roy f. weston; i nc, · 5599 san felipe, suite 700 houston, tx 77056 march 2001 000697. november...

R O Y F . W E S T O N ; i N C ,N O V E M B E R 2000

G R O U N D W A T E R M O N I T O R I N G REPORTT E X A R K A N A WOOD P R E S E R V I N G C O . S U P E R F U N D S I T E

T E X A R K A N A , BOWIE C O U N T Y , T XT N R C C C O N T R A C T NO. 43000000002

913546

M W 6 E R S \-^' O E S I W E R S C O N S U L T A N T S

000696

N O V E M B E R 2000G R O U N D W A T E R M O N I T O R I N G REPORT

T E X A R K A N A WOOD P R E S E R V I N G C O . S U P E R F U N D S I T ET E X A R K A N A , BOWIE C O U N T Y , T X

T N R C C C O N T R A C T NO. 43000000002

Prepared forTexas Natural Resource Conservation Commission

P.O. Box 13087Austin, TX 78711

Prepared byRoy F. Weston, Inc.

5599 San F e l i p e , S u i t e 700Hous ton , TX 77056

March 2001

000697




T A B L E OF CONTENTS

S E C T I O N T I T L E P A G E

1 INTRODUCTION............................................................................................................ 1-11.1 PURPOSE AND SCOPE..................................................................................... 1-11.2 OBJECTIVES...................................................................................................... 1-1

2 SAMPLING AND ANALYSES ACTIVITIES............................................................... 2-12.1 OVERVIEW................,...................................................................................... -!2.2 SAMPLING PROCEDURES.............................................................................. 2-12.3 ANALYTICAL PROCEDURES......................................................................... 2-2

3 ANALYTICAL RESULTS.............................................................................................. 3-13.1 DATA MANAGEMENT OVERVIEW.............................................................. 3-13.2 G R O U N D W A T E R ANALYTICAL RESULTS ................................................. 3-1

4 CONCLUSIONS..............................................................................................................4-15 RECOMMENDATIONS................................................................................................. 5-1

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L I S T O F F I G U R E S

F I G U R E T I T L E PAGE

2-1 Monitoring W e l l Locations.................................................................................. 2-3

L I S T O F A T T A C H M E N T S

A T T A C H M E N T T I T L E

T A B L E ST a b l e 1 Groundwater Action Level sT a b l e 2 Summary of Analyse s and MeasurementsT a b l e 3 Summary of W e l l MeasurementsT a b l e 4 Groundwater A n a l y t i c a l Summary

FIELD LOG BOOKR E G I O N A L D A T A REVIEW REPORTA N A L Y T I C A L R E S U L T S

T a b l e 1 PAH/PCP and BAP Result sT I C R E S U L T S

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S E C T I O N 1I N T R O D U C T I O N

1.1 PURPOSE AND SCOPERoy F. Weston, Inc. (WESTON®) was contracted by the Texas Natural Resource ConservationCommission (TNRCC) to p er f orm groundwater monitoring activities at the Texarkana WoodPreserving Company (TWPC) S u p e r f u n d site. The primary purpose of the groundwatermonitoring activities at the T W P C site was to analyze groundwater from on-site permanentmonitoring we l l s to observe increases or decreases in concentrations of consti tuents of concern(polynuclear aromatic hydrocarbons [PAHs] and pentachlorophenol [PCP]) and determine ifknown plumes have migrated since the last s ampl ing and analysis event conducted in July 1999.The groundwater monitoring activit ie s included evaluating analytical data obtained through theco l l e c t ion and analysis of groundwater samples from selected exis t ing monitoring wel l s at thesite.In addi t ion to activities described above, the f o l l o w i n g additional sampling activity wasper formed:

• Measure f i e l d parameters (di s so lved oxygen, ox idat ion/reduc t ion p o t e n t i a l , pH,temperature, and s p e c i f i c conductivity).

The s p e c i f i c Data Quality Object ives (DQOs) for this e f f o r t are provided in the Projec t Quali tyAssurance Projec t Plan (QAPP) dated December 1997 in Element A, T a b l e A.1.2 O B J E C T I V E SThe ob j e c t ive s of WESTON's groundwater sampl ing in November 2000 included:

• Purge and sample selected shallow monitoring we l l s (MW-01, MW-03, MW-04,MW-06, MW-07, MW-08, MW-09, M W - 1 3 , MW-14, MW-27, and MW-28).

• Purge and sample selected intermediate monitoring wel l s ( M W - 1 7 , M W - 1 9 ,M W - 2 0 , a n d M W - 2 6 ) .

• Record f i e l d measurements (water l eve l , di s solved oxygen, ox ida t i on/reduc t i onp o t e n t i a l , pH, temperature, and s p e c i f i c conduct ivi ty) for a l l we l l s sampled.

• Analyze groundwater samples for selected s emivola t i l e organic compound(SVOC) consti tuents using SW-846 Method 8270C.

• Determine if site at tr ibutable contaminants are detected in monitoring we l l s , andcompare contaminant concentrations to the site s p e c i f i c action l eve l s presented inT a b l e 1 in Attachment 1.

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• Record water level s in the above-mentioned monitoring wel l s to compare to waterlevel s measured in previous sampl ing events.

• Compare collected data to previous site reports to i d e n t i f y potential plumemovements.

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000701

SECTION 2S A M P L I N G A N D A N A L Y S E S A C T I V I T I E S

2.1 OVERVIEWFourteen monitoring we l l s (MW-01, MW-03, MW-06, MW-07, MW-08, MW-09, M W - 1 3 ,MW-14, MW-17, MW-19, MW-20, MW-26, MW-27, and MW-28) were purged and sampledfor analysis during the November 2000 Groundwater S a m p l i n g Act iv i t i e s as well as c o l l e c t i n g awater level measurement at MW-04. Due to severe weather conditions, a groundwater samplefrom MW-04 was not co l l e c t ed . Monitoring well locations are shown on Figure 2-1.There are three water-bearing zones mat have been logged at the site. Thes e include shal low,intermediate, and deep water-bearing zones. The w e l l s in the shal low zone have comple t i ond e p t h s ranging from 13 to 25 f e e t below ground surface (bgs). Monitor we l l s in the intermediatezone have completion dep th s ranging from 56 to 63 f e e t bgs. Monitor wel l s in the deep zonehave completion dep th s ranging from 119 to 120 f e e t bgs. Ten shal low water-bearing zone w e l l sand four intermediate water-bearing zone wel l s were selected j o i n t l y by WESTON and TNRCC,as presented in the Groundwater Monitoring Plan submitted by WESTON to TNRCC in October2000. Thes e we l l s were selected for groundwater s a m p l i n g to observe increases or decreases inconcentrations of constituents of concern and to determine if the downgradient boundaries ofknown plumes have migrated since the last monitoring event.A summary of the tasks performed during the November 2000 sampl ing event is as f o l l o w s :

• F i e l d measurements (water l eve l , pH, temperature, di s so lved oxygen, ox ida t i on/reduction p o t e n t i a l , and s p e c i f i c conduc t iv i ty); and

• Groundwater sampl ing for analysis of const i tuents of concern (PAHs and PCP).A summary of analyses and f i e l d measurements p er f ormed for each well is shown in T a b l e 2 ofAttachment 1. T a b l e 3 in Attachment 1 tabulates the measurements recorded from each well. Allf i e l d activities were recorded in a site logbook by the W E S T O N f i e l d team leader Monitor wellpurging and sampl ing information was recorded on Groundwater S a m p l i n g F i e l d Data Sheet s .Photocopie s of the logbook pages and groundwater sampl ing data sheets are provided asAttachment 2.2.2 SAMPLING PROCEDURESS a m p l i n g procedures were f o l l o w e d as d e ta i l ed in Attachment One of the Q A P P — S t a n d a r dOperating Procedures ( S O P s ) . Photocopie s of all f i e l d logbook pages are included asAttachment 2 of this document. In summary, a l o w - f l o w (minimal drawdown) s a m p l i n gtechnique was used to purge and sample groundwater from the monitoring well s . S a m p l e tubingwas pos i t ioned to col lect groundwater from the midpo in t of the water column. N o n d i s p o s a b l es a m p l i n g equipment was decontaminated f o l l o w i n g ac t ivi t i e s at each well as outlined in the

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QAPP. S a m p l e s were sent for analysis by overnight delivery to an Environmental ProtectionAgency (EPA) designated Contract Laboratory Program (CLP) laboratory. S a m p l e s werehandled, lab e l ed , packed, and sh ipped in accordance with the site QAPP.

2.3 ANALYTICAL PROCEDURESGroundwater samples were analyzed for PAHs and PCP by Mitkem Corporation in Warwick,Rhode I s l a n d , using U.S. EPA SW-846 Method 8270C. QA/QC sample s were col lec ted andanalyzed as part of the groundwater sampl ing activities as required by Element B5 of the QAPP.

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000703

FIGURE 2-1.RKANA WOOD PRESERVING CO

VEMBER 2000 GROUNDWATER

000704

S E C T I O N 3A N A L Y T I C A L R E S U L T S

3.1 D A T E M A N A G E M E N T O V E R V I E WThe samples co l l e c t ed from each well were analyzed by Mitkem Corporation for the constituentsl i s t e d in Attachment 1, T a b l e 2-1 in accordance with the QAPP. After sample co l l e c t i on , theassociated chain-of-custody forms and analytical results were entered into WESTON On-Line, aproprie tary data management system for ease in tabu la t ing and presenting data. W E S T O NOn-Line was also used to calculate benzo(a)pyrene (BAP) equivalents, as s p e c i f i e d in the 1998ROD Amendment No. 1, to determine if const i tuents were above the e s tabl i shed action l eve l s forthe site. The EPA Region 6 Hous t on Branch ESAT data review team comple ted a review of theCLP data package. A copy of the Regional Data Review Report is included in Attachment 3.3 . 2 G R O U N D W A T E R A N A L Y T I C A L R E S U L T SThe analytical results for the November 2000 sampl ing event revealed that one of the 14 we l l shad one of the groundwater contaminants of concern, acenaphthene, above the laboratoryreporting l i m i t s but below the site action levels . A summary of the result s is presented in T a b l e 4of Attachment 1. Attachment 4 of this Groundwater Moni tor ing Report is the d e ta i l ed analyticalresults for PAH/PCP and BAP analysis-One unknown t en ta t ive ly i d e n t i f i e d compound (TIC) was detected in MW-06, and four TICswere detected in an equipment blank co l l e c t ed at M W - 1 7 . TICs are compounds that are nott y p i c a l l y reported for the analysis p er formed. However, they are compounds that are measuredby the laboratory instrumentation. The sample collected at MW-06 was collected ut i l iz ingd i s p o s a b l e s ampl ing equipment. T h e r e f o r e the TICs in MW-06 are not associated with the TICsin the equipment blank. Furthermore., the samples c o l l e c t ed at M W - 1 7 , M W - 1 9 , MW-20, andMW-26 which u t i l i z ed non-di sposable s ampl ing equipment, did not have TICs reported by thelaboratory. T h i s indicate s that the presence of TICs in the equipment blank did not a f f e c t thesamples c o l l e c t ed using this equipment. Attachment 5 includes resul t s for TICs.No groundwater sample s c o l l e c t ed exceeded the action l eve l s of 0.01 mi l l igrams per l i t e r ( m g / L )and 0.2 m g / L , e s tabl i shed for total carcinogenic PAHs (cPAHs), expressed as BAP equivalents,and P C P , re spec t ive ly.

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000705

S E C T I O N 4C O N C L U S I O N S

Based on the analytical data from the November 2000 Groundwater Monitoring Act iv i t i e s , thef o l l o w i n g conclusions may be drawn:

• No de t e c tab l e concentrations of PAHs and PCP are present in downgradientshal low monitoring we l l s MW-03, MW-06, MW-07, MW-08, MW-09, M W - 1 3 ,MW-14, a n d M W - 2 8 .

• No detectable concentrations of PAHs and PCP are present in upgradient shallowmonitoring well MW-01.

• No de t e c tab l e concentrations of PAHs and PCP are present in intermediatemonitoring w e l l s M W - 1 7 , M W - 1 9 , MW-20, and MW-26.

• Detected concentrations of groundwater contaminants of concern in MW-27 andMW-27 ( d u p l i c a t e ) have not increased since the 1998 and 1999 s a m p l i n g events.Acenaphthene was the only constituent of concern detected above the laboratoryreport ing limit in MW-27 at a concentration of 0.009 mg/L.

• One unknown TIC was detected in MW-06 at an estimated concentration of0.014 mg/L.

• It appears that the general conf igurat ions of the p lume s that were de l ineatedduring the 1989 RI and the 1999 A d d i t i o n a l F i e l d S a m p l i n g Trip Report continueto represent the p lumes of contaminated groundwater.

• The concentrations of total non-carcinogenic PAHs, carcinogenic PAHs(expressed as BAP equivalent s), and PCP have not shown a s ign i f i can t increase ordecrease from previous s a m p l i n g events (November 1997 - July 1999) in thewel l s sampled.

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000706

IIIIIIIIIIIIIIIIIII

S E C T I O N 5R E C O M M E N D A T I O N S

Based on the conclusions provided in Sec t i on 4, WESTON makes the f o l l o w i n grecommendations:

• Continue to sample the eleven shallow we l l s i d e n t i f i e d as being downgradientwel l s for analysis of PAHs and PCP on an annual basis. Thes e eleven w e l l s areMW-03, MW-06, MW-07, MW-08, MW-09, M W - 1 1 , M W - 1 3 , MW-14, MW-22,MW-27, and MW-28.

• Continue annual s a m p l i n g of upgradient monitoring we l l s MW-01, MW-04 andMW-23 to observe increases or decreases in concentrations of contaminants ofconcern and determine if the groundwater plume has migrated to the north or ifo f f - s i t e sources are at tr ibutable .

• Continue s a m p l i n g of the intermediate monitoring we l l s ( M W - 1 7 , M W - 1 9 ,MW-20 and M W - 2 6 ) once every three years to observe if any contaminants ofconcern have migrated from the shal low water-bearing zone to the intermediatewater-bearing zone.

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000707

IIII

A T T A C H M E N T S

000708

A T T A C H M E N T 1T A B L E S

T A B L E 1 G R O U N D W A T E R A C T I O N L E V E L ST A B L E 2 S U M M A R Y OF ANALYSES AND M E A S U R E M E N T ST A B L E 3 SUMMARY OF W E L L MEASUREMENTST A B L E 4 G R O U N D W A T E R A N A L Y T I C A L S U M M A R Y

000709

T A B L E 1G R O U N D W A T E R A C T I O N L E V E L S 1

N O V E M B E R 2000 S A M P L I N G E V E N T

COMPOUNDT o t a l carcinogenic PAHs (expressed astotal BAP equivalent s)T o t a l noncarcinogenic P A H sT o t a l carcinogenic d i o x i n / f u r a n s(expres sed as 2 ,3,7,8-TCDD equivalent s)PCP

G R O U N D W A T E R A C T I O NLEVEL ( m g / L )

0.010NA

0.0010.2

1 Reference: Record of Decision for Texarkana Wood Preserving Co. EPA, 1990.

000710

T A B L E 2S U M M A R Y O F A N A L Y S E S A N D M E A S U R E M E N T S C O N D U C T E D


' A N A L Y S E S ' . . " " - - - - /Moni tor ing

W e l l Number 1

MW-01MW-02MW-03MW-04MW-05MW-06MW-07MW-08MW-09M W - 1 0M W - 1 1M W - 1 2M W - 1 3M W - 1 4

M W - 1 7 C

M W - 1 8M W - 1 9 e

MW-20 C

MW-22MW-23MW-25

MW-26 e

MW-27MW-28

Well Location 2

Upgradi en tW i t h i n

DowngradientUpgrad i en t

W i t h i nDowngradientDowngradientDowngradientDowngradient

W i t h i nBetween

W i t h i nDowngradientDowngradient

W i t h i nDowngradient

W i t h i nW i t h i n

DowngradientUpgrad i en tU p g r a d i e n tUpgradi en t

DowngradientDowngradient

P A H s / P C P(Method 8270C)

XX

XXXX

XXXXX

XXX

F i e l dMeasurements3

XX

water level onlyXXXX

XXXXX

XXX

T I C 4

X

W e l l s l i s t e d i n c l u d e a l l s h a l l o w a n d in t ermed ia t e we l l s .W e l l l o ca t i on ind i ca t e s the l o ca t ion of the we l l with respect to the two p lume boundaries that were d e l i n e a t e d in the 1999A d d i t i o n a l F i e l d S a m p l i n g T r i p Report.F i e l d measurements i n c l u d e : water l ev e l , d i s s o l v e d oxygen, o x i d a t i o n / r e d u c t i o n p o t e n t i a l , p H , temperature, a n d s p e c i f i cc o n d u c t i v i t y .T e n t a t i v e l y I d e n t i f i e d Compounds.I n t e r m e d i a t e moni tor ing we l l .

000711

T A B L E 3S U M M A R Y O F W E L L M E A S U R E M E N T S


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000712

T A B L E 3S U M M A R Y OF WELL M E A S U R E M E N T S


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000713



M W - 2 7 1 1 / 1 7 / 0 0 3.56 375380379379377377

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000714



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000715

T A B L E 4G R O U N D W A T E R A N A L Y T I C A L S U M M A R Y 1

N O V E M B E R 2000 S A M P L I N G E V E N T R E S U L T S ( m g / L ) 2

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MW-27 ( D u p l i c a t e )MW-28

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000716

A T T A C H M E N T 2FIELD LOG BOOK

000717

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A L L - W E A T H E REnvironmentalF I E L D BOOKN < K 5 5 0 F

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"Rite in the Rain" - a unique a l l -wea th er writ ing sur fac e createdto shed water and to enhance the writ ten image. Makes itp o s s i b l e to write sharp, l e g i b l e field data in any kind of weather.A v a i l a b l e in a variety of standard and custom printed case-bound field books, loose leaf, sp iral and s t a p l e d notebooks,mul t i - copy sets and copier papers .

a product ofJ X D A R L I N G C O R P O R A T I O NT A C O M A , W A 98424-1017 U S A

www.riteintherain.com

C O N T E N T SR E F E R E N C E D A T E

Referenc e Page I n d e x147 Error codes, Hazardou s c l a s s i f i c a t i o n s , Container types148 S a m p l i n g guide l ine s ( L i q u i d s )149 S a m p l i n g guide l ine s (Solid s)150 A p p r o x i m a t e Volume of W a t e r in Casing or Hole, Ground Water Monitoring Well151 PVC Pipe casing tables152 Soil C l a s s i f i c a t i o n^S3 Soil C l a s s i f i c a t i o n154 Conversions (Length , Weight . Vo lume , T e m p , etc...)155 Conversions (Concentrations, V o l u m e / F l o w or Time. V e l o c i t y , Acce l era t ion)156 Maximum Concentration of Contaminants for the T o x i c i t y Characteristic

C1 we J. L DAPUNO CORP.

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000725

000726

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000727

GROUNDWATER SAMPLING FIELD DATA SHEET T a s k \OOO( L a s t W e l l I D N o . Last DateI W e l l I D N o .( C a s i n g Diameter

in{ C a s i n g S t i c k u pJ T o t a l W e l l I D e p t h•(from T O C )[ S t a t i c W a t e rLevel ( f r o m T O C )

f t .

Last T o t a l W e l lD e p t h

Last S t a t i c WaterLevel

I W a t e r T h i c k n e s sI W e l l Diameter F a c t o r

Diameter 2" 4" 6" 8"F a c t o r .16 .65 1.47 2.61{ C a s i n g V o l u m e gal .I S c r e e n e d I n t e r v a l ( f r o m G S ) f t ,

Purge Equipment:Geotech P e r i s t a l t i c P u m pSeria l No.________S a m p l e Equipment:Geotech P e r i s t a l t i c PumpS e r i a l No.________A n a y l t i c a l Equipment:( p H / c o n d / D O / T e m p )Y S I 3 5 6 0 X LS e r i a l No._______Water Level Meter:S o l i n s tPurge Conta iner iz ed?Y e s N oDes t ina t ion:

Log Book #_________> Page \ of 1DateT i m e

Meter C a l i b r a t i o nPH = at

T i m eT i m e

p H _ atConduc tance S t a n d a r d : ,Measured V a l u e : _Dissolved OxygenCalibra t ed to___

______nmhos/cm a t 2 5 ° CT i m e

_nmhos/cm at 2 5 ° C _ _ _ _ _ _ _ _ _ _ _T i m e

_mg/l at.N A P L Present? Y e s N oEstimated v o l u m e / t h i c k n e s s ( g a l / i n ) ? _Descript ion:S a m p l e c o l l e c t ed? Y e s N oS a m p l e ID:___________Groundwat er S a m p l e C o l l e c t e d ?Groundwat er S a m p l e D e p t h ( f t . ) :Groundwater S a m p l e I D :

T i m eN u m b e r o f C a s i n g

V o l u m e sG a l l o n s

RemovedW a t e rLevel T e r n p

Vi ~E.nmhos/cm PH

Dissolved0 2 m g / l i t e r R a t ^ G P I

^xpprox.P u m pDepth f t . V i s u a l

Des cr ip t i on

z / M470

1.2?

A n a l y s e s Requested (see C O C ) F u l l S u i t e Part ia l S u i t e ( e x p l a i n )|QC S a m p l e s : GC/MS Rinse Blank Field Blank Trip Blank

d d i t i o n a l A n a l y s e s :

D H N u I n i t i a l Readings: S a m p l e Readings:D OVA TOC;_____ TOC_____D Micro t ip BZ_______

B k g n d _

l ^ d d i t i o n a l Comments: (&DQ

BZ__________Bkgnd____

Protective Level:B C D

S E R I A L NO.__H S O S i g n a t u r e :C o n d i t i o n o f Wel l , Remarks:

S a m p l e r ' s S i g n a t u i

000728

| GROUNDWA TER SAMPLING FIELD DA TA SHEETLast W e l l I D N o . Last DateI W e l l I D N o .1 K"\UUO3>~ £n - t^\—O 7( C a s i n g Diameter / J /1 f in

•Casing S t i c k u p sy /| Z. inJ T o t a l W e l l Depth Last T o t a l W e l l|(from T O C ) D e p t h1 2i»A\ f t . f t .J S t a t i c Water Last S t a t i c W a t e rLevel ( f r o m TOC) Levelf / / . 2 / O f t . f t .j W a t e r T h i c k n e s sI ft

I W e l l Diameter Factor1 Diameter 2"f 4") 6" 8"[ F a c t o r .16 1. £? 1.47 2.61Leasing V o l u m eL galScreened I n t e r v a l ( f r o m G S ) f t .

| T i m e

\OKZoqvL ^ / 5IdQzC

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N u m b e r o f C a s i n gV o l u m e s

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/ A t -0,1o . ' 2 -0. 3t f / 5(9c; "

Purge Equipment:Geotech P e r i s t a l t i c P u m pS e r i a l N o .S a m p l e E q u i p m e n t :Geotech P e r i s t a l t i c P u m pS e r i a l N o .A n a y l t i c a l Equipment:( p H / c o n d / D O / T e m p )Y S I 3560XLS e r i a l N o .W a t e r Level Meter:S o l i n s tP u r g e ' C o n t a i n e r i z e d ?

/ Y e s / N oDest ina t i on: . ;/

(J\^l U D\)Y*d(^W a t e rLevel

i L 7 71 1,97

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T a s k I<£OD L o q B o o k #j o b # Zo&?7 c£te-co3

S a m p l e r ' s I n i t i a l sPage / of /

T i m e DateMeter C a l i b r a t i o n T i m eo H = a t ° C

T i m ep H = a t ° CConduc tanc e S t a n d a r d : umhos/cm a t 2 5 ° CMeasured V a l u e :

T i m eumhos/cm a t 2 5 ° C

Dis s o lv ed OxygenC a l i b r a t e d to ma/I at

T i m e° C

N A P L Present? Y e s N oEst imated v o l u m e / t h i c k n e s s ( q a l / i n ) ?Descr ip t i on:S a m p l e c o l l e c t ed? Y e s N oS a m p l e I D :Groundwater S a m p lGroundwater S a m p l eGroundwater S a m p l e

PH

t f - D H£ / ; /

Q.?/6.41<£<?/^9/9 ' ^ T /

A n a l y s e s Requested (see C O C ) F u l l S u i t e Part ia l S u i t e ( e x p l a i n )Q C S a m p l e s : G C / M S Rinse Blank F i e l d B l a n k T r i p B l a n kA d d i t i o n a l A n a l y s e s :

Addi t i ona l Comments: ffife{& £ .O/W>'£ f -*"JTJ? U' i<Jr [1^ U J O ~ j T t v

1

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D H N uD O V AO M i c r o t i p

^ ""iVB C o l l e c t e d ? / Y e s > NoD e p t h f lU: ( ^^I D : f Y l U ^ O ^ - ^ i - M - o l

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A p p r o x .P u m p

D e p t h f t .V i s u a l

Descript ion

C\3ji2s^l l

U(<

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11

I n i t i a l Readings: S a m p l e Readings:TOC TOCBZ BZBkqnd Bkqnd

Protect ive Leve l:B

S E R I A L N O .C D

H S O S i g n a t u r e :C o n d i t i o n o f Wel l , Remarks:

S a m p l e r ' s Signatur^/^fe^?^— j _I000729

| GROUNDWA TER SAMPLING FIELD DA TA SHEET^Last Wel l ID No. Last Date•Well ID No. .• m M3u> - 67 - A. \-TZ> 7[Cas ing Diameter i ftJ S in•Casing S t i c k u p i / /• / , U ' j nj T o t a l W e l l D e p t h Last T o t a l W e l l• ( f r o m T O C ) , D e p t h• -2(2, / Y f t . f t

[ S t a t i c W a t e r Last S t a t i c W a t e rJ l e v e l ( f r o m T O C ) Level• / Z - 4 5 f t f tH W a t e r T h i c k n e s sJ ft

•Well Diameter Fac loTN• Diameter 2" / 4" J 6" 8"H F a c t o r .16 (..6J^> 1.47 2.61J C a s i n g V o l u m e• gal.^Screened I n t e r v a l ( f r o m G S ) .

| T i m e

1 / 0 / 3J I ( ? I 81 I D Z 31/4? zsJ / 6 3 3IT / 0 ^


Int-G a l l o n s

Removed

0d|

O.L0.<J0*6?0&

Purge Equ ipmen t:Geotech P e r i s t a l t i c PumpSerial No.S a m p l e Equ ipment:Geotech P e r i s t a l t i c P u m pS e r i a l N o .A n a y l t i c a l Equipment:( p H / c o n d / D O / T e m p )Y S I 3560XLS e r i a l N o .W a t e r Level Meter:S o l i n s tPurge-Containerized?/ Y e s ) N oDes t ina t i on: -. .

