection well and the monitoring wells A
conservative tracer that is one that is not preferentially adsorbed to rock or organic matter will be
selected for the tracer test Tracer injection equipment including tanks and flow-regulating and metering
equipment and pumps will be used to mix the tracer at the surface prior to injection Fractures may be
packered in the injection well and tracer solution will be injected at a rate determined during preparation
of the Tracer Test Work Plan During injection the potentiometric surface of the aquifer will be
monitored to verify that the potentiometric surface remains relatively constant during the injection
process
nsow WOODARD amp CURRAN 18 September 302003 20564309
Prior to injection of the tracer background concentration will be established by collecting samples from
up to six wells in the area of the tracer test and analyzing them for the tracer using an appropriate
analytical method Following injection of the tracer solutions the concentration of the tracer in
downgradient wells and borings will be measured A monitoring network will be established using nearby
monitoring wells Downhole probes will be installed in six new and existing wells near the injection well
to be identified in the work plan first to determine the background tracer concentrations and then to
monitor for the presence of the tracer upon initiation of the test Measurements will be collected at
periodic intervals to be determined based on the results of packer testing If an increase in tracer
concentration is detected or at a minimum on a weekly basis a water sample will be collected using low
flow sampling methodologies and analyzed in an off-site laboratory to evaluate the concentration of the
tracer The concentration of the tracer will be recorded Monitoring of the tracer concentration will
continue throughout the duration of the test The tracer will be allowed to flow with groundwater for one
month or until detected in wells in the vicinity of MW-106 whichever is shorter
313 Task 3 - TI Evaluation and Reporting
The TI Evaluation and reporting task includes the following five subtasks
bull Data evaluation
bull Summary data package
bull Draft TI Evaluation
bull Meetings with PRP Group and USEPA and
bull Revise and finalize TI Evaluation
As the subtasks of the field investigation are completed the data will be evaluated for the purpose of
addressing the data gaps identified by USEPA Specifically the data will be used to further refine the
cleanup times for non-source area groundwater presented in the Interim ROD
The data obtained during the field investigation will be reduced and evaluated and a summary data
package will be prepared that will include a discussion of the field activities completed and presentation
of the data It is anticipated that up to two meetings with USEPA will be necessary before the data
evaluation and summary report are completed
TISOW WOODARDampCURRAN 19 September 302003 20564309
Data collected during the pumping test will be analyzed with Aquifer Win32 Results will be summarized
in the summary data package and will also be presented as part of the RD submittals
Following submittal of the summary data package the TI evaluation will be prepared In accordance with
EPA guidance (1993) the TI waiver evaluation document will address the following topics
1 Specific ARARS or media cleanup standards for which TI determination is sought This section of the
TI Evaluation will identify the specific contaminants for which the TI determination is sought Based on
information available to date a waiver may be appropriate for pesticides PCBs chlorinated organic
compounds and other site-related contaminants that upon evaluation will not attain ARARs in a
reasonable period of time
2 Spatial area over which the TI waiver will apply The purpose of the additional site investigation
outlined in this SOW is to obtain the data necessary to further refine cleanup times presented in the
Interim ROD to determine what portions of the Site will not be expected to reach ARARs within a
reasonable time Consistent with TI guidance (USEPA 1993) the TI evaluation will specify the
horizontal and vertical extent of the area for which TI determination is sought Groundwater
concentration data from the RI and the TI SOW will be used to refine the distribution of the plume Data
from the drilling geophysical logging packer testing and pumping and tracer tests will be used to refine
the Site conceptual model and the cleanup times that will serve as the basis for establishing the scope and
nature of the TI zone
3 Conceptual Model The conceptual model forms the technical core of the TI Waiver Evaluation since
it provides basis for understanding of the restoration potential of the site The conceptual model outlines
the physical and hydrogeological constraints that hinder remediation or removal of Site contaminants and
it is the extent of these constraints rather than restoration timeframe alone that USEPA will use to
evaluate the necessity of the TI waiver of ARARs The conceptual model is the link between restoration
potential and restoration timeframe since it explains why proposed technologies are unlikely to work
either at all or within the desired 100-year timeframe
The Site conceptual model is not a mathematical model however as the result of the extensive modeling
and investigations of the site WampC has a strong understanding of the complex bedrock and overburden
TISOW WOODARDampCURRAN 20 September 302003 20564309
groundwater system beneath this site This understanding has been presented previously in both the RI
report and the FS and will be refined based on the TI SOW as necessary and summarized in the TI
Waiver Evaluation with specific attention to the physical and hydrogeological constraints on remediation
In particular the Site conceptual model will be reviewed in light of the new geologic data from drilling
logging and packer testing and the new hydrogeologic data obtained from the pumping test and tracer test
and will be revised to incorporate the new understanding
4 An evaluation of the restoration potential of the site This section will consist of a several components
It will present a systematic review of the technologies potentially capable of remediating the site given
the physical and hydrogeological constraints identified in the site model The newly acquired data will
provide an improved understanding of bedrock hydraulic properties that will allow a more Site-specific
evaluation of technologies The review of technologies will also include review of innovative
technologies and will evaluate whether existing remedial technologies or strategies would be capable of
achieving groundwater restoration at the site in a reasonable timeframe The section reference the FS and
will summarize the alternative remedies considered in the FS focusing on the ability of each to restore
groundwater in a reasonable timeframe It will also include a discussion of the selected hydraulic
containment system in light of the data gathered from the pumping test conducted in conjunction with the
TI SOW
Based on the Batch Flushing Model and using the agreed upon koc data from the RI as well as data from
this TI SOW including the f data collected as part of Subtask 4 a restoration timeframe analysis will be
conducted Following completion of the timeframe analysis and consideration of the results of drilling
rock and water analyses and pumping and tracer test a determination will be made regarding the Source
Area and the portion of the Non-Source Area VOC plume that will not attain ARARs in a reasonable
time
TISOW WOODARD amp CURRAN 21 September 302003 20564309
40 SCHEDULE
A proposed project schedule is included with this plan as Figure 4-1 This schedule is included for
discussion purposes and will be modified as necessary once the final scope of work as been approved by
all parties and the field work activities are coordinated with the subcontractors
TISOW WOODARD amp CURRAN 22 September 302003 20564309
ID
2
3
4
5
6
7 a i 10
11
12
13
14
15
16
17
16
19
20
21
22
24
25
26
27
26
29
30
31
32
Task Name
Project Meeting with EPA
Finalize SOW
Prepare Work Plans QAPP HASP Revision
Submit Work Plans for EPA Approval
Project Meeting with EPA
Revisions to work plans
Submit final work plans
Subcontractor Contracts
Project Meeting wEPA
Field Investigation
Site Mobilization
Install Borings
Borehole Geophysics
Packer Testing amp Collect GW Samples
Pumping Test
Tracer Test
Test setup
Injection
Monitoring
Data Reporting
InstallDevelop Wells
Data Evaluation
Prepare Data Package
Data Package Submittal to EPA
Draft Tl Evaluation Repon
Draft Tl Evaluation Report Submttal to EPA
EPA ReviewComment on Tl Evaluation ReF
Project Meeting wEPA
Revisions to Tl Evaluation Report
Submit Final Tl Evaluation Report
Start
Wed 070903
Thu 071003
Fri 101003
Mon 120103
Mon 121503
Mon 122903
Mon 011204
Tue 011304
Thu 021904
Fri 032104
Fri 032604
Fri 040204
Fri 041604
Fri 042304
Thu 050604
Wed 060204
Wed 060204
Wed 060904
Wed 060904
Wed 062304
Wed 070704
Wed 042804
Wed 062304
Mon 080204
Mon 070504
Tue 082404
Wed 082504
Wed 091504
Thu 0916AM
Thu 093004
Finish
Wed 070903
Fri 1OtO7u3
Fri 112803
Fri 122603
Mon 121503
Fri 010904
Mon 011204
Mon 012604
Thu 021904
Tue 071304
Thu 040104
Thu 042204
Tue 042704
Wed 050504
Tue 052504
Tue 071304
Tue 060804
Tue 061504
Tue 070604
Tue 071304
Fri 070904
Tue 072004
Fri 073004
Mon 080204
Mon 082304
Tue 082404
Tue 091404
Wed 091504
Wed 082904
Thu 093004
FIGURE 4-1 DRAFT HOWS CORNER SUPERFUND SITE
Tl EVALUATION amp RELD WORK FOR HYDRAUUC CONTAINMENT SYSTEM DESIGN PROPOSED PROJECT SCHEDULE
2003 2004 Mav |
Jun | Jul
ltamp i
Aug
i
Sen Oct I Nov Dec Jan Feb I Mar
ii i i
k ^tr 1
1V i
I t bull ^
I
ta^M bull bull M W
l LgtH^HBKLii LJ Mi
I
bull bull raquo bull laquo^ 0930
Task Progress I^MLHHHI^LB Summary ^^^^^^^^f External Tasks M B WMMM Deadline ^7 Project Hows Comer Schedule6A bull bull bull 1 UData Fri 101003 Split Milestone ^ Project Summary ^f^KKKKKK^^ External Milestone ^
Pagei
50 ACRONYMS
AOC Administrative Order by Consent
ARARs Applicable or Relevant and Appropriate Requirements
ATV acoustic televiewer
bgs below ground surface
CERCLA Comprehensive Environmental Resource and Conservation Liability Act
DNAPL Dense Non-Aqueous Phase Liquid
GAC granular activated carbon
gpm gallons per minute
HASP Health and Safety Plan
row investigation-derived waste
MCL Maximum Containment Level
MEDEP Maine Department of Environmental Protection
MEG Maine Enforcement Guideline
mgkg milligrams per kilogram
Hg kg micrograms per kilogram
NCP National Contingency Plan
PCB polychlorinated biphenyl
PID photo ionization detector
ppm parts per million
PRP Potentially Responsible Party
TISOW WOODARD amp CURRAN 24 September 302003 20564309
QAPP Quality Assurance Project Plan
QAQC Quality AssuranceQuality Control
RA Remedial Action
RAO Remedial Action Objective
RCRA Resource Conservation and Recovery Act
RD Remedial Design
RIFS Remedial InvestigationFeasibility Study
ROD Record of Decision
SAP Sampling and Analysis Plan
SOW Statement of Work
TAL target analyte list
TI Technical Impracticability
USEPA United State Environmental Protection Agency
VOCs volatile organic compounds
WampC Woodard amp Curran Inc
TISOW WOODARD amp CURRAN 25 September 302003 20564309
REFERENCES
Everts CJ RS Kanwar (1994) Evaluation of Rhodamine WT as an adsorbed tracer in an agricultural
soil J Hydrology 153 53-70
Kasnavia T D Vu DA Sabatini (1999) Fluorescent dye and media properties affecting sorption and
tracer selection Groundwater 37 376-381
Ptak T G Schmid (1996) Dual-tracer transport experiments in a physically and chemically
heterogeneous porous aquifer effective transport parameters and spatial variability J Hydrology
183 117-138
Sabatini DA T A Austin (1991) Characteristics of Rhodamine WT and fluorescein as adsorbing
ground-water tracers Ground Water 29 341-349
Trudgill ST (1987) Soil water dye tracing with special reference to the use of Rhodamanie WT
Lissamine FF and Amino G acid Hydrological Processes 1 149-170
US Environmental Protection Agency (USEPA) 1993 Guidance for Evaluating the Technical
Impracticability of Ground-Water Restoration - Interim Final Office of Solid Waste and
Emergency Response Washington DC Directive 92342-25 September 1993
US Environmental Protection Agency (USEPA) 2002 Interim Record of Decision Summary shy
Operable Unit One Non-Source Area Groundwater West SiteHows Corner Superfund Site
Plymouth Maine EPA Region 1 September 2002
US Environmental Protection Agency (USEPA) 2003 Proposed Scope of Work West SiteHows
Corner Superfund Site Plymouth Maine EPA Region 1 4 pages September 2002
Vasudevan D RL Fimmen AB Francisco (2001) Tracer-grade Rhodamine WT Structure of
constituent isomers and their sorption behavior Environ Sci Technol 35 4089-4096
nsow WOODARD amp CURRAN 26 September 30 2003 20564309
Woodard amp Curran Inc (WampC) 2002 Final Feasibility Study Report - Non-Source Area Groundwater
Hows Comer Superfund Site Plymouth Maine July 2002
TISOW WOODARD amp CURRAN 27 September 302003 20564309
f
m WOODARD amp CURRAN Maine Massachusetts New Hampshire Connecticut Florida Illinois Operational offices across the US 1-800-426-4262 wwwwoodardcurrancom
i
TABLE OF CONTENTS
SECTION NO TITLE PAGE NO
10 INTRODUCTION 1
20 SITE DESCRIPTION AND INVESTIGATION HISTORY 3
30 INVESTIGATION TECHNICAL APPROACH 6 31 INVESTIGATIVE APPROACH 6
311 Task 1 - Project Planning 7 312 Task 2 - Field Investigation 7 313 Task 3 - TI Evaluation and Reporting 19
40 SCHEDULE 22
50 ACRONYMS 24
LIST OF FIGURES
FIGURE NO TITLE PAGE NO
Figure 1-1 Site Locus Plan 2 Figure 2-1 Site Plan Detail 4 Figure 3-1 Proposed Well Locations 10 Figure 4-1 Proposed Project Schedule 23
LIST OF TABLES
TABLE NO TITLE PAGE NO
Table 3-1 Rationale for Proposed Well Locations 11
TISOW WOODARD amp CURRAN TOC-I September 302003 20564309
10 INTRODUCTION
The purpose of this scope of work (SOW) is to provide an overview of the tasks proposed in response to
United States Environmental Protection Agency (USEPA) guidance and site-specific requirements for the
Technical Impracticability (TI) Evaluation of the West SiteHows Corner Superfund Site (Site) as well as
an overview of a pumping test to support design of the hydraulic containment system selected in the
Interim Record of Decision (ROD) for the Non Source-Area Groundwater at the Site (USEPA 2002)
Details of the site characterization activities described in this SOW will be provided in the three
subsequent major project-planning documents that will be produced after agreement is reached on scope
and content of the SOW
bull Work Plan
bull Health and Safety Plan (HASP)
bull Quality Assurance Project Plan (QAPP)-Including the Sampling and Analysis Plan
(SAP)
The Site is located in Plymouth Maine as depicted in Figure 1-1 The Potentially Responsible Party
Group (the PRP Group) for the Site has been asked to implement additional site characterization to
address data gaps identified by the USEPA (USEPA 2003) so that a final ROD can be issued for the Site
In addition the data developed from the pumping test described in this SOW will be used to evaluate the
number and spacing of wells for development of the hydraulic containment system design This SOW
specifies the approach proposed by the PRP Group to (1) improve the understanding of groundwater
movement including solute transport in the fractured bedrock aquifer (2) establish the limits of the TI
zone at the Site and (3) provide information that will assist in designing the hydraulic containment
system specified in the Interim ROD
This SOW is organized into four Sections Section 2 presents a brief Site description and history
followed by a discussion of the Site Conceptual Model that was previously developed for the Site based
on existing data Section 3 presents the proposed technical approach to the investigation including
rationale for well locations and investigation techniques as well as a pumping test that will be used to
assist in development of the hydraulic containment system design that will be conducted pursuant to the
authority of the Administrative Order by Consent (AOC) for the Remedial Design (RD) Details
regarding the development of the hydraulic containment system will be presented in the Remedial Design
Work Plan Section 4 presents the overall schedule for implementing this TI SOW including the
pumping test and completing the TI Evaluation Report
TISOW WOODARDampCURRAN 1 September 302003 20564309
I I1 J1 - ^
i i i KA ^$^ c E I I F L Ti M O U T H
C -j--MlI e ^P
I
I Source USGS Topographic 75-minute Series Quadrangles
Plymouth ME 1982 and Dixmont ME 1982 bull MAINR
c Figure 1-1 Quadrangle Location Site Location Map
Hows Corner Superfund Site c Plymouth Maine 4000
WOODARDampCURRAN 99503716risiteloc
I
bull 20 SITE DESCRIPTION AND INVESTIGATION HISTORY
The Site is located in east-central Maine in the town of Plymouth The Site includes a 17-acre parcel of
land owned by George West and is comprised of Operable Unit One (Non-source Area Groundwater) and
the Source Area Groundwater as generally depicted on Figure 2-1 Mr West used a small two-acre
portion of the site to operate a waste oil facility from 1965 to 1980 During investigations conducted by
the Maine Department of Environmental Protection (MEDEP) in the early 1990s a fence was placed
ft around this 2-acre portion of the Site This fenced area is referred to in the RIFS and the Interim ROD as
the Source Area (Figure 2-1) Source Area Groundwater however is defined in the ROD as
d groundwater with total volatile organic compound (VOC) concentration equal to or greater than 10 parts
per million (ppm) and may exist outside the 2-acre fenced area
m From October 1999 to May 2001 the PRP Group with oversight by USEPA and MEDEP conducted a
Remedial Investigation (RI) to determine the nature and extent of contamination to characterize the fate
and transport of contaminants and to assess the potential risks that the contamination poses to both
human health and the environment The findings of the RI show that VOCs in groundwater and
polychlorinated biphenyls (PCBs) in soil within the fenced area of the Site were present at concentrations
exceeding the target risk levels of 105 carcinogenic risk or a Hazard Index of 1 for non-carcinogenic risk
In addition modeling of Site groundwater shows that groundwater flows radially away from the source
area and discharges to the surface in many spring-fed ponds and to the surface on the flanks of the hill
bull Under current conditions contamination from the Site has reached its maximum extent This
groundwater plume consists of both Source Area Groundwater which is defined as groundwater where
total VOC concentrations are greater than or equal to 10 ppm and Non-Source Area Groundwater which
is groundwater containing total VOC concentrations below 10 ppm (USEPA 2002) (see Figure 2-1) A
(0 detailed description of the distribution and extent of groundwater contamination at the Site is provided in
sections 40 and 50 of the RI Report
4 In July 2002 the PRP Group with oversight by USEPA and MEDEP completed a Feasibility Study (FS)
to develop and evaluate a range of remedial alternatives to address potential risks to human health and the
environment that were identified during the RI for the non-source area groundwater
TISOW WOODARD amp CURRAN 3 September 302003 20564309
NonmdashSource Area Groundwater
Source Atea Groundirater
17mdashAcre George West Property
_bdquoVOCugllppm
0
| n r nA
= Volatile Orgamc Compound _ = Microgram per Liter
= Parts per Million
300 600
FEET
Notes 1 Shaded areas based on Maximum Extent of total VOCs j n e | t h e r D e c e m b e r 1 9 9 9 P r e _ R 0 D o r J u n e 2 0 0 0 Supplemental Sampling Events
2 Source Area Groundwater is defined as groundwater with total VOC concentration equal to or greater than 10000 ugl (10 ppm) Extent of Source Area Groundwater plume inferred east of 2-Acre Fenced Area
3 Non Source Area Groundwater is defined as groundwater with total VOC concentrations less then 10000 ugl (10ppm)
Figure 2-1 Site Plan Detail
Hows Corner Superfund Site Plymouth Maine
WOODARD ampCURRAN Engineering bull Science Operations
205643wipsite sowu2-1A
0
Soil within the fenced area of the Site that presented a human health risk was excavated during pilot
testing for the FS and disposed of off-site The three remedial alternatives evaluated in the FS (WampC
bull 2002) were
bull No further Action
lt$ bull Limited Action and
bull Hydraulic Containment
$t As stated in Section 40 of the FS the possible presence of a remnant dense non-aqueous phase liquid
(DNAPL) source within the groundwater plume raises the question as to whether or not complete
restoration of the aquifer can be achieved in a reasonable period of time (eg less than 100 years)
Because of the uncertainties associated with the groundwater recharge rate the mass of DNAPL in
^ Source Area Groundwater the fractional organic carbon (foe) in the bedrock and the tetrachloroethene
(PCE) organic carbon partitioning coefficient (Koc) the restoration potential of both Source Area and
^ Non-Source Area Groundwater could not be assessed within a reasonable degree of scientific certainty in
the FS
The Interim ROD for Operable Unit One Non-Source Area Groundwater (USEPA 2002) was completed
in September 2002 The remedy selected in the Interim ROD consisted of
bull Installation of groundwater extraction and treatment system to contain Source Area Groundwater
bull Monitoring of surface water sediments and Non-Source Area Groundwater to measure the
progress of natural attenuation toward meeting Applicable or Relevant and Appropriate
Requirements (ARARs)
^9 bull Residential well monitoring with a public water contingency
bull Institutional Controls to prevent use of both Source and Non-Source Area Groundwater and
( i bull Five-year Reviews
4) Following completion of the FS Report and preparation of the Interim ROD for Operable Unit One
USEPA requested that further site characterization be completed to assist in making a determination
Jsect concerning the feasibility of attaining ARARs within a reasonable time Section 3 of this SOW outlines
the tasks proposed by the PRP Group to address the requirement for additional Site data necessary for a
pound TI evaluation and containment system design
TISOW WOODARD amp CURRAN 5 September 302003 20564309
bull 30 INVESTIGATION TECHNICAL APPROACH
On behalf of the PRP Group Woodard amp Curran (WampC) has developed a proposed SOW in response to
bull USEPAs request for additional field tasks to further refine the cleanup times presented in the 2002
Interim ROD for this site This approach has been designed to evaluate the following additional data
lt9 needs identified by USEPA to refine cleanup times
4t bull Aquifer hydraulic conductivity
bull Aquifer porosity (matrix and bulk) and
H bull Partitioning of contaminants to the bedrock
^ The data from these additional field tasks will also be used by USEPA to define the TI zone for the Final
ROD and assist the PRPs in developing the design for the hydraulic containment system for the Source
j Area Groundwater which is being conducted under the authority of the RD AOC Details regarding
development of the hydraulic containment system will be presented in the Remedial Design Work Plan
The proposed TI SOW is based on information available during its preparation and may be amended
subject to USEPA approval as additional information regarding subsurface conditions becomes available
during the field investigation The following section describes the overall field investigation approach A
comprehensive presentation of each task in the field investigation will be provided in the Sampling and
bull Analysis Plan (SAP) which will be amended following approval of a final scope of work
bull0 31 Investigative Approach
j The work proposed to meet the additional data requirements stated by USEPA consists of the three
primary tasks described below and further outlined as subtasks Brief descriptions of each task are
presented in the subsections that follow
Task 1 - Project Planning
Task 2 - Field Investigation
Task 3 - TI Evaluation and Reporting
WOODARD amp CURRAN 6 September 302003 20564309
311 Task 1 - Project Planning
Project planning is the first task and includes the following five subtasks
bull Finalize the SOW
bull Prepare work plan
bull Revise existing site-specific Quality Assurance Project Plan (QAPP) Sampling and Analysis
Plan (SAP) and Health and Safety Plan (HASP) and
bull Secure subcontractor contracts
bull Mobilize to the Site and establish a field office
In order to finalize the SOW for this TI evaluation it is anticipated that a minimum of one meeting will
occur between the PRP Group USEPA MEDEP and WampC Once the SOW is finalized the QAPP
SAP and HASP (the Plans) will be revised to incorporate necessary modifications to reflect the agreed-
upon work methods and technology The SAP will be modified to include a detailed plan for the
additional field activities Once the Plans have been revised and the Work Plan prepared they will be
submitted to USEPA for review USEPA comments will be incorporated into the plans and final
approved plans will be issued
After final plans have been issued WampC will negotiate contracts with subcontractors for certain field
activities including boring and monitoring well installation geophysical survey packer testing and
investigation-derived waste (IDW) storage and disposal It is anticipated that a second meeting between
the parties may be needed prior to the commencement of the field activities
Because of the duration of the field activities described in this SOW and the need for on-site evaluation of
field results in order to make program decisions during the investigation WampC will mobilize a trailer to
the Site to serve as a field office The trailer will be equipped with telephone and fax machine
312 Task 2 - Field Investigation
The field investigation task will include the following subtasks
bull Subtask 1 - Boring installation
bull Subtask 2 - Borehole geophysics
TISOW
WOODARDampCURRAN 7 September 302003 20564309
0
0 bull Subtask 3 - Packer testing
bull Subtask 4 - Sampling and analysis
bull bull Subtask 5 - Monitoring well installation
bull Subtask 5 - Pumping test and
bull Subtask 6 - Tracer test
Each of the subtasks is summarized below however a comprehensive discussion of these subtasks and
associated methodologies will be provided in the SAP
Subtask 1 - Boring Installation
j Information obtained during the installation of the new borings will be used in the evaluation of the
aquifer hydraulic conductivity and the analysis of other aquifer properties (eg porosity fracture
frequency) For this subtask it is anticipated that one angled boring will be completed to a depth of 150
feet (ft) below ground surface (bgs) One additional angled boring and four new vertical bedrock borings
will be completed to depths of approximately 100 ft bgs This depth is consistent with the depth
evaluated in the RI and will allow evaluation of bedrock and groundwater properties to depths below the
transition from less competent to more competent bedrock (approximately 50 to 80 ft bgs)
m One additional vertical boring will be installed to a depth of 100 ft bgs as the pumping well location for
bull the pumping test The pumping well location will be based on the results of field work conducted prior to
its installation The proposed drilling program is designed to enhance understanding of the flow system
by aligning new boring locations with existing wells to characterize hydraulic properties of the fracture
network and bulk bedrock Furthermore the program allows for additional characterization of
M contamination in the Source Area groundwater The rationale for the boring locations is summarized in
Table 3-1 and the proposed locations of the borings are depicted on Figure 3-1 Actual locations may
M vary depending on field conditions and accessibility
jlt The drilling protocol employed during installation of both the angled and the vertical wells will allow for
evaluation of the potential presence of DNAPL in the rock and the need for modifications to the drilling
method if DNAPL is detected If sheen or product is observed in the return water core or cuttings from a
boring an interface probe may be employed to determine whether a NAPL is present in the boring
Based on the presence of DNAPL the boring may be terminated at a shallower depth than planned the
J TISOW 4 1 WOODARD amp CURRAN 8 September 302003
20564309
location may be abandoned or other practices may be employed to reduce the potential for causing
downward migration of DNAPL The protocol will be described in the Work Plan and the SAP
Angled Borings Two angled borings will be installed using air-hammer drilling methods The first
angled boring (AW-201) will be installed to a depth of 150 ft bgs in the vicinity of existing well MWshy
106 northeast of and outside of the source area and within the dissolved phase groundwater plume This
well will be angled from the surface toward the southeast at depth in order to intersect as many northwest-
dipping near-vertical fractures as possible The angle of this boring will be approximately 30deg to 40deg
from the vertical resulting in a surface projection of approximately 84 to 126 ft and total length of
approximately 173 to 195 ft The second angled boring (AW-202) will be installed to a depth of 100 ft
bgs in the vicinity of the existing MW-2 well cluster within the source area This well also will be angled
from the surface toward the southeast at depth in order to intersect near-vertical fractures The angle of
this boring will be approximately 30deg to 40deg from the vertical resulting in a surface projection of
approximately 58 to 84 ft and total length of approximately 115 to 130 ft
m
4
sect
i
TISOW WOODARD amp CURRAN 9 September 302003 20564309
Table 3-1
Rationale for Proposed Well Locations
Hows Corner Technical Impracticability Evaluation and Field work for Hydraulic Containment System Design
Well Identification
AW-201
AW-202
MW-203
MW-204
MW-205
MW-206
PW-207
Boring Orientation
Angled
Angled
Vertical
Vertical
Vertical
Vertical
Vertical
Minimum Boring Diameter (inches)
4
4
4
4
4
4
6
Drilling Method
Air Hammer
Air Hammer
Coring
Air Hammer
Air Hammer
Air Hammer
Core Air Hammer Over -drilling
Source Area Non-Source Area
Non-Source Area
Source Area
Non-Source Area
Non-Source Area
Source Area
Source Area
Source Area
Rationale for Boring
bull Intercept near-vertical fractures to understand subsurface geology bull Aid in iting MW-203 bull Intercept near-vertical fractures to understand subsurface geology bull Aid in siting PW-201 (Pumping well) bull ion of contamination bull 1 future monitoring location bull Potential reinjection well for hydraulic containment system bull Core for matrix diffusion evaluation bullbullbullbull Ibullbullbullbull 1bullbullbullbull 1bullbull bull 1
tion point for pumping test tion point in tracer test ion of contamination
future monitoring location tion point for pumping test tion point in tracer test ion of contamination
future monitoring location tion point for pumping test tion point in tracer test ion of contamination
future monitoring location tion point for pumping test
test well extraction well
bull Core for matrix diffusion evaluation bull i point for tracer test
TISOW September 30 2003 WOODARD amp CURRAN 20564309
MW-105D MW-5B
Primary Bedding Secondary Cleavage
Tertsry Fracturing
NOTE A total of 60 observations warn made rtrtjs roprtraont tticopy number of obsafvatk noted wtthln each azimutha) segment
MW-1 1 3D euro MW-205
2 AcreSource
Fenced-^ Area i
MW-103D MW-103S
17-Acre Property Boundary
MW-104D MW-1041 bull
MW-104S
Legend Figure 3-1 J Proposed Monitoring Well Proposed Well Locations
o- Site Property Boundary bull^bullProposed Pumping Well Hows Corner Superfund Site -xmdashx- Source Area Plymouth Maine
^ ^Proposed Angled Well bullamp Existing Monitoring Well bullWDODARDampCURRAN
Englnoortng bull Science bull Operations 205643wipsite-8OlaquoAx-opt-1-2-u3-1D
bull During the installation of each angled boring observations will be made regarding water gainloss
drilling rate and bit behavior to assess the depth of potential fractures In addition water levels will be
9 measured in nearby borings using either hand measurements data loggers or both to evaluate
connectivity between locations A change in water level in a nearby boring will indicate a hydraulic
at connection between the borings Borehole geophysics will also be performed on the borings (See Subtask
2 below) Information from each angled boring will be used to site an adjacent vertical well (MW-203
^ and PW-207) so that it intercepts a fracture observed in the angled boring
^ Vertical Borings Two of the vertical borings will be completed with rotary diamond coring to
approximately 100 ft bgs These borings will be adjacent to the angled borings described above One of
^ the cored borings (MW-203) will be located near MW-106 outside of the source area within the
dissolved-phase groundwater plume (see Figure 3-1) The other cored boring (PW-207) will be the
pumping well which is anticipated to be located within the source area in the vicinity of the existing
MW-2 well cluster Coring will allow data collection for several purposes including direct observation
of bedrock for determination of the nature of the rock matrix determination of the location and nature of
fractures and the degree of fracturing comparison with geophysical logs (Subtask 2) to verify
interpretation of the logs and collection of core samples for analysis (Subtask 4)
The remaining borings will be located east of the 2-acre fenced area within or near the periphery of the
source area and will be sited to align approximately with existing wells based on the known fracture
orientations at the Site (MW-204 and MW-205) or with new wells based on the known fracture
pound orientations at the Site (MW-206) Data from these locations in conjunction with the other borings
installed as part of this TI SOW and the existing wells will be used in the interpretation of the pumping
^ test (Subtask 6) and tracer test (Subtask 7) In addition these three borings will further delineate
contamination and provide potential monitoring locations for long-term monitoring Each of these
^ borings will be advanced to approximately 100 ft bgs with a minimum four-inch diameter air hammer
^ During the installation of each boring observations will be made regarding water gainloss drilling rate
and bit behavior to assess the depth of potential fractures In addition water levels will be measured in
nearby borings using either hand measurements data loggers or both to evaluate connectivity between
locations A change in water level in a nearby boring will indicate a hydraulic connection between the
TISOW WOODARD amp CURRAN 12 September 302003 20564309
borings Borehole geophysics and packer testing will also be performed on the borings (See Subtasks 2
and 3 below)
Drilling water will be containerized on site and treated through granular activated carbon (GAC) Treated
water will be analyzed to verify that PCB and VOC concentrations have been reduced to below ARARs
prior to discharge to the ground surface Cuttings will be spread on the ground surface at the site
consistent with the Remedial Investigation work plan
It is anticipated that up to 10 core samples from each cored boring (total of 20 cores) will be collected and
submitted to an off-site laboratory for analyses of porosity (matrix and bulk) permeability bulk density
and fraction of organic carbon (f^) using methods described in Subtask 4
Subtask 2 - Borehole Geophysics
To supplement information on fracture location and connectivity obtained during boring advancement a
borehole geophysical survey will be conducted on the newly installed bedrock borings to evaluate the
nature and orientation of water bearing fractures in the borings The survey will be performed at the
completion of the angled borings and again at the completion of the vertical borings The information
obtained during the survey may be used to identify the location of subsequent boring(s) by refining the
understanding of the depth aperture and orientation of bedrock fractures The following measurements
are proposed for the new borings caliper fluid temperature fluid resistivity and acoustic televiewer
(ATV) Single-point resistively and 16 inch normal measurements will also be made in the first two
borings installed and the data will be compared to data from the other geophysical logs to determine if
the measurements confirm and significantly improve the interpretation regarding the presence of water-
bearing fractures If the measurements are applicable to identification of fractures they may be included
in lieu of other geophysical logs in the remainder of the borings
Subtask 3 - Packer Testing
To further refine information on the aquifer hydraulic conductivity the hydraulic connection between
fractures in the borings will be evaluated during packer testing of vertical borings The data will be used
to estimate the hydraulic conductivity of specific fractures and fracture zones The packer testing will be
performed after the vertical borings have been installed and the borehole geophysical survey completed
TISOW WOODARD amp CURRAN 13 September 30 2003 20564309
bull
m
M
Drilling observations and information from borehole geophysics will be used to identify specific fractures
below the water table that are capable of transmitting water Prior to water injection for hydraulic
conductivity and fracture connectivity testing groundwater samples will be collected at selected intervals
for analysis of VOCs (See Subtask 4) Sampling intervals will be selected based on drilling observations
and logging results that indicate water is moving into or out of the borehole or that fractures exist to
promote water movement such as rapid increase in the amount of water returned rapid change in
temperature or highly fractured interval
^
^
bull
f$
Double packer testing will be performed at selected intervals within each newly installed boring It is
anticipated that up to six intervals per well will be tested for a maximum of 24 intervals and that for each
interval the test will include an approximate 15-minute injection of potable water at four progressively
increasing pressures Packer spacing is anticipated to be 10 ft however spacing may vary so that packers
are not located in potential fracture zones identified using information from rock cores drilling
observations and borehole geophysics The tests at an individual interval will be terminated if it appears
that the interval is not accepting water Care will be taken to minimize over-pumping or over-
pressurizing of the fractures The flow rate will be measured to evaluate the characteristics of the
fracture Water levels in adjacent borings will be measured during the packer testing to determine if a
hydraulic connection exists between the borings Water generated during packer testing will be
containerized on site and treated through GAC Treated water will be analyzed to verify that PCB and
VOC concentrations have been reduced to below ARARs prior to discharge to the ground surface
4 Subtask 4 Sampling and Analysis
~d
^
Rock and groundwater samples will be collected during the field program for laboratory analysis The
results of the analyses will be used to help refine the distribution of the plume and to estimate bedrock
properties These analyses will be used in conjunction with existing data during the TI evaluation to
refine cleanup times and establish the limits of the TI zone
As described in Subtask 1 it is anticipated that up to 10 core samples from each cored boring (total of 20
core samples) will be collected and submitted to an off-site laboratory for analyses of porosity (matrix and
bulk) permeability bulk density and fraction of organic carbon (f^) using existing industry methods
Subject to further evaluation of industry methods Woodard amp Curran proposes that porosity
TISOW WOODARD amp CURRAN20564309
14 September 302003
permeability and density will be measured using methods in the American Petroleum Institutes API RPshy
40 Fraction of organic carbon (f^) will be measured using either the LECO TOC method or Walkey-
Black method The LECO TOC method is a standard method in the petroleum industry and involves the
direct combustion of a ground rock sample The Walkey-Black method is a commonly used USEPA-
approved chemical oxidation method for determination of foe in soils In addition either method could be
used if a sample were scraped from a fracture surface To develop a reasonable range of f for Site
bedrock up to five samples will be selected from each boring from the unfractured matrix and up to five
from the fracture surfaces In addition Woodard amp Curran will evaluate the appropriateness of selecting
rock samples from a subset of the core samples from areas near fractures as well as from non-fractured
areas and submitting the samples for VOC analysis following methanol extraction
Results from these analyses will be used in conjunction with groundwater contaminant concentrations to
evaluate the significance of diffusion of contamination from the bedrock matrix in both the Source Area
and the Non-Source Area Although matrix diffusion likely is a significant factor in the determination of
cleanup times within the Source Area the potential applicability of matrix diffusion in the Non-Source
Area is not known These core analyses may provide evidence to assist in developing an estimate
through calculations of the effect of matrix diffusion on cleanup times
As noted in Subtask 3 prior to injection of water during packer testing groundwater samples will be
collected at selected intervals for analysis of volatile organic compounds (VOCs) Up to a total of 20
groundwater samples plus appropriate quality control samples will be collected from the newly installed
borings The samples will be submitted to an off-site laboratory for analysis Analytical results will be
validated in accordance with USEPA protocol and the data will be managed in WampCs existing
groundwater sampling analytical database for this site
Up to 21 existing monitoring wells from within or nearby the 17-acre property plus four new wells once
constructed will be sampled using low-flow techniques and submitted to an off-site laboratory for VOC
analysis Analytical results will be validated in accordance with USEPA protocol and the data will be
managed in WampCs existing groundwater sampling analytical database for this site
TISOW WOODARD amp CURRAN 15 September 302003 20564309
Subtask 5 - Monitoring Well Installation
Although it is anticipated that the newly installed borings will be left as open holes for tracer testing and
for pumping tests monitoring wells will be installed and developed in the newly installed borings unless
the USEPA MEDEP and PRP Group determine that the location is inappropriate for such use The
monitoring wells will be constructed of two-inch schedule 40 PVC screen and riser Screen intervals will
be selected based on the location of fractures identified during drilling geophysical logging and packer
testing A sand pack will be placed around the screen and will extend from approximately two ft below
the screen to approximately two ft above the screen
Subtask 6 - Pumping Test
WampC will conduct a single constant discharge pumping test to evaluate hydraulic properties of the
aquifer It is anticipated that the test will be conducted in a new pumping well in the vicinity of the
existing MW-2 well cluster within the source area Data from the pumping test will be used in
conjunction with other data from the investigation to improve the understanding of groundwater
movement and contaminant transport in the Source and Non-Source areas The results of the pumping
test will be used to refine the Site conceptual model as well as in the design of the hydraulic containment
system that is being constructed under the authority of the AOC for the RD
The groundwater pumping test will include the following components (1) Pumping test setup (2) Pretest
monitoring (3) Constant Discharge Pumping Test (4) Post-test monitoring and (5) Data Analysis
Pumping Test Setup In support of the groundwater pumping test WampC will install a pumping well
(PW-207) and procure and install the required groundwater extraction treatment and storage equipment at
the Site The well will be cored and over drilled to allow construction of a 4-inch well The location will
be in the vicinity of the MW-2 well cluster and be based upon results of the angled bedrock boring AWshy
202 The equipment will include but not be limited to
bull Down well pump plumbing and appurtances
bull Two (2) 20000 frac tanks
bull Groundwater transfer pumps and controls
bull Settlingaerationsand filtration treatment processes for the treatment of inorganics (if needed) and
nsow WOODARD amp CURRAN 16 September 302003 20564309
bull Granular activated carbon units for the treatment of dissolved organics in the groundwater
The groundwater treatment process will include the following processes 1) an oxidation and filtration
step to remove the inorganics from the groundwater and GAC units to treat the organic contaminants in
the extracted groundwater
Pretest Monitoring Prior to initiation of pumping WampC will monitor water levels in existing wells and
newly installed borings adjacent to the pumping well using a combination of hand measurements and data
loggers to develop an understanding of the piezometric surface under unstressed conditions The wells
proposed for water-level monitoring will be described in the work plan In addition all gauges
transducers flow meters and other equipment used in conducting the pumping tests shall be calibrated
before use
Constant Discharge Pumping Test The pumping test will be conducted in the source area using
newly-installed pumping well PW-207 It is anticipated that the test will be conducted at a pumping rate
of approximately 2 gallons per minute (gpm) for a period of 2 to 3 days however a higher or lower rate
may be shown to be appropriate based on the drilling and packer testing conducted during boring
installation Woodard amp Curran proposes to conduct this test using a vacuum-enhanced recovery system
(VERS) as described in the ROD so that the water level is not lowered appreciably in the vicinity of the
pumping well to prevent the potential migration of NAPLs to deeper bedrock zones The appropriateness
and feasibility of the VERS for the pumping test will be determined by field testing or literature
evaluation prior to completion of the Work Plan Because of the short duration of this test it is not
anticipated that stability of water levels will be reached in observation wells The test will however
provide information to estimate hydraulic conductivity and bedrock storage During the test the water
levels in the pumping well and selected monitoring wells will be logged continuously via down well data
loggers It is anticipated that water levels in approximately 24 wells will be measured using hand
measurements and data loggers
Groundwater extracted during the pumping test will be stored temporarily in an on-site frac tank prior to
on-site treatment and disposal
TISOW WOODARD amp CURRAN 17 September 302003 20564309
Post-Test Monitoring After the pump is turned off in the pumping well water levels will continue to be
monitored using hand measurements and data loggers until they have returned to within 10 of the preshy
test levels For planning purposes this has been estimated to be two weeks
Data Analysis Data collected during the pumping test will be analyzed with Aquifer Win32 Results of
the pumping test will be summarized in the summary data package for the TI Evaluation and the results
will also be used in the design of the hydraulic containment system specified in the Interim ROD that is
being conducted under the authority of the AOC for the RD Detail regarding use of the pumping test
data in hydraulic system design will be provided in the Remedial Design Work Plan
Subtask 7 - Tracer Test
WampC will conduct a tracer test using a conservative tracer to evaluate fracture connectivity porosity
dispersivity and matrix diffusion of the bedrock aquifer in both the Source Area and Non-Source Area
To increase the potential for success of this test results of the pumping test evaluation will be used to
revise the tracer test plan proposed here as necessary Following rebound of water levels after
completion of the pumping test WampC will initiate a single natural gradient tracer test The test will
consist of injecting a tracer into well PW-207 in the source area (Figure 3-1) for up to five days and
monitoring the tracers arrival in nearby wells Borehole geophysics core evaluation and packer testing
will be used to select the specific injection depth(s) in the well
A Tracer Test Work Plan will be completed prior to initiation of injection to determine the type quantity
and concentration of tracer based on the distance between the injection well and the monitoring wells A
conservative tracer that is one that is not preferentially adsorbed to rock or organic matter will be
selected for the tracer test Tracer injection equipment including tanks and flow-regulating and metering
equipment and pumps will be used to mix the tracer at the surface prior to injection Fractures may be
packered in the injection well and tracer solution will be injected at a rate determined during preparation
of the Tracer Test Work Plan During injection the potentiometric surface of the aquifer will be
monitored to verify that the potentiometric surface remains relatively constant during the injection
process
nsow WOODARD amp CURRAN 18 September 302003 20564309
Prior to injection of the tracer background concentration will be established by collecting samples from
up to six wells in the area of the tracer test and analyzing them for the tracer using an appropriate
analytical method Following injection of the tracer solutions the concentration of the tracer in
downgradient wells and borings will be measured A monitoring network will be established using nearby
monitoring wells Downhole probes will be installed in six new and existing wells near the injection well
to be identified in the work plan first to determine the background tracer concentrations and then to
monitor for the presence of the tracer upon initiation of the test Measurements will be collected at
periodic intervals to be determined based on the results of packer testing If an increase in tracer
concentration is detected or at a minimum on a weekly basis a water sample will be collected using low
flow sampling methodologies and analyzed in an off-site laboratory to evaluate the concentration of the
tracer The concentration of the tracer will be recorded Monitoring of the tracer concentration will
continue throughout the duration of the test The tracer will be allowed to flow with groundwater for one
month or until detected in wells in the vicinity of MW-106 whichever is shorter
313 Task 3 - TI Evaluation and Reporting
The TI Evaluation and reporting task includes the following five subtasks
bull Data evaluation
bull Summary data package
bull Draft TI Evaluation
bull Meetings with PRP Group and USEPA and
bull Revise and finalize TI Evaluation
As the subtasks of the field investigation are completed the data will be evaluated for the purpose of
addressing the data gaps identified by USEPA Specifically the data will be used to further refine the
cleanup times for non-source area groundwater presented in the Interim ROD
The data obtained during the field investigation will be reduced and evaluated and a summary data
package will be prepared that will include a discussion of the field activities completed and presentation
of the data It is anticipated that up to two meetings with USEPA will be necessary before the data
evaluation and summary report are completed
TISOW WOODARDampCURRAN 19 September 302003 20564309
Data collected during the pumping test will be analyzed with Aquifer Win32 Results will be summarized
in the summary data package and will also be presented as part of the RD submittals
Following submittal of the summary data package the TI evaluation will be prepared In accordance with
EPA guidance (1993) the TI waiver evaluation document will address the following topics
1 Specific ARARS or media cleanup standards for which TI determination is sought This section of the
TI Evaluation will identify the specific contaminants for which the TI determination is sought Based on
information available to date a waiver may be appropriate for pesticides PCBs chlorinated organic
compounds and other site-related contaminants that upon evaluation will not attain ARARs in a
reasonable period of time
2 Spatial area over which the TI waiver will apply The purpose of the additional site investigation
outlined in this SOW is to obtain the data necessary to further refine cleanup times presented in the
Interim ROD to determine what portions of the Site will not be expected to reach ARARs within a
reasonable time Consistent with TI guidance (USEPA 1993) the TI evaluation will specify the
horizontal and vertical extent of the area for which TI determination is sought Groundwater
concentration data from the RI and the TI SOW will be used to refine the distribution of the plume Data
from the drilling geophysical logging packer testing and pumping and tracer tests will be used to refine
the Site conceptual model and the cleanup times that will serve as the basis for establishing the scope and
nature of the TI zone
3 Conceptual Model The conceptual model forms the technical core of the TI Waiver Evaluation since
it provides basis for understanding of the restoration potential of the site The conceptual model outlines
the physical and hydrogeological constraints that hinder remediation or removal of Site contaminants and
it is the extent of these constraints rather than restoration timeframe alone that USEPA will use to
evaluate the necessity of the TI waiver of ARARs The conceptual model is the link between restoration
potential and restoration timeframe since it explains why proposed technologies are unlikely to work
either at all or within the desired 100-year timeframe
The Site conceptual model is not a mathematical model however as the result of the extensive modeling
and investigations of the site WampC has a strong understanding of the complex bedrock and overburden
TISOW WOODARDampCURRAN 20 September 302003 20564309
groundwater system beneath this site This understanding has been presented previously in both the RI
report and the FS and will be refined based on the TI SOW as necessary and summarized in the TI
Waiver Evaluation with specific attention to the physical and hydrogeological constraints on remediation
In particular the Site conceptual model will be reviewed in light of the new geologic data from drilling
logging and packer testing and the new hydrogeologic data obtained from the pumping test and tracer test
and will be revised to incorporate the new understanding
4 An evaluation of the restoration potential of the site This section will consist of a several components
It will present a systematic review of the technologies potentially capable of remediating the site given
the physical and hydrogeological constraints identified in the site model The newly acquired data will
provide an improved understanding of bedrock hydraulic properties that will allow a more Site-specific
evaluation of technologies The review of technologies will also include review of innovative
technologies and will evaluate whether existing remedial technologies or strategies would be capable of
achieving groundwater restoration at the site in a reasonable timeframe The section reference the FS and
will summarize the alternative remedies considered in the FS focusing on the ability of each to restore
groundwater in a reasonable timeframe It will also include a discussion of the selected hydraulic
containment system in light of the data gathered from the pumping test conducted in conjunction with the
TI SOW
Based on the Batch Flushing Model and using the agreed upon koc data from the RI as well as data from
this TI SOW including the f data collected as part of Subtask 4 a restoration timeframe analysis will be
conducted Following completion of the timeframe analysis and consideration of the results of drilling
rock and water analyses and pumping and tracer test a determination will be made regarding the Source
Area and the portion of the Non-Source Area VOC plume that will not attain ARARs in a reasonable
time
TISOW WOODARD amp CURRAN 21 September 302003 20564309
40 SCHEDULE
A proposed project schedule is included with this plan as Figure 4-1 This schedule is included for
discussion purposes and will be modified as necessary once the final scope of work as been approved by
all parties and the field work activities are coordinated with the subcontractors
TISOW WOODARD amp CURRAN 22 September 302003 20564309
ID
2
3
4
5
6
7 a i 10
11
12
13
14
15
16
17
16
19
20
21
22
24
25
26
27
26
29
30
31
32
Task Name
Project Meeting with EPA
Finalize SOW
Prepare Work Plans QAPP HASP Revision
Submit Work Plans for EPA Approval
Project Meeting with EPA
Revisions to work plans
Submit final work plans
Subcontractor Contracts
Project Meeting wEPA
Field Investigation
Site Mobilization
Install Borings
Borehole Geophysics
Packer Testing amp Collect GW Samples
Pumping Test
Tracer Test
Test setup
Injection
Monitoring
Data Reporting
InstallDevelop Wells
Data Evaluation
Prepare Data Package
Data Package Submittal to EPA
Draft Tl Evaluation Repon
Draft Tl Evaluation Report Submttal to EPA
EPA ReviewComment on Tl Evaluation ReF
Project Meeting wEPA
Revisions to Tl Evaluation Report
Submit Final Tl Evaluation Report
Start
Wed 070903
Thu 071003
Fri 101003
Mon 120103
Mon 121503
Mon 122903
Mon 011204
Tue 011304
Thu 021904
Fri 032104
Fri 032604
Fri 040204
Fri 041604
Fri 042304
Thu 050604
Wed 060204
Wed 060204
Wed 060904
Wed 060904
Wed 062304
Wed 070704
Wed 042804
Wed 062304
Mon 080204
Mon 070504
Tue 082404
Wed 082504
Wed 091504
Thu 0916AM
Thu 093004
Finish
Wed 070903
Fri 1OtO7u3
Fri 112803
Fri 122603
Mon 121503
Fri 010904
Mon 011204
Mon 012604
Thu 021904
Tue 071304
Thu 040104
Thu 042204
Tue 042704
Wed 050504
Tue 052504
Tue 071304
Tue 060804
Tue 061504
Tue 070604
Tue 071304
Fri 070904
Tue 072004
Fri 073004
Mon 080204
Mon 082304
Tue 082404
Tue 091404
Wed 091504
Wed 082904
Thu 093004
FIGURE 4-1 DRAFT HOWS CORNER SUPERFUND SITE
Tl EVALUATION amp RELD WORK FOR HYDRAUUC CONTAINMENT SYSTEM DESIGN PROPOSED PROJECT SCHEDULE
2003 2004 Mav |
Jun | Jul
ltamp i
Aug
i
Sen Oct I Nov Dec Jan Feb I Mar
ii i i
k ^tr 1
1V i
I t bull ^
I
ta^M bull bull M W
l LgtH^HBKLii LJ Mi
I
bull bull raquo bull laquo^ 0930
Task Progress I^MLHHHI^LB Summary ^^^^^^^^f External Tasks M B WMMM Deadline ^7 Project Hows Comer Schedule6A bull bull bull 1 UData Fri 101003 Split Milestone ^ Project Summary ^f^KKKKKK^^ External Milestone ^
Pagei
50 ACRONYMS
AOC Administrative Order by Consent
ARARs Applicable or Relevant and Appropriate Requirements
ATV acoustic televiewer
bgs below ground surface
CERCLA Comprehensive Environmental Resource and Conservation Liability Act
DNAPL Dense Non-Aqueous Phase Liquid
GAC granular activated carbon
gpm gallons per minute
HASP Health and Safety Plan
row investigation-derived waste
MCL Maximum Containment Level
MEDEP Maine Department of Environmental Protection
MEG Maine Enforcement Guideline
mgkg milligrams per kilogram
Hg kg micrograms per kilogram
NCP National Contingency Plan
PCB polychlorinated biphenyl
PID photo ionization detector
ppm parts per million
PRP Potentially Responsible Party
TISOW WOODARD amp CURRAN 24 September 302003 20564309
QAPP Quality Assurance Project Plan
QAQC Quality AssuranceQuality Control
RA Remedial Action
RAO Remedial Action Objective
RCRA Resource Conservation and Recovery Act
RD Remedial Design
RIFS Remedial InvestigationFeasibility Study
ROD Record of Decision
SAP Sampling and Analysis Plan
SOW Statement of Work
TAL target analyte list
TI Technical Impracticability
USEPA United State Environmental Protection Agency
VOCs volatile organic compounds
WampC Woodard amp Curran Inc
TISOW WOODARD amp CURRAN 25 September 302003 20564309
REFERENCES
Everts CJ RS Kanwar (1994) Evaluation of Rhodamine WT as an adsorbed tracer in an agricultural
soil J Hydrology 153 53-70
Kasnavia T D Vu DA Sabatini (1999) Fluorescent dye and media properties affecting sorption and
tracer selection Groundwater 37 376-381
Ptak T G Schmid (1996) Dual-tracer transport experiments in a physically and chemically
heterogeneous porous aquifer effective transport parameters and spatial variability J Hydrology
183 117-138
Sabatini DA T A Austin (1991) Characteristics of Rhodamine WT and fluorescein as adsorbing
ground-water tracers Ground Water 29 341-349
Trudgill ST (1987) Soil water dye tracing with special reference to the use of Rhodamanie WT
Lissamine FF and Amino G acid Hydrological Processes 1 149-170
US Environmental Protection Agency (USEPA) 1993 Guidance for Evaluating the Technical
Impracticability of Ground-Water Restoration - Interim Final Office of Solid Waste and
Emergency Response Washington DC Directive 92342-25 September 1993
US Environmental Protection Agency (USEPA) 2002 Interim Record of Decision Summary shy
Operable Unit One Non-Source Area Groundwater West SiteHows Corner Superfund Site
Plymouth Maine EPA Region 1 September 2002
US Environmental Protection Agency (USEPA) 2003 Proposed Scope of Work West SiteHows
Corner Superfund Site Plymouth Maine EPA Region 1 4 pages September 2002
Vasudevan D RL Fimmen AB Francisco (2001) Tracer-grade Rhodamine WT Structure of
constituent isomers and their sorption behavior Environ Sci Technol 35 4089-4096
nsow WOODARD amp CURRAN 26 September 30 2003 20564309
Woodard amp Curran Inc (WampC) 2002 Final Feasibility Study Report - Non-Source Area Groundwater
Hows Comer Superfund Site Plymouth Maine July 2002
TISOW WOODARD amp CURRAN 27 September 302003 20564309
f
m WOODARD amp CURRAN Maine Massachusetts New Hampshire Connecticut Florida Illinois Operational offices across the US 1-800-426-4262 wwwwoodardcurrancom
i
10 INTRODUCTION
The purpose of this scope of work (SOW) is to provide an overview of the tasks proposed in response to
United States Environmental Protection Agency (USEPA) guidance and site-specific requirements for the
Technical Impracticability (TI) Evaluation of the West SiteHows Corner Superfund Site (Site) as well as
an overview of a pumping test to support design of the hydraulic containment system selected in the
Interim Record of Decision (ROD) for the Non Source-Area Groundwater at the Site (USEPA 2002)
Details of the site characterization activities described in this SOW will be provided in the three
subsequent major project-planning documents that will be produced after agreement is reached on scope
and content of the SOW
bull Work Plan
bull Health and Safety Plan (HASP)
bull Quality Assurance Project Plan (QAPP)-Including the Sampling and Analysis Plan
(SAP)
The Site is located in Plymouth Maine as depicted in Figure 1-1 The Potentially Responsible Party
Group (the PRP Group) for the Site has been asked to implement additional site characterization to
address data gaps identified by the USEPA (USEPA 2003) so that a final ROD can be issued for the Site
In addition the data developed from the pumping test described in this SOW will be used to evaluate the
number and spacing of wells for development of the hydraulic containment system design This SOW
specifies the approach proposed by the PRP Group to (1) improve the understanding of groundwater
movement including solute transport in the fractured bedrock aquifer (2) establish the limits of the TI
zone at the Site and (3) provide information that will assist in designing the hydraulic containment
system specified in the Interim ROD
This SOW is organized into four Sections Section 2 presents a brief Site description and history
followed by a discussion of the Site Conceptual Model that was previously developed for the Site based
on existing data Section 3 presents the proposed technical approach to the investigation including
rationale for well locations and investigation techniques as well as a pumping test that will be used to
assist in development of the hydraulic containment system design that will be conducted pursuant to the
authority of the Administrative Order by Consent (AOC) for the Remedial Design (RD) Details
regarding the development of the hydraulic containment system will be presented in the Remedial Design
Work Plan Section 4 presents the overall schedule for implementing this TI SOW including the
pumping test and completing the TI Evaluation Report
TISOW WOODARDampCURRAN 1 September 302003 20564309
I I1 J1 - ^
i i i KA ^$^ c E I I F L Ti M O U T H
C -j--MlI e ^P
I
I Source USGS Topographic 75-minute Series Quadrangles
Plymouth ME 1982 and Dixmont ME 1982 bull MAINR
c Figure 1-1 Quadrangle Location Site Location Map
Hows Corner Superfund Site c Plymouth Maine 4000
WOODARDampCURRAN 99503716risiteloc
I
bull 20 SITE DESCRIPTION AND INVESTIGATION HISTORY
The Site is located in east-central Maine in the town of Plymouth The Site includes a 17-acre parcel of
land owned by George West and is comprised of Operable Unit One (Non-source Area Groundwater) and
the Source Area Groundwater as generally depicted on Figure 2-1 Mr West used a small two-acre
portion of the site to operate a waste oil facility from 1965 to 1980 During investigations conducted by
the Maine Department of Environmental Protection (MEDEP) in the early 1990s a fence was placed
ft around this 2-acre portion of the Site This fenced area is referred to in the RIFS and the Interim ROD as
the Source Area (Figure 2-1) Source Area Groundwater however is defined in the ROD as
d groundwater with total volatile organic compound (VOC) concentration equal to or greater than 10 parts
per million (ppm) and may exist outside the 2-acre fenced area
m From October 1999 to May 2001 the PRP Group with oversight by USEPA and MEDEP conducted a
Remedial Investigation (RI) to determine the nature and extent of contamination to characterize the fate
and transport of contaminants and to assess the potential risks that the contamination poses to both
human health and the environment The findings of the RI show that VOCs in groundwater and
polychlorinated biphenyls (PCBs) in soil within the fenced area of the Site were present at concentrations
exceeding the target risk levels of 105 carcinogenic risk or a Hazard Index of 1 for non-carcinogenic risk
In addition modeling of Site groundwater shows that groundwater flows radially away from the source
area and discharges to the surface in many spring-fed ponds and to the surface on the flanks of the hill
bull Under current conditions contamination from the Site has reached its maximum extent This
groundwater plume consists of both Source Area Groundwater which is defined as groundwater where
total VOC concentrations are greater than or equal to 10 ppm and Non-Source Area Groundwater which
is groundwater containing total VOC concentrations below 10 ppm (USEPA 2002) (see Figure 2-1) A
(0 detailed description of the distribution and extent of groundwater contamination at the Site is provided in
sections 40 and 50 of the RI Report
4 In July 2002 the PRP Group with oversight by USEPA and MEDEP completed a Feasibility Study (FS)
to develop and evaluate a range of remedial alternatives to address potential risks to human health and the
environment that were identified during the RI for the non-source area groundwater
TISOW WOODARD amp CURRAN 3 September 302003 20564309
NonmdashSource Area Groundwater
Source Atea Groundirater
17mdashAcre George West Property
_bdquoVOCugllppm
0
| n r nA
= Volatile Orgamc Compound _ = Microgram per Liter
= Parts per Million
300 600
FEET
Notes 1 Shaded areas based on Maximum Extent of total VOCs j n e | t h e r D e c e m b e r 1 9 9 9 P r e _ R 0 D o r J u n e 2 0 0 0 Supplemental Sampling Events
2 Source Area Groundwater is defined as groundwater with total VOC concentration equal to or greater than 10000 ugl (10 ppm) Extent of Source Area Groundwater plume inferred east of 2-Acre Fenced Area
3 Non Source Area Groundwater is defined as groundwater with total VOC concentrations less then 10000 ugl (10ppm)
Figure 2-1 Site Plan Detail
Hows Corner Superfund Site Plymouth Maine
WOODARD ampCURRAN Engineering bull Science Operations
205643wipsite sowu2-1A
0
Soil within the fenced area of the Site that presented a human health risk was excavated during pilot
testing for the FS and disposed of off-site The three remedial alternatives evaluated in the FS (WampC
bull 2002) were
bull No further Action
lt$ bull Limited Action and
bull Hydraulic Containment
$t As stated in Section 40 of the FS the possible presence of a remnant dense non-aqueous phase liquid
(DNAPL) source within the groundwater plume raises the question as to whether or not complete
restoration of the aquifer can be achieved in a reasonable period of time (eg less than 100 years)
Because of the uncertainties associated with the groundwater recharge rate the mass of DNAPL in
^ Source Area Groundwater the fractional organic carbon (foe) in the bedrock and the tetrachloroethene
(PCE) organic carbon partitioning coefficient (Koc) the restoration potential of both Source Area and
^ Non-Source Area Groundwater could not be assessed within a reasonable degree of scientific certainty in
the FS
The Interim ROD for Operable Unit One Non-Source Area Groundwater (USEPA 2002) was completed
in September 2002 The remedy selected in the Interim ROD consisted of
bull Installation of groundwater extraction and treatment system to contain Source Area Groundwater
bull Monitoring of surface water sediments and Non-Source Area Groundwater to measure the
progress of natural attenuation toward meeting Applicable or Relevant and Appropriate
Requirements (ARARs)
^9 bull Residential well monitoring with a public water contingency
bull Institutional Controls to prevent use of both Source and Non-Source Area Groundwater and
( i bull Five-year Reviews
4) Following completion of the FS Report and preparation of the Interim ROD for Operable Unit One
USEPA requested that further site characterization be completed to assist in making a determination
Jsect concerning the feasibility of attaining ARARs within a reasonable time Section 3 of this SOW outlines
the tasks proposed by the PRP Group to address the requirement for additional Site data necessary for a
pound TI evaluation and containment system design
TISOW WOODARD amp CURRAN 5 September 302003 20564309
bull 30 INVESTIGATION TECHNICAL APPROACH
On behalf of the PRP Group Woodard amp Curran (WampC) has developed a proposed SOW in response to
bull USEPAs request for additional field tasks to further refine the cleanup times presented in the 2002
Interim ROD for this site This approach has been designed to evaluate the following additional data
lt9 needs identified by USEPA to refine cleanup times
4t bull Aquifer hydraulic conductivity
bull Aquifer porosity (matrix and bulk) and
H bull Partitioning of contaminants to the bedrock
^ The data from these additional field tasks will also be used by USEPA to define the TI zone for the Final
ROD and assist the PRPs in developing the design for the hydraulic containment system for the Source
j Area Groundwater which is being conducted under the authority of the RD AOC Details regarding
development of the hydraulic containment system will be presented in the Remedial Design Work Plan
The proposed TI SOW is based on information available during its preparation and may be amended
subject to USEPA approval as additional information regarding subsurface conditions becomes available
during the field investigation The following section describes the overall field investigation approach A
comprehensive presentation of each task in the field investigation will be provided in the Sampling and
bull Analysis Plan (SAP) which will be amended following approval of a final scope of work
bull0 31 Investigative Approach
j The work proposed to meet the additional data requirements stated by USEPA consists of the three
primary tasks described below and further outlined as subtasks Brief descriptions of each task are
presented in the subsections that follow
Task 1 - Project Planning
Task 2 - Field Investigation
Task 3 - TI Evaluation and Reporting
WOODARD amp CURRAN 6 September 302003 20564309
311 Task 1 - Project Planning
Project planning is the first task and includes the following five subtasks
bull Finalize the SOW
bull Prepare work plan
bull Revise existing site-specific Quality Assurance Project Plan (QAPP) Sampling and Analysis
Plan (SAP) and Health and Safety Plan (HASP) and
bull Secure subcontractor contracts
bull Mobilize to the Site and establish a field office
In order to finalize the SOW for this TI evaluation it is anticipated that a minimum of one meeting will
occur between the PRP Group USEPA MEDEP and WampC Once the SOW is finalized the QAPP
SAP and HASP (the Plans) will be revised to incorporate necessary modifications to reflect the agreed-
upon work methods and technology The SAP will be modified to include a detailed plan for the
additional field activities Once the Plans have been revised and the Work Plan prepared they will be
submitted to USEPA for review USEPA comments will be incorporated into the plans and final
approved plans will be issued
After final plans have been issued WampC will negotiate contracts with subcontractors for certain field
activities including boring and monitoring well installation geophysical survey packer testing and
investigation-derived waste (IDW) storage and disposal It is anticipated that a second meeting between
the parties may be needed prior to the commencement of the field activities
Because of the duration of the field activities described in this SOW and the need for on-site evaluation of
field results in order to make program decisions during the investigation WampC will mobilize a trailer to
the Site to serve as a field office The trailer will be equipped with telephone and fax machine
312 Task 2 - Field Investigation
The field investigation task will include the following subtasks
bull Subtask 1 - Boring installation
bull Subtask 2 - Borehole geophysics
TISOW
WOODARDampCURRAN 7 September 302003 20564309
0
0 bull Subtask 3 - Packer testing
bull Subtask 4 - Sampling and analysis
bull bull Subtask 5 - Monitoring well installation
bull Subtask 5 - Pumping test and
bull Subtask 6 - Tracer test
Each of the subtasks is summarized below however a comprehensive discussion of these subtasks and
associated methodologies will be provided in the SAP
Subtask 1 - Boring Installation
j Information obtained during the installation of the new borings will be used in the evaluation of the
aquifer hydraulic conductivity and the analysis of other aquifer properties (eg porosity fracture
frequency) For this subtask it is anticipated that one angled boring will be completed to a depth of 150
feet (ft) below ground surface (bgs) One additional angled boring and four new vertical bedrock borings
will be completed to depths of approximately 100 ft bgs This depth is consistent with the depth
evaluated in the RI and will allow evaluation of bedrock and groundwater properties to depths below the
transition from less competent to more competent bedrock (approximately 50 to 80 ft bgs)
m One additional vertical boring will be installed to a depth of 100 ft bgs as the pumping well location for
bull the pumping test The pumping well location will be based on the results of field work conducted prior to
its installation The proposed drilling program is designed to enhance understanding of the flow system
by aligning new boring locations with existing wells to characterize hydraulic properties of the fracture
network and bulk bedrock Furthermore the program allows for additional characterization of
M contamination in the Source Area groundwater The rationale for the boring locations is summarized in
Table 3-1 and the proposed locations of the borings are depicted on Figure 3-1 Actual locations may
M vary depending on field conditions and accessibility
jlt The drilling protocol employed during installation of both the angled and the vertical wells will allow for
evaluation of the potential presence of DNAPL in the rock and the need for modifications to the drilling
method if DNAPL is detected If sheen or product is observed in the return water core or cuttings from a
boring an interface probe may be employed to determine whether a NAPL is present in the boring
Based on the presence of DNAPL the boring may be terminated at a shallower depth than planned the
J TISOW 4 1 WOODARD amp CURRAN 8 September 302003
20564309
location may be abandoned or other practices may be employed to reduce the potential for causing
downward migration of DNAPL The protocol will be described in the Work Plan and the SAP
Angled Borings Two angled borings will be installed using air-hammer drilling methods The first
angled boring (AW-201) will be installed to a depth of 150 ft bgs in the vicinity of existing well MWshy
106 northeast of and outside of the source area and within the dissolved phase groundwater plume This
well will be angled from the surface toward the southeast at depth in order to intersect as many northwest-
dipping near-vertical fractures as possible The angle of this boring will be approximately 30deg to 40deg
from the vertical resulting in a surface projection of approximately 84 to 126 ft and total length of
approximately 173 to 195 ft The second angled boring (AW-202) will be installed to a depth of 100 ft
bgs in the vicinity of the existing MW-2 well cluster within the source area This well also will be angled
from the surface toward the southeast at depth in order to intersect near-vertical fractures The angle of
this boring will be approximately 30deg to 40deg from the vertical resulting in a surface projection of
approximately 58 to 84 ft and total length of approximately 115 to 130 ft
m
4
sect
i
TISOW WOODARD amp CURRAN 9 September 302003 20564309
Table 3-1
Rationale for Proposed Well Locations
Hows Corner Technical Impracticability Evaluation and Field work for Hydraulic Containment System Design
Well Identification
AW-201
AW-202
MW-203
MW-204
MW-205
MW-206
PW-207
Boring Orientation
Angled
Angled
Vertical
Vertical
Vertical
Vertical
Vertical
Minimum Boring Diameter (inches)
4
4
4
4
4
4
6
Drilling Method
Air Hammer
Air Hammer
Coring
Air Hammer
Air Hammer
Air Hammer
Core Air Hammer Over -drilling
Source Area Non-Source Area
Non-Source Area
Source Area
Non-Source Area
Non-Source Area
Source Area
Source Area
Source Area
Rationale for Boring
bull Intercept near-vertical fractures to understand subsurface geology bull Aid in iting MW-203 bull Intercept near-vertical fractures to understand subsurface geology bull Aid in siting PW-201 (Pumping well) bull ion of contamination bull 1 future monitoring location bull Potential reinjection well for hydraulic containment system bull Core for matrix diffusion evaluation bullbullbullbull Ibullbullbullbull 1bullbullbullbull 1bullbull bull 1
tion point for pumping test tion point in tracer test ion of contamination
future monitoring location tion point for pumping test tion point in tracer test ion of contamination
future monitoring location tion point for pumping test tion point in tracer test ion of contamination
future monitoring location tion point for pumping test
test well extraction well
bull Core for matrix diffusion evaluation bull i point for tracer test
TISOW September 30 2003 WOODARD amp CURRAN 20564309
MW-105D MW-5B
Primary Bedding Secondary Cleavage
Tertsry Fracturing
NOTE A total of 60 observations warn made rtrtjs roprtraont tticopy number of obsafvatk noted wtthln each azimutha) segment
MW-1 1 3D euro MW-205
2 AcreSource
Fenced-^ Area i
MW-103D MW-103S
17-Acre Property Boundary
MW-104D MW-1041 bull
MW-104S
Legend Figure 3-1 J Proposed Monitoring Well Proposed Well Locations
o- Site Property Boundary bull^bullProposed Pumping Well Hows Corner Superfund Site -xmdashx- Source Area Plymouth Maine
^ ^Proposed Angled Well bullamp Existing Monitoring Well bullWDODARDampCURRAN
Englnoortng bull Science bull Operations 205643wipsite-8OlaquoAx-opt-1-2-u3-1D
bull During the installation of each angled boring observations will be made regarding water gainloss
drilling rate and bit behavior to assess the depth of potential fractures In addition water levels will be
9 measured in nearby borings using either hand measurements data loggers or both to evaluate
connectivity between locations A change in water level in a nearby boring will indicate a hydraulic
at connection between the borings Borehole geophysics will also be performed on the borings (See Subtask
2 below) Information from each angled boring will be used to site an adjacent vertical well (MW-203
^ and PW-207) so that it intercepts a fracture observed in the angled boring
^ Vertical Borings Two of the vertical borings will be completed with rotary diamond coring to
approximately 100 ft bgs These borings will be adjacent to the angled borings described above One of
^ the cored borings (MW-203) will be located near MW-106 outside of the source area within the
dissolved-phase groundwater plume (see Figure 3-1) The other cored boring (PW-207) will be the
pumping well which is anticipated to be located within the source area in the vicinity of the existing
MW-2 well cluster Coring will allow data collection for several purposes including direct observation
of bedrock for determination of the nature of the rock matrix determination of the location and nature of
fractures and the degree of fracturing comparison with geophysical logs (Subtask 2) to verify
interpretation of the logs and collection of core samples for analysis (Subtask 4)
The remaining borings will be located east of the 2-acre fenced area within or near the periphery of the
source area and will be sited to align approximately with existing wells based on the known fracture
orientations at the Site (MW-204 and MW-205) or with new wells based on the known fracture
pound orientations at the Site (MW-206) Data from these locations in conjunction with the other borings
installed as part of this TI SOW and the existing wells will be used in the interpretation of the pumping
^ test (Subtask 6) and tracer test (Subtask 7) In addition these three borings will further delineate
contamination and provide potential monitoring locations for long-term monitoring Each of these
^ borings will be advanced to approximately 100 ft bgs with a minimum four-inch diameter air hammer
^ During the installation of each boring observations will be made regarding water gainloss drilling rate
and bit behavior to assess the depth of potential fractures In addition water levels will be measured in
nearby borings using either hand measurements data loggers or both to evaluate connectivity between
locations A change in water level in a nearby boring will indicate a hydraulic connection between the
TISOW WOODARD amp CURRAN 12 September 302003 20564309
borings Borehole geophysics and packer testing will also be performed on the borings (See Subtasks 2
and 3 below)
Drilling water will be containerized on site and treated through granular activated carbon (GAC) Treated
water will be analyzed to verify that PCB and VOC concentrations have been reduced to below ARARs
prior to discharge to the ground surface Cuttings will be spread on the ground surface at the site
consistent with the Remedial Investigation work plan
It is anticipated that up to 10 core samples from each cored boring (total of 20 cores) will be collected and
submitted to an off-site laboratory for analyses of porosity (matrix and bulk) permeability bulk density
and fraction of organic carbon (f^) using methods described in Subtask 4
Subtask 2 - Borehole Geophysics
To supplement information on fracture location and connectivity obtained during boring advancement a
borehole geophysical survey will be conducted on the newly installed bedrock borings to evaluate the
nature and orientation of water bearing fractures in the borings The survey will be performed at the
completion of the angled borings and again at the completion of the vertical borings The information
obtained during the survey may be used to identify the location of subsequent boring(s) by refining the
understanding of the depth aperture and orientation of bedrock fractures The following measurements
are proposed for the new borings caliper fluid temperature fluid resistivity and acoustic televiewer
(ATV) Single-point resistively and 16 inch normal measurements will also be made in the first two
borings installed and the data will be compared to data from the other geophysical logs to determine if
the measurements confirm and significantly improve the interpretation regarding the presence of water-
bearing fractures If the measurements are applicable to identification of fractures they may be included
in lieu of other geophysical logs in the remainder of the borings
Subtask 3 - Packer Testing
To further refine information on the aquifer hydraulic conductivity the hydraulic connection between
fractures in the borings will be evaluated during packer testing of vertical borings The data will be used
to estimate the hydraulic conductivity of specific fractures and fracture zones The packer testing will be
performed after the vertical borings have been installed and the borehole geophysical survey completed
TISOW WOODARD amp CURRAN 13 September 30 2003 20564309
bull
m
M
Drilling observations and information from borehole geophysics will be used to identify specific fractures
below the water table that are capable of transmitting water Prior to water injection for hydraulic
conductivity and fracture connectivity testing groundwater samples will be collected at selected intervals
for analysis of VOCs (See Subtask 4) Sampling intervals will be selected based on drilling observations
and logging results that indicate water is moving into or out of the borehole or that fractures exist to
promote water movement such as rapid increase in the amount of water returned rapid change in
temperature or highly fractured interval
^
^
bull
f$
Double packer testing will be performed at selected intervals within each newly installed boring It is
anticipated that up to six intervals per well will be tested for a maximum of 24 intervals and that for each
interval the test will include an approximate 15-minute injection of potable water at four progressively
increasing pressures Packer spacing is anticipated to be 10 ft however spacing may vary so that packers
are not located in potential fracture zones identified using information from rock cores drilling
observations and borehole geophysics The tests at an individual interval will be terminated if it appears
that the interval is not accepting water Care will be taken to minimize over-pumping or over-
pressurizing of the fractures The flow rate will be measured to evaluate the characteristics of the
fracture Water levels in adjacent borings will be measured during the packer testing to determine if a
hydraulic connection exists between the borings Water generated during packer testing will be
containerized on site and treated through GAC Treated water will be analyzed to verify that PCB and
VOC concentrations have been reduced to below ARARs prior to discharge to the ground surface
4 Subtask 4 Sampling and Analysis
~d
^
Rock and groundwater samples will be collected during the field program for laboratory analysis The
results of the analyses will be used to help refine the distribution of the plume and to estimate bedrock
properties These analyses will be used in conjunction with existing data during the TI evaluation to
refine cleanup times and establish the limits of the TI zone
