samic 2008 international to nanosystems - unipd.it – 16.55 f. enrichi , r. riccò, a. meneghello,...
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National Research Council of Italy
Molecular Design Department
Italian Interuniversity Consortium
on Materials Science and Technology
National Research Council of Italy
Molecular Design Department
Italian Interuniversity Consortium
on Materials Science and Technology
SSAMIC AMIC International
20082008From MoleculesFrom Molecules
to to NanosystemsNanosystemsSSAMIC AMIC International
20082008From MoleculesFrom Molecules
to to NanosystemsNanosystems
University of Padova
Department of Chemical Sciences
Comune di Bressanone
Gemeinde Brixen
University of Padova
Department of Chemical Sciences
Comune di Bressanone
Gemeinde Brixen
Scientific Committee
L. Armelao CNR – Padova D. Barreca CNR – Padova R. Cipollini University – Roma E. Coronado University – Valencia G. Férey University – Versailles R. Fischer University – Bochum I.L. Fragalà University – Catania D. Gatteschi University – Firenze K. Müller University – Stuttgart E. Rizzarelli University – Catania U. Schubert University – Wien A. Sgamellotti University – Perugia E. Tondello University – Padova R. Ugo Università – Milano T. Valente Università – Roma S. Viticoli CNR – Roma R. Winpenny University – Manchester
Organizing Committee
G. Bottaro CNR – Bari A. Gasparotto University – Padova S. Gross CNR – Padova
Administrative Staff
C. Bettaccini INSTM – Firenze S. Bagnoli INSTM – Firenze S. Chiani INSTM – Firenze E. Pecchi INSTM – Firenze
Sunday November 30, 2008
15.00 – 18.00 Registration of the participants
17.30 – 19.00 Welcome Cocktail
Monday December 1, 2008
Session 1
8.30 – 9.30 Registration of the participants
9.30 – 9.40 Opening remarks
9.40 – 10.25 J. Maier: “Downsizing Matter: Impact on Electrochemical Energy
Conversion and Storage” (Plenary)
10.25 – 11.10 J. Fontanella: “Electrical relaxation in Ultem
, mesoporous silica, and
Ultem
containing mesoporous silica“ (Plenary)
11.10 – 11.40 Coffee break
11.40 – 12.00 V. Bambagioni, C. Bianchini, J. Filippi, W. Oberhauser, A. Marchionni, F.
Vizza, R. Psaro, L. Sordelli: “Ethanol oxidation on electrocatalysts
obtained by the spontaneous deposition of palladium onto nickel-zinc
materials”
12.00 – 12.20 C. Resini, T. Montanari, L. Barattini, G. Ramis, G. Busca, S. Presto, P.
Riani, R. Marazza, M. Sisani, F. Marmottini, U. Costantino: “Ni-Zn-Al and
Ni-Mg-Al catalysts derived from hydrotalcite-like precursors for hydrogen
production by ethanol steam reforming”
Session 2
15.00 – 15.45 U. Schubert: “Functional Clusters as Nano-sized Building Blocks for
Inorganic-Organic Hybrid Materials” (Plenary)
15.45 – 16.30 G. Férey: “Hybrid porous solids: a new world” (Plenary)
16.30 – 16.50 M. Taddei, F. Costantino, U. Costantino, M. Nocchetti, R. Vivani: “Hybrid
low dimensional zirconium phosphonates”
16.50 – 17.15 Coffee break
17.15 – 17.35 M. Bonchio, M. Carraro, C. Maccato, A. Sartorel, G. Scorrano, F. M.
