iii. sample data packet
TRANSCRIPT
III. SAMPLE DATA PACKETE.P.A. CASE NO. £33^_____
E.P.A. Sample No. = CompuChem No.
£,=:... ;/'~ T.J- :' ai-4
A, HSL Results — Organic Analysis ' E, TCDD Chromatogram(s)/Data Sheets Quantltalion Report
B, Tentatively Identified CompoundsUst 'F. Pesticide Chromatogram(s|/
•C, VOA Chromatogramls]/ Quantitatlon ReportQuantllatlon Report • Mass Spectra o< GC/MS• Dual Mass Spectra ol HSL Confirmation If Required
Compounds .Q Work Sheets• Ubrary Search Spectra . Analysis WorKsheets
•D, Semi-volatile Chromatogram(s)/ • Extraction WorKsheetsQuantitatlon Report • Compound Usts
I-..IT •• Dual Mass Spectra ol HSL • Miscellaneous CalculationCompounds • Sheets • i
• Ubrary Search Spectra ' '
1 Sequence repeated as required /••'., **' *"' w&j a
024738
A. HSL, Results — Organic Analysis Data SheetsResults are reported on the specified forms lor each fraction of each sample, Detectionlimits are CompuChem's, determined as described in IV-G, Differences in sample sizes ordilutions require application of correction factors, noted in appropriate boxes to bechecked, Dry weights have been determined lor solid samples, and the values on theOrganic Analysis Data Sheets represent dry weight concentrations, % moisture figuresare also noted lor each sample, Where footnotes are applicable, they have been notedwith data qualifiers as described In I -D.
"024739
ORGANICS ANALYSIS DATA SHEET
Laboratory Nome: MeaJ CompuChem___________ Case Numbers.Lab Sample ID No.! ; q 2. toff- °C Report No.iSample Matrix: Solid_________________ Contract No.!Data Re 18050 Author I zed By! /•'/ Date Sample Received: l-
SEMI VOLATILE COPOUNDS
CONCENTRATIOH:w)MEDIUM HIGH (circle-one)DATE EXTRACTED/PREPARED:
DATE ANALYZED: g)-//.gl/PERCENT MOISTURE:
Multiply Detection limits by I Qor loQor(Chock Box tor Appropriate Factor)
iig/lPP» CASil afggAk) PPjr_ CAS>
(circle one)I21A) 6B-06-2 2,4,6-trlchlorophenol _____ 10U (J2BI B7-6B-3 hexachlorobutadlene ________I22AI J9-50-7 p-cnloro-iti-cresol ...ffii (53B) 77-47-4 hexachlorocvclopentadlene IOU(24A) 95-57-B 2-chlorophenol __________ IOU (54B1 76-59-1 Isophorone _________ IOUOIA) I22-B3-2 2,4-dlchlorophenol _______ IOU_ (55B1 91-20-3 naphthalene ___________ [OU_(3<A1 105-67-9 2,<-dlmethYlphenol _______ KW (56BI 98-95-3 nitrobenzene __________ IOU_(J7A) BB-75-5 2-nltrophenol __________ 20U_ 162B) 86-30-6 N-nllrosodlphenylniiilne _____ 10U_(88A) 100-02-7 4-nltrophenol __________ IOOU (63BI 6M-6t-l N-nltrosodl-n-propylamlne ZOU
51-68-5 2,-l-dlnltrophenol ________ SOU (66B) 117-81-7 blsli-ethylhexyllphthalate IOU(60A) »«-52-l 4,6-tJlnltro-Z-methylphenol 20U (67B) 85-68-7 butyl benzyl phthalnte _____ 1£U_I64A) B7-J6-5 pentachlorophanol ________ 201 (6BB) M-T4-2 dl-n-butyl phthelate ______ IOU_I6JA) 108-95-2 phenol ___________ /.T •*&<£& '(69B1 H7-9<-0 dl-n-octyl phthalate ______ 10U_
65-65-0 baiuolc add __________ IOOU (70B) 84-66-2 dlethyl phthelate ________ IOU_95-it6-7 ;-methy I phenol __________ IOU (71B) 131-11-3 dimethyl phthalate _______ HW
____ 106-i9-it 4-methy I phenol _____ JlooO WffS) (72B1 J6-S5-3 ben;ola)anthracene _______ HW95-95-4 2,4,5-trlchlorophenol _____ IOOU (73B) 50-33-B beniolelpyrene _________ 20U_
( IB) 63-32-9 acenaphthene __________ |OU_ I74B1 205-99-2 ben;o(b)<luoranthene ______ 20U_( 5B1 9Z-67-5 Pent I dine ____________ JOU 175B) 207-OB-9 benzothUluoranthene ______ 30UI 8B) 120-02-1 1,2,4-trlchlorobenzene _____ IDU 176B) JI8-01-9 chrvsene _____________ JOU_( 9B) 116-14-1 nexacnlorobeneene ________ imj_ (77B) 208-96-B acenephthylene _________ IOU_II2B) 67-72-1 hexachloroathane ________ IOU_ (7BB) 120-1 2-7 anthracene ____________ [OU_(1BB1 111-^-4 bl8(2-cnloroethyl)ether ____ 1£U_ (798) l8l-2«-2 bentotghllperylene _______ 20U_(20B) 91-86-7 2-chloronephthalane _______ IOU_ (BOB) B6-73-7 fluorene _____________ imj_(25B) 95-50-1 1,2-dlchlorotiemene _______ [OU (81B) 65-01-8 phenenthrene __________ [OU_IZ6B) S4I-7M l.3-dlchlorQ6en;ene _______ IOU (8!B) 53-70-3 d I bento( a, h) anthracene _____ 20U_I27B) 106-46-7 1 .4-dlehlorobentene _______ [OU (B3B) 183-39-5 Indenod ,2.i-cd)pyrene _____ 20U_IZBB) 91-91-1 i.i'-dlchlorobenzldlne _____ 20U_ (84BI 129-00-0 pyrene ______________ [OU_I3JB1 m-M-2 2,4-dlnltrotoluene _______ 2£U 62-5>3 aniline _____________ JOU_136B) 6M-20-2 2.6-dlnltrotoluene _______ 20U_ 100-81-6 benzyl alcohol _________ 20U_I37B1 122-66-7 1 ,2-dlphenylhydratlne _____ 20U 106-47-6 <-chloroanlllne _________ 50U_I39B) 206-44-0 (luornnthene ___________ [OU_ 132-64-9 dlbento(uran ___________ [OU_(40B1 7008-72-3 4-chlorophenyl phenylether IOU 91-57-6 2-inethy I naphthalene ______ 2CWI41B) 101-55-3 4-broiiophenyl phenyl ether IOU eB-74-4 2-nltroanlllne _________ IOOUI42B) 3963B-32-9 bls-(2-chlorol80propyl)ether 20U 99-09-2 3-nltroanlllne _________ IOOU,I43B) 1II-9I-I I) I i- ( 2-ch loroethony Imethane 20U 100-01-6 4-nltroanlllne ______ IOOU
''••• ' .July, 1983024740
- ••. .-, _ .. ... , .,..».,,.., /w»>«w> • *- jaiiiyn] naiiaytjr.u. Box 010, Alexandria, Virginia 22313 • 703/597-2490
^ It ?>S-Q
ORGAfllCS ANALYSIS DATA SHEET«»Laboratory Name: CnmiuClian_______________ Case Number 3* i 3 j»Lab Sample ID No: I<i2ilf ______________ OC Report No. ______Sample Matrix! Solid______________ Contract No.: &P- 01-Data Release Authorized By! _____)(_t ______ Date Sample Received:
VOtATILES PESTICIDES
CONCENTRATION: @) MEDIUM HIGH (circle) CONCENTRATION: (JmJlCDIUM HIGH (circle one)DATE EXTRACTED/PREPARED! t-24-f-U-_________ DATE EXTRACTED/PREPARED: h- A -f !fU______DATE ANALYZED: /-3/-W________________ DATE ANALYZED: J,/'?V-____________PERCENT MOISTURE: I7.<f PACfS>£.zCtt/o7a_____ PERCENT MOISTURE: /•?.$ £*