As described in Subtask 1 it is anticipated that up to 10 core samples from each cored boring (total of 20
core samples) will be collected and submitted to an off-site laboratory for analyses of porosity (matrix and
bulk) permeability bulk density and fraction of organic carbon (f^) using existing industry methods
Subject to further evaluation of industry methods Woodard amp Curran proposes that porosity
TISOW WOODARD amp CURRAN20564309
14 September 302003
permeability and density will be measured using methods in the American Petroleum Institutes API RPshy
40 Fraction of organic carbon (f^) will be measured using either the LECO TOC method or Walkey-
Black method The LECO TOC method is a standard method in the petroleum industry and involves the
direct combustion of a ground rock sample The Walkey-Black method is a commonly used USEPA-
approved chemical oxidation method for determination of foe in soils In addition either method could be
used if a sample were scraped from a fracture surface To develop a reasonable range of f for Site
bedrock up to five samples will be selected from each boring from the unfractured matrix and up to five
from the fracture surfaces In addition Woodard amp Curran will evaluate the appropriateness of selecting
rock samples from a subset of the core samples from areas near fractures as well as from non-fractured
areas and submitting the samples for VOC analysis following methanol extraction
Results from these analyses will be used in conjunction with groundwater contaminant concentrations to
evaluate the significance of diffusion of contamination from the bedrock matrix in both the Source Area
and the Non-Source Area Although matrix diffusion likely is a significant factor in the determination of
cleanup times within the Source Area the potential applicability of matrix diffusion in the Non-Source
Area is not known These core analyses may provide evidence to assist in developing an estimate
through calculations of the effect of matrix diffusion on cleanup times
As noted in Subtask 3 prior to injection of water during packer testing groundwater samples will be
collected at selected intervals for analysis of volatile organic compounds (VOCs) Up to a total of 20
groundwater samples plus appropriate quality control samples will be collected from the newly installed
borings The samples will be submitted to an off-site laboratory for analysis Analytical results will be
validated in accordance with USEPA protocol and the data will be managed in WampCs existing
groundwater sampling analytical database for this site
Up to 21 existing monitoring wells from within or nearby the 17-acre property plus four new wells once
constructed will be sampled using low-flow techniques and submitted to an off-site laboratory for VOC
analysis Analytical results will be validated in accordance with USEPA protocol and the data will be
managed in WampCs existing groundwater sampling analytical database for this site
TISOW WOODARD amp CURRAN 15 September 302003 20564309
Subtask 5 - Monitoring Well Installation
Although it is anticipated that the newly installed borings will be left as open holes for tracer testing and
for pumping tests monitoring wells will be installed and developed in the newly installed borings unless
the USEPA MEDEP and PRP Group determine that the location is inappropriate for such use The
monitoring wells will be constructed of two-inch schedule 40 PVC screen and riser Screen intervals will
be selected based on the location of fractures identified during drilling geophysical logging and packer
testing A sand pack will be placed around the screen and will extend from approximately two ft below
the screen to approximately two ft above the screen
Subtask 6 - Pumping Test
WampC will conduct a single constant discharge pumping test to evaluate hydraulic properties of the
aquifer It is anticipated that the test will be conducted in a new pumping well in the vicinity of the
existing MW-2 well cluster within the source area Data from the pumping test will be used in
conjunction with other data from the investigation to improve the understanding of groundwater
movement and contaminant transport in the Source and Non-Source areas The results of the pumping
test will be used to refine the Site conceptual model as well as in the design of the hydraulic containment
system that is being constructed under the authority of the AOC for the RD
The groundwater pumping test will include the following components (1) Pumping test setup (2) Pretest
monitoring (3) Constant Discharge Pumping Test (4) Post-test monitoring and (5) Data Analysis
Pumping Test Setup In support of the groundwater pumping test WampC will install a pumping well
(PW-207) and procure and install the required groundwater extraction treatment and storage equipment at
the Site The well will be cored and over drilled to allow construction of a 4-inch well The location will
be in the vicinity of the MW-2 well cluster and be based upon results of the angled bedrock boring AWshy
202 The equipment will include but not be limited to
bull Down well pump plumbing and appurtances
bull Two (2) 20000 frac tanks
bull Groundwater transfer pumps and controls
bull Settlingaerationsand filtration treatment processes for the treatment of inorganics (if needed) and
nsow WOODARD amp CURRAN 16 September 302003 20564309
bull Granular activated carbon units for the treatment of dissolved organics in the groundwater
The groundwater treatment process will include the following processes 1) an oxidation and filtration
step to remove the inorganics from the groundwater and GAC units to treat the organic contaminants in
the extracted groundwater
Pretest Monitoring Prior to initiation of pumping WampC will monitor water levels in existing wells and
newly installed borings adjacent to the pumping well using a combination of hand measurements and data
loggers to develop an understanding of the piezometric surface under unstressed conditions The wells
proposed for water-level monitoring will be described in the work plan In addition all gauges
transducers flow meters and other equipment used in conducting the pumping tests shall be calibrated
before use
Constant Discharge Pumping Test The pumping test will be conducted in the source area using
newly-installed pumping well PW-207 It is anticipated that the test will be conducted at a pumping rate
of approximately 2 gallons per minute (gpm) for a period of 2 to 3 days however a higher or lower rate
may be shown to be appropriate based on the drilling and packer testing conducted during boring
installation Woodard amp Curran proposes to conduct this test using a vacuum-enhanced recovery system
(VERS) as described in the ROD so that the water level is not lowered appreciably in the vicinity of the
pumping well to prevent the potential migration of NAPLs to deeper bedrock zones The appropriateness
and feasibility of the VERS for the pumping test will be determined by field testing or literature
evaluation prior to completion of the Work Plan Because of the short duration of this test it is not
anticipated that stability of water levels will be reached in observation wells The test will however
provide information to estimate hydraulic conductivity and bedrock storage During the test the water
levels in the pumping well and selected monitoring wells will be logged continuously via down well data
loggers It is anticipated that water levels in approximately 24 wells will be measured using hand
measurements and data loggers
Groundwater extracted during the pumping test will be stored temporarily in an on-site frac tank prior to
on-site treatment and disposal
TISOW WOODARD amp CURRAN 17 September 302003 20564309
Post-Test Monitoring After the pump is turned off in the pumping well water levels will continue to be
monitored using hand measurements and data loggers until they have returned to within 10 of the preshy
test levels For planning purposes this has been estimated to be two weeks
Data Analysis Data collected during the pumping test will be analyzed with Aquifer Win32 Results of
the pumping test will be summarized in the summary data package for the TI Evaluation and the results
will also be used in the design of the hydraulic containment system specified in the Interim ROD that is
being conducted under the authority of the AOC for the RD Detail regarding use of the pumping test
data in hydraulic system design will be provided in the Remedial Design Work Plan
Subtask 7 - Tracer Test
WampC will conduct a tracer test using a conservative tracer to evaluate fracture connectivity porosity
dispersivity and matrix diffusion of the bedrock aquifer in both the Source Area and Non-Source Area
To increase the potential for success of this test results of the pumping test evaluation will be used to
revise the tracer test plan proposed here as necessary Following rebound of water levels after
completion of the pumping test WampC will initiate a single natural gradient tracer test The test will
consist of injecting a tracer into well PW-207 in the source area (Figure 3-1) for up to five days and
monitoring the tracers arrival in nearby wells Borehole geophysics core evaluation and packer testing
will be used to select the specific injection depth(s) in the well
A Tracer Test Work Plan will be completed prior to initiation of injection to determine the type quantity
and concentration of tracer based on the distance between the injection well and the monitoring wells A
conservative tracer that is one that is not preferentially adsorbed to rock or organic matter will be
selected for the tracer test Tracer injection equipment including tanks and flow-regulating and metering
equipment and pumps will be used to mix the tracer at the surface prior to injection Fractures may be
packered in the injection well and tracer solution will be injected at a rate determined during preparation
of the Tracer Test Work Plan During injection the potentiometric surface of the aquifer will be
monitored to verify that the potentiometric surface remains relatively constant during the injection
process
nsow WOODARD amp CURRAN 18 September 302003 20564309
Prior to injection of the tracer background concentration will be established by collecting samples from
up to six wells in the area of the tracer test and analyzing them for the tracer using an appropriate
analytical method Following injection of the tracer solutions the concentration of the tracer in
downgradient wells and borings will be measured A monitoring network will be established using nearby
monitoring wells Downhole probes will be installed in six new and existing wells near the injection well
to be identified in the work plan first to determine the background tracer concentrations and then to
monitor for the presence of the tracer upon initiation of the test Measurements will be collected at
periodic intervals to be determined based on the results of packer testing If an increase in tracer
concentration is detected or at a minimum on a weekly basis a water sample will be collected using low
flow sampling methodologies and analyzed in an off-site laboratory to evaluate the concentration of the
tracer The concentration of the tracer will be recorded Monitoring of the tracer concentration will
continue throughout the duration of the test The tracer will be allowed to flow with groundwater for one
month or until detected in wells in the vicinity of MW-106 whichever is shorter
313 Task 3 - TI Evaluation and Reporting
The TI Evaluation and reporting task includes the following five subtasks
bull Data evaluation
bull Summary data package
bull Draft TI Evaluation
bull Meetings with PRP Group and USEPA and
bull Revise and finalize TI Evaluation
As the subtasks of the field investigation are completed the data will be evaluated for the purpose of
addressing the data gaps identified by USEPA Specifically the data will be used to further refine the
cleanup times for non-source area groundwater presented in the Interim ROD
The data obtained during the field investigation will be reduced and evaluated and a summary data
package will be prepared that will include a discussion of the field activities completed and presentation
of the data It is anticipated that up to two meetings with USEPA will be necessary before the data
evaluation and summary report are completed
TISOW WOODARDampCURRAN 19 September 302003 20564309
Data collected during the pumping test will be analyzed with Aquifer Win32 Results will be summarized
in the summary data package and will also be presented as part of the RD submittals
Following submittal of the summary data package the TI evaluation will be prepared In accordance with
EPA guidance (1993) the TI waiver evaluation document will address the following topics
1 Specific ARARS or media cleanup standards for which TI determination is sought This section of the
TI Evaluation will identify the specific contaminants for which the TI determination is sought Based on
information available to date a waiver may be appropriate for pesticides PCBs chlorinated organic
compounds and other site-related contaminants that upon evaluation will not attain ARARs in a
reasonable period of time
2 Spatial area over which the TI waiver will apply The purpose of the additional site investigation
outlined in this SOW is to obtain the data necessary to further refine cleanup times presented in the
Interim ROD to determine what portions of the Site will not be expected to reach ARARs within a
reasonable time Consistent with TI guidance (USEPA 1993) the TI evaluation will specify the
horizontal and vertical extent of the area for which TI determination is sought Groundwater
concentration data from the RI and the TI SOW will be used to refine the distribution of the plume Data
from the drilling geophysical logging packer testing and pumping and tracer tests will be used to refine
the Site conceptual model and the cleanup times that will serve as the basis for establishing the scope and
nature of the TI zone
3 Conceptual Model The conceptual model forms the technical core of the TI Waiver Evaluation since
it provides basis for understanding of the restoration potential of the site The conceptual model outlines
the physical and hydrogeological constraints that hinder remediation or removal of Site contaminants and
it is the extent of these constraints rather than restoration timeframe alone that USEPA will use to
evaluate the necessity of the TI waiver of ARARs The conceptual model is the link between restoration
potential and restoration timeframe since it explains why proposed technologies are unlikely to work
either at all or within the desired 100-year timeframe
The Site conceptual model is not a mathematical model however as the result of the extensive modeling
and investigations of the site WampC has a strong understanding of the complex bedrock and overburden
TISOW WOODARDampCURRAN 20 September 302003 20564309
groundwater system beneath this site This understanding has been presented previously in both the RI
report and the FS and will be refined based on the TI SOW as necessary and summarized in the TI
Waiver Evaluation with specific attention to the physical and hydrogeological constraints on remediation
In particular the Site conceptual model will be reviewed in light of the new geologic data from drilling
logging and packer testing and the new hydrogeologic data obtained from the pumping test and tracer test
and will be revised to incorporate the new understanding
4 An evaluation of the restoration potential of the site This section will consist of a several components
It will present a systematic review of the technologies potentially capable of remediating the site given
the physical and hydrogeological constraints identified in the site model The newly acquired data will
provide an improved understanding of bedrock hydraulic properties that will allow a more Site-specific
evaluation of technologies The review of technologies will also include review of innovative
technologies and will evaluate whether existing remedial technologies or strategies would be capable of
achieving groundwater restoration at the site in a reasonable timeframe The section reference the FS and
will summarize the alternative remedies considered in the FS focusing on the ability of each to restore
groundwater in a reasonable timeframe It will also include a discussion of the selected hydraulic
containment system in light of the data gathered from the pumping test conducted in conjunction with the
TI SOW
Based on the Batch Flushing Model and using the agreed upon koc data from the RI as well as data from
this TI SOW including the f data collected as part of Subtask 4 a restoration timeframe analysis will be
conducted Following completion of the timeframe analysis and consideration of the results of drilling
rock and water analyses and pumping and tracer test a determination will be made regarding the Source
Area and the portion of the Non-Source Area VOC plume that will not attain ARARs in a reasonable
time
TISOW WOODARD amp CURRAN 21 September 302003 20564309
40 SCHEDULE
A proposed project schedule is included with this plan as Figure 4-1 This schedule is included for
discussion purposes and will be modified as necessary once the final scope of work as been approved by
all parties and the field work activities are coordinated with the subcontractors
TISOW WOODARD amp CURRAN 22 September 302003 20564309
ID
2
3
4
5
6
7 a i 10
11
12
13
14
15
16
17
16
19
20
21
22
24
25
26
27
26
29
30
31
32
Task Name
Project Meeting with EPA
Finalize SOW
Prepare Work Plans QAPP HASP Revision
Submit Work Plans for EPA Approval
Project Meeting with EPA
Revisions to work plans
Submit final work plans
Subcontractor Contracts
Project Meeting wEPA
Field Investigation
Site Mobilization
Install Borings
Borehole Geophysics
Packer Testing amp Collect GW Samples
Pumping Test
Tracer Test
Test setup
Injection
Monitoring
Data Reporting
InstallDevelop Wells
Data Evaluation
Prepare Data Package
Data Package Submittal to EPA
Draft Tl Evaluation Repon
Draft Tl Evaluation Report Submttal to EPA
EPA ReviewComment on Tl Evaluation ReF
Project Meeting wEPA
Revisions to Tl Evaluation Report
Submit Final Tl Evaluation Report
Start
Wed 070903
Thu 071003
Fri 101003
Mon 120103
Mon 121503
Mon 122903
Mon 011204
Tue 011304
Thu 021904
Fri 032104
Fri 032604
Fri 040204
Fri 041604
Fri 042304
Thu 050604
Wed 060204
Wed 060204
Wed 060904
Wed 060904
Wed 062304
Wed 070704
Wed 042804
Wed 062304
Mon 080204
Mon 070504
Tue 082404
Wed 082504
Wed 091504
Thu 0916AM
Thu 093004
Finish
Wed 070903
Fri 1OtO7u3
Fri 112803
Fri 122603
Mon 121503
Fri 010904
Mon 011204
Mon 012604
Thu 021904
Tue 071304
Thu 040104
Thu 042204
Tue 042704
Wed 050504
Tue 052504
Tue 071304
Tue 060804
Tue 061504
Tue 070604
Tue 071304
Fri 070904
Tue 072004
Fri 073004
Mon 080204
Mon 082304
Tue 082404
Tue 091404
Wed 091504
Wed 082904
Thu 093004
FIGURE 4-1 DRAFT HOWS CORNER SUPERFUND SITE
Tl EVALUATION amp RELD WORK FOR HYDRAUUC CONTAINMENT SYSTEM DESIGN PROPOSED PROJECT SCHEDULE
2003 2004 Mav |
Jun | Jul
ltamp i
Aug
i
Sen Oct I Nov Dec Jan Feb I Mar
ii i i
k ^tr 1
1V i
I t bull ^
I
ta^M bull bull M W
l LgtH^HBKLii LJ Mi
I
bull bull raquo bull laquo^ 0930
Task Progress I^MLHHHI^LB Summary ^^^^^^^^f External Tasks M B WMMM Deadline ^7 Project Hows Comer Schedule6A bull bull bull 1 UData Fri 101003 Split Milestone ^ Project Summary ^f^KKKKKK^^ External Milestone ^
Pagei
50 ACRONYMS
AOC Administrative Order by Consent
ARARs Applicable or Relevant and Appropriate Requirements
ATV acoustic televiewer
bgs below ground surface
CERCLA Comprehensive Environmental Resource and Conservation Liability Act
DNAPL Dense Non-Aqueous Phase Liquid
GAC granular activated carbon
gpm gallons per minute
HASP Health and Safety Plan
row investigation-derived waste
MCL Maximum Containment Level
MEDEP Maine Department of Environmental Protection
MEG Maine Enforcement Guideline
mgkg milligrams per kilogram
Hg kg micrograms per kilogram
NCP National Contingency Plan
PCB polychlorinated biphenyl
PID photo ionization detector
ppm parts per million
PRP Potentially Responsible Party
TISOW WOODARD amp CURRAN 24 September 302003 20564309
QAPP Quality Assurance Project Plan
QAQC Quality AssuranceQuality Control
RA Remedial Action
RAO Remedial Action Objective
RCRA Resource Conservation and Recovery Act
RD Remedial Design
RIFS Remedial InvestigationFeasibility Study
ROD Record of Decision
SAP Sampling and Analysis Plan
SOW Statement of Work
TAL target analyte list
TI Technical Impracticability
USEPA United State Environmental Protection Agency
VOCs volatile organic compounds
WampC Woodard amp Curran Inc
TISOW WOODARD amp CURRAN 25 September 302003 20564309
REFERENCES
Everts CJ RS Kanwar (1994) Evaluation of Rhodamine WT as an adsorbed tracer in an agricultural
soil J Hydrology 153 53-70
Kasnavia T D Vu DA Sabatini (1999) Fluorescent dye and media properties affecting sorption and
tracer selection Groundwater 37 376-381
Ptak T G Schmid (1996) Dual-tracer transport experiments in a physically and chemically
heterogeneous porous aquifer effective transport parameters and spatial variability J Hydrology
183 117-138
Sabatini DA T A Austin (1991) Characteristics of Rhodamine WT and fluorescein as adsorbing
ground-water tracers Ground Water 29 341-349
Trudgill ST (1987) Soil water dye tracing with special reference to the use of Rhodamanie WT
Lissamine FF and Amino G acid Hydrological Processes 1 149-170
US Environmental Protection Agency (USEPA) 1993 Guidance for Evaluating the Technical
Impracticability of Ground-Water Restoration - Interim Final Office of Solid Waste and
Emergency Response Washington DC Directive 92342-25 September 1993
US Environmental Protection Agency (USEPA) 2002 Interim Record of Decision Summary shy
Operable Unit One Non-Source Area Groundwater West SiteHows Corner Superfund Site
Plymouth Maine EPA Region 1 September 2002
US Environmental Protection Agency (USEPA) 2003 Proposed Scope of Work West SiteHows
Corner Superfund Site Plymouth Maine EPA Region 1 4 pages September 2002
Vasudevan D RL Fimmen AB Francisco (2001) Tracer-grade Rhodamine WT Structure of
constituent isomers and their sorption behavior Environ Sci Technol 35 4089-4096
nsow WOODARD amp CURRAN 26 September 30 2003 20564309
Woodard amp Curran Inc (WampC) 2002 Final Feasibility Study Report - Non-Source Area Groundwater
Hows Comer Superfund Site Plymouth Maine July 2002
TISOW WOODARD amp CURRAN 27 September 302003 20564309
f
m WOODARD amp CURRAN Maine Massachusetts New Hampshire Connecticut Florida Illinois Operational offices across the US 1-800-426-4262 wwwwoodardcurrancom
i
I I1 J1 - ^
i i i KA ^$^ c E I I F L Ti M O U T H
C -j--MlI e ^P
I
I Source USGS Topographic 75-minute Series Quadrangles
Plymouth ME 1982 and Dixmont ME 1982 bull MAINR
c Figure 1-1 Quadrangle Location Site Location Map
Hows Corner Superfund Site c Plymouth Maine 4000
WOODARDampCURRAN 99503716risiteloc
I
bull 20 SITE DESCRIPTION AND INVESTIGATION HISTORY
The Site is located in east-central Maine in the town of Plymouth The Site includes a 17-acre parcel of
land owned by George West and is comprised of Operable Unit One (Non-source Area Groundwater) and
the Source Area Groundwater as generally depicted on Figure 2-1 Mr West used a small two-acre
portion of the site to operate a waste oil facility from 1965 to 1980 During investigations conducted by
the Maine Department of Environmental Protection (MEDEP) in the early 1990s a fence was placed
ft around this 2-acre portion of the Site This fenced area is referred to in the RIFS and the Interim ROD as
the Source Area (Figure 2-1) Source Area Groundwater however is defined in the ROD as
d groundwater with total volatile organic compound (VOC) concentration equal to or greater than 10 parts
per million (ppm) and may exist outside the 2-acre fenced area
m From October 1999 to May 2001 the PRP Group with oversight by USEPA and MEDEP conducted a
Remedial Investigation (RI) to determine the nature and extent of contamination to characterize the fate
and transport of contaminants and to assess the potential risks that the contamination poses to both
human health and the environment The findings of the RI show that VOCs in groundwater and
polychlorinated biphenyls (PCBs) in soil within the fenced area of the Site were present at concentrations
exceeding the target risk levels of 105 carcinogenic risk or a Hazard Index of 1 for non-carcinogenic risk
In addition modeling of Site groundwater shows that groundwater flows radially away from the source
area and discharges to the surface in many spring-fed ponds and to the surface on the flanks of the hill
bull Under current conditions contamination from the Site has reached its maximum extent This
groundwater plume consists of both Source Area Groundwater which is defined as groundwater where
total VOC concentrations are greater than or equal to 10 ppm and Non-Source Area Groundwater which
is groundwater containing total VOC concentrations below 10 ppm (USEPA 2002) (see Figure 2-1) A
(0 detailed description of the distribution and extent of groundwater contamination at the Site is provided in
sections 40 and 50 of the RI Report
4 In July 2002 the PRP Group with oversight by USEPA and MEDEP completed a Feasibility Study (FS)
to develop and evaluate a range of remedial alternatives to address potential risks to human health and the
environment that were identified during the RI for the non-source area groundwater
TISOW WOODARD amp CURRAN 3 September 302003 20564309
NonmdashSource Area Groundwater
Source Atea Groundirater
17mdashAcre George West Property
_bdquoVOCugllppm
0
| n r nA
= Volatile Orgamc Compound _ = Microgram per Liter
= Parts per Million
300 600
FEET
Notes 1 Shaded areas based on Maximum Extent of total VOCs j n e | t h e r D e c e m b e r 1 9 9 9 P r e _ R 0 D o r J u n e 2 0 0 0 Supplemental Sampling Events
2 Source Area Groundwater is defined as groundwater with total VOC concentration equal to or greater than 10000 ugl (10 ppm) Extent of Source Area Groundwater plume inferred east of 2-Acre Fenced Area
3 Non Source Area Groundwater is defined as groundwater with total VOC concentrations less then 10000 ugl (10ppm)
Figure 2-1 Site Plan Detail
Hows Corner Superfund Site Plymouth Maine
WOODARD ampCURRAN Engineering bull Science Operations
205643wipsite sowu2-1A
0
Soil within the fenced area of the Site that presented a human health risk was excavated during pilot
testing for the FS and disposed of off-site The three remedial alternatives evaluated in the FS (WampC
bull 2002) were
bull No further Action
lt$ bull Limited Action and
bull Hydraulic Containment
$t As stated in Section 40 of the FS the possible presence of a remnant dense non-aqueous phase liquid
(DNAPL) source within the groundwater plume raises the question as to whether or not complete
restoration of the aquifer can be achieved in a reasonable period of time (eg less than 100 years)
Because of the uncertainties associated with the groundwater recharge rate the mass of DNAPL in
^ Source Area Groundwater the fractional organic carbon (foe) in the bedrock and the tetrachloroethene
(PCE) organic carbon partitioning coefficient (Koc) the restoration potential of both Source Area and
^ Non-Source Area Groundwater could not be assessed within a reasonable degree of scientific certainty in
the FS
The Interim ROD for Operable Unit One Non-Source Area Groundwater (USEPA 2002) was completed
in September 2002 The remedy selected in the Interim ROD consisted of
bull Installation of groundwater extraction and treatment system to contain Source Area Groundwater
bull Monitoring of surface water sediments and Non-Source Area Groundwater to measure the
progress of natural attenuation toward meeting Applicable or Relevant and Appropriate
Requirements (ARARs)
^9 bull Residential well monitoring with a public water contingency
bull Institutional Controls to prevent use of both Source and Non-Source Area Groundwater and
( i bull Five-year Reviews
4) Following completion of the FS Report and preparation of the Interim ROD for Operable Unit One
USEPA requested that further site characterization be completed to assist in making a determination
Jsect concerning the feasibility of attaining ARARs within a reasonable time Section 3 of this SOW outlines
the tasks proposed by the PRP Group to address the requirement for additional Site data necessary for a
pound TI evaluation and containment system design
TISOW WOODARD amp CURRAN 5 September 302003 20564309
bull 30 INVESTIGATION TECHNICAL APPROACH
On behalf of the PRP Group Woodard amp Curran (WampC) has developed a proposed SOW in response to
bull USEPAs request for additional field tasks to further refine the cleanup times presented in the 2002
Interim ROD for this site This approach has been designed to evaluate the following additional data
lt9 needs identified by USEPA to refine cleanup times
4t bull Aquifer hydraulic conductivity
bull Aquifer porosity (matrix and bulk) and
H bull Partitioning of contaminants to the bedrock
^ The data from these additional field tasks will also be used by USEPA to define the TI zone for the Final
ROD and assist the PRPs in developing the design for the hydraulic containment system for the Source
j Area Groundwater which is being conducted under the authority of the RD AOC Details regarding
development of the hydraulic containment system will be presented in the Remedial Design Work Plan
The proposed TI SOW is based on information available during its preparation and may be amended
subject to USEPA approval as additional information regarding subsurface conditions becomes available
during the field investigation The following section describes the overall field investigation approach A
comprehensive presentation of each task in the field investigation will be provided in the Sampling and
bull Analysis Plan (SAP) which will be amended following approval of a final scope of work
bull0 31 Investigative Approach
j The work proposed to meet the additional data requirements stated by USEPA consists of the three
primary tasks described below and further outlined as subtasks Brief descriptions of each task are
presented in the subsections that follow
Task 1 - Project Planning
Task 2 - Field Investigation
Task 3 - TI Evaluation and Reporting
WOODARD amp CURRAN 6 September 302003 20564309
311 Task 1 - Project Planning
Project planning is the first task and includes the following five subtasks
bull Finalize the SOW
bull Prepare work plan
bull Revise existing site-specific Quality Assurance Project Plan (QAPP) Sampling and Analysis
Plan (SAP) and Health and Safety Plan (HASP) and
bull Secure subcontractor contracts
bull Mobilize to the Site and establish a field office
In order to finalize the SOW for this TI evaluation it is anticipated that a minimum of one meeting will
occur between the PRP Group USEPA MEDEP and WampC Once the SOW is finalized the QAPP
SAP and HASP (the Plans) will be revised to incorporate necessary modifications to reflect the agreed-
upon work methods and technology The SAP will be modified to include a detailed plan for the
additional field activities Once the Plans have been revised and the Work Plan prepared they will be
submitted to USEPA for review USEPA comments will be incorporated into the plans and final
approved plans will be issued
After final plans have been issued WampC will negotiate contracts with subcontractors for certain field
activities including boring and monitoring well installation geophysical survey packer testing and
investigation-derived waste (IDW) storage and disposal It is anticipated that a second meeting between
the parties may be needed prior to the commencement of the field activities
Because of the duration of the field activities described in this SOW and the need for on-site evaluation of
field results in order to make program decisions during the investigation WampC will mobilize a trailer to
the Site to serve as a field office The trailer will be equipped with telephone and fax machine
312 Task 2 - Field Investigation
The field investigation task will include the following subtasks
bull Subtask 1 - Boring installation
bull Subtask 2 - Borehole geophysics
TISOW
WOODARDampCURRAN 7 September 302003 20564309
0
0 bull Subtask 3 - Packer testing
bull Subtask 4 - Sampling and analysis
bull bull Subtask 5 - Monitoring well installation
bull Subtask 5 - Pumping test and
bull Subtask 6 - Tracer test
Each of the subtasks is summarized below however a comprehensive discussion of these subtasks and
associated methodologies will be provided in the SAP
Subtask 1 - Boring Installation
j Information obtained during the installation of the new borings will be used in the evaluation of the
aquifer hydraulic conductivity and the analysis of other aquifer properties (eg porosity fracture
frequency) For this subtask it is anticipated that one angled boring will be completed to a depth of 150
feet (ft) below ground surface (bgs) One additional angled boring and four new vertical bedrock borings
will be completed to depths of approximately 100 ft bgs This depth is consistent with the depth
evaluated in the RI and will allow evaluation of bedrock and groundwater properties to depths below the
transition from less competent to more competent bedrock (approximately 50 to 80 ft bgs)
m One additional vertical boring will be installed to a depth of 100 ft bgs as the pumping well location for
bull the pumping test The pumping well location will be based on the results of field work conducted prior to
its installation The proposed drilling program is designed to enhance understanding of the flow system
by aligning new boring locations with existing wells to characterize hydraulic properties of the fracture
network and bulk bedrock Furthermore the program allows for additional characterization of
M contamination in the Source Area groundwater The rationale for the boring locations is summarized in
Table 3-1 and the proposed locations of the borings are depicted on Figure 3-1 Actual locations may
M vary depending on field conditions and accessibility
jlt The drilling protocol employed during installation of both the angled and the vertical wells will allow for
evaluation of the potential presence of DNAPL in the rock and the need for modifications to the drilling
method if DNAPL is detected If sheen or product is observed in the return water core or cuttings from a
boring an interface probe may be employed to determine whether a NAPL is present in the boring
Based on the presence of DNAPL the boring may be terminated at a shallower depth than planned the
J TISOW 4 1 WOODARD amp CURRAN 8 September 302003
20564309
location may be abandoned or other practices may be employed to reduce the potential for causing
downward migration of DNAPL The protocol will be described in the Work Plan and the SAP
Angled Borings Two angled borings will be installed using air-hammer drilling methods The first
angled boring (AW-201) will be installed to a depth of 150 ft bgs in the vicinity of existing well MWshy
106 northeast of and outside of the source area and within the dissolved phase groundwater plume This
well will be angled from the surface toward the southeast at depth in order to intersect as many northwest-
dipping near-vertical fractures as possible The angle of this boring will be approximately 30deg to 40deg
from the vertical resulting in a surface projection of approximately 84 to 126 ft and total length of
approximately 173 to 195 ft The second angled boring (AW-202) will be installed to a depth of 100 ft
bgs in the vicinity of the existing MW-2 well cluster within the source area This well also will be angled
from the surface toward the southeast at depth in order to intersect near-vertical fractures The angle of
this boring will be approximately 30deg to 40deg from the vertical resulting in a surface projection of
approximately 58 to 84 ft and total length of approximately 115 to 130 ft
m
4
sect
i
TISOW WOODARD amp CURRAN 9 September 302003 20564309
Table 3-1
Rationale for Proposed Well Locations
Hows Corner Technical Impracticability Evaluation and Field work for Hydraulic Containment System Design
Well Identification
AW-201
AW-202
MW-203
MW-204
MW-205
MW-206
PW-207
Boring Orientation
Angled
Angled
Vertical
Vertical
Vertical
Vertical
Vertical
Minimum Boring Diameter (inches)
4
4
4
4
4
4
6
Drilling Method
Air Hammer
Air Hammer
Coring
Air Hammer
Air Hammer
Air Hammer
Core Air Hammer Over -drilling
Source Area Non-Source Area
Non-Source Area
Source Area
Non-Source Area
Non-Source Area
Source Area
Source Area
Source Area
Rationale for Boring
bull Intercept near-vertical fractures to understand subsurface geology bull Aid in iting MW-203 bull Intercept near-vertical fractures to understand subsurface geology bull Aid in siting PW-201 (Pumping well) bull ion of contamination bull 1 future monitoring location bull Potential reinjection well for hydraulic containment system bull Core for matrix diffusion evaluation bullbullbullbull Ibullbullbullbull 1bullbullbullbull 1bullbull bull 1
tion point for pumping test tion point in tracer test ion of contamination
future monitoring location tion point for pumping test tion point in tracer test ion of contamination
future monitoring location tion point for pumping test tion point in tracer test ion of contamination
future monitoring location tion point for pumping test
test well extraction well
bull Core for matrix diffusion evaluation bull i point for tracer test
TISOW September 30 2003 WOODARD amp CURRAN 20564309
MW-105D MW-5B
Primary Bedding Secondary Cleavage
Tertsry Fracturing
NOTE A total of 60 observations warn made rtrtjs roprtraont tticopy number of obsafvatk noted wtthln each azimutha) segment
MW-1 1 3D euro MW-205
2 AcreSource
Fenced-^ Area i
MW-103D MW-103S
17-Acre Property Boundary
MW-104D MW-1041 bull
MW-104S
Legend Figure 3-1 J Proposed Monitoring Well Proposed Well Locations
o- Site Property Boundary bull^bullProposed Pumping Well Hows Corner Superfund Site -xmdashx- Source Area Plymouth Maine
^ ^Proposed Angled Well bullamp Existing Monitoring Well bullWDODARDampCURRAN
Englnoortng bull Science bull Operations 205643wipsite-8OlaquoAx-opt-1-2-u3-1D
bull During the installation of each angled boring observations will be made regarding water gainloss
drilling rate and bit behavior to assess the depth of potential fractures In addition water levels will be
9 measured in nearby borings using either hand measurements data loggers or both to evaluate
connectivity between locations A change in water level in a nearby boring will indicate a hydraulic
at connection between the borings Borehole geophysics will also be performed on the borings (See Subtask
2 below) Information from each angled boring will be used to site an adjacent vertical well (MW-203
^ and PW-207) so that it intercepts a fracture observed in the angled boring
^ Vertical Borings Two of the vertical borings will be completed with rotary diamond coring to
approximately 100 ft bgs These borings will be adjacent to the angled borings described above One of
^ the cored borings (MW-203) will be located near MW-106 outside of the source area within the
dissolved-phase groundwater plume (see Figure 3-1) The other cored boring (PW-207) will be the
pumping well which is anticipated to be located within the source area in the vicinity of the existing
MW-2 well cluster Coring will allow data collection for several purposes including direct observation
of bedrock for determination of the nature of the rock matrix determination of the location and nature of
fractures and the degree of fracturing comparison with geophysical logs (Subtask 2) to verify
interpretation of the logs and collection of core samples for analysis (Subtask 4)
The remaining borings will be located east of the 2-acre fenced area within or near the periphery of the
source area and will be sited to align approximately with existing wells based on the known fracture
orientations at the Site (MW-204 and MW-205) or with new wells based on the known fracture
pound orientations at the Site (MW-206) Data from these locations in conjunction with the other borings
installed as part of this TI SOW and the existing wells will be used in the interpretation of the pumping
^ test (Subtask 6) and tracer test (Subtask 7) In addition these three borings will further delineate
contamination and provide potential monitoring locations for long-term monitoring Each of these
^ borings will be advanced to approximately 100 ft bgs with a minimum four-inch diameter air hammer
^ During the installation of each boring observations will be made regarding water gainloss drilling rate
and bit behavior to assess the depth of potential fractures In addition water levels will be measured in
nearby borings using either hand measurements data loggers or both to evaluate connectivity between
locations A change in water level in a nearby boring will indicate a hydraulic connection between the
TISOW WOODARD amp CURRAN 12 September 302003 20564309
borings Borehole geophysics and packer testing will also be performed on the borings (See Subtasks 2
and 3 below)
Drilling water will be containerized on site and treated through granular activated carbon (GAC) Treated
water will be analyzed to verify that PCB and VOC concentrations have been reduced to below ARARs
prior to discharge to the ground surface Cuttings will be spread on the ground surface at the site
consistent with the Remedial Investigation work plan
It is anticipated that up to 10 core samples from each cored boring (total of 20 cores) will be collected and
submitted to an off-site laboratory for analyses of porosity (matrix and bulk) permeability bulk density
and fraction of organic carbon (f^) using methods described in Subtask 4
Subtask 2 - Borehole Geophysics
To supplement information on fracture location and connectivity obtained during boring advancement a
borehole geophysical survey will be conducted on the newly installed bedrock borings to evaluate the
nature and orientation of water bearing fractures in the borings The survey will be performed at the
completion of the angled borings and again at the completion of the vertical borings The information
obtained during the survey may be used to identify the location of subsequent boring(s) by refining the
understanding of the depth aperture and orientation of bedrock fractures The following measurements
are proposed for the new borings caliper fluid temperature fluid resistivity and acoustic televiewer
(ATV) Single-point resistively and 16 inch normal measurements will also be made in the first two
borings installed and the data will be compared to data from the other geophysical logs to determine if
the measurements confirm and significantly improve the interpretation regarding the presence of water-
bearing fractures If the measurements are applicable to identification of fractures they may be included
in lieu of other geophysical logs in the remainder of the borings
Subtask 3 - Packer Testing
To further refine information on the aquifer hydraulic conductivity the hydraulic connection between
fractures in the borings will be evaluated during packer testing of vertical borings The data will be used
to estimate the hydraulic conductivity of specific fractures and fracture zones The packer testing will be
performed after the vertical borings have been installed and the borehole geophysical survey completed
TISOW WOODARD amp CURRAN 13 September 30 2003 20564309
bull
m
M
Drilling observations and information from borehole geophysics will be used to identify specific fractures
below the water table that are capable of transmitting water Prior to water injection for hydraulic
conductivity and fracture connectivity testing groundwater samples will be collected at selected intervals
for analysis of VOCs (See Subtask 4) Sampling intervals will be selected based on drilling observations
and logging results that indicate water is moving into or out of the borehole or that fractures exist to
promote water movement such as rapid increase in the amount of water returned rapid change in
temperature or highly fractured interval
^
^
bull
f$
Double packer testing will be performed at selected intervals within each newly installed boring It is
anticipated that up to six intervals per well will be tested for a maximum of 24 intervals and that for each
interval the test will include an approximate 15-minute injection of potable water at four progressively
increasing pressures Packer spacing is anticipated to be 10 ft however spacing may vary so that packers
are not located in potential fracture zones identified using information from rock cores drilling
observations and borehole geophysics The tests at an individual interval will be terminated if it appears
that the interval is not accepting water Care will be taken to minimize over-pumping or over-
pressurizing of the fractures The flow rate will be measured to evaluate the characteristics of the
fracture Water levels in adjacent borings will be measured during the packer testing to determine if a
hydraulic connection exists between the borings Water generated during packer testing will be
containerized on site and treated through GAC Treated water will be analyzed to verify that PCB and
VOC concentrations have been reduced to below ARARs prior to discharge to the ground surface
4 Subtask 4 Sampling and Analysis
~d
^
Rock and groundwater samples will be collected during the field program for laboratory analysis The
results of the analyses will be used to help refine the distribution of the plume and to estimate bedrock
properties These analyses will be used in conjunction with existing data during the TI evaluation to
refine cleanup times and establish the limits of the TI zone
As described in Subtask 1 it is anticipated that up to 10 core samples from each cored boring (total of 20
core samples) will be collected and submitted to an off-site laboratory for analyses of porosity (matrix and
bulk) permeability bulk density and fraction of organic carbon (f^) using existing industry methods
Subject to further evaluation of industry methods Woodard amp Curran proposes that porosity
TISOW WOODARD amp CURRAN20564309
14 September 302003
permeability and density will be measured using methods in the American Petroleum Institutes API RPshy
40 Fraction of organic carbon (f^) will be measured using either the LECO TOC method or Walkey-
Black method The LECO TOC method is a standard method in the petroleum industry and involves the
direct combustion of a ground rock sample The Walkey-Black method is a commonly used USEPA-
approved chemical oxidation method for determination of foe in soils In addition either method could be
used if a sample were scraped from a fracture surface To develop a reasonable range of f for Site
bedrock up to five samples will be selected from each boring from the unfractured matrix and up to five
from the fracture surfaces In addition Woodard amp Curran will evaluate the appropriateness of selecting
rock samples from a subset of the core samples from areas near fractures as well as from non-fractured
areas and submitting the samples for VOC analysis following methanol extraction
Results from these analyses will be used in conjunction with groundwater contaminant concentrations to
evaluate the significance of diffusion of contamination from the bedrock matrix in both the Source Area
and the Non-Source Area Although matrix diffusion likely is a significant factor in the determination of
cleanup times within the Source Area the potential applicability of matrix diffusion in the Non-Source
Area is not known These core analyses may provide evidence to assist in developing an estimate
through calculations of the effect of matrix diffusion on cleanup times
As noted in Subtask 3 prior to injection of water during packer testing groundwater samples will be
collected at selected intervals for analysis of volatile organic compounds (VOCs) Up to a total of 20
groundwater samples plus appropriate quality control samples will be collected from the newly installed
borings The samples will be submitted to an off-site laboratory for analysis Analytical results will be
validated in accordance with USEPA protocol and the data will be managed in WampCs existing
groundwater sampling analytical database for this site
Up to 21 existing monitoring wells from within or nearby the 17-acre property plus four new wells once
constructed will be sampled using low-flow techniques and submitted to an off-site laboratory for VOC
analysis Analytical results will be validated in accordance with USEPA protocol and the data will be
managed in WampCs existing groundwater sampling analytical database for this site
TISOW WOODARD amp CURRAN 15 September 302003 20564309
Subtask 5 - Monitoring Well Installation
Although it is anticipated that the newly installed borings will be left as open holes for tracer testing and
for pumping tests monitoring wells will be installed and developed in the newly installed borings unless
the USEPA MEDEP and PRP Group determine that the location is inappropriate for such use The
monitoring wells will be constructed of two-inch schedule 40 PVC screen and riser Screen intervals will
be selected based on the location of fractures identified during drilling geophysical logging and packer
testing A sand pack will be placed around the screen and will extend from approximately two ft below
the screen to approximately two ft above the screen
Subtask 6 - Pumping Test
WampC will conduct a single constant discharge pumping test to evaluate hydraulic properties of the
aquifer It is anticipated that the test will be conducted in a new pumping well in the vicinity of the
existing MW-2 well cluster within the source area Data from the pumping test will be used in
conjunction with other data from the investigation to improve the understanding of groundwater
movement and contaminant transport in the Source and Non-Source areas The results of the pumping
test will be used to refine the Site conceptual model as well as in the design of the hydraulic containment
system that is being constructed under the authority of the AOC for the RD
The groundwater pumping test will include the following components (1) Pumping test setup (2) Pretest
monitoring (3) Constant Discharge Pumping Test (4) Post-test monitoring and (5) Data Analysis
Pumping Test Setup In support of the groundwater pumping test WampC will install a pumping well
(PW-207) and procure and install the required groundwater extraction treatment and storage equipment at
the Site The well will be cored and over drilled to allow construction of a 4-inch well The location will
be in the vicinity of the MW-2 well cluster and be based upon results of the angled bedrock boring AWshy
202 The equipment will include but not be limited to
bull Down well pump plumbing and appurtances
bull Two (2) 20000 frac tanks
bull Groundwater transfer pumps and controls
bull Settlingaerationsand filtration treatment processes for the treatment of inorganics (if needed) and
nsow WOODARD amp CURRAN 16 September 302003 20564309
bull Granular activated carbon units for the treatment of dissolved organics in the groundwater
The groundwater treatment process will include the following processes 1) an oxidation and filtration
step to remove the inorganics from the groundwater and GAC units to treat the organic contaminants in
the extracted groundwater
Pretest Monitoring Prior to initiation of pumping WampC will monitor water levels in existing wells and
newly installed borings adjacent to the pumping well using a combination of hand measurements and data
loggers to develop an understanding of the piezometric surface under unstressed conditions The wells
proposed for water-level monitoring will be described in the work plan In addition all gauges
transducers flow meters and other equipment used in conducting the pumping tests shall be calibrated
before use
Constant Discharge Pumping Test The pumping test will be conducted in the source area using
newly-installed pumping well PW-207 It is anticipated that the test will be conducted at a pumping rate
of approximately 2 gallons per minute (gpm) for a period of 2 to 3 days however a higher or lower rate
may be shown to be appropriate based on the drilling and packer testing conducted during boring
installation Woodard amp Curran proposes to conduct this test using a vacuum-enhanced recovery system
(VERS) as described in the ROD so that the water level is not lowered appreciably in the vicinity of the
pumping well to prevent the potential migration of NAPLs to deeper bedrock zones The appropriateness
and feasibility of the VERS for the pumping test will be determined by field testing or literature
evaluation prior to completion of the Work Plan Because of the short duration of this test it is not
anticipated that stability of water levels will be reached in observation wells The test will however
provide information to estimate hydraulic conductivity and bedrock storage During the test the water
levels in the pumping well and selected monitoring wells will be logged continuously via down well data
loggers It is anticipated that water levels in approximately 24 wells will be measured using hand
measurements and data loggers
Groundwater extracted during the pumping test will be stored temporarily in an on-site frac tank prior to
on-site treatment and disposal
TISOW WOODARD amp CURRAN 17 September 302003 20564309
Post-Test Monitoring After the pump is turned off in the pumping well water levels will continue to be
monitored using hand measurements and data loggers until they have returned to within 10 of the preshy
test levels For planning purposes this has been estimated to be two weeks
Data Analysis Data collected during the pumping test will be analyzed with Aquifer Win32 Results of
the pumping test will be summarized in the summary data package for the TI Evaluation and the results
will also be used in the design of the hydraulic containment system specified in the Interim ROD that is
being conducted under the authority of the AOC for the RD Detail regarding use of the pumping test
data in hydraulic system design will be provided in the Remedial Design Work Plan
Subtask 7 - Tracer Test
WampC will conduct a tracer test using a conservative tracer to evaluate fracture connectivity porosity
dispersivity and matrix diffusion of the bedrock aquifer in both the Source Area and Non-Source Area
To increase the potential for success of this test results of the pumping test evaluation will be used to
revise the tracer test plan proposed here as necessary Following rebound of water levels after
completion of the pumping test WampC will initiate a single natural gradient tracer test The test will
consist of injecting a tracer into well PW-207 in the source area (Figure 3-1) for up to five days and
monitoring the tracers arrival in nearby wells Borehole geophysics core evaluation and packer testing
will be used to select the specific injection depth(s) in the well
A Tracer Test Work Plan will be completed prior to initiation of injection to determine the type quantity
and concentration of tracer based on the distance between the injection well and the monitoring wells A
conservative tracer that is one that is not preferentially adsorbed to rock or organic matter will be
selected for the tracer test Tracer injection equipment including tanks and flow-regulating and metering
equipment and pumps will be used to mix the tracer at the surface prior to injection Fractures may be
packered in the injection well and tracer solution will be injected at a rate determined during preparation
of the Tracer Test Work Plan During injection the potentiometric surface of the aquifer will be
monitored to verify that the potentiometric surface remains relatively constant during the injection
process
nsow WOODARD amp CURRAN 18 September 302003 20564309
Prior to injection of the tracer background concentration will be established by collecting samples from
up to six wells in the area of the tracer test and analyzing them for the tracer using an appropriate
analytical method Following injection of the tracer solutions the concentration of the tracer in
downgradient wells and borings will be measured A monitoring network will be established using nearby
monitoring wells Downhole probes will be installed in six new and existing wells near the injection well
to be identified in the work plan first to determine the background tracer concentrations and then to
monitor for the presence of the tracer upon initiation of the test Measurements will be collected at
periodic intervals to be determined based on the results of packer testing If an increase in tracer
concentration is detected or at a minimum on a weekly basis a water sample will be collected using low
flow sampling methodologies and analyzed in an off-site laboratory to evaluate the concentration of the
tracer The concentration of the tracer will be recorded Monitoring of the tracer concentration will
continue throughout the duration of the test The tracer will be allowed to flow with groundwater for one
month or until detected in wells in the vicinity of MW-106 whichever is shorter
313 Task 3 - TI Evaluation and Reporting
The TI Evaluation and reporting task includes the following five subtasks
bull Data evaluation
bull Summary data package
bull Draft TI Evaluation
bull Meetings with PRP Group and USEPA and
bull Revise and finalize TI Evaluation
As the subtasks of the field investigation are completed the data will be evaluated for the purpose of
addressing the data gaps identified by USEPA Specifically the data will be used to further refine the
cleanup times for non-source area groundwater presented in the Interim ROD
The data obtained during the field investigation will be reduced and evaluated and a summary data
package will be prepared that will include a discussion of the field activities completed and presentation
of the data It is anticipated that up to two meetings with USEPA will be necessary before the data
evaluation and summary report are completed
TISOW WOODARDampCURRAN 19 September 302003 20564309
Data collected during the pumping test will be analyzed with Aquifer Win32 Results will be summarized
in the summary data package and will also be presented as part of the RD submittals
Following submittal of the summary data package the TI evaluation will be prepared In accordance with
EPA guidance (1993) the TI waiver evaluation document will address the following topics
1 Specific ARARS or media cleanup standards for which TI determination is sought This section of the
TI Evaluation will identify the specific contaminants for which the TI determination is sought Based on
information available to date a waiver may be appropriate for pesticides PCBs chlorinated organic
compounds and other site-related contaminants that upon evaluation will not attain ARARs in a
reasonable period of time
2 Spatial area over which the TI waiver will apply The purpose of the additional site investigation
outlined in this SOW is to obtain the data necessary to further refine cleanup times presented in the
Interim ROD to determine what portions of the Site will not be expected to reach ARARs within a
reasonable time Consistent with TI guidance (USEPA 1993) the TI evaluation will specify the
horizontal and vertical extent of the area for which TI determination is sought Groundwater
concentration data from the RI and the TI SOW will be used to refine the distribution of the plume Data
from the drilling geophysical logging packer testing and pumping and tracer tests will be used to refine
the Site conceptual model and the cleanup times that will serve as the basis for establishing the scope and
nature of the TI zone
3 Conceptual Model The conceptual model forms the technical core of the TI Waiver Evaluation since
it provides basis for understanding of the restoration potential of the site The conceptual model outlines
the physical and hydrogeological constraints that hinder remediation or removal of Site contaminants and
it is the extent of these constraints rather than restoration timeframe alone that USEPA will use to
evaluate the necessity of the TI waiver of ARARs The conceptual model is the link between restoration
potential and restoration timeframe since it explains why proposed technologies are unlikely to work
either at all or within the desired 100-year timeframe
The Site conceptual model is not a mathematical model however as the result of the extensive modeling
and investigations of the site WampC has a strong understanding of the complex bedrock and overburden
TISOW WOODARDampCURRAN 20 September 302003 20564309
groundwater system beneath this site This understanding has been presented previously in both the RI
report and the FS and will be refined based on the TI SOW as necessary and summarized in the TI
Waiver Evaluation with specific attention to the physical and hydrogeological constraints on remediation
In particular the Site conceptual model will be reviewed in light of the new geologic data from drilling
logging and packer testing and the new hydrogeologic data obtained from the pumping test and tracer test
and will be revised to incorporate the new understanding
4 An evaluation of the restoration potential of the site This section will consist of a several components
It will present a systematic review of the technologies potentially capable of remediating the site given
the physical and hydrogeological constraints identified in the site model The newly acquired data will
provide an improved understanding of bedrock hydraulic properties that will allow a more Site-specific
evaluation of technologies The review of technologies will also include review of innovative
technologies and will evaluate whether existing remedial technologies or strategies would be capable of
achieving groundwater restoration at the site in a reasonable timeframe The section reference the FS and
will summarize the alternative remedies considered in the FS focusing on the ability of each to restore
groundwater in a reasonable timeframe It will also include a discussion of the selected hydraulic
containment system in light of the data gathered from the pumping test conducted in conjunction with the
TI SOW
Based on the Batch Flushing Model and using the agreed upon koc data from the RI as well as data from
this TI SOW including the f data collected as part of Subtask 4 a restoration timeframe analysis will be
conducted Following completion of the timeframe analysis and consideration of the results of drilling
rock and water analyses and pumping and tracer test a determination will be made regarding the Source
Area and the portion of the Non-Source Area VOC plume that will not attain ARARs in a reasonable
time
TISOW WOODARD amp CURRAN 21 September 302003 20564309
40 SCHEDULE
A proposed project schedule is included with this plan as Figure 4-1 This schedule is included for
discussion purposes and will be modified as necessary once the final scope of work as been approved by
all parties and the field work activities are coordinated with the subcontractors
TISOW WOODARD amp CURRAN 22 September 302003 20564309
ID
2
3
4
5
6
7 a i 10
11
12
13
14
15
16
17
16
19
20
21
22
24
25
26
27
26
29
30
31
32
Task Name
Project Meeting with EPA
Finalize SOW
Prepare Work Plans QAPP HASP Revision
Submit Work Plans for EPA Approval
Project Meeting with EPA
Revisions to work plans
Submit final work plans
Subcontractor Contracts
Project Meeting wEPA
Field Investigation
Site Mobilization
Install Borings
Borehole Geophysics
Packer Testing amp Collect GW Samples
Pumping Test
Tracer Test
Test setup
Injection
Monitoring
Data Reporting
InstallDevelop Wells
Data Evaluation
Prepare Data Package
Data Package Submittal to EPA
Draft Tl Evaluation Repon
Draft Tl Evaluation Report Submttal to EPA
EPA ReviewComment on Tl Evaluation ReF
Project Meeting wEPA
Revisions to Tl Evaluation Report
Submit Final Tl Evaluation Report
Start
Wed 070903
Thu 071003
Fri 101003
Mon 120103
Mon 121503
Mon 122903
Mon 011204
Tue 011304
Thu 021904
Fri 032104
Fri 032604
Fri 040204
Fri 041604
Fri 042304
Thu 050604
Wed 060204
Wed 060204
Wed 060904
Wed 060904
Wed 062304
Wed 070704
Wed 042804
Wed 062304
Mon 080204
Mon 070504
Tue 082404
Wed 082504
Wed 091504
Thu 0916AM
Thu 093004
Finish
Wed 070903
Fri 1OtO7u3
Fri 112803
Fri 122603
Mon 121503
Fri 010904
Mon 011204
Mon 012604
Thu 021904
Tue 071304
Thu 040104
Thu 042204
Tue 042704
Wed 050504
Tue 052504
Tue 071304
Tue 060804
Tue 061504
Tue 070604
Tue 071304
Fri 070904
Tue 072004
Fri 073004
Mon 080204
Mon 082304
Tue 082404
Tue 091404
Wed 091504
Wed 082904
Thu 093004
FIGURE 4-1 DRAFT HOWS CORNER SUPERFUND SITE
Tl EVALUATION amp RELD WORK FOR HYDRAUUC CONTAINMENT SYSTEM DESIGN PROPOSED PROJECT SCHEDULE
2003 2004 Mav |
Jun | Jul
ltamp i
Aug
i
Sen Oct I Nov Dec Jan Feb I Mar
ii i i
k ^tr 1
1V i
I t bull ^
I
ta^M bull bull M W
l LgtH^HBKLii LJ Mi
I
bull bull raquo bull laquo^ 0930
Task Progress I^MLHHHI^LB Summary ^^^^^^^^f External Tasks M B WMMM Deadline ^7 Project Hows Comer Schedule6A bull bull bull 1 UData Fri 101003 Split Milestone ^ Project Summary ^f^KKKKKK^^ External Milestone ^
Pagei
50 ACRONYMS
AOC Administrative Order by Consent
ARARs Applicable or Relevant and Appropriate Requirements
ATV acoustic televiewer
bgs below ground surface
CERCLA Comprehensive Environmental Resource and Conservation Liability Act
DNAPL Dense Non-Aqueous Phase Liquid
GAC granular activated carbon
gpm gallons per minute
HASP Health and Safety Plan
row investigation-derived waste
MCL Maximum Containment Level
MEDEP Maine Department of Environmental Protection
MEG Maine Enforcement Guideline
mgkg milligrams per kilogram
Hg kg micrograms per kilogram
NCP National Contingency Plan
PCB polychlorinated biphenyl
PID photo ionization detector
ppm parts per million
PRP Potentially Responsible Party
TISOW WOODARD amp CURRAN 24 September 302003 20564309
QAPP Quality Assurance Project Plan
QAQC Quality AssuranceQuality Control
RA Remedial Action
RAO Remedial Action Objective
RCRA Resource Conservation and Recovery Act
RD Remedial Design
RIFS Remedial InvestigationFeasibility Study
ROD Record of Decision
SAP Sampling and Analysis Plan
SOW Statement of Work
TAL target analyte list
TI Technical Impracticability
USEPA United State Environmental Protection Agency
VOCs volatile organic compounds
WampC Woodard amp Curran Inc
TISOW WOODARD amp CURRAN 25 September 302003 20564309
REFERENCES
Everts CJ RS Kanwar (1994) Evaluation of Rhodamine WT as an adsorbed tracer in an agricultural
soil J Hydrology 153 53-70
Kasnavia T D Vu DA Sabatini (1999) Fluorescent dye and media properties affecting sorption and
tracer selection Groundwater 37 376-381
Ptak T G Schmid (1996) Dual-tracer transport experiments in a physically and chemically
heterogeneous porous aquifer effective transport parameters and spatial variability J Hydrology
183 117-138
Sabatini DA T A Austin (1991) Characteristics of Rhodamine WT and fluorescein as adsorbing
ground-water tracers Ground Water 29 341-349
Trudgill ST (1987) Soil water dye tracing with special reference to the use of Rhodamanie WT
Lissamine FF and Amino G acid Hydrological Processes 1 149-170
US Environmental Protection Agency (USEPA) 1993 Guidance for Evaluating the Technical
Impracticability of Ground-Water Restoration - Interim Final Office of Solid Waste and
Emergency Response Washington DC Directive 92342-25 September 1993
US Environmental Protection Agency (USEPA) 2002 Interim Record of Decision Summary shy
Operable Unit One Non-Source Area Groundwater West SiteHows Corner Superfund Site
Plymouth Maine EPA Region 1 September 2002
US Environmental Protection Agency (USEPA) 2003 Proposed Scope of Work West SiteHows
Corner Superfund Site Plymouth Maine EPA Region 1 4 pages September 2002
Vasudevan D RL Fimmen AB Francisco (2001) Tracer-grade Rhodamine WT Structure of
constituent isomers and their sorption behavior Environ Sci Technol 35 4089-4096
nsow WOODARD amp CURRAN 26 September 30 2003 20564309
Woodard amp Curran Inc (WampC) 2002 Final Feasibility Study Report - Non-Source Area Groundwater
Hows Comer Superfund Site Plymouth Maine July 2002
TISOW WOODARD amp CURRAN 27 September 302003 20564309
f
m WOODARD amp CURRAN Maine Massachusetts New Hampshire Connecticut Florida Illinois Operational offices across the US 1-800-426-4262 wwwwoodardcurrancom
i
bull 20 SITE DESCRIPTION AND INVESTIGATION HISTORY
The Site is located in east-central Maine in the town of Plymouth The Site includes a 17-acre parcel of
land owned by George West and is comprised of Operable Unit One (Non-source Area Groundwater) and
the Source Area Groundwater as generally depicted on Figure 2-1 Mr West used a small two-acre
portion of the site to operate a waste oil facility from 1965 to 1980 During investigations conducted by
the Maine Department of Environmental Protection (MEDEP) in the early 1990s a fence was placed
ft around this 2-acre portion of the Site This fenced area is referred to in the RIFS and the Interim ROD as
the Source Area (Figure 2-1) Source Area Groundwater however is defined in the ROD as
d groundwater with total volatile organic compound (VOC) concentration equal to or greater than 10 parts
per million (ppm) and may exist outside the 2-acre fenced area
m From October 1999 to May 2001 the PRP Group with oversight by USEPA and MEDEP conducted a
Remedial Investigation (RI) to determine the nature and extent of contamination to characterize the fate
and transport of contaminants and to assess the potential risks that the contamination poses to both
human health and the environment The findings of the RI show that VOCs in groundwater and
polychlorinated biphenyls (PCBs) in soil within the fenced area of the Site were present at concentrations
exceeding the target risk levels of 105 carcinogenic risk or a Hazard Index of 1 for non-carcinogenic risk
In addition modeling of Site groundwater shows that groundwater flows radially away from the source
area and discharges to the surface in many spring-fed ponds and to the surface on the flanks of the hill
bull Under current conditions contamination from the Site has reached its maximum extent This
groundwater plume consists of both Source Area Groundwater which is defined as groundwater where
total VOC concentrations are greater than or equal to 10 ppm and Non-Source Area Groundwater which
is groundwater containing total VOC concentrations below 10 ppm (USEPA 2002) (see Figure 2-1) A
(0 detailed description of the distribution and extent of groundwater contamination at the Site is provided in
sections 40 and 50 of the RI Report
4 In July 2002 the PRP Group with oversight by USEPA and MEDEP completed a Feasibility Study (FS)
to develop and evaluate a range of remedial alternatives to address potential risks to human health and the
environment that were identified during the RI for the non-source area groundwater
TISOW WOODARD amp CURRAN 3 September 302003 20564309
NonmdashSource Area Groundwater
Source Atea Groundirater
17mdashAcre George West Property
_bdquoVOCugllppm
0
| n r nA
= Volatile Orgamc Compound _ = Microgram per Liter
= Parts per Million
300 600
FEET
Notes 1 Shaded areas based on Maximum Extent of total VOCs j n e | t h e r D e c e m b e r 1 9 9 9 P r e _ R 0 D o r J u n e 2 0 0 0 Supplemental Sampling Events
2 Source Area Groundwater is defined as groundwater with total VOC concentration equal to or greater than 10000 ugl (10 ppm) Extent of Source Area Groundwater plume inferred east of 2-Acre Fenced Area
3 Non Source Area Groundwater is defined as groundwater with total VOC concentrations less then 10000 ugl (10ppm)
Figure 2-1 Site Plan Detail
Hows Corner Superfund Site Plymouth Maine
WOODARD ampCURRAN Engineering bull Science Operations
205643wipsite sowu2-1A
0
Soil within the fenced area of the Site that presented a human health risk was excavated during pilot
testing for the FS and disposed of off-site The three remedial alternatives evaluated in the FS (WampC
bull 2002) were
bull No further Action
lt$ bull Limited Action and
bull Hydraulic Containment
$t As stated in Section 40 of the FS the possible presence of a remnant dense non-aqueous phase liquid
(DNAPL) source within the groundwater plume raises the question as to whether or not complete
restoration of the aquifer can be achieved in a reasonable period of time (eg less than 100 years)
Because of the uncertainties associated with the groundwater recharge rate the mass of DNAPL in
^ Source Area Groundwater the fractional organic carbon (foe) in the bedrock and the tetrachloroethene
(PCE) organic carbon partitioning coefficient (Koc) the restoration potential of both Source Area and
^ Non-Source Area Groundwater could not be assessed within a reasonable degree of scientific certainty in
the FS
The Interim ROD for Operable Unit One Non-Source Area Groundwater (USEPA 2002) was completed
in September 2002 The remedy selected in the Interim ROD consisted of
bull Installation of groundwater extraction and treatment system to contain Source Area Groundwater
bull Monitoring of surface water sediments and Non-Source Area Groundwater to measure the
progress of natural attenuation toward meeting Applicable or Relevant and Appropriate
Requirements (ARARs)
^9 bull Residential well monitoring with a public water contingency
bull Institutional Controls to prevent use of both Source and Non-Source Area Groundwater and
( i bull Five-year Reviews
4) Following completion of the FS Report and preparation of the Interim ROD for Operable Unit One
USEPA requested that further site characterization be completed to assist in making a determination
Jsect concerning the feasibility of attaining ARARs within a reasonable time Section 3 of this SOW outlines
the tasks proposed by the PRP Group to address the requirement for additional Site data necessary for a
pound TI evaluation and containment system design
TISOW WOODARD amp CURRAN 5 September 302003 20564309
bull 30 INVESTIGATION TECHNICAL APPROACH
On behalf of the PRP Group Woodard amp Curran (WampC) has developed a proposed SOW in response to
bull USEPAs request for additional field tasks to further refine the cleanup times presented in the 2002
Interim ROD for this site This approach has been designed to evaluate the following additional data
lt9 needs identified by USEPA to refine cleanup times
4t bull Aquifer hydraulic conductivity
bull Aquifer porosity (matrix and bulk) and
H bull Partitioning of contaminants to the bedrock
^ The data from these additional field tasks will also be used by USEPA to define the TI zone for the Final
ROD and assist the PRPs in developing the design for the hydraulic containment system for the Source
j Area Groundwater which is being conducted under the authority of the RD AOC Details regarding
development of the hydraulic containment system will be presented in the Remedial Design Work Plan
The proposed TI SOW is based on information available during its preparation and may be amended
subject to USEPA approval as additional information regarding subsurface conditions becomes available
during the field investigation The following section describes the overall field investigation approach A
comprehensive presentation of each task in the field investigation will be provided in the Sampling and
bull Analysis Plan (SAP) which will be amended following approval of a final scope of work
bull0 31 Investigative Approach
j The work proposed to meet the additional data requirements stated by USEPA consists of the three
primary tasks described below and further outlined as subtasks Brief descriptions of each task are
presented in the subsections that follow
Task 1 - Project Planning
Task 2 - Field Investigation
Task 3 - TI Evaluation and Reporting
WOODARD amp CURRAN 6 September 302003 20564309
311 Task 1 - Project Planning
Project planning is the first task and includes the following five subtasks
bull Finalize the SOW
bull Prepare work plan
bull Revise existing site-specific Quality Assurance Project Plan (QAPP) Sampling and Analysis
Plan (SAP) and Health and Safety Plan (HASP) and
bull Secure subcontractor contracts
bull Mobilize to the Site and establish a field office
In order to finalize the SOW for this TI evaluation it is anticipated that a minimum of one meeting will
occur between the PRP Group USEPA MEDEP and WampC Once the SOW is finalized the QAPP
SAP and HASP (the Plans) will be revised to incorporate necessary modifications to reflect the agreed-
upon work methods and technology The SAP will be modified to include a detailed plan for the
additional field activities Once the Plans have been revised and the Work Plan prepared they will be
submitted to USEPA for review USEPA comments will be incorporated into the plans and final
approved plans will be issued
After final plans have been issued WampC will negotiate contracts with subcontractors for certain field
activities including boring and monitoring well installation geophysical survey packer testing and
investigation-derived waste (IDW) storage and disposal It is anticipated that a second meeting between
the parties may be needed prior to the commencement of the field activities
Because of the duration of the field activities described in this SOW and the need for on-site evaluation of
field results in order to make program decisions during the investigation WampC will mobilize a trailer to
the Site to serve as a field office The trailer will be equipped with telephone and fax machine
312 Task 2 - Field Investigation
The field investigation task will include the following subtasks
bull Subtask 1 - Boring installation
bull Subtask 2 - Borehole geophysics
TISOW
WOODARDampCURRAN 7 September 302003 20564309
0
0 bull Subtask 3 - Packer testing
bull Subtask 4 - Sampling and analysis
bull bull Subtask 5 - Monitoring well installation
bull Subtask 5 - Pumping test and
bull Subtask 6 - Tracer test
Each of the subtasks is summarized below however a comprehensive discussion of these subtasks and
associated methodologies will be provided in the SAP
Subtask 1 - Boring Installation
j Information obtained during the installation of the new borings will be used in the evaluation of the
aquifer hydraulic conductivity and the analysis of other aquifer properties (eg porosity fracture
frequency) For this subtask it is anticipated that one angled boring will be completed to a depth of 150
feet (ft) below ground surface (bgs) One additional angled boring and four new vertical bedrock borings
will be completed to depths of approximately 100 ft bgs This depth is consistent with the depth
evaluated in the RI and will allow evaluation of bedrock and groundwater properties to depths below the
transition from less competent to more competent bedrock (approximately 50 to 80 ft bgs)
m One additional vertical boring will be installed to a depth of 100 ft bgs as the pumping well location for
bull the pumping test The pumping well location will be based on the results of field work conducted prior to
its installation The proposed drilling program is designed to enhance understanding of the flow system
by aligning new boring locations with existing wells to characterize hydraulic properties of the fracture
network and bulk bedrock Furthermore the program allows for additional characterization of
M contamination in the Source Area groundwater The rationale for the boring locations is summarized in
Table 3-1 and the proposed locations of the borings are depicted on Figure 3-1 Actual locations may
M vary depending on field conditions and accessibility
jlt The drilling protocol employed during installation of both the angled and the vertical wells will allow for
evaluation of the potential presence of DNAPL in the rock and the need for modifications to the drilling
method if DNAPL is detected If sheen or product is observed in the return water core or cuttings from a
boring an interface probe may be employed to determine whether a NAPL is present in the boring
Based on the presence of DNAPL the boring may be terminated at a shallower depth than planned the
J TISOW 4 1 WOODARD amp CURRAN 8 September 302003
20564309
location may be abandoned or other practices may be employed to reduce the potential for causing
downward migration of DNAPL The protocol will be described in the Work Plan and the SAP
Angled Borings Two angled borings will be installed using air-hammer drilling methods The first
angled boring (AW-201) will be installed to a depth of 150 ft bgs in the vicinity of existing well MWshy
106 northeast of and outside of the source area and within the dissolved phase groundwater plume This
well will be angled from the surface toward the southeast at depth in order to intersect as many northwest-
dipping near-vertical fractures as possible The angle of this boring will be approximately 30deg to 40deg
from the vertical resulting in a surface projection of approximately 84 to 126 ft and total length of
approximately 173 to 195 ft The second angled boring (AW-202) will be installed to a depth of 100 ft
bgs in the vicinity of the existing MW-2 well cluster within the source area This well also will be angled
from the surface toward the southeast at depth in order to intersect near-vertical fractures The angle of
this boring will be approximately 30deg to 40deg from the vertical resulting in a surface projection of
approximately 58 to 84 ft and total length of approximately 115 to 130 ft
m
4
sect
i
TISOW WOODARD amp CURRAN 9 September 302003 20564309
Table 3-1
Rationale for Proposed Well Locations
Hows Corner Technical Impracticability Evaluation and Field work for Hydraulic Containment System Design
Well Identification
AW-201
AW-202
MW-203
MW-204
MW-205
MW-206
PW-207
Boring Orientation
Angled
Angled
Vertical
Vertical
Vertical
Vertical
Vertical
Minimum Boring Diameter (inches)
4
4
4
4
4
4
6
Drilling Method
Air Hammer
Air Hammer
Coring
Air Hammer
Air Hammer
Air Hammer
Core Air Hammer Over -drilling
Source Area Non-Source Area
Non-Source Area
Source Area
Non-Source Area
Non-Source Area
Source Area
Source Area
Source Area
Rationale for Boring
bull Intercept near-vertical fractures to understand subsurface geology bull Aid in iting MW-203 bull Intercept near-vertical fractures to understand subsurface geology bull Aid in siting PW-201 (Pumping well) bull ion of contamination bull 1 future monitoring location bull Potential reinjection well for hydraulic containment system bull Core for matrix diffusion evaluation bullbullbullbull Ibullbullbullbull 1bullbullbullbull 1bullbull bull 1
tion point for pumping test tion point in tracer test ion of contamination
future monitoring location tion point for pumping test tion point in tracer test ion of contamination
future monitoring location tion point for pumping test tion point in tracer test ion of contamination
future monitoring location tion point for pumping test
test well extraction well
bull Core for matrix diffusion evaluation bull i point for tracer test
TISOW September 30 2003 WOODARD amp CURRAN 20564309
MW-105D MW-5B
Primary Bedding Secondary Cleavage
Tertsry Fracturing
NOTE A total of 60 observations warn made rtrtjs roprtraont tticopy number of obsafvatk noted wtthln each azimutha) segment
MW-1 1 3D euro MW-205
2 AcreSource
Fenced-^ Area i
MW-103D MW-103S
17-Acre Property Boundary
MW-104D MW-1041 bull
MW-104S
Legend Figure 3-1 J Proposed Monitoring Well Proposed Well Locations
o- Site Property Boundary bull^bullProposed Pumping Well Hows Corner Superfund Site -xmdashx- Source Area Plymouth Maine
^ ^Proposed Angled Well bullamp Existing Monitoring Well bullWDODARDampCURRAN
Englnoortng bull Science bull Operations 205643wipsite-8OlaquoAx-opt-1-2-u3-1D
bull During the installation of each angled boring observations will be made regarding water gainloss
drilling rate and bit behavior to assess the depth of potential fractures In addition water levels will be
9 measured in nearby borings using either hand measurements data loggers or both to evaluate
connectivity between locations A change in water level in a nearby boring will indicate a hydraulic
at connection between the borings Borehole geophysics will also be performed on the borings (See Subtask
2 below) Information from each angled boring will be used to site an adjacent vertical well (MW-203
^ and PW-207) so that it intercepts a fracture observed in the angled boring
^ Vertical Borings Two of the vertical borings will be completed with rotary diamond coring to
approximately 100 ft bgs These borings will be adjacent to the angled borings described above One of
^ the cored borings (MW-203) will be located near MW-106 outside of the source area within the
dissolved-phase groundwater plume (see Figure 3-1) The other cored boring (PW-207) will be the
pumping well which is anticipated to be located within the source area in the vicinity of the existing
MW-2 well cluster Coring will allow data collection for several purposes including direct observation
of bedrock for determination of the nature of the rock matrix determination of the location and nature of
fractures and the degree of fracturing comparison with geophysical logs (Subtask 2) to verify
interpretation of the logs and collection of core samples for analysis (Subtask 4)
The remaining borings will be located east of the 2-acre fenced area within or near the periphery of the
source area and will be sited to align approximately with existing wells based on the known fracture
orientations at the Site (MW-204 and MW-205) or with new wells based on the known fracture
pound orientations at the Site (MW-206) Data from these locations in conjunction with the other borings
installed as part of this TI SOW and the existing wells will be used in the interpretation of the pumping
^ test (Subtask 6) and tracer test (Subtask 7) In addition these three borings will further delineate
contamination and provide potential monitoring locations for long-term monitoring Each of these
^ borings will be advanced to approximately 100 ft bgs with a minimum four-inch diameter air hammer
^ During the installation of each boring observations will be made regarding water gainloss drilling rate
and bit behavior to assess the depth of potential fractures In addition water levels will be measured in
nearby borings using either hand measurements data loggers or both to evaluate connectivity between
locations A change in water level in a nearby boring will indicate a hydraulic connection between the
TISOW WOODARD amp CURRAN 12 September 302003 20564309
borings Borehole geophysics and packer testing will also be performed on the borings (See Subtasks 2
and 3 below)
Drilling water will be containerized on site and treated through granular activated carbon (GAC) Treated
water will be analyzed to verify that PCB and VOC concentrations have been reduced to below ARARs
prior to discharge to the ground surface Cuttings will be spread on the ground surface at the site
consistent with the Remedial Investigation work plan
It is anticipated that up to 10 core samples from each cored boring (total of 20 cores) will be collected and
submitted to an off-site laboratory for analyses of porosity (matrix and bulk) permeability bulk density
and fraction of organic carbon (f^) using methods described in Subtask 4
Subtask 2 - Borehole Geophysics
To supplement information on fracture location and connectivity obtained during boring advancement a
borehole geophysical survey will be conducted on the newly installed bedrock borings to evaluate the
nature and orientation of water bearing fractures in the borings The survey will be performed at the
completion of the angled borings and again at the completion of the vertical borings The information
obtained during the survey may be used to identify the location of subsequent boring(s) by refining the
understanding of the depth aperture and orientation of bedrock fractures The following measurements
are proposed for the new borings caliper fluid temperature fluid resistivity and acoustic televiewer
(ATV) Single-point resistively and 16 inch normal measurements will also be made in the first two
