research journal of chemistry and...
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Research Journal of
Chemistry and Environment
Vol. 22 (Special Issue II), August 2018
E-ISSN: 2278 - 4527 ! PRINT-ISSN No. 0972 - 0626
Journal is indexed in SCOPUS andChemical Abstracts
ii
GOD IS.
E-ISSN: 2278 – 4527 PRINT-ISSN No. 0972-0626
RESEARCH JOURNAL OF CHEMISTRY AND ENVIRONMENT
An International Research Journal of Chemical Sciences and Environmental Sciences
Res. J. Chem. Environ., Volume 22(Special Issue II), Pages 1-350, August (2018)
Editor- in- Chief (Hon.)
Dr. D.K. Vardhan Mumbai, INDIA
Correspondence Address:
Research Journal of Chemistry and Environment
Sector AG/80, Scheme No. 54, Indore 452 010 (M.P.) INDIA
Phone and Fax: +91-731-4004000
Website: https://worldresearchersassociations.com
E-mail: [email protected]
CONTENTS
Research Papers:
1. Biosynthesis of Silver Nanoparticles using Jicama Extract and Its Application for Colorimetric
Sensing of Mercury Ions
- Firdaus M. Lutfi, Megarani Juwita, Purawiardi R. Ibrahim, Eddy Diana Rakhmawaty and Rahayu Iman
1-3
2. Synthesis and Structural Analysis of Aurivillius Phase, Ca1-xBi3+xNdTi4-xMnxO15
- Zulhadjri, Bilian Sahiga J.I., Wendari Tio Putra and Emriadi
4-9
3. Digital-Based Image Detection System in Simple Silver Nanoparticles-based Cyanide Assays
- Tambaru David, Nomi Anastasia Grandivoriana and Nitti Fidelis
10-14
4. Preparation of Mixed Matrix Polymeric Membrane for removing of contaminants in Crude Biodiesel
- Saiful, Ramli Muliadi, Maulana Ilham, Fadli and Yusuf M.
15-21
5. A new zinc (II) responsive MRI contrast agent
- Adhitiyawarman and Mark P. Lowe
22-30
6. Synthesis of Benzyl-Protected Robtein (2,3,4,4,5-Pentahydroxychalcone) as an Intermediate to (–)-
Robidanol
- Suharti, Achmadi Suminar S., Irfana Luthfan, Sugita Purwantiningsih, Wukirsari Tuti, Ilmiawati Auliya
and Arifin Budi
31-38
7. Antibacterial and antioxidant activities of pyrogallol and synthetic pyrogallol dimer
- Cynthia, Ignatia Florence, Sutanto Hery and Darmawan Akhmad
39-47
8. Preparation and Characterization of Titania/Bentonite Composite Application on the Degradation of
Naphthol Blue Black Dye
- Lubis Surya, Sheilatina, Putra Vicky Praja and Nika Syahrinta Sepia
48-53
9. Optimization of Light Exposure on Superoxide Scavenger Test of Manganese (III)-Salen Acetate
Complex - Nurrahmajanti Asiyah, Onggo Djulia and Deawati Yusi
54-57
10. Application of Molecularly Imprinted Polymer Technique on Chitosan Membranes for Increasing
Creatinine Transport Effectiveness
- Eka Sulistyaningsih
58-64
11. Total Phenolic and Flavonoid Contents and Antimicrobial activity of Acorus calamus L. Rhizome
Ethanol Extract
- Rita Wiwik Susanah, Kawuri Retno and Swantara I. Made Dira
65-70
iii
12. Optimization of process parameters for inulinase production from endophytic fungi Fusarium solani
LBKURCC67, Humicola fuscoatra LBKURCC68 and Fusarium oxysporum LBKURCC69
- Devi Silvera, Illiyin Luthfin, Ardhi Aulia, Pratiwi Nova Wahyu and Saryono
71-78
13. Morphological identification and hydrolytic enzyme-producing abilities of fungi associated with
wilting banana plants (Musa sp.)
- Saryono, Piska Finna, Sari Nurmala, Pratiwi Nova Wahyu and Ardhi Aulia
79-86
14. 20-Epibryonolic Acid from Tetrameles nudiflora Leaves
- Darmawan Akhmad, Fajriah Sofa, Megawati and Lotulung Puspa Dewi N.
