oil refinery

Upload: techzones

Post on 16-Oct-2015

37 views

Category:

Documents


0 download

DESCRIPTION

Oil Refinery

TRANSCRIPT

  • 5/26/2018 Oil Refinery

    1/11

    Oil refinery 1

    Oil refinery

    Anacortes Refinery (Tesoro), on the north end of March Point southeast of

    Anacortes, Washington

    An oil refinery or petroleum refinery is an

    industrial process plant where crude oil is

    processed and refined into more useful

    products such as petroleum naphtha,

    gasoline, diesel fuel, asphalt base, heating

    oil, kerosene and liquefied petroleum gas.

    Oil refineries are typically large, sprawling

    industrial complexes with extensive piping

    running throughout, carrying streams of

    fluids between large chemical processing

    units. In many ways, oil refineries use much

    of the technology of, and can be thought of,

    as types of chemical plants. The crude oil

    feedstock has typically been processed by an

    oil production plant. There is usually an oil

    depot (tank farm) at or near an oil refinery

    for the storage of incoming crude oil

    feedstock as well as bulk liquid products.

    An oil refinery is considered an essential part of the downstream side of the petroleum industry.

    http://en.wikipedia.org/w/index.php?title=Petroleum_industryhttp://en.wikipedia.org/w/index.php?title=Downstream_%28petroleum_industry%29http://en.wikipedia.org/w/index.php?title=Refineryhttp://en.wikipedia.org/w/index.php?title=Oil_depothttp://en.wikipedia.org/w/index.php?title=Oil_depothttp://en.wikipedia.org/w/index.php?title=Oil_production_planthttp://en.wikipedia.org/w/index.php?title=Chemical_planthttp://en.wikipedia.org/w/index.php?title=Chemical_processhttp://en.wikipedia.org/w/index.php?title=Fluidhttp://en.wikipedia.org/w/index.php?title=Pipinghttp://en.wikipedia.org/w/index.php?title=Industryhttp://en.wikipedia.org/w/index.php?title=Liquefied_petroleum_gashttp://en.wikipedia.org/w/index.php?title=Kerosenehttp://en.wikipedia.org/w/index.php?title=Heating_oilhttp://en.wikipedia.org/w/index.php?title=Heating_oilhttp://en.wikipedia.org/w/index.php?title=Asphalthttp://en.wikipedia.org/w/index.php?title=Diesel_fuelhttp://en.wikipedia.org/w/index.php?title=Gasolinehttp://en.wikipedia.org/w/index.php?title=Petroleum_naphthahttp://en.wikipedia.org/w/index.php?title=Crude_oilhttp://en.wikipedia.org/w/index.php?title=Factoryhttp://en.wikipedia.org/w/index.php?title=Industrial_processhttp://en.wikipedia.org/w/index.php?title=File%3AAnacortes_Refinery_31911.JPGhttp://en.wikipedia.org/w/index.php?title=Anacortes%2C_Washingtonhttp://en.wikipedia.org/w/index.php?title=Tesoro
  • 5/26/2018 Oil Refinery

    2/11

    Oil refinery 2

    Operation

    Crude oil is separated into fractions by fractional distillation.

    The fractions at the top of the fractionating column have

    lower boiling points than the fractions at the bottom. The

    heavy bottom fractions are often cracked into lighter, more

    useful products. All of the fractions are processed further in

    other refining units.

    Raw or unprocessed crude oil is not generally useful in

    industrial applications, although "light, sweet" (low

    viscosity, low sulfur) crude oil has been used directly as a

    burner fuel to produce steam for the propulsion of seagoing

    vessels. The lighter elements, however, form explosive

    vapors in the fuel tanks and are therefore hazardous,

    especially in warships. Instead, the hundreds of different

    hydrocarbon molecules in crude oil are separated in a

    refinery into components which can be used as fuels,

    lubricants, and as feedstocks in petrochemical processes that

    manufacture such products as plastics, detergents, solvents,

    elastomers and fibers such as nylon and polyesters.

    Petroleum fossil fuels are burned in internal combustion

    engines to provide power for ships, automobiles, aircraftengines, lawn mowers, chainsaws, and other machines.

    Different boiling points allow the hydrocarbons to be

    separated by distillation. Since the lighter liquid products are

    in great demand for use in internal combustion engines, a

    modern refinery will convert heavy hydrocarbons and lighter

    gaseous elements into these higher value products.

    The oil refinery in Haifa, Israel is capable of

    processing about 9 million tons (66 million

    barrels) of crude oil a year. Its two cooling towers

    are landmarks of the city's skyline.

    Oil can be used in a variety of ways because it contains hydrocarbons

    of varying molecular masses, forms and lengths such as paraffins,

    aromatics, naphthenes (or cycloalkanes), alkenes, dienes, and alkynes.

    While the molecules in crude oil include different atoms such as sulfur

    and nitrogen, the hydrocarbons are the most common form of

    molecules, which are molecules of varying lengths and complexity

    made of hydrogen and carbon atoms, and a small number of oxygen

    atoms. The differences in the structure of these molecules account for

    their varying physical and chemical properties, and it is this variety

    that makes crude oil useful in a broad range of several applications.

    Once separated and purified of any contaminants and impurities, the

    fuel or lubricant can be sold without further processing. Smaller

    molecules such as isobutane and propylene or butylenes can be

    recombined to meet specific octane requirements by processes such as alkylation, or less commonly, dimerization.

    Octane grade of gasoline can also be improved by catalytic reforming, which involves removing hydrogen from

    hydrocarbons producing compounds with higher octane ratings such as aromatics. Intermediate products such as

    gasoils can even be reprocessed to break a heavy, long-chained oil into a lighter short-chained one, by various forms

    of cracking such as fluid catalytic cracking, thermal cracking, and hydrocracking. The final step in gasoline

    production is the blending of fuels with different octane ratings, vapor pressures, and other properties to meetproduct specifications.

