imcd brazil + ingevity a new partnership · 2021. 3. 30. · estolides ! bio-based base oil !...

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IMCD Brazil + Ingevity A new partnership

Ingevity High Performance Additives

Who We Are Bold, Energetic, Ingenious and Genuine

Why We’re Here Purify, Protect and Enhance

What’s Important to Us §  Safety and Sustainability §  Customers §  People

§  Integrity and Ethical Behavior §  Creativity and Innovation §  Commitment to Excellence

What We Want to Be §  Recognized leader in our markets §  Proud of where we work §  Positive influence in our communities

Our History

6

1846 1888 1900s 1934 1954 1964 1977

1984 2003 1997 2002 2011 2012

Jan-2015 Jun-2015 Jul-2015 Sep-2015 May-2016 Our Future

Ingevity announced as

name of specialty

chemicals business

MWV merges with RockTenn

to become WestRock

Ingevity Zhuhai, China carbon facility

opened

Ingevity spinoff from

WestRock

A thriving specialty

chemicals and materials company

Ellis, Chaflin & Co. founded,

later Mead Paper Company

Piedmont Pulp & Paper Co.

founded, later Westvaco

Carbon production begins at

Tyrone, Pa. (1914) and Luke,

Md. (1931)

Tall oil distillation and lignin

Development began in

Covington, Va.

Pine chemicals production moved to

Charleston, S.C.

Formal incorporation

of SCD businesses

DeRidder, La. plant added

to operations base

Commercial Applications

Center established

in Shanghai, China

Wickliffe, Ky. Carbon Plant

added to operations base

Mead and Westvaco

merged to form MeadWestvaco,

rebranded to MWV in 2008

Purification Materials

Wujiang (PMW) China carbon plant added to

operations base

MWV adds Brazil locations

& DRT Alliance formed

MWV announces plans to separate

specialty chemicals business

St. Johns Chemical added to

operations base

116 202 0

80 25 107

255 133 31

77 87 95

115 182 50

6 91 186

196 184 170


Meet Ingevity §  Headquarters: Charleston, South Carolina §  Formerly known as: MWV Specialty Chemicals, spun off May 2016

§  Named #1 U.S. spinoff by Forbes

§  Sales: $900+ Million (2016) §  Employees: 1,500+

4 Ingevity High Performance Additives

The meaning behind Ingevity


Purify Protect Enhance

Purifying air and water. Protecting crops and roads.

Enhance metalworking cuts and oilfield drilling performance.

Ingevity’s Lubricants Group

$10M+ !in growth

11 globally located team

members

Ingevity High Performance Additives 7

Launch AltaLUB 5300

in 2016

DeRidder, La.

Waynesboro, Ga.

Covington, Va.

Wickliffe, Ky.

Zhuhai, China

Wujiang, China

Shanghai, China

Charleston, S.C. Lille, France

Charleston, S.C.

Manufacturing Technical Administration and Sales

116 202 0

80 25 107

255 133 31

77 87 95

115 182 50

6 91 186

196 184 170

Performance Chemicals Performance Materials

Our Global Presence



The Value of our Products

• Adhesives • Publication Inks • Paper Chemicals • Rubber

• Oilfield • Asphalt • Metalworking • Chemical Intermediates

• Coatings • Lubricants • Soaps & Detergents • Mining

• Nutraceuticals • Bio-fuels • Binders

Ingevity Value Added Processing End Markets

Fatty Acids & Distilled Tall Oil Rosin Bio-fractions

Pulp Mill

Crude Tall Oil

Bio-Refinery

IMCD Brazil + Ingevity"

• Helps broaden Ingevity’s territory and allows for better service tocustomers in Brazil

• Increases IMCD Brazil’s product portfolio


High Performance Lubricant Additives

Have you heard? We’re not just TOFA & DTO anymore.


Key Functionalities of our Product Strategy

12

Lubrication

Emulsification Corrosion Inhibition

Lubrication Lubrication

Corrosion Corrosion Inhibition Emulsification Emulsification Emulsification


Ingevity’s Metalworking Fluid Additives

Category DTO TOFA Diacid 1550 AltaLUB 5300

Co-emulsifiers " " " "

Surfactants (wetting agents) " " "

Corrosion Inhibitors "

Lubricity Additives " " " "

Couplers "


TOFA is primarily used by customers to create derivatives. Benefits: §  Lubricity agent

§  Low viscosity allows easy handling

§  Rosin content lends less bioactivity relative to vegetable alternatives

§  Multiple reactive sites for derivatization

Metalworking TOFA


Tall Oil Fatty Acids (TOFA)

Palmitic acid (C16:0) CH3 O

OH

O

OH

CH3Stearic acid (C18:0)

Oleic acid (C18:1)

