Mass Spec Chemical Mass Spec Chemical Profiling with the Dq1000Profiling with the Dq1000TMTM

The Dq1000 is a portable quadrapole mass analyzer for use on drilling wells. It replaces all conventional gas detectors. It analyzes C1-C10 petroleum species, and inorganic compounds such as CO2, He, N2, O2 and sulfur bearing volatiles. It can discriminate among paraffins, naphthenes and aromatics, as well as contributions from the drilling fluid.

The Dq1000 is capable of delineating charged zones, petroleum type, compartmentalization, fluid contacts and seals to a much greater extent than conventional instrumentation. Interpretation of data follows from our 18 years of experience with subsurface fluid chemistry

Helium Injection Lag Helium Injection Lag DeterminationsDeterminations

Trigger Helium Injections and monitor Trigger Helium Injections and monitor them for lag determination and gas them for lag determination and gas monitoring equipment performance monitoring equipment performance evaluationevaluation

Considerations for Considerations for Isotube Sample Isotube Sample Collection:Collection:

Sample must be time and depth Sample must be time and depth correlativecorrelative

Considerations for Considerations for Isotube Sample Isotube Sample Collection:Collection:

Sample must be time and depth Sample must be time and depth correlativecorrelative

Considerations for Considerations for Isotube Sample Isotube Sample Collection:Collection:

Sample must be time and depth Sample must be time and depth correlativecorrelative

Dq1000 Chemical Profile Dq1000 Chemical Profile CurvesCurves

Along with Paraffin, Aromatic, Along with Paraffin, Aromatic, Naphthenic, Inorganics, Sulfur species, Naphthenic, Inorganics, Sulfur species, etc. we’ve now added Character and etc. we’ve now added Character and Balance calculations and Pixler RatiosBalance calculations and Pixler Ratios

Considerations for Considerations for Isotube Sample Isotube Sample Collection:Collection:

Sample must be time and depth Sample must be time and depth correlativecorrelative

““d.las”d.las”DataDataFile:File:

Depth .F : Track # 0Depth .F : Track # 0 Time .SEC : Track # 1Time .SEC : Track # 1 HC1 .UNKN : Track # 2HC1 .UNKN : Track # 2 HC2 .UNKN : Track # 3HC2 .UNKN : Track # 3 HC3 .UNKN : Track # 4HC3 .UNKN : Track # 4 HC4 .UNKN : Track # 5HC4 .UNKN : Track # 5 HC5 .UNKN : Track # 6HC5 .UNKN : Track # 6 HC6 .UNKN : Track # 7HC6 .UNKN : Track # 7 HC7 .UNKN : Track # 8HC7 .UNKN : Track # 8 HC8 .UNKN : Track # 9HC8 .UNKN : Track # 9 HC9 .UNKN : Track # 10HC9 .UNKN : Track # 10 HC10 .UNKN : Track # 11HC10 .UNKN : Track # 11 TOTAL_GAS .UNKN : Track # TOTAL_GAS .UNKN : Track #

