(roman)zemente: struktur- und phasenanalyse aus dem

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Dave Hughes University of Bradford, UK Formulating mortars for use in restoration practice Natural cements in European cultural heritage Les ciments naturels dans le patrimoine européen PARIS – 26/27-04-2012

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Page 1: (Roman)zemente: Struktur- und Phasenanalyse aus dem

Dave Hughes

University of Bradford, UK

Formulating mortars for use in restoration practice

Natural cements in European cultural heritage Les ciments naturels dans le patrimoine européen

PARIS – 26/27-04-2012

Page 2: (Roman)zemente: Struktur- und Phasenanalyse aus dem

Details may be found on Posters

Presentation is an Overview

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Materials

Cements

Vicat Prompt

MBM Gartenau - ROCARE

W&P Wietersdorf – ROCARE

Sand

Carbonate 0 – 4 mm

Mortars

Cast elements & renders

Page 4: (Roman)zemente: Struktur- und Phasenanalyse aus dem

Mortar specifications

Cast mortars – Proportions: 0.5 and 1:1 by volume Flow: 19.5 cm Workable life: 15 – 30 minutes Retarder: Citric acid

Citric acid w/c

(1:0.5) (1:1)

Prompt 0.5% 0.46 0.55

Gartenau 1.0% 0.5 0.57

Wietersdorf 0.4% 0.47 0.54

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Cast Mortar (1:0.5) - strength

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Cast Mortar (1:0.5) – Shrinkage

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Cast Mortar – Water Absorption (kg/m2/hr0.5)

4 week cure 26 week cure

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Cast Mortar – Vapour Permeability (kg/m2/Pa/s * 10-9)

4 week cure 26 week cure

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Mortar specifications

Render mortars – Proportions: 1:1.5 and 1:2.5 by vol Flow: 15.5 cm Workable life: 1 – 2 hours Retarder: Citric acid (Prompt) Deactivation process

(ROCARE cements)

Page 10: (Roman)zemente: Struktur- und Phasenanalyse aus dem

Deactivation Process (DARC)

Stage 1 • Mix sand with a small amount of water for

2 minutes (deactivation water) • Add cement and mix for 2 minutes • Store for short period of time Stage 2 • Mix mortar for longer than cast mortars

Page 11: (Roman)zemente: Struktur- und Phasenanalyse aus dem

Mortar specifications

Retarder w/c

(1:1.5) (1:2.5)

Prompt 1.5% CA* 0.42 0.59

Gartenau DARC** 0.5 0.57

Wietersdorf DARC 0.56 0.76

* May be considered excessive ** Requires twice the deactivation water as Wietersdorf cement

Page 12: (Roman)zemente: Struktur- und Phasenanalyse aus dem

Render Mortar (1:2.5) - strength

Page 13: (Roman)zemente: Struktur- und Phasenanalyse aus dem

Render Mortar – Water Absorption (kg/m2/hr0.5)

NHL 5 @ 4 w

22 – 25

NHL 5

@ 26 w

11 - 12

4 week cure 26 week cure

Page 14: (Roman)zemente: Struktur- und Phasenanalyse aus dem

Render Mortar – Vapour Permeability (kg/m2/Pa/s * 10-9)

4 week cure 26 week cure

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Render Mortar (1:2.5) – Shrinkage

Page 16: (Roman)zemente: Struktur- und Phasenanalyse aus dem

Hybrid mortars – 1:1.5

50% Gartenau – 50% NHL5* / CL90 33% Gartenau – 67% NHL5* / CL90 * Otterbein NHL5

Pure Gartenau DARC Gartenau

Page 17: (Roman)zemente: Struktur- und Phasenanalyse aus dem

Hybrid mortars – w/b ratio workable life

50% NHL 5 67% NHL5 50% CL90 67% CL90

w/b

DARC Gartenau 0.75 0.79 0.81 0.85

Pure Gartenau 0.99 0.97 1.07 1.07

Workable Life

DARC Gartenau ~95 min ~105 min ~100 min ~110 min

Pure Gartenau ~270 min ~200 min ~220 min ~170 min

Original DARC ~60 min

Page 18: (Roman)zemente: Struktur- und Phasenanalyse aus dem

Hybrid mortars – strength & WAC

50% lime

67% lime 50% lime

67% lime

50% lime

67% lime

50% lime

67% lime

Page 19: (Roman)zemente: Struktur- und Phasenanalyse aus dem

Conclusions

• Different cements require different retardation techniques for render mortars • Not all cements may facilitate rapid demoulding of cast elements • DARC render mortars have low early age strength • Hybrid mortars permit further control of strength and water transmission • Carbonate sands may yield high shrinkage for

some grading profiles

Page 20: (Roman)zemente: Struktur- und Phasenanalyse aus dem

If you have any questions contact me at [email protected]

For additional information see

Poster Exhibition and

www.rocare.eu

Page 21: (Roman)zemente: Struktur- und Phasenanalyse aus dem

Influence of sand - grading

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Influence of sand – rheology (const w/c)

020406080

100120140160

1 2 3 4

Shea

r Str

engt

h

Sand

Mortar Shear Strength

Silica

Carbonate

0

5

10

15

20

25

30

1 2 3 4

Shea

r Str

engt

h

Sand

Paste Shear Strength

Silica

Carbonate

0

0,05

0,1

0,15

0,2

0,25

1 2 3 4

Visc

osity

Sand

Mortar Viscosity

Silica

Carbonate

0

0,02

0,04

0,06

0,08

0,1

0,12

0,14

1 2 3 4

Visc

osity

Sand

Paste Viscosity

Silica

Carbonate

~14 µm ~23 µm ~24 µm ~47 µm

Page 23: (Roman)zemente: Struktur- und Phasenanalyse aus dem

Influence of sand – Shrinkage

Page 24: (Roman)zemente: Struktur- und Phasenanalyse aus dem

Influence of sand – Shrinkage

Page 25: (Roman)zemente: Struktur- und Phasenanalyse aus dem

Influence of sand – Shrinkage

Page 26: (Roman)zemente: Struktur- und Phasenanalyse aus dem

Conclusions

• Different cements require different retardation techniques for render mortars • Not all cements may facilitate rapid demoulding of cast elements • DARC render mortars have low early age strength • Carbonate sands may yield high shrinkage for some grading profiles • Hybrid mortars permit further control of strength and water transmission

Page 27: (Roman)zemente: Struktur- und Phasenanalyse aus dem

If you have any questions contact me at [email protected]

For additional information see

Poster Exhibition and

www.rocare.eu