    http://en.wikipedia.org/w/index.php?title=Vapor_pressurehttp://en.wikipedia.org/w/index.php?title=Hydrocrackinghttp://en.wikipedia.org/w/index.php?title=Thermal_crackinghttp://en.wikipedia.org/w/index.php?title=Fluid_catalytic_crackinghttp://en.wikipedia.org/w/index.php?title=Cracking_%28chemistry%29http://en.wikipedia.org/w/index.php?title=Gasoilhttp://en.wikipedia.org/w/index.php?title=Aromaticshttp://en.wikipedia.org/w/index.php?title=Hydrogenhttp://en.wikipedia.org/w/index.php?title=Catalytic_reforminghttp://en.wikipedia.org/w/index.php?title=Dimer_%28chemistry%29http://en.wikipedia.org/w/index.php?title=Alkylationhttp://en.wikipedia.org/w/index.php?title=Octane_ratinghttp://en.wikipedia.org/w/index.php?title=Butylenehttp://en.wikipedia.org/w/index.php?title=Propylenehttp://en.wikipedia.org/w/index.php?title=Isobutanehttp://en.wikipedia.org/w/index.php?title=Chemical_propertyhttp://en.wikipedia.org/w/index.php?title=Physical_propertyhttp://en.wikipedia.org/w/index.php?title=Atomhttp://en.wikipedia.org/w/index.php?title=Carbonhttp://en.wikipedia.org/w/index.php?title=Hydrogenhttp://en.wikipedia.org/w/index.php?title=Alkynehttp://en.wikipedia.org/w/index.php?title=Dienehttp://en.wikipedia.org/w/index.php?title=Alkenehttp://en.wikipedia.org/w/index.php?title=Cycloalkanehttp://en.wikipedia.org/w/index.php?title=Naphthenehttp://en.wikipedia.org/w/index.php?title=Aromatichttp://en.wikipedia.org/w/index.php?title=Alkanehttp://en.wikipedia.org/w/index.php?title=Molecular_masshttp://en.wikipedia.org/w/index.php?title=File%3AHaifa_Refinery_by_David_Shankbone.jpghttp://en.wikipedia.org/w/index.php?title=Cooling_towerhttp://en.wikipedia.org/w/index.php?title=Crude_oilhttp://en.wikipedia.org/w/index.php?title=Haifa%2C_Israelhttp://en.wikipedia.org/w/index.php?title=Hydrocarbonshttp://en.wikipedia.org/w/index.php?title=Distillationhttp://en.wikipedia.org/w/index.php?title=Hydrocarbonhttp://en.wikipedia.org/w/index.php?title=Boiling_pointhttp://en.wikipedia.org/w/index.php?title=Enginehttp://en.wikipedia.org/w/index.php?title=Fossil_fuelshttp://en.wikipedia.org/w/index.php?title=Petroleumhttp://en.wikipedia.org/w/index.php?title=Polyestershttp://en.wikipedia.org/w/index.php?title=Nylonhttp://en.wikipedia.org/w/index.php?title=Fiberhttp://en.wikipedia.org/w/index.php?title=Elastomerhttp://en.wikipedia.org/w/index.php?title=Solventhttp://en.wikipedia.org/w/index.php?title=Detergenthttp://en.wikipedia.org/w/index.php?title=Plastichttp://en.wikipedia.org/w/index.php?title=Petrochemicalhttp://en.wikipedia.org/w/index.php?title=Lubricantshttp://en.wikipedia.org/w/index.php?title=Fuelshttp://en.wikipedia.org/w/index.php?title=Warshipshttp://en.wikipedia.org/w/index.php?title=Sulfurhttp://en.wikipedia.org/w/index.php?title=File%3ACrude_Oil_Distillation-en.svghttp://en.wikipedia.org/w/index.php?title=Cracking_%28chemistry%29http://en.wikipedia.org/w/index.php?title=Boiling_pointhttp://en.wikipedia.org/w/index.php?title=Fractionating_columnhttp://en.wikipedia.org/w/index.php?title=Fractional_distillationhttp://en.wikipedia.org/w/index.php?title=Crude_oil
  • 5/26/2018 Oil Refinery

    3/11

    Oil refinery 3

    Oil refineries are large scale plants, processing about a hundred thousand to several hundred thousand barrels of

    crude oil a day. Because of the high capacity, many of the units operate continuously, as opposed to processing in

    batches, at steady state or nearly steady state for months to years. The high capacity also makes process optimization

    and advanced process control very desirable.

    Major productsPetroleum products are usually grouped into three categories: light distillates (LPG, gasoline, naphtha), middle

    distillates (kerosene, diesel), heavy distillates and residuum (heavy fuel oil, lubricating oils, wax, asphalt). This

    classification is based on the way crude oil is distilled and separated into fractions (called distillates and residuum) as

    in the above drawing.

    Liquified petroleum gas (LPG)

    Gasoline (also known as petrol)

    Naphtha

    Kerosene and related jet aircraft fuels

    Diesel fuel

    Fuel oils

    Lubricating oils

    Paraffin wax

    Asphalt and tar

    Petroleum coke

    Sulfur

    Oil refineries also produce various intermediate products such as hydrogen, light hydrocarbons, reformate and

    pyrolysis gasoline. These are not usually transported but instead are blended or processed further on-site. Chemical

    plants are thus often adjacent to oil refineries. For example, light hydrocarbons are steam-cracked in an ethylene

    plant, and the produced ethylene is polymerized to produce polyethene.

    Common process units found in a refinery

    Storage tanks and towers at Shell Puget Sound

    Refinery (Shell Oil Company), Anacortes,

    Washington

    Desalter unit washes out salt from the crude oil before it enters the

    atmospheric distillation unit.

    Atmospheric distillation unit distills crude oil into fractions. See

    Continuous distillation.

    Vacuum distillation unit further distills residual bottoms after

    atmospheric distillation.

    Naphtha hydrotreater unit uses hydrogen to desulfurize naphthafrom atmospheric distillation. Must hydrotreat the naphtha before

    sending to a Catalytic Reformer unit.

    Catalytic reformer unit is used to convert the naphtha-boiling range

    molecules into higher octane reformate (reformer product). The

    reformate has higher content of aromatics and cyclic hydrocarbons).

    An important byproduct of a reformer is hydrogen released during the catalyst reaction. The hydrogen is used

    either in the hydrotreaters or the hydrocracker.

    Distillate hydrotreater unit desulfurizes distillates (such as diesel) after atmospheric distillation.

    Fluid catalytic cracker (FCC) unit upgrades heavier fractions into lighter, more valuable products.