borings installed and the data will be compared to data from the other geophysical logs to determine if
the measurements confirm and significantly improve the interpretation regarding the presence of water-
bearing fractures If the measurements are applicable to identification of fractures they may be included
in lieu of other geophysical logs in the remainder of the borings
Subtask 3 - Packer Testing
To further refine information on the aquifer hydraulic conductivity the hydraulic connection between
fractures in the borings will be evaluated during packer testing of vertical borings The data will be used
to estimate the hydraulic conductivity of specific fractures and fracture zones The packer testing will be
performed after the vertical borings have been installed and the borehole geophysical survey completed
TISOW WOODARD amp CURRAN 13 September 30 2003 20564309
bull
m
M
Drilling observations and information from borehole geophysics will be used to identify specific fractures
below the water table that are capable of transmitting water Prior to water injection for hydraulic
conductivity and fracture connectivity testing groundwater samples will be collected at selected intervals
for analysis of VOCs (See Subtask 4) Sampling intervals will be selected based on drilling observations
and logging results that indicate water is moving into or out of the borehole or that fractures exist to
promote water movement such as rapid increase in the amount of water returned rapid change in
temperature or highly fractured interval
^
^
bull
f$
Double packer testing will be performed at selected intervals within each newly installed boring It is
anticipated that up to six intervals per well will be tested for a maximum of 24 intervals and that for each
interval the test will include an approximate 15-minute injection of potable water at four progressively
increasing pressures Packer spacing is anticipated to be 10 ft however spacing may vary so that packers
are not located in potential fracture zones identified using information from rock cores drilling
observations and borehole geophysics The tests at an individual interval will be terminated if it appears
that the interval is not accepting water Care will be taken to minimize over-pumping or over-
pressurizing of the fractures The flow rate will be measured to evaluate the characteristics of the
fracture Water levels in adjacent borings will be measured during the packer testing to determine if a
hydraulic connection exists between the borings Water generated during packer testing will be
containerized on site and treated through GAC Treated water will be analyzed to verify that PCB and
VOC concentrations have been reduced to below ARARs prior to discharge to the ground surface
4 Subtask 4 Sampling and Analysis
~d
^
Rock and groundwater samples will be collected during the field program for laboratory analysis The
results of the analyses will be used to help refine the distribution of the plume and to estimate bedrock
properties These analyses will be used in conjunction with existing data during the TI evaluation to
refine cleanup times and establish the limits of the TI zone
As described in Subtask 1 it is anticipated that up to 10 core samples from each cored boring (total of 20
core samples) will be collected and submitted to an off-site laboratory for analyses of porosity (matrix and
bulk) permeability bulk density and fraction of organic carbon (f^) using existing industry methods
Subject to further evaluation of industry methods Woodard amp Curran proposes that porosity
TISOW WOODARD amp CURRAN20564309
14 September 302003
permeability and density will be measured using methods in the American Petroleum Institutes API RPshy
40 Fraction of organic carbon (f^) will be measured using either the LECO TOC method or Walkey-
Black method The LECO TOC method is a standard method in the petroleum industry and involves the
direct combustion of a ground rock sample The Walkey-Black method is a commonly used USEPA-
approved chemical oxidation method for determination of foe in soils In addition either method could be
used if a sample were scraped from a fracture surface To develop a reasonable range of f for Site
bedrock up to five samples will be selected from each boring from the unfractured matrix and up to five
from the fracture surfaces In addition Woodard amp Curran will evaluate the appropriateness of selecting
rock samples from a subset of the core samples from areas near fractures as well as from non-fractured
areas and submitting the samples for VOC analysis following methanol extraction
Results from these analyses will be used in conjunction with groundwater contaminant concentrations to
evaluate the significance of diffusion of contamination from the bedrock matrix in both the Source Area
and the Non-Source Area Although matrix diffusion likely is a significant factor in the determination of
cleanup times within the Source Area the potential applicability of matrix diffusion in the Non-Source
Area is not known These core analyses may provide evidence to assist in developing an estimate
through calculations of the effect of matrix diffusion on cleanup times
As noted in Subtask 3 prior to injection of water during packer testing groundwater samples will be
collected at selected intervals for analysis of volatile organic compounds (VOCs) Up to a total of 20
groundwater samples plus appropriate quality control samples will be collected from the newly installed
borings The samples will be submitted to an off-site laboratory for analysis Analytical results will be
validated in accordance with USEPA protocol and the data will be managed in WampCs existing
groundwater sampling analytical database for this site
Up to 21 existing monitoring wells from within or nearby the 17-acre property plus four new wells once
constructed will be sampled using low-flow techniques and submitted to an off-site laboratory for VOC
analysis Analytical results will be validated in accordance with USEPA protocol and the data will be
managed in WampCs existing groundwater sampling analytical database for this site
TISOW WOODARD amp CURRAN 15 September 302003 20564309
Subtask 5 - Monitoring Well Installation
Although it is anticipated that the newly installed borings will be left as open holes for tracer testing and
for pumping tests monitoring wells will be installed and developed in the newly installed borings unless
the USEPA MEDEP and PRP Group determine that the location is inappropriate for such use The
monitoring wells will be constructed of two-inch schedule 40 PVC screen and riser Screen intervals will
be selected based on the location of fractures identified during drilling geophysical logging and packer
testing A sand pack will be placed around the screen and will extend from approximately two ft below
the screen to approximately two ft above the screen
Subtask 6 - Pumping Test
WampC will conduct a single constant discharge pumping test to evaluate hydraulic properties of the
aquifer It is anticipated that the test will be conducted in a new pumping well in the vicinity of the
existing MW-2 well cluster within the source area Data from the pumping test will be used in
conjunction with other data from the investigation to improve the understanding of groundwater
movement and contaminant transport in the Source and Non-Source areas The results of the pumping
test will be used to refine the Site conceptual model as well as in the design of the hydraulic containment
system that is being constructed under the authority of the AOC for the RD
The groundwater pumping test will include the following components (1) Pumping test setup (2) Pretest
monitoring (3) Constant Discharge Pumping Test (4) Post-test monitoring and (5) Data Analysis
Pumping Test Setup In support of the groundwater pumping test WampC will install a pumping well
(PW-207) and procure and install the required groundwater extraction treatment and storage equipment at
the Site The well will be cored and over drilled to allow construction of a 4-inch well The location will
be in the vicinity of the MW-2 well cluster and be based upon results of the angled bedrock boring AWshy
202 The equipment will include but not be limited to
bull Down well pump plumbing and appurtances
bull Two (2) 20000 frac tanks
bull Groundwater transfer pumps and controls
bull Settlingaerationsand filtration treatment processes for the treatment of inorganics (if needed) and
nsow WOODARD amp CURRAN 16 September 302003 20564309
bull Granular activated carbon units for the treatment of dissolved organics in the groundwater
The groundwater treatment process will include the following processes 1) an oxidation and filtration
step to remove the inorganics from the groundwater and GAC units to treat the organic contaminants in
the extracted groundwater
Pretest Monitoring Prior to initiation of pumping WampC will monitor water levels in existing wells and
newly installed borings adjacent to the pumping well using a combination of hand measurements and data
loggers to develop an understanding of the piezometric surface under unstressed conditions The wells
proposed for water-level monitoring will be described in the work plan In addition all gauges
transducers flow meters and other equipment used in conducting the pumping tests shall be calibrated
before use
Constant Discharge Pumping Test The pumping test will be conducted in the source area using
newly-installed pumping well PW-207 It is anticipated that the test will be conducted at a pumping rate
of approximately 2 gallons per minute (gpm) for a period of 2 to 3 days however a higher or lower rate
may be shown to be appropriate based on the drilling and packer testing conducted during boring
installation Woodard amp Curran proposes to conduct this test using a vacuum-enhanced recovery system
(VERS) as described in the ROD so that the water level is not lowered appreciably in the vicinity of the
pumping well to prevent the potential migration of NAPLs to deeper bedrock zones The appropriateness
and feasibility of the VERS for the pumping test will be determined by field testing or literature
evaluation prior to completion of the Work Plan Because of the short duration of this test it is not
anticipated that stability of water levels will be reached in observation wells The test will however
provide information to estimate hydraulic conductivity and bedrock storage During the test the water
levels in the pumping well and selected monitoring wells will be logged continuously via down well data
loggers It is anticipated that water levels in approximately 24 wells will be measured using hand
measurements and data loggers
Groundwater extracted during the pumping test will be stored temporarily in an on-site frac tank prior to
on-site treatment and disposal
TISOW WOODARD amp CURRAN 17 September 302003 20564309
Post-Test Monitoring After the pump is turned off in the pumping well water levels will continue to be
monitored using hand measurements and data loggers until they have returned to within 10 of the preshy
test levels For planning purposes this has been estimated to be two weeks
Data Analysis Data collected during the pumping test will be analyzed with Aquifer Win32 Results of
the pumping test will be summarized in the summary data package for the TI Evaluation and the results
will also be used in the design of the hydraulic containment system specified in the Interim ROD that is
being conducted under the authority of the AOC for the RD Detail regarding use of the pumping test
data in hydraulic system design will be provided in the Remedial Design Work Plan
Subtask 7 - Tracer Test
WampC will conduct a tracer test using a conservative tracer to evaluate fracture connectivity porosity
dispersivity and matrix diffusion of the bedrock aquifer in both the Source Area and Non-Source Area
To increase the potential for success of this test results of the pumping test evaluation will be used to
revise the tracer test plan proposed here as necessary Following rebound of water levels after
completion of the pumping test WampC will initiate a single natural gradient tracer test The test will
consist of injecting a tracer into well PW-207 in the source area (Figure 3-1) for up to five days and
monitoring the tracers arrival in nearby wells Borehole geophysics core evaluation and packer testing
will be used to select the specific injection depth(s) in the well
A Tracer Test Work Plan will be completed prior to initiation of injection to determine the type quantity
and concentration of tracer based on the distance between the injection well and the monitoring wells A
conservative tracer that is one that is not preferentially adsorbed to rock or organic matter will be
selected for the tracer test Tracer injection equipment including tanks and flow-regulating and metering
equipment and pumps will be used to mix the tracer at the surface prior to injection Fractures may be
packered in the injection well and tracer solution will be injected at a rate determined during preparation
of the Tracer Test Work Plan During injection the potentiometric surface of the aquifer will be
monitored to verify that the potentiometric surface remains relatively constant during the injection
process
nsow WOODARD amp CURRAN 18 September 302003 20564309
Prior to injection of the tracer background concentration will be established by collecting samples from
up to six wells in the area of the tracer test and analyzing them for the tracer using an appropriate
analytical method Following injection of the tracer solutions the concentration of the tracer in
downgradient wells and borings will be measured A monitoring network will be established using nearby
monitoring wells Downhole probes will be installed in six new and existing wells near the injection well
to be identified in the work plan first to determine the background tracer concentrations and then to
monitor for the presence of the tracer upon initiation of the test Measurements will be collected at
periodic intervals to be determined based on the results of packer testing If an increase in tracer
concentration is detected or at a minimum on a weekly basis a water sample will be collected using low
flow sampling methodologies and analyzed in an off-site laboratory to evaluate the concentration of the
tracer The concentration of the tracer will be recorded Monitoring of the tracer concentration will
continue throughout the duration of the test The tracer will be allowed to flow with groundwater for one
month or until detected in wells in the vicinity of MW-106 whichever is shorter
313 Task 3 - TI Evaluation and Reporting
The TI Evaluation and reporting task includes the following five subtasks
bull Data evaluation
bull Summary data package
bull Draft TI Evaluation
bull Meetings with PRP Group and USEPA and
bull Revise and finalize TI Evaluation
As the subtasks of the field investigation are completed the data will be evaluated for the purpose of
addressing the data gaps identified by USEPA Specifically the data will be used to further refine the
cleanup times for non-source area groundwater presented in the Interim ROD
The data obtained during the field investigation will be reduced and evaluated and a summary data
package will be prepared that will include a discussion of the field activities completed and presentation
of the data It is anticipated that up to two meetings with USEPA will be necessary before the data
evaluation and summary report are completed
TISOW WOODARDampCURRAN 19 September 302003 20564309
Data collected during the pumping test will be analyzed with Aquifer Win32 Results will be summarized
in the summary data package and will also be presented as part of the RD submittals
Following submittal of the summary data package the TI evaluation will be prepared In accordance with
EPA guidance (1993) the TI waiver evaluation document will address the following topics
1 Specific ARARS or media cleanup standards for which TI determination is sought This section of the
TI Evaluation will identify the specific contaminants for which the TI determination is sought Based on
information available to date a waiver may be appropriate for pesticides PCBs chlorinated organic
compounds and other site-related contaminants that upon evaluation will not attain ARARs in a
reasonable period of time
2 Spatial area over which the TI waiver will apply The purpose of the additional site investigation
outlined in this SOW is to obtain the data necessary to further refine cleanup times presented in the
Interim ROD to determine what portions of the Site will not be expected to reach ARARs within a
reasonable time Consistent with TI guidance (USEPA 1993) the TI evaluation will specify the
horizontal and vertical extent of the area for which TI determination is sought Groundwater
concentration data from the RI and the TI SOW will be used to refine the distribution of the plume Data
from the drilling geophysical logging packer testing and pumping and tracer tests will be used to refine
the Site conceptual model and the cleanup times that will serve as the basis for establishing the scope and
nature of the TI zone
3 Conceptual Model The conceptual model forms the technical core of the TI Waiver Evaluation since
it provides basis for understanding of the restoration potential of the site The conceptual model outlines
the physical and hydrogeological constraints that hinder remediation or removal of Site contaminants and
it is the extent of these constraints rather than restoration timeframe alone that USEPA will use to
evaluate the necessity of the TI waiver of ARARs The conceptual model is the link between restoration
potential and restoration timeframe since it explains why proposed technologies are unlikely to work
either at all or within the desired 100-year timeframe
The Site conceptual model is not a mathematical model however as the result of the extensive modeling
and investigations of the site WampC has a strong understanding of the complex bedrock and overburden
TISOW WOODARDampCURRAN 20 September 302003 20564309
groundwater system beneath this site This understanding has been presented previously in both the RI
report and the FS and will be refined based on the TI SOW as necessary and summarized in the TI
Waiver Evaluation with specific attention to the physical and hydrogeological constraints on remediation
In particular the Site conceptual model will be reviewed in light of the new geologic data from drilling
logging and packer testing and the new hydrogeologic data obtained from the pumping test and tracer test
and will be revised to incorporate the new understanding
4 An evaluation of the restoration potential of the site This section will consist of a several components
It will present a systematic review of the technologies potentially capable of remediating the site given
the physical and hydrogeological constraints identified in the site model The newly acquired data will
provide an improved understanding of bedrock hydraulic properties that will allow a more Site-specific
evaluation of technologies The review of technologies will also include review of innovative
technologies and will evaluate whether existing remedial technologies or strategies would be capable of
achieving groundwater restoration at the site in a reasonable timeframe The section reference the FS and
will summarize the alternative remedies considered in the FS focusing on the ability of each to restore
groundwater in a reasonable timeframe It will also include a discussion of the selected hydraulic
containment system in light of the data gathered from the pumping test conducted in conjunction with the
TI SOW
Based on the Batch Flushing Model and using the agreed upon koc data from the RI as well as data from
this TI SOW including the f data collected as part of Subtask 4 a restoration timeframe analysis will be
conducted Following completion of the timeframe analysis and consideration of the results of drilling
rock and water analyses and pumping and tracer test a determination will be made regarding the Source
Area and the portion of the Non-Source Area VOC plume that will not attain ARARs in a reasonable
time
TISOW WOODARD amp CURRAN 21 September 302003 20564309
40 SCHEDULE
A proposed project schedule is included with this plan as Figure 4-1 This schedule is included for
discussion purposes and will be modified as necessary once the final scope of work as been approved by
all parties and the field work activities are coordinated with the subcontractors
TISOW WOODARD amp CURRAN 22 September 302003 20564309
ID
2
3
4
5
6
7 a i 10
11
12
13
14
15
16
17
16
19
20
21
22
24
25
26
27
26
29
30
31
32
Task Name
Project Meeting with EPA
Finalize SOW
Prepare Work Plans QAPP HASP Revision
Submit Work Plans for EPA Approval
Project Meeting with EPA
Revisions to work plans
Submit final work plans
Subcontractor Contracts
Project Meeting wEPA
Field Investigation
Site Mobilization
Install Borings
Borehole Geophysics
Packer Testing amp Collect GW Samples
Pumping Test
Tracer Test
Test setup
Injection
Monitoring
Data Reporting
InstallDevelop Wells
Data Evaluation
Prepare Data Package
Data Package Submittal to EPA
Draft Tl Evaluation Repon
Draft Tl Evaluation Report Submttal to EPA
EPA ReviewComment on Tl Evaluation ReF
Project Meeting wEPA
Revisions to Tl Evaluation Report
Submit Final Tl Evaluation Report
Start
Wed 070903
Thu 071003
Fri 101003
Mon 120103
Mon 121503
Mon 122903
Mon 011204
Tue 011304
Thu 021904
Fri 032104
Fri 032604
Fri 040204
Fri 041604
Fri 042304
Thu 050604
Wed 060204
Wed 060204
Wed 060904
Wed 060904
Wed 062304
Wed 070704
Wed 042804
Wed 062304
Mon 080204
Mon 070504
Tue 082404
Wed 082504
Wed 091504
Thu 0916AM
Thu 093004
Finish
Wed 070903
Fri 1OtO7u3
Fri 112803
Fri 122603
Mon 121503
Fri 010904
Mon 011204
Mon 012604
Thu 021904
Tue 071304
Thu 040104
Thu 042204
Tue 042704
Wed 050504
Tue 052504
Tue 071304
Tue 060804
Tue 061504
Tue 070604
Tue 071304
Fri 070904
Tue 072004
Fri 073004
Mon 080204
Mon 082304
Tue 082404
Tue 091404
Wed 091504
Wed 082904
Thu 093004
FIGURE 4-1 DRAFT HOWS CORNER SUPERFUND SITE
Tl EVALUATION amp RELD WORK FOR HYDRAUUC CONTAINMENT SYSTEM DESIGN PROPOSED PROJECT SCHEDULE
2003 2004 Mav |
Jun | Jul
ltamp i
Aug
i
Sen Oct I Nov Dec Jan Feb I Mar
ii i i
k ^tr 1
1V i
I t bull ^
I
ta^M bull bull M W
l LgtH^HBKLii LJ Mi
I
bull bull raquo bull laquo^ 0930
Task Progress I^MLHHHI^LB Summary ^^^^^^^^f External Tasks M B WMMM Deadline ^7 Project Hows Comer Schedule6A bull bull bull 1 UData Fri 101003 Split Milestone ^ Project Summary ^f^KKKKKK^^ External Milestone ^
Pagei
50 ACRONYMS
AOC Administrative Order by Consent
ARARs Applicable or Relevant and Appropriate Requirements
ATV acoustic televiewer
bgs below ground surface
CERCLA Comprehensive Environmental Resource and Conservation Liability Act
DNAPL Dense Non-Aqueous Phase Liquid
GAC granular activated carbon
gpm gallons per minute
HASP Health and Safety Plan
row investigation-derived waste
MCL Maximum Containment Level
MEDEP Maine Department of Environmental Protection
MEG Maine Enforcement Guideline
mgkg milligrams per kilogram
Hg kg micrograms per kilogram
NCP National Contingency Plan
PCB polychlorinated biphenyl
PID photo ionization detector
ppm parts per million
PRP Potentially Responsible Party
TISOW WOODARD amp CURRAN 24 September 302003 20564309
QAPP Quality Assurance Project Plan
QAQC Quality AssuranceQuality Control
RA Remedial Action
RAO Remedial Action Objective
RCRA Resource Conservation and Recovery Act
RD Remedial Design
RIFS Remedial InvestigationFeasibility Study
ROD Record of Decision
SAP Sampling and Analysis Plan
SOW Statement of Work
TAL target analyte list
TI Technical Impracticability
USEPA United State Environmental Protection Agency
VOCs volatile organic compounds
WampC Woodard amp Curran Inc
TISOW WOODARD amp CURRAN 25 September 302003 20564309
REFERENCES
Everts CJ RS Kanwar (1994) Evaluation of Rhodamine WT as an adsorbed tracer in an agricultural
soil J Hydrology 153 53-70
Kasnavia T D Vu DA Sabatini (1999) Fluorescent dye and media properties affecting sorption and
tracer selection Groundwater 37 376-381
Ptak T G Schmid (1996) Dual-tracer transport experiments in a physically and chemically
heterogeneous porous aquifer effective transport parameters and spatial variability J Hydrology
183 117-138
Sabatini DA T A Austin (1991) Characteristics of Rhodamine WT and fluorescein as adsorbing
ground-water tracers Ground Water 29 341-349
Trudgill ST (1987) Soil water dye tracing with special reference to the use of Rhodamanie WT
Lissamine FF and Amino G acid Hydrological Processes 1 149-170
US Environmental Protection Agency (USEPA) 1993 Guidance for Evaluating the Technical
Impracticability of Ground-Water Restoration - Interim Final Office of Solid Waste and
Emergency Response Washington DC Directive 92342-25 September 1993
US Environmental Protection Agency (USEPA) 2002 Interim Record of Decision Summary shy
Operable Unit One Non-Source Area Groundwater West SiteHows Corner Superfund Site
Plymouth Maine EPA Region 1 September 2002
US Environmental Protection Agency (USEPA) 2003 Proposed Scope of Work West SiteHows
Corner Superfund Site Plymouth Maine EPA Region 1 4 pages September 2002
Vasudevan D RL Fimmen AB Francisco (2001) Tracer-grade Rhodamine WT Structure of
constituent isomers and their sorption behavior Environ Sci Technol 35 4089-4096
nsow WOODARD amp CURRAN 26 September 30 2003 20564309
Woodard amp Curran Inc (WampC) 2002 Final Feasibility Study Report - Non-Source Area Groundwater
Hows Comer Superfund Site Plymouth Maine July 2002
TISOW WOODARD amp CURRAN 27 September 302003 20564309
f
m WOODARD amp CURRAN Maine Massachusetts New Hampshire Connecticut Florida Illinois Operational offices across the US 1-800-426-4262 wwwwoodardcurrancom
i
NonmdashSource Area Groundwater
Source Atea Groundirater
17mdashAcre George West Property
_bdquoVOCugllppm
0
| n r nA
= Volatile Orgamc Compound _ = Microgram per Liter
= Parts per Million
300 600
FEET
Notes 1 Shaded areas based on Maximum Extent of total VOCs j n e | t h e r D e c e m b e r 1 9 9 9 P r e _ R 0 D o r J u n e 2 0 0 0 Supplemental Sampling Events
2 Source Area Groundwater is defined as groundwater with total VOC concentration equal to or greater than 10000 ugl (10 ppm) Extent of Source Area Groundwater plume inferred east of 2-Acre Fenced Area
3 Non Source Area Groundwater is defined as groundwater with total VOC concentrations less then 10000 ugl (10ppm)
Figure 2-1 Site Plan Detail
Hows Corner Superfund Site Plymouth Maine
WOODARD ampCURRAN Engineering bull Science Operations
205643wipsite sowu2-1A
0
Soil within the fenced area of the Site that presented a human health risk was excavated during pilot
testing for the FS and disposed of off-site The three remedial alternatives evaluated in the FS (WampC
bull 2002) were
bull No further Action
lt$ bull Limited Action and
bull Hydraulic Containment
$t As stated in Section 40 of the FS the possible presence of a remnant dense non-aqueous phase liquid
(DNAPL) source within the groundwater plume raises the question as to whether or not complete
restoration of the aquifer can be achieved in a reasonable period of time (eg less than 100 years)
Because of the uncertainties associated with the groundwater recharge rate the mass of DNAPL in
^ Source Area Groundwater the fractional organic carbon (foe) in the bedrock and the tetrachloroethene
(PCE) organic carbon partitioning coefficient (Koc) the restoration potential of both Source Area and
^ Non-Source Area Groundwater could not be assessed within a reasonable degree of scientific certainty in
the FS
The Interim ROD for Operable Unit One Non-Source Area Groundwater (USEPA 2002) was completed
in September 2002 The remedy selected in the Interim ROD consisted of
bull Installation of groundwater extraction and treatment system to contain Source Area Groundwater
bull Monitoring of surface water sediments and Non-Source Area Groundwater to measure the
progress of natural attenuation toward meeting Applicable or Relevant and Appropriate
Requirements (ARARs)
^9 bull Residential well monitoring with a public water contingency
bull Institutional Controls to prevent use of both Source and Non-Source Area Groundwater and
( i bull Five-year Reviews
4) Following completion of the FS Report and preparation of the Interim ROD for Operable Unit One
USEPA requested that further site characterization be completed to assist in making a determination
Jsect concerning the feasibility of attaining ARARs within a reasonable time Section 3 of this SOW outlines
the tasks proposed by the PRP Group to address the requirement for additional Site data necessary for a
pound TI evaluation and containment system design
TISOW WOODARD amp CURRAN 5 September 302003 20564309
bull 30 INVESTIGATION TECHNICAL APPROACH
On behalf of the PRP Group Woodard amp Curran (WampC) has developed a proposed SOW in response to
bull USEPAs request for additional field tasks to further refine the cleanup times presented in the 2002
Interim ROD for this site This approach has been designed to evaluate the following additional data
lt9 needs identified by USEPA to refine cleanup times
4t bull Aquifer hydraulic conductivity
bull Aquifer porosity (matrix and bulk) and
H bull Partitioning of contaminants to the bedrock
^ The data from these additional field tasks will also be used by USEPA to define the TI zone for the Final
ROD and assist the PRPs in developing the design for the hydraulic containment system for the Source
j Area Groundwater which is being conducted under the authority of the RD AOC Details regarding
development of the hydraulic containment system will be presented in the Remedial Design Work Plan
The proposed TI SOW is based on information available during its preparation and may be amended
subject to USEPA approval as additional information regarding subsurface conditions becomes available
during the field investigation The following section describes the overall field investigation approach A
comprehensive presentation of each task in the field investigation will be provided in the Sampling and
bull Analysis Plan (SAP) which will be amended following approval of a final scope of work
bull0 31 Investigative Approach
j The work proposed to meet the additional data requirements stated by USEPA consists of the three
primary tasks described below and further outlined as subtasks Brief descriptions of each task are
presented in the subsections that follow
Task 1 - Project Planning
Task 2 - Field Investigation
Task 3 - TI Evaluation and Reporting
WOODARD amp CURRAN 6 September 302003 20564309
311 Task 1 - Project Planning
Project planning is the first task and includes the following five subtasks
bull Finalize the SOW
bull Prepare work plan
bull Revise existing site-specific Quality Assurance Project Plan (QAPP) Sampling and Analysis
Plan (SAP) and Health and Safety Plan (HASP) and
bull Secure subcontractor contracts
bull Mobilize to the Site and establish a field office
In order to finalize the SOW for this TI evaluation it is anticipated that a minimum of one meeting will
occur between the PRP Group USEPA MEDEP and WampC Once the SOW is finalized the QAPP
SAP and HASP (the Plans) will be revised to incorporate necessary modifications to reflect the agreed-
upon work methods and technology The SAP will be modified to include a detailed plan for the
additional field activities Once the Plans have been revised and the Work Plan prepared they will be
submitted to USEPA for review USEPA comments will be incorporated into the plans and final
approved plans will be issued
After final plans have been issued WampC will negotiate contracts with subcontractors for certain field
activities including boring and monitoring well installation geophysical survey packer testing and
investigation-derived waste (IDW) storage and disposal It is anticipated that a second meeting between
the parties may be needed prior to the commencement of the field activities
Because of the duration of the field activities described in this SOW and the need for on-site evaluation of
field results in order to make program decisions during the investigation WampC will mobilize a trailer to
the Site to serve as a field office The trailer will be equipped with telephone and fax machine
312 Task 2 - Field Investigation
The field investigation task will include the following subtasks
bull Subtask 1 - Boring installation
bull Subtask 2 - Borehole geophysics
TISOW
WOODARDampCURRAN 7 September 302003 20564309
0
0 bull Subtask 3 - Packer testing
bull Subtask 4 - Sampling and analysis
bull bull Subtask 5 - Monitoring well installation
bull Subtask 5 - Pumping test and
bull Subtask 6 - Tracer test
Each of the subtasks is summarized below however a comprehensive discussion of these subtasks and
associated methodologies will be provided in the SAP
Subtask 1 - Boring Installation
j Information obtained during the installation of the new borings will be used in the evaluation of the
aquifer hydraulic conductivity and the analysis of other aquifer properties (eg porosity fracture
frequency) For this subtask it is anticipated that one angled boring will be completed to a depth of 150
feet (ft) below ground surface (bgs) One additional angled boring and four new vertical bedrock borings
will be completed to depths of approximately 100 ft bgs This depth is consistent with the depth
evaluated in the RI and will allow evaluation of bedrock and groundwater properties to depths below the
transition from less competent to more competent bedrock (approximately 50 to 80 ft bgs)
m One additional vertical boring will be installed to a depth of 100 ft bgs as the pumping well location for
bull the pumping test The pumping well location will be based on the results of field work conducted prior to
its installation The proposed drilling program is designed to enhance understanding of the flow system
by aligning new boring locations with existing wells to characterize hydraulic properties of the fracture
network and bulk bedrock Furthermore the program allows for additional characterization of
M contamination in the Source Area groundwater The rationale for the boring locations is summarized in
Table 3-1 and the proposed locations of the borings are depicted on Figure 3-1 Actual locations may
M vary depending on field conditions and accessibility
jlt The drilling protocol employed during installation of both the angled and the vertical wells will allow for
evaluation of the potential presence of DNAPL in the rock and the need for modifications to the drilling
method if DNAPL is detected If sheen or product is observed in the return water core or cuttings from a
boring an interface probe may be employed to determine whether a NAPL is present in the boring
Based on the presence of DNAPL the boring may be terminated at a shallower depth than planned the
J TISOW 4 1 WOODARD amp CURRAN 8 September 302003
20564309
location may be abandoned or other practices may be employed to reduce the potential for causing
downward migration of DNAPL The protocol will be described in the Work Plan and the SAP
Angled Borings Two angled borings will be installed using air-hammer drilling methods The first
angled boring (AW-201) will be installed to a depth of 150 ft bgs in the vicinity of existing well MWshy
106 northeast of and outside of the source area and within the dissolved phase groundwater plume This
well will be angled from the surface toward the southeast at depth in order to intersect as many northwest-
dipping near-vertical fractures as possible The angle of this boring will be approximately 30deg to 40deg
from the vertical resulting in a surface projection of approximately 84 to 126 ft and total length of
approximately 173 to 195 ft The second angled boring (AW-202) will be installed to a depth of 100 ft
bgs in the vicinity of the existing MW-2 well cluster within the source area This well also will be angled
from the surface toward the southeast at depth in order to intersect near-vertical fractures The angle of
this boring will be approximately 30deg to 40deg from the vertical resulting in a surface projection of
approximately 58 to 84 ft and total length of approximately 115 to 130 ft
m
4
sect
i
TISOW WOODARD amp CURRAN 9 September 302003 20564309
Table 3-1
Rationale for Proposed Well Locations
Hows Corner Technical Impracticability Evaluation and Field work for Hydraulic Containment System Design
Well Identification
AW-201
AW-202
MW-203
MW-204
MW-205
MW-206
PW-207
Boring Orientation
Angled
Angled
Vertical
Vertical
Vertical
Vertical
Vertical
Minimum Boring Diameter (inches)
4
4
4
4
4
4
6
Drilling Method
Air Hammer
Air Hammer
Coring
Air Hammer
Air Hammer
Air Hammer
Core Air Hammer Over -drilling
Source Area Non-Source Area
Non-Source Area
Source Area
Non-Source Area
Non-Source Area
Source Area
Source Area
Source Area
Rationale for Boring
bull Intercept near-vertical fractures to understand subsurface geology bull Aid in iting MW-203 bull Intercept near-vertical fractures to understand subsurface geology bull Aid in siting PW-201 (Pumping well) bull ion of contamination bull 1 future monitoring location bull Potential reinjection well for hydraulic containment system bull Core for matrix diffusion evaluation bullbullbullbull Ibullbullbullbull 1bullbullbullbull 1bullbull bull 1
tion point for pumping test tion point in tracer test ion of contamination
future monitoring location tion point for pumping test tion point in tracer test ion of contamination
future monitoring location tion point for pumping test tion point in tracer test ion of contamination
future monitoring location tion point for pumping test
test well extraction well
bull Core for matrix diffusion evaluation bull i point for tracer test
TISOW September 30 2003 WOODARD amp CURRAN 20564309
MW-105D MW-5B
Primary Bedding Secondary Cleavage
Tertsry Fracturing
NOTE A total of 60 observations warn made rtrtjs roprtraont tticopy number of obsafvatk noted wtthln each azimutha) segment
MW-1 1 3D euro MW-205
2 AcreSource
Fenced-^ Area i
MW-103D MW-103S
17-Acre Property Boundary
MW-104D MW-1041 bull
MW-104S
Legend Figure 3-1 J Proposed Monitoring Well Proposed Well Locations
o- Site Property Boundary bull^bullProposed Pumping Well Hows Corner Superfund Site -xmdashx- Source Area Plymouth Maine
^ ^Proposed Angled Well bullamp Existing Monitoring Well bullWDODARDampCURRAN
Englnoortng bull Science bull Operations 205643wipsite-8OlaquoAx-opt-1-2-u3-1D
bull During the installation of each angled boring observations will be made regarding water gainloss
drilling rate and bit behavior to assess the depth of potential fractures In addition water levels will be
9 measured in nearby borings using either hand measurements data loggers or both to evaluate
connectivity between locations A change in water level in a nearby boring will indicate a hydraulic
at connection between the borings Borehole geophysics will also be performed on the borings (See Subtask
2 below) Information from each angled boring will be used to site an adjacent vertical well (MW-203
^ and PW-207) so that it intercepts a fracture observed in the angled boring
^ Vertical Borings Two of the vertical borings will be completed with rotary diamond coring to
approximately 100 ft bgs These borings will be adjacent to the angled borings described above One of
^ the cored borings (MW-203) will be located near MW-106 outside of the source area within the
dissolved-phase groundwater plume (see Figure 3-1) The other cored boring (PW-207) will be the
pumping well which is anticipated to be located within the source area in the vicinity of the existing
MW-2 well cluster Coring will allow data collection for several purposes including direct observation
of bedrock for determination of the nature of the rock matrix determination of the location and nature of
fractures and the degree of fracturing comparison with geophysical logs (Subtask 2) to verify
interpretation of the logs and collection of core samples for analysis (Subtask 4)
The remaining borings will be located east of the 2-acre fenced area within or near the periphery of the
source area and will be sited to align approximately with existing wells based on the known fracture
orientations at the Site (MW-204 and MW-205) or with new wells based on the known fracture
pound orientations at the Site (MW-206) Data from these locations in conjunction with the other borings
installed as part of this TI SOW and the existing wells will be used in the interpretation of the pumping
^ test (Subtask 6) and tracer test (Subtask 7) In addition these three borings will further delineate
contamination and provide potential monitoring locations for long-term monitoring Each of these
^ borings will be advanced to approximately 100 ft bgs with a minimum four-inch diameter air hammer
^ During the installation of each boring observations will be made regarding water gainloss drilling rate
and bit behavior to assess the depth of potential fractures In addition water levels will be measured in
nearby borings using either hand measurements data loggers or both to evaluate connectivity between
locations A change in water level in a nearby boring will indicate a hydraulic connection between the
TISOW WOODARD amp CURRAN 12 September 302003 20564309
borings Borehole geophysics and packer testing will also be performed on the borings (See Subtasks 2
and 3 below)
Drilling water will be containerized on site and treated through granular activated carbon (GAC) Treated
water will be analyzed to verify that PCB and VOC concentrations have been reduced to below ARARs
prior to discharge to the ground surface Cuttings will be spread on the ground surface at the site
consistent with the Remedial Investigation work plan
It is anticipated that up to 10 core samples from each cored boring (total of 20 cores) will be collected and
submitted to an off-site laboratory for analyses of porosity (matrix and bulk) permeability bulk density
and fraction of organic carbon (f^) using methods described in Subtask 4
Subtask 2 - Borehole Geophysics
To supplement information on fracture location and connectivity obtained during boring advancement a
borehole geophysical survey will be conducted on the newly installed bedrock borings to evaluate the
nature and orientation of water bearing fractures in the borings The survey will be performed at the
completion of the angled borings and again at the completion of the vertical borings The information
obtained during the survey may be used to identify the location of subsequent boring(s) by refining the
understanding of the depth aperture and orientation of bedrock fractures The following measurements
are proposed for the new borings caliper fluid temperature fluid resistivity and acoustic televiewer
(ATV) Single-point resistively and 16 inch normal measurements will also be made in the first two
borings installed and the data will be compared to data from the other geophysical logs to determine if
the measurements confirm and significantly improve the interpretation regarding the presence of water-
bearing fractures If the measurements are applicable to identification of fractures they may be included
in lieu of other geophysical logs in the remainder of the borings
Subtask 3 - Packer Testing
To further refine information on the aquifer hydraulic conductivity the hydraulic connection between
fractures in the borings will be evaluated during packer testing of vertical borings The data will be used
to estimate the hydraulic conductivity of specific fractures and fracture zones The packer testing will be
performed after the vertical borings have been installed and the borehole geophysical survey completed
TISOW WOODARD amp CURRAN 13 September 30 2003 20564309
bull
m
M
Drilling observations and information from borehole geophysics will be used to identify specific fractures
below the water table that are capable of transmitting water Prior to water injection for hydraulic
conductivity and fracture connectivity testing groundwater samples will be collected at selected intervals
for analysis of VOCs (See Subtask 4) Sampling intervals will be selected based on drilling observations
and logging results that indicate water is moving into or out of the borehole or that fractures exist to
promote water movement such as rapid increase in the amount of water returned rapid change in
temperature or highly fractured interval
^
^
bull
f$
Double packer testing will be performed at selected intervals within each newly installed boring It is
anticipated that up to six intervals per well will be tested for a maximum of 24 intervals and that for each
interval the test will include an approximate 15-minute injection of potable water at four progressively
increasing pressures Packer spacing is anticipated to be 10 ft however spacing may vary so that packers
are not located in potential fracture zones identified using information from rock cores drilling
observations and borehole geophysics The tests at an individual interval will be terminated if it appears
that the interval is not accepting water Care will be taken to minimize over-pumping or over-
pressurizing of the fractures The flow rate will be measured to evaluate the characteristics of the
fracture Water levels in adjacent borings will be measured during the packer testing to determine if a
hydraulic connection exists between the borings Water generated during packer testing will be
containerized on site and treated through GAC Treated water will be analyzed to verify that PCB and
VOC concentrations have been reduced to below ARARs prior to discharge to the ground surface
4 Subtask 4 Sampling and Analysis
~d
^
Rock and groundwater samples will be collected during the field program for laboratory analysis The
results of the analyses will be used to help refine the distribution of the plume and to estimate bedrock
properties These analyses will be used in conjunction with existing data during the TI evaluation to
refine cleanup times and establish the limits of the TI zone
As described in Subtask 1 it is anticipated that up to 10 core samples from each cored boring (total of 20
core samples) will be collected and submitted to an off-site laboratory for analyses of porosity (matrix and
bulk) permeability bulk density and fraction of organic carbon (f^) using existing industry methods
Subject to further evaluation of industry methods Woodard amp Curran proposes that porosity
TISOW WOODARD amp CURRAN20564309
14 September 302003
permeability and density will be measured using methods in the American Petroleum Institutes API RPshy
40 Fraction of organic carbon (f^) will be measured using either the LECO TOC method or Walkey-
Black method The LECO TOC method is a standard method in the petroleum industry and involves the
direct combustion of a ground rock sample The Walkey-Black method is a commonly used USEPA-
approved chemical oxidation method for determination of foe in soils In addition either method could be
used if a sample were scraped from a fracture surface To develop a reasonable range of f for Site
bedrock up to five samples will be selected from each boring from the unfractured matrix and up to five
from the fracture surfaces In addition Woodard amp Curran will evaluate the appropriateness of selecting
rock samples from a subset of the core samples from areas near fractures as well as from non-fractured
areas and submitting the samples for VOC analysis following methanol extraction
Results from these analyses will be used in conjunction with groundwater contaminant concentrations to
evaluate the significance of diffusion of contamination from the bedrock matrix in both the Source Area
and the Non-Source Area Although matrix diffusion likely is a significant factor in the determination of
cleanup times within the Source Area the potential applicability of matrix diffusion in the Non-Source
Area is not known These core analyses may provide evidence to assist in developing an estimate
through calculations of the effect of matrix diffusion on cleanup times
As noted in Subtask 3 prior to injection of water during packer testing groundwater samples will be
collected at selected intervals for analysis of volatile organic compounds (VOCs) Up to a total of 20
groundwater samples plus appropriate quality control samples will be collected from the newly installed
borings The samples will be submitted to an off-site laboratory for analysis Analytical results will be
validated in accordance with USEPA protocol and the data will be managed in WampCs existing
groundwater sampling analytical database for this site
Up to 21 existing monitoring wells from within or nearby the 17-acre property plus four new wells once
constructed will be sampled using low-flow techniques and submitted to an off-site laboratory for VOC
analysis Analytical results will be validated in accordance with USEPA protocol and the data will be
managed in WampCs existing groundwater sampling analytical database for this site
TISOW WOODARD amp CURRAN 15 September 302003 20564309
Subtask 5 - Monitoring Well Installation
Although it is anticipated that the newly installed borings will be left as open holes for tracer testing and
for pumping tests monitoring wells will be installed and developed in the newly installed borings unless
the USEPA MEDEP and PRP Group determine that the location is inappropriate for such use The
monitoring wells will be constructed of two-inch schedule 40 PVC screen and riser Screen intervals will
be selected based on the location of fractures identified during drilling geophysical logging and packer
testing A sand pack will be placed around the screen and will extend from approximately two ft below
the screen to approximately two ft above the screen
Subtask 6 - Pumping Test
WampC will conduct a single constant discharge pumping test to evaluate hydraulic properties of the
aquifer It is anticipated that the test will be conducted in a new pumping well in the vicinity of the
existing MW-2 well cluster within the source area Data from the pumping test will be used in
conjunction with other data from the investigation to improve the understanding of groundwater
movement and contaminant transport in the Source and Non-Source areas The results of the pumping
test will be used to refine the Site conceptual model as well as in the design of the hydraulic containment
system that is being constructed under the authority of the AOC for the RD
The groundwater pumping test will include the following components (1) Pumping test setup (2) Pretest
monitoring (3) Constant Discharge Pumping Test (4) Post-test monitoring and (5) Data Analysis
Pumping Test Setup In support of the groundwater pumping test WampC will install a pumping well
(PW-207) and procure and install the required groundwater extraction treatment and storage equipment at
the Site The well will be cored and over drilled to allow construction of a 4-inch well The location will
be in the vicinity of the MW-2 well cluster and be based upon results of the angled bedrock boring AWshy
202 The equipment will include but not be limited to
bull Down well pump plumbing and appurtances
bull Two (2) 20000 frac tanks
bull Groundwater transfer pumps and controls
bull Settlingaerationsand filtration treatment processes for the treatment of inorganics (if needed) and
nsow WOODARD amp CURRAN 16 September 302003 20564309
bull Granular activated carbon units for the treatment of dissolved organics in the groundwater
The groundwater treatment process will include the following processes 1) an oxidation and filtration
step to remove the inorganics from the groundwater and GAC units to treat the organic contaminants in
the extracted groundwater
Pretest Monitoring Prior to initiation of pumping WampC will monitor water levels in existing wells and
newly installed borings adjacent to the pumping well using a combination of hand measurements and data
loggers to develop an understanding of the piezometric surface under unstressed conditions The wells
proposed for water-level monitoring will be described in the work plan In addition all gauges
transducers flow meters and other equipment used in conducting the pumping tests shall be calibrated
before use
Constant Discharge Pumping Test The pumping test will be conducted in the source area using
newly-installed pumping well PW-207 It is anticipated that the test will be conducted at a pumping rate
of approximately 2 gallons per minute (gpm) for a period of 2 to 3 days however a higher or lower rate
may be shown to be appropriate based on the drilling and packer testing conducted during boring
installation Woodard amp Curran proposes to conduct this test using a vacuum-enhanced recovery system
(VERS) as described in the ROD so that the water level is not lowered appreciably in the vicinity of the
pumping well to prevent the potential migration of NAPLs to deeper bedrock zones The appropriateness
and feasibility of the VERS for the pumping test will be determined by field testing or literature
evaluation prior to completion of the Work Plan Because of the short duration of this test it is not
anticipated that stability of water levels will be reached in observation wells The test will however
provide information to estimate hydraulic conductivity and bedrock storage During the test the water
levels in the pumping well and selected monitoring wells will be logged continuously via down well data
loggers It is anticipated that water levels in approximately 24 wells will be measured using hand
measurements and data loggers
Groundwater extracted during the pumping test will be stored temporarily in an on-site frac tank prior to
on-site treatment and disposal
TISOW WOODARD amp CURRAN 17 September 302003 20564309
Post-Test Monitoring After the pump is turned off in the pumping well water levels will continue to be
monitored using hand measurements and data loggers until they have returned to within 10 of the preshy
test levels For planning purposes this has been estimated to be two weeks
Data Analysis Data collected during the pumping test will be analyzed with Aquifer Win32 Results of
the pumping test will be summarized in the summary data package for the TI Evaluation and the results
will also be used in the design of the hydraulic containment system specified in the Interim ROD that is
being conducted under the authority of the AOC for the RD Detail regarding use of the pumping test
data in hydraulic system design will be provided in the Remedial Design Work Plan
Subtask 7 - Tracer Test
WampC will conduct a tracer test using a conservative tracer to evaluate fracture connectivity porosity
dispersivity and matrix diffusion of the bedrock aquifer in both the Source Area and Non-Source Area
To increase the potential for success of this test results of the pumping test evaluation will be used to
revise the tracer test plan proposed here as necessary Following rebound of water levels after
completion of the pumping test WampC will initiate a single natural gradient tracer test The test will
consist of injecting a tracer into well PW-207 in the source area (Figure 3-1) for up to five days and
monitoring the tracers arrival in nearby wells Borehole geophysics core evaluation and packer testing
will be used to select the specific injection depth(s) in the well
A Tracer Test Work Plan will be completed prior to initiation of injection to determine the type quantity
and concentration of tracer based on the distance between the injection well and the monitoring wells A
conservative tracer that is one that is not preferentially adsorbed to rock or organic matter will be
selected for the tracer test Tracer injection equipment including tanks and flow-regulating and metering
equipment and pumps will be used to mix the tracer at the surface prior to injection Fractures may be
packered in the injection well and tracer solution will be injected at a rate determined during preparation
of the Tracer Test Work Plan During injection the potentiometric surface of the aquifer will be
monitored to verify that the potentiometric surface remains relatively constant during the injection
process
nsow WOODARD amp CURRAN 18 September 302003 20564309
Prior to injection of the tracer background concentration will be established by collecting samples from
up to six wells in the area of the tracer test and analyzing them for the tracer using an appropriate
analytical method Following injection of the tracer solutions the concentration of the tracer in
downgradient wells and borings will be measured A monitoring network will be established using nearby
monitoring wells Downhole probes will be installed in six new and existing wells near the injection well
to be identified in the work plan first to determine the background tracer concentrations and then to
monitor for the presence of the tracer upon initiation of the test Measurements will be collected at
periodic intervals to be determined based on the results of packer testing If an increase in tracer
concentration is detected or at a minimum on a weekly basis a water sample will be collected using low
flow sampling methodologies and analyzed in an off-site laboratory to evaluate the concentration of the
tracer The concentration of the tracer will be recorded Monitoring of the tracer concentration will
continue throughout the duration of the test The tracer will be allowed to flow with groundwater for one
month or until detected in wells in the vicinity of MW-106 whichever is shorter
313 Task 3 - TI Evaluation and Reporting
The TI Evaluation and reporting task includes the following five subtasks
bull Data evaluation
bull Summary data package
bull Draft TI Evaluation
bull Meetings with PRP Group and USEPA and
bull Revise and finalize TI Evaluation
As the subtasks of the field investigation are completed the data will be evaluated for the purpose of
addressing the data gaps identified by USEPA Specifically the data will be used to further refine the
cleanup times for non-source area groundwater presented in the Interim ROD
The data obtained during the field investigation will be reduced and evaluated and a summary data
package will be prepared that will include a discussion of the field activities completed and presentation
of the data It is anticipated that up to two meetings with USEPA will be necessary before the data
evaluation and summary report are completed
TISOW WOODARDampCURRAN 19 September 302003 20564309
Data collected during the pumping test will be analyzed with Aquifer Win32 Results will be summarized
in the summary data package and will also be presented as part of the RD submittals
Following submittal of the summary data package the TI evaluation will be prepared In accordance with
EPA guidance (1993) the TI waiver evaluation document will address the following topics
1 Specific ARARS or media cleanup standards for which TI determination is sought This section of the
TI Evaluation will identify the specific contaminants for which the TI determination is sought Based on
information available to date a waiver may be appropriate for pesticides PCBs chlorinated organic
compounds and other site-related contaminants that upon evaluation will not attain ARARs in a
reasonable period of time
2 Spatial area over which the TI waiver will apply The purpose of the additional site investigation
outlined in this SOW is to obtain the data necessary to further refine cleanup times presented in the
Interim ROD to determine what portions of the Site will not be expected to reach ARARs within a
reasonable time Consistent with TI guidance (USEPA 1993) the TI evaluation will specify the
horizontal and vertical extent of the area for which TI determination is sought Groundwater
concentration data from the RI and the TI SOW will be used to refine the distribution of the plume Data
from the drilling geophysical logging packer testing and pumping and tracer tests will be used to refine
the Site conceptual model and the cleanup times that will serve as the basis for establishing the scope and
nature of the TI zone
3 Conceptual Model The conceptual model forms the technical core of the TI Waiver Evaluation since
it provides basis for understanding of the restoration potential of the site The conceptual model outlines
the physical and hydrogeological constraints that hinder remediation or removal of Site contaminants and
it is the extent of these constraints rather than restoration timeframe alone that USEPA will use to
evaluate the necessity of the TI waiver of ARARs The conceptual model is the link between restoration
potential and restoration timeframe since it explains why proposed technologies are unlikely to work
either at all or within the desired 100-year timeframe
The Site conceptual model is not a mathematical model however as the result of the extensive modeling
and investigations of the site WampC has a strong understanding of the complex bedrock and overburden
TISOW WOODARDampCURRAN 20 September 302003 20564309
groundwater system beneath this site This understanding has been presented previously in both the RI
report and the FS and will be refined based on the TI SOW as necessary and summarized in the TI
Waiver Evaluation with specific attention to the physical and hydrogeological constraints on remediation
In particular the Site conceptual model will be reviewed in light of the new geologic data from drilling
logging and packer testing and the new hydrogeologic data obtained from the pumping test and tracer test
and will be revised to incorporate the new understanding
4 An evaluation of the restoration potential of the site This section will consist of a several components
It will present a systematic review of the technologies potentially capable of remediating the site given
the physical and hydrogeological constraints identified in the site model The newly acquired data will
provide an improved understanding of bedrock hydraulic properties that will allow a more Site-specific
evaluation of technologies The review of technologies will also include review of innovative
technologies and will evaluate whether existing remedial technologies or strategies would be capable of
achieving groundwater restoration at the site in a reasonable timeframe The section reference the FS and
will summarize the alternative remedies considered in the FS focusing on the ability of each to restore
groundwater in a reasonable timeframe It will also include a discussion of the selected hydraulic
containment system in light of the data gathered from the pumping test conducted in conjunction with the
TI SOW
Based on the Batch Flushing Model and using the agreed upon koc data from the RI as well as data from
this TI SOW including the f data collected as part of Subtask 4 a restoration timeframe analysis will be
conducted Following completion of the timeframe analysis and consideration of the results of drilling
rock and water analyses and pumping and tracer test a determination will be made regarding the Source
Area and the portion of the Non-Source Area VOC plume that will not attain ARARs in a reasonable
time
TISOW WOODARD amp CURRAN 21 September 302003 20564309
40 SCHEDULE
A proposed project schedule is included with this plan as Figure 4-1 This schedule is included for
discussion purposes and will be modified as necessary once the final scope of work as been approved by
all parties and the field work activities are coordinated with the subcontractors
TISOW WOODARD amp CURRAN 22 September 302003 20564309
ID
2
3
4
5
6
7 a i 10
11
12
13
14
15
16
17
16
19
20
21
22
24
25
26
27
26
29
30
31
32
Task Name
Project Meeting with EPA
Finalize SOW
Prepare Work Plans QAPP HASP Revision
Submit Work Plans for EPA Approval
Project Meeting with EPA
Revisions to work plans
Submit final work plans
Subcontractor Contracts
Project Meeting wEPA
Field Investigation
Site Mobilization
Install Borings
Borehole Geophysics
Packer Testing amp Collect GW Samples
Pumping Test
Tracer Test
Test setup
Injection
Monitoring
Data Reporting
InstallDevelop Wells
Data Evaluation
Prepare Data Package
Data Package Submittal to EPA
Draft Tl Evaluation Repon
Draft Tl Evaluation Report Submttal to EPA
EPA ReviewComment on Tl Evaluation ReF
Project Meeting wEPA
Revisions to Tl Evaluation Report
Submit Final Tl Evaluation Report
Start
Wed 070903
Thu 071003
Fri 101003
Mon 120103
Mon 121503
Mon 122903
Mon 011204
Tue 011304
Thu 021904
Fri 032104
Fri 032604
Fri 040204
Fri 041604
Fri 042304
Thu 050604
Wed 060204
Wed 060204
Wed 060904
Wed 060904
Wed 062304
Wed 070704
Wed 042804
Wed 062304
Mon 080204
Mon 070504
Tue 082404
Wed 082504
Wed 091504
Thu 0916AM
Thu 093004
Finish
Wed 070903
Fri 1OtO7u3
Fri 112803
Fri 122603
Mon 121503
Fri 010904
Mon 011204
Mon 012604
Thu 021904
Tue 071304
Thu 040104
Thu 042204
Tue 042704
Wed 050504
Tue 052504
Tue 071304
Tue 060804
Tue 061504
Tue 070604
Tue 071304
Fri 070904
Tue 072004
Fri 073004
Mon 080204
Mon 082304
Tue 082404
Tue 091404
Wed 091504
Wed 082904
Thu 093004
FIGURE 4-1 DRAFT HOWS CORNER SUPERFUND SITE
Tl EVALUATION amp RELD WORK FOR HYDRAUUC CONTAINMENT SYSTEM DESIGN PROPOSED PROJECT SCHEDULE
2003 2004 Mav |
Jun | Jul
ltamp i
Aug
i
Sen Oct I Nov Dec Jan Feb I Mar
ii i i
k ^tr 1
1V i
I t bull ^
I
ta^M bull bull M W
l LgtH^HBKLii LJ Mi
I
bull bull raquo bull laquo^ 0930
Task Progress I^MLHHHI^LB Summary ^^^^^^^^f External Tasks M B WMMM Deadline ^7 Project Hows Comer Schedule6A bull bull bull 1 UData Fri 101003 Split Milestone ^ Project Summary ^f^KKKKKK^^ External Milestone ^
Pagei
50 ACRONYMS
AOC Administrative Order by Consent
ARARs Applicable or Relevant and Appropriate Requirements
ATV acoustic televiewer
bgs below ground surface
CERCLA Comprehensive Environmental Resource and Conservation Liability Act
DNAPL Dense Non-Aqueous Phase Liquid
GAC granular activated carbon
gpm gallons per minute
HASP Health and Safety Plan
row investigation-derived waste
MCL Maximum Containment Level
MEDEP Maine Department of Environmental Protection
MEG Maine Enforcement Guideline
mgkg milligrams per kilogram
Hg kg micrograms per kilogram
NCP National Contingency Plan
PCB polychlorinated biphenyl
PID photo ionization detector
ppm parts per million
PRP Potentially Responsible Party
TISOW WOODARD amp CURRAN 24 September 302003 20564309
QAPP Quality Assurance Project Plan
QAQC Quality AssuranceQuality Control
RA Remedial Action
RAO Remedial Action Objective
RCRA Resource Conservation and Recovery Act
RD Remedial Design
RIFS Remedial InvestigationFeasibility Study
ROD Record of Decision
SAP Sampling and Analysis Plan
SOW Statement of Work
TAL target analyte list
TI Technical Impracticability
USEPA United State Environmental Protection Agency
VOCs volatile organic compounds
WampC Woodard amp Curran Inc
TISOW WOODARD amp CURRAN 25 September 302003 20564309
REFERENCES
Everts CJ RS Kanwar (1994) Evaluation of Rhodamine WT as an adsorbed tracer in an agricultural
soil J Hydrology 153 53-70
Kasnavia T D Vu DA Sabatini (1999) Fluorescent dye and media properties affecting sorption and
tracer selection Groundwater 37 376-381
Ptak T G Schmid (1996) Dual-tracer transport experiments in a physically and chemically
heterogeneous porous aquifer effective transport parameters and spatial variability J Hydrology
183 117-138
Sabatini DA T A Austin (1991) Characteristics of Rhodamine WT and fluorescein as adsorbing
ground-water tracers Ground Water 29 341-349
Trudgill ST (1987) Soil water dye tracing with special reference to the use of Rhodamanie WT
Lissamine FF and Amino G acid Hydrological Processes 1 149-170
US Environmental Protection Agency (USEPA) 1993 Guidance for Evaluating the Technical
Impracticability of Ground-Water Restoration - Interim Final Office of Solid Waste and
Emergency Response Washington DC Directive 92342-25 September 1993
US Environmental Protection Agency (USEPA) 2002 Interim Record of Decision Summary shy
Operable Unit One Non-Source Area Groundwater West SiteHows Corner Superfund Site
Plymouth Maine EPA Region 1 September 2002
US Environmental Protection Agency (USEPA) 2003 Proposed Scope of Work West SiteHows
Corner Superfund Site Plymouth Maine EPA Region 1 4 pages September 2002
Vasudevan D RL Fimmen AB Francisco (2001) Tracer-grade Rhodamine WT Structure of
constituent isomers and their sorption behavior Environ Sci Technol 35 4089-4096
nsow WOODARD amp CURRAN 26 September 30 2003 20564309
Woodard amp Curran Inc (WampC) 2002 Final Feasibility Study Report - Non-Source Area Groundwater
Hows Comer Superfund Site Plymouth Maine July 2002
TISOW WOODARD amp CURRAN 27 September 302003 20564309
f
m WOODARD amp CURRAN Maine Massachusetts New Hampshire Connecticut Florida Illinois Operational offices across the US 1-800-426-4262 wwwwoodardcurrancom
i
0
Soil within the fenced area of the Site that presented a human health risk was excavated during pilot
testing for the FS and disposed of off-site The three remedial alternatives evaluated in the FS (WampC
bull 2002) were
bull No further Action
lt$ bull Limited Action and
bull Hydraulic Containment
$t As stated in Section 40 of the FS the possible presence of a remnant dense non-aqueous phase liquid
(DNAPL) source within the groundwater plume raises the question as to whether or not complete
restoration of the aquifer can be achieved in a reasonable period of time (eg less than 100 years)
Because of the uncertainties associated with the groundwater recharge rate the mass of DNAPL in
^ Source Area Groundwater the fractional organic carbon (foe) in the bedrock and the tetrachloroethene
(PCE) organic carbon partitioning coefficient (Koc) the restoration potential of both Source Area and
^ Non-Source Area Groundwater could not be assessed within a reasonable degree of scientific certainty in
the FS
The Interim ROD for Operable Unit One Non-Source Area Groundwater (USEPA 2002) was completed
in September 2002 The remedy selected in the Interim ROD consisted of
bull Installation of groundwater extraction and treatment system to contain Source Area Groundwater
bull Monitoring of surface water sediments and Non-Source Area Groundwater to measure the
progress of natural attenuation toward meeting Applicable or Relevant and Appropriate
Requirements (ARARs)
^9 bull Residential well monitoring with a public water contingency
bull Institutional Controls to prevent use of both Source and Non-Source Area Groundwater and
( i bull Five-year Reviews
4) Following completion of the FS Report and preparation of the Interim ROD for Operable Unit One
USEPA requested that further site characterization be completed to assist in making a determination
Jsect concerning the feasibility of attaining ARARs within a reasonable time Section 3 of this SOW outlines
the tasks proposed by the PRP Group to address the requirement for additional Site data necessary for a
pound TI evaluation and containment system design
TISOW WOODARD amp CURRAN 5 September 302003 20564309
bull 30 INVESTIGATION TECHNICAL APPROACH
On behalf of the PRP Group Woodard amp Curran (WampC) has developed a proposed SOW in response to
bull USEPAs request for additional field tasks to further refine the cleanup times presented in the 2002
Interim ROD for this site This approach has been designed to evaluate the following additional data
lt9 needs identified by USEPA to refine cleanup times
4t bull Aquifer hydraulic conductivity
bull Aquifer porosity (matrix and bulk) and
H bull Partitioning of contaminants to the bedrock
^ The data from these additional field tasks will also be used by USEPA to define the TI zone for the Final
ROD and assist the PRPs in developing the design for the hydraulic containment system for the Source
j Area Groundwater which is being conducted under the authority of the RD AOC Details regarding
development of the hydraulic containment system will be presented in the Remedial Design Work Plan
The proposed TI SOW is based on information available during its preparation and may be amended
subject to USEPA approval as additional information regarding subsurface conditions becomes available
during the field investigation The following section describes the overall field investigation approach A
comprehensive presentation of each task in the field investigation will be provided in the Sampling and
bull Analysis Plan (SAP) which will be amended following approval of a final scope of work
bull0 31 Investigative Approach
j The work proposed to meet the additional data requirements stated by USEPA consists of the three
primary tasks described below and further outlined as subtasks Brief descriptions of each task are
presented in the subsections that follow
Task 1 - Project Planning
Task 2 - Field Investigation
Task 3 - TI Evaluation and Reporting
WOODARD amp CURRAN 6 September 302003 20564309
311 Task 1 - Project Planning
Project planning is the first task and includes the following five subtasks
bull Finalize the SOW
bull Prepare work plan
bull Revise existing site-specific Quality Assurance Project Plan (QAPP) Sampling and Analysis
Plan (SAP) and Health and Safety Plan (HASP) and
bull Secure subcontractor contracts
bull Mobilize to the Site and establish a field office
In order to finalize the SOW for this TI evaluation it is anticipated that a minimum of one meeting will
occur between the PRP Group USEPA MEDEP and WampC Once the SOW is finalized the QAPP
SAP and HASP (the Plans) will be revised to incorporate necessary modifications to reflect the agreed-
upon work methods and technology The SAP will be modified to include a detailed plan for the
additional field activities Once the Plans have been revised and the Work Plan prepared they will be
submitted to USEPA for review USEPA comments will be incorporated into the plans and final
approved plans will be issued
After final plans have been issued WampC will negotiate contracts with subcontractors for certain field
activities including boring and monitoring well installation geophysical survey packer testing and
investigation-derived waste (IDW) storage and disposal It is anticipated that a second meeting between
the parties may be needed prior to the commencement of the field activities
Because of the duration of the field activities described in this SOW and the need for on-site evaluation of
field results in order to make program decisions during the investigation WampC will mobilize a trailer to
the Site to serve as a field office The trailer will be equipped with telephone and fax machine
312 Task 2 - Field Investigation
The field investigation task will include the following subtasks
bull Subtask 1 - Boring installation
bull Subtask 2 - Borehole geophysics
TISOW
WOODARDampCURRAN 7 September 302003 20564309
0
0 bull Subtask 3 - Packer testing
bull Subtask 4 - Sampling and analysis
bull bull Subtask 5 - Monitoring well installation
bull Subtask 5 - Pumping test and
bull Subtask 6 - Tracer test
Each of the subtasks is summarized below however a comprehensive discussion of these subtasks and
associated methodologies will be provided in the SAP
Subtask 1 - Boring Installation
j Information obtained during the installation of the new borings will be used in the evaluation of the
aquifer hydraulic conductivity and the analysis of other aquifer properties (eg porosity fracture
frequency) For this subtask it is anticipated that one angled boring will be completed to a depth of 150
feet (ft) below ground surface (bgs) One additional angled boring and four new vertical bedrock borings
will be completed to depths of approximately 100 ft bgs This depth is consistent with the depth
evaluated in the RI and will allow evaluation of bedrock and groundwater properties to depths below the
transition from less competent to more competent bedrock (approximately 50 to 80 ft bgs)
m One additional vertical boring will be installed to a depth of 100 ft bgs as the pumping well location for
bull the pumping test The pumping well location will be based on the results of field work conducted prior to
its installation The proposed drilling program is designed to enhance understanding of the flow system
by aligning new boring locations with existing wells to characterize hydraulic properties of the fracture
network and bulk bedrock Furthermore the program allows for additional characterization of
M contamination in the Source Area groundwater The rationale for the boring locations is summarized in
Table 3-1 and the proposed locations of the borings are depicted on Figure 3-1 Actual locations may
M vary depending on field conditions and accessibility
jlt The drilling protocol employed during installation of both the angled and the vertical wells will allow for
evaluation of the potential presence of DNAPL in the rock and the need for modifications to the drilling
method if DNAPL is detected If sheen or product is observed in the return water core or cuttings from a
boring an interface probe may be employed to determine whether a NAPL is present in the boring
Based on the presence of DNAPL the boring may be terminated at a shallower depth than planned the
J TISOW 4 1 WOODARD amp CURRAN 8 September 302003
20564309
location may be abandoned or other practices may be employed to reduce the potential for causing
downward migration of DNAPL The protocol will be described in the Work Plan and the SAP
Angled Borings Two angled borings will be installed using air-hammer drilling methods The first
angled boring (AW-201) will be installed to a depth of 150 ft bgs in the vicinity of existing well MWshy
106 northeast of and outside of the source area and within the dissolved phase groundwater plume This
well will be angled from the surface toward the southeast at depth in order to intersect as many northwest-
dipping near-vertical fractures as possible The angle of this boring will be approximately 30deg to 40deg
from the vertical resulting in a surface projection of approximately 84 to 126 ft and total length of
approximately 173 to 195 ft The second angled boring (AW-202) will be installed to a depth of 100 ft
bgs in the vicinity of the existing MW-2 well cluster within the source area This well also will be angled
from the surface toward the southeast at depth in order to intersect near-vertical fractures The angle of
this boring will be approximately 30deg to 40deg from the vertical resulting in a surface projection of
approximately 58 to 84 ft and total length of approximately 115 to 130 ft
m
4
sect
i
TISOW WOODARD amp CURRAN 9 September 302003 20564309
Table 3-1
Rationale for Proposed Well Locations
Hows Corner Technical Impracticability Evaluation and Field work for Hydraulic Containment System Design
Well Identification
AW-201
AW-202
MW-203
MW-204
MW-205
MW-206
PW-207
Boring Orientation
Angled
Angled
Vertical
Vertical
Vertical
Vertical
Vertical
Minimum Boring Diameter (inches)
4
4
4
4
4
4
6
Drilling Method
Air Hammer
Air Hammer
Coring
Air Hammer
Air Hammer
Air Hammer
Core Air Hammer Over -drilling
Source Area Non-Source Area
Non-Source Area
Source Area
Non-Source Area
Non-Source Area
Source Area
Source Area
Source Area
Rationale for Boring
bull Intercept near-vertical fractures to understand subsurface geology bull Aid in iting MW-203 bull Intercept near-vertical fractures to understand subsurface geology bull Aid in siting PW-201 (Pumping well) bull ion of contamination bull 1 future monitoring location bull Potential reinjection well for hydraulic containment system bull Core for matrix diffusion evaluation bullbullbullbull Ibullbullbullbull 1bullbullbullbull 1bullbull bull 1
tion point for pumping test tion point in tracer test ion of contamination
future monitoring location tion point for pumping test tion point in tracer test ion of contamination
future monitoring location tion point for pumping test tion point in tracer test ion of contamination
future monitoring location tion point for pumping test
test well extraction well
bull Core for matrix diffusion evaluation bull i point for tracer test
TISOW September 30 2003 WOODARD amp CURRAN 20564309
MW-105D MW-5B
Primary Bedding Secondary Cleavage
Tertsry Fracturing
NOTE A total of 60 observations warn made rtrtjs roprtraont tticopy number of obsafvatk noted wtthln each azimutha) segment
MW-1 1 3D euro MW-205
2 AcreSource
Fenced-^ Area i
MW-103D MW-103S
17-Acre Property Boundary
MW-104D MW-1041 bull
MW-104S
Legend Figure 3-1 J Proposed Monitoring Well Proposed Well Locations
o- Site Property Boundary bull^bullProposed Pumping Well Hows Corner Superfund Site -xmdashx- Source Area Plymouth Maine
^ ^Proposed Angled Well bullamp Existing Monitoring Well bullWDODARDampCURRAN
Englnoortng bull Science bull Operations 205643wipsite-8OlaquoAx-opt-1-2-u3-1D
bull During the installation of each angled boring observations will be made regarding water gainloss
drilling rate and bit behavior to assess the depth of potential fractures In addition water levels will be
9 measured in nearby borings using either hand measurements data loggers or both to evaluate
connectivity between locations A change in water level in a nearby boring will indicate a hydraulic
at connection between the borings Borehole geophysics will also be performed on the borings (See Subtask
2 below) Information from each angled boring will be used to site an adjacent vertical well (MW-203
^ and PW-207) so that it intercepts a fracture observed in the angled boring
^ Vertical Borings Two of the vertical borings will be completed with rotary diamond coring to
approximately 100 ft bgs These borings will be adjacent to the angled borings described above One of
^ the cored borings (MW-203) will be located near MW-106 outside of the source area within the
dissolved-phase groundwater plume (see Figure 3-1) The other cored boring (PW-207) will be the
pumping well which is anticipated to be located within the source area in the vicinity of the existing
MW-2 well cluster Coring will allow data collection for several purposes including direct observation
of bedrock for determination of the nature of the rock matrix determination of the location and nature of
fractures and the degree of fracturing comparison with geophysical logs (Subtask 2) to verify
interpretation of the logs and collection of core samples for analysis (Subtask 4)
The remaining borings will be located east of the 2-acre fenced area within or near the periphery of the
source area and will be sited to align approximately with existing wells based on the known fracture
orientations at the Site (MW-204 and MW-205) or with new wells based on the known fracture
pound orientations at the Site (MW-206) Data from these locations in conjunction with the other borings
installed as part of this TI SOW and the existing wells will be used in the interpretation of the pumping
^ test (Subtask 6) and tracer test (Subtask 7) In addition these three borings will further delineate
contamination and provide potential monitoring locations for long-term monitoring Each of these
^ borings will be advanced to approximately 100 ft bgs with a minimum four-inch diameter air hammer
^ During the installation of each boring observations will be made regarding water gainloss drilling rate
and bit behavior to assess the depth of potential fractures In addition water levels will be measured in
nearby borings using either hand measurements data loggers or both to evaluate connectivity between
locations A change in water level in a nearby boring will indicate a hydraulic connection between the
TISOW WOODARD amp CURRAN 12 September 302003 20564309
borings Borehole geophysics and packer testing will also be performed on the borings (See Subtasks 2
and 3 below)
Drilling water will be containerized on site and treated through granular activated carbon (GAC) Treated
water will be analyzed to verify that PCB and VOC concentrations have been reduced to below ARARs
prior to discharge to the ground surface Cuttings will be spread on the ground surface at the site
consistent with the Remedial Investigation work plan
It is anticipated that up to 10 core samples from each cored boring (total of 20 cores) will be collected and
submitted to an off-site laboratory for analyses of porosity (matrix and bulk) permeability bulk density
and fraction of organic carbon (f^) using methods described in Subtask 4
Subtask 2 - Borehole Geophysics
To supplement information on fracture location and connectivity obtained during boring advancement a
borehole geophysical survey will be conducted on the newly installed bedrock borings to evaluate the
nature and orientation of water bearing fractures in the borings The survey will be performed at the
completion of the angled borings and again at the completion of the vertical borings The information
obtained during the survey may be used to identify the location of subsequent boring(s) by refining the
understanding of the depth aperture and orientation of bedrock fractures The following measurements
are proposed for the new borings caliper fluid temperature fluid resistivity and acoustic televiewer
(ATV) Single-point resistively and 16 inch normal measurements will also be made in the first two
borings installed and the data will be compared to data from the other geophysical logs to determine if
the measurements confirm and significantly improve the interpretation regarding the presence of water-
bearing fractures If the measurements are applicable to identification of fractures they may be included
in lieu of other geophysical logs in the remainder of the borings
Subtask 3 - Packer Testing
To further refine information on the aquifer hydraulic conductivity the hydraulic connection between
fractures in the borings will be evaluated during packer testing of vertical borings The data will be used
to estimate the hydraulic conductivity of specific fractures and fracture zones The packer testing will be
performed after the vertical borings have been installed and the borehole geophysical survey completed
TISOW WOODARD amp CURRAN 13 September 30 2003 20564309
bull
m
M
Drilling observations and information from borehole geophysics will be used to identify specific fractures
below the water table that are capable of transmitting water Prior to water injection for hydraulic
conductivity and fracture connectivity testing groundwater samples will be collected at selected intervals
for analysis of VOCs (See Subtask 4) Sampling intervals will be selected based on drilling observations
and logging results that indicate water is moving into or out of the borehole or that fractures exist to
promote water movement such as rapid increase in the amount of water returned rapid change in
temperature or highly fractured interval
^
^
bull
f$
Double packer testing will be performed at selected intervals within each newly installed boring It is
anticipated that up to six intervals per well will be tested for a maximum of 24 intervals and that for each
interval the test will include an approximate 15-minute injection of potable water at four progressively
increasing pressures Packer spacing is anticipated to be 10 ft however spacing may vary so that packers
are not located in potential fracture zones identified using information from rock cores drilling
observations and borehole geophysics The tests at an individual interval will be terminated if it appears
that the interval is not accepting water Care will be taken to minimize over-pumping or over-
pressurizing of the fractures The flow rate will be measured to evaluate the characteristics of the
fracture Water levels in adjacent borings will be measured during the packer testing to determine if a
hydraulic connection exists between the borings Water generated during packer testing will be
containerized on site and treated through GAC Treated water will be analyzed to verify that PCB and
VOC concentrations have been reduced to below ARARs prior to discharge to the ground surface
4 Subtask 4 Sampling and Analysis
~d
^
Rock and groundwater samples will be collected during the field program for laboratory analysis The
results of the analyses will be used to help refine the distribution of the plume and to estimate bedrock