OA-S("ti &J~ \A-t*~~^-WaterLevel

\1Wft,0\fr¥i&Mfcffi

T e r n p ^ f

9 t . Z lg?6M7(AA(ji?l*Q\&.03

E.G.p m h o s / c m

45 *\2J(f'2~.^'L4></%•?4u&

T a s k 1 Oo& Loa Book #J o b # ' Z C D ^ ' I . C X X ^ . O O ^S a m p l e r s I m t j a l s T i

PCme iqe / of // D a t e/ ( ( ( 1 / ^ c c nMeter Calibrat ion Time

p H = a t ° CTime.

o H = a t ° CConductance S t a n d a r d : urnMeasured Value: umhos/cm at 2Dissolved OxygenC a l i b r a t e d to ma/I at

hos/cm a t 2 5 ° CT i m e5 ° C

T i m e° C

N A P L Present? Y e s N oEst imated v o l u m e / t h i c k n e s s ( q a l / i n ) ?Descript ion:S a m p l e c o l l e c t e d ? Y e s N oS a m p l e I D :

s — \Groundwater S a m p l e C o l l e c t e d ? (Yesy N oGroundwater S a m p l e D e p t h ( f t . ) :Groundwat er S a m p l e ID: JT \[/Oo(0~ fa - N-O"7

PH

b&Lteftb(j?^b.uebnot*f-i\

•Analyses Requested (see C O C ) F u l l S u i t e Part ial S u i t e ( e x p l a i n )| Q C S a m p l e s : G C / M S Rinse Blank F i e l d Blank T r i p Blank

•Addit ional Analyses:

• A d d i t i o n a l Comments: (Q^1^ CiX-U?^ Sx^vp^ Odt~l'Y\L,1 for s^cs 00fc>

Disso lved0 2 m g / l i t e r

330£-2-7/-^?/-^\.0(0,cil

D H N uD O V AD M i c r o t i p

PumprRate^GPMm j 0meItoX/ 9 7 - IA v 7 , 6/ 5 M


D e p t h f t . V i s u a lDes cr ip t i on

cfasCte&u^6l&*-^6to-rCk^rd^r


Prote c t ive Level:B



S a m p l e r ' s Signaturef^"^ j^^ff^I000730

GROUNDWATER SAMPLING FIELD DATA SHEET T a s kEast W e l l I D N o . Last Date

l IDasing Diameter L in

ta s ing S t i c k u pin

|Tota l W e l l I DepthI r o m T O C ) f t .

( S t a t i c W a t e rsvel t f r o m J O C )

f t -

Last T o t a l W e l lDepth

Las t S t a t i c W a t e rLevel

water T h i c k n e s s| / e l l Diameter Fac top-x

Diameter 2" /4" ) 6" 8"F a c t o r .16 ( .65 ,0 1.47 2.61

Rasing V o l u m egalcreened I n t e r v a l ( f r o m G S ) f t .

J o b #Purge Equipment:Geotech P e r i s t a l t i c PumpSeria l No._________S a m p l e Equ ipmen t:Geotech P e r i s t a l t i c P u m pSerial No.____A n a y l t i c a l Equ ipmen t:( p H / c o n d / D O / T e r n p )Y S I 3 5 6 0 X LS e r i a l N o .Water Level Meter:S o l i n s tP u r g p - G o n t a i n e r i z e d ?

es J NoDestination:

S a m p l e r ' s I n i t i a l s

Log Book #

T i m e Page I of I' oweMeter C a l i b r a t i o npH____=____at_

at

T i m eT i m e

pHConductance S t a n d a r d :Measured Value:_Dissolved OxygenC a l i b r a t e d to

_______nmhos/cm a t 2 5 ° CT i m e

_ p m h o s / c m at 2 5 ° C _ _ _ _ _ _T i m e

_mg/l at.N A P L Present? Y e s N oEstimated v o l u m e / t h i c k n e s s ( g a l / i n ) ? _Descr ip t ion:S a m p l e c o l l e c t ed? Y e s N oS a m p l e ID:___________Groundwat er S a m p l e C o l l e c t e d ?Groundwater S a m p l e D e p t h ( f t . ) : N oGroundwat e r S a m p l e ID: JYll^O~}- 6l- A/- <? 7


VolumesG a l l o n s

RemovedW a t e rLevel

E.C.f j m h o s / c m Dissolved

0 2 m g / l i t e rA p p r o x .

P u m pD e p t h f t .

V i s u a lDescr ip t ion

1/vL 0 1 1 * 2 / 7

0/b / , b,,/ ' V Z-71/ .23 IM.2\0l 2,0 Cto/

l a l y s e s Requested (see C O C ) F u l l S u i t e Part ia l S u i t e ( e x p l a i n )1C S a m p l e s : GC/MS Rinse Blank Fie ld Blank Trip Blank

j i t i o n a l A n a l y s e s :

D H N u I n i t i a l Readings: S a m p l e Readings:D OVA TOC______ TOC______D M i c r o t i p BZ______ BZ______

Bkgnd_ Bkgnd_

d i t l o n a l Comments:Protect ive Level:

B C DS E R I A L NO.__H S O S i g n a t u r e :C o n d i t i o n o f Wel l , Remarks:

S a m p l e r ' s S i g n a t u if000731

GROUNDWA TER SAMPLING FIELD DA TA SHEET Taska s t W e l l I D N o . Last Date

s ing Diameterasing S t i c k u p

T o t a l W e l l 1 D e p t h

s ta t i c Waterevel ( f r o m TOQ/ 0 , 6 Y n .

Last T o t a l W e l lD e p t hLast S t a t i c WaterLevel

V a t e r T h i c k n e s sVeil Diameter F a c t o r \

Diameter 27 4" ) 6" 8"F a c t o r .16V..65/ 1.47 2.61asing V o l u m e

creened I n t e r v a l ( f r o m G S )

Log Book #_

Purge Equipment:Geotech P e r i s t a l t i c PumpSerial No.S a m p l e Equ ipment:Geotech P e r i s t a l t i c PumpS e r i a l N o .A n a y l t i c a l Equ ipmen t:( p H / c o n d / D O / T e m p )Y S I 3560XLSerial No.W a t e r Level Meter:S o l i n s tPurge-Containerized?(Xss-' N oDestinat ion:

T i m e Page J of f

Meter C a l i b r a t i o npH = at

T i m eT i m e

pH at ° CConductance S t a n d a r d :Measured V a l u e : _Dissolved OxygenC a l i b r a t e d to

______nmhos/cm a t 2 5 ° CT i m e

_umhos/cm at 2 5 ° C _ _ _ _ _ _T i m e

_ m g / l a t .N A P L Present? Y e s N oEst imated v o l u m e / t h i c k n e s s ( g a l / i n ) ? _Descr ip t i on:S a m p l e c o l l e c t e d ? Y e s N oS a m p l e ID:___________Groundwat er S a m p l e C o l l e c t e d ?Groundwater S a m p l e D e p t h ( f t . ) : _Groundwater S a m p l e I D :

NO

T i m eNumber of Casing

V o l u m e sGal lon s

RemovedWaterLevel T e m p ^ C

E.G.H mhos/cm PH

Dissolved0 2 m g / l i t e r G P M

A p p r o x .Pump

D e p t h f t . VisualDescript ion

' i r \ Y 0 to 1,0 Ckas3 lo&l (/I. faooo CM CAM ffb.4

67-0

nalyse s Requested (see C O C ) F u l l S u i t e P a r t i a l S u i t e ( e x p l a i n )S a m p l e s : G C / M S Rinse Blank F i e l d Blank T r i p Blank

d d i t i o n a l Analy s e s :

D H N u I n i t i a l Readings: S a m p l e Readings:D OVA TOC______ TOC______D M i c r o t i p BZ______ BZ __

Bkgnd. Bkgnd_

d i t i o n a l Comments:Protective Leve l:

B C DS E R I A L N O . _ _H S O Signature:C o n d i t i o n o f Wel l , Remarks:

S a m p l e r ' s S i

I000732

GROUNDWA TER SAMPLING FIELD DA TA SHEET T a s ka s t W e l l I D N o . Last Date

asing Diameterr, /in

asing S t i c k u protal W e l l ! D e p t h

t a t i c W a t e revel ( f r o f f l T O C )

Last T o t a l W e l lD e p t hLast S t a t i c W a t e rLevel

/ a t e r T h i c k n e s s|/el l Diameter FacroK

Diameter 2" / 4 " ) 6" 8"F a c t o r .16 \.65/J 1.47 2.61

( C a s i n g V o l u m e gai.creened I n t e r v a l ( from G S )*.

Log Book #_

Purge Equipment:Geotech P e r i s t a l t i c PumpSerial No.S a m p l e Equipment:Geotech P e r i s t a l t i c PumpS e r i a l N o .A n a y l t i c a l Equipment:( p H / c o n d / D O / T e m p )Y S I 3560XLSeria l No.W a t e r Level Meter:S o l i n s t

tainerized?N oDestination^ •/cm -set/.

TimeMeter C a l i b r a t i o nDH = at

T i m eT i m e

DH atConduc tance S t a n d a r d : _Measured Value:____Dissolved OxygenCal i bra t ed to______

_umhos/cm a t 2 5 ° CT i m e_umhos/cm a t 2 5 ° C __mg/l at T i m e

N A P L Present? Y e s N oEstimated v o l u m e / t h i c k n e s s ( g a l / i n ) ? _Descript ion:S a m p l e c o l l e c t e d ? Y e s N oS a m p l e ID:_____________Groundwat e r S a m p l e C o l l e c t e d ?Groundwater S a m p l e Depth ( f t . ) : _Groundwat er S a m p l e I D :

N o

T i m eN u m b e r o f Ca s ing

V o l u m e sG a l l o n sRemoved

W a t e rLevel T e m p ° C

E.G.f j m h o s / c m PH

Dissolved0 2 m g / l i t e r

P u r p pRate^GPMA p p r o x .


Visua lDescription

I 0 5 0 O 770

0,1-O05 0,71

1,0

-2.0 (*,(£>

K a ly s e s Requested (see C O C ) F u l l S u i t e Partial S u i t e ( e x p l a i n )S a m p l e s : G C / M S Rinse Blank F i e l d Blank T r i p Blanki t ional Analyse s: . . . / .MM l^as a

D H N u I n i t i a l Readings: S a m p l e Readings:D OVA TOC______ TOC______D M i c r o t i p BZ______ BZ__________

B k g n d _ Bkgnd_Protective Level:

B C Dd i t i o n a l Comments: S E R I A L N O .

H S O S i g n a t u r e :Condi t ion of W e l l , Remarks:

S a m p l e r ' s S i g

000733

J GROUNDWA TER SAMPLING FIELD DA TA SHEET•Last W e l l I D N o . Last Date

j r ' S ^ o n ^ - A f - c nRasing Diameter•basing S t i c k u pT r o t a l W e l l Depth•from T O C )

[ S t a t i c W a t e rA.evel ( f r o m TOC)(Ivater T h i c k n e s s

t\ inLfy' in

Last T o t a l W e l lD e p t hf t

Last S t a t i c W a t e rLevel f t

f t•Veil Diameter Fack5r~\• Diameter 2" / 4" J 6" 8"T Fac tor .16 \J§5/ 1.47 2.61l ea s ing V o l u m e galScreened I n t e r v a l ( f r o m G S )

r T i m emt\fi\*\20l i ( 2 Sf t e o||35p40Lf1

N u m b e r o f Ca s ingV o l u m e s\fk

G a l l o n sRemoved

o0.103OfyOil*

Purge Equipment:Geotech P e r i s t a l t i c P u m pS e r i a l N o .S a m p l e Equipment:Geotech P e r i s t a l t i c PumpS e r i a l No .Anayl t i ca l Equipment:( p H / c o n d / D O / T e m p )Y S I 3560XLSeria l No.W a t e r Level Meter:S o l i n s tPurge-Containerized?/ Y e s / N oDestination: /

W a t e rLevel

4,t<# t &fr\D<s)K j 2-^

T e m p V/

IfZV*W&)Mf&(fi*2\&JO

umhos/cm

24 '2*\(j^nVitoMb•1Mb

T a s k loOOJob # 'T&C&'l. QC^f . CX»:S a m p l e r ' s I n i t i a l sj / O ( 2 .

Loq Book #1 P.T i m e 3geJ_of_\

I ° 1 t e

Meter C a l i b r a t i o n T i m ep H = a t ° C

Timep H = a t ° CConductance S t a n d a r d : umhos/cm a t 2 5 ° CMeasured Value:

T i m eumhos/cm at 25 °C

Dissolved OxygenC a l i b r a t e d to ma/1 at

T i m e° C

N A P L Present? Y e s N oEstimated v o l u m e / t h i c k n e s s ( q a l / i n ) ?Description:S a m p l e c o l l e c t ed? Y e s N oS a m p l e I D :G r o u n d w a t e r S a m p l e C o l l e c t e cGroundwater S a m p l e Depth ( f t . ) :Groundwater S a m p l e ID: X10U/ t t y

PH

<

(ffi(fle.M

(fti'Lb.(*\le&

wialyses Requested (see C O C ) F u l l S u i t e Par t ia l S u i t e ( e x p l a i n )H e S a m p l e s : G C / M S Rinse Blank F i e l d Blank T r i p BlankM i d i t i o n a l A n a l y s e s :

w J d i t i o n a l Comments:

1k <*•** •«3


~7.<ft(0&1

(t.V-3^2.

G$o^ \A


S E R I A L N O .

f\6l)P uoro

R a f l G P M

I1&&\74$n?£\i\i.i\I7?>\

I -7

^^^I? <$e%) No^ l 3 ~ 6 i - k l - O T 7A p p r o x .


VisualDescript ion

(bosdeaScW( £ L>-

(j&U''



H S O S i g n a t u r e :Condi t ion of W e l l , Remarks:

S a m p l e r ' s Signatui^-TT*^^-^I000734

| GROUNDWA TER SAMPLING FIELD DA TA SHEETiLas t W e l l I D N o . Last Date• W e l l I D N o .1 /h t<J/V~ Cy- AJ -O~ll ea s ing Diameter ^\ / i n•Casing S t i c k u p /\ /. / in.j T o t a l W e l l 1 Depth Last T o t a l W e l l( ( f r a m J D C j i D e p t h1 I1?* £• ft. ft.(Stat i c Water Last Sta t i c WaterJ L e v e J ( f r o m T O C ) Level

W a t e r T h i c k n e s s f t .•Wel l Diameter Factory1 Diameter 2" /4" 6" 8"| F a c t o r .16 (.65/ 1.47 2.61

J C a s i n g V o l u m e ^ ~ ^1 gai.(Screened I n t e r v a l ( f r o m G S ) .

1 T i m e

\13ao

\&ic

\\vZ1325

\\5%>\?>&>


0

(A


/ / i ta\o.t-OX\-o2,o2.5

Purge Equ ipmen t:Geotech P e r i s t a l t i c P u m pSeria l N o .S a m p l e E q u i p m e n t :Geotech P e r i s t a l t i c PumpS e r i a l N o .A n a y l t i c a l E q u i p m e n t :( p H / c o n d / D O / T e m p )Y S I 3560XLS e r i a l N o .W a t e r Level Meter:S o l i n s tPurge-Container ized?/ Y e s i /D e s j i n a t i o r

W a t e rLevel

19-'8A\$A\

$A(o^/7rrq#

N o

Temp^o

{ff&&faW&i< n^ K C 3U54c

(fj&iU5Mffi.ee>

LV/Y-^tenmhos/ cm

^d x C j r*)

3eL(&i-<d3£2-<£\

T a s k 1 000 Loa Book #Job # t T OO(0-C03

S a m o j e r ' s I n i t i a l s Paqe ofT i m e| < ( ( T j § M DMeter C a l i b r a t i o n T i m e

p H = a t ° CT i m e

D H a t ° CConduc tanc e S t a n d a r d : urnMeasured V a l u e : umhos/cm at 2Dissolved OxygenC a l i b r a t e d to mq/l at

hos/cm a t 2 5 ° CT i m e

5 ° CTime

° CN A P L Present? Y e s N oEst imated v o l u m e / t h i c k n e s s ( q a l / i n ) ?Descr ipt ion:S a m p l e c o l l e c t ed? Y e s N oS a m p l e I D :Groundwater S a m p lGroundwat e r S a m p l eGroundwater S a m p l e

PH

#. fr7<y.&fZto!G,ttfCjWctt'ltt\^7

[ A n a l y s e s Requested ( s e e C O C ) F u l l S u i t e Par t ia l S u i t e ( e x p l a i n )| Q C S a m p l e s : G C / M S Rinse Blank F i e l d Blank T r i p B l a n k[ A d d i t i o n a l A n a l y s e s :

[Additional Comments: \-^^{O C-O-W. C\ ' <rj\r^lf CUT H^lOi^ PGV^

Disso lved0 2 m g / l i t e r7,4.3

6.0q& . f c >&&eh-&2-(£/i2~&nli,\0


^ _ e C o l l e c t e d ? (Ye^ NoD e p t h ( f t . ) :I D : f h l O K ^ f c - - / a - c r 7

Pump^

Icf5las'23\Vn4

M f c t f\%Afli-l-ILD&

A p p r o x .Pump


Descr ip t ion

(l\&y~Cl&U''Ch&s-LfetJJ^cie^r6 / t £ * / ~

tiers'Cfar-


Protective Level:B



S a m p l e r ' s Signaturej^/^--^-^^I000735

| GROUNDWA TER SAMPLING FIELD DA TA SHEETBast W e l l I D N o . Last Date•/Veil I D N o .• i"\uJt7-C?-AJ -O~7( C a s i n g Diameter y //f c a s i n g S t i c k u pj T o t a l W e l l ( D e p t h•from TOC) ^T s t a t i c WaterAevel (from TOC)P j V a t e r Thi ckne s s

d-. 9- ffr inLast T o t a l W e l lDepth

f tLast Stat i c WaterLevel f t

3 - 3 Z - f t•Veil Diameter Factors.• Diameter 2" /4" ] 6" 8"T Factor .16 (..65l e a s i n g Volume v L 1.47 2.61

gal.•Screened I n t e r v a l ( f r o m G S )

T T i m e1/300I / 3 0 LK Mf c ' k VD o0«3i0LfI

N u m b e r of Cas ingVolumes0


|7\tZL\

(fg\0

'Purge Equipment:Geotech P e r i s t a l t i c PumpSerial N o .S a m p l e Equipment:Geotech P e r i s t a l t i c PumpSerial No.A n a y l t i c a l Equipment:( p H / c o n d / D O f i " e m p )Y S I 3560XLS e r i a l N o .Water Level Meter:S o l i n s tPurge Containerized?

( Yes J NoDestination: jC K \ < ( b T ) f f ^

W a t e rLevel

I I . - 7&.(*\<o.1\k.*>lle.l

tT e m p ^ C

&&d>tft l&M3i>u? T • -UO(j/(-\r(£(t>U^'70

( D O n J U c f v iumhos/cm

3Z<^2W%WVUlZ1632o

T a s k \OCO> 1 II / Mf'f^ ** f~\T\i * **V\ ^?I f l h if ^r^^^iJ 1 » \*r\JL0 lJd3 ^C

S a m p l e r ' s I n i t i a l s

Log Book #P<T i m e age_J_of _ 1.

/ DateMeter C a l i b r a t i o n T i m eo H = a t ° C

T i m ep H = a t ° CConductance S t a n d a r d : umhos/cm a t 2 5 ° CMeasured Value:


Dissolved OxygenCal ibra t ed to mg/l atN A P L P rEst imateDescriptiS a m p l e cS a m p l e 1

Time° C

^ _ vesent? Yes @*ojd v o l u m e / t h i c k n e s s 7 g a l / i n ) ?on::ol l e c t ed? Y e s N oD:

Groundwat er S a m p l e C o l l e c t e d ? ( Y e s / N oGroundwater S a m p l e D e p t h ( f t . ) :Groundwater S a m p l e I D : f o O U -

PHg&

K>41low|l.o311-0(0l\.t>l

•Analyses Requested ( s e e C O C ) F u l l S u i t e Partial S u i t e ( e x p l a i n )He Samples: GC/MS Rinse Blank Field Blank Trip BlankH d d i t i o n a l Analyse s:

^ J d i t i o n a l Comments: \\003\vn&SCLfr&h*>

GOUkclv^Dif Arwon-

1 nr&tcte h&nL


e.ty2^2^I.WZ.l%2A<3

D H N uD O V AD Microt ip

Purpd 'Ra^GPM

'2-tf-lo.-Z.-4:1-1.1-5>o-4.\

n~i-Gi-t*j-cnA p p r o x .Pump

Depth f t .V i s u a l

Descr ip t i on

Ck&s'C\&xsdyy

C(tas-CJU&LT

CJt&U<>


Protective Level:B


H S O S i g n a t u r e :Condit ion of W e l l , Remarks:

S a m p l e r ' s S i g n a t u r e : /I000736

GROUNDWATER SAMPLING FIELD DATA SHEET T a s k^ a s t W e l H D N o . Last Date

V e i l I D N o ./ y ? £ / / ?l ea s ing Diameterbasing S t i c k u p

inin

(Tota l W e l l I Depthom T O C )

( S t a t i c W a t e rbevel ( f r o m T O C )a. ?/ ft-


f tLast S t a t i c W a t e rLevel

Vater Thickness^-___S 3.Q7V e i l Diameter F a cDiameter 2"/ 4" ] 6" 8"F a c t o r .16 .65/ 1.47 2.61

Rasing V o l u m e galcreened I n t e r v a l ( f r o m G S )

Log Book #_Job # . 00tt -002

Purge Equipment:Geotech P e r i s t a l t i c PumpSeria l No.__________S a m p l e Equipment:Geotech P e r i s t a l t i c PumpSerial No.___________A n a y l t i c a l Equipment:( p H / c o n d / D O / T e m p )Y S I 3560XLS e r i a l No.___Water Level Meter:S o l i n s t

tainerized?N o

Dest ination:

S a m p l e r ' s I n i t i a l s T i m ePage | of (

ateMeter C a l i b r a t i o nPH = at

T i m eT i m e

atPHConductance Standard: .Measured Value:____Dissolved OxygenCal i bra t ed to ___

j i m h o s / c m a t 2 5 ° CT i m e

_ f i m h o s / c m a t 2 5 ° C __ m g / l a t _ _ _ _ _ ° C

T i m e

N A P L Present? Y e s / N o / 'Estimated v o l u m e / t h i c k n e £ s f g a l / i n ) ? _Descript ion:S a m p l e c o l l e c t e d ? Y e s N oS a m p l e ID:__________;__Groundwat er S a m p l e C o l l e c t e d ?Groundwater S a m p l e Depth ( f t . ) : _Groundwater S a m p l e I D :

N o? - - Q -7

T i m eN u m b e r o f Ca s ing

V o l u m e sG a l l o n sRemoved

WaterLevel T e m p '

E.G.nmhos/cm PH




Descript ion

11.0V o / M - *jg. I

6 ^ ' 2 7 40,9-

l a l y s e s Requested (see C O C ) F u l l S u i t e Part ial S u i t e ( e x p l a i n ): S a m p l e s : G C / M S Rinse Blank F i e l d Blank T r i p Blank

J d i t i o n a l A n a l y s e s :

D H N u I n i t i a l Readings: S a m p l e Readings:D OVA TOC______ TOC______D M i c r o t i p BZ________

Bkgnd_BZBkgnd_

d d i t i o n a l Comments: coil&ut s*s^f>l-(- w\(&n-(3^-&}Svbcs

Protect ive Level:B C D

S E R I A L NO.__H S O S i g n a t u r e :

Il o n d i t i o n o f Wel l , Remarks:

S a m p l e r ' s S i g n a t u n

000737

• GROUNDWA TER SAMPLING FIELD DA TA SHEETJ$$eM>^ - Last Date•Well I D N o .• wuJ£O-£>-A)~ O~7( C a s i n g Diameter

/ ' n•Casing S t i c k u pj T o t a l Wel l 1 Depth•(from T O C )

[ S t a t i c Water•Level ( f r o m T O C )Twater Thicknes s ,•Well Diameter Factor .• Diameter 2" /A"

j F a c t o r .16 (.65J C a s i n g V o l u m e " '


f t .Las t S t a t i c WaterLevel f t .

