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California Environmental Protection Agency Department of Toxic Substances Control Hazardous Materials Laboratory (Inorganic Section) 2151 Berkeley Way, Berkeley, CA 94704 Phone: (510) 540-3003 or (ATSS) 571-3003 Collector's Name: Site of Sampling: DAN ZIARLOWSKI/ESS LAVA CAP MINE 14501 LAVA CAP MINE NEVADA CITY 95959 RECORDS CTR 4112-00006 HML f: 970U24 tc 970029 SOMSDocID 88217743 Auth. NO.: EMM3306 Activity I 8MB Date Collected:|D7/08/97 Date Received: 07/11/09 Analytical Procedure: EPA-SW 846 Method: Samples are digested with 1:1 EN03 (and 30% H202, and 1:1 HCl, if applicable) over a hot plate. Digests are cooled, filtered and made to final volume with deionized E2O. Metal analysis of the digests is by ICPAES (EPA #6010). Units are Big/kg. 3050* for solids; 3010 for liquids; 3005 for clean vater. HML Number: Collector's Sample No.: Sample Type: As-Arsenic Ba-Barium Be-Beryllium Cd-Cadmium Co-Cobalt Cr-Chromium Cu-Copper Mo-Molybdenum Ni-Nickel Pb-Lead Se-Selenium Tl-Thallium V-Vanadium Zn-Zinc 970028 WETLAND-01 SEDIMENT 1750 68.3 0.18 0.65 8.79 <1.60 15.9 <1.50 6.04 5.16 <3.00 <6.00 4.94 56.3 970029 WETLAND-08 SEDIMENT 264 431 0.79 1.10 14.4 26.4 57.9 <3.75 15.2 16.8 <7.50 <15.0 76.3 59.3 Notes: < » below detection limit of method. ICP Analyst Merlyn Jah. Chemist's Signature Fatima Hussain, Chemist Date

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California Environmental Protection AgencyDepartment of Toxic Substances ControlHazardous Materials Laboratory (Inorganic Section)2151 Berkeley Way, Berkeley, CA 94704

Phone: (510) 540-3003 or (ATSS) 571-3003

Collector's Name:Site of Sampling:

DAN ZIARLOWSKI/ESSLAVA CAP MINE14501 LAVA CAP MINENEVADA CITY 95959

RECORDS CTR

4112-00006HML f: 970U24 tc

970029

SOMSDocID 88217743

Auth. NO.: EMM3306Activity I 8MBDate Collected:|D7/08/97Date Received: 07/11/09

AnalyticalProcedure:EPA-SW 846

Method:

Samples are digested with 1:1 EN03 (and 30% H202, and 1:1 HCl,if applicable) over a hot plate. Digests are cooled, filteredand made to final volume with deionized E2O. Metal analysis ofthe digests is by ICPAES (EPA #6010). Units are Big/kg.

3050* for solids; 3010 for liquids; 3005 for clean vater.

HML Number:Collector'sSample No.:Sample Type:

As-ArsenicBa-BariumBe-BerylliumCd-CadmiumCo-CobaltCr-ChromiumCu-CopperMo-MolybdenumNi-NickelPb-LeadSe-SeleniumTl-ThalliumV-VanadiumZn-Zinc

970028

WETLAND-01SEDIMENT

175068.30.180.658.79<1.6015.9<1.506.045.16<3.00<6.004.9456.3

970029

WETLAND-08SEDIMENT

2644310.791.1014.426.457.9

<3.7515.216.8

<7.50<15.076.359.3

Notes: < » below detection limit of method.

ICP AnalystMerlyn

Jah.Chemist's SignatureFatima Hussain, Chemist

Date

California Department of I oxic Substances ControlHazardous Materials LaboratoryInorganic Section — ... . -» . . ——

Quality Assurance Summary for ICP

HML Number:to

9/0022970029•

Element

As-ArsenicBa-BariumBe-BerylliumCd-CadmiumCo-CobaltCr-ChromiumCu-CopperMo-MolybdenumNi-NickelPb-LeadSe-SeleniumTI-ThalliumV-VanadiumZn-Zinc

Element

As-ArsenicBa-BariumBe-BerylliumCd-CadmiumCo-CobaltCr-ChromiumCu-CopperMo-MolybdenumNi-NickelPb-LeadSe-SelentumTI-ThalliumV-VanadiumZn-Zinc

HML Soil QC Sample

mg/kg

found

67.748.322.426.721.864.937.831.037.434.274.5132

42.949.1

known

63.344.721.525.520.759.637.730.335.431.072.8125

40.946.3

%

107108104105105109100102106110102106105106

HML Liquid QC Sample

mg/kg

found known %

MethodBlank

mg/L

<0.10< 0.005<0.003<0.009<0.05<0.08<0.05<0.08<0.05<0.10<0.15<0.30<0.06<0.05

ReagentBlank

mg/L<0.10< 0.005<0.003< 0.009<0.05<0.08<0.05' <0.08<0.05<0.10<0.15<0.30<0.06<0.05

Calibration VerificationStandard

mg/L

found

10.610.12.0310.510.610.410.210.310.610.510.210.510.310.5

known

10.010.02.0010.010.010.010.010.010.010.010.010.010.010.0

%

106101102105106104102103106105102105103105

Inorganic VenturesReference Standard

mg/Lfound

1.061.010.201.041.031.061.011.011.051.021.041.041.021.03

known

1.001.000.201.001.001.001.00.00.00.00.00.00.00.00

%

106101100104

103

106101101105102104104102103

Duplicate Spiked Sample

Spike Results mg/kg

A:

511528102485494524563473517569509478512605

B:

528550104501511543562490537554521492530618

RPD

3.854.411.943.253.733.590.963.533.832.841.942.893.632.87

Duplicate Spiked Sample

Spike Results mg/kg

A: B: RPD

^

HML No.: 970020

UnspikedResult(mg/kg}

<5.0039.80.320.777.4331.840.0<3.7531.134.8<7.50<15.025.189.1

HML No.:

UnspikedResult(mg/kg)

^7^

SpikeAdded(mg/kgl

500500100500500500500500500500500500500500

SpikeAdded(mg/kg)

s *

Matrix: SEDIMENT

% Recovery

A:

10297.6102

96.897.398.4105

94,697.2107102

95.697.4103

B:

106102104100101102104

98.0101104104

98.4101106

Matrix:

% Recovery

A: B:

ICP Analyst's Signature:Chemist: Fatima HussaiDate Analyzed: 07/15/97

Milad S. Iskander, Supervi Date:

State if California-California Environmental Protection Agency Oapartmant of Toxic Substances ControlHazardous Materials Laboratory

HAZARDOUS MATERIALSSAMPLE ANALYSIS REQUEST

1. Authorization Number

o To2. Page

of

3. Requester:Address (To Receive Results):

4. Phone )*-Sf - 5. Priority Level: 1

a. Authorized by

6. Date Sampled •j-.g- 7. Time Sampled Hours

9. Activity. Q SEB Q FPB FMB HQ OTHER

8. Codes (fill in all applicable codes)

a.STC

10. SAMPLING LOCATION

b. Site

a. EPA ID No.

c. Address.

11. SAMPLES

a. ID

9lrMt

b. Collector's No.

/ L

H

c. Lab No.