Multiply Detection limits by I ["jorffi /7 Multiply Detection limits by I POT(Check Box (or Appropriate Factor) (Check Box (or Appropriate Factor)
ug/l Jifl—i-PP» CASf OE-aWKD PP* CASf oOa/g)
(clrdeljfie)_2V) 107-02-B acroleln________________SOU (B9P) 309-00-2 aldrln________ .OU3V) 107-13-1 acrvlonltrlln_____________SOU OOP) 60-57-1____dleldrln
(91P) '57-74-9 chlordane^6V) 56-23-5 carbon tetrachlorlde ' 2.5U 192P) 50-29-3 4.4'-DDT7VI I OB-90-7 ehlorobenzene 2.5U 193P) 72-55-9
ItOVI T07-Q6-2 l.2-dlehloro«thane 2.5U' (94P)~72-54-B~(11V)(I3V1
l.l.l-trlchloroatnane 2.51T (95P) 115-29-7 endosulfan I!'!"-lch!or°att""1° ?'?H! *. -'—-!l?rz?_7- andosulfan II]?y? I?'??'- 1.1.2-trlehloroethana 2.5U (97P) '1031-07-B andosuKan suKatei. j.Z-g1.1.2.2--la—»5V) 79-34-5 • 1.1.2.2-tatrachloroathana 2T5JT I9BPI 7B-20-B
. T 6 V 1 7 5 - 0 0 - 3 c h l o r o a t h a n a 5 T 5 1 T (99P) 7421-43-4 andrln aldehyde(19V) llP-75-a 2-chloroethylvlnvl ether 2.SIT (100P1 76-44-B hectachlorT123Vj 67-66-3 chloroform 2.5U (10IPI 1024-57-3 hrotachlor epoxlde
l.l-dlchloroathene 2.SiT (I02P) 319-B4-6 BHC-Alph~(30V) 156-60-5 1.2-trans-dlcnloroethenB 2.5U' ?!9???lj!_"_j"l -!!.".??'(32V1 7B B7-5 1,2-dlchloropropane 2.5U (104Pr3l9-B6-B(33V) 10061-02-6 trans-l.3-dlchloroorooene 2.5U' (105P) 5B-B9-9
10061-01-05 cl5.1.3-dlehloropropene W_ H06PJ53469-2I-9 PCB-1242(3BV) 100-41-4 ethyl benzene /.'/" rifcjy' (107P) 11097-69-7 PCB-1254(44VI 75-09-2 mathy I one chloride -a A-a- tfe), (IOBP) 11I04-2B-2 PCB-I22I(45V) " 74-B7-3 ehloromethane 2.5U 1109P) I1I41-I6-S PCB-1232(46VI 74-63-9 bromomethane 2.5U (HOP) 12672-29-6 PCB-I24B(47V) 75-25-2 broniQ(orm 2.SIT (HIP) II096-B2-5 PCB-1260
.OUOU
' ( 4 B V ) 7 5 - 2 7 - 4 b r a n o d I e h l o r o m e t h a n e 2 . 5 U (112P) 12674-11-2PCB-1016(49V) 75-69-4 (luorotrlchloromethane ,y; -iri i. (113P) BOOI-35-2 toxmihen7~'(51V) 124-46-1 chlorodlbromomethane 2.51T(B5V) 1.7-rB l tatrachloroathane(B6VI IOB-BB-3 toluene /fQ -2*m&S< DIOXINS(B7V) 79-01-6 trlchloroathena(BBVI 75-01-4 vinyl chloride______2.5U
1 67-64-1 " acetone y'7gO-5Wdi>''i-nutancinB >/ cioOJBjjpg •_ CONCENTRATIONj .flg) MEDIUM HIGH (clrclo)
75-15-0 cnrbondlsuldde ----- ^j— ^^ EXTRACTED/PWAREP! !,!£——————— 2-haxanona ' -I •kdZR$M&' DATE ANALYZED: ______J£"~
— ll'-f f»i,4-methvI-2-pentanone / 3fit >-Mtt»-P . PERCENT MOISTURE:
vinyl acetate 5U ug/i
Iclrc'2,3,7,6-tetrachlorodlbenzo-
(129B) 1746-01-6 p-dloxln_________0.16U
July, I9B3
024741
B. Tentatively Identified Compounds ListThe form used to list tentatively Identified compounds Is generated at CompuChem by theGC/MS Instrument data system lor each fraction analyzed. This form lists the fraction,sample number, scan number, CASiC, name, and estimated concentration for compounds'whose peaks exceed 25% ol the nearest internal standard's response. Appropriatefactors for correction of sample or extract volumes, dilutions, etc, are added by theanalyst prior to injection, so that the concentration has been adjusted when it Is printed onthe form. There are places on the form lor the spectral interpretation expert to noteInformation and opinions about the identification, and to initial the searches.
.024742
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C. VOA Chromatogram(s)/Quantitation ReportFor those compounds detected at greater than '/i the detection limits on the MSL listing,dual mass spectra are provided, These spectra are labeled with the CAS# and theCompuChem compound number associated, and can also be identified with reference tothe scan number and base Ion noted on the automatic quantitallon report. The spectra fornon-HSL. compounds present at greater than 25% of the response of the nearest internalstandard are also Included. These are obtained from a library search of the EPA/NIHspectral data base,These spectra were generated via a limited-library search against standards run at thebeginning ol the contract work, on each instrument.
I 31024745
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:. ?024746
PROCEDURE: RK DIAGNOSTIC REPORT 1/31/84 11:46:4-DATA FILE: GH019264A1BREFERENCE: V23B
METHOD: V23Q INITIALIZATION OPTION: 3 PROCESSING OPTION: 3
< •—— STANDARDS ——— X. —— PLUS UNKNOWNS —— X - LIST NAMES - ?PROC USED POSS RMS PROC USED POSS RMS STANDARD/UNKNOWN
3 a i o 44 11 i 46 VH3ssi/v_3Bui
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111S34567891011121314IS16171819234567891011121323456789234
-H30-411-491-54-87-106-130-172-182-182-195-an-2202-283-247-261-S70-285-284-313-320-321-327-356-360-371-384-3B5-386-382-407-436-448-479-483-484-5516-546-608-748-791-283-5312-691
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CIUANTITATION REPORT FILE: GH019-64A18
DATA: GH019864A1S. T_01/31/84 11:06:00SrVJjjjLE! 10 CM OF SAMPLE «19264 •(• Si UL 10941*10936 ON »1SSUTTCTrED BY: ttiB ANALYST: 633
AMOUNT=AREA * REF. AMNT/tREF. AREA)* RESP. FACT)RE8P. FAC, FROM LIBRARY ENTRY
NO NAME1 * BROMOCHLOROMETHANE (IS)8 221 CHLOROMETHANEa 220 BROMQMETHANE - '4 231 VINYL. CHLORIDE-i 209 CHLOROETHANE6 222 METHYLENE CHLORIDE7 252 ACETONE (2-PROPANONE)8 201 ACROUEIN9 302 ACRYLONITRILE10 830 TRICHLOROFLUOROMETHANE11 254 CARBON DISULFIDE18 216 1, 1-DICMLOROETHYLENE13 314 1, 1-DICHLOROETHANE11 226 TRANS-1/ 2-DICHLOROETHYLENEIK 211 CHLOROFORM16 815 1. 8-DICHLOROETHANE17 '253 H-BUTANQNE113 227 1, i, 1-TRICHLOROETHANE19 206 CARBON TETRACHLORIDE2|M * 2-BROMO-l-CHLOROPROPANE ,2i 257 VINYt ACETATE . . Ias'' 212 BROMODICHLOROMETHANE „_83 217 1, 8-DICHLOROPROPANE2/1 250 TRANS-1, 3-DICHLOROPROPENESB 229 TRICHLOROETHYLENE26 203 BENZENE27 288 1, 1, 8-TRICHLOROETHANE20 218 CIS-1, 3-DICHLOROPROPENE89 208 DIBROMOCHLOROMETHANE30 210 3-CHLOROETHYL VINYL ETHER31 205 BROMOFORM3P. 256 4-METHYL-2-PENTANONE33 * DICHLOROBUTANE34 255 8-HEXANONE38 223 1, 1, 2, 2-TETRACHLOROETHANf36 224 TETRACHLOROETHENE37 225 TOLUENE3P 207 CHLOROBENZENE39 219 ETHYLBENZENE40 S51 STYRENE41 239 0-XYLENE4M tt D4-1, 2-DICHLOROETHANE43 # OS-TOLUENE44 (t BROMOFLUOROBENZENE