    Hydrocracker unit uses hydrogen to upgrade heavier fractions into lighter, more valuable products.

    http://en.wikipedia.org/w/index.php?title=Cracking_%28chemistry%29http://en.wikipedia.org/w/index.php?title=Fluid_catalytic_crackinghttp://en.wikipedia.org/w/index.php?title=Reformatehttp://en.wikipedia.org/w/index.php?title=Catalytic_reforminghttp://en.wikipedia.org/w/index.php?title=Hydrogenhttp://en.wikipedia.org/w/index.php?title=Hydrotreaterhttp://en.wikipedia.org/w/index.php?title=Vacuum_distillationhttp://en.wikipedia.org/w/index.php?title=Continuous_distillationhttp://en.wikipedia.org/w/index.php?title=Desalterhttp://en.wikipedia.org/w/index.php?title=File%3AAnacortes_Refinery_32017.JPGhttp://en.wikipedia.org/w/index.php?title=Anacortes%2C_Washingtonhttp://en.wikipedia.org/w/index.php?title=Anacortes%2C_Washingtonhttp://en.wikipedia.org/w/index.php?title=Shell_Oil_Companyhttp://en.wikipedia.org/w/index.php?title=Polyethenehttp://en.wikipedia.org/w/index.php?title=Ethylenehttp://en.wikipedia.org/w/index.php?title=Pyrolysis_gasolinehttp://en.wikipedia.org/w/index.php?title=Reformatehttp://en.wikipedia.org/w/index.php?title=Hydrogenhttp://en.wikipedia.org/w/index.php?title=Sulfurhttp://en.wikipedia.org/w/index.php?title=Petroleum_cokehttp://en.wikipedia.org/w/index.php?title=Tarhttp://en.wikipedia.org/w/index.php?title=Asphalthttp://en.wikipedia.org/w/index.php?title=Paraffin_waxhttp://en.wikipedia.org/w/index.php?title=Lubricant%23Base_oil_groupshttp://en.wikipedia.org/w/index.php?title=Fuel_oilhttp://en.wikipedia.org/w/index.php?title=Diesel_fuelhttp://en.wikipedia.org/w/index.php?title=Jet_fuelhttp://en.wikipedia.org/w/index.php?title=Kerosenehttp://en.wikipedia.org/w/index.php?title=Naphthahttp://en.wikipedia.org/w/index.php?title=Gasolinehttp://en.wikipedia.org/w/index.php?title=Liquified_petroleum_gashttp://en.wiktionary.org/wiki/residuumhttp://en.wiktionary.org/wiki/distillatehttp://en.wikipedia.org/w/index.php?title=Advanced_process_controlhttp://en.wikipedia.org/w/index.php?title=Process_optimizationhttp://en.wikipedia.org/w/index.php?title=Steady_statehttp://en.wikipedia.org/w/index.php?title=Batch_productionhttp://en.wikipedia.org/w/index.php?title=Continuous_productionhttp://en.wikipedia.org/w/index.php?title=Barrel_%28volume%29
  • 5/26/2018 Oil Refinery

    4/11

    Oil refinery 4

    Visbreaking unit upgrades heavy residual oils by thermally cracking them into lighter, more valuable reduced

    viscosity products.

    Merox unit treats LPG, kerosene or jet fuel by oxidizing mercaptans to organic disulfides.

    Alternative processes for removing mercaptans are known, e.g. doctor sweetening process and caustic washing.

    Coking units (delayed coking, fluid coker, and flexicoker) process very heavy residual oils into gasoline and

    diesel fuel, leaving petroleum coke as a residual product. Alkylation unit produces high-octane component for gasoline blending.

    Dimerization unit converts olefins into higher-octane gasoline blending components. For example, butenes can be

    dimerized into isooctene which may subsequently be hydrogenated to form isooctane. There are also other uses

    for dimerization. Gasoline produced trough dimerization is highly unsaturated and very reactive. It tends

    spontaneously to form gums. For this reason the effluent from the dimerization need to be blended into the

    finished gasoline pool immediately or hydrogenated.

    Isomerization unit converts linear molecules to higher-octane branched molecules for blending into gasoline or

    feed to alkylation units.

    Steam reforming unit produces hydrogen for the hydrotreaters or hydrocracker.

    Liquified gas storage vessels store propane and similar gaseous fuels at pressure sufficient to maintain them inliquid form. These are usually spherical vessels or "bullets" (i.e., horizontal vessels with rounded ends).

    Storage tanks store crude oil and finished products, usually cylindrical, with some sort of vapor emission control

    and surrounded by an earthen berm to contain spills.

    Amine gas treater, Claus unit, and tail gas treatment convert hydrogen sulfide from hydrodesulfurization into

    elemental sulfur.

    Utility units such as cooling towers circulate cooling water, boiler plants generates steam, and instrument air

    systems include pneumatically operated control valves and an electrical substation.

    Wastewater collection and treating systems consist of API separators, dissolved air flotation (DAF) units and

    further treatment units such as an activated sludge biotreater to make water suitable for reuse or for disposal.

    Solvent refining units use solvent such as cresol or furfural to remove unwanted, mainly aromatics fromlubricating oil stock or diesel stock.

    Solvent dewaxing units remove the heavy waxy constituents petrolatum from vacuum distillation products.

    Flow diagram of typical refinery

    The image below is a schematic flow diagram of a typical oil refinery[1]

    that depicts the various unit processes and

    the flow of intermediate product streams that occurs between the inlet crude oil feedstock and the final end products.

    The diagram depicts only one of the literally hundreds of different oil refinery configurations. The diagram also does

    not include any of the usual refinery facilities providing utilities such as steam, cooling water, and electric power as

    well as storage tanks for crude oil feedstock and for intermediate products and end products.[2][3][4]

    http://en.wikipedia.org/w/index.php?title=Diagramhttp://en.wikipedia.org/w/index.php?title=Chemical_plant%23Chemical_processeshttp://en.wikipedia.org/w/index.php?title=Process_flow_diagramhttp://en.wikipedia.org/w/index.php?title=Petrolatumhttp://en.wikipedia.org/w/index.php?title=Furfuralhttp://en.wikipedia.org/w/index.php?title=Cresolhttp://en.wikipedia.org/w/index.php?title=Activated_sludgehttp://en.wikipedia.org/w/index.php?title=Dissolved_air_flotationhttp://en.wikipedia.org/w/index.php?title=API_separatorhttp://en.wikipedia.org/w/index.php?title=Wastewaterhttp://en.wikipedia.org/w/index.php?title=Electrical_substationhttp://en.wikipedia.org/w/index.php?title=Control_valveshttp://en.wikipedia.org/w/index.php?title=Steamhttp://en.wikipedia.org/w/index.php?title=Boilerhttp://en.wikipedia.org/w/index.php?title=Cooling_towershttp://en.wikipedia.org/w/index.php?title=Hydrodesulfurizationhttp://en.wikipedia.org/w/index.php?title=Hydrogen_sulfidehttp://en.wikipedia.org/w/index.php?title=Claus_processhttp://en.wikipedia.org/w/index.php?title=Amine_gas_treaterhttp://en.wikipedia.org/w/index.php?title=Bermhttp://en.wikipedia.org/w/index.php?title=Steam_reforminghttp://en.wikipedia.org/w/index.php?title=Isomerizationhttp://en.wikipedia.org/w/index.php?title=Isooctanehttp://en.wikipedia.org/w/index.php?title=Butenehttp://en.wikipedia.org/w/index.php?title=Olefinshttp://en.wikipedia.org/w/index.php?title=Dimer_%28chemistry%29http://en.wikipedia.org/w/index.php?title=Alkylationhttp://en.wikipedia.org/w/index.php?title=Delayed_cokinghttp://en.wikipedia.org/w/index.php?title=Coker_unithttp://en.wikipedia.org/w/index.php?title=Doctor_sweetening_processhttp://en.wikipedia.org/w/index.php?title=Disulfidehttp://en.wikipedia.org/w/index.php?title=Mercaptanhttp://en.wikipedia.org/w/index.php?title=Meroxhttp://en.wikipedia.org/w/index.php?title=Visbreaker
  • 5/26/2018 Oil Refinery