MlCrr?J

Dty

Sampled. Type

Zip

Container

g. County

e. Type f. Size\ L,

g. Field Information

12. ANALYSIS REQUESTED

b.Scan

c. r~\ Metals(Spec)

d.

f. D VOA-8020

g. D VOA-H/S .

h. Q VOA-8240

i. n VOA-8260

FlashPoint

m.Q C1 -Pes-ticides

n. OP-Pes-ticides

j. SVO-8270

VOA-8010Diesel/

k. [J Gasoline

o.Q

P.D

q.Q

13. SPECIAL REMARKS:

MMM/Trtt* tncluuv* O«M

16. LAB REMARKS:

<Fomi»rlv OHS 8002»Oriflirnl-Lib • Ouolicat>-Fil« • Triplic«te-l>Mp«ctor NLY (HMU

•*>

4112-00006California Department of Toxic Substances ControlHazardous Materials Laboratory2151 Berkeley Way, Berkeley, Ca. 94704Tel No. (510) 540-3003

HMU;970022tp:970029

Date Sampled;07/08/97Date Recieved;07/11/97

LABORATORY REPORT

Collector's Name: Dan ZiarkowskiLocation: Lava Cap Mine

14501 Lava Cap Mine Rd.Nevada Citv 95959

Activity: 8MBCollector's *;LL797-Ol

to:Wetland-02Authorization*:HMN3306

AnalyticalProcedure:

Samples were extracted with 0.2M citrate buffer atpH 5 for 48 hours. The extracts were centrifucred and filtered.Analysis is done bv ICPAES. Results in rog/L,

Extraction: HML Method #910.

Analysis: EPA Method #6010A.

Analysis Results:

HMLNo.

970028961413

Collector'sSample No.

Wetland-01Wetland-02

Type ofPbSample

SedimentSediment

As

2437.37

Signatures:

Fatima HussainAnalyst

Datfe DateSupervisor

California Department of Toxic Substances ControlHazardous Materials Laboratory2151 Berkeley Way, Berkeley, Ca. 94704Tel No: (510) 540-3003

Inorganic Quality Assurance

Collector's Name: Dan ZiarkowskiSample Location: Lava Cap Mine

14501 Lava Cap Mine RdNevada Citv 95959

HML#;970022to;970029

Collector's#;LL797-01to:Wetland-02

Activity ; SMB

Analytical Procedure Used:Concentration units: mg/L

WET extraction and analysis bv ICPAESHML Method #910

1. InitialCalibrationVerification

2 . ContinuingCalibrationVerification

SpikeDuplicateResult

SpikeRecoveryResult

ReferenceStandard

Source: IVLot#:M-MEB69013Exp'date:7/98

Determinat ion

Found

True

Recovery

Method Blank

StandardSolutionSource: IVLot#:M-MEB69013

Found

True

% Recovery

Preparation Blank

Sample No.HML #970029

Matrix:Extract

Sample No.HML #970029

Matrix:Extract

Spike ResultA

Spike Results

Spike Added

Samp Result

% Recovery A

% Recovery B

% RPD

As

1.05

1.00

105

<0.10

10.6

10.0

106

<0.10

62.2

62.2

50.0

7.37

110

110

0.00

Signatures:

Fatima HussainAnalyst

DateSupervisor

State of California-California Environmental Protection Agency Department of Toxic Substances ControlHazardous Materials Laboratory

HAZARDOUS MATERIALSSAMPLE ANALYSIS REQUEST

1. Authorization Number

iA To

2. Page

of

.-3. Requester:Address (To Receive Results):

4. Phone (lit 5. Priority Level: 1

a. Authorized by

6. Date Sampled "J— 7. Time Sampled •lours

9. Activity: SEB ELSMB FpB D LT3 HQ Q OTHER

8. Codes (fill in all applicable codes)

a.STC

10. SAMPLING LOCATION

b. Site

a. EPA ID No.

c. Address.UiimK.r~ 'Numotr

11. SAMPLES

a. ID b. Collector's No.

Strwt City j I

B

H

c. Lab No.Sampled. Type

Zip

Container

g. County

e. Type f. Size g. Field Information

12. ANALYSIS REQUESTED

a.

b. ra Metal ^Scan

c.

d.

Metals(Spec)

g.

h.

i.

j.

VOA-8020

VOA-H/S .

VOA-8240

VOA-8260

SVO-8270

VOA-8010Diesel/

k. (_] Gasoline

n.

o.Q

P.Dq-D

Point

C1 -Pes-ticides

OP-Pes-ticides

13. SPECIAL REMARKS:

err7*' r. "!*'>*' :"14. SUPPLEMENTAL,. REQUESTS

Sigiutur* Ntnw/Titl* lnelu«m DIIM

16. LAB REMARKS: Toa,

PJSC 1116/REV. 1/94> Ongin*l-Lib • Duplicatt-Fito • Tnpliote-tnstMctor NLY(HML)

4112-00006California Environmental Protection AgencyDepartment of Toxic Substances ControlHazardous Materials Laboratory (Inorganic Section)2151 Berkeley Way, Berkeley, CA 94704

Phone: (510) 540-3003 or (ATSS) 571-3003

HML f: 961327 to961335

Collector's Name:Site of Sampling:

DANIEL ZIARKOWSKILAVA CAP MINES14501 LAVA CAPNEVADA, 95959

Auth. NO.: EMM3246Activity : 8MB ,Date Collected:I/19/97Date Received: 5/21/97

Analytical Samples are extracted in 0.2 M Citrate buffer, pH 5.0 vith constantProcedure: agitation for 48 hours, followed by filtration through a 0.45 micros

membrane filter. Ratio of buffer to sample is 100 ml->!0 g. Metalanalysis of extract is by ICPAES (EPA #6010). Units are mg/L.

Method: HML S.O.P. 910 California Wast* Extraction Test

HML Number:Collector'sSample No.:Sample Type:

As-ArsenicBa-BariumBe-BerylliumCd-CadmiumCo-CobaltCr-ChromiumCu-CopperMo-MolybdenumNi-NickelPb-LeadSe-SeleniumTI-ThalliumV-Vanadium2n-Zinc

961327

WC-01SOIL

33.54.100.010.091.24<0.304.45<0.302.640.92<0.80<1.50<0.258.18

961328

WC-02SOIL

59.64.460.010.151.80<0.305.86<0.303.591.43

<0.80<1.50<0.2513.1

961329

WC-03SOIL

63.82.810.010.121.51<0.304.74<0.302.731.89<0.80<1.50<0.259.69

961330

WC-04SOIL

13200.18<0.010.840.890.932.89<0.302.58<0.50<0.80<1.500.3037.3

961331

WC-05SOIL

16.60.570.01 .0.160.84<0.301.98<0.300.990.76<0.80<1.500.337.44

Notes: < » below detection limit of method.

> » beyond standard calibration curve;(to be confirmed; an additional report will follow)

M

ate emist's Sigtfatjjdre DateZaida R. liejay, Chemist

er, Supervisor Date '

California Environmental Protection AgencyDepartment of Toxic Substances ControlHazardous Materials Laboratory (Inorganic Section)2151 Berkeley Way, Berkeley, CA 94704

Phone: (510) 540-3003 or (ATSS) 571-3003

HML #: 961327 to961335

Collector's Name:Site of Sampling:

DANIEL ZIARKOWSKILAVA CAP MINES14501 LAVA CAPNEVADA, 95959

Auth. No.: KMM3246Activity : 8MBDate Collected:5/19/97Date Received: 5/21/97

AnalyticalProcedure:

Method:

Samples are extracted in 0.2 M Citrate buffer, pH 5.0 with constantagitation for 48 hours, followed by filtration through a 0.45 micro:membrane filter. Ratio of buffer to sample is 100 ml->10 g. Metalanalysis of extract is by ZCPAES (EPA #6010). Units are mg/L.