properties These analyses will be used in conjunction with existing data during the TI evaluation to
refine cleanup times and establish the limits of the TI zone
As described in Subtask 1 it is anticipated that up to 10 core samples from each cored boring (total of 20
core samples) will be collected and submitted to an off-site laboratory for analyses of porosity (matrix and
bulk) permeability bulk density and fraction of organic carbon (f^) using existing industry methods
Subject to further evaluation of industry methods Woodard amp Curran proposes that porosity
TISOW WOODARD amp CURRAN20564309
14 September 302003
permeability and density will be measured using methods in the American Petroleum Institutes API RPshy
40 Fraction of organic carbon (f^) will be measured using either the LECO TOC method or Walkey-
Black method The LECO TOC method is a standard method in the petroleum industry and involves the
direct combustion of a ground rock sample The Walkey-Black method is a commonly used USEPA-
approved chemical oxidation method for determination of foe in soils In addition either method could be
used if a sample were scraped from a fracture surface To develop a reasonable range of f for Site
bedrock up to five samples will be selected from each boring from the unfractured matrix and up to five
from the fracture surfaces In addition Woodard amp Curran will evaluate the appropriateness of selecting
rock samples from a subset of the core samples from areas near fractures as well as from non-fractured
areas and submitting the samples for VOC analysis following methanol extraction
Results from these analyses will be used in conjunction with groundwater contaminant concentrations to
evaluate the significance of diffusion of contamination from the bedrock matrix in both the Source Area
and the Non-Source Area Although matrix diffusion likely is a significant factor in the determination of
cleanup times within the Source Area the potential applicability of matrix diffusion in the Non-Source
Area is not known These core analyses may provide evidence to assist in developing an estimate
through calculations of the effect of matrix diffusion on cleanup times
As noted in Subtask 3 prior to injection of water during packer testing groundwater samples will be
collected at selected intervals for analysis of volatile organic compounds (VOCs) Up to a total of 20
groundwater samples plus appropriate quality control samples will be collected from the newly installed
borings The samples will be submitted to an off-site laboratory for analysis Analytical results will be
validated in accordance with USEPA protocol and the data will be managed in WampCs existing
groundwater sampling analytical database for this site
Up to 21 existing monitoring wells from within or nearby the 17-acre property plus four new wells once
constructed will be sampled using low-flow techniques and submitted to an off-site laboratory for VOC
analysis Analytical results will be validated in accordance with USEPA protocol and the data will be
managed in WampCs existing groundwater sampling analytical database for this site
TISOW WOODARD amp CURRAN 15 September 302003 20564309
Subtask 5 - Monitoring Well Installation
Although it is anticipated that the newly installed borings will be left as open holes for tracer testing and
for pumping tests monitoring wells will be installed and developed in the newly installed borings unless
the USEPA MEDEP and PRP Group determine that the location is inappropriate for such use The
monitoring wells will be constructed of two-inch schedule 40 PVC screen and riser Screen intervals will
be selected based on the location of fractures identified during drilling geophysical logging and packer
testing A sand pack will be placed around the screen and will extend from approximately two ft below
the screen to approximately two ft above the screen
Subtask 6 - Pumping Test
WampC will conduct a single constant discharge pumping test to evaluate hydraulic properties of the
aquifer It is anticipated that the test will be conducted in a new pumping well in the vicinity of the
existing MW-2 well cluster within the source area Data from the pumping test will be used in
conjunction with other data from the investigation to improve the understanding of groundwater
movement and contaminant transport in the Source and Non-Source areas The results of the pumping
test will be used to refine the Site conceptual model as well as in the design of the hydraulic containment
system that is being constructed under the authority of the AOC for the RD
The groundwater pumping test will include the following components (1) Pumping test setup (2) Pretest
monitoring (3) Constant Discharge Pumping Test (4) Post-test monitoring and (5) Data Analysis
Pumping Test Setup In support of the groundwater pumping test WampC will install a pumping well
(PW-207) and procure and install the required groundwater extraction treatment and storage equipment at
the Site The well will be cored and over drilled to allow construction of a 4-inch well The location will
be in the vicinity of the MW-2 well cluster and be based upon results of the angled bedrock boring AWshy
202 The equipment will include but not be limited to
bull Down well pump plumbing and appurtances
bull Two (2) 20000 frac tanks
bull Groundwater transfer pumps and controls
bull Settlingaerationsand filtration treatment processes for the treatment of inorganics (if needed) and
nsow WOODARD amp CURRAN 16 September 302003 20564309
bull Granular activated carbon units for the treatment of dissolved organics in the groundwater
The groundwater treatment process will include the following processes 1) an oxidation and filtration
step to remove the inorganics from the groundwater and GAC units to treat the organic contaminants in
the extracted groundwater
Pretest Monitoring Prior to initiation of pumping WampC will monitor water levels in existing wells and
newly installed borings adjacent to the pumping well using a combination of hand measurements and data
loggers to develop an understanding of the piezometric surface under unstressed conditions The wells
proposed for water-level monitoring will be described in the work plan In addition all gauges
transducers flow meters and other equipment used in conducting the pumping tests shall be calibrated
before use
Constant Discharge Pumping Test The pumping test will be conducted in the source area using
newly-installed pumping well PW-207 It is anticipated that the test will be conducted at a pumping rate
of approximately 2 gallons per minute (gpm) for a period of 2 to 3 days however a higher or lower rate
may be shown to be appropriate based on the drilling and packer testing conducted during boring
installation Woodard amp Curran proposes to conduct this test using a vacuum-enhanced recovery system
(VERS) as described in the ROD so that the water level is not lowered appreciably in the vicinity of the
pumping well to prevent the potential migration of NAPLs to deeper bedrock zones The appropriateness
and feasibility of the VERS for the pumping test will be determined by field testing or literature
evaluation prior to completion of the Work Plan Because of the short duration of this test it is not
anticipated that stability of water levels will be reached in observation wells The test will however
provide information to estimate hydraulic conductivity and bedrock storage During the test the water
levels in the pumping well and selected monitoring wells will be logged continuously via down well data
loggers It is anticipated that water levels in approximately 24 wells will be measured using hand
measurements and data loggers
Groundwater extracted during the pumping test will be stored temporarily in an on-site frac tank prior to
on-site treatment and disposal
TISOW WOODARD amp CURRAN 17 September 302003 20564309
Post-Test Monitoring After the pump is turned off in the pumping well water levels will continue to be
monitored using hand measurements and data loggers until they have returned to within 10 of the preshy
test levels For planning purposes this has been estimated to be two weeks
Data Analysis Data collected during the pumping test will be analyzed with Aquifer Win32 Results of
the pumping test will be summarized in the summary data package for the TI Evaluation and the results
will also be used in the design of the hydraulic containment system specified in the Interim ROD that is
being conducted under the authority of the AOC for the RD Detail regarding use of the pumping test
data in hydraulic system design will be provided in the Remedial Design Work Plan
Subtask 7 - Tracer Test
WampC will conduct a tracer test using a conservative tracer to evaluate fracture connectivity porosity
dispersivity and matrix diffusion of the bedrock aquifer in both the Source Area and Non-Source Area
To increase the potential for success of this test results of the pumping test evaluation will be used to
revise the tracer test plan proposed here as necessary Following rebound of water levels after
completion of the pumping test WampC will initiate a single natural gradient tracer test The test will
consist of injecting a tracer into well PW-207 in the source area (Figure 3-1) for up to five days and
monitoring the tracers arrival in nearby wells Borehole geophysics core evaluation and packer testing
will be used to select the specific injection depth(s) in the well
A Tracer Test Work Plan will be completed prior to initiation of injection to determine the type quantity
and concentration of tracer based on the distance between the injection well and the monitoring wells A
conservative tracer that is one that is not preferentially adsorbed to rock or organic matter will be
selected for the tracer test Tracer injection equipment including tanks and flow-regulating and metering
equipment and pumps will be used to mix the tracer at the surface prior to injection Fractures may be
packered in the injection well and tracer solution will be injected at a rate determined during preparation
of the Tracer Test Work Plan During injection the potentiometric surface of the aquifer will be
monitored to verify that the potentiometric surface remains relatively constant during the injection
process
nsow WOODARD amp CURRAN 18 September 302003 20564309
Prior to injection of the tracer background concentration will be established by collecting samples from
up to six wells in the area of the tracer test and analyzing them for the tracer using an appropriate
analytical method Following injection of the tracer solutions the concentration of the tracer in
downgradient wells and borings will be measured A monitoring network will be established using nearby
monitoring wells Downhole probes will be installed in six new and existing wells near the injection well
to be identified in the work plan first to determine the background tracer concentrations and then to
monitor for the presence of the tracer upon initiation of the test Measurements will be collected at
periodic intervals to be determined based on the results of packer testing If an increase in tracer
concentration is detected or at a minimum on a weekly basis a water sample will be collected using low
flow sampling methodologies and analyzed in an off-site laboratory to evaluate the concentration of the
tracer The concentration of the tracer will be recorded Monitoring of the tracer concentration will
continue throughout the duration of the test The tracer will be allowed to flow with groundwater for one
month or until detected in wells in the vicinity of MW-106 whichever is shorter
313 Task 3 - TI Evaluation and Reporting
The TI Evaluation and reporting task includes the following five subtasks
bull Data evaluation
bull Summary data package
bull Draft TI Evaluation
bull Meetings with PRP Group and USEPA and
bull Revise and finalize TI Evaluation
As the subtasks of the field investigation are completed the data will be evaluated for the purpose of
addressing the data gaps identified by USEPA Specifically the data will be used to further refine the
cleanup times for non-source area groundwater presented in the Interim ROD
The data obtained during the field investigation will be reduced and evaluated and a summary data
package will be prepared that will include a discussion of the field activities completed and presentation
of the data It is anticipated that up to two meetings with USEPA will be necessary before the data
evaluation and summary report are completed
TISOW WOODARDampCURRAN 19 September 302003 20564309
Data collected during the pumping test will be analyzed with Aquifer Win32 Results will be summarized
in the summary data package and will also be presented as part of the RD submittals
Following submittal of the summary data package the TI evaluation will be prepared In accordance with
EPA guidance (1993) the TI waiver evaluation document will address the following topics
1 Specific ARARS or media cleanup standards for which TI determination is sought This section of the
TI Evaluation will identify the specific contaminants for which the TI determination is sought Based on
information available to date a waiver may be appropriate for pesticides PCBs chlorinated organic
compounds and other site-related contaminants that upon evaluation will not attain ARARs in a
reasonable period of time
2 Spatial area over which the TI waiver will apply The purpose of the additional site investigation
outlined in this SOW is to obtain the data necessary to further refine cleanup times presented in the
Interim ROD to determine what portions of the Site will not be expected to reach ARARs within a
reasonable time Consistent with TI guidance (USEPA 1993) the TI evaluation will specify the
horizontal and vertical extent of the area for which TI determination is sought Groundwater
concentration data from the RI and the TI SOW will be used to refine the distribution of the plume Data
from the drilling geophysical logging packer testing and pumping and tracer tests will be used to refine
the Site conceptual model and the cleanup times that will serve as the basis for establishing the scope and
nature of the TI zone
3 Conceptual Model The conceptual model forms the technical core of the TI Waiver Evaluation since
it provides basis for understanding of the restoration potential of the site The conceptual model outlines
the physical and hydrogeological constraints that hinder remediation or removal of Site contaminants and
it is the extent of these constraints rather than restoration timeframe alone that USEPA will use to
evaluate the necessity of the TI waiver of ARARs The conceptual model is the link between restoration
potential and restoration timeframe since it explains why proposed technologies are unlikely to work
either at all or within the desired 100-year timeframe
The Site conceptual model is not a mathematical model however as the result of the extensive modeling
and investigations of the site WampC has a strong understanding of the complex bedrock and overburden
TISOW WOODARDampCURRAN 20 September 302003 20564309
groundwater system beneath this site This understanding has been presented previously in both the RI
report and the FS and will be refined based on the TI SOW as necessary and summarized in the TI
Waiver Evaluation with specific attention to the physical and hydrogeological constraints on remediation
In particular the Site conceptual model will be reviewed in light of the new geologic data from drilling
logging and packer testing and the new hydrogeologic data obtained from the pumping test and tracer test
and will be revised to incorporate the new understanding
4 An evaluation of the restoration potential of the site This section will consist of a several components
It will present a systematic review of the technologies potentially capable of remediating the site given
the physical and hydrogeological constraints identified in the site model The newly acquired data will
provide an improved understanding of bedrock hydraulic properties that will allow a more Site-specific
evaluation of technologies The review of technologies will also include review of innovative
technologies and will evaluate whether existing remedial technologies or strategies would be capable of
achieving groundwater restoration at the site in a reasonable timeframe The section reference the FS and
will summarize the alternative remedies considered in the FS focusing on the ability of each to restore
groundwater in a reasonable timeframe It will also include a discussion of the selected hydraulic
containment system in light of the data gathered from the pumping test conducted in conjunction with the
TI SOW
Based on the Batch Flushing Model and using the agreed upon koc data from the RI as well as data from
this TI SOW including the f data collected as part of Subtask 4 a restoration timeframe analysis will be
conducted Following completion of the timeframe analysis and consideration of the results of drilling
rock and water analyses and pumping and tracer test a determination will be made regarding the Source
Area and the portion of the Non-Source Area VOC plume that will not attain ARARs in a reasonable
time
TISOW WOODARD amp CURRAN 21 September 302003 20564309
40 SCHEDULE
A proposed project schedule is included with this plan as Figure 4-1 This schedule is included for
discussion purposes and will be modified as necessary once the final scope of work as been approved by
all parties and the field work activities are coordinated with the subcontractors
TISOW WOODARD amp CURRAN 22 September 302003 20564309
ID
2
3
4
5
6
7 a i 10
11
12
13
14
15
16
17
16
19
20
21
22
24
25
26
27
26
29
30
31
32
Task Name
Project Meeting with EPA
Finalize SOW
Prepare Work Plans QAPP HASP Revision
Submit Work Plans for EPA Approval
Project Meeting with EPA
Revisions to work plans
Submit final work plans
Subcontractor Contracts
Project Meeting wEPA
Field Investigation
Site Mobilization
Install Borings
Borehole Geophysics
Packer Testing amp Collect GW Samples
Pumping Test
Tracer Test
Test setup
Injection
Monitoring
Data Reporting
InstallDevelop Wells
Data Evaluation
Prepare Data Package
Data Package Submittal to EPA
Draft Tl Evaluation Repon
Draft Tl Evaluation Report Submttal to EPA
EPA ReviewComment on Tl Evaluation ReF
Project Meeting wEPA
Revisions to Tl Evaluation Report
Submit Final Tl Evaluation Report
Start
Wed 070903
Thu 071003
Fri 101003
Mon 120103
Mon 121503
Mon 122903
Mon 011204
Tue 011304
Thu 021904
Fri 032104
Fri 032604
Fri 040204
Fri 041604
Fri 042304
Thu 050604
Wed 060204
Wed 060204
Wed 060904
Wed 060904
Wed 062304
Wed 070704
Wed 042804
Wed 062304
Mon 080204
Mon 070504
Tue 082404
Wed 082504
Wed 091504
Thu 0916AM
Thu 093004
Finish
Wed 070903
Fri 1OtO7u3
Fri 112803
Fri 122603
Mon 121503
Fri 010904
Mon 011204
Mon 012604
Thu 021904
Tue 071304
Thu 040104
Thu 042204
Tue 042704
Wed 050504
Tue 052504
Tue 071304
Tue 060804
Tue 061504
Tue 070604
Tue 071304
Fri 070904
Tue 072004
Fri 073004
Mon 080204
Mon 082304
Tue 082404
Tue 091404
Wed 091504
Wed 082904
Thu 093004
FIGURE 4-1 DRAFT HOWS CORNER SUPERFUND SITE
Tl EVALUATION amp RELD WORK FOR HYDRAUUC CONTAINMENT SYSTEM DESIGN PROPOSED PROJECT SCHEDULE
2003 2004 Mav |
Jun | Jul
ltamp i
Aug
i
Sen Oct I Nov Dec Jan Feb I Mar
ii i i
k ^tr 1
1V i
I t bull ^
I
ta^M bull bull M W
l LgtH^HBKLii LJ Mi
I
bull bull raquo bull laquo^ 0930
Task Progress I^MLHHHI^LB Summary ^^^^^^^^f External Tasks M B WMMM Deadline ^7 Project Hows Comer Schedule6A bull bull bull 1 UData Fri 101003 Split Milestone ^ Project Summary ^f^KKKKKK^^ External Milestone ^
Pagei
50 ACRONYMS
AOC Administrative Order by Consent
ARARs Applicable or Relevant and Appropriate Requirements
ATV acoustic televiewer
bgs below ground surface
CERCLA Comprehensive Environmental Resource and Conservation Liability Act
DNAPL Dense Non-Aqueous Phase Liquid
GAC granular activated carbon
gpm gallons per minute
HASP Health and Safety Plan
row investigation-derived waste
MCL Maximum Containment Level
MEDEP Maine Department of Environmental Protection
MEG Maine Enforcement Guideline
mgkg milligrams per kilogram
Hg kg micrograms per kilogram
NCP National Contingency Plan
PCB polychlorinated biphenyl
PID photo ionization detector
ppm parts per million
PRP Potentially Responsible Party
TISOW WOODARD amp CURRAN 24 September 302003 20564309
QAPP Quality Assurance Project Plan
QAQC Quality AssuranceQuality Control
RA Remedial Action
RAO Remedial Action Objective
RCRA Resource Conservation and Recovery Act
RD Remedial Design
RIFS Remedial InvestigationFeasibility Study
ROD Record of Decision
SAP Sampling and Analysis Plan
SOW Statement of Work
TAL target analyte list
TI Technical Impracticability
USEPA United State Environmental Protection Agency
VOCs volatile organic compounds
WampC Woodard amp Curran Inc
TISOW WOODARD amp CURRAN 25 September 302003 20564309
REFERENCES
Everts CJ RS Kanwar (1994) Evaluation of Rhodamine WT as an adsorbed tracer in an agricultural
soil J Hydrology 153 53-70
Kasnavia T D Vu DA Sabatini (1999) Fluorescent dye and media properties affecting sorption and
tracer selection Groundwater 37 376-381
Ptak T G Schmid (1996) Dual-tracer transport experiments in a physically and chemically
heterogeneous porous aquifer effective transport parameters and spatial variability J Hydrology
183 117-138
Sabatini DA T A Austin (1991) Characteristics of Rhodamine WT and fluorescein as adsorbing
ground-water tracers Ground Water 29 341-349
Trudgill ST (1987) Soil water dye tracing with special reference to the use of Rhodamanie WT
Lissamine FF and Amino G acid Hydrological Processes 1 149-170
US Environmental Protection Agency (USEPA) 1993 Guidance for Evaluating the Technical
Impracticability of Ground-Water Restoration - Interim Final Office of Solid Waste and
Emergency Response Washington DC Directive 92342-25 September 1993
US Environmental Protection Agency (USEPA) 2002 Interim Record of Decision Summary shy
Operable Unit One Non-Source Area Groundwater West SiteHows Corner Superfund Site
Plymouth Maine EPA Region 1 September 2002
US Environmental Protection Agency (USEPA) 2003 Proposed Scope of Work West SiteHows
Corner Superfund Site Plymouth Maine EPA Region 1 4 pages September 2002
Vasudevan D RL Fimmen AB Francisco (2001) Tracer-grade Rhodamine WT Structure of
constituent isomers and their sorption behavior Environ Sci Technol 35 4089-4096
nsow WOODARD amp CURRAN 26 September 30 2003 20564309
Woodard amp Curran Inc (WampC) 2002 Final Feasibility Study Report - Non-Source Area Groundwater
Hows Comer Superfund Site Plymouth Maine July 2002
TISOW WOODARD amp CURRAN 27 September 302003 20564309
f
m WOODARD amp CURRAN Maine Massachusetts New Hampshire Connecticut Florida Illinois Operational offices across the US 1-800-426-4262 wwwwoodardcurrancom
i
bull 30 INVESTIGATION TECHNICAL APPROACH
On behalf of the PRP Group Woodard amp Curran (WampC) has developed a proposed SOW in response to
bull USEPAs request for additional field tasks to further refine the cleanup times presented in the 2002
Interim ROD for this site This approach has been designed to evaluate the following additional data
lt9 needs identified by USEPA to refine cleanup times
4t bull Aquifer hydraulic conductivity
bull Aquifer porosity (matrix and bulk) and
H bull Partitioning of contaminants to the bedrock
^ The data from these additional field tasks will also be used by USEPA to define the TI zone for the Final
ROD and assist the PRPs in developing the design for the hydraulic containment system for the Source
j Area Groundwater which is being conducted under the authority of the RD AOC Details regarding
development of the hydraulic containment system will be presented in the Remedial Design Work Plan
The proposed TI SOW is based on information available during its preparation and may be amended
subject to USEPA approval as additional information regarding subsurface conditions becomes available
during the field investigation The following section describes the overall field investigation approach A
comprehensive presentation of each task in the field investigation will be provided in the Sampling and
bull Analysis Plan (SAP) which will be amended following approval of a final scope of work
bull0 31 Investigative Approach
j The work proposed to meet the additional data requirements stated by USEPA consists of the three
primary tasks described below and further outlined as subtasks Brief descriptions of each task are
presented in the subsections that follow
Task 1 - Project Planning
Task 2 - Field Investigation
Task 3 - TI Evaluation and Reporting
WOODARD amp CURRAN 6 September 302003 20564309
311 Task 1 - Project Planning
Project planning is the first task and includes the following five subtasks
bull Finalize the SOW
bull Prepare work plan
bull Revise existing site-specific Quality Assurance Project Plan (QAPP) Sampling and Analysis
Plan (SAP) and Health and Safety Plan (HASP) and
bull Secure subcontractor contracts
bull Mobilize to the Site and establish a field office
In order to finalize the SOW for this TI evaluation it is anticipated that a minimum of one meeting will
occur between the PRP Group USEPA MEDEP and WampC Once the SOW is finalized the QAPP
SAP and HASP (the Plans) will be revised to incorporate necessary modifications to reflect the agreed-
upon work methods and technology The SAP will be modified to include a detailed plan for the
additional field activities Once the Plans have been revised and the Work Plan prepared they will be
submitted to USEPA for review USEPA comments will be incorporated into the plans and final
approved plans will be issued
After final plans have been issued WampC will negotiate contracts with subcontractors for certain field
activities including boring and monitoring well installation geophysical survey packer testing and
investigation-derived waste (IDW) storage and disposal It is anticipated that a second meeting between
the parties may be needed prior to the commencement of the field activities
Because of the duration of the field activities described in this SOW and the need for on-site evaluation of
field results in order to make program decisions during the investigation WampC will mobilize a trailer to
the Site to serve as a field office The trailer will be equipped with telephone and fax machine
312 Task 2 - Field Investigation
The field investigation task will include the following subtasks
bull Subtask 1 - Boring installation
bull Subtask 2 - Borehole geophysics
TISOW
WOODARDampCURRAN 7 September 302003 20564309
0
0 bull Subtask 3 - Packer testing
bull Subtask 4 - Sampling and analysis
bull bull Subtask 5 - Monitoring well installation
bull Subtask 5 - Pumping test and
bull Subtask 6 - Tracer test
Each of the subtasks is summarized below however a comprehensive discussion of these subtasks and
associated methodologies will be provided in the SAP
Subtask 1 - Boring Installation
j Information obtained during the installation of the new borings will be used in the evaluation of the
aquifer hydraulic conductivity and the analysis of other aquifer properties (eg porosity fracture
frequency) For this subtask it is anticipated that one angled boring will be completed to a depth of 150
feet (ft) below ground surface (bgs) One additional angled boring and four new vertical bedrock borings
will be completed to depths of approximately 100 ft bgs This depth is consistent with the depth
evaluated in the RI and will allow evaluation of bedrock and groundwater properties to depths below the
transition from less competent to more competent bedrock (approximately 50 to 80 ft bgs)
m One additional vertical boring will be installed to a depth of 100 ft bgs as the pumping well location for
bull the pumping test The pumping well location will be based on the results of field work conducted prior to
its installation The proposed drilling program is designed to enhance understanding of the flow system
by aligning new boring locations with existing wells to characterize hydraulic properties of the fracture
network and bulk bedrock Furthermore the program allows for additional characterization of
M contamination in the Source Area groundwater The rationale for the boring locations is summarized in
Table 3-1 and the proposed locations of the borings are depicted on Figure 3-1 Actual locations may
M vary depending on field conditions and accessibility
jlt The drilling protocol employed during installation of both the angled and the vertical wells will allow for
evaluation of the potential presence of DNAPL in the rock and the need for modifications to the drilling
method if DNAPL is detected If sheen or product is observed in the return water core or cuttings from a
boring an interface probe may be employed to determine whether a NAPL is present in the boring
Based on the presence of DNAPL the boring may be terminated at a shallower depth than planned the
J TISOW 4 1 WOODARD amp CURRAN 8 September 302003
20564309
location may be abandoned or other practices may be employed to reduce the potential for causing
downward migration of DNAPL The protocol will be described in the Work Plan and the SAP
Angled Borings Two angled borings will be installed using air-hammer drilling methods The first
angled boring (AW-201) will be installed to a depth of 150 ft bgs in the vicinity of existing well MWshy
106 northeast of and outside of the source area and within the dissolved phase groundwater plume This
well will be angled from the surface toward the southeast at depth in order to intersect as many northwest-
dipping near-vertical fractures as possible The angle of this boring will be approximately 30deg to 40deg
from the vertical resulting in a surface projection of approximately 84 to 126 ft and total length of
approximately 173 to 195 ft The second angled boring (AW-202) will be installed to a depth of 100 ft
bgs in the vicinity of the existing MW-2 well cluster within the source area This well also will be angled
from the surface toward the southeast at depth in order to intersect near-vertical fractures The angle of
this boring will be approximately 30deg to 40deg from the vertical resulting in a surface projection of
approximately 58 to 84 ft and total length of approximately 115 to 130 ft
m
4
sect
i
TISOW WOODARD amp CURRAN 9 September 302003 20564309
Table 3-1
Rationale for Proposed Well Locations
Hows Corner Technical Impracticability Evaluation and Field work for Hydraulic Containment System Design
Well Identification
AW-201
AW-202
MW-203
MW-204
MW-205
MW-206
PW-207
Boring Orientation
Angled
Angled
Vertical
Vertical
Vertical
Vertical
Vertical
Minimum Boring Diameter (inches)
4
4
4
4
4
4
6
Drilling Method
Air Hammer
Air Hammer
Coring
Air Hammer
Air Hammer
Air Hammer
Core Air Hammer Over -drilling
Source Area Non-Source Area
Non-Source Area
Source Area
Non-Source Area
Non-Source Area
Source Area
Source Area
Source Area
Rationale for Boring
bull Intercept near-vertical fractures to understand subsurface geology bull Aid in iting MW-203 bull Intercept near-vertical fractures to understand subsurface geology bull Aid in siting PW-201 (Pumping well) bull ion of contamination bull 1 future monitoring location bull Potential reinjection well for hydraulic containment system bull Core for matrix diffusion evaluation bullbullbullbull Ibullbullbullbull 1bullbullbullbull 1bullbull bull 1
tion point for pumping test tion point in tracer test ion of contamination
future monitoring location tion point for pumping test tion point in tracer test ion of contamination
future monitoring location tion point for pumping test tion point in tracer test ion of contamination
future monitoring location tion point for pumping test
test well extraction well
bull Core for matrix diffusion evaluation bull i point for tracer test
TISOW September 30 2003 WOODARD amp CURRAN 20564309
MW-105D MW-5B
Primary Bedding Secondary Cleavage
Tertsry Fracturing
NOTE A total of 60 observations warn made rtrtjs roprtraont tticopy number of obsafvatk noted wtthln each azimutha) segment
MW-1 1 3D euro MW-205
2 AcreSource
Fenced-^ Area i
MW-103D MW-103S
17-Acre Property Boundary
MW-104D MW-1041 bull
MW-104S
Legend Figure 3-1 J Proposed Monitoring Well Proposed Well Locations
o- Site Property Boundary bull^bullProposed Pumping Well Hows Corner Superfund Site -xmdashx- Source Area Plymouth Maine
^ ^Proposed Angled Well bullamp Existing Monitoring Well bullWDODARDampCURRAN
Englnoortng bull Science bull Operations 205643wipsite-8OlaquoAx-opt-1-2-u3-1D
bull During the installation of each angled boring observations will be made regarding water gainloss
drilling rate and bit behavior to assess the depth of potential fractures In addition water levels will be
9 measured in nearby borings using either hand measurements data loggers or both to evaluate
connectivity between locations A change in water level in a nearby boring will indicate a hydraulic
at connection between the borings Borehole geophysics will also be performed on the borings (See Subtask
2 below) Information from each angled boring will be used to site an adjacent vertical well (MW-203
^ and PW-207) so that it intercepts a fracture observed in the angled boring
^ Vertical Borings Two of the vertical borings will be completed with rotary diamond coring to
approximately 100 ft bgs These borings will be adjacent to the angled borings described above One of
^ the cored borings (MW-203) will be located near MW-106 outside of the source area within the
dissolved-phase groundwater plume (see Figure 3-1) The other cored boring (PW-207) will be the
pumping well which is anticipated to be located within the source area in the vicinity of the existing
MW-2 well cluster Coring will allow data collection for several purposes including direct observation
of bedrock for determination of the nature of the rock matrix determination of the location and nature of
fractures and the degree of fracturing comparison with geophysical logs (Subtask 2) to verify
interpretation of the logs and collection of core samples for analysis (Subtask 4)
The remaining borings will be located east of the 2-acre fenced area within or near the periphery of the
source area and will be sited to align approximately with existing wells based on the known fracture
orientations at the Site (MW-204 and MW-205) or with new wells based on the known fracture
pound orientations at the Site (MW-206) Data from these locations in conjunction with the other borings
installed as part of this TI SOW and the existing wells will be used in the interpretation of the pumping
^ test (Subtask 6) and tracer test (Subtask 7) In addition these three borings will further delineate
contamination and provide potential monitoring locations for long-term monitoring Each of these
^ borings will be advanced to approximately 100 ft bgs with a minimum four-inch diameter air hammer
^ During the installation of each boring observations will be made regarding water gainloss drilling rate
and bit behavior to assess the depth of potential fractures In addition water levels will be measured in
nearby borings using either hand measurements data loggers or both to evaluate connectivity between
locations A change in water level in a nearby boring will indicate a hydraulic connection between the
TISOW WOODARD amp CURRAN 12 September 302003 20564309
borings Borehole geophysics and packer testing will also be performed on the borings (See Subtasks 2
and 3 below)
Drilling water will be containerized on site and treated through granular activated carbon (GAC) Treated
water will be analyzed to verify that PCB and VOC concentrations have been reduced to below ARARs
prior to discharge to the ground surface Cuttings will be spread on the ground surface at the site
consistent with the Remedial Investigation work plan
It is anticipated that up to 10 core samples from each cored boring (total of 20 cores) will be collected and
submitted to an off-site laboratory for analyses of porosity (matrix and bulk) permeability bulk density
and fraction of organic carbon (f^) using methods described in Subtask 4
Subtask 2 - Borehole Geophysics
To supplement information on fracture location and connectivity obtained during boring advancement a
borehole geophysical survey will be conducted on the newly installed bedrock borings to evaluate the
nature and orientation of water bearing fractures in the borings The survey will be performed at the
completion of the angled borings and again at the completion of the vertical borings The information
obtained during the survey may be used to identify the location of subsequent boring(s) by refining the
understanding of the depth aperture and orientation of bedrock fractures The following measurements
are proposed for the new borings caliper fluid temperature fluid resistivity and acoustic televiewer
(ATV) Single-point resistively and 16 inch normal measurements will also be made in the first two
borings installed and the data will be compared to data from the other geophysical logs to determine if
the measurements confirm and significantly improve the interpretation regarding the presence of water-
bearing fractures If the measurements are applicable to identification of fractures they may be included
in lieu of other geophysical logs in the remainder of the borings
Subtask 3 - Packer Testing
To further refine information on the aquifer hydraulic conductivity the hydraulic connection between
fractures in the borings will be evaluated during packer testing of vertical borings The data will be used
to estimate the hydraulic conductivity of specific fractures and fracture zones The packer testing will be
performed after the vertical borings have been installed and the borehole geophysical survey completed
TISOW WOODARD amp CURRAN 13 September 30 2003 20564309
bull
m
M
Drilling observations and information from borehole geophysics will be used to identify specific fractures
below the water table that are capable of transmitting water Prior to water injection for hydraulic
conductivity and fracture connectivity testing groundwater samples will be collected at selected intervals
for analysis of VOCs (See Subtask 4) Sampling intervals will be selected based on drilling observations
and logging results that indicate water is moving into or out of the borehole or that fractures exist to
promote water movement such as rapid increase in the amount of water returned rapid change in
temperature or highly fractured interval
^
^
bull
f$
Double packer testing will be performed at selected intervals within each newly installed boring It is
anticipated that up to six intervals per well will be tested for a maximum of 24 intervals and that for each
interval the test will include an approximate 15-minute injection of potable water at four progressively
increasing pressures Packer spacing is anticipated to be 10 ft however spacing may vary so that packers
are not located in potential fracture zones identified using information from rock cores drilling
observations and borehole geophysics The tests at an individual interval will be terminated if it appears
that the interval is not accepting water Care will be taken to minimize over-pumping or over-
pressurizing of the fractures The flow rate will be measured to evaluate the characteristics of the
fracture Water levels in adjacent borings will be measured during the packer testing to determine if a
hydraulic connection exists between the borings Water generated during packer testing will be
containerized on site and treated through GAC Treated water will be analyzed to verify that PCB and
VOC concentrations have been reduced to below ARARs prior to discharge to the ground surface
4 Subtask 4 Sampling and Analysis
~d
^
Rock and groundwater samples will be collected during the field program for laboratory analysis The
results of the analyses will be used to help refine the distribution of the plume and to estimate bedrock
properties These analyses will be used in conjunction with existing data during the TI evaluation to
refine cleanup times and establish the limits of the TI zone
As described in Subtask 1 it is anticipated that up to 10 core samples from each cored boring (total of 20
core samples) will be collected and submitted to an off-site laboratory for analyses of porosity (matrix and
bulk) permeability bulk density and fraction of organic carbon (f^) using existing industry methods
Subject to further evaluation of industry methods Woodard amp Curran proposes that porosity
TISOW WOODARD amp CURRAN20564309
14 September 302003
permeability and density will be measured using methods in the American Petroleum Institutes API RPshy
40 Fraction of organic carbon (f^) will be measured using either the LECO TOC method or Walkey-
Black method The LECO TOC method is a standard method in the petroleum industry and involves the
direct combustion of a ground rock sample The Walkey-Black method is a commonly used USEPA-
approved chemical oxidation method for determination of foe in soils In addition either method could be
used if a sample were scraped from a fracture surface To develop a reasonable range of f for Site
bedrock up to five samples will be selected from each boring from the unfractured matrix and up to five
from the fracture surfaces In addition Woodard amp Curran will evaluate the appropriateness of selecting
rock samples from a subset of the core samples from areas near fractures as well as from non-fractured
areas and submitting the samples for VOC analysis following methanol extraction
Results from these analyses will be used in conjunction with groundwater contaminant concentrations to
evaluate the significance of diffusion of contamination from the bedrock matrix in both the Source Area
and the Non-Source Area Although matrix diffusion likely is a significant factor in the determination of
cleanup times within the Source Area the potential applicability of matrix diffusion in the Non-Source
Area is not known These core analyses may provide evidence to assist in developing an estimate
through calculations of the effect of matrix diffusion on cleanup times
As noted in Subtask 3 prior to injection of water during packer testing groundwater samples will be
collected at selected intervals for analysis of volatile organic compounds (VOCs) Up to a total of 20
groundwater samples plus appropriate quality control samples will be collected from the newly installed
borings The samples will be submitted to an off-site laboratory for analysis Analytical results will be
validated in accordance with USEPA protocol and the data will be managed in WampCs existing
groundwater sampling analytical database for this site
Up to 21 existing monitoring wells from within or nearby the 17-acre property plus four new wells once
constructed will be sampled using low-flow techniques and submitted to an off-site laboratory for VOC
analysis Analytical results will be validated in accordance with USEPA protocol and the data will be
managed in WampCs existing groundwater sampling analytical database for this site
TISOW WOODARD amp CURRAN 15 September 302003 20564309
Subtask 5 - Monitoring Well Installation
Although it is anticipated that the newly installed borings will be left as open holes for tracer testing and
for pumping tests monitoring wells will be installed and developed in the newly installed borings unless
the USEPA MEDEP and PRP Group determine that the location is inappropriate for such use The
monitoring wells will be constructed of two-inch schedule 40 PVC screen and riser Screen intervals will
be selected based on the location of fractures identified during drilling geophysical logging and packer
testing A sand pack will be placed around the screen and will extend from approximately two ft below
the screen to approximately two ft above the screen
Subtask 6 - Pumping Test
WampC will conduct a single constant discharge pumping test to evaluate hydraulic properties of the
aquifer It is anticipated that the test will be conducted in a new pumping well in the vicinity of the
existing MW-2 well cluster within the source area Data from the pumping test will be used in
conjunction with other data from the investigation to improve the understanding of groundwater
movement and contaminant transport in the Source and Non-Source areas The results of the pumping
test will be used to refine the Site conceptual model as well as in the design of the hydraulic containment
system that is being constructed under the authority of the AOC for the RD
The groundwater pumping test will include the following components (1) Pumping test setup (2) Pretest
monitoring (3) Constant Discharge Pumping Test (4) Post-test monitoring and (5) Data Analysis
Pumping Test Setup In support of the groundwater pumping test WampC will install a pumping well
(PW-207) and procure and install the required groundwater extraction treatment and storage equipment at
the Site The well will be cored and over drilled to allow construction of a 4-inch well The location will
be in the vicinity of the MW-2 well cluster and be based upon results of the angled bedrock boring AWshy
202 The equipment will include but not be limited to
bull Down well pump plumbing and appurtances
bull Two (2) 20000 frac tanks
bull Groundwater transfer pumps and controls
bull Settlingaerationsand filtration treatment processes for the treatment of inorganics (if needed) and
nsow WOODARD amp CURRAN 16 September 302003 20564309
bull Granular activated carbon units for the treatment of dissolved organics in the groundwater
The groundwater treatment process will include the following processes 1) an oxidation and filtration
step to remove the inorganics from the groundwater and GAC units to treat the organic contaminants in
the extracted groundwater
Pretest Monitoring Prior to initiation of pumping WampC will monitor water levels in existing wells and
newly installed borings adjacent to the pumping well using a combination of hand measurements and data
loggers to develop an understanding of the piezometric surface under unstressed conditions The wells
proposed for water-level monitoring will be described in the work plan In addition all gauges
transducers flow meters and other equipment used in conducting the pumping tests shall be calibrated
before use
Constant Discharge Pumping Test The pumping test will be conducted in the source area using
newly-installed pumping well PW-207 It is anticipated that the test will be conducted at a pumping rate
of approximately 2 gallons per minute (gpm) for a period of 2 to 3 days however a higher or lower rate
may be shown to be appropriate based on the drilling and packer testing conducted during boring
installation Woodard amp Curran proposes to conduct this test using a vacuum-enhanced recovery system
(VERS) as described in the ROD so that the water level is not lowered appreciably in the vicinity of the
pumping well to prevent the potential migration of NAPLs to deeper bedrock zones The appropriateness
and feasibility of the VERS for the pumping test will be determined by field testing or literature
evaluation prior to completion of the Work Plan Because of the short duration of this test it is not
anticipated that stability of water levels will be reached in observation wells The test will however
provide information to estimate hydraulic conductivity and bedrock storage During the test the water
levels in the pumping well and selected monitoring wells will be logged continuously via down well data
loggers It is anticipated that water levels in approximately 24 wells will be measured using hand
measurements and data loggers
Groundwater extracted during the pumping test will be stored temporarily in an on-site frac tank prior to
on-site treatment and disposal
TISOW WOODARD amp CURRAN 17 September 302003 20564309
Post-Test Monitoring After the pump is turned off in the pumping well water levels will continue to be
monitored using hand measurements and data loggers until they have returned to within 10 of the preshy
test levels For planning purposes this has been estimated to be two weeks
Data Analysis Data collected during the pumping test will be analyzed with Aquifer Win32 Results of
the pumping test will be summarized in the summary data package for the TI Evaluation and the results
will also be used in the design of the hydraulic containment system specified in the Interim ROD that is
being conducted under the authority of the AOC for the RD Detail regarding use of the pumping test
data in hydraulic system design will be provided in the Remedial Design Work Plan
Subtask 7 - Tracer Test
WampC will conduct a tracer test using a conservative tracer to evaluate fracture connectivity porosity
dispersivity and matrix diffusion of the bedrock aquifer in both the Source Area and Non-Source Area
To increase the potential for success of this test results of the pumping test evaluation will be used to
revise the tracer test plan proposed here as necessary Following rebound of water levels after
completion of the pumping test WampC will initiate a single natural gradient tracer test The test will
consist of injecting a tracer into well PW-207 in the source area (Figure 3-1) for up to five days and
monitoring the tracers arrival in nearby wells Borehole geophysics core evaluation and packer testing
will be used to select the specific injection depth(s) in the well
A Tracer Test Work Plan will be completed prior to initiation of injection to determine the type quantity
and concentration of tracer based on the distance between the injection well and the monitoring wells A
conservative tracer that is one that is not preferentially adsorbed to rock or organic matter will be
selected for the tracer test Tracer injection equipment including tanks and flow-regulating and metering
equipment and pumps will be used to mix the tracer at the surface prior to injection Fractures may be
packered in the injection well and tracer solution will be injected at a rate determined during preparation
of the Tracer Test Work Plan During injection the potentiometric surface of the aquifer will be
monitored to verify that the potentiometric surface remains relatively constant during the injection
process
nsow WOODARD amp CURRAN 18 September 302003 20564309
Prior to injection of the tracer background concentration will be established by collecting samples from
up to six wells in the area of the tracer test and analyzing them for the tracer using an appropriate
analytical method Following injection of the tracer solutions the concentration of the tracer in
downgradient wells and borings will be measured A monitoring network will be established using nearby
monitoring wells Downhole probes will be installed in six new and existing wells near the injection well
to be identified in the work plan first to determine the background tracer concentrations and then to
monitor for the presence of the tracer upon initiation of the test Measurements will be collected at
periodic intervals to be determined based on the results of packer testing If an increase in tracer
concentration is detected or at a minimum on a weekly basis a water sample will be collected using low
flow sampling methodologies and analyzed in an off-site laboratory to evaluate the concentration of the
tracer The concentration of the tracer will be recorded Monitoring of the tracer concentration will
continue throughout the duration of the test The tracer will be allowed to flow with groundwater for one
month or until detected in wells in the vicinity of MW-106 whichever is shorter
313 Task 3 - TI Evaluation and Reporting
The TI Evaluation and reporting task includes the following five subtasks
bull Data evaluation
bull Summary data package
bull Draft TI Evaluation
bull Meetings with PRP Group and USEPA and
bull Revise and finalize TI Evaluation
As the subtasks of the field investigation are completed the data will be evaluated for the purpose of
addressing the data gaps identified by USEPA Specifically the data will be used to further refine the
cleanup times for non-source area groundwater presented in the Interim ROD
The data obtained during the field investigation will be reduced and evaluated and a summary data
package will be prepared that will include a discussion of the field activities completed and presentation
of the data It is anticipated that up to two meetings with USEPA will be necessary before the data
evaluation and summary report are completed
TISOW WOODARDampCURRAN 19 September 302003 20564309
Data collected during the pumping test will be analyzed with Aquifer Win32 Results will be summarized
in the summary data package and will also be presented as part of the RD submittals
Following submittal of the summary data package the TI evaluation will be prepared In accordance with
EPA guidance (1993) the TI waiver evaluation document will address the following topics
1 Specific ARARS or media cleanup standards for which TI determination is sought This section of the
TI Evaluation will identify the specific contaminants for which the TI determination is sought Based on
information available to date a waiver may be appropriate for pesticides PCBs chlorinated organic
compounds and other site-related contaminants that upon evaluation will not attain ARARs in a
reasonable period of time
2 Spatial area over which the TI waiver will apply The purpose of the additional site investigation
outlined in this SOW is to obtain the data necessary to further refine cleanup times presented in the
Interim ROD to determine what portions of the Site will not be expected to reach ARARs within a
reasonable time Consistent with TI guidance (USEPA 1993) the TI evaluation will specify the
horizontal and vertical extent of the area for which TI determination is sought Groundwater
concentration data from the RI and the TI SOW will be used to refine the distribution of the plume Data
from the drilling geophysical logging packer testing and pumping and tracer tests will be used to refine
the Site conceptual model and the cleanup times that will serve as the basis for establishing the scope and
nature of the TI zone
3 Conceptual Model The conceptual model forms the technical core of the TI Waiver Evaluation since
it provides basis for understanding of the restoration potential of the site The conceptual model outlines
the physical and hydrogeological constraints that hinder remediation or removal of Site contaminants and
it is the extent of these constraints rather than restoration timeframe alone that USEPA will use to
evaluate the necessity of the TI waiver of ARARs The conceptual model is the link between restoration
potential and restoration timeframe since it explains why proposed technologies are unlikely to work
either at all or within the desired 100-year timeframe
The Site conceptual model is not a mathematical model however as the result of the extensive modeling
and investigations of the site WampC has a strong understanding of the complex bedrock and overburden
TISOW WOODARDampCURRAN 20 September 302003 20564309
groundwater system beneath this site This understanding has been presented previously in both the RI
report and the FS and will be refined based on the TI SOW as necessary and summarized in the TI
Waiver Evaluation with specific attention to the physical and hydrogeological constraints on remediation
In particular the Site conceptual model will be reviewed in light of the new geologic data from drilling
logging and packer testing and the new hydrogeologic data obtained from the pumping test and tracer test
and will be revised to incorporate the new understanding
4 An evaluation of the restoration potential of the site This section will consist of a several components
It will present a systematic review of the technologies potentially capable of remediating the site given
the physical and hydrogeological constraints identified in the site model The newly acquired data will
provide an improved understanding of bedrock hydraulic properties that will allow a more Site-specific
evaluation of technologies The review of technologies will also include review of innovative
technologies and will evaluate whether existing remedial technologies or strategies would be capable of
achieving groundwater restoration at the site in a reasonable timeframe The section reference the FS and
will summarize the alternative remedies considered in the FS focusing on the ability of each to restore
groundwater in a reasonable timeframe It will also include a discussion of the selected hydraulic
containment system in light of the data gathered from the pumping test conducted in conjunction with the
TI SOW
Based on the Batch Flushing Model and using the agreed upon koc data from the RI as well as data from
this TI SOW including the f data collected as part of Subtask 4 a restoration timeframe analysis will be
conducted Following completion of the timeframe analysis and consideration of the results of drilling
rock and water analyses and pumping and tracer test a determination will be made regarding the Source
Area and the portion of the Non-Source Area VOC plume that will not attain ARARs in a reasonable
time
TISOW WOODARD amp CURRAN 21 September 302003 20564309
40 SCHEDULE
A proposed project schedule is included with this plan as Figure 4-1 This schedule is included for
discussion purposes and will be modified as necessary once the final scope of work as been approved by
all parties and the field work activities are coordinated with the subcontractors
TISOW WOODARD amp CURRAN 22 September 302003 20564309
ID
2
3
4
5
6
7 a i 10
11
12
13
14
15
16
17
16
19
20
21
22
24
25
26
27
26
29
30
31
32
Task Name
Project Meeting with EPA
Finalize SOW
Prepare Work Plans QAPP HASP Revision
Submit Work Plans for EPA Approval
Project Meeting with EPA
Revisions to work plans
Submit final work plans
Subcontractor Contracts
Project Meeting wEPA
Field Investigation
Site Mobilization
Install Borings
Borehole Geophysics
Packer Testing amp Collect GW Samples
Pumping Test
Tracer Test
Test setup
Injection
Monitoring
Data Reporting
InstallDevelop Wells
Data Evaluation
Prepare Data Package
Data Package Submittal to EPA
Draft Tl Evaluation Repon
Draft Tl Evaluation Report Submttal to EPA
EPA ReviewComment on Tl Evaluation ReF
Project Meeting wEPA
Revisions to Tl Evaluation Report
Submit Final Tl Evaluation Report
Start
Wed 070903
Thu 071003
Fri 101003
Mon 120103
Mon 121503
Mon 122903
Mon 011204
Tue 011304
Thu 021904
Fri 032104
Fri 032604
Fri 040204
Fri 041604
Fri 042304
Thu 050604
Wed 060204
Wed 060204
Wed 060904
Wed 060904
Wed 062304
Wed 070704
Wed 042804
Wed 062304
Mon 080204
Mon 070504
Tue 082404
Wed 082504
Wed 091504
Thu 0916AM
Thu 093004
Finish
Wed 070903
Fri 1OtO7u3
Fri 112803
Fri 122603
Mon 121503
Fri 010904
Mon 011204
Mon 012604
Thu 021904
Tue 071304
Thu 040104
Thu 042204
Tue 042704
Wed 050504
Tue 052504
Tue 071304
Tue 060804
Tue 061504
Tue 070604
Tue 071304
Fri 070904
Tue 072004
Fri 073004
Mon 080204
Mon 082304
Tue 082404
Tue 091404
Wed 091504
Wed 082904
Thu 093004
FIGURE 4-1 DRAFT HOWS CORNER SUPERFUND SITE
Tl EVALUATION amp RELD WORK FOR HYDRAUUC CONTAINMENT SYSTEM DESIGN PROPOSED PROJECT SCHEDULE
2003 2004 Mav |
Jun | Jul
ltamp i
Aug
i
Sen Oct I Nov Dec Jan Feb I Mar
ii i i
k ^tr 1
1V i
I t bull ^
I
ta^M bull bull M W
l LgtH^HBKLii LJ Mi
I
bull bull raquo bull laquo^ 0930
Task Progress I^MLHHHI^LB Summary ^^^^^^^^f External Tasks M B WMMM Deadline ^7 Project Hows Comer Schedule6A bull bull bull 1 UData Fri 101003 Split Milestone ^ Project Summary ^f^KKKKKK^^ External Milestone ^
Pagei
50 ACRONYMS
AOC Administrative Order by Consent
ARARs Applicable or Relevant and Appropriate Requirements
ATV acoustic televiewer
bgs below ground surface
CERCLA Comprehensive Environmental Resource and Conservation Liability Act
DNAPL Dense Non-Aqueous Phase Liquid
GAC granular activated carbon
gpm gallons per minute
HASP Health and Safety Plan
row investigation-derived waste
MCL Maximum Containment Level
MEDEP Maine Department of Environmental Protection
MEG Maine Enforcement Guideline
mgkg milligrams per kilogram
Hg kg micrograms per kilogram
NCP National Contingency Plan
PCB polychlorinated biphenyl
PID photo ionization detector
ppm parts per million
PRP Potentially Responsible Party
TISOW WOODARD amp CURRAN 24 September 302003 20564309
QAPP Quality Assurance Project Plan
QAQC Quality AssuranceQuality Control
RA Remedial Action
RAO Remedial Action Objective
RCRA Resource Conservation and Recovery Act
RD Remedial Design
RIFS Remedial InvestigationFeasibility Study
ROD Record of Decision
SAP Sampling and Analysis Plan
SOW Statement of Work
TAL target analyte list
TI Technical Impracticability
USEPA United State Environmental Protection Agency
VOCs volatile organic compounds
WampC Woodard amp Curran Inc
TISOW WOODARD amp CURRAN 25 September 302003 20564309
REFERENCES
Everts CJ RS Kanwar (1994) Evaluation of Rhodamine WT as an adsorbed tracer in an agricultural
soil J Hydrology 153 53-70
Kasnavia T D Vu DA Sabatini (1999) Fluorescent dye and media properties affecting sorption and
tracer selection Groundwater 37 376-381
Ptak T G Schmid (1996) Dual-tracer transport experiments in a physically and chemically
heterogeneous porous aquifer effective transport parameters and spatial variability J Hydrology
183 117-138
Sabatini DA T A Austin (1991) Characteristics of Rhodamine WT and fluorescein as adsorbing
ground-water tracers Ground Water 29 341-349
Trudgill ST (1987) Soil water dye tracing with special reference to the use of Rhodamanie WT
Lissamine FF and Amino G acid Hydrological Processes 1 149-170
US Environmental Protection Agency (USEPA) 1993 Guidance for Evaluating the Technical
Impracticability of Ground-Water Restoration - Interim Final Office of Solid Waste and
Emergency Response Washington DC Directive 92342-25 September 1993
US Environmental Protection Agency (USEPA) 2002 Interim Record of Decision Summary shy
Operable Unit One Non-Source Area Groundwater West SiteHows Corner Superfund Site
Plymouth Maine EPA Region 1 September 2002
US Environmental Protection Agency (USEPA) 2003 Proposed Scope of Work West SiteHows
Corner Superfund Site Plymouth Maine EPA Region 1 4 pages September 2002
Vasudevan D RL Fimmen AB Francisco (2001) Tracer-grade Rhodamine WT Structure of
constituent isomers and their sorption behavior Environ Sci Technol 35 4089-4096
nsow WOODARD amp CURRAN 26 September 30 2003 20564309
Woodard amp Curran Inc (WampC) 2002 Final Feasibility Study Report - Non-Source Area Groundwater
Hows Comer Superfund Site Plymouth Maine July 2002
TISOW WOODARD amp CURRAN 27 September 302003 20564309
f
m WOODARD amp CURRAN Maine Massachusetts New Hampshire Connecticut Florida Illinois Operational offices across the US 1-800-426-4262 wwwwoodardcurrancom
i
311 Task 1 - Project Planning
Project planning is the first task and includes the following five subtasks
bull Finalize the SOW
bull Prepare work plan
bull Revise existing site-specific Quality Assurance Project Plan (QAPP) Sampling and Analysis
Plan (SAP) and Health and Safety Plan (HASP) and
bull Secure subcontractor contracts
bull Mobilize to the Site and establish a field office
In order to finalize the SOW for this TI evaluation it is anticipated that a minimum of one meeting will
occur between the PRP Group USEPA MEDEP and WampC Once the SOW is finalized the QAPP
SAP and HASP (the Plans) will be revised to incorporate necessary modifications to reflect the agreed-
upon work methods and technology The SAP will be modified to include a detailed plan for the
additional field activities Once the Plans have been revised and the Work Plan prepared they will be
submitted to USEPA for review USEPA comments will be incorporated into the plans and final
approved plans will be issued
After final plans have been issued WampC will negotiate contracts with subcontractors for certain field
activities including boring and monitoring well installation geophysical survey packer testing and
investigation-derived waste (IDW) storage and disposal It is anticipated that a second meeting between
the parties may be needed prior to the commencement of the field activities
Because of the duration of the field activities described in this SOW and the need for on-site evaluation of
field results in order to make program decisions during the investigation WampC will mobilize a trailer to
the Site to serve as a field office The trailer will be equipped with telephone and fax machine
312 Task 2 - Field Investigation
The field investigation task will include the following subtasks
bull Subtask 1 - Boring installation
bull Subtask 2 - Borehole geophysics
TISOW
WOODARDampCURRAN 7 September 302003 20564309
0
0 bull Subtask 3 - Packer testing
bull Subtask 4 - Sampling and analysis
bull bull Subtask 5 - Monitoring well installation
bull Subtask 5 - Pumping test and
bull Subtask 6 - Tracer test
Each of the subtasks is summarized below however a comprehensive discussion of these subtasks and
associated methodologies will be provided in the SAP
Subtask 1 - Boring Installation
j Information obtained during the installation of the new borings will be used in the evaluation of the
aquifer hydraulic conductivity and the analysis of other aquifer properties (eg porosity fracture
frequency) For this subtask it is anticipated that one angled boring will be completed to a depth of 150
feet (ft) below ground surface (bgs) One additional angled boring and four new vertical bedrock borings
will be completed to depths of approximately 100 ft bgs This depth is consistent with the depth
evaluated in the RI and will allow evaluation of bedrock and groundwater properties to depths below the
transition from less competent to more competent bedrock (approximately 50 to 80 ft bgs)
m One additional vertical boring will be installed to a depth of 100 ft bgs as the pumping well location for
bull the pumping test The pumping well location will be based on the results of field work conducted prior to
its installation The proposed drilling program is designed to enhance understanding of the flow system
by aligning new boring locations with existing wells to characterize hydraulic properties of the fracture
network and bulk bedrock Furthermore the program allows for additional characterization of
M contamination in the Source Area groundwater The rationale for the boring locations is summarized in
Table 3-1 and the proposed locations of the borings are depicted on Figure 3-1 Actual locations may
M vary depending on field conditions and accessibility
jlt The drilling protocol employed during installation of both the angled and the vertical wells will allow for
evaluation of the potential presence of DNAPL in the rock and the need for modifications to the drilling
method if DNAPL is detected If sheen or product is observed in the return water core or cuttings from a
boring an interface probe may be employed to determine whether a NAPL is present in the boring
Based on the presence of DNAPL the boring may be terminated at a shallower depth than planned the
J TISOW 4 1 WOODARD amp CURRAN 8 September 302003
20564309
location may be abandoned or other practices may be employed to reduce the potential for causing
downward migration of DNAPL The protocol will be described in the Work Plan and the SAP
Angled Borings Two angled borings will be installed using air-hammer drilling methods The first
angled boring (AW-201) will be installed to a depth of 150 ft bgs in the vicinity of existing well MWshy
106 northeast of and outside of the source area and within the dissolved phase groundwater plume This
well will be angled from the surface toward the southeast at depth in order to intersect as many northwest-
dipping near-vertical fractures as possible The angle of this boring will be approximately 30deg to 40deg
from the vertical resulting in a surface projection of approximately 84 to 126 ft and total length of
approximately 173 to 195 ft The second angled boring (AW-202) will be installed to a depth of 100 ft
bgs in the vicinity of the existing MW-2 well cluster within the source area This well also will be angled
from the surface toward the southeast at depth in order to intersect near-vertical fractures The angle of
this boring will be approximately 30deg to 40deg from the vertical resulting in a surface projection of
approximately 58 to 84 ft and total length of approximately 115 to 130 ft
m
4
sect
i
TISOW WOODARD amp CURRAN 9 September 302003 20564309
Table 3-1
Rationale for Proposed Well Locations
Hows Corner Technical Impracticability Evaluation and Field work for Hydraulic Containment System Design
Well Identification
AW-201
AW-202
MW-203
MW-204
MW-205
MW-206
PW-207
Boring Orientation
Angled
Angled
Vertical
Vertical
Vertical
Vertical
Vertical
Minimum Boring Diameter (inches)
4
4
4
4
4
4
6
Drilling Method
Air Hammer
Air Hammer
Coring
Air Hammer
Air Hammer
Air Hammer
Core Air Hammer Over -drilling
Source Area Non-Source Area
Non-Source Area
Source Area
Non-Source Area
Non-Source Area
Source Area
Source Area
Source Area
Rationale for Boring
bull Intercept near-vertical fractures to understand subsurface geology bull Aid in iting MW-203 bull Intercept near-vertical fractures to understand subsurface geology bull Aid in siting PW-201 (Pumping well) bull ion of contamination bull 1 future monitoring location bull Potential reinjection well for hydraulic containment system bull Core for matrix diffusion evaluation bullbullbullbull Ibullbullbullbull 1bullbullbullbull 1bullbull bull 1
tion point for pumping test tion point in tracer test ion of contamination
future monitoring location tion point for pumping test tion point in tracer test ion of contamination
future monitoring location tion point for pumping test tion point in tracer test ion of contamination
future monitoring location tion point for pumping test
test well extraction well
bull Core for matrix diffusion evaluation bull i point for tracer test
TISOW September 30 2003 WOODARD amp CURRAN 20564309
MW-105D MW-5B
Primary Bedding Secondary Cleavage
Tertsry Fracturing
NOTE A total of 60 observations warn made rtrtjs roprtraont tticopy number of obsafvatk noted wtthln each azimutha) segment
MW-1 1 3D euro MW-205
2 AcreSource
Fenced-^ Area i
MW-103D MW-103S
17-Acre Property Boundary
MW-104D MW-1041 bull
MW-104S
Legend Figure 3-1 J Proposed Monitoring Well Proposed Well Locations
o- Site Property Boundary bull^bullProposed Pumping Well Hows Corner Superfund Site -xmdashx- Source Area Plymouth Maine
^ ^Proposed Angled Well bullamp Existing Monitoring Well bullWDODARDampCURRAN
Englnoortng bull Science bull Operations 205643wipsite-8OlaquoAx-opt-1-2-u3-1D
bull During the installation of each angled boring observations will be made regarding water gainloss
drilling rate and bit behavior to assess the depth of potential fractures In addition water levels will be
9 measured in nearby borings using either hand measurements data loggers or both to evaluate
connectivity between locations A change in water level in a nearby boring will indicate a hydraulic
at connection between the borings Borehole geophysics will also be performed on the borings (See Subtask
2 below) Information from each angled boring will be used to site an adjacent vertical well (MW-203
^ and PW-207) so that it intercepts a fracture observed in the angled boring
^ Vertical Borings Two of the vertical borings will be completed with rotary diamond coring to
approximately 100 ft bgs These borings will be adjacent to the angled borings described above One of
^ the cored borings (MW-203) will be located near MW-106 outside of the source area within the
dissolved-phase groundwater plume (see Figure 3-1) The other cored boring (PW-207) will be the
pumping well which is anticipated to be located within the source area in the vicinity of the existing
MW-2 well cluster Coring will allow data collection for several purposes including direct observation
of bedrock for determination of the nature of the rock matrix determination of the location and nature of
fractures and the degree of fracturing comparison with geophysical logs (Subtask 2) to verify
interpretation of the logs and collection of core samples for analysis (Subtask 4)
The remaining borings will be located east of the 2-acre fenced area within or near the periphery of the
source area and will be sited to align approximately with existing wells based on the known fracture
orientations at the Site (MW-204 and MW-205) or with new wells based on the known fracture
pound orientations at the Site (MW-206) Data from these locations in conjunction with the other borings
installed as part of this TI SOW and the existing wells will be used in the interpretation of the pumping
^ test (Subtask 6) and tracer test (Subtask 7) In addition these three borings will further delineate
contamination and provide potential monitoring locations for long-term monitoring Each of these
^ borings will be advanced to approximately 100 ft bgs with a minimum four-inch diameter air hammer
^ During the installation of each boring observations will be made regarding water gainloss drilling rate
and bit behavior to assess the depth of potential fractures In addition water levels will be measured in
nearby borings using either hand measurements data loggers or both to evaluate connectivity between
locations A change in water level in a nearby boring will indicate a hydraulic connection between the
TISOW WOODARD amp CURRAN 12 September 302003 20564309
borings Borehole geophysics and packer testing will also be performed on the borings (See Subtasks 2
and 3 below)
Drilling water will be containerized on site and treated through granular activated carbon (GAC) Treated
water will be analyzed to verify that PCB and VOC concentrations have been reduced to below ARARs
prior to discharge to the ground surface Cuttings will be spread on the ground surface at the site
consistent with the Remedial Investigation work plan
It is anticipated that up to 10 core samples from each cored boring (total of 20 cores) will be collected and
submitted to an off-site laboratory for analyses of porosity (matrix and bulk) permeability bulk density
and fraction of organic carbon (f^) using methods described in Subtask 4
Subtask 2 - Borehole Geophysics
To supplement information on fracture location and connectivity obtained during boring advancement a
borehole geophysical survey will be conducted on the newly installed bedrock borings to evaluate the
nature and orientation of water bearing fractures in the borings The survey will be performed at the
completion of the angled borings and again at the completion of the vertical borings The information
obtained during the survey may be used to identify the location of subsequent boring(s) by refining the
understanding of the depth aperture and orientation of bedrock fractures The following measurements
are proposed for the new borings caliper fluid temperature fluid resistivity and acoustic televiewer
(ATV) Single-point resistively and 16 inch normal measurements will also be made in the first two
borings installed and the data will be compared to data from the other geophysical logs to determine if
the measurements confirm and significantly improve the interpretation regarding the presence of water-
bearing fractures If the measurements are applicable to identification of fractures they may be included
in lieu of other geophysical logs in the remainder of the borings
Subtask 3 - Packer Testing
To further refine information on the aquifer hydraulic conductivity the hydraulic connection between
fractures in the borings will be evaluated during packer testing of vertical borings The data will be used
to estimate the hydraulic conductivity of specific fractures and fracture zones The packer testing will be
performed after the vertical borings have been installed and the borehole geophysical survey completed
TISOW WOODARD amp CURRAN 13 September 30 2003 20564309
bull
m
M
Drilling observations and information from borehole geophysics will be used to identify specific fractures
below the water table that are capable of transmitting water Prior to water injection for hydraulic
conductivity and fracture connectivity testing groundwater samples will be collected at selected intervals
for analysis of VOCs (See Subtask 4) Sampling intervals will be selected based on drilling observations
and logging results that indicate water is moving into or out of the borehole or that fractures exist to
promote water movement such as rapid increase in the amount of water returned rapid change in
temperature or highly fractured interval
^
^
bull
f$
Double packer testing will be performed at selected intervals within each newly installed boring It is
anticipated that up to six intervals per well will be tested for a maximum of 24 intervals and that for each
interval the test will include an approximate 15-minute injection of potable water at four progressively
increasing pressures Packer spacing is anticipated to be 10 ft however spacing may vary so that packers
are not located in potential fracture zones identified using information from rock cores drilling
observations and borehole geophysics The tests at an individual interval will be terminated if it appears
that the interval is not accepting water Care will be taken to minimize over-pumping or over-
pressurizing of the fractures The flow rate will be measured to evaluate the characteristics of the
fracture Water levels in adjacent borings will be measured during the packer testing to determine if a
hydraulic connection exists between the borings Water generated during packer testing will be
containerized on site and treated through GAC Treated water will be analyzed to verify that PCB and
VOC concentrations have been reduced to below ARARs prior to discharge to the ground surface
4 Subtask 4 Sampling and Analysis
~d
^
Rock and groundwater samples will be collected during the field program for laboratory analysis The
results of the analyses will be used to help refine the distribution of the plume and to estimate bedrock
properties These analyses will be used in conjunction with existing data during the TI evaluation to
refine cleanup times and establish the limits of the TI zone
As described in Subtask 1 it is anticipated that up to 10 core samples from each cored boring (total of 20
core samples) will be collected and submitted to an off-site laboratory for analyses of porosity (matrix and
bulk) permeability bulk density and fraction of organic carbon (f^) using existing industry methods
Subject to further evaluation of industry methods Woodard amp Curran proposes that porosity
TISOW WOODARD amp CURRAN20564309
14 September 302003
permeability and density will be measured using methods in the American Petroleum Institutes API RPshy
40 Fraction of organic carbon (f^) will be measured using either the LECO TOC method or Walkey-
Black method The LECO TOC method is a standard method in the petroleum industry and involves the
direct combustion of a ground rock sample The Walkey-Black method is a commonly used USEPA-
approved chemical oxidation method for determination of foe in soils In addition either method could be
used if a sample were scraped from a fracture surface To develop a reasonable range of f for Site
bedrock up to five samples will be selected from each boring from the unfractured matrix and up to five
from the fracture surfaces In addition Woodard amp Curran will evaluate the appropriateness of selecting
rock samples from a subset of the core samples from areas near fractures as well as from non-fractured
areas and submitting the samples for VOC analysis following methanol extraction
Results from these analyses will be used in conjunction with groundwater contaminant concentrations to
evaluate the significance of diffusion of contamination from the bedrock matrix in both the Source Area
and the Non-Source Area Although matrix diffusion likely is a significant factor in the determination of
cleanup times within the Source Area the potential applicability of matrix diffusion in the Non-Source
Area is not known These core analyses may provide evidence to assist in developing an estimate
through calculations of the effect of matrix diffusion on cleanup times
As noted in Subtask 3 prior to injection of water during packer testing groundwater samples will be
collected at selected intervals for analysis of volatile organic compounds (VOCs) Up to a total of 20
groundwater samples plus appropriate quality control samples will be collected from the newly installed
borings The samples will be submitted to an off-site laboratory for analysis Analytical results will be
validated in accordance with USEPA protocol and the data will be managed in WampCs existing
groundwater sampling analytical database for this site
Up to 21 existing monitoring wells from within or nearby the 17-acre property plus four new wells once
constructed will be sampled using low-flow techniques and submitted to an off-site laboratory for VOC
analysis Analytical results will be validated in accordance with USEPA protocol and the data will be
managed in WampCs existing groundwater sampling analytical database for this site
TISOW WOODARD amp CURRAN 15 September 302003 20564309
Subtask 5 - Monitoring Well Installation
Although it is anticipated that the newly installed borings will be left as open holes for tracer testing and
for pumping tests monitoring wells will be installed and developed in the newly installed borings unless
the USEPA MEDEP and PRP Group determine that the location is inappropriate for such use The
monitoring wells will be constructed of two-inch schedule 40 PVC screen and riser Screen intervals will
be selected based on the location of fractures identified during drilling geophysical logging and packer
testing A sand pack will be placed around the screen and will extend from approximately two ft below
the screen to approximately two ft above the screen
Subtask 6 - Pumping Test
WampC will conduct a single constant discharge pumping test to evaluate hydraulic properties of the
aquifer It is anticipated that the test will be conducted in a new pumping well in the vicinity of the
existing MW-2 well cluster within the source area Data from the pumping test will be used in
conjunction with other data from the investigation to improve the understanding of groundwater
movement and contaminant transport in the Source and Non-Source areas The results of the pumping
test will be used to refine the Site conceptual model as well as in the design of the hydraulic containment
system that is being constructed under the authority of the AOC for the RD
The groundwater pumping test will include the following components (1) Pumping test setup (2) Pretest
monitoring (3) Constant Discharge Pumping Test (4) Post-test monitoring and (5) Data Analysis
Pumping Test Setup In support of the groundwater pumping test WampC will install a pumping well
(PW-207) and procure and install the required groundwater extraction treatment and storage equipment at
the Site The well will be cored and over drilled to allow construction of a 4-inch well The location will
be in the vicinity of the MW-2 well cluster and be based upon results of the angled bedrock boring AWshy
202 The equipment will include but not be limited to
bull Down well pump plumbing and appurtances
bull Two (2) 20000 frac tanks
bull Groundwater transfer pumps and controls
bull Settlingaerationsand filtration treatment processes for the treatment of inorganics (if needed) and
nsow WOODARD amp CURRAN 16 September 302003 20564309
bull Granular activated carbon units for the treatment of dissolved organics in the groundwater
The groundwater treatment process will include the following processes 1) an oxidation and filtration
step to remove the inorganics from the groundwater and GAC units to treat the organic contaminants in
the extracted groundwater
Pretest Monitoring Prior to initiation of pumping WampC will monitor water levels in existing wells and
newly installed borings adjacent to the pumping well using a combination of hand measurements and data
loggers to develop an understanding of the piezometric surface under unstressed conditions The wells
proposed for water-level monitoring will be described in the work plan In addition all gauges
transducers flow meters and other equipment used in conducting the pumping tests shall be calibrated
before use
Constant Discharge Pumping Test The pumping test will be conducted in the source area using
newly-installed pumping well PW-207 It is anticipated that the test will be conducted at a pumping rate
of approximately 2 gallons per minute (gpm) for a period of 2 to 3 days however a higher or lower rate
may be shown to be appropriate based on the drilling and packer testing conducted during boring
installation Woodard amp Curran proposes to conduct this test using a vacuum-enhanced recovery system
(VERS) as described in the ROD so that the water level is not lowered appreciably in the vicinity of the
pumping well to prevent the potential migration of NAPLs to deeper bedrock zones The appropriateness
and feasibility of the VERS for the pumping test will be determined by field testing or literature
evaluation prior to completion of the Work Plan Because of the short duration of this test it is not
anticipated that stability of water levels will be reached in observation wells The test will however
provide information to estimate hydraulic conductivity and bedrock storage During the test the water
levels in the pumping well and selected monitoring wells will be logged continuously via down well data
loggers It is anticipated that water levels in approximately 24 wells will be measured using hand
measurements and data loggers
Groundwater extracted during the pumping test will be stored temporarily in an on-site frac tank prior to
on-site treatment and disposal
TISOW WOODARD amp CURRAN 17 September 302003 20564309
Post-Test Monitoring After the pump is turned off in the pumping well water levels will continue to be
monitored using hand measurements and data loggers until they have returned to within 10 of the preshy
test levels For planning purposes this has been estimated to be two weeks
Data Analysis Data collected during the pumping test will be analyzed with Aquifer Win32 Results of
the pumping test will be summarized in the summary data package for the TI Evaluation and the results
will also be used in the design of the hydraulic containment system specified in the Interim ROD that is
being conducted under the authority of the AOC for the RD Detail regarding use of the pumping test
data in hydraulic system design will be provided in the Remedial Design Work Plan
Subtask 7 - Tracer Test
WampC will conduct a tracer test using a conservative tracer to evaluate fracture connectivity porosity
dispersivity and matrix diffusion of the bedrock aquifer in both the Source Area and Non-Source Area
To increase the potential for success of this test results of the pumping test evaluation will be used to
revise the tracer test plan proposed here as necessary Following rebound of water levels after
completion of the pumping test WampC will initiate a single natural gradient tracer test The test will
consist of injecting a tracer into well PW-207 in the source area (Figure 3-1) for up to five days and
monitoring the tracers arrival in nearby wells Borehole geophysics core evaluation and packer testing
will be used to select the specific injection depth(s) in the well
A Tracer Test Work Plan will be completed prior to initiation of injection to determine the type quantity
and concentration of tracer based on the distance between the injection well and the monitoring wells A
conservative tracer that is one that is not preferentially adsorbed to rock or organic matter will be
selected for the tracer test Tracer injection equipment including tanks and flow-regulating and metering
equipment and pumps will be used to mix the tracer at the surface prior to injection Fractures may be
packered in the injection well and tracer solution will be injected at a rate determined during preparation