    5/11

    Oil refinery 5

    Schematic flow diagram of a typical oil refinery

    There are many process configurations other than that depicted above. For example, the vacuum distillation unit may

    also produce fractions that can be refined into endproducts such as: spindle oil used in the textile industry, light

    machinery oil, motor oil, and various waxes.

    The crude oil distillation unit

    The crude oil distillation unit (CDU) is the first processing unit in virtually all petroleum refineries. The CDU distills

    the incoming crude oil into various fractions of different boiling ranges, each of which are then processed further in

    the other refinery processing units. The CDU is often referred to as the atmospheric distillation unit because it

    operates at slightly above atmospheric pressure.

    Below is a schematic flow diagram of a typical crude oil distillation unit. The incoming crude oil is preheated byexchanging heat with some of the hot, distilled fractions and other streams. It is then desalted to remove inorganic

    salts (primarily sodium chloride).

    Following the desalter, the crude oil is further heated by exchanging heat with some of the hot, distilled fractions and

    other streams. It is then heated in a fuel-fired furnace (fired heater) to a temperature of about 398 C and routed into

    the bottom of the distillation unit.

    The cooling and condensing of the distillation tower overhead is provided partially by exchanging heat with the

    incoming crude oil and partially by either an air-cooled or water-cooled condenser. Additional heat is removed from

    the distillation column by a pumparound system as shown in the diagram below.

    As shown in the flow diagram, the overhead distillate fraction from the distillation column is naphtha. The fractionsremoved from the side of the distillation column at various points between the column top and bottom are called

    sidecuts. Each of the sidecuts (i.e., the kerosene, light gas oil and heavy gas oil) is cooled by exchanging heat with

    the incoming crude oil. All of the fractions (i.e., the overhead naphtha, the sidecuts and the bottom residue) are sent

    to intermediate storage tanks before being processed further.

    http://en.wikipedia.org/w/index.php?title=Vacuum_distillationhttp://en.wikipedia.org/w/index.php?title=File%3ARefineryFlow.png
  • 5/26/2018 Oil Refinery

    6/11

    Oil refinery 6

    Schematic flow diagram of a typical crude oil distillation unit as used in petroleum crude oil refineries.

    Specialty end products

    These require blending various feedstocks, mixing appropriate additives, providing short term storage, and

    preparation for bulk loading to trucks, barges, product ships, and railcars:

    Gaseous fuels such as propane, stored and shipped in liquid form under pressure in specialized railcars to

    distributors.

    Lubricants (produces light machine oils, motor oils, and greases, adding viscosity stabilizers as required), usually

    shipped in bulk to an offsite packaging plant.

    Wax (paraffin), used in the packaging of frozen foods, among others. May be shipped in bulk to a site to prepare

    as packaged blocks.

    Sulfur (or sulfuric acid), byproducts of sulfur removal from petroleum which may have up to a couple percentsulfur as organic sulfur-containing compounds. Sulfur and sulfuric acid are useful industrial materials. Sulfuric

    acid is usually prepared and shipped as the acid precursor oleum.

    Bulk tar shipping for offsite unit packaging for use in tar-and-gravel roofing.

    Asphalt unit. Prepares bulk asphalt for shipment.

    Petroleum coke, used in specialty carbon products or as solid fuel.

    Petrochemicals or petrochemical feedstocks, which are often sent to petrochemical plants for further processing in

    a variety of ways. The petrochemicals may be olefins or their precursors, or various types of aromatic

    petrochemicals.

    http://en.wikipedia.org/w/index.php?title=Aromatichttp://en.wikipedia.org/w/index.php?title=Olefinhttp://en.wikipedia.org/w/index.php?title=Chemical_planthttp://en.wikipedia.org/w/index.php?title=Petrochemicalhttp://en.wikipedia.org/w/index.php?title=Petroleum_cokehttp://en.wikipedia.org/w/index.php?title=Asphalthttp://en.wikipedia.org/w/index.php?title=Tarhttp://en.wikipedia.org/w/index.php?title=Oleumhttp://en.wikipedia.org/w/index.php?title=Sulfuric_acidhttp://en.wikipedia.org/w/index.php?title=Sulfurhttp://en.wikipedia.org/w/index.php?title=Frozen_foodhttp://en.wikipedia.org/w/index.php?title=Waxhttp://en.wikipedia.org/w/index.php?title=Viscosityhttp://en.wikipedia.org/w/index.php?title=Grease_%28lubricant%29http://en.wikipedia.org/w/index.php?title=Motor_oilhttp://en.wikipedia.org/w/index.php?title=Lubricanthttp://en.wikipedia.org/w/index.php?title=Propanehttp://en.wikipedia.org/w/index.php?title=File%3ACrude_Oil_Distillation_Unit.png
  • 5/26/2018 Oil Refinery

    7/11

    Oil refinery 7

    Siting/locating of petroleum refineries

    A party searching for a site to construct a refinery or a chemical plant needs to consider the following issues:

    The site has to be reasonably far from residential areas.

    Infrastructure should be available for supply of raw materials and shipment of products to markets.

    Energy to operate the plant should be available. Facilities should be available for waste disposal.

    Refineries which use a large amount of steam and cooling water need to have an abundant source of water. Oil

    refineries therefore are often located nearby navigable rivers or on a sea shore, nearby a port. Such location also

    gives access to transportation by river or by sea. The advantages of transporting crude oil by pipeline are evident,

    and oil companies often transport a large volume of fuel to distribution terminals by pipeline. Pipeline may not be

    practical for products with small output, and rail cars, road tankers, and barges are used.