HML 8.0.P. 910 California Waste Extraction Test

HML Number:Collector'sSample No.:Sample Type:

As-ArsenicBa-BariumBe-BerylliumCd-CadmiumCo-CobaltCr-ChromiumCu-CopperMo-MolybdenumNi-NickelPb-LeadSe-SeleniumTI-ThalliumV-VanadiumZn-Zinc

961332

WC-06SOIL

4.661.50<0.010.211.50<0.301.92<0.303.65<0.50<0.80<1.50<0.257.53

961333

WC-07SOIL

13.81.10<0.010.350.55<0.301.91<0.300.930.82

<0.80<1.50<0.2519.2

961334

WC-08SOIL

47.12.46<0.010.09<0.201.37<0.10<0.300.952.02

<0.80<1.50<0.251.65

961335

WC-09SOIL

70.82.12<0.010.140.31<0.300.52<0.301.084.28

<0.80<1.50<0.25

4.37

Notes: < " below detection limit of method.

•fc &v—ICP Analyst, " jft»JHerlyn

Date

Milad S. Is Date

phemist's Sigfta ture DateZaida R. Ilejay, Chemist

California Environmental Protection AgencyDepartment of Toxic Substances ControlHazardous Materials Laboratory (Inorganic Section)2151 Berkeley Way, Berkeley, CA 94704

Phone: (510) 540-3003 or (ATSS) 571-3003

HML f: 961327 to961335

Collector's Name:Site of Sampling:

DANIEL ZIARKOWSKZLAVA CAP MINES14501 LAVA CAPNEVADA, 95959

Auth. NO.: EMM3246Activity : 8MBDate Collected:5/19/97Date Received: 5/21/97

AnalyticalProcedure:

Method:

Samples are extracted in 0.2 M Citrate buffer, pH 5.0 with constantagitation for 48 hours, followed by filtration through a 0.45 micronmembrane filter. Ratio of buffer to sample is 100 ml->!0 g. Metalanalysis of extract is by ICPAES (EPA #6010). Units are mg/L.

HML 8.O.P. 910 California Waste Extraction Test

HML Number:Collector'sSample No.:Sample Type:

As-ArsenicBa-BariumBe-BerylliumCd-CadmiumCo-CobaltCr-ChromiumCu-CopperMo-MolybdenumNi-NickelPb-LeadSe-SeleniumTI-ThalliumV-VanadiumZn-Zinc

961327

WC-01SOIL

0.360.02<0.001<0.004<0.02<0.03<0.01<0.03<0.03<0.05<0.08<0.15<0.030.03

961328

WC-02SOIL

0.390.030.0010.01<0.02<0.03<0.01<0.03<0.03<0.05<0.08<0.15<0.030.04

961329

WC-03SOIL

0.610.01<0.001<0.004<0.02<0.03<0.01<0.03<0.03<0.05<0.08<0.15<0.030.02

961330

WC-04SOIL

32.70.040.010.500.920.211.30<0.032.36<0.05<0.08<0.15<0.0344.1

961331

WC-05SOIL

<0.040.05<0.001<0.0040.03<0.03<0.01<0.03<0.03<9 >50.15<0.15<0.030.02

Notes: < - below detection limit of method.

Samples were extracted with deionized water in place of citrate buffer.

ICP Analyst,Merlyn 4e*T5Uzman

jfemist's Signature Datelida R. Ilejay, Chemist

upervisor Date

California Environmental Protection AgencyDepartment of Toxic Substances ControlHazardous Materials Laboratory (Inorganic Section)2151 Berkeley Way, Berkeley, CA 94704

Phone: (510) 540-3003 or (ATSS) 571-3003

HML f: 961327 to961335

Collector's Name:Site of Sampling:

DANIEL ZIARKOWSKILAVA CAP MINES14501 LAVA CAPNEVADA, 95959

Auth. No.: HMM3246Activity : 8MBDate Collected:5/19/97Date Received: 5/21/97

AnalyticalProcedure:

Method:

Samples are extracted in 0.2 M Citrate buffer, pB 5.0 vith constantagitation for 48 hours, followed by filtration through a 0.45 micro:membrane filter. Ratio of buffer to sample is 100 ml->10 g. Metalanalysis of extract is by ICPAES (EPA #6010). Units are mg/L.

HML 8.O.P. 910 California Waste Extraction Test

HML Number:Collector'sSample No.:Sample Type:

As-ArsenicBa-BariumBe-BerylliumCd-CadmiumCo-CobaltCr-ChromiumCu-CopperMo-MolybdenumNi-NickelPb-LeadSe-SeleniumTI-ThalliumV-VanadiumZn-Zinc

961332

WC-06SOIL

<0.040.02<0.001<0.004<0.02<0.03<0.01<0.03<0.03<0.05<0.08<0.15<0.03<0.01

961333

WC-07SOIL

0.190.01

<0.001<0.004<0.02<0.03<0.01<0.03<0.03<0.05<0.08<0.15<0.030.06

961334

WC-08SOIL

0.070.03<0.001<0.004<0.02<0.03<0.01<0.03<0.03<0.05<0.08<0.15<0.03<0.01

961335

WC-09SOIL

0.050.03<0.001<0.004<0.02<0.03<0.01<0.03<0.03<0.05<0.08<0.15<0.03<0.01

Notes: < « below detection limit of method.

Samples were extracted with deionized water in place of citrate buffer.

Date (Chemist's Sig^a^ure DateZaida R. Ilejay, Chemist

Milad S. Iskander, Supervisor Date

CA Department of Toxic Substances ControlHazardous Materials Laboratory2151 Berkeley Way, CA 94704

HML No.:To:'

961327961335

LABORATORY REPORT

Collector's Name: Daniel ZiarkowskiSite or Location: Lava Cap Mines

14501 Lava Cap Mine Rd.Nevada City

Auth. Number HMM3246Activity: SMB

Date Sampled: S/19/97Date Received: 5/21/97

Analytical Extracts are digested with 1:1 HNO3 (and 30% HjOj, and 1:1 HCI, If applicable) over ahot plate.Procedure Used: Digest are cooled, filtered amd made to final volume with deionized H2O. Metal analysis of

the digests is by ICPAES (EPA # 6010). Units are mg/kg.

Reference: EPA Methods 3050 & 6010

Analysis Results:

HMLNumber

961330

Collector'sSample No.:

WC-04

SampleType

SOIL

As-Arsenic

15400

Signatures:

jda R. IlejayChemist

Date Milad IskanderSupervisor

Date

California Department of Toxic Substances ControlHazardous Materials Laboratory

inorganic section Quality Assurance Summary for ICP

HML Number: 961327.t0 961335

Bement

As-ArsenicBa-BariumBe-BerylliumCd-CadmiumCo-CobaltCr-ChromiumCu-CopperMo-MolybdenumNi-NickelPb-LeadSe-SelenhimTI-ThalliumV-VanadiumZn-Zinc

Element

As-ArsenicBa-BariumBe-BervllhjmCd-CadmiumCo-CobaltCr-ChromiumCu-CoooerMo-MolybdenumNi-NickelPb-LeadSe-SeleniumTI-ThalliumV-VanadiumZn-Zinc

HML Sofl QC Sample

mg/kg

found known %

HML Uqukf QC Samp**

mg/kg

found known %

MethodBlank

rrtfl/L<0.040.012<0.001< 0.004<0.02<0.03<0.010<0.03<0.03<0.05<0.08<0.15<0.03<0.015

ReagentBlank

mg/L<0.04<0.002<0.001< 0.004<0.02<0.030.04<0.03<0.03<0.05<0.08<0.15<0.03<0.015

Calibration VerificationStandard

mg/Lfound

10.110.12.0810.410.310.210.310.110.310.110.410.510.110.4

known

10.010.02.0010.010.010.010.010.010.010.010.010.010.010.0

Inorganic VenturesReference Standart

mgfound

1.031.000.201.081.071.051.001.051.071.061.041.061.011.06

known

1.001.000.201.001.001.00.00.00.00.00.00.00.00.00

%101101104104103102103101103101104105101104

1%

103100100108107105100105107106104106101106

Duplicate Spiked Sample

Spike Results mg/kg

A: B: RPD

Duplicate Spiked Sample

Spike Results mg/kg

A:

14499.120.3104103101106101103104123101

98.0115

B:

14499.120.2104103101105101104105123101

98.0116

RPD

0.000.000.000.000.000.000.990.001.000.970.000.000.00^-W&/>

HML No.:

UnspikedResult(mg/kg)

SpikeAdded(mg/kg)

HML No.: 961327

UnspikedResult(mg/kg)

33.54.100.010.091.24<0.304.45<0.302.640.92<0.80<1.50<0.25

7 8.18

SpikeAdded(mg/kg)

100100

20.0100100100100100100100100100100ft V

Matrix:

% Recovery

A: B:

Matrix: SOIL .