87-90
15. Synthesis of fluorescent compound, 7-Hydroxy-4-methyl-2H-chroman-2-one via Pechmann
condensation of citric acid and resorcinol
- Al Anshori Jamaludin, Rahayu Diah Siti, Hidayat Ace Tatang, Hidayat Ika Wiani and Zainuddin Achmad
91-96
16. Distinguishing of Oligosaccharide Linkage Isomers by Nanoparticle-assisted Fragmentation in
MALDI-TOF MS
- Primadona Indah, Dedi, Wang Yi-Sheng and Chen Yu-Ju
97-101
17. Recombinant Anti BNP-SCFV Production in Escherichia coli and its Application for the Detection of
Heart Failure by Electrochemical Immunosensor using Screen-Printed Carbon Electrode-Gold
Nanoparticles (SPCE-GNP)
- Gaffar Shabarni, Hartati Yeni Wahyuni, Susanti Rini and Subroto Toto
102-107
18. Chemical Compositions of Banana Peels (Musa sapientum) Fruits cultivated in Malaysia using
proximate analysis
- Hassan Pyar and Peh K.K.
108-113
19. Isolation and Identification of Quercetin Derivatives and their -Glucosidase Inhibitory Acitivities
from Bryophyllum pinnatum
- Fajriah Sofa, Darmawan Akhmad, Megawati Megawati and Hanafi Muhammad
114-119
20. Influence of synthesis time on Lanthanum Silicate Apatite (La9.33Si6O26) properties
- Noviyanti Atiek Rostika, Juliandri, Agustina Shofia Utari and Malik Yoga Trianzar
120-123
21. A comparison of the fermentation performance and stress tolerance of baker’s yeast cells grown in
media with or without magnesium addition
- Rachman Saadah D., Hidayat Risma W., Safari Agus and Ishmayana Safri
124-128
22. Investigating Aluminasilicate Source in Geopolymer Compressive Strength: Surface Morphology and
Crystal Phase Study
- Anggarini Ufafa and Sukmana Ndaru Candra
129-133
23.
Optimization Density of Geopolymer Concrete based on Taguchi Method
- Sukmana Ndaru Candra, Pambudi Andry Agung and Anggarini Ufafa
134-138
24. Synthesis of 5-(4’-Chlorobenzylidene) hydantoin and N-3 Substituted 5-(4’-Chlorobenzylidene)-3-
Methylhydantoin
- Naufal Muhammad, Hamdani Ulfi Dadan, Maharani Rani, Al Anshori Jamaludin and Hidayat Ika Wiani
139-145
25. In vitro antioxidant activity of Sonneratia ovata Backer extract
- Khumaidah Laili, Nurmalasari Fatati, Putri Fatmawati Inneke, Purnomo Adi Setyo, Santoso Mardi,
Ersam Taslim and Fatmawati Sri
146-150
26. Effects of bacterium Ralstonia pickettii addition on DDT biodegradation by Daedalea dickinsii
- Purnomo Adi Setyo, Rizqi Hamdan Dwi, Fatmawati Sri, Putro Herdayanto Sulistyo and Kamei Ichiro
151-156
iv
27. The effect of Calcination Temperature of Sulfated Zirconia Catalyst for Simultaneous Reactions in
Biodiesel Production
- Andrijanto Eko and Brown Rob
157-162
28. Synthesis of Zirconia 1-D Nanomaterials from Local Zircon-Based Zr(OH)4 mediated by PEG-6000
- Septawendar Rifki, Nuruddin Ahmad, Maryani Eneng, Sutardi Suhanda and Purwasasmita Bambang
Sunendar
163-171
29. Effects of the Precipitation pH of Sodium Silicate on the Amorphous Silica Characteristics and its
capability in the Pb and Cd Adsorption
- Maryani Eneng, Septawendar Rifki and Suhanda
172-178
30. Critical Parameters of Silver Nanoparticles (AgNPs) synthesized by Sodium Borohydride Reduction
- Sholikhah Umi Nur, Pujiyanto Anung, Lestari Enny, Sarmini Endang, Lubis Hotman, Widyaningrum
Triani and Febriana Siska
179-183
31. Antibacterial Activity of Prenylated Xanthones from Pericarp of Garcinia mangostana against
Persistent Dental Infection Microorganism Enterococcus faecalis
- Setiawan Arlette Suzy, Herawati Mieke, Dewi Warta and Supratman Unang
184-188
32. Identification of a DNA Polymerase I Gene Fragment from a Local Isolate (PLS 80) from an
Underwater Hot Spring
- Febriani, Helwati H., Velayati M.A. and Iqbalsyah T.M.