£~ f t .^ 6" 8"/ 1.47 2.61£.£>/ gal .

^Screened I n t e r v a l ( f r o m G S )

J T i m e

1 Q&&t&&TQ&ZOlo&*^\C#fiA\ Q#oi*•T1


0


I jvf"*2__4(oe10

T a s k \OOO Loo Book #Job#'2OCS7-OOU>.00'3> P a q e l o f (

Purge E q u i p m e n t :Geotech P e r i s t a l t i c PumpS e r i a l N o .S a m p l e Equ ipment:Geotech P e r i s t a l t i c P u m pS e r i a l N o .A n a y l t i c a l Equipment:( p H / c o n d / D O / T e m p )Y S I 3560XLS e r i a l N o .Water Level Meter:S o l i n s t /We/ tQlP u p c J i T t t o n t a i n e r i z e d ?

Dest inat ion: Qf\.^ fo r^J^,

WaterLevel

qf^

1 o , 0

«?T e m p ^

1*M.I^\^w&>M.&

MM

Ca/tfMCfrd^mhos/cm

/J*" *^^}

SJ ij rt

^^^\/o i f *J

(**' i £**

2*\

S a m p l e r ' s I n i t i a l s T i m e e ate/(j>\OOMeter C a l i b r a t i o n T i m e

p H = a t ° CT i m e

D H = a t ° CConductance S t a n d a r d : umhos/cm a t 2 5 ° CMeasured Value:


Dissolved OxygenCal i bra t ed to ma/I at

T i m e° Cs~\NAPL Present? Yes (ttojEst imateDescr ip t iS a m p l e c

S a m p l e 1

d volume/thickness{g|Won: /^>&£:ol l ec t ed? fc&lgssD: \\4*->£& 1>-K

Groundwat er S a m p lGroundwater S a m p l eGroundwater S a m p l e•y

pH

"7,£

fa&'LbM(U<^(t&

(03d

•Analyses Requested (se e COC) Full S u i t e Partial S u i t e ( e x p l a i n )J Q C S a m p l e s : G C / M S Rinse Blank F i e l d B l a n k T r i p Blank

• A d d i t i o n a l A n a l y s e s :

• A d d i t i o n a l Comments: CRoo collect S*-K-p(f ^102^-6-^-0-7far 3wc&


*.-w0 $ > '^ x '

QM*I.G00.^1.OMt.


f t ) ?

-0 7 Q%2^~^e C o l l e c t e d ? Q f e s ^ X N oD e p t h ( f t . ) :

I D : miOto-^KJ-D-?P u m p

Rate GPMA p p r o x .

P u m pD e p t h f t . V i s u a lDescr ip t i on

cfoJ^cleaJ^cLeaj^cl&z-^xC. 2- "

Cv&u-^


Protective Leve l:B



S a m p l e r ' s S i g n a t u r e : ^ 7 y ^ / L / 7I r000738

GROUNDWATER SAMPLING FIELD DATA SHEET T a s k \QQQLast W e l l I D N o . Last DateW e l l I D N o .

[ C a s i n g Diameter• / I ,easing S t i c k u p

inlotal W e l l 1 Depth

•(from T O C )f t -J S t a t i c Water

Level ( f r o m T D C ) tt.

Last T o t a l W e l lD e p t hLast S t a t i c WaterLevel

W a t e r T h i c k n e s sI W e l l Diameter F a c

Diameter 2" / 4" ) 6" 8"F a c t o r .161 ,65/ 1.47 2.61

casing V o l u m egal .Screened I n t e r v a l ( f r o m G S )

Log Book #_

Purge Equipment:Geotech Peristalt ic PumpSerial N o .S a m p l e Equ ipment:Geotech P e r i s t a l t i c PumpSerial No.A n a y l t i c a l Equipment:( p H / c o n d / D O / T e m p )Y S I 3560XLSeria l N o .W a t e r Level Meter:S o l i n s tPurge Containerized?Y e s N oDest inat ion:

S a m p l e r ' s I n i t i a l sm p l e r ' s I T i m ePage I of /

Meter C a l i b r a t i o nDH = at

T i m e

atPHConductance Standard:

_ ° C _° C

T i m e

Measured V a l u e : _Dissolved OxygenC a l i b r a t e d to___

______nmhos/cm at 25 °CT i m e

_nmhos/cm at 2 5 ° C _ _ _ _ _ _T i m e

_mg/l at.N A P L Present? Y e s N oEst imated v o l u m e / t h i c k n e s s ( g a l / i n ) ? _Descript ion:S a m p l e c o l l e c t ed? Y e s N oS a m p l e ID:___________Groundwater S a m p l e C o l l e c t e d ?Groundwater S a m p l e Depth ( f t . ) : _Groundwater S a m p l e I D :

N o


V o l u m e sG a l l o n s

RemovedWaterLevel tT e m p ' C nmhos/cm PH



D e p t h f t . V i s u a lDescr ip t i on

01.05&?&

2 7%7.33

Z.

alyses Requested (see COC) Full S u i t e Partial S u i t e ( e x p l a i n )e S a m p l e s : G C / M S Rinse Blank F i e l d Blank T r i p Blank

d i t i o n a l Analy s e s :

D H N u I n i t i a l Readings: S a m p l e Readings:D OVA TOC______ TOC______D M i c r o t i p BZ______ BZ_____B k g n d _ Bkgnd_

J d i t i o n a l Comments:Protective Level:

B . C DS E R I A L N O . _ _H S O S i g n a t u r e :

H

I

C o n d i t i o n o f Wel l , Remarks:

S a m p l e r ' s Signat^jfed^^-^

000739

f GROUNDWA TER SAMPLING FIELD DA TA SHEET•Last W e l l ID No. Last Date•/Vei l ID No. , ^-nRasing Diameter //•basing S t i c k u p o i

j t o t a l W e l l Depth Last T o t a l W e l l•from TOC) DepthI M.U'l «. ftJ S t a t i c Water Last S t a t i c WaterA.evel ( from TOC) Levelwater T h i c k n e s s•Veil Diameter Factor• Diameter /2" ) 4" 6" 8"T F a c t o r (l,6y).65 1.47 2.61l ea s ing V o l u m l r• g a ' -f t creened Interva l ( f r o m G S )

r Time

m/$!']Aaô\\eyz•No\\lf&It^bLfI

N u m b e r of Cas ingVolumes

intG a l l o n sRemoved

OOA(1,2,a 305C.te

T a s k OOC? Log Book #Job # /> -~ l-LsUL{>-C&3 Page (of /

Purge Equipment:Geotech P e r i s t a l t i c PumpSerial No.S a m p l e Equipment:Geotech P e r i s t a l t i c P u m pSeria l No.A n a y l t i c a l Equipment:( p H / c o n d / D O / T e m p )Y S I 3560XLS e r i a l N o .Water Level Meter:S o l i n s tPurgp-Conta iner i z ed?Gr MoDestinat ion: =-. A

W a t e rLevel

500<5.0&og

'Si Cc*^d

T e m p o s

^1,^

3B&1k>ou\(fidt?c» /^(00. fc

E.C.umhos/cm

375"3

3 ' ^ /37^TI3 / 7

S a m p l e r ' s l n i t i a l s Time ( / / I T / S f i bMeter C a l i b r a t i o n T i m ep H = a t ° C

T i m ep H = a t ° CConductance S t a n d a r d : umhos/cm a t 2 5 ° CMeasured V a l u e :


Dissolved OxygenC a l i b r a t e d to mq/l at

T i m e° C

N A P L Present? Y e s N oEstimated v o l u m e / t h i c k n e s s ( g a l / i n )?Descript ion:S a m p l e c o l l e c t ed? Y e s N oS a m p l e I D :

^ i «fc.Groundwat er S a m p l e C o l l e c t e d ? fre$J N oGroundwat er S a m p l e D e p t h (ft. ): **=*Groundwater S a m p l e ID: YY\ V^7~l~î - M~ O"l

pH6.<&

U£>(*M6

fafvL(*&>bfi'3

•Analyses Requested (see C O C ) F u l l S u i t e Part ia l S u i t e ( e x p l a i n )pC S a m p l e s : GC/MS Rinse Blank Fie ld Blank Trip Blank•bditional Analyse s: (/(,&/(. ~p(JJ^L . l^dt^J^. K \ 2 S S n ^ j / U

Îdi t i ona l Comments. \~)QQ 0(}AJ£Cr 2rt.rT~pu? (~'J*&

L / Y n ( A > 2-"*?" tl ' O*"Cx 7 S t f X


73.W

^ -, *&2,3o2AZI - T 3

D H N uD OVAD M i c r o t i p

Pump

l&>3m<\41 iDiz<\7*.}

-7?, 7

A p p r o x .PumpDepth f t .

V i s u a lDescription

f / O l t f f ac \vJLja^d'^^/OVCiCMr/o^jy-i x k 5 l / d > ' 0 - /

I n i t i a l Readings: S a m p l e Readings.TOC TOCBZ BZBkqnd Bkqnd


S E R I A L N O .H S O Signature:C o n d i t i o n o f Well , Remarks:

S a m p l e r ' s S i g n a t u r e : (^^l^fiI000740

| GROUNDWA TER SAMPLING FIELD DA TA SHEETilast W e l l I D N o . Last Date

W r Y \ v o £ $ -<rt- j U - f v 7l eas ing Diameter _1 ' /L, in

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S a m p l e r ' s S i g n a t u f e r y l'û^r^'I000741

A T T A C H M E N T 3R E G I O N A L DATA REVIEW REPORT

000742

U N I T E D S T A T E S E N V I R O N M E N T A L P R O T E C T I O N A G E N C Y* ** *I" f~. \ REGION 6H O U S T O N B R A N C H

10625 F A L L S T O N E R D .H O U S T O N , T E X A S 77099

M E M O R A N D U M

Date: December 11, 2000S u b j e c t : Contrac t Laboratory Program Data Review

^ 6**u^ <~M a r v e l y j V H u m p r i r f t y , A rF r o m : M a r v e l y n / H u m p H r & y , Alt erna t e E S A T RPO, 6 M D - H CT o : D . A b s h i r e , 6 S F - A T

S i t e : _ _ _ _ T E X A R K A N A WOOD P R E S E R V I N G C O .

Cas e#: 28724_____________________S D G # ; F05C1______________________

The EPA Region 6 H o u s t o n Branch ESAT d a t a review team hasc o m p l e t e d a review of the submit t ed C o n t r a c t Laboratory Program(CLP ) da ta pa ckage f o r t h e r e f e r e n c e d s i t e . The s a m p l e s analyzedand reviewed are d e t a i l e d in the a t t a ch ed Regional d a t a reviewrepor t .The d a t a package i s a c c e p t a b l e f or regional use. Prob l ems , i fany, are l i s t e d in the report narrative.If you have any questions r egard ing the da ta review r e p o r t ,p l e a s e cal l me at ( 2 8 1 ) 983-2140 .A t t a c h m e n t scc: R. F l o r e s , Region 6 C L P / T P O

M. E l - F e k y , Region 6 Data Coord ina torF i l e s ( 2 )

000743

L O C K H E E D M A R T I N S E R V I C E S GROUPE S A T R E G I O N V I

10101 S O U T H W E S T F R E E W A Y , S U I T E 5 0 0H O U S T O N , T X 77074

MEMORANDUM

D A T E : December 11, 2000T O : M e l v i n R i t t e r / M a r v e l y n H u m p h r e y , E S A T R P O / A l t e r n a t e

R P O , R e g i o n VI .F R O M : T o m C . H . C h i a n g , E S A T T e a m M / ^ a g e r , Region V IS U B J E C T : C L P Data Review

3am M^mc

R E F : T D F # 6-1071A E S A T # 0-2282E S A T C o n t r a c t N o . 68-D6-0005

A t t a c h e d i s the d a t a review summary for Case # 28724S D G # F Q 5 C 1S i t e T e x a r k a n a W o o dP r e s e r v i n g C o .

C O M M E N T S :

I . C O N T R A C T U A L A S S E S S M E N T O F T H E D A T A P A C K A G EThe CCS r epor t was u n a v a i l a b l e a t th e time th i s d a t a reviewr epor t w a s p r e p a r e d . T h e reviewer f o u n d t h e h a r d c o p yp a c k a g e c o n t r a c t u a l l y c o m p l i a n t .

I I . T E C H N I C A L U S A B I L I T Y A S S E S S M E N T O F T H E D A T A P A C K A G ET h e t o t a l number o f r e s u l t s reviewed w a s 1,003 f o r t h i s d a t ap a c k a g e . A l l r e s u l t s a r e a c c e p t a b l e .

Page 1 of 17

000744

U N I T E D S T A T E S E N V I R O N M E N T A L P R O T E C T I O N A G E N C YR E G I O N 6

H O U S T O N B R A N C H10625 FALLSTONE ROADH O U S T O N , T E X A S 77099

O R G A N I C R E G I O N A L D A T A A S S E S S M E N T

C A S E N O . _ _L A B O R A T O R YC O N T R A C T # _SDG#______SOW#______A C C T # _ _ _ _ _S F #

2 8 7 2 4M I T K E M6 8 - D 6 - 0 0 6 3F 0 5 C 1S O W O L C 0 2 . 11 5 Q 1 0 2 D J N 1 35 0 1 0 2 D 9 1

S I T E T e x a r k a n a W o o d P r e s e r v i n g C o .N O . O F SAMPLES________17________M A T R I X _ _ _ _ _ _ _ _ _ _ _ W a t e rE S A TR E V I E W E R ( I F N O T E S D )R E V I E W E R ' S N A M E Y i n a - P i n g H s i e hCOMPLETION DATE December 11. 2000

S A M P L E N O . F O - 5 C 1F O - 5 C 2F O - 5 C 3F O - 5 C 4

F O - 5 C 5F O - 5 C 6F O - 5 C 7F O - 5 C 8

F O - 5 C 9F Q - 5 D QF O - 5 D 1F O - 5 D 2

F O - 5 D 3F O - 5 D 4F O - 5 D 5F O - 5 D 6

F O - 5 D 7

D A T A A S S E S S M E N T S U M M A R YB N A

0

1 . H O L D I N G T I M E S2 . G C / M S T U N E / I N S T R . P E R F O R M .3 . C A L I B R A T I O N S4 . B L A N K S5 . S M C / S U R R O G A T E S6 . L A B O R A T O R Y C O N T R O L S A M P L E S ( L C S )7. OTHER QC8 . I N T E R N A L S T A N D A R D S9 . C O M P O U N D I D / Q U A N T I T A T I O N

1 0 . P E R F O R M A N C E / C O M P L E T E N E S S1 1 . O V E R A L L A S S E S S M E N T0 = D a t a had no p r o b l e m s .M = D a t a q u a l i f i e d due to m a j o r or minor p r o b l e m s ,Z = Data u n a c c e p t a b l e . .N A = N o t a p p l i c a b l e .

A C T I O N I T E M S :AREA OF C O N C E R N :N O T A B L E P E R F O R M A N C E : T h e d a t a p a c k a g e arrived 3 c a l e n d a r d a y se a r l y f o r t h e c o n t r a c t u a l 14-day t u r n a r o u n d t ime.

Page 2 of 17

000745

C O M M E N T S / C L A R I F I C A T I O N SR E G I O N VI CLP QA REVIEW

C A S E 2 8 7 2 4 S D G F 0 5 C 1 S I T E T e x a r k a n a W o o d P r e s e r v i n g C o . L A B M I T K E MThe f o l l o w i n g i s a summary of s a m p l e q u a l i f i e r s used by Region 6i n r e p o r t i n g t h i s C L P d a t a :

____No.___ A c c e p t a b l e _ P r o v i s i o n a l U n a c c e p t a b l eBNA _____12_____ ___________ ___________

C O M M E N T S : T h i s S D G conta ins 1 7 water s a m p l e s f o r l o wc o n c e n t r a t i o n B N A a n a l y s i s b y S O W O L C 0 2 . 1 . A c c o r d i n g t o t h eO T R / C O C r e cord s , s a m p l e s F O - 5 D 2 a n d F O - 5 D 3 were f i e l d d u p l i c a t e s ,s a m p l e F O - 5 D 4 was a f i e l d b l a n k , and s a m p l e F O - 5 C 3 was a r in sa t e .T h e d a t a p a c k a g e arrived 3 c a l e n d a r d a y s e a r l y f o r t h ec o n t r a c t u a l 14-day turnaround t ime , and it was c o n t r a c t u a l l yc o m p l i a n t .The o n l y t a r g e t a n a l y t e r e p o r t e d a t a c o n c e n t r a t i o n above theCRQL was a c e n a p h t h e n e in t h i s S D G , and it was on ly d e t e c t e d ins a m p l e s F O - 5 D 2 a n d F O - 5 D 3 . A l l r e s u l t s a r e a c c e p t a b l e . T h et e c h n i c a l u s a b i l i t y o f a l l r e p o r t e d s a m p l e r e s u l t s i s i n d i c a t e db y E S A T ' s f i n a l d a t a q u a l i f i e r s i n t h e Data Summary T a b l e . A nE v i d e n c e A u d i t w a s c o n d u c t e d f o r t h e C o m p l e t e S a m p l e D e l i v e r yG r o u p F i l e ( C S F ) , a n d t h e aud i t r e s u l t s were documented i n t h eE v i d e n c e I n v e n t o r y C h e c k l i s t .N O T E : T H E F O L L O W I N G R E V I E W N A R R A T I V E A D D R E S S E S B O T H C O N T R A C T U A LI S S U E S ( B A S E D O N T H E S T A T E M E N T O F W O R K ) A N D T E C H N I C A L I S S U E S( B A S E D O N T H E N A T I O N A L F U N C T I O N A L G U I D E L I N E S ) . T H E A S S E S S M E N T

M A D E F O R E A C H Q C P A R A M E T E R I S S O L E L Y B A S E D O N T H E T E C H N I C A L D A T AU S A B I L I T Y , W H I C H M A Y N O T N E C E S S A R I L Y B E A F F E C T E D B Y C O N T R A C T U A LP R O B L E M S . T H E A S S E S S M E N T S A R E D E F I N E D B E L O W .A c c e p t a b l e = N o r e s u l t s were q u a l i f i e d f o r a n y p r o b l e ma s s o c i a t e d w i t h t h i s QC p a r a m e t e r .P r o v i s i o n a l = S o m e r e s u l t s were q u a l i f i e d because o f p r o b l e m sa s s o c i a t e d w i t h t h i s QC p a r a m e t e r .U n u s a b l e = All r e s u l t s a r e u n u s a b l e because o f m a j o r p r o b l e m sa s s o c i a t e d w i t h t h i s QC p a r a m e t e r .1 . H o l d i n g T i m e s : A c c e p t a b l e . A l l s a m p l e s m e t c o n t r a c t u a l a n dt e c h n i c a l ( 4 0 C F R P a r t 1 3 6 ) h o l d i n g t ime c r i t e r i a .2 . T u n i n g / P e r f o r m a n c e : A c c e p t a b l e . T h e D F T P P a n a l y s e s m e t G C / M St u n i n g c r i t e r i a .3 . C a l i b r a t i o n s : A c c e p t a b l e . T C L c o m p o u n d s m e t c o n t r a c t u a lc a l i b r a t i o n c r i t e r i a . T h e a n a l y t e 4 - c h l o r o a n i l i n e f a i l e dt e c h n i c a l % R S D a n d % D c a l i b r a t i o n c r i t e r i a . D a t a q u a l i f i c a t i o nwas u n n e c e s s a r y because t h i s a n a l y t e was not d e t e c t e d in anys a m p l e .

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000746

ORGZANIC QA REVIEWC O N T I N U A T I O N PAGE

C A S E 2 8 7 2 4 S D G F 0 5 C 1 S I T E T e x a r k a n a W o o d P r e s e r v i n g C o . L A B M I T K E M4. Blanks: A c c e p t a b l e . The method b l a n k s me t th e c o n t r a c t u a lc r i t e r i a . N o t a r g e t a n a l y t e s were d e t e c t e d i n t h e me thod b l a n k s .F i e l d Blank: N o t a r g e t a n a l y t e s were d e t e c t e d i n f i e l d b l a n ks a m p l e F O - 5 D 4 , d e m o n s t r a t i n g th er e w a s n o f i e l d c o n t a m i n a t i o n .Rinsate: The a n a l y t e b i s ( 2 - e t h y l h e x y l ) p h t h a l a t e wa s d e t e c t e d a t ac o n c e n t r a t i o n b e l o w t h e CRQL i n r i n s a t e s a m p l e F O - 5 C 3 .A s s e s s m e n t for s a m p l i n g e q u i p m e n t c o n t a m i n a t i o n can not bep e r f o r m e d because i n f o r m a t i o n a s s o c i a t i n g t h e s a m p l e s w i th t h er i n s a t e i s no t a v a i l a b l e . H o w e v e r , p l e a s e note tha tb i s ( 2 - e t h y l h e x y l ) p h t h a l a t e was o n l y d e t e c t e d at a c o n c e n t r a t i o nbe low t h e CRQL i n s a m p l e F O - 5 C 7 i n t h i s S D G .5 . S y s t e m Moni t or ing Compounds ( S M C ' s ) / S u r r o g a t e s : A c c e p t a b l e .All s u r r o g a t e recoveries met QC c r i t e r i a .6 . Laboratory Control S a m p l e s ( L C S ) : A c c e p t a b l e . T h e L C Srecover i e s m e t c o n t r a c t u a l c r i t e r i a . A l t h o u g h c o n t r a c t u a l l ya c c e p t a b l e , the recovery of 4 - c h l o r o a n i l i n e e x c e ed ed the QCl i m i t . S i n c e 4 - c h l o r o a n i l i n e was no t d e t e c t e d in any s a m p l e ,d a t a q u a l i f i c a t i o n w a s unnece s sary.7. Other QC:F i e l d d u p l i c a t e s ; A c c e p t a b l e . T h e r e s u l t s f o r t h e f i e l dd u p l i c a t e s were c o n s i s t e n t .8 . I n t e r n a l S t a n d a r d s ( I S ) : A c c e p t a b l e . I n t e r n a l s t a n d a r dp e r f o r m a n c e me t the QC c r i t e r i a for a l l s a m p l e s and s t a n d a r d s .9 . Compound I d e n t i t y / Q u a n t i t a t i o n : A c c e p t a b l e . T h e o n l y t a r g e ta n a l y t e r e p o r t e d at a c o n c e n t r a t i o n above the CRQL wasa c e n a p h t h e n e in t h i s SDG, and i t wa s o n l y d e t e c t e d in s a m p l e sF O - 5 D 2 a n d F O - 5 D 3 . T h e r e p o r t e d a n a l y t e s m e t compoundi d e n t i f i c a t i o n c r i t e r i a .1 0 . P e r f o r m a n c e / C o m p l e t e n e s s : A c c e p t a b l e . T h e d a t a p a c k a g e w a sc o m p l e t e but had one o m i s s i o n and some r e p o r t i n g errors. Thel a b o r a t o r y was c o n t a c t e d for the needed c orre c t i on s andr e s u b m i s s i o n s ( s e e F A X Record L o g ) .11. Overall A s s e s s m e n t : All r e s u l t s are a c c e p t a b l e .

P a g e 4 of 17

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O R G A N I C D A T A Q U A L I F I E R D E F I N I T I O N S

T h e f o l l o w i n g d e f i n i t i o n s p r o v i d e b r i e f e x p l a n a t i o n s o f t h eE S A T - R e g i o n 6 q u a l i f i e r s a s s i g n e d t o r e s u l t s in th e Data S u m m a r yT a b l e .

D Not d e t e c t e d a t r e p o r t e d q u a n t i t a t i o n l i m i t .N I d e n t i f i c a t i o n i s t e n t a t i v e .J E s t i m a t e d va lue .L R e p o r t e d c o n c e n t r a t i o n i s b e l ow the C R Q L .M R e p o r t e d c o n c e n t r a t i o n shou ld be used as a raisedq u a n t i t a t i o n l imi t because o f i n t e r f e r e n c e s a n d / o rl a b o r a t o r y c o n t a m i n a t i o n .R • U n u s a b l e .

H i g h b i a s e d . A c t u a l c o n c e n t r a t i o n may be lower than thec o n c e n t r a t i o n r e p o r t e d .v Low b i a s e d . A c t u a l c o n c e n t r a t i o n may be h i g h e r than thec o n c e n t r a t i o n r e p o r t e d .F + A f a l s e p o s i t i v e e x i s t s .F - A f a l s e n e g a t i v e e x i s t s .B T h i s r e s u l t may be h i g h b ia s ed because o f l a b o r a t o r y / f i e l dc o n t a m i n a t i o n . The r e p o r t e d c o n c e n t r a t i o n is above 5X or10X the c o n c e n t r a t i o n r e p o r t e d in the m e t h o d / f i e l d b l a n k .U J E s t i m a t e d q u a n t i t a t i o n l i m i t .T I d e n t i f i c a t i o n i s q u e s t i o n a b l e because of absence of o thercommonly c o e x i s t i n g p e s t i c i d e s .* R e s u l t no t recommended for u s e because o f a s s o c i a t e d Q A / Q Cp e r f o r m a n c e i n f e r i o r t o tha t f r o m o ther a n a l y s i s .