% Recovery

A:

11095.0101104102101102101100103123101

98.0107

B:

11095.0101104102101101101101104123101

98.0108

ICP Analyst's Signature:Chemist: Zatda llejDate Analyzed: 06/26/97

Milad S. Iskander, Supervisor Date; £/$} 7/4*7

I ••...?..,.".State of California-California Environmental Protection Agency Department of Toxic Substances Control

Hazardous Materials Laboratory

HAZARDOUS MATERIALSSAMPLE ANALYSIS REQUEST

1. Authorization Number HML No.

To

2. Page

3. Requester VJP^ I U Address {To Receive Results): jolS \

. Phone filfe ) XiS*Mft A^CYc ,y,

5. Priority Level: 1

a. Authorized by

6. Date Sampled 5"-\1-et"7 7. Time Sampled Hours 8. Codes (fill in alj'applicable codes)

9. Activity: D SEB • [&SMB Q FPB Q FMB Q HQ Q OTHER

10. SAMPLING LOCATION

b. Site

c. Addr

11. SAMPLES

a. ID b. Collector's No.

B

H

c. Lab No.Sampled. Type e. Type f. Size g. Field Information

12. ANALYSIS REQUESTED

a. l pH ft;ft,C,Q,6//

b. fi,

c. [51 Metals(Spec)

d. n W.E.T.

• ft

f. D VOA-8020

L. g. D VOA-H/S .

Jl h. D VOA-8240

i. QVOA-8260

F'»shPoint

VOA-8010

SVO-8270

Diesel/Gasoli

13. SPECIAL REMARKS:

m.n Cl-Pes-ticides

n. D OP-Pes-ticides

0. [MT"»

P.D

q-D

; f\ fe^Cj b.F P C. H

Sigiwtiirt

/ / - VHwM/TM*

V . /

16. LAB REMARKS:

OTSC 1116 (REV. 1/84) Ori«inal-Ub • Dupticatt-Fito • Triptic«»-ln»p«aor

I fState of California-California Environmental Protection Agency Department of Toxic Substances Control

Hazardous Materials Laboratory

1. Authorization NumberHAZARDOUS MATERIALSSAMPLE ANALYSIS REQUEST

/OTSC 4. Phone (3. RequesienJJftrJ^V. 5. Priority Level: 1

a. Authorized byAddress (To Receive Results): \Q { $ \

8. Codes (fill in all applicable codes)7. Time Sampled6. Date Sampled £—\*\ ~<)-,

Q «»B Q FMB . Q HQ Q OTHER

10. SAMPLING LOCATION

LAVA

-7 , 1 S? S1c. Arirfr«« \ H

11. SAMPLES

a. ID b. Collector'sSample'd. Type fl. Field Information

I. D FlashPoint

12. ANALYSIS REQUESTED

Scan

Metals(Spec) V

d. [BXW.E.T.

i. Q VOA-8260

Diesel/k. [J Gasoline

13. SPECIAL REMARKS:

15. CHAIN OF GUSTO

*j>^>^ .\J if <

16. LAB REMARKS:

i

California Environmental Protection Agency .Department of Toxic Substances ControlHazardous Materials Laboratory (Inorganic Section)2151 Berkeley Wayf Berkeley, CA 94704

Phone: (510) 540-3003 or (ATSS) 571-3003

4H2-00006HML /: 961327 to

961335

Collector's Name:Site of Sampling:

DANIEL ZIARROWSKILAVA CAP MINE14501 LAVA CAP MINE ROADNEVADA CITY 95959

Auth. NO.: EMM3246Activity : 8MB —Date Collected£p5/19/97Date Received: TD5/21/97

AnalyticalProcedure:EPA-SW 846

Method:

Samples are digested with Itl ENO3 (and 30% H202, and 1:1 HC1,if applicable) over a hot plate. Digests are cooled, filteredand made to final volume with deionized E2O. Metal analysis ofthe digests is by ICPAES (EPA #6010). Units are mg/kg.

3050 for solids; 3010 for liquids; 3005 for clean water.#«£3 '

HML Number:Collector'sSample No.:Sample Type:

As-ArsenicBa-BariumBe-BerylliumCd-CadmiumCo-CobaltCr-ChromiumCu-CopperMo-MolybdenumNi-NickelPb-LeadSe-SeleniumTI-ThalliumV-VanadiumZn-Zinc

961327

WC-01SOIL

16701400.873.8619.317.7121<3.7559.746.28.74<15.023.8192

961328

WC-02SOIL

319097.50.664.6021.78.55121<3.7557.760.89.59<15.015.8197

961329

WC-03SOIL

284077.30.804.2321.111.1119<3.7548.760.511.3<15.023.8198

961330

WC-04SOIL

>1600037.70.3914.68.8728.7122<3.7526.858718.6<15.015.9723

961331

WC-05SOIL

10601010.705.2612.720.776.8<3.7526.067.012.6<15.047.9140

Notes: < « below detection limit of method.

> » beyond standard calibration curve;(to be confirmed; an additional report will follow)

fafaA ' Chemist's sigjfcljpre Date

Zaida R. Ilejay, Chemist

Milad S. Sskander", Supervisor Date

California Environmental Protection AgencyDepartment of Toxic Substances ControlHazardous Materials Laboratory (Inorganic Section)2151 Berkeley Way, Berkeley, CA 94704

Phone: (510) 540-3003 or (ATSS) 571-3003

HML f: 961327 to961335

Collector's Name:Site of Sampling:

DANIEL ZIARKOWSKILAVA CAP MINE14501 LAVA CAP MINE ROADNEVADA CITY 95959

Auth. NO.: EMM3246Activity : 8MBDate Collected:05/19/97Date Received: 05/21/97

AnalyticalProcedure:EPA-SW 846

Method:

Samples are digested with Isl ENO3 (and 30% H202, and 1:1 HCl,if applicable) over a hot plate. Digests are cooled/ filteredand made to final volume with deionized E2O. Metal analysis ofthe digests is by ZCPAES (EPA #6010). Units are mg/kg.

3050 for solids; 3010 for liquids; 3005 for clean vater.

HML Number:Collector'sSample No.:Sample Type:

As-ArsenicBa-BariumBe-BerylliumCd-CadmiumCo-CobaltCr-ChromiumCu-CopperMo-MolybdenumNi-NickelPb-LeadSe-SeleniumTI-ThalliumV-VanadiumZn-Zinc

961332

WC-06SOIL

101087.71.047.0025.118.287.55.8786.244.715.4<15.037.5239

961333

WC-07SOIL

118040.00.414.987.309.6850.4<3.7517.558.5<7.50<15.018.9312

961334

WC-08SOIL

66971.90.504.624.3079.429.5<3.7515.231.1<7.50<15.018.6257

961335

WC-09SOIL

116066.40.594.244.6616.523.8<3.7516.353.3<7.50<15.024.9193

Notes: < - below detection limit of method.

