organic reactions. complete combustion hydrocarbon ignited in a condition of excess oxygen will...
DESCRIPTION
Combustion is an exothermic reaction (so the net reaction involves the net output of heat energy)TRANSCRIPT
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Organic Reactions
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Complete Combustion• Hydrocarbon ignited in a
condition of excess oxygen will combust (oxidize)• Forms carbon dioxide,
energy and water
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• Combustion is an exothermic reaction (so the net reaction involves the net output of heat energy)
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Example
• Write the chemical equation that describes the combustion of propane in an oxygenated environment.
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Incomplete Combustion• chemical combustion is
assumed complete unless otherwise stated• If the oxygen is
stoichiometrically limited, the combustion is incomplete
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Products of Incomplete Combustion• CO2, CO and C are all created
and manifest as soot or ash
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Substitution• One or more hydrogen atoms
are replaced by another atom (or group)• Occurs on alkanes• Only 1 atom may be added per
substitution
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•Often occurs with halogens (producing a halocarbon and hydrogen halide)
HC + halogen halocarbon + hydrogen halide
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Examples
1. Reaction of butane with bromine
2. Reaction of toluene with iodine
3. Reaction of decane with fluorine
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Addition• Addition reactions involve the
breaking of UNSATURATED BONDS (double or triple bonds)
• 4 types of addition:
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1. Hydrogenation• hydrogen atoms are added
to an unsaturated compound to make it more saturated
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2. Hydration• Water is added to
unsaturated hydrocarbons to create an alcohol
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3. Addition of Halogens, Hydrogen Halides and Acids
• Halogens break the unsaturated bonds to add attached atoms
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4. Multiple Additions• Multiple molecular additions
are usually additions with aromatics or alkynes
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Examples
1. The addition of hydrogen to propene
2. The addition of water to cyclohexene
3. The addition of fluorine to ethyne can occur twice
4. The addition of water to prop-1-yne followed by the addition of iodine
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Cracking• In the presence of a catalyst
and / or heat, hydrogen gas can be used to split hydrocarbon chains• addition of 2 hydrogens
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Example
• Cracking 2,3,5-trimethyl nonane on the 4th bond
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Reforming• Opposite of hydrocarbon
cracking• Heat and / or catalyst is used
to join smaller molecules• Hydrogen gas is produced
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Dehydrogenation • Creating an unsaturated bond from a
saturated hydrocarbon
Example: • Creating butene from butane in the presence
of heat
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Esterification• Condensation reaction
between a carboxylic acid and an alcohol produces an ester and water
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• The hydrogen atom leaves the alcohol and a hydroxyl group leaves the carboxylic acid (creating water)
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Example
1. The reaction between ethanol and butanoic acid
2. The reaction between pentanoic acid and decanol
3. The reaction between benzenoic acid and phenol
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Elimination• Reaction of an alkyl halide
with a hydroxide ion to form an alkene, a halide ion and water
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• The hydroxide (OH-) takes a hydrogen from the hydrocarbon to form water• The halide breaks away from
the hydrocarbon chain and the HC forms a double bond
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Example
1. The addition of hydroxide ion to 3-chloroheptane
2. The addition of hydroxide ion to iodo-cyclooctane
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