remedial excavation, verification soil sampling and
TRANSCRIPT
515 LEGGET DRIVE, SUITE 200, KANATA, ONTARIO K2K 3G4 PHONE: (613) 592-3387 FAX: (613) 592-5897 ENVIRONMENTAL HEALTH & SAFETY MANAGEMENT SERVICES FROM OFFICES ACROSS CANADA
www.pinchin.com
Remedial Excavation, Verification Soil Sampling and Injection Program
Herongate Mall, 1670 Heron Road Ottawa, Ontario
Prepared for:
TransGlobe Property Management Services 5925 Airport Road, Suite 700
Mississauga, ON L4V 1W1
Attention: Mr. Daniel Drimmer
March 30, 2011
Pinchin File: 47880.002
Copyright © 2010 by Pinchin Environmental Ltd.
Remedial Excavation and Verification Soil Sampling Program Herongate Mall – 1670 Heron Road, Ottawa, Ontario March 30, 2011 TransGlobe Property Management Services Pinchin File: 47880.002
© 2010 Pinchin Environmental Ltd. Page i
EXECUTIVE SUMMARY
Pinchin Environmental Ltd. (“Pinchin”) was retained through an Authorization to Proceed signed by Mr. Daniel Drimmer of TransGlobe Property Management Services (the “Client”) to supervise a remedial excavation of suspect soils which underlie a current dry cleaning facility and perform a verification soil sampling program at the property referred to as the Herongate Mall located at 1670 Heron Road, Ottawa, Ontario (hereafter referred to as the “Site”). In order to address impacted groundwater, Pinchin was also authorized to complete the installation of an injection gallery and subsequent injections of an oxidizing solution to mitigate any residually impacted groundwater.
The Site is developed with one single-storey multi-tenant commercial building (the “Site Building”), situated in an area of predominant residential and commercial land use. Potable water is supplied to the Site through City of Ottawa municipal services which utilizes the Ottawa River as the potable water source.
The objective of the remedial excavation was to excavate the soils located beneath the dry cleaning equipment which were suspected of being a source of volatile organic compound (“VOC”) impacts which would exceed applicable Ontario Ministry of the Environment “(MOE”) clean-up standards. Removal of the potentially impacted subsurface materials would effectively eliminate any source for future contamination to the groundwater which underlies the Site and verify that the Site is in compliance with applicable MOE assessment standards.
The following is a summary of activities and results of this comprehensive remedial program conducted at the Site:
1. From September 28 through October 15, 2010, Pinchin field personnel were on-Site to supervise the excavation activities completed by Ontario Specialty Contracting (“OSC”). A mini-track driven excavator operated by OSC was used to remove the surficial concrete material and all accessible overburden soils;
2. Data collected during the excavation operations indicated that the subsurface material at the Site generally consisted of concrete underlain by a sand gravel fill material, successively underlain by native brown silt clay over bedrock, which was observed at a minimum depth of 5.5 meters below ground surface (“mbgs”);
3. Pinchin field personnel completed a field screening and segregation program using visual, olfactory and organic vapour measurements recorded using a photo-ionization detector (“PID”). The final limits of the excavation were extended until little or no visual or olfactory evidence of environmental impacts were observed.
4. The non-impacted soil was segregated from the impacted soil as a result of the field screening program and stockpiled on Site for reuse as fill material. The excavation area extended to a maximum depth of 4.5 mbgs and terminated upon encountering a shale/bedrock material. Approximately 100 metric tonnes of impacted soil was removed
Remedial Excavation and Verification Soil Sampling Program Herongate Mall – 1670 Heron Road, Ottawa, Ontario March 30, 2011 TransGlobe Property Management Services Pinchin File: 47880.002
© 2010 Pinchin Environmental Ltd. Page ii
from the excavation and stockpiled on-Site for subsequent disposal at a certified waste handling facility, pending the results of the laboratory analysis;
5. To facilitate soil disposal, a “worst case” soil sample (labelled TCLP) was collected from the excavation area and submitted for chemical analysis of metal, benzene and total petroleum hydrocarbons using a Toxicity Characteristic Leaching Procedure (“TCLP”) in accordance with Ontario Regulation 558/00, in order to classify the soil for landfill disposal. The results of the laboratory TCLP analysis indicated that the soils would be classified as a non-hazardous solid waste;
6. Based on the Site specific conditions, the soil quality at the Site was assessed using the Table 3 (non-potable groundwater conditions) Standards for commercial/industrial/institutional land use and coarse grained soils. The standards referenced above are outlined in the “Soil, Groundwater and Sediment Standards for Use Under Part XV.1 of the Environmental Protection Act”, MOE, March 9, 2004;
7. The most apparent “worst case” soil samples based on vapour concentrations as well as visual and/or olfactory considerations were recovered from the limits of the excavation and submitted for laboratory chemical analysis. Based on the size of the excavation which had a measured floor area of approximately 28 square metres, three floor samples (FL-5, FL-6 and FL-8) and six wall samples (EW-3, WW-2, SW-4, NW-4, WW-8 and EW-7) were submitted for laboratory analysis.
8. All verification soil samples were collected and submitted to Paracel Laboratories (“Paracel”) located in Ottawa, Ontario in accordance with the Ontario Ministry of the Environment’s (“MOE”) Guidance on Sampling and Analytical Methods for Use at Contaminated Sites in Ontario (1996) and submitted for laboratory analysis of VOC parameters
9. The results of the soil chemical analysis indicated that all of the verification soil samples collected at the Site reported concentrations of all target parameters which satisfied the applicable criteria specified in the applicable Table 3 (non-potable groundwater condition) Standards;
10. In order to address any residual impacted groundwater remaining in the vicinity of the excavation area, two injection galleries were installed on the base of the excavation area, following the collection of the verification soil samples. The injection galleries systems consisted of a 7 meter perforated pipe placed horizontally within the base of the excavation, connected with 90 degree elbows at the ends to solid pipe which was extended vertically to the concrete surface. The horizontal perforated pipe was situated within a bed of clear stone with an approximate thickness of one metre;
11. Following the collection of all verification soil samples from the excavations, all non-impacted material which was stockpiled on-Site was reinstated within the excavations and compacted. Approximately 80 metric tonnes of Granular B, 8.1 metric tonnes of Granular A and 2.4 metric tonnes of clear stone material was imported to the Site and compacted within the excavations in order to restore the excavation areas to the original grade levels. Once the backfill material had been placed and compacted to the appropriate geotechnical standards, the concrete floor slab was reinstated;
Remedial Excavation and Verification Soil Sampling Program Herongate Mall – 1670 Heron Road, Ottawa, Ontario March 30, 2011 TransGlobe Property Management Services Pinchin File: 47880.002
© 2010 Pinchin Environmental Ltd. Page iii
12. Upon completion of the reinstatement of the excavation area, Pinchin retained Strata Soil Sampling Inc. to advance one borehole (MW10-1) on October 14, 2010. The borehole was advanced using a Geoprobe 6620 DT direct push drill rig within the central portion of the dry cleaning facility in the immediate vicinity of the dry cleaning equipment. The borehole was advanced to a maximum depth of 4.5 mbgs and terminated upon encountering the underlying shale/bedrock interface. The borehole was instrumented with a monitoring well to enable groundwater monitoring and sampling. The monitoring well MW10-1, which replaced monitoring wells MW05-1 and MW07-1 that had been decommissioned as part of the remedial excavation process, was installed within the dry cleaning facility in order evaluate the environmental condition of the groundwater subsequent to the remedial activities;
13. On October 14, 2010, Pinchin field personnel completed an initial injection program under Certificate of Authorization provided by the MOE. A total of 520 kilograms of sodium permanganate was mixed with 400 litres of clean water and injected into the galleries using a passive gravity injection approach (approx 182 Kg / 140 L was placed into gallery IW10-1A and 338 Kg / 260 L was placed into gallery IW10-2A);
14. In order to determine the effectiveness of the initial injection program, Pinchin returned to the Site on November 19, 2010 to collect groundwater samples from monitoring well MW10-1 (located within the dry cleaning facility) as well as the existing monitoring wells MW05-2 and MW07-2 (which are located immediately adjacent to the dry cleaning facility in the dollarama lunch room). The samples were submitted to Paracel for chemical analysis of VOC parameters;
15. The results of the groundwater sampling program indicated that the groundwater sample collected from the dry cleaning (MW10-1) facility reported concentrations of all VOC parameters which satisfied the Table 3 (non-potable groundwater condition) Standards. However, the groundwater samples collected from the dollarama (MW05-2 and MW07-2) reported concentrations of tetrachloroethylene (“PCE”) at 6.8 ug/L and 6.1 ug/L respectively which marginally exceeded the Table 3 (non-potable groundwater condition) Standard of 5.0 ug/L;
16. As such, Pinchin field personnel returned to the Site on December 13, 2010, to complete a supplemental injection program in order to address the marginal PCE exceedances. A total of 50 kilograms of sodium permanganate was mixed with 200 litres of clean water and injected into the galleries using a passive gravity injection approach (approx 50 L of solution was placed into each of galleries IW10-1A and IW10-2A as well as monitoring well MW05-2 and MW07-2);
Remedial Excavation and Verification Soil Sampling Program Herongate Mall – 1670 Heron Road, Ottawa, Ontario March 30, 2011 TransGlobe Property Management Services Pinchin File: 47880.002
© 2010 Pinchin Environmental Ltd. Page iv
17. Pinchin field personnel returned to the Site on February 23, 2011 to collect verification groundwater samples from the monitoring wells which had previously shown exceedances of the applicable standards (MW05-2 and MW07-2). It should be noted that at the time of this sampling event, the groundwater sample collected from MW07-2 still showed signs of oxidant in solution (ie, deep purple in color) and as such, a sample from MW07-2 was not submitted for chemical analysis due to potential interference of the oxidant with the lab instrumentation. The results of the lab analysis indicated that the sample collected from MW05-2 reported concentrations of all target parameters which satisfied the Table 3 (non-potable groundwater condition) Standard; and,
18. Subsequently, Pinchin field personnel returned to the Site on March 24, 2011 to collect a verification groundwater sample from only remaining monitoring well which had previously shown exceedances of the applicable standards (MW07-2). The results of the lab analysis indicated that the sample collected from MW07-2 reported concentrations of all target parameters which satisfied the Table 3 (non-potable groundwater condition)
Standard;
Based on the results of the Remedial Excavation and Verification Soil Sampling Program completed at the Site, including the results of the laboratory analysis, the soils from the area of the Site included as part of this program are deemed to be in compliance with the applicable Table 3 (non-potable groundwater condition) Standards for industrial/commercial/institutional land use and coarse grained soil. In addition, it was reported that the dry cleaning operation has recently switched to environmentally friendly dry cleaning solutions, therefore the potential for the adverse environmental effects to the Site due to the on-going Site operations is not expected. As such, given that the source of the contamination has been eliminated and the potential for recontamination is minimal, no further work is warranted with respect to the soils which underlie the dry cleaning facility.
In terms of the potential for residually impacted groundwater, it should be noted that the concentrations of PCE detected within the groundwater samples collected from within the dry cleaning have decreased from 38 ug/L to 4.6 ug/L and concentrations within the adjacent tenant space have decreased from 6.1 ug/L to 2.3 ug/L as a result of the soil excavation and injection programs. This data infers that the remedial activities completed at the Site have been successful in achieving their remedial objectives of bringing the dry cleaning facility and adjacent tenant space into compliance with the Table 3 (non-potable groundwater condition) Standards.
This Executive Summary is subject to the same standard limitations as contained in the report and must be read in conjunction with the entire report.
Remedial Excavation and Verification Soil Sampling Program Herongate Mall – 1670 Heron Road, Ottawa, Ontario March 30, 2011 TransGlobe Property Management Services Pinchin File: 47880.002
© 2010 Pinchin Environmental Ltd. Page v
TABLE OF CONTENTS
1.0 INTRODUCTION..............................................................................................................1 1.1 Site Description ......................................................................................................1
2.0 BACKGROUND ................................................................................................................1 2.1 Scope of Work ........................................................................................................1
3.0 METHODOLOGY ............................................................................................................2 3.1 Excavation Activities .............................................................................................2 3.2 Field Screening Samples ........................................................................................2 3.3 Verification Soil Sampling ....................................................................................3 3.4 QA/QC Protocols ...................................................................................................3 3.5 Applicable Regulatory Standards ........................................................................4
4.0 VERIFICATION SOIL SAMPLING RESULTS ...........................................................5 4.1 Site Geology ............................................................................................................5 4.2 Analytical Results...................................................................................................5
4.2.1 Contaminated Soil Disposal Analysis ..........................................................5 4.2.2 Verification Soil Sample Analysis ...............................................................6
4.3 Earthwork Volumes ...............................................................................................6 4.4 Groundwater Monitoring Well Reinstatement ...................................................6
5.0 IN-SITU CHEMICAL OXIDATION PROGRAM ........................................................7 5.1 Initial Injection Event ............................................................................................7 5.2 Post-Injection Groundwater Sampling Program ................................................7 5.3 Supplemental Injection Program .........................................................................8
6.0 CONCLUSIONS ................................................................................................................9
7.0 RECOMMENDATIONS .................................................................................................12
8.0 DISCLAIMER..................................................................................................................12
9.0 SIGNATURE PAGE ........................................................................................................14
APPENDICES
Appendix I – Figures
Appendix II – Summary Tables
Appendix III – Site Photographs
Appendix IV – Laboratory Certificate of Analysis
FIGURES
Figure 1 – Key Map
Figure 2 – Generalized Site and Verification Soil Sample Location Plan
Figure 3 – Verification Soil Sampling Location Plan
Remedial Excavation and Verification Soil Sampling Program Herongate Mall – 1670 Heron Road, Ottawa, Ontario March 30, 2011 TransGlobe Property Management Services Pinchin File: 47880.002
© 2010 Pinchin Environmental Ltd. Page vi
TABLES
Table 1 – Laboratory Analysis for Toxicity Characteristic Leaching Procedure Parameters in Soil
Table 2 – Laboratory Analysis for VOC Parameters in Verification Soil Samples
Table 3 – Laboratory Analysis for VOC Parameters in Verification Groundwater Sample
Remedial Excavation and Verification Soil Sampling Program Herongate Mall – 1670 Heron Road, Ottawa, Ontario March 30, 2011 TransGlobe Property Management Services Pinchin File: 47880.002
© 2010 Pinchin Environmental Ltd. Page 1
1.0 INTRODUCTION
Pinchin Environmental Ltd. (“Pinchin”) was retained through an Authorization to Proceed signed by Mr. Daniel Drimmer of TransGlobe Property Management Services (the “Client”) to supervise a remedial excavation of suspect soils which underlie a current dry cleaning facility and perform a verification soil sampling program at the property referred to as the Herongate Mall located at 1670 Heron Road, Ottawa, Ontario (hereafter referred to as the “Site”). In order to address impacted groundwater, Pinchin was also authorized to complete the installation of an injection gallery and subsequent injection of an oxidizing solution to mitigate any residually impacted groundwater.
1.1 Site Description
The Site is developed with one single-storey multi-tenant commercial building (the “Site Building”), situated in an area of predominant residential and commercial land use. Potable water is supplied to the Site through City of Ottawa municipal services which utilizes the Ottawa River as the potable water source.
As indicated on Figure 1, located in Appendix I, the Site is located on at the intersection of Walkley Road and Heron Road, in Ottawa, Ontario. The Site is situated in an area that predominantly consists of commercial and residential land uses.
2.0 BACKGROUND
The objective of the remedial excavation was to excavate the soils located beneath the dry cleaning equipment which were suspected of being a source of volatile organic compound (“VOC”) impacts which would exceed applicable Ontario Ministry of the Environment “(MOE”) clean-up standards. Removal of the potentially impacted subsurface materials would effectively eliminate any source for future contamination to the groundwater which underlies the Site and verify that the Site is in compliance with applicable MOE assessment standards.
Based on information provided by the Client, it is Pinchin’s understanding that the Client is in the process of completing due diligence at the Site with respect to the potential divestiture of the Site.
2.1 Scope of Work
The scope of work proposed by Pinchin, outlined in the proposal dated October 20, 2010, submitted to the Client included the removal of the concrete floor slab, excavation of all subsurface materials, verification soil sample collection and field interpretation, laboratory analysis, data analysis and report preparation.
Remedial Excavation and Verification Soil Sampling Program Herongate Mall – 1670 Heron Road, Ottawa, Ontario March 30, 2011 TransGlobe Property Management Services Pinchin File: 47880.002
© 2010 Pinchin Environmental Ltd. Page 2
3.0 METHODOLOGY
3.1 Excavation Activities
From September 28 through October 15, 2010, Pinchin field personnel were on-Site to supervise the excavation activities completed by Ontario Specialty Contracting (“OSC”). A mini-track driven excavator operated by OSC was used to remove the surficial concrete material and all accessible overburden soils.
Data collected during the excavation operations indicated that the subsurface material at the Site generally consisted of concrete underlain by a sand gravel fill material, successively underlain by native brown silt clay over bedrock, which was observed at a minimum depth of 4.0 meters below ground surface (“mbgs”).
Pinchin field personnel completed a field screening and segregation program using visual, olfactory and organic vapour measurements recorded using a photo-ionization detector (“PID”). The final limits of the excavation were extended until little or no visual or olfactory evidence of environmental impacts were observed.
The non-impacted soil was segregated from the impacted soil as a result of the field screening program and stockpiled on Site for reuse as fill material. The excavation area extended to a maximum depth of 4.0 mbgs and terminated upon encountering a shale/bedrock material. Approximately 100 metric tonnes of impacted soil was removed from the excavation and stockpiled on-Site for subsequent disposal at a certified waste handling facility, pending the results of the laboratory analysis
To facilitate soil disposal, a “worst case” soil sample (labelled TCLP) was collected from the excavation area and submitted for chemical analysis of metal, benzene and total petroleum hydrocarbons using a Toxicity Characteristic Leaching Procedure (“TCLP”) in accordance with Ontario Regulation 558/00, in order to classify the soil for landfill disposal. The results of the laboratory TCLP analysis indicated that the soils would be classified as a non-hazardous solid waste. Photographs of the excavation activities are located in Appendix III.