    Petrochemical plants and solvent manufacturing (fine fractionating) plants need spaces for further processing of a

    large volume of refinery products for further processing, or to mix chemical additives with a product at source rather

    than at blending terminals.

    Safety and environmental concerns

    Fire-extinguishing operations after the Texas City

    refinery explosion.

    The refining process releases a number of different chemicals into the

    atmosphere (see AP 42 Compilation of Air Pollutant Emission Factors)

    and a notable odor normally accompanies the presence of a refinery.

    Aside from air pollution impacts there are also wastewater concerns,

    risks of industrial accidents such as fire and explosion, and noise health

    effects due to industrial noise.

    Many governments worldwide have mandated restrictions oncontaminants that refineries release, and most refineries have installed

    the equipment needed to comply with the requirements of the pertinent

    environmental protection regulatory agencies. In the United States,

    there is strong pressure to prevent the development of new refineries, and no major refinery has been built in the

    country since Marathon's Garyville, Louisiana facility in 1976. However, many existing refineries have been

    expanded during that time. Environmental restrictions and pressure to prevent construction of new refineries may

    have also contributed to rising fuel prices in the United States. Additionally, many refineries (more than 100 since

    the 1980s) have closed due to obsolescence and/or merger activity within the industry itself.

    Environmental and safety concerns mean that oil refineries are sometimes located some distance away from major

    urban areas. Nevertheless, there are many instances where refinery operations are close to populated areas and pose

    health risks In California's Contra Costa County and Solano County, a shoreline necklace of refineries, built in the

    early 20th century before this area was populated, and associated chemical plants are adjacent to urban areas in

    Richmond, Martinez, Pacheco, Concord, Pittsburg, Vallejo and Benicia, with occasional accidental events that

    require "shelter in place" orders to the adjacent populations.

    http://en.wikipedia.org/w/index.php?title=Shelter_in_placehttp://en.wikipedia.org/w/index.php?title=Benicia%2C_Californiahttp://en.wikipedia.org/w/index.php?title=Vallejo%2C_Californiahttp://en.wikipedia.org/w/index.php?title=Pittsburg%2C_Californiahttp://en.wikipedia.org/w/index.php?title=Concord%2C_Californiahttp://en.wikipedia.org/w/index.php?title=Pacheco%2C_Californiahttp://en.wikipedia.org/w/index.php?title=Martinez%2C_Californiahttp://en.wikipedia.org/w/index.php?title=Chevron_Richmond_Refineryhttp://en.wikipedia.org/w/index.php?title=Solano_Countyhttp://en.wikipedia.org/w/index.php?title=Contra_Costa_Countyhttp://en.wikipedia.org/w/index.php?title=Californiahttp://en.wikipedia.org/w/index.php?title=Garyville%2C_Louisianahttp://en.wikipedia.org/w/index.php?title=Marathon_Petroleum_Companyhttp://en.wikipedia.org/w/index.php?title=Industrial_noisehttp://en.wikipedia.org/w/index.php?title=Noise_health_effectshttp://en.wikipedia.org/w/index.php?title=Noise_health_effectshttp://en.wikipedia.org/w/index.php?title=Industrial_accidenthttp://en.wikipedia.org/w/index.php?title=Odorhttp://en.wikipedia.org/w/index.php?title=AP_42_Compilation_of_Air_Pollutant_Emission_Factorshttp://en.wikipedia.org/w/index.php?title=Earth%27s_atmospherehttp://en.wikipedia.org/w/index.php?title=File%3ABP_PLANT_EXPLOSION-1_lowres2.jpg
  • 5/26/2018 Oil Refinery

    8/11

    Oil refinery 8

    Corrosion problems and prevention

    Petroleum refineries run as efficiently as possible to reduce costs. One major factor that decreases efficiency is

    corrosion of the metallic components found throughout refining process. Corrosion causes the failure of equipment

    items as well as dictating the maintenance schedule of the refinery, during which part or all of the refinery must be

    shut down. The corrosion-related direct costs in the U.S. petroleum industry as of 1996 was estimated as US$3.7

    billion per year.[5][6]

    Corrosion occurs in various forms in the refining process, such as pitting corrosion from water droplets,

    embrittlement from hydrogen, and stress corrosion cracking from sulfide attack.[7]

    From a materials standpoint,

    carbon steel is used for upwards of 80 per cent of refinery components, which is beneficial due to its low cost.

    Carbon steel is resistant to the most common forms of corrosion, particularly from hydrocarbon impurities at

    temperatures below 205 C, but other corrosive chemicals and environments prevent its use everywhere. Common

    replacement materials are low alloy steels containing chromium and molybdenum, with stainless steels containing

    more chromium dealing with more corrosive environments. More expensive materials commonly used are nickel,

    titanium, and copper alloys. These are primarily saved for the most problematic areas where extremely high

    temperatures and/or very corrosive chemicals are present.[8]

    Corrosion is fought by a complex system of monitoring, preventative repairs and careful use of materials.

    Monitoring methods include both off-line checks taken during maintenance and on-line monitoring. Off-line checks

    measure corrosion after it has occurred, telling the engineer when equipment must be replaced based on the historical

    information he has collected. This is referred to as preventative management.

    On-line systems are a more modern development, and are revolutionizing theway corrosion is approached. There are

    several types of on-line corrosion monitoring technologies such as linear polarization resistance, electrochemical

    noise and electrical resistance. On-Line monitoring has generally had slow reporting rates in the past (minutes or

    hours) and been limited by process conditions and sources of error but newer technologies can report rates up to

    twice per minute with much higher accuracy (referred to as real-time monitoring). This allows process engineers to

    treat corrosion as another process variable that can be optimized in the system. Immediate responses to processchanges allow the control of corrosion mechanisms, so they can be minimized while also maximizing production

    output.[9]

    In an ideal situation having on-line corrosion information that is accurate and real-time will allow

    conditions that cause high corrosion rates to be identified and reduced. This is known as predictive management.

    Materials methods include selecting the proper material for the application. In areas of minimal corrosion, cheap

    materials are preferable, but when bad corrosion can occur, more expensive but longer lasting materials should be

    used. Other materials methods come in the form of protective barriers between corrosive substances and the

    equipment metals. These can be either a lining of refractory material such as standard Portland cement or other

    special acid-resistant cements that are shot onto the inner surface of the vessel. Also available are thin overlays of

    more expensive metals that protect cheaper metal against corrosion without requiring lots of material.[10]

    History

    The world's first refinery opened at Ploieti, Romania, in 1856-1857, with United States investment. After being

    taken over by Nazi Germany, the Ploieti refineries were bombed in Operation Tidal Wave by the Allies during the

    Oil Campaign of World War II.