of the Tracer Test Work Plan During injection the potentiometric surface of the aquifer will be
monitored to verify that the potentiometric surface remains relatively constant during the injection
process
nsow WOODARD amp CURRAN 18 September 302003 20564309
Prior to injection of the tracer background concentration will be established by collecting samples from
up to six wells in the area of the tracer test and analyzing them for the tracer using an appropriate
analytical method Following injection of the tracer solutions the concentration of the tracer in
downgradient wells and borings will be measured A monitoring network will be established using nearby
monitoring wells Downhole probes will be installed in six new and existing wells near the injection well
to be identified in the work plan first to determine the background tracer concentrations and then to
monitor for the presence of the tracer upon initiation of the test Measurements will be collected at
periodic intervals to be determined based on the results of packer testing If an increase in tracer
concentration is detected or at a minimum on a weekly basis a water sample will be collected using low
flow sampling methodologies and analyzed in an off-site laboratory to evaluate the concentration of the
tracer The concentration of the tracer will be recorded Monitoring of the tracer concentration will
continue throughout the duration of the test The tracer will be allowed to flow with groundwater for one
month or until detected in wells in the vicinity of MW-106 whichever is shorter
313 Task 3 - TI Evaluation and Reporting
The TI Evaluation and reporting task includes the following five subtasks
bull Data evaluation
bull Summary data package
bull Draft TI Evaluation
bull Meetings with PRP Group and USEPA and
bull Revise and finalize TI Evaluation
As the subtasks of the field investigation are completed the data will be evaluated for the purpose of
addressing the data gaps identified by USEPA Specifically the data will be used to further refine the
cleanup times for non-source area groundwater presented in the Interim ROD
The data obtained during the field investigation will be reduced and evaluated and a summary data
package will be prepared that will include a discussion of the field activities completed and presentation
of the data It is anticipated that up to two meetings with USEPA will be necessary before the data
evaluation and summary report are completed
TISOW WOODARDampCURRAN 19 September 302003 20564309
Data collected during the pumping test will be analyzed with Aquifer Win32 Results will be summarized
in the summary data package and will also be presented as part of the RD submittals
Following submittal of the summary data package the TI evaluation will be prepared In accordance with
EPA guidance (1993) the TI waiver evaluation document will address the following topics
1 Specific ARARS or media cleanup standards for which TI determination is sought This section of the
TI Evaluation will identify the specific contaminants for which the TI determination is sought Based on
information available to date a waiver may be appropriate for pesticides PCBs chlorinated organic
compounds and other site-related contaminants that upon evaluation will not attain ARARs in a
reasonable period of time
2 Spatial area over which the TI waiver will apply The purpose of the additional site investigation
outlined in this SOW is to obtain the data necessary to further refine cleanup times presented in the
Interim ROD to determine what portions of the Site will not be expected to reach ARARs within a
reasonable time Consistent with TI guidance (USEPA 1993) the TI evaluation will specify the
horizontal and vertical extent of the area for which TI determination is sought Groundwater
concentration data from the RI and the TI SOW will be used to refine the distribution of the plume Data
from the drilling geophysical logging packer testing and pumping and tracer tests will be used to refine
the Site conceptual model and the cleanup times that will serve as the basis for establishing the scope and
nature of the TI zone
3 Conceptual Model The conceptual model forms the technical core of the TI Waiver Evaluation since
it provides basis for understanding of the restoration potential of the site The conceptual model outlines
the physical and hydrogeological constraints that hinder remediation or removal of Site contaminants and
it is the extent of these constraints rather than restoration timeframe alone that USEPA will use to
evaluate the necessity of the TI waiver of ARARs The conceptual model is the link between restoration
potential and restoration timeframe since it explains why proposed technologies are unlikely to work
either at all or within the desired 100-year timeframe
The Site conceptual model is not a mathematical model however as the result of the extensive modeling
and investigations of the site WampC has a strong understanding of the complex bedrock and overburden
TISOW WOODARDampCURRAN 20 September 302003 20564309
groundwater system beneath this site This understanding has been presented previously in both the RI
report and the FS and will be refined based on the TI SOW as necessary and summarized in the TI
Waiver Evaluation with specific attention to the physical and hydrogeological constraints on remediation
In particular the Site conceptual model will be reviewed in light of the new geologic data from drilling
logging and packer testing and the new hydrogeologic data obtained from the pumping test and tracer test
and will be revised to incorporate the new understanding
4 An evaluation of the restoration potential of the site This section will consist of a several components
It will present a systematic review of the technologies potentially capable of remediating the site given
the physical and hydrogeological constraints identified in the site model The newly acquired data will
provide an improved understanding of bedrock hydraulic properties that will allow a more Site-specific
evaluation of technologies The review of technologies will also include review of innovative
technologies and will evaluate whether existing remedial technologies or strategies would be capable of
achieving groundwater restoration at the site in a reasonable timeframe The section reference the FS and
will summarize the alternative remedies considered in the FS focusing on the ability of each to restore
groundwater in a reasonable timeframe It will also include a discussion of the selected hydraulic
containment system in light of the data gathered from the pumping test conducted in conjunction with the
TI SOW
Based on the Batch Flushing Model and using the agreed upon koc data from the RI as well as data from
this TI SOW including the f data collected as part of Subtask 4 a restoration timeframe analysis will be
conducted Following completion of the timeframe analysis and consideration of the results of drilling
rock and water analyses and pumping and tracer test a determination will be made regarding the Source
Area and the portion of the Non-Source Area VOC plume that will not attain ARARs in a reasonable
time
TISOW WOODARD amp CURRAN 21 September 302003 20564309
40 SCHEDULE
A proposed project schedule is included with this plan as Figure 4-1 This schedule is included for
discussion purposes and will be modified as necessary once the final scope of work as been approved by
all parties and the field work activities are coordinated with the subcontractors
TISOW WOODARD amp CURRAN 22 September 302003 20564309
ID
2
3
4
5
6
7 a i 10
11
12
13
14
15
16
17
16
19
20
21
22
24
25
26
27
26
29
30
31
32
Task Name
Project Meeting with EPA
Finalize SOW
Prepare Work Plans QAPP HASP Revision
Submit Work Plans for EPA Approval
Project Meeting with EPA
Revisions to work plans
Submit final work plans
Subcontractor Contracts
Project Meeting wEPA
Field Investigation
Site Mobilization
Install Borings
Borehole Geophysics
Packer Testing amp Collect GW Samples
Pumping Test
Tracer Test
Test setup
Injection
Monitoring
Data Reporting
InstallDevelop Wells
Data Evaluation
Prepare Data Package
Data Package Submittal to EPA
Draft Tl Evaluation Repon
Draft Tl Evaluation Report Submttal to EPA
EPA ReviewComment on Tl Evaluation ReF
Project Meeting wEPA
Revisions to Tl Evaluation Report
Submit Final Tl Evaluation Report
Start
Wed 070903
Thu 071003
Fri 101003
Mon 120103
Mon 121503
Mon 122903
Mon 011204
Tue 011304
Thu 021904
Fri 032104
Fri 032604
Fri 040204
Fri 041604
Fri 042304
Thu 050604
Wed 060204
Wed 060204
Wed 060904
Wed 060904
Wed 062304
Wed 070704
Wed 042804
Wed 062304
Mon 080204
Mon 070504
Tue 082404
Wed 082504
Wed 091504
Thu 0916AM
Thu 093004
Finish
Wed 070903
Fri 1OtO7u3
Fri 112803
Fri 122603
Mon 121503
Fri 010904
Mon 011204
Mon 012604
Thu 021904
Tue 071304
Thu 040104
Thu 042204
Tue 042704
Wed 050504
Tue 052504
Tue 071304
Tue 060804
Tue 061504
Tue 070604
Tue 071304
Fri 070904
Tue 072004
Fri 073004
Mon 080204
Mon 082304
Tue 082404
Tue 091404
Wed 091504
Wed 082904
Thu 093004
FIGURE 4-1 DRAFT HOWS CORNER SUPERFUND SITE
Tl EVALUATION amp RELD WORK FOR HYDRAUUC CONTAINMENT SYSTEM DESIGN PROPOSED PROJECT SCHEDULE
2003 2004 Mav |
Jun | Jul
ltamp i
Aug
i
Sen Oct I Nov Dec Jan Feb I Mar
ii i i
k ^tr 1
1V i
I t bull ^
I
ta^M bull bull M W
l LgtH^HBKLii LJ Mi
I
bull bull raquo bull laquo^ 0930
Task Progress I^MLHHHI^LB Summary ^^^^^^^^f External Tasks M B WMMM Deadline ^7 Project Hows Comer Schedule6A bull bull bull 1 UData Fri 101003 Split Milestone ^ Project Summary ^f^KKKKKK^^ External Milestone ^
Pagei
50 ACRONYMS
AOC Administrative Order by Consent
ARARs Applicable or Relevant and Appropriate Requirements
ATV acoustic televiewer
bgs below ground surface
CERCLA Comprehensive Environmental Resource and Conservation Liability Act
DNAPL Dense Non-Aqueous Phase Liquid
GAC granular activated carbon
gpm gallons per minute
HASP Health and Safety Plan
row investigation-derived waste
MCL Maximum Containment Level
MEDEP Maine Department of Environmental Protection
MEG Maine Enforcement Guideline
mgkg milligrams per kilogram
Hg kg micrograms per kilogram
NCP National Contingency Plan
PCB polychlorinated biphenyl
PID photo ionization detector
ppm parts per million
PRP Potentially Responsible Party
TISOW WOODARD amp CURRAN 24 September 302003 20564309
QAPP Quality Assurance Project Plan
QAQC Quality AssuranceQuality Control
RA Remedial Action
RAO Remedial Action Objective
RCRA Resource Conservation and Recovery Act
RD Remedial Design
RIFS Remedial InvestigationFeasibility Study
ROD Record of Decision
SAP Sampling and Analysis Plan
SOW Statement of Work
TAL target analyte list
TI Technical Impracticability
USEPA United State Environmental Protection Agency
VOCs volatile organic compounds
WampC Woodard amp Curran Inc
TISOW WOODARD amp CURRAN 25 September 302003 20564309
REFERENCES
Everts CJ RS Kanwar (1994) Evaluation of Rhodamine WT as an adsorbed tracer in an agricultural
soil J Hydrology 153 53-70
Kasnavia T D Vu DA Sabatini (1999) Fluorescent dye and media properties affecting sorption and
tracer selection Groundwater 37 376-381
Ptak T G Schmid (1996) Dual-tracer transport experiments in a physically and chemically
heterogeneous porous aquifer effective transport parameters and spatial variability J Hydrology
183 117-138
Sabatini DA T A Austin (1991) Characteristics of Rhodamine WT and fluorescein as adsorbing
ground-water tracers Ground Water 29 341-349
Trudgill ST (1987) Soil water dye tracing with special reference to the use of Rhodamanie WT
Lissamine FF and Amino G acid Hydrological Processes 1 149-170
US Environmental Protection Agency (USEPA) 1993 Guidance for Evaluating the Technical
Impracticability of Ground-Water Restoration - Interim Final Office of Solid Waste and
Emergency Response Washington DC Directive 92342-25 September 1993
US Environmental Protection Agency (USEPA) 2002 Interim Record of Decision Summary shy
Operable Unit One Non-Source Area Groundwater West SiteHows Corner Superfund Site
Plymouth Maine EPA Region 1 September 2002
US Environmental Protection Agency (USEPA) 2003 Proposed Scope of Work West SiteHows
Corner Superfund Site Plymouth Maine EPA Region 1 4 pages September 2002
Vasudevan D RL Fimmen AB Francisco (2001) Tracer-grade Rhodamine WT Structure of
constituent isomers and their sorption behavior Environ Sci Technol 35 4089-4096
nsow WOODARD amp CURRAN 26 September 30 2003 20564309
Woodard amp Curran Inc (WampC) 2002 Final Feasibility Study Report - Non-Source Area Groundwater
Hows Comer Superfund Site Plymouth Maine July 2002
TISOW WOODARD amp CURRAN 27 September 302003 20564309
f
m WOODARD amp CURRAN Maine Massachusetts New Hampshire Connecticut Florida Illinois Operational offices across the US 1-800-426-4262 wwwwoodardcurrancom
i
0
0 bull Subtask 3 - Packer testing
bull Subtask 4 - Sampling and analysis
bull bull Subtask 5 - Monitoring well installation
bull Subtask 5 - Pumping test and
bull Subtask 6 - Tracer test
Each of the subtasks is summarized below however a comprehensive discussion of these subtasks and
associated methodologies will be provided in the SAP
Subtask 1 - Boring Installation
j Information obtained during the installation of the new borings will be used in the evaluation of the
aquifer hydraulic conductivity and the analysis of other aquifer properties (eg porosity fracture
frequency) For this subtask it is anticipated that one angled boring will be completed to a depth of 150
feet (ft) below ground surface (bgs) One additional angled boring and four new vertical bedrock borings
will be completed to depths of approximately 100 ft bgs This depth is consistent with the depth
evaluated in the RI and will allow evaluation of bedrock and groundwater properties to depths below the
transition from less competent to more competent bedrock (approximately 50 to 80 ft bgs)
m One additional vertical boring will be installed to a depth of 100 ft bgs as the pumping well location for
bull the pumping test The pumping well location will be based on the results of field work conducted prior to
its installation The proposed drilling program is designed to enhance understanding of the flow system
by aligning new boring locations with existing wells to characterize hydraulic properties of the fracture
network and bulk bedrock Furthermore the program allows for additional characterization of
M contamination in the Source Area groundwater The rationale for the boring locations is summarized in
Table 3-1 and the proposed locations of the borings are depicted on Figure 3-1 Actual locations may
M vary depending on field conditions and accessibility
jlt The drilling protocol employed during installation of both the angled and the vertical wells will allow for
evaluation of the potential presence of DNAPL in the rock and the need for modifications to the drilling
method if DNAPL is detected If sheen or product is observed in the return water core or cuttings from a
boring an interface probe may be employed to determine whether a NAPL is present in the boring
Based on the presence of DNAPL the boring may be terminated at a shallower depth than planned the
J TISOW 4 1 WOODARD amp CURRAN 8 September 302003
20564309
location may be abandoned or other practices may be employed to reduce the potential for causing
downward migration of DNAPL The protocol will be described in the Work Plan and the SAP
Angled Borings Two angled borings will be installed using air-hammer drilling methods The first
angled boring (AW-201) will be installed to a depth of 150 ft bgs in the vicinity of existing well MWshy
106 northeast of and outside of the source area and within the dissolved phase groundwater plume This
well will be angled from the surface toward the southeast at depth in order to intersect as many northwest-
dipping near-vertical fractures as possible The angle of this boring will be approximately 30deg to 40deg
from the vertical resulting in a surface projection of approximately 84 to 126 ft and total length of
approximately 173 to 195 ft The second angled boring (AW-202) will be installed to a depth of 100 ft
bgs in the vicinity of the existing MW-2 well cluster within the source area This well also will be angled
from the surface toward the southeast at depth in order to intersect near-vertical fractures The angle of
this boring will be approximately 30deg to 40deg from the vertical resulting in a surface projection of
approximately 58 to 84 ft and total length of approximately 115 to 130 ft
m
4
sect
i
TISOW WOODARD amp CURRAN 9 September 302003 20564309
Table 3-1
Rationale for Proposed Well Locations
Hows Corner Technical Impracticability Evaluation and Field work for Hydraulic Containment System Design
Well Identification
AW-201
AW-202
MW-203
MW-204
MW-205
MW-206
PW-207
Boring Orientation
Angled
Angled
Vertical
Vertical
Vertical
Vertical
Vertical
Minimum Boring Diameter (inches)
4
4
4
4
4
4
6
Drilling Method
Air Hammer
Air Hammer
Coring
Air Hammer
Air Hammer
Air Hammer
Core Air Hammer Over -drilling
Source Area Non-Source Area
Non-Source Area
Source Area
Non-Source Area
Non-Source Area
Source Area
Source Area
Source Area
Rationale for Boring
bull Intercept near-vertical fractures to understand subsurface geology bull Aid in iting MW-203 bull Intercept near-vertical fractures to understand subsurface geology bull Aid in siting PW-201 (Pumping well) bull ion of contamination bull 1 future monitoring location bull Potential reinjection well for hydraulic containment system bull Core for matrix diffusion evaluation bullbullbullbull Ibullbullbullbull 1bullbullbullbull 1bullbull bull 1
tion point for pumping test tion point in tracer test ion of contamination
future monitoring location tion point for pumping test tion point in tracer test ion of contamination
future monitoring location tion point for pumping test tion point in tracer test ion of contamination
future monitoring location tion point for pumping test
test well extraction well
bull Core for matrix diffusion evaluation bull i point for tracer test
TISOW September 30 2003 WOODARD amp CURRAN 20564309
MW-105D MW-5B
Primary Bedding Secondary Cleavage
Tertsry Fracturing
NOTE A total of 60 observations warn made rtrtjs roprtraont tticopy number of obsafvatk noted wtthln each azimutha) segment
MW-1 1 3D euro MW-205
2 AcreSource
Fenced-^ Area i
MW-103D MW-103S
17-Acre Property Boundary
MW-104D MW-1041 bull
MW-104S
Legend Figure 3-1 J Proposed Monitoring Well Proposed Well Locations
o- Site Property Boundary bull^bullProposed Pumping Well Hows Corner Superfund Site -xmdashx- Source Area Plymouth Maine
^ ^Proposed Angled Well bullamp Existing Monitoring Well bullWDODARDampCURRAN
Englnoortng bull Science bull Operations 205643wipsite-8OlaquoAx-opt-1-2-u3-1D
bull During the installation of each angled boring observations will be made regarding water gainloss
drilling rate and bit behavior to assess the depth of potential fractures In addition water levels will be
9 measured in nearby borings using either hand measurements data loggers or both to evaluate
connectivity between locations A change in water level in a nearby boring will indicate a hydraulic
at connection between the borings Borehole geophysics will also be performed on the borings (See Subtask
2 below) Information from each angled boring will be used to site an adjacent vertical well (MW-203
^ and PW-207) so that it intercepts a fracture observed in the angled boring
^ Vertical Borings Two of the vertical borings will be completed with rotary diamond coring to
approximately 100 ft bgs These borings will be adjacent to the angled borings described above One of
^ the cored borings (MW-203) will be located near MW-106 outside of the source area within the
dissolved-phase groundwater plume (see Figure 3-1) The other cored boring (PW-207) will be the
pumping well which is anticipated to be located within the source area in the vicinity of the existing
MW-2 well cluster Coring will allow data collection for several purposes including direct observation
of bedrock for determination of the nature of the rock matrix determination of the location and nature of
fractures and the degree of fracturing comparison with geophysical logs (Subtask 2) to verify
interpretation of the logs and collection of core samples for analysis (Subtask 4)
The remaining borings will be located east of the 2-acre fenced area within or near the periphery of the
source area and will be sited to align approximately with existing wells based on the known fracture
orientations at the Site (MW-204 and MW-205) or with new wells based on the known fracture
pound orientations at the Site (MW-206) Data from these locations in conjunction with the other borings
installed as part of this TI SOW and the existing wells will be used in the interpretation of the pumping
^ test (Subtask 6) and tracer test (Subtask 7) In addition these three borings will further delineate
contamination and provide potential monitoring locations for long-term monitoring Each of these
^ borings will be advanced to approximately 100 ft bgs with a minimum four-inch diameter air hammer
^ During the installation of each boring observations will be made regarding water gainloss drilling rate
and bit behavior to assess the depth of potential fractures In addition water levels will be measured in
nearby borings using either hand measurements data loggers or both to evaluate connectivity between
locations A change in water level in a nearby boring will indicate a hydraulic connection between the
TISOW WOODARD amp CURRAN 12 September 302003 20564309
borings Borehole geophysics and packer testing will also be performed on the borings (See Subtasks 2
and 3 below)
Drilling water will be containerized on site and treated through granular activated carbon (GAC) Treated
water will be analyzed to verify that PCB and VOC concentrations have been reduced to below ARARs
prior to discharge to the ground surface Cuttings will be spread on the ground surface at the site
consistent with the Remedial Investigation work plan
It is anticipated that up to 10 core samples from each cored boring (total of 20 cores) will be collected and
submitted to an off-site laboratory for analyses of porosity (matrix and bulk) permeability bulk density
and fraction of organic carbon (f^) using methods described in Subtask 4
Subtask 2 - Borehole Geophysics
To supplement information on fracture location and connectivity obtained during boring advancement a
borehole geophysical survey will be conducted on the newly installed bedrock borings to evaluate the
nature and orientation of water bearing fractures in the borings The survey will be performed at the
completion of the angled borings and again at the completion of the vertical borings The information
obtained during the survey may be used to identify the location of subsequent boring(s) by refining the
understanding of the depth aperture and orientation of bedrock fractures The following measurements
are proposed for the new borings caliper fluid temperature fluid resistivity and acoustic televiewer
(ATV) Single-point resistively and 16 inch normal measurements will also be made in the first two
borings installed and the data will be compared to data from the other geophysical logs to determine if
the measurements confirm and significantly improve the interpretation regarding the presence of water-
bearing fractures If the measurements are applicable to identification of fractures they may be included
in lieu of other geophysical logs in the remainder of the borings
Subtask 3 - Packer Testing
To further refine information on the aquifer hydraulic conductivity the hydraulic connection between
fractures in the borings will be evaluated during packer testing of vertical borings The data will be used
to estimate the hydraulic conductivity of specific fractures and fracture zones The packer testing will be
performed after the vertical borings have been installed and the borehole geophysical survey completed
TISOW WOODARD amp CURRAN 13 September 30 2003 20564309
bull
m
M
Drilling observations and information from borehole geophysics will be used to identify specific fractures
below the water table that are capable of transmitting water Prior to water injection for hydraulic
conductivity and fracture connectivity testing groundwater samples will be collected at selected intervals
for analysis of VOCs (See Subtask 4) Sampling intervals will be selected based on drilling observations
and logging results that indicate water is moving into or out of the borehole or that fractures exist to
promote water movement such as rapid increase in the amount of water returned rapid change in
temperature or highly fractured interval
^
^
bull
f$
Double packer testing will be performed at selected intervals within each newly installed boring It is
anticipated that up to six intervals per well will be tested for a maximum of 24 intervals and that for each
interval the test will include an approximate 15-minute injection of potable water at four progressively
increasing pressures Packer spacing is anticipated to be 10 ft however spacing may vary so that packers
are not located in potential fracture zones identified using information from rock cores drilling
observations and borehole geophysics The tests at an individual interval will be terminated if it appears
that the interval is not accepting water Care will be taken to minimize over-pumping or over-
pressurizing of the fractures The flow rate will be measured to evaluate the characteristics of the
fracture Water levels in adjacent borings will be measured during the packer testing to determine if a
hydraulic connection exists between the borings Water generated during packer testing will be
containerized on site and treated through GAC Treated water will be analyzed to verify that PCB and
VOC concentrations have been reduced to below ARARs prior to discharge to the ground surface
4 Subtask 4 Sampling and Analysis
~d
^
Rock and groundwater samples will be collected during the field program for laboratory analysis The
results of the analyses will be used to help refine the distribution of the plume and to estimate bedrock
properties These analyses will be used in conjunction with existing data during the TI evaluation to
refine cleanup times and establish the limits of the TI zone
As described in Subtask 1 it is anticipated that up to 10 core samples from each cored boring (total of 20
core samples) will be collected and submitted to an off-site laboratory for analyses of porosity (matrix and
bulk) permeability bulk density and fraction of organic carbon (f^) using existing industry methods
Subject to further evaluation of industry methods Woodard amp Curran proposes that porosity
TISOW WOODARD amp CURRAN20564309
14 September 302003
permeability and density will be measured using methods in the American Petroleum Institutes API RPshy
40 Fraction of organic carbon (f^) will be measured using either the LECO TOC method or Walkey-
Black method The LECO TOC method is a standard method in the petroleum industry and involves the
direct combustion of a ground rock sample The Walkey-Black method is a commonly used USEPA-
approved chemical oxidation method for determination of foe in soils In addition either method could be
used if a sample were scraped from a fracture surface To develop a reasonable range of f for Site
bedrock up to five samples will be selected from each boring from the unfractured matrix and up to five
from the fracture surfaces In addition Woodard amp Curran will evaluate the appropriateness of selecting
rock samples from a subset of the core samples from areas near fractures as well as from non-fractured
areas and submitting the samples for VOC analysis following methanol extraction
Results from these analyses will be used in conjunction with groundwater contaminant concentrations to
evaluate the significance of diffusion of contamination from the bedrock matrix in both the Source Area
and the Non-Source Area Although matrix diffusion likely is a significant factor in the determination of
cleanup times within the Source Area the potential applicability of matrix diffusion in the Non-Source
Area is not known These core analyses may provide evidence to assist in developing an estimate
through calculations of the effect of matrix diffusion on cleanup times
As noted in Subtask 3 prior to injection of water during packer testing groundwater samples will be
collected at selected intervals for analysis of volatile organic compounds (VOCs) Up to a total of 20
groundwater samples plus appropriate quality control samples will be collected from the newly installed
borings The samples will be submitted to an off-site laboratory for analysis Analytical results will be
validated in accordance with USEPA protocol and the data will be managed in WampCs existing
groundwater sampling analytical database for this site
Up to 21 existing monitoring wells from within or nearby the 17-acre property plus four new wells once
constructed will be sampled using low-flow techniques and submitted to an off-site laboratory for VOC
analysis Analytical results will be validated in accordance with USEPA protocol and the data will be
managed in WampCs existing groundwater sampling analytical database for this site
TISOW WOODARD amp CURRAN 15 September 302003 20564309
Subtask 5 - Monitoring Well Installation
Although it is anticipated that the newly installed borings will be left as open holes for tracer testing and
for pumping tests monitoring wells will be installed and developed in the newly installed borings unless
the USEPA MEDEP and PRP Group determine that the location is inappropriate for such use The
monitoring wells will be constructed of two-inch schedule 40 PVC screen and riser Screen intervals will
be selected based on the location of fractures identified during drilling geophysical logging and packer
testing A sand pack will be placed around the screen and will extend from approximately two ft below
the screen to approximately two ft above the screen
Subtask 6 - Pumping Test
WampC will conduct a single constant discharge pumping test to evaluate hydraulic properties of the
aquifer It is anticipated that the test will be conducted in a new pumping well in the vicinity of the
existing MW-2 well cluster within the source area Data from the pumping test will be used in
conjunction with other data from the investigation to improve the understanding of groundwater
movement and contaminant transport in the Source and Non-Source areas The results of the pumping
test will be used to refine the Site conceptual model as well as in the design of the hydraulic containment
system that is being constructed under the authority of the AOC for the RD
The groundwater pumping test will include the following components (1) Pumping test setup (2) Pretest
monitoring (3) Constant Discharge Pumping Test (4) Post-test monitoring and (5) Data Analysis
Pumping Test Setup In support of the groundwater pumping test WampC will install a pumping well
(PW-207) and procure and install the required groundwater extraction treatment and storage equipment at
the Site The well will be cored and over drilled to allow construction of a 4-inch well The location will
be in the vicinity of the MW-2 well cluster and be based upon results of the angled bedrock boring AWshy
202 The equipment will include but not be limited to
bull Down well pump plumbing and appurtances
bull Two (2) 20000 frac tanks
bull Groundwater transfer pumps and controls
bull Settlingaerationsand filtration treatment processes for the treatment of inorganics (if needed) and
nsow WOODARD amp CURRAN 16 September 302003 20564309
bull Granular activated carbon units for the treatment of dissolved organics in the groundwater
The groundwater treatment process will include the following processes 1) an oxidation and filtration
step to remove the inorganics from the groundwater and GAC units to treat the organic contaminants in
the extracted groundwater
Pretest Monitoring Prior to initiation of pumping WampC will monitor water levels in existing wells and
newly installed borings adjacent to the pumping well using a combination of hand measurements and data
loggers to develop an understanding of the piezometric surface under unstressed conditions The wells
proposed for water-level monitoring will be described in the work plan In addition all gauges
transducers flow meters and other equipment used in conducting the pumping tests shall be calibrated
before use
Constant Discharge Pumping Test The pumping test will be conducted in the source area using
newly-installed pumping well PW-207 It is anticipated that the test will be conducted at a pumping rate
of approximately 2 gallons per minute (gpm) for a period of 2 to 3 days however a higher or lower rate
may be shown to be appropriate based on the drilling and packer testing conducted during boring
installation Woodard amp Curran proposes to conduct this test using a vacuum-enhanced recovery system
(VERS) as described in the ROD so that the water level is not lowered appreciably in the vicinity of the
pumping well to prevent the potential migration of NAPLs to deeper bedrock zones The appropriateness
and feasibility of the VERS for the pumping test will be determined by field testing or literature
evaluation prior to completion of the Work Plan Because of the short duration of this test it is not
anticipated that stability of water levels will be reached in observation wells The test will however
provide information to estimate hydraulic conductivity and bedrock storage During the test the water
levels in the pumping well and selected monitoring wells will be logged continuously via down well data
loggers It is anticipated that water levels in approximately 24 wells will be measured using hand
measurements and data loggers
Groundwater extracted during the pumping test will be stored temporarily in an on-site frac tank prior to
on-site treatment and disposal
TISOW WOODARD amp CURRAN 17 September 302003 20564309
Post-Test Monitoring After the pump is turned off in the pumping well water levels will continue to be
monitored using hand measurements and data loggers until they have returned to within 10 of the preshy
test levels For planning purposes this has been estimated to be two weeks
Data Analysis Data collected during the pumping test will be analyzed with Aquifer Win32 Results of
the pumping test will be summarized in the summary data package for the TI Evaluation and the results
will also be used in the design of the hydraulic containment system specified in the Interim ROD that is
being conducted under the authority of the AOC for the RD Detail regarding use of the pumping test
data in hydraulic system design will be provided in the Remedial Design Work Plan
Subtask 7 - Tracer Test
WampC will conduct a tracer test using a conservative tracer to evaluate fracture connectivity porosity
dispersivity and matrix diffusion of the bedrock aquifer in both the Source Area and Non-Source Area
To increase the potential for success of this test results of the pumping test evaluation will be used to
revise the tracer test plan proposed here as necessary Following rebound of water levels after
completion of the pumping test WampC will initiate a single natural gradient tracer test The test will
consist of injecting a tracer into well PW-207 in the source area (Figure 3-1) for up to five days and
monitoring the tracers arrival in nearby wells Borehole geophysics core evaluation and packer testing
will be used to select the specific injection depth(s) in the well
A Tracer Test Work Plan will be completed prior to initiation of injection to determine the type quantity
and concentration of tracer based on the distance between the injection well and the monitoring wells A
conservative tracer that is one that is not preferentially adsorbed to rock or organic matter will be
selected for the tracer test Tracer injection equipment including tanks and flow-regulating and metering
equipment and pumps will be used to mix the tracer at the surface prior to injection Fractures may be
packered in the injection well and tracer solution will be injected at a rate determined during preparation
of the Tracer Test Work Plan During injection the potentiometric surface of the aquifer will be
monitored to verify that the potentiometric surface remains relatively constant during the injection
process
nsow WOODARD amp CURRAN 18 September 302003 20564309
Prior to injection of the tracer background concentration will be established by collecting samples from
up to six wells in the area of the tracer test and analyzing them for the tracer using an appropriate
analytical method Following injection of the tracer solutions the concentration of the tracer in
downgradient wells and borings will be measured A monitoring network will be established using nearby
monitoring wells Downhole probes will be installed in six new and existing wells near the injection well
to be identified in the work plan first to determine the background tracer concentrations and then to
monitor for the presence of the tracer upon initiation of the test Measurements will be collected at
periodic intervals to be determined based on the results of packer testing If an increase in tracer
concentration is detected or at a minimum on a weekly basis a water sample will be collected using low
flow sampling methodologies and analyzed in an off-site laboratory to evaluate the concentration of the
tracer The concentration of the tracer will be recorded Monitoring of the tracer concentration will
continue throughout the duration of the test The tracer will be allowed to flow with groundwater for one
month or until detected in wells in the vicinity of MW-106 whichever is shorter
313 Task 3 - TI Evaluation and Reporting
The TI Evaluation and reporting task includes the following five subtasks
bull Data evaluation
bull Summary data package
bull Draft TI Evaluation
bull Meetings with PRP Group and USEPA and
bull Revise and finalize TI Evaluation
As the subtasks of the field investigation are completed the data will be evaluated for the purpose of
addressing the data gaps identified by USEPA Specifically the data will be used to further refine the
cleanup times for non-source area groundwater presented in the Interim ROD
The data obtained during the field investigation will be reduced and evaluated and a summary data
package will be prepared that will include a discussion of the field activities completed and presentation
of the data It is anticipated that up to two meetings with USEPA will be necessary before the data
evaluation and summary report are completed
TISOW WOODARDampCURRAN 19 September 302003 20564309
Data collected during the pumping test will be analyzed with Aquifer Win32 Results will be summarized
in the summary data package and will also be presented as part of the RD submittals
Following submittal of the summary data package the TI evaluation will be prepared In accordance with
EPA guidance (1993) the TI waiver evaluation document will address the following topics
1 Specific ARARS or media cleanup standards for which TI determination is sought This section of the
TI Evaluation will identify the specific contaminants for which the TI determination is sought Based on
information available to date a waiver may be appropriate for pesticides PCBs chlorinated organic
compounds and other site-related contaminants that upon evaluation will not attain ARARs in a
reasonable period of time
2 Spatial area over which the TI waiver will apply The purpose of the additional site investigation
outlined in this SOW is to obtain the data necessary to further refine cleanup times presented in the
Interim ROD to determine what portions of the Site will not be expected to reach ARARs within a
reasonable time Consistent with TI guidance (USEPA 1993) the TI evaluation will specify the
horizontal and vertical extent of the area for which TI determination is sought Groundwater
concentration data from the RI and the TI SOW will be used to refine the distribution of the plume Data
from the drilling geophysical logging packer testing and pumping and tracer tests will be used to refine
the Site conceptual model and the cleanup times that will serve as the basis for establishing the scope and
nature of the TI zone
3 Conceptual Model The conceptual model forms the technical core of the TI Waiver Evaluation since
it provides basis for understanding of the restoration potential of the site The conceptual model outlines
the physical and hydrogeological constraints that hinder remediation or removal of Site contaminants and
it is the extent of these constraints rather than restoration timeframe alone that USEPA will use to
evaluate the necessity of the TI waiver of ARARs The conceptual model is the link between restoration
potential and restoration timeframe since it explains why proposed technologies are unlikely to work
either at all or within the desired 100-year timeframe
The Site conceptual model is not a mathematical model however as the result of the extensive modeling
and investigations of the site WampC has a strong understanding of the complex bedrock and overburden
TISOW WOODARDampCURRAN 20 September 302003 20564309
groundwater system beneath this site This understanding has been presented previously in both the RI
report and the FS and will be refined based on the TI SOW as necessary and summarized in the TI
Waiver Evaluation with specific attention to the physical and hydrogeological constraints on remediation
In particular the Site conceptual model will be reviewed in light of the new geologic data from drilling
logging and packer testing and the new hydrogeologic data obtained from the pumping test and tracer test
and will be revised to incorporate the new understanding
4 An evaluation of the restoration potential of the site This section will consist of a several components
It will present a systematic review of the technologies potentially capable of remediating the site given
the physical and hydrogeological constraints identified in the site model The newly acquired data will
provide an improved understanding of bedrock hydraulic properties that will allow a more Site-specific
evaluation of technologies The review of technologies will also include review of innovative
technologies and will evaluate whether existing remedial technologies or strategies would be capable of
achieving groundwater restoration at the site in a reasonable timeframe The section reference the FS and
will summarize the alternative remedies considered in the FS focusing on the ability of each to restore
groundwater in a reasonable timeframe It will also include a discussion of the selected hydraulic
containment system in light of the data gathered from the pumping test conducted in conjunction with the
TI SOW
Based on the Batch Flushing Model and using the agreed upon koc data from the RI as well as data from
this TI SOW including the f data collected as part of Subtask 4 a restoration timeframe analysis will be
conducted Following completion of the timeframe analysis and consideration of the results of drilling
rock and water analyses and pumping and tracer test a determination will be made regarding the Source
Area and the portion of the Non-Source Area VOC plume that will not attain ARARs in a reasonable
time
TISOW WOODARD amp CURRAN 21 September 302003 20564309
40 SCHEDULE
A proposed project schedule is included with this plan as Figure 4-1 This schedule is included for
discussion purposes and will be modified as necessary once the final scope of work as been approved by
all parties and the field work activities are coordinated with the subcontractors
TISOW WOODARD amp CURRAN 22 September 302003 20564309
ID
2
3
4
5
6
7 a i 10
11
12
13
14
15
16
17
16
19
20
21
22
24
25
26
27
26
29
30
31
32
Task Name
Project Meeting with EPA
Finalize SOW
Prepare Work Plans QAPP HASP Revision
Submit Work Plans for EPA Approval
Project Meeting with EPA
Revisions to work plans
Submit final work plans
Subcontractor Contracts
Project Meeting wEPA
Field Investigation
Site Mobilization
Install Borings
Borehole Geophysics
Packer Testing amp Collect GW Samples
Pumping Test
Tracer Test
Test setup
Injection
Monitoring
Data Reporting
InstallDevelop Wells
Data Evaluation
Prepare Data Package
Data Package Submittal to EPA
Draft Tl Evaluation Repon
Draft Tl Evaluation Report Submttal to EPA
EPA ReviewComment on Tl Evaluation ReF
Project Meeting wEPA
Revisions to Tl Evaluation Report
Submit Final Tl Evaluation Report
Start
Wed 070903
Thu 071003
Fri 101003
Mon 120103
Mon 121503
Mon 122903
Mon 011204
Tue 011304
Thu 021904
Fri 032104
Fri 032604
Fri 040204
Fri 041604
Fri 042304
Thu 050604
Wed 060204
Wed 060204
Wed 060904
Wed 060904
Wed 062304
Wed 070704
Wed 042804
Wed 062304
Mon 080204
Mon 070504
Tue 082404
Wed 082504
Wed 091504
Thu 0916AM
Thu 093004
Finish
Wed 070903
Fri 1OtO7u3
Fri 112803
Fri 122603
Mon 121503
Fri 010904
Mon 011204
Mon 012604
Thu 021904
Tue 071304
Thu 040104
Thu 042204
Tue 042704
Wed 050504
Tue 052504
Tue 071304
Tue 060804
Tue 061504
Tue 070604
Tue 071304
Fri 070904
Tue 072004
Fri 073004
Mon 080204
Mon 082304
Tue 082404
Tue 091404
Wed 091504
Wed 082904
Thu 093004
FIGURE 4-1 DRAFT HOWS CORNER SUPERFUND SITE
Tl EVALUATION amp RELD WORK FOR HYDRAUUC CONTAINMENT SYSTEM DESIGN PROPOSED PROJECT SCHEDULE
2003 2004 Mav |
Jun | Jul
ltamp i
Aug
i
Sen Oct I Nov Dec Jan Feb I Mar
ii i i
k ^tr 1
1V i
I t bull ^
I
ta^M bull bull M W
l LgtH^HBKLii LJ Mi
I
bull bull raquo bull laquo^ 0930
Task Progress I^MLHHHI^LB Summary ^^^^^^^^f External Tasks M B WMMM Deadline ^7 Project Hows Comer Schedule6A bull bull bull 1 UData Fri 101003 Split Milestone ^ Project Summary ^f^KKKKKK^^ External Milestone ^
Pagei
50 ACRONYMS
AOC Administrative Order by Consent
ARARs Applicable or Relevant and Appropriate Requirements
ATV acoustic televiewer
bgs below ground surface
CERCLA Comprehensive Environmental Resource and Conservation Liability Act
DNAPL Dense Non-Aqueous Phase Liquid
GAC granular activated carbon
gpm gallons per minute
HASP Health and Safety Plan
row investigation-derived waste
MCL Maximum Containment Level
MEDEP Maine Department of Environmental Protection
MEG Maine Enforcement Guideline
mgkg milligrams per kilogram
Hg kg micrograms per kilogram
NCP National Contingency Plan
PCB polychlorinated biphenyl
PID photo ionization detector
ppm parts per million
PRP Potentially Responsible Party
TISOW WOODARD amp CURRAN 24 September 302003 20564309
QAPP Quality Assurance Project Plan
QAQC Quality AssuranceQuality Control
RA Remedial Action
RAO Remedial Action Objective
RCRA Resource Conservation and Recovery Act
RD Remedial Design
RIFS Remedial InvestigationFeasibility Study
ROD Record of Decision
SAP Sampling and Analysis Plan
SOW Statement of Work
TAL target analyte list
TI Technical Impracticability
USEPA United State Environmental Protection Agency
VOCs volatile organic compounds
WampC Woodard amp Curran Inc
TISOW WOODARD amp CURRAN 25 September 302003 20564309
REFERENCES
Everts CJ RS Kanwar (1994) Evaluation of Rhodamine WT as an adsorbed tracer in an agricultural
soil J Hydrology 153 53-70
Kasnavia T D Vu DA Sabatini (1999) Fluorescent dye and media properties affecting sorption and
tracer selection Groundwater 37 376-381
Ptak T G Schmid (1996) Dual-tracer transport experiments in a physically and chemically
heterogeneous porous aquifer effective transport parameters and spatial variability J Hydrology
183 117-138
Sabatini DA T A Austin (1991) Characteristics of Rhodamine WT and fluorescein as adsorbing
ground-water tracers Ground Water 29 341-349
Trudgill ST (1987) Soil water dye tracing with special reference to the use of Rhodamanie WT
Lissamine FF and Amino G acid Hydrological Processes 1 149-170
US Environmental Protection Agency (USEPA) 1993 Guidance for Evaluating the Technical
Impracticability of Ground-Water Restoration - Interim Final Office of Solid Waste and
Emergency Response Washington DC Directive 92342-25 September 1993
US Environmental Protection Agency (USEPA) 2002 Interim Record of Decision Summary shy
Operable Unit One Non-Source Area Groundwater West SiteHows Corner Superfund Site
Plymouth Maine EPA Region 1 September 2002
US Environmental Protection Agency (USEPA) 2003 Proposed Scope of Work West SiteHows
Corner Superfund Site Plymouth Maine EPA Region 1 4 pages September 2002
Vasudevan D RL Fimmen AB Francisco (2001) Tracer-grade Rhodamine WT Structure of
constituent isomers and their sorption behavior Environ Sci Technol 35 4089-4096
nsow WOODARD amp CURRAN 26 September 30 2003 20564309
Woodard amp Curran Inc (WampC) 2002 Final Feasibility Study Report - Non-Source Area Groundwater
Hows Comer Superfund Site Plymouth Maine July 2002
TISOW WOODARD amp CURRAN 27 September 302003 20564309
f
m WOODARD amp CURRAN Maine Massachusetts New Hampshire Connecticut Florida Illinois Operational offices across the US 1-800-426-4262 wwwwoodardcurrancom
i
location may be abandoned or other practices may be employed to reduce the potential for causing
downward migration of DNAPL The protocol will be described in the Work Plan and the SAP
Angled Borings Two angled borings will be installed using air-hammer drilling methods The first
angled boring (AW-201) will be installed to a depth of 150 ft bgs in the vicinity of existing well MWshy
106 northeast of and outside of the source area and within the dissolved phase groundwater plume This
well will be angled from the surface toward the southeast at depth in order to intersect as many northwest-
dipping near-vertical fractures as possible The angle of this boring will be approximately 30deg to 40deg
from the vertical resulting in a surface projection of approximately 84 to 126 ft and total length of
approximately 173 to 195 ft The second angled boring (AW-202) will be installed to a depth of 100 ft
bgs in the vicinity of the existing MW-2 well cluster within the source area This well also will be angled
from the surface toward the southeast at depth in order to intersect near-vertical fractures The angle of
this boring will be approximately 30deg to 40deg from the vertical resulting in a surface projection of
approximately 58 to 84 ft and total length of approximately 115 to 130 ft
m
4
sect
i
TISOW WOODARD amp CURRAN 9 September 302003 20564309
Table 3-1
Rationale for Proposed Well Locations
Hows Corner Technical Impracticability Evaluation and Field work for Hydraulic Containment System Design
Well Identification
AW-201
AW-202
MW-203
MW-204
MW-205
MW-206
PW-207
Boring Orientation
Angled
Angled
Vertical
Vertical
Vertical
Vertical
Vertical
Minimum Boring Diameter (inches)
4
4
4
4
4
4
6
Drilling Method
Air Hammer
Air Hammer
Coring
Air Hammer
Air Hammer
Air Hammer
Core Air Hammer Over -drilling
Source Area Non-Source Area
Non-Source Area
Source Area
Non-Source Area
Non-Source Area
Source Area
Source Area
Source Area
Rationale for Boring
bull Intercept near-vertical fractures to understand subsurface geology bull Aid in iting MW-203 bull Intercept near-vertical fractures to understand subsurface geology bull Aid in siting PW-201 (Pumping well) bull ion of contamination bull 1 future monitoring location bull Potential reinjection well for hydraulic containment system bull Core for matrix diffusion evaluation bullbullbullbull Ibullbullbullbull 1bullbullbullbull 1bullbull bull 1
tion point for pumping test tion point in tracer test ion of contamination
future monitoring location tion point for pumping test tion point in tracer test ion of contamination
future monitoring location tion point for pumping test tion point in tracer test ion of contamination
future monitoring location tion point for pumping test
test well extraction well
bull Core for matrix diffusion evaluation bull i point for tracer test
TISOW September 30 2003 WOODARD amp CURRAN 20564309
MW-105D MW-5B
Primary Bedding Secondary Cleavage
Tertsry Fracturing
NOTE A total of 60 observations warn made rtrtjs roprtraont tticopy number of obsafvatk noted wtthln each azimutha) segment
MW-1 1 3D euro MW-205
2 AcreSource
Fenced-^ Area i
MW-103D MW-103S
17-Acre Property Boundary
MW-104D MW-1041 bull
MW-104S
Legend Figure 3-1 J Proposed Monitoring Well Proposed Well Locations
o- Site Property Boundary bull^bullProposed Pumping Well Hows Corner Superfund Site -xmdashx- Source Area Plymouth Maine
^ ^Proposed Angled Well bullamp Existing Monitoring Well bullWDODARDampCURRAN
Englnoortng bull Science bull Operations 205643wipsite-8OlaquoAx-opt-1-2-u3-1D
bull During the installation of each angled boring observations will be made regarding water gainloss
drilling rate and bit behavior to assess the depth of potential fractures In addition water levels will be
9 measured in nearby borings using either hand measurements data loggers or both to evaluate
connectivity between locations A change in water level in a nearby boring will indicate a hydraulic
at connection between the borings Borehole geophysics will also be performed on the borings (See Subtask
2 below) Information from each angled boring will be used to site an adjacent vertical well (MW-203
^ and PW-207) so that it intercepts a fracture observed in the angled boring
^ Vertical Borings Two of the vertical borings will be completed with rotary diamond coring to
approximately 100 ft bgs These borings will be adjacent to the angled borings described above One of
^ the cored borings (MW-203) will be located near MW-106 outside of the source area within the
dissolved-phase groundwater plume (see Figure 3-1) The other cored boring (PW-207) will be the
pumping well which is anticipated to be located within the source area in the vicinity of the existing
MW-2 well cluster Coring will allow data collection for several purposes including direct observation
of bedrock for determination of the nature of the rock matrix determination of the location and nature of
fractures and the degree of fracturing comparison with geophysical logs (Subtask 2) to verify
interpretation of the logs and collection of core samples for analysis (Subtask 4)
The remaining borings will be located east of the 2-acre fenced area within or near the periphery of the
source area and will be sited to align approximately with existing wells based on the known fracture
orientations at the Site (MW-204 and MW-205) or with new wells based on the known fracture
pound orientations at the Site (MW-206) Data from these locations in conjunction with the other borings
installed as part of this TI SOW and the existing wells will be used in the interpretation of the pumping
^ test (Subtask 6) and tracer test (Subtask 7) In addition these three borings will further delineate
contamination and provide potential monitoring locations for long-term monitoring Each of these
^ borings will be advanced to approximately 100 ft bgs with a minimum four-inch diameter air hammer
^ During the installation of each boring observations will be made regarding water gainloss drilling rate
and bit behavior to assess the depth of potential fractures In addition water levels will be measured in
nearby borings using either hand measurements data loggers or both to evaluate connectivity between
locations A change in water level in a nearby boring will indicate a hydraulic connection between the
TISOW WOODARD amp CURRAN 12 September 302003 20564309
borings Borehole geophysics and packer testing will also be performed on the borings (See Subtasks 2
and 3 below)
Drilling water will be containerized on site and treated through granular activated carbon (GAC) Treated
water will be analyzed to verify that PCB and VOC concentrations have been reduced to below ARARs
prior to discharge to the ground surface Cuttings will be spread on the ground surface at the site
consistent with the Remedial Investigation work plan
It is anticipated that up to 10 core samples from each cored boring (total of 20 cores) will be collected and
submitted to an off-site laboratory for analyses of porosity (matrix and bulk) permeability bulk density
and fraction of organic carbon (f^) using methods described in Subtask 4
Subtask 2 - Borehole Geophysics
To supplement information on fracture location and connectivity obtained during boring advancement a
borehole geophysical survey will be conducted on the newly installed bedrock borings to evaluate the
nature and orientation of water bearing fractures in the borings The survey will be performed at the
completion of the angled borings and again at the completion of the vertical borings The information
obtained during the survey may be used to identify the location of subsequent boring(s) by refining the
understanding of the depth aperture and orientation of bedrock fractures The following measurements
are proposed for the new borings caliper fluid temperature fluid resistivity and acoustic televiewer
(ATV) Single-point resistively and 16 inch normal measurements will also be made in the first two
borings installed and the data will be compared to data from the other geophysical logs to determine if
the measurements confirm and significantly improve the interpretation regarding the presence of water-
bearing fractures If the measurements are applicable to identification of fractures they may be included
in lieu of other geophysical logs in the remainder of the borings
Subtask 3 - Packer Testing
To further refine information on the aquifer hydraulic conductivity the hydraulic connection between
fractures in the borings will be evaluated during packer testing of vertical borings The data will be used
to estimate the hydraulic conductivity of specific fractures and fracture zones The packer testing will be
performed after the vertical borings have been installed and the borehole geophysical survey completed
TISOW WOODARD amp CURRAN 13 September 30 2003 20564309
bull
m
M
Drilling observations and information from borehole geophysics will be used to identify specific fractures
below the water table that are capable of transmitting water Prior to water injection for hydraulic
conductivity and fracture connectivity testing groundwater samples will be collected at selected intervals
for analysis of VOCs (See Subtask 4) Sampling intervals will be selected based on drilling observations
and logging results that indicate water is moving into or out of the borehole or that fractures exist to
promote water movement such as rapid increase in the amount of water returned rapid change in
temperature or highly fractured interval
^
^
bull
f$
Double packer testing will be performed at selected intervals within each newly installed boring It is
anticipated that up to six intervals per well will be tested for a maximum of 24 intervals and that for each
interval the test will include an approximate 15-minute injection of potable water at four progressively
increasing pressures Packer spacing is anticipated to be 10 ft however spacing may vary so that packers
are not located in potential fracture zones identified using information from rock cores drilling
observations and borehole geophysics The tests at an individual interval will be terminated if it appears
that the interval is not accepting water Care will be taken to minimize over-pumping or over-
pressurizing of the fractures The flow rate will be measured to evaluate the characteristics of the
fracture Water levels in adjacent borings will be measured during the packer testing to determine if a
hydraulic connection exists between the borings Water generated during packer testing will be
containerized on site and treated through GAC Treated water will be analyzed to verify that PCB and
VOC concentrations have been reduced to below ARARs prior to discharge to the ground surface
4 Subtask 4 Sampling and Analysis
~d
^
Rock and groundwater samples will be collected during the field program for laboratory analysis The
results of the analyses will be used to help refine the distribution of the plume and to estimate bedrock
properties These analyses will be used in conjunction with existing data during the TI evaluation to
refine cleanup times and establish the limits of the TI zone
As described in Subtask 1 it is anticipated that up to 10 core samples from each cored boring (total of 20
core samples) will be collected and submitted to an off-site laboratory for analyses of porosity (matrix and
bulk) permeability bulk density and fraction of organic carbon (f^) using existing industry methods
Subject to further evaluation of industry methods Woodard amp Curran proposes that porosity
TISOW WOODARD amp CURRAN20564309
14 September 302003
permeability and density will be measured using methods in the American Petroleum Institutes API RPshy
40 Fraction of organic carbon (f^) will be measured using either the LECO TOC method or Walkey-
Black method The LECO TOC method is a standard method in the petroleum industry and involves the
direct combustion of a ground rock sample The Walkey-Black method is a commonly used USEPA-
approved chemical oxidation method for determination of foe in soils In addition either method could be
used if a sample were scraped from a fracture surface To develop a reasonable range of f for Site
bedrock up to five samples will be selected from each boring from the unfractured matrix and up to five
from the fracture surfaces In addition Woodard amp Curran will evaluate the appropriateness of selecting
rock samples from a subset of the core samples from areas near fractures as well as from non-fractured
areas and submitting the samples for VOC analysis following methanol extraction
Results from these analyses will be used in conjunction with groundwater contaminant concentrations to
evaluate the significance of diffusion of contamination from the bedrock matrix in both the Source Area
and the Non-Source Area Although matrix diffusion likely is a significant factor in the determination of
cleanup times within the Source Area the potential applicability of matrix diffusion in the Non-Source
Area is not known These core analyses may provide evidence to assist in developing an estimate
through calculations of the effect of matrix diffusion on cleanup times
As noted in Subtask 3 prior to injection of water during packer testing groundwater samples will be
collected at selected intervals for analysis of volatile organic compounds (VOCs) Up to a total of 20
groundwater samples plus appropriate quality control samples will be collected from the newly installed
borings The samples will be submitted to an off-site laboratory for analysis Analytical results will be
validated in accordance with USEPA protocol and the data will be managed in WampCs existing
groundwater sampling analytical database for this site
Up to 21 existing monitoring wells from within or nearby the 17-acre property plus four new wells once
constructed will be sampled using low-flow techniques and submitted to an off-site laboratory for VOC
analysis Analytical results will be validated in accordance with USEPA protocol and the data will be
managed in WampCs existing groundwater sampling analytical database for this site
TISOW WOODARD amp CURRAN 15 September 302003 20564309
Subtask 5 - Monitoring Well Installation
Although it is anticipated that the newly installed borings will be left as open holes for tracer testing and
for pumping tests monitoring wells will be installed and developed in the newly installed borings unless
the USEPA MEDEP and PRP Group determine that the location is inappropriate for such use The
monitoring wells will be constructed of two-inch schedule 40 PVC screen and riser Screen intervals will
be selected based on the location of fractures identified during drilling geophysical logging and packer
testing A sand pack will be placed around the screen and will extend from approximately two ft below
the screen to approximately two ft above the screen
Subtask 6 - Pumping Test
WampC will conduct a single constant discharge pumping test to evaluate hydraulic properties of the
aquifer It is anticipated that the test will be conducted in a new pumping well in the vicinity of the
existing MW-2 well cluster within the source area Data from the pumping test will be used in
conjunction with other data from the investigation to improve the understanding of groundwater
movement and contaminant transport in the Source and Non-Source areas The results of the pumping
test will be used to refine the Site conceptual model as well as in the design of the hydraulic containment
system that is being constructed under the authority of the AOC for the RD
The groundwater pumping test will include the following components (1) Pumping test setup (2) Pretest
monitoring (3) Constant Discharge Pumping Test (4) Post-test monitoring and (5) Data Analysis
Pumping Test Setup In support of the groundwater pumping test WampC will install a pumping well
(PW-207) and procure and install the required groundwater extraction treatment and storage equipment at
the Site The well will be cored and over drilled to allow construction of a 4-inch well The location will
be in the vicinity of the MW-2 well cluster and be based upon results of the angled bedrock boring AWshy
202 The equipment will include but not be limited to
bull Down well pump plumbing and appurtances
bull Two (2) 20000 frac tanks
bull Groundwater transfer pumps and controls
bull Settlingaerationsand filtration treatment processes for the treatment of inorganics (if needed) and
nsow WOODARD amp CURRAN 16 September 302003 20564309
bull Granular activated carbon units for the treatment of dissolved organics in the groundwater
The groundwater treatment process will include the following processes 1) an oxidation and filtration
step to remove the inorganics from the groundwater and GAC units to treat the organic contaminants in
the extracted groundwater
Pretest Monitoring Prior to initiation of pumping WampC will monitor water levels in existing wells and
newly installed borings adjacent to the pumping well using a combination of hand measurements and data
loggers to develop an understanding of the piezometric surface under unstressed conditions The wells
proposed for water-level monitoring will be described in the work plan In addition all gauges
transducers flow meters and other equipment used in conducting the pumping tests shall be calibrated
before use
Constant Discharge Pumping Test The pumping test will be conducted in the source area using
newly-installed pumping well PW-207 It is anticipated that the test will be conducted at a pumping rate
of approximately 2 gallons per minute (gpm) for a period of 2 to 3 days however a higher or lower rate
may be shown to be appropriate based on the drilling and packer testing conducted during boring
installation Woodard amp Curran proposes to conduct this test using a vacuum-enhanced recovery system
(VERS) as described in the ROD so that the water level is not lowered appreciably in the vicinity of the
pumping well to prevent the potential migration of NAPLs to deeper bedrock zones The appropriateness
and feasibility of the VERS for the pumping test will be determined by field testing or literature
evaluation prior to completion of the Work Plan Because of the short duration of this test it is not
anticipated that stability of water levels will be reached in observation wells The test will however
provide information to estimate hydraulic conductivity and bedrock storage During the test the water
levels in the pumping well and selected monitoring wells will be logged continuously via down well data
loggers It is anticipated that water levels in approximately 24 wells will be measured using hand
measurements and data loggers
Groundwater extracted during the pumping test will be stored temporarily in an on-site frac tank prior to
on-site treatment and disposal
TISOW WOODARD amp CURRAN 17 September 302003 20564309
Post-Test Monitoring After the pump is turned off in the pumping well water levels will continue to be
monitored using hand measurements and data loggers until they have returned to within 10 of the preshy
test levels For planning purposes this has been estimated to be two weeks
Data Analysis Data collected during the pumping test will be analyzed with Aquifer Win32 Results of
the pumping test will be summarized in the summary data package for the TI Evaluation and the results
will also be used in the design of the hydraulic containment system specified in the Interim ROD that is
being conducted under the authority of the AOC for the RD Detail regarding use of the pumping test
data in hydraulic system design will be provided in the Remedial Design Work Plan
Subtask 7 - Tracer Test
WampC will conduct a tracer test using a conservative tracer to evaluate fracture connectivity porosity
dispersivity and matrix diffusion of the bedrock aquifer in both the Source Area and Non-Source Area
To increase the potential for success of this test results of the pumping test evaluation will be used to
revise the tracer test plan proposed here as necessary Following rebound of water levels after
completion of the pumping test WampC will initiate a single natural gradient tracer test The test will
consist of injecting a tracer into well PW-207 in the source area (Figure 3-1) for up to five days and
monitoring the tracers arrival in nearby wells Borehole geophysics core evaluation and packer testing
will be used to select the specific injection depth(s) in the well
A Tracer Test Work Plan will be completed prior to initiation of injection to determine the type quantity
and concentration of tracer based on the distance between the injection well and the monitoring wells A
conservative tracer that is one that is not preferentially adsorbed to rock or organic matter will be
selected for the tracer test Tracer injection equipment including tanks and flow-regulating and metering
equipment and pumps will be used to mix the tracer at the surface prior to injection Fractures may be
packered in the injection well and tracer solution will be injected at a rate determined during preparation
of the Tracer Test Work Plan During injection the potentiometric surface of the aquifer will be
monitored to verify that the potentiometric surface remains relatively constant during the injection
process
nsow WOODARD amp CURRAN 18 September 302003 20564309
Prior to injection of the tracer background concentration will be established by collecting samples from
up to six wells in the area of the tracer test and analyzing them for the tracer using an appropriate
analytical method Following injection of the tracer solutions the concentration of the tracer in
downgradient wells and borings will be measured A monitoring network will be established using nearby
monitoring wells Downhole probes will be installed in six new and existing wells near the injection well
to be identified in the work plan first to determine the background tracer concentrations and then to
monitor for the presence of the tracer upon initiation of the test Measurements will be collected at
periodic intervals to be determined based on the results of packer testing If an increase in tracer
concentration is detected or at a minimum on a weekly basis a water sample will be collected using low
flow sampling methodologies and analyzed in an off-site laboratory to evaluate the concentration of the
tracer The concentration of the tracer will be recorded Monitoring of the tracer concentration will
continue throughout the duration of the test The tracer will be allowed to flow with groundwater for one
month or until detected in wells in the vicinity of MW-106 whichever is shorter
313 Task 3 - TI Evaluation and Reporting
The TI Evaluation and reporting task includes the following five subtasks
bull Data evaluation
bull Summary data package
bull Draft TI Evaluation
bull Meetings with PRP Group and USEPA and
bull Revise and finalize TI Evaluation
As the subtasks of the field investigation are completed the data will be evaluated for the purpose of
addressing the data gaps identified by USEPA Specifically the data will be used to further refine the
cleanup times for non-source area groundwater presented in the Interim ROD
The data obtained during the field investigation will be reduced and evaluated and a summary data
package will be prepared that will include a discussion of the field activities completed and presentation
of the data It is anticipated that up to two meetings with USEPA will be necessary before the data
evaluation and summary report are completed
TISOW WOODARDampCURRAN 19 September 302003 20564309
Data collected during the pumping test will be analyzed with Aquifer Win32 Results will be summarized
in the summary data package and will also be presented as part of the RD submittals
Following submittal of the summary data package the TI evaluation will be prepared In accordance with
EPA guidance (1993) the TI waiver evaluation document will address the following topics
1 Specific ARARS or media cleanup standards for which TI determination is sought This section of the
TI Evaluation will identify the specific contaminants for which the TI determination is sought Based on
information available to date a waiver may be appropriate for pesticides PCBs chlorinated organic
compounds and other site-related contaminants that upon evaluation will not attain ARARs in a
reasonable period of time
2 Spatial area over which the TI waiver will apply The purpose of the additional site investigation
outlined in this SOW is to obtain the data necessary to further refine cleanup times presented in the
Interim ROD to determine what portions of the Site will not be expected to reach ARARs within a
reasonable time Consistent with TI guidance (USEPA 1993) the TI evaluation will specify the
horizontal and vertical extent of the area for which TI determination is sought Groundwater
concentration data from the RI and the TI SOW will be used to refine the distribution of the plume Data
from the drilling geophysical logging packer testing and pumping and tracer tests will be used to refine
the Site conceptual model and the cleanup times that will serve as the basis for establishing the scope and
nature of the TI zone
3 Conceptual Model The conceptual model forms the technical core of the TI Waiver Evaluation since
it provides basis for understanding of the restoration potential of the site The conceptual model outlines
the physical and hydrogeological constraints that hinder remediation or removal of Site contaminants and
it is the extent of these constraints rather than restoration timeframe alone that USEPA will use to
evaluate the necessity of the TI waiver of ARARs The conceptual model is the link between restoration
potential and restoration timeframe since it explains why proposed technologies are unlikely to work
either at all or within the desired 100-year timeframe
The Site conceptual model is not a mathematical model however as the result of the extensive modeling
and investigations of the site WampC has a strong understanding of the complex bedrock and overburden
TISOW WOODARDampCURRAN 20 September 302003 20564309
groundwater system beneath this site This understanding has been presented previously in both the RI
report and the FS and will be refined based on the TI SOW as necessary and summarized in the TI
Waiver Evaluation with specific attention to the physical and hydrogeological constraints on remediation
In particular the Site conceptual model will be reviewed in light of the new geologic data from drilling
logging and packer testing and the new hydrogeologic data obtained from the pumping test and tracer test
and will be revised to incorporate the new understanding
4 An evaluation of the restoration potential of the site This section will consist of a several components
It will present a systematic review of the technologies potentially capable of remediating the site given
the physical and hydrogeological constraints identified in the site model The newly acquired data will
provide an improved understanding of bedrock hydraulic properties that will allow a more Site-specific
evaluation of technologies The review of technologies will also include review of innovative
technologies and will evaluate whether existing remedial technologies or strategies would be capable of
achieving groundwater restoration at the site in a reasonable timeframe The section reference the FS and
will summarize the alternative remedies considered in the FS focusing on the ability of each to restore
groundwater in a reasonable timeframe It will also include a discussion of the selected hydraulic
containment system in light of the data gathered from the pumping test conducted in conjunction with the
TI SOW
Based on the Batch Flushing Model and using the agreed upon koc data from the RI as well as data from
this TI SOW including the f data collected as part of Subtask 4 a restoration timeframe analysis will be
conducted Following completion of the timeframe analysis and consideration of the results of drilling
rock and water analyses and pumping and tracer test a determination will be made regarding the Source
Area and the portion of the Non-Source Area VOC plume that will not attain ARARs in a reasonable
time
TISOW WOODARD amp CURRAN 21 September 302003 20564309
40 SCHEDULE
A proposed project schedule is included with this plan as Figure 4-1 This schedule is included for
discussion purposes and will be modified as necessary once the final scope of work as been approved by
all parties and the field work activities are coordinated with the subcontractors
TISOW WOODARD amp CURRAN 22 September 302003 20564309
ID
2
3
4
5
6
7 a i 10
11
12
13
14
15
16
17
16
19
20
21
22
24
25
26
27
26
29
30
31
32
Task Name
Project Meeting with EPA
Finalize SOW
Prepare Work Plans QAPP HASP Revision
Submit Work Plans for EPA Approval
Project Meeting with EPA
Revisions to work plans
Submit final work plans
Subcontractor Contracts
Project Meeting wEPA
Field Investigation
Site Mobilization
Install Borings
Borehole Geophysics
Packer Testing amp Collect GW Samples
Pumping Test
Tracer Test
Test setup
Injection
Monitoring
Data Reporting
InstallDevelop Wells
Data Evaluation
Prepare Data Package
Data Package Submittal to EPA
Draft Tl Evaluation Repon
Draft Tl Evaluation Report Submttal to EPA
EPA ReviewComment on Tl Evaluation ReF
Project Meeting wEPA
Revisions to Tl Evaluation Report
Submit Final Tl Evaluation Report
Start
Wed 070903
Thu 071003
Fri 101003
Mon 120103
Mon 121503
Mon 122903
Mon 011204
Tue 011304
Thu 021904
Fri 032104
Fri 032604
Fri 040204
Fri 041604
Fri 042304
Thu 050604
Wed 060204
Wed 060204
Wed 060904
Wed 060904
Wed 062304
Wed 070704
Wed 042804
Wed 062304
Mon 080204
Mon 070504
Tue 082404
Wed 082504
Wed 091504
Thu 0916AM
Thu 093004
Finish
Wed 070903
Fri 1OtO7u3
Fri 112803
Fri 122603
Mon 121503
Fri 010904
Mon 011204
Mon 012604
Thu 021904
Tue 071304
Thu 040104
Thu 042204
Tue 042704
Wed 050504
Tue 052504
Tue 071304
Tue 060804
Tue 061504
Tue 070604
Tue 071304
Fri 070904
Tue 072004
Fri 073004
Mon 080204
Mon 082304
Tue 082404
Tue 091404
Wed 091504
Wed 082904
Thu 093004
FIGURE 4-1 DRAFT HOWS CORNER SUPERFUND SITE
Tl EVALUATION amp RELD WORK FOR HYDRAUUC CONTAINMENT SYSTEM DESIGN PROPOSED PROJECT SCHEDULE
2003 2004 Mav |
Jun | Jul
ltamp i
Aug
i
Sen Oct I Nov Dec Jan Feb I Mar
ii i i
k ^tr 1
1V i
I t bull ^
I
ta^M bull bull M W
l LgtH^HBKLii LJ Mi
I
bull bull raquo bull laquo^ 0930
Task Progress I^MLHHHI^LB Summary ^^^^^^^^f External Tasks M B WMMM Deadline ^7 Project Hows Comer Schedule6A bull bull bull 1 UData Fri 101003 Split Milestone ^ Project Summary ^f^KKKKKK^^ External Milestone ^
Pagei
50 ACRONYMS
AOC Administrative Order by Consent
ARARs Applicable or Relevant and Appropriate Requirements
ATV acoustic televiewer
bgs below ground surface
CERCLA Comprehensive Environmental Resource and Conservation Liability Act
DNAPL Dense Non-Aqueous Phase Liquid
GAC granular activated carbon
gpm gallons per minute
HASP Health and Safety Plan
row investigation-derived waste
MCL Maximum Containment Level
MEDEP Maine Department of Environmental Protection
MEG Maine Enforcement Guideline
mgkg milligrams per kilogram
Hg kg micrograms per kilogram
NCP National Contingency Plan
PCB polychlorinated biphenyl
PID photo ionization detector
ppm parts per million
PRP Potentially Responsible Party
TISOW WOODARD amp CURRAN 24 September 302003 20564309
QAPP Quality Assurance Project Plan
QAQC Quality AssuranceQuality Control
RA Remedial Action
RAO Remedial Action Objective
RCRA Resource Conservation and Recovery Act
RD Remedial Design
RIFS Remedial InvestigationFeasibility Study
ROD Record of Decision
SAP Sampling and Analysis Plan
SOW Statement of Work
TAL target analyte list
TI Technical Impracticability
USEPA United State Environmental Protection Agency
VOCs volatile organic compounds
WampC Woodard amp Curran Inc
TISOW WOODARD amp CURRAN 25 September 302003 20564309
REFERENCES
Everts CJ RS Kanwar (1994) Evaluation of Rhodamine WT as an adsorbed tracer in an agricultural
soil J Hydrology 153 53-70
Kasnavia T D Vu DA Sabatini (1999) Fluorescent dye and media properties affecting sorption and
tracer selection Groundwater 37 376-381
Ptak T G Schmid (1996) Dual-tracer transport experiments in a physically and chemically
heterogeneous porous aquifer effective transport parameters and spatial variability J Hydrology
183 117-138
Sabatini DA T A Austin (1991) Characteristics of Rhodamine WT and fluorescein as adsorbing
ground-water tracers Ground Water 29 341-349
Trudgill ST (1987) Soil water dye tracing with special reference to the use of Rhodamanie WT
Lissamine FF and Amino G acid Hydrological Processes 1 149-170
US Environmental Protection Agency (USEPA) 1993 Guidance for Evaluating the Technical
Impracticability of Ground-Water Restoration - Interim Final Office of Solid Waste and
Emergency Response Washington DC Directive 92342-25 September 1993
US Environmental Protection Agency (USEPA) 2002 Interim Record of Decision Summary shy
Operable Unit One Non-Source Area Groundwater West SiteHows Corner Superfund Site
Plymouth Maine EPA Region 1 September 2002
US Environmental Protection Agency (USEPA) 2003 Proposed Scope of Work West SiteHows
Corner Superfund Site Plymouth Maine EPA Region 1 4 pages September 2002
Vasudevan D RL Fimmen AB Francisco (2001) Tracer-grade Rhodamine WT Structure of
constituent isomers and their sorption behavior Environ Sci Technol 35 4089-4096
nsow WOODARD amp CURRAN 26 September 30 2003 20564309
Woodard amp Curran Inc (WampC) 2002 Final Feasibility Study Report - Non-Source Area Groundwater
Hows Comer Superfund Site Plymouth Maine July 2002
TISOW WOODARD amp CURRAN 27 September 302003 20564309
f
m WOODARD amp CURRAN Maine Massachusetts New Hampshire Connecticut Florida Illinois Operational offices across the US 1-800-426-4262 wwwwoodardcurrancom
i
Table 3-1
Rationale for Proposed Well Locations
Hows Corner Technical Impracticability Evaluation and Field work for Hydraulic Containment System Design
Well Identification
AW-201
AW-202
MW-203
MW-204
MW-205
MW-206
PW-207
Boring Orientation
Angled
Angled
Vertical
Vertical
Vertical
Vertical
Vertical
Minimum Boring Diameter (inches)
4
4
4
4
4
4
6
Drilling Method
Air Hammer
Air Hammer
Coring
Air Hammer
Air Hammer
Air Hammer
Core Air Hammer Over -drilling
Source Area Non-Source Area
Non-Source Area
Source Area
Non-Source Area
Non-Source Area
Source Area
Source Area
Source Area
Rationale for Boring
bull Intercept near-vertical fractures to understand subsurface geology bull Aid in iting MW-203 bull Intercept near-vertical fractures to understand subsurface geology bull Aid in siting PW-201 (Pumping well) bull ion of contamination bull 1 future monitoring location bull Potential reinjection well for hydraulic containment system bull Core for matrix diffusion evaluation bullbullbullbull Ibullbullbullbull 1bullbullbullbull 1bullbull bull 1
tion point for pumping test tion point in tracer test ion of contamination
future monitoring location tion point for pumping test tion point in tracer test ion of contamination
future monitoring location tion point for pumping test tion point in tracer test ion of contamination
future monitoring location tion point for pumping test
test well extraction well
bull Core for matrix diffusion evaluation bull i point for tracer test
TISOW September 30 2003 WOODARD amp CURRAN 20564309
MW-105D MW-5B
Primary Bedding Secondary Cleavage
Tertsry Fracturing
NOTE A total of 60 observations warn made rtrtjs roprtraont tticopy number of obsafvatk noted wtthln each azimutha) segment
MW-1 1 3D euro MW-205
2 AcreSource
Fenced-^ Area i
MW-103D MW-103S
17-Acre Property Boundary
MW-104D MW-1041 bull
MW-104S
Legend Figure 3-1 J Proposed Monitoring Well Proposed Well Locations
o- Site Property Boundary bull^bullProposed Pumping Well Hows Corner Superfund Site -xmdashx- Source Area Plymouth Maine
^ ^Proposed Angled Well bullamp Existing Monitoring Well bullWDODARDampCURRAN
Englnoortng bull Science bull Operations 205643wipsite-8OlaquoAx-opt-1-2-u3-1D
bull During the installation of each angled boring observations will be made regarding water gainloss
drilling rate and bit behavior to assess the depth of potential fractures In addition water levels will be
9 measured in nearby borings using either hand measurements data loggers or both to evaluate
connectivity between locations A change in water level in a nearby boring will indicate a hydraulic
at connection between the borings Borehole geophysics will also be performed on the borings (See Subtask
2 below) Information from each angled boring will be used to site an adjacent vertical well (MW-203
^ and PW-207) so that it intercepts a fracture observed in the angled boring
^ Vertical Borings Two of the vertical borings will be completed with rotary diamond coring to
approximately 100 ft bgs These borings will be adjacent to the angled borings described above One of
^ the cored borings (MW-203) will be located near MW-106 outside of the source area within the
dissolved-phase groundwater plume (see Figure 3-1) The other cored boring (PW-207) will be the
pumping well which is anticipated to be located within the source area in the vicinity of the existing
MW-2 well cluster Coring will allow data collection for several purposes including direct observation
of bedrock for determination of the nature of the rock matrix determination of the location and nature of
fractures and the degree of fracturing comparison with geophysical logs (Subtask 2) to verify
interpretation of the logs and collection of core samples for analysis (Subtask 4)
The remaining borings will be located east of the 2-acre fenced area within or near the periphery of the
source area and will be sited to align approximately with existing wells based on the known fracture
orientations at the Site (MW-204 and MW-205) or with new wells based on the known fracture
pound orientations at the Site (MW-206) Data from these locations in conjunction with the other borings
installed as part of this TI SOW and the existing wells will be used in the interpretation of the pumping
^ test (Subtask 6) and tracer test (Subtask 7) In addition these three borings will further delineate
contamination and provide potential monitoring locations for long-term monitoring Each of these
^ borings will be advanced to approximately 100 ft bgs with a minimum four-inch diameter air hammer
^ During the installation of each boring observations will be made regarding water gainloss drilling rate
and bit behavior to assess the depth of potential fractures In addition water levels will be measured in
nearby borings using either hand measurements data loggers or both to evaluate connectivity between
locations A change in water level in a nearby boring will indicate a hydraulic connection between the
TISOW WOODARD amp CURRAN 12 September 302003 20564309
borings Borehole geophysics and packer testing will also be performed on the borings (See Subtasks 2
and 3 below)
Drilling water will be containerized on site and treated through granular activated carbon (GAC) Treated
water will be analyzed to verify that PCB and VOC concentrations have been reduced to below ARARs
