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Green wet processing of new bio-based fibres to increase their lifespan and reduce their environmental impact Teppies Project Brokerage Event 2019 11 october 2019, Brussels Sustainable Fashion in A Circular Economy ReInventFashion 1

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Green wet processing of new bio-based fibres to • increase their lifespan and• reduce their environmental impact

Teppies Project Brokerage Event 201911 october 2019, Brussels

Sustainable Fashion in A Circular Economy

ReInventFashion1

• French Textile Engineering institute with 2 main missions : education and research on textile advanced materials

• Its research laboratory (Gemtex):

➢100 members (30 professors,10 engineers and technicians,56 PhD students)

➢55 RDI programs & 12 patents since 2013

➢3 research groups: Human Centred Design (HCD), Mechanics Textiles Composites (MTC) and Multifonctional Textiles and Processes (MTP) + a cross-cutting axis in sustainabledevelopment

• Fields of application: clothing, aeronautics, transport, medical, wellness, sport & leisure, construction…

ENSAIT

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Sustainable development

ENSAIT – Skills of the MTP Groups

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Topic: CE-FNR-14-2020 – Innovative textiles - reinventing fashion

IA - Single stage - Deadline: 22/01/2020

Project:

• Development of bio-based textiles with high level of performance, recyclability and lowest environmental impact categories, avoiding the release of pollutants and microfibers in water during processing and use phase.

• Ensait aims to optimize wet processing of new-biosourced fibres : scouring, dyeing and finishing. The goal is to cater for appropriate functionalities required for apparels and increase the lifespanand recyclability.

• Ensait has significant experience in sustainable wet processing of all usual of fibres (natural and man-made), and more particulary on flax and polyester fibres.

Project

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ReInventFashion

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Shift from a Linear economy to a more Circular economy

Linear economy Circular economy

End-of Life

Manufacture(materials andprocesses

USE

MAKE USE DISPOSE

Sustainable Fashion in A Circular Economy

Reduce use of new raw material

Re-InventFASHION

Eco-technologies/biotechnologies for a greener wet-processing of new-biosourced fibres

Reduce environmental impact of apparels(manufacture, use, recycling)

Increase LifeSpan catering for slow and more sustainable fashion –Reinvent Fashion

Reduce release of pollutants and microfibers

Upcycling while recycling

Beyond fast Fashion

Cater for appropriate functionalities while reducing impacts during use-phase (less ironing/washing)

Fast fashion

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Eco-technologies/biotechnologies for greener textile wet-processing:to reduce environmental impacts

Eco-technologies (plasma, microwaves, ozone, ultrasounds, Supercritical CO2….)

Biotechnologies

Reduced energy, water, chemical consumption, reduced release of chemicals

Use of bio-based enzymes (lower temperature wet processing)Use of functional bio-based molecules (multifunctional) combined with ecotechnology for improved durability, and reduced number of processing steps. Use of biomordants to improve wash/rub/light durability of bio-based dyes

WET PROCESSINGS : Scouring, Bleaching, dyeing, finishing

WET PROCESSING

water repellent

Fire retardant

Anti bacterial

water

energy

chemicals

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End-of LifeManufacture(materials andprocesses

USE

Increase Lifespan f (fiber quality, textile structure, wet processing)Reduce electricity, and water

consumptionand reduce chemical and microfiber release

Sustainable wet processing(plasma, enzymes, microwaves)

-appropriate durable functionalities with eco-friendly products/processes

Functionalities

-to increase lifespan

-to reduce impacts during production and use-phase

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Better extraction of bio-sourced (natural) fibers-High quality fibers

-Improved flexibility for Fashion useRecyclingSustainable end-of –life wet processingFor upcycling

Green Wet-processing of new-biosourced fibres for a Sustainable Fashion in a Circular Economy Using Eco-technologies/biotechnologies to reduce environmental impacts

Removal of color and finishes(ozone, microwave, Fenton)

(ultrasound, ozone, enzymes)

Washing

Drying

Ironing

ENSAIT SKILLS IN ECOTECHNIOLOGIES AND BIOTECHNOLOGIES

PLASMA : atmospheric plasma (PET)-activation and improved durability of finishing, printing

MICROWAVE(for bio-based functionalisation, eco-friendly dyeing, and upcycling through color removal)

OZONE (for improved recycling-removal of dye and finishing, and for 1-step linen cleaningand bleaching)

ENZYMES (for extraction of bio-based linen fibers, coton bioscouring, wool anti-feltinghydrophilisation of PET)