    At one point, the refinery in Ras Tanura, Saudi Arabia owned by Saudi Aramco was claimed to be the largest oil

    refinery in the world. For most of the 20th century, the largest refinery was the Abadan Refinery in Iran. This

    refinery suffered extensive damage during the Iran-Iraq war. The world's largest refinery complex is the Jamnagar

    Refinery Complex, consisting of two refineries side by side operated by Reliance Industries Limited in Jamnagar,

    India with a combined production capacity of 1,240,000 barrels per day (197,000 m3/d). PDVSA's Paraguan

    Refinery Complex in Paraguan Peninsula, Venezuela with a capacity of 956,000 bbl/d (152,000 m3/d) and SK

    http://en.wikipedia.org/w/index.php?title=Iran-Iraq_warhttp://en.wikipedia.org/w/index.php?title=Jamnagar_Refineryhttp://en.wikipedia.org/w/index.php?title=Reliance_Industries_Limitedhttp://en.wikipedia.org/w/index.php?title=PDVSAhttp://en.wikipedia.org/w/index.php?title=Paraguan%C3%A1_Refinery_Complexhttp://en.wikipedia.org/w/index.php?title=Paraguan%C3%A1_Peninsulahttp://en.wikipedia.org/w/index.php?title=Venezuelahttp://en.wikipedia.org/w/index.php?title=Iran-Iraq_warhttp://en.wikipedia.org/w/index.php?title=Jamnagar_Refineryhttp://en.wikipedia.org/w/index.php?title=Reliance_Industries_Limitedhttp://en.wikipedia.org/w/index.php?title=PDVSAhttp://en.wikipedia.org/w/index.php?title=Paraguan%C3%A1_Refinery_Complexhttp://en.wikipedia.org/w/index.php?title=Paraguan%C3%A1_Peninsulahttp://en.wikipedia.org/w/index.php?title=Venezuelahttp://en.wikipedia.org/w/index.php?title=Paraguan%C3%A1_Refinery_Complexhttp://en.wikipedia.org/w/index.php?title=Paraguan%C3%A1_Peninsulahttp://en.wikipedia.org/w/index.php?title=Venezuelahttp://en.wikipedia.org/w/index.php?title=Paraguan%C3%A1_Refinery_Complexhttp://en.wikipedia.org/w/index.php?title=Paraguan%C3%A1_Peninsulahttp://en.wikipedia.org/w/index.php?title=Venezuelahttp://en.wikipedia.org/w/index.php?title=SK_Energyhttp://en.wikipedia.org/w/index.php?title=Venezuelahttp://en.wikipedia.org/w/index.php?title=Paraguan%C3%A1_Peninsulahttp://en.wikipedia.org/w/index.php?title=Paraguan%C3%A1_Refinery_Complexhttp://en.wikipedia.org/w/index.php?title=Paraguan%C3%A1_Refinery_Complexhttp://en.wikipedia.org/w/index.php?title=PDVSAhttp://en.wikipedia.org/w/index.php?title=Reliance_Industries_Limitedhttp://en.wikipedia.org/w/index.php?title=Jamnagar_Refineryhttp://en.wikipedia.org/w/index.php?title=Jamnagar_Refineryhttp://en.wikipedia.org/w/index.php?title=Iran-Iraq_warhttp://en.wikipedia.org/w/index.php?title=Iranhttp://en.wikipedia.org/w/index.php?title=Abadan_Refineryhttp://en.wikipedia.org/w/index.php?title=Saudi_Aramcohttp://en.wikipedia.org/w/index.php?title=Saudi_Arabiahttp://en.wikipedia.org/w/index.php?title=Ras_Tanurahttp://en.wikipedia.org/w/index.php?title=Oil_Campaign_of_World_War_IIhttp://en.wikipedia.org/w/index.php?title=Allies_of_World_War_IIhttp://en.wikipedia.org/w/index.php?title=Operation_Tidal_Wavehttp://en.wikipedia.org/w/index.php?title=Nazi_Germanyhttp://en.wikipedia.org/w/index.php?title=United_Stateshttp://en.wikipedia.org/w/index.php?title=Romaniahttp://en.wikipedia.org/w/index.php?title=Ploie%C8%99tihttp://en.wikipedia.org/w/index.php?title=Electrochemical_noisehttp://en.wikipedia.org/w/index.php?title=Electrochemical_noisehttp://en.wikipedia.org/w/index.php?title=Copperhttp://en.wikipedia.org/w/index.php?title=Titaniumhttp://en.wikipedia.org/w/index.php?title=Nickelhttp://en.wikipedia.org/w/index.php?title=Stainless_steelshttp://en.wikipedia.org/w/index.php?title=Molybdenumhttp://en.wikipedia.org/w/index.php?title=Chromiumhttp://en.wikipedia.org/w/index.php?title=Low_alloy_steelhttp://en.wikipedia.org/w/index.php?title=Carbon_steelhttp://en.wikipedia.org/w/index.php?title=Corrosion
  • 5/26/2018 Oil Refinery

    9/11

    Oil refinery 9

    Energy's Ulsan in South Korea with 840,000 bbl/d (134,000 m3/d) are the second and third largest,

    respectively.Wikipedia:Manual of Style/Dates and numbers#Chronological items

    Oil refining in the United States

    In the 19th century, refineries in the U.S. processed crude oil primarily to recover the kerosene. There was no market

    for the more volatile fraction, including gasoline, which was considered waste and was often dumped directly intothe nearest river. The invention of the automobile shifted the demand to gasoline and diesel, which remain the

    primary refined products today. Today, national and state legislation requires refineries to meet stringent air and

    water cleanliness standards. In fact, oil companies in the U.S. perceive obtaining a permit to build a modern refinery

    to be so difficult and costly that no new refineries have been built (though many have been expanded) in the U.S.

    since 1976. More than half the refineries that existed in 1981 are now closed due to low utilization rates and

    accelerating mergers.[11]As a result of these closures total US refinery capacity fell between 1981 to 1995, though

    the operating capacity stayed fairly constant in that time period at around 15,000,000 barrels per day

    (2,400,000 m3/d). Increases in facility size and improvements in efficiencies have offset much of the lost physical

    capacity of the industry. In 1982 (the earliest data provided), the United States operated 301 refineries with a

    combined capacity of 17.9 million barrels (2,850,000 m3) of crude oil each calendar day. In 2010, there were 149operable U.S. refineries with a combined capacity of 17.6 million barrels (2,800,000 m

    3) per calendar day.