1212 RAW_NAPH .UNKN : Track # RAW_NAPH .UNKN : Track #

1313 C3_C1 .UNKN : Track # 14C3_C1 .UNKN : Track # 14 NormC1 .UNKN : Track # 15NormC1 .UNKN : Track # 15 NormC4 .UNKN : Track # 16NormC4 .UNKN : Track # 16 NormC7 .UNKN : Track # 17NormC7 .UNKN : Track # 17 NormBen_Tol .UNKN : Track # 18NormBen_Tol .UNKN : Track # 18 PIX1 .UNKN : Track # 19PIX1 .UNKN : Track # 19 PIX2 .UNKN : Track # 20PIX2 .UNKN : Track # 20 PIX3 .UNKN : Track # 21PIX3 .UNKN : Track # 21 PIX4 .UNKN : Track # 22PIX4 .UNKN : Track # 22 Para .UNKN : Track # 23Para .UNKN : Track # 23 Naph .UNKN : Track # 24Naph .UNKN : Track # 24 Arom .UNKN : Track # 25Arom .UNKN : Track # 25 Ben_Tol .UNKN : Track # 26Ben_Tol .UNKN : Track # 26 Benzene .UNKN : Track # 27Benzene .UNKN : Track # 27 AceticAcid .UNKN : Track # 28AceticAcid .UNKN : Track # 28 TotalArom .UNKN : Track # 29TotalArom .UNKN : Track # 29 Arom_cHex .UNKN : Track # 30Arom_cHex .UNKN : Track # 30 Sulf_HC .UNKN : Track # 31Sulf_HC .UNKN : Track # 31 Ben_cHex .UNKN : Track # 32Ben_cHex .UNKN : Track # 32 Helium .UNKN : Track # 33Helium .UNKN : Track # 33 Hydrogen .UNKN : Track # 34Hydrogen .UNKN : Track # 34 CO2Raw .UNKN : Track # 35CO2Raw .UNKN : Track # 35 CO2pp .UNKN : Track # 36CO2pp .UNKN : Track # 36 CO2calc2 .UNKN : Track # 37CO2calc2 .UNKN : Track # 37 SO .UNKN : Track # 38SO .UNKN : Track # 38 SO2 .UNKN : Track # 39SO2 .UNKN : Track # 39

CS2 .UNKN : Track # 40CS2 .UNKN : Track # 40 N2 .UNKN : Track # 41N2 .UNKN : Track # 41 O2 .UNKN : Track # 42O2 .UNKN : Track # 42 Ar .UNKN : Track # 43Ar .UNKN : Track # 43 H2O .UNKN : Track # 44H2O .UNKN : Track # 44 Air1 .UNKN : Track # 45Air1 .UNKN : Track # 45 Air2 .UNKN : Track # 46Air2 .UNKN : Track # 46 NormHe .UNKN : Track # 47NormHe .UNKN : Track # 47 NormH .UNKN : Track # 48NormH .UNKN : Track # 48 NormCO2 .UNKN : Track # 49NormCO2 .UNKN : Track # 49 NormCO2pp .UNKN : Track # 50NormCO2pp .UNKN : Track # 50 NormBen .UNKN : Track # 51NormBen .UNKN : Track # 51 NormTol .UNKN : Track # 52NormTol .UNKN : Track # 52 NormN2 .UNKN : Track # 53NormN2 .UNKN : Track # 53 NormO2 .UNKN : Track # 54NormO2 .UNKN : Track # 54 NormAr .UNKN : Track # 55NormAr .UNKN : Track # 55 C2calc .UNKN : Track # 56C2calc .UNKN : Track # 56 C1_THC .UNKN : Track # 57C1_THC .UNKN : Track # 57 G_L .UNKN : Track # 58G_L .UNKN : Track # 58 HCvsW .UNKN : Track # 59HCvsW .UNKN : Track # 59 Ben_C1 .UNKN : Track # 60Ben_C1 .UNKN : Track # 60 Xylene .UNKN : Track # 61Xylene .UNKN : Track # 61 Arom_Alk .UNKN : Track # 62Arom_Alk .UNKN : Track # 62 HC .UNKN : Track # 63HC .UNKN : Track # 63 Permratio .UNKN : Track # 64Permratio .UNKN : Track # 64 GO .UNKN : Track # 65GO .UNKN : Track # 65 Tol_nC7 .UNKN : Track # 66Tol_nC7 .UNKN : Track # 66 TL .UNKN : Track # 67TL .UNKN : Track # 67 Percent_Gas .UNKN : Track # 68Percent_Gas .UNKN : Track # 68 Wh_calc .UNKN : Track # 69Wh_calc .UNKN : Track # 69 Bh_calc .UNKN : Track # 70Bh_calc .UNKN : Track # 70 Ch_calc .UNKN : Track # 71Ch_calc .UNKN : Track # 71 nC4 .UNKN : Track # 72nC4 .UNKN : Track # 72 nC4_C1 .UNKN : Track # 73nC4_C1 .UNKN : Track # 73 nC6 .UNKN : Track # 74nC6 .UNKN : Track # 74 cC6 .UNKN : Track # 75cC6 .UNKN : Track # 75 C3_C2 .UNKN : Track # 76C3_C2 .UNKN : Track # 76 C5_C1 .UNKN : Track # 77C5_C1 .UNKN : Track # 77 Toluene .UNKN : Track # 78Toluene .UNKN : Track # 78 Ben_cC6 .UNKN : Track # 79Ben_cC6 .UNKN : Track # 79