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000748

Case N o . :Laboratory:

28724M I T K E M

O R G A N I C D A T A S U M M A R YS D G : F 0 5 C 1M a t r i x : Water

Reviewer: Y. H s i e hU n i t s : ug/L

5 U 5 U 5 UQÊggl?M5T^^^gg^gg5go^!^âB^^p^;^s^^5gug^g!^^^ûS^0 5 U 5 U 5 U 5 U 5 Ub i s ( 2 - C h l o r o e t h y l ) ether

aVtexachloroe thane

^2 ,4-Dime thy lpheno l2,4-Dichtorophenol

oro-3-meUiylphenolH e x a c h l o r o c y d o p e n t a d i e n e

" "

ga^ _.. ._______ _______ ______f f i ^ ~4.6-binitro-2-meUiylphenol

5 u ——————~5~0'_; " ""~S~D0 U

4-BromophenyPphenyl e th erPentach loropheno l

F l u o r a n t t i e n e 5 U^ 'B u t y l b e n z y l p h t n a l a t eBenzo(a)anthracene 5 U

_______5 U________5 U________SU__________________ ___:o£U.a^H!?Si3maa;iu.'a!SijgK^^^.5^S U S U S U S U S U 5 U ^b i s ( 2 - E l h y l h e x y l ) p h t h a l a t e 5 UB e n z o ( b ) f l u o r a n t h e n e i t s s u a f f i i a e K g ^ ^ S i j i J i J t p ' i g l ^ ^ g s a u g . g g ]Benzo(a)pyrene .5 U .S U S U S U ^sjgâfeffeias-^ggJgBai^^^-sSHiSIo U 5 U 5 uDibenzo(a, h j a n l f i r a c e n e

S a m p l e V o l u m e ( m L ) :D i l u t i o n F a c t o r :

N u m b e r o f T I C ' s :

5" U 5 U 5 U 5 U 5 U 5 U 5 U

100010

100010

100014

100010

100010

100010

100010

Note: For the r e su l t s l i s t e d in the Data S u m m a r y T a b l e , ESAT has r ep laced the laboratory assigned f lag s withESAT Organic Data Q u a l i f i e r s . The ESAT flag s indi ca t e the technical u s a b i l i t y o f th e reported result s .Page 6 of 17

000749


28724M I T K E M


Reviewer: Y. H s i e hU n i t s : ug /L

S e l H J V U t A T I L cE P A S A M P L E N U M B E R : FO-5C8 F O - 5 C 9 FO-5DO FO-5D1 FO-5D2 FO-5D3 FO-5D4

Hexacnloro e thane

2,4-Dimethylpheno l

Dibenzofuran 5 U5 U S U 5 U 5 U5 U 5 U 5 U 5 U

_LJ_ _ _ _

MiML».*^XrUU2>C&^aixl£Um£2i2£,4,6-Pini t ro-2-me thylpheno l 20 U 20 U 20 U 20_______ 3 LJ _____ 5 U ___ag^

5 U 5 U 5 U 5 U20 U 20 U

4 - B r o m o p h e n y t - p h e n y l e t h e r 5 U 5 U

5 U 5 Uf f i i t e & S M g s i a ^ j S pajpg^ur^^

Ben2o(a)pyrenef^SlS^«Dibenzo(a,h)anthrac ene 5 U fgsre^^5 U S U 5 U , ,_ . , . .S U __ __ 5 U ________ 5 U^


Number o f T I C ' s :

100011

100010

100010

100010

100010

100010

100010

N o t e : For th e r e s u l t s l i s t e d in th e Data Summary T a b l e , ESAT has replaced th e laboratory ass igned f l a g s withE S A T Organi c Data Q u a l i f i e r s . T h e E S A T f l a g s indi ca t e t h e technical u s a b i l i t y o f t h e reported results.

P a g e 7 of 17

000750


28724M I T K E M


Reviewer: Y. H s i e hU n i t s : ug /L

O C M I V U 1 _ A I T L tE R A S A M P L E N U M B E R P L H o IFO-5D5 FO-5D6 FO-5D7'b i s ( 2 - C h l o r o e t h y i ) ether

2 - M e t h y l p h e n o l4 - M e t h y l p h e n o l:NJNitrbs ib^P^r" H e x a c h i o F o e i h a r i e '

2r4-bichloropn~enbl4 - C h l o r o a n i l i n e4 - C h l o r o - 3 - m e t h y l p h e n o l;2M?Sii^PM'l!«Q8;3IH e x a c h l o r o c y c l o p e n t a d i e n e2 5 G S T j p r a ! S ^ o i2 , 4 . 5 - f r i c h l o r o p h e n o l£M^B2 - N i t r b a n i l i n eP:!0M$pA c e n a p h t h y l e n eZ i e L D l n i l i M u3 - N i t r o a n i l i n e>?5eBsiipêQ2 , 4 - D i n i t r o p h e n o lDibenzo furan•aâinitrpSKD i e t h y l p h t h a l a t e"^Chl 'F l u o r e r i e•SNrtîiie^lîSf4 , 6 - D i n i t r o H 2 - m e t h y l p h e n o lS i r N j t f s s a a i p l w n y i a J i M^ B r o m b p h e n y l - p h e n y l e t r i e rHl«i?iIpr^y)2en"P^ntachiorophenolPha^rilrireAnthrac eneD K £ ! ? ^ p ' i t * ! a ! l ! e iF l u o r a n t h e r i e ~Pyreriiei:*S^*J"SiB u t y l b e n z y l p h t h a l a t e^Jî^^&raKB e n z o ( i ) a n t H r a c e n e

__ . _ . . . _ . _ . _ . . . . . . _.„......_......._._....._.._______^^•^'W^^^:irf?S?M^fsyi^M^^^^S^^jH§5 U 5 U 5 U

5 U 5 U___ ___5 U _____________________ _________5 U 5 U 5 U%jjg!^S]irU33;g j»g3^5 U 5 U 5 U ___ _____ ______ ___

"5 U "5 U ___ 5 U _______________ ___ ___ ___^^^?±smî^^^sô^^^^smJ?^^f^Si:ii&^^^S^^^^^S^î^^SS?^!^^^^^^S^5 U 5 U 5 U5 U_ 5 U________5 U ___________________________ __ ______i s g^ s sy jpy sg s f i pg^ s^ iSSi^T^^— — — ~ 2 d ~ U " *20 U 20 U

20 U 20 U 20 U ________5 U 5 U ___ (5 U _____________ ___ _______' * ? ^ - S " " i " > S ' J S s " S i ^ ^ ' < ' ' " i y ^S^^^S^f^s^^^^S^^S^^Sg^SSS^^S^^^^j^î^^^^l^^20 0 20 U 20 U _______ _____ ___

20 U 20 U 20 U ___ __________________ ___________5 U 5 U 5 U5 U 5 U 5 U __________ ___________siujiggg^gfss-^TO 5 U 5 U

20 U 20 U 20 U_____ _____

b i s ( 2 - E t n y l h e x y l ) p h t h ' a l a * t eD p i v o c t y l p h t h a l a t e j j "W-S^B e h i : o ( b ) f l u b r a H t h e n e,B e n z b ( a ) p y r e n eD i b e n z o ( a , h j a n t h r a c e n eBenzoCg,h; i)peryIene ~ ' • j • .,7-."


N u m b e r o f T I C ' S :

_____ ____ _______ _______________

20 U 20 U 20 U5"'U " 5 "U 5 U ___ ___________ " ___ ___E££5Sy.ggl!Si§1^5gu;3îM^^^5~U ' " ' 5"U "5"U" ______ ________ ___ ___?^^r~~.S''fU'^^F*^^5~iUT?^~-^~^~-5^-_,,_-*.., . ..-...-:-.. . - g.-g - ___

_ Ij^^KS^MlgMSlîsp^tgagg^~" "5 'U ---— 5 u 5 u ~-;:^r^s:;u^^^^;;S'JUK ? : ° : ^?^saSTUg^^^gg^ÎK~2i5J.u^jj^SS-. 5";u^^v?j2^"5jyjEiM5"B!S^^5 U 5 U 5 U

^ ' " " " " • • s - - ' Q ^ - - - - ^ - - ^ - ^ - - ' - y ' - Q s ^ ^ - - ^ ' - ' - - ^ - 5r f - u ^ ^ ^ - - ' - " - ^ J - " ' ' " ' ~^"^" ^ ~a^~~"~~*~"''i'"' ^_ J a * ^ :

100010

100010

100010

N o i e : F o r t h e r e s u l t s l i s t e d i n t h e Data S u m m a r y T a b l e , E S A T h a s r ep lac ed t h e laboratory ass igned f l a g s wi thE S A T Organi c Data Q u a l i f i e r s . T h e E S A T f l a g s i n d i c a t e t h e t echnical u s a b i l i t y o f t h e reported r e su l t s .

P a g e 8 of 17

000751

I I N O R G A N I C / O R G A N I C C O M P L E T E S D G F I L E ( C S F ) I N V E N T O R Y C H E C K L I S TCase No. 28724 SDG No. F 0 5 C 1 SDG Nos. To F o l l o w SAS No. Date Rec 1 2 / 1 / Q Q

EPA Lab ID: MITKEMLab Location: 175 M«ro Center Blvd.. Warwick. RI 02886Region: 6 Audit Mn • 7 8 7 2 4 / F 0 5 C 1PP S u b m i t t e d CSF? Yes No X

• RnxNor.0: 1C O M M E N T S :

I t e m DescriDtion8. The C a s e / S D G numbers were entered incorrectly onForm DC-1 (page 250). The auditor corrected them.

Over for addit ional comments.

O R I G I N A L SC U S T O D Y S E A L S1 . Present on package?2. Intact upon receipt?FORM DC-23. Numbering scheme accurate?4. Are enclosed documents l i s t ed?5. Are l i s t ed documents enclosed?FORM DC-16. Present?7. Complete?8. Accurate?C H A I N - O F - C U S T O D YRECORD(s)9. Signed?10. Dated?T R A F F I C REPORT(s)P A C K I N G L I S T ( s )11. Signed?12. Dated?A I R B I L L S / A I R B I L L S T I C K E R13. Present?14. Sinned?15. Dated?

S A M P L E T A G S16. Does DC-1 list tags as being included?17. Present?O T H E R D O C U M E N T S18. Compl e t e?19. Legible?20. Orieinal?20a. If "NO", does the copy indicatewhere original documents are located?

YES

XXXXXXX

XX

XX

XXX

XXXX

X

NO

X

X

N / A

S sf »

I A u d i t e d by:Audited by:Audit ed by:

Signature

Ying-Ping Hsieh/ESAT Data Reviewer

Printed N a m e / T i t l e

Date 12/8/00DateDate

Date Recvd by CEAT:Entered by:

Reviewed by:

TO BE C O M P L E T E D BY CEATDate Entered: Date Reviewed:

Signature - Printed Name/Title

IDC-2

Page 9 of 17

000752

of 1I n R e f e r e n c e t o C a s e N o ( s ) :2 8 7 2 4 S D G : F 0 5 C 1 ( O - 2 2 8 2 )

Contract Laboratory ProgramR E G I O N A L / L A B O R A T O R Y C O M M U N I C A T I O N S Y S T E M

FAX. Record LogLaboratory Name: ______MITKEM_____________Lab Contac t: ______ A g n e s R. Ng _________Region : ______ 6 _________________Regional Contac t : Mahmoud E l - F e k y - EPA _____E S A T Reviewer: _ Y i n g — P i n g H s i e h — E S A T ____FAX initiated by: ___ L a b o r a t o r y X Region

In reference to data for the f o l l o w i n g f ra c t i on s:C S F D e l i v e r a b l e s B N A

Summary of Q u e s t i o n s / I s s u e s :A . C S F Deliverables

The C a s e / S D G numbers were entered i n c o r r e c t l y on F o r m DC-1( p a g e 2 5 0 ) . P l e a s e revise and resubmit th i s p a g e .B. BNA

F o r m 8 ' s f o r t h e i n i t i a l c a l i b r a t i o n were omi t t ed ( O L C 0 2 . 1 ,p. B-18, sec. 2 . 6 . 4 . 1 . 5 ) . P l e a s e submit at th i s time asp a g e s 18A and 18B.N O T E : Any l a b o r a t o r y re submis s ion shou ld be submi t t ed e i ther asan a d d e n d u m to the o r i g i n a l CSF wi th a revised F o r m DC-2 ors u b m i t t e d as a new CSF with a new F o r m DC-2 ( O L C 0 2 . 1 , p. B-31,2 . 7 . 3 ) , except those conta in ing only replacement p a g e s . C u s t o d ys e a l s a r e required f o r a l l C S F re submis s ion s h i p m e n t s .P l e a s e r e spond to the above i tems within 7 davs to:

M r . Mahmoud E l - F e k yU . S . E P A Region 6 L a b o r a t o r y10625 F a l l s t o n e RoadH o u s t o n , T X 77099If you have any q u e s t i o n s , p l e a s e contact me a t ( 2 8 1 ) 983-2128.

______________ _______________S i c j n a t u r ' e ^ . DateDistribution: (1) Lab C o p y , (2) Region Copy, and (3) ESAT CopyPage 10 of 17

000753

led Sidles Environmental PrContrac t Laboratory Programi c c& C h a i n of C u s t o d y Record(For Organic CLP Analys i s)

1. Project Code 6. MaliixC o f c m n / 4 )1. Surf ace Water2. Ground Water3. Leachate4. R e l d Q C '5. Soil/Sediment6. PE-waler7. PE-soil8 . 0 t h e r f s p e c / 7 y / nColumn A)

7. Preservative/Enter InColumn D)1. HCI2. HN033. NaHS044. H2S045. Ice only6. CH30H7. Other (specify/n Column D)N. Not Preserved

CLPS a m p l eNumbers( f r o m l a b e l s )AM a t r i x(fromBox 6)

Olhcr:

BCone.:LowMed

CS a m p l eType:Comp./Grab

DPreser-vative( f r o mBox 7)Other:

TA( d r d o o w )PR* 7 14 21

RAS Analysi sTA( d r d t o M )

PR* 7 U 21VOA

TA(drcbom)PR* 7 14 21B N A PesVPCB

Regional S p e c i f i cTracking Numberor Tag NumbersG •Station 'Location ,I d e n t i f i e r

HM o / D a y /Y e a r / T i m eS a m p l eCollec t ion

ICorre spondingCLP InorganicS a m p l e N o .I

JS a m p l e rIni t ia l sKField QCQualif ier

Bbf* S ' F i t U S p & eD - F i d d D u p f c a d ,R*Rlnut tPE-PvtemEnLU21 y f c t o f c

1100

S h i p m e n t f o r CaseC o m p l e t e ? ( Y / $ Pageol V O A M S / M S P Required? Y / N S a m p l e d :BNA MS/MSP Required? Y/fQ S a m p l e #: A d d i t i o n a l S a m p l e r S i g n a t u r e s Chain of Cus t ody Seal Number(s)Pesl/PCB MSMSD Required? YW Sampl e 0:

*PR provides 7-day d a t a turnaround in add i t i on to pre l iminary results. Requests for _. . , _ . . ._ .pre l iminary r e su l t s will increase analyl i ca l costs. Cha in Of C u s t o d y RecordRelinmi i sh cd by: (Signaluta)

Relinqui shed by: (SigiUlure)

Relinquished by: (Signature)

Dale / Time0-M>/02?Date / T i m e

IDate / TimeI

Received by: (Signature)M 5 f . f 5 TReceived by: (Signature)

Received for Laboratory by:(Signature)


Relinquished by: (Signature)iDale / T i m e

1"Distiibulion: Glue - Region Copy Pink -SMO CopyWhile - Lab Copy for Relurn to SMO Yellow . Lab Copy tor Return to Region ERA F o r m 9110-

D a t e /

D a t e /

T i m e

TimeReceived by: (Signature) /

Received by: (Signature^

•Remarks: Is custody seal inlact? Y/N/none \ /I

2 (2/99)See Raver s \%JQ[Xddi l i onal Standard Ins truc t i on s"See Reverse for Purpose Code Definitions

C L A S S - 9 M O I

" 3 9 6 8 3 4000754

c c f R& C h o f C u s t o d y R o r d( F o r Organic C L P A n a l y s i s )1. Proj e c t Code

Account CodeS i t e N a m e

C i t y . S t a t e S i t e S p i l l I D Op Unit

2. Region No.E: Sampling Co.r (Name)r Signat

3.SFPRPsrF E DBZ

Eaity ActionPAH E MH I

X E S I

long-TermAction

4. Dale Shipped CarnAirbil l Number5 . Ship To: / H T 7 -

6. Matrix(Enter inColumn A)1. S u r f a c e W a t e r2. Ground Water3. Leachate4. Field QC '5. Soil/Sediment6. PE-waler7. PE-soil8. Other (specify /nColumn A)

A T T N :

7. Preservative(Enter inColumn D;1. HCI2. HN033. NaHS044. H 2 S 0 45. Ice only6. CH30H7. Other Cspec/'/V/n Column D)N. Not Preserved

C L PS a m p l eN u m b e r s( f r o m l a b e l s )AM a t r i x( f r o m8 0 x 6 )

Oilier:

BCone.:LowMed

ca m p l eT y p e :Comp./Grab

D3reser-valive( f r o mBox 7)Other:

TA(cvcloom)PR* 7 14 21

RAS Analy s i sTA( d t d a w e j

PR* 7 14 21VOA

TA(circle one)PR* 7 14 21

B N A Pes t /PCS

Regional S p e c i f i cT r a c k i n g Numberor Tag N u m b e r sGS t a t i o nLocationI d e n t i f i e r

HM o / D a y /Y e a r / T i m eS a m p l eCollection

1C o r r e s p o n d i n gC L P Inorgan i cS a m p l e N o .JS a m p l e rI n i t i a l s

KField QCQ u a l i f i e rB ' B l j n k S - f i d d S f A eD . f k * J O u p 6 c < «R ' R i n s a t aPE-PotormEval .

\/S Tifm fan Q~

5- •*2. u / / W oFo^CJS L- yL x;S h i p m e n t f o r CaseComple t e? ( Y ( N j ) , Page_ L o f J _ V O A M S / M S D Required? S a m p l e d :

B N A M S / M S P Required? Y ( N j S a m p l e # : A d d i t i o n a l S a m p l e r S i g n a t u r e s Chain o f C u s t o d y Seal Number(s)Pest/PCBMS/MSD Required? Y/N S a m p l e #:

*PR prov ide s 7-day d a t a turnaround in a d d i t i o n to pre l iminary result s . Requests for /%uoi« «« o..«.»»<!.. D«»Mr^p r e l i m i n a r y r e s u l t s wi l l increase a n a l y t i c a l costs. ____Chain Of C u s t o d y RecordRelinquished by: (Signature)

T^~~^l?*£:*=£~T<-Gt~f~'Rel inqu i sh ed by: (Signature)

R e l i n q u i s h e d by: (Signature)

it ..Date/ Time//" l\f 'QPl&'"gZDale / Time

Date / Time

Received by: (Signature)





Date / T i m e1

Dale / T i m e .1Dale /Time •1

Received by: (Signature) /

Revived by: (Signature) / .\ • /

Remarks: Is cus tody seal intact? Y/N/none \ , /Diminution: Dlue • Rugion Copy Pink • SMO CopyWhile • Lab Copy (or Return to SMO Yellow - Lab Copy lor Return to Region

EPA F o r m 9110-2 (2/99)See Reverse for Addi t ional Standard I n s t r u c t i o n s"See Reverse . fo jXirpose Code Def ini t ions

CUSS-99.001

3 9 6 8 3 5000755

Unit e d Sta l e s Environmental Protection AgencyContract Laboratory Programi n i c ' n w f i c& Chain of C u s t o d y Record( F o r Organic C L P A n a l y s i s )

1, P r o j e c t CodeAccount CodeS i t e N a m e

C i t y . S t a l e S i t e S p i l l I D Op Unit

2. Region No. Sampling Co.(Name)

>ler Signature3. Purpose**leaf SF

E aily Ac lionI APA_ R £ MRl

4. Date Shipped\\l\-T\7ocAiroi l l NumberCarrier

5.

A T T N :

6. Matrix(Enter inColumn A)1. Surface Water2. Ground Water3. Leachate4. Field QC '5. Soil/Sediment6. PE-water7. PE-soil8. Other (specify/ViColumn A)

7. Preservative(Enter inColumn D)1. HCI2. HN033. NaHS044. H2S04. 5. Ice only6. CH30H7. Other (specifyIn Column D)N. Not Preserved

CLPS a m p l eN u m b e r s( f r o m l a b e l s )AM a t r i x( I r o mBox 6)

O f t e n

BCone.:LowMed

CS a m p l eT y p e :Comp./Grab

DPreser-vative( f r o mBox 7)Other

RAS Analy s i sT A( c i t f o o r a )PR* 7 U 21 PR

VOA

TA( A d O O J

BNA

TA(drc too iu)Pesl/PCS

FRegional Spec i f i cTrack ing Numberor Tag Number sG iStation 'LocationI d e n t i f i e r

HM o / D a y /Y e a r / T i m eS a m p l eCol l e c t i on

ICorre spondingCLP Inorgani cS a m p l e N o .I

S a m p l e rI n i t i a l sKField QC .Q u a l i f i e r

B«B»k S - F l c U S p f e0« Field DupBubR ' R i n s a t eP E - P a f c m E n L

S h i p m e n t f or CaseC o m p l e t e ? ( Y / f l ) ) Page_ L o f _ L VOA MS/MSP Required? Y/N S a m p l e 0:SNA MS/MSO Required? Y<^ S a m p l e #: A d d i t i o n a l S a m p l e r Signature s Chain of Cus t ody Seal Number(s)Pesl^CBMS/MSD Required? Y/N S a m p l e #:

*PR provide s 7-day d a t a turnaround in a d d i t i o n to pre l iminary results,p r e l i m i n a r y re sul t s will increase analytical costs. Requests for Chain of C u s t o d y Record LRelinquished by: (Signature) -

Relinqui shed by: (Signature^

Relinqui shed by: (Signature)

• Date / Timef / / /7^} (&1D

Da

Da

e / T i m ei

e / T i m e .


Received by: (Signature)t ' •



Relinquished by: (Signalure)iDale / T i m e

1

Date / Time\1 \Date / T i m e1



. Remarks: Is custody seal intact? Y/N/none ^—^Distribution: Blue • Region Copy Pink-SMO C o p yWhile • Lab Copy for Return lo SMO Yellow - Lab Copy for Return to Region

ERA F o r m 9110-2 (2/99)See Reverse for Addit ional Standard Instruct ions' S e e Reverse f o r Purpose Code Def ini t ions

C L A S S - 9 9 - 0 0 1

396836000756

( F o r Organic C L P A n a l y s i s )1. P r o j e c l C o d e 6. Matrix(Enter inColumn A)

1. S u r f a c e W a t e r2. Ground Water3. Leachale .4. Field QC5. Soil/Sediment6. PE-waler7. PE-soil •8. Other ( s p e c i f y inColumn A)

7. Preservative(EnleiinColumn OJ1. HCI2. HN033. NaHS044. H2S045. Ice only6. CH30H7. Olher (specifyin Column D)N. Not Preserved

C L PS a m p l eN u m b e r s( f r o m l a b e l s )AM a t r i x( f r o mBox 6)

Olher:

BCone.:LowMed

cS a m p l eT y p e :omp./Grab

DPreser-vative( f r o mB o x ? )Olher.

RAS Analys i stt

PR*VOA

TA

B N A

TA(dic ioone)R* 7 U 21P f t i UPCB

Regional S p e c i f i cTracking Numberor Tag N u m b e r sGS t a t i o nLocationI d e n t i f i e r

HM o / D a y /Y e a r / T i m eS a m p l eC o l l e c t i o n

1Corre spondingCLP InorganicS a m p l e N o .JS a m p l e rI n i t i a l s

KField QCQ u a l i f i e rB ' B a n k S « F l d d S p i k e|. Field Dupfcae(•RinutaPE • Perionn Eval.

L u/n/oo•fra

S h i p m e n t f or Case,C o m p l e t e ? ( Y / « ) yPagei r d g e .