3.2 Field Screening Samples
Field screening was employed to assess the extent of the potential impacts and aid in segregating suspected impacted material from non-impacted material. Screening samples were placed in Ziploc bags and allowed to equilibrate to ambient temperature. The samples were then screened for total organic vapour (“TOV”) concentrations using the PID, which was calibrated to a known isobutylene standard.
The excavation extended to a maximum depth of approximately 4.0 metres below ground surface (“mbgs”) and terminated without encountering competent bedrock. At a minimum, the soil samples used for field screening were collected at the following intervals:
Remedial Excavation and Verification Soil Sampling Program Herongate Mall – 1670 Heron Road, Ottawa, Ontario March 30, 2011 TransGlobe Property Management Services Pinchin File: 47880.002
© 2010 Pinchin Environmental Ltd. Page 3
The floors were divided into a 5 square metre grid pattern; and
Soil samples were collected from each grid unit for field screening of organic vapour concentrations and observations (i.e., location, depth, soil type, grain size, colour and odour).
The limits of the excavation were expanded both vertically and laterally until the results of the field screening program indicated that concentrations of target parameters would satisfy the applicable criteria. The final limits of the excavation are depicted in Figure 2 and a cross section of the remedial excavation is depicted in Figure 3, located in Appendix I.
3.3 Verification Soil Sampling
Once the final limits of the excavation had been established, Pinchin field personnel collected verification soil samples from the excavation area in order to identify remaining soil contaminant levels, if any. The frequency of verification soil samples submitted for laboratory analysis were conducted in accordance with the Ontario Ministry of the Environment’s (“MOE”) Guidance on Sampling and Analytical Methods for Use at Contaminated Sites in Ontario (1996).
The most apparent “worst case” soil samples based on vapour concentrations as well as visual and/or olfactory considerations were recovered from the limits of the excavation and submitted for laboratory chemical analysis. Based on the size of the excavation which had a measured floor area of approximately 28 square metres, three floor samples (FL-5, FL-6 and FL-8) and six wall samples (EW-3, WW-2, SW-4, NW-4, WW-8 and EW-7) were submitted for laboratory analysis.
All verification soil samples were submitted to Paracel Laboratories located in Ottawa, Ontario, an independent and CALA accredited laboratory for chemical analysis of VOC parameters. Approximate locations of verification soil samples collected from the floor of the excavation are depicted in Figure 2 and Figure 3 located in Appendix I.
3.4 QA/QC Protocols
Quality assurance/quality control (QA/QC) protocols were followed during excavation activities and verification soil sampling to ensure that representative samples were obtained. Field protocols that were employed included:
extraction of soil samples from the interior of the sampling device (where possible), rather than from areas in contact with the sampler walls to minimize the chance of cross-contamination;
soil samples collected were placed in laboratory-supplied glass sample jars;
refrigeration of all samples immediately upon collection and maintained en route to the laboratory;
Remedial Excavation and Verification Soil Sampling Program Herongate Mall – 1670 Heron Road, Ottawa, Ontario March 30, 2011 TransGlobe Property Management Services Pinchin File: 47880.002
© 2010 Pinchin Environmental Ltd. Page 4
use of nitrile gloves for all sample handling; and
sample collection and handling procedures were performed in accordance with the document “Guidance on Sampling and Analytical Methods for Use at Contaminated Sites in Ontario,” MOE, 1996.
3.5 Applicable Regulatory Standards
The generic soil and groundwater criteria previously provided in the MOE Guideline have been replaced by the Soil, Groundwater and Sediment Standards for Use Under Part XV.1 of the Environmental Protection Act (March 9, 2004). For the most part the numerical standards are identical to their predecessor generic criteria, the only difference being the incorporation of the Canada Wide Standards (“CWS”) for PHCs. The current MOE Standards provide advice and information to property owners and consultants to use when assessing the environmental condition of a property, when determining whether or not restoration is required, and in determining the kind of restoration needed to allow continued use or re-use of the Site. The regulation provides three approaches, which may be used for site restoration. These include:
Background Approach: the restoration of the site to the naturally occurring background concentrations;
Generic Approach: the restoration of the site to generically derived soil and groundwater criteria which are protective of human health and of the natural environment; and
Risk Assessment Approach (RA): the restoration of the site to soil and groundwater criteria derived for a specific site, which are protective of human health and of the natural environment but may be less stringent than the generic criteria.
The generic approach involves the application of soil and groundwater quality criteria, which have been developed to provide protection against potential adverse effects to human health, ecological health, and the natural environment. The guideline provides four sets of generic criteria for 118 parameters, including volatile organic compounds and petroleum hydrocarbons. These criteria have been developed using a risk-based approach. The application of the appropriate criteria is dependent upon several site-specific conditions including:
the existing/proposed land use;
the existing/potential groundwater use;
soil depth; and
soil texture.
In many instances, despite the final restoration approach adopted, the generic criteria developed by the MOE serve as the necessary benchmarks for evaluating the need for additional investigations and/or the implementation of a risk management or remedial strategy at the Site.
Remedial Excavation and Verification Soil Sampling Program Herongate Mall – 1670 Heron Road, Ottawa, Ontario March 30, 2011 TransGlobe Property Management Services Pinchin File: 47880.002
© 2010 Pinchin Environmental Ltd. Page 5
The Site is a commercial property located in Ottawa, Ontario. It is Pinchin’s understanding that potable water for the Site and surrounding area is supplied by City of Ottawa municipal services which utilizes the Ottawa River as the water source. The Site is situated in an area that predominantly consists of residential and commercial land uses. Representative soil sample were submitted for grain size distribution and pH analysis, and were reported as coarse grained and having a pH within the applicable range for the use of the generic approach.
Based on the Site specific information presented above, the soil quality at the Site was assessed using Table 3 (non-potable groundwater conditions) Standards for industrial/commercial/institutional land use and coarse grained soils. The standards referenced above are outlined in the “Soil, Groundwater and Sediment Standards for Use Under Part XV.1 of the Environmental Protection Act”, MOE, March 9, 2004.
4.0 VERIFICATION SOIL SAMPLING RESULTS
4.1 Site Geology
Data collected during the excavation operation indicated that the subsurface material at the Site generally consisted of concrete underlain by a sandy gravel fill material, successively underlain by native brown silt clay over bedrock. The excavation extended to a maximum depth of 4.0 mbgs and terminated without encountering bedrock. The excavation extended until no visual or olfactory evidence of environmental impacts were observed.
4.2 Analytical Results
4.2.1 Contaminated Soil Disposal Analysis
One “worst case” soil sample was collected from the stockpiled soil (labelled ‘TCLP’), and submitted to the laboratory for chemical analysis of leachable metal, benzene and total petroleum hydrocarbon parameters using a Toxicity Characteristic Leaching Procedure (“TCLP”) in accordance with Ontario Regulation 558/00, in order to classify the soil for landfill disposal.
The results of the laboratory analysis of the “worst case” soil sample which was submitted for chemical analysis of leachable metals and leachable VOC parameters using a TCLP, is summarized in Table 1, and can be found in Appendix II. The laboratory certificates of analyses are provided in Appendix III.
The results of the TCLP analyses indicated that the impacted soil removed from the Site was classified as non-hazardous solid waste.
Remedial Excavation and Verification Soil Sampling Program Herongate Mall – 1670 Heron Road, Ottawa, Ontario March 30, 2011 TransGlobe Property Management Services Pinchin File: 47880.002
© 2010 Pinchin Environmental Ltd. Page 6
4.2.2 Verification Soil Sample Analysis
The results of the laboratory analysis completed on the verification soil samples submitted for chemical analysis of VOC parameters along with their applicable standards are summarized in Table 2, and can be found in Appendix II. The laboratory certificates of analysis are located in Appendix IV.
The results of the laboratory analysis indicated that the verification soil samples submitted for chemical analysis reported concentrations of all targeted parameters which satisfied applicable criteria specified in the Table 3 (non-potable groundwater conditions) Standards.
4.3 Earthwork Volumes
The non-impacted soil was segregated from the impacted soil as a result of the field screening program and stockpiled on Site for reuse as fill material. Approximately 100 metric tonnes of impacted soil was segregated from the excavation and held on-Site for subsequent disposal at an approved landfill and certified waste handling facility.
Following the collection of all verification soil samples from the excavations, all non-impacted material which was stockpiled on-Site was reinstated within the excavations and compacted. Approximately 80 metric tonnes of Granular B, 8.1 metric tonnes of Granular A and 2.4 metric tonnes of clear stone material was imported to the Site and compacted within the excavations in order to restore the excavation areas to the original grade levels.
4.4 Groundwater Monitoring Well Reinstatement
Upon completion of the reinstatement of the excavation area, Pinchin retained Strata Soil Sampling Inc. to advance one borehole (MW10-1) on October 14, 2010. The borehole was advanced using a Geoprobe 6620 DT direct push drill rig within the central portion of the dry cleaning facility in the immediate vicinity of the dry cleaning equipment. The borehole was advanced to a maximum depth of 4.5 mbgs and terminated upon encountering the underlying shale/bedrock interface. The borehole was instrumented with a monitoring well to enable groundwater monitoring and sampling. The monitoring well MW10-1, which replaced monitoring wells MW05-1 and MW07-1 that had been decommissioned as part of the remedial excavation process, was installed within the dry cleaning facility in order evaluate the environmental condition of the groundwater subsequent to the remedial activities.
The Screen was sealed using threaded caps and the riser was sealed with a lockable J-plug cap. Silica sand was placed around and above the screened interval to form a filter pack around the well screen. A layer of bentonite was placed above the silica sand and was extended to the ground surface. A protective flush-mount cover was installed over the riser pipe at the ground surface and cemented in place. The location of the monitoring well is shown on Figure 2 of Appendix I.
Remedial Excavation and Verification Soil Sampling Program Herongate Mall – 1670 Heron Road, Ottawa, Ontario March 30, 2011 TransGlobe Property Management Services Pinchin File: 47880.002
© 2010 Pinchin Environmental Ltd. Page 7
5.0 IN-SITU CHEMICAL OXIDATION PROGRAM
In order to address any residual impacted groundwater remaining in the vicinity of the excavation area, two injection galleries were installed on the base of the excavation area, following the collection of the verification soil samples. The injection gallery system consisted of a 7 meter length of perforated pipe placed horizontally within the base of the excavation, connected with 90 degree elbows at the ends to solid pipe which was extended vertically to the concrete surface. The horizontal perforated pipe was situated within a bed of clear stone with an approximate thickness of one metre.
Briefly, sodium permanganate crystals were dissolved in water and injected under passive gravity influence into the contaminated aquifer. Sodium permanganate is a relatively inexpensive product and the one most commonly used for remediation work of this nature. At some sites PCE has been reduced more than 97% in less than 10 days. It has been Pinchin’s experience that for many contaminated properties, potassium permanganate is the preferred technology for the remediation of dry cleaning sites. Permanganate chemically oxidizes PCE, TCE, DCE and VC to produce carbon dioxide, manganese oxide and potassium, chloride and hydrogen ions (all of which are non-harmful constituents). Permanganate solutions are purple and this colour can be used to track the distribution of the oxidant. When the permanganate reacts with the contaminants of concern (i.e., PCE in this case) the manganese oxide that forms is a dark brown colour.
5.1 Initial Injection Event
On October 14, 2010, Pinchin field personnel returned to the Site with OSC to complete an initial injection program under Certificate of Authorization provided by the MOE. A total of 520 kilograms of sodium permanganate was mixed with 400 litres of clean water and injected into the galleries using a passive gravity injection approach (approx 182 Kg / 140 L was placed into gallery IW10-1A and 338 Kg / 260 L was placed into gallery IW10-2A).
5.2 Post-Injection Groundwater Sampling Program
In order to determine the effectiveness of the initial injection program, Pinchin returned to the Site on November 19, 2010 to collect groundwater samples from monitoring well MW10-1 (located within the dry cleaning facility) as well as the existing monitoring wells MW05-2 and MW07-2 (which are located immediately adjacent to the dry cleaning facility in the dollarama lunch room). The groundwater samples were submitted to Paracel for chemical analysis of VOC parameters.
The results of the groundwater sampling program indicated that the groundwater sample collected from the dry cleaning facility (MW10-1) reported concentrations of all VOC parameters which satisfied the Table 3 (non-potable groundwater condition) Standards. The groundwater samples collected from the dollarama (MW05-2 and MW07-2) displayed
Remedial Excavation and Verification Soil Sampling Program Herongate Mall – 1670 Heron Road, Ottawa, Ontario March 30, 2011 TransGlobe Property Management Services Pinchin File: 47880.002
© 2010 Pinchin Environmental Ltd. Page 8
decreasing concentration trends for tetrachloroethylene (“PCE”) at 6.8 ug/L and 6.1 ug/L respectively which marginally exceeded the Table 3 (non-potable groundwater condition) Standard of 5.0 ug/L.
The results of the laboratory analysis completed on the post-remediation groundwater verification samples that were submitted for chemical analysis of VOC parameters along with their applicable standards are summarized in Table 3, and can be found in Appendix II. The laboratory certificates of analysis are located in Appendix IV.
Pinchin has included analytical data from groundwater sampling events completed prior and subsequent to this remedial program for comparison purposes. It should be noted that overall, the groundwater samples collected subsequent to the remedial program including the initial injection event, have demonstrated a significant reduction in VOC parameters (specifically PCE) when compared to the data collected prior to the remediation program. This infers that the remedial excavation and oxidation injection program were successful in reaching their remedial objectives for the dry cleaning facility.
5.3 Supplemental Injection Program
In order to address the low level impacted groundwater detected in MW05-2 and MW07-2, Pinchin field personnel returned to the Site on December 13, 2010, to complete a supplemental injection program in order to address the marginal PCE exceedances. A total of 50 kilograms of sodium permanganate was mixed with 200 litres of clean water and injected into the galleries using a passive gravity injection approach (approx 50 L of solution was placed into each of galleries IW10-1A and IW10-2A as well as monitoring well MW05-2 and MW07-2).
Pinchin field personnel returned to the Site on February 23, 2011 to collect verification groundwater samples from the monitoring wells which had previously shown exceedances of the applicable standards (MW05-2 and MW07-2). It should be noted that at the time of this sampling event, the groundwater sample collected from MW07-2 still showed signs of oxidant in solution (ie, deep purple in color) and as such, a sample from MW07-2 was not submitted for chemical analysis due to potential interference of the oxidant with the lab instrumentation. The results of the lab analysis indicated that the groundwater verification sample collected from MW05-2 reported concentrations of all target parameters which satisfied the Table 3 (non-
potable groundwater condition) Standard.
Subsequently, Pinchin field personnel returned to the Site on March 24, 2011 to collect a verification groundwater sample from only remaining monitoring well which had previously shown exceedances of the applicable standards (MW07-2). The results of the lab analysis indicated that the sample collected from MW07-2 reported concentrations of all target parameters which satisfied the Table 3 (non-potable groundwater condition) Standard.
Remedial Excavation and Verification Soil Sampling Program Herongate Mall – 1670 Heron Road, Ottawa, Ontario March 30, 2011 TransGlobe Property Management Services Pinchin File: 47880.002
© 2010 Pinchin Environmental Ltd. Page 9
6.0 CONCLUSIONS
The following is a summary of activities and results of this comprehensive remedial program conducted at the Site:
1. From September 28 through October 15, 2010, Pinchin field personnel were on-Site to supervise the excavation activities completed by Ontario Specialty Contracting (“OSC”). A mini-track driven excavator operated by OSC was used to remove the surficial concrete material and all accessible overburden soils;
2. Data collected during the excavation operations indicated that the subsurface material at the Site generally consisted of concrete underlain by a sand gravel fill material, successively underlain by native brown silt clay over bedrock, which was observed at a minimum depth of 5.5 meters below ground surface (“mbgs”);
3. Pinchin field personnel completed a field screening and segregation program using visual, olfactory and organic vapour measurements recorded using a photo-ionization detector (“PID”). The final limits of the excavation were extended until little or no visual or olfactory evidence of environmental impacts were observed.
4. The non-impacted soil was segregated from the impacted soil as a result of the field screening program and stockpiled on Site for reuse as fill material. The excavation area extended to a maximum depth of 4.5 mbgs and terminated upon encountering a shale/bedrock material. Approximately 100 metric tonnes of impacted soil was removed from the excavation and stockpiled on-Site for subsequent disposal at a certified waste handling facility, pending the results of the laboratory analysis;
5. To facilitate soil disposal, a “worst case” soil sample (labelled TCLP) was collected from the excavation area and submitted for chemical analysis of metal, benzene and total petroleum hydrocarbons using a Toxicity Characteristic Leaching Procedure (“TCLP”) in accordance with Ontario Regulation 558/00, in order to classify the soil for landfill disposal. The results of the laboratory TCLP analysis indicated that the soils would be classified as a non-hazardous solid waste;
6. Based on the Site specific conditions, the soil quality at the Site was assessed using the Table 3 (non-potable groundwater conditions) Standards for commercial/industrial/institutional land use and coarse grained soils. The standards referenced above are outlined in the “Soil, Groundwater and Sediment Standards for Use Under Part XV.1 of the Environmental Protection Act”, MOE, March 9, 2004;
7. The most apparent “worst case” soil samples based on vapour concentrations as well as visual and/or olfactory considerations were recovered from the limits of the excavation and submitted for laboratory chemical analysis. Based on the size of the excavation which had a measured floor area of approximately 28 square metres, three floor samples (FL-5, FL-6 and FL-8) and six wall samples (EW-3, WW-2, SW-4, NW-4, WW-8 and EW-7) were submitted for laboratory analysis.