189-192
33. Biohydrogen Production through Separate Hydrolysis and Fermentation and Simultaneous
Saccharification and Fermentation of Empty Fruit Bunch of Palm Oil
- Kusmardini Diah, Prasetyo Joni, Saepudin Endang and Hudiyono Sumi
193-197
34. Study Cytotoxicity of Haarlem Oil by Crystal Violet Staining Assay
- Khairan Khairan, Jamier Vincent and Jacob Claus
198-202
35. Determination of Optimum Pressure for Gd3+ Separation from Gd-DTPA with Nanofiltration
Membrane
- Rahayu Iman, Winanti Anti, Juliandri, Noviyanti Atiek Rostika, Eddy Diana Rakhmawaty, Anggraeni Anni
and Bahti Husein H.
203-205
36. Cytotoxic Effects of Cassava (Manihot esculenta Crantz), Adira-2, Karikil and Sao Pedro Petro
Varieties against P-388 Murine Leukemia Cells
- Widiastuti Diana, Mulyati Ade Heri, Eka Herlina, Siti Warnasih, Suchyadi Yudhie, Triastinurmiatiningsih
and Supratman Unang
206-208
37. Coating of Nanotube Ti-6Al-4V Alloy with Hydroxyapatite-Chitosan Composite by Electrophoretic
Deposition Method
- Charlena, Suparto Irma Herawati and Puspitawati Tuti
209-213
38. pH Effect of Gold Nanoparticles Synthesis Encapsulation in Polyamide Amine Generation 3.0
(AuNP-PAMAM G3.0)
- Pujiyanto Anung, Lestari Enny, Kurniasih Dede, Mujinah, Sholikhah Umi Nur, Gunawan Adang Hardi,
Amalia Sarah S. and Mutalib Abdul
214-219
39. Mode of action of an insecticidal oleanane glycoside on digestive enzymes of Crocidolomia pavonana
- Maharani Rani, Rizqiani Anggun Fuji, Ishmayana Safri, Hidayat Yusup and Dono Danar
220-225
40. Comparative assessment of yeast fermentation performance, ethanol tolerance and membrane fluidity
- Ishmayana Safri, Kennedy Ursula J. and Learmonth Robert P.
226-235
v
41. Preparation of ZnO/SiO2 Composite using Silica isolated from Rice Husk
- Eddy Diana Rakhmawaty, Ishmayana Safri, Noviyanti Atiek Rostika and Wahyuni Astri
236-239
42. Separation of Radioisotope Iodine-131 from Radiotellurium-131 using Dowex-1x8 resin column
chromatography
- Setiawan Duyeh, Nugraha Nabil Aulia and Hastiawan Iwan
240-244
43. Prelimimary Study of using Palm Oil Mill Effluent to produce Bio Hydrogen as Biofuel
- Prasetyo Joni, Febijanto Irhan, Murti S.D. Sumbogo and Dewi Eniya L.
245-248
44. Analysis and Characterization of Complex Compound Gadolinium-(1,4,7,10-Tetraazacyclododecane,
1-4-7-10-Tetraacetic Acid)n-Poliamidoamine Generation 3-Trastuzumab as a Novel Contrast Agent
for Magnetic Resonance Imaging
- Kusuma Yenni Nugraha Wira, Mutalib Abdul, Anggraeni Anni, Ramli Martalena, Fauzia Retna Putri and
Bahti Husein H.
249-254
45. Comparison of Different Methods for Purification of Gold Nanoparticles– Polyamidoamine
(PAMAM) Generation 4 Dendrimer
- Narsa Angga Cipta, Pujiyanto Anung, Gunawan Adang H., Yusup Iyus Maolana, Listyowati Indrarini,
Fauzia Retna Putri, Bratadiredja Marline Abdassah, Mutalib Abdul, Soetikno Ristaniah D. and
Soedjanaatmadja R. Ukun M.S.