._|_of_lV G A M S J M S D Required? Y / N S a m p l e f tB N A M S / M S D Required? Y [ N j S a m p l e d

A d d i t i o n a l S a m p l e r S i g n a t u r e s Chain o f C u s t o d y Seal Number(s)P e s U P C B M S / M S D Required? Y / N S a m p l e d :

*PR provide s 7-day d a t a turnaround in a d d i t i o n to pr e l iminary resul t s . Requests for /»u-:« «f r ,.^nri., D^^Ap r e l i m i n a r y r e s u l t s wil l increase ana ly t i ca l costs. __ C h a i n Of C u s t o d y Record LR e l i n o / i i s h e d by: (Signature) t

Rel inqu i sh ed by: (Signature)

R e l i n q u i s h e d by: (Signature)1

/ Dale / T i m eNrff i$zoDal

Da

e / T i m e

e / Time





Relinquished by: (Signature)i•. Date /Time1 1

Date / T i m eIDate / T i m eI



.Remarks: Is custody seal intact? Y/N/none v /\ ' /

Distribution: Blue - Region Copy Pint -SMO CopyWhile • Lab C o p y (or Return to SMO Yellow • Lab Copy lor Return to RegionEPA F o r m 9110-2 (2/99)

See Reverse f o t Addi t i ona l Standard I n s t r u c t i o n s"See Reverse for Purpose Code DefinitionsC L A S S - 9 9 - 0 0 1

000757

( F o r Organic C L P A n a l y s i s1. P r o j e c t Code 6. MatrixlEnlarinColumn A)

1. Surface Water2. Ground Water3. Leachale4. Field QC5. Soil/Sediment6. PE-water7. PE-soil8. Q\ker (specify inColumn A)

7. PreservativelEnierint o i u f f l / i D )1. HCI2. HN033. NaHS044. H2S045. Ice only6. CH30H7. Other (specifyIn Column D)N. Not Preserved

C L PS a m p l eN u m b e r s( f r o m l a b e l s )AM a t r i x( f r o mBox 6)Other:

BCone.:LowMed


DPreser-vative( f r o mBox 7)Other.

RAS Analysi sT A(ci idoont)

PR* 7 14 21TA( c k c h O K )

PR* 7 < f T ) 2 1VOA

TA(cuctomw)PR* 7 14 21

B N A Pest/PCB

Regional S p e c i f i cTrack ing Numberor Tag N u m b e r sG :Station 'LocationIdent i f i er '

HM o / D a y /Y e a r / T i m eS a m p l eColle c t ion

1Corre spond ingCLP InorganicS a m p l e N o .1

JS a m p l e rI n i t i a l sKField QCQ u a l i f i e r

B "Blank S>FU«Splk«0« Field OvftateR . R j f l U t aPE* Perform EnL

L. 6Dtf L-

S h i p m e n t f o r CaseC o m p l e t e ? ( Y > ( J ) Page VOA MS/MSD Required? Y/N S a m p l e #:BNA MS/MSD Required? Y/<P S a m p l e #:

A d d i t i o n a l S a m p l e r S i g n a t u r e s Chain of C u s t o d y Seal Number(s)P e s l / P C B M S / M S D Required? Y / N S a m p l e d :

*PR prov ide s 7-day d a t a turnaround in a d d i t i o n to pre l iminary results. Requests for «!.»:« «* o..<.«_,!.. D A ~ M »Jp r e l i m i n a r y r e s u l t s Vvil l increase a n a l y t t c a T c o s t s . •_______Chain Of C u s t o d y RecordRelinqui shed by: (Signature)

Relinqui shed by: '(Signature)

Relinqu i sh ed by: (Signature)

/ Date /Time .Vri^BaoDale / T i m e

I :

Dale / TimeI


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Relinquished by: (Signature). ;

Relinquished by: (Signature)iDate / T i m e, | .

Dale / T i m e1Dale / T i m e1

Received by: (Signaturp) . .

Received by: (Signature) •V /..Remarks: Is custody seal intact? Y/N/none \ /

Distribut ion: Blue• Region Copy P i n k - S M O C o p yWhile - lab Copy luf Return to SMO Yellow • Lab Copy for Return to Region EPA F o r m 9110-2 (2/99)See Reverse for Addit ional Standard Ins truc t i on s"See Reverse for Purpose Code Definitions

CLASS-99401

000758

(For. Organic CLP Analy s i s)1. P r o j e c l C o d eAccount CodeS i t e Name

Pre serif M Co.C i t y . S l a t e S i t e S p i l l I D O p U n i t

2. ReflOfiNo.ir ling Co.Sampler (Name) .. _KtJfSa3. Purpose**l e a d

PRPS TF E DBZ

Early ActionPAREMI I

5 "I

4 6. Matrix

5- Ship To:1. S u r f a c e Water2. Ground Water3. Leachate4. Field QC5. Soil/rudiment6. PE-waler7. PE-soil8. Olher fspec/Yy/nColumn A)

7. Preservative(Enter inColumn D)1. HCI2. HN033. NaHS044. H2S045. Ice only6. CH30H7. Olher (specifyin Column D)N. Not Preserved

CLPS a m p l eN u m b e r s( f r o m l a b e l s )AM a t r i x( f r o m8 0 x 6 )

Olher:

Bone.:LowMed


' r e s e r -vative( f r o mB o x ? )Olher:

RAS Analys i sT A(tirdo one)

' R * 7 1 4 2 1TA(welt one)

P R * 7 / T 0 2 1VOA

TA( d r c l t c n e )PR* 7 14 21

B N A ' Pest/PCS

Regional S p e d f i cTracking Numberor Tag N u m b e r sG :Station 'Location ,Ident i f i e r •

HM o / D a y /Y e a r / T i m eS a m p l eC o l l e c t i o n

1Corre spondingCLP InorganicS a m p l e N o .JS a m p l e rI n i t i a l s

KField QCQ u a l i f i e rB-Blani S ' F i d d S p & eD- Field OuptcMP E ' P o f e n n E v i l .

L

S h i p m e n t f o r C aC o m p l e t e ? (Y Page_ j _ o f j _VOA MS/MSD Required? Y/rj S a m p l e #:B N A M S / M S D Required? Y t N J S a m p l e # :

A d d i t i o n a l S a m p l e r S i g n a t u r e s Chain of Cus t ody Seal Numberf sVP e s l / P C B M S / W S D R e q u i r e d ? Y / N S a m p l e d :

*PR prov ide s 7-day d a t a turnaround in a d d i t i o n to pr e l iminary results. Requests for /%• • */-. i j n jp r e l i m i n a r y r e su l t s Will increase analy l i ca l costs. H ' Cha in of C u s t o d y R e C O f d zlR e l i n q u i s h e d by: (Signature}/



. Date / T i m e/ / O T / t o DDate / Time

I ;

Date / T i m eI



Received for Laboratory by:(Signature) ;


Relinquished by: (Signature)i, Date /Time

Dale / T i m e1Dale /Time i1 \

Received by: ("S/gnalurej . . ./Received by! (Signature)

.Remarks: Is custody seal intact? Y/Nl/none /Disliibulion: Blue • Region Copy Pink • SMO CopyWhile - lab C o p y lor Relum lo SMO Yellow • Lab Copy lor Relum lo Region EPA F o r m 9110-2 (2/99)

Reverse for Additional Standard Instructions" S e V f f e v e r s e f o r Purpose Code Def in i t i on sC L A S S - 9 M 0 1

396840000759

77

*PR provide s 7-day d a l a turnaround in add i t i on to pre l iminary results. Requests for «... • *> . • n jp r e l i m i n a r y r e s u l t s ^increase a n a l y t i c a T c o s t s . H • ' • H C h a i n of C u s t o d y RecordRelinqui shed by: (Signature)

Relinqu i sh ed by: (Signature]?

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Date / Timet o i f l / i a f e a rDa

Da

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Disliibution: Blue • Region Copy Pink -SMO CopyWhile • Lab Copy lot Relum lo SMO Yellow - Lab Copy lor Return to Region ERA F o r m 9110-

Dale / T i m e1

Date /Time ...• :•

1 '

Received by: (Signature) /' , / • ' 'Received by: (Signature!/ ;\ i /

: Remarks: Is custody seal intact? Y/N/none \ /See Revers^ for A/ditional Standard Instructions**See Reverse Wr Purpose Code Definitions

2 ( 2 / 9 9 ) V / CIASS-9WXH

3 9 6 8 3 9000760

A T T A C H M E N T 4A N A L Y T I C A L R E S U L T S

T A B L E 1 PAH/PCP and BAP RESULTS

000761

A N A L Y T I C A L R E S U L T S N O T E S P A G E

1. The BAP Equivalent ca l cu la t i on inc ludes the f o l l o w i n g constituents:benzo(a)anthracene; benzo(a)pyrene; b enzo(b)f luoran thene; b enzo(k)f luoranthene;chrysene; dibenzo(a,h)anthracene; and indeno(l ,2 ,3-cd)pyrene .

2. The T o t a l Non-Carcinogenic PAH cal cu la t i on includes the f o l l o w i n g const i tuents:acenaphthene, acenaphthylene, anthracene, dibenzofi iran, f luoranthene , f luorene ,naphthalene, phenanthrene, and pyrene.

3. Def in i t i on of qual i f i er s:J Es t imated value;L Reported concentration is below the contract required quanti sation l imi t ( C R Q L ) ;

andU Not detected at reported quantisation l imi t .

000762

T a b l e 1Groundwat er Moni t o r ing S a m p l i n g S e m i - V o l a t i l e Organics Resul t s , November 2000 ( m g / 1 )

Texarkana Wood Preserving C o m p a n y

S t a t i o n I DS a m p l e I D

Lab IDDate

A n a l y t e QCPhenolb i s [ 2 - C h l o r o e t h y l ] ether2 - C h l o r o p h e n o l2 - M e t h y l p h e n o l2 ,2 ' -Oxyb i s( 1 - c h l o r o p r o p a n e )4 - M e t h y l p h e n o lN - N i t r o s o - d i - n - p r o p y l a m i n eHexachloroe thaneN i t r o b e n z e n eI s o p h o r o n c2 - N i t r o p h e n o l2 , 4 - D i m e t h y l p h e n o lbis [ 2 - C h l o r o e t h o x y ] methane2,4-Dichloropheno lN a p h t h a l e n e4 - C h l o r o a n i l i n eH e x a c h l o r o b u t a d i e n e4 - C h l o r o - 3 - M e t h y l p h e n o l2 - M e t h y l n a p h t h a l e n eH e x a c h l o r o c y c l o p e n t a d i e n e2 , 4 , 6 - T r i c h l o r o p h e n o l2 , 4 , 5 - T r i c h l o r o p h e n o l2 - C h I o r o n a p h t h a l e n e2 - N i t r o a n i l i n eD i m e t h y l p h t h a l a t e

MW-01MW01-G-N-07

FO-5C61 1 / 1 6 / 2 0 0 0

N o r m a l0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u

0.02 u0.005 u

0.02 u0.005 u

MW-03MW03-G-N-07

FO-5C711/17/2000

N o r m a l0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 U0.005 U0.005 U0.005 U0.005 U j0.005 U0.005 U0.005 U0.005 U0.005 U0.005 U

0.02 u0.005 u

0.02 u0.005 u

MW-06MW06-G-N-07

FO-5C81 1 / 1 7 / 2 0 0 0

N o r m a l0.005 u0.005 U0.005 U0.005 u0.005 u0.005 U0.005 U0.005 u0.005 u0.005 u0.005 U0.005 U0.005 U0.005 U0.005 U0.005 u0.005 u0.005 U0.005 u0.005 U0.005 u

0.02 u0.005 u

0.02 u0.005 u

MW-07MW07-G-N-07

FO-5D511/18/2000

N o r m a l0.005 U0.005 . U0.005 U0.005 U0.005 u0.005 U0.005 U0.005 U0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u

0.02 u0.005 U

0.02 U0.005 u

MW-08MW08-G-N-07

FO-5D61 1 / 1 8 / 2 0 0 0


0.02 u0.005 u0.02 u

0.005 u

MVV-09MW09-G-N-07

FO-5D711/18/2000

N o r m a l0.005 u0.005 u0.005 U0.005 U0.005 U0.005 u0.005 u0.005 u0.005 U0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u

0.02 u0.005 u

0.02 u0.005 U

See notes page f or q u a l i f i e r and equ iva l en t c a l c u l a t i o n i n f o r m a t i o n-1

dalaSOSO.frx 0 1 / 3 1 / 2 0 0 1

000763

T a b l e 1 ( C o n t i n u e d )Groundwat er M o n i t o r i n g S a m p l i n g S e m i - V o l a t i l e Organics Resul t s , November 2000 ( m g / 1 )



L a b I DDate

A n a l y t e QCA c e n a p h t h y l e n e2 , 6 - D i n i t r o t o l u e n e3 - N i t r o a n i l i n eA c e n a p h t h e n e2 , 4 - D i n i t r o p h e n o l4 - N i t r o p h e n o lDibenzo furan2 , 4 - D i n i t r o t o I u e n eD i e t h y l p h t h a l a t e4 - C h l o r o p h e n y ! - p h e n y l etherF l u o r e n e4 - N i t r o a n i l i n e4 , 6 - D i n i t r o - 2 - m e t h y l p h c n o lN - N i t r o s o d i p h e n y l a m i n e4 - B r o m o p h e n y l - p h e n y l e t h e rH e x a c h l o r o b e n z e n eP e n t a c h l o r o p h e n o lPhenanthreneA n t h r a c e n eD i - n - b u t y l p h t h a l a t eF l u o r a n t h e n ePyreneB u t y l b e n z y l p h t h a l a t e3 , 3 ' - D i c h l o r o b e n z i d i n eBenzo(a)anthracene

MW-01MW01-G-N-07

FO-5C61 1 / 1 6 / 2 0 0 0

N o r m a l0.005 u0.005 u

0.02 u0.005 u

0.02 u0.02 u

0.002 u0.005 u0.005 u0.005 u0.005 u

0.02 u0.02 u

0.005 u0.005 u0.005 u

0.02 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u

MW-03MW03-G-N-07

FO-5C71 1 / 1 7 / 2 0 0 0

N o r m a l0.005 u0.005 u

0.02 u0.005 u

0.02 u0.02 u

0.005 u0.005 u0.005 u0.005 u0.005 . u

0.02 u0.02 u

0.005 u0.005 u0.005 u

0.02 u0.005 U0.005 U0.005 u0.005 U0.005 u0.002 u0.005 u0.005 u

MW-06MW06-G-N-07

FO-5C811/17/2000

N o r m a l0.005 U0.005 u

0.02 u0.005 u

0.02 u0.02 u

0.005 u0.005 u0.005 u0.005 u0.005 u

0.02 u0.02 u

0.005 u0.005 u0.005 u

0.02 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u

MW-07MW07-G-N-07

FO-5D51 1 / 1 8 / 2 0 0 0

N o r m a l0.005 u0.005 . u

0.02 u0.005 u

0.02 U0.02 u

0.005 U0.005 U0.005 U0.005 U0.005 u

0.02 u0.02 u

0.005 u0.005 U0.005 u

0.02 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 U0.005 U0.005 U

MW-08MW08-G-N-07

FO-5D61 1 / 1 8 / 2 0 0 0

N o r m a l0.005 u0.005 u

0.02 u0.005 u

0.02 u0.02 u

0.005 u0.005 u0.005 u0.005 u0.005 u

0.02 u0.02 u

0.005 u0.005 u0.005 u

0.02 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u

MW-09MW09-G-N-07

FO-5D711/18/2000

N o r m a l0.005 u0.005 U

0.02 U0.005 U

0.02 U0.02 U

0.005 U0.005 U0.005 U0.005 U0.005 U

0.02 U0.02 U

0.005 U0.005 U0.005 U

0.02 u0.005 U0.005 U0.005 V0.005 U0.005 U0.005 U0.005 U0.005 U


dataSOSO.frx 0 1 / 3 1 / 2 0 0 1

000764


T e x a r k a n a Wood Preserving C o m p a n y


L a b I DDate

A n a l y t e QCChryseneb i s ( 2 - E t h y l h e x y l ) p h t h a l a t eD i - n - o c t y l p h t h a l a t eB e n z o ( b ) f l u o r a n t h e n eB e n z o ( k ) f l u o r a n t h e n eBenzo(a)pyrenelndeno( 1 ,2 ,3-cd)pyreneDibenz(a,h)anthraceneB e n z o ( g , h , i ) p e r y l e n eBAP EquivalentT o t a l N o n - C a r c i n o g e n i c P A H s

MW-01MW01-G-N-07

FO-5C611/16/2000

N o r m a l0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u

0.01155 u0.042 u

MW-03MW03-G-N-07

FO-5C71 1 / 1 7 / 2 0 0 0

N o r m a l0.005 U0.002 U0.005 U0.005 U0.005 U0.005 u0.005 U0.005 U0.005 U

0.01155 U0.045 U

MW-06MW06-G-N-07

FO-5C81 1 / 1 7 / 2 0 0 0

N o r m a l0.005 u0.005 U0.005 U0.005 u0.005 u0.005 U0.005 u0.005 u0.005 U

0.01155 u0.045 U

MW-07MW07-G-N-07

FO-5D51 1 / 1 8 / 2 0 0 0

N o r m a l0.005 U0.005 u0.005 u0.005 U0.005 U0.005 u0.005 u0.005 U0.005 u

0.01155 u0.045 u

MW-08MW08-G-N-07

FO-5D611/18/2000


0.01155 u0.045 u

MW-09MW09-G-N-07

FO-5D711/18/2000

N o r m a l0.005 u0.005 u0.005 U0.005 U0.005 u0.005 U0.005 U0.005 U0.005 U

0.01155 U0.045 U

dataSOSO.frx 0 1 / 3 1 / 2 0 0 1


000765

T a b l e 1 ( C o n t i n u e d )Groundwat er M o n i t o r i n g S a m p l i n g S e m i - V o l a t i l e Organics Resu l t s , N o v e m b e r 2000 ( m g / 1 )



Lab IDDate

A n a l y t e QCPhenolbis [ 2 - C h l o r o e t h y l ] ether2 - C h l o r o p h e n o l2 - M e t h y l p h e n o l2 , 2 ' - O x y b i s ( 1 - c h l o r o p r o p a n e )4 - M e t h y l p h e n o lN - N i t r o s o - d i - n - p r o p y l a m i n eH e x a c h l o r o e t h a n eN i t r o b e n z e n eIsophorone2 - N i t r o p h e n o l2 , 4 - D i m e t h y l p h e n o lbis [ 2 - C h l o r o e t h o x y ] methane2 , 4 - D i c h l o r o p h e n o lN a p h t h a l e n e4 - C h l o r o a n i I i n eH e x a c h l o r o b u t a d i e n e4-Chloro-3-Methylpheno l2 - M e t h y l n a p h t h a l e n eH e x a c h l o r o c y c l o p e n t a d i e n e2 , 4 , 6 - T r i c h l o r o p h e n o l2 , 4 , 5 - T r i c h l o r o p h e n o l2-Chloronaph tha l en e2 - N i t r o a n i l i n eD i m e t h y l p h t h a l a t e

MW-13MW13-G-N-07

FO-5DO11/17/2000


0.02 u0.005 u

0.02 u0.005 u

M W - 1 4MW14-G-N-07

FO-5C91 1 / 1 7 / 2 0 0 0

N o r m a l0.005 U0.005 U0.005 U0.005 U0.005 u0.005 u0.005 U0.005 U0.005 U0.005 U0.005 U0.005 u0.005 U0.005 U0.005 U0.005 u0.005 u0.005 U0.005 U0.005 u0.005 u

0.02 u0.005 u

0.02 u0.005 u

MW-17G W 1 7 - G - N - 0 7

FO-5C31 1 / 1 6 / 2 0 0 0

Rinsate0.005 U0.005 U0.005 u0.005 U0.005 U0.005 U0.005 U0.005 U0.005 U0.005 U0.005 U0.005 U0.005 U0.005 u0.005 U0.005 U0.005 U0.005 U0.005 U0.005 U0.005 U

0.02 U0.005 U

0.02 U0.005 U

M W - 1 7MW17-G-N-07

FO-5C41 1 / 1 6 / 2 0 0 0

N o r m a l0.005 u0.005 . u0.005 u0.005 u0.005 u0.005 u0.005 U0.005 u0.005 u0.005 U0.005 U0.005 U0.005 U0.005 U0.005 U0.005 U0.005 u0.005 u0.005 U0.005 U0.005 U

0.02 U0.005 U

0.02 u0.005 u

MW-19MW19-G-N-07

FO-5C21 1 / 1 6 / 2 0 0 0


0.02 u0.005 u

0.02 u0.005 u

MW-20MW20-G-N-07

FO-5C11 1 / 1 6 / 2 0 0 0

N o r m a l0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 U0.005 U0.005 U0.005 U0.005 U0.005 U0.005 U0.005 u0.005 U0.005 U0.005 U0.005 U0.005 U0.005 U0.005 U

0.02 U0.005 U

0.02 U0.005 U


dalaSOSa.frx 0 1 / 3 1 / 2 0 0 1

000766

T a b l e 1 ( C o n t i n u e d )Groundwat er M o n i t o r i n g S a m p l i n g S e m i - V o l a t i l e Organics Resu l t s , November 2000 ( m g / 1 )



L a b I DDate

A n a l y t e QCA c e n a p h t h y l e n e2 , 6 - D i n i t r o t o l u e n e3 - N i t r o a n i l i n eA c e n a p h t h e n e2 , 4 - D i n i t r o p h e n o l4 - N i t r o p h e n o lD i b e n z o f u r a n2,4-DinitrotoIueneD i e t h y l p h t h a l a t e4 - C h i o r o p h e n y l - p h e n y I etherF l u o r e n e4 - N i t r o a n i l i n e4 ,6-Dini t ro-2-me thy lpheno lN - N i t r o s o d i p h e n y l a m i n e4-Bromopheny 1-pheny l e t h e rHexachlorobenzeneP c n t a c h l o r o p h e n o lPhenanthreneAnthraceneD i - n - b u t y l p h t h a l a t eF l u o r a n t h e n ePyreneB u t y l b e n z y l p h t h a l a t e3 , 3 ' - D i c h l o r o b e n z i d i n eBenzo(a)anthracene

MW-13MW13-G-N-07

FO-5DO11/17/2000

Normal0.005 u0.005 u

0.02 u0.005 u

0.02 u0.02 u

0.005 u0.005 u0.005 u0.005 u0.005 u

0.02 u0.02 u

0.005 u0.005 u0.005 u

0.02 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u

M W - 1 4MW14-G-N-07

FO-5C91 1 / 1 7 / 2 0 0 0

N o r m a l0.005 u0.005 ti

0.02 u0.005 U

0.02 u0.02 U

0.005 u0.005 u0.005 u0.005 u0.005 U

0.02 u0.02 U

0.005 u0.005 U0.005 U

0.02 u0.005 u0.005 u0.005 U0.005 u0.005 u0.005 u0.005 u0.005 u

MW-17GW17-G-N-07

FO-5C31 1 / 1 6 / 2 0 0 0

Rinsate0.005 U0.005 U

0.02 u0.005 u

0.02 u0.02 u

0.005 u0.005 u0.005 u0.005 u0.005 u

0.02 u0.02 u

0.005 u0.005 u0.005 u

0.02 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u

M W - 1 7MW17-G-N-07

FO-5C41 1 / 1 6 / 2 0 0 0

Normal0.005 u0.005 U

0.02 U0.005 U

0.02 U0.02 u

0.005 u0.005 U0.005 U0.005 U0.005 U

0.02 U0.02 U

0.005 U0.005 U0.005 u

0.02 U0.005 U0.005 U0.005 U0.005 U0.005 U0.005 U0.005 U0.005 U

MW-19MW19-G-N-07

FO-5C21 1 / 1 6 / 2 0 0 0

N o r m a l0.005 u0.005 u

0.02 u0.005 u

0.02 u0.02 u

0.005 u0.005 u0.005 u0.005 u0.005 u

0.02 u0.02 u

0.005 u0.005 u0.005 u

0.02 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u

MW-20MW20-G-N-07

FO-5C11 1 / 1 6 / 2 0 0 0

Normal0.005 u0.005 U

0.02 U0.005 U

0.02 U0.02 u

0.005 U0.005 U0.005 U0.005 U0.005 U

0.02 U0.02 U

0.005 U0.005 U0.005 u

0.02 u0.005 u0.005 u0.005 U0.005 U0.005 U0.005 U0.005 u0.005 u

See notes page for q u a l i f i e r and equival ent c a l c u l a t i o n i n f o r m a t i o n-5

dalaSOSO.frx 0 1 / 3 1 / 2 0 0 1

000767




Lab IDDate

A n a l y t e QCChryseneb i s ( 2 - E l h y l h e x y l ) p h t h a l a t eD i - n - o c t y l p h t h a l a t eBenzo(b)fluorantheneB e n z o ( k ) f l u o r a n t h e n eBenzo(a)pyreneI n d e n o ( 1 ,2 ,3-cd)pyreneDibenz(a,h)anthraceneB e n z o ( g , h , i ) p e r y l e n eBAP Equ iva l en tT o t a l Non-Carc inogen i c P A H s

M W - 1 3M W 1 3 - G - N - 0 7

FO-5DO11/17/2000


0.01155 u0.045 u

M W - 1 4MW14-G-N-07

FO-5C91 1 / 1 7 / 2 0 0 0

N o r m a l0.005 u0.005 U0.005 U0.005 u0.005 U0.005 u0.005 u0.005 u0.005 u

0.01155 U0.045 u

l V f W - 1 7G W 1 7 - G - N - 0 7

FO-5C31 1 / 1 6 / 2 0 0 0

Rinsate0.005 U0.002 U0.005 U0.005 U0.005 U0.005 U0.005 U0.005 U0.005 U

0.01155 U0.045 U

MW-17MW17-G-N-07

FO-5C411/16/2000

N o r m a l0.005 u0.005 . u0.005 U0.005 U0.005 u0.005 u0.005 u0.005 u0.005 u

0.01155 u0.045 u

MW-19MW19-G-N-07

FO-5C21 1 / 1 6 / 2 0 0 0


0.01155 u0.045 u

MW-20MW20-G-N-07

FO-5C11 1 / 1 6 / 2 0 0 0

N o r m a l0.005 U0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u

0.01155 u0.045 u

dalaSOSO.frx 0 1 / 3 1 / 2 0 0 1

See notes page for q u a l i f i e r and equivalent c a l c u l a t i o n i n f o r m a t i o n-6

