power point thesis env
TRANSCRIPT
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EXPOSURE TO PLANT PROTECTION PRODUCTS DURING AND AFTER APPLICATION IN
ORNAMENTAL GREENHOUSES
NELSON AMBUEH PANGSI
PROMOTER Prof. Dr. ir. Pieter Spanoghe
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Presentation outline
Introduction Materials and methods
Sampling location and crop type Studied products and pesticides (active substances) Sampling methods, experimental set up and analysis Risk assessment
Results and discussion Conclusion
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Introduction Importance of plant protection products
• To kill or prevent pest, diseases and weeds
• To ensure effective plant growth and high yields
Problems of plant protection products
• Presents a potential health risk to the operators, workers
and bystanders
• A potential risk to the environment
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Introduction Problems of plant protection products
• Human exposure to plant protection products
• Operator
• Worker
• Bystander
Operator Workers Bystanders
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Introduction
General objective To study the exposure of workers and operators to plant
protection products during and after application in
ornamental greenhouses
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Introduction
Specific objectives Determine the quantity of pesticides operators and
workers are exposed to
OPERATOR: Study the distribution of exposure on
the body of operators
WORKER : Identification of the re-entry activities of
workers having high and low rate of pesticide
exposure
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Materials and methods
Sampling location and crop type Materials for the study was from an ornamental greenhouse pot
plant grower in East-Flanders.
Some ornamentals grown are: Clivias, Orchids and Azaleas
Clivias Orchid Azalea
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Materials and methods
Study products and active substances imidacloprid (Warrant 200 SL)
deltamethrin ( Decis EC 2.5)
A combination of fluazinam and metalaxyl-m (Epok 600 EC)
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Material and methods Sampling methods and experimental set up
Dermal exposure WORKERS and OPERATORS
Whole body dosimeter for the body and gloves for the hands
Coverall (DuPont Tyvex model CHF5) and gloves
OPERATORS activities
Mixing/loading
Application
deltamethrin and imidacloprid
Figure 1 Coverall sections for PDE (Flores et al., 2011)
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Materials and methods Sampling methods and experimental set up
WORKERS activities considered includes;
Sorting and cleaning of plants treated with imidacloprid and
fluazinam
Transferring plants treated with imidacloprid
Selecting plants treated with fluazinam
Potting plants treated with fluazinam and imidacloprid into soil
Sampling of gloves, leaves (from clivia) and soil materials
Sampling duration: 2 hours
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Materials and methods Chemical analysis
Analysis was made by GC-MS for all materials on deltamethrin
and fluazinam
Analysis was made by HPLC for all materials on imidacloprid
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Materials and methods Risk assessment The amount of the pesticides in the different materials analyzed
were used to calculate the potential dermal exposure (PDE),
DFR, soil residue, Transfer Coefficient. PDE = DFR x TC x T
DFR = AR/LAI
Soil Residue = Amount (µg)/ mass of soil measured (mg)
Transfer Coefficient = PDE/DFR
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Materials and methods Risk assessment From the calculated potential dermal exposure (PDE), the
absorbed doses and risk indices were calculated as well. Absorbed dose 10%
Risk Index
RI = analysed human exposure / toxicity normation (AOEL)
If RI ≥1 problem
If RI < 1 no problem
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Results and discussion
Figure 2. Distribution of operator dermal exposure for deltamethrin (9 trial )
Lower legs and hands having high exposure
The arms and head having low exposure
right hand (gloves)