BIO-BASED FUNCTIONALISATION (Multifunctional molecules/polymers for dyeing, coating, finishing. Ex: Antibacterial, anti-UV, luminescent textiles, soil-release properties, improvedcolor fastness of natural dyes using biomordants – Multifunctional textiles

ENSAIT SKILLS in LCA OF TEXTILE PRODUCTS AND PROCESSES

Life Cycle assessments: « gate to gate », « Cradle to Grave »

Transfer to New Bio-based fibres -natural (ex: Hemp)-artificial cellulosic(ex: viscose)-synthetic (ex: BIOPET, PTT-SORONA)

PET, Linen, cotton Transfer to New Bio-based fibers (cellulosic, BIOPET…)

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Anne

PERWUELZN. M. BEHARY

[email protected]@ensait.fr

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Research projects :• ACTVEX, Interreg (2008/12) - LCA in the textile industry

• ECLIN, PhD Thesis with ECOTLC (2015- 2018) - Rethinking Linen Textile Design for Circular Economy

• DURATEX, Interreg V France - Wallonie-Flanders (2016 /20)- Ecofriendly water and oil repellent textiles for building and architectural applications

• ECyTWIN, Interreg (2018/22) - Eco-cycle Innovation of the Textile and Woodworking Industries

• SMDTEX, Eramus Mundus ( 2013/21) - Joint Doctorate Program about Sustainable Management and Design for Textile: 40 ph D

• OZONEFLAX-(2019-2020)- Région Nord-Picardie- Pre-treatment and bleaching of linen fabrics

ENSAIT projects in substainable development

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Partnership

ENSAIT• Green wet processing

through eco/biotechnologies

• LCA

Coordinator(Search)

TecnatoxWater toxicologyanalysis

Industrial partners(Search)

• Manufacturers of natural fibres

• Manufacturers of new bio-based polymerfibres (artificial or synthetic)

• Yarn manufacturers• Suppliers of • Biobased or eco-

friendly products for functionalisation

End-users(Search)

Research laboratory/IndustryOptimization of textile structure -processing (search)

-for increased apparel lifespan, and comfort-less release of microfibers, less ironing-reduced environmental impacts-easy recyclability

ReInventFashion

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T. AGNHAGE, A. PERWUELZ, N. BEHARY, “Eco-Innovative Coloration and Surface modification of Woven Polyester Fabric Using Bio-Based Materials and Plasma Technology”, Industrial Crops and Products, 2016, 86 : 334–41.(IF=3.18)

S.YASIN, N. BEHARY, G. ROVERO, V. KUMAR, “Statistical analysis of use-phase energy consumption of textile products”, Int J Life Cycle Assess, vol. 21, n° 12, pp. 1776-1788, 2016 ·(IF=3.17)

AGNHAGE T, PERWUELZ A, BEHARY N, “Dyeing of polyester fabric with bio-based madder dye and assessment of environmental impacts using LCA tool.” Fibers and textiles, 2016,3:4-9 ·(IF=0.2)

AGNHAGE T, ZHOU Y, GUAN J, CHEN G, PERWUELZ A, BEHARY N, NIERSTRASZ V Bioactive and multifunctional textile using plant based madder dye: Characterization of UV protection ability and antibacterial activity Fibers and Polymers, 2017, 8(11):2170–2175 (IF=1.113)

S.YASIN, CURTI M., ROVERO G., BEHARY N., A. PERWUELZ., S.GIRAUD, G.MIGLIAVACCA G.CHEN, J. GUAN, “An alternative for the end-of-life phase of flame retardant textile products: Degradation of flame retardant and preliminary settings of energy valorization by gasification”, Bioresources, 2017,12(3):5196-5211 (IF =1.334)

T. AGNHAGE, A. PERWUELZ, N. BEHARY, Towards Sustainable Rubia Tinctorum L. Dyeing of Woven Fabric: How Life Cycle Assessment Can Contribute, Journal of Cleaner Production, 2017, 141: 1221–1230.(IF=5.71)

I. BELHAJ KHALIFA, N. LADHARI, N. BEHARY, C. CAMPAGNE, “Crosslinking of sericin on air atmospheric plasma treated polyester fabric,”, J. Text. I., 2017, 108 (5) (IF=1.007)

S.YASIN, BEHARY N., A. PERWUELZ., J. GUAN, Life cycle assessment of flame retardant cotton textiles with optimized end-of-life phase, Journal of Cleaner Production, 2017, 172, DOI 10.1016/j.jclepro.2017.10.198.(IF=5.71)