    In 2009 through 2010, as revenue streams in the oil business dried up and profitability of oil refineries fell due to

    lower demand for product and high reserves of supply preceding the economic recession, oil companies began to

    close or sell refineries.

    ExxonMobil oil refinery in Baton Rouge (the second-largest in the United States)

    References

    [1] Crude Oil Solids Removal (http://www.processgroupintl.com/cms/page/54/oil-treatment)

    [2] Guide to Refining (http://www.chevron.com/products/prodserv/fuels/bulletin/motorgas/3_refining-testing/pg2. asp) from Chevron

    Oil's website

    [3] Refinery flowchart (http:/

    /

    www.

    uop.

    com/

    refining/

    1010.

    html) from Universal Oil Products' website[4] An example flowchart (http://www.cheresources.com/refining15.gif) of fractions from crude oil at a refinery

    [5] Corrosion Costs and Preventive Strategies in the United States (http://www.nace.org/uploadedFiles/Publications/ccsupp.pdf), a

    publication of NACE International.

    [6] R.D. Kane, Corrosion in Petroleum Refining and Petrochemical Operations, Corrosion: Environments and Industries, Vol 13C, ASM

    Handbook, ASM International, 2006, p 9671014.

    [7] E.N. Skinner, J.F. Mason, and J.J. Moran, High Temperature Corrosion in Refinery and Petrochemical Service, Corrosion, Vol 16 (No. 12),

    1960, p 593t600t.

    [8] E.L. Hildebrand, Materials Selection for Petroleum Refineries and Petrochemical Plants, Mater. Prot. Perform., Vol 11 (No. 7), 1972,

    p1922.

    [9] R.D. Kane, D.C. Eden, and D.A. Eden, Innovative Solutions Integrate Corrosion Monitoring with Process Control, Mater. Perform., Feb

    2005, p 3641.

    [10] W.A. McGill and M.J. Weinbaum, Aluminum-Diffused Steel Lasts Longer, Oil Gas J., Vol 70, Oct 9, 1972, p 6669.

    [11] White Paper on Refining Capacity (http://www.ftc.gov/bcp/workshops/energymarkets/background/hazle.pdf), Federal Trade

    Commission, April, 2007.

    http://www.ftc.gov/bcp/workshops/energymarkets/background/hazle.pdfhttp://www.ftc.gov/bcp/workshops/energymarkets/background/hazle.pdfhttp://en.wikipedia.org/w/index.php?title=Corrosion_Monitoringhttp://en.wikipedia.org/w/index.php?title=NACE_Internationalhttp://www.nace.org/uploadedFiles/Publications/ccsupp.pdfhttp://www.cheresources.com/refining15.gifhttp://en.wikipedia.org/w/index.php?title=UOP_LLChttp://www.uop.com/refining/1010.htmlhttp://en.wikipedia.org/w/index.php?title=Chevron_Corporationhttp://en.wikipedia.org/w/index.php?title=Chevron_Corporationhttp://www.chevron.com/products/prodserv/fuels/bulletin/motorgas/3_refining-testing/pg2.asphttp://www.processgroupintl.com/cms/page/54/oil-treatmenthttp://en.wikipedia.org/w/index.php?title=File%3AExxonMobil_Baton_Rouge.jpghttp://en.wikipedia.org/w/index.php?title=United_Stateshttp://en.wikipedia.org/w/index.php?title=Baton_Rougehttp://en.wikipedia.org/w/index.php?title=ExxonMobilhttp://en.wikipedia.org/w/index.php?title=Late-2000s_recessionhttp://en.wikipedia.org/w/index.php?title=Kerosenehttp://en.wikipedia.org/wiki/Manual_of_Style/Dates_and_numbers#Chronological_itemshttp://en.wikipedia.org/w/index.php?title=South_Koreahttp://en.wikipedia.org/w/index.php?title=Ulsanhttp://en.wikipedia.org/w/index.php?title=SK_Energy
  • 5/26/2018 Oil Refinery

    10/11

    Oil refinery 10

    External links

    Interactive map of UK refineries (http://www.energyinst.org.uk/education/refineries/map. htm)

    Searchable United States Refinery Map (http://www.energysupplylogistics.com/refineries)

    Complete, detailed refinery description (http://www.osha.gov/dts/osta/otm/otm_iv/otm_iv_2.html)

    Ecomuseum Bergslagen (http://www.ekomuseum.se/english/besoksmal/oljeon.html) - history of Oljen,

    Sweden Fueling Profits: Report on Industry Consolidation (http://www.consumerfed.org/pdfs/oilprofits.pdf)

    (publication of the Consumer Federation of America)

    Price Spikes, Excess Profits and Excuses (http://www.consumerfed.org/pdfs/gasoline1003.pdf) (publication

    of the Consumer Federation of America)

    Basics of Oil Refining (http://www.petrostrategies.org/Learning_Center/refining.htm) Overview of crude oil

    refining process

    Refining NZ Learning Centre (http://www.refiningnz.com/visitors--learning.aspx) Oil Refinery Process

    Animations,Videos & 360 Degree Views

    http://www.refiningnz.com/visitors--learning.aspxhttp://www.petrostrategies.org/Learning_Center/refining.htmhttp://www.consumerfed.org/pdfs/gasoline1003.pdfhttp://www.consumerfed.org/pdfs/oilprofits.pdfhttp://en.wikipedia.org/w/index.php?title=Swedenhttp://www.ekomuseum.se/english/besoksmal/oljeon.htmlhttp://www.osha.gov/dts/osta/otm/otm_iv/otm_iv_2.htmlhttp://www.energysupplylogistics.com/refinerieshttp://www.energyinst.org.uk/education/refineries/map.htm
  • 5/26/2018 Oil Refinery

    11/11

    Article Sources and Contributors 11

    Article Sources and ContributorsOil refinery Source: http://en.wikipedia.org/w/index.php?oldid=605775380 Contributors: *drew, .:Ajvol:., 21655, 28421u2232nfenfcenc, Aaronw08, Aboriginal Noise, Adbar, Addshore,

    AdiJapan, Ageekgal, Aitias, Alansohn, Aldis90, Aleator, Alex.muller, Ali, Allen Info, Allen Mesch, Amp121212, AndrewKeenanRichardson, Andrewpmk, Anlace, Annwhent, Anonymous6494,