ICP Analyst,Merlyn

Date t smist's Signgt\4re Datelida R. Ilejay, Chemist

California Department of Toxic Substances ControlHazardous Materials Laboratory

section Quality Assurance Summary for ICP

HML Number:to

961327961335

Element

As-ArsenicBa-BariumBe-BerylliumCd-Cadmfum

Co-CobaltCr-ChromiumCu-CopperMo-MolybdenumNi-NickelPb-LeadSe-SeleniumTI-ThalliumV-VanadiumZn-Zinc

IDcrnent

As-ArsenicBa-BariumBe-BervlHumCd-CadmiumCo-CobaltCr-ChromiumCu-CooperMo-MolybdenumNi-NickelPb-LeadSe-SeleniumTI-ThalliumV-VanadiumZn-Zinc

HML Soil QC Sample

mg/kgfound

61.041.320.224.519.151.736.127.533.029.373.5122

35.141.6

known

63.344.721.525.520.759.637.730.335.431.072.8125

40.946.3

%

96.492.494.096.192.386.795.890.893.294.5101

97.685.889.8

HML UquW QC Sample

mg/kg

found

2.823.100.843.032.375.3629.91.964.7210.13.3610.22.5654.6*

known

3.013.010.852.472.435.3929.01.974.9610.23.4710.12.4957.1

%

93.7103

98.8123

97.599.4103

99.595.299.096.8101103

95.6

MethodBlank

ma/L<0.10<0.005< 0.003< 0.009<0.05<0.08<0.05<0.08<0.05<0.10<0.15<0.30<0.06<0.05

ReagentBlank

ma/L<0.10<0.005< 0.003<0.009<0.05<0.08<0.05<0.08<0.05<0.10<0.15<0.30<0.06<0.05

Calibration VerificationStandard

mg/Lfound

10.39.892.0810.410.410.310.310.210.410.310.610.210.210.6

known

10.010.02.0010.010.010.010.010.010.010.010.010.010.010.0

%103

98.9104104104103103102104103106102102106

Inorganic VenturesReference Standard

mg/Lfound

1.041.010.211.071.061.040.991.05.06.05.03.05.01.06

known

1.001.000.20.00.00.00.00.00

1.001.001.001.001.001.00

%

104101105107106104

99.0105106105103105101106

Duplicate Spiked Sample

Spike Results mg/kg

A:

43661798.3455470494537467487505475424560552

B:

42358594.4445457469503447470495457427504529

RPD

3.035.773.972.282.875.427.304.383.792.273.860.7111.65.29

Duplicate Spiked Sample

Spike Results mg/kg

A: B: RPD• •••• •••• •••• *••• •••• •••• •••• •••• •••• •••• •••• • ••• •••• •••^

HML No.: 961331

UnspikedResult(mg/kg)

<5.0080.5

0.7511.210.420.354.6<3.7529.460.1<7.50<15.058.9106

HML No.:

UnspikedResult(mg/kg)

'7j?

SpikeAdded(mg/kg)

500500100500500500500500500500500500500500

SpikeAdded(mg/kg)

/*

Matrix: SOIL

% Recovery

A:

87.210797.588.891.994.796.593.491.589.095.084.810089.2

B:

84.610193.786.889.389.789.789.488.187.091.485.489.084.6

Matrix:

% Recovery

A: B:

ICP Analyst's Signature:Chemist: Zaida R. lleiav Chemist's Signature;Date Analyzed: 06/19/97

Milad S. Iskander, Supervisor: Date;

California Department of Toxic Substances ControlHazardous Materials Laboratory2151 Berkeley Way, Berkeley, CA 94704(510) 540-3003

LABORATORY REPORT

Collector's Name: Daniel Ziarskawski

HML #: 961327To: 961335

Location: Lava Cap Mines14501 Lava Cap Mine RdNevada City 95957

Auth. No.:Activity:

HMM3246SMB

Date Sampled;5/19/97Date Received:5/21/97

Analytical Procedure Used: pH determined using Accumet 825MP pH metercalibrated with pH buffers 1, 4, 1, 10 and 13.

Reference: EPA Methods 9040 & 9045

Analysis Results:

HMLNO.

961327961328961329961330961331961332961333961334961335

COLLECTOR'SSAMPLE NO.

WC-01WC-01WC-03WC-04WC-05WC-06WC-07WC-08WC-09

TYPE OFSAMPLE

SOILSOILSOILSOILSOILSOILSOILSOILSOIL

pH

8.87859332

6.908.148.288.126.94

Signatures:

SupervisorDate

California Department of Toxic Substances ControlHazardous Materials Laboratory2151 Berkeley Way, Berkeley, Ca 94704

Quality AssurancepH

Procedure: pH by electrometric method

I. Calibration Standard Data

Reference: EPA 9040 & 9045

ID VendorPN

FISHER

FISHER

FISHER

EM SCIENCE

LotNo.

960128-24

960985-24

955105-24

34119

Exp.Date

8/97

2/98

11/97

BufferType

SOL'N

SOL'N

SOL'N

SQL'N

PHBuffer

4.0

7.0

10.0

13.0

mvReading

38.2

-138.4

-316.2

-482.9

Efficiency

1.0204

1.0245

0.95513

Calibration for 961330

FISHER

VWR

960285-18

9508152

7/97

8/97

SOL'N

SOL'N

1.00

7.00

-140.8

204.2

II. Laboratory Control Sample

PHBuffer

4.00

7.00

1.00

13.00

LotNo.

9510098

9508152

960285-18

34119

Source

VWR

VWR

FISHER

EM SCI

ExpectedResult

4.00

7.00

1.00

13.00

ObservedResult

4.004

€.97

0.998

13.003

AbsoluteDiff.

0.004

0.03

0.002

0.003

pH of DI H20 used in dilution 6.78

III. Laboratory Duplicate Sample Results

HMLNo.

961327

961330

SampleType

SOIL

SOIL

SampleResult

8.874

2.315

Dupl.Result

8.877

2.317

AbsoluteDifference

0.003

0.002

Analyst:lida

Supervisor:

Date;

Date:

State of California-California Environmental Protection Agency Department of Toxic Substances ControlHazardous Materials Laboratory

HAZARDOUS MATERIALSSAMPLE ANALYSIS REQUEST

1. Authorization Number

r^v

HML No.To

2. Page

3. Requester: U^»*J i U "Address (To Receive Results): |oVS V

Phone (Ufe ) "15$ - 3C X°l, /-vTe $,****</ ,

t

5. Priority Level: 1

a. Authorized by

6. Date Sampled 5"*"\ct-el"7 7. Time Sampled Hours

9. Activity: Q SEB E£SMB D PPB Q FMB Q HQ Q OTHER

10. SAMPLING LOCATION

b. Site _

a. EPA ID No.

c. Address.Numlxr

8. Codes (fill in alj applicable codes)

a.STC

b. Region

c. INDEX

d.PCA

•.MPC

I.SITE

g. County

11. SAMPLES

a. ID b. Collector's No.

B

u>C-o5

UP 6-0*0H

c. Lab No.

^5(330

' Cny

Sample -d. Type

Zip

Containere. Type f. Size g. Field Information

6JSu>v>e</

12. ANALYSIS REQUESTED

a.

b.

c.

. 6ScanMetals(Spec)

d. n W.E.T.

vw*. ft

VOA-8010

f- D VOA-8020

g. D VOA-H/S .

h. n VOA-8240

i. D VOA-8260

j. D SVO-8270_ Diesel/

k. [J Gasolin

I. D FlashPoint

n.