Ajinkya Powar1, 2, 3, 4, Anne Perwuelz1, Nemeshwaree Behary1, Levinh Hoang5, Aussenac Thierry5

COLOR STRIPPING OF THE REACTIVE DYED FABRIC BY CONVENTIONAL AND OZONE ASSISTED PROCESS-A COMPARATIVE STUDY, IOA World Congress & Exhibition, Nice, France-20-25 October 2019

Amira Belhaj Rhouma1, 2, Anne Perwuelz 1, Nemeshwaree Behary1, Xavier Legrand1, Levinh Hoang 2, Thierry Aussenac 2, Comparison of conventional bleaching treatments and ozone bleaching treatment of linen fabrics for clothing and furniture applications, IOA World Congress & Exhibition, Nice, France-20-25 October 2019

WOOL ENZYMATIC AND CHEMICAL SHRINK-PROOFING TREATMENTS AND COMPARISON OF ENVIRONMENTAL IMPACTS USING LCA ANALYSIS, submitted

Mercerizing of cotton for the improvement of the environmental impacts of shirts, June 2013Melliand Textilberichte 94(2):116-118

V. TAKKE, N. BEHARY, A. PERWUELZ, C. CAMPAGNE, “Studies on the atmospheric air–plasma treatment of PET (polyethylene terephtalate) woven fabrics: Effect of process parameters and of aging”. Journal of Applied Polymer Science vol. 114 issue 1, 5 October 2009. p. 348 – 357

A. KERKENI, D .GUPTA, A. PERWUELZ, N. BEHARY, “Chemical grafting of curcumin at polyethylene terephthalate woven fabric surface using a prior surface activation with ultraviolet excimer lamp”. Journal of Applied Polymer Science vol. 120 issue 3, 5 May 2011. p. 1583-1590

V. TAKKE, N. BEHARY, A. PERWUELZ, C. CAMPAGNE, “Surface and adhesion properties of poly(ethylene glycol) on polyester(polyethylene terephthalate) fabric surface: Effect of air-atmospheric plasma treatment “. Journal of Applied Polymer Science vol. 122 issue 4, 15 November 2011. p. 2621-2629

A.KERKENI, N.BEHARY A. PERWUELZ , D. GUPTA, “Dyeing of PET woven fabric with Curcumin: Effect of dye concentrations and surface pre-activation using Air-atmospheric plasma and UV excimer treatment, Coloration Technology vol. 128, N° 3 , 2012. p. 223-229

A.KERKENI, N. BEHARY, P.DHULSTER , N.E.CHIHIB, A.PERWUELZ, “Study on the Effect of Plasma Treatment of Woven Polyester Fabrics with Respect to Nisin Adsorption and Antibacterial Activity”, Journal of Applied Polymer Science, Special Issue: Polymers for Biomedical Applications, Vol. 129, Issue 2, 2013; 866–873.

N. BEHARY, A. KERKENI, A.PERWUELZ, N.E.CHIHIB , P.DHULSTER, “Bioactivation of PETwoven fabrics using alginate biopolymer and the bacteriocin nisin”, Textile Research Journal, July,2, 2013.

V. PASQUET, A. PERWUELZ, N. BEHARY, J. ISAAD, “Vanillin, a potential carrier for low temperature dyeing of polyester fabrics”, Journal of Cleaner Production, Volume 43, March 2013, 20–26

V. PASQUET, A. PERWUELZ, N. BEHARY, “Environmental Impacts of Chemical/Ecotechnological /Biotechnological hydrophilisation of Polyester fabrics”, Journal of Cleaner Production, Volume 65, 15 February 2014, p. 551–560 (IF=5.7)

S. OTERO CAMAÑO, N. BEHARY, P. VROMAN, C.CAMPAGNE, “Comparison of Bio and Eco technologies with chemical methods for pre-treatment of flax fibers: impact on fiber properties, Journal of Engineered Fibers and Fabrics , Volume 9, 4, December 2014. (IF=0.99)

S. YASIN, N. BEHARY, S. GIRAUD, A. PERWUELZ. “In situ degradation of organophosphorus flame retardant on cellulosic fabric using advanced oxidation process: a study on degradation and characterization”, Polymer Degradation and Stability, 2016, 126:1–8 (IF=3.57)

RESEARCH ON ECOTECHNOLOGIES/BIOTECHNOLOGIES

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Thank you for your attention

N. Massika Behary, Professor - [email protected] Perwuelz, Professor - [email protected] Doumeng, Project manager – [email protected]

Contacts

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ReInventFashion

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