prior to discharge to the ground surface Cuttings will be spread on the ground surface at the site
consistent with the Remedial Investigation work plan
It is anticipated that up to 10 core samples from each cored boring (total of 20 cores) will be collected and
submitted to an off-site laboratory for analyses of porosity (matrix and bulk) permeability bulk density
and fraction of organic carbon (f^) using methods described in Subtask 4
Subtask 2 - Borehole Geophysics
To supplement information on fracture location and connectivity obtained during boring advancement a
borehole geophysical survey will be conducted on the newly installed bedrock borings to evaluate the
nature and orientation of water bearing fractures in the borings The survey will be performed at the
completion of the angled borings and again at the completion of the vertical borings The information
obtained during the survey may be used to identify the location of subsequent boring(s) by refining the
understanding of the depth aperture and orientation of bedrock fractures The following measurements
are proposed for the new borings caliper fluid temperature fluid resistivity and acoustic televiewer
(ATV) Single-point resistively and 16 inch normal measurements will also be made in the first two
borings installed and the data will be compared to data from the other geophysical logs to determine if
the measurements confirm and significantly improve the interpretation regarding the presence of water-
bearing fractures If the measurements are applicable to identification of fractures they may be included
in lieu of other geophysical logs in the remainder of the borings
Subtask 3 - Packer Testing
To further refine information on the aquifer hydraulic conductivity the hydraulic connection between
fractures in the borings will be evaluated during packer testing of vertical borings The data will be used
to estimate the hydraulic conductivity of specific fractures and fracture zones The packer testing will be
performed after the vertical borings have been installed and the borehole geophysical survey completed
TISOW WOODARD amp CURRAN 13 September 30 2003 20564309
bull
m
M
Drilling observations and information from borehole geophysics will be used to identify specific fractures
below the water table that are capable of transmitting water Prior to water injection for hydraulic
conductivity and fracture connectivity testing groundwater samples will be collected at selected intervals
for analysis of VOCs (See Subtask 4) Sampling intervals will be selected based on drilling observations
and logging results that indicate water is moving into or out of the borehole or that fractures exist to
promote water movement such as rapid increase in the amount of water returned rapid change in
temperature or highly fractured interval
^
^
bull
f$
Double packer testing will be performed at selected intervals within each newly installed boring It is
anticipated that up to six intervals per well will be tested for a maximum of 24 intervals and that for each
interval the test will include an approximate 15-minute injection of potable water at four progressively
increasing pressures Packer spacing is anticipated to be 10 ft however spacing may vary so that packers
are not located in potential fracture zones identified using information from rock cores drilling
observations and borehole geophysics The tests at an individual interval will be terminated if it appears
that the interval is not accepting water Care will be taken to minimize over-pumping or over-
pressurizing of the fractures The flow rate will be measured to evaluate the characteristics of the
fracture Water levels in adjacent borings will be measured during the packer testing to determine if a
hydraulic connection exists between the borings Water generated during packer testing will be
containerized on site and treated through GAC Treated water will be analyzed to verify that PCB and
VOC concentrations have been reduced to below ARARs prior to discharge to the ground surface
4 Subtask 4 Sampling and Analysis
~d
^
Rock and groundwater samples will be collected during the field program for laboratory analysis The
results of the analyses will be used to help refine the distribution of the plume and to estimate bedrock
properties These analyses will be used in conjunction with existing data during the TI evaluation to
refine cleanup times and establish the limits of the TI zone
As described in Subtask 1 it is anticipated that up to 10 core samples from each cored boring (total of 20
core samples) will be collected and submitted to an off-site laboratory for analyses of porosity (matrix and
bulk) permeability bulk density and fraction of organic carbon (f^) using existing industry methods
Subject to further evaluation of industry methods Woodard amp Curran proposes that porosity
TISOW WOODARD amp CURRAN20564309
14 September 302003
permeability and density will be measured using methods in the American Petroleum Institutes API RPshy
40 Fraction of organic carbon (f^) will be measured using either the LECO TOC method or Walkey-
Black method The LECO TOC method is a standard method in the petroleum industry and involves the
direct combustion of a ground rock sample The Walkey-Black method is a commonly used USEPA-
approved chemical oxidation method for determination of foe in soils In addition either method could be
used if a sample were scraped from a fracture surface To develop a reasonable range of f for Site
bedrock up to five samples will be selected from each boring from the unfractured matrix and up to five
from the fracture surfaces In addition Woodard amp Curran will evaluate the appropriateness of selecting
rock samples from a subset of the core samples from areas near fractures as well as from non-fractured
areas and submitting the samples for VOC analysis following methanol extraction
Results from these analyses will be used in conjunction with groundwater contaminant concentrations to
evaluate the significance of diffusion of contamination from the bedrock matrix in both the Source Area
and the Non-Source Area Although matrix diffusion likely is a significant factor in the determination of
cleanup times within the Source Area the potential applicability of matrix diffusion in the Non-Source
Area is not known These core analyses may provide evidence to assist in developing an estimate
through calculations of the effect of matrix diffusion on cleanup times
As noted in Subtask 3 prior to injection of water during packer testing groundwater samples will be
collected at selected intervals for analysis of volatile organic compounds (VOCs) Up to a total of 20
groundwater samples plus appropriate quality control samples will be collected from the newly installed
borings The samples will be submitted to an off-site laboratory for analysis Analytical results will be
validated in accordance with USEPA protocol and the data will be managed in WampCs existing
groundwater sampling analytical database for this site
Up to 21 existing monitoring wells from within or nearby the 17-acre property plus four new wells once
constructed will be sampled using low-flow techniques and submitted to an off-site laboratory for VOC
analysis Analytical results will be validated in accordance with USEPA protocol and the data will be
managed in WampCs existing groundwater sampling analytical database for this site
TISOW WOODARD amp CURRAN 15 September 302003 20564309
Subtask 5 - Monitoring Well Installation
Although it is anticipated that the newly installed borings will be left as open holes for tracer testing and
for pumping tests monitoring wells will be installed and developed in the newly installed borings unless
the USEPA MEDEP and PRP Group determine that the location is inappropriate for such use The
monitoring wells will be constructed of two-inch schedule 40 PVC screen and riser Screen intervals will
be selected based on the location of fractures identified during drilling geophysical logging and packer
testing A sand pack will be placed around the screen and will extend from approximately two ft below
the screen to approximately two ft above the screen
Subtask 6 - Pumping Test
WampC will conduct a single constant discharge pumping test to evaluate hydraulic properties of the
aquifer It is anticipated that the test will be conducted in a new pumping well in the vicinity of the
existing MW-2 well cluster within the source area Data from the pumping test will be used in
conjunction with other data from the investigation to improve the understanding of groundwater
movement and contaminant transport in the Source and Non-Source areas The results of the pumping
test will be used to refine the Site conceptual model as well as in the design of the hydraulic containment
system that is being constructed under the authority of the AOC for the RD
The groundwater pumping test will include the following components (1) Pumping test setup (2) Pretest
monitoring (3) Constant Discharge Pumping Test (4) Post-test monitoring and (5) Data Analysis
Pumping Test Setup In support of the groundwater pumping test WampC will install a pumping well
(PW-207) and procure and install the required groundwater extraction treatment and storage equipment at
the Site The well will be cored and over drilled to allow construction of a 4-inch well The location will
be in the vicinity of the MW-2 well cluster and be based upon results of the angled bedrock boring AWshy
202 The equipment will include but not be limited to
bull Down well pump plumbing and appurtances
bull Two (2) 20000 frac tanks
bull Groundwater transfer pumps and controls
bull Settlingaerationsand filtration treatment processes for the treatment of inorganics (if needed) and
nsow WOODARD amp CURRAN 16 September 302003 20564309
bull Granular activated carbon units for the treatment of dissolved organics in the groundwater
The groundwater treatment process will include the following processes 1) an oxidation and filtration
step to remove the inorganics from the groundwater and GAC units to treat the organic contaminants in
the extracted groundwater
Pretest Monitoring Prior to initiation of pumping WampC will monitor water levels in existing wells and
newly installed borings adjacent to the pumping well using a combination of hand measurements and data
loggers to develop an understanding of the piezometric surface under unstressed conditions The wells
proposed for water-level monitoring will be described in the work plan In addition all gauges
transducers flow meters and other equipment used in conducting the pumping tests shall be calibrated
before use
Constant Discharge Pumping Test The pumping test will be conducted in the source area using
newly-installed pumping well PW-207 It is anticipated that the test will be conducted at a pumping rate
of approximately 2 gallons per minute (gpm) for a period of 2 to 3 days however a higher or lower rate
may be shown to be appropriate based on the drilling and packer testing conducted during boring
installation Woodard amp Curran proposes to conduct this test using a vacuum-enhanced recovery system
(VERS) as described in the ROD so that the water level is not lowered appreciably in the vicinity of the
pumping well to prevent the potential migration of NAPLs to deeper bedrock zones The appropriateness
and feasibility of the VERS for the pumping test will be determined by field testing or literature
evaluation prior to completion of the Work Plan Because of the short duration of this test it is not
anticipated that stability of water levels will be reached in observation wells The test will however
provide information to estimate hydraulic conductivity and bedrock storage During the test the water
levels in the pumping well and selected monitoring wells will be logged continuously via down well data
loggers It is anticipated that water levels in approximately 24 wells will be measured using hand
measurements and data loggers
Groundwater extracted during the pumping test will be stored temporarily in an on-site frac tank prior to
on-site treatment and disposal
TISOW WOODARD amp CURRAN 17 September 302003 20564309
Post-Test Monitoring After the pump is turned off in the pumping well water levels will continue to be
monitored using hand measurements and data loggers until they have returned to within 10 of the preshy
test levels For planning purposes this has been estimated to be two weeks
Data Analysis Data collected during the pumping test will be analyzed with Aquifer Win32 Results of
the pumping test will be summarized in the summary data package for the TI Evaluation and the results
will also be used in the design of the hydraulic containment system specified in the Interim ROD that is
being conducted under the authority of the AOC for the RD Detail regarding use of the pumping test
data in hydraulic system design will be provided in the Remedial Design Work Plan
Subtask 7 - Tracer Test
WampC will conduct a tracer test using a conservative tracer to evaluate fracture connectivity porosity
dispersivity and matrix diffusion of the bedrock aquifer in both the Source Area and Non-Source Area
To increase the potential for success of this test results of the pumping test evaluation will be used to
revise the tracer test plan proposed here as necessary Following rebound of water levels after
completion of the pumping test WampC will initiate a single natural gradient tracer test The test will
consist of injecting a tracer into well PW-207 in the source area (Figure 3-1) for up to five days and
monitoring the tracers arrival in nearby wells Borehole geophysics core evaluation and packer testing
will be used to select the specific injection depth(s) in the well
A Tracer Test Work Plan will be completed prior to initiation of injection to determine the type quantity
and concentration of tracer based on the distance between the injection well and the monitoring wells A
conservative tracer that is one that is not preferentially adsorbed to rock or organic matter will be
selected for the tracer test Tracer injection equipment including tanks and flow-regulating and metering
equipment and pumps will be used to mix the tracer at the surface prior to injection Fractures may be
packered in the injection well and tracer solution will be injected at a rate determined during preparation
of the Tracer Test Work Plan During injection the potentiometric surface of the aquifer will be
monitored to verify that the potentiometric surface remains relatively constant during the injection
process
nsow WOODARD amp CURRAN 18 September 302003 20564309
Prior to injection of the tracer background concentration will be established by collecting samples from
up to six wells in the area of the tracer test and analyzing them for the tracer using an appropriate
analytical method Following injection of the tracer solutions the concentration of the tracer in
downgradient wells and borings will be measured A monitoring network will be established using nearby
monitoring wells Downhole probes will be installed in six new and existing wells near the injection well
to be identified in the work plan first to determine the background tracer concentrations and then to
monitor for the presence of the tracer upon initiation of the test Measurements will be collected at
periodic intervals to be determined based on the results of packer testing If an increase in tracer
concentration is detected or at a minimum on a weekly basis a water sample will be collected using low
flow sampling methodologies and analyzed in an off-site laboratory to evaluate the concentration of the
tracer The concentration of the tracer will be recorded Monitoring of the tracer concentration will
continue throughout the duration of the test The tracer will be allowed to flow with groundwater for one
month or until detected in wells in the vicinity of MW-106 whichever is shorter
313 Task 3 - TI Evaluation and Reporting
The TI Evaluation and reporting task includes the following five subtasks
bull Data evaluation
bull Summary data package
bull Draft TI Evaluation
bull Meetings with PRP Group and USEPA and
bull Revise and finalize TI Evaluation
As the subtasks of the field investigation are completed the data will be evaluated for the purpose of
addressing the data gaps identified by USEPA Specifically the data will be used to further refine the
cleanup times for non-source area groundwater presented in the Interim ROD
The data obtained during the field investigation will be reduced and evaluated and a summary data
package will be prepared that will include a discussion of the field activities completed and presentation
of the data It is anticipated that up to two meetings with USEPA will be necessary before the data
evaluation and summary report are completed
TISOW WOODARDampCURRAN 19 September 302003 20564309
Data collected during the pumping test will be analyzed with Aquifer Win32 Results will be summarized
in the summary data package and will also be presented as part of the RD submittals
Following submittal of the summary data package the TI evaluation will be prepared In accordance with
EPA guidance (1993) the TI waiver evaluation document will address the following topics
1 Specific ARARS or media cleanup standards for which TI determination is sought This section of the
TI Evaluation will identify the specific contaminants for which the TI determination is sought Based on
information available to date a waiver may be appropriate for pesticides PCBs chlorinated organic
compounds and other site-related contaminants that upon evaluation will not attain ARARs in a
reasonable period of time
2 Spatial area over which the TI waiver will apply The purpose of the additional site investigation
outlined in this SOW is to obtain the data necessary to further refine cleanup times presented in the
Interim ROD to determine what portions of the Site will not be expected to reach ARARs within a
reasonable time Consistent with TI guidance (USEPA 1993) the TI evaluation will specify the
horizontal and vertical extent of the area for which TI determination is sought Groundwater
concentration data from the RI and the TI SOW will be used to refine the distribution of the plume Data
from the drilling geophysical logging packer testing and pumping and tracer tests will be used to refine
the Site conceptual model and the cleanup times that will serve as the basis for establishing the scope and
nature of the TI zone
3 Conceptual Model The conceptual model forms the technical core of the TI Waiver Evaluation since
it provides basis for understanding of the restoration potential of the site The conceptual model outlines
the physical and hydrogeological constraints that hinder remediation or removal of Site contaminants and
it is the extent of these constraints rather than restoration timeframe alone that USEPA will use to
evaluate the necessity of the TI waiver of ARARs The conceptual model is the link between restoration
potential and restoration timeframe since it explains why proposed technologies are unlikely to work
either at all or within the desired 100-year timeframe
The Site conceptual model is not a mathematical model however as the result of the extensive modeling
and investigations of the site WampC has a strong understanding of the complex bedrock and overburden
TISOW WOODARDampCURRAN 20 September 302003 20564309
groundwater system beneath this site This understanding has been presented previously in both the RI
report and the FS and will be refined based on the TI SOW as necessary and summarized in the TI
Waiver Evaluation with specific attention to the physical and hydrogeological constraints on remediation
In particular the Site conceptual model will be reviewed in light of the new geologic data from drilling
logging and packer testing and the new hydrogeologic data obtained from the pumping test and tracer test
and will be revised to incorporate the new understanding
4 An evaluation of the restoration potential of the site This section will consist of a several components
It will present a systematic review of the technologies potentially capable of remediating the site given
the physical and hydrogeological constraints identified in the site model The newly acquired data will
provide an improved understanding of bedrock hydraulic properties that will allow a more Site-specific
evaluation of technologies The review of technologies will also include review of innovative
technologies and will evaluate whether existing remedial technologies or strategies would be capable of
achieving groundwater restoration at the site in a reasonable timeframe The section reference the FS and
will summarize the alternative remedies considered in the FS focusing on the ability of each to restore
groundwater in a reasonable timeframe It will also include a discussion of the selected hydraulic
containment system in light of the data gathered from the pumping test conducted in conjunction with the
TI SOW
Based on the Batch Flushing Model and using the agreed upon koc data from the RI as well as data from
this TI SOW including the f data collected as part of Subtask 4 a restoration timeframe analysis will be
conducted Following completion of the timeframe analysis and consideration of the results of drilling
rock and water analyses and pumping and tracer test a determination will be made regarding the Source
Area and the portion of the Non-Source Area VOC plume that will not attain ARARs in a reasonable
time
TISOW WOODARD amp CURRAN 21 September 302003 20564309
40 SCHEDULE
A proposed project schedule is included with this plan as Figure 4-1 This schedule is included for
discussion purposes and will be modified as necessary once the final scope of work as been approved by
all parties and the field work activities are coordinated with the subcontractors
TISOW WOODARD amp CURRAN 22 September 302003 20564309
ID
2
3
4
5
6
7 a i 10
11
12
13
14
15
16
17
16
19
20
21
22
24
25
26
27
26
29
30
31
32
Task Name
Project Meeting with EPA
Finalize SOW
Prepare Work Plans QAPP HASP Revision
Submit Work Plans for EPA Approval
Project Meeting with EPA
Revisions to work plans
Submit final work plans
Subcontractor Contracts
Project Meeting wEPA
Field Investigation
Site Mobilization
Install Borings
Borehole Geophysics
Packer Testing amp Collect GW Samples
Pumping Test
Tracer Test
Test setup
Injection
Monitoring
Data Reporting
InstallDevelop Wells
Data Evaluation
Prepare Data Package
Data Package Submittal to EPA
Draft Tl Evaluation Repon
Draft Tl Evaluation Report Submttal to EPA
EPA ReviewComment on Tl Evaluation ReF
Project Meeting wEPA
Revisions to Tl Evaluation Report
Submit Final Tl Evaluation Report
Start
Wed 070903
Thu 071003
Fri 101003
Mon 120103
Mon 121503
Mon 122903
Mon 011204
Tue 011304
Thu 021904
Fri 032104
Fri 032604
Fri 040204
Fri 041604
Fri 042304
Thu 050604
Wed 060204
Wed 060204
Wed 060904
Wed 060904
Wed 062304
Wed 070704
Wed 042804
Wed 062304
Mon 080204
Mon 070504
Tue 082404
Wed 082504
Wed 091504
Thu 0916AM
Thu 093004
Finish
Wed 070903
Fri 1OtO7u3
Fri 112803
Fri 122603
Mon 121503
Fri 010904
Mon 011204
Mon 012604
Thu 021904
Tue 071304
Thu 040104
Thu 042204
Tue 042704
Wed 050504
Tue 052504
Tue 071304
Tue 060804
Tue 061504
Tue 070604
Tue 071304
Fri 070904
Tue 072004
Fri 073004
Mon 080204
Mon 082304
Tue 082404
Tue 091404
Wed 091504
Wed 082904
Thu 093004
FIGURE 4-1 DRAFT HOWS CORNER SUPERFUND SITE
Tl EVALUATION amp RELD WORK FOR HYDRAUUC CONTAINMENT SYSTEM DESIGN PROPOSED PROJECT SCHEDULE
2003 2004 Mav |
Jun | Jul
ltamp i
Aug
i
Sen Oct I Nov Dec Jan Feb I Mar
ii i i
k ^tr 1
1V i
I t bull ^
I
ta^M bull bull M W
l LgtH^HBKLii LJ Mi
I
bull bull raquo bull laquo^ 0930
Task Progress I^MLHHHI^LB Summary ^^^^^^^^f External Tasks M B WMMM Deadline ^7 Project Hows Comer Schedule6A bull bull bull 1 UData Fri 101003 Split Milestone ^ Project Summary ^f^KKKKKK^^ External Milestone ^
Pagei
50 ACRONYMS
AOC Administrative Order by Consent
ARARs Applicable or Relevant and Appropriate Requirements
ATV acoustic televiewer
bgs below ground surface
CERCLA Comprehensive Environmental Resource and Conservation Liability Act
DNAPL Dense Non-Aqueous Phase Liquid
GAC granular activated carbon
gpm gallons per minute
HASP Health and Safety Plan
row investigation-derived waste
MCL Maximum Containment Level
MEDEP Maine Department of Environmental Protection
MEG Maine Enforcement Guideline
mgkg milligrams per kilogram
Hg kg micrograms per kilogram
NCP National Contingency Plan
PCB polychlorinated biphenyl
PID photo ionization detector
ppm parts per million
PRP Potentially Responsible Party
TISOW WOODARD amp CURRAN 24 September 302003 20564309
QAPP Quality Assurance Project Plan
QAQC Quality AssuranceQuality Control
RA Remedial Action
RAO Remedial Action Objective
RCRA Resource Conservation and Recovery Act
RD Remedial Design
RIFS Remedial InvestigationFeasibility Study
ROD Record of Decision
SAP Sampling and Analysis Plan
SOW Statement of Work
TAL target analyte list
TI Technical Impracticability
USEPA United State Environmental Protection Agency
VOCs volatile organic compounds
WampC Woodard amp Curran Inc
TISOW WOODARD amp CURRAN 25 September 302003 20564309
REFERENCES
Everts CJ RS Kanwar (1994) Evaluation of Rhodamine WT as an adsorbed tracer in an agricultural
soil J Hydrology 153 53-70
Kasnavia T D Vu DA Sabatini (1999) Fluorescent dye and media properties affecting sorption and
tracer selection Groundwater 37 376-381
Ptak T G Schmid (1996) Dual-tracer transport experiments in a physically and chemically
heterogeneous porous aquifer effective transport parameters and spatial variability J Hydrology
183 117-138
Sabatini DA T A Austin (1991) Characteristics of Rhodamine WT and fluorescein as adsorbing
ground-water tracers Ground Water 29 341-349
Trudgill ST (1987) Soil water dye tracing with special reference to the use of Rhodamanie WT
Lissamine FF and Amino G acid Hydrological Processes 1 149-170
US Environmental Protection Agency (USEPA) 1993 Guidance for Evaluating the Technical
Impracticability of Ground-Water Restoration - Interim Final Office of Solid Waste and
Emergency Response Washington DC Directive 92342-25 September 1993
US Environmental Protection Agency (USEPA) 2002 Interim Record of Decision Summary shy
Operable Unit One Non-Source Area Groundwater West SiteHows Corner Superfund Site
Plymouth Maine EPA Region 1 September 2002
US Environmental Protection Agency (USEPA) 2003 Proposed Scope of Work West SiteHows
Corner Superfund Site Plymouth Maine EPA Region 1 4 pages September 2002
Vasudevan D RL Fimmen AB Francisco (2001) Tracer-grade Rhodamine WT Structure of
constituent isomers and their sorption behavior Environ Sci Technol 35 4089-4096
nsow WOODARD amp CURRAN 26 September 30 2003 20564309
Woodard amp Curran Inc (WampC) 2002 Final Feasibility Study Report - Non-Source Area Groundwater
Hows Comer Superfund Site Plymouth Maine July 2002
TISOW WOODARD amp CURRAN 27 September 302003 20564309
f
m WOODARD amp CURRAN Maine Massachusetts New Hampshire Connecticut Florida Illinois Operational offices across the US 1-800-426-4262 wwwwoodardcurrancom
i
MW-105D MW-5B
Primary Bedding Secondary Cleavage
Tertsry Fracturing
NOTE A total of 60 observations warn made rtrtjs roprtraont tticopy number of obsafvatk noted wtthln each azimutha) segment
MW-1 1 3D euro MW-205
2 AcreSource
Fenced-^ Area i
MW-103D MW-103S
17-Acre Property Boundary
MW-104D MW-1041 bull
MW-104S
Legend Figure 3-1 J Proposed Monitoring Well Proposed Well Locations
o- Site Property Boundary bull^bullProposed Pumping Well Hows Corner Superfund Site -xmdashx- Source Area Plymouth Maine
^ ^Proposed Angled Well bullamp Existing Monitoring Well bullWDODARDampCURRAN
Englnoortng bull Science bull Operations 205643wipsite-8OlaquoAx-opt-1-2-u3-1D
bull During the installation of each angled boring observations will be made regarding water gainloss
drilling rate and bit behavior to assess the depth of potential fractures In addition water levels will be
9 measured in nearby borings using either hand measurements data loggers or both to evaluate
connectivity between locations A change in water level in a nearby boring will indicate a hydraulic
at connection between the borings Borehole geophysics will also be performed on the borings (See Subtask
2 below) Information from each angled boring will be used to site an adjacent vertical well (MW-203
^ and PW-207) so that it intercepts a fracture observed in the angled boring
^ Vertical Borings Two of the vertical borings will be completed with rotary diamond coring to
approximately 100 ft bgs These borings will be adjacent to the angled borings described above One of
^ the cored borings (MW-203) will be located near MW-106 outside of the source area within the
dissolved-phase groundwater plume (see Figure 3-1) The other cored boring (PW-207) will be the
pumping well which is anticipated to be located within the source area in the vicinity of the existing
MW-2 well cluster Coring will allow data collection for several purposes including direct observation
of bedrock for determination of the nature of the rock matrix determination of the location and nature of
fractures and the degree of fracturing comparison with geophysical logs (Subtask 2) to verify
interpretation of the logs and collection of core samples for analysis (Subtask 4)
The remaining borings will be located east of the 2-acre fenced area within or near the periphery of the
source area and will be sited to align approximately with existing wells based on the known fracture
orientations at the Site (MW-204 and MW-205) or with new wells based on the known fracture
pound orientations at the Site (MW-206) Data from these locations in conjunction with the other borings
installed as part of this TI SOW and the existing wells will be used in the interpretation of the pumping
^ test (Subtask 6) and tracer test (Subtask 7) In addition these three borings will further delineate
contamination and provide potential monitoring locations for long-term monitoring Each of these
^ borings will be advanced to approximately 100 ft bgs with a minimum four-inch diameter air hammer
^ During the installation of each boring observations will be made regarding water gainloss drilling rate
and bit behavior to assess the depth of potential fractures In addition water levels will be measured in
nearby borings using either hand measurements data loggers or both to evaluate connectivity between
locations A change in water level in a nearby boring will indicate a hydraulic connection between the
TISOW WOODARD amp CURRAN 12 September 302003 20564309
borings Borehole geophysics and packer testing will also be performed on the borings (See Subtasks 2
and 3 below)
Drilling water will be containerized on site and treated through granular activated carbon (GAC) Treated
water will be analyzed to verify that PCB and VOC concentrations have been reduced to below ARARs
prior to discharge to the ground surface Cuttings will be spread on the ground surface at the site
consistent with the Remedial Investigation work plan
It is anticipated that up to 10 core samples from each cored boring (total of 20 cores) will be collected and
submitted to an off-site laboratory for analyses of porosity (matrix and bulk) permeability bulk density
and fraction of organic carbon (f^) using methods described in Subtask 4
Subtask 2 - Borehole Geophysics
To supplement information on fracture location and connectivity obtained during boring advancement a
borehole geophysical survey will be conducted on the newly installed bedrock borings to evaluate the
nature and orientation of water bearing fractures in the borings The survey will be performed at the
completion of the angled borings and again at the completion of the vertical borings The information
obtained during the survey may be used to identify the location of subsequent boring(s) by refining the
understanding of the depth aperture and orientation of bedrock fractures The following measurements
are proposed for the new borings caliper fluid temperature fluid resistivity and acoustic televiewer
(ATV) Single-point resistively and 16 inch normal measurements will also be made in the first two
borings installed and the data will be compared to data from the other geophysical logs to determine if
the measurements confirm and significantly improve the interpretation regarding the presence of water-
bearing fractures If the measurements are applicable to identification of fractures they may be included
in lieu of other geophysical logs in the remainder of the borings
Subtask 3 - Packer Testing
To further refine information on the aquifer hydraulic conductivity the hydraulic connection between
fractures in the borings will be evaluated during packer testing of vertical borings The data will be used
to estimate the hydraulic conductivity of specific fractures and fracture zones The packer testing will be
performed after the vertical borings have been installed and the borehole geophysical survey completed
TISOW WOODARD amp CURRAN 13 September 30 2003 20564309
bull
m
M
Drilling observations and information from borehole geophysics will be used to identify specific fractures
below the water table that are capable of transmitting water Prior to water injection for hydraulic
conductivity and fracture connectivity testing groundwater samples will be collected at selected intervals
for analysis of VOCs (See Subtask 4) Sampling intervals will be selected based on drilling observations
and logging results that indicate water is moving into or out of the borehole or that fractures exist to
promote water movement such as rapid increase in the amount of water returned rapid change in
temperature or highly fractured interval
^
^
bull
f$
Double packer testing will be performed at selected intervals within each newly installed boring It is
anticipated that up to six intervals per well will be tested for a maximum of 24 intervals and that for each
interval the test will include an approximate 15-minute injection of potable water at four progressively
increasing pressures Packer spacing is anticipated to be 10 ft however spacing may vary so that packers
are not located in potential fracture zones identified using information from rock cores drilling
observations and borehole geophysics The tests at an individual interval will be terminated if it appears
that the interval is not accepting water Care will be taken to minimize over-pumping or over-
pressurizing of the fractures The flow rate will be measured to evaluate the characteristics of the
fracture Water levels in adjacent borings will be measured during the packer testing to determine if a
hydraulic connection exists between the borings Water generated during packer testing will be
containerized on site and treated through GAC Treated water will be analyzed to verify that PCB and
VOC concentrations have been reduced to below ARARs prior to discharge to the ground surface
4 Subtask 4 Sampling and Analysis
~d
^
Rock and groundwater samples will be collected during the field program for laboratory analysis The
results of the analyses will be used to help refine the distribution of the plume and to estimate bedrock
properties These analyses will be used in conjunction with existing data during the TI evaluation to
refine cleanup times and establish the limits of the TI zone
As described in Subtask 1 it is anticipated that up to 10 core samples from each cored boring (total of 20
core samples) will be collected and submitted to an off-site laboratory for analyses of porosity (matrix and
bulk) permeability bulk density and fraction of organic carbon (f^) using existing industry methods
Subject to further evaluation of industry methods Woodard amp Curran proposes that porosity
TISOW WOODARD amp CURRAN20564309
14 September 302003
permeability and density will be measured using methods in the American Petroleum Institutes API RPshy
40 Fraction of organic carbon (f^) will be measured using either the LECO TOC method or Walkey-
Black method The LECO TOC method is a standard method in the petroleum industry and involves the
direct combustion of a ground rock sample The Walkey-Black method is a commonly used USEPA-
approved chemical oxidation method for determination of foe in soils In addition either method could be
used if a sample were scraped from a fracture surface To develop a reasonable range of f for Site
bedrock up to five samples will be selected from each boring from the unfractured matrix and up to five
from the fracture surfaces In addition Woodard amp Curran will evaluate the appropriateness of selecting
rock samples from a subset of the core samples from areas near fractures as well as from non-fractured
areas and submitting the samples for VOC analysis following methanol extraction
Results from these analyses will be used in conjunction with groundwater contaminant concentrations to
evaluate the significance of diffusion of contamination from the bedrock matrix in both the Source Area
and the Non-Source Area Although matrix diffusion likely is a significant factor in the determination of
cleanup times within the Source Area the potential applicability of matrix diffusion in the Non-Source
Area is not known These core analyses may provide evidence to assist in developing an estimate
through calculations of the effect of matrix diffusion on cleanup times
As noted in Subtask 3 prior to injection of water during packer testing groundwater samples will be
collected at selected intervals for analysis of volatile organic compounds (VOCs) Up to a total of 20
groundwater samples plus appropriate quality control samples will be collected from the newly installed
borings The samples will be submitted to an off-site laboratory for analysis Analytical results will be
validated in accordance with USEPA protocol and the data will be managed in WampCs existing
groundwater sampling analytical database for this site
Up to 21 existing monitoring wells from within or nearby the 17-acre property plus four new wells once
constructed will be sampled using low-flow techniques and submitted to an off-site laboratory for VOC
analysis Analytical results will be validated in accordance with USEPA protocol and the data will be
managed in WampCs existing groundwater sampling analytical database for this site
TISOW WOODARD amp CURRAN 15 September 302003 20564309
Subtask 5 - Monitoring Well Installation
Although it is anticipated that the newly installed borings will be left as open holes for tracer testing and
for pumping tests monitoring wells will be installed and developed in the newly installed borings unless
the USEPA MEDEP and PRP Group determine that the location is inappropriate for such use The
monitoring wells will be constructed of two-inch schedule 40 PVC screen and riser Screen intervals will
be selected based on the location of fractures identified during drilling geophysical logging and packer
testing A sand pack will be placed around the screen and will extend from approximately two ft below
the screen to approximately two ft above the screen
Subtask 6 - Pumping Test
WampC will conduct a single constant discharge pumping test to evaluate hydraulic properties of the
aquifer It is anticipated that the test will be conducted in a new pumping well in the vicinity of the
existing MW-2 well cluster within the source area Data from the pumping test will be used in
conjunction with other data from the investigation to improve the understanding of groundwater
movement and contaminant transport in the Source and Non-Source areas The results of the pumping
test will be used to refine the Site conceptual model as well as in the design of the hydraulic containment
system that is being constructed under the authority of the AOC for the RD
The groundwater pumping test will include the following components (1) Pumping test setup (2) Pretest
monitoring (3) Constant Discharge Pumping Test (4) Post-test monitoring and (5) Data Analysis
Pumping Test Setup In support of the groundwater pumping test WampC will install a pumping well
(PW-207) and procure and install the required groundwater extraction treatment and storage equipment at
the Site The well will be cored and over drilled to allow construction of a 4-inch well The location will
be in the vicinity of the MW-2 well cluster and be based upon results of the angled bedrock boring AWshy
202 The equipment will include but not be limited to
bull Down well pump plumbing and appurtances
bull Two (2) 20000 frac tanks
bull Groundwater transfer pumps and controls
bull Settlingaerationsand filtration treatment processes for the treatment of inorganics (if needed) and
nsow WOODARD amp CURRAN 16 September 302003 20564309
bull Granular activated carbon units for the treatment of dissolved organics in the groundwater
The groundwater treatment process will include the following processes 1) an oxidation and filtration
step to remove the inorganics from the groundwater and GAC units to treat the organic contaminants in
the extracted groundwater
Pretest Monitoring Prior to initiation of pumping WampC will monitor water levels in existing wells and
newly installed borings adjacent to the pumping well using a combination of hand measurements and data
loggers to develop an understanding of the piezometric surface under unstressed conditions The wells
proposed for water-level monitoring will be described in the work plan In addition all gauges
transducers flow meters and other equipment used in conducting the pumping tests shall be calibrated
before use
Constant Discharge Pumping Test The pumping test will be conducted in the source area using
newly-installed pumping well PW-207 It is anticipated that the test will be conducted at a pumping rate
of approximately 2 gallons per minute (gpm) for a period of 2 to 3 days however a higher or lower rate
may be shown to be appropriate based on the drilling and packer testing conducted during boring
installation Woodard amp Curran proposes to conduct this test using a vacuum-enhanced recovery system
(VERS) as described in the ROD so that the water level is not lowered appreciably in the vicinity of the
pumping well to prevent the potential migration of NAPLs to deeper bedrock zones The appropriateness
and feasibility of the VERS for the pumping test will be determined by field testing or literature
evaluation prior to completion of the Work Plan Because of the short duration of this test it is not
anticipated that stability of water levels will be reached in observation wells The test will however
provide information to estimate hydraulic conductivity and bedrock storage During the test the water
levels in the pumping well and selected monitoring wells will be logged continuously via down well data
loggers It is anticipated that water levels in approximately 24 wells will be measured using hand
measurements and data loggers
Groundwater extracted during the pumping test will be stored temporarily in an on-site frac tank prior to
on-site treatment and disposal
TISOW WOODARD amp CURRAN 17 September 302003 20564309
Post-Test Monitoring After the pump is turned off in the pumping well water levels will continue to be
monitored using hand measurements and data loggers until they have returned to within 10 of the preshy
test levels For planning purposes this has been estimated to be two weeks
Data Analysis Data collected during the pumping test will be analyzed with Aquifer Win32 Results of
the pumping test will be summarized in the summary data package for the TI Evaluation and the results
will also be used in the design of the hydraulic containment system specified in the Interim ROD that is
being conducted under the authority of the AOC for the RD Detail regarding use of the pumping test
data in hydraulic system design will be provided in the Remedial Design Work Plan
Subtask 7 - Tracer Test
WampC will conduct a tracer test using a conservative tracer to evaluate fracture connectivity porosity
dispersivity and matrix diffusion of the bedrock aquifer in both the Source Area and Non-Source Area
To increase the potential for success of this test results of the pumping test evaluation will be used to
revise the tracer test plan proposed here as necessary Following rebound of water levels after
completion of the pumping test WampC will initiate a single natural gradient tracer test The test will
consist of injecting a tracer into well PW-207 in the source area (Figure 3-1) for up to five days and
monitoring the tracers arrival in nearby wells Borehole geophysics core evaluation and packer testing
will be used to select the specific injection depth(s) in the well
A Tracer Test Work Plan will be completed prior to initiation of injection to determine the type quantity
and concentration of tracer based on the distance between the injection well and the monitoring wells A
conservative tracer that is one that is not preferentially adsorbed to rock or organic matter will be
selected for the tracer test Tracer injection equipment including tanks and flow-regulating and metering
equipment and pumps will be used to mix the tracer at the surface prior to injection Fractures may be
packered in the injection well and tracer solution will be injected at a rate determined during preparation
of the Tracer Test Work Plan During injection the potentiometric surface of the aquifer will be
monitored to verify that the potentiometric surface remains relatively constant during the injection
process
nsow WOODARD amp CURRAN 18 September 302003 20564309
Prior to injection of the tracer background concentration will be established by collecting samples from
up to six wells in the area of the tracer test and analyzing them for the tracer using an appropriate
analytical method Following injection of the tracer solutions the concentration of the tracer in
downgradient wells and borings will be measured A monitoring network will be established using nearby
monitoring wells Downhole probes will be installed in six new and existing wells near the injection well
to be identified in the work plan first to determine the background tracer concentrations and then to
monitor for the presence of the tracer upon initiation of the test Measurements will be collected at
periodic intervals to be determined based on the results of packer testing If an increase in tracer
concentration is detected or at a minimum on a weekly basis a water sample will be collected using low
flow sampling methodologies and analyzed in an off-site laboratory to evaluate the concentration of the
tracer The concentration of the tracer will be recorded Monitoring of the tracer concentration will
continue throughout the duration of the test The tracer will be allowed to flow with groundwater for one
month or until detected in wells in the vicinity of MW-106 whichever is shorter
313 Task 3 - TI Evaluation and Reporting
The TI Evaluation and reporting task includes the following five subtasks
bull Data evaluation
bull Summary data package
bull Draft TI Evaluation
bull Meetings with PRP Group and USEPA and
bull Revise and finalize TI Evaluation
As the subtasks of the field investigation are completed the data will be evaluated for the purpose of
addressing the data gaps identified by USEPA Specifically the data will be used to further refine the
cleanup times for non-source area groundwater presented in the Interim ROD
The data obtained during the field investigation will be reduced and evaluated and a summary data
package will be prepared that will include a discussion of the field activities completed and presentation
of the data It is anticipated that up to two meetings with USEPA will be necessary before the data
evaluation and summary report are completed
TISOW WOODARDampCURRAN 19 September 302003 20564309
Data collected during the pumping test will be analyzed with Aquifer Win32 Results will be summarized
in the summary data package and will also be presented as part of the RD submittals
Following submittal of the summary data package the TI evaluation will be prepared In accordance with
EPA guidance (1993) the TI waiver evaluation document will address the following topics
1 Specific ARARS or media cleanup standards for which TI determination is sought This section of the
TI Evaluation will identify the specific contaminants for which the TI determination is sought Based on
information available to date a waiver may be appropriate for pesticides PCBs chlorinated organic
compounds and other site-related contaminants that upon evaluation will not attain ARARs in a
reasonable period of time
2 Spatial area over which the TI waiver will apply The purpose of the additional site investigation
outlined in this SOW is to obtain the data necessary to further refine cleanup times presented in the
Interim ROD to determine what portions of the Site will not be expected to reach ARARs within a
reasonable time Consistent with TI guidance (USEPA 1993) the TI evaluation will specify the
horizontal and vertical extent of the area for which TI determination is sought Groundwater
concentration data from the RI and the TI SOW will be used to refine the distribution of the plume Data
from the drilling geophysical logging packer testing and pumping and tracer tests will be used to refine
the Site conceptual model and the cleanup times that will serve as the basis for establishing the scope and
nature of the TI zone
3 Conceptual Model The conceptual model forms the technical core of the TI Waiver Evaluation since
it provides basis for understanding of the restoration potential of the site The conceptual model outlines
the physical and hydrogeological constraints that hinder remediation or removal of Site contaminants and
it is the extent of these constraints rather than restoration timeframe alone that USEPA will use to
evaluate the necessity of the TI waiver of ARARs The conceptual model is the link between restoration
potential and restoration timeframe since it explains why proposed technologies are unlikely to work
either at all or within the desired 100-year timeframe
The Site conceptual model is not a mathematical model however as the result of the extensive modeling
and investigations of the site WampC has a strong understanding of the complex bedrock and overburden
TISOW WOODARDampCURRAN 20 September 302003 20564309
groundwater system beneath this site This understanding has been presented previously in both the RI
report and the FS and will be refined based on the TI SOW as necessary and summarized in the TI
Waiver Evaluation with specific attention to the physical and hydrogeological constraints on remediation
In particular the Site conceptual model will be reviewed in light of the new geologic data from drilling
logging and packer testing and the new hydrogeologic data obtained from the pumping test and tracer test
and will be revised to incorporate the new understanding
4 An evaluation of the restoration potential of the site This section will consist of a several components
It will present a systematic review of the technologies potentially capable of remediating the site given
the physical and hydrogeological constraints identified in the site model The newly acquired data will
provide an improved understanding of bedrock hydraulic properties that will allow a more Site-specific
evaluation of technologies The review of technologies will also include review of innovative
technologies and will evaluate whether existing remedial technologies or strategies would be capable of
achieving groundwater restoration at the site in a reasonable timeframe The section reference the FS and
will summarize the alternative remedies considered in the FS focusing on the ability of each to restore
groundwater in a reasonable timeframe It will also include a discussion of the selected hydraulic
containment system in light of the data gathered from the pumping test conducted in conjunction with the
TI SOW
Based on the Batch Flushing Model and using the agreed upon koc data from the RI as well as data from
this TI SOW including the f data collected as part of Subtask 4 a restoration timeframe analysis will be
conducted Following completion of the timeframe analysis and consideration of the results of drilling
rock and water analyses and pumping and tracer test a determination will be made regarding the Source
Area and the portion of the Non-Source Area VOC plume that will not attain ARARs in a reasonable
time
TISOW WOODARD amp CURRAN 21 September 302003 20564309
40 SCHEDULE
A proposed project schedule is included with this plan as Figure 4-1 This schedule is included for
discussion purposes and will be modified as necessary once the final scope of work as been approved by
all parties and the field work activities are coordinated with the subcontractors
TISOW WOODARD amp CURRAN 22 September 302003 20564309
ID
2
3
4
5
6
7 a i 10
11
12
13
14
15
16
17
16
19
20
21
22
24
25
26
27
26
29
30
31
32
Task Name
Project Meeting with EPA
Finalize SOW
Prepare Work Plans QAPP HASP Revision
Submit Work Plans for EPA Approval
Project Meeting with EPA
Revisions to work plans
Submit final work plans
Subcontractor Contracts
Project Meeting wEPA
Field Investigation
Site Mobilization
Install Borings
Borehole Geophysics
Packer Testing amp Collect GW Samples
Pumping Test
Tracer Test
Test setup
Injection
Monitoring
Data Reporting
InstallDevelop Wells
Data Evaluation
Prepare Data Package
Data Package Submittal to EPA
Draft Tl Evaluation Repon
Draft Tl Evaluation Report Submttal to EPA
EPA ReviewComment on Tl Evaluation ReF
Project Meeting wEPA
Revisions to Tl Evaluation Report
Submit Final Tl Evaluation Report
Start
Wed 070903
Thu 071003
Fri 101003
Mon 120103
Mon 121503
Mon 122903
Mon 011204
Tue 011304
Thu 021904
Fri 032104
Fri 032604
Fri 040204
Fri 041604
Fri 042304
Thu 050604
Wed 060204
Wed 060204
Wed 060904
Wed 060904
Wed 062304
Wed 070704
Wed 042804
Wed 062304
Mon 080204
Mon 070504
Tue 082404
Wed 082504
Wed 091504
Thu 0916AM
Thu 093004
Finish
Wed 070903
Fri 1OtO7u3
Fri 112803
Fri 122603
Mon 121503
Fri 010904
Mon 011204
Mon 012604
Thu 021904
Tue 071304
Thu 040104
Thu 042204
Tue 042704
Wed 050504
Tue 052504
Tue 071304
Tue 060804
Tue 061504
Tue 070604
Tue 071304
Fri 070904
Tue 072004
Fri 073004
Mon 080204
Mon 082304
Tue 082404
Tue 091404
Wed 091504
Wed 082904
Thu 093004
FIGURE 4-1 DRAFT HOWS CORNER SUPERFUND SITE
Tl EVALUATION amp RELD WORK FOR HYDRAUUC CONTAINMENT SYSTEM DESIGN PROPOSED PROJECT SCHEDULE
2003 2004 Mav |
Jun | Jul
ltamp i
Aug
i
Sen Oct I Nov Dec Jan Feb I Mar
ii i i
k ^tr 1
1V i
I t bull ^
I
ta^M bull bull M W
l LgtH^HBKLii LJ Mi
I
bull bull raquo bull laquo^ 0930
Task Progress I^MLHHHI^LB Summary ^^^^^^^^f External Tasks M B WMMM Deadline ^7 Project Hows Comer Schedule6A bull bull bull 1 UData Fri 101003 Split Milestone ^ Project Summary ^f^KKKKKK^^ External Milestone ^
Pagei
50 ACRONYMS
AOC Administrative Order by Consent
ARARs Applicable or Relevant and Appropriate Requirements
ATV acoustic televiewer
bgs below ground surface
CERCLA Comprehensive Environmental Resource and Conservation Liability Act
DNAPL Dense Non-Aqueous Phase Liquid
GAC granular activated carbon
gpm gallons per minute
HASP Health and Safety Plan
row investigation-derived waste
MCL Maximum Containment Level
MEDEP Maine Department of Environmental Protection
MEG Maine Enforcement Guideline
mgkg milligrams per kilogram
Hg kg micrograms per kilogram
NCP National Contingency Plan
PCB polychlorinated biphenyl
PID photo ionization detector
ppm parts per million
PRP Potentially Responsible Party
TISOW WOODARD amp CURRAN 24 September 302003 20564309
QAPP Quality Assurance Project Plan
QAQC Quality AssuranceQuality Control
RA Remedial Action
RAO Remedial Action Objective
RCRA Resource Conservation and Recovery Act
RD Remedial Design
RIFS Remedial InvestigationFeasibility Study
ROD Record of Decision
SAP Sampling and Analysis Plan
SOW Statement of Work
TAL target analyte list
TI Technical Impracticability
USEPA United State Environmental Protection Agency
VOCs volatile organic compounds
WampC Woodard amp Curran Inc
TISOW WOODARD amp CURRAN 25 September 302003 20564309
REFERENCES
Everts CJ RS Kanwar (1994) Evaluation of Rhodamine WT as an adsorbed tracer in an agricultural
soil J Hydrology 153 53-70
Kasnavia T D Vu DA Sabatini (1999) Fluorescent dye and media properties affecting sorption and
tracer selection Groundwater 37 376-381
Ptak T G Schmid (1996) Dual-tracer transport experiments in a physically and chemically
heterogeneous porous aquifer effective transport parameters and spatial variability J Hydrology
183 117-138
Sabatini DA T A Austin (1991) Characteristics of Rhodamine WT and fluorescein as adsorbing
ground-water tracers Ground Water 29 341-349
Trudgill ST (1987) Soil water dye tracing with special reference to the use of Rhodamanie WT
Lissamine FF and Amino G acid Hydrological Processes 1 149-170
US Environmental Protection Agency (USEPA) 1993 Guidance for Evaluating the Technical
Impracticability of Ground-Water Restoration - Interim Final Office of Solid Waste and
Emergency Response Washington DC Directive 92342-25 September 1993
US Environmental Protection Agency (USEPA) 2002 Interim Record of Decision Summary shy
Operable Unit One Non-Source Area Groundwater West SiteHows Corner Superfund Site
Plymouth Maine EPA Region 1 September 2002
US Environmental Protection Agency (USEPA) 2003 Proposed Scope of Work West SiteHows
Corner Superfund Site Plymouth Maine EPA Region 1 4 pages September 2002
Vasudevan D RL Fimmen AB Francisco (2001) Tracer-grade Rhodamine WT Structure of
constituent isomers and their sorption behavior Environ Sci Technol 35 4089-4096
nsow WOODARD amp CURRAN 26 September 30 2003 20564309
Woodard amp Curran Inc (WampC) 2002 Final Feasibility Study Report - Non-Source Area Groundwater
Hows Comer Superfund Site Plymouth Maine July 2002
TISOW WOODARD amp CURRAN 27 September 302003 20564309
f
m WOODARD amp CURRAN Maine Massachusetts New Hampshire Connecticut Florida Illinois Operational offices across the US 1-800-426-4262 wwwwoodardcurrancom
i
bull During the installation of each angled boring observations will be made regarding water gainloss
drilling rate and bit behavior to assess the depth of potential fractures In addition water levels will be
9 measured in nearby borings using either hand measurements data loggers or both to evaluate
connectivity between locations A change in water level in a nearby boring will indicate a hydraulic
at connection between the borings Borehole geophysics will also be performed on the borings (See Subtask
2 below) Information from each angled boring will be used to site an adjacent vertical well (MW-203
^ and PW-207) so that it intercepts a fracture observed in the angled boring
^ Vertical Borings Two of the vertical borings will be completed with rotary diamond coring to
approximately 100 ft bgs These borings will be adjacent to the angled borings described above One of
^ the cored borings (MW-203) will be located near MW-106 outside of the source area within the
dissolved-phase groundwater plume (see Figure 3-1) The other cored boring (PW-207) will be the
pumping well which is anticipated to be located within the source area in the vicinity of the existing
MW-2 well cluster Coring will allow data collection for several purposes including direct observation
of bedrock for determination of the nature of the rock matrix determination of the location and nature of
fractures and the degree of fracturing comparison with geophysical logs (Subtask 2) to verify
interpretation of the logs and collection of core samples for analysis (Subtask 4)
The remaining borings will be located east of the 2-acre fenced area within or near the periphery of the
source area and will be sited to align approximately with existing wells based on the known fracture
orientations at the Site (MW-204 and MW-205) or with new wells based on the known fracture
pound orientations at the Site (MW-206) Data from these locations in conjunction with the other borings
installed as part of this TI SOW and the existing wells will be used in the interpretation of the pumping
^ test (Subtask 6) and tracer test (Subtask 7) In addition these three borings will further delineate
contamination and provide potential monitoring locations for long-term monitoring Each of these
^ borings will be advanced to approximately 100 ft bgs with a minimum four-inch diameter air hammer
^ During the installation of each boring observations will be made regarding water gainloss drilling rate
and bit behavior to assess the depth of potential fractures In addition water levels will be measured in
nearby borings using either hand measurements data loggers or both to evaluate connectivity between
locations A change in water level in a nearby boring will indicate a hydraulic connection between the
TISOW WOODARD amp CURRAN 12 September 302003 20564309
borings Borehole geophysics and packer testing will also be performed on the borings (See Subtasks 2
and 3 below)
Drilling water will be containerized on site and treated through granular activated carbon (GAC) Treated
water will be analyzed to verify that PCB and VOC concentrations have been reduced to below ARARs
prior to discharge to the ground surface Cuttings will be spread on the ground surface at the site
consistent with the Remedial Investigation work plan
It is anticipated that up to 10 core samples from each cored boring (total of 20 cores) will be collected and
submitted to an off-site laboratory for analyses of porosity (matrix and bulk) permeability bulk density
and fraction of organic carbon (f^) using methods described in Subtask 4
Subtask 2 - Borehole Geophysics
To supplement information on fracture location and connectivity obtained during boring advancement a
borehole geophysical survey will be conducted on the newly installed bedrock borings to evaluate the
nature and orientation of water bearing fractures in the borings The survey will be performed at the
completion of the angled borings and again at the completion of the vertical borings The information
obtained during the survey may be used to identify the location of subsequent boring(s) by refining the
understanding of the depth aperture and orientation of bedrock fractures The following measurements
are proposed for the new borings caliper fluid temperature fluid resistivity and acoustic televiewer
(ATV) Single-point resistively and 16 inch normal measurements will also be made in the first two
borings installed and the data will be compared to data from the other geophysical logs to determine if
the measurements confirm and significantly improve the interpretation regarding the presence of water-
bearing fractures If the measurements are applicable to identification of fractures they may be included
in lieu of other geophysical logs in the remainder of the borings
Subtask 3 - Packer Testing
To further refine information on the aquifer hydraulic conductivity the hydraulic connection between
fractures in the borings will be evaluated during packer testing of vertical borings The data will be used
to estimate the hydraulic conductivity of specific fractures and fracture zones The packer testing will be
performed after the vertical borings have been installed and the borehole geophysical survey completed
TISOW WOODARD amp CURRAN 13 September 30 2003 20564309
bull
m
M
Drilling observations and information from borehole geophysics will be used to identify specific fractures
below the water table that are capable of transmitting water Prior to water injection for hydraulic
conductivity and fracture connectivity testing groundwater samples will be collected at selected intervals
for analysis of VOCs (See Subtask 4) Sampling intervals will be selected based on drilling observations
and logging results that indicate water is moving into or out of the borehole or that fractures exist to
promote water movement such as rapid increase in the amount of water returned rapid change in
temperature or highly fractured interval
^
^
bull
f$
Double packer testing will be performed at selected intervals within each newly installed boring It is
anticipated that up to six intervals per well will be tested for a maximum of 24 intervals and that for each
interval the test will include an approximate 15-minute injection of potable water at four progressively
increasing pressures Packer spacing is anticipated to be 10 ft however spacing may vary so that packers
are not located in potential fracture zones identified using information from rock cores drilling
observations and borehole geophysics The tests at an individual interval will be terminated if it appears
that the interval is not accepting water Care will be taken to minimize over-pumping or over-
pressurizing of the fractures The flow rate will be measured to evaluate the characteristics of the
fracture Water levels in adjacent borings will be measured during the packer testing to determine if a
hydraulic connection exists between the borings Water generated during packer testing will be
containerized on site and treated through GAC Treated water will be analyzed to verify that PCB and
VOC concentrations have been reduced to below ARARs prior to discharge to the ground surface
4 Subtask 4 Sampling and Analysis
~d
^
Rock and groundwater samples will be collected during the field program for laboratory analysis The
results of the analyses will be used to help refine the distribution of the plume and to estimate bedrock
properties These analyses will be used in conjunction with existing data during the TI evaluation to
refine cleanup times and establish the limits of the TI zone
As described in Subtask 1 it is anticipated that up to 10 core samples from each cored boring (total of 20
core samples) will be collected and submitted to an off-site laboratory for analyses of porosity (matrix and
bulk) permeability bulk density and fraction of organic carbon (f^) using existing industry methods
Subject to further evaluation of industry methods Woodard amp Curran proposes that porosity
TISOW WOODARD amp CURRAN20564309
14 September 302003
permeability and density will be measured using methods in the American Petroleum Institutes API RPshy
40 Fraction of organic carbon (f^) will be measured using either the LECO TOC method or Walkey-
Black method The LECO TOC method is a standard method in the petroleum industry and involves the
direct combustion of a ground rock sample The Walkey-Black method is a commonly used USEPA-
approved chemical oxidation method for determination of foe in soils In addition either method could be
used if a sample were scraped from a fracture surface To develop a reasonable range of f for Site
bedrock up to five samples will be selected from each boring from the unfractured matrix and up to five
from the fracture surfaces In addition Woodard amp Curran will evaluate the appropriateness of selecting
rock samples from a subset of the core samples from areas near fractures as well as from non-fractured
areas and submitting the samples for VOC analysis following methanol extraction
Results from these analyses will be used in conjunction with groundwater contaminant concentrations to
evaluate the significance of diffusion of contamination from the bedrock matrix in both the Source Area
and the Non-Source Area Although matrix diffusion likely is a significant factor in the determination of
cleanup times within the Source Area the potential applicability of matrix diffusion in the Non-Source
Area is not known These core analyses may provide evidence to assist in developing an estimate
through calculations of the effect of matrix diffusion on cleanup times
As noted in Subtask 3 prior to injection of water during packer testing groundwater samples will be
collected at selected intervals for analysis of volatile organic compounds (VOCs) Up to a total of 20
groundwater samples plus appropriate quality control samples will be collected from the newly installed
borings The samples will be submitted to an off-site laboratory for analysis Analytical results will be
validated in accordance with USEPA protocol and the data will be managed in WampCs existing
groundwater sampling analytical database for this site
Up to 21 existing monitoring wells from within or nearby the 17-acre property plus four new wells once
constructed will be sampled using low-flow techniques and submitted to an off-site laboratory for VOC
analysis Analytical results will be validated in accordance with USEPA protocol and the data will be
managed in WampCs existing groundwater sampling analytical database for this site
TISOW WOODARD amp CURRAN 15 September 302003 20564309
Subtask 5 - Monitoring Well Installation
Although it is anticipated that the newly installed borings will be left as open holes for tracer testing and
for pumping tests monitoring wells will be installed and developed in the newly installed borings unless
the USEPA MEDEP and PRP Group determine that the location is inappropriate for such use The
monitoring wells will be constructed of two-inch schedule 40 PVC screen and riser Screen intervals will
be selected based on the location of fractures identified during drilling geophysical logging and packer
testing A sand pack will be placed around the screen and will extend from approximately two ft below
the screen to approximately two ft above the screen
Subtask 6 - Pumping Test
WampC will conduct a single constant discharge pumping test to evaluate hydraulic properties of the
aquifer It is anticipated that the test will be conducted in a new pumping well in the vicinity of the
existing MW-2 well cluster within the source area Data from the pumping test will be used in
conjunction with other data from the investigation to improve the understanding of groundwater
movement and contaminant transport in the Source and Non-Source areas The results of the pumping
test will be used to refine the Site conceptual model as well as in the design of the hydraulic containment
system that is being constructed under the authority of the AOC for the RD
The groundwater pumping test will include the following components (1) Pumping test setup (2) Pretest
monitoring (3) Constant Discharge Pumping Test (4) Post-test monitoring and (5) Data Analysis
Pumping Test Setup In support of the groundwater pumping test WampC will install a pumping well
(PW-207) and procure and install the required groundwater extraction treatment and storage equipment at
the Site The well will be cored and over drilled to allow construction of a 4-inch well The location will
be in the vicinity of the MW-2 well cluster and be based upon results of the angled bedrock boring AWshy
202 The equipment will include but not be limited to
bull Down well pump plumbing and appurtances
bull Two (2) 20000 frac tanks
bull Groundwater transfer pumps and controls
bull Settlingaerationsand filtration treatment processes for the treatment of inorganics (if needed) and
nsow WOODARD amp CURRAN 16 September 302003 20564309
bull Granular activated carbon units for the treatment of dissolved organics in the groundwater
The groundwater treatment process will include the following processes 1) an oxidation and filtration
step to remove the inorganics from the groundwater and GAC units to treat the organic contaminants in
the extracted groundwater
Pretest Monitoring Prior to initiation of pumping WampC will monitor water levels in existing wells and
newly installed borings adjacent to the pumping well using a combination of hand measurements and data
loggers to develop an understanding of the piezometric surface under unstressed conditions The wells
proposed for water-level monitoring will be described in the work plan In addition all gauges
transducers flow meters and other equipment used in conducting the pumping tests shall be calibrated
before use
Constant Discharge Pumping Test The pumping test will be conducted in the source area using
newly-installed pumping well PW-207 It is anticipated that the test will be conducted at a pumping rate
of approximately 2 gallons per minute (gpm) for a period of 2 to 3 days however a higher or lower rate
may be shown to be appropriate based on the drilling and packer testing conducted during boring
installation Woodard amp Curran proposes to conduct this test using a vacuum-enhanced recovery system
(VERS) as described in the ROD so that the water level is not lowered appreciably in the vicinity of the
pumping well to prevent the potential migration of NAPLs to deeper bedrock zones The appropriateness
and feasibility of the VERS for the pumping test will be determined by field testing or literature
evaluation prior to completion of the Work Plan Because of the short duration of this test it is not
anticipated that stability of water levels will be reached in observation wells The test will however
provide information to estimate hydraulic conductivity and bedrock storage During the test the water
levels in the pumping well and selected monitoring wells will be logged continuously via down well data
loggers It is anticipated that water levels in approximately 24 wells will be measured using hand
measurements and data loggers
Groundwater extracted during the pumping test will be stored temporarily in an on-site frac tank prior to
on-site treatment and disposal
TISOW WOODARD amp CURRAN 17 September 302003 20564309
Post-Test Monitoring After the pump is turned off in the pumping well water levels will continue to be
monitored using hand measurements and data loggers until they have returned to within 10 of the preshy
test levels For planning purposes this has been estimated to be two weeks
Data Analysis Data collected during the pumping test will be analyzed with Aquifer Win32 Results of
the pumping test will be summarized in the summary data package for the TI Evaluation and the results
will also be used in the design of the hydraulic containment system specified in the Interim ROD that is
being conducted under the authority of the AOC for the RD Detail regarding use of the pumping test
data in hydraulic system design will be provided in the Remedial Design Work Plan
Subtask 7 - Tracer Test
WampC will conduct a tracer test using a conservative tracer to evaluate fracture connectivity porosity
dispersivity and matrix diffusion of the bedrock aquifer in both the Source Area and Non-Source Area
To increase the potential for success of this test results of the pumping test evaluation will be used to
revise the tracer test plan proposed here as necessary Following rebound of water levels after
completion of the pumping test WampC will initiate a single natural gradient tracer test The test will
consist of injecting a tracer into well PW-207 in the source area (Figure 3-1) for up to five days and
monitoring the tracers arrival in nearby wells Borehole geophysics core evaluation and packer testing
will be used to select the specific injection depth(s) in the well
A Tracer Test Work Plan will be completed prior to initiation of injection to determine the type quantity
and concentration of tracer based on the distance between the injection well and the monitoring wells A
conservative tracer that is one that is not preferentially adsorbed to rock or organic matter will be
selected for the tracer test Tracer injection equipment including tanks and flow-regulating and metering
equipment and pumps will be used to mix the tracer at the surface prior to injection Fractures may be
packered in the injection well and tracer solution will be injected at a rate determined during preparation
of the Tracer Test Work Plan During injection the potentiometric surface of the aquifer will be
monitored to verify that the potentiometric surface remains relatively constant during the injection
process
nsow WOODARD amp CURRAN 18 September 302003 20564309
Prior to injection of the tracer background concentration will be established by collecting samples from
up to six wells in the area of the tracer test and analyzing them for the tracer using an appropriate
analytical method Following injection of the tracer solutions the concentration of the tracer in
downgradient wells and borings will be measured A monitoring network will be established using nearby
monitoring wells Downhole probes will be installed in six new and existing wells near the injection well
to be identified in the work plan first to determine the background tracer concentrations and then to
monitor for the presence of the tracer upon initiation of the test Measurements will be collected at
periodic intervals to be determined based on the results of packer testing If an increase in tracer
concentration is detected or at a minimum on a weekly basis a water sample will be collected using low
flow sampling methodologies and analyzed in an off-site laboratory to evaluate the concentration of the
tracer The concentration of the tracer will be recorded Monitoring of the tracer concentration will
continue throughout the duration of the test The tracer will be allowed to flow with groundwater for one
month or until detected in wells in the vicinity of MW-106 whichever is shorter
313 Task 3 - TI Evaluation and Reporting
The TI Evaluation and reporting task includes the following five subtasks
bull Data evaluation
bull Summary data package
bull Draft TI Evaluation
bull Meetings with PRP Group and USEPA and
bull Revise and finalize TI Evaluation
As the subtasks of the field investigation are completed the data will be evaluated for the purpose of
addressing the data gaps identified by USEPA Specifically the data will be used to further refine the
cleanup times for non-source area groundwater presented in the Interim ROD
The data obtained during the field investigation will be reduced and evaluated and a summary data
package will be prepared that will include a discussion of the field activities completed and presentation
of the data It is anticipated that up to two meetings with USEPA will be necessary before the data
evaluation and summary report are completed
TISOW WOODARDampCURRAN 19 September 302003 20564309
Data collected during the pumping test will be analyzed with Aquifer Win32 Results will be summarized
in the summary data package and will also be presented as part of the RD submittals
Following submittal of the summary data package the TI evaluation will be prepared In accordance with
EPA guidance (1993) the TI waiver evaluation document will address the following topics
1 Specific ARARS or media cleanup standards for which TI determination is sought This section of the
TI Evaluation will identify the specific contaminants for which the TI determination is sought Based on
information available to date a waiver may be appropriate for pesticides PCBs chlorinated organic
compounds and other site-related contaminants that upon evaluation will not attain ARARs in a
reasonable period of time
2 Spatial area over which the TI waiver will apply The purpose of the additional site investigation
outlined in this SOW is to obtain the data necessary to further refine cleanup times presented in the
Interim ROD to determine what portions of the Site will not be expected to reach ARARs within a
reasonable time Consistent with TI guidance (USEPA 1993) the TI evaluation will specify the
horizontal and vertical extent of the area for which TI determination is sought Groundwater
concentration data from the RI and the TI SOW will be used to refine the distribution of the plume Data
from the drilling geophysical logging packer testing and pumping and tracer tests will be used to refine
the Site conceptual model and the cleanup times that will serve as the basis for establishing the scope and
nature of the TI zone
3 Conceptual Model The conceptual model forms the technical core of the TI Waiver Evaluation since
it provides basis for understanding of the restoration potential of the site The conceptual model outlines
the physical and hydrogeological constraints that hinder remediation or removal of Site contaminants and
it is the extent of these constraints rather than restoration timeframe alone that USEPA will use to
evaluate the necessity of the TI waiver of ARARs The conceptual model is the link between restoration
potential and restoration timeframe since it explains why proposed technologies are unlikely to work
either at all or within the desired 100-year timeframe
The Site conceptual model is not a mathematical model however as the result of the extensive modeling
and investigations of the site WampC has a strong understanding of the complex bedrock and overburden
TISOW WOODARDampCURRAN 20 September 302003 20564309
groundwater system beneath this site This understanding has been presented previously in both the RI
report and the FS and will be refined based on the TI SOW as necessary and summarized in the TI
Waiver Evaluation with specific attention to the physical and hydrogeological constraints on remediation
In particular the Site conceptual model will be reviewed in light of the new geologic data from drilling
logging and packer testing and the new hydrogeologic data obtained from the pumping test and tracer test
and will be revised to incorporate the new understanding
4 An evaluation of the restoration potential of the site This section will consist of a several components
It will present a systematic review of the technologies potentially capable of remediating the site given
the physical and hydrogeological constraints identified in the site model The newly acquired data will
provide an improved understanding of bedrock hydraulic properties that will allow a more Site-specific
evaluation of technologies The review of technologies will also include review of innovative
technologies and will evaluate whether existing remedial technologies or strategies would be capable of
achieving groundwater restoration at the site in a reasonable timeframe The section reference the FS and
will summarize the alternative remedies considered in the FS focusing on the ability of each to restore
groundwater in a reasonable timeframe It will also include a discussion of the selected hydraulic
containment system in light of the data gathered from the pumping test conducted in conjunction with the
TI SOW
Based on the Batch Flushing Model and using the agreed upon koc data from the RI as well as data from
this TI SOW including the f data collected as part of Subtask 4 a restoration timeframe analysis will be
conducted Following completion of the timeframe analysis and consideration of the results of drilling
rock and water analyses and pumping and tracer test a determination will be made regarding the Source
Area and the portion of the Non-Source Area VOC plume that will not attain ARARs in a reasonable
time
TISOW WOODARD amp CURRAN 21 September 302003 20564309
40 SCHEDULE
A proposed project schedule is included with this plan as Figure 4-1 This schedule is included for
discussion purposes and will be modified as necessary once the final scope of work as been approved by
all parties and the field work activities are coordinated with the subcontractors
TISOW WOODARD amp CURRAN 22 September 302003 20564309
ID
2
3
4
5
6
7 a i 10
11
12
13
14
15
16
17
16
19
20
21
22
24
25
26
27
26
29
30
31
32
Task Name
Project Meeting with EPA
Finalize SOW
Prepare Work Plans QAPP HASP Revision
Submit Work Plans for EPA Approval
Project Meeting with EPA
Revisions to work plans
Submit final work plans
Subcontractor Contracts
Project Meeting wEPA
Field Investigation
Site Mobilization
Install Borings
Borehole Geophysics
Packer Testing amp Collect GW Samples
Pumping Test
Tracer Test
Test setup
Injection
Monitoring
Data Reporting
InstallDevelop Wells
Data Evaluation
Prepare Data Package
Data Package Submittal to EPA
Draft Tl Evaluation Repon
Draft Tl Evaluation Report Submttal to EPA
EPA ReviewComment on Tl Evaluation ReF
Project Meeting wEPA
Revisions to Tl Evaluation Report
Submit Final Tl Evaluation Report
Start
Wed 070903
Thu 071003
Fri 101003
Mon 120103
Mon 121503
Mon 122903
Mon 011204
Tue 011304
Thu 021904
Fri 032104
Fri 032604
Fri 040204
Fri 041604
Fri 042304
Thu 050604
Wed 060204
Wed 060204
Wed 060904
Wed 060904
Wed 062304
Wed 070704
Wed 042804
Wed 062304
Mon 080204
Mon 070504
Tue 082404
Wed 082504
Wed 091504
Thu 0916AM
Thu 093004
Finish
Wed 070903
Fri 1OtO7u3
Fri 112803
Fri 122603
Mon 121503
Fri 010904
Mon 011204
Mon 012604
Thu 021904
Tue 071304
Thu 040104
Thu 042204
Tue 042704
Wed 050504
Tue 052504
Tue 071304
Tue 060804
Tue 061504
Tue 070604
Tue 071304
Fri 070904
Tue 072004
Fri 073004
Mon 080204
Mon 082304
Tue 082404
Tue 091404
Wed 091504
Wed 082904
Thu 093004
FIGURE 4-1 DRAFT HOWS CORNER SUPERFUND SITE
Tl EVALUATION amp RELD WORK FOR HYDRAUUC CONTAINMENT SYSTEM DESIGN PROPOSED PROJECT SCHEDULE
2003 2004 Mav |
Jun | Jul
ltamp i
Aug
i
Sen Oct I Nov Dec Jan Feb I Mar
ii i i
k ^tr 1
1V i
I t bull ^
I
ta^M bull bull M W
l LgtH^HBKLii LJ Mi
I
bull bull raquo bull laquo^ 0930
Task Progress I^MLHHHI^LB Summary ^^^^^^^^f External Tasks M B WMMM Deadline ^7 Project Hows Comer Schedule6A bull bull bull 1 UData Fri 101003 Split Milestone ^ Project Summary ^f^KKKKKK^^ External Milestone ^
Pagei
50 ACRONYMS
AOC Administrative Order by Consent
ARARs Applicable or Relevant and Appropriate Requirements
ATV acoustic televiewer
bgs below ground surface
CERCLA Comprehensive Environmental Resource and Conservation Liability Act
DNAPL Dense Non-Aqueous Phase Liquid
GAC granular activated carbon
gpm gallons per minute
HASP Health and Safety Plan
row investigation-derived waste
MCL Maximum Containment Level
MEDEP Maine Department of Environmental Protection
MEG Maine Enforcement Guideline
mgkg milligrams per kilogram
Hg kg micrograms per kilogram
NCP National Contingency Plan
PCB polychlorinated biphenyl
PID photo ionization detector
ppm parts per million
PRP Potentially Responsible Party
TISOW WOODARD amp CURRAN 24 September 302003 20564309
QAPP Quality Assurance Project Plan
QAQC Quality AssuranceQuality Control
RA Remedial Action
RAO Remedial Action Objective
RCRA Resource Conservation and Recovery Act
RD Remedial Design
RIFS Remedial InvestigationFeasibility Study
ROD Record of Decision
SAP Sampling and Analysis Plan
SOW Statement of Work
TAL target analyte list
TI Technical Impracticability
USEPA United State Environmental Protection Agency
VOCs volatile organic compounds
WampC Woodard amp Curran Inc
TISOW WOODARD amp CURRAN 25 September 302003 20564309
REFERENCES
Everts CJ RS Kanwar (1994) Evaluation of Rhodamine WT as an adsorbed tracer in an agricultural
soil J Hydrology 153 53-70
Kasnavia T D Vu DA Sabatini (1999) Fluorescent dye and media properties affecting sorption and
tracer selection Groundwater 37 376-381
Ptak T G Schmid (1996) Dual-tracer transport experiments in a physically and chemically
heterogeneous porous aquifer effective transport parameters and spatial variability J Hydrology
183 117-138
Sabatini DA T A Austin (1991) Characteristics of Rhodamine WT and fluorescein as adsorbing
ground-water tracers Ground Water 29 341-349
Trudgill ST (1987) Soil water dye tracing with special reference to the use of Rhodamanie WT
Lissamine FF and Amino G acid Hydrological Processes 1 149-170
US Environmental Protection Agency (USEPA) 1993 Guidance for Evaluating the Technical
Impracticability of Ground-Water Restoration - Interim Final Office of Solid Waste and
Emergency Response Washington DC Directive 92342-25 September 1993
US Environmental Protection Agency (USEPA) 2002 Interim Record of Decision Summary shy
Operable Unit One Non-Source Area Groundwater West SiteHows Corner Superfund Site
Plymouth Maine EPA Region 1 September 2002
US Environmental Protection Agency (USEPA) 2003 Proposed Scope of Work West SiteHows
Corner Superfund Site Plymouth Maine EPA Region 1 4 pages September 2002
Vasudevan D RL Fimmen AB Francisco (2001) Tracer-grade Rhodamine WT Structure of
constituent isomers and their sorption behavior Environ Sci Technol 35 4089-4096
nsow WOODARD amp CURRAN 26 September 30 2003 20564309
Woodard amp Curran Inc (WampC) 2002 Final Feasibility Study Report - Non-Source Area Groundwater
Hows Comer Superfund Site Plymouth Maine July 2002
TISOW WOODARD amp CURRAN 27 September 302003 20564309
f