Toma, M. A. Herrero, G. Scoles, M. Prato: “Towards artificial
photosynthesis: water oxidation catalysis by nanostructured
polyoxometalate domains”
17.35 – 17.55 B. Botar, P. Kögerler: “Controlled metalation and demetalation in
multiiron polyoxotungstates”
17.55 – 19.15 Poster Session I
Tuesday December 2, 2008
Session 3
9.15 – 10.00 D. Gatteschi: “Magnetic nanoparticles and molecular nanomagnets:
parallel lives” (Plenary)
10.00 – 10.20 F. Pineider, M. Mannini, C. Danieli, L. Armelao, F. Piras, Ph. Sainctavit,
L. Gorini, E. Tondello, A. Cornia, D. Gatteschi, R. Sessoli “Monolayers of
FE4 single molecule magnets organized on Au(111) surfaces”
10.20 – 10.40 M. Rancan, M. L. Baker, C. A. Muryn, R. Pritchard, G. A. Timco, F. Tuna
R. E. P. Winpenny: “Chromium horseshoes: chemistry, magnetism and
EPR”
10.40 – 10.55 Coffee break
10.55 – 11.40 E. Coronado: “Nanostructures of magnetic molecules” (Plenary)
11.40 – 12.00 F. Costantino, F. Marmottini, A. Ienco, S. Midollini, A. Guerri, T. Bataille:
“A study on the flexibility of coordination polymers based on Cu2+
and
pc2p (pc2p = P,P’-diphenylethylenediphosphinate): a metastable 3D phase
and its spontaneus transformations”
Session 4
14.30 – 15.15 M. Antonietti: “Nanoparticles for Material Science” (Plenary)
15.15 – 15.35 R. Scotti, M. D’Arienzo, I. R. Bellobono, F. Morazzoni: “Photocatalytic
properties of nanosized TiO2: the role of the phase composition in the
stability of UV-generated charge trapped sites”
15.35 – 15.55 C. Giordano, W. Yao, A. Thomas, M. Antonietti: “Synthesis of Mo- and
W- carbide and -nitride nanoparticles via a urea route”
15.55 – 16.15 I. Venditti, I. Fratoddi, M. V. Russo, L. Chronopoulou, C. Palocci:
“Polymeric nanobeads for drug delivery”
16.15 – 16.35 Coffee break
16.35 – 17.20 K. Müller: “Solid-State NMR Spectroscopy: A Powerful Tool for probing
Molecular Motions in Solids” (Plenary)
17.20 – 17.40 A. Bassano, V. Buscaglia, M. Viviani, M. T. Buscaglia, P. Nanni, R.
Marazza: “Preparation of fine BaCeO3 and BaCe0.9Y0.1O3-δ”
20.30 Social Dinner
Wednesday December 3, 2008
Session 5
9.20 – 10.05 I. L. Fragalà: “Strategies for self-assembling of functional molecules on Si
and SiO2 surfaces” (Plenary)
10.05 – 10.25 G. De Luca, A. Romeo, V. Villari, N. Micali, I. Foltran, G. I. Lesci, T.
Zuccheri, E. Foresti, N. Roveri, L. Monsù Scolaro “Ionic self assembly
with chrysotile nanotubes: supporting functional materials”
10.25 – 10.45 M. Favazza, E. Biavardi, A. Motta, I. L. Fragalà, L. Prodi, M. Montalti, G.
G. Condorelli, E. Dalcanale: “Reversible ion complexation on cavitand
functionalizated silicon surfaces”
10.45 – 11.05 Coffee break
11.05 – 11.40 G. de Petris: “Modeling in the gas phase: molecular synthesis and
hydrocarbons functionalization” (Key note)
11.40 – 12.00 M. C. Aragoni, M. Arca, F. A. Devillanova, F. Isaia, V. Lippolis, A.
Pintus: “Electronic structure of [M(R-dmet)2] metal dithiolenes: a density
functional approach”
12.00 – 12.20 G. Giorgi, X. Cartoixà, A. Sgamellotti, R. Rurali: “Mn-doped silicon
nanowires”
Session 6
14.30 – 15.05 P. Mazzoldi: “Enhancement of the Er3+
luminescence by few-atom metal
aggregates” (Key note)
15.05 – 15.40 F. Heigl: “X-ray excited optical luminescence from rare earths in a
nanostructured host” (Key note)
15.40 – 16.00 Coffee break
16.00 – 16.35 O. Diwald: “Photoluminescent Nanoparticle Surfaces: Alkaline Earth
Oxides’ Potential for optical Applications” (Key note)
16.35 – 16.55 F. Enrichi, R. Riccò, A. Meneghello, K. Fincati: “Fluorophore doped
luminescent silica nanoparticles as efficient labels in DNA-microarrays”
16.55 – 18.15 Poster Session II
Thursday December 4, 2008
Session 7
9.30 – 10.05 N. Hüsing: “Innovative synthesis routes towards hierarchically organized
materials” (Key note)
10.05 – 10.25 S. Mascotto, D. Wallacher, A. Brandt, T. Hauß, B. Smarsly: “Pore
network organization study in hierarchical mesoporous silica via
combination of gas physisorption with SANS”
10.25 – 10.45 M. Mba, M. Pontini, S. Lovat, C. Zonta, G. Licini: “V(v) complexes as
effective catalysts for fast and selective oxidations”
10.45 – 11.00 Coffee break
11.00 – 11.20 R. Psaro, V. Dal Santo, L. Sordelli, V. De Grandi, A. Gallo:
“Nanostructured Rh catalysts for hydrogen production prepared by OM-
CVD of Rh(acac)(CO)2”
11.20 – 11.40 E. Comini, M. Ferroni, N. Poli, G. Sberveglieri, S. Kaciulis, A. Mezzi, L.