Linoleic acid (C18:2) C H 3 O H

O C H

3 O H

O

Isomer ratios determined by the CTO – pine trees change regionally so TOFA varies


Tall Oil Based Derivatives

§  TOFA is an ideal base material for derivatization

§  Many tall oil derivatives are used in lubricants

C H 3

O H

O

C H 3 O H

O



Esters §  Fuel lubricity additives §  Metalworking fluid lubricants §  Can be ethoxylated to make non-ionic surfactants



Amides §  Emulsifiers and lubricants for Metalworking §  Corrosion inhibitors §  Detergents in fuel systems

H2O



Diacids and Dimer Acids §  Corrosion inhibitors in water based-systems §  Dimers and dimer esters for fuel additive lubricants §  Emulsifiers/couplers in MWF



Estolides §  Bio-based base oil §  Engine oil §  Metalworking fluid base oil §  Demonstrate exceptional results in the areas of

oxidative stability, hydrolytic stability, volatility, biodegradability and renewable carbon content


TOFA Product list


Product Acid value,

min (mg KOH/g)

Color, max (Gardner)

Rosin content, max (%)

Country of origin

Altapyne™ L-1 192 4.0 1.0 United States

Altapyne L-5 190 7.0 5.0 United States

DTO is primarily used by customers as co-emulsifiers. Benefits: §  Excellent co-emulsification additive §  Fatty acid component provides good lubricity §  Higher rosin content contributes to:

§  Reduced foam §  Reduced bioactivity relative to fatty acids

Metalworking DTO


Crude Tall Oil—Valuable Bio Mass Based Raw Material for the Chemical Industry

Biorefinery

Renewable Forests

Tall Oil Fatty Acid Soap, detergents, cleaners, asphalt emulsifiers, rubber emulsifiers, adhesives, paints, coatings, Lubricant Additives, Oilfield Chemicals

Rubber emulsifiers, lubricants Ink resins, paper size, adhesives and rubber emulsifiers

Mining

Distilled Tall Oil

Tall Oil Rosin

Tall Oil Pitch

Energy Use !!Destroys Natural

Functionality !!Does not capture

nature’s chemical value !!Poor use of renewable

resource

Tall Oil Heads

Mining, fuels

Nutraceuticals, Pitch fuel for energy

Extraction


Distilled Tall Oil (DTO) TOFA: and TOR:

C H 3 O H

O

C H 3 O H

O

CH3

CH3CH3

O

OHCH3

CH3

CH3CH3

O

OHCH3

DTO has the properties of both TOFA and Rosin: the best of both worlds.


Metalworking DTO Usage

§ Useful as co-emulsifier in soluble oil and in synthetic formulations § DTO is oil soluble § Must be neutralized to make it water soluble §  The acid number of the DTO is used to determine how much base

needed to neutralize §  Best to add DTO to oil phase first and then add neutralizing base

before adding water


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What makes DTO perform so well?

Acid Number Softening Point

Color, Gardner

Tall Oil Rosin 170-175 >72 4-7

dehydrobetic acid neoabietic acid abietic acid palustric acid

Isomers Comprising Tall Oil Rosin

neoabietic acid abietic acid palustric acid

55% of rosin acid content


Mixed Tall Oil Fatty Acid and Rosin (DTO)


Product Acid value,

min (mg KOH/g)

Color, max (Gardner)

Rosin content, max (%)

Country of origin

Altapyne 226 170 7 30 United States

Diacid 1550


Why use Diacid 1550?

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Unique technology

Branched structure is less vulnerable to microbial contamination

Commonly used amine salts are already TSCA registered

Diacid 1550 is a specialty additive


Diacid 1550 features


§ Multifaceted additive with key benefits

§ Corrosion Inhibition—It’s a great alternative to Corfree M1

§  Emulsification—It’s the best additive on the market for tightening emulsions

§  Lubrication—It’s a great lubricity additive, especially in aluminum forming applications

Diacid 1550 is the best additive for tightening emulsions. See for yourself…


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Emulsion Video


Diacid 1550 is a great alternative to Corfree M1 because ________.



Corrosion testing in formulation These results were obtained from a single metalworking fluid formulation. Each formulation is different, and other formulations may demonstrate different performance.

% Surface Rust as Function of Total Corrosion Inhibitor

100.0050.0025.0012.506.253.131.560.780.390.200.100.050.020.010.01

0.023 0.043 0.063 0.083 0.103 0.123

% Corrosion Inhibitor (Acid + Amine)

% S

urf

ace

Ru

st

Corfree M1Diacid 1550, 7%OCD 2010OCD 536


Corrosion test picture in formulation

How to formulate with Diacid 1550:

1.  Diacid 1550 is easiest to formulate with when added into the oil phase of a semi-synthetic or soluble oil.

2.  From there, the water soluble components and bases can be added later, effectively neutralizing Diacid 1550 and allowing it to function.