255-259
46. Utilization of Sericin on Modification of Cotton Dyeing using Acid Dyes
- Ramadhani Puri Awaliyah and Umam Khairul
260-266
47. Toxicity of Seed oil of Azadirachta indica, Calophyllum inophyllum and their Mixture against
Crocidolomia pavonana Larvae
- Kadarusman Ratna Puji Astuti, Widayani Neneng S., Dono Danar, Hidayat Yusup, Sunarto Toto,
Hartati Sri and Maharani Rani
267-273
48. Addition of mango essence to methyl eugenol more attracted to Bactrocera dorsalis Complex
(Diptera: Tephritidae) on mango plantation in Majalengka, West Java
- Susanto Agus, Djaya Luciana and Sudrajat Rian Aprianti
274-279
49. Solubility Improvement of Antimalaria Drug through Co-Crystalization with Malic Acid
- Gozali Dolih, Alatas Fikri and Sugandi Rani
280-284
50.
Simple method and environmentally friendly ash content removal process from rice husk char using
potassium carbonate solution
- Solihudin, Rustaman and Haryono
285-288
51. Polymer Electrolyte Membrane Fuel Cell based on Sulfonated Polystyrene and Phosphoric Acid with
Biocellulose as a Matrix
- Fadlinatin Naumi, Christi L. Natanael, Iman Rahayu, Lucia Indrarti and Sunit Hendrana
289-293
52. A Voltammetric Immunosensor for Detection of HER2 using Gold Modified-Screen Printed Carbon
Electrode
- Hartati Yeni Wahyuni, Beladona Siti U. Misonia, Wyantuti Santhy and Gaffar Shabarni
294-301
53. Fast and Simultaneous Detection of Sm, Eu, Gd, Tb and Dy using combination of Voltammetry
Method and Multivariate Analysis
- Wyantuti Santhy, Pratomo Uji, Hartati Yeni Wahyuni, Anggraeni Anni and Bahti Husein H.
302-306
54. Vannamei Shrimp (Litopenaeus vannamei, Boone, 1931) Performance with Bacillus and Lactobacillus
Probiotic Formulation Consortium in Dry Preparation
- Andriani Yuli, Safitri Ratu and Fauziah Shaiyanne
307-312
vi
55. The Implementation of Natural Pigments of Pumpkin Meal to enhance the Color Quality of Koi Fish
(Cyprinus carpio)
- Yustiati Ayi, Arisya Yuni, Herawati Titin, Rachman Boedi and Andriani Yuli
313-318
56. Novel Mechanical Filter for reducing Ammonia Concentration of Silver Barb culture in a
Recirculating Aquaculture System (RAS)
- Hasan Zahidah, Rajibbusalam, Maulina Ine and Andriani Yuli
319-324
57. The Reduction of Lead in Fish Meat from Floating Net Cages in Cirata Reservoir by Citric Acid
- Junianto, Hasan Zahidah and Afrianto Eddy
325-329
58. Cytotoxic Sesquiterpenoid from the Stembark of Aglaia argentea (Meliaceae)
- Harneti Desi, Farabi Kindi, Nurlelasari, Maharani Rani, Supratman Unang and Shiono Yoshihito
330-333
59. Cellulose isolation from Gracilaria Genus and its Potential as Bioethanol Raw Material
- Satiyarti Rina Budi, Febrishaummy Indriani, Yun Yenny Febriyani and Mulyani Rahmaniar
334-336
60. Sn (IV) doped lanthanum silicate apatite structure (La9.33Si6-xSnxO26; x: 0.1; 0.3; 0.5) as an electrolyte
- Noviyanti Atiek Rostika, Eddy Diana Rakhmawaty, Hastiawan Iwan, Dzulfikar Muhammad
and Syarif Dani Gustaman
337-341
61. Determination of Individual Spectra of Sm, Eu, Gd, Tb and Dy from the UV-Vis Spectrum of
Mixture Solution
- Anggraeni Anni, Avian Mohamad Sepril, Purnama Andrew and Mutalib Abdul
342-346
62. Secondary Metabolites from Steambarks of Dysoxylum alliaceum
- Mayanti Tri, Nurcahyanti Ois, Darwati, Julaeha Euis, Farabi Kindi, Sumiarsa Dadan
and Dinata Deden Indra
347-350
Research Journal of Chemistry and Environment________________________________________Special Issue August (2018) Res. J. Chem. Environ.