Pandolfi: “Doped zinc oxide nanowires preparation“
11.40 – 12.00 P. Centomo, P. Canton, C. Meneghini, M. Rovezzi, M. Zecca, B. Corain:
“Direct synthesis of H2O2: role of Au in the Au-Pd active phase”
12.00 Closing of the meeting
Plenary lectures
L1 Plenary Lecture J. Maier
L2 Plenary Lecture J. Fontanella
L3 Plenary Lecture U. Schubert
L4 Plenary Lecture G. Férey
L5 Plenary Lecture D. Gatteschi
L6 Plenary Lecture E. Coronado
L7 Plenary Lecture M. Antonietti
L8 Plenary Lecture K. Müller
L9 Plenary Lecture I. L. Fragalà
L10 Key Note G. de Petris
L11 Key Note P. Mazzoldi
L12 Key Note F. Heigl
L13 Key Note O. Diwald
L14 Key Note N. Hüsing
Poster Session I
P1 S. Barison, S. Battiston, S. Boldrini, M. Bolzan, S. Daolio, L. Doubova, M. Fabrizio, S.
Fiameni, R. Gerbasi, M. Meneghetti, E. Miorin, F. Montagner, C. Mortalò, C. Pagura:
“New hybrid material SWCNH/TiO2 obtained via MOCVD”
P2 S. Battiston, M. Bolzan, M. Favaro, R. Gerbasi, C. Pagura, F. Visentin: “Design of a new
fluidized-bed MOCVD reactor for TiO2 coating of carbon nanohorn powders”
P3 S. Barison, A. Campiglio, S. Daolio, M. Fabrizio, S. Fiameni: “Nanostructured silver
films for antimicrobial and water purifying applications”
P4 S. Belaid, A. Landreau, S. Djebbar, O. Benali-Baitich, M. A. Khan, G. Bouet: “Synthesis,
characterization and antifungal activity of a series of cobalt (II) and nickel (II) complexes
with ligands derived from reduced N, N’-O-phenylenebis(salicylideneimine)”
P5 L. Armelao, D. Barreca, G. Bottaro, A. Gasparotto, C. Maccato, E. Tondello, U.
Lavrenčič Štangar, D. Mahne: “Ag/TiO2 nanocomposites obtained by a hybrid rf-
sputtering/sol–gel approach: tailoring structure-property relationships”
P6 D. Barreca, A. Gasparotto, C. Maccato, E. Tondello, U. Lavrenčič Štangar, S. R. Patil:
“Photoinduced superhydrophilicity and photocatalytic performances of ZnO
nanoplatelets obtained by chemical vapor deposition”
P7 F. Lupo, M. E. Fragalà, A. Gulino: “Semiconducting nanodimensional substrate free ZnO
films”
P8 P. Fornasiero, V. Gombac, T. Montini, M. Graziani: “Metal doped TiO2 for hydrogen
production”
P9 N. El Habra, M. Bolzan, C. De Zorzi, M. Casarin, G. Rossetto: “Development of an
aerosol-CVD process for the deposition of porous films for Solid Oxide Fuel Cells
(SOFC)”
P10 M. P. Carpanese, M. Bandini, A. Barbucci, G. Cerisola, P. Nanni, M. Viviani, S. Presto,
R. Marazza, C. Nicolella: “Experimental and theoretical analysis of the distribution of
active sited in composite electrodes”
P11 M. P. Carpanese, M. Bandini, A. Barbucci, G. Cerisola, P. Nanni, M. Viviani, P.
Fornasiero, S. Presto, R. Marazza: “Realisation and characterisation of planar anode
supported SOFC”
P12 M. Abele, M. M. Natile, E. Tondello, K. Müller: “Preparation and characterization of
nanostructured doped lanthanumgallates”
P13 V. Di Noto, S. Lavina, E. Negro, G. Pace: “Structure and interactions in [nafion/(core-
shell-oxoclusters)x] hybrid proton-conducting membranes: vibrational spectroscopy
studies”
P14 L. Minati, G. Speranza, M. Ferrari, C. Migliaresi: “Synthesis and characterization of
carbon nanotubes/gold nanoparticles composite”
P15 P. Benzi, E. Bottizzo, C. Demaria: “Correlation among hydrogen bonding configuration,
structural order and optical coefficients in hydrogenated amorphous germanium
obtained by X-ray CVD”
P16 L. P. Curecheriu, M. T. Buscaglia, V. Buscaglia, A. Ianculescu, E. Vasile, A. Ioncea, L.
