i70 - united states agency for international developmentto ascertan, but tgl.eetad, 1, l,....

72
AGENCY FOR INTERNATIONAL DEVELOPMENT FOR AID USE ONLY WASHINGTON, D. C. 20523 BIBLIOGRAPHIC INPUT SHEET A. PRIMARY I. SUBJECT Agriculture CLASSI- FICATION B. SECONDARY Soils and Fertilizer 2. TITLE AND SUBTITLE Improved Fertilizers for Developing Countries J. AUTHOR(S) National Fertilizer Development Center, TVA 4. DOCUMENT DATE 5s. NUM BER OF PAG ES 6. ARC NUMISER 1974 I70 P. ARC 7. REFERENCE ORGANIZATION NAME AND ADDRESS Tennessee Valley Authority National Ferti.lizer Development Center Muscle Shoals, Alabama 35660 6. SUPPLEMENTARY NOTES (Sponsoring Oranlzatlon, Pubflaherse Avaltablllty) 9. ABSTRACT This report is a project report covering the period from December 1972 (when the bulletin "Tailoring of Fertilizer for Rice" was issued) through June 1974. The present project is our expansion of the previous project, which was restricted to the use of fertilizer for rice, in that new and improved fertilizers are to be tested on a number of tropical crops. In addition to actual. agronomic evaluations of new materials, increased emphasis is placed on developing and demonstrating methods of introducing new fertilizers to farmers so that they will be properly used or they become commercially available. Additional data has been received from a number of countries pertaining to the use of SCU for rice. In general, these data tend to substantiate those previously reported in that SCU is a superior source of N for rice grainiunder conditions of intermittent flooding, but that it is no better than conventional sources of N when conditions of intermittent flooding or severe leaching do not exist. A discussion of the commercial potential of SCU in tropical agriculture follows this section. Insufficient data are available for tropical crops other than rice to warrant any general conclusions at this time. 0, CONTRCL NUMMER i. PR(ICE OF DOcUMENT ?N-Mn1 - /,0 F lIDij, OICHIPTOII s" (' lJ1(1 IJNPf , 12. 94CHPTOFS 1, PV'OJI-(Cl NUJM Fr" Rice, Sugarcane, Corn, Cnanva, Cotton, Bananan, 931-11-190-832 ,.(ON,,nA( NUMnrR Cocoa, Tropical Crops, SCU, Rock Phosphate, Micronutrlent4 rIN;A-NUTA0- RSS;A-No .TVA.-OI-74 it. TYPr Of t)O(AJMINI _ _ _ Renearch Re.port Alt) 11)0.I I..?aI

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Page 1: I70 - United States Agency for International Developmentto ascertan, but tgl.eetad, 1, L,. ("Tailoring of Pertiltiters for ice,'" TVA ulletin Y-52) states that the staft of IOi has

AGENCY FOR INTERNATIONAL DEVELOPMENT FOR AID USE ONLY WASHINGTON D C 20523

BIBLIOGRAPHIC INPUT SHEET A PRIMARY

I SUBJECT Agriculture CLASSI-FICATION B SECONDARY

Soils and Fertilizer 2 TITLE AND SUBTITLE

Improved Fertilizers for Developing Countries

J AUTHOR(S)

National Fertilizer Development Center TVA

4 DOCUMENT DATE 5sNUM BER OF PAG ES 6 ARC NUMISER

1974 I70 P ARC 7 REFERENCE ORGANIZATION NAME AND ADDRESS

Tennessee Valley Authority National Fertilizer Development Center Muscle Shoals Alabama 35660 6 SUPPLEMENTARY NOTES (Sponsoring Oranlzatlon Pubflaherse Avaltablllty)

9 ABSTRACT

This report is a project report covering the period from December 1972 (when the bulletin Tailoring of Fertilizer for Rice was issued) through June 1974 The present project is our expansion of the previous project which was restricted to the use of fertilizer for rice in that new and improved fertilizers are to be tested on a number of tropical crops In addition to actual agronomic evaluations of new materials increased emphasis is placed on developing and demonstrating methods of introducing new fertilizers to farmers so that they will be properly used or they become commercially available

Additional data has been received from a number of countries pertaining to the use of SCU for rice In general these data tend to substantiate those previously reported in that SCU is a superior source of N for rice grainiunder conditions of intermittent flooding but that it is no better than conventional sources of N when conditions of intermittent flooding or severe leaching do not exist A discussion of the commercial potential of SCU in tropical agriculture follows this section

Insufficient data are available for tropical crops other than rice to warrant any general conclusions at this time