8. All verification soil samples were collected and submitted to Paracel Laboratories (“Paracel”) located in Ottawa, Ontario in accordance with the Ontario Ministry of the Environment’s (“MOE”) Guidance on Sampling and Analytical Methods for Use at
Remedial Excavation and Verification Soil Sampling Program Herongate Mall – 1670 Heron Road, Ottawa, Ontario March 30, 2011 TransGlobe Property Management Services Pinchin File: 47880.002
© 2010 Pinchin Environmental Ltd. Page 10
Contaminated Sites in Ontario (1996) and submitted for laboratory analysis of VOC parameters
9. The results of the soil chemical analysis indicated that all of the verification soil samples collected at the Site reported concentrations of all target parameters which satisfied the applicable criteria specified in the applicable Table 3 (non-potable groundwater condition) Standards;
10. In order to address any residual impacted groundwater remaining in the vicinity of the excavation area, two injection galleries were installed on the base of the excavation area, following the collection of the verification soil samples. The injection galleries systems consisted of a 7 meter perforated pipe placed horizontally within the base of the excavation, connected with 90 degree elbows at the ends to solid pipe which was extended vertically to the concrete surface. The horizontal perforated pipe was situated within a bed of clear stone with an approximate thickness of one metre;
11. Following the collection of all verification soil samples from the excavations, all non-impacted material which was stockpiled on-Site was reinstated within the excavations and compacted. Approximately 80 metric tonnes of Granular B, 8.1 metric tonnes of Granular A and 2.4 metric tonnes of clear stone material was imported to the Site and compacted within the excavations in order to restore the excavation areas to the original grade levels. Once the backfill material had been placed and compacted to the appropriate geotechnical standards, the concrete floor slab was reinstated;
12. Upon completion of the reinstatement of the excavation area, Pinchin retained Strata Soil Sampling Inc. to advance one borehole (MW10-1) on October 14, 2010. The borehole was advanced using a Geoprobe 6620 DT direct push drill rig within the central portion of the dry cleaning facility in the immediate vicinity of the dry cleaning equipment. The borehole was advanced to a maximum depth of 4.5 mbgs and terminated upon encountering the underlying shale/bedrock interface. The borehole was instrumented with a monitoring well to enable groundwater monitoring and sampling. The monitoring well MW10-1, which replaced monitoring wells MW05-1 and MW07-1 that had been decommissioned as part of the remedial excavation process, was installed within the dry cleaning facility in order evaluate the environmental condition of the groundwater subsequent to the remedial activities;
13. On October 14, 2010, Pinchin field personnel completed an initial injection program under Certificate of Authorization provided by the MOE. A total of 520 kilograms of sodium permanganate was mixed with 400 litres of clean water and injected into the galleries using a passive gravity injection approach (approx 182 Kg / 140 L was placed into gallery IW10-1A and 338 Kg / 260 L was placed into gallery IW10-2A);
14. In order to determine the effectiveness of the initial injection program, Pinchin returned to the Site on November 19, 2010 to collect groundwater samples from monitoring well
Remedial Excavation and Verification Soil Sampling Program Herongate Mall – 1670 Heron Road, Ottawa, Ontario March 30, 2011 TransGlobe Property Management Services Pinchin File: 47880.002
© 2010 Pinchin Environmental Ltd. Page 11
MW10-1 (located within the dry cleaning facility) as well as the existing monitoring wells MW05-2 and MW07-2 (which are located immediately adjacent to the dry cleaning facility in the dollarama lunch room). The samples were submitted to Paracel for chemical analysis of VOC parameters;
15. The results of the groundwater sampling program indicated that the groundwater sample collected from the dry cleaning (MW10-1) facility reported concentrations of all VOC parameters which satisfied the Table 3 (non-potable groundwater condition) Standards. However, the groundwater samples collected from the dollarama (MW05-2 and MW07-2) reported concentrations of tetrachloroethylene (“PCE”) at 6.8 ug/L and 6.1 ug/L respectively which marginally exceeded the Table 3 (non-potable groundwater condition) Standard of 5.0 ug/L;
16. As such, Pinchin field personnel returned to the Site on December 13, 2010, to complete a supplemental injection program in order to address the marginal PCE exceedances. A total of 50 kilograms of sodium permanganate was mixed with 200 litres of clean water and injected into the galleries using a passive gravity injection approach (approx 50 L of solution was placed into each of galleries IW10-1A and IW10-2A as well as monitoring well MW05-2 and MW07-2);
17. Pinchin field personnel returned to the Site on February 23, 2011 to collect verification groundwater samples from the monitoring wells which had previously shown exceedances of the applicable standards (MW05-2 and MW07-2). It should be noted that at the time of this sampling event, the groundwater sample collected from MW07-2 still showed signs of oxidant in solution (ie, deep purple in color) and as such, a sample from MW07-2 was not submitted for chemical analysis due to potential interference of the oxidant with the lab instrumentation. The results of the lab analysis indicated that the sample collected from MW05-2 reported concentrations of all target parameters which satisfied the Table 3 (non-potable groundwater condition) Standard; and,
18. Subsequently, Pinchin field personnel returned to the Site on March 24, 2011 to collect a verification groundwater sample from only remaining monitoring well which had previously shown exceedances of the applicable standards (MW07-2). The results of the lab analysis indicated that the sample collected from MW07-2 reported concentrations of all target parameters which satisfied the Table 3 (non-potable groundwater condition)
Standard;
Remedial Excavation and Verification Soil Sampling Program Herongate Mall – 1670 Heron Road, Ottawa, Ontario March 30, 2011 TransGlobe Property Management Services Pinchin File: 47880.002
© 2010 Pinchin Environmental Ltd. Page 12
7.0 RECOMMENDATIONS
Based on the results of the Remedial Excavation and Verification Soil Sampling Program completed at the Site, including the results of the laboratory analysis, the soils from the area of the Site included as part of this program are deemed to be in compliance with the applicable Table 3 (non-potable groundwater condition) Standards for industrial/commercial/institutional land use and coarse grained soil. In addition, it was reported that the dry cleaning operation has recently switched to environmentally friendly dry cleaning solutions, therefore the potential for the adverse environmental effects to the Site due to the on-going Site operations is not expected. As such, given that the source of the contamination has been eliminated and the potential for recontamination is minimal, no further work is warranted with respect to the soils which underlie the dry cleaning facility.
In terms of the potential for residually impacted groundwater, it should be noted that the concentrations of PCE detected within the groundwater samples collected from within the dry cleaning have decreased from 38 ug/L to 4.6 ug/L and concentrations within the adjacent tenant space have decreased from 6.1 ug/L to 2.3 ug/L as a result of the soil excavation and injection programs. This data infers that the remedial activities completed at the Site have been successful in achieving their remedial objectives of bringing the dry cleaning facility and adjacent tenant space into compliance with the Table 3 (non-potable groundwater condition) Standards.
8.0 DISCLAIMER
This Remedial Excavation and Verification Soil Sampling Program were performed in order to mitigate the recognized environmental conditions which were detected beneath the dry cleaning facility at 1670 Heron Road (“Site”). The term ‘recognized environmental condition’ means the presence or likely presence of any hazardous substance on a property under conditions that indicate an existing release, past release, or a material threat of a release of a hazardous substance into structures on the property or into the ground, groundwater, or surface water of the property.
Conclusions derived are specific to the immediate area of study and cannot be extrapolated extensively away from sample locations. Samples have been analyzed for a limited number of contaminants that are expected to be present at the Site, and the absence of information relating to a specific contaminant does not indicate that it is not present.
No environmental remedial excavation can wholly eliminate uncertainty regarding the potential for recognized environmental conditions on the property. Performance of this remedial excavation to the standards established by Pinchin is intended to remediate the area outlined in the scope of work, but does not eliminate uncertainty regarding the potential for recognized environmental conditions on the property, and recognizes reasonable limits on time and cost.
Remedial Excavation and Verification Soil Sampling Program Herongate Mall – 1670 Heron Road, Ottawa, Ontario March 30, 2011 TransGlobe Property Management Services Pinchin File: 47880.002
© 2010 Pinchin Environmental Ltd. Page 13
This Remedial Excavation and Verification Soil Sampling Program were performed in general compliance with currently acceptable practices for environmental site investigations, and specific client requests, as applicable to this Site. This report was prepared for the exclusive use of TransGlobe Property Management Services, subject to the conditions and limitations contained within the duly authorized workplan. Any use which a third party makes of this report, or any reliance on or decisions to be made based on it, are the responsibility of the third parties. If additional parties require reliance on this report, written authorization from Pinchin will be required. Pinchin disclaims responsibility of consequential financial effects on transactions or property values, or requirements for follow-up actions and costs. No other warranties are implied or expressed.
Pinchin will not be responsible for any consequential or indirect damages. Pinchin will only be held liable for damages resulting from negligence of Pinchin. Pinchin will not be liable for any losses or damage if Client has failed, within a period of two (2) years following the date upon which the claim is discovered within the meaning of the Limitations Act, 2002 (Ontario), to commence legal proceedings against Pinchin to recover such losses or damage.
Pinchin makes no other representations whatsoever, including those concerning the legal significance of its findings, or as to other legal matters touched on in this report, including, but not limited to, ownership of any property, or the application of any law to the facts set forth herein. With respect to regulatory compliance issues, regulatory statutes are subject to interpretation and these interpretations may change over time.
APPENDIX I
FIGURES
PROJECT NAME
REMEDIAL EXCAVATION & INJECTION PROGRAM CLIENT NAME
TRANSGLOBE PROPERTY MANAGEMENT SERVICES PROJECT LOCATION
1670 HERON ROAD, OTTAWA, ONTARIO DRAWING NAME DRAWING NO.
FIG. 1
GENERALIZED SITE LOCATION MAP SCALE PROJECT NO. DATE
NTS 47880.002 MARCH 2011
APPENDIX II
SUMMARY TABLES
O.Reg 558/00Schedule 4
TCLP (Leachate Quality Criteria)27-Sep-10
Arsenic < 0.05 2.5Barium 1.21 100.0Boron 0.07 500.0Cadmium < 0.01 0.5Chromium < 0.05 5Lead < 0.05 5Selenium < 0.05 1Silver < 0.05 5Uranium < 0.05 10Mercury < 0.0005 0.1Benzene <0.0005 0.52-Butonone (MEK) <0.03 200Carbon Tetrachloride <0.0005 0.5Chlorobenzene < 0.0004 8Chloroform < 0.0006 101,2-Dichlorobenzene < 0.0004 201,4-Dichlorobenzene < 0.0004 0.51,2-Dichloroethane < 0.0005 0.51,1-Dichloroethylene < 0.0006 1.4
Parameter
TABLE 1.Laboratory Analysis for Toxicity Characteristic Leaching Procedures in Soil
1670 Heron Road, Ottawa, ONProject # 47880.002
Sample Identification
1,1 Dichloroethylene < 0.0006 1.4Methylene Chloride < 0.004 5Tetrachloroethylene 0.03 3Trichloroethylene < 0.0004 5Vinyl Chloride < 0.0005 0.2TPH (gasoline) <10 NVTPH (diesel) <10 NVNitrite as N <1 1000Nitrate as N <1 1000Final pH 5.96 NVInitial pH 9.13 NV
Notes:MDL - Method Detection Limits in mg/L unless otherwise statedND = Reported Concentration Below Method Detection Limit (Non-Detect)NV - No published value Result exceeds Ontario Regulation 558/00 Schedule 4 Leachate Quality Criteria50
Pinchin Environmental Limited Page 1 of 1
Current EPA StandardsTable 3
FL-5 EW-3 WW-2 SW-4 NW-4 FL-6 FL-8 WW-8 EW-7 (Full-Depth, Non-Potable)2.58 mbgs 2.58 mbgs 1.83 mbgs 2.13 mbgs 2.58 mbgs 3.05 mbgs 3.05 mbgs 2.58 mbgs 2.58 mbgs I/C/C Land Use5-Oct-10 5-Oct-10 5-Oct-10 5-Oct-10 12-Oct-10 12-Oct-10 12-Oct-10 12-Oct-10 12-Oct-10 Coarse Grained Soils