000768

T a b l e 1 ( C o n t i n u e d )Groundwa t e r M o n i t o r i n g S a m p l i n g S e m i - V o l a t i l e Organics Resul t s , November 2000 ( m g / I )



L a b I DDate

A n a l y t e QCPhenolb i s [ 2 - C h l o r o e t h y l ] ether2 - C h l o r o p h e n o l2 - M e t h y l p h e n o l2 . 2 ' - O x y b i s ( 1 - ch loropropane)4 - M e l h y l p h e n o lN - N i t r o s o - d i - n - p r o p y l a r n i n eHexachloroe thaneN i t r o b e n z e n eI s o p h o r o n e2 - N i t r o p h e n o l2 , 4 - D i m e t h y l p h e n o lbis [ 2 - C h l o r o e t h o x y ] methane2,4-Dich loropheno lN a p h t h a l e n e4-Chloroani l ineH e x a c h l o r o b u t a d i e n e4 - C h l o r o - 3 - M e t h y I p h e n o I2 - M e t h y l n a p h t h a l e n eH e x a c h l o r o c y c l o p e n t a d i e n e2 , 4 , 6 - T r i c h l o r o p h e n o l2 , 4 , 5 - T r i c h l o r o p h e n o l2 - C h l o r o n a p h t h a l e n e2 - N i t r o a n i l i n eD i m e t h y l p h t h a l a t e

MW-26MW26-G-N-07

FO-5C51 1 / 1 6 / 2 0 0 0

Normal0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u

0.02 u0.005 u

0.02 u0.005 u

MW-27GW27-G-N-07

FO-5D41 1 / 1 7 / 2 0 0 0

F i e l d Blank0.005 U0.005 U0.005 U0.005 u0.005 u0.005 u0.005 u0.005 U0.005 u0.005 U0.005 U0.005 U0.005 U0.005 U0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u

0.02 u0.005 u

0.02 u0.005 U

MW-27MW27-G-D-07

FO-5D31 1 / 1 7 / 2 0 0 0D u p l i c a t e

0.005 U0.005 u0.005 U0.005 u0.005 U0.005 U0.005 U0.005 U0.005 u0.005 U0.005 U0.005 U0.005 U0.005 U0.005 U0.005 U0.005 u0.005 u0.005 u0.005 u0.005 u

0.02 u0.005 u

0.02 u0.005 u

MW-27MW27-G-N-07

FO-5D21 1 / 1 7 / 2 0 0 0

N o r m a l0.005 u0.005 . U0.005 U0.005 U0.005 U0.005 u0.005 U0.005 U0.005 u0.005 U0.005 U0.005 U0.005 U0.005 U0.005 U0.005 U0.005 U0.005 U0.005 u0.005 U0.005 U

0.02 U0.005 U

0.02 U0.005 u

MW-28MW28-G-N-07

FO-5D11 1 / 1 7 / 2 0 0 0

Normal0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u

0.02 u0.005 u

0.02 u0.005 u

L e f tBlank On

P u r p o s e

See notes page for q u a l i f i e r and equival ent c a l c u l a t i o n i n f o r m a t i o n-7

dataSOSO.frx 0 1 / 3 1 / 2 0 0 1

000769

T a b l e 1 ( C o n t i n u e d )Groundwater M o n i t o r i n g S a m p l i n g S e m i - V o l a t i l e Organics Resul t s , November 2000 ( m g / 1 )



L a b I DDate

A n a l y t e QCA c e n a p h t h y l e n e2 , 6 - D i n i t r o t o l u e n e3 - N i t r o a n i l i n eA c e n a p h t h e n e2 , 4 - D i n i t r o p h e n o l4 - N i t r o p h e n o lD i b e n z o f u r a n2,4-Dini tro to lu eneD i e t h y l p h t h a l a t e4 - C h l o r o p h e n y l - p h e n y l etherF l u o r e n e4 - N i t r o a n i l i n e4 , 6 - D i n i t r o - 2 - m e t h y l p h e n o lN - N i t r o s o d i p h e n y l a m i n e4 - B r o m o p h e n y I - p h e n y l e t h e rH e x a c h l o r o b e n z e n eP e n t a c h l o r o p h e n o lPhenanthreneAnthrac eneD i - n - b u t y l p h t h a l a t eF l u o r a n t h e n ePyreneB u t y l b e n z y l p h t h a l a t e3 , 3 ' - D i c h l o r o b e n z i d i n eBenzo(a)anthracene

MW-26MW26-G-N-07

FO-5C511/16/2000

N o r m a l0.005 u0.005 u

0.02 u0.005 u

0.02 u0.02 u

0.005 u0.005 u0.005 u0.005 u0.005 u

0.02 u0.02 u

0.005 u0.005 u0.005 u

0.02 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u

MW-27GW27-G-N-07

FO-5D41 1 / 1 7 / 2 0 0 0

F i e l d B l a n k0.005 U0.005 U

0.02 u0.005 V

0.02 u0.02 u

0.005 U0.005 u0.005 U0.005 U0.005 U

0.02 U0.02 U

0.005 U0.005 U0.005 u

0.02 U0.005 u0.005 U0.005 U0.005 U0.005 u0.005 U0.005 u0.005 u

MW-27MW27-G-D-07

FO-5D31 1/17/2000D u p l i c a t e

0.005 U0.005 U

0.02 U0.009

0.02 u0.02 u

0.005 u0.005 u0.005 u0.005 u0.003 u

0.02 u0.02 u

0.005 u0.005 u0.005 u

0.02 u0.005 u0.005 u0.005 u0.005 U0.005 u0.005 u0.005 u0.005 u

MW-27MW27-G-N-07

FO-5D21 1 / 1 7 / 2 0 0 0

N o r m a l0.005 u0.005 . U

0.02 u0.006

0.02 U0.02 U

0.005 U0.005 U0.005 u0.005 U0.002 LJ

0.02 U0.02 U

0.005 U0.005 U0.005 U

0.02 U0.005 U0.005 U0.005 U0.005 U0.005 U0.005 U0.005 U0.005 U

MW-28MW28-G-N-07

FO-5D11 1 / 1 7 / 2 0 0 0

N o r m a l0.005 u0.005 u

0.02 u0.005 u

0.02 u0.02 u

0.005 u0.005 u0.005 u0.005 u0.005 u

0.02 u0.02 u

0.005 u0.005 u0.005 u

0.02 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u

L e f tBlank OnP u r p o s e


dataSOSO.frx 0 1 / 3 1 / 2 0 0 1

000770

T a b l e 1 ( C o n t i n u e d )Groundwater M o n i t o r i n g S a m p l i n g S e m i - V o l a t i l e Organics Resul t s , November 2000 ( m g / 1 )



L a b I DDate

A n a l y t e QCChryseneb i s ( 2 - E t h y l h e x y l ) p h t h a l a t eD i - n - o c t y l p h t h a l a t eB e n z o ( b ) f l u o r a n t h e n eB e n z o ( k ) f l u o r a n t h e n eBenzo(a)pyreneI n d e n o ( 1 ,2 ,3-cd)pyreneDibenz(a,h)anthraceneB c n z o ( g , h , i ) p e r y l e n eBAP EquivalentT o t a l Non-Carcinogenic P A H s

MW-26MW26-G-N-07

FO-5C511/16/2000


0.01155 u0.045 u

MW-27GW27-G-N-07

FO-5D41 1 / 1 7 / 2 0 0 0

F i e l d Blank0.005 u0.005 u0.005 u0.005 u0.005 u0.005 U0.005 u0.005 u0.005 u

0.01155 u0.045 u

MW-27MW27-G-D-07

FO-5D31 1 / 1 7 / 2 0 0 0D u p l i c a t e

0.005 u0.005 u0.005 u0.005 u0.005 U0.005 U0.005 u0.005 U0.005 U

0.01155 u0.047

MW-27MW27-G-N-07

FO-5D21 1 / 1 7 / 2 0 0 0

N o r m a l0.005 U0.005 U0.005 U0.005 U0.005 u0.005 U0.005 U0.005 u0.005 U

0.01155 U0.043

MW-28MW28-G-N-07

FO-5D11 1 / 1 7 / 2 0 0 0


0.01155 u0.045 u

L e f tBlank OnPurpo s e

dalaSOSO.frx 0 1 / 3 1 / 2 0 0 1


000771

A T T A C H M E N T 5T I C R E S U L T S

000772

MW-06

000773

1LCBL O W C Q N C . W A T E R S E M I V O L A T I L E O R G A N I C S A N A L Y S I S D A T A S H E E T EPA SAMPLE NO.

F 0 5 C 8Lab Name: MITKEM CORPORATION Contract: 68-D6-0063Lab Code: MITKEM Case N o . : 28724 SAS N o . : SDG No. : F 0 5 C 1Lab S a m p l e ID: 71881013L a b F i l e I D : S 3 A 6 6 8 3S a m p l e Volume: 1000.00 (mL)Concentrated Extract Volume:I n j e c t i o n Volume: 1 ( u L )

1 0 0 0 ( u L )

Date Received: 1 1 / 1 8 / 0 0Date Extracted: 1 1 / 1 8 / 0 0Date Analyzed: 1 1 / 2 8 / 0 0Dilution Factor: 1.0

CAS NO. COMPOUNDC O N C E N T R A T I O N( u g / L ) Q

1 0 8 - 9 5 - 2 — — — — — — P h e n o l _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _1 1 1 - 4 4 - 4 — — — — - b i s (- 2 - C h l o r o e t h y l ) Ether9 5 - 5 7 - 8 — — — — — - 2 - C h l o r o p h e n o l _ _ _ _ _ _ _ _ _ _95-48-7— — — — -2-Methylphenol1 0 8 - 6 0 - 1 — — — — — 2 , 2 ' -oxybis (1-Chloropropane)1 0 6 - 4 4 - 5 — — — — — 4 -Methylphenol________6 2 1 - 6 4 - 7 — — — — — N - N i t r b s o - d i - n - p r o p y l a m i n e67-72-1— — — — -Hexachloroethane__________9 8 - 9 5 - 3 — — — — — — N i t r o b a n z e n e _ _ _ _ _ _ _ _ _ _ _ _ _ _78-59-1-- — — — -Isophorone__________________8 8 - 7 5 - 5 — — — — — — 2 - N i t r o p h e n o l ________1 0 5 - 6 7 - 9 — — — — -2,4-Dimethylphenol1 1 1 - 9 1 - 1 - — — — - b i s ( - 2 - C h l o r o e t h o x y ) m e t h a n e _1 2 0 - 8 3 - 2 — — — — - 2 , 4 -Dichlorophenol__________91-20-3 — — — — -Naphthalene______________1 0 6 - 4 7 - 8 — — — — -4 -Chloroaniline8 7 - 6 8 - 3 — — — — — — H e x a c h l o r o b u t a d i e n e5 9 - 5 0 - 7 — — —— -4 -Chloro- 3 -Methylphenol____9 1 - 5 7 - 6 — — — — — — 2 - M e t h y l n a p h t h a l e n e _ _ i i _ _ _ _ _7 7 - 4 7 - 4 - — — — - - - H e x a c h l o r o c y c l o p e n t a d i e n e88-06-2 —— — — -2,4 ,6-Trichlorophenol_______9 5 - 9 5 - 4 — — — — — - 2 , 4 , 5 - T r i c h l o r o p h e n o l _ _ _ _9 1 - 5 8 - 7 — — — — — — 2 - C h l o r o n a p h t h a l e n e _ _ _ _ _ _ _8 8 - 7 4 - 4 — — — — — — 2 -Nitroaniline____________1 3 1 - 1 1 - 3 — — — — — D i m e t h y l p h t h a l a t e _ _ _ _ _ _ _ _ _ _208-96-8- —— - - -Acenaphthylene___________606-20-2- —— ---2,6-Dinitrotoluene_________99-09-2— — — — -3 -Nitroaniline___________8 3 - 3 2 - 9 — — — — — — A c e n a p h t h e n e _ _ _ _ _ _ _ _ _ _

555555555555555555555

205

20

205

UUUUUUUUUUUUUUUUUUUUUU

FORM I L C S V - 1 OLC02.1077

000774

1LCCL O W C O N C . W A T E R S E M I V O L A T I L E O R G A N I C S A N A L Y S I S D A T A S H E E T EPA S A M P L E NO.

F 0 5 C 8Lab Name: MITKEM CORPORATION Contract: 68-D6-0063Lab Code: MITKEM Case N o . : 28724 SAS N o . : SDG No. : F05C1Lab S a m p l e ID: 71881013L a b F i l e I D : S 3 A 6 6 8 3S a m p l e Volume: 1000.00 (mL)Concentrated Extract Volume:I n j e c t i o n Volume: 1 ( u L )

1 0 0 0 ( u L )

Date Received: 11/18/00Date Extracted: 1 1 / 1 8 / 0 0Date Analyzed: 1 1 / 2 8 / 0 0Dilution Factor: 1.0

CAS NO. COMPOUNDC O N C E N T R A T I O N( u g / L ) Q

-2,4 -Dinitrotoluene_-Diethylphthalat e_-4 -Nitroanil ine

5 1 - 2 8 - 5 — — — — — ' - 2 , 4 - D i n i t r o p h e n o l1 0 0 - 0 2 - 7 — — — — — 4 - N i t r o p h e n o l _ _ "132-64-9- — — — -Dibenzofuran __1 2 1 - 1 4 - 2 — — — •8 4 - 6 6 - 2 — — — — - _____7005-72-3 — — — -4-Chlo:cophenyl-phenylether_8 6 - 7 3 - 7 — - - — — F l u o r e n e1 0 0 - 0 1 - 6 — — —5 3 4 - 5 2 - 1 — — — -86-30-6 ——— --101-55-3 — — — -1 1 8 - 7 4 - 1 — — — -8 7 - 8 6 - 5 — — — — -85-01-8 — — — — -1 2 0 - 1 2 - 7 — — —84-74-2 — — — — -2 0 6 - 4 4 - 0 — — — -1 2 9 - 0 0 - 0 — — — —8 5 - 6 8 - 7 — — — -91-94-1— — —56-55-3 — — —2 1 8 - 0 1 - 9 — — —

-4,6-Dimitro-2 -methylphenol_-N-nitrosodiphenylamine ( 1 ) ~-4-Bromophenyl-phenylether_-Hexachlorobenzene_______-Pentachlorophenol_______-Phenanthrene__________-Anthracene ___ ____-Di-n-butylphthalate_-Fluoranthene____"-Pyrene-Butylbenzylphthalate-3,3"-Dichlorobenzidine_-Benzo(a)anthracene___-Chrysene1 1 7 - 8 1 - 7 — — — — — b i s ( 2 -Ethylhexyl) phthalate1 1 7 - 8 4 - 0 — — — — — D i - n - o c t y l p h t h a l a t e _ _ _ _ _ ~2 0 5 - 9 9 - 2 — — — — — B e n z o ( b ) fluoranthene_____207-08-9- — —— -Benzo (k) fluoranthene_______50-32-8— — -- — -Benzo (a) pyrene1 9 3 - 3 9 - 5 — — — — I n d e n o ( l , 2 , 3 -cd) pyrene53-70-3 — — — — — — D i b e n z o ( a , h ) anthracene191-24-2- — -- — -Benzo(g,h , i)perylene_________(1) - Cannot be separated from Diphenylamine

20205555520

2055520

UUUUUUUUUUUUUUUUUUUUUUUUU

UU


000775

1LCFL O W C O N C . W A T E R S E M I V O L A T I L E O R G A N I C S A N A L Y S I S D A T A S H E E TT E N T A T I V E L Y I D E N T I F I E D COMPOUNDS

EPA S A M P L E NO.

F 0 5 C 8Lab Name: MITKEM CORPORATION Contract: 68-D6-0063Lab Code: MITKEM Case N o . : 28724 SAS N o . : SDG No. : F 0 5 C 1Lab S a m p l e ID: 71881013L a b F i l e I D : S 3 A 6 6 8 3S a m p l e Volume: 1000.00 ( m L )Concentrated Extract Volume:I n j e c t i o n Volume: 1 (uL)

1000 (uL)


Number TICs found: 1CAS NUMBER1.2.3.4.5.6.7.8.9.

10.11.12.13.14.15.16.17.18.19.20.21.22.23.24.25.26.27.28.29.30.

COMPOUND N A M EU N K N O W N

RT12.63

E S T . C O N C .( u g / L )14

QJ

FORM I L C S V - T I C OLC02.1

079

000776

Data F i l e j \ \ A V O G f t D R O \ U S E R D A T f l S O r g a n i c S s v o a \ s 3 , i \ 0 0 1 1 2 8 . B \ S 3 f t 6 6 8 3 . DDate t 28-NOV-2000 09:29 'C l i e n t I D : F05C8 -S a m p l e I n f o : 7 1 8 8 1 0 1 3 , F 0 5 C 8 , S 1 1 1 8 - B W 2 , C S , , F 0 5 C i

Instrument: s3.i

V o l u m e I n j e c t e d <uL>: 1.0Column phase: DB-5HS

3,4-;3.3-;3 0 "* ~3.1-j3.042.9-j2.84Z-7':2.6-j2.5-j2 . 4 J2.342.242.1-12.041.9-j

3 1.8I H~ 1.641.541.4-iH ' 1"i ii.0:: 30.94 f0.840.740.6^0.5-j0.4-;° ' 3 J :0.240.14 : -»- i - - -*-. ., i - * ••

Operator: CSColumn diameter: 0.25

\\AVOGADRO\USERDATASOrgan i cSs voa\s3 . iS001128 . B S S 3 A 6 6 8 3 . Drt rt - -? iOl Ol* 1-9 e

00IJHI

t>7 1E « TOl 71" ?Oi C

b 1

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ol -d5

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ich:

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L. .1. . ~J

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|•-«l l _<!.

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18

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0J ]' • 4

t 3* 7N i,Ol

1ia.i

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fi-t

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(VI*H

I»-«

'

CD 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 381 — — — f t p — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — H i n _____________________________________________________________

000777

Data F i l e : S 3 A 6 6 8 3 . DReport Date: 2 9 - N O V - 2 0 0 0 10:54

Data f i l eLab Smp IdI n j DateOperatorS m p I n f oM i s c I n f oCommentMethodM e t h DateCal DateA l s b o t t l eDil F a c t o rI n t e g r a t o r

M i t k e m Corpora t i onC L P O L C 0 2 Q U A N T I T A T I O N REPORT\ \ A V O G A D R O \ U S E R D A T A \ O r g a n i c \ s v o a \ s 3 . i \ 0 0 1 1 2 8 . B \ S 3 A 6 6 8 3 . D71881013 Cl i en t S m p I D : F 0 5 C 8 '

2 8 - N O V - 2 0 0 0 0 9 : 2 9 'C S I n s t I D : S 3 . i7 1 8 8 1 0 1 3 / F 0 5 C 8 , S 1 1 1 8 - B W 2 , C S , , F 0 5 C 1, , , ! , , , , , , , 1 8 - N O V - O O , 1 8 - N O V - O O\ \ A V O G A D R O \ U S E R D A T A \ O r g a n i c \ s v o a \ s 3 . i \ 0 0 1 1 2 8 . B \ s 3 _ C l p _ l o w . m2 8 - N O V - 2 0 0 0 13:58 m t l Quant T y p e : I S T D2 8 - N O V - 2 0 0 0 04:45 C a l F i l e : S 3 A 6 6 7 7 . D2 9 • — — — — — *1.00000H P R T E Compound S u b l i s t : a l l . s u bT a r g e t Ver s i on: 4.03Proce s s ing H o s t : T A R G E T ?

Concentrat ion F o r m u l a : Amt * DF * Uf * V t / ( V o * Vi)Name

DFU fVtVOVi

V a l u e D e s c r i p t i o n1.000 Dilu t ion F a c t o r1.000 ng unit correction f a c t o r1000.000 Volume o f f i n a l extract ( u L )1000.000 Volume o f sample extracted ( m L )1.000 Volume i n j e c t e d ( u L )

CompoundsQ U A N T S I G

M A S S

$ 1 2 - F l u o r o p h e n o l$ 2 Phenol -dS* 6 1,4-Dichlorobenzene-d4$ 12 N i t r o b e n z e n e - d S* 19 N a p h t h a l e n a - d e$ 28 2 - F l u o r o b i p h e n y l* 35 Acenaphthene-d lO$ 47 2 , 4 , f i - T r i b r o m o p h e n o l* 51 Phenanthrene-dl0$ 57 T e r p h e n y l - d l 4* 61 C h r y s e n e - d l 2* 68 F e r y l e n e - d l 2

HT EXP RT REL RT R E S P O N S E

C O N C E N T R A T I O N SO N - C O L U M N F I N A L

( ng} ( u g / L )

11299

15282

136172164330188244240264

101213141518192122252831

.050

.400

.180

.387

.910

.175

.569

.199

.641

.937

.090

.172

101213141518192122252831

.047

.403

.178

.390

.913

.178

.572

.207

.644

.940

.093

.181

( 0(0(1(0(1(0(1(0(1( 0(1(1

. 7 6 2 )

. 941)

. 000)

. 9 0 4 )

. 0 0 0 )

. 9 2 9 )

.000)

. 9 3 6 )

. 000). 9 2 3 ). 0 0 0 ). 000)

4718726 8 0 2 0 B353397801353

14084421489840

816179477800

1310228175820711933261135402

101020282027203720292020

.7896

.9494

.0000

.0185

.0000

.4400 '

.0000

.0807

.0000

.6736

.0000

.0000

1111

28

27

37

30

081

000778

Data F i l e : S 3 A 6 6 8 3 . DReport Date: 29-Nov-2000 10:54

Data f i l eLab Smp idI n j DateOperatorS m p I n f oM i s c I n f oCommentM e t h o dM e t h DateCal DateA l s b o t t l eDi l F a c t o rI n t e g r a t o r

M i t k e m Corpora t i onC L P O L C 0 2 Q U A N T I T A T I O N REPORT\ \ A V O G A D R O \ U S E R D A T A \ O r g a n i c \ S V O a \ s 3 . i \ 0 0 1 1 2 8 . B \ S 3 A 6 6 8 3 . D71881013 C l i e n t S m p I D : F 0 5 C 8

2 8 - N O V - 2 0 0 0 0 9 : 2 9C S I n s t I D : S 3 . i7 1 8 8 1 0 1 3 , F 0 5 C 8 , S 1 1 1 8 - B W 2 , C S , , F 0 5 C 1, , , ! , , , , , , , 1 8 - N O V - 0 0 , 1 8 - N O V - 0 0\ \ A V O G A D R O \ U S E R D A T A \ O r g a n i c \ s v o a \ s 3 . i \ 0 0 1 1 2 8 , B \ s 3 _ c l p _ l o w . m2 8 - N O V - 2 0 0 0 13:58 m t l Quant T y p e : I S T D2 8 - N O V - 2 0 0 0 04:45 C a l F i l e : S 3 A 6 6 7 7 . D291.00000H P R T E Compound S u b l i s t : a l l . s u bT a r g e t Version: 4.03Proce s s ing H o s t : T A R G E T 7

Concentrat ion F o r m u l a : Amt * DP * Uf * V t / ( V o * Vi)Name

DFU fVtvoVi

V a l u e D e s c r i p t i o n1.000 D i l u t i o n F a c t o r1.000 ng unit correction f a c t o r1000.000 Volume o f f i n a l extract ( u L )1000.000 Volume o f s ampl e ex tracted (mL)1.000 Volume i n j e c t e d ( u L )

I S T D RT AREA A M O U N T

6 l , 4-Dich l orob enz ene-d4 13.180 2139870 20.000

C O N C E N T R A T I O N SRT AREA ON-COM ng) FINAL ( u g / L ) QUAL

Q U A N TL I B R A R Y L I B E N T R Y C P N D tt

Unknown12.630

CAS #:1507508 14.0897157 14

082

000779

Data F i l e : S\AVOGADROSUSERBATA\Organic\ svoaSs3. i\001128.B\S3A6683.DDate : 28-NOV-2000 09:29C l i e n t ID: F05C8 I n s t r u m e n t ; s3.iS a m p l e I n f o : 71881013 ,F05C8,S1118-BU2,CS,,F05C1V o l u m e I n j e c t e d (uL>: 1.0 Operator: CSC o l u m n phase: DB-5MS C o l u m n diameter: 0.25Library Search Compound HatchUnknown1,4-Dioxane, d i m e t h y l -Ethane, isothiocyanato-1,3-Dioxolane, 2-e thyl-4-methyl-

CAS Number Library Entry

25136-55-4 NBS75K.L 3278542-85-8 N B S 7 5 K . L 628764359-46-0 NBS75K.L 3247

Q u a l i t y F o r m u l a W e i g h t

64 C6H1202 11664 C3H5NS 8750 C6H1202 116

10.08.0

PO£> 6.0THX: 4.0

J 2.00.0

20

10.08.0

1 6.0r4X: 4.0§5 2.0-

0.0 u.20

10.08.0

3> 6.0

X 4.0II 2.0

0.0 120

10.08.0

> 6.0I~ 4.0

2.00.0

31N

J20

j

Scan 1599 (12.630 m i n ) o f S3A6683.D ( S u b t r a c t e d ) (SCALED)

59s.