0 CONTRCL NUMMER i PR(ICE OF DOcUMENT

N-Mn1 - 0 F lIDij OICHIPTOII s ( lJ1(1 IJNPf

12 94CHPTOFS 1 PVOJI-(Cl NUJM Fr

Rice Sugarcane Corn Cnanva Cotton Bananan 931-11-190-832 (ONnA( NUMnrR

Cocoa Tropical Crops SCU Rock Phosphate Micronutrlent4 rINA-NUTA0shyRSSA-No TVA-OI-74

it TYPr Of t)O(AJMINI

_ _ _ Renearch ReportAlt) 11)0I IaI

Progress Report of TVA-AID Project

TVA-02-74

Improved Fertilizers for Developing Countries

Agronomic Research

July 1 1974

International Fertilizer Development Staff

Tennessee Valley Authority

Huecle Shoala A14bam4

TABLE OFCONTENTS

Summary 1

Potential for Use of Sulfur-Coated Urea 3

Background and Objectives of Project

Scope of Work o bull 99

Project Plans for Fiscal 1975 bull 11

Engineering andDevelopment bull bull 0bull11

Agronomic Testing and Evaluation bull bull bull 14

Economic Evaluations

Workshop at Muscle Shoals a o bull bull bull 19

bull bull o bull bull bull 18

Literature Survey bull bull 19

Agronomic Research bull bull 21

Research by Overseas Cooperators bull 21

Greenhouse Research by TVA at Mlcle Shoals 51

57 Appendix

58Performance of Sulfur-Coated Urea for Rice In Peru

Response of Flooded Rice to Phosphtate Rocki 0 63

SUMMARY

This report is a project report covering the period from

December 1972 (when the bulletin Tailoring of Fertilizers for Rice

was issued) through June 1974 The present project is our expansion

of the previous project which was restricted to the use of fertilizer

for rice in that new and improved fertilizers are to be tested on a

number of tropical crops In addition to actual agronomic evaluations

of new materials increased emphasis will be placed on developing and

demonstrating methods of introducing new fertilizers to farmers so that

they will be properly used or they become commercially available

Testing of sulfur-coated urea (SCU) will be expanded to

include a number of additional crops such as sugar cane corn cassava

cottonbananas and cocoa Additional experiements vill be conducted

with rice to more precisely define the areas and conditions where the

use of SCU will be advantageous and to introduce its use to agricultural

workers and Industry representatives

Additional studies are planned vith rock phosphate to evaluate

its o(fectiveasee for direct applications and to study mans of increasing

its phosphorous availability by relatively tople muthoda for local

gomo aitionalV06 will be cOndvct44 with xronutolt4 msatvres of vorious

aterltele With rock p Wephut

smtprfallairy wVr to Ceonepl44 001teitn w4ltr g fut

of W41114090~f vowmllo It to felt thut ~ Ot 0~t ea I fo

0 setvl to 011folf OW 10offft 4 Aiee441bj ftiIOt

hepll4t 0 14W l0a khef t~ l to1141l(0

-2-

The need for fertilizers containing secondary andor microshy

nutrients will be evaluated in several countries where deficiencies

are known or suspected but where no commercial sources of these nutrients

are presently available

Additional data has been received from a number of countries

pertaining to the use of SCU for rice In general these data tend to

substantiate those previously reported in that SCU is a superior source

of N for rice grain under conditions of intermittent flooding but that

it is no better than conventional sources of N when conditions of intershy

mittent flooding or severe leaching do not exist A discussion of the

commercial potential of SCU in tropical agriculture follows this section

Insufficient data are available for tropical crops other than

rice to warrant any general conclusions at this time

-3-

POTENTIAL FOR USE OF SULFUR-COATED UREA

The major portion of the agronomic research reported herein

deals with the evaluation of SCU (sulfur-coated urea) as a source of

nitrogen for rice These results generally confirm those previously

reported by TVA (Tailoring of Fertilizers for Rice TVA Bulletin Y-52

December 1972) in that SCU is a superior source of nitrogen for rice

grown under conditions where flooding is delayed or intermittent

However the results of some experiments from India and West

Africa where rice was grown under conditions where only leaching and not

both leaching and dentrification would be expected to occur suggest that

SCU may be a superior source of N for rice grown under these conditions

as well In certain parts of the world large areas of floating or

deeply submerged rice are grown very little information relative to N

response i available but in general yields are comparatively low

Further research is planned to 4valuate SCU for rice grown under those

conditions

The exact areamp of rice grown in developing countries under

conditions where both leaching and donitrification can occur is diffitcult

to ascertan but tgleetad 1 L (Tailoring of Pertiltiters for ice

TVA ulletin Y-52) states that the staft of IOi has ea|aited that uvor

7I of the rice in outheat Asia So Arown under this type ofter meASe

sent Prelisneary bfbervetio eu est Oat at t l PsIblySoea (a4

ofe) of tw frie to Vat Atfica to gmrae 4nder delayd of totriltest

irwiM4 to FAD report MD00llIO owtoifar f rce rt Imvi

W1110010 teveW ftJ 4 We 04001406w 1 141410tIf 0 ferl4iiio 10

-4shy

applied at a rate of 60 kg Nha then approximately 2600000 mt of

N could profitably be used as SCU In 1972 33700000 mt of N was

used in the world and these figures suggest that as much as 8 of the

world consumption could potentially be expected to be applied as SCU

on rice

On a smaller scale approximately 114000 ha of rice are grown

in Peru nearly all of which is grown under conditions where SCU would

be the most desirable source of N Average rice yields in Peru are about

4000 kgha but research by Sanchez and coworkers (see attached report)

