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MSDSMATERIAL SAFETY DATA SHEET

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It is an important component of workplace safety, and

intended to provide procedures for handling or

working with that substance in a safe manner, storage,

disposal, protective equipment, and spill handling

procedures.

16 point (section) EU format conforming to 29CFR

1910.1200

CFR (code of Federal Regulation)

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INTRODUCTION

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Gives the product name, description, manufacturer, and

emergency numbers. Manufacturer/ supplier name & address

Product trade name

CAS no.

Synonyms

Generic chemical name

Product type

Preparation/ revision date

Transportation emergency phone number MSDS number

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1- Chemical Product & Company Identification

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Hazardous ingredients

Components

CAS no.

Percentage (by wt)

Carcinogen

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2- Chemical composition and common name

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Lists the main hazards

Appearance

Odor

Principal hazards

Target organs

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3- Hazard identification

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Action to be taken if a person is affected

Eyes

Skin

Inhalation

Oral

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4- First aid measures

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Details required in case of fires

Flash point

Extinguishing media

Fire fighting procedures

Unusual fire & explosion hazards

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5- Fire fighting measures

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Steps to be taken in case of spillage/ leakage

Spill control procedures

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6- Accidental release measures

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Pumping temperature

Maximum handling temperature

Handling procedures

Maximum storage temperature

Storage procedures

Loading temperature

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7- Handling and storage information

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Mainly deals with personal protective equipments

Exposure limits

Other exposure limits

Engineering controls

Gloves protection

Eyes protection

Respiratory protection

Clothing recommendation

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8- Exposure control and personal protection

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Flash point

Specific gravity/ density

Solubility

ViscosityPour point

And others

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9- Physical and chemical properties

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Stability

Decomposition temperature

Incompatibility

Polymerization

Thermal decomposition

Conditions to avoid

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10- Stability and reactivity

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Related to acute & chronic exposure

ACUTEo Eye irritation

o Skin irritation

o Respiratory irritation

o Dermal toxicity

o Inhalation toxicity

o Oral toxicity

o Dermal sensitization

o Inhalation sensitization

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11- Toxicological information

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CHRONIC

Chronic toxicity

Carcinogenicity

Mutagenicity

Reproductive toxicity

teratogenicity

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11- Toxicological information

contd

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Details regarding environmental toxicity & fate

ENVIRONMENTAL TOXICITYFreshwater fish toxicity

Freshwater invertebrates toxicity

Algal inhibition

Saltwater fish toxicity

Saltwater invertebrates toxicity

Bacterial toxicity

Miscellaneous

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12- Ecological information

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ENVIRONMENTAL FATEBiodegradation

Bioaccumulation

Soil mobility

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12- Ecological information

contd.

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Details required for waste disposal

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13- Disposal information

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ICAO/ IATA

IMDG EMS

MARPOL

USCG

U.S. DOT

DOT NAERG

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14- Transport information

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Global chemical inventories

US federal regulations

State regulations

Product registrations

Local statutory

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15- Regulatory information

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NFPA codes

o Health

o Fire

o Reactivity

HMIS codes

o Healtho Fire

o Reactivity

Precautionary labels

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16- Information not covered in the other sections

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QUESTIONS ?

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CAS registry numbers are unique numerical identifiers

for chemical, element, compound, polymer, alloys,mixtures

As of Sep 2009, there are 50 million organic/ inorganic

substances in CAS registry

e.g. 7732-18-5

Last digit is single, a checksum

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PPE Personal Protective Equipment

DOT Department of Transportation

CERCLA Comprehensive Environmental Response,

Compensation, and Liability Actof 1980 (USA)

OSHA Occupational Safety and Health

Administration

NIOSH National Institute for Occupational Safety

and Health

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LC50 (Lethal Concentration 50) is the concentration of achemical which kills 50% of a sample population.

This measure is generally used when exposure to a

chemical is through the animal breathing it in.

LD50 (Lethal Dose 50) is the dose of a chemical whichkills 50% of a sample population. It is used when

exposure is by swallowing, skin contact, injection.

EC50 (half maximal effective concentration) , ED50 (effective dose 50), IC50 (half maximal inhibitory concentration)

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PEL permissible exposure limit in ppm or mg/m3

TWA time weighted average

STEL short term exposure limit, usually for 8 h period

ACGIH American Conference of Industrial Hygienists

MSHA Mine Safety and Health Administration

IARC International Agency for Research on Cancer(WHO)

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OECD Organization for economic co-operation and

development

RCRA Resource Conservation and Recovery Act (RCRA),enacted in 1976, is the principal Federal law in the

United States governing the disposal of solid waste.

ICAO International Civil Aviation Organization

IATA International Air Transport Association

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IMDG International Maritime Dangerous Goods

IMDG EmS IMDG emergency schedule

MFAG Medical First Aid Guide

MARPOL International Convention for the Prevention ofPollution From Ships

USCG United States Coast Guard

NAERG North American Emergency Response Guidebook

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TSCA Toxic Substances Control Act

EU/ EEC European Union/ European Economic Committee

SARA Superfund Amendments and Reauthorization Act

consolidated list of chemicals subject to emergencyplanning

NFPA National Fire Protection Association

HMIS Health Management Information System

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