3.  Once the effects of Diacid 1550 in a particular system are realized, the formulator can adjust the percentage to optimize the benefits.

Diacid 1550 is oil-soluble or lipophilic. However when neutralized with an appropriate base (sodium or potassium hydroxide or an alkanolamine such as TEA), the resulting salt becomes water soluble.


Key Trend: •  Non-ionic emulsifiers with mid-level

HLB values (around 12 HLB) will lead to higher foam or “more stabilized” foam •  EXAMPLE: TEA salts of Diacid 1550

~ 12 HLB •  These will create a synergistic

effect on building foam. •  If your customer already has

foaming issues, using a TEA salt of Diacid 1550 may not be the right path forward to decrease foam.

Diacid 1550 Foaming Trend Study

Reducing the non-ionic emulsifier dose Increasing Diacid 1550

Generally results in lower foam


Foam

Yes

∆ NI HLB

∆ to low HLB(≤10 HLB)

∆ to high HLB (≥13)

Do not ∆ to mid HLB

(10–13)

Foam

�Diacid 1550 conc.

(≥2%)

Foam

�NI conc.

(≤3%)

No foam

No foam

∆ NI Conc.

∆ Diacid Conc.

No

Foam No foam

Foam No foam

�Diacid 1550 conc.

(≥2)

�NI conc.

(≤3%)

∆ to low Diacid 1550 conc. (1%)

∆ to mid Diacid 1550 conc. (1.5%)

∆ to high Diacid 1550 conc. ( 2%)

Foam

�NI HLB

(≤10)

No foam

�NI HLB

(≤10)�NI HLB

(≥13)

�NI dosage (4–5%)

∆ to low conc. (≤3%)

∆ to mid conc. (3.1–4.9%)

Do not ∆ to high conc. (≥5%)

∆ Diacid 1550 conc. (1–1.5%)

�NI HLB

(≤10)

�Diacid 1550

conc. (≥2%)

�NI HLB

(≤10)

Diacid 1550Decision Guide

ingevity.com

Foam No foam Foam No foam

Foam No foam



The above are only recommendations to reduce foam and may not solve your particular challenge. Please contact the Ingevity technical team for more assistance at [email protected].

KeyHLB Hydrophilic-lipophilic balanceNI Non-ionicconc. Concentration∆ Change� Increase� Decrease

39

Diacid 1550 LubricationAluminum Can Drawing Trial

40

Diacid 1550 provides superior lubrication, requiring less force than isostearic acid to extrude cans. Cans made with Diacid 1550 were also smoother and rounder, and Diacid 1550 foamed less than isostearic acid. Finally, Diacid 1550 also acted as a cleaner, leaving less residue on the cans and dies after application.


AltaLUB 5300


Introducing AltaLUB 5300

AltaLUB 5300 is a performance lubricity additive that:

§  offers ease of formulation

§  demonstrates low foam profiles

§  is hydrolytically stable

Robust performance for:

§  semi-synthetics

§  synthetics

§  soluble oils


Description AltaLUB 5300 is a lubricant performance additive for metalworking fluids. Its unique chemical properties lend themselves to applications where low foam and high lubricity are valued. It also demonstrates ease of formulation versus other complex self-emulsifying esters currently available in the market. Applications include soluble oils, semi-synthetic and synthetic metalworking fluid formulations. Features §  High boundary lubrication §  Low foam §  Ease of formulation

Property Result

Appearance at 25°C amber liquid

Color, Gardner 6 - 7 Odor mild

Acid number, mg KOH/g 100-110 Viscosity at 25°C, cP 460

Weight average molecular weight, g/mol 500

Flash point, closed cup °C 227

Density at 25°C, g/mL 0.8

AltaLUB 5300 Typical Properties


Four-Ball Test Data

20 minute ramp to 200 kg, 600rpm

AltaLUB 5300

LA-8330

Methyl Ester

Standard

Scar diameter (mm) 0.89 0.95 1.05

Torque (kgf·∙m) 0.0756 0.0976 0.0921

Coefficient of Friction 0.08 0.11 0.1

Fluid Temperature (°F)

127 157 150

AltaLUB 5300 is an excellent lubricant as it had the: §  lowest torque §  lowest scar

diameter

§  lowest coefficient of friction

§  lowest fluid temperature

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Falex Four-Ball Wear Testing


Hydrolytic Stability

Samples were mixed with 2000ppm DI water and placed in an oven for 14 days. Acid number was tested periodically. An increase in acid number indicates hydrolysis. AltaLUB 5300 showed no significant hydrolysis after 14 days

Esters often have low hydrolytic stability. AltaLUB 5300 was tested at 80°C versus a competitive self emulsifying ester, and a methyl ester standard for benchmarking.

