Material Safety Data Sheet(MSDS-TNT)

PRODUCT IDENTIFICATION Product Name TNT Trade Names and Synonyms 2,4,6 Trinitrotoluene Manufacturer/Distributor Various Transportation Emergency 800-255-3924 (24 hrs -- CHEM • TEL)

PREVENTION OF ACCIDENTS IN THE USE OF EXPLOSIVES

The prevention of accidents in the use of explosives is a result of careful planning and observance of the best known practices. The explosives user must remember that he is dealing with a powerful force and that various devices and methods have been developed to assist him in directing this force. He should realize that this force, if misdirected, may either kill or injure both him and his fellow workers.

WARNING All explosives are dangerous and must be carefully handled and used following approved safety procedures either by or under the direction of competent, experienced persons in accordance with all applicable federal, state, and local laws, regulations, or ordinances. If you have any questions or doubts as to how to use any explosive product, DO NOT USE IT before consulting with your supervisor, or the manufacturer, if you do not have a supervisor. If your supervisor has any questions or doubts, he should consult the manufacturer before use.

MSDS-TNT PAGE 1 Issued 04/30/97 Reviewed 2/22/06

HAZARDOUS COMPONENTS Material or Component CAS No. TLV PEL

TNT (Trinitrotoluene)

38082-89-2 1.5 MG/M3 .5 MG/M3

N/A = Not assigned NE = Not established

PHYSICAL DATA Boiling Point 464° F Vapor Pressure .057 MPa @ 179° F Vapor Density N/A Solubility in Water Insoluble Specific Gravity 1.5 - 1.6 Melting Point 176°F Evaporation Rate N/A Appearance and Odor Yellow Flakes, with bitter almond odor.

HAZARDOUS REACTIVITY Instability Stable Incompatibility No data applicable Hazardous decomposition Nitrous Oxide Polymerization Polymerization will not occur

FIRE AND EXPLOSION DATA Flashpoint Not applicable Extinguishing media None Special fire fighting procedures ALL EXPLOSIVES: DO NOT FIGHT EXPLOSIVES FIRES. Try to keep

fire from reaching explosives. Isolate area. Guard against intruders.

Division 1.1 Explosives: Evacuate the area for 5000 feet (1 mile). Consult the 2000 Emergency Response Guidebook, Guide 112 for further details.

Unusual fire and explosion hazards Will detonate if suitably primed by heat or flame.

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HEALTH HAZARDS General

TNT is a Division 1.1 explosive, and detonation may cause severe physical injury, including death. All explosives are dangerous and must be handled carefully and used following approved safety procedures under the direction of competent, experienced persons in accordance with all applicable federal, state, and local laws, regulations, and ordinances.

Inhalation of explosives powders may cause nervous system irregularities including headaches and dizziness.

Nitrogen oxides generated during use are skin, eye, and respiratory tract irritants. Carcinogenicity None of the components of TNT are listed as a carcinogen by NTP, IARC, or OSHA.

FIRST AID Inhalation If detonation fumes are inhaled, remove to fresh air. If not breathing, give artificial

respiration, preferably mouth to mouth. If breathing is difficult, give oxygen and call a physician.

Eye and skin contact Flush eyes with water. Wash skin with soap and water. Ingestion Induce vomiting immediately by giving two glasses of water and sticking finger down

throat. Injury from detonation Seek prompt medical attention.

SPILL OR LEAK PROCEDURES Spill/leak response Review fire and explosion hazards before proceeding with clean up. Remove all ignition

sources. Wear protective equipment during clean up. Mop up with water. Waste disposal Dispose of in compliance with federal regulations under the authority of the Resource

Conservation and Recovery Act (40 CFR Parts 260-271).

SPECIAL PROTECTION INFORMATION Ventilation General ventilation with local exhaust in operation area. Respiratory Wear fitted NIOSH approved respirator, avoid dusting by keeping wet when possible . Eye Chemical goggles. Gloves Cotton or leather gloves Other Flame proof coveralls and conductive boots.

SPECIAL PRECAUTIONS Refer to manufacturer’s instructions and warnings supplied with product.

STORAGE CONDITIONS Store in accordance with the requirements of Subpart K, ATF: Explosives Law and Regulations (27 CFR 55.201-55.219).

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SHIPPING INFORMATION Proper shipping name TNT Hazard class 1.1D UN Number UN0209 (1.1D) DOT Label & Placard DOT Label EXPLOSIVE 1.1D DOT Placard EXPLOSIVES 1.1

The information contained in this Material Safety Data Sheet is based upon available data and believed to be correct; however, as such has been obtained from various sources, including the manufacturer and independent laboratories, it is given without warranty or representation that it is complete, accurate, and can be relied upon. OWEN COMPLIANCE SERVICES, INC. has not attempted to conceal in any manner the deleterious aspects of the product listed herein, but makes no warranty as to such. Further, OWEN COMPLIANCE SERVICES, INC. cannot anticipate nor control the many situations in which the product or this information may be used; there is no guarantee that the health and safety precautions suggested will be proper under all conditions. It is the sole responsibility of each user of the product to determine and comply with the requirements of all applicable laws and regulations regarding its use. This information is given solely for the purposes of safety to persons and property. Any other use of this information is expressly prohibited.

For further information contact: David W. Boston, President OWEN COMPLIANCE SERVICES, INC. 12001 County Road 1000 P.O. Box 765 Godley, TX 76044

Telephone number: 817-551-0660 FAX number: 817-396-4584

MSDS prepared by: Johnny R. Rodriguez, Compliance Specialist Original publication date: 04/30/97 Review date: 2/22/06

12/03/03

MSDS-TNT PAGE 4 Issued 04/30/97 Reviewed 2/22/06