L . . J . I l , J l l ..

"-87

127\ y156 l"\ 236v 284%. y296 427x434.... . .. L .. .1. . .,1. . . . . . . .

40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380 400 420

.3f

[\

m/z_ _Entry #3278, 1,4-Dioxane, d i m e t h y l - ( f r o m N B S 7 5 K . L ) ( S C A L E D )

/**1 11, 1 1 ..

•67

, . S"40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380 400 420

/**

140

s.

...1,40

m/z87-

I 1 J

Entry #62876, Ethane, i s o th iocyanato- ( f r o m N B S 7 5 K . L ) ( S C A L E D )

i60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380 400 420m / z

Elsa

. ...

/~

.1. ..

itru #3247, 1,3-Dioxolane, 2-e thyl-4-methyl- ( f r o m N B S 7 5 K . L ) ( S C A L E D )

60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380 400 420m / z

083

000780

E Q U I P M E N T B L A N K A T MW-17

000781

1LCBL O W C O N C . W A T E R S E M I V O L A T I L E O R G A N I C S A N A L Y S I S D A T A S H E E T EPA S A M P L E NO.

F 0 5 C 3Lab Name: MITKEM CORPORATION Contract: 68-D6-0063Lab Code: MITKEM Case No.: 28724 SAS No.: SDG No.: F 0 5 C 1Lab S a m p l e ID: 71881006Lab F i l e ID: S 3 A 6 6 7 2S a m p l e Volume: 1000.00 (mL)Concentrated Extract Volume:I n j e c t i o n Volume: 1 (uL)

1000(uL)

Date Received: 1 1 / 1 7 / 0 0Date Extracted: 11/17/00Date Analyzed: 1 1 / 2 8 / 0 0Dilution Factor: 1.0

CAS NO. COMPOUNDC O N C E N T R A T I O N

( u g / L ) Q

- b i s ( - 2 - C h l o r o e t h y l ) E t h e r _- 2 - Chlorophenol_______~

-Isophorone- 2-Nitrophenol____-2,4-Dimethylpheno l_

1 0 8 - 9 5 - 2 — — — — — P h e n o l1 1 1 - 4 4 - 4 — — — •95-57-8 — — — — •9 5 - 4 8 - 7 — — — — — - 2 - M e t h y l p h e n o l _ _ _ _ _ _ _ _ _1 0 . 8 - 6 0 - 1 — — — — — - 2 , 2 ' -oxybis (1-Chloropropane)1 0 6 - 4 4 - 5 — — — — — 4 - M e t h y l p h e n o l _ _ _ _ _ _ '6 2 1 - 6 4 - 7 — — — — — N - N i t r o s o - d i - n - p r o p y l a m i n e67-72-1 — — — — — -Hexachloroethane98-95-3 —— — — -Nitrobenzene7 8 - 5 9 - 1 — — — -88-75-5 — — — —1 0 5 - 6 7 - 9 — — — -111-91-1- — — — -bis (-2-Chloroe thoxy)methane_1 2 0 - 8 3 - 2 — — — — — 2 , 4 - D i c h l o r o p h e n o l91-20-3 — — — — — - N a p h t h a l e n e _ _ _ [1 0 6 - 4 7 - 8 - — — — - 4 - C h l o r o a n i l i n e :

8 7 - 6 8 - 3 — — —59-50-7 — — — —9 1 - 5 7 - 6 — — — —77-47-4 — — —8 8 - 0 6 - 2 — — — — —9 5 - 9 5 - 4 — — — —

-Hexachlorobutadiene-4-Chloro-3-Methylphenol-2-Methylnaphthalene— - — ---Hexachlorocyclopentadaene— — — - 2 , 4 , 6 - T r i C h l o r o p h e n o l _ _ _ ~— — — — 2 , 4 , 5 - T r i c h l o r o p h e n o l91-58-7— — — — — 2 - C h l o r o n a p h t h a l e n e _ _ _ _8 8 - 7 4 - 4 — — — — — -2-Nitroanil ine1 3 1 - 1 1 - 3 — — ~2 0 8 - 9 6 - 8 — — — _ ___6 0 6 - 2 0 - 2 — — — — — 2 , 6 - D i n i t r o t o l u e n e _99-09-2 — —— — -3-Nitroaniline___83-32-9— — — — -Acenaphthene______

•Dimethylphthalate_•Acenaphthylene_

55555555555555555555520520

20

UUUUUUUUUUUUUUUUUUUUUUUUU

U


000782

1LCCL O W C O N C . W A T E R S E M I V O L A T I L E O R G A N I C S A N A L Y S I S D A T A S H E E T EPA SAMPLE NO.

F 0 5 C 3Lab Name: MITKEM CORPORATION Contract: 68-D6-0063Lab Code: MITKEM Case N o . : 28724 SAS N o . : SDG No. : F 0 5 C 1Lab S a m p l e ID: 71881006Lab F i l e ID: S 3 A 6 6 7 2S a m p l e Volume: 1000.00 ( m L )Concentrated Extract Volume:I n j e c t i o n Volume: 1 ( u L )

1 0 0 0 ( u L )

Date Received: 1 1 / 1 7 / 0 0Date Extracted: 11/17/00Date Analyzed: 1 1 / 2 8 / 0 0Dilution Factor: 1.0

CAS NO. COMPOUND C O N C E N T R A T I O N( u g / L )

-2,4 -Dinitrotoluene_-Diethylphthalate_

5 1 - 2 8 - 5 — — — — — 2 , 4 - D i n i t r o p h e n o l1 0 0 - 0 2 - 7 — — — — — 4 - N i t r o p h e n o l _ _ ~ _1 3 2 - 6 4 - 9 — — — — — D i b e n z o f u r a n1 2 1 - 1 4 - 2 — — -84-66-2 ——— - _________7005-72-3 — -- — -4-Chlorophenyl-phenylether_8 6 - 7 3 - 7 — — — — -Fluorene100-01-6- — — — -4-Nitroaniline5 3 4 - 5 2 - 1 — — — —8 6 - 3 0 - 6 — — — — —101-55-3 —— ~

-Di - n-butylphthalate_- Fluoranthene____~-Pyrene_

-----4,6-Dinitro-2-methylphenol- — -N-nitrosodiphenylamine (1) [_- - — -4 -Bromophenyl -phenylether__118-74-1- —— - - -Hexachlorobenzene87-86-5— — — — -Pentachlorophenol85-01-8— — — — -Phenanthrene___[120-12-7- — — — -Anthracene84-74-2 —— —2 0 6 - 4 4 - 0 — — -1 2 9 - 0 0 - 0 — — — •8 5 - 6 8 - 7 — — — — •9 1 - 9 4 - 1 — — — — •5 6 - 5 5 - 3 — — — — -2 1 8 - 0 1 - 9 — — — -1 1 7 - 8 1 - 7 — — — -117-84-0 ——— -2 0 5 - 9 9 - 2 — — — -2 0 7 - 0 8 - 9 — — — -50-32-8 — — — — -1 9 3 - 3 9 - 5 — — — -53-70-3 — — — — -1 9 1 - 2 4 - 2 — — - -

-Butylbenzylphthalate-3,3"-Dichlorobenzidine-Benzo (a) anthracene-Chrysene-bis (2 -Ethylhexyl) phthalate_-Di -n-octylphthalate______-Benzo (b) f luoranthene_____-Benzo (k) f luoranthene______-Benzo (a) pyrene_-Indeno ( 1 , 2 , 3 -cd) pyrene_-Dibenzo (a, h) anthracene"- B e n z o ( g , h , i ) perylene_(1) - Cannot be separated from Diphenylamine

202055520

2055205555555552

UuUuuuuuuuuuuuuuuuuuuuJ


000783

1LCFL O W C O N C . W A T E R S E M I V O L A T I L E O R G f t N I C S A N A L Y S I S D A T A S H E E TT E N T A T I V E L Y I D E N T I F I E D COMPOUNDS

EPA S A M P L E NO.

F 0 5 C 3Lab Name: MITKEM CORPORATION Contract: 68-D6-0063Lab Code: MITKEM Case N o . : 28724 SAS N o . : SDG No. : F 0 5 C 1Lab S a m p l e ID: 71881006Lab F i l e ID: S 3 A 6 6 7 2S a m p l e Volume: 1000.00 (mL)Concentrated Extract Volume:I n j e c t i o n Volume: 1 ( u L )

1000 (uL)


Number TICs found: 4CAS NUMBER1. 630-01-32. 629-94-73. 638-67-54. 630-03-55.6.7.8.9.10.11.12.

13.14.15.16.17.18.19.20.21.22.23.24.25.26.27.28.29.30.

COMPOUND N A M EH E X A C O S A N EH E N E I C O S A N ET R I C O S A N EN O N A C O S A N E

RT28.5229.1629.8230.57

E S T . C O N C .( u g / L )2322

QN JN JN JN J

FORM I L C S V - T I C037

OLC02.1

000784

Data F i l e : S S A V O G A D R O S U S E R D A T A S O r g a n i c S s v o a S s S . i S 0 0 1 1 2 7 f l . B S S 3 A 6 6 7 2 . DDate : 28-NOV-2000 01:22 'C l i e n t I D : F 0 5 C 3 /S a m p l e I n f o : 71881006,F05C3,S1117-BW4,CS,,F05C1V o l u m e I n j e c t e d <uL>: 1.0C o l u m n phase: DB-5HS

Ins trumen t: s3.i

Operator: CSC o l u m n diameter: 0.25

\ \ A V O G f l D R u \ U S E R D A T A \ O r g a n i c\SvoaSs3 . i \001127 A . BSS3A6672 . D3.5-1 |> g3.4 4 4"i * i3.2-;3.1-j3.02.9^2.8-j2.7-;2 ' 5 12.4.J f2.3-: |2*°": 1 !g |

* 1.8-= -° S!i i • H !

l .O-j '0.9-j0.80.7-:0.6-;0.5-:

0.3-j0.2-;

•

j(M

O

1

1

1?

11iOJ

0

i.4>c

1

34£I

1GTi 6 8 10 12 14 16 18 20 22 24 26^^ Hin

<M

!

1v

28^

1•v

, 1 .'

L . I . .30 32 34 36 38

000785


Data f i l eLab S n a p IdI n j DateOperatorS m p I n f oM i s c I n f oCommentMethodM e t h DateCal DateA l s b o t t l eOil F a c t o rI n t e g r a t o r

Mitkem Corporat ionC L P OLC02 Q U A N T I T A T I O N REPORT\ \ A V O G A D R O \ U S E R D A T A \ O r g a n i c \ S V O a \ s 3 . i \ 0 0 1 1 2 7 A . B \ S 3 A 6 6 7 2 . D71881006 C l i e n t S m p I D : F 0 5 C 3 -

2 8 - N O V - 2 0 0 0 01:22 'C S I n s t I D : S 3 . i7 1 8 8 1 0 0 6 , F 0 5 C 3 , S 1 1 1 7 - B W 4 , C S , , F 0 5 C 1i i f l r f f f r f , 1 7 - N O V - 0 0 , 1 7 - N O V - 0 0\ \ A V O G A D R O \ U S E R D A T A \ O r g a n i c \ s v o a \ s 3 . i \ 0 0 1 1 2 7 A . B \ s 3 _ c l p _ l o w . m2 9 - N O V - 2 0 0 0 11:05 m t l Quant T y p e : I S T D2 7 - N O V - 2 0 0 0 16:41 C a l F i l e : S 3 A 6 6 6 1 . D1 9 — — — — — — '1.00000H P R T E Compound S u b l i s t : a l l . s u bT a r g e t Ver s i on: 4.03Proce s s ing H o s t : T A R G E T 7

Concentrat ion F o r m u l a : Amt * DP * Uf * v t / ( v o * vi)Name V a l u e D e s c r i p t i o n

DFU fVtVOvi

1.0001.0001000.0001000.0001.000

Dilut ion F a c t o rng unit correction f a c t o rVolume of f i n a l extract ( u L )Volume o f s ampl e ex tracted ( m L )Volume i n j e c t e d ( u L )

CompoundsQ U A N T S I 6

M A S S

$ 1 2-Fluoropheno l$ 2 Phenol-dS* 6 l ,4-Dichlorobenzene-d4$ 12 N i t r o b e n z e n e - d 5* 19 N a p h t h a l e n e - d S$ 28 2 - F l u o r o b i p h e n y l* 35 Acenaphthene-dlO$ 47 2 ,4 ,6-Tribromopheno l* 51 Phenanthrene-dlO$ 57 T e r p h e n y l - d l 4* f i l Chzysene-dl2

62 b i a ( 2 - E t h y l h e x y l ) p h t h a l a t e* 68 P e r y l e n e - d l 2

RT EXP RT EEL RT R E S P O N S E


( ng) ( u g / L )= = BB

11299

15282

136172164330188244240149264

10121314151819212225282831

K B

.047

.397

.177

.384

.912

.177

.566.201.643.939.092

1012131415181921222528

.124 -28

.175 31

.052

.408

.183

.390

.912

.178

.577

.212

.649

.940

.098.130.186

(0(0(1(0(1(0(1(0(1(0(1(1(1

.762)

.941)

. 0 0 0 )

.904).000). 9 2 9 ).000). 9 3 6 ).000). 9 2 3 ). 000).001).000)

570090813831344992763684

13323381533968

774834568421

125899218547301228817104219

1207003

13.13.20.29.20.29.20.44.20.30.20.

1411185000001206000027300000605400002267 /0000

1313

29

29

45

30

1.79555 220. 0000

039

000786


QC F l a g Legenda - T a r g e t compound d e t e c t e d but, quanti tated amountBelow Limit Of Q u a n t i t a t i o n ( B L O Q ) .

040

000787


Data f i l eL a b S m p I dI n j DateOperatorS m p I n f oM i s c I n f oCommentM e t h o dM e t h DateCal DateA l s b o t t l eD i l F a c t o rI n t e g r a t o r

M i t k e m Corpora t i onC L P O L C 0 2 Q U A N T I T A T I O N REPORT\ \ A V O G A D R O \ U S E R D A T A \ O r g a n i c \ S v o a \ s 3 . i \ 0 0 1 1 2 7 A . B \ S 3 A 6 6 7 2 . D

71881006 C l i e n t S m p I D : F 0 5 C 32 8 - N O V - 2 0 0 0 01:22C S I n s t I D : S 3 . i7 1 8 8 1 0 0 6 , F 0 5 C 3 , S 1 1 1 7 - B W 4 / C S , , F 0 5 C 1, , , ! , , , , , , , 1 7 - N O V - 0 0 , 1 7 - N O V - 0 0\ \ A V O G A D R O \ U S E R D A T A \ O r g a n i c \ s v o a \ s 3 . i \ 0 0 1 1 2 7 A . B \ s 3 _ c l p _ l o w . m2 9 - N O V - 2 0 0 0 11:05 m t l Quant T y p e : I S T D2 7 - N O V - 2 0 0 0 16:41 C a l F i l e : S 3 A 6 6 6 1 . D191.00000H P R T E Compound S u b l i s t : a l l . s u bT a r g e t V e r s i o n : 4.03Process ing H o s t : T A R G E T 7

Concentrat ion F o r m u l a : Amt * DF * Uf * V t / ( V o * Vi)Name V a l u e D e s c r i p t i o n

DFU fVtVOVi

1.0001.0001000.0001000.0001.000

Dilution Factorng unit correction f a c t o rVolume o f f i n a l extract ( u L )Volume o f s a m p l e ex trac ted ( m L )Volume i n j e c t e d ( u L )I S T D RT AREA A M O U N T

* 61 C h r y s e n e - d l 2* 68 P e r y l e n e - d l 2

2 8 . 0 9 231.175

40734494 0 0 6 6 6 8

20.00020.000

C O N C E N T R A T I O N SAREA O N - C O L ( n g ) F I N A L ( u g / L ) QUAL

Q U A N TL I B R A R Y L I B E N T R Y C P N D #

Hexacosane28.520 516367 2 . 5 3 5 2 8 1 5 3

CAS #: 630-01-39 5 N B S 7 5 K . L 73943 6 1 ( L )

Heneico sane29.155 546171 2.68161644

CAS #: 629-94-79 0 N B S 7 5 K . L 42201 6 1 ( M L )

041

000788

Data F i l e : S 3 A 6 6 7 2 . D .Report Date: 2 9 - N o v - 2 0 0 0 11:24

C O N C E N T R A T I O N S Q U A N TR T AREA O N - C O L ( n g ) F I N A L ! u g / L ) QUAL L I B R A R Y L I B E N T R Y C P N D #

Trico sane29.818 499170 2 .49169634

CAS #: £38-67-59 3 N B S 7 S K . L 73318 6 8 ( L )

Nonacosane30.571 420137 2 .09718899

CAS »: 630-03-594 N B S 7 5 K . L 54526 6 8 ( L )

QC F l a g LegendM - Compound response manually in t egra t ed .L - Operator s e l e c t ed an al ternate library search match.

042

000789

Data F i l e t \ S A V O G A D R O S U S E R D A T A \ O r g a n i c S s v o a \ s 3 . i \ 0 0 1 1 2 7 A . B \ S 3 A 6 6 7 2 . DDate : 28-NOV-2000 01:22C l i e n t I D : F 0 5 C 3 Ins trument: s3.iS a m p l e I n f o : 71881006 ,F05C3,S1117-BW4,CS,,F05C1V o l u m e I n j e c t e d C u t ) : 1.0 Operator: CSColumn phase: DB-5MS Column diameter; 0.25

62 b i s < 2 - E t h y l h e x y l > p h t h a l a t e Concentration: 2 u g / L

7.06.05.0

? 4.0* 3.0> 2.0

1.00.0

Scan 4499149-"

57\1

J l j l a j L . , J L L ,

(28.124 min) of S3A6672.D

>d67

207. / 2 4 ° /2"\ , / «381 .J I ^1

50 75 100 125 150 175 200 225 250 275 300 325' m/z

7.06.05.0

f 4.0y

< 3.0*• 2.0

1.0o.o.

Scan 4499 (28.124 m i n ) of S3A6672 .D ( S u b t r a c t e d )149-"

=\J[.Jli!^L., ..

Ion 1497.5-7.0{6.5-j6.0-j5 .5- j5 .0J4.5-j

^N i

1 "1^ 3.0-j*" 2 . 5 - j

2.0,;

1.5-!1.0-:0.5-:o.o-:-* —— ~~- — ~j

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lK-r_r - x -JL^r - - ri-27.8 28.0 28.2 28.4 28.6H i n

|| Ion 167.00II 99

1XL67

/ 2 4 ° >279

50 75 100 125 150 175 200 225 250 275 300 325m / z10.09.08.07.0

~ 6.0> 5.0: 4.0

> 3.02.01.00.0-

62 b i s ( 2 - E t h H l h e > $

*\1

|| 1 "N.ill ..jii..i.i,.i..L,i.. .JI..JJL, .... i... ...

y D p h t h a l a t e ( R e f e r e n c e S p e c t r u m )

/240/167

y279

50 75 100 125 150 175 200 225 250 275 300 325m / zScan 4499 (28.124 m i n ) o f S 3 A 6 6 7 2 . D ( X D I F F E R E N C E )100

80604020

0-20

z -40-60-80

-100

x93 yd.19,.r....r..-,... — _,....„_..„,. — . —— ............. — . —— .-.,„....-.. — .... . . .....1'

.50 75 100 125 150 175 200 225 250 275 300 325

1.8-j1.6;

? 1.2-^ * :^ 1 * ° i> 0.8-

0.6-:0.4;0.2-:0 ,,••„. .. . ., J kAjvA.^^ — *• -* '•*'

27.8 28.0 28.2 28.4 28.6H i n

043m/z 1

000790

Data F i l e t \ \ A V O C f t D R O S U S E R D f l T A S O r g a n i c S s v o a \ s 3 . i \ 0 0 1 1 2 7 A . B S S 3 A 6 6 7 2 . DDate : 28-NOV-2000 01:22C l i e n t ID: F05C3 Instrument: s3.iS a m p l e I n f o : 71881006 ,F05C3,S1117-BW4,CS,,F05C1V o l u m e I n j e c t e d ( u L ) : 1.0 Operator: CSC o l u m n phase; DB-5HS C o l u m n d iame t er; 0.25Library Search Compound Hatch

HexaoosaneH e p t a d e c a n e , 2,6,10,15-tetramethyl-Octadecane

COS Number Library Entry

630-01-3 N B S 7 5 K . L 7394354833-48-6 N B S 7 5 K . L 42196593-45-3 NBS75K.L 71559


95 C26H54 36693 C21H44 29693 C18H38 254

10.C8.0

nrHX\,

1 2.00.0

10.08.0

•>o 6.0X: 4.0\ 2.0

0.0-

10.08.0

> 6.0

~ 4.0<0

i 2.0.0.0

10.08.06.0

« 4.02.00.0

,

,

25

43\

... Jl. .,25

25

25

57*-

50

s.

50

J50

j

L J l l50

Scan 4573 (28.520 m i n ) o f S 3 A 6 6 7 2 . D ( S u b t r a c t e d ) (SCALED)

I f X 1 1 3|J 1 1 i /168211v ,239 /281324v 366v 416v /40BI I I J N . 1 . / \ / x v \ x / \ .L l l l l . . j J I , . J L . . J l . .,L ..L...O. ..ll.....i . * . . . . . . . . . . . . . . . . ' . ... . .. . . . >75 100 125 150 175 200 225 250 275 300 325 350 375 400 425 450 475m / ' z

Entry #73943, Hexacosane ( f r o m N B S 7 5 K . L ) ( S C A L E D )

1 /»' X*41 ^/183 ,225 /253 /295 366x^^/3681 .ll . . .II. .11 ...ll. . .|L . .J. .J. .J. .1. .1. -i. .... ..1. ..L .. .. .. ... .. .. . ...

75 100 125 150 175 200 225 250 275 300 325 350 375 400 425 450 475m / ' zEntry #42196, H e p t a d e c a n e , 2 ,6,10,15-te tramethyl- ( f r o m N B S 7 5 K . L ) ( S C A L E D )* 57

/*

75 100 125 150 175 200 225 250 275 300 325 350 375 400 425 450 475m / ' zEntry #71559, Octadecane ( f r o m N B S 7 5 K . L ) ( S C A L E D )"-•57

1 A*

J / X L 6 9 254v..Jl. -J .....jl _ il _ il ..t. .j. ... ... .. .. .. . 1

75 100 125 150 175 200 225 250 275 300 325 350 375 400 425 450 475m / z044

000791

Data F i l e : \ S A V u G A D R O S U S E R D A T A \ O r g a n i c S s v o a \ s 3 . i S 0 0 1 1 2 7 A . B N S 3 A 6 6 7 2 . DDate : 28-NOV-2000 01:22C l i e n t I D : F05C3 I n s t r u m e n t : s3.iS a m p l e I n f o : 71881006 ,F05C3,S1117-BW4,CS,,F05C1V o l u m e I n j e c t e d ( u L ) : 1.0 Operator: CSColumn phase: DB-5HS Column diameter: 0.25Library Search Compound H a t c h

Heneico saneH e p t a c o s a n eTetraco sane

CAS Number L i b r a r y Entry

629-94-7 N B S 7 5 K . L 42201593-49-7 N B S 7 5 K . L 74082646-31-1 NBS75K.L 73543


90 C21H44 29689 C 2 7 H 5 6 38087 C24H50 338

10.08.0

roo 6.0X

I 4.01 2.0

0.0

10.08.0

3S 6.0X

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I s±13I ,1 | X 1 5 5 207\ /2Zi 267v / 2 9 5 /323 380v x»05 /429«61

nil., i 1. . i l l Jl. ...il i..,h ii. J. . il . . i ... » ii in. i ...i.. .j. ... . .. .. .1... . . » . . i . .. ii75 100 125 150 175 200 225 250 275 300 325 350 375 400 425 450m / z

Entry #42201, Hene i c o sane ( f r o m N B S 7 5 K . L ) ( S C A L E D )

1

J 1 , X*27 A™ y!97 ,239 296v /298, 1 J u 1 i x / / \XL ..ill. ...1 L .. j l l . . J l . , l l . ..1. .Jl .1. .jl . .1. ..i. .. .. .. .. . L.75 100 125 150 175 200 225 250 275 300 325 350 375 400 425 450m/z

Entry #74082, H e p t a c o s a n e ( f r o m N B S 7 5 K . L ) ( S C A L E D )

X 6 5

; X 4 1 3 /*ss A 9 7 253\ y267 / 3 ° 9 380\ /382....1 -...Jill .-..•lL.....JIt.-..i.lL... ..«Jk...._jL.. ...J.. ._dl. ....... .«dl. .»._lk. ...*.... .«|L.. ..*.. »k. .*-• -fc. fm .b. .. _ .t.