N', ,M/E SCAN TIME- REF RRT METH AREAtHGHT) AMOUNT '/.TOT
NO M/E SCAN TIME REF RRT METH AREA(HGHT) AMOUNT '/.TOT1 130 22S 11:35 1 1,000 ABB 7489S, 10. 000 UC/KC 0,28?. NOT FOUND
«-*, NOT FOUND. NOT FOUND5 NOT FOUND
84 4,68 8:32 1 0, 737 A BB 940123. CjtA. 12S UC/KC 4. -.7 58 _;____ 9:06 1 0.785 'A BV 324472, QS69. 535 UP/KG 16 53S NOT FOUND ——————~~9 NOT FOUND _ ———10 101 809 10:37 1 0.917 ABB 318S8, (ji. 729 UC/KG B, l...11 76 _§l 10:13 1 0, 882 ABB 1268. 0. 053 UC/KG 0.00IS NOT FOUND ~ '13 NOT FOUND14 NOT FOUNDIS 83 269 13:40 1 1, 180 A BB 3000. 0. 259 UG/KG 0. 0116 68 283 14:23 1 1,244 A BB 1364. 0, ISO UC/KG 0, 01 (|17 78 883 14:23 1 1.241 A BV 8848880, />gSn"?.'BO- UG/KC 73, 46 S) viilIB NOT FOUND U_-.!'3--19 MOT FOUND80 79 411 80:54 20 1,000 ABB 34333. 10. 000 UC/KG 0.8821 NOT FOUND23 NOT FOUND23 NOT FOUND24 NOT FOUND _____8S NOT FOUND -*~-"—————'26 78 383 19:28 1 1. 680 A BV 24257. C±. 487 UP/KG27 NOT FOONiT ———————SB NOT FOUND:*•* NOT FOUND3W NOT FOUND31 NOT FOUND3B 58 448 22:46 1 1. 965 A BV 175996.33 55 491 24: SB 33 1, 000 A BB 86496.34 58 479 24:21 1 2. 104. A BB 83264.3S NOT FQUN&36 NOT FOUND ____________37 98 516 86:14 1 3. 263 A BB 182818, (iB, 903 UC/KC O.J38 NOT FOUND-
10, 000 UG/KC(41, 204 UG/KG'
3? .106 60J_ 30:54 1 2.667 ABB 11965, fl734a UC/KC 0. 044ft 104 748 38:01 1 3. 281 AWB 2740. 0, 153 UG/KC 0. 004J 106 798 40:16 1 3. 474 A*VV 12936. i, 179 UG/KG 0. 034& 65 282 14:20 1 1. 237 A BV 10303S. 12. 222 UC/KG 0. 3540 100 512 26: OS 1 2. 246 A BB 153452, 12, 039 UO/KC 0, 3441 176 691 35:08 1 3. 031 A BB 170857. 12. 283 UG/KG 0. 35
NO RET(L) RATIO RRT(L) RATIO AMNT AMNT(L) R, FAC R. FAC(L) RATIO.1 11: 41 0, 99 1. 000 1, 00 10, 00 10, 00 i, 000 1, 000 1, 00H 2:45 0. 235 40, 00 0, 497a 4:35 0. 378 40, 00 1, 8314 5:83 0. 461 40, 00 1, 8758 6:36 0, 565 40, 00 0. 3796 8:45 0. 98 0, 74S 0, 99 164, 13 40. 00 3, 138 0, 765 4, 10V 9:4,5 0. 98 0. 791 0, 99 S69, 53 899, 99 0. 144 0, 076 1, 9013 9:4,5 0. 791 399. 99 9, 091
; 9:55 0.848 399,99 0.210It) 10:44 0. 99 0, 917 1, 00 2, 73 40, 00 0, 104 1. 531 0. 07
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D. Semi-Volatile Chromatogram(s)/Quantitation ReportFor those compounds detected at greater than Vi the detection limits on the HSL Hating,dual mass spectra are provided. These spectra are labeled with the CAS# and theCompuChem compound number associated, and can also lie identified with reference toIhe scairnumDer and base ion noted on the automatic quantllatlon report. The spectra lornon-MSL compounds present at greater than 25% ol the response ol the nearest Internalstandard are also included, These are obtained from a library search ol Ihe EPA/NIHspectral data base,These spectra were generated via a limitecHlbrary search against standards run at thebeginning ol the contract work, on each instrument.
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PROCEDURE; RK DIAGNOSTIC REPORT 2/11/04 13:37DATA FILE: GR019264C14REFERENCE: FSCC7
METHOD: FSCC7 INITIALIZATION OPTION: 2 PROCESSING OPTION: 3REPORT: FSCC7S1
f. —-- STANDARDS ——— X —— PLUS UNKNOWNS —— X - LIST NAMES - >PROC USED PCISS RMS PROC USED PQSS RMS STANDARD/UNKNOWN
6 6 I 67 04 7 1 93 F5CC751/FSCC7U16 6 1 67 34 13 1 108 FSCC7S2/FSCG7U2
< COMPOUND X ————————— SEARCH ————————— X SAT X ———— CHRONO LIB ENTRY REF PRED SEL DELTA PEAKS FIT PEAKS M/E TOP DELTA1 Cl 1 -789 792 792 . 1 981 , 190 7922 C2 1 -1033 1056 10S7 1 1 983 . 136 1036 -I3 C3 1 -1445 1448 1447 -1 1 991 , 164 14474 C4 1 -1773 1775 1775 . 1 933 180 1774 -13 C5 1 -2375 2377 2377 . 1 835 S40 23776 C6 1 -2661 2663 2663 , 1 828 264 26637 Cl 2 -299 303 . , , ,74 301B C l 3 -753 7 5 7 . . . . . 9 4 7 3 89 Cl 4 -738 742 931 0 C l 5 -738 7 6 2 , , . . . 9 3 7 6 011 Cl 6 -756 760 . , , . 1 2 0 .12 Cl 7 -779 783 , . . . 14613 Cl 8 -791 795 , , . , . 14614 Cl 9 -834 838 . . , 106
i- 1 13 Cl 10 -827 831 , , , , 14616 Cl 11 -868 B'72 , . , 10817 Cl 12 -866 870 , . , . 12118 Cl 13 -900 904 905 1 1 970 . 108 90519 Cl 14 -896 900 , . . , 13020 Cl 15 -BB7 891 , . . . 117
. 21 Cl 16 -914 918 , , , , 1232 2 C 2 2 -967 9 7 1 . . . . . B S . .23 C2 3 -982 986 , . , , 13924 C2 4 -1009 1013 12225 C2 5 -1027 1031 9326 C2 6 -1070 1073 10527 C2 .7 -1035 1038 . , , , , 162 .2 8 C Z 8 -1047 1030 . . . . . 1 8 0 . ,2 9 C 2 9 -1058 1061 . . . . . 1 2 8 , .30 C2 10 -1087 1090 1273 1 C 2 1 1 -1106 1109 . . . . . 2 2 5 . .3 2 C 2 1 2 -1206 1209 , . . . . 1 0 7 . .3 3 C 2 1 3 -1212 1215 . . . . . 1 1 5 , .34 C2 14 -1263 1268 23733 C2 15 -1287 1290 . , . . 1963 6 C 2 1 6 -1293 1298 . . . . . 1 9 6 , .37 C3 2 -1317 1320 1623 8 C 3 3 -1360 1363 . . . . 1 3 8 . ,39 C3 4 -1416 1419 16340 C3 5 -1409 1412 1524 1 C 3 6 -1427 1430 . . . . . 1 6 5 , .4 2 C 3 7 -1449 1452 . . . . . 1 3 8 , .4 3 C 3 B -1432 1433 . . . . . 1 5 4 024781'44 C3 9 -1478 1481 , . . , 1B4 , .4 3 C 3 1 0 -1312 1313 , . . . . 1 0 9 , .46 C3 11 -1488 1491 , , b „ . , 1 6 847 C3 12 -131S 1315 . . r 0 1 , . 1 6 5