Benzene <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 5.3Bromodichloromethane <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 25Bromoform <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 2.3Bromomethane <0.003 <0.003 <0.003 <0.003 <0.003 <0.003 <0.003 <0.003 <0.003 0.061Carbon Tetrachloride <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 0.1Chlorobenzene <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 8Chloroform <0.003 <0.003 <0.003 <0.003 <0.003 <0.003 <0.003 <0.003 <0.003 0.79Dibromochloromethane <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 18Dichlorobenzene, 1,2- <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 30Dichlorobenzene, 1,3- <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 30Dichlorobenzene, 1,4- <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 30Dichlorodiflouromethane <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 NVDichloroethane, 1,1- <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 22Dichloroethane, 1,2- <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 0.022Dichloroethylene, 1,1- <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 0.0024Dichloroethylene, c-1,2- <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 2.3Dichloroethylene, t-1,2- <0.003 <0.003 <0.003 <0.003 <0.003 <0.003 <0.003 <0.003 <0.003 4.1Dichloropropane, 1,2- <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 0.019Dichloropropene, 1,3- <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 0.066Ethylbenzene <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 290Ethylene dibromide <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 0.0056Hexane (n) <0 005 <0 005 <0 005 <0 005 <0 005 <0 005 <0 005 <0 005 <0 005 NV
Parameter
Sample (Location / Depth / Date)
TABLE 2.Laboratory Analysis for VOC Parameters in Soil
1670 Heron Road, Ottawa, ONProject # 47880.002
Hexane (n) <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 NVMethyl Ethyl Ketone <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 38Methyl Isobutyl Ketone <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 58Methyl tert-Butyl Ether <0.004 <0.004 <0.004 <0.004 <0.004 <0.004 <0.004 <0.004 <0.004 120Methylene Chloride <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 140Styrene <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 1.2Tetrachloroethane, 1,1,1,2- <0.003 <0.003 <0.003 <0.003 <0.003 <0.003 <0.003 <0.003 <0.003 0.019Tetrachloroethane, 1,1,2,2- <0.003 <0.003 <0.003 <0.003 <0.003 <0.003 <0.003 <0.003 <0.003 0.037Tetrachloroethylene <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 0.005 0.002 0.002 0.45Toluene <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 34Trichloroethane, 1,1,1- <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 26Trichloroethane, 1,1,2- <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 3.1Trichloroethylene <0.003 <0.003 <0.003 <0.003 <0.003 <0.003 <0.003 <0.003 <0.003 1.1Trichlorofluoromethane <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 NVVinyl Chloride <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 0.003Total Xylenes <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 34
Notes:All units in µg/g (parts per billion)EPA Standards = Soil, Groundwater and Sediment Standards for Use Under Part XV.1 of the Environmental Protection Act (March 9, 2004)<0.002 = Reported Concentration Below Method Detection Limit (Non-Detect)NV = No published value
Parameter Concentration Exceeds Current EPA O-Reg 153 Table 3 Criterion for Non-Potable Groundwater Use for Coarse Grained Soil500
Pinchin Environmental LimitedPage 1 of 1
EPA StandardsCurrent Table 3
MW05-1 MW07-1 MW10-1 (Full-Depth, Non-Potable)10-Mar-10 10-Mar-10 19-Nov-10 I/C/C Land Use
Benzene < 0.5 < 0.5 < 0.5 1,900Bromodichloromethane < 0.4 < 0.4 < 0.4 50,000Bromoform < 0.8 < 0.8 < 0.8 840Bromomethane < 1 < 1 < 1 3.7Carbon Tetrachloride < 0.5 < 0.5 < 0.5 17Chlorobenzene < 0.4 < 0.4 < 0.4 500Chlroroethane < 1 < 1 < 1 NVChloroform 2.2 < 0.6 < 0.6 430Chloromethane < 3 < 3 < 3 NVDibromochloromethane < 0.5 < 0.5 < 0.5 50,0001,2-Dibromoethane < 1 < 1 < 1 NVm-Dichlorobenzene < 0.4 < 0.4 < 0.4 7,600o-Dichlorobenzene < 0.4 < 0.4 < 0.4 7,600p-Dichlorobenzene < 0.4 < 0.4 < 0.4 7,6001,1-Dichloroethane < 0.5 < 0.5 < 0.5 9,0001,2-Dichloroethane < 0.5 < 0.5 < 0.5 171,1-Dichloroethylene < 0.6 < 0.6 < 0.6 0.66cis-1,2-Dichloroethylene < 0.4 < 0.4 < 0.4 70trans-1,2-Dichloroethylene < 1 < 1 < 1 1001,2-Dichloropropane < 0.7 < 0.7 < 0.7 9.3cis-1,3-Dichloropropene < 0.4 < 0.4 < 0.4 4
TABLE 3.Laboratory Analysis for Volatile Organic Compound Parameters in Verification Groundwater Samples
Herongate Mall, 1670 Heron Road, Ottawa, ONProject # 47880.002
ParameterSample (Location / Date)
trans-1,3-Dichloropropene < 0.5 < 0.5 < 0.5 4Ethylbenzene < 0.5 < 0.5 < 0.5 28,000Methylene Chloride < 4 < 4 < 4 50,000Styrene < 0.4 < 0.4 < 0.4 9401,1,2,2-Tetrachloroethane < 0.5 < 0.5 < 0.5 221,1,1,2-Tetracholroethane < 0.6 < 0.6 < 0.6 6Tetrachloroethylene 53.9 17.8 4.6 5Toluene < 0.5 < 0.5 < 0.5 5,9001,1,1-Trichloroethane < 0.4 < 0.4 < 0.4 2001,1,2-Trichloroethane < 0.6 < 0.6 < 0.6 16,000Trichloroethylene < 0.4 < 0.4 < 0.4 50Trichlorofluoromethane < 1 < 1 < 1 NV1,3,5-Trimethylbenzene < 0.5 < 0.5 < 0.5 NVVinyl Chloride < 0.5 < 0.5 < 0.5 0.5(m + p)-Xylenes < 1 < 1 < 1 NVo-Xylene < 0.5 < 0.5 < 0.5 NVXylenes <1.5 <1.5 <1.5 5,600
Notes:All units in µg/L (parts per billion)EPA Standards = Soil, Groundwater and Sediment Standards for Use Under Part XV.1 of the Environmental Protection Act (March 9, 2004)NV = No published value<0.002 - Reported Concentration Below Method Detection Limit (Non-Detect)
Parameter Concentration Exceeds O.Reg 153/04 - Table 3 Criterion for Non-Potable Groundwater Conditions
Monitoring wells MW05-1 and MW07-1 were decomissioned as part of the excavation process and MW10-1 was reinstalled within the dry cleaner area for verification purposes
500
Pinchin Environmental Ltd. Page 1 of 3
EPA StandardsCurrent Table 3
(Full-Depth, Non-Potable)10-Mar-10 19-Nov-10 23-Feb-11 I/C/C Land Use
Benzene < 0.5 < 0.5 < 0.5 1,900Bromodichloromethane < 0.4 < 0.4 < 0.4 50,000Bromoform < 0.8 < 0.8 < 0.8 840Bromomethane < 1 < 1 < 1 3.7Carbon Tetrachloride < 0.5 < 0.5 < 0.5 17Chlorobenzene < 0.4 < 0.4 < 0.4 500Chlroroethane < 1 < 1 < 1 NVChloroform < 0.6 < 0.6 < 0.6 430Chloromethane < 3 < 3 < 3 NVDibromochloromethane < 0.5 < 0.5 < 0.5 50,0001,2-Dibromoethane < 1 < 1 < 1 NVm-Dichlorobenzene < 0.4 < 0.4 < 0.4 7,600o-Dichlorobenzene < 0.4 < 0.4 < 0.4 7,600p-Dichlorobenzene < 0.4 < 0.4 < 0.4 7,6001,1-Dichloroethane < 0.5 < 0.5 < 0.5 9,0001,2-Dichloroethane < 0.5 < 0.5 < 0.5 171,1-Dichloroethylene < 0.6 < 0.6 < 0.6 0.66cis-1,2-Dichloroethylene < 0.4 < 0.4 < 0.4 70trans-1,2-Dichloroethylene < 1 < 1 < 1 1001,2-Dichloropropane < 0.7 < 0.7 < 0.7 9.3cis 1 3 Dichloropropene < 0 4 < 0 4 < 0 4 4
TABLE 3.Laboratory Analysis for Volatile Organic Compound Parameters in Verification Groundwater Samples
Herongate Mall, 1670 Heron Road, Ottawa, ONProject # 47880.002
ParameterSample (Location / Date)
MW05-2
cis-1,3-Dichloropropene < 0.4 < 0.4 < 0.4 4trans-1,3-Dichloropropene < 0.5 < 0.5 < 0.5 4Ethylbenzene < 0.5 < 0.5 < 0.5 28,000Methylene Chloride < 4 < 4 < 4 50,000Styrene < 0.4 < 0.4 < 0.4 9401,1,2,2-Tetrachloroethane < 0.5 < 0.5 < 0.5 221,1,1,2-Tetracholroethane < 0.6 < 0.6 < 0.6 6Tetrachloroethylene 9.5 6.8 3.2 5Toluene < 0.5 < 0.5 < 0.5 5,9001,1,1-Trichloroethane < 0.4 < 0.4 < 0.4 2001,1,2-Trichloroethane < 0.6 < 0.6 < 0.6 16,000Trichloroethylene < 0.4 < 0.4 < 0.4 50Trichlorofluoromethane < 1 < 1 < 1 NV1,3,5-Trimethylbenzene < 0.5 < 0.5 < 0.5 NVVinyl Chloride < 0.5 < 0.5 < 0.5 0.5(m + p)-Xylenes < 1 < 1 < 1 NVo-Xylene < 0.5 < 0.5 < 0.5 NVXylenes <1.5 <1.5 <1.5 5,600
Notes:All units in µg/L (parts per billion)EPA Standards = Soil, Groundwater and Sediment Standards for Use Under Part XV.1 of the Environmental Protection Act (March 9, 2004)NV = No published value<0.002 - Reported Concentration Below Method Detection Limit (Non-Detect)
Parameter Concentration Exceeds O.Reg 153/04 - Table 3 Criterion for Non-Potable Groundwater Conditions500
Pinchin Environmental Ltd. Page 2 of 3
EPA StandardsCurrent Table 3
(Full-Depth, Non-Potable)10-Mar-10 19-Nov-10 24-Mar-11 I/C/C Land Use
Benzene < 0.5 < 0.5 < 0.5 1,900Bromodichloromethane < 0.4 < 0.4 < 0.4 50,000Bromoform < 0.8 < 0.8 < 0.8 840Bromomethane < 1 < 1 < 1 3.7Carbon Tetrachloride < 0.5 < 0.5 < 0.5 17Chlorobenzene < 0.4 < 0.4 < 0.4 500Chlroroethane < 1 < 1 < 1 NVChloroform < 0.6 < 0.6 < 0.6 430Chloromethane < 3 < 3 < 3 NVDibromochloromethane < 0.5 < 0.5 < 0.5 50,0001,2-Dibromoethane < 1 < 1 < 1 NVm-Dichlorobenzene < 0.4 < 0.4 < 0.4 7,600o-Dichlorobenzene < 0.4 < 0.4 < 0.4 7,600p-Dichlorobenzene < 0.4 < 0.4 < 0.4 7,6001,1-Dichloroethane < 0.5 < 0.5 < 0.5 9,0001,2-Dichloroethane < 0.5 < 0.5 < 0.5 171,1-Dichloroethylene < 0.6 < 0.6 < 0.6 0.66cis-1,2-Dichloroethylene < 0.4 < 0.4 < 0.4 70trans-1,2-Dichloroethylene < 1 < 1 < 1 1001,2-Dichloropropane < 0.7 < 0.7 < 0.7 9.3cis 1 3 Dichloropropene < 0 4 < 0 4 < 0 4 4
TABLE 3.Laboratory Analysis for Volatile Organic Compound Parameters in Verification Groundwater Samples
Herongate Mall, 1670 Heron Road, Ottawa, ONProject # 47880.002
ParameterSample (Location / Date)
MW07-2
cis-1,3-Dichloropropene < 0.4 < 0.4 < 0.4 4trans-1,3-Dichloropropene < 0.5 < 0.5 < 0.5 4Ethylbenzene < 0.5 < 0.5 < 0.5 28,000Methylene Chloride < 4 < 4 < 4 50,000Styrene < 0.4 < 0.4 < 0.4 9401,1,2,2-Tetrachloroethane < 0.5 < 0.5 < 0.5 221,1,1,2-Tetracholroethane < 0.6 < 0.6 < 0.6 6Tetrachloroethylene 18 6.1 2.3 5Toluene < 0.5 1.5 < 0.5 5,9001,1,1-Trichloroethane < 0.4 < 0.4 < 0.4 2001,1,2-Trichloroethane < 0.6 < 0.6 < 0.6 16,000Trichloroethylene < 0.4 < 0.4 < 0.4 50Trichlorofluoromethane < 1 < 1 < 1 NV1,3,5-Trimethylbenzene < 0.5 < 0.5 < 0.5 NVVinyl Chloride < 0.5 < 0.5 < 0.5 0.5(m + p)-Xylenes < 1 < 1 < 1 NVo-Xylene < 0.5 < 0.5 < 0.5 NVXylenes <1.5 <1.5 <1.5 5,600
Notes:All units in µg/L (parts per billion)EPA Standards = Soil, Groundwater and Sediment Standards for Use Under Part XV.1 of the Environmental Protection Act (March 9, 2004)NV = No published value<0.002 - Reported Concentration Below Method Detection Limit (Non-Detect) Parameter Concentration Exceeds O.Reg 153/04 - Table 3 Criterion for Non-Potable Groundwater Conditions500
Pinchin Environmental Ltd. Page 3 of 3
APPENDIX III
SITE PHOTOGRAPHS
Underground Storage Tank Removal and Remedial Excavation Program 898 County Road 2, Lansdowne, Ontario November 12, 2010 Mr. Joe McNeely Pinchin File: 62418
(c) 2010 Pinchin Environmental Ltd.
Photo 1 – Vacuum truck extracting remaining product from the USTs.
Photo 2 – Removal of the 15,000-litre diesel UST.
Underground Storage Tank Removal and Remedial Excavation Program 898 County Road 2, Lansdowne, Ontario November 12, 2010 Mr. Joe McNeely Pinchin File: 62418
(c) 2010 Pinchin Environmental Ltd.
Photo 3 – Groundwater was observed infiltrating the UST excavation.
Photo 4 – USTs were observed to be in good condition with no corrosion or rusting.
Underground Storage Tank Removal and Remedial Excavation Program 898 County Road 2, Lansdowne, Ontario November 12, 2010 Mr. Joe McNeely Pinchin File: 62418
(c) 2010 Pinchin Environmental Ltd.
Photo 5 – The excavation below the pump island was extended until competent bedrock was encountered.
Photo 6 – Following the collecting of all verification soil samples, non-impacted material was reinstated within the excavation.
APPENDIX IV
LABORATORY CERTIFICATE OF ANALYSES
Order Date: 5-Oct-2010 Report Date: 12-Oct-2010
Fax: (613) 592-5897Phone: (613) 592-3387
Client PO:
This Certificate of Analysis contains analytical data applicable to the following samples as submitted:
Custody: 68238
Attn: Peter RobertsKanata, ON K2K 3G4200-515 Legget Dr.
Certificate of Analysis
Paracel ID Client ID
Pinchin Environmental Ltd. (Ottawa)
Order #: 1041097
Project: 47880.002 Herongate
1041097-01 FL-51041097-02 EW-31041097-03 WW-21041097-04 SW-4
Approved By:Mark Foto, M.Sc. For Dale Robertson, BScLaboratory Director
Page 1 of 8
Any use of these results implies your agreement that our total liabilty in connection with this work, however arising shall be limited to the amount paid by you for this work, and that our employees or agents shall not under circumstances be liable to you in connection with this work
Certificate of AnalysisClient:
Report Date: 12-Oct-2010Order Date:5-Oct-2010
Client PO: Project Description: 47880.002 HerongatePinchin Environmental Ltd. (Ottawa)
Order #: 1041097
Analysis Summary Table
Analysis Method Reference/Description Extraction Date Analysis Date
Gravimetric, calculation 7-Oct-10 7-Oct-10Solids, %EPA 8260 - P&T GC-MS 5-Oct-10 8-Oct-10VOCs
Page 2 of 8
Certificate of AnalysisClient:
Report Date: 12-Oct-2010Order Date:5-Oct-2010
Client PO: Project Description: 47880.002 HerongatePinchin Environmental Ltd. (Ottawa)
Order #: 1041097
Client ID: FL-5 EW-3 WW-2 SW-4Sample Date: 05-Oct-1005-Oct-1005-Oct-1005-Oct-10
1041097-01 1041097-02 1041097-03 1041097-04Sample ID:MDL/Units Soil Soil Soil Soil
Physical Characteristics
% Solids 75.195.072.776.10.1 % by Wt.
Volatiles
Benzene <0.002<0.002<0.002<0.0020.002 ug/g dry
Bromodichloromethane <0.002<0.002<0.002<0.0020.002 ug/g dry
Bromoform <0.002<0.002<0.002<0.0020.002 ug/g dry
Bromomethane <0.003<0.003<0.003<0.0030.003 ug/g dry
Carbon Tetrachloride <0.002<0.002<0.002<0.0020.002 ug/g dry
Chlorobenzene <0.002<0.002<0.002<0.0020.002 ug/g dry
Chloroethane <0.005<0.005<0.005<0.0050.005 ug/g dry
Chloroform <0.003<0.003<0.003<0.0030.003 ug/g dry
Chloromethane <0.020<0.020<0.020<0.0200.020 ug/g dry
Dibromochloromethane <0.002<0.002<0.002<0.0020.002 ug/g dry
1,2-Dibromoethane <0.002<0.002<0.002<0.0020.002 ug/g dry