AA_nC4 .UNKN : Track # 80AA_nC4 .UNKN : Track # 80 He_C1 .UNKN : Track # 81He_C1 .UNKN : Track # 81 CO2_C1 .UNKN : Track # 82CO2_C1 .UNKN : Track # 82 MZ34 .UNKN : Track # 83MZ34 .UNKN : Track # 83 Atm .UNKN : Track # 84Atm .UNKN : Track # 84 Atm_TOT .UNKN : Track # 85Atm_TOT .UNKN : Track # 85 Atm_NormTOT .UNKN : Track # Atm_NormTOT .UNKN : Track #

8686 N_Atm .UNKN : Track # 87N_Atm .UNKN : Track # 87 O_Atm .UNKN : Track # 88O_Atm .UNKN : Track # 88 Ar_Atm .UNKN : Track # 89Ar_Atm .UNKN : Track # 89 OBMC3 .UNKN : Track # 90OBMC3 .UNKN : Track # 90 OBMC4 .UNKN : Track # 91OBMC4 .UNKN : Track # 91 OBMC5 .UNKN : Track # 92OBMC5 .UNKN : Track # 92 OBMC6 .UNKN : Track # 93OBMC6 .UNKN : Track # 93 OBMC7 .UNKN : Track # 94OBMC7 .UNKN : Track # 94 OBMC8 .UNKN : Track # 95OBMC8 .UNKN : Track # 95 OBMC9 .UNKN : Track # 96OBMC9 .UNKN : Track # 96 HC2_HC1 .UNKN : Track # 97HC2_HC1 .UNKN : Track # 97 HC3_HC1 .UNKN : Track # 98HC3_HC1 .UNKN : Track # 98 HC5_HC3 .UNKN : Track # 99HC5_HC3 .UNKN : Track # 99 HC7_HC3 .UNKN : Track # 100HC7_HC3 .UNKN : Track # 100 Ben_nC6 .UNKN : Track # 101Ben_nC6 .UNKN : Track # 101

Dq1000 Auxillary Sensor Dq1000 Auxillary Sensor InputsInputs

H2S, IR THAH2S, IR THA WITS in and WITS outWITS in and WITS out

Dq1000Dq1000AuxillaryAuxillarySensorSensorInputsInputs

FIT’s New Gas Cannibal FIT’s New Gas Cannibal constant volume gas constant volume gas

extractorextractor Intrinsically safe pneumatic control circuit Intrinsically safe pneumatic control circuit

automatically tracks the mud level in the automatically tracks the mud level in the header tank and adjusts the extractor header tank and adjusts the extractor height proactivelyheight proactively

FIT’s New CV Gas TrapFIT’s New CV Gas TrapTop Graph shows mud level, which was raised or lowered about 4 inches every 5 minutes. The gear will automatically compensate for up to 12 inches of movement from a fixed position (19 inches total with manual adjustment).

Bottom graph effectively shows the variation in gas head space in the trap (white) and pressure deviations in the sensor system used to trigger the pneumatic control unit (red). Mud level (consequently head space volume) was effectively maintained within +/- ¼ inch of setpoint. This virtually eliminates variations in gas readings common in fixed traps due to pit level fluctuations.