50 C3 IS -1565 156S . . . . . 166 .31 C3 16 -1620 1623 . . . . . 138 .52 C3 17 -1601 1604 . . . . , 19B33 C3 18 -1608 1611 . . . . , 169 .54 C3 19 -1610 1613 . . , . 7755 C4 2 -1683 1686 . . . . 24856 C4 3 -1706 1709 . . , , . 2 8 4 .5 7 C 4 4 -1754 1737 . . . . . 2 6 658 C4 3 -1777 1780 . . , . . 178 ,59 C4 6 -1787 1790 . . , , , 178 .6 0 C 4 7 -1949 1932 . . . . . 1 4 9 195161 C4 8 -2047 2050 . . . . . 202 •' ,62 C3 2 -2095 2097 , . . . 202" • .63 C3 3 , . , , . , . 184 .64 C5 4 -2284 2286 . . . , „. 149 .65 C3 5 . . , . . . 25.266 C5 6 -2372 2374 . . . , 22867 C5 7 -2429 2431 , . . , 149 ,6B C5 8 -2381 2383 . . . , 22869 C5 9 -2562 2364 , . . , 14970 C6 2 -2604 2606 , . , , 25271 C6 3 -260B 2610 , , , , 25272 C6 4 -2665 2667 , , , , 25273 C6 S -2909 2910 , . , , 27674 C6 6 -2920 2921 , . . , . 27B ,75 C6 7 -2977 2978 , . . , 27676 C7 2 -564 568 569 177 C7 3 -730 754 736 278 C7 4 -910 914 913 -179 C7 5 -1306 1309 1308 -180 C7 6 -1625 1628 1629 1
995 , 112 369B99 . 99 756994 . 82 913991 , 172 1308949 , 330 1628 -1
* « 81 C7 7 -2091 2093 2094 1 • 1 914 , 212 209482 C7 8 -2131 2153 2154 1 1 983 , 244 2154
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QUANTITATZON REPORT FILE: OR019264C14
DATA: OR019S64C14, TIIM| 02/11/84 12;32:00
SAMPLE; 1UL 19264R + 5UL IS (10933)SUBMITTED BY: 14 ANALYST: 754
AMOUNTnAREA * REF, AMNT/(REF. AREA)* RESP. FACT)REBP. FAC. FROM LIBRARY ENTRY
NO NAME '' •1 *D4~1.4-DICHLQRQBENZENE (IS)2 441 N-NITROSQDIrlETHYAniNE _. ...3 610 PHENOL4 473 ANILINE5 411 B IS (2-CHLOROETHYL (EITHER6 601 2-CHLQRQPHENOL7 421 1.3-DICHLOROBENZENE8 422 1>4-DICHLOROBENZENE9 474 BENZYL ALCOHOL10 420 1,2-DICHLOROBENZENE11 620 2-METHYLPHENOL12 412 BIS (2-CHUaRQISQPROPYD ETHER13 622 4-METHYLPHENOL14 442 N-NITROSO-DI-N-PRQPYLAI1INE15 436 HEXACHLOROETHANE16 440 NITROBENZENE17 »460 D8-NAPHTHALENE (IS)IB 438 ISOPHORONE
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j 43 424 DIETHYLPHTHALATE46 417 4-CHLQRQPHENYL PHENYL ETHER 024783
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NO NAME47 43s PL.UORENE4B 480 4-MTROANILINE49 604 4i 6-DINITRO-Q-CRESDL50 443 DIPHENYLAMINE (N-NITRQSO)51 430 1, 2-DIPHENYLHYDRAZINE (AZQBENZENE)52 *467 D10-PHENANTHRENE (IS)S3 414 4-BRQMOPHENYL PHENYL ETHER54 433 HEXACHLOROBENZENE35 609 PENTACHLOROPHENOL '' '56 444 PHENANTHRENE57 403 ANTHRACENE ' - -58 426 DI-N-BUTYLPHTHALATE59 431 FLUQRANTHENE60 #439 D12-CHRYSENE (IS)61 44S PYRENE62 404 BENZIDENE63 415 BUTYLBENZYLPHTHALATE64 423 3, S'-DICHLOROBENZIDINE65 405 BENZQ(A(ANTHRACENE66 413 BIS(2-ETHYLHEXYL)PHTHALATE67 418 CHRYSENE6B 429 DI-N-OCTYLPHTHALATE69 #D12-BENZQ(A)PYRENE (IS)70 407 BENZO(B)FLUQRANTHENE71 409 BENZO(K)FLUORANTHENE72 406 BENZO(A)PYRENE73 437 INDENO(1,2,3-C,D)PYRENE74 419 DIBENZO(A,H)ANTHRACENE75. 408 BENZO<G,H, DPERYLENE •76 619 2-FLUQROPHENQL (SURROGATE)77 D5-PHENDL (SURROGATE)78 447 D5-NITROBENZENE (SURROGATE)79 44B 2-FLUQRQBIPHENYL (SURROGATE)80 TRIBRQMOPHENQL (SURROGATE)81 D10-PYRENE (SURROGATE)82 D14-TERPHENYL (SURROGATE)
NO M/E SCAN TIME REF RRT METH AREA(HGHT) AMOUNT "/.TOT1 150 792 9:54 1 1,000 ABB 36046. 40.000 NG 3,412 74 301 3:46 1 0. 3BO A*W 3241. 9. 940 NG 0, 85<tt>3 94 758 9:28 1 0,957 A'BB 6472, 7.363 NG 0.4 NOT FOUND3 93 760 9:30 1 0. 960 A BB 1978. 2. 642 NG 0, 236 NOT FOUND
. 7 NOT FOUND8 NOT FOUND9 NOT FOUND10 NOT FOUND11 NOT FOUND12 NOT FOUND13 108 905 11:19 1 1,143 ABB 13968, 21.651NG14 NOT FOUND15 NOT FOUND16 NOT FOUND .17 136 1056 13:12 17 1,000 ABB 77504, 40. 000 NG 3.4118 NOT FOUND 024784
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NO M/E SCAN TINE REF RRT METH AREA(HGHT) AMOUNT '/.TOT19 NOT F-IUND20 NOT FO.-ND21 NOT FOUND22 NOT FOUND23 NOT FOUND24 NOT FOUND25 NOT FOUND26 NOT FOUND27 NOT FOUND2B NOT FOUND29 NOT FOUND - -30 NOT FOUND31 NOT FOUND32 NOT FOUND33 164 1447 18:05 33 1.000 ABB 38367. 40.000 NG 3,4134 NOT FOUND35 NOT FOUND36 NOT FOUND37 NOT FOUND3B NOT FOUND39 NOT FOUND40 NOT FOUND41 NOT FOUND42 NOT FOUND43 NOT FOUND44 NOT FOUND45 NOT FOUND46 NOT FOUND47 NOT FOUND48 NOT FOUND49 NOT FOUND50 NOT FOUND51 NOT FOUND52 188 1774 22:10 52 1.000 A BV 62723. . 40. 000 NG 3.4153 NOT FOUND54 NOT FOUND55 NOT FOUND56 NOT FOUND57 NOT FOUND58 149 1951 24:23 52 1,100 ABB 831, 0, 357 NG 0,0359 NOT FOUND60 240 2377 29:43 60 1,000 AW 24705. 40, 000 NG 3.4161 NOT FOUND62 NOT FOUND63 NOT FOUND64 NOT FOUND65 NOT FOUND66 NOT FOUND67 NOT FOUND68 NOT FOUND69 264 2663 33:17 69 1.000 ABB 14606. 40, 000 NG 3,4170 NOT FOUND71 NOT FOUND72 NOT FOUND .73 NOT FOUND74 NOT FOUND
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NO M/E SCAN TIME REF RRT METH AREA(HGHT) AMOUNT '/.TOT75 NOT FOUND„__, 76 112 ?69 7:07 1 0,718 A#BV 68334. 139.141 NG 11.SB
77 99 736 9:27 17 0.716 A BV 68963. 86. 513 NG 7.3878 82 .913 11:25 17 0.863 A BV 94036. 123,707 NG 10,3679 172 1308 16:21 17 1,239 ABB 178423, 130, 323 NG 11,1280 330 1628 20:S1 33 1.125 ABB 11776, 76. 699 NG 6,3581 212 2094 26:10 60 0.881 A BV 200849. 191, 210 NG 16.3282 244 2134 26:55 52 1.214 A BV 146393. 142. 373 .NG 12.17
NO RET(L) RATIO RRT(L) RATIO AMNT AMNT(L) R, FAC R.FAC(L) RATIO1 9:52 1.00 1,000 1,00 40.00 40.00 1. QOO . 1.000 1.002 3; 44 1.01 0,379 1.00 9.94 50.00 0,072 0.362 0.203 9:25 1.01 0.954 1.00 7.36 50,00 0,144 "0.973 0.154 9; 13 0, 933 50, 00 0, 9993 9; 28 1,00 0,961 1,00 2.64 30,00 0,044 0.831 0,036 9:27 0. 958 50. 00 0.7427 9; 44 0. 9B7 50,00 0.857B 9:53 1,003 50,00 0.9119 10:25 1.057 50.00 0.43310 10:20 1.048 50,00 0.82611 10:51 1.100 50.00 0.58812 10:49 1,098 50.00 0.21113 11:15 1,01 1,141 1,00 21,65 50.00 0,310 0.716 0,4314 11; 12 1. 1-6 50, 00 . 0. 12415 11:03 1,124 50.00 0.31116 11:25 1.158 ' 50,00 0,39017 13:10 1.00 1,000 1.00 40.00 40,00 1.000 1.000 1,00