m WOODARD amp CURRAN Maine Massachusetts New Hampshire Connecticut Florida Illinois Operational offices across the US 1-800-426-4262 wwwwoodardcurrancom
i
borings Borehole geophysics and packer testing will also be performed on the borings (See Subtasks 2
and 3 below)
Drilling water will be containerized on site and treated through granular activated carbon (GAC) Treated
water will be analyzed to verify that PCB and VOC concentrations have been reduced to below ARARs
prior to discharge to the ground surface Cuttings will be spread on the ground surface at the site
consistent with the Remedial Investigation work plan
It is anticipated that up to 10 core samples from each cored boring (total of 20 cores) will be collected and
submitted to an off-site laboratory for analyses of porosity (matrix and bulk) permeability bulk density
and fraction of organic carbon (f^) using methods described in Subtask 4
Subtask 2 - Borehole Geophysics
To supplement information on fracture location and connectivity obtained during boring advancement a
borehole geophysical survey will be conducted on the newly installed bedrock borings to evaluate the
nature and orientation of water bearing fractures in the borings The survey will be performed at the
completion of the angled borings and again at the completion of the vertical borings The information
obtained during the survey may be used to identify the location of subsequent boring(s) by refining the
understanding of the depth aperture and orientation of bedrock fractures The following measurements
are proposed for the new borings caliper fluid temperature fluid resistivity and acoustic televiewer
(ATV) Single-point resistively and 16 inch normal measurements will also be made in the first two
borings installed and the data will be compared to data from the other geophysical logs to determine if
the measurements confirm and significantly improve the interpretation regarding the presence of water-
bearing fractures If the measurements are applicable to identification of fractures they may be included
in lieu of other geophysical logs in the remainder of the borings
Subtask 3 - Packer Testing
To further refine information on the aquifer hydraulic conductivity the hydraulic connection between
fractures in the borings will be evaluated during packer testing of vertical borings The data will be used
to estimate the hydraulic conductivity of specific fractures and fracture zones The packer testing will be
performed after the vertical borings have been installed and the borehole geophysical survey completed
TISOW WOODARD amp CURRAN 13 September 30 2003 20564309
bull
m
M
Drilling observations and information from borehole geophysics will be used to identify specific fractures
below the water table that are capable of transmitting water Prior to water injection for hydraulic
conductivity and fracture connectivity testing groundwater samples will be collected at selected intervals
for analysis of VOCs (See Subtask 4) Sampling intervals will be selected based on drilling observations
and logging results that indicate water is moving into or out of the borehole or that fractures exist to
promote water movement such as rapid increase in the amount of water returned rapid change in
temperature or highly fractured interval
^
^
bull
f$
Double packer testing will be performed at selected intervals within each newly installed boring It is
anticipated that up to six intervals per well will be tested for a maximum of 24 intervals and that for each
interval the test will include an approximate 15-minute injection of potable water at four progressively
increasing pressures Packer spacing is anticipated to be 10 ft however spacing may vary so that packers
are not located in potential fracture zones identified using information from rock cores drilling
observations and borehole geophysics The tests at an individual interval will be terminated if it appears
that the interval is not accepting water Care will be taken to minimize over-pumping or over-
pressurizing of the fractures The flow rate will be measured to evaluate the characteristics of the
fracture Water levels in adjacent borings will be measured during the packer testing to determine if a
hydraulic connection exists between the borings Water generated during packer testing will be
containerized on site and treated through GAC Treated water will be analyzed to verify that PCB and
VOC concentrations have been reduced to below ARARs prior to discharge to the ground surface
4 Subtask 4 Sampling and Analysis
~d
^
Rock and groundwater samples will be collected during the field program for laboratory analysis The
results of the analyses will be used to help refine the distribution of the plume and to estimate bedrock
properties These analyses will be used in conjunction with existing data during the TI evaluation to
refine cleanup times and establish the limits of the TI zone
As described in Subtask 1 it is anticipated that up to 10 core samples from each cored boring (total of 20
core samples) will be collected and submitted to an off-site laboratory for analyses of porosity (matrix and
bulk) permeability bulk density and fraction of organic carbon (f^) using existing industry methods
Subject to further evaluation of industry methods Woodard amp Curran proposes that porosity
TISOW WOODARD amp CURRAN20564309
14 September 302003
permeability and density will be measured using methods in the American Petroleum Institutes API RPshy
40 Fraction of organic carbon (f^) will be measured using either the LECO TOC method or Walkey-
Black method The LECO TOC method is a standard method in the petroleum industry and involves the
direct combustion of a ground rock sample The Walkey-Black method is a commonly used USEPA-
approved chemical oxidation method for determination of foe in soils In addition either method could be
used if a sample were scraped from a fracture surface To develop a reasonable range of f for Site
bedrock up to five samples will be selected from each boring from the unfractured matrix and up to five
from the fracture surfaces In addition Woodard amp Curran will evaluate the appropriateness of selecting
rock samples from a subset of the core samples from areas near fractures as well as from non-fractured
areas and submitting the samples for VOC analysis following methanol extraction
Results from these analyses will be used in conjunction with groundwater contaminant concentrations to
evaluate the significance of diffusion of contamination from the bedrock matrix in both the Source Area
and the Non-Source Area Although matrix diffusion likely is a significant factor in the determination of
cleanup times within the Source Area the potential applicability of matrix diffusion in the Non-Source
Area is not known These core analyses may provide evidence to assist in developing an estimate
through calculations of the effect of matrix diffusion on cleanup times
As noted in Subtask 3 prior to injection of water during packer testing groundwater samples will be
collected at selected intervals for analysis of volatile organic compounds (VOCs) Up to a total of 20
groundwater samples plus appropriate quality control samples will be collected from the newly installed
borings The samples will be submitted to an off-site laboratory for analysis Analytical results will be
validated in accordance with USEPA protocol and the data will be managed in WampCs existing
groundwater sampling analytical database for this site
Up to 21 existing monitoring wells from within or nearby the 17-acre property plus four new wells once
constructed will be sampled using low-flow techniques and submitted to an off-site laboratory for VOC
analysis Analytical results will be validated in accordance with USEPA protocol and the data will be
managed in WampCs existing groundwater sampling analytical database for this site
TISOW WOODARD amp CURRAN 15 September 302003 20564309
Subtask 5 - Monitoring Well Installation
Although it is anticipated that the newly installed borings will be left as open holes for tracer testing and
for pumping tests monitoring wells will be installed and developed in the newly installed borings unless
the USEPA MEDEP and PRP Group determine that the location is inappropriate for such use The
monitoring wells will be constructed of two-inch schedule 40 PVC screen and riser Screen intervals will
be selected based on the location of fractures identified during drilling geophysical logging and packer
testing A sand pack will be placed around the screen and will extend from approximately two ft below
the screen to approximately two ft above the screen
Subtask 6 - Pumping Test
WampC will conduct a single constant discharge pumping test to evaluate hydraulic properties of the
aquifer It is anticipated that the test will be conducted in a new pumping well in the vicinity of the
existing MW-2 well cluster within the source area Data from the pumping test will be used in
conjunction with other data from the investigation to improve the understanding of groundwater
movement and contaminant transport in the Source and Non-Source areas The results of the pumping
test will be used to refine the Site conceptual model as well as in the design of the hydraulic containment
system that is being constructed under the authority of the AOC for the RD
The groundwater pumping test will include the following components (1) Pumping test setup (2) Pretest
monitoring (3) Constant Discharge Pumping Test (4) Post-test monitoring and (5) Data Analysis
Pumping Test Setup In support of the groundwater pumping test WampC will install a pumping well
(PW-207) and procure and install the required groundwater extraction treatment and storage equipment at
the Site The well will be cored and over drilled to allow construction of a 4-inch well The location will
be in the vicinity of the MW-2 well cluster and be based upon results of the angled bedrock boring AWshy
202 The equipment will include but not be limited to
bull Down well pump plumbing and appurtances
bull Two (2) 20000 frac tanks
bull Groundwater transfer pumps and controls
bull Settlingaerationsand filtration treatment processes for the treatment of inorganics (if needed) and
nsow WOODARD amp CURRAN 16 September 302003 20564309
bull Granular activated carbon units for the treatment of dissolved organics in the groundwater
The groundwater treatment process will include the following processes 1) an oxidation and filtration
step to remove the inorganics from the groundwater and GAC units to treat the organic contaminants in
the extracted groundwater
Pretest Monitoring Prior to initiation of pumping WampC will monitor water levels in existing wells and
newly installed borings adjacent to the pumping well using a combination of hand measurements and data
loggers to develop an understanding of the piezometric surface under unstressed conditions The wells
proposed for water-level monitoring will be described in the work plan In addition all gauges
transducers flow meters and other equipment used in conducting the pumping tests shall be calibrated
before use
Constant Discharge Pumping Test The pumping test will be conducted in the source area using
newly-installed pumping well PW-207 It is anticipated that the test will be conducted at a pumping rate
of approximately 2 gallons per minute (gpm) for a period of 2 to 3 days however a higher or lower rate
may be shown to be appropriate based on the drilling and packer testing conducted during boring
installation Woodard amp Curran proposes to conduct this test using a vacuum-enhanced recovery system
(VERS) as described in the ROD so that the water level is not lowered appreciably in the vicinity of the
pumping well to prevent the potential migration of NAPLs to deeper bedrock zones The appropriateness
and feasibility of the VERS for the pumping test will be determined by field testing or literature
evaluation prior to completion of the Work Plan Because of the short duration of this test it is not
anticipated that stability of water levels will be reached in observation wells The test will however
provide information to estimate hydraulic conductivity and bedrock storage During the test the water
levels in the pumping well and selected monitoring wells will be logged continuously via down well data
loggers It is anticipated that water levels in approximately 24 wells will be measured using hand
measurements and data loggers
Groundwater extracted during the pumping test will be stored temporarily in an on-site frac tank prior to
on-site treatment and disposal
TISOW WOODARD amp CURRAN 17 September 302003 20564309
Post-Test Monitoring After the pump is turned off in the pumping well water levels will continue to be
monitored using hand measurements and data loggers until they have returned to within 10 of the preshy
test levels For planning purposes this has been estimated to be two weeks
Data Analysis Data collected during the pumping test will be analyzed with Aquifer Win32 Results of
the pumping test will be summarized in the summary data package for the TI Evaluation and the results
will also be used in the design of the hydraulic containment system specified in the Interim ROD that is
being conducted under the authority of the AOC for the RD Detail regarding use of the pumping test
data in hydraulic system design will be provided in the Remedial Design Work Plan
Subtask 7 - Tracer Test
WampC will conduct a tracer test using a conservative tracer to evaluate fracture connectivity porosity
dispersivity and matrix diffusion of the bedrock aquifer in both the Source Area and Non-Source Area
To increase the potential for success of this test results of the pumping test evaluation will be used to
revise the tracer test plan proposed here as necessary Following rebound of water levels after
completion of the pumping test WampC will initiate a single natural gradient tracer test The test will
consist of injecting a tracer into well PW-207 in the source area (Figure 3-1) for up to five days and
monitoring the tracers arrival in nearby wells Borehole geophysics core evaluation and packer testing
will be used to select the specific injection depth(s) in the well
A Tracer Test Work Plan will be completed prior to initiation of injection to determine the type quantity
and concentration of tracer based on the distance between the injection well and the monitoring wells A
conservative tracer that is one that is not preferentially adsorbed to rock or organic matter will be
selected for the tracer test Tracer injection equipment including tanks and flow-regulating and metering
equipment and pumps will be used to mix the tracer at the surface prior to injection Fractures may be
packered in the injection well and tracer solution will be injected at a rate determined during preparation
of the Tracer Test Work Plan During injection the potentiometric surface of the aquifer will be
monitored to verify that the potentiometric surface remains relatively constant during the injection
process
nsow WOODARD amp CURRAN 18 September 302003 20564309
Prior to injection of the tracer background concentration will be established by collecting samples from
up to six wells in the area of the tracer test and analyzing them for the tracer using an appropriate
analytical method Following injection of the tracer solutions the concentration of the tracer in
downgradient wells and borings will be measured A monitoring network will be established using nearby
monitoring wells Downhole probes will be installed in six new and existing wells near the injection well
to be identified in the work plan first to determine the background tracer concentrations and then to
monitor for the presence of the tracer upon initiation of the test Measurements will be collected at
periodic intervals to be determined based on the results of packer testing If an increase in tracer
concentration is detected or at a minimum on a weekly basis a water sample will be collected using low
flow sampling methodologies and analyzed in an off-site laboratory to evaluate the concentration of the
tracer The concentration of the tracer will be recorded Monitoring of the tracer concentration will
continue throughout the duration of the test The tracer will be allowed to flow with groundwater for one
month or until detected in wells in the vicinity of MW-106 whichever is shorter
313 Task 3 - TI Evaluation and Reporting
The TI Evaluation and reporting task includes the following five subtasks
bull Data evaluation
bull Summary data package
bull Draft TI Evaluation
bull Meetings with PRP Group and USEPA and
bull Revise and finalize TI Evaluation
As the subtasks of the field investigation are completed the data will be evaluated for the purpose of
addressing the data gaps identified by USEPA Specifically the data will be used to further refine the
cleanup times for non-source area groundwater presented in the Interim ROD
The data obtained during the field investigation will be reduced and evaluated and a summary data
package will be prepared that will include a discussion of the field activities completed and presentation
of the data It is anticipated that up to two meetings with USEPA will be necessary before the data
evaluation and summary report are completed
TISOW WOODARDampCURRAN 19 September 302003 20564309
Data collected during the pumping test will be analyzed with Aquifer Win32 Results will be summarized
in the summary data package and will also be presented as part of the RD submittals
Following submittal of the summary data package the TI evaluation will be prepared In accordance with
EPA guidance (1993) the TI waiver evaluation document will address the following topics
1 Specific ARARS or media cleanup standards for which TI determination is sought This section of the
TI Evaluation will identify the specific contaminants for which the TI determination is sought Based on
information available to date a waiver may be appropriate for pesticides PCBs chlorinated organic
compounds and other site-related contaminants that upon evaluation will not attain ARARs in a
reasonable period of time
2 Spatial area over which the TI waiver will apply The purpose of the additional site investigation
outlined in this SOW is to obtain the data necessary to further refine cleanup times presented in the
Interim ROD to determine what portions of the Site will not be expected to reach ARARs within a
reasonable time Consistent with TI guidance (USEPA 1993) the TI evaluation will specify the
horizontal and vertical extent of the area for which TI determination is sought Groundwater
concentration data from the RI and the TI SOW will be used to refine the distribution of the plume Data
from the drilling geophysical logging packer testing and pumping and tracer tests will be used to refine
the Site conceptual model and the cleanup times that will serve as the basis for establishing the scope and
nature of the TI zone
3 Conceptual Model The conceptual model forms the technical core of the TI Waiver Evaluation since
it provides basis for understanding of the restoration potential of the site The conceptual model outlines
the physical and hydrogeological constraints that hinder remediation or removal of Site contaminants and
it is the extent of these constraints rather than restoration timeframe alone that USEPA will use to
evaluate the necessity of the TI waiver of ARARs The conceptual model is the link between restoration
potential and restoration timeframe since it explains why proposed technologies are unlikely to work
either at all or within the desired 100-year timeframe
The Site conceptual model is not a mathematical model however as the result of the extensive modeling
and investigations of the site WampC has a strong understanding of the complex bedrock and overburden
TISOW WOODARDampCURRAN 20 September 302003 20564309
groundwater system beneath this site This understanding has been presented previously in both the RI
report and the FS and will be refined based on the TI SOW as necessary and summarized in the TI
Waiver Evaluation with specific attention to the physical and hydrogeological constraints on remediation
In particular the Site conceptual model will be reviewed in light of the new geologic data from drilling
logging and packer testing and the new hydrogeologic data obtained from the pumping test and tracer test
and will be revised to incorporate the new understanding
4 An evaluation of the restoration potential of the site This section will consist of a several components
It will present a systematic review of the technologies potentially capable of remediating the site given
the physical and hydrogeological constraints identified in the site model The newly acquired data will
provide an improved understanding of bedrock hydraulic properties that will allow a more Site-specific
evaluation of technologies The review of technologies will also include review of innovative
technologies and will evaluate whether existing remedial technologies or strategies would be capable of
achieving groundwater restoration at the site in a reasonable timeframe The section reference the FS and
will summarize the alternative remedies considered in the FS focusing on the ability of each to restore
groundwater in a reasonable timeframe It will also include a discussion of the selected hydraulic
containment system in light of the data gathered from the pumping test conducted in conjunction with the
TI SOW
Based on the Batch Flushing Model and using the agreed upon koc data from the RI as well as data from
this TI SOW including the f data collected as part of Subtask 4 a restoration timeframe analysis will be
conducted Following completion of the timeframe analysis and consideration of the results of drilling
rock and water analyses and pumping and tracer test a determination will be made regarding the Source
Area and the portion of the Non-Source Area VOC plume that will not attain ARARs in a reasonable
time
TISOW WOODARD amp CURRAN 21 September 302003 20564309
40 SCHEDULE
A proposed project schedule is included with this plan as Figure 4-1 This schedule is included for
discussion purposes and will be modified as necessary once the final scope of work as been approved by
all parties and the field work activities are coordinated with the subcontractors
TISOW WOODARD amp CURRAN 22 September 302003 20564309
ID
2
3
4
5
6
7 a i 10
11
12
13
14
15
16
17
16
19
20
21
22
24
25
26
27
26
29
30
31
32
Task Name
Project Meeting with EPA
Finalize SOW
Prepare Work Plans QAPP HASP Revision
Submit Work Plans for EPA Approval
Project Meeting with EPA
Revisions to work plans
Submit final work plans
Subcontractor Contracts
Project Meeting wEPA
Field Investigation
Site Mobilization
Install Borings
Borehole Geophysics
Packer Testing amp Collect GW Samples
Pumping Test
Tracer Test
Test setup
Injection
Monitoring
Data Reporting
InstallDevelop Wells
Data Evaluation
Prepare Data Package
Data Package Submittal to EPA
Draft Tl Evaluation Repon
Draft Tl Evaluation Report Submttal to EPA
EPA ReviewComment on Tl Evaluation ReF
Project Meeting wEPA
Revisions to Tl Evaluation Report
Submit Final Tl Evaluation Report
Start
Wed 070903
Thu 071003
Fri 101003
Mon 120103
Mon 121503
Mon 122903
Mon 011204
Tue 011304
Thu 021904
Fri 032104
Fri 032604
Fri 040204
Fri 041604
Fri 042304
Thu 050604
Wed 060204
Wed 060204
Wed 060904
Wed 060904
Wed 062304
Wed 070704
Wed 042804
Wed 062304
Mon 080204
Mon 070504
Tue 082404
Wed 082504
Wed 091504
Thu 0916AM
Thu 093004
Finish
Wed 070903
Fri 1OtO7u3
Fri 112803
Fri 122603
Mon 121503
Fri 010904
Mon 011204
Mon 012604
Thu 021904
Tue 071304
Thu 040104
Thu 042204
Tue 042704
Wed 050504
Tue 052504
Tue 071304
Tue 060804
Tue 061504
Tue 070604
Tue 071304
Fri 070904
Tue 072004
Fri 073004
Mon 080204
Mon 082304
Tue 082404
Tue 091404
Wed 091504
Wed 082904
Thu 093004
FIGURE 4-1 DRAFT HOWS CORNER SUPERFUND SITE
Tl EVALUATION amp RELD WORK FOR HYDRAUUC CONTAINMENT SYSTEM DESIGN PROPOSED PROJECT SCHEDULE
2003 2004 Mav |
Jun | Jul
ltamp i
Aug
i
Sen Oct I Nov Dec Jan Feb I Mar
ii i i
k ^tr 1
1V i
I t bull ^
I
ta^M bull bull M W
l LgtH^HBKLii LJ Mi
I
bull bull raquo bull laquo^ 0930
Task Progress I^MLHHHI^LB Summary ^^^^^^^^f External Tasks M B WMMM Deadline ^7 Project Hows Comer Schedule6A bull bull bull 1 UData Fri 101003 Split Milestone ^ Project Summary ^f^KKKKKK^^ External Milestone ^
Pagei
50 ACRONYMS
AOC Administrative Order by Consent
ARARs Applicable or Relevant and Appropriate Requirements
ATV acoustic televiewer
bgs below ground surface
CERCLA Comprehensive Environmental Resource and Conservation Liability Act
DNAPL Dense Non-Aqueous Phase Liquid
GAC granular activated carbon
gpm gallons per minute
HASP Health and Safety Plan
row investigation-derived waste
MCL Maximum Containment Level
MEDEP Maine Department of Environmental Protection
MEG Maine Enforcement Guideline
mgkg milligrams per kilogram
Hg kg micrograms per kilogram
NCP National Contingency Plan
PCB polychlorinated biphenyl
PID photo ionization detector
ppm parts per million
PRP Potentially Responsible Party
TISOW WOODARD amp CURRAN 24 September 302003 20564309
QAPP Quality Assurance Project Plan
QAQC Quality AssuranceQuality Control
RA Remedial Action
RAO Remedial Action Objective
RCRA Resource Conservation and Recovery Act
RD Remedial Design
RIFS Remedial InvestigationFeasibility Study
ROD Record of Decision
SAP Sampling and Analysis Plan
SOW Statement of Work
TAL target analyte list
TI Technical Impracticability
USEPA United State Environmental Protection Agency
VOCs volatile organic compounds
WampC Woodard amp Curran Inc
TISOW WOODARD amp CURRAN 25 September 302003 20564309
REFERENCES
Everts CJ RS Kanwar (1994) Evaluation of Rhodamine WT as an adsorbed tracer in an agricultural
soil J Hydrology 153 53-70
Kasnavia T D Vu DA Sabatini (1999) Fluorescent dye and media properties affecting sorption and
tracer selection Groundwater 37 376-381
Ptak T G Schmid (1996) Dual-tracer transport experiments in a physically and chemically
heterogeneous porous aquifer effective transport parameters and spatial variability J Hydrology
183 117-138
Sabatini DA T A Austin (1991) Characteristics of Rhodamine WT and fluorescein as adsorbing
ground-water tracers Ground Water 29 341-349
Trudgill ST (1987) Soil water dye tracing with special reference to the use of Rhodamanie WT
Lissamine FF and Amino G acid Hydrological Processes 1 149-170
US Environmental Protection Agency (USEPA) 1993 Guidance for Evaluating the Technical
Impracticability of Ground-Water Restoration - Interim Final Office of Solid Waste and
Emergency Response Washington DC Directive 92342-25 September 1993
US Environmental Protection Agency (USEPA) 2002 Interim Record of Decision Summary shy
Operable Unit One Non-Source Area Groundwater West SiteHows Corner Superfund Site
Plymouth Maine EPA Region 1 September 2002
US Environmental Protection Agency (USEPA) 2003 Proposed Scope of Work West SiteHows
Corner Superfund Site Plymouth Maine EPA Region 1 4 pages September 2002
Vasudevan D RL Fimmen AB Francisco (2001) Tracer-grade Rhodamine WT Structure of
constituent isomers and their sorption behavior Environ Sci Technol 35 4089-4096
nsow WOODARD amp CURRAN 26 September 30 2003 20564309
Woodard amp Curran Inc (WampC) 2002 Final Feasibility Study Report - Non-Source Area Groundwater
Hows Comer Superfund Site Plymouth Maine July 2002
TISOW WOODARD amp CURRAN 27 September 302003 20564309
f
m WOODARD amp CURRAN Maine Massachusetts New Hampshire Connecticut Florida Illinois Operational offices across the US 1-800-426-4262 wwwwoodardcurrancom
i
bull
m
M
Drilling observations and information from borehole geophysics will be used to identify specific fractures
below the water table that are capable of transmitting water Prior to water injection for hydraulic
conductivity and fracture connectivity testing groundwater samples will be collected at selected intervals
for analysis of VOCs (See Subtask 4) Sampling intervals will be selected based on drilling observations
and logging results that indicate water is moving into or out of the borehole or that fractures exist to
promote water movement such as rapid increase in the amount of water returned rapid change in
temperature or highly fractured interval
^
^
bull
f$
Double packer testing will be performed at selected intervals within each newly installed boring It is
anticipated that up to six intervals per well will be tested for a maximum of 24 intervals and that for each
interval the test will include an approximate 15-minute injection of potable water at four progressively
increasing pressures Packer spacing is anticipated to be 10 ft however spacing may vary so that packers
are not located in potential fracture zones identified using information from rock cores drilling
observations and borehole geophysics The tests at an individual interval will be terminated if it appears
that the interval is not accepting water Care will be taken to minimize over-pumping or over-
pressurizing of the fractures The flow rate will be measured to evaluate the characteristics of the
fracture Water levels in adjacent borings will be measured during the packer testing to determine if a
hydraulic connection exists between the borings Water generated during packer testing will be
containerized on site and treated through GAC Treated water will be analyzed to verify that PCB and
VOC concentrations have been reduced to below ARARs prior to discharge to the ground surface
4 Subtask 4 Sampling and Analysis
~d
^
Rock and groundwater samples will be collected during the field program for laboratory analysis The
results of the analyses will be used to help refine the distribution of the plume and to estimate bedrock
properties These analyses will be used in conjunction with existing data during the TI evaluation to
refine cleanup times and establish the limits of the TI zone
As described in Subtask 1 it is anticipated that up to 10 core samples from each cored boring (total of 20
core samples) will be collected and submitted to an off-site laboratory for analyses of porosity (matrix and
bulk) permeability bulk density and fraction of organic carbon (f^) using existing industry methods
Subject to further evaluation of industry methods Woodard amp Curran proposes that porosity
TISOW WOODARD amp CURRAN20564309
14 September 302003
permeability and density will be measured using methods in the American Petroleum Institutes API RPshy
40 Fraction of organic carbon (f^) will be measured using either the LECO TOC method or Walkey-
Black method The LECO TOC method is a standard method in the petroleum industry and involves the
direct combustion of a ground rock sample The Walkey-Black method is a commonly used USEPA-
approved chemical oxidation method for determination of foe in soils In addition either method could be
used if a sample were scraped from a fracture surface To develop a reasonable range of f for Site
bedrock up to five samples will be selected from each boring from the unfractured matrix and up to five
from the fracture surfaces In addition Woodard amp Curran will evaluate the appropriateness of selecting
rock samples from a subset of the core samples from areas near fractures as well as from non-fractured
areas and submitting the samples for VOC analysis following methanol extraction
Results from these analyses will be used in conjunction with groundwater contaminant concentrations to
evaluate the significance of diffusion of contamination from the bedrock matrix in both the Source Area
and the Non-Source Area Although matrix diffusion likely is a significant factor in the determination of
cleanup times within the Source Area the potential applicability of matrix diffusion in the Non-Source
Area is not known These core analyses may provide evidence to assist in developing an estimate
through calculations of the effect of matrix diffusion on cleanup times
As noted in Subtask 3 prior to injection of water during packer testing groundwater samples will be
collected at selected intervals for analysis of volatile organic compounds (VOCs) Up to a total of 20
groundwater samples plus appropriate quality control samples will be collected from the newly installed
borings The samples will be submitted to an off-site laboratory for analysis Analytical results will be
validated in accordance with USEPA protocol and the data will be managed in WampCs existing
groundwater sampling analytical database for this site
Up to 21 existing monitoring wells from within or nearby the 17-acre property plus four new wells once
constructed will be sampled using low-flow techniques and submitted to an off-site laboratory for VOC
analysis Analytical results will be validated in accordance with USEPA protocol and the data will be
managed in WampCs existing groundwater sampling analytical database for this site
TISOW WOODARD amp CURRAN 15 September 302003 20564309
Subtask 5 - Monitoring Well Installation
Although it is anticipated that the newly installed borings will be left as open holes for tracer testing and
for pumping tests monitoring wells will be installed and developed in the newly installed borings unless
the USEPA MEDEP and PRP Group determine that the location is inappropriate for such use The
monitoring wells will be constructed of two-inch schedule 40 PVC screen and riser Screen intervals will
be selected based on the location of fractures identified during drilling geophysical logging and packer
testing A sand pack will be placed around the screen and will extend from approximately two ft below
the screen to approximately two ft above the screen
Subtask 6 - Pumping Test
WampC will conduct a single constant discharge pumping test to evaluate hydraulic properties of the
aquifer It is anticipated that the test will be conducted in a new pumping well in the vicinity of the
existing MW-2 well cluster within the source area Data from the pumping test will be used in
conjunction with other data from the investigation to improve the understanding of groundwater
movement and contaminant transport in the Source and Non-Source areas The results of the pumping
test will be used to refine the Site conceptual model as well as in the design of the hydraulic containment
system that is being constructed under the authority of the AOC for the RD
The groundwater pumping test will include the following components (1) Pumping test setup (2) Pretest
monitoring (3) Constant Discharge Pumping Test (4) Post-test monitoring and (5) Data Analysis
Pumping Test Setup In support of the groundwater pumping test WampC will install a pumping well
(PW-207) and procure and install the required groundwater extraction treatment and storage equipment at
the Site The well will be cored and over drilled to allow construction of a 4-inch well The location will
be in the vicinity of the MW-2 well cluster and be based upon results of the angled bedrock boring AWshy
202 The equipment will include but not be limited to
bull Down well pump plumbing and appurtances
bull Two (2) 20000 frac tanks
bull Groundwater transfer pumps and controls
bull Settlingaerationsand filtration treatment processes for the treatment of inorganics (if needed) and
nsow WOODARD amp CURRAN 16 September 302003 20564309
bull Granular activated carbon units for the treatment of dissolved organics in the groundwater
The groundwater treatment process will include the following processes 1) an oxidation and filtration
step to remove the inorganics from the groundwater and GAC units to treat the organic contaminants in
the extracted groundwater
Pretest Monitoring Prior to initiation of pumping WampC will monitor water levels in existing wells and
newly installed borings adjacent to the pumping well using a combination of hand measurements and data
loggers to develop an understanding of the piezometric surface under unstressed conditions The wells
proposed for water-level monitoring will be described in the work plan In addition all gauges
transducers flow meters and other equipment used in conducting the pumping tests shall be calibrated
before use
Constant Discharge Pumping Test The pumping test will be conducted in the source area using
newly-installed pumping well PW-207 It is anticipated that the test will be conducted at a pumping rate
of approximately 2 gallons per minute (gpm) for a period of 2 to 3 days however a higher or lower rate
may be shown to be appropriate based on the drilling and packer testing conducted during boring
installation Woodard amp Curran proposes to conduct this test using a vacuum-enhanced recovery system
(VERS) as described in the ROD so that the water level is not lowered appreciably in the vicinity of the
pumping well to prevent the potential migration of NAPLs to deeper bedrock zones The appropriateness
and feasibility of the VERS for the pumping test will be determined by field testing or literature
evaluation prior to completion of the Work Plan Because of the short duration of this test it is not
anticipated that stability of water levels will be reached in observation wells The test will however
provide information to estimate hydraulic conductivity and bedrock storage During the test the water
levels in the pumping well and selected monitoring wells will be logged continuously via down well data
loggers It is anticipated that water levels in approximately 24 wells will be measured using hand
measurements and data loggers
Groundwater extracted during the pumping test will be stored temporarily in an on-site frac tank prior to
on-site treatment and disposal
TISOW WOODARD amp CURRAN 17 September 302003 20564309
Post-Test Monitoring After the pump is turned off in the pumping well water levels will continue to be
monitored using hand measurements and data loggers until they have returned to within 10 of the preshy
test levels For planning purposes this has been estimated to be two weeks
Data Analysis Data collected during the pumping test will be analyzed with Aquifer Win32 Results of
the pumping test will be summarized in the summary data package for the TI Evaluation and the results
will also be used in the design of the hydraulic containment system specified in the Interim ROD that is
being conducted under the authority of the AOC for the RD Detail regarding use of the pumping test
data in hydraulic system design will be provided in the Remedial Design Work Plan
Subtask 7 - Tracer Test
WampC will conduct a tracer test using a conservative tracer to evaluate fracture connectivity porosity
dispersivity and matrix diffusion of the bedrock aquifer in both the Source Area and Non-Source Area
To increase the potential for success of this test results of the pumping test evaluation will be used to
revise the tracer test plan proposed here as necessary Following rebound of water levels after
completion of the pumping test WampC will initiate a single natural gradient tracer test The test will
consist of injecting a tracer into well PW-207 in the source area (Figure 3-1) for up to five days and
monitoring the tracers arrival in nearby wells Borehole geophysics core evaluation and packer testing
will be used to select the specific injection depth(s) in the well
A Tracer Test Work Plan will be completed prior to initiation of injection to determine the type quantity
and concentration of tracer based on the distance between the injection well and the monitoring wells A
conservative tracer that is one that is not preferentially adsorbed to rock or organic matter will be
selected for the tracer test Tracer injection equipment including tanks and flow-regulating and metering
equipment and pumps will be used to mix the tracer at the surface prior to injection Fractures may be
packered in the injection well and tracer solution will be injected at a rate determined during preparation
of the Tracer Test Work Plan During injection the potentiometric surface of the aquifer will be
monitored to verify that the potentiometric surface remains relatively constant during the injection
process
nsow WOODARD amp CURRAN 18 September 302003 20564309
Prior to injection of the tracer background concentration will be established by collecting samples from
up to six wells in the area of the tracer test and analyzing them for the tracer using an appropriate
analytical method Following injection of the tracer solutions the concentration of the tracer in
downgradient wells and borings will be measured A monitoring network will be established using nearby
monitoring wells Downhole probes will be installed in six new and existing wells near the injection well
to be identified in the work plan first to determine the background tracer concentrations and then to
monitor for the presence of the tracer upon initiation of the test Measurements will be collected at
periodic intervals to be determined based on the results of packer testing If an increase in tracer
concentration is detected or at a minimum on a weekly basis a water sample will be collected using low
flow sampling methodologies and analyzed in an off-site laboratory to evaluate the concentration of the
tracer The concentration of the tracer will be recorded Monitoring of the tracer concentration will
continue throughout the duration of the test The tracer will be allowed to flow with groundwater for one
month or until detected in wells in the vicinity of MW-106 whichever is shorter
313 Task 3 - TI Evaluation and Reporting
The TI Evaluation and reporting task includes the following five subtasks
bull Data evaluation
bull Summary data package
bull Draft TI Evaluation
bull Meetings with PRP Group and USEPA and
bull Revise and finalize TI Evaluation
As the subtasks of the field investigation are completed the data will be evaluated for the purpose of
addressing the data gaps identified by USEPA Specifically the data will be used to further refine the
cleanup times for non-source area groundwater presented in the Interim ROD
The data obtained during the field investigation will be reduced and evaluated and a summary data
package will be prepared that will include a discussion of the field activities completed and presentation
of the data It is anticipated that up to two meetings with USEPA will be necessary before the data
evaluation and summary report are completed
TISOW WOODARDampCURRAN 19 September 302003 20564309
Data collected during the pumping test will be analyzed with Aquifer Win32 Results will be summarized
in the summary data package and will also be presented as part of the RD submittals
Following submittal of the summary data package the TI evaluation will be prepared In accordance with
EPA guidance (1993) the TI waiver evaluation document will address the following topics
1 Specific ARARS or media cleanup standards for which TI determination is sought This section of the
TI Evaluation will identify the specific contaminants for which the TI determination is sought Based on
information available to date a waiver may be appropriate for pesticides PCBs chlorinated organic
compounds and other site-related contaminants that upon evaluation will not attain ARARs in a
reasonable period of time
2 Spatial area over which the TI waiver will apply The purpose of the additional site investigation
outlined in this SOW is to obtain the data necessary to further refine cleanup times presented in the
Interim ROD to determine what portions of the Site will not be expected to reach ARARs within a
reasonable time Consistent with TI guidance (USEPA 1993) the TI evaluation will specify the
horizontal and vertical extent of the area for which TI determination is sought Groundwater
concentration data from the RI and the TI SOW will be used to refine the distribution of the plume Data
from the drilling geophysical logging packer testing and pumping and tracer tests will be used to refine
the Site conceptual model and the cleanup times that will serve as the basis for establishing the scope and
nature of the TI zone
3 Conceptual Model The conceptual model forms the technical core of the TI Waiver Evaluation since
it provides basis for understanding of the restoration potential of the site The conceptual model outlines
the physical and hydrogeological constraints that hinder remediation or removal of Site contaminants and
it is the extent of these constraints rather than restoration timeframe alone that USEPA will use to
evaluate the necessity of the TI waiver of ARARs The conceptual model is the link between restoration
potential and restoration timeframe since it explains why proposed technologies are unlikely to work
either at all or within the desired 100-year timeframe
The Site conceptual model is not a mathematical model however as the result of the extensive modeling
and investigations of the site WampC has a strong understanding of the complex bedrock and overburden
TISOW WOODARDampCURRAN 20 September 302003 20564309
groundwater system beneath this site This understanding has been presented previously in both the RI
report and the FS and will be refined based on the TI SOW as necessary and summarized in the TI
Waiver Evaluation with specific attention to the physical and hydrogeological constraints on remediation
In particular the Site conceptual model will be reviewed in light of the new geologic data from drilling
logging and packer testing and the new hydrogeologic data obtained from the pumping test and tracer test
and will be revised to incorporate the new understanding
4 An evaluation of the restoration potential of the site This section will consist of a several components
It will present a systematic review of the technologies potentially capable of remediating the site given
the physical and hydrogeological constraints identified in the site model The newly acquired data will
provide an improved understanding of bedrock hydraulic properties that will allow a more Site-specific
evaluation of technologies The review of technologies will also include review of innovative
technologies and will evaluate whether existing remedial technologies or strategies would be capable of
achieving groundwater restoration at the site in a reasonable timeframe The section reference the FS and
will summarize the alternative remedies considered in the FS focusing on the ability of each to restore
groundwater in a reasonable timeframe It will also include a discussion of the selected hydraulic
containment system in light of the data gathered from the pumping test conducted in conjunction with the
TI SOW
Based on the Batch Flushing Model and using the agreed upon koc data from the RI as well as data from
this TI SOW including the f data collected as part of Subtask 4 a restoration timeframe analysis will be
conducted Following completion of the timeframe analysis and consideration of the results of drilling
rock and water analyses and pumping and tracer test a determination will be made regarding the Source
Area and the portion of the Non-Source Area VOC plume that will not attain ARARs in a reasonable
time
TISOW WOODARD amp CURRAN 21 September 302003 20564309
40 SCHEDULE
A proposed project schedule is included with this plan as Figure 4-1 This schedule is included for
discussion purposes and will be modified as necessary once the final scope of work as been approved by
all parties and the field work activities are coordinated with the subcontractors
TISOW WOODARD amp CURRAN 22 September 302003 20564309
ID
2
3
4
5
6
7 a i 10
11
12
13
14
15
16
17
16
19
20
21
22
24
25
26
27
26
29
30
31
32
Task Name
Project Meeting with EPA
Finalize SOW
Prepare Work Plans QAPP HASP Revision
Submit Work Plans for EPA Approval
Project Meeting with EPA
Revisions to work plans
Submit final work plans
Subcontractor Contracts
Project Meeting wEPA
Field Investigation
Site Mobilization
Install Borings
Borehole Geophysics
Packer Testing amp Collect GW Samples
Pumping Test
Tracer Test
Test setup
Injection
Monitoring
Data Reporting
InstallDevelop Wells
Data Evaluation
Prepare Data Package
Data Package Submittal to EPA
Draft Tl Evaluation Repon
Draft Tl Evaluation Report Submttal to EPA
EPA ReviewComment on Tl Evaluation ReF
Project Meeting wEPA
Revisions to Tl Evaluation Report
Submit Final Tl Evaluation Report
Start
Wed 070903
Thu 071003
Fri 101003
Mon 120103
Mon 121503
Mon 122903
Mon 011204
Tue 011304
Thu 021904
Fri 032104
Fri 032604
Fri 040204
Fri 041604
Fri 042304
Thu 050604
Wed 060204
Wed 060204
Wed 060904
Wed 060904
Wed 062304
Wed 070704
Wed 042804
Wed 062304
Mon 080204
Mon 070504
Tue 082404
Wed 082504
Wed 091504
Thu 0916AM
Thu 093004
Finish
Wed 070903
Fri 1OtO7u3
Fri 112803
Fri 122603
Mon 121503
Fri 010904
Mon 011204
Mon 012604
Thu 021904
Tue 071304
Thu 040104
Thu 042204
Tue 042704
Wed 050504
Tue 052504
Tue 071304
Tue 060804
Tue 061504
Tue 070604
Tue 071304
Fri 070904
Tue 072004
Fri 073004
Mon 080204
Mon 082304
Tue 082404
Tue 091404
Wed 091504
Wed 082904
Thu 093004
FIGURE 4-1 DRAFT HOWS CORNER SUPERFUND SITE
Tl EVALUATION amp RELD WORK FOR HYDRAUUC CONTAINMENT SYSTEM DESIGN PROPOSED PROJECT SCHEDULE
2003 2004 Mav |
Jun | Jul
ltamp i
Aug
i
Sen Oct I Nov Dec Jan Feb I Mar
ii i i
k ^tr 1
1V i
I t bull ^
I
ta^M bull bull M W
l LgtH^HBKLii LJ Mi
I
bull bull raquo bull laquo^ 0930
Task Progress I^MLHHHI^LB Summary ^^^^^^^^f External Tasks M B WMMM Deadline ^7 Project Hows Comer Schedule6A bull bull bull 1 UData Fri 101003 Split Milestone ^ Project Summary ^f^KKKKKK^^ External Milestone ^
Pagei
50 ACRONYMS
AOC Administrative Order by Consent
ARARs Applicable or Relevant and Appropriate Requirements
ATV acoustic televiewer
bgs below ground surface
CERCLA Comprehensive Environmental Resource and Conservation Liability Act
DNAPL Dense Non-Aqueous Phase Liquid
GAC granular activated carbon
gpm gallons per minute
HASP Health and Safety Plan
row investigation-derived waste
MCL Maximum Containment Level
MEDEP Maine Department of Environmental Protection
MEG Maine Enforcement Guideline
mgkg milligrams per kilogram
Hg kg micrograms per kilogram
NCP National Contingency Plan
PCB polychlorinated biphenyl
PID photo ionization detector
ppm parts per million
PRP Potentially Responsible Party
TISOW WOODARD amp CURRAN 24 September 302003 20564309
QAPP Quality Assurance Project Plan
QAQC Quality AssuranceQuality Control
RA Remedial Action
RAO Remedial Action Objective
RCRA Resource Conservation and Recovery Act
RD Remedial Design
RIFS Remedial InvestigationFeasibility Study
ROD Record of Decision
SAP Sampling and Analysis Plan
SOW Statement of Work
TAL target analyte list
TI Technical Impracticability
USEPA United State Environmental Protection Agency
VOCs volatile organic compounds
WampC Woodard amp Curran Inc
TISOW WOODARD amp CURRAN 25 September 302003 20564309
REFERENCES
Everts CJ RS Kanwar (1994) Evaluation of Rhodamine WT as an adsorbed tracer in an agricultural
soil J Hydrology 153 53-70
Kasnavia T D Vu DA Sabatini (1999) Fluorescent dye and media properties affecting sorption and
tracer selection Groundwater 37 376-381
Ptak T G Schmid (1996) Dual-tracer transport experiments in a physically and chemically
heterogeneous porous aquifer effective transport parameters and spatial variability J Hydrology
183 117-138
Sabatini DA T A Austin (1991) Characteristics of Rhodamine WT and fluorescein as adsorbing
ground-water tracers Ground Water 29 341-349
Trudgill ST (1987) Soil water dye tracing with special reference to the use of Rhodamanie WT
Lissamine FF and Amino G acid Hydrological Processes 1 149-170
US Environmental Protection Agency (USEPA) 1993 Guidance for Evaluating the Technical
Impracticability of Ground-Water Restoration - Interim Final Office of Solid Waste and
Emergency Response Washington DC Directive 92342-25 September 1993
US Environmental Protection Agency (USEPA) 2002 Interim Record of Decision Summary shy
Operable Unit One Non-Source Area Groundwater West SiteHows Corner Superfund Site
Plymouth Maine EPA Region 1 September 2002
US Environmental Protection Agency (USEPA) 2003 Proposed Scope of Work West SiteHows
Corner Superfund Site Plymouth Maine EPA Region 1 4 pages September 2002
Vasudevan D RL Fimmen AB Francisco (2001) Tracer-grade Rhodamine WT Structure of
constituent isomers and their sorption behavior Environ Sci Technol 35 4089-4096
nsow WOODARD amp CURRAN 26 September 30 2003 20564309
Woodard amp Curran Inc (WampC) 2002 Final Feasibility Study Report - Non-Source Area Groundwater
Hows Comer Superfund Site Plymouth Maine July 2002
TISOW WOODARD amp CURRAN 27 September 302003 20564309
f
m WOODARD amp CURRAN Maine Massachusetts New Hampshire Connecticut Florida Illinois Operational offices across the US 1-800-426-4262 wwwwoodardcurrancom
i
permeability and density will be measured using methods in the American Petroleum Institutes API RPshy
40 Fraction of organic carbon (f^) will be measured using either the LECO TOC method or Walkey-
Black method The LECO TOC method is a standard method in the petroleum industry and involves the
direct combustion of a ground rock sample The Walkey-Black method is a commonly used USEPA-
approved chemical oxidation method for determination of foe in soils In addition either method could be
used if a sample were scraped from a fracture surface To develop a reasonable range of f for Site
bedrock up to five samples will be selected from each boring from the unfractured matrix and up to five
from the fracture surfaces In addition Woodard amp Curran will evaluate the appropriateness of selecting
rock samples from a subset of the core samples from areas near fractures as well as from non-fractured
areas and submitting the samples for VOC analysis following methanol extraction
Results from these analyses will be used in conjunction with groundwater contaminant concentrations to
evaluate the significance of diffusion of contamination from the bedrock matrix in both the Source Area
and the Non-Source Area Although matrix diffusion likely is a significant factor in the determination of
cleanup times within the Source Area the potential applicability of matrix diffusion in the Non-Source
Area is not known These core analyses may provide evidence to assist in developing an estimate
through calculations of the effect of matrix diffusion on cleanup times
As noted in Subtask 3 prior to injection of water during packer testing groundwater samples will be
collected at selected intervals for analysis of volatile organic compounds (VOCs) Up to a total of 20
groundwater samples plus appropriate quality control samples will be collected from the newly installed
borings The samples will be submitted to an off-site laboratory for analysis Analytical results will be
validated in accordance with USEPA protocol and the data will be managed in WampCs existing
groundwater sampling analytical database for this site
Up to 21 existing monitoring wells from within or nearby the 17-acre property plus four new wells once
constructed will be sampled using low-flow techniques and submitted to an off-site laboratory for VOC
analysis Analytical results will be validated in accordance with USEPA protocol and the data will be
managed in WampCs existing groundwater sampling analytical database for this site
TISOW WOODARD amp CURRAN 15 September 302003 20564309
Subtask 5 - Monitoring Well Installation
Although it is anticipated that the newly installed borings will be left as open holes for tracer testing and
for pumping tests monitoring wells will be installed and developed in the newly installed borings unless
the USEPA MEDEP and PRP Group determine that the location is inappropriate for such use The
monitoring wells will be constructed of two-inch schedule 40 PVC screen and riser Screen intervals will
be selected based on the location of fractures identified during drilling geophysical logging and packer
testing A sand pack will be placed around the screen and will extend from approximately two ft below
the screen to approximately two ft above the screen
Subtask 6 - Pumping Test
WampC will conduct a single constant discharge pumping test to evaluate hydraulic properties of the
aquifer It is anticipated that the test will be conducted in a new pumping well in the vicinity of the
existing MW-2 well cluster within the source area Data from the pumping test will be used in
conjunction with other data from the investigation to improve the understanding of groundwater
movement and contaminant transport in the Source and Non-Source areas The results of the pumping
test will be used to refine the Site conceptual model as well as in the design of the hydraulic containment
system that is being constructed under the authority of the AOC for the RD
The groundwater pumping test will include the following components (1) Pumping test setup (2) Pretest
monitoring (3) Constant Discharge Pumping Test (4) Post-test monitoring and (5) Data Analysis
Pumping Test Setup In support of the groundwater pumping test WampC will install a pumping well
(PW-207) and procure and install the required groundwater extraction treatment and storage equipment at
the Site The well will be cored and over drilled to allow construction of a 4-inch well The location will
be in the vicinity of the MW-2 well cluster and be based upon results of the angled bedrock boring AWshy
202 The equipment will include but not be limited to
bull Down well pump plumbing and appurtances
bull Two (2) 20000 frac tanks
bull Groundwater transfer pumps and controls
bull Settlingaerationsand filtration treatment processes for the treatment of inorganics (if needed) and
nsow WOODARD amp CURRAN 16 September 302003 20564309
bull Granular activated carbon units for the treatment of dissolved organics in the groundwater
The groundwater treatment process will include the following processes 1) an oxidation and filtration
step to remove the inorganics from the groundwater and GAC units to treat the organic contaminants in
the extracted groundwater
Pretest Monitoring Prior to initiation of pumping WampC will monitor water levels in existing wells and
newly installed borings adjacent to the pumping well using a combination of hand measurements and data
loggers to develop an understanding of the piezometric surface under unstressed conditions The wells
proposed for water-level monitoring will be described in the work plan In addition all gauges
transducers flow meters and other equipment used in conducting the pumping tests shall be calibrated
before use
Constant Discharge Pumping Test The pumping test will be conducted in the source area using
newly-installed pumping well PW-207 It is anticipated that the test will be conducted at a pumping rate
of approximately 2 gallons per minute (gpm) for a period of 2 to 3 days however a higher or lower rate
may be shown to be appropriate based on the drilling and packer testing conducted during boring
installation Woodard amp Curran proposes to conduct this test using a vacuum-enhanced recovery system
(VERS) as described in the ROD so that the water level is not lowered appreciably in the vicinity of the
pumping well to prevent the potential migration of NAPLs to deeper bedrock zones The appropriateness
and feasibility of the VERS for the pumping test will be determined by field testing or literature
evaluation prior to completion of the Work Plan Because of the short duration of this test it is not
anticipated that stability of water levels will be reached in observation wells The test will however
provide information to estimate hydraulic conductivity and bedrock storage During the test the water
levels in the pumping well and selected monitoring wells will be logged continuously via down well data
loggers It is anticipated that water levels in approximately 24 wells will be measured using hand
measurements and data loggers
Groundwater extracted during the pumping test will be stored temporarily in an on-site frac tank prior to
on-site treatment and disposal
TISOW WOODARD amp CURRAN 17 September 302003 20564309
Post-Test Monitoring After the pump is turned off in the pumping well water levels will continue to be
monitored using hand measurements and data loggers until they have returned to within 10 of the preshy
test levels For planning purposes this has been estimated to be two weeks
Data Analysis Data collected during the pumping test will be analyzed with Aquifer Win32 Results of
the pumping test will be summarized in the summary data package for the TI Evaluation and the results
will also be used in the design of the hydraulic containment system specified in the Interim ROD that is
being conducted under the authority of the AOC for the RD Detail regarding use of the pumping test
data in hydraulic system design will be provided in the Remedial Design Work Plan
Subtask 7 - Tracer Test
WampC will conduct a tracer test using a conservative tracer to evaluate fracture connectivity porosity
dispersivity and matrix diffusion of the bedrock aquifer in both the Source Area and Non-Source Area
To increase the potential for success of this test results of the pumping test evaluation will be used to
revise the tracer test plan proposed here as necessary Following rebound of water levels after
completion of the pumping test WampC will initiate a single natural gradient tracer test The test will
consist of injecting a tracer into well PW-207 in the source area (Figure 3-1) for up to five days and
monitoring the tracers arrival in nearby wells Borehole geophysics core evaluation and packer testing
will be used to select the specific injection depth(s) in the well
A Tracer Test Work Plan will be completed prior to initiation of injection to determine the type quantity
and concentration of tracer based on the distance between the injection well and the monitoring wells A
conservative tracer that is one that is not preferentially adsorbed to rock or organic matter will be
selected for the tracer test Tracer injection equipment including tanks and flow-regulating and metering
equipment and pumps will be used to mix the tracer at the surface prior to injection Fractures may be
packered in the injection well and tracer solution will be injected at a rate determined during preparation
of the Tracer Test Work Plan During injection the potentiometric surface of the aquifer will be
monitored to verify that the potentiometric surface remains relatively constant during the injection
process
nsow WOODARD amp CURRAN 18 September 302003 20564309
Prior to injection of the tracer background concentration will be established by collecting samples from
up to six wells in the area of the tracer test and analyzing them for the tracer using an appropriate
analytical method Following injection of the tracer solutions the concentration of the tracer in
downgradient wells and borings will be measured A monitoring network will be established using nearby
monitoring wells Downhole probes will be installed in six new and existing wells near the injection well
to be identified in the work plan first to determine the background tracer concentrations and then to
monitor for the presence of the tracer upon initiation of the test Measurements will be collected at
periodic intervals to be determined based on the results of packer testing If an increase in tracer
concentration is detected or at a minimum on a weekly basis a water sample will be collected using low
flow sampling methodologies and analyzed in an off-site laboratory to evaluate the concentration of the
tracer The concentration of the tracer will be recorded Monitoring of the tracer concentration will
continue throughout the duration of the test The tracer will be allowed to flow with groundwater for one
month or until detected in wells in the vicinity of MW-106 whichever is shorter
313 Task 3 - TI Evaluation and Reporting
The TI Evaluation and reporting task includes the following five subtasks
bull Data evaluation
bull Summary data package
bull Draft TI Evaluation
bull Meetings with PRP Group and USEPA and
bull Revise and finalize TI Evaluation
As the subtasks of the field investigation are completed the data will be evaluated for the purpose of
addressing the data gaps identified by USEPA Specifically the data will be used to further refine the
cleanup times for non-source area groundwater presented in the Interim ROD
The data obtained during the field investigation will be reduced and evaluated and a summary data
package will be prepared that will include a discussion of the field activities completed and presentation
of the data It is anticipated that up to two meetings with USEPA will be necessary before the data
evaluation and summary report are completed
TISOW WOODARDampCURRAN 19 September 302003 20564309
Data collected during the pumping test will be analyzed with Aquifer Win32 Results will be summarized
in the summary data package and will also be presented as part of the RD submittals
Following submittal of the summary data package the TI evaluation will be prepared In accordance with
EPA guidance (1993) the TI waiver evaluation document will address the following topics
1 Specific ARARS or media cleanup standards for which TI determination is sought This section of the
TI Evaluation will identify the specific contaminants for which the TI determination is sought Based on
information available to date a waiver may be appropriate for pesticides PCBs chlorinated organic
compounds and other site-related contaminants that upon evaluation will not attain ARARs in a
reasonable period of time
2 Spatial area over which the TI waiver will apply The purpose of the additional site investigation
outlined in this SOW is to obtain the data necessary to further refine cleanup times presented in the
Interim ROD to determine what portions of the Site will not be expected to reach ARARs within a
reasonable time Consistent with TI guidance (USEPA 1993) the TI evaluation will specify the
horizontal and vertical extent of the area for which TI determination is sought Groundwater
concentration data from the RI and the TI SOW will be used to refine the distribution of the plume Data
from the drilling geophysical logging packer testing and pumping and tracer tests will be used to refine
the Site conceptual model and the cleanup times that will serve as the basis for establishing the scope and
nature of the TI zone
3 Conceptual Model The conceptual model forms the technical core of the TI Waiver Evaluation since
it provides basis for understanding of the restoration potential of the site The conceptual model outlines
the physical and hydrogeological constraints that hinder remediation or removal of Site contaminants and
it is the extent of these constraints rather than restoration timeframe alone that USEPA will use to
evaluate the necessity of the TI waiver of ARARs The conceptual model is the link between restoration
potential and restoration timeframe since it explains why proposed technologies are unlikely to work
either at all or within the desired 100-year timeframe
The Site conceptual model is not a mathematical model however as the result of the extensive modeling
and investigations of the site WampC has a strong understanding of the complex bedrock and overburden
TISOW WOODARDampCURRAN 20 September 302003 20564309
groundwater system beneath this site This understanding has been presented previously in both the RI
report and the FS and will be refined based on the TI SOW as necessary and summarized in the TI
Waiver Evaluation with specific attention to the physical and hydrogeological constraints on remediation
In particular the Site conceptual model will be reviewed in light of the new geologic data from drilling
logging and packer testing and the new hydrogeologic data obtained from the pumping test and tracer test
and will be revised to incorporate the new understanding
4 An evaluation of the restoration potential of the site This section will consist of a several components
It will present a systematic review of the technologies potentially capable of remediating the site given
the physical and hydrogeological constraints identified in the site model The newly acquired data will
provide an improved understanding of bedrock hydraulic properties that will allow a more Site-specific
evaluation of technologies The review of technologies will also include review of innovative
technologies and will evaluate whether existing remedial technologies or strategies would be capable of
achieving groundwater restoration at the site in a reasonable timeframe The section reference the FS and
will summarize the alternative remedies considered in the FS focusing on the ability of each to restore
groundwater in a reasonable timeframe It will also include a discussion of the selected hydraulic
containment system in light of the data gathered from the pumping test conducted in conjunction with the
TI SOW
Based on the Batch Flushing Model and using the agreed upon koc data from the RI as well as data from
this TI SOW including the f data collected as part of Subtask 4 a restoration timeframe analysis will be
conducted Following completion of the timeframe analysis and consideration of the results of drilling
rock and water analyses and pumping and tracer test a determination will be made regarding the Source
Area and the portion of the Non-Source Area VOC plume that will not attain ARARs in a reasonable
time
TISOW WOODARD amp CURRAN 21 September 302003 20564309
40 SCHEDULE
A proposed project schedule is included with this plan as Figure 4-1 This schedule is included for
discussion purposes and will be modified as necessary once the final scope of work as been approved by
all parties and the field work activities are coordinated with the subcontractors
TISOW WOODARD amp CURRAN 22 September 302003 20564309
ID
2
3
4
5
6
7 a i 10
11
12
13
14
15
16
17
16
19
20
21
22
24
25
26
27
26
29
30
31
32
Task Name
Project Meeting with EPA
Finalize SOW
Prepare Work Plans QAPP HASP Revision
Submit Work Plans for EPA Approval
Project Meeting with EPA
Revisions to work plans
Submit final work plans
Subcontractor Contracts
Project Meeting wEPA
Field Investigation
Site Mobilization
Install Borings
Borehole Geophysics
Packer Testing amp Collect GW Samples
Pumping Test
Tracer Test
Test setup
Injection
Monitoring
Data Reporting
InstallDevelop Wells
Data Evaluation
Prepare Data Package
Data Package Submittal to EPA
Draft Tl Evaluation Repon
Draft Tl Evaluation Report Submttal to EPA
EPA ReviewComment on Tl Evaluation ReF
Project Meeting wEPA
Revisions to Tl Evaluation Report
Submit Final Tl Evaluation Report
Start
Wed 070903
Thu 071003
Fri 101003
Mon 120103
Mon 121503
Mon 122903
Mon 011204
Tue 011304
Thu 021904
Fri 032104
Fri 032604
Fri 040204
Fri 041604
Fri 042304
Thu 050604
Wed 060204
Wed 060204
Wed 060904
Wed 060904
Wed 062304
Wed 070704
Wed 042804
Wed 062304
Mon 080204
Mon 070504
Tue 082404
Wed 082504
Wed 091504
Thu 0916AM
Thu 093004
Finish
Wed 070903
Fri 1OtO7u3
Fri 112803
Fri 122603
Mon 121503
Fri 010904
Mon 011204
Mon 012604
Thu 021904
Tue 071304
Thu 040104
Thu 042204
Tue 042704
Wed 050504
Tue 052504
Tue 071304
Tue 060804
Tue 061504
Tue 070604
Tue 071304
Fri 070904
Tue 072004
Fri 073004
Mon 080204
Mon 082304
Tue 082404
Tue 091404
Wed 091504
Wed 082904
Thu 093004
FIGURE 4-1 DRAFT HOWS CORNER SUPERFUND SITE
Tl EVALUATION amp RELD WORK FOR HYDRAUUC CONTAINMENT SYSTEM DESIGN PROPOSED PROJECT SCHEDULE
2003 2004 Mav |
Jun | Jul
ltamp i
Aug
i
Sen Oct I Nov Dec Jan Feb I Mar
ii i i
k ^tr 1
1V i
I t bull ^
I
ta^M bull bull M W
l LgtH^HBKLii LJ Mi
I
bull bull raquo bull laquo^ 0930
Task Progress I^MLHHHI^LB Summary ^^^^^^^^f External Tasks M B WMMM Deadline ^7 Project Hows Comer Schedule6A bull bull bull 1 UData Fri 101003 Split Milestone ^ Project Summary ^f^KKKKKK^^ External Milestone ^
Pagei
50 ACRONYMS
AOC Administrative Order by Consent
ARARs Applicable or Relevant and Appropriate Requirements
ATV acoustic televiewer
bgs below ground surface
CERCLA Comprehensive Environmental Resource and Conservation Liability Act
DNAPL Dense Non-Aqueous Phase Liquid
GAC granular activated carbon
gpm gallons per minute
HASP Health and Safety Plan
row investigation-derived waste
MCL Maximum Containment Level
MEDEP Maine Department of Environmental Protection
MEG Maine Enforcement Guideline
mgkg milligrams per kilogram
Hg kg micrograms per kilogram
NCP National Contingency Plan
PCB polychlorinated biphenyl
PID photo ionization detector
ppm parts per million
PRP Potentially Responsible Party
TISOW WOODARD amp CURRAN 24 September 302003 20564309
QAPP Quality Assurance Project Plan
QAQC Quality AssuranceQuality Control
RA Remedial Action
RAO Remedial Action Objective
RCRA Resource Conservation and Recovery Act
RD Remedial Design
RIFS Remedial InvestigationFeasibility Study
ROD Record of Decision
SAP Sampling and Analysis Plan
SOW Statement of Work
TAL target analyte list
TI Technical Impracticability
USEPA United State Environmental Protection Agency
VOCs volatile organic compounds
WampC Woodard amp Curran Inc
TISOW WOODARD amp CURRAN 25 September 302003 20564309
REFERENCES
Everts CJ RS Kanwar (1994) Evaluation of Rhodamine WT as an adsorbed tracer in an agricultural
soil J Hydrology 153 53-70
Kasnavia T D Vu DA Sabatini (1999) Fluorescent dye and media properties affecting sorption and
tracer selection Groundwater 37 376-381
Ptak T G Schmid (1996) Dual-tracer transport experiments in a physically and chemically
heterogeneous porous aquifer effective transport parameters and spatial variability J Hydrology
183 117-138
Sabatini DA T A Austin (1991) Characteristics of Rhodamine WT and fluorescein as adsorbing
ground-water tracers Ground Water 29 341-349
Trudgill ST (1987) Soil water dye tracing with special reference to the use of Rhodamanie WT
Lissamine FF and Amino G acid Hydrological Processes 1 149-170
US Environmental Protection Agency (USEPA) 1993 Guidance for Evaluating the Technical
Impracticability of Ground-Water Restoration - Interim Final Office of Solid Waste and
Emergency Response Washington DC Directive 92342-25 September 1993
US Environmental Protection Agency (USEPA) 2002 Interim Record of Decision Summary shy
Operable Unit One Non-Source Area Groundwater West SiteHows Corner Superfund Site
Plymouth Maine EPA Region 1 September 2002
US Environmental Protection Agency (USEPA) 2003 Proposed Scope of Work West SiteHows
Corner Superfund Site Plymouth Maine EPA Region 1 4 pages September 2002
Vasudevan D RL Fimmen AB Francisco (2001) Tracer-grade Rhodamine WT Structure of
constituent isomers and their sorption behavior Environ Sci Technol 35 4089-4096
nsow WOODARD amp CURRAN 26 September 30 2003 20564309
Woodard amp Curran Inc (WampC) 2002 Final Feasibility Study Report - Non-Source Area Groundwater
Hows Comer Superfund Site Plymouth Maine July 2002
TISOW WOODARD amp CURRAN 27 September 302003 20564309
f
m WOODARD amp CURRAN Maine Massachusetts New Hampshire Connecticut Florida Illinois Operational offices across the US 1-800-426-4262 wwwwoodardcurrancom
i
Subtask 5 - Monitoring Well Installation
Although it is anticipated that the newly installed borings will be left as open holes for tracer testing and
for pumping tests monitoring wells will be installed and developed in the newly installed borings unless
the USEPA MEDEP and PRP Group determine that the location is inappropriate for such use The
monitoring wells will be constructed of two-inch schedule 40 PVC screen and riser Screen intervals will
be selected based on the location of fractures identified during drilling geophysical logging and packer
testing A sand pack will be placed around the screen and will extend from approximately two ft below
the screen to approximately two ft above the screen
Subtask 6 - Pumping Test
WampC will conduct a single constant discharge pumping test to evaluate hydraulic properties of the
aquifer It is anticipated that the test will be conducted in a new pumping well in the vicinity of the
existing MW-2 well cluster within the source area Data from the pumping test will be used in
conjunction with other data from the investigation to improve the understanding of groundwater
movement and contaminant transport in the Source and Non-Source areas The results of the pumping
test will be used to refine the Site conceptual model as well as in the design of the hydraulic containment
system that is being constructed under the authority of the AOC for the RD
The groundwater pumping test will include the following components (1) Pumping test setup (2) Pretest
monitoring (3) Constant Discharge Pumping Test (4) Post-test monitoring and (5) Data Analysis
Pumping Test Setup In support of the groundwater pumping test WampC will install a pumping well
(PW-207) and procure and install the required groundwater extraction treatment and storage equipment at
the Site The well will be cored and over drilled to allow construction of a 4-inch well The location will
be in the vicinity of the MW-2 well cluster and be based upon results of the angled bedrock boring AWshy
202 The equipment will include but not be limited to
bull Down well pump plumbing and appurtances
bull Two (2) 20000 frac tanks
bull Groundwater transfer pumps and controls
bull Settlingaerationsand filtration treatment processes for the treatment of inorganics (if needed) and
nsow WOODARD amp CURRAN 16 September 302003 20564309
bull Granular activated carbon units for the treatment of dissolved organics in the groundwater
The groundwater treatment process will include the following processes 1) an oxidation and filtration
step to remove the inorganics from the groundwater and GAC units to treat the organic contaminants in
the extracted groundwater
Pretest Monitoring Prior to initiation of pumping WampC will monitor water levels in existing wells and
newly installed borings adjacent to the pumping well using a combination of hand measurements and data
loggers to develop an understanding of the piezometric surface under unstressed conditions The wells
proposed for water-level monitoring will be described in the work plan In addition all gauges
transducers flow meters and other equipment used in conducting the pumping tests shall be calibrated
before use
Constant Discharge Pumping Test The pumping test will be conducted in the source area using
newly-installed pumping well PW-207 It is anticipated that the test will be conducted at a pumping rate
of approximately 2 gallons per minute (gpm) for a period of 2 to 3 days however a higher or lower rate
may be shown to be appropriate based on the drilling and packer testing conducted during boring
installation Woodard amp Curran proposes to conduct this test using a vacuum-enhanced recovery system
(VERS) as described in the ROD so that the water level is not lowered appreciably in the vicinity of the
pumping well to prevent the potential migration of NAPLs to deeper bedrock zones The appropriateness
and feasibility of the VERS for the pumping test will be determined by field testing or literature
evaluation prior to completion of the Work Plan Because of the short duration of this test it is not
anticipated that stability of water levels will be reached in observation wells The test will however
provide information to estimate hydraulic conductivity and bedrock storage During the test the water
levels in the pumping well and selected monitoring wells will be logged continuously via down well data
loggers It is anticipated that water levels in approximately 24 wells will be measured using hand
measurements and data loggers
Groundwater extracted during the pumping test will be stored temporarily in an on-site frac tank prior to
on-site treatment and disposal
TISOW WOODARD amp CURRAN 17 September 302003 20564309
Post-Test Monitoring After the pump is turned off in the pumping well water levels will continue to be
monitored using hand measurements and data loggers until they have returned to within 10 of the preshy
test levels For planning purposes this has been estimated to be two weeks
Data Analysis Data collected during the pumping test will be analyzed with Aquifer Win32 Results of
the pumping test will be summarized in the summary data package for the TI Evaluation and the results
will also be used in the design of the hydraulic containment system specified in the Interim ROD that is
being conducted under the authority of the AOC for the RD Detail regarding use of the pumping test
data in hydraulic system design will be provided in the Remedial Design Work Plan
Subtask 7 - Tracer Test
WampC will conduct a tracer test using a conservative tracer to evaluate fracture connectivity porosity
dispersivity and matrix diffusion of the bedrock aquifer in both the Source Area and Non-Source Area
To increase the potential for success of this test results of the pumping test evaluation will be used to
revise the tracer test plan proposed here as necessary Following rebound of water levels after
completion of the pumping test WampC will initiate a single natural gradient tracer test The test will
consist of injecting a tracer into well PW-207 in the source area (Figure 3-1) for up to five days and
monitoring the tracers arrival in nearby wells Borehole geophysics core evaluation and packer testing
will be used to select the specific injection depth(s) in the well
A Tracer Test Work Plan will be completed prior to initiation of injection to determine the type quantity
and concentration of tracer based on the distance between the injection well and the monitoring wells A
conservative tracer that is one that is not preferentially adsorbed to rock or organic matter will be
selected for the tracer test Tracer injection equipment including tanks and flow-regulating and metering
equipment and pumps will be used to mix the tracer at the surface prior to injection Fractures may be
packered in the injection well and tracer solution will be injected at a rate determined during preparation
of the Tracer Test Work Plan During injection the potentiometric surface of the aquifer will be
monitored to verify that the potentiometric surface remains relatively constant during the injection
process
nsow WOODARD amp CURRAN 18 September 302003 20564309
Prior to injection of the tracer background concentration will be established by collecting samples from
up to six wells in the area of the tracer test and analyzing them for the tracer using an appropriate
analytical method Following injection of the tracer solutions the concentration of the tracer in
downgradient wells and borings will be measured A monitoring network will be established using nearby
monitoring wells Downhole probes will be installed in six new and existing wells near the injection well
to be identified in the work plan first to determine the background tracer concentrations and then to
monitor for the presence of the tracer upon initiation of the test Measurements will be collected at
periodic intervals to be determined based on the results of packer testing If an increase in tracer
concentration is detected or at a minimum on a weekly basis a water sample will be collected using low
flow sampling methodologies and analyzed in an off-site laboratory to evaluate the concentration of the
tracer The concentration of the tracer will be recorded Monitoring of the tracer concentration will
continue throughout the duration of the test The tracer will be allowed to flow with groundwater for one
month or until detected in wells in the vicinity of MW-106 whichever is shorter
313 Task 3 - TI Evaluation and Reporting
The TI Evaluation and reporting task includes the following five subtasks
bull Data evaluation
bull Summary data package
bull Draft TI Evaluation
bull Meetings with PRP Group and USEPA and
bull Revise and finalize TI Evaluation
As the subtasks of the field investigation are completed the data will be evaluated for the purpose of
addressing the data gaps identified by USEPA Specifically the data will be used to further refine the
cleanup times for non-source area groundwater presented in the Interim ROD
The data obtained during the field investigation will be reduced and evaluated and a summary data
package will be prepared that will include a discussion of the field activities completed and presentation
of the data It is anticipated that up to two meetings with USEPA will be necessary before the data
evaluation and summary report are completed
TISOW WOODARDampCURRAN 19 September 302003 20564309
Data collected during the pumping test will be analyzed with Aquifer Win32 Results will be summarized
in the summary data package and will also be presented as part of the RD submittals
Following submittal of the summary data package the TI evaluation will be prepared In accordance with
EPA guidance (1993) the TI waiver evaluation document will address the following topics
1 Specific ARARS or media cleanup standards for which TI determination is sought This section of the
TI Evaluation will identify the specific contaminants for which the TI determination is sought Based on
information available to date a waiver may be appropriate for pesticides PCBs chlorinated organic
compounds and other site-related contaminants that upon evaluation will not attain ARARs in a
reasonable period of time
2 Spatial area over which the TI waiver will apply The purpose of the additional site investigation
outlined in this SOW is to obtain the data necessary to further refine cleanup times presented in the
Interim ROD to determine what portions of the Site will not be expected to reach ARARs within a
reasonable time Consistent with TI guidance (USEPA 1993) the TI evaluation will specify the
horizontal and vertical extent of the area for which TI determination is sought Groundwater
concentration data from the RI and the TI SOW will be used to refine the distribution of the plume Data
from the drilling geophysical logging packer testing and pumping and tracer tests will be used to refine
the Site conceptual model and the cleanup times that will serve as the basis for establishing the scope and
nature of the TI zone
3 Conceptual Model The conceptual model forms the technical core of the TI Waiver Evaluation since
it provides basis for understanding of the restoration potential of the site The conceptual model outlines
the physical and hydrogeological constraints that hinder remediation or removal of Site contaminants and
it is the extent of these constraints rather than restoration timeframe alone that USEPA will use to
evaluate the necessity of the TI waiver of ARARs The conceptual model is the link between restoration
potential and restoration timeframe since it explains why proposed technologies are unlikely to work
either at all or within the desired 100-year timeframe
The Site conceptual model is not a mathematical model however as the result of the extensive modeling
and investigations of the site WampC has a strong understanding of the complex bedrock and overburden
TISOW WOODARDampCURRAN 20 September 302003 20564309
groundwater system beneath this site This understanding has been presented previously in both the RI
report and the FS and will be refined based on the TI SOW as necessary and summarized in the TI
Waiver Evaluation with specific attention to the physical and hydrogeological constraints on remediation
In particular the Site conceptual model will be reviewed in light of the new geologic data from drilling
logging and packer testing and the new hydrogeologic data obtained from the pumping test and tracer test
and will be revised to incorporate the new understanding
4 An evaluation of the restoration potential of the site This section will consist of a several components
It will present a systematic review of the technologies potentially capable of remediating the site given
the physical and hydrogeological constraints identified in the site model The newly acquired data will
provide an improved understanding of bedrock hydraulic properties that will allow a more Site-specific
evaluation of technologies The review of technologies will also include review of innovative
technologies and will evaluate whether existing remedial technologies or strategies would be capable of
achieving groundwater restoration at the site in a reasonable timeframe The section reference the FS and
will summarize the alternative remedies considered in the FS focusing on the ability of each to restore
groundwater in a reasonable timeframe It will also include a discussion of the selected hydraulic