    AntSmith, Antonrojo, Apancu, Arham pincha, Arinnian, Arthena, Asoleimanif, Avicennasis, BNSDRX09, Beagel, BenFrantzDale, Betterusername, Bogdangiusca, Bongomatic, Bongwarrior,

    Boswell, Brandonlighty, BritishWatcher, BruceRD, Bryan Derksen, Caltas, Calvero JP, Can't sleep, clown will eat me, Caulde, Cccefalon, Cdcon, CharlieEchoTango, Chris Buckey,

    ChrisGualtieri, Chubbz1995, Coemgenus, Colonies Chris, Cometstyles, Commutator, Corusant, CorvetteZ51, Crentsch, DMacks, DRGrim, Dan East, Darolew, David Shankbone, Dbushong,

    Desertroad, Dh m83, Dirac1933, Discospinster, Donner60, Doulos Christos, Dthomsen8, Duckrob47, Dycedarg, ESkog, Eagleamn, Edgar181, Edward, Edward Z. Yang, Elader, Ender Everett,

    Epbr123, Erazlogo, Euphonisten, Explocontrol, Falcon8765, Falconeer, Fatal!ty, Firien, Flavus Ahenobarbus, Flewis, Fozia nasir, Francophile124, Fratrep, GBuilder, Gail, Gbinal, Gepwiki,Geremy.Hebert, Gilliam, Glane23, Ground Zero, Grsz11, H Padleckas, HISTMichelleS253, Happysailor, Hardyplants, Hatster301, Hazmat2, Helloaday, Hemanshu, Hmains, Hooperbloob,

    Hubba, Hut 6.5, Hyd12, IGeMiNix, Igoldste, Ikar.us, Ilyaroz, Insomnia64, J.delanoy, J04n, JRWalko, JaGa, JimmyCraig, John, JohnSRoberts99, Jorge Stolfi, KGV, Kahar13, Katieh5584,

    Kcordina, Kiko4564, Kittylionel, Kjkolb, KnowledgeOfSelf, Knuto, Koavf, Kosm, Lakshmix, LeadSongDog, Lear's Fool, LeaveSleaves, Leonard G., Lhademmor, Lightmouse, Lohrmann

    International, Lollypopcandygum, Lollypopcandygum1, LouisBB, Lowellt, Luk, Lupin, M karzarj, M0RD00R, M0rphzone, Mani1, Markrobi, Materialscientist, Mauler90, Mausy5043, Maximus

    Rex, MayaSimFan, Mbeychok, Meters, Michaelraymond40170, Minimac, Monk, MrOllie, Mugs2109, Mulad, Mur61j, Nathanael Bar-Aur L., Neutrality, Nikopoley, Nk, Nono64,

    Northamerica1000, Nuno Tavares, Nuttycoconut, Oxymoron83, Peterbmoorman, Phil Boswell, Philip Trueman, Pinethicket, Pit, Plazak, PoccilScript, Poofacejim, Preeteshdeora, Pretzelpaws,

    Psarianos, Putje81, Raymondwinn, Rdaveh, RedWolf, Renelia Richter, Richhoncho, Rifleman 82, RobDe68, Robo4321, Rogermw, Ronhjones, Rorshacma, Rpalyvoda, Ryanwilliams98,

    SEWilco, Salsb, Sameeraemail, Samuel-em, Saperaud, Saravask, Scientific29, Scott Burley, SeanMack, Shimi925, Sicvolo, Silvio1973, SimonD, Skizzik, Snowolf, Sozchick101, Spalding,

    Spongessuck, Stan Shebs, Steam5, Stephenb, Stevenwmccrary58, Stuhacking, Tech408, Tex, Tgeairn, Thatguyflint, The Thing That Should Not Be, Thecoolmusic, Theresa knott, Thingg,

    Thiswebsitesuckssomuch, Tide rolls, Tillman, Tom harrison, Tommy2010, Tpbradbury, Troyster87, Txag99, Unconcerned, UrbanNerd, Useight, Utain, Uthican, Vrenator, Vuvar1, Wavelength,

    Widr, WikHead, Wiki alf, WilfriedC, Wimt, Wk muriithi, Woodshed, Work permit, Wsiegmund, Wtt, Xanthar, XterraGuy, Yellowdesk, Yueni, Zip822, Zsinj, Zujua, , 571 anonymous

    edits

    Image Sources, Licenses and ContributorsImage:Anacortes Refinery 31911.JPG Source: http://en.wikipedia.org/w/index.php?title=File:Anacortes_Refinery_31911.JPGLicense: Creative Commons Attribution 2.5 Contributors:

    Walter Siegmund (talk)

    File:Crude Oil Distillation-en.svg Source: http://en.wikipedia.org/w/index.php?title=File:Crude_Oil_Distillation-en.svgLicense: GNU Free Documentation License Contributors:

    Crude_Oil_Distillation-fr.svg: Image originale:Psarianos, Theresa knott ; image vectorielle:Rogilbert derivative work: Utain (talk)

    Image:Haifa Refinery by David Shankbone.jpg Source: http://en.wikipedia.org/w/index.php?title=File:Haifa_Refinery_by_David_Shankbone.jpgLicense: GNU Free Documentation License

    Contributors: David Shankbone

    Image:Anacortes Refinery 32017.JPG Source: http://en.wikipedia.org/w/index.php?title=File:Anacortes_Refinery_32017.JPGLicense: Creative Commons Attribution-ShareAlike 3.0

    Unported Contributors: Walter Siegmund (talk)

    Image:RefineryFlow.png Source: http://en.wikipedia.org/w/index.php?title=File:RefineryFlow.pngLicense: GNU Free Documentation License Contributors: User:Mbeychok, User:mbeychok

    File:Crude Oil Distillation Unit.png Source: http://en.wikipedia.org/w/index.php?title=File:Crude_Oil_Distillation_Unit.pngLicense: Creative Commons Attribution-Sharealike 3.0

    Contributors: Mbeychok

    File:BP PLANT EXPLOSION-1 lowres2.jpg Source: http://en.wikipedia.org/w/index.php?title=File:BP_PLANT_EXPLOSION-1_lowres2.jpgLicense: Public Domain Contributors:

    Linksfuss

    File:ExxonMobil Baton Rouge.jpg Source: http://en.wikipedia.org/w/index.php?title=File:ExxonMobil_Baton_Rouge.jpgLicense: Creative Commons Attribution-Sharealike 3.0 Contributors:

    User:Adbar

    License

    Creative Commons Attribution-Share Alike 3.0//creativecommons.org/licenses/by-sa/3.0/