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Product Starting AN Final AN Change

AltaLUB 5300 110.8 110.6 -0.2

Competitive SEE 31.1 31.0 -0.1

TOFA Methyl Ester 4.3 14.2 +9.9


Microtap Torque Test Test Results

Superior performance on aluminum Equivalent performance on steel

AltaLUB 5300 was tested in a semi-synthetic formulation versus a self-emulsifying ester control. The concentrates were diluted to 5% with DI water, and four samples were tested per fluid, per metal.


AltaLUB 5300 Complex self-emulsifying ester

Objective: Quantitatively determine performance differences between self emulsifying ester lubrication additives and AltaLUB 5300 .

How: Measure drill wear using a semi-synthetic metal working fluid at low concentration and low flow rate to stress the drilling conditions.

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Drill Wear Machine Shop Testing


48

21 rows x 59 holes per row = lots of holes!


Wear Face

50

Drill Face Area of measured wear


! Resolution is 200x! Outside edge is a high speed area, subject to

wear! Drill tends to “flatten” here! Area is integrated to measure drill wear

51

Drill Face Area of measured wear


AltaLUB 5300 Value-In-Use in a semi-synthetic formulation

More consistency & precision, lower variability

0,050

0,060

0,070

0,080

0,090

0,100

0,110

4000 5000 6000 7000 8000 9000 10000

Dril

l Wea

r

Altalub 5300

Competitive SEE

Number of Holes Drilled


Machine Shop Trial !Ra Values

53

For each fluid, 29,412 holes were drilled. The Ra was measured on the cutting surface inside the hole after every 9,804 holes.

16,4%

28,5%

# Ra

41,429

45,322

Average Ra

Lower surface roughness on average Less change over course of trial

Higher precision cutting for longer

Va ues

AltaLUB 5300 Performance in Twist Compression Testing

Good mixed-film boundary lubricant

54

TCT @ 10,000 PSI vs. 42% chlorinated paraffin

AltaLUB 5300 42% Cl Paraffin

AltaLUB 5300 TBD = 26.52s

CP TBD = 32.62s

*Testing on cold rolled steel

55

AltaLUB 5300: Bridging the Gap

AltaLUB 5300

0 100 200 300 400 500 600 700 800 900 1000 1100

Temperature (°C)

Temperature profiles of EP lubricantsC

oeff

icie

nt o

f fri

ctio

n0.5

0.4

0.3

0.2

0.1

0.0

Mineral oil Chlorinated paraffins

Phosphorous compounds

Sulfur compounds

Fatty products


AltaLUB 5300 High Pressure Forming Performance


0

2

4

6

8

10

12

14

16

18

AltaLUB 5300 & Active Sulfur

Polymeric Ester & Active Sulfur

TCT Friction

0

0,5

1

1,5

2

2,5

3

3,5

4

4,5

5

ALtaLUB 5300 & Active Sulfur

Ploymeric Ester & Active Sulfur

Time to Breakdown

Twist Compression Testing on SS304 Ester lubricant & sulfur compounds

AltaLUB 5300 High Pressure Forming Performance


Twist Compression Testing on SS304 Ester lubricant & sulfur compounds

10

10,5

11

11,5

12

12,5

13

13,5

AltaLUB 5300 & Inactive Sulfur

Polyol Ester & Inactive Sulfur

Polymeric Ester & Inactive Sulfur

TCT Friction

0 0,5

1 1,5

2 2,5

3 3,5

4 4,5

5

AltaLUB 5300 & Inactive Sulfur

Polyol Ester & Inactive Sulfur

Polymeric Ester & Inactive

Sulfur

Time to Breakdown

Customer Feedback: Highlights Favorable §  Easy to formulate in synthetic and semis §  Helps stabilize emulsions §  Extends the life of existing formulas §  Very good mixed boundary lubricant §  Important part of some effective CP replacement systems Challenges §  Foam in some synthetic systems §  Doesn’t drop-in for more water soluble lubes §  Not a drop-in for high MW synthetic esters §  Regulatory status is a challenge

IMCD Brazil’s new distribution line from Ingevity Refinery Products §  Altapyne™ L-1

§  Good lubricity §  Easy to handle §  Great for derivatization

§  Altapyne L-5 §  Good lubricity §  Easy to handle §  Great for derivatization

§  Altapyne 226 §  Good co-emulsifier §  Rosin content enhances

performance (lower foam, added biostability)


Specialty Products §  Diacid 1550

§  Multi-faceted product §  Great coupler, corrosion

inhibitor, lubricant (particularly aluminum forming)

§  AltaLUB™ 5300 §  Excellent mixed-boundary

lubricant §  Useful for removing and forming

applications

? Questions

imcd brazil + ingevity a new partnership · 2021. 3. 30. · estolides ! bio-based base oil !...

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