• IB 12:05 6.918 . 30,00 0.62619 . 12: 16 0, 933 50, 00 0, 169
' 20 12:37 0.938 50.00 0. 32421 12; 50 0, 975 50, 00 0. 45522 13:22 1.016 250,00 0.08423 12: 56 0. 983 SO. 00 0. 27624 13:05 0.994 30.00 0,36025 13; 13 1. 005 30. 00 1, 15726 13:35 1.032 249.99 0.26927 13:49 1. 050 50, 00 0. 17028 13; 04 1. 145 30,00 0. 36929 13:09 1. 151 30.00 0, 26330 15:49 1.201 30,00 0.09231 16:05 1.222 50,00 0,21032 16:11 1.230 249,99 0.20033 18:04 1,00 1.000 1.00 40.00 40.00 1.000 1,000 1.0034 16:28 0.911 50.00 1,22635 17:00 0. 941 .249. 99 0. 44936 17:42 0.980 50,00 1.48637 17:37 0.975 30,00 1.49738 17: 50 0, 988 50. 00 0.29339 18:07 1.003 249.99 0.06140 18:09 1,005 30,00 1.15541 18:28 1.023 249.99 0.08142 18:54 1,046 125,00 0.04443 18:36 1,030 50,00 1.70744 18:54 1,046 50.00 0.40745 19:43 ' 1.092 50,00 1,54846 19:42 1.091 50.00 0,521
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47 19:3- 1.083 50.00 1.29648 20:15 1.121 249.99 0.03149 20:01 1. 10S 249.99 0,14950 20:06 1,113 50,00 0,63451 20:07 1.114 50.00 1,46552 22:10 1,00 1.000 1.00 40.00 40.00 1.000 1.000 1.0053 21:02 0,949 50.00 0.17654 21:19 0.962 50.00 0/22755 21:53 0.989 50,00 0/08756 22:13 1.002 50,00 1. 17657 22:20 1,008 50,00 - -0,94558 24:22 1.00 1.099 1,00 0.36 50.00 0.011 .1,484 0.0159 25; 35 1.155 50,00 1.10560 29:41 1.00 1.000 1.00 40.00 40.00 1. 000 1.000 1.0061 26:11 0,882 30.00 1.93462 26:59 0.908 50.00 0,01063 28:33 0.962 30,00 1,04464 30; 43 1.007 50,00 0.01865 29:39 0.999 50.00 1.39066 30:22 1,023 50.00 1,43367 29; 46 1.003 50,00 1,13668 32:01 1.079 50.00 2.36169 33:16 1.00 1,000 1,00 40,00 40.00 1.000 1.000 1.0070 32:33 0.979 50, 00 1. 40171 32; 36 0,9BO 30.00 1.13272 33; 19 1.002 50,00 1.12873 36:22 1.093 30.00 0.52774 36:30 1,097 50,00 0.47375 37:13 1,119 50.00 0.510 I76 7:03 1,01 0,713 1,01 139.14 30.00 1,517 0.545 2,7877 9:22 1.01 0.712 1.01 86,52 50.00 0,712 0,411 1,7378 11:22 1,00 0.864 1.00 123.71 30,00 0.971 0.392 2.4779 16:19 1.00 1,240 1,00 130,32 50,00 1.842 0.707 2.6180 20:19 1,00 1,125 1.00 76,70 50,00 0,246 0,160 1.5381 26:08 1.00 0. 8BO 1.00 191.21 30.00 6.504 1.701 3.8382 26:53 1,00 1,213 1,00 142,57 50,00 1.867 0,655 2.85
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E. TCDD Chromatogram(s)/Quantitation ReportInstead ot the GC chromatogram required In the contract, Ihe TCDD extract is analyzedby GC/MS, and Ihe RIC, EICP. and mass chromatogram la Included, as well as theautomatic quantltatlon report. An Internal standard, carbon- 13'labeled 2,3,7,8-TCDD. isused lor quantitatlon ol surrogate and any native which might be present. If the presenceol an Interference Is detected, an external standard calculation Is used, II Ihe presence ofnative 2,3,7,8-TCDD Is detected, Ihe Sample Management Olflue Is Informed so furtheranalysis can be performed,
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I 31
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PROCEDURE-. RK DIAGNOSTIC REPORT 2/10/B4 4iAB-._BDATA FILE-. TC019a64C05P^ERENCEi TC"" METHOD-. TC INITIALIZATION OPTION: 3 PROCESSING OPTION: 3
REPORT-. TCS
< —— STANDARDS ——— X —— PLUS UNKNOWNS —— X - LIST NAMES - >PROC USED POSS RMS PROC USED POSS RUB STANDARD/UNKNOWN
2 2 8 293 7 7 J. 3T TCS/TCU
7 COMPOUNDS PROCESSED. 7 FOUND " •
< COMPOUND X -'—--———•-- SEARCH -———--—•- x SAT IK. ---—•• CHRO c——-— yNO LIB ENTRY REF PRED SEL DELTA PEAKS FIT PEAKS IVE~ TOP DELTA PEAKS1 TC i 787 711 709 -2 i B31 , 332 709 . 1S TC S 685 6B9 691 2 2 991 . 320 _9i . i3 TC 3 685 691 691 . 1 991 3H2 69, -1 i4 TC 4 685 691 691 . 1 991 257 691 , 15 TC 5 70B 710 710 . 1 791 320 707 -3 36 TC 6 70S 710 710 . 1 791 322 710 . 17 TC 7 70S 710 709 -1 1 B44 , 257 710 i i
024814
3,
MEAD COMPUCHEMQUANTITATION REPORT FILE; TC019264C05
W4TA: TC019264C05, TI-_/i0/84 3: 56-. 00SAMPLE: 3/30 UL CCtti9264(EPA*R35031-26> OWA «SSUBMITTED BY: 5 ANALYST: 763
AMOUNT-AREA(HCHTJ * REF, AMNT/IREF. AREA*HCHT>* RE9P. FACT)RESP, FAC. FROM LIBRARY ENTRY
NO NAME1 #13Cia-2, 3,7,8-TCDDIINTERNAL STANDARD) - -2 1, 8. 3r 4-TCDD3 1. 2, 3r 4-TCDD4 1, Sr 3. 4-TCDD5 2, a 7, B-TCDD6 S, 3r 7. B-TCDD7 2, a 7r B-TCDD
NO M/E SCAN TIME REF RRT METH AREA(HCHT) AMOUNT XTOTi 332 709 15:57 1 1. 000 A BV 2773470, 200. 000 PC/UL 30. B62 320 691 15:33 1 0. 975 A VV 2673350, 155, B14 PG/UL 23, Bl3 322 690 15:32 1 0, 973 A W 33425B0, 154. 618 PC/UL 23. 624 257 691 15:33 1 0. 975 A VV 1B15190, 76, 176 PC/UL 11, 645 320 707 15:55 1 0. 997 AtVB 52001, 3, 703 PC/UL 0, 576 322 710 15:59 1 1. 001 A VV 64B24, 3, 732 PC/UL 0, 577 257 710 15:59 i 1. 001 A VV 487544. 60. 498 PC/UL 9, 24
10 RET(L) RATIO RRT(L') RATIO AMNT AMNT<L> R. FAC R, FAC(L) RATIO i1 15:56 1. 00 1. 000 1, 00 200. 00 200, 00 1. 000 1, 000 1. 002 15-, 25 1, 01 0. 968 1, 01 155, Bl 200. 00 0. 964 1, 237 0. 7B3 15:25 1, 01 0, 96B 1, 01 154. 62 200. 00 1. 205 1. 35"? 0. 774 15'. 26 1. 01 0. 969 1, 01 76. IB 200. 00 0. 654 1, 718 0. SB5 15:56 1. 00 1, 000 1, 00 3, 70 200. 00 0. 019 1, 013 0. 026 15'. 56 1, 00 i. 000 1, 00 3, 73 200, 00 0. 023 1, 253 0, 027 15:56 1, 00 1, 000 1. 00 60. 50 200. 00 0. 176 0, 581 0. 30
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P. Pesticide Chromatogram(s)/Quantitation ReportChromatograms Irom the paoKed and capillary column GC analyses of pesticide fractionsare Included, Where Ihe retention lime Indicates the presence ol a pesticide on Ihe HSLlist in the sample, it ia confirmed on an alternate column. It the concentration is highenough, OC/MS confirmation Is provided and documented with a spectrum, as describedin Ihe contract, Exhibit D, page B ol 70, sections 1.1 • 1.2.