184
Antibacterial Activity of Prenylated Xanthones from Pericarp of Garcinia mangostana against Persistent
Dental Infection Microorganism Enterococcus faecalis Setiawan Arlette Suzy1, Herawati Mieke1, Dewi Warta1 and Supratman Unang2*
1. Faculty of Dentristry, Universitas Padjadjaran, Jatinangor 45363, Sumedang, INDONESIA 2. Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Padjadjaran, Jatinangor 45363, Sumedang, INDONESIA
*[email protected] Abstract As a part of ongoing research on antibacterial agents from botanical dietary supplements, Garcinia mangostana L. (commonly known as manggis in Indonesia) was selected for a detailed study. The dried and milled pericarp of G. mangostana was extracted by maceration with MeOH (3 × 5 L) at room temperature for 3 days. After filtration and evaporation of the solvent under reduced pressure, the combined crude methanolic extract (250 g) was suspended in H2O (600 mL) to produce an aqueous solution, then partitioned in turn with n-hexane (3 × 500 mL), EtOAc (3 × 500 mL) and n-BuOH (3 × 500 mL) to afford dried n-hexane (32 g), EtOAc (40 g) and n-BuOH (60 g) extracts. The EtOAc-soluble extract was found to have a significant antibacterial activity against Enterococcus faecalis ATCC 29212. Therefore, the EtOAc extract was selected for detailed purification. Repeated chromatography on silica gel of a EtOAc-soluble extract of pericarp led to isolation of four prenylated xanthones. The chemical structures of compounds 1-4 were identified as a-mangostin, b-mangostin, g-mangostin and garcinone-D on the basis of spectroscopic data and comparison to those related data previously reported. The antibacterial activities of these compounds were evaluated against E. faecalis performed using broth micro dilution method. Among all compounds, compound 3 (g-mangostin) exhibit the most potent since it has a high inhibition diameter value in low concentration (10.93 d/mm in 100 mg/L). Keywords: Garcinia mangostana, mangostin, antibacterial activity, Enterococcus faecalis. Introduction A successful pulp treatment depends on the technique and the status of radicular and coronal pulp tissues as well as on the type of medications used. In addition, infection control is an important factor that cannot be separated from successful primary dental pulp treatment.1 Reducing or eliminating microorganism infection is the most important
factor for this success through chemomechanic instrumentation process that can reduce most of the bacteria. However, microorganism retention in the dentin tubule usually causes permanent infection.2
The complexity of pulp chamber anatomy, as well as the microorganisms’ ability to survive during starvation, leads to a situation where the microorganisms remain in the pulp chamber and root canal despite appropriate mechanical instrumentation and irrigation procedures.3
Therefore, pulp medications should be able to eliminate the residual microorganisms, neutralize the microorganism toxic products and prevent recurrent infection. The microorganism that is often isolated in the case of failed pulp treatment is Enterococcus faecalis anaerob facultative positive gram coccus. Although it is isolated in a small number in the primary tooth, this pathogen is able to proliferate in the root canal; therefore, it should be eliminated to recover and restore the tooth’s normal function.4 Pharmacological tests have shown that materials from nature are a source for potential bioactive compounds that may act as antibacterial agent. This antibacterial characteristic has led to a search for bioactive compounds that can be used as a primary tooth disinfection material especially against E. faecalis.5
Garcinia mangostana Linn. (mangosteen) belongs to Guttiferae family that has been used as in traditional medicine such as to cure skin infections, diarrhea, and chronic wound.6 Mangosteen rind has been reported to contain a secondary metabolite that has a broad antibacterial biological activity including against Enterococcus.7 Phytochemical study showed that the active component comes from the xanthone derivative group. Xanthone is a secondary metabolite that can be found in high-plants including mangosteen. Several studies show that xanthone extracted from mangosteen presents biological activities such as antioxidant, antitumor, anti-inflammation, antiallergic, antibacterial, antifungal, and antiviral activities.8
Although xanthone is already known as having a broad-spectrum of antibacterial activity, its use against E. faecalis has not been widely tested. The purpose of this study was to evaluate anti-bacterial activity of xanthone derivative compounds of mangosteen (G. mangostana) peel extract against E. faecalis.