1,2-Dichlorobenzene <0.002<0.002<0.002<0.0020.002 ug/g dry
1,3-Dichlorobenzene <0.002<0.002<0.002<0.0020.002 ug/g dry
1,4-Dichlorobenzene <0.002<0.002<0.002<0.0020.002 ug/g dry
1,1-Dichloroethane <0.002<0.002<0.002<0.0020.002 ug/g dry
1,2-Dichloroethane <0.002<0.002<0.002<0.0020.002 ug/g dry
1,1-Dichloroethylene <0.002<0.002<0.002<0.0020.002 ug/g dry
cis-1,2-Dichloroethylene <0.002<0.002<0.002<0.0020.002 ug/g dry
trans-1,2-Dichloroethylene <0.003<0.003<0.003<0.0030.003 ug/g dry
1,2-Dichloroethylene, total <0.003<0.003<0.003<0.0030.003 ug/g dry
1,2-Dichloropropane <0.002<0.002<0.002<0.0020.002 ug/g dry
cis-1,3-Dichloropropylene <0.002<0.002<0.002<0.0020.002 ug/g dry
trans-1,3-Dichloropropylene <0.002<0.002<0.002<0.0020.002 ug/g dry
1,3-Dichloropropene, total <0.002<0.002<0.002<0.0020.002 ug/g dry
Ethylbenzene <0.002<0.002<0.002<0.0020.002 ug/g dry
Methylene Chloride <0.003<0.003<0.003<0.0030.003 ug/g dry
Styrene <0.002<0.002<0.002<0.0020.002 ug/g dry
1,1,1,2-Tetrachloroethane <0.003<0.003<0.003<0.0030.003 ug/g dry
1,1,2,2-Tetrachloroethane <0.003<0.003<0.003<0.0030.003 ug/g dry
Tetrachloroethylene <0.002<0.002<0.002<0.0020.002 ug/g dry
Toluene <0.002<0.002<0.002<0.0020.002 ug/g dry
Page 3 of 8
Certificate of AnalysisClient:
Report Date: 12-Oct-2010Order Date:5-Oct-2010
Client PO: Project Description: 47880.002 HerongatePinchin Environmental Ltd. (Ottawa)
Order #: 1041097
Client ID: FL-5 EW-3 WW-2 SW-4Sample Date: 05-Oct-1005-Oct-1005-Oct-1005-Oct-10
1041097-01 1041097-02 1041097-03 1041097-04Sample ID:MDL/Units Soil Soil Soil Soil
1,1,1-Trichloroethane <0.002<0.002<0.002<0.0020.002 ug/g dry
1,1,2-Trichloroethane <0.002<0.002<0.002<0.0020.002 ug/g dry
Trichloroethylene <0.003<0.003<0.003<0.0030.003 ug/g dry
Trichlorofluoromethane <0.005<0.005<0.005<0.0050.005 ug/g dry
1,3,5-Trimethylbenzene <0.003<0.003<0.003<0.0030.003 ug/g dry
Vinyl chloride <0.002<0.002<0.002<0.0020.002 ug/g dry
m,p-Xylenes <0.002<0.002<0.002<0.0020.002 ug/g dry
o-Xylene <0.002<0.002<0.002<0.0020.002 ug/g dry
Xylenes, total <0.002<0.002<0.002<0.0020.002 ug/g dry
4-Bromofluorobenzene Surrogate 117% 118% 117% 116%
Dibromofluoromethane Surrogate 89.9% 101% 99.2% 93.1%
Toluene-d8 Surrogate 99.3% 97.4% 99.6% 100%
Page 4 of 8
Certificate of AnalysisClient:
Report Date: 12-Oct-2010Order Date:5-Oct-2010
Client PO: Project Description: 47880.002 HerongatePinchin Environmental Ltd. (Ottawa)
Order #: 1041097
Method Quality Control: Blank Analyte Result
ReportingLimit Units
SourceResult %REC
%RECLimit RPD
RPDLimit Notes
VolatilesBenzene ND 0.002 ug/gBromodichloromethane ND 0.002 ug/gBromoform ND 0.002 ug/gBromomethane ND 0.003 ug/gCarbon Tetrachloride ND 0.002 ug/gChlorobenzene ND 0.002 ug/gChloroethane ND 0.005 ug/gChloroform ND 0.003 ug/gChloromethane ND 0.020 ug/gDibromochloromethane ND 0.002 ug/g1,2-Dibromoethane ND 0.002 ug/g1,2-Dichlorobenzene ND 0.002 ug/g1,3-Dichlorobenzene ND 0.002 ug/g1,4-Dichlorobenzene ND 0.002 ug/g1,1-Dichloroethane ND 0.002 ug/g1,2-Dichloroethane ND 0.002 ug/g1,1-Dichloroethylene ND 0.002 ug/gcis-1,2-Dichloroethylene ND 0.002 ug/gtrans-1,2-Dichloroethylene ND 0.003 ug/g1,2-Dichloroethylene, total ND 0.003 ug/g1,2-Dichloropropane ND 0.002 ug/gcis-1,3-Dichloropropylene ND 0.002 ug/gtrans-1,3-Dichloropropylene ND 0.002 ug/g1,3-Dichloropropene, total ND 0.002 ug/gEthylbenzene ND 0.002 ug/gMethylene Chloride ND 0.003 ug/gStyrene ND 0.002 ug/g1,1,1,2-Tetrachloroethane ND 0.003 ug/g1,1,2,2-Tetrachloroethane ND 0.003 ug/gTetrachloroethylene ND 0.002 ug/gToluene ND 0.002 ug/g1,1,1-Trichloroethane ND 0.002 ug/g1,1,2-Trichloroethane ND 0.002 ug/gTrichloroethylene ND 0.003 ug/gTrichlorofluoromethane ND 0.005 ug/g1,3,5-Trimethylbenzene ND 0.003 ug/gVinyl chloride ND 0.002 ug/gm,p-Xylenes ND 0.002 ug/go-Xylene ND 0.002 ug/gXylenes, total ND 0.002 ug/gSurrogate: 4-Bromofluorobenzene 0.133 97.6 83-134ug/gSurrogate: Dibromofluoromethane 0.133 98.0 78-124ug/gSurrogate: Toluene-d8 0.137 101 76-118ug/g
Page 5 of 8
Certificate of AnalysisClient:
Report Date: 12-Oct-2010Order Date:5-Oct-2010
Client PO: Project Description: 47880.002 HerongatePinchin Environmental Ltd. (Ottawa)
Order #: 1041097
Method Quality Control: Duplicate Analyte Result
ReportingLimit Units
SourceResult %REC
%RECLimit RPD
RPDLimit Notes
Physical Characteristics% Solids 93.3 0.1 % by Wt. 93.7 250.4
VolatilesBenzene ND 0.002 ug/g dry ND 50Bromodichloromethane ND 0.002 ug/g dry ND 50Bromoform ND 0.002 ug/g dry ND 50Bromomethane ND 0.003 ug/g dry ND 50Carbon Tetrachloride ND 0.002 ug/g dry ND 50Chlorobenzene ND 0.002 ug/g dry ND 50Chloroethane ND 0.005 ug/g dry ND 50Chloroform ND 0.003 ug/g dry ND 32Chloromethane ND 0.020 ug/g dry ND 50Dibromochloromethane ND 0.002 ug/g dry ND 501,2-Dibromoethane ND 0.002 ug/g dry ND 501,2-Dichlorobenzene ND 0.002 ug/g dry ND 501,3-Dichlorobenzene ND 0.002 ug/g dry ND 501,4-Dichlorobenzene ND 0.002 ug/g dry ND 501,1-Dichloroethane ND 0.002 ug/g dry ND 271,2-Dichloroethane ND 0.002 ug/g dry ND 501,1-Dichloroethylene ND 0.002 ug/g dry ND 50cis-1,2-Dichloroethylene ND 0.002 ug/g dry ND 33trans-1,2-Dichloroethylene ND 0.003 ug/g dry ND 501,2-Dichloropropane ND 0.002 ug/g dry ND 50cis-1,3-Dichloropropylene ND 0.002 ug/g dry ND 50trans-1,3-Dichloropropylene ND 0.002 ug/g dry ND 50Ethylbenzene ND 0.002 ug/g dry ND 34Methylene Chloride ND 0.003 ug/g dry ND 50Styrene ND 0.002 ug/g dry ND 501,1,1,2-Tetrachloroethane ND 0.003 ug/g dry ND 501,1,2,2-Tetrachloroethane ND 0.003 ug/g dry ND 50Tetrachloroethylene ND 0.002 ug/g dry ND 32Toluene ND 0.002 ug/g dry ND 321,1,1-Trichloroethane ND 0.002 ug/g dry ND 501,1,2-Trichloroethane ND 0.002 ug/g dry ND 50Trichloroethylene ND 0.003 ug/g dry ND 31Trichlorofluoromethane ND 0.005 ug/g dry ND 501,3,5-Trimethylbenzene ND 0.003 ug/g dry ND 43Vinyl chloride ND 0.002 ug/g dry ND 50m,p-Xylenes ND 0.002 ug/g dry ND 35o-Xylene ND 0.002 ug/g dry ND 50Surrogate: 4-Bromofluorobenzene 0.193 ug/g dry 101 83-134NDSurrogate: Dibromofluoromethane 0.187 ug/g dry 97.6 78-124NDSurrogate: Toluene-d8 0.194 ug/g dry 102 76-118ND
Page 6 of 8
Certificate of AnalysisClient:
Report Date: 12-Oct-2010Order Date:5-Oct-2010
Client PO: Project Description: 47880.002 HerongatePinchin Environmental Ltd. (Ottawa)
Order #: 1041097
Method Quality Control: Spike Analyte Result
ReportingLimit Units
SourceResult %REC
%RECLimit RPD
RPDLimit Notes
VolatilesBenzene 0.0609 ND 89.6 55-1410.002 ug/gBromodichloromethane 0.0577 ND 84.9 52-1390.002 ug/gBromoform 0.0651 ND 95.7 52-1700.002 ug/gBromomethane 0.0345 ND 50.8 32-1380.003 ug/gCarbon Tetrachloride 0.0560 ND 82.4 49-1490.002 ug/gChlorobenzene 0.0660 ND 97.1 64-1370.002 ug/gChloroethane 0.0637 ND 93.7 39-1520.005 ug/gChloroform 0.0576 ND 84.7 58-1380.003 ug/gChloromethane 0.0840 ND 124 24-1630.020 ug/gDibromochloromethane 0.0676 ND 99.5 61-1530.002 ug/g1,2-Dibromoethane 0.0705 ND 104 61-1450.002 ug/g1,2-Dichlorobenzene 0.0602 ND 88.6 60-1500.002 ug/g1,3-Dichlorobenzene 0.0730 ND 107 62-1490.002 ug/g1,4-Dichlorobenzene 0.0776 ND 114 63-1320.002 ug/g1,1-Dichloroethane 0.0633 ND 93.0 51-1560.002 ug/g1,2-Dichloroethane 0.0697 ND 102 50-1400.002 ug/g1,1-Dichloroethylene 0.0626 ND 92.1 43-1530.002 ug/gcis-1,2-Dichloroethylene 0.0568 ND 83.6 58-1450.002 ug/gtrans-1,2-Dichloroethylene 0.0699 ND 103 51-1450.003 ug/g1,2-Dichloropropane 0.0586 ND 86.2 56-1360.002 ug/gcis-1,3-Dichloropropylene 0.0617 ND 90.7 54-1410.002 ug/gtrans-1,3-Dichloropropylene 0.0734 ND 108 61-1400.002 ug/gEthylbenzene 0.0670 ND 98.5 61-1390.002 ug/gMethylene Chloride 0.0767 ND 113 58-1490.003 ug/gStyrene 0.0628 ND 92.4 63-1430.002 ug/g1,1,1,2-Tetrachloroethane 0.0730 ND 107 61-1480.003 ug/g1,1,2,2-Tetrachloroethane 0.0811 ND 119 50-1570.003 ug/gTetrachloroethylene 0.0702 ND 103 51-1450.002 ug/gToluene 0.0622 ND 91.5 54-1360.002 ug/g1,1,1-Trichloroethane 0.0619 ND 91.1 55-1400.002 ug/g1,1,2-Trichloroethane 0.0619 ND 91.0 63-1440.002 ug/gTrichloroethylene 0.0581 ND 85.4 52-1350.003 ug/gTrichlorofluoromethane 0.0673 ND 99.0 37-1550.005 ug/g1,3,5-Trimethylbenzene 0.0798 ND 117 61-1510.003 ug/gVinyl chloride 0.0696 ND 102 31-1590.002 ug/gm,p-Xylenes 0.134 ND 98.8 61-1390.002 ug/go-Xylene 0.0663 ND 97.6 60-1420.002 ug/gSurrogate: 4-Bromofluorobenzene 0.139 102 83-134ug/gSurrogate: Dibromofluoromethane 0.131 96.0 78-124ug/gSurrogate: Toluene-d8 0.125 91.7 76-118ug/g
Page 7 of 8
Certificate of AnalysisClient:
Report Date: 12-Oct-2010Order Date:5-Oct-2010
Client PO: Project Description: 47880.002 HerongatePinchin Environmental Ltd. (Ottawa)
Order #: 1041097
Sample and QC Qualifiers NotesNone
Sample Data RevisionsNone
Work Order Revisions/Comments:
None
Other Report Notes:
MDL: Method Detection Limitn/a: not applicable
Source Result: Data used as source for matrix and duplicate samples%REC: Percent recovery.RPD: Relative percent difference.Soil results are reported on a dry weight basis when the units are denoted with 'dry'.Where %Solids is reported, moisture loss includes the loss of volatile hydrocarbons.
Page 8 of 8
Order Date: 13-Oct-2010 Report Date: 19-Oct-2010
Fax: (613) 592-5897Phone: (613) 592-3387
Client PO:
This Certificate of Analysis contains analytical data applicable to the following samples as submitted:
Custody: 79935/34
Attn: Peter RobertsKanata, ON K2K 3G4200-515 Legget Dr.
Certificate of Analysis
Paracel ID Client ID
Pinchin Environmental Ltd. (Ottawa)
Order #: 1042087
Project: 47880 Herongate
1042087-01 PH-A1042087-02 PH-B1042087-04 NW-41042087-05 FL-61042087-06 FL-81042087-07 WW-81042087-08 EW-7
Approved By:Mark Foto, M.Sc. For Dale Robertson, BScLaboratory Director
Page 1 of 10
Any use of these results implies your agreement that our total liabilty in connection with this work, however arising shall be limited to the amount paid by you for this work, and that our employees or agents shall not under circumstances be liable to you in connection with this work
Certificate of AnalysisClient:
Report Date: 19-Oct-2010Order Date:13-Oct-2010
Client PO: Project Description: 47880 HerongatePinchin Environmental Ltd. (Ottawa)
Order #: 1042087
Analysis Summary Table
Analysis Method Reference/Description Extraction Date Analysis Date
EPA 150.1 - pH probe, water extraction 19-Oct-10 19-Oct-10pHGravimetric, calculation 15-Oct-10 15-Oct-10Solids, %EPA 8260 - P&T GC-MS 13-Oct-10 16-Oct-10VOCs
Page 2 of 10
Certificate of AnalysisClient:
Report Date: 19-Oct-2010Order Date:13-Oct-2010
Client PO: Project Description: 47880 HerongatePinchin Environmental Ltd. (Ottawa)
Order #: 1042087
Client ID: PH-A PH-B NW-4 FL-6Sample Date: 12-Oct-1012-Oct-1012-Oct-1012-Oct-10
1042087-01 1042087-02 1042087-04 1042087-05Sample ID:MDL/Units Soil Soil Soil Soil
Physical Characteristics
% Solids 68.579.777.574.30.1 % by Wt.
General Inorganics
pH --7.297.430.05 pH Units
Volatiles
Benzene <0.002<0.002--0.002 ug/g dry
Bromodichloromethane <0.002<0.002--0.002 ug/g dry
Bromoform <0.002<0.002--0.002 ug/g dry
Bromomethane <0.003<0.003--0.003 ug/g dry
Carbon Tetrachloride <0.002<0.002--0.002 ug/g dry
Chlorobenzene <0.002<0.002--0.002 ug/g dry
Chloroethane <0.005<0.005--0.005 ug/g dry
Chloroform <0.003<0.003--0.003 ug/g dry
Chloromethane <0.020<0.020--0.020 ug/g dry
Dibromochloromethane <0.002<0.002--0.002 ug/g dry
1,2-Dibromoethane <0.002<0.002--0.002 ug/g dry
1,2-Dichlorobenzene <0.002<0.002--0.002 ug/g dry
1,3-Dichlorobenzene <0.002<0.002--0.002 ug/g dry
1,4-Dichlorobenzene <0.002<0.002--0.002 ug/g dry
1,1-Dichloroethane <0.002<0.002--0.002 ug/g dry
1,2-Dichloroethane <0.002<0.002--0.002 ug/g dry
1,1-Dichloroethylene <0.002<0.002--0.002 ug/g dry
cis-1,2-Dichloroethylene <0.002<0.002--0.002 ug/g dry
trans-1,2-Dichloroethylene <0.003<0.003--0.003 ug/g dry
1,2-Dichloroethylene, total <0.003<0.003--0.003 ug/g dry
1,2-Dichloropropane <0.002<0.002--0.002 ug/g dry
cis-1,3-Dichloropropylene <0.002<0.002--0.002 ug/g dry
trans-1,3-Dichloropropylene <0.002<0.002--0.002 ug/g dry
1,3-Dichloropropene, total <0.002<0.002--0.002 ug/g dry
Ethylbenzene <0.002<0.002--0.002 ug/g dry
Methylene Chloride <0.003<0.003--0.003 ug/g dry
Styrene <0.002<0.002--0.002 ug/g dry
1,1,1,2-Tetrachloroethane <0.003<0.003--0.003 ug/g dry
1,1,2,2-Tetrachloroethane <0.003<0.003--0.003 ug/g dry
Page 3 of 10
Certificate of AnalysisClient:
Report Date: 19-Oct-2010Order Date:13-Oct-2010
Client PO: Project Description: 47880 HerongatePinchin Environmental Ltd. (Ottawa)
Order #: 1042087
Client ID: PH-A PH-B NW-4 FL-6Sample Date: 12-Oct-1012-Oct-1012-Oct-1012-Oct-10
1042087-01 1042087-02 1042087-04 1042087-05Sample ID:MDL/Units Soil Soil Soil Soil
Tetrachloroethylene 0.006<0.002--0.002 ug/g dry
Toluene <0.002<0.002--0.002 ug/g dry
1,1,1-Trichloroethane <0.002<0.002--0.002 ug/g dry
1,1,2-Trichloroethane <0.002<0.002--0.002 ug/g dry
Trichloroethylene <0.003<0.003--0.003 ug/g dry
Trichlorofluoromethane <0.005<0.005--0.005 ug/g dry
1,3,5-Trimethylbenzene <0.003<0.003--0.003 ug/g dry
Vinyl chloride <0.002<0.002--0.002 ug/g dry
m,p-Xylenes <0.002<0.002--0.002 ug/g dry
o-Xylene <0.002<0.002--0.002 ug/g dry
Xylenes, total <0.002<0.002--0.002 ug/g dry
4-Bromofluorobenzene Surrogate - - 113% 106%
Dibromofluoromethane Surrogate - - 92.4% 97.3%
Toluene-d8 Surrogate - - 116% 109%
Page 4 of 10
Certificate of AnalysisClient:
Report Date: 19-Oct-2010Order Date:13-Oct-2010
Client PO: Project Description: 47880 HerongatePinchin Environmental Ltd. (Ottawa)
Order #: 1042087
Client ID: FL-8 WW-8 EW-7 -Sample Date: -12-Oct-1012-Oct-1012-Oct-10
1042087-06 1042087-07 1042087-08 -Sample ID:MDL/Units Soil Soil Soil -
Physical Characteristics
% Solids -72.283.774.60.1 % by Wt.