Left hand (gloves)
lower leg left
lower leg right
Upper leg left
Upper leg right
upper arm left
upper arm right
lower arm left
lower arm right
head
torso front
torso back
- 20.00 40.00 60.00 80.00 100.00 120.00 140.00 160.00
51.05
97.78
116.14
141.28
28.53
8.17
9.45
2.27
2.18
2.34
4.05
41.49
21.96
PDE (µg/h)
Bod
y Pa
rts
OPERATOR exposure – deltamethrin glasshouse 9 trial
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Results and discussion
Figure 3. Distribution of operator dermal exposure for imidacloprid (12 trial )
The hands, lower right leg, upper left leg , and upper right leg having high exposure
The torsos, head , lower left leg and right arm having low exposure
right hand (gloves)
Left hand (gloves)
lower leg left
lower leg right
Upper leg left
Upper leg right
upper arm left
upper arm right
lower arm left
lower arm right
head
torso front
torso back
- 100.00 200.00 300.00 400.00 500.00 600.00 700.00
580.50
223.89
0.08
98.55
161.08
119.32
71.94
13.36
38.06
0.08
0.08
2.06
0.08
PDE (µg/h)
Bod
y Pa
rts
OPERATOR exposure – imidacloprid glasshouse 12 trial
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Results and discussion
Figure 4. Distribution of operator dermal exposure for imidacloprid (trial 21 )
The hands and legs having the high exposure
The torsos, head , upper and lower arms having low exposure
right hand (gloves)
Left hand (gloves)
lower leg left
lower leg right
Upper leg left
Upper leg right
upper arm left
upper arm right
lower arm left
lower arm right
head
torso front
torso back
-
200.0
0
400.0
0
600.0
0
800.0
0
1,00
0.00
1,20
0.00
1,40
0.00
1,60
0.00
1,80
0.00
1,562.15
645.27
645.27
316.44
50.58
69.18
6.05
10.24
4.80
39.91
8.65
0.08
1.18
PDE (µg/h)
Bod
y Pa
rts
OPERATOR exposure – imidacloprid glasshouse 21 trial
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Results and discussion
Operators activities Absorbed dose (10 %) Risk index (RI)
Mixing/loading and application of deltamethrin glasshouse 9 trial
7.52E-05 1.00E-02
Mixing/loading and application of imidacloprid glasshouse 12 trial
1.87E-04 2.34E-03
Mixing/loading and application of imidacloprid glasshouse 21 trial
4.80E-04 5.99E-03
Operators activities and absorbed dose
AOEL imidacloprid = 0.08 mg/kgBW/day, deltamethrin = 0.0075 mg/kgBw/day
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Results and discussionWorkers activities PDE(µg/h) DFR (µg/cm2 ) TC (cm2 /h) SR (µg/mg)
Sorting and cleaning plants treated with imidacloprid and fluazinam
1 (Imidacloprid) 9.23 2.96E-03 3118.24
2 (fluazinam) 3.51 4.60E-02 76.30
3 (fluazinam) 3.77 6.98E-03 540.11
Transferring plant treated with imidacloprid
1 24.85 0.03 828.33
2 7.48 0.03 249.33
3 50.80 0.06 846.67
Selecting plant treated with fluazinam
1 1.14 0.05 22.8
Potting plants treated with fluazinam
1 1.14 0.63 0.005
2 3.51 1.95 0.005
3 3.77 3.48 0.003
Potting plants treated with imidacloprid
1 0.23 0.63 0.001
2 0.70 1.95 0.001
3 1.26 3.48 0.001
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Workers activities and absorbed dosesWorkers activities Absorbed dose (10 %) Risk index (RI)
Sorting and cleaning plants treated with imidacloprid and fluazinam
(AOEL fluazinam = 0.004 mg/kg BW/day)( AOEL imidacloprid = 0.08 mg/kg BW/day)
1 (Imidacloprid) 1.05E-05 1.31E-04
2 (fluazinam) 4.01E-06 1.00E-03
3 (fluazinam) 4.31E-06 1.08E-03
Transferring plant treated with imidacloprid
1 2.84E-05 3.55E-04
2 8.55E-06 1.06E-04
3 5.81E-05 7.26E-04
Selecting plant treated with fluazinam
1 1.30E-06 3.25E-04
Potting plants treated with fluazinam
1 1.30E-06 3.25E-04
2 4.01E-06 1.00E-03
3 4.31E-06 1.08E-03
Potting plants treated with imidacloprid
1 2.63E-10 3.29E-09
2 8.00E-10 1.00E-08
3 1.44E-09 1.80E-08
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Conclusions Hands and legs are the most exposed during spraying
Transferring plants in pots caused the highest exposure
Exposure of the hands with the treated leaves (DFR) ends up in
a higher amount compared to the hands touching the soil (SR).
Absorbed doses (internal exposure) for both the workers and
operators were less than the AOEL of the different PPP applied
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THANKS FOR YOUR KIND ATTENTION