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.fib (/ _, (Kill a. Ill) ' _i.76'/bun-Link Dvl I.-.l.v- He-P-fil'W %IHU XDal -I-" .I'm
NO II, IKI 0 .30 ..(I Kill. Oil . Nil
Actual, run tinei 30.013 n-nutesk'eadjnrjfs)Ended not on baseline
R'l ITM factor Area eU'li.A %
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I 31
S3.71) 73.<;ib . UIOllOlH'Ol. 612L1..1. BV 61233. 'Jill)KS...17 9V. 36 ..111 (I I) (It,-i 111 Will1.,. 81) V7.'I!,. Millas..win i). Do .lii)76_ •o1..; 11.1(716. av . ia&i'1..'. 76) 111. 69 .10011(11.'Mil i-'.i-JlVV. BV SytMlVV, .(III-9.06114.7,1 .IIIIIDIIL" Mil U9ll/;i6. Si) ,'<90b6,1100
ToTfi.1 Area = 4ll(fi6ail7/:1. 'lotal Ak'l.fl % -• UVH66. Oli l ih'd.&'M.e'cl dfltfi f i i J i s i l'"/".il/ k'atj datri •Cj;ii?i k'V.17
024820
31
024821
31
Report i 3.1,85.00 Channpli S C*!?333 R3503*"^Mr)lei OP 19264 Injected at 11. u?6i?,l. f)N Ff.B 3, 1.984ESTDMethodi PADKO!?. Spq i 8EQSS Siib«ir|/SaMri i I/I? B t l s 4!?Si-width MV/Min Delay Min-Ar Bunch
.500 .300 0.00 SO AutoSup-llnli DvT ID-lvl. Ref-RTW %RTW JSOil-f Ten
NO 0.00 0 .30 5,0 100,0(1 10Actual run tlciei 85.008 Minutes
RT ITM Factor Arsa UR/ML Nane
.38 1.51 .lOOOOE+flt R01.ll. SB 80111. 453
.48 2.01 .10000F.+II1 17H05S. SB 178058.2811
.63 8.9S .10000E+01. 304961. SB 304961. 440
.74 3.5J .10000F.+IM RJSftfl. SB BJSAO.ISS.as 4.04 .looooe+ot ?M?.f>. SB 86aa6.is61,06 5,05 .100IIOE+fli HBB1 . SB S581.3751.1,3 5.39 ,10000F>01 St33. SB 5.1.33.063l.!?B 6.09 .lfl()flim+(H. !??47. SB P.846,5631,49 7.08 .135t55E-0'i 1951.07, SB .864 ALPHA BHC1,76 8, 38 ,10(lflflF. + 01 S49. SB 248,9691.87 R.88 .lOOOOFI+Ol R9H. SB 291,7813, 09 9,95 .lflOOOE+01 4701, SB 4701.313a. 48 11.81) .IflOOOKflM IOR04, SB 10!?04.4063,4616,44 .iOOOOG+O) 701. SB 700,8134.57 21.73 .10000F.+01. 1898. SB 1897,68135,4735.96 .10765F.-05' 86290, SB ,093 F.NDOSUI..FAN „'6.48 30,49 .IflOOflE+Ol 1.6000. SB 1.6000,501)8,01 38.03 .10000F.+01 5968. SB 5968.12511,27 53,54 .lOOOOF.tOl 6559. SB 6558.50015.48 73,54 .17SOPE-05 H093, SB .004 F.NDOSUI.FAN SULFATH18.85 R9.50 .IflOOOF+OL 3554. SB 3554,251)SI. 06100. 00 .1711BF..-06 17834. SB ,003Total Area - 9663H3. Total UR/ML = 1.7834, 50Processed data fiJei P254P Raw data filei R.54H
,-,.-, 024822
31
G. Work SheetsWorksheets for each type ol fraction are Included, There are extraction worksheet!!,describing which samples are processed in a batch, and listing the associated reagentblank, date, analyst, standards used, and conditions, Analysis worksheets are used at Iheinstrument station to denote condition ol extracts, file names, standards used, dilutions,etc, Compound lists are Ihe wilhln-lab reporting forms used by the analysts to record hitsand perform calculations to determine concentrations of compounds, Data Is transferredfrom compound lists to ERA forms {Organic Analysis Data Sheets). When secondary ioncalculations or other adjustments are necessary, these calculations are performed onseparate pages and Included with the associated worksheets to document Ihecalculation,
024823
I 31
T»i CASEI < DATE DUE>S(.• VOA NORKSHEETV•«*-*
iLOW LEVEL SOLID
• Dellverahles Code 069,
Dry Height Factor H-1)t
' OMAf /? D1skf 1%$m Lot i /c <=? 31
f BFBFIle SPSVo/B/C/PBlank File (f AS^o/5/C/cf
• Injected Sample Volume /O •!SUIT Std t 383 • Lotl/0?v/_nt Std f 002 Lot 1 «rf3(.
ConuChei f / J " SPA -TO?Swple Prep Code 111Instrument Code 238Compound List 96SUIT Std List 383 Int Std List 002
•• .
"-
6C/HS Analyst /.'*AShift /4 Dlt_//3l|iy
Standards File G-SfVOI 2>/c/?
1. 10 Peak Se»rch Required:2. t of Peaks Found3. ERA, sign Chronicles ____ (Initials)Cotments: . '
?-• — f*"-] .JJ" Jl.
Checked by £ufo_____D.tej.i'iMSecondary Analysis Required
Initiator __________Date_
SURROGATE:
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31
CASE * o'3'3. . DUEDATE
_• SEHMOLATILES ' ••. COMPUCHEM. I __ .
• •' WHS H-RKSrlEEl • Sample Prep Code • 12B' " • " ' " ' . . T ' ' "• Inttrment Code .40
v..'.,-CV: ' Compound List 97LOW LEVEL SOLID .. '.'I".:.: Surrogate Std. •.._Deliverable Code « :Q69 . .. ".'.::-'.'.- .•.• ,s- -!: lnttr»1.4»... Utt • -33 il.de'd Fy SC/HS)• • ' ' • - • • • - ' - - - - - ' '
•Original 6C/MS Analysts: " " . Extraction Date of Klal Analyzed_.'-'.rfeflH W ZZfahjA Add. Vol /<?<? ' ul
" ""'_"lnt. St£vol. Mded JT - -ul , \' •'^J!''': ' ''-'•/'
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CASE* AWS DATE \KR?l/93/8/-
TCDD COMPUCHEH IHORKSHEET Sample Prep Code 713
Instrument Code 22?Compound List ,___63
LOH LEVEL SOLID Surrogate Std.Deliverable Code - 069 Internal Std. List "' '
Blank Associatedwith CaseCOWENTS:
»_._________ Dry Height Factor
Analysis, , Instrumentation Code ____________» • "V *\ i..---------*----.- ----.*-*-----..-.--------
Instrument f ^>L'$"2-I________ Analyst ^_J________________________Calibration Std. Lot f f^J-V
Pa.s 1 Pass 2 , Pass 3 Pass 4 ,Date ___ ___ ___ ___ J_Log Reference ___ ___ ___ ___Comments:
Area Count TCDD Surrogate Standard ____________t unitsArea Count Surrogate In Sample,________ units
Recovery
Checked By.______flJf*_)i^~-_ Drte,
024826
31
CASE l D A T E D O Ef ' PESTICIDESMl WORKSHEET
LOW LEVEL SOLIDDeliverable Code - 069
SAS imf{$5D$Blank Associated with Case ____ _COItlENTS:
FlorlsllSample Volume >Reagent SetDate Florlsll CompleteFinal Volume I. H.