Volatiles
Benzene -<0.002<0.002<0.0020.002 ug/g dry
Bromodichloromethane -<0.002<0.002<0.0020.002 ug/g dry
Bromoform -<0.002<0.002<0.0020.002 ug/g dry
Bromomethane -<0.003<0.003<0.0030.003 ug/g dry
Carbon Tetrachloride -<0.002<0.002<0.0020.002 ug/g dry
Chlorobenzene -<0.002<0.002<0.0020.002 ug/g dry
Chloroethane -<0.005<0.005<0.0050.005 ug/g dry
Chloroform -<0.003<0.003<0.0030.003 ug/g dry
Chloromethane -<0.020<0.020<0.0200.020 ug/g dry
Dibromochloromethane -<0.002<0.002<0.0020.002 ug/g dry
1,2-Dibromoethane -<0.002<0.002<0.0020.002 ug/g dry
1,2-Dichlorobenzene -<0.002<0.002<0.0020.002 ug/g dry
1,3-Dichlorobenzene -<0.002<0.002<0.0020.002 ug/g dry
1,4-Dichlorobenzene -<0.002<0.002<0.0020.002 ug/g dry
1,1-Dichloroethane -<0.002<0.002<0.0020.002 ug/g dry
1,2-Dichloroethane -<0.002<0.002<0.0020.002 ug/g dry
1,1-Dichloroethylene -<0.002<0.002<0.0020.002 ug/g dry
cis-1,2-Dichloroethylene -<0.002<0.002<0.0020.002 ug/g dry
trans-1,2-Dichloroethylene -<0.003<0.003<0.0030.003 ug/g dry
1,2-Dichloroethylene, total -<0.003<0.003<0.0030.003 ug/g dry
1,2-Dichloropropane -<0.002<0.002<0.0020.002 ug/g dry
cis-1,3-Dichloropropylene -<0.002<0.002<0.0020.002 ug/g dry
trans-1,3-Dichloropropylene -<0.002<0.002<0.0020.002 ug/g dry
1,3-Dichloropropene, total -<0.002<0.002<0.0020.002 ug/g dry
Ethylbenzene -<0.002<0.002<0.0020.002 ug/g dry
Methylene Chloride -<0.003<0.003<0.0030.003 ug/g dry
Styrene -<0.002<0.002<0.0020.002 ug/g dry
1,1,1,2-Tetrachloroethane -<0.003<0.003<0.0030.003 ug/g dry
1,1,2,2-Tetrachloroethane -<0.003<0.003<0.0030.003 ug/g dry
Tetrachloroethylene -0.0020.0020.0050.002 ug/g dry
Toluene -<0.002<0.002<0.0020.002 ug/g dry
Page 5 of 10
Certificate of AnalysisClient:
Report Date: 19-Oct-2010Order Date:13-Oct-2010
Client PO: Project Description: 47880 HerongatePinchin Environmental Ltd. (Ottawa)
Order #: 1042087
Client ID: FL-8 WW-8 EW-7 -Sample Date: -12-Oct-1012-Oct-1012-Oct-10
1042087-06 1042087-07 1042087-08 -Sample ID:MDL/Units Soil Soil Soil -
1,1,1-Trichloroethane -<0.002<0.002<0.0020.002 ug/g dry
1,1,2-Trichloroethane -<0.002<0.002<0.0020.002 ug/g dry
Trichloroethylene -<0.003<0.003<0.0030.003 ug/g dry
Trichlorofluoromethane -<0.005<0.005<0.0050.005 ug/g dry
1,3,5-Trimethylbenzene -<0.003<0.003<0.0030.003 ug/g dry
Vinyl chloride -<0.002<0.002<0.0020.002 ug/g dry
m,p-Xylenes -<0.002<0.002<0.0020.002 ug/g dry
o-Xylene -<0.002<0.002<0.0020.002 ug/g dry
Xylenes, total -<0.002<0.002<0.0020.002 ug/g dry
4-Bromofluorobenzene Surrogate -108%90.5%104%
Dibromofluoromethane Surrogate -85.4%88.2%91.3%
Toluene-d8 Surrogate -92.0%112%112%
Page 6 of 10
Certificate of AnalysisClient:
Report Date: 19-Oct-2010Order Date:13-Oct-2010
Client PO: Project Description: 47880 HerongatePinchin Environmental Ltd. (Ottawa)
Order #: 1042087
Method Quality Control: Blank Analyte Result
ReportingLimit Units
SourceResult %REC
%RECLimit RPD
RPDLimit Notes
VolatilesBenzene ND 0.002 ug/gBromodichloromethane ND 0.002 ug/gBromoform ND 0.002 ug/gBromomethane ND 0.003 ug/gCarbon Tetrachloride ND 0.002 ug/gChlorobenzene ND 0.002 ug/gChloroethane ND 0.005 ug/gChloroform ND 0.003 ug/gChloromethane ND 0.020 ug/gDibromochloromethane ND 0.002 ug/g1,2-Dibromoethane ND 0.002 ug/g1,2-Dichlorobenzene ND 0.002 ug/g1,3-Dichlorobenzene ND 0.002 ug/g1,4-Dichlorobenzene ND 0.002 ug/g1,1-Dichloroethane ND 0.002 ug/g1,2-Dichloroethane ND 0.002 ug/g1,1-Dichloroethylene ND 0.002 ug/gcis-1,2-Dichloroethylene ND 0.002 ug/gtrans-1,2-Dichloroethylene ND 0.003 ug/g1,2-Dichloroethylene, total ND 0.003 ug/g1,2-Dichloropropane ND 0.002 ug/gcis-1,3-Dichloropropylene ND 0.002 ug/gtrans-1,3-Dichloropropylene ND 0.002 ug/g1,3-Dichloropropene, total ND 0.002 ug/gEthylbenzene ND 0.002 ug/gMethylene Chloride ND 0.003 ug/gStyrene ND 0.002 ug/g1,1,1,2-Tetrachloroethane ND 0.003 ug/g1,1,2,2-Tetrachloroethane ND 0.003 ug/gTetrachloroethylene ND 0.002 ug/gToluene ND 0.002 ug/g1,1,1-Trichloroethane ND 0.002 ug/g1,1,2-Trichloroethane ND 0.002 ug/gTrichloroethylene ND 0.003 ug/gTrichlorofluoromethane ND 0.005 ug/g1,3,5-Trimethylbenzene ND 0.003 ug/gVinyl chloride ND 0.002 ug/gm,p-Xylenes ND 0.002 ug/go-Xylene ND 0.002 ug/gXylenes, total ND 0.002 ug/gSurrogate: 4-Bromofluorobenzene 0.153 113 83-134ug/gSurrogate: Dibromofluoromethane 0.130 95.6 78-124ug/gSurrogate: Toluene-d8 0.134 98.8 76-118ug/g
Page 7 of 10
Certificate of AnalysisClient:
Report Date: 19-Oct-2010Order Date:13-Oct-2010
Client PO: Project Description: 47880 HerongatePinchin Environmental Ltd. (Ottawa)
Order #: 1042087
Method Quality Control: Duplicate Analyte Result
ReportingLimit Units
SourceResult %REC
%RECLimit RPD
RPDLimit Notes
General InorganicspH 7.46 0.05 pH Units 7.43 100.4
Physical Characteristics% Solids 100 0.1 % by Wt. 90.3 2510.1
VolatilesBenzene ND 0.002 ug/g dry ND 50Bromodichloromethane ND 0.002 ug/g dry ND 50Bromoform ND 0.002 ug/g dry ND 50Bromomethane ND 0.003 ug/g dry ND 50Carbon Tetrachloride ND 0.002 ug/g dry ND 50Chlorobenzene ND 0.002 ug/g dry ND 50Chloroethane ND 0.005 ug/g dry ND 50Chloroform ND 0.003 ug/g dry ND 32Chloromethane ND 0.020 ug/g dry ND 50Dibromochloromethane ND 0.002 ug/g dry ND 501,2-Dibromoethane ND 0.002 ug/g dry ND 501,2-Dichlorobenzene ND 0.002 ug/g dry ND 501,3-Dichlorobenzene ND 0.002 ug/g dry ND 501,4-Dichlorobenzene ND 0.002 ug/g dry ND 501,1-Dichloroethane ND 0.002 ug/g dry ND 271,2-Dichloroethane ND 0.002 ug/g dry ND 501,1-Dichloroethylene ND 0.002 ug/g dry ND 50cis-1,2-Dichloroethylene ND 0.002 ug/g dry ND 33trans-1,2-Dichloroethylene ND 0.003 ug/g dry ND 501,2-Dichloropropane ND 0.002 ug/g dry ND 50cis-1,3-Dichloropropylene ND 0.002 ug/g dry ND 50trans-1,3-Dichloropropylene ND 0.002 ug/g dry ND 50Ethylbenzene ND 0.002 ug/g dry ND 34Methylene Chloride ND 0.003 ug/g dry ND 50Styrene ND 0.002 ug/g dry ND 501,1,1,2-Tetrachloroethane ND 0.003 ug/g dry ND 501,1,2,2-Tetrachloroethane ND 0.003 ug/g dry ND 50Tetrachloroethylene ND 0.002 ug/g dry ND 32Toluene ND 0.002 ug/g dry ND 321,1,1-Trichloroethane ND 0.002 ug/g dry ND 501,1,2-Trichloroethane ND 0.002 ug/g dry ND 50Trichloroethylene ND 0.003 ug/g dry ND 31Trichlorofluoromethane ND 0.005 ug/g dry ND 501,3,5-Trimethylbenzene ND 0.003 ug/g dry ND 43Vinyl chloride ND 0.002 ug/g dry ND 50m,p-Xylenes ND 0.002 ug/g dry ND 35o-Xylene ND 0.002 ug/g dry ND 50Surrogate: 4-Bromofluorobenzene 0.188 ug/g dry 114 83-134NDSurrogate: Dibromofluoromethane 0.158 ug/g dry 95.7 78-124NDSurrogate: Toluene-d8 0.162 ug/g dry 98.0 76-118ND
Page 8 of 10
Certificate of AnalysisClient:
Report Date: 19-Oct-2010Order Date:13-Oct-2010
Client PO: Project Description: 47880 HerongatePinchin Environmental Ltd. (Ottawa)
Order #: 1042087
Method Quality Control: Spike Analyte Result
ReportingLimit Units
SourceResult %REC
%RECLimit RPD
RPDLimit Notes
VolatilesBenzene 0.0623 ND 91.6 55-1410.002 ug/gBromodichloromethane 0.0671 ND 98.7 52-1390.002 ug/gBromoform 0.0840 ND 124 52-1700.002 ug/gBromomethane 0.0325 ND 47.9 32-1380.003 ug/gCarbon Tetrachloride 0.0604 ND 88.8 49-1490.002 ug/gChlorobenzene 0.0668 ND 98.2 64-1370.002 ug/gChloroethane 0.0482 ND 70.9 39-1520.005 ug/gChloroform 0.0669 ND 98.3 58-1380.003 ug/gChloromethane 0.0580 ND 85.3 24-1630.020 ug/gDibromochloromethane 0.0768 ND 113 61-1530.002 ug/g1,2-Dibromoethane 0.0708 ND 104 61-1450.002 ug/g1,2-Dichlorobenzene 0.0649 ND 95.4 60-1500.002 ug/g1,3-Dichlorobenzene 0.0772 ND 114 62-1490.002 ug/g1,4-Dichlorobenzene 0.0837 ND 123 63-1320.002 ug/g1,1-Dichloroethane 0.0643 ND 94.6 51-1560.002 ug/g1,2-Dichloroethane 0.0674 ND 99.2 50-1400.002 ug/g1,1-Dichloroethylene 0.0587 ND 86.4 43-1530.002 ug/gcis-1,2-Dichloroethylene 0.0591 ND 86.8 58-1450.002 ug/gtrans-1,2-Dichloroethylene 0.0671 ND 98.7 51-1450.003 ug/g1,2-Dichloropropane 0.0661 ND 97.2 56-1360.002 ug/gcis-1,3-Dichloropropylene 0.0675 ND 99.3 54-1410.002 ug/gtrans-1,3-Dichloropropylene 0.0827 ND 122 61-1400.002 ug/gEthylbenzene 0.0689 ND 101 61-1390.002 ug/gMethylene Chloride 0.0711 ND 105 58-1490.003 ug/gStyrene 0.0659 ND 96.9 63-1430.002 ug/g1,1,1,2-Tetrachloroethane 0.0796 ND 117 61-1480.003 ug/g1,1,2,2-Tetrachloroethane 0.0876 ND 129 50-1570.003 ug/gTetrachloroethylene 0.0683 ND 100 51-1450.002 ug/gToluene 0.0631 ND 92.7 54-1360.002 ug/g1,1,1-Trichloroethane 0.0643 ND 94.5 55-1400.002 ug/g1,1,2-Trichloroethane 0.0694 ND 102 63-1440.002 ug/gTrichloroethylene 0.0623 ND 91.7 52-1350.003 ug/gTrichlorofluoromethane 0.0583 ND 85.8 37-1550.005 ug/g1,3,5-Trimethylbenzene 0.0842 ND 124 61-1510.003 ug/gVinyl chloride 0.0450 ND 66.2 31-1590.002 ug/gm,p-Xylenes 0.142 ND 104 61-1390.002 ug/go-Xylene 0.0679 ND 99.9 60-1420.002 ug/gSurrogate: 4-Bromofluorobenzene 0.136 99.9 83-134ug/gSurrogate: Dibromofluoromethane 0.124 91.0 78-124ug/gSurrogate: Toluene-d8 0.114 83.9 76-118ug/g
Page 9 of 10
Certificate of AnalysisClient:
Report Date: 19-Oct-2010Order Date:13-Oct-2010
Client PO: Project Description: 47880 HerongatePinchin Environmental Ltd. (Ottawa)
Order #: 1042087
Sample and QC Qualifiers NotesNone
Sample Data RevisionsNone
Work Order Revisions/Comments:
None
Other Report Notes:
MDL: Method Detection Limitn/a: not applicable
Source Result: Data used as source for matrix and duplicate samples%REC: Percent recovery.RPD: Relative percent difference.Soil results are reported on a dry weight basis when the units are denoted with 'dry'.Where %Solids is reported, moisture loss includes the loss of volatile hydrocarbons.
Page 10 of 10
Order Date: 19-Nov-2010 Report Date: 23-Nov-2010
Fax: (613) 592-5897Phone: (613) 592-3387
Client PO:
This Certificate of Analysis contains analytical data applicable to the following samples as submitted:
Custody: 80841
Attn: Ryan LaRondeKanata, ON K2K 3G4200-515 Legget Dr.
Certificate of Analysis
Paracel ID Client ID
Pinchin Environmental Ltd. (Ottawa)
Order #: 1047238
Project: 47880.002 Herongate
1047238-01 MW10-11047238-02 MW05-21047238-03 MW07-2
Approved By:Mark Foto, M.Sc. For Dale Robertson, BScLaboratory Director
Page 1 of 8
Any use of these results implies your agreement that our total liabilty in connection with this work, however arising shall be limited to the amount paid by you for this work, and that our employees or agents shall not under circumstances be liable to you in connection with this work
Certificate of AnalysisClient:
Report Date: 23-Nov-2010Order Date:19-Nov-2010
Client PO: Project Description: 47880.002 HerongatePinchin Environmental Ltd. (Ottawa)
Order #: 1047238
Analysis Summary Table
Analysis Method Reference/Description Extraction Date Analysis Date
EPA 624 - P&T GC-MS 19-Nov-10 23-Nov-10VOCs
Page 2 of 8
Certificate of AnalysisClient:
Report Date: 23-Nov-2010Order Date:19-Nov-2010
Client PO: Project Description: 47880.002 HerongatePinchin Environmental Ltd. (Ottawa)
Order #: 1047238
Client ID: MW10-1 MW05-2 MW07-2 -Sample Date: -19-Nov-1019-Nov-1019-Nov-10
1047238-01 1047238-02 1047238-03 -Sample ID:MDL/Units Water Water Water -
Volatiles
Benzene -<0.5<0.5<0.50.5 ug/L
Bromodichloromethane -<0.4<0.4<0.40.4 ug/L
Bromoform -<0.5<0.5<0.50.5 ug/L
Bromomethane -<0.7<0.7<0.70.7 ug/L
Carbon Tetrachloride -<0.5<0.5<0.50.5 ug/L
Chlorobenzene -<0.4<0.4<0.40.4 ug/L
Chloroethane -<1.0<1.0<1.01.0 ug/L
Chloroform -<0.5<0.51.20.5 ug/L
Chloromethane -<3.0<3.0<3.03.0 ug/L
Dibromochloromethane -<0.5<0.5<0.50.5 ug/L
1,2-Dibromoethane -<1.0<1.0<1.01.0 ug/L
1,2-Dichlorobenzene -<0.4<0.4<0.40.4 ug/L
1,3-Dichlorobenzene -<0.4<0.4<0.40.4 ug/L
1,4-Dichlorobenzene -<0.4<0.4<0.40.4 ug/L
1,1-Dichloroethane -<0.5<0.5<0.50.5 ug/L
1,2-Dichloroethane -<0.5<0.5<0.50.5 ug/L
1,1-Dichloroethylene -<0.5<0.5<0.50.5 ug/L
cis-1,2-Dichloroethylene -<0.4<0.4<0.40.4 ug/L
trans-1,2-Dichloroethylene -<1.0<1.0<1.01.0 ug/L
1,2-Dichloroethylene, total -<1.4<1.4<1.41.4 ug/L
1,2-Dichloropropane -<0.5<0.5<0.50.5 ug/L
cis-1,3-Dichloropropylene -<0.4<0.4<0.40.4 ug/L
trans-1,3-Dichloropropylene -<0.5<0.5<0.50.5 ug/L
1,3-Dichloropropene, total -<0.9<0.9<0.90.9 ug/L
Ethylbenzene -<0.5<0.5<0.50.5 ug/L
Methylene Chloride -<4.0<4.0<4.04.0 ug/L
Styrene -<0.4<0.4<0.40.4 ug/L
1,1,1,2-Tetrachloroethane -<0.5<0.5<0.50.5 ug/L
1,1,2,2-Tetrachloroethane -<0.6<0.6<0.60.6 ug/L
Tetrachloroethylene -6.16.84.60.5 ug/L
Toluene -1.5<0.5<0.50.5 ug/L
1,1,1-Trichloroethane -<0.4<0.4<0.40.4 ug/L
1,1,2-Trichloroethane -<0.6<0.6<0.60.6 ug/L
Page 3 of 8
Certificate of AnalysisClient:
Report Date: 23-Nov-2010Order Date:19-Nov-2010
Client PO: Project Description: 47880.002 HerongatePinchin Environmental Ltd. (Ottawa)
Order #: 1047238
Client ID: MW10-1 MW05-2 MW07-2 -Sample Date: -19-Nov-1019-Nov-1019-Nov-10
1047238-01 1047238-02 1047238-03 -Sample ID:MDL/Units Water Water Water -
Trichloroethylene -<0.4<0.4<0.40.4 ug/L
Trichlorofluoromethane -<1.0<1.0<1.01.0 ug/L
1,3,5-Trimethylbenzene -<0.5<0.5<0.50.5 ug/L
Vinyl chloride -<0.4<0.4<0.40.4 ug/L
m,p-Xylenes -<0.5<0.5<0.50.5 ug/L
o-Xylene -<0.5<0.5<0.50.5 ug/L
Xylenes, total -<1.0<1.0<1.01.0 ug/L
4-Bromofluorobenzene Surrogate 91.4% 91.6% 92.2% -
Dibromofluoromethane Surrogate 112% 109% 108% -
Toluene-d8 Surrogate 100% 100% 100% -
Page 4 of 8
Certificate of AnalysisClient:
Report Date: 23-Nov-2010Order Date:19-Nov-2010
Client PO: Project Description: 47880.002 HerongatePinchin Environmental Ltd. (Ottawa)
Order #: 1047238
Method Quality Control: Blank Analyte Result
ReportingLimit Units
SourceResult %REC
%RECLimit RPD
RPDLimit Notes
VolatilesBenzene ND 0.5 ug/LBromodichloromethane ND 0.4 ug/LBromoform ND 0.5 ug/LBromomethane ND 0.7 ug/LCarbon Tetrachloride ND 0.5 ug/LChlorobenzene ND 0.4 ug/LChloroethane ND 1.0 ug/LChloroform ND 0.5 ug/LChloromethane ND 3.0 ug/LDibromochloromethane ND 0.5 ug/L1,2-Dibromoethane ND 1.0 ug/L1,2-Dichlorobenzene ND 0.4 ug/L1,3-Dichlorobenzene ND 0.4 ug/L1,4-Dichlorobenzene ND 0.4 ug/L1,1-Dichloroethane ND 0.5 ug/L1,2-Dichloroethane ND 0.5 ug/L1,1-Dichloroethylene ND 0.5 ug/Lcis-1,2-Dichloroethylene ND 0.4 ug/Ltrans-1,2-Dichloroethylene ND 1.0 ug/L1,2-Dichloroethylene, total ND 1.4 ug/L1,2-Dichloropropane ND 0.5 ug/Lcis-1,3-Dichloropropylene ND 0.4 ug/Ltrans-1,3-Dichloropropylene ND 0.5 ug/L1,3-Dichloropropene, total ND 0.9 ug/LEthylbenzene ND 0.5 ug/LMethylene Chloride ND 4.0 ug/LStyrene ND 0.4 ug/L1,1,1,2-Tetrachloroethane ND 0.5 ug/L1,1,2,2-Tetrachloroethane ND 0.6 ug/LTetrachloroethylene ND 0.5 ug/LToluene ND 0.5 ug/L1,1,1-Trichloroethane ND 0.4 ug/L1,1,2-Trichloroethane ND 0.6 ug/LTrichloroethylene ND 0.4 ug/LTrichlorofluoromethane ND 1.0 ug/L1,3,5-Trimethylbenzene ND 0.5 ug/LVinyl chloride ND 0.4 ug/Lm,p-Xylenes ND 0.5 ug/Lo-Xylene ND 0.5 ug/LXylenes, total ND 1.0 ug/LSurrogate: 4-Bromofluorobenzene 29.5 92.3 83-134ug/LSurrogate: Dibromofluoromethane 33.6 105 78-124ug/LSurrogate: Toluene-d8 32.3 101 76-118ug/L