C1-Pes- .ticides

OP-Pes-ticides

. H

P.Q

13. SPECIAL REMARKS:

15. CHAIN OF OUSTODY

d.Sifnmurt MwiwDMM

16. LAB REMARKS:

>T5C 1116 (REV. Drioin»l-L»b e TripUeet NLY(HMU

Stata of California-California Environmental Protection Agency Department of Toxic Substances ControlHazardous Materials Laboratory

HAZARDOUS MATERIALSI SAMPLE ANALYSIS REQUEST

1. Authorization Number

i\ rv\To

2. Page

3. Requesten^rvKfi^Address (To Receive Results):^oi£\

4. Phone 5. Priority Level:

a. Authorized by

,' 6. Date Sampled g — \ <\ —,

7. Time Sampled , • Hours 8. Codes (fill in all applicable codes)

9. Activity: SEB JF^SMB D FpB D FMB D HQ Q OTHER

10. SAMPLING LOCATION

CVp

a. EPA ID No.

c. Address i±LS£lNumber SUMt

11. SAMPLES

a. ID b. Collector's No.

B

H

c. Lab No.

City I f

Sample"d. Type*G>] U.

Containere. Type f. Size g. Field Information

12. ANALYSIS REQUESTED

b. MetalScan

~~ (Spec) V

d. [&W.E.T. J .

« W

f. U VOA-E

g.D

h. ni. n VOA-8260

«. n VOA-8010Diesel/Gasoline

13. SPECIAL REMARKS:

n. I I

o. [J0

P-D

q-D

Flash _Point

d-Pes- .ticides

OP-Pes-ticides

c.Slfwttir*

Stgn«tura InclwmOdM

16. LAB REMARKS:

Ml V fUMt t

4112-00006California Environmental Protection AgencyDepartment of Toxic Substances ControlHazardous Materials Laboratory (Inorganic Section)2151 Berkeley Way, Berkeley, CA 94704

Phone: (510) 540-3003 or (ATSS) 571-3003

HML #: 960957 to960966

Collector's Name:Site of Sampling:

DANIEL ZIARKOWSKILAVA CAP MINE14501 LAVA CAP MINE RDNEVADA CITY, 95959

Auth. NO.: HMM3163SActivity : SMB „Date Collected:J/14/97Date Received: 3/18/97

Analytical Samples are extracted in 0.2 M citrate buffer, pH 5.0 with constantProcedure: agitation for 48 hours, followed by filtration through a 0.45 micron

membrane filter. Ratio of buffer to sample is 100 ml->10 g. Metalanalysis of extract is by ICPAES (EPA #6010). Units are mg/L.

Method:

HML Number:Collector'sSample No.:Sample Type:

As-ArsenicBa-BariumBe-BerylliumCd-CadmiumCo-CobaltCr-ChromiumCu-CopperMo-MolybdenumNi-NickelPb-LeadSe-SeleniumTI-ThalliumV-VanadiumZn-Zinc

960957

LCS-1SOIL

11.70.980.010.08

<0.20<0.300.27<0.300.472.08

<0.80<1.50<0.252.92

960958

LCS-2SOIL

11.81.06<0.010.07<0.20<0.300.14<0.300.432.23

<0.80<1.50<0.252.92

960959

LCS-3SOIL

12.51.28<0.010.070.22<0.300.32<0.300.371.67<0.80<1.50<0.253.67

960960

LCS-4SOIL

9.776.490.020.080.77

<0.300.91<0.300.480.88<0.80<1.501.095.52

960961

LCS-5SOIL

28.12.12<0.010.060.22<0.300.25<0.300.361.12<0.80<1.50<0.253.99

Notes: < - below detection limit of method.

o&sICP Analyst,Merlyn de

Date

Milad S. Iskander,'Supervisor ate

Chemist's SignatureFatima Hussain, Chemist

tltifDat<i

California Environmental Protection AgencyDepartment of Toxic Substances ControlHazardous Materials Laboratory (Inorganic Section)2151 Berkeley Way, Berkeley, CA 94704

Phone: (510) 540-3003 or (ATSS) 571-3003

HML fl 960957 to960966

Collector's Name:Site of Sampling:

DANIEL ZIARKOWSKILAVA CAP MINE14501 LAVA CAP MINE RDNEVADA CITY, 95959

Auth. No.: HMM3163SActivity : 8MBDate Collected:3/14/97Date Received: 3/18/97

AnalyticalProcedure:

Method:

Samples are extracted in 0.2 M Citrate buffer, pH 5.0 with constantagitation for 48 hours, followed by filtration through a 0.45 micronmembrane filter. Ratio of buffer to sample is 100 ml->10 g. Metalanalysis of extract is by ICPAES (EPA i6010). Units are mg/L.

HML 8.0.P. 910 California Waste Extraction Test

HML Number:Collector'sSample No.:Sample Type:

As-ArsenicBa-BariumBe-BerylliumCd-CadmiumCo-CobaltCr-ChromiumCu-CopperMo-MolybdenumNi-NickelPb-LeadSe-SeleniumTI-ThalliumV-VanadiumZn-Zinc

960962

LCS-6SOIL

19.22.750.010.110.46

<0.300.76

<0.300.751.89

<0.80<1.50

0.276.20

960963

LCS-7SOIL

9.507.230.030.090.84

<0.301.13

<0.300.690.92

<0.80<1.50

1.294.82

960964

LCS-8SOIL

6.206.120.020.061.44

<0.300.79

<0.303.140.80

<0.80<1.50

0.883.46

960965

LCS-9Sediment

24.84.040.020.100.29

<0.300.70

<0.300.682.05

<0.80<1.50

0.466.12

960966

LCS-10Sfediment

29.33.760.010.100.35

<0.300.54

<0.300.582.00

<0.80<1.50

0.517.02

Notes: < - below detection limit of method.

CP Attalyst,Merlyn de

Mi lad S. Iskander, Supervisor Date

Chemist's SignatureFatima Hussain, Chemist

Date

California Environmental Protection AgencyDepartment of Toxic Substances ControlHazardous Materials Laboratory (Inorganic Section)2151 Berkeley Way, Berkeley, CA 94704

Phone: (510) 540-3003 or (ATSS) 571-3003

HML 960957 to960966

Collector's Name:Site of Sampling:

DANIEL ZIARKOWSKILAVA CAP MINE14501 LAVA CAP MINE RDNEVADA CITY, 95959

Auth. No. : HMM31633Activity : 8MBDate Collected:3/14/97Date Received: 3/18/97

AnalyticalProcedure:

Method:

Samples are extracted in 0.2 M Citrate buffer, pH 5.0 with constantagitation for 48 hours, followed by filtration through a 0.45 micronmembrane filter. Ratio of buffer to sample is 100 ml->10 g. Metalanalysis of extract is by ICPAES (EPA #6010). Units are mg/L.

HML S.O.P. 910 California Waste Extraction Test

HML Number:Collector'sSample No.:Sample Type:

As-ArsenicBa-BariumBe-BerylliumCd-CadmiumCo-CobaltCr-ChromiumCu-CopperMo-MolybdenumNi-NickelPb-LeadSe-SeleniumTI-ThalliumV-VanadiumZn-Zinc

960957

LCS-1SOIL

0.08<0.002<0.001<0.004<0.02<0.03<0.01<0.03<0.03<0.05<0.08<0.15<0.030.02

960958

LCS-2SOIL

0.270.010.0020.01<0.02<0.030.010.04

<0.03<0.05<0.08<0.15<0.030.02

960959

LCS-3SOIL

0.20<0.002<0.001<0.004<0.02<0.03<0.01<0.03<0.03<0.05<0.08<0.15<0.03<0.01

960960

LCS-4SOIL

<0.040.02<0.001<0.004<0.02<0.03<0.01<0.03<0.03<0.05<0.08<0.15<0.03<0.01

960961

LCS-5SOIL

0.110.02<0.001<0.004<0.02<0.03<0.01<0.03<0.03<0.05<0.08<0.15<0.03<0.01

Notes: < « below detection limit of method.