Analysis i 3 ExtractsIt ,'rument 1 (f.°[Calibration Sta'ndard Lot i /2_p*yDate l&f/for __$__^_-Log Reference ___ __ __ _
II. ___ ___ _
in. _I_____ H
COMPUCHEM * /^/Sample Prep Code 7 12Instrument Code 115compound List QJIsurrogate Std. 366
' / '
•
Dry Height Factor rt.Q'ISStf
—— — • • "
Sample Prep CodeTechnician
III.
Instrumentation CodeAnalyst S*7?
__ i __ ___ Comments:
t
Checked by
" '
Date
POSTEDFEB 6 m
31
N9 ..1109^ ASSIMB) TO M>~<' ______ PA1E_
C—SupltH
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Cat*"NO.
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Sctw-ult ltofir*nc*_Aaoimt faa'ff 200 JL~ Mwuil CountiT )lt
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If""'"If ASSIBHEOTO _ (tU ^ OA7E__/_£_ti_
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(Tipfi__l_J-_-
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Scrw-ns
TM
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/133d
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Surrogati No..__________ Sch-Ailo Rof«r«no>_Kwiu.l Cauirtcr /MIJVT-
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•4832
COMPOUND LIST NC. ____———— IDENT1F1ER yOLATUES .. Lom..V.L SOLID
COUNTER
2.3.4.5.6.7.8.9.10.11.12.13.
15.16.17.IB.19.21.22.23.24.25.26.27.28.29.30.31.32.34.35.
COMPOUNDNUMBER
22122023120922225220120223025421621422621121525222720625721221725022920322B218208210205256255223
QUANT.REPORT CORRECTION RESULTS DETECTION
COMPOUNDS • VALUE x FACTOR • lug/kg) LlC.:T(ug/kg)
CHLOROMETHANE ............ [_7BROMOMETHANE ............. J]
PMI flonrTUAurHETHYLENE CHLORIDE ....... _/.Qiprinur < *7fiiconi riuirpvi nuiTPll F -^
TRICHLOROFLUOROMETHANE ... 3 _
1,1-DICHLOROETHYLENE ..... ____ _1,1-DKHLOROETHANE ....... ____ _TRANS-1, 2-DICHLOROETHYLENE ____ _CHLOROFORM ...............1,2-D1CHLOROETHANC .......2-BUTANONE ............... 3QQQ1,1,1-TRI CHLOROETHANE .... ____ _CARBON TETRACHLORIDE ..... ___ \ _VINYL ACETATE ............BROMODICHLOROMETHAHE ..... ____ _1,2-DlCHLOROPROPANE ...... ____ ___TRANS-1.3-DICHLOROPROPENE. ____ _TR1CHLOROETHYLENE ........ ____ ___BFu7rur / c**1,1,2-TRICHLOROETHANE .... ____ _CIS-1,3, DICHLOROPROPENE.. ____ __D1BROHOCHLOROMETHANE ..... ____ __CHLOROETHYLVINYL ETHER.... ____ _BROMOFORK ................4-METHYL-2-PENTANONE ..... 7-2. __2_urv.unur ........ HI
1,1,2,2-TETRACHLOROETHANE. ____ _J
J3 ____ W_ ____ 2.5_ ____ 2.8_ ____ 2.5_ 3700 2.5_ 3700 ' 50_ -. _ __ 50
H ; s\ 2.5_ ____ 5_ ____ 2.5_ ____ 2.5_ ____ 2.5_ ____ 2.5_ ____ 2.5_ 57000 100
2.5___ ____ 2.5_ ____ 5__ ____ 2.5__ ____ 2.5_ ____ 2.5
2.5
—— -©- 2'5_ ____ 2.5__ ____ 5_ ____ 2.5__ ____ 2.5_ ___ 2.5_ /tflQO /-50tT^^-t^
••in i-_- is .--
___ 2.5
fUL
wi
PLEASE COMPLETE CORRECTION FACTOR CALCULATIONS ON SECOND SHEET OF THE COMPOUND LIST!! I024833
31
. • - COMPUCHEMNO. ___ DATECOMPOUND LIST NO.____ —————
——~ IDENTIFIER VOLAT1LES ...OK LEVEL SOLID
QUANT.mi COMPOUND REPORT CORRECTION RESULTS DETECTIONCOUNTER NUMBER,, COMPOUNDS_________ VALUE X FACTOR " ("°' LlKlTlue/fco
36. 224 TETRACHLOROETHENE.37.' 225 TOLUENE...........38. 207 CHLOROBENZENE.,...39. 219 ETHYLBENZENE .....40. 251 STYRENE...........41. 239 0-XYLENE..........
QUANT.COMPOUND SURROGATE REPORT AMOUNT »• t \ RECOVERYNUMBER _ COMPOUNDS ______ VALUE SPIKED RECOVERY UINDOV,125B D4-1,2,DICHLOROETHANE (SURR) /j.33. 10.0 AaA._ (50-150)'233 DE-TOLUENE (SURR).......... /g?-Pf .' 10.0 /3.0_ (81-120)24? BROMOFLUOROBENZENE (SURR).. Ag.fff 10.0 JA3_ ( 57-137 )•
•Advisory Limits ' i
T . Recovery « Quant. Report Value .... ' "~
CORRECTION FACTOR CALCULATION: '.nstrument Code 238\Q g ________
Ver Ht. of sample used » Dilution Factor « Dry WQlrt Factor •
,7.1
JRT 11/83024834
COMPUCHEM NO. /(?<Q(0il# DATE ______ 1 of 3COMPOUND LIST NO. ____ ——————
———— IDENTIFIER SEMl-VOLATILES —— LOW LEVEL SOLID
QUANT.- COMPOUND REPORT CORRECTION RESULTS DET. LIMITCOUNTER JUMBER COMPOUNDS_____ VALUE x FACTOR x = (ug/Kg) Jug/kg)
2 441 N-NITROSODIMETHYLAMINE3 610 PHENOL ................4 473 ANILINE ................5 411 BIS(2-CHLOROETHYL)ETHER6 601 2-CHLOROPHENOL .........7 421 1,3-DICHLOROBENZENE ....8 422 1,4-DICHLOROBENZENE ....9 474 BENZYL ALCOHOL .........10 420 1,2-DICHLOROBENZENE.....11 620 2-METHYLPHENOL .........12 412 BIS(2-CHLOROISOPROPYL)ETHER13 622 4-METHYLPHENOL14 442 N-NITROSO-D1-N-PROPYLAMINE15 436 HEXACHLOROETHANE ..........16 440 NITROBENZENE ..............18 438 ISOPHORONE ................19 606 2-N1TROPHENOL .............20 603 2,4-DlMETHYLPHENOL ........21 410 BIS(2-CHLOROETHOXY)METHANE22 625 BENZOIC ACID ..............23 602 2,4-DICHLOROPHENOL ........24 446 1,2,4-TRICHLOROBENZENE25 439 NAPHTHALENE .............26 475 4-CHLOROANILINE .........27 . 434 HEXACHLOROBUTADIENE .....28 608 P-CHLORO-M-CRESOL .......29 477 2-METHYLNAPTHALENE ......30 435 HEXACHLOROCYCLOPENTADIENE31 611 2,4,6-TRICHLOROPHENOL.32 626 2,4,5-TRICHLOROPHENOL34 416 2-CHLORONAPHTHALENE .35 479 3-NITROANILINE ......36 425 DIMETHYLPHTHALATE ...37 402 ACENAPHTHYLENE ......38 428 2,-6-DINITROTOLUENE ..
• • I
• • • I • I
jj __ 10-uT 10
10101010102020102010201010102010201001010105010202010101001010010
20
At'
PLEASE COMPLETE CORRECTION FACTOR CALCULATIONS ON THIRD SHEET OF THE COMPOUND LIST!!!