Page 5 of 8
Certificate of AnalysisClient:
Report Date: 23-Nov-2010Order Date:19-Nov-2010
Client PO: Project Description: 47880.002 HerongatePinchin Environmental Ltd. (Ottawa)
Order #: 1047238
Method Quality Control: Duplicate Analyte Result
ReportingLimit Units
SourceResult %REC
%RECLimit RPD
RPDLimit Notes
VolatilesBenzene ND 0.5 ug/L ND 20Bromodichloromethane 3.85 0.4 ug/L 3.21 2518.1Bromoform ND 0.5 ug/L ND 25Bromomethane ND 0.7 ug/L ND 25Carbon Tetrachloride ND 0.5 ug/L ND 25Chlorobenzene ND 0.4 ug/L ND 25Chloroethane ND 1.0 ug/L ND 25Chloroform 27.0 0.5 ug/L 24.3 1910.5Chloromethane ND 3.0 ug/L ND 25Dibromochloromethane ND 0.5 ug/L ND 251,2-Dibromoethane ND 1.0 ug/L ND 251,2-Dichlorobenzene ND 0.4 ug/L ND 251,3-Dichlorobenzene ND 0.4 ug/L ND 251,4-Dichlorobenzene ND 0.4 ug/L ND 251,1-Dichloroethane ND 0.5 ug/L ND 211,2-Dichloroethane ND 0.5 ug/L ND 251,1-Dichloroethylene ND 0.5 ug/L ND 21cis-1,2-Dichloroethylene ND 0.4 ug/L ND 20trans-1,2-Dichloroethylene ND 1.0 ug/L ND 251,2-Dichloropropane ND 0.5 ug/L ND 25cis-1,3-Dichloropropylene ND 0.4 ug/L ND 25trans-1,3-Dichloropropylene ND 0.5 ug/L ND 25Ethylbenzene ND 0.5 ug/L ND 35Methylene Chloride ND 4.0 ug/L ND 25Styrene ND 0.4 ug/L ND 251,1,1,2-Tetrachloroethane ND 0.5 ug/L ND 251,1,2,2-Tetrachloroethane ND 0.6 ug/L ND 25Tetrachloroethylene ND 0.5 ug/L ND 31Toluene ND 0.5 ug/L ND 301,1,1-Trichloroethane ND 0.4 ug/L ND 251,1,2-Trichloroethane ND 0.6 ug/L ND 25Trichloroethylene ND 0.4 ug/L ND 30Trichlorofluoromethane ND 1.0 ug/L ND 251,3,5-Trimethylbenzene ND 0.5 ug/L ND 20Vinyl chloride ND 0.4 ug/L ND 25m,p-Xylenes ND 0.5 ug/L ND 34o-Xylene ND 0.5 ug/L ND 32Surrogate: 4-Bromofluorobenzene 28.5 ug/L 89.0 83-134NDSurrogate: Dibromofluoromethane 31.7 ug/L 99.0 78-124NDSurrogate: Toluene-d8 30.9 ug/L 96.6 76-118ND
Page 6 of 8
Certificate of AnalysisClient:
Report Date: 23-Nov-2010Order Date:19-Nov-2010
Client PO: Project Description: 47880.002 HerongatePinchin Environmental Ltd. (Ottawa)
Order #: 1047238
Method Quality Control: Spike Analyte Result
ReportingLimit Units
SourceResult %REC
%RECLimit RPD
RPDLimit Notes
VolatilesBenzene 35.3 ND 88.2 55-1410.5 ug/LBromodichloromethane 33.3 ND 83.2 52-1390.4 ug/LBromoform 39.9 ND 99.7 52-1700.5 ug/LBromomethane 13.8 ND 34.5 32-1380.7 ug/LCarbon Tetrachloride 41.2 ND 103 49-1490.5 ug/LChlorobenzene 36.3 ND 90.8 64-1370.4 ug/LChloroethane 38.5 ND 96.4 39-1521.0 ug/LChloroform 31.9 ND 79.8 58-1380.5 ug/LChloromethane 23.2 ND 58.0 24-1633.0 ug/LDibromochloromethane 34.1 ND 85.4 61-1530.5 ug/L1,2-Dibromoethane 34.7 ND 86.8 61-1451.0 ug/L1,2-Dichlorobenzene 35.3 ND 88.2 60-1500.4 ug/L1,3-Dichlorobenzene 34.8 ND 87.1 62-1490.4 ug/L1,4-Dichlorobenzene 35.4 ND 88.6 63-1320.4 ug/L1,1-Dichloroethane 27.4 ND 68.5 51-1560.5 ug/L1,2-Dichloroethane 33.6 ND 84.0 50-1400.5 ug/L1,1-Dichloroethylene 29.7 ND 74.2 43-1530.5 ug/Lcis-1,2-Dichloroethylene 31.6 ND 79.0 58-1450.4 ug/Ltrans-1,2-Dichloroethylene 34.1 ND 85.2 51-1451.0 ug/L1,2-Dichloropropane 34.4 ND 86.1 56-1360.5 ug/Lcis-1,3-Dichloropropylene 28.4 ND 71.0 54-1410.4 ug/Ltrans-1,3-Dichloropropylene 26.0 ND 65.0 61-1400.5 ug/LEthylbenzene 37.3 ND 93.3 61-1390.5 ug/LMethylene Chloride 31.7 ND 79.3 58-1494.0 ug/LStyrene 37.8 ND 94.5 63-1430.4 ug/L1,1,1,2-Tetrachloroethane 36.0 ND 89.9 61-1480.5 ug/L1,1,2,2-Tetrachloroethane 31.8 ND 79.4 50-1570.6 ug/LTetrachloroethylene 35.4 ND 88.6 51-1450.5 ug/LToluene 31.4 ND 78.5 54-1360.5 ug/L1,1,1-Trichloroethane 31.2 ND 77.9 55-1400.4 ug/L1,1,2-Trichloroethane 33.8 ND 84.5 63-1440.6 ug/LTrichloroethylene 34.6 ND 86.6 52-1350.4 ug/LTrichlorofluoromethane 26.3 ND 65.8 37-1551.0 ug/L1,3,5-Trimethylbenzene 38.2 ND 95.4 61-1510.5 ug/LVinyl chloride 26.2 ND 65.6 31-1590.4 ug/Lm,p-Xylenes 71.2 ND 89.1 61-1390.5 ug/Lo-Xylene 36.7 ND 91.8 60-1420.5 ug/LSurrogate: 4-Bromofluorobenzene 29.8 93.2 83-134ug/LSurrogate: Dibromofluoromethane 33.2 104 78-124ug/LSurrogate: Toluene-d8 32.6 102 76-118ug/L
Page 7 of 8
Certificate of AnalysisClient:
Report Date: 23-Nov-2010Order Date:19-Nov-2010
Client PO: Project Description: 47880.002 HerongatePinchin Environmental Ltd. (Ottawa)
Order #: 1047238
Sample and QC Qualifiers NotesNone
Sample Data RevisionsNone
Work Order Revisions/Comments:
None
Other Report Notes:
MDL: Method Detection Limitn/a: not applicable
Source Result: Data used as source for matrix and duplicate samples%REC: Percent recovery.RPD: Relative percent difference.
Page 8 of 8
Order Date: 23-Feb-2011 Report Date: 28-Feb-2011
Fax: (613) 592-5897Phone: (613) 592-3387
Client PO:
This Certificate of Analysis contains analytical data applicable to the following samples as submitted:
Custody: 81479
Attn: Ryan LaRondeKanata, ON K2K 3G4200-515 Legget Dr.
Certificate of Analysis
Paracel ID Client ID
Pinchin Environmental Ltd. (Ottawa)
Order #: 1109093
Project: 47880.002 Heron
1109093-01 MW05-21109093-02 MW07-2
Approved By:Mark Foto, M.Sc. For Dale Robertson, BScLaboratory Director
Page 1 of 8
Any use of these results implies your agreement that our total liabilty in connection with this work, however arising shall be limited to the amount paid by you for this work, and that our employees or agents shall not under circumstances be liable to you in connection with this work
Certificate of AnalysisClient:
Report Date: 28-Feb-2011Order Date:23-Feb-2011
Client PO: Project Description: 47880.002 HeronPinchin Environmental Ltd. (Ottawa)
Order #: 1109093
Analysis Summary Table
Analysis Method Reference/Description Extraction Date Analysis Date
EPA 624 - P&T GC-MS 24-Feb-11 25-Feb-11VOCs
Page 2 of 8
Certificate of AnalysisClient:
Report Date: 28-Feb-2011Order Date:23-Feb-2011
Client PO: Project Description: 47880.002 HeronPinchin Environmental Ltd. (Ottawa)
Order #: 1109093
Client ID: MW05-2 MW07-2 - -Sample Date: --23-Feb-1123-Feb-11
1109093-01 1109093-02 - -Sample ID:MDL/Units Water Water - -
Volatiles
Benzene --<25.0 [1]<0.50.5 ug/L
Bromodichloromethane --<20.0 [1]<0.40.4 ug/L
Bromoform --<25.0 [1]<0.50.5 ug/L
Bromomethane --<35.0 [1]<0.70.7 ug/L
Carbon Tetrachloride --<25.0 [1]<0.50.5 ug/L
Chlorobenzene --<20.0 [1]<0.40.4 ug/L
Chloroethane --<50.0 [1]<1.01.0 ug/L
Chloroform --<25.0 [1]<0.50.5 ug/L
Chloromethane --<150 [1]<3.03.0 ug/L
Dibromochloromethane --<25.0 [1]<0.50.5 ug/L
1,2-Dibromoethane --<50.0 [1]<1.01.0 ug/L
1,2-Dichlorobenzene --<20.0 [1]<0.40.4 ug/L
1,3-Dichlorobenzene --<20.0 [1]<0.40.4 ug/L
1,4-Dichlorobenzene --<20.0 [1]<0.40.4 ug/L
1,1-Dichloroethane --<25.0 [1]<0.50.5 ug/L
1,2-Dichloroethane --<25.0 [1]<0.50.5 ug/L
1,1-Dichloroethylene --<25.0 [1]<0.50.5 ug/L
cis-1,2-Dichloroethylene --<20.0 [1]<0.40.4 ug/L
trans-1,2-Dichloroethylene --<50.0 [1]<1.01.0 ug/L
1,2-Dichloroethylene, total --<70.0 [1]<1.41.4 ug/L
1,2-Dichloropropane --<25.0 [1]<0.50.5 ug/L
cis-1,3-Dichloropropylene --<20.0 [1]<0.40.4 ug/L
trans-1,3-Dichloropropylene --<25.0 [1]<0.50.5 ug/L
1,3-Dichloropropene, total --<45.0 [1]<0.90.9 ug/L
Ethylbenzene --<25.0 [1]<0.50.5 ug/L
Methylene Chloride --<200 [1]<4.04.0 ug/L
Styrene --<20.0 [1]<0.40.4 ug/L
1,1,1,2-Tetrachloroethane --<25.0 [1]<0.50.5 ug/L
1,1,2,2-Tetrachloroethane --<30.0 [1]<0.60.6 ug/L
Tetrachloroethylene --<25.0 [1]3.20.5 ug/L
Toluene --<25.0 [1]<0.50.5 ug/L
1,1,1-Trichloroethane --<20.0 [1]<0.40.4 ug/L
1,1,2-Trichloroethane --<30.0 [1]<0.60.6 ug/L
Page 3 of 8
Certificate of AnalysisClient:
Report Date: 28-Feb-2011Order Date:23-Feb-2011
Client PO: Project Description: 47880.002 HeronPinchin Environmental Ltd. (Ottawa)
Order #: 1109093
Client ID: MW05-2 MW07-2 - -Sample Date: --23-Feb-1123-Feb-11
1109093-01 1109093-02 - -Sample ID:MDL/Units Water Water - -
Trichloroethylene --<20.0 [1]<0.40.4 ug/L
Trichlorofluoromethane --<50.0 [1]<1.01.0 ug/L
1,3,5-Trimethylbenzene --<25.0 [1]<0.50.5 ug/L
Vinyl chloride --<20.0 [1]<0.40.4 ug/L
m,p-Xylenes --<25.0 [1]<0.50.5 ug/L
o-Xylene --<25.0 [1]<0.50.5 ug/L
Xylenes, total --<50.0 [1]<1.01.0 ug/L
4-Bromofluorobenzene Surrogate 108% 109% [1] - -
Dibromofluoromethane Surrogate 81.6% 86.6% [1] - -
Toluene-d8 Surrogate 110% 113% [1] - -
Page 4 of 8
Certificate of AnalysisClient:
Report Date: 28-Feb-2011Order Date:23-Feb-2011
Client PO: Project Description: 47880.002 HeronPinchin Environmental Ltd. (Ottawa)
Order #: 1109093
Method Quality Control: Blank Analyte Result
ReportingLimit Units
SourceResult %REC
%RECLimit RPD
RPDLimit Notes
VolatilesBenzene ND 0.5 ug/LBromodichloromethane ND 0.4 ug/LBromoform ND 0.5 ug/LBromomethane ND 0.7 ug/LCarbon Tetrachloride ND 0.5 ug/LChlorobenzene ND 0.4 ug/LChloroethane ND 1.0 ug/LChloroform ND 0.5 ug/LChloromethane ND 3.0 ug/LDibromochloromethane ND 0.5 ug/L1,2-Dibromoethane ND 1.0 ug/L1,2-Dichlorobenzene ND 0.4 ug/L1,3-Dichlorobenzene ND 0.4 ug/L1,4-Dichlorobenzene ND 0.4 ug/L1,1-Dichloroethane ND 0.5 ug/L1,2-Dichloroethane ND 0.5 ug/L1,1-Dichloroethylene ND 0.5 ug/Lcis-1,2-Dichloroethylene ND 0.4 ug/Ltrans-1,2-Dichloroethylene ND 1.0 ug/L1,2-Dichloroethylene, total ND 1.4 ug/L1,2-Dichloropropane ND 0.5 ug/Lcis-1,3-Dichloropropylene ND 0.4 ug/Ltrans-1,3-Dichloropropylene ND 0.5 ug/L1,3-Dichloropropene, total ND 0.9 ug/LEthylbenzene ND 0.5 ug/LMethylene Chloride ND 4.0 ug/LStyrene ND 0.4 ug/L1,1,1,2-Tetrachloroethane ND 0.5 ug/L1,1,2,2-Tetrachloroethane ND 0.6 ug/LTetrachloroethylene ND 0.5 ug/LToluene ND 0.5 ug/L1,1,1-Trichloroethane ND 0.4 ug/L1,1,2-Trichloroethane ND 0.6 ug/LTrichloroethylene ND 0.4 ug/LTrichlorofluoromethane ND 1.0 ug/L1,3,5-Trimethylbenzene ND 0.5 ug/LVinyl chloride ND 0.4 ug/Lm,p-Xylenes ND 0.5 ug/Lo-Xylene ND 0.5 ug/LXylenes, total ND 1.0 ug/LSurrogate: 4-Bromofluorobenzene 35.1 110 83-134ug/LSurrogate: Dibromofluoromethane 27.4 85.8 78-124ug/LSurrogate: Toluene-d8 36.1 113 76-118ug/L
Page 5 of 8
Certificate of AnalysisClient:
Report Date: 28-Feb-2011Order Date:23-Feb-2011
Client PO: Project Description: 47880.002 HeronPinchin Environmental Ltd. (Ottawa)
Order #: 1109093
Method Quality Control: Duplicate Analyte Result
ReportingLimit Units
SourceResult %REC
%RECLimit RPD
RPDLimit Notes
VolatilesBenzene ND 0.5 ug/L ND 20Bromodichloromethane 3.10 0.4 ug/L 5.66 25 QR-0458.4Bromoform ND 0.5 ug/L ND 25Bromomethane ND 0.7 ug/L ND 25Carbon Tetrachloride ND 0.5 ug/L ND 25Chlorobenzene ND 0.4 ug/L ND 25Chloroethane ND 1.0 ug/L ND 25Chloroform 4.20 0.5 ug/L 3.63 1914.6Chloromethane ND 3.0 ug/L ND 25Dibromochloromethane 1.73 0.5 ug/L 1.50 2514.21,2-Dibromoethane ND 1.0 ug/L ND 251,2-Dichlorobenzene ND 0.4 ug/L ND 251,3-Dichlorobenzene ND 0.4 ug/L ND 251,4-Dichlorobenzene ND 0.4 ug/L ND 251,1-Dichloroethane ND 0.5 ug/L ND 211,2-Dichloroethane ND 0.5 ug/L ND 251,1-Dichloroethylene ND 0.5 ug/L ND 21cis-1,2-Dichloroethylene ND 0.4 ug/L ND 20trans-1,2-Dichloroethylene ND 1.0 ug/L ND 251,2-Dichloropropane ND 0.5 ug/L ND 25cis-1,3-Dichloropropylene ND 0.4 ug/L ND 25trans-1,3-Dichloropropylene ND 0.5 ug/L ND 25Ethylbenzene ND 0.5 ug/L ND 35Methylene Chloride ND 4.0 ug/L ND 25Styrene ND 0.4 ug/L ND 251,1,1,2-Tetrachloroethane ND 0.5 ug/L ND 251,1,2,2-Tetrachloroethane ND 0.6 ug/L ND 25Tetrachloroethylene ND 0.5 ug/L ND 31Toluene ND 0.5 ug/L ND 301,1,1-Trichloroethane ND 0.4 ug/L ND 251,1,2-Trichloroethane ND 0.6 ug/L ND 25Trichloroethylene ND 0.4 ug/L ND 30Trichlorofluoromethane ND 1.0 ug/L ND 251,3,5-Trimethylbenzene ND 0.5 ug/L ND 20Vinyl chloride ND 0.4 ug/L ND 25m,p-Xylenes ND 0.5 ug/L ND 34o-Xylene ND 0.5 ug/L ND 32Surrogate: 4-Bromofluorobenzene 35.5 ug/L 111 83-134NDSurrogate: Dibromofluoromethane 36.9 ug/L 115 78-124NDSurrogate: Toluene-d8 35.5 ug/L 111 76-118ND
Page 6 of 8
Certificate of AnalysisClient:
Report Date: 28-Feb-2011Order Date:23-Feb-2011
Client PO: Project Description: 47880.002 HeronPinchin Environmental Ltd. (Ottawa)
Order #: 1109093
Method Quality Control: Spike Analyte Result
ReportingLimit Units
SourceResult %REC
%RECLimit RPD
RPDLimit Notes
VolatilesBenzene 26.1 ND 65.2 55-1410.5 ug/LBromodichloromethane 33.3 ND 83.2 52-1390.4 ug/LBromoform 30.2 ND 75.6 52-1700.5 ug/LBromomethane 23.3 ND 58.3 32-1380.7 ug/LCarbon Tetrachloride 23.8 ND 59.6 49-1490.5 ug/LChlorobenzene 31.2 ND 78.1 64-1370.4 ug/LChloroethane 23.3 ND 58.3 39-1521.0 ug/LChloroform 30.4 ND 76.0 58-1380.5 ug/LChloromethane 28.3 ND 70.8 24-1633.0 ug/LDibromochloromethane 32.2 ND 80.5 61-1530.5 ug/L1,2-Dibromoethane 32.6 ND 81.4 61-1451.0 ug/L1,2-Dichlorobenzene 36.0 ND 90.0 60-1500.4 ug/L1,3-Dichlorobenzene 35.8 ND 89.5 62-1490.4 ug/L1,4-Dichlorobenzene 34.7 ND 86.7 63-1320.4 ug/L1,1-Dichloroethane 29.7 ND 74.3 51-1560.5 ug/L1,2-Dichloroethane 26.5 ND 66.2 50-1400.5 ug/L1,1-Dichloroethylene 28.1 ND 70.2 43-1530.5 ug/Lcis-1,2-Dichloroethylene 27.8 ND 69.5 58-1450.4 ug/Ltrans-1,2-Dichloroethylene 27.7 ND 69.2 51-1451.0 ug/L1,2-Dichloropropane 35.4 ND 88.6 56-1360.5 ug/Lcis-1,3-Dichloropropylene 22.6 ND 56.5 54-1410.4 ug/Ltrans-1,3-Dichloropropylene 33.6 ND 84.0 61-1400.5 ug/LEthylbenzene 30.5 ND 76.3 61-1390.5 ug/LMethylene Chloride 27.1 ND 67.8 58-1494.0 ug/LStyrene 31.5 ND 78.6 63-1430.4 ug/L1,1,1,2-Tetrachloroethane 32.0 ND 80.1 61-1480.5 ug/L1,1,2,2-Tetrachloroethane 32.2 ND 80.4 50-1570.6 ug/LTetrachloroethylene 24.2 ND 60.4 51-1450.5 ug/LToluene 30.9 ND 77.2 54-1360.5 ug/L1,1,1-Trichloroethane 25.4 ND 63.4 55-1400.4 ug/L1,1,2-Trichloroethane 38.5 ND 96.4 63-1440.6 ug/LTrichloroethylene 26.2 ND 65.5 52-1350.4 ug/LTrichlorofluoromethane 16.5 ND 41.2 37-1551.0 ug/L1,3,5-Trimethylbenzene 38.7 ND 96.6 61-1510.5 ug/LVinyl chloride 27.3 ND 68.2 31-1590.4 ug/Lm,p-Xylenes 59.7 ND 74.6 61-1390.5 ug/Lo-Xylene 30.0 ND 75.1 60-1420.5 ug/LSurrogate: 4-Bromofluorobenzene 32.3 101 83-134ug/LSurrogate: Dibromofluoromethane 32.6 102 78-124ug/LSurrogate: Toluene-d8 28.8 90.1 76-118ug/L
Page 7 of 8
Certificate of AnalysisClient:
Report Date: 28-Feb-2011Order Date:23-Feb-2011
Client PO: Project Description: 47880.002 HeronPinchin Environmental Ltd. (Ottawa)
Order #: 1109093
Sample and QC Qualifiers Notes1- GEN02 : Elevated Reporting Limit due to matrix interference.