Mitoseriu, P. Nanni: “In-situ preparation of multiferroic composite nanopowders with
core-shell structures”
P17 F. Prihor, P. Postolache, A. Ianculescu, N. Lupu, H. Chiriac, L. Mitoseriu: “Preparation
and investigation of the BiFeO3–based multiferroic ceramics”
P18 F. Rosalbino: “Study of pulse plated nickel-molybdenum and nickel-tungsten
nanocrystalline alloys as oxygen electrodes in alkaline water electrolysis”
P19 G. V. Bianco, M. M. Giangregorio, M. Losurdo, P. Capezzuto, G. Bruno: “Catalyzed-
VLS growth as a general syntehtic route to all semiconductors nanostructures”
P20 D. Cauzzi, E. Feci, S. Palanti, G. Predieri, F. Vignali: “Wood functionalization with
inorganic-organic hybrid silica nanosols”
Poster Session II
P21 A. Famengo, S. Gross, M. Casarin, T. Devic, A. Vittadini, E Tondello: “Unusual Zn-
mercaptonicotinate coordination polymer: synthesis, experimental and theoretical
investigation”
P22 M. Daghetta, G. Peli, P. Macchi, A. Sironi, L. Garlaschelli: “Tetrairidium carbonyl
clusters linked by diphosphane ligands via solvothermal synthesis”
P23 M. Mba, M. Pontini, E. Nagy, A. Vittadini, M. Casarin, G. Licini: “On the high stability
of a S6 mu-oxo-Ti(IV) dinuclear complex”
P24 G. Peli, A. Maspero, S. Galli, N. Masciocchi: “Metal coordination frameworks of the
novel 1,4-bis(5-tetrazolyl)-benzene ligand”
P25 S. Gross, C. Serre, T. Devic, M. Dan, V. Guillerm, A. Vittadini, G. Férey: “First example
of hexanuclear Zr oxocluster as SBU for the synthesis of a Zr(IV)-based MOF by ligand
exhange”
P26 S. Gross, G. Timco, V. Di Noto, S. Lavina, M. Rancan, R. E. P. Winpenny: “First
example of chromium wheel-based hybrid organic-inorganic materials for functional
dielectric applications”
P27 M. Licchelli, C. Zanini: “Anion recognition by urea-metallocyclam conjugates”
P28 K. Upendra Kumar, F. Piccinelli, C. K. Jayasankar, M. Bettinelli, A. Speghini:
“Synthesis, structural characterization and optical spectroscopy of lanthanide doped
nanocrystalline alkali niobates”
P29 L. Bovo, F. Anselmi, L. Armelao, M. Bettinelli, P. Caliceti, E. Tondello: “Nanostructural
ZnO as an innovative material for optical and bio-sensing applications”
P30 C. Scalera, S. Quici, M. Cavazzini, G. Accorsi, M. Bolognesi, L. Armelao, G. Bottaro:
“Highly photoluminescent silica layers doped with efficient Eu(III) and Tb(III) antenna
complexes”
P31 V. Calabrese, S. Quici, M. Cavazzini, E. Rossi, C. Dragonetti, E. Tordin, F. De Angelis,
S. Fantacci: “Second order non linear optical (NLO) properties of novel polyaromatic
chromophores and of their metal complexes”
P32 D. Aiello, L. Malfatti, T. Kidchob, R. Aiello, F. Testa, I. Aiello, M. Ghedini, M. La Deda,
T. Martino, M. Casula, P. Innocenzi: “Mesoporous hybrid titania and silica films
prepared via post-synthesis grafting of luminescent zinc(II) complex”
P33 G. Poneti, M. A. Arrio, N. Brookes, J. C. Cezar, A. Dei, M. Mannini, A. Rogalev, P.
Sainctavit, L. Sorace, F. Wilhelm: “Solvent effects on the thermal and light induced
valence tautomerism in a 1 : 1 cobalt : dioxolene species”
P34 F. Enrichi, R. Riccò, A. Parma, P. Riello, A. Benedetti: “Incorporation of luminescent Eu
ions into monodisperse silica nanospheres”
P35 P. Mazzoldi, G. Mattei, S. Mariazzi, R. S. Brusa, G. Battaglin: “Positron annihilation
spectroscopy: characterization of radiation damage in implanted silica”
P36 G. Tabacchi, E. Fois, A. Gamba, D. Barreca, A. Gasparotto, R. Seraglia, E. Tondello:
“Cu(hfa)2•TMEDA as an innovative CVD precursor of copper oxides: an experimental
and theoretical investigation”
P37 G. Carta, L. Crociani, M. Natali, G. Rossetto, P. Zanella: “MOCVD deposition of VOx
films from a novel vanadium (III) precursor”