COMPOUND LIST NO. ___ ————— "————————— IDENTIFIER 5EM1-VOLAT1LES——• LOW LEVEL SOLID
QUANT.COMPOUND REPORT CORRECTION RESULTS DET LIMIT
COUNTER JUMBER COMPOUNDS_____ VALUE x FACTOR x « jug/kg) Jug/kg)
39 476 2-N1TROAN1L1NE40 401 ACENAPHTHENE41 605 2,4-DlNITROPMENOL42 607 4-NITROPHENOL43 476 DIBENZOFURAII44 427 2,4-DINITROTOLUENE45 424 DIETHYLPHTHALATE ..........46 417 4-CHLOROPHENYL PHENYL ETHER.47 432 FLUORENE ...................48 480 4-NITROANILINF. ...................49 604 4,6-DlNlTRO-O-CRESOL .............50 443 DIPHENYLAMINE (N-NITROSO) .......51 430 1,2-DIPHENYLHYDRAZINE (AZOBENZENE)53 414 4-BROMOPHENYL PHENYL ETHER .......54 433 HEXACHLOROBENZENE ................55 609 PENTACHLOROPHENOL ................56 444 PHENANTHRENE .......57 403 ANTHRACENE .........58 426 DI-N-BUTYLPHTHALATE59 431 FLUORANTHENE .......61 445 PYRENE .............62 404 BENZIDINE .................63 415 BUTYLBENZYLPHTHALATE ......64 423 3,3'-DICHLOROBEI!ZIDINE ....65 405 BENZO(A)ANTHRACENE .......66 413 BIS(2-ETHYLHEXYL)PHTHALATE.67 418 CHRYSENE ..................68 429 Dl-N-OCTYLPHTHALATE .......70 407 BENZOIBIFLUORANTHENE ......71 409 BENZO(K)FLUORANTHENE.......72 406 BENZO(A)PYRENE ............73 437 INDENO(1,2,3-C,D)PYRENE ...74 419 DIBENZO(A,H)ANTHRACENE ....75 408 BENZO(_,H,I)PERYLENE ......
*3/0C 100 N10501001020101010100201020101020101010101040102010101010202020202020
>x
(See calculations and' surrogates on back) 02 36
COMPUCHEM NO. lfy(,t/& DATE ______ 3 ofCOMP°UND L1ST N°-———— IDENTIFIER SEM1-VOLATILES - LOV! LEVEL SOLID
C**-":" QUANT. / \REPORTCOMPOUND SURROGATE [l REPORT/ >flM * JJ.. ttCRE.[!5BLENUMBER COMPOUNDS__ ^ VALUER SPlKEft x RECQVbKT HftN._
619 2-FLUOROPHENOL /f_3 /V 185 f612 05-PHENOL ?7 _ _ _ _ _____447 D5-NITROBENZENE l£o A9 125 j44B 2-FLUOROBIPHENYL l3D £& 125 *— —----..„.._.... _ —, . \. ...628 TRIBROMOPHENOL 7?? 125 •471 010-PYRENE /fO ___i£_ 125 t496 Dj4-TERPHENYL ..
tl /»)/D (26-116)J_g_£/b( 10-104)
,(19-115)(17-125)(32-124)
H( NA )i(34-126)'
«
Recovery • Quant. Report Valueguani. Keport Amount spued x 10°*
CORRECTION FACTOR CALCULATION;
DryFinal extraction volumelm!) 50 g c_!l_J10nx Facff1ml for Add. 0.5ml tor BN » Met Height Extracted ig> » Factor x Factor
BO
QUANT. REPORT AMOUNT SPIKED CONVERSION FACTOR;
250 .1______ Final Extract Vol. (ril) Dilution'Amount Surrogate Added l u l l * TmV for Acid, O.snil tor BN * Factor •
250 ui_____ : T v;. *""' « /—————-^————[uTT x T70"and.O.WI A / • | /
*For Advisory Purposes Only npdfi^7
JRT 11/8311 •'''•' • ' ,.'
31
TCDD 069 DXACJNP»TX_S.
___ FXUBNAM- TC.J.9264C.5™™H|
Dxr.Norrxc VAUUK PA.B/FAXL,
320/322 PtATXO1.SUHBDOATI; (e. 6fl - 0. 94) ft B5
AN/M.VT* (_. A7 - 8. B7) 0. 80
ANALVTR KLUT_» HXTHXN 3 SCANSOF XNTEBrMrtU. BTrtND/MIP:
SuPtrtQDATI •KFARATK. AT -.-AST 5SCAN* FROM ANAL.VTE'
024833
r 31
TCDD LOM LEVEL SOLID
FILENAME-. TC019264C0S CQMPUCHEM No. _____„.„(__ DATE 0S/10/B4«*%»LE! 3/50 UL CC*19264(EPA*R35031~H6) OHA #5
EPA SAMPLE: _&;._-_)_l__i . CA*E NUMBER! ___
COMPOUND COMPOUND QUANT REPORT * CORRKCTXON « RKKUUT DETECTION LIMITNo. VALUE FACTOR (UO/HO) '' IUO/HO)
469 S378-TCDD 3. 70 0, 0160 BDL _. - 8. 513 (-.319)
SurtROGATE (Ij 2< 3)4*TC-H-J RECOVERV = (AMT MEAP4WED / AMT BfXKED) * 100X
RBCOVKRV • 6S. 3%
CORRECTXDN FACTOR!• (EXTRACT vot. (ML.) / C, 1 ML.) * (50 o / AMT EXTRACTED) * 0, flOB
FACTOR * 0. 0160
NOTE'. TH*. 0. 319 D_T*CT.__TJ LXMXT x» THE OPTIMAL. (100X -•COVERv) DETECTION LIMIT,THE 0, 513 DETEr.TnJfJ LIMIT XS THE RECOVERV-CORRKCTEDr ANALV»I»-BPECIFIC
DKTECTXPN-t-SKST. '
f 31
CQMPUCHEM NO.___ DATE
IDENTIFIER PESTICIDES (LOH LEVEL-SOLID)
COMPOUND LIST HO.
COUNTER1.2.3.4.S.6.7.8.9.10.11.12.13.14.15 116.17.IB.19.20.21.22.23.24.25.
COMPOUNDNUMBER
COMPUCHEMCOMPOUNDNUMBER0701070207030704070507060707070807090710071107120713071407150716071707180719072007210722072307240725
SURROGATECOMPOUNDS
COMPOUND NAME RESULT DETECTION LIMIT (ug/kg)ii noiw -.--._..._.._...._. _ n 5il DUA OUP 1 fl
DPTft DUP A n
GAMM&_.nur _.._._. ...-,-.--._ i nDELTA-BHC —— ............ 4.0 'CHLORDANE —..—.—.... 4.04,4 '.DOT —— .— - ——— 4.04, 4'- DDE -—..— ....... 4.04,4 '-ODD ......... ..—— 4.0ntFi nDTU ...... ..- ......... A nALPHA-ENDOSULFAN —— — - 4.0BETA-ENDOSULFAN — — -— - 4.0ENDOSULFAN SULFATE — -— A 4.0runDTU „__„„__„___.___ ' in/ll / 4 nENDRIN ALDEHYDE -«.—.— 4.0UTDT10UI flP . ...__... A (\
HEPTACHLOR EPOXIDE — —• • 4.0f_MQ 4 All A ' J A
Df*D 14Cj| J l\
PCB-1221 •»-——.—.— 4,0PPR.197? ...............i... i nDPR IWfl . .-.-....-i A H
PPR.I-ttn .M.....--.-I---I-.J. A 0
PCB-1016 ———————— 4.0 \TOXAPHENE —— - —— - —— - 4.0
<a/• .
QUANT.(RECOVERY REPORT CORRECTION AMOUNT tWINDOW VALUE FACTOR RESULT SPIKED RECOV
0738 DIBUTYL CHLORENDATE (41-121)* ___ ___ _______ SlT- -31
'Advisory Limit
r
•. * •• V V . . A ••.». * ' _
KCOHDMY ION CALCUUTIOM
A l> *K •
lUiponti Factor •
Aoount of Canpount•
*
CD WOUND
, n '
»•
«
•
ION
SI '
-
•
• . Calculate, ly r 633
Ana | Act.Coflip 1 .1.Aril » Ant.I.S. * I.S.
Arai « tat.i • Coirrpd. l.S.
1 Aral . I.Fft A
RtiPDKiL F At TOR
jSft-'il--.
••" ...
•
Vhcrt all ariit and amountt ire•btatn.d-frea Wn itindirdanilyili.
Hncrt all artu and amounts artftbtilMd front the unplaanil/ili.
CO^OUND AM3UNT
'"jj}' •
•
•
**~~*
• '31
-I; LAUOKA'ICII.'Y
EXTRACTION -NKORrtATION.
Wt. or vol. of sanole 'skV \
porrion of wt. or YD! in pest/herb ___ f
dry wt. correction factor /rf\
final Yolune of extract 5"* "is
dilution factors / for run * tf5"t?~_for run »____,__,J'or.run *___for run #___
ANALYSTS COMMENTS.
&fc 1 2
004942
31