Camples were extracted with rteionized ureter instead JDf-£.2M citrate buffer,

ICP Arfelyst,Merlyn

/f 7ate Chemist's Signature /Date

Fatima Hussain, Chemist

Milad S. Iskander,'SupervisorW7/97Date

California Environmental Protection AgencyDepartment of Toxic Substances ControlHazardous Materials Laboratory (Inorganic Section)2151 Berkeley Way, Berkeley, CA 94704

Phone: (510) 540-3003 or (ATSS) 571-3003

HML f: 960957 to960966

Collector's Name:Site of Sampling:

DANIEL ZIARKOWSKILAVA CAP MINE14501 LAVA CAP MINE RDNEVADA CITY, 95959

Auth. NO.: EMMS163SActivity : 8MBDate Collected:3/14/97Date Received: 3/18/97

AnalyticalProcedure:

Method:

Samples are extracted in 0.2 M citrate buffer, pH 5.0 with constantagitation for 48 hours, followed by filtration through a 0.45 micro:membrane filter. Ratio of buffer to sample is 100 ml->10 g. Metalanalysis of extract is by ZCPAES (EPA #6010). units are mg/L.

HML S.O.P. 910 California Waste Extraction Test

HML Number:Collector'sSample No.:Sample Type:

As-ArsenicBa-BariumBe-BerylliumCd-CadmiumCo-CobaltCr-ChromiumCu-CopperMo-MolybdenumNi-NickelPb-LeadSe-SeleniumTI-ThalliumV-VanadiumZn-Zinc

960962

LCS-6SOIL

0.090.01<0.001<0.004<0.02<0.03<0.01<0.03<0.03<0.05<0.08<0.15<0.03<0.01

960963

LCS-7SOIL

<0.040.04<0.001<0.004<0.02<0.03<0.01<0.03<0.03<0.05<0.08<0.15<0.03<0.01

960964

LCS-8SOIL

<0.040.02<0.001<0.004<0.02<0.03<0.01<0.03<0.03<0.05<0.08<0.15<0.03<0.01

960965

LCS-9Sbediroent

0.090.07<0.001<0.004<0.02<0.03<0.01<0.03<0.03<0.05<0.08<0.15<0.03<0.01

960966

LCS-10Sodiraent

0.070.07<0.001<0.004<0.02<0.03<0.01<0.03<0.03<0.05<0.08<0.15<0.03<0.01

Notes: < » below detection limit of method.

Samples were extracted with deionized water instead of 0.2M citrate buffer.

ICP Analyst,Merlyn de G

Chemist's Signature /DateFatima Hussain, Chemist

Milad S. Iskahder, 'Supervisor Date

California Department of Toxic Substances ControlHazardous Materials LaboratoryInorganic Section —. ... A _ *• i i-»

Quality Assurance Summary for ICP

HML Number: 960957 ;'to 960966"

Element

As-ArsenteBa-BariumBe-BerylliumCd-CadmiumCo-CobaltCr-ChromiumCu-CopperMo-MolybdenumNi-NickelPb-LeadSe-SeleniumTI-ThalliumV-VanadiumZn-Zinc

Element

As-ArsenicBa-BariumBe-BerylliumCd-CadmiumCo-CobaltCr-ChromiumCu-CopperMo-MolybdenumNi-NickelPb-LeadSe-SeleniumTI-ThalliumV-VanadiumZn-Zinc

HML Sod QC Sample

mg/kgfound known %

HML Liquid QC Sample

mg/kg

found known %

MethodBlank

ma/L<0.04< 0.002<0.001<0.004<0.02<0.03<0.010<0.03<0.03<0.05<0.08<0.15<0.03<0.015

ReagentBlank

mg/L

<0.04<0.002< 0.001<0.004<0.02<0.030.03<0.03<0.03<0.05<0.08<0.15<0.03<0.015

Calibration VerificationStandard

mg/Lfound

10.110.02.0310.310.310.110.110.210.310.210.310.29.9910.3

known

10.010.02.0010.010.010.010.010.010.010.010.010.010.010.0

%101100102103103101101102103102103102

99.9103

Inorganic VenturesReference Standard

mg/L

found

1.021.010.201.031.031.021.051.011.041.021.031.021.001.03

known

1.001.000.201.001.001.001.001.001.001.001.001.001.001.00

%

102101100103103102105101104102103102100103

Duplicate Spiked Sample

Spike Results mg/L

A:

67.849.910.152.752.251.651.152.452.655.261.551.550.0 .57.5

B:

67.549.810.152.151.651.051.051.851.954.661.350.549.657.1

RPD

0.00.250.000.961.161.170.000.970.970.950.331.960.800.92

Duplicate Spiked Sample

Spike Results mg/L

A:

5.294.981.025.265.185.084.995.095.215.245.475.144.935.39

B:

5.344.971.025.325.265.154.975.175.265.325.515.204.975.46

RPD

0.240.050.000.001.150.150.100.390.240.380.180.290.200.32^

HML No.: 960957

UnspikedResult(mg/L)

11.70.980.010.08<0.20<0.300.27<0.300.472.08<0.80<1.50<0.252.92

HML No.:

UnspikedResult{mg/U

0.08<0.002<0.001< 0.004<0.02<0.03<0.01<0.03<0.03<0.05<0.08<0.15<0.03

t532

SpikeAdded(mg/L)

50.050.010.050.050.050.050.050.050.050.050.050.050.050.0960957

SpikeAddedImg/L)

5.005.001.005.005.005.005.005.005.005.005.005.005.005/ 0

Matrix: Extract

% Recovery

A:

11297.8101105104103102104104106123103100109

1 B:

"11297.610110410310210210310310512310199.2108

Matrix: ExtractWater

% Recovery

A:

10410010210510210410010210410510910398.6107

B:

10599.410210510610399.4.10310510611010499.4109

»CP Analyst's Signature:Chemist: Fatima HDate Analyzed: 04/16/97

Milad S. Iskander, Supervisor: Date; (f//7/?7

•Gt«et of £alftcmia-C»liforni8 Environmenta Department of Toxic Substances ControlHazardous Materials Laboratory

HAZARDOUS MATERIALSSAMPLE ANALYSIS REQUEST

1. Authorization Number;3

HML No.

To

2. Page

^ - -

3. Requester: \>V\J tWC^n^A /G"i~>K 4. Phone (M6 ) T_5^ - 36Address (To Receive Results): \p|S|

- - - -

5. Priority Level:

a. Authorized

6. Date Sampled 7. Time Sampled Hours

9. Activity: Q SEB jtf SMB Q FPB Q FMB Q HQ Q-OTHER

10. SAMPLING LOCATION

b. Site UvJA

8. Codes (fill in all applicable codes)

a.STC

b. Region

a. EPA ID No.

c. Address

11. SAMPLES

a. ID

Number Suwt'

b. Collector's No.LCS-t

B

H LCT-V

c. Lab No.

C«y

Sampled. Type

Containere. Type f. Size g. Field Information

12. ANALYSIS REQUESTED

a.

. 0.Metal V\6,C,0 P..Ef firsn 7 1 J

C.

d.