75 100 125 150 175 200 225 250 275 300 325 350 375 400 425 450m/zEntry #73543, Tetraco sane ( f r o m N B S 7 5 K . L ) ( S C A L E D )

X 6 5

L X 1 2 7 y455 X 9 7 / 2 3 9 / 2 6 7 339v1 i i ,i j , ,r . ., r .. .. / , / .. . . >.75 100 125 150 175 200 225 250 275 300 325 350 375 400 425 450

043

000792

Data F i l e : S N A V O G A D R O N U S E R D A T A S O r g a n i c S s v o a N s S . i \ 0 0 1 1 2 7 A . B \ S 3 A 6 6 7 2 . DDate : 28-NOV-2000 01:22C l i e n t I D : F 0 5 C 3 I n s t r u m e n t : s3.iS a m p l e I n f o : 7 1 8 8 1 0 0 6 , F 0 5 C 3 , S 1 1 1 7 - B W 4 , C S , , F 0 5 C 1V o l u m e I n j e c t e d ( u L ) : 1.0 Operator: CSC o l u m n phase: DB-5MS C o l u m n diameter: 0.25Library Search Compound H a t c h

Tri co saneHenei co sane , l l - ( l - e t h y l p r o p y l ) -Nonadecane

CAS Number Library Entry

638-67-5 N B S 7 5 K . L 7331855282-11-6 NBS75K.L 51002629-92-5 NBS75K.L 71949


93 C23H4887 C26H5487 C19H40

324366268

10.08.0

r*>S 6.0

£ 2.00.0

10.08.0

MS 6.03

o.oJ

10.08.0

> 6.0TH

4.0ii 2.0.

0.0

10.0

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4(

J40

J40

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Scan 4816 (29.018 m i n ) of S 3 A 6 6 7 2 . D ( S u b t r a c t e d ) (SCALED)

/71

/" .I 155\ 183. A93 238v 267\ /281 327 337 3^5

i J. i il ,1 1 ' \ ^ ' \ / / \II. Jillll . ...Jill jllli.. ..III. . . . i l l i . .ill ...1. ...i. i .1.. it, . .. „. ...i. .. i,. ....i . ii. i... ii... . ..... .... ... . . .160 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380m / z

Entry #73318, T r i c o s a n e ( f r o m N B S 7 5 K . L ) ( S C A L E D )

/

1X 1 1 3 ^41 a.69 211 239 y267 324v y326

60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380m/TEntry #51002, H e n e i c o t a n e , l l - ( l - e t h y l p r o p y l ) - ( f r o m N B S 7 5 K . L ) ( S C A L E D )

71

J ,| . X 1 4 1 X 1 6 9 x197 / 2 2 5 /25 3 295\ 33?\.. __ || l .«. . . l l l l l l ....t,,|lL ____ .III. ____ .III. ___ ...1.1, ____ ml... ___ ,.!.. ...II.. .....1 __ ._,.. ...1 __ . ..... .™ __ .. I I . . ...

>0 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380m/zEntry #7191-9, Nonade cane ( f r o m N B S 7 5 K . L ) ( S C A L E D )

X 7 11 ^I X 1 2 7 /155 AS3 /210 268..Illi .In .id. .J. ,ii. ,i / ., ., .. : .. . ,.0 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380m / z

04 u

000793

Data F i l e : S \ A V O G A D R O M J S E R D A T A M J r g a n i c S s v o a \ s 3 . i \ 0 0 1 1 2 7 A . B \ S 3 A 6 6 7 2 . DDate : 28-NOV-2000 01:22C l i e n t I D : F 0 5 C 3 Ins t rumen t: s3.iS a m p l e I n f o : 7 1 8 8 1 0 0 6 , F 0 5 C 3 , S 1 1 1 7 - B W 4 , C S , , F 0 5 C 1V o l u m e I n j e c t e d ( u L ) : 1.0 Operator: CSC o l u m n phase: DB-5HS C o l u m n diameter: 0.25Library Search Compound H a t c h

NonacosaneEicosaneTricosane

CAS Number Library

630-03-5112-95-8638-67-5

N B S 7 5 K . LN B S 7 5 K . LN B S 7 5 K . L

Entry

545263986273318


94 C 2 9 H 6 0 40890 C 2 0 H 4 2 28290 C23H48 324

10.0

8.0nS 6.0

<D| 2.0

0.0

10.08.0

£ 6.0X~ 4.0-3 2.0

0.0 't10.0

8.0' 6.0HC

X 4*°!i 2.0.0.0

2

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8.0> 6.0

I

~ 4.02.00.0-

2

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5

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1

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.50

J50

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\50

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€

,,3

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75

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,15


y65

•1 . i / 455 210v x237 295v ./309 x355 409v y430 49Ov

|| iH M i l l l r i l . i i j l ,.,b i l . l li. il IIMI • ttt, l i l t • ill 1 U 1 .. • »• ill 1 i • i i ill • ii i . i i100 125 150 175 200 225 250 275 300 325 350 375 400 425 450 475m/z

Entry #54526, Nonacosane ( f r o m N B S 7 5 K . L ) ( S C A L E D )

/es

/"* /155 ^7 /225 /267 /309 /337 40^

100 125 150 175 200 225 250 275 300 325 350 375 400 425 450 475m/zEntry #39862, Eicosane ( f r o m N B S 7 5 K . L ) ( S C A L E D )

L

y113 141 .183 .,211 282\ 284. .Jl . ...ji... ..ll. .J. .1. ..jl ..A . L. . ..1. ..t. ..i. .. .. ..I.

100 125 150 175 200 225 250 275 300 325 350 375 400 425 450 475m/zEntry #73318, T r i c o s a n e ( f r o m N B S 7 5 K . L ) ( S C A L E D )

.AK/es

y127 y!69 x211 /253 324\ /326-JL iL .1 . .1. i ., .L . / „ . : . . _ r100 125 150 175 200 225 250 275 300 325 350 375 400 425 450 475m/z 04V

000794


F 0 5 C 4Lab Name: MITKEM CORPORATION Contract: 68-D6-0063L a b Code: M I T K E M Case N o . : 28724 S A S N o . : S D G N o . : F 0 5 C 1Lab S a m p l e ID: 71881001L a b F i l e I D : S 3 A 6 6 7 5S a m p l e Volume: 1000.00 (mL)Concentrated Extract Volume:I n j e c t i o n Volume: 1 (uL)

CAS NO. COMPOUND

Date Received: 1 1 / 1 7 / 0 0Date Extracted: 1 1 / 1 7 / 0 0Date Analyzed: 1 1 / 2 8 / 0 0

1 0 0 0 ( u L ) Dilution Factor: 1.0

C O N C E N T R A T I O N( u g / L )1 l " l f l _ Q c : _ O _ — .111-44-4 —— -95-57-8 — — — -95-48-7 — — — -108-60-1 —— -106-44-5- ——621-64-7 — — —/TT *7O TQ Q QC O•7 Q CO T/ o - b y - j - - - - -Q Q T K t ;oo— /D— 3— — — — —-i f\ cr £«7 Q111-91-1 — — —•t on Q I _ O _ _ _J.^U — O J~ £~ — — —qi _on_-3 _____y ± £*\j ^3106-47-8 — — —Q"7 CO 1 _59-50-7 — — — —Q1 K*7 C*t T A *T A77-47-4-----o Q n/r o95-95-4 — — — —Q1 CQ T88-74-4 — — — —131-11-3 — — —208-96-8 — — —Cf\C OO O99-09-2 — — —O*3 "3 O Q

-- — .-Phenol- —— bis ( - 2 - Chloroethyl ) Ether _____- — - 2 - Chlorophenol• - — - 2 -Methylphenol•- — -2,2' -oxybis (1-Chloropropane)- — -4 -Methylphenol— — N-Nitro so-d i-n-propylamine- — -HexachLoroethane- — - Isophorone— - -2 -Nitrophenol----2,4 -Dimethylphenol- — -bis ( - 2 -Chloroethoxy ) methane_- — -2,4 -Dichlorophenol— -Naphthalene— -4 -Chloroaniline— -Hexachlorobutadiene- — -4 -Chloro- 3 -Methylphenol—— 2 -Methylnaphthalene- - - -Hexachlorocyclopentadiene----2,4,6 -Tri chlorophenol- — -2,4,5 -Tri chlorophenol—— 2 -Chloronaphthalene- — -2 -Nitroanil ine- - - -Dimethylphthalate— -Acenaphthylene—— -2,6 -Dini t ro toluene- — 3 -Nitroanil ine

555555555555555555555205

20555205

UUUUUUUUUUUUUUUUUUUUUUUUUUUUU


000795


F 0 5 C 4Lab Name: MITKEM CORPORATION Contract: 68-D6-0063Lab Code: MITKEM Case N o . : 28724 SAS N o . : SDG No. : F 0 5 C 1Lab S a m p l e ID: 71881001L a b F i l e I D : S 3 A 6 6 7 5S a m p l e Volume: 1000.00 ( m L )Concentrated Extract Volume:I n j e c t i o n Volume: 1 ( u L )

1 0 0 0 ( u L )


CAS NO. COMPOUNDC O N C E N T R A T I O N( u g / L )

5 1 - 2 8 - 5 — — — —.-2,4-Dinitrophenol1 0 0 - 0 2 - 7 — — — — - 4 - N i t r o p h e n o l _ _ _ ~132-64-9- —— — --Dibenzofuran1 2 1 - 1 4 - 2 — — — — — 2 , 4 - D i n i t r o t o l u e n e _ _ _ _ _ _ _84-66-2 — — — — — — D i e t h y l p h t h a l a t e _ _ _ _ _ _ _ _ _ _7005-72-3--—---4-Chlorophenyl-phenyle ther_8 6 - 7 3 - 7 — — — — — - F l u o r e n e•4,6-Dinitro-2-methylphenol_•N-nitrosodiphenylamine ( 1 ) ~4 -Broirophenyl -phenylether__Hexachlorobenzene_________Pentachlorophenol_______

100-01-6- — — — — -4-Nitroamline5 3 4 - 5 2 - 1 — — — •86-30-6 — — — •101-55-3 ——— -1 1 8 - 7 4 - 1 — — — -87-86-5 — — — — -8 5 - 0 1 - 8 — — — - - - P h e n a n t h r e n e1 2 0 - 1 2 - 7 - — — — — A n t h r a c e n e84-74-2 ——— -206-44-0 — — — -1 2 9 - 0 0 - 0 — — — -8 5 - 6 8 - 7 — — — - _ __9 1 - 9 4 - 1 - - - - - - - - - 3 , 3 ' - D i c h l o r o b e n z i d i n e _5 6 - 5 5 - 3 — — — —2 1 8 - 0 1 - 9 — — — -

-Di-n-butylphthalate_- Fluoranthene_____~-Pyrene-Butylbenzylphthalate_-Benzo(a)anthracene-Chrysene_1 1 7 - 8 1 - 7 — — — — — b i s ( 2 -Ethylhexy l) ph tha la t e_1 1 7 - 8 4 - 0 — — — — — - D i - n - o c t y l p h t h a l a t e _ _ _ _ _ _ _ _ _ _2 0 5 - 9 9 - 2 — — — — - B e n z o ( b ) fluoranthene_________207-08-9- — — — — -Benzo(k)fluoranthene_____50-32-8------—-Benzo(a)pyrene1 9 3 - 3 9 - 5 — — — — — I n d e n o ( l > 2 / 3 - c d ) p y r e n e53-70-3 — — —— -Dibenzo (a, h) anthracene____191-24-2- — — — -Benzo(g,h,i)perylene_______

01 - Cannot be separated f rom Diphenylamine

2020

5552020

2055555555

UUUUUUUUUUUUUUUUUUUUU

FORM I L C S V - 2 .1

000796

1LCFL O W C O N C . W A T E R S E M I V O L A T I L E O R G A N I C S A N A L Y S I S D A T A S H E E TT E N T A T I V E L Y I D E N T I F I E D COMPOUNDSEPA S A M P L E NO.

F 0 5 C 4Lab Name: MITKEM CORPORATION Contract: 68-D6-0063L a b Code: M I T K E M ' Case N o . : 28724 S A S N o . : S D G N o . : F 0 5 C 1Lab S a m p l e ID: 71881001L a b F i l e I D : S 3 A 6 6 7 5S a m p l e Volume: 1000.00 (mL)Concentrated Extract Volume:I n j e c t i o n Volume: 1 ( u L )

1 0 0 0 ( u L )


Number T l C s f ound: 0CAS NUMBER1.2.3.4.5.6.7.8.9.10.

11.12.13.14.15.16.17.18.19.20.21.22.23.24.25.26.27.28.29.30.

COMPOUND NAME RT E S T . C O N C .( u g / L ) Q

FORM I L C S V - T I C OLC02.1

000797

Data F i l e : S S f l V O G A D R O M J S E R D f t T f t \ O r g a n i c S s v o a S s 3 . i \ 0 0 1 1 2 7 f l , B S S 3 A 6 6 7 5 . DDate : 28-NOV-2000 03:43C l i e n t I D : F 0 5 C 4S a m p l e I n f o : 71881001 ,F05C4,S1117-BU4,CS,,F05C1V o l u m e I n j e c t e d <uL>: 1.0Column phase: DB-5MS

Instrument: s3.iOperator: CSColumn diameter: 0.25

W W O C f l D R O \ U S E R D A T A \ O r g a n i c X s v o a S s 3 . i S 0 0 1 1 2 7 f l . B S S 3 A «3.9-:•J Q * •-* C3.8-: £ £• 7 7 - n j• 13 63.*B-j |3.4 |

3.2-; ?3.143.042.9-12.842.7-j2.6-j ?2.5-i g2. 44 ^ 52.3-: "** 22*3 i ? I\ t ' j i « ^ t

^ i!aJ -E> I-H C1«7- o fl

1.6J I f1.54 , g1.3-j ?1.2-! 7i.i41.0-j0.940.8-j

0.6-j0.5-10.440.340.2-j

o 1! iV

o

c

101c<E1

!I(C

7I11

675. DST J1

O

(VI7

1

a1"55.a.

>

i

_. 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38' - Min

000798

Data F i l e : S 3 A 6 6 7 5 . DReport Date: 2 9 - N o v - 2 0 0 0 11:24

Data f i l eLab Smp IdI n j DateOperatorS m p I n f oM i s c I n f oCommentMethodM e t h DateCal DateA l s b o t t l eDil F a c t o rI n t e g r a t o r

M i t k e m Corpora t i onC L P O L C 0 2 Q U A N T I T A T I O N REPORT\ \ A V O G A D R O \ U S E R D A T A \ O r g a n i c \ S V O a \ s 3 . i \ 0 0 1 1 2 7 A . B \ S 3 A 6 6 7 5 . D71881001 C l i e n t S m p I D : F 0 5 C 4 /

2 8 - N O V - 2 0 0 0 0 3 : 4 3 'C S Inst I D : S 3 . i7 1 8 8 1 0 0 1 , F 0 5 C 4 , S 1 1 1 7 - B W 4 , C S , , F 0 5 C 1f . .1. t , * . . , 1 7 - N O V - O O , 1 7 - N O V - O O\ \ A V O G A D R O \ U S E R D A T A \ O r g a n i c \ s v o a \ s 3 . i \ 0 0 1 1 2 7 A . B \ s 3 _ c l p _ l o w . m2 9 - N O V - 2 0 0 0 11:05 m t l Quant T y p e : I S T D2 7 - N O V - 2 0 0 0 16:41 C a l F i l e : S 3 A 6 6 6 1 . D221.00000H P R T E Compound S u b l i s t : a l l . s u bTarge t Version: 4.03Proce s s ing H o s t : T A R G E T 7

Concen tra t i on F o r m u l a : Amt * DF * Uf * V t / ( V o * Vi)Name V a l u e D e s c r i p t i o n

DFU fVtVoVi

1.0001.0001000.0001000.0001.000

Dilu t i on F a c t o rng unit correction f a c t o rVolume of f ina l extract (uL)Volume o f s a m p l e extracted ( m L )Volume i n j e c t e d ( u L )

CompoundsQ U A N T S I Q

M A S S

$ 1 2-Fluoropheno l$ 2 Pheno l-d s* 6 1,4-Dichlorobenzene-d4$ 12 Nitrobenzene-d5* 19 N a p h t h a l e n e - d S$ 28 2 - F l u o r o b i p h e n y l* 35 Acenaph thene-d lO$ 4 7 2 , 4 , 6 - T r i b r o m o p h e n o l* 51 Phenanthrene-dlO$ 57 T e r p h e n y l - d l 4* 61 Chrys ene-d l2* 68 P e r y l e n e - d l 2

HT EXP RT REL RT R E S P O N S E


( ng) ( ug/L)

11299

15282

136172164330188244240264

101213141518192122252331

.047

.398

.183

.385

.913

.178

.567

.201

.639

.940

.087

.175

101213141518192122252831

.052

.408

.183

.390

.912

.178

.577

.212.649.940.098.186

(0(0(1(0(1(0(1(0(1(0(1

. 7 6 2 )

. 9 4 0 )

. 0 0 0 )

. 9 0 4 )

. 000)

. 9 2 9 )

.000)

. 9 3 7 ). 0 0 0 ). 9 2 4 ).000)

( 1 . 0 0 0 )

652649900481364066813712

14399521557809

8412066 3 7 2 4 9

1334070196614212280921177497

141320282027204720322020

.2560

.8245

.0000

.7093

.0000

.3824

.0000

.1923

.0000

.0613

.0000

.0000

1414

29

27

47

32

052

000799

Data F i l e : S 3 A 6 6 7 5 . DReport Date: 29-Nov-2000 11:24

Data f i l eLab Smp idI n j DateOperatorS m p I n f oM i s c I n f oCommentM e t h o dM e t h DateCal DateA l s b o t t l eDil F a c t o rI n t e g r a t o r

M i t k e m Corpora t i onC L P OLC02 Q U A N T I T A T I O N REPORT\ \ A V O G A D R O \ U S E R D A T A \ O r g a n i c \ S V O a \ s 3 . i \ 0 0 1 1 2 7 A . B \ S 3 A 6 6 7 5 . D

71881001 C l i e n t S m p I D : F 0 5 C 42 8 - N O V - 2 0 0 0 03:43CS Ins t ID: s3.i7 1 8 8 1 0 0 1 , F 0 5 C 4 , S 1 1 1 7 - B W 4 f C S , , F 0 5 C 1, , , ! , , , , , , , 1 7 - N O V - 0 0 , 1 7 - N O V - 0 0\ \ A V O G A D R O \ U S E R D A T A \ O r g a n i c \ S V O a \ s 3 . i \ 0 0 1 1 2 7 A . B \ s 3 _ c l p _ l o w . m2 9 - N O V - 2 0 0 0 11:05 m t l Quant T y p e : I S T D2 7 - N O V - 2 0 0 0 16:41 C a l F i l e : S 3 A 6 6 6 1 . D221.00000H P R T E Compound S u b l i s t : a l l . s u bTarge t Version: 4.03Proce s s ing H o s t : T A R G E T 7

- N O T E N T A T I V E L Y I D E N T I F I E D C O M P O U N D S -

053

000800


F 0 5 C 5Lab Name: MITKEM CORPORATION Contract: 68-D6-0063Lab Code: MITKEM Case N o . : 28724 SAS N o . : SDG No. : F 0 5 C 1Lab S a m p l e ID: 71881002L a b F i l e I D : S 3 A 6 6 7 0S a m p l e Volume: 1000.00 (inL)Concentrated Extract Volume:I n j e c t i o n Volume: 1 ( u L )

1000 (uL)


CAS NO. COMPOUNDC O N C E N T R A T I O N

( u g / L )

1 0 8 - 9 5 - 2 — — — — — — P h e n o l _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _1 1 1 - 4 4 - 4 — — — — - - b i s (-2-Chloroe thvl) Ether9 5 - 5 7 - 8 — — — — — — 2 - C h l o r o p h e n o l _ _ _ _ _ _ _ _ _ _9 5 - 4 8 - 7 — — — — — — 2 - M e t h y l p h e n o l _ _ _ _ _ _ _ _ _108-60-1- — — — — - 2 , 2 ' -oxybis (1-Chloropropane)1 0 6 - 4 4 - 5 — — — — — — 4 -Methylphenol_______^6 2 1 - 6 4 - 7 — — — — — N - N i t roso -di - n-propylamine67-72-1— — — - - -Hexachloroethane________98-95-3 — — — — ---Nitrobenzene___________78-59-1— —— — -Isophorone____________8 8 - 7 5 - 5 — — — — — — 2 - N i t r o p h e n o l _ _ _ _ _ _ _ _ _ _ _1 0 5 - 6 7 - 9 — — — — — 2 , 4 - D i m e t h y l p h e n o l _ _ _ _ _ _1 1 1 - 9 1 - 1 — — — — — b i s (-2-Chloroe thoxy) methane_1 2 0 - 8 3 - 2 - — — — - 2 , 4 - D i c h l o r o p h e n o l _ _ _ _ _ _91-20-3-- — — — — -Naphthalene__________1 0 6 - 4 7 - 8 - — — — — 4 - C h l o r o a n i l i n e87-68-3 — — — — -Hexachlorobutadiene5 9 - 5 0 - 7 — — — — — — 4 - C h l o r o - 3 - M e t h y l p h e n o l _ _ _9 1 - 5 7 - 6 — — — — — — 2 - M e t h v l n a p h t h a l e n e7 7 - 4 7 - 4 — — — — — — H e x a c h l o r o c y c l o p e n t a d i e n e88-06-2---------2,4,6-Trichlorophenol____9 5 - 9 5 - 4 — - - — — -2,4,5-Trichlorophenol____9 1 - 5 8 - 7 — — — — — — 2 - C h l o r o n a p h t h a l e n e _ _ _ _ _8 8 - 7 4 - 4 — — — — — — — 2 -Nitroaniline__________131-11-3 — — — — — D i m e t h y l p h t h a l a t e _ _ _ _ _ _ _ _ _2 0 8 - 9 6 - 8 — — — — — A c e n a p h t h y l e n e _ _ _ _ _ _ _ _ _ _ _ _ _ _606-20-2- — — — -2,6-Dinitrotoluene_________99-09-2— — — -—3-Nitroaniline____________8 3 - 3 2 - 9 — — — — — A c e n a p h t h e n e _ _ _ _ _ _ _ _ _ _ _ _ _ _

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FORM I L C S V - 1 O L C 0 2 . 1054

000801


F 0 5 C 5Lab Name: MITKEM CORPORATION Contract: 68-D6-0063L a b Code: M I T K E M Case N O . : 28724 S A S N o . : S D G N o . : F 0 5 C 1Lab S a m p l e ID: 71881002L a b F i l e I D : S 3 A 6 6 7 0S a m p l e Volume: 1000.00 (mL)Concentrated Extract Volume:I n j e c t i o n Volume: 1 ( u L )

1000 (uL)


CAS NO. COMPOUND C O N C E N T R A T I O N( u g / L )5 1 - 2 8 - 5 — — — — — — 2 , 4 - D i n i t r o p h e n o l _100-02-7- — --- - -4 -Nitrophenol__~1 3 2 - 6 4 - 9 — — - - - - D i b e n z o f u r a n1 2 1 - 1 4 - 2 — — — — —84-66-2 — — — — — — • _________7005-72-3 — -- — -4-Chlorophenyl-phenylether_86-73-7— — -- — -Fluorene

-2,4 -Dinitrotoluene_-Die thylphthala t e_

1 0 0 - 0 1 - 6 — — — — 4 - N i t r o a n i l i n e5 3 4 - 5 2 - 1 — — — —8 6 - 3 0 - 6 — — — — —1 0 1 - 5 5 - 3 — — — —

-Di -n-butylphthalate_- Fluoranthene_____~-Pyrene_

-----4,6-Dinitro-2-methylphenol- - — -N-nitrosodiphenylamine (1)-----4-Bromophenyl-phenylether_118-74-1- — -- — -Hexachlorobenzene______87-86-5-- —— ---Pentachlorophenol______85-01-8 — -------Phenanthrene__________120-12-7-—-----Anthracene8 4 - 7 4 - 2 — — — —206-44-0 — — — •129-00-0 — — — •8 5 - 6 8 - 7 — — — — -9 1 - 9 4 - 1 — — — — -56-55-3 — — — — -2 1 8 - 0 1 - 9 — — — -1 1 7 - 8 1 - 7 — — — -1 1 7 - 8 4 - 0 — — — -2 0 5 - 9 9 - 2 — — — -2 0 7 - 0 8 - 9 — — — -50-32-8 — — — — -1 9 3 - 3 9 - 5 — — — -53-70-3 — — — — -1 9 1 - 2 4 - 2 — — — -

-Butylbenzylphthalate- 3 , 3 ' - D i c h l o r o b e n z i d i n e _-Benzo (a) anthracene___~-Chryseneb i s ( 2 - E t h y l h e x y l ) p h t n a l a t e-Di - n- oc tylphthalate_________-Benzo (b) f luoranthene________-Benzo(k)fluoranthene______-Benzo(a)pyrene- I n d e n o ( 1 , 2 , 3 - c d ) p y r e n e _-Dibenzo (a, h) anthracene-Benzo (g, h, i) perylene_(1) - Cannot be separated from Diphenylamine

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FORM I L C S V - 2

000802

roy f. weston; i nc, · 5599 san felipe, suite 700 houston, tx 77056 march 2001 000697. november...

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