Gas Gas Cannibal on Cannibal on Mongoose Mongoose

Shale Shale ShakerShaker

Gas Gas Extractor Extractor

PerformancPerformance Evaluatione Evaluation

Dq1000 in Ultra-Deep Water Dq1000 in Ultra-Deep Water Drilling with Volatility-Drilling with Volatility-

Enhancing Gas ExtractionEnhancing Gas Extraction Volatility-Enhancing gas extraction is a Volatility-Enhancing gas extraction is a

mus in ultra dep water applications due mus in ultra dep water applications due to cold mud, diluted mudto cold mud, diluted mud

TheTheUltra-Ultra-DeepDeep

ChallengeChallenge

Cold, Dilute Mud Cold, Dilute Mud withwith

ConventionalConventionalExtractorExtractor

Cold, Dilute Mud Cold, Dilute Mud withwith

Volatility-EnhancingVolatility-EnhancingExtractorExtractor

IsotechIsotechIsotubeIsotubeAutoloaderAutoloader

•Isotubes contain radio Isotubes contain radio tags encoded with tags encoded with unique serial numbersunique serial numbers

•The Autoloader adds a The Autoloader adds a time stamp to each tag time stamp to each tag together with its own together with its own serial number each serial number each time a sample is taken time a sample is taken

•Reduces analysis of Reduces analysis of empty tubesempty tubes

•Precludes “rapid-fire” Precludes “rapid-fire” “catch-up” sampling to “catch-up” sampling to compensate for missed compensate for missed intervals intervals

FIT-Dq1000 Chemical FIT-Dq1000 Chemical ProfilerProfiler

Isotech-Isotube Autoloader Isotech-Isotube Autoloader InterfaceInterface By interfacing the Isotube Autoloader By interfacing the Isotube Autoloader

with the Dq1000 Chemical Profiler, with the Dq1000 Chemical Profiler, Isotube sampling can be driven by both Isotube sampling can be driven by both time and depth-based criteriatime and depth-based criteria

Sampling can also be triggered remotely Sampling can also be triggered remotely – while viewing gas composition data off – while viewing gas composition data off site using the Dq1000 monitor softwaresite using the Dq1000 monitor software

Eventually, auto-triggering based on Eventually, auto-triggering based on chemical criteria will also be possiblechemical criteria will also be possible

Considerations for Considerations for Isotube Sample Isotube Sample Collection:Collection:

Sample must be time and depth Sample must be time and depth correlativecorrelative

Considerations for Considerations for Isotube Sample Isotube Sample Collection:Collection:

Sample must be time and depth Sample must be time and depth correlativecorrelative

Considerations for Considerations for Isotube Sample Isotube Sample Collection:Collection:

Sample must be time and depth Sample must be time and depth correlativecorrelative

IsotubeIsotubeSampleSampleRecord:Record:

~Curve Information Block~Curve Information Block #MNEM.UNIT API CODE Curve Description#MNEM.UNIT API CODE Curve Description #---------- ----------- -----------------#---------- ----------- ----------------- Sample # .--- : Track # 0Sample # .--- : Track # 0 Time (Abs) .Sec : Track # 1Time (Abs) .Sec : Track # 1 Date .Local : Track # 2Date .Local : Track # 2 Time .Local : Track # 3Time .Local : Track # 3 Depth .F : Track # 4Depth .F : Track # 4 Trigger .UNKN : Track # 5Trigger .UNKN : Track # 5 ~Ascii FIS DATA~Ascii FIS DATA 1 3378514101.00 01/21/2011 22:08:21 11313.00 Isotube Time1 3378514101.00 01/21/2011 22:08:21 11313.00 Isotube Time 2 3378514310.00 01/21/2011 22:11:50 11315.00 Isotube Man Rmt2 3378514310.00 01/21/2011 22:11:50 11315.00 Isotube Man Rmt 3 3378517913.00 01/21/2011 23:11:53 11343.00 Isotube Time3 3378517913.00 01/21/2011 23:11:53 11343.00 Isotube Time 4 3378521515.00 01/22/2011 00:11:55 11367.00 Isotube Time4 3378521515.00 01/22/2011 00:11:55 11367.00 Isotube Time 5 3378525118.00 01/22/2011 01:11:58 11390.00 Isotube Time5 3378525118.00 01/22/2011 01:11:58 11390.00 Isotube Time 6 3378528721.00 01/22/2011 02:12:01 11407.00 Isotube Time6 3378528721.00 01/22/2011 02:12:01 11407.00 Isotube Time 7 3378532324.00 01/22/2011 03:12:04 11436.00 Isotube Time7 3378532324.00 01/22/2011 03:12:04 11436.00 Isotube Time 8 3378535927.00 01/22/2011 04:12:07 11454.00 Isotube Time8 3378535927.00 01/22/2011 04:12:07 11454.00 Isotube Time 9 3378539530.00 01/22/2011 05:12:10 11465.00 Isotube Time9 3378539530.00 01/22/2011 05:12:10 11465.00 Isotube Time 10 3378543132.00 01/22/2011 06:12:12 11487.00 Isotube Time10 3378543132.00 01/22/2011 06:12:12 11487.00 Isotube Time 11 3378546735.00 01/22/2011 07:12:15 11504.00 Isotube Time11 3378546735.00 01/22/2011 07:12:15 11504.00 Isotube Time 12 3378550409.00 01/22/2011 08:13:29 11531.00 Isotube Time12 3378550409.00 01/22/2011 08:13:29 11531.00 Isotube Time 13 3378554012.00 01/22/2011 09:13:32 11551.00 Isotube Time13 3378554012.00 01/22/2011 09:13:32 11551.00 Isotube Time 14 3378557617.00 01/22/2011 10:13:37 11585.00 Isotube Time14 3378557617.00 01/22/2011 10:13:37 11585.00 Isotube Time 15 3378561217.00 01/22/2011 11:13:37 11611.00 Isotube Time15 3378561217.00 01/22/2011 11:13:37 11611.00 Isotube Time 16 3378564820.00 01/22/2011 12:13:40 11632.00 Isotube Time16 3378564820.00 01/22/2011 12:13:40 11632.00 Isotube Time 17 3378568055.00 01/22/2011 13:07:35 11638.00 Isotube Man Loc17 3378568055.00 01/22/2011 13:07:35 11638.00 Isotube Man Loc 18 3378568260.00 01/22/2011 13:11:00 11638.00 Isotube Man Loc18 3378568260.00 01/22/2011 13:11:00 11638.00 Isotube Man Loc 19 3378569061.00 01/22/2011 13:24:21 11638.00 Isotube Man Loc19 3378569061.00 01/22/2011 13:24:21 11638.00 Isotube Man Loc 20 3378569152.00 01/22/2011 13:25:52 11639.00 Isotube Man Loc20 3378569152.00 01/22/2011 13:25:52 11639.00 Isotube Man Loc 21 3378572755.00 01/22/2011 14:25:55 11650.00 Isotube Time21 3378572755.00 01/22/2011 14:25:55 11650.00 Isotube Time 22 3378576358.00 01/22/2011 15:25:58 11660.00 Isotube Time22 3378576358.00 01/22/2011 15:25:58 11660.00 Isotube Time 23 3378578200.00 01/22/2011 15:56:40 11670.00 Isotube Depth23 3378578200.00 01/22/2011 15:56:40 11670.00 Isotube Depth 24 3378582351.00 01/22/2011 17:05:51 11680.00 Isotube Time24 3378582351.00 01/22/2011 17:05:51 11680.00 Isotube Time 25 3378585494.00 01/22/2011 17:58:14 11690.00 Isotube Depth25 3378585494.00 01/22/2011 17:58:14 11690.00 Isotube Depth 26 3378587620.00 01/22/2011 18:33:40 11700.00 Isotube Depth26 3378587620.00 01/22/2011 18:33:40 11700.00 Isotube Depth 27 3378589847.00 01/22/2011 19:10:47 11710.00 Isotube Depth27 3378589847.00 01/22/2011 19:10:47 11710.00 Isotube Depth 28 3378593086.00 01/22/2011 20:04:46 11721.00 Isotube Depth28 3378593086.00 01/22/2011 20:04:46 11721.00 Isotube Depth 29 3378595618.00 01/22/2011 20:46:58 11731.00 Isotube Depth29 3378595618.00 01/22/2011 20:46:58 11731.00 Isotube Depth

Considerations for Considerations for Isotube Sample Isotube Sample Collection:Collection:

Sample must be time and depth Sample must be time and depth correlativecorrelative