(Spec)

W.E.T.

f. Q VOA-8020

g. D VOA-H/S .

h. D VOA-8240

i. D VOA-8260

FlashPoint

j. SVO-8270

e. Q VOA-8010Diesel/

k. [j Gasoline

n. 1_J

p-D

q-D

C1-Pes-ticides

OP-Pes-ticides

13. SPECIAL REMARKS:

18. CHAIN Of CUSTODYILH. V I f f

orsrc rrrefffev. i/-94j(Formerly DHS 8002) Original-Lab • Dupltcatt-File • Triplicate-Inspector TJfFl NLY(HML)

State pf California-California Environmental Protection Agency,._

7 Department of .Toxie~S• ,• Hazardous Materials''' -

HAZARDOUS MATERIALSSAMPLE ANALYSIS REQUEST

1. Authorization Number

tv\3. Requester:

Address (To Receive Results): lO|s-|- Phone (q,L6°) 1X5" -vOyf Svtte.1 CrO

5. Priority Level:

a. Authorized b

6. Date Sampled S -JH" 7. Time Sampled •lours

9. Activity: D SEB Q n FMB n HQ D OTHER

10. SAMPLING LOCATION

b. sitea. EPA ID No.

Mwe

c. Address.

8. Codes (fill in alj applicable codes)*<•$.''*

a.STC

b. Region

c. INDEX

d. PCA

e.MPC

f. SITE

g. County]Numtxr

11. SAMPLES

a. ID b. Collector's No.

StTMI

B L C S -lo

H

c. Lab No.Sampled. Type

Containere. Type f. Size g. Field Information

PLASTIC

12. ANALYSIS REQUESTED

a. n pH

b.TX

c. fift Metals^Spec)

d. D W.E.T.

f. n VOA-8020

g; n VOA-H/S .

Point

MetalScan

H^

fe,E]i h. D VOA-8240

_ i. D VOA-8260

j. SVO-8270

e. n VOA-8010Diesel/

k. [J Gasoline

n.

o.

P.Dq.Q

C1-Pes-ticides

OP-Pes-ticides

13. SPECIAL REMARKS:

15. CHAIN OfACl/SJODY

3 V /H /T7

CigrwAjr*

Sipniiur*

~~" Indimv* Dim

/ / . / /Nwnt/TiU*

Signnurt

Induclvt Ottu

/ / - / /lndu»iv« D>lu

16. LAB REMARKS&k

Y

DISC 1116 (REV. 1/94){Formerly PHS 8O02)

Original-Lab • Ouplica»-Ble • Triplicat»-lnsp«cior NLY(HML)

-03-19-91 03:02PM FROM DTSC REGION i SACTO. TO 914157441916 P009

i 12:04 FAX 8106403616 HML AQ. PARK

4112California EAviroxmental Protection AgencyDepartment of Toxic Substances Controlaaz&rdous ftaterlals Lauorarory (inorganic sect ion j2151 Berlcelay Nay, Berkeley, CA 94704

Phone: (510) 540-3003 or (ATSS) 571*3003

Coll«cst:or«« Nwn«n CAM aiARXOWCKISite of Caioplingj lAVA CAP MINE

14501 LAVA. CAP MINE RDNEVADA CITY

i!02

ft 960813 to960820

HO.;Activity : 5MBDate Collected; 1/31/97Data Received: 2/4/97

AnalyticalProcedure:1PA-SW 846

Kethod:

HMLCollector ' sSample No. :Sample Type:

As-ArsenicBa-BariunBe-BerylliumGel-CadmiumCo-cobaltCr-ChromiumCu-copperMo-Molybdenum

Sanples are digested with 1:1 10703 [and 30% H202, and 1:1 HCl,if applicable) over a hot plate. Digests are cooled, filteredand »adia to final volume with deioni.zed H2O. Ketal analysis orthe digests is by ICPAES (EPA feoio). units are mg/kg.

305O for solids; 3O10 for liquids; 3DOS £oxr clean wator.

9610813 960814 O6O815 . 96O816 96O817

Tl-ttialliumv-vanadiua

LLWWATER

<1.00<0.05<O.O3<0.09<0.50<0.80<0.50<0*TS14.2

<1.00-Cl.SOo.oo<0.60

2,32

•HRSSOII.

55226.00.222.484.135.8515.3

0.7510.229.7

<7,50

13.2155

DAMSSOIJu

39216.30.181.783.544.6814.9

<3.758.7427.7

<7.50<15.0

8.85116

Notes: <£ » bo low datac^lon limit of

Chemislr * sr SignatureAt if H. K

Date

R-95X 5105403615 02-26"87 P002

03/19/97 WED 14:27 [TX/RX NO 8507]

03-19-91 03:02PM FROM DTSC REGION 1 SACTO. TO 914151441916

. 02/&/B7 12:04 FAX 5105403815 HML AQ. PARK

P010

[fi 03

California Environmental Protection Agency&epaxrfcst«mt: of Toxxo Subvbanooc controlHaaardouo Materials Laboratory (inorganic Section)2151 BerVfelay Way. Berkeley, CA 94704

Phone: (51O) 540-3O03 or (AT58) 571-3003

collector's Name: DAN ZIARKOWSXISite of Sampling: XAVA CAP KIKE

14501 IAVA CAP MINE RDNEVADA CITY

HML *: 960813 to960820

AUth. WO.: HMM3126Activity : sx&Date Collected: 1/31/97Date Received: 2/4/97

AnalyticalProcedure:SPA-SW 846

Methods

EML Number:collector ' sSample No. :Sample Type:

As-ArsenicBa-BariumBe-Bery 11 iumCd-Cad&iimCo-Cobaltcr-ChromiumCu-CopperMo-«olybdenurojri-NickelPb-LeadSis-Selenium

sanples are digested with 1:1 HNO3 (and 301; H202, and iti Hci,if applicable) over a hot plate. Digests are cooled, filteredand aade to final volume with deionized B2O. Metal analysis ofthe digests is by ICPAES (EPA 46010). Units are mg/kg.

30SO for solides 3010 for liquids; 3005 for clean water.

960818 960819 960820

V-VanadixunZn-Zinc

DAHWWATER

<1.OO0.07

<O.O3<O.09<O.SO<O.BO<0.50<0»75<0.50<1.00<1.SO<3.00<O_6O<O,50

LCRHSSOIL

51141.80.27a. 664.977.8113.2

<3.7S11.826.0<7-50<15.014.5161

LCRHWHATER

<1.00<0. 05<0.03<O.O9•CO. 50<O.80<0.50<0.75<0.50<i.OO<1.SO<3.00<O.6O<O.5O

KTotes: < — below dot notion limit of aethed.

Date_

SionatureAt if R. loziaan, Chemist

Date

Milad s. iskand r, supervisor Date

5105403615 02-36-97 12:40PM P003 If0 J

03/19/97 WED 14:27 [TX/RX NO 8507]

03-19:91 03-.02PM FROM DTSC REGION 1 SACTO. TO 914151441916 P01

SOIL/WATER SAMPLE LOCATIONS

LAVA CAP MINE/LITTLE CLIPPER CREEK

Samples collected 1-31-97

SAMPLE #

LLW

LLS

HRW

HRG

DAMS

DAMW

LCRMS

LCRMW

LOCATION DESCRIPTION

Lost Lake water

Lost Lake soil

Water sample collected @Greenhorn Rd and LittleClipper Creek

Soil sample collected SGreenhorn Road andLittle Clipper Creek

Soil collected near thedam breach at Lava Cap Mine

Pore water from DAMS soil

Soil sample coJ 1 untied @Raccoon Mountain Road soiland Little Clipper Creek

Water sample collected @Raccoon Mountain Road andLittle Clipper Creek

sample results attached

03/19/97 WED 14:27 [TX/RX NO 8507]

03-19--91 03:02PM FROM DISC REGION 1 SACTO, TO 914151441916 P012

I

™ i ^

03/19/97 WED 14:27 [TX/RX NO 8507]