2- QR-04 : Duplicate results exceeds RPD limits due to non-homogeneous matrix.
Sample Data RevisionsNone
Work Order Revisions/Comments:
None
Other Report Notes:
MDL: Method Detection Limitn/a: not applicable
Source Result: Data used as source for matrix and duplicate samples%REC: Percent recovery.RPD: Relative percent difference.
Page 8 of 8
Order Date: 23-Feb-2011 Report Date: 28-Feb-2011
Fax: (613) 592-5897Phone: (613) 592-3387
Client PO:
This Certificate of Analysis contains analytical data applicable to the following samples as submitted:
Custody: 81480
Attn: Ryan LaRondeKanata, ON K2K 3G4200-515 Legget Dr.
Certificate of Analysis
Paracel ID Client ID
Pinchin Environmental Ltd. (Ottawa)
Order #: 1109094
Project: 47880.002 Heron
1109094-01 MW10-1
Approved By:Mark Foto, M.Sc. For Dale Robertson, BScLaboratory Director
Page 1 of 8
Any use of these results implies your agreement that our total liabilty in connection with this work, however arising shall be limited to the amount paid by you for this work, and that our employees or agents shall not under circumstances be liable to you in connection with this work
Certificate of AnalysisClient:
Report Date: 28-Feb-2011Order Date:23-Feb-2011
Client PO: Project Description: 47880.002 HeronPinchin Environmental Ltd. (Ottawa)
Order #: 1109094
Analysis Summary Table
Analysis Method Reference/Description Extraction Date Analysis Date
EPA 624 - P&T GC-MS 24-Feb-11 25-Feb-11VOCs
Page 2 of 8
Certificate of AnalysisClient:
Report Date: 28-Feb-2011Order Date:23-Feb-2011
Client PO: Project Description: 47880.002 HeronPinchin Environmental Ltd. (Ottawa)
Order #: 1109094
Client ID: MW10-1 - - -Sample Date: ---23-Feb-11
1109094-01 - - -Sample ID:MDL/Units Water - - -
Volatiles
Benzene ---<25.0 [1]0.5 ug/L
Bromodichloromethane ---<20.0 [1]0.4 ug/L
Bromoform ---<25.0 [1]0.5 ug/L
Bromomethane ---<35.0 [1]0.7 ug/L
Carbon Tetrachloride ---<25.0 [1]0.5 ug/L
Chlorobenzene ---<20.0 [1]0.4 ug/L
Chloroethane ---<50.0 [1]1.0 ug/L
Chloroform ---<25.0 [1]0.5 ug/L
Chloromethane ---<150 [1]3.0 ug/L
Dibromochloromethane ---<25.0 [1]0.5 ug/L
1,2-Dibromoethane ---<50.0 [1]1.0 ug/L
1,2-Dichlorobenzene ---<20.0 [1]0.4 ug/L
1,3-Dichlorobenzene ---<20.0 [1]0.4 ug/L
1,4-Dichlorobenzene ---<20.0 [1]0.4 ug/L
1,1-Dichloroethane ---<25.0 [1]0.5 ug/L
1,2-Dichloroethane ---<25.0 [1]0.5 ug/L
1,1-Dichloroethylene ---<25.0 [1]0.5 ug/L
cis-1,2-Dichloroethylene ---<20.0 [1]0.4 ug/L
trans-1,2-Dichloroethylene ---<50.0 [1]1.0 ug/L
1,2-Dichloroethylene, total ---<70.0 [1]1.4 ug/L
1,2-Dichloropropane ---<25.0 [1]0.5 ug/L
cis-1,3-Dichloropropylene ---<20.0 [1]0.4 ug/L
trans-1,3-Dichloropropylene ---<25.0 [1]0.5 ug/L
1,3-Dichloropropene, total ---<45.0 [1]0.9 ug/L
Ethylbenzene ---<25.0 [1]0.5 ug/L
Methylene Chloride ---<200 [1]4.0 ug/L
Styrene ---<20.0 [1]0.4 ug/L
1,1,1,2-Tetrachloroethane ---<25.0 [1]0.5 ug/L
1,1,2,2-Tetrachloroethane ---<30.0 [1]0.6 ug/L
Tetrachloroethylene ---<25.0 [1]0.5 ug/L
Toluene ---<25.0 [1]0.5 ug/L
1,1,1-Trichloroethane ---<20.0 [1]0.4 ug/L
1,1,2-Trichloroethane ---<30.0 [1]0.6 ug/L
Page 3 of 8
Certificate of AnalysisClient:
Report Date: 28-Feb-2011Order Date:23-Feb-2011
Client PO: Project Description: 47880.002 HeronPinchin Environmental Ltd. (Ottawa)
Order #: 1109094
Client ID: MW10-1 - - -Sample Date: ---23-Feb-11
1109094-01 - - -Sample ID:MDL/Units Water - - -
Trichloroethylene ---<20.0 [1]0.4 ug/L
Trichlorofluoromethane ---<50.0 [1]1.0 ug/L
1,3,5-Trimethylbenzene ---<25.0 [1]0.5 ug/L
Vinyl chloride ---<20.0 [1]0.4 ug/L
m,p-Xylenes ---<25.0 [1]0.5 ug/L
o-Xylene ---<25.0 [1]0.5 ug/L
Xylenes, total ---<50.0 [1]1.0 ug/L
4-Bromofluorobenzene Surrogate 108% [1] - - -
Dibromofluoromethane Surrogate 88.8% [1] - - -
Toluene-d8 Surrogate 112% [1] - - -
Page 4 of 8
Certificate of AnalysisClient:
Report Date: 28-Feb-2011Order Date:23-Feb-2011
Client PO: Project Description: 47880.002 HeronPinchin Environmental Ltd. (Ottawa)
Order #: 1109094
Method Quality Control: Blank Analyte Result
ReportingLimit Units
SourceResult %REC
%RECLimit RPD
RPDLimit Notes
VolatilesBenzene ND 0.5 ug/LBromodichloromethane ND 0.4 ug/LBromoform ND 0.5 ug/LBromomethane ND 0.7 ug/LCarbon Tetrachloride ND 0.5 ug/LChlorobenzene ND 0.4 ug/LChloroethane ND 1.0 ug/LChloroform ND 0.5 ug/LChloromethane ND 3.0 ug/LDibromochloromethane ND 0.5 ug/L1,2-Dibromoethane ND 1.0 ug/L1,2-Dichlorobenzene ND 0.4 ug/L1,3-Dichlorobenzene ND 0.4 ug/L1,4-Dichlorobenzene ND 0.4 ug/L1,1-Dichloroethane ND 0.5 ug/L1,2-Dichloroethane ND 0.5 ug/L1,1-Dichloroethylene ND 0.5 ug/Lcis-1,2-Dichloroethylene ND 0.4 ug/Ltrans-1,2-Dichloroethylene ND 1.0 ug/L1,2-Dichloroethylene, total ND 1.4 ug/L1,2-Dichloropropane ND 0.5 ug/Lcis-1,3-Dichloropropylene ND 0.4 ug/Ltrans-1,3-Dichloropropylene ND 0.5 ug/L1,3-Dichloropropene, total ND 0.9 ug/LEthylbenzene ND 0.5 ug/LMethylene Chloride ND 4.0 ug/LStyrene ND 0.4 ug/L1,1,1,2-Tetrachloroethane ND 0.5 ug/L1,1,2,2-Tetrachloroethane ND 0.6 ug/LTetrachloroethylene ND 0.5 ug/LToluene ND 0.5 ug/L1,1,1-Trichloroethane ND 0.4 ug/L1,1,2-Trichloroethane ND 0.6 ug/LTrichloroethylene ND 0.4 ug/LTrichlorofluoromethane ND 1.0 ug/L1,3,5-Trimethylbenzene ND 0.5 ug/LVinyl chloride ND 0.4 ug/Lm,p-Xylenes ND 0.5 ug/Lo-Xylene ND 0.5 ug/LXylenes, total ND 1.0 ug/LSurrogate: 4-Bromofluorobenzene 35.1 110 83-134ug/LSurrogate: Dibromofluoromethane 27.4 85.8 78-124ug/LSurrogate: Toluene-d8 36.1 113 76-118ug/L
Page 5 of 8
Certificate of AnalysisClient:
Report Date: 28-Feb-2011Order Date:23-Feb-2011
Client PO: Project Description: 47880.002 HeronPinchin Environmental Ltd. (Ottawa)
Order #: 1109094
Method Quality Control: Duplicate Analyte Result
ReportingLimit Units
SourceResult %REC
%RECLimit RPD
RPDLimit Notes
VolatilesBenzene ND 0.5 ug/L ND 20Bromodichloromethane 3.10 0.4 ug/L 5.66 25 QR-0458.4Bromoform ND 0.5 ug/L ND 25Bromomethane ND 0.7 ug/L ND 25Carbon Tetrachloride ND 0.5 ug/L ND 25Chlorobenzene ND 0.4 ug/L ND 25Chloroethane ND 1.0 ug/L ND 25Chloroform 4.20 0.5 ug/L 3.63 1914.6Chloromethane ND 3.0 ug/L ND 25Dibromochloromethane 1.73 0.5 ug/L 1.50 2514.21,2-Dibromoethane ND 1.0 ug/L ND 251,2-Dichlorobenzene ND 0.4 ug/L ND 251,3-Dichlorobenzene ND 0.4 ug/L ND 251,4-Dichlorobenzene ND 0.4 ug/L ND 251,1-Dichloroethane ND 0.5 ug/L ND 211,2-Dichloroethane ND 0.5 ug/L ND 251,1-Dichloroethylene ND 0.5 ug/L ND 21cis-1,2-Dichloroethylene ND 0.4 ug/L ND 20trans-1,2-Dichloroethylene ND 1.0 ug/L ND 251,2-Dichloropropane ND 0.5 ug/L ND 25cis-1,3-Dichloropropylene ND 0.4 ug/L ND 25trans-1,3-Dichloropropylene ND 0.5 ug/L ND 25Ethylbenzene ND 0.5 ug/L ND 35Methylene Chloride ND 4.0 ug/L ND 25Styrene ND 0.4 ug/L ND 251,1,1,2-Tetrachloroethane ND 0.5 ug/L ND 251,1,2,2-Tetrachloroethane ND 0.6 ug/L ND 25Tetrachloroethylene ND 0.5 ug/L ND 31Toluene ND 0.5 ug/L ND 301,1,1-Trichloroethane ND 0.4 ug/L ND 251,1,2-Trichloroethane ND 0.6 ug/L ND 25Trichloroethylene ND 0.4 ug/L ND 30Trichlorofluoromethane ND 1.0 ug/L ND 251,3,5-Trimethylbenzene ND 0.5 ug/L ND 20Vinyl chloride ND 0.4 ug/L ND 25m,p-Xylenes ND 0.5 ug/L ND 34o-Xylene ND 0.5 ug/L ND 32Surrogate: 4-Bromofluorobenzene 35.5 ug/L 111 83-134NDSurrogate: Dibromofluoromethane 36.9 ug/L 115 78-124NDSurrogate: Toluene-d8 35.5 ug/L 111 76-118ND
Page 6 of 8
Certificate of AnalysisClient:
Report Date: 28-Feb-2011Order Date:23-Feb-2011
Client PO: Project Description: 47880.002 HeronPinchin Environmental Ltd. (Ottawa)
Order #: 1109094
Method Quality Control: Spike Analyte Result
ReportingLimit Units
SourceResult %REC
%RECLimit RPD
RPDLimit Notes
VolatilesBenzene 26.1 ND 65.2 55-1410.5 ug/LBromodichloromethane 33.3 ND 83.2 52-1390.4 ug/LBromoform 30.2 ND 75.6 52-1700.5 ug/LBromomethane 23.3 ND 58.3 32-1380.7 ug/LCarbon Tetrachloride 23.8 ND 59.6 49-1490.5 ug/LChlorobenzene 31.2 ND 78.1 64-1370.4 ug/LChloroethane 23.3 ND 58.3 39-1521.0 ug/LChloroform 30.4 ND 76.0 58-1380.5 ug/LChloromethane 28.3 ND 70.8 24-1633.0 ug/LDibromochloromethane 32.2 ND 80.5 61-1530.5 ug/L1,2-Dibromoethane 32.6 ND 81.4 61-1451.0 ug/L1,2-Dichlorobenzene 36.0 ND 90.0 60-1500.4 ug/L1,3-Dichlorobenzene 35.8 ND 89.5 62-1490.4 ug/L1,4-Dichlorobenzene 34.7 ND 86.7 63-1320.4 ug/L1,1-Dichloroethane 29.7 ND 74.3 51-1560.5 ug/L1,2-Dichloroethane 26.5 ND 66.2 50-1400.5 ug/L1,1-Dichloroethylene 28.1 ND 70.2 43-1530.5 ug/Lcis-1,2-Dichloroethylene 27.8 ND 69.5 58-1450.4 ug/Ltrans-1,2-Dichloroethylene 27.7 ND 69.2 51-1451.0 ug/L1,2-Dichloropropane 35.4 ND 88.6 56-1360.5 ug/Lcis-1,3-Dichloropropylene 22.6 ND 56.5 54-1410.4 ug/Ltrans-1,3-Dichloropropylene 33.6 ND 84.0 61-1400.5 ug/LEthylbenzene 30.5 ND 76.3 61-1390.5 ug/LMethylene Chloride 27.1 ND 67.8 58-1494.0 ug/LStyrene 31.5 ND 78.6 63-1430.4 ug/L1,1,1,2-Tetrachloroethane 32.0 ND 80.1 61-1480.5 ug/L1,1,2,2-Tetrachloroethane 32.2 ND 80.4 50-1570.6 ug/LTetrachloroethylene 24.2 ND 60.4 51-1450.5 ug/LToluene 30.9 ND 77.2 54-1360.5 ug/L1,1,1-Trichloroethane 25.4 ND 63.4 55-1400.4 ug/L1,1,2-Trichloroethane 38.5 ND 96.4 63-1440.6 ug/LTrichloroethylene 26.2 ND 65.5 52-1350.4 ug/LTrichlorofluoromethane 16.5 ND 41.2 37-1551.0 ug/L1,3,5-Trimethylbenzene 38.7 ND 96.6 61-1510.5 ug/LVinyl chloride 27.3 ND 68.2 31-1590.4 ug/Lm,p-Xylenes 59.7 ND 74.6 61-1390.5 ug/Lo-Xylene 30.0 ND 75.1 60-1420.5 ug/LSurrogate: 4-Bromofluorobenzene 32.3 101 83-134ug/LSurrogate: Dibromofluoromethane 32.6 102 78-124ug/LSurrogate: Toluene-d8 28.8 90.1 76-118ug/L
Page 7 of 8
Certificate of AnalysisClient:
Report Date: 28-Feb-2011Order Date:23-Feb-2011
Client PO: Project Description: 47880.002 HeronPinchin Environmental Ltd. (Ottawa)
Order #: 1109094
Sample and QC Qualifiers Notes1- GEN02 : Elevated Reporting Limit due to matrix interference.
2- QR-04 : Duplicate results exceeds RPD limits due to non-homogeneous matrix.
Sample Data RevisionsNone
Work Order Revisions/Comments:
None
Other Report Notes:
MDL: Method Detection Limitn/a: not applicable
Source Result: Data used as source for matrix and duplicate samples%REC: Percent recovery.RPD: Relative percent difference.
Page 8 of 8