containment system in light of the data gathered from the pumping test conducted in conjunction with the
TI SOW
Based on the Batch Flushing Model and using the agreed upon koc data from the RI as well as data from
this TI SOW including the f data collected as part of Subtask 4 a restoration timeframe analysis will be
conducted Following completion of the timeframe analysis and consideration of the results of drilling
rock and water analyses and pumping and tracer test a determination will be made regarding the Source
Area and the portion of the Non-Source Area VOC plume that will not attain ARARs in a reasonable
time
TISOW WOODARD amp CURRAN 21 September 302003 20564309
40 SCHEDULE
A proposed project schedule is included with this plan as Figure 4-1 This schedule is included for
discussion purposes and will be modified as necessary once the final scope of work as been approved by
all parties and the field work activities are coordinated with the subcontractors
TISOW WOODARD amp CURRAN 22 September 302003 20564309
ID
2
3
4
5
6
7 a i 10
11
12
13
14
15
16
17
16
19
20
21
22
24
25
26
27
26
29
30
31
32
Task Name
Project Meeting with EPA
Finalize SOW
Prepare Work Plans QAPP HASP Revision
Submit Work Plans for EPA Approval
Project Meeting with EPA
Revisions to work plans
Submit final work plans
Subcontractor Contracts
Project Meeting wEPA
Field Investigation
Site Mobilization
Install Borings
Borehole Geophysics
Packer Testing amp Collect GW Samples
Pumping Test
Tracer Test
Test setup
Injection
Monitoring
Data Reporting
InstallDevelop Wells
Data Evaluation
Prepare Data Package
Data Package Submittal to EPA
Draft Tl Evaluation Repon
Draft Tl Evaluation Report Submttal to EPA
EPA ReviewComment on Tl Evaluation ReF
Project Meeting wEPA
Revisions to Tl Evaluation Report
Submit Final Tl Evaluation Report
Start
Wed 070903
Thu 071003
Fri 101003
Mon 120103
Mon 121503
Mon 122903
Mon 011204
Tue 011304
Thu 021904
Fri 032104
Fri 032604
Fri 040204
Fri 041604
Fri 042304
Thu 050604
Wed 060204
Wed 060204
Wed 060904
Wed 060904
Wed 062304
Wed 070704
Wed 042804
Wed 062304
Mon 080204
Mon 070504
Tue 082404
Wed 082504
Wed 091504
Thu 0916AM
Thu 093004
Finish
Wed 070903
Fri 1OtO7u3
Fri 112803
Fri 122603
Mon 121503
Fri 010904
Mon 011204
Mon 012604
Thu 021904
Tue 071304
Thu 040104
Thu 042204
Tue 042704
Wed 050504
Tue 052504
Tue 071304
Tue 060804
Tue 061504
Tue 070604
Tue 071304
Fri 070904
Tue 072004
Fri 073004
Mon 080204
Mon 082304
Tue 082404
Tue 091404
Wed 091504
Wed 082904
Thu 093004
FIGURE 4-1 DRAFT HOWS CORNER SUPERFUND SITE
Tl EVALUATION amp RELD WORK FOR HYDRAUUC CONTAINMENT SYSTEM DESIGN PROPOSED PROJECT SCHEDULE
2003 2004 Mav |
Jun | Jul
ltamp i
Aug
i
Sen Oct I Nov Dec Jan Feb I Mar
ii i i
k ^tr 1
1V i
I t bull ^
I
ta^M bull bull M W
l LgtH^HBKLii LJ Mi
I
bull bull raquo bull laquo^ 0930
Task Progress I^MLHHHI^LB Summary ^^^^^^^^f External Tasks M B WMMM Deadline ^7 Project Hows Comer Schedule6A bull bull bull 1 UData Fri 101003 Split Milestone ^ Project Summary ^f^KKKKKK^^ External Milestone ^
Pagei
50 ACRONYMS
AOC Administrative Order by Consent
ARARs Applicable or Relevant and Appropriate Requirements
ATV acoustic televiewer
bgs below ground surface
CERCLA Comprehensive Environmental Resource and Conservation Liability Act
DNAPL Dense Non-Aqueous Phase Liquid
GAC granular activated carbon
gpm gallons per minute
HASP Health and Safety Plan
row investigation-derived waste
MCL Maximum Containment Level
MEDEP Maine Department of Environmental Protection
MEG Maine Enforcement Guideline
mgkg milligrams per kilogram
Hg kg micrograms per kilogram
NCP National Contingency Plan
PCB polychlorinated biphenyl
PID photo ionization detector
ppm parts per million
PRP Potentially Responsible Party
TISOW WOODARD amp CURRAN 24 September 302003 20564309
QAPP Quality Assurance Project Plan
QAQC Quality AssuranceQuality Control
RA Remedial Action
RAO Remedial Action Objective
RCRA Resource Conservation and Recovery Act
RD Remedial Design
RIFS Remedial InvestigationFeasibility Study
ROD Record of Decision
SAP Sampling and Analysis Plan
SOW Statement of Work
TAL target analyte list
TI Technical Impracticability
USEPA United State Environmental Protection Agency
VOCs volatile organic compounds
WampC Woodard amp Curran Inc
TISOW WOODARD amp CURRAN 25 September 302003 20564309
REFERENCES
Everts CJ RS Kanwar (1994) Evaluation of Rhodamine WT as an adsorbed tracer in an agricultural
soil J Hydrology 153 53-70
Kasnavia T D Vu DA Sabatini (1999) Fluorescent dye and media properties affecting sorption and
tracer selection Groundwater 37 376-381
Ptak T G Schmid (1996) Dual-tracer transport experiments in a physically and chemically
heterogeneous porous aquifer effective transport parameters and spatial variability J Hydrology
183 117-138
Sabatini DA T A Austin (1991) Characteristics of Rhodamine WT and fluorescein as adsorbing
ground-water tracers Ground Water 29 341-349
Trudgill ST (1987) Soil water dye tracing with special reference to the use of Rhodamanie WT
Lissamine FF and Amino G acid Hydrological Processes 1 149-170
US Environmental Protection Agency (USEPA) 1993 Guidance for Evaluating the Technical
Impracticability of Ground-Water Restoration - Interim Final Office of Solid Waste and
Emergency Response Washington DC Directive 92342-25 September 1993
US Environmental Protection Agency (USEPA) 2002 Interim Record of Decision Summary shy
Operable Unit One Non-Source Area Groundwater West SiteHows Corner Superfund Site
Plymouth Maine EPA Region 1 September 2002
US Environmental Protection Agency (USEPA) 2003 Proposed Scope of Work West SiteHows
Corner Superfund Site Plymouth Maine EPA Region 1 4 pages September 2002
Vasudevan D RL Fimmen AB Francisco (2001) Tracer-grade Rhodamine WT Structure of
constituent isomers and their sorption behavior Environ Sci Technol 35 4089-4096
nsow WOODARD amp CURRAN 26 September 30 2003 20564309
Woodard amp Curran Inc (WampC) 2002 Final Feasibility Study Report - Non-Source Area Groundwater
Hows Comer Superfund Site Plymouth Maine July 2002
TISOW WOODARD amp CURRAN 27 September 302003 20564309
f
m WOODARD amp CURRAN Maine Massachusetts New Hampshire Connecticut Florida Illinois Operational offices across the US 1-800-426-4262 wwwwoodardcurrancom
i
bull Granular activated carbon units for the treatment of dissolved organics in the groundwater
The groundwater treatment process will include the following processes 1) an oxidation and filtration
step to remove the inorganics from the groundwater and GAC units to treat the organic contaminants in
the extracted groundwater
Pretest Monitoring Prior to initiation of pumping WampC will monitor water levels in existing wells and
newly installed borings adjacent to the pumping well using a combination of hand measurements and data
loggers to develop an understanding of the piezometric surface under unstressed conditions The wells
proposed for water-level monitoring will be described in the work plan In addition all gauges
transducers flow meters and other equipment used in conducting the pumping tests shall be calibrated
before use
Constant Discharge Pumping Test The pumping test will be conducted in the source area using
newly-installed pumping well PW-207 It is anticipated that the test will be conducted at a pumping rate
of approximately 2 gallons per minute (gpm) for a period of 2 to 3 days however a higher or lower rate
may be shown to be appropriate based on the drilling and packer testing conducted during boring
installation Woodard amp Curran proposes to conduct this test using a vacuum-enhanced recovery system
(VERS) as described in the ROD so that the water level is not lowered appreciably in the vicinity of the
pumping well to prevent the potential migration of NAPLs to deeper bedrock zones The appropriateness
and feasibility of the VERS for the pumping test will be determined by field testing or literature
evaluation prior to completion of the Work Plan Because of the short duration of this test it is not
anticipated that stability of water levels will be reached in observation wells The test will however
provide information to estimate hydraulic conductivity and bedrock storage During the test the water
levels in the pumping well and selected monitoring wells will be logged continuously via down well data
loggers It is anticipated that water levels in approximately 24 wells will be measured using hand
measurements and data loggers
Groundwater extracted during the pumping test will be stored temporarily in an on-site frac tank prior to
on-site treatment and disposal
TISOW WOODARD amp CURRAN 17 September 302003 20564309
Post-Test Monitoring After the pump is turned off in the pumping well water levels will continue to be
monitored using hand measurements and data loggers until they have returned to within 10 of the preshy
test levels For planning purposes this has been estimated to be two weeks
Data Analysis Data collected during the pumping test will be analyzed with Aquifer Win32 Results of
the pumping test will be summarized in the summary data package for the TI Evaluation and the results
will also be used in the design of the hydraulic containment system specified in the Interim ROD that is
being conducted under the authority of the AOC for the RD Detail regarding use of the pumping test
data in hydraulic system design will be provided in the Remedial Design Work Plan
Subtask 7 - Tracer Test
WampC will conduct a tracer test using a conservative tracer to evaluate fracture connectivity porosity
dispersivity and matrix diffusion of the bedrock aquifer in both the Source Area and Non-Source Area
To increase the potential for success of this test results of the pumping test evaluation will be used to
revise the tracer test plan proposed here as necessary Following rebound of water levels after
completion of the pumping test WampC will initiate a single natural gradient tracer test The test will
consist of injecting a tracer into well PW-207 in the source area (Figure 3-1) for up to five days and
monitoring the tracers arrival in nearby wells Borehole geophysics core evaluation and packer testing
will be used to select the specific injection depth(s) in the well
A Tracer Test Work Plan will be completed prior to initiation of injection to determine the type quantity
and concentration of tracer based on the distance between the injection well and the monitoring wells A
conservative tracer that is one that is not preferentially adsorbed to rock or organic matter will be
selected for the tracer test Tracer injection equipment including tanks and flow-regulating and metering
equipment and pumps will be used to mix the tracer at the surface prior to injection Fractures may be
packered in the injection well and tracer solution will be injected at a rate determined during preparation
of the Tracer Test Work Plan During injection the potentiometric surface of the aquifer will be
monitored to verify that the potentiometric surface remains relatively constant during the injection
process
nsow WOODARD amp CURRAN 18 September 302003 20564309
Prior to injection of the tracer background concentration will be established by collecting samples from
up to six wells in the area of the tracer test and analyzing them for the tracer using an appropriate
analytical method Following injection of the tracer solutions the concentration of the tracer in
downgradient wells and borings will be measured A monitoring network will be established using nearby
monitoring wells Downhole probes will be installed in six new and existing wells near the injection well
to be identified in the work plan first to determine the background tracer concentrations and then to
monitor for the presence of the tracer upon initiation of the test Measurements will be collected at
periodic intervals to be determined based on the results of packer testing If an increase in tracer
concentration is detected or at a minimum on a weekly basis a water sample will be collected using low
flow sampling methodologies and analyzed in an off-site laboratory to evaluate the concentration of the
tracer The concentration of the tracer will be recorded Monitoring of the tracer concentration will
continue throughout the duration of the test The tracer will be allowed to flow with groundwater for one
month or until detected in wells in the vicinity of MW-106 whichever is shorter
313 Task 3 - TI Evaluation and Reporting
The TI Evaluation and reporting task includes the following five subtasks
bull Data evaluation
bull Summary data package
bull Draft TI Evaluation
bull Meetings with PRP Group and USEPA and
bull Revise and finalize TI Evaluation
As the subtasks of the field investigation are completed the data will be evaluated for the purpose of
addressing the data gaps identified by USEPA Specifically the data will be used to further refine the
cleanup times for non-source area groundwater presented in the Interim ROD
The data obtained during the field investigation will be reduced and evaluated and a summary data
package will be prepared that will include a discussion of the field activities completed and presentation
of the data It is anticipated that up to two meetings with USEPA will be necessary before the data
evaluation and summary report are completed
TISOW WOODARDampCURRAN 19 September 302003 20564309
Data collected during the pumping test will be analyzed with Aquifer Win32 Results will be summarized
in the summary data package and will also be presented as part of the RD submittals
Following submittal of the summary data package the TI evaluation will be prepared In accordance with
EPA guidance (1993) the TI waiver evaluation document will address the following topics
1 Specific ARARS or media cleanup standards for which TI determination is sought This section of the
TI Evaluation will identify the specific contaminants for which the TI determination is sought Based on
information available to date a waiver may be appropriate for pesticides PCBs chlorinated organic
compounds and other site-related contaminants that upon evaluation will not attain ARARs in a
reasonable period of time
2 Spatial area over which the TI waiver will apply The purpose of the additional site investigation
outlined in this SOW is to obtain the data necessary to further refine cleanup times presented in the
Interim ROD to determine what portions of the Site will not be expected to reach ARARs within a
reasonable time Consistent with TI guidance (USEPA 1993) the TI evaluation will specify the
horizontal and vertical extent of the area for which TI determination is sought Groundwater
concentration data from the RI and the TI SOW will be used to refine the distribution of the plume Data
from the drilling geophysical logging packer testing and pumping and tracer tests will be used to refine
the Site conceptual model and the cleanup times that will serve as the basis for establishing the scope and
nature of the TI zone
3 Conceptual Model The conceptual model forms the technical core of the TI Waiver Evaluation since
it provides basis for understanding of the restoration potential of the site The conceptual model outlines
the physical and hydrogeological constraints that hinder remediation or removal of Site contaminants and
it is the extent of these constraints rather than restoration timeframe alone that USEPA will use to
evaluate the necessity of the TI waiver of ARARs The conceptual model is the link between restoration
potential and restoration timeframe since it explains why proposed technologies are unlikely to work
either at all or within the desired 100-year timeframe
The Site conceptual model is not a mathematical model however as the result of the extensive modeling
and investigations of the site WampC has a strong understanding of the complex bedrock and overburden
TISOW WOODARDampCURRAN 20 September 302003 20564309
groundwater system beneath this site This understanding has been presented previously in both the RI
report and the FS and will be refined based on the TI SOW as necessary and summarized in the TI
Waiver Evaluation with specific attention to the physical and hydrogeological constraints on remediation
In particular the Site conceptual model will be reviewed in light of the new geologic data from drilling
logging and packer testing and the new hydrogeologic data obtained from the pumping test and tracer test
and will be revised to incorporate the new understanding
4 An evaluation of the restoration potential of the site This section will consist of a several components
It will present a systematic review of the technologies potentially capable of remediating the site given
the physical and hydrogeological constraints identified in the site model The newly acquired data will
provide an improved understanding of bedrock hydraulic properties that will allow a more Site-specific
evaluation of technologies The review of technologies will also include review of innovative
technologies and will evaluate whether existing remedial technologies or strategies would be capable of
achieving groundwater restoration at the site in a reasonable timeframe The section reference the FS and
will summarize the alternative remedies considered in the FS focusing on the ability of each to restore
groundwater in a reasonable timeframe It will also include a discussion of the selected hydraulic
containment system in light of the data gathered from the pumping test conducted in conjunction with the
TI SOW
Based on the Batch Flushing Model and using the agreed upon koc data from the RI as well as data from
this TI SOW including the f data collected as part of Subtask 4 a restoration timeframe analysis will be
conducted Following completion of the timeframe analysis and consideration of the results of drilling
rock and water analyses and pumping and tracer test a determination will be made regarding the Source
Area and the portion of the Non-Source Area VOC plume that will not attain ARARs in a reasonable
time
TISOW WOODARD amp CURRAN 21 September 302003 20564309
40 SCHEDULE
A proposed project schedule is included with this plan as Figure 4-1 This schedule is included for
discussion purposes and will be modified as necessary once the final scope of work as been approved by
all parties and the field work activities are coordinated with the subcontractors
TISOW WOODARD amp CURRAN 22 September 302003 20564309
ID
2
3
4
5
6
7 a i 10
11
12
13
14
15
16
17
16
19
20
21
22
24
25
26
27
26
29
30
31
32
Task Name
Project Meeting with EPA
Finalize SOW
Prepare Work Plans QAPP HASP Revision
Submit Work Plans for EPA Approval
Project Meeting with EPA
Revisions to work plans
Submit final work plans
Subcontractor Contracts
Project Meeting wEPA
Field Investigation
Site Mobilization
Install Borings
Borehole Geophysics
Packer Testing amp Collect GW Samples
Pumping Test
Tracer Test
Test setup
Injection
Monitoring
Data Reporting
InstallDevelop Wells
Data Evaluation
Prepare Data Package
Data Package Submittal to EPA
Draft Tl Evaluation Repon
Draft Tl Evaluation Report Submttal to EPA
EPA ReviewComment on Tl Evaluation ReF
Project Meeting wEPA
Revisions to Tl Evaluation Report
Submit Final Tl Evaluation Report
Start
Wed 070903
Thu 071003
Fri 101003
Mon 120103
Mon 121503
Mon 122903
Mon 011204
Tue 011304
Thu 021904
Fri 032104
Fri 032604
Fri 040204
Fri 041604
Fri 042304
Thu 050604
Wed 060204
Wed 060204
Wed 060904
Wed 060904
Wed 062304
Wed 070704
Wed 042804
Wed 062304
Mon 080204
Mon 070504
Tue 082404
Wed 082504
Wed 091504
Thu 0916AM
Thu 093004
Finish
Wed 070903
Fri 1OtO7u3
Fri 112803
Fri 122603
Mon 121503
Fri 010904
Mon 011204
Mon 012604
Thu 021904
Tue 071304
Thu 040104
Thu 042204
Tue 042704
Wed 050504
Tue 052504
Tue 071304
Tue 060804
Tue 061504
Tue 070604
Tue 071304
Fri 070904
Tue 072004
Fri 073004
Mon 080204
Mon 082304
Tue 082404
Tue 091404
Wed 091504
Wed 082904
Thu 093004
FIGURE 4-1 DRAFT HOWS CORNER SUPERFUND SITE
Tl EVALUATION amp RELD WORK FOR HYDRAUUC CONTAINMENT SYSTEM DESIGN PROPOSED PROJECT SCHEDULE
2003 2004 Mav |
Jun | Jul
ltamp i
Aug
i
Sen Oct I Nov Dec Jan Feb I Mar
ii i i
k ^tr 1
1V i
I t bull ^
I
ta^M bull bull M W
l LgtH^HBKLii LJ Mi
I
bull bull raquo bull laquo^ 0930
Task Progress I^MLHHHI^LB Summary ^^^^^^^^f External Tasks M B WMMM Deadline ^7 Project Hows Comer Schedule6A bull bull bull 1 UData Fri 101003 Split Milestone ^ Project Summary ^f^KKKKKK^^ External Milestone ^
Pagei
50 ACRONYMS
AOC Administrative Order by Consent
ARARs Applicable or Relevant and Appropriate Requirements
ATV acoustic televiewer
bgs below ground surface
CERCLA Comprehensive Environmental Resource and Conservation Liability Act
DNAPL Dense Non-Aqueous Phase Liquid
GAC granular activated carbon
gpm gallons per minute
HASP Health and Safety Plan
row investigation-derived waste
MCL Maximum Containment Level
MEDEP Maine Department of Environmental Protection
MEG Maine Enforcement Guideline
mgkg milligrams per kilogram
Hg kg micrograms per kilogram
NCP National Contingency Plan
PCB polychlorinated biphenyl
PID photo ionization detector
ppm parts per million
PRP Potentially Responsible Party
TISOW WOODARD amp CURRAN 24 September 302003 20564309
QAPP Quality Assurance Project Plan
QAQC Quality AssuranceQuality Control
RA Remedial Action
RAO Remedial Action Objective
RCRA Resource Conservation and Recovery Act
RD Remedial Design
RIFS Remedial InvestigationFeasibility Study
ROD Record of Decision
SAP Sampling and Analysis Plan
SOW Statement of Work
TAL target analyte list
TI Technical Impracticability
USEPA United State Environmental Protection Agency
VOCs volatile organic compounds
WampC Woodard amp Curran Inc
TISOW WOODARD amp CURRAN 25 September 302003 20564309
REFERENCES
Everts CJ RS Kanwar (1994) Evaluation of Rhodamine WT as an adsorbed tracer in an agricultural
soil J Hydrology 153 53-70
Kasnavia T D Vu DA Sabatini (1999) Fluorescent dye and media properties affecting sorption and
tracer selection Groundwater 37 376-381
Ptak T G Schmid (1996) Dual-tracer transport experiments in a physically and chemically
heterogeneous porous aquifer effective transport parameters and spatial variability J Hydrology
183 117-138
Sabatini DA T A Austin (1991) Characteristics of Rhodamine WT and fluorescein as adsorbing
ground-water tracers Ground Water 29 341-349
Trudgill ST (1987) Soil water dye tracing with special reference to the use of Rhodamanie WT
Lissamine FF and Amino G acid Hydrological Processes 1 149-170
US Environmental Protection Agency (USEPA) 1993 Guidance for Evaluating the Technical
Impracticability of Ground-Water Restoration - Interim Final Office of Solid Waste and
Emergency Response Washington DC Directive 92342-25 September 1993
US Environmental Protection Agency (USEPA) 2002 Interim Record of Decision Summary shy
Operable Unit One Non-Source Area Groundwater West SiteHows Corner Superfund Site
Plymouth Maine EPA Region 1 September 2002
US Environmental Protection Agency (USEPA) 2003 Proposed Scope of Work West SiteHows
Corner Superfund Site Plymouth Maine EPA Region 1 4 pages September 2002
Vasudevan D RL Fimmen AB Francisco (2001) Tracer-grade Rhodamine WT Structure of
constituent isomers and their sorption behavior Environ Sci Technol 35 4089-4096
nsow WOODARD amp CURRAN 26 September 30 2003 20564309
Woodard amp Curran Inc (WampC) 2002 Final Feasibility Study Report - Non-Source Area Groundwater
Hows Comer Superfund Site Plymouth Maine July 2002
TISOW WOODARD amp CURRAN 27 September 302003 20564309
f
m WOODARD amp CURRAN Maine Massachusetts New Hampshire Connecticut Florida Illinois Operational offices across the US 1-800-426-4262 wwwwoodardcurrancom
i
Post-Test Monitoring After the pump is turned off in the pumping well water levels will continue to be
monitored using hand measurements and data loggers until they have returned to within 10 of the preshy
test levels For planning purposes this has been estimated to be two weeks
Data Analysis Data collected during the pumping test will be analyzed with Aquifer Win32 Results of
the pumping test will be summarized in the summary data package for the TI Evaluation and the results
will also be used in the design of the hydraulic containment system specified in the Interim ROD that is
being conducted under the authority of the AOC for the RD Detail regarding use of the pumping test
data in hydraulic system design will be provided in the Remedial Design Work Plan
Subtask 7 - Tracer Test
WampC will conduct a tracer test using a conservative tracer to evaluate fracture connectivity porosity
dispersivity and matrix diffusion of the bedrock aquifer in both the Source Area and Non-Source Area
To increase the potential for success of this test results of the pumping test evaluation will be used to
revise the tracer test plan proposed here as necessary Following rebound of water levels after
completion of the pumping test WampC will initiate a single natural gradient tracer test The test will
consist of injecting a tracer into well PW-207 in the source area (Figure 3-1) for up to five days and
monitoring the tracers arrival in nearby wells Borehole geophysics core evaluation and packer testing
will be used to select the specific injection depth(s) in the well
A Tracer Test Work Plan will be completed prior to initiation of injection to determine the type quantity
and concentration of tracer based on the distance between the injection well and the monitoring wells A
conservative tracer that is one that is not preferentially adsorbed to rock or organic matter will be
selected for the tracer test Tracer injection equipment including tanks and flow-regulating and metering
equipment and pumps will be used to mix the tracer at the surface prior to injection Fractures may be
packered in the injection well and tracer solution will be injected at a rate determined during preparation
of the Tracer Test Work Plan During injection the potentiometric surface of the aquifer will be
monitored to verify that the potentiometric surface remains relatively constant during the injection
process
nsow WOODARD amp CURRAN 18 September 302003 20564309
Prior to injection of the tracer background concentration will be established by collecting samples from
up to six wells in the area of the tracer test and analyzing them for the tracer using an appropriate
analytical method Following injection of the tracer solutions the concentration of the tracer in
downgradient wells and borings will be measured A monitoring network will be established using nearby
monitoring wells Downhole probes will be installed in six new and existing wells near the injection well
to be identified in the work plan first to determine the background tracer concentrations and then to
monitor for the presence of the tracer upon initiation of the test Measurements will be collected at
periodic intervals to be determined based on the results of packer testing If an increase in tracer
concentration is detected or at a minimum on a weekly basis a water sample will be collected using low
flow sampling methodologies and analyzed in an off-site laboratory to evaluate the concentration of the
tracer The concentration of the tracer will be recorded Monitoring of the tracer concentration will
continue throughout the duration of the test The tracer will be allowed to flow with groundwater for one
month or until detected in wells in the vicinity of MW-106 whichever is shorter
313 Task 3 - TI Evaluation and Reporting
The TI Evaluation and reporting task includes the following five subtasks
bull Data evaluation
bull Summary data package
bull Draft TI Evaluation
bull Meetings with PRP Group and USEPA and
bull Revise and finalize TI Evaluation
As the subtasks of the field investigation are completed the data will be evaluated for the purpose of
addressing the data gaps identified by USEPA Specifically the data will be used to further refine the
cleanup times for non-source area groundwater presented in the Interim ROD
The data obtained during the field investigation will be reduced and evaluated and a summary data
package will be prepared that will include a discussion of the field activities completed and presentation
of the data It is anticipated that up to two meetings with USEPA will be necessary before the data
evaluation and summary report are completed
TISOW WOODARDampCURRAN 19 September 302003 20564309
Data collected during the pumping test will be analyzed with Aquifer Win32 Results will be summarized
in the summary data package and will also be presented as part of the RD submittals
Following submittal of the summary data package the TI evaluation will be prepared In accordance with
EPA guidance (1993) the TI waiver evaluation document will address the following topics
1 Specific ARARS or media cleanup standards for which TI determination is sought This section of the
TI Evaluation will identify the specific contaminants for which the TI determination is sought Based on
information available to date a waiver may be appropriate for pesticides PCBs chlorinated organic
compounds and other site-related contaminants that upon evaluation will not attain ARARs in a
reasonable period of time
2 Spatial area over which the TI waiver will apply The purpose of the additional site investigation
outlined in this SOW is to obtain the data necessary to further refine cleanup times presented in the
Interim ROD to determine what portions of the Site will not be expected to reach ARARs within a
reasonable time Consistent with TI guidance (USEPA 1993) the TI evaluation will specify the
horizontal and vertical extent of the area for which TI determination is sought Groundwater
concentration data from the RI and the TI SOW will be used to refine the distribution of the plume Data
from the drilling geophysical logging packer testing and pumping and tracer tests will be used to refine
the Site conceptual model and the cleanup times that will serve as the basis for establishing the scope and
nature of the TI zone
3 Conceptual Model The conceptual model forms the technical core of the TI Waiver Evaluation since
it provides basis for understanding of the restoration potential of the site The conceptual model outlines
the physical and hydrogeological constraints that hinder remediation or removal of Site contaminants and
it is the extent of these constraints rather than restoration timeframe alone that USEPA will use to
evaluate the necessity of the TI waiver of ARARs The conceptual model is the link between restoration
potential and restoration timeframe since it explains why proposed technologies are unlikely to work
either at all or within the desired 100-year timeframe
The Site conceptual model is not a mathematical model however as the result of the extensive modeling
and investigations of the site WampC has a strong understanding of the complex bedrock and overburden
TISOW WOODARDampCURRAN 20 September 302003 20564309
groundwater system beneath this site This understanding has been presented previously in both the RI
report and the FS and will be refined based on the TI SOW as necessary and summarized in the TI
Waiver Evaluation with specific attention to the physical and hydrogeological constraints on remediation
In particular the Site conceptual model will be reviewed in light of the new geologic data from drilling
logging and packer testing and the new hydrogeologic data obtained from the pumping test and tracer test
and will be revised to incorporate the new understanding
4 An evaluation of the restoration potential of the site This section will consist of a several components
It will present a systematic review of the technologies potentially capable of remediating the site given
the physical and hydrogeological constraints identified in the site model The newly acquired data will
provide an improved understanding of bedrock hydraulic properties that will allow a more Site-specific
evaluation of technologies The review of technologies will also include review of innovative
technologies and will evaluate whether existing remedial technologies or strategies would be capable of
achieving groundwater restoration at the site in a reasonable timeframe The section reference the FS and
will summarize the alternative remedies considered in the FS focusing on the ability of each to restore
groundwater in a reasonable timeframe It will also include a discussion of the selected hydraulic
containment system in light of the data gathered from the pumping test conducted in conjunction with the
TI SOW
Based on the Batch Flushing Model and using the agreed upon koc data from the RI as well as data from
this TI SOW including the f data collected as part of Subtask 4 a restoration timeframe analysis will be
conducted Following completion of the timeframe analysis and consideration of the results of drilling
rock and water analyses and pumping and tracer test a determination will be made regarding the Source
Area and the portion of the Non-Source Area VOC plume that will not attain ARARs in a reasonable
time
TISOW WOODARD amp CURRAN 21 September 302003 20564309
40 SCHEDULE
A proposed project schedule is included with this plan as Figure 4-1 This schedule is included for
discussion purposes and will be modified as necessary once the final scope of work as been approved by
all parties and the field work activities are coordinated with the subcontractors
TISOW WOODARD amp CURRAN 22 September 302003 20564309
ID
2
3
4
5
6
7 a i 10
11
12
13
14
15
16
17
16
19
20
21
22
24
25
26
27
26
29
30
31
32
Task Name
Project Meeting with EPA
Finalize SOW
Prepare Work Plans QAPP HASP Revision
Submit Work Plans for EPA Approval
Project Meeting with EPA
Revisions to work plans
Submit final work plans
Subcontractor Contracts
Project Meeting wEPA
Field Investigation
Site Mobilization
Install Borings
Borehole Geophysics
Packer Testing amp Collect GW Samples
Pumping Test
Tracer Test
Test setup
Injection
Monitoring
Data Reporting
InstallDevelop Wells
Data Evaluation
Prepare Data Package
Data Package Submittal to EPA
Draft Tl Evaluation Repon
Draft Tl Evaluation Report Submttal to EPA
EPA ReviewComment on Tl Evaluation ReF
Project Meeting wEPA
Revisions to Tl Evaluation Report
Submit Final Tl Evaluation Report
Start
Wed 070903
Thu 071003
Fri 101003
Mon 120103
Mon 121503
Mon 122903
Mon 011204
Tue 011304
Thu 021904
Fri 032104
Fri 032604
Fri 040204
Fri 041604
Fri 042304
Thu 050604
Wed 060204
Wed 060204
Wed 060904
Wed 060904
Wed 062304
Wed 070704
Wed 042804
Wed 062304
Mon 080204
Mon 070504
Tue 082404
Wed 082504
Wed 091504
Thu 0916AM
Thu 093004
Finish
Wed 070903
Fri 1OtO7u3
Fri 112803
Fri 122603
Mon 121503
Fri 010904
Mon 011204
Mon 012604
Thu 021904
Tue 071304
Thu 040104
Thu 042204
Tue 042704
Wed 050504
Tue 052504
Tue 071304
Tue 060804
Tue 061504
Tue 070604
Tue 071304
Fri 070904
Tue 072004
Fri 073004
Mon 080204
Mon 082304
Tue 082404
Tue 091404
Wed 091504
Wed 082904
Thu 093004
FIGURE 4-1 DRAFT HOWS CORNER SUPERFUND SITE
Tl EVALUATION amp RELD WORK FOR HYDRAUUC CONTAINMENT SYSTEM DESIGN PROPOSED PROJECT SCHEDULE
2003 2004 Mav |
Jun | Jul
ltamp i
Aug
i
Sen Oct I Nov Dec Jan Feb I Mar
ii i i
k ^tr 1
1V i
I t bull ^
I
ta^M bull bull M W
l LgtH^HBKLii LJ Mi
I
bull bull raquo bull laquo^ 0930
Task Progress I^MLHHHI^LB Summary ^^^^^^^^f External Tasks M B WMMM Deadline ^7 Project Hows Comer Schedule6A bull bull bull 1 UData Fri 101003 Split Milestone ^ Project Summary ^f^KKKKKK^^ External Milestone ^
Pagei
50 ACRONYMS
AOC Administrative Order by Consent
ARARs Applicable or Relevant and Appropriate Requirements
ATV acoustic televiewer
bgs below ground surface
CERCLA Comprehensive Environmental Resource and Conservation Liability Act
DNAPL Dense Non-Aqueous Phase Liquid
GAC granular activated carbon
gpm gallons per minute
HASP Health and Safety Plan
row investigation-derived waste
MCL Maximum Containment Level
MEDEP Maine Department of Environmental Protection
MEG Maine Enforcement Guideline
mgkg milligrams per kilogram
Hg kg micrograms per kilogram
NCP National Contingency Plan
PCB polychlorinated biphenyl
PID photo ionization detector
ppm parts per million
PRP Potentially Responsible Party
TISOW WOODARD amp CURRAN 24 September 302003 20564309
QAPP Quality Assurance Project Plan
QAQC Quality AssuranceQuality Control
RA Remedial Action
RAO Remedial Action Objective
RCRA Resource Conservation and Recovery Act
RD Remedial Design
RIFS Remedial InvestigationFeasibility Study
ROD Record of Decision
SAP Sampling and Analysis Plan
SOW Statement of Work
TAL target analyte list
TI Technical Impracticability
USEPA United State Environmental Protection Agency
VOCs volatile organic compounds
WampC Woodard amp Curran Inc
TISOW WOODARD amp CURRAN 25 September 302003 20564309
REFERENCES
Everts CJ RS Kanwar (1994) Evaluation of Rhodamine WT as an adsorbed tracer in an agricultural
soil J Hydrology 153 53-70
Kasnavia T D Vu DA Sabatini (1999) Fluorescent dye and media properties affecting sorption and
tracer selection Groundwater 37 376-381
Ptak T G Schmid (1996) Dual-tracer transport experiments in a physically and chemically
heterogeneous porous aquifer effective transport parameters and spatial variability J Hydrology
183 117-138
Sabatini DA T A Austin (1991) Characteristics of Rhodamine WT and fluorescein as adsorbing
ground-water tracers Ground Water 29 341-349
Trudgill ST (1987) Soil water dye tracing with special reference to the use of Rhodamanie WT
Lissamine FF and Amino G acid Hydrological Processes 1 149-170
US Environmental Protection Agency (USEPA) 1993 Guidance for Evaluating the Technical
Impracticability of Ground-Water Restoration - Interim Final Office of Solid Waste and
Emergency Response Washington DC Directive 92342-25 September 1993
US Environmental Protection Agency (USEPA) 2002 Interim Record of Decision Summary shy
Operable Unit One Non-Source Area Groundwater West SiteHows Corner Superfund Site
Plymouth Maine EPA Region 1 September 2002
US Environmental Protection Agency (USEPA) 2003 Proposed Scope of Work West SiteHows
Corner Superfund Site Plymouth Maine EPA Region 1 4 pages September 2002
Vasudevan D RL Fimmen AB Francisco (2001) Tracer-grade Rhodamine WT Structure of
constituent isomers and their sorption behavior Environ Sci Technol 35 4089-4096
nsow WOODARD amp CURRAN 26 September 30 2003 20564309
Woodard amp Curran Inc (WampC) 2002 Final Feasibility Study Report - Non-Source Area Groundwater
Hows Comer Superfund Site Plymouth Maine July 2002
TISOW WOODARD amp CURRAN 27 September 302003 20564309
f
m WOODARD amp CURRAN Maine Massachusetts New Hampshire Connecticut Florida Illinois Operational offices across the US 1-800-426-4262 wwwwoodardcurrancom
i
Prior to injection of the tracer background concentration will be established by collecting samples from
up to six wells in the area of the tracer test and analyzing them for the tracer using an appropriate
analytical method Following injection of the tracer solutions the concentration of the tracer in
downgradient wells and borings will be measured A monitoring network will be established using nearby
monitoring wells Downhole probes will be installed in six new and existing wells near the injection well
to be identified in the work plan first to determine the background tracer concentrations and then to
monitor for the presence of the tracer upon initiation of the test Measurements will be collected at
periodic intervals to be determined based on the results of packer testing If an increase in tracer
concentration is detected or at a minimum on a weekly basis a water sample will be collected using low
flow sampling methodologies and analyzed in an off-site laboratory to evaluate the concentration of the
tracer The concentration of the tracer will be recorded Monitoring of the tracer concentration will
continue throughout the duration of the test The tracer will be allowed to flow with groundwater for one
month or until detected in wells in the vicinity of MW-106 whichever is shorter
313 Task 3 - TI Evaluation and Reporting
The TI Evaluation and reporting task includes the following five subtasks
bull Data evaluation
bull Summary data package
bull Draft TI Evaluation
bull Meetings with PRP Group and USEPA and
bull Revise and finalize TI Evaluation
As the subtasks of the field investigation are completed the data will be evaluated for the purpose of
addressing the data gaps identified by USEPA Specifically the data will be used to further refine the
cleanup times for non-source area groundwater presented in the Interim ROD
The data obtained during the field investigation will be reduced and evaluated and a summary data
package will be prepared that will include a discussion of the field activities completed and presentation
of the data It is anticipated that up to two meetings with USEPA will be necessary before the data
evaluation and summary report are completed
TISOW WOODARDampCURRAN 19 September 302003 20564309
Data collected during the pumping test will be analyzed with Aquifer Win32 Results will be summarized
in the summary data package and will also be presented as part of the RD submittals
Following submittal of the summary data package the TI evaluation will be prepared In accordance with
EPA guidance (1993) the TI waiver evaluation document will address the following topics
1 Specific ARARS or media cleanup standards for which TI determination is sought This section of the
TI Evaluation will identify the specific contaminants for which the TI determination is sought Based on
information available to date a waiver may be appropriate for pesticides PCBs chlorinated organic
compounds and other site-related contaminants that upon evaluation will not attain ARARs in a
reasonable period of time
2 Spatial area over which the TI waiver will apply The purpose of the additional site investigation
outlined in this SOW is to obtain the data necessary to further refine cleanup times presented in the
Interim ROD to determine what portions of the Site will not be expected to reach ARARs within a
reasonable time Consistent with TI guidance (USEPA 1993) the TI evaluation will specify the
horizontal and vertical extent of the area for which TI determination is sought Groundwater
concentration data from the RI and the TI SOW will be used to refine the distribution of the plume Data
from the drilling geophysical logging packer testing and pumping and tracer tests will be used to refine
the Site conceptual model and the cleanup times that will serve as the basis for establishing the scope and
nature of the TI zone
3 Conceptual Model The conceptual model forms the technical core of the TI Waiver Evaluation since
it provides basis for understanding of the restoration potential of the site The conceptual model outlines
the physical and hydrogeological constraints that hinder remediation or removal of Site contaminants and
it is the extent of these constraints rather than restoration timeframe alone that USEPA will use to
evaluate the necessity of the TI waiver of ARARs The conceptual model is the link between restoration
potential and restoration timeframe since it explains why proposed technologies are unlikely to work
either at all or within the desired 100-year timeframe
The Site conceptual model is not a mathematical model however as the result of the extensive modeling
and investigations of the site WampC has a strong understanding of the complex bedrock and overburden
TISOW WOODARDampCURRAN 20 September 302003 20564309
groundwater system beneath this site This understanding has been presented previously in both the RI
report and the FS and will be refined based on the TI SOW as necessary and summarized in the TI
Waiver Evaluation with specific attention to the physical and hydrogeological constraints on remediation
In particular the Site conceptual model will be reviewed in light of the new geologic data from drilling
logging and packer testing and the new hydrogeologic data obtained from the pumping test and tracer test
and will be revised to incorporate the new understanding
4 An evaluation of the restoration potential of the site This section will consist of a several components
It will present a systematic review of the technologies potentially capable of remediating the site given
the physical and hydrogeological constraints identified in the site model The newly acquired data will
provide an improved understanding of bedrock hydraulic properties that will allow a more Site-specific
evaluation of technologies The review of technologies will also include review of innovative
technologies and will evaluate whether existing remedial technologies or strategies would be capable of
achieving groundwater restoration at the site in a reasonable timeframe The section reference the FS and
will summarize the alternative remedies considered in the FS focusing on the ability of each to restore
groundwater in a reasonable timeframe It will also include a discussion of the selected hydraulic
containment system in light of the data gathered from the pumping test conducted in conjunction with the
TI SOW
Based on the Batch Flushing Model and using the agreed upon koc data from the RI as well as data from
this TI SOW including the f data collected as part of Subtask 4 a restoration timeframe analysis will be
conducted Following completion of the timeframe analysis and consideration of the results of drilling
rock and water analyses and pumping and tracer test a determination will be made regarding the Source
Area and the portion of the Non-Source Area VOC plume that will not attain ARARs in a reasonable
time
TISOW WOODARD amp CURRAN 21 September 302003 20564309
40 SCHEDULE
A proposed project schedule is included with this plan as Figure 4-1 This schedule is included for
discussion purposes and will be modified as necessary once the final scope of work as been approved by
all parties and the field work activities are coordinated with the subcontractors
TISOW WOODARD amp CURRAN 22 September 302003 20564309
ID
2
3
4
5
6
7 a i 10
11
12
13
14
15
16
17
16
19
20
21
22
24
25
26
27
26
29
30
31
32
Task Name
Project Meeting with EPA
Finalize SOW
Prepare Work Plans QAPP HASP Revision
Submit Work Plans for EPA Approval
Project Meeting with EPA
Revisions to work plans
Submit final work plans
Subcontractor Contracts
Project Meeting wEPA
Field Investigation
Site Mobilization
Install Borings
Borehole Geophysics
Packer Testing amp Collect GW Samples
Pumping Test
Tracer Test
Test setup
Injection
Monitoring
Data Reporting
InstallDevelop Wells
Data Evaluation
Prepare Data Package
Data Package Submittal to EPA
Draft Tl Evaluation Repon
Draft Tl Evaluation Report Submttal to EPA
EPA ReviewComment on Tl Evaluation ReF
Project Meeting wEPA
Revisions to Tl Evaluation Report
Submit Final Tl Evaluation Report
Start
Wed 070903
Thu 071003
Fri 101003
Mon 120103
Mon 121503
Mon 122903
Mon 011204
Tue 011304
Thu 021904
Fri 032104
Fri 032604
Fri 040204
Fri 041604
Fri 042304
Thu 050604
Wed 060204
Wed 060204
Wed 060904
Wed 060904
Wed 062304
Wed 070704
Wed 042804
Wed 062304
Mon 080204
Mon 070504
Tue 082404
Wed 082504
Wed 091504
Thu 0916AM
Thu 093004
Finish
Wed 070903
Fri 1OtO7u3
Fri 112803
Fri 122603
Mon 121503
Fri 010904
Mon 011204
Mon 012604
Thu 021904
Tue 071304
Thu 040104
Thu 042204
Tue 042704
Wed 050504
Tue 052504
Tue 071304
Tue 060804
Tue 061504
Tue 070604
Tue 071304
Fri 070904
Tue 072004
Fri 073004
Mon 080204
Mon 082304
Tue 082404
Tue 091404
Wed 091504
Wed 082904
Thu 093004
FIGURE 4-1 DRAFT HOWS CORNER SUPERFUND SITE
Tl EVALUATION amp RELD WORK FOR HYDRAUUC CONTAINMENT SYSTEM DESIGN PROPOSED PROJECT SCHEDULE
2003 2004 Mav |
Jun | Jul
ltamp i
Aug
i
Sen Oct I Nov Dec Jan Feb I Mar
ii i i
k ^tr 1
1V i
I t bull ^
I
ta^M bull bull M W
l LgtH^HBKLii LJ Mi
I
bull bull raquo bull laquo^ 0930
Task Progress I^MLHHHI^LB Summary ^^^^^^^^f External Tasks M B WMMM Deadline ^7 Project Hows Comer Schedule6A bull bull bull 1 UData Fri 101003 Split Milestone ^ Project Summary ^f^KKKKKK^^ External Milestone ^
Pagei
50 ACRONYMS
AOC Administrative Order by Consent
ARARs Applicable or Relevant and Appropriate Requirements
ATV acoustic televiewer
bgs below ground surface
CERCLA Comprehensive Environmental Resource and Conservation Liability Act
DNAPL Dense Non-Aqueous Phase Liquid
GAC granular activated carbon
gpm gallons per minute
HASP Health and Safety Plan
row investigation-derived waste
MCL Maximum Containment Level
MEDEP Maine Department of Environmental Protection
MEG Maine Enforcement Guideline
mgkg milligrams per kilogram
Hg kg micrograms per kilogram
NCP National Contingency Plan
PCB polychlorinated biphenyl
PID photo ionization detector
ppm parts per million
PRP Potentially Responsible Party
TISOW WOODARD amp CURRAN 24 September 302003 20564309
QAPP Quality Assurance Project Plan
QAQC Quality AssuranceQuality Control
RA Remedial Action
RAO Remedial Action Objective
RCRA Resource Conservation and Recovery Act
RD Remedial Design
RIFS Remedial InvestigationFeasibility Study
ROD Record of Decision
SAP Sampling and Analysis Plan
SOW Statement of Work
TAL target analyte list
TI Technical Impracticability
USEPA United State Environmental Protection Agency
VOCs volatile organic compounds
WampC Woodard amp Curran Inc
TISOW WOODARD amp CURRAN 25 September 302003 20564309
REFERENCES
Everts CJ RS Kanwar (1994) Evaluation of Rhodamine WT as an adsorbed tracer in an agricultural
soil J Hydrology 153 53-70
Kasnavia T D Vu DA Sabatini (1999) Fluorescent dye and media properties affecting sorption and
tracer selection Groundwater 37 376-381
Ptak T G Schmid (1996) Dual-tracer transport experiments in a physically and chemically
heterogeneous porous aquifer effective transport parameters and spatial variability J Hydrology
183 117-138
Sabatini DA T A Austin (1991) Characteristics of Rhodamine WT and fluorescein as adsorbing
ground-water tracers Ground Water 29 341-349
Trudgill ST (1987) Soil water dye tracing with special reference to the use of Rhodamanie WT
Lissamine FF and Amino G acid Hydrological Processes 1 149-170
US Environmental Protection Agency (USEPA) 1993 Guidance for Evaluating the Technical
Impracticability of Ground-Water Restoration - Interim Final Office of Solid Waste and
Emergency Response Washington DC Directive 92342-25 September 1993
US Environmental Protection Agency (USEPA) 2002 Interim Record of Decision Summary shy
Operable Unit One Non-Source Area Groundwater West SiteHows Corner Superfund Site
Plymouth Maine EPA Region 1 September 2002
US Environmental Protection Agency (USEPA) 2003 Proposed Scope of Work West SiteHows
Corner Superfund Site Plymouth Maine EPA Region 1 4 pages September 2002
Vasudevan D RL Fimmen AB Francisco (2001) Tracer-grade Rhodamine WT Structure of
constituent isomers and their sorption behavior Environ Sci Technol 35 4089-4096
nsow WOODARD amp CURRAN 26 September 30 2003 20564309
Woodard amp Curran Inc (WampC) 2002 Final Feasibility Study Report - Non-Source Area Groundwater
Hows Comer Superfund Site Plymouth Maine July 2002
TISOW WOODARD amp CURRAN 27 September 302003 20564309
f
m WOODARD amp CURRAN Maine Massachusetts New Hampshire Connecticut Florida Illinois Operational offices across the US 1-800-426-4262 wwwwoodardcurrancom
i
Data collected during the pumping test will be analyzed with Aquifer Win32 Results will be summarized
in the summary data package and will also be presented as part of the RD submittals
Following submittal of the summary data package the TI evaluation will be prepared In accordance with
EPA guidance (1993) the TI waiver evaluation document will address the following topics
1 Specific ARARS or media cleanup standards for which TI determination is sought This section of the
TI Evaluation will identify the specific contaminants for which the TI determination is sought Based on
information available to date a waiver may be appropriate for pesticides PCBs chlorinated organic
compounds and other site-related contaminants that upon evaluation will not attain ARARs in a
reasonable period of time
2 Spatial area over which the TI waiver will apply The purpose of the additional site investigation
outlined in this SOW is to obtain the data necessary to further refine cleanup times presented in the
Interim ROD to determine what portions of the Site will not be expected to reach ARARs within a
reasonable time Consistent with TI guidance (USEPA 1993) the TI evaluation will specify the
horizontal and vertical extent of the area for which TI determination is sought Groundwater
concentration data from the RI and the TI SOW will be used to refine the distribution of the plume Data
from the drilling geophysical logging packer testing and pumping and tracer tests will be used to refine
the Site conceptual model and the cleanup times that will serve as the basis for establishing the scope and
nature of the TI zone
3 Conceptual Model The conceptual model forms the technical core of the TI Waiver Evaluation since
it provides basis for understanding of the restoration potential of the site The conceptual model outlines
the physical and hydrogeological constraints that hinder remediation or removal of Site contaminants and
it is the extent of these constraints rather than restoration timeframe alone that USEPA will use to
evaluate the necessity of the TI waiver of ARARs The conceptual model is the link between restoration
potential and restoration timeframe since it explains why proposed technologies are unlikely to work
either at all or within the desired 100-year timeframe
The Site conceptual model is not a mathematical model however as the result of the extensive modeling
and investigations of the site WampC has a strong understanding of the complex bedrock and overburden
TISOW WOODARDampCURRAN 20 September 302003 20564309
groundwater system beneath this site This understanding has been presented previously in both the RI
report and the FS and will be refined based on the TI SOW as necessary and summarized in the TI
Waiver Evaluation with specific attention to the physical and hydrogeological constraints on remediation
In particular the Site conceptual model will be reviewed in light of the new geologic data from drilling
logging and packer testing and the new hydrogeologic data obtained from the pumping test and tracer test
and will be revised to incorporate the new understanding
4 An evaluation of the restoration potential of the site This section will consist of a several components
It will present a systematic review of the technologies potentially capable of remediating the site given
the physical and hydrogeological constraints identified in the site model The newly acquired data will
provide an improved understanding of bedrock hydraulic properties that will allow a more Site-specific
evaluation of technologies The review of technologies will also include review of innovative
technologies and will evaluate whether existing remedial technologies or strategies would be capable of
achieving groundwater restoration at the site in a reasonable timeframe The section reference the FS and
will summarize the alternative remedies considered in the FS focusing on the ability of each to restore
groundwater in a reasonable timeframe It will also include a discussion of the selected hydraulic
containment system in light of the data gathered from the pumping test conducted in conjunction with the
TI SOW
Based on the Batch Flushing Model and using the agreed upon koc data from the RI as well as data from
this TI SOW including the f data collected as part of Subtask 4 a restoration timeframe analysis will be
conducted Following completion of the timeframe analysis and consideration of the results of drilling
rock and water analyses and pumping and tracer test a determination will be made regarding the Source
Area and the portion of the Non-Source Area VOC plume that will not attain ARARs in a reasonable
time
TISOW WOODARD amp CURRAN 21 September 302003 20564309
40 SCHEDULE
A proposed project schedule is included with this plan as Figure 4-1 This schedule is included for
discussion purposes and will be modified as necessary once the final scope of work as been approved by
all parties and the field work activities are coordinated with the subcontractors
TISOW WOODARD amp CURRAN 22 September 302003 20564309
ID
2
3
4
5
6
7 a i 10
11
12
13
14
15
16
17
16
19
20
21
22
24
25
26
27
26
29
30
31
32
Task Name
Project Meeting with EPA
Finalize SOW
Prepare Work Plans QAPP HASP Revision
Submit Work Plans for EPA Approval
Project Meeting with EPA
Revisions to work plans
Submit final work plans
Subcontractor Contracts
Project Meeting wEPA
Field Investigation
Site Mobilization
Install Borings
Borehole Geophysics
Packer Testing amp Collect GW Samples
Pumping Test
Tracer Test
Test setup
Injection
Monitoring
Data Reporting
InstallDevelop Wells
Data Evaluation
Prepare Data Package
Data Package Submittal to EPA
Draft Tl Evaluation Repon
Draft Tl Evaluation Report Submttal to EPA
EPA ReviewComment on Tl Evaluation ReF
Project Meeting wEPA
Revisions to Tl Evaluation Report
Submit Final Tl Evaluation Report
Start
Wed 070903
Thu 071003
Fri 101003
Mon 120103
Mon 121503
Mon 122903
Mon 011204
Tue 011304
Thu 021904
Fri 032104
Fri 032604
Fri 040204
Fri 041604
Fri 042304
Thu 050604
Wed 060204
Wed 060204
Wed 060904
Wed 060904
Wed 062304
Wed 070704
Wed 042804
Wed 062304
Mon 080204
Mon 070504
Tue 082404
Wed 082504
Wed 091504
Thu 0916AM
Thu 093004
Finish
Wed 070903
Fri 1OtO7u3
Fri 112803
Fri 122603
Mon 121503
Fri 010904
Mon 011204
Mon 012604
Thu 021904
Tue 071304
Thu 040104
Thu 042204
Tue 042704
Wed 050504
Tue 052504
Tue 071304
Tue 060804
Tue 061504
Tue 070604
Tue 071304
Fri 070904
Tue 072004
Fri 073004
Mon 080204
Mon 082304
Tue 082404
Tue 091404
Wed 091504
Wed 082904
Thu 093004
FIGURE 4-1 DRAFT HOWS CORNER SUPERFUND SITE
Tl EVALUATION amp RELD WORK FOR HYDRAUUC CONTAINMENT SYSTEM DESIGN PROPOSED PROJECT SCHEDULE
2003 2004 Mav |
Jun | Jul
ltamp i
Aug
i
Sen Oct I Nov Dec Jan Feb I Mar
ii i i
k ^tr 1
1V i
I t bull ^
I
ta^M bull bull M W
l LgtH^HBKLii LJ Mi
I
bull bull raquo bull laquo^ 0930
Task Progress I^MLHHHI^LB Summary ^^^^^^^^f External Tasks M B WMMM Deadline ^7 Project Hows Comer Schedule6A bull bull bull 1 UData Fri 101003 Split Milestone ^ Project Summary ^f^KKKKKK^^ External Milestone ^
Pagei
50 ACRONYMS
AOC Administrative Order by Consent
ARARs Applicable or Relevant and Appropriate Requirements
ATV acoustic televiewer
bgs below ground surface
CERCLA Comprehensive Environmental Resource and Conservation Liability Act
DNAPL Dense Non-Aqueous Phase Liquid
GAC granular activated carbon
gpm gallons per minute
HASP Health and Safety Plan
row investigation-derived waste
MCL Maximum Containment Level
MEDEP Maine Department of Environmental Protection
MEG Maine Enforcement Guideline
mgkg milligrams per kilogram
Hg kg micrograms per kilogram
NCP National Contingency Plan
PCB polychlorinated biphenyl
PID photo ionization detector
ppm parts per million
PRP Potentially Responsible Party
TISOW WOODARD amp CURRAN 24 September 302003 20564309
QAPP Quality Assurance Project Plan
QAQC Quality AssuranceQuality Control
RA Remedial Action
RAO Remedial Action Objective
RCRA Resource Conservation and Recovery Act
RD Remedial Design
RIFS Remedial InvestigationFeasibility Study
ROD Record of Decision
SAP Sampling and Analysis Plan
SOW Statement of Work
TAL target analyte list
TI Technical Impracticability
USEPA United State Environmental Protection Agency
VOCs volatile organic compounds
WampC Woodard amp Curran Inc
TISOW WOODARD amp CURRAN 25 September 302003 20564309
REFERENCES
Everts CJ RS Kanwar (1994) Evaluation of Rhodamine WT as an adsorbed tracer in an agricultural
soil J Hydrology 153 53-70
Kasnavia T D Vu DA Sabatini (1999) Fluorescent dye and media properties affecting sorption and
tracer selection Groundwater 37 376-381
Ptak T G Schmid (1996) Dual-tracer transport experiments in a physically and chemically
heterogeneous porous aquifer effective transport parameters and spatial variability J Hydrology
183 117-138
Sabatini DA T A Austin (1991) Characteristics of Rhodamine WT and fluorescein as adsorbing
ground-water tracers Ground Water 29 341-349
Trudgill ST (1987) Soil water dye tracing with special reference to the use of Rhodamanie WT
Lissamine FF and Amino G acid Hydrological Processes 1 149-170
US Environmental Protection Agency (USEPA) 1993 Guidance for Evaluating the Technical
Impracticability of Ground-Water Restoration - Interim Final Office of Solid Waste and
Emergency Response Washington DC Directive 92342-25 September 1993
US Environmental Protection Agency (USEPA) 2002 Interim Record of Decision Summary shy
Operable Unit One Non-Source Area Groundwater West SiteHows Corner Superfund Site
Plymouth Maine EPA Region 1 September 2002
US Environmental Protection Agency (USEPA) 2003 Proposed Scope of Work West SiteHows
Corner Superfund Site Plymouth Maine EPA Region 1 4 pages September 2002
Vasudevan D RL Fimmen AB Francisco (2001) Tracer-grade Rhodamine WT Structure of
constituent isomers and their sorption behavior Environ Sci Technol 35 4089-4096
nsow WOODARD amp CURRAN 26 September 30 2003 20564309
Woodard amp Curran Inc (WampC) 2002 Final Feasibility Study Report - Non-Source Area Groundwater
Hows Comer Superfund Site Plymouth Maine July 2002
TISOW WOODARD amp CURRAN 27 September 302003 20564309
f
m WOODARD amp CURRAN Maine Massachusetts New Hampshire Connecticut Florida Illinois Operational offices across the US 1-800-426-4262 wwwwoodardcurrancom
i
groundwater system beneath this site This understanding has been presented previously in both the RI
report and the FS and will be refined based on the TI SOW as necessary and summarized in the TI
Waiver Evaluation with specific attention to the physical and hydrogeological constraints on remediation
In particular the Site conceptual model will be reviewed in light of the new geologic data from drilling
logging and packer testing and the new hydrogeologic data obtained from the pumping test and tracer test
and will be revised to incorporate the new understanding
4 An evaluation of the restoration potential of the site This section will consist of a several components
It will present a systematic review of the technologies potentially capable of remediating the site given
the physical and hydrogeological constraints identified in the site model The newly acquired data will
provide an improved understanding of bedrock hydraulic properties that will allow a more Site-specific
evaluation of technologies The review of technologies will also include review of innovative
technologies and will evaluate whether existing remedial technologies or strategies would be capable of
achieving groundwater restoration at the site in a reasonable timeframe The section reference the FS and
will summarize the alternative remedies considered in the FS focusing on the ability of each to restore
groundwater in a reasonable timeframe It will also include a discussion of the selected hydraulic
containment system in light of the data gathered from the pumping test conducted in conjunction with the
TI SOW
Based on the Batch Flushing Model and using the agreed upon koc data from the RI as well as data from
this TI SOW including the f data collected as part of Subtask 4 a restoration timeframe analysis will be
conducted Following completion of the timeframe analysis and consideration of the results of drilling
rock and water analyses and pumping and tracer test a determination will be made regarding the Source
Area and the portion of the Non-Source Area VOC plume that will not attain ARARs in a reasonable
time
TISOW WOODARD amp CURRAN 21 September 302003 20564309
40 SCHEDULE
A proposed project schedule is included with this plan as Figure 4-1 This schedule is included for
discussion purposes and will be modified as necessary once the final scope of work as been approved by
all parties and the field work activities are coordinated with the subcontractors
TISOW WOODARD amp CURRAN 22 September 302003 20564309
ID
2
3
4
5
6
7 a i 10
11
12
13
14
15
16
17
16
19
20
21
22
24
25
26
27
26
29
30
31
32
Task Name
Project Meeting with EPA
Finalize SOW
Prepare Work Plans QAPP HASP Revision
Submit Work Plans for EPA Approval
Project Meeting with EPA
Revisions to work plans
Submit final work plans
Subcontractor Contracts
Project Meeting wEPA
Field Investigation
Site Mobilization
Install Borings
Borehole Geophysics
Packer Testing amp Collect GW Samples
Pumping Test
Tracer Test
Test setup
Injection
Monitoring
Data Reporting
InstallDevelop Wells
Data Evaluation
Prepare Data Package
Data Package Submittal to EPA
Draft Tl Evaluation Repon
Draft Tl Evaluation Report Submttal to EPA
EPA ReviewComment on Tl Evaluation ReF
Project Meeting wEPA
Revisions to Tl Evaluation Report
Submit Final Tl Evaluation Report
Start
Wed 070903
Thu 071003
Fri 101003
Mon 120103
Mon 121503
Mon 122903
Mon 011204
Tue 011304
Thu 021904
Fri 032104
Fri 032604
Fri 040204
Fri 041604
Fri 042304
Thu 050604
Wed 060204
Wed 060204
Wed 060904
Wed 060904
Wed 062304
Wed 070704
Wed 042804
Wed 062304
Mon 080204
Mon 070504
Tue 082404
Wed 082504
Wed 091504
Thu 0916AM
Thu 093004
Finish
Wed 070903
Fri 1OtO7u3
Fri 112803
Fri 122603
Mon 121503
Fri 010904
Mon 011204
Mon 012604
Thu 021904
Tue 071304
Thu 040104
Thu 042204
Tue 042704
Wed 050504
Tue 052504
Tue 071304
Tue 060804
Tue 061504
Tue 070604
Tue 071304
Fri 070904
Tue 072004
Fri 073004
Mon 080204
Mon 082304
Tue 082404
Tue 091404
Wed 091504
Wed 082904
Thu 093004
FIGURE 4-1 DRAFT HOWS CORNER SUPERFUND SITE
Tl EVALUATION amp RELD WORK FOR HYDRAUUC CONTAINMENT SYSTEM DESIGN PROPOSED PROJECT SCHEDULE
2003 2004 Mav |
Jun | Jul
ltamp i
Aug
i
Sen Oct I Nov Dec Jan Feb I Mar
ii i i
k ^tr 1
1V i
I t bull ^
I
ta^M bull bull M W
l LgtH^HBKLii LJ Mi
I
bull bull raquo bull laquo^ 0930
Task Progress I^MLHHHI^LB Summary ^^^^^^^^f External Tasks M B WMMM Deadline ^7 Project Hows Comer Schedule6A bull bull bull 1 UData Fri 101003 Split Milestone ^ Project Summary ^f^KKKKKK^^ External Milestone ^
Pagei
50 ACRONYMS
AOC Administrative Order by Consent
ARARs Applicable or Relevant and Appropriate Requirements
ATV acoustic televiewer
bgs below ground surface
CERCLA Comprehensive Environmental Resource and Conservation Liability Act
DNAPL Dense Non-Aqueous Phase Liquid
GAC granular activated carbon
gpm gallons per minute
HASP Health and Safety Plan
row investigation-derived waste
MCL Maximum Containment Level
MEDEP Maine Department of Environmental Protection
MEG Maine Enforcement Guideline
mgkg milligrams per kilogram
Hg kg micrograms per kilogram
NCP National Contingency Plan
PCB polychlorinated biphenyl
PID photo ionization detector
ppm parts per million
PRP Potentially Responsible Party
TISOW WOODARD amp CURRAN 24 September 302003 20564309
QAPP Quality Assurance Project Plan
QAQC Quality AssuranceQuality Control
RA Remedial Action
RAO Remedial Action Objective
RCRA Resource Conservation and Recovery Act
RD Remedial Design
RIFS Remedial InvestigationFeasibility Study
ROD Record of Decision
SAP Sampling and Analysis Plan
SOW Statement of Work
TAL target analyte list
TI Technical Impracticability
USEPA United State Environmental Protection Agency
VOCs volatile organic compounds
WampC Woodard amp Curran Inc
TISOW WOODARD amp CURRAN 25 September 302003 20564309
REFERENCES
Everts CJ RS Kanwar (1994) Evaluation of Rhodamine WT as an adsorbed tracer in an agricultural
soil J Hydrology 153 53-70
Kasnavia T D Vu DA Sabatini (1999) Fluorescent dye and media properties affecting sorption and
tracer selection Groundwater 37 376-381
Ptak T G Schmid (1996) Dual-tracer transport experiments in a physically and chemically
heterogeneous porous aquifer effective transport parameters and spatial variability J Hydrology
183 117-138
Sabatini DA T A Austin (1991) Characteristics of Rhodamine WT and fluorescein as adsorbing
ground-water tracers Ground Water 29 341-349
Trudgill ST (1987) Soil water dye tracing with special reference to the use of Rhodamanie WT
Lissamine FF and Amino G acid Hydrological Processes 1 149-170
US Environmental Protection Agency (USEPA) 1993 Guidance for Evaluating the Technical
Impracticability of Ground-Water Restoration - Interim Final Office of Solid Waste and
Emergency Response Washington DC Directive 92342-25 September 1993
US Environmental Protection Agency (USEPA) 2002 Interim Record of Decision Summary shy
Operable Unit One Non-Source Area Groundwater West SiteHows Corner Superfund Site
Plymouth Maine EPA Region 1 September 2002
US Environmental Protection Agency (USEPA) 2003 Proposed Scope of Work West SiteHows
Corner Superfund Site Plymouth Maine EPA Region 1 4 pages September 2002
Vasudevan D RL Fimmen AB Francisco (2001) Tracer-grade Rhodamine WT Structure of
constituent isomers and their sorption behavior Environ Sci Technol 35 4089-4096
nsow WOODARD amp CURRAN 26 September 30 2003 20564309
Woodard amp Curran Inc (WampC) 2002 Final Feasibility Study Report - Non-Source Area Groundwater
Hows Comer Superfund Site Plymouth Maine July 2002
TISOW WOODARD amp CURRAN 27 September 302003 20564309
f
m WOODARD amp CURRAN Maine Massachusetts New Hampshire Connecticut Florida Illinois Operational offices across the US 1-800-426-4262 wwwwoodardcurrancom
i
40 SCHEDULE
A proposed project schedule is included with this plan as Figure 4-1 This schedule is included for
discussion purposes and will be modified as necessary once the final scope of work as been approved by
all parties and the field work activities are coordinated with the subcontractors
TISOW WOODARD amp CURRAN 22 September 302003 20564309
ID
2
3
4
5
6
7 a i 10
11
12
13
14
15
16
17
16
19
20
21
22
24
25
26
27
26
29
30
31
32
Task Name
Project Meeting with EPA
Finalize SOW
Prepare Work Plans QAPP HASP Revision
Submit Work Plans for EPA Approval
Project Meeting with EPA
Revisions to work plans
Submit final work plans
Subcontractor Contracts
Project Meeting wEPA
Field Investigation
Site Mobilization
Install Borings
Borehole Geophysics
Packer Testing amp Collect GW Samples
Pumping Test
Tracer Test
Test setup
Injection
Monitoring
Data Reporting
InstallDevelop Wells
Data Evaluation
Prepare Data Package
Data Package Submittal to EPA
Draft Tl Evaluation Repon
Draft Tl Evaluation Report Submttal to EPA
EPA ReviewComment on Tl Evaluation ReF
Project Meeting wEPA
Revisions to Tl Evaluation Report
Submit Final Tl Evaluation Report
Start
Wed 070903
Thu 071003
Fri 101003
Mon 120103
Mon 121503
Mon 122903
Mon 011204
Tue 011304
Thu 021904
Fri 032104
Fri 032604
Fri 040204
Fri 041604
Fri 042304
Thu 050604
Wed 060204
Wed 060204
Wed 060904
Wed 060904
Wed 062304
Wed 070704
Wed 042804
Wed 062304
Mon 080204
Mon 070504
Tue 082404
Wed 082504
Wed 091504
Thu 0916AM
Thu 093004
Finish
Wed 070903
Fri 1OtO7u3
Fri 112803
Fri 122603
Mon 121503
Fri 010904
Mon 011204
Mon 012604
Thu 021904
Tue 071304
Thu 040104
Thu 042204
Tue 042704
Wed 050504
Tue 052504
Tue 071304
Tue 060804
Tue 061504
Tue 070604
Tue 071304
Fri 070904
Tue 072004
Fri 073004
Mon 080204
Mon 082304
Tue 082404
Tue 091404
Wed 091504
Wed 082904
Thu 093004
FIGURE 4-1 DRAFT HOWS CORNER SUPERFUND SITE
Tl EVALUATION amp RELD WORK FOR HYDRAUUC CONTAINMENT SYSTEM DESIGN PROPOSED PROJECT SCHEDULE
2003 2004 Mav |
Jun | Jul
ltamp i
Aug
i
Sen Oct I Nov Dec Jan Feb I Mar
ii i i
k ^tr 1
1V i
I t bull ^
I
ta^M bull bull M W
l LgtH^HBKLii LJ Mi
I
bull bull raquo bull laquo^ 0930
Task Progress I^MLHHHI^LB Summary ^^^^^^^^f External Tasks M B WMMM Deadline ^7 Project Hows Comer Schedule6A bull bull bull 1 UData Fri 101003 Split Milestone ^ Project Summary ^f^KKKKKK^^ External Milestone ^
Pagei
50 ACRONYMS
AOC Administrative Order by Consent
ARARs Applicable or Relevant and Appropriate Requirements
ATV acoustic televiewer
bgs below ground surface
CERCLA Comprehensive Environmental Resource and Conservation Liability Act
DNAPL Dense Non-Aqueous Phase Liquid
GAC granular activated carbon
gpm gallons per minute
HASP Health and Safety Plan
row investigation-derived waste
MCL Maximum Containment Level
MEDEP Maine Department of Environmental Protection
MEG Maine Enforcement Guideline
mgkg milligrams per kilogram
Hg kg micrograms per kilogram
NCP National Contingency Plan
PCB polychlorinated biphenyl
PID photo ionization detector
ppm parts per million
PRP Potentially Responsible Party
TISOW WOODARD amp CURRAN 24 September 302003 20564309
QAPP Quality Assurance Project Plan
QAQC Quality AssuranceQuality Control
RA Remedial Action
RAO Remedial Action Objective
RCRA Resource Conservation and Recovery Act
RD Remedial Design
RIFS Remedial InvestigationFeasibility Study
ROD Record of Decision
SAP Sampling and Analysis Plan
SOW Statement of Work
TAL target analyte list
TI Technical Impracticability
USEPA United State Environmental Protection Agency
VOCs volatile organic compounds
WampC Woodard amp Curran Inc
TISOW WOODARD amp CURRAN 25 September 302003 20564309
REFERENCES
Everts CJ RS Kanwar (1994) Evaluation of Rhodamine WT as an adsorbed tracer in an agricultural
soil J Hydrology 153 53-70
Kasnavia T D Vu DA Sabatini (1999) Fluorescent dye and media properties affecting sorption and
tracer selection Groundwater 37 376-381
Ptak T G Schmid (1996) Dual-tracer transport experiments in a physically and chemically
heterogeneous porous aquifer effective transport parameters and spatial variability J Hydrology
183 117-138
Sabatini DA T A Austin (1991) Characteristics of Rhodamine WT and fluorescein as adsorbing
ground-water tracers Ground Water 29 341-349
Trudgill ST (1987) Soil water dye tracing with special reference to the use of Rhodamanie WT
Lissamine FF and Amino G acid Hydrological Processes 1 149-170
US Environmental Protection Agency (USEPA) 1993 Guidance for Evaluating the Technical
Impracticability of Ground-Water Restoration - Interim Final Office of Solid Waste and
Emergency Response Washington DC Directive 92342-25 September 1993
US Environmental Protection Agency (USEPA) 2002 Interim Record of Decision Summary shy
Operable Unit One Non-Source Area Groundwater West SiteHows Corner Superfund Site
Plymouth Maine EPA Region 1 September 2002
US Environmental Protection Agency (USEPA) 2003 Proposed Scope of Work West SiteHows
Corner Superfund Site Plymouth Maine EPA Region 1 4 pages September 2002
Vasudevan D RL Fimmen AB Francisco (2001) Tracer-grade Rhodamine WT Structure of
constituent isomers and their sorption behavior Environ Sci Technol 35 4089-4096
nsow WOODARD amp CURRAN 26 September 30 2003 20564309
Woodard amp Curran Inc (WampC) 2002 Final Feasibility Study Report - Non-Source Area Groundwater
Hows Comer Superfund Site Plymouth Maine July 2002
TISOW WOODARD amp CURRAN 27 September 302003 20564309
f
m WOODARD amp CURRAN Maine Massachusetts New Hampshire Connecticut Florida Illinois Operational offices across the US 1-800-426-4262 wwwwoodardcurrancom
i
ID
2
3
4
5
6
7 a i 10
11
12
13
14
15
16
17
16
19
20
21
22
24
25
26
27
26
29
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32
Task Name
Project Meeting with EPA
Finalize SOW
Prepare Work Plans QAPP HASP Revision
Submit Work Plans for EPA Approval
Project Meeting with EPA
Revisions to work plans
Submit final work plans
Subcontractor Contracts
Project Meeting wEPA
Field Investigation
Site Mobilization
Install Borings
Borehole Geophysics
Packer Testing amp Collect GW Samples
Pumping Test
Tracer Test
Test setup
Injection
Monitoring
Data Reporting
InstallDevelop Wells
Data Evaluation
Prepare Data Package
Data Package Submittal to EPA
Draft Tl Evaluation Repon
Draft Tl Evaluation Report Submttal to EPA
EPA ReviewComment on Tl Evaluation ReF
Project Meeting wEPA
Revisions to Tl Evaluation Report
Submit Final Tl Evaluation Report
Start
Wed 070903
Thu 071003
Fri 101003
Mon 120103
Mon 121503
Mon 122903
Mon 011204
Tue 011304
Thu 021904
Fri 032104
Fri 032604
Fri 040204
Fri 041604
Fri 042304
Thu 050604
Wed 060204
Wed 060204
Wed 060904
Wed 060904
Wed 062304
Wed 070704
Wed 042804
Wed 062304
Mon 080204
Mon 070504
Tue 082404
Wed 082504
Wed 091504
Thu 0916AM
Thu 093004
Finish
Wed 070903
Fri 1OtO7u3
Fri 112803
Fri 122603
Mon 121503
Fri 010904
Mon 011204
Mon 012604
Thu 021904
Tue 071304
Thu 040104
Thu 042204
Tue 042704
Wed 050504
Tue 052504
Tue 071304
Tue 060804
Tue 061504
Tue 070604
Tue 071304
Fri 070904
Tue 072004
Fri 073004
Mon 080204
Mon 082304
Tue 082404
Tue 091404
Wed 091504
Wed 082904
Thu 093004
FIGURE 4-1 DRAFT HOWS CORNER SUPERFUND SITE
Tl EVALUATION amp RELD WORK FOR HYDRAUUC CONTAINMENT SYSTEM DESIGN PROPOSED PROJECT SCHEDULE
2003 2004 Mav |
Jun | Jul
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Aug
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Sen Oct I Nov Dec Jan Feb I Mar
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1V i
I t bull ^
I
ta^M bull bull M W
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I
bull bull raquo bull laquo^ 0930
Task Progress I^MLHHHI^LB Summary ^^^^^^^^f External Tasks M B WMMM Deadline ^7 Project Hows Comer Schedule6A bull bull bull 1 UData Fri 101003 Split Milestone ^ Project Summary ^f^KKKKKK^^ External Milestone ^
Pagei
50 ACRONYMS
AOC Administrative Order by Consent
ARARs Applicable or Relevant and Appropriate Requirements
ATV acoustic televiewer
bgs below ground surface
CERCLA Comprehensive Environmental Resource and Conservation Liability Act
DNAPL Dense Non-Aqueous Phase Liquid
GAC granular activated carbon
gpm gallons per minute
HASP Health and Safety Plan
row investigation-derived waste
MCL Maximum Containment Level
MEDEP Maine Department of Environmental Protection
MEG Maine Enforcement Guideline
mgkg milligrams per kilogram
Hg kg micrograms per kilogram
NCP National Contingency Plan
PCB polychlorinated biphenyl
PID photo ionization detector
ppm parts per million
PRP Potentially Responsible Party
TISOW WOODARD amp CURRAN 24 September 302003 20564309
QAPP Quality Assurance Project Plan
QAQC Quality AssuranceQuality Control
RA Remedial Action
RAO Remedial Action Objective
RCRA Resource Conservation and Recovery Act
RD Remedial Design
RIFS Remedial InvestigationFeasibility Study
ROD Record of Decision
SAP Sampling and Analysis Plan
SOW Statement of Work
TAL target analyte list
TI Technical Impracticability
USEPA United State Environmental Protection Agency
VOCs volatile organic compounds
WampC Woodard amp Curran Inc
TISOW WOODARD amp CURRAN 25 September 302003 20564309
REFERENCES
Everts CJ RS Kanwar (1994) Evaluation of Rhodamine WT as an adsorbed tracer in an agricultural
soil J Hydrology 153 53-70
Kasnavia T D Vu DA Sabatini (1999) Fluorescent dye and media properties affecting sorption and
tracer selection Groundwater 37 376-381
Ptak T G Schmid (1996) Dual-tracer transport experiments in a physically and chemically
heterogeneous porous aquifer effective transport parameters and spatial variability J Hydrology
183 117-138
Sabatini DA T A Austin (1991) Characteristics of Rhodamine WT and fluorescein as adsorbing
ground-water tracers Ground Water 29 341-349
Trudgill ST (1987) Soil water dye tracing with special reference to the use of Rhodamanie WT
Lissamine FF and Amino G acid Hydrological Processes 1 149-170
US Environmental Protection Agency (USEPA) 1993 Guidance for Evaluating the Technical
Impracticability of Ground-Water Restoration - Interim Final Office of Solid Waste and
Emergency Response Washington DC Directive 92342-25 September 1993
US Environmental Protection Agency (USEPA) 2002 Interim Record of Decision Summary shy
Operable Unit One Non-Source Area Groundwater West SiteHows Corner Superfund Site
Plymouth Maine EPA Region 1 September 2002
US Environmental Protection Agency (USEPA) 2003 Proposed Scope of Work West SiteHows
Corner Superfund Site Plymouth Maine EPA Region 1 4 pages September 2002
Vasudevan D RL Fimmen AB Francisco (2001) Tracer-grade Rhodamine WT Structure of
constituent isomers and their sorption behavior Environ Sci Technol 35 4089-4096
nsow WOODARD amp CURRAN 26 September 30 2003 20564309
Woodard amp Curran Inc (WampC) 2002 Final Feasibility Study Report - Non-Source Area Groundwater
Hows Comer Superfund Site Plymouth Maine July 2002
TISOW WOODARD amp CURRAN 27 September 302003 20564309
f
m WOODARD amp CURRAN Maine Massachusetts New Hampshire Connecticut Florida Illinois Operational offices across the US 1-800-426-4262 wwwwoodardcurrancom
i
50 ACRONYMS
AOC Administrative Order by Consent
ARARs Applicable or Relevant and Appropriate Requirements
ATV acoustic televiewer
bgs below ground surface
CERCLA Comprehensive Environmental Resource and Conservation Liability Act
DNAPL Dense Non-Aqueous Phase Liquid
GAC granular activated carbon
gpm gallons per minute
HASP Health and Safety Plan
row investigation-derived waste
MCL Maximum Containment Level
MEDEP Maine Department of Environmental Protection
MEG Maine Enforcement Guideline
mgkg milligrams per kilogram
Hg kg micrograms per kilogram
NCP National Contingency Plan
PCB polychlorinated biphenyl
PID photo ionization detector
ppm parts per million
PRP Potentially Responsible Party
TISOW WOODARD amp CURRAN 24 September 302003 20564309
QAPP Quality Assurance Project Plan
QAQC Quality AssuranceQuality Control
RA Remedial Action
RAO Remedial Action Objective
RCRA Resource Conservation and Recovery Act
RD Remedial Design
RIFS Remedial InvestigationFeasibility Study
ROD Record of Decision
SAP Sampling and Analysis Plan
SOW Statement of Work
TAL target analyte list
TI Technical Impracticability
USEPA United State Environmental Protection Agency
VOCs volatile organic compounds
WampC Woodard amp Curran Inc
TISOW WOODARD amp CURRAN 25 September 302003 20564309
REFERENCES
Everts CJ RS Kanwar (1994) Evaluation of Rhodamine WT as an adsorbed tracer in an agricultural
soil J Hydrology 153 53-70
Kasnavia T D Vu DA Sabatini (1999) Fluorescent dye and media properties affecting sorption and
tracer selection Groundwater 37 376-381
Ptak T G Schmid (1996) Dual-tracer transport experiments in a physically and chemically
heterogeneous porous aquifer effective transport parameters and spatial variability J Hydrology
183 117-138
Sabatini DA T A Austin (1991) Characteristics of Rhodamine WT and fluorescein as adsorbing
ground-water tracers Ground Water 29 341-349
Trudgill ST (1987) Soil water dye tracing with special reference to the use of Rhodamanie WT
Lissamine FF and Amino G acid Hydrological Processes 1 149-170
US Environmental Protection Agency (USEPA) 1993 Guidance for Evaluating the Technical
Impracticability of Ground-Water Restoration - Interim Final Office of Solid Waste and
Emergency Response Washington DC Directive 92342-25 September 1993
US Environmental Protection Agency (USEPA) 2002 Interim Record of Decision Summary shy
Operable Unit One Non-Source Area Groundwater West SiteHows Corner Superfund Site
Plymouth Maine EPA Region 1 September 2002
US Environmental Protection Agency (USEPA) 2003 Proposed Scope of Work West SiteHows
Corner Superfund Site Plymouth Maine EPA Region 1 4 pages September 2002
Vasudevan D RL Fimmen AB Francisco (2001) Tracer-grade Rhodamine WT Structure of
constituent isomers and their sorption behavior Environ Sci Technol 35 4089-4096
nsow WOODARD amp CURRAN 26 September 30 2003 20564309
Woodard amp Curran Inc (WampC) 2002 Final Feasibility Study Report - Non-Source Area Groundwater
Hows Comer Superfund Site Plymouth Maine July 2002
TISOW WOODARD amp CURRAN 27 September 302003 20564309
f
m WOODARD amp CURRAN Maine Massachusetts New Hampshire Connecticut Florida Illinois Operational offices across the US 1-800-426-4262 wwwwoodardcurrancom
i
QAPP Quality Assurance Project Plan
QAQC Quality AssuranceQuality Control
RA Remedial Action
RAO Remedial Action Objective
RCRA Resource Conservation and Recovery Act
RD Remedial Design
RIFS Remedial InvestigationFeasibility Study
ROD Record of Decision
SAP Sampling and Analysis Plan
SOW Statement of Work
TAL target analyte list
TI Technical Impracticability
USEPA United State Environmental Protection Agency
VOCs volatile organic compounds
WampC Woodard amp Curran Inc
TISOW WOODARD amp CURRAN 25 September 302003 20564309
REFERENCES
Everts CJ RS Kanwar (1994) Evaluation of Rhodamine WT as an adsorbed tracer in an agricultural
soil J Hydrology 153 53-70
Kasnavia T D Vu DA Sabatini (1999) Fluorescent dye and media properties affecting sorption and
tracer selection Groundwater 37 376-381
Ptak T G Schmid (1996) Dual-tracer transport experiments in a physically and chemically
heterogeneous porous aquifer effective transport parameters and spatial variability J Hydrology
183 117-138
Sabatini DA T A Austin (1991) Characteristics of Rhodamine WT and fluorescein as adsorbing
ground-water tracers Ground Water 29 341-349
Trudgill ST (1987) Soil water dye tracing with special reference to the use of Rhodamanie WT
Lissamine FF and Amino G acid Hydrological Processes 1 149-170
US Environmental Protection Agency (USEPA) 1993 Guidance for Evaluating the Technical
Impracticability of Ground-Water Restoration - Interim Final Office of Solid Waste and
Emergency Response Washington DC Directive 92342-25 September 1993
US Environmental Protection Agency (USEPA) 2002 Interim Record of Decision Summary shy
Operable Unit One Non-Source Area Groundwater West SiteHows Corner Superfund Site
Plymouth Maine EPA Region 1 September 2002
US Environmental Protection Agency (USEPA) 2003 Proposed Scope of Work West SiteHows
Corner Superfund Site Plymouth Maine EPA Region 1 4 pages September 2002
Vasudevan D RL Fimmen AB Francisco (2001) Tracer-grade Rhodamine WT Structure of
constituent isomers and their sorption behavior Environ Sci Technol 35 4089-4096
nsow WOODARD amp CURRAN 26 September 30 2003 20564309
Woodard amp Curran Inc (WampC) 2002 Final Feasibility Study Report - Non-Source Area Groundwater
Hows Comer Superfund Site Plymouth Maine July 2002
TISOW WOODARD amp CURRAN 27 September 302003 20564309
f
m WOODARD amp CURRAN Maine Massachusetts New Hampshire Connecticut Florida Illinois Operational offices across the US 1-800-426-4262 wwwwoodardcurrancom
i
REFERENCES
Everts CJ RS Kanwar (1994) Evaluation of Rhodamine WT as an adsorbed tracer in an agricultural
soil J Hydrology 153 53-70
Kasnavia T D Vu DA Sabatini (1999) Fluorescent dye and media properties affecting sorption and
tracer selection Groundwater 37 376-381
Ptak T G Schmid (1996) Dual-tracer transport experiments in a physically and chemically
heterogeneous porous aquifer effective transport parameters and spatial variability J Hydrology
183 117-138
Sabatini DA T A Austin (1991) Characteristics of Rhodamine WT and fluorescein as adsorbing
ground-water tracers Ground Water 29 341-349
Trudgill ST (1987) Soil water dye tracing with special reference to the use of Rhodamanie WT
Lissamine FF and Amino G acid Hydrological Processes 1 149-170
US Environmental Protection Agency (USEPA) 1993 Guidance for Evaluating the Technical
Impracticability of Ground-Water Restoration - Interim Final Office of Solid Waste and
Emergency Response Washington DC Directive 92342-25 September 1993
US Environmental Protection Agency (USEPA) 2002 Interim Record of Decision Summary shy
Operable Unit One Non-Source Area Groundwater West SiteHows Corner Superfund Site
Plymouth Maine EPA Region 1 September 2002
US Environmental Protection Agency (USEPA) 2003 Proposed Scope of Work West SiteHows
Corner Superfund Site Plymouth Maine EPA Region 1 4 pages September 2002
Vasudevan D RL Fimmen AB Francisco (2001) Tracer-grade Rhodamine WT Structure of
constituent isomers and their sorption behavior Environ Sci Technol 35 4089-4096
nsow WOODARD amp CURRAN 26 September 30 2003 20564309
Woodard amp Curran Inc (WampC) 2002 Final Feasibility Study Report - Non-Source Area Groundwater
Hows Comer Superfund Site Plymouth Maine July 2002
TISOW WOODARD amp CURRAN 27 September 302003 20564309
f
m WOODARD amp CURRAN Maine Massachusetts New Hampshire Connecticut Florida Illinois Operational offices across the US 1-800-426-4262 wwwwoodardcurrancom
i
Woodard amp Curran Inc (WampC) 2002 Final Feasibility Study Report - Non-Source Area Groundwater
Hows Comer Superfund Site Plymouth Maine July 2002
TISOW WOODARD amp CURRAN 27 September 302003 20564309
f
m WOODARD amp CURRAN Maine Massachusetts New Hampshire Connecticut Florida Illinois Operational offices across the US 1-800-426-4262 wwwwoodardcurrancom
i
f
m WOODARD amp CURRAN Maine Massachusetts New Hampshire Connecticut Florida Illinois Operational offices across the US 1-800-426-4262 wwwwoodardcurrancom
i