indicates that with ample N yields of 9000 kgha can be attained To

obtain these yields 25500 at of N as SCU would be needed compared to

42000 at of N as straight ure to obtain the same yield Thus SCU

would save 16500 tons of N or roughly 40 of the N needs

Results from India indicated that when equal amounts of N were

applied an average of about 1000 kgha more grain was produced on exshy

porLsentail plots This average figure included some areas where SCU was

not superior to AS In 1972 36500000 ha of rice were grown in India

with an average yield of 1616 kgha Proper use of SCU in place of

conventional form probably would not Increase yields an average of 1000

kghe under fam conditions as it would on the research plots but an

average of 500 k8 would be raoom ble This would rotult to an Increaa

of a50000 m of rice an Incras of 311 over the 197 production of

$90o000000 mt

The 40 04Melee Ore cited t dMWMaftampt tbe iAnCicoo in

ftc prodwilu peble Ihrow~h proer t o of 60 a wvrf of 0 for

fiff MWere- f04ieb di at Peded t1 1if1 pfJiiea1y 4i fie toshy

ditlsw winde Iee idveitu f~ rics a to JMe(0wiaihthe of 1CM La f

-5shy

precisely evaluate the economics of its use

Preliminary data indicated that SCU may be a superior source

of N for other tropical crops particularly long-season crops such as

sugar cane and pineapply grown in areas of high rainfall

The results of the wheat experiment followed by sorghum in

Pakistan in which the residual effects of SCU were evaluated suggest

that in intercropping and multiple cropping systems fertilizer nitroshy

gen may be applied in a slow-release form (SCU) at a convenient time in

the cropping system so that the nutrient elements will be released for

utilization by succeeding crops

Information already obtained indicate that SCU is a superior

source of N for crops grown on large enough areas to economically justify

its commercial production As more data are obtained with more crops

and from new areal the potential for its use will undoubtedly increase

Consequently as adequate supplies become available programs need to be

initiated in selected areas to introduce the use of SCU to agricultural

extension workers to the fertilizer industry end to farmers and to

encourage its coinercial production Since the cost per unit of N will

always be higher in SCU than in regular urea the use of SCU will be

econmically practical only under specific conditions and these restricshy

tions as to its use make it perative that effective education and

inforuation progra- be conducted prior to the comerctel Introduction

Of SU On 4 Wid eeie

-6-

BACKGROUND AND OBJECTIVES OF PROJECT

The present project is designed to capitalize on the momentum

and knowledge gained in the previous project Tailoring of Fertilizers

for Rice This project demonstrated that a superior nitrogen fertilshy

izer can be developed for tropical areas and that some relatively low

cost phosphate sources can be effectively utilized The present project

seeks to broaden the base for development of improved fertilizers through

a wider range of agronomic economic and engineering evaluations Preshy

viously the emphasis was placed on SCU as a nitrogen source and the dirshy

ect application of a limited number of selected phosphate rocks as phosshy

phorus sources for rice fertilization In this project a wider range of

fertilizer materials will be tested on a variety of upland crops such as

maize wheat sorghum and sugar cane cassava and others of national imshy

portance in various countries

Through its domestic fertilizer research and development proshy

gram TVA produces experimental fertilizer materials that may have poshy

tential for tropical soil conditions and crops With support from AID

in this project the capability viii exist to work toward improving fershy

tilitors for developing countrive through the necessary and logical soshy

quenco of production to ramer aceptonce to sess the potential for

co mrcial production

Pertilliers now being used in 4eveloping countriee relAtive

OeCOtcs And shortcoMiNge of the Mterials viii be Ovai6Isd Ktshy

true thel ena 4 4 0(fiashyporimrtAl product wlornriee pilot plt

ties OaI1 pl0t4 Will be W0bsutd to fcresMq tet in jre

tof f~wrisea with caomvstmwl siatofials rr f P0041610 161i

-7shy

screening will be done using soils of the area where the fertilizer

will be used Materials showing potential in greenhouse tests will

be further evaluated in actual field programs in selected countries

If successful at this stage economic and engineering data will be

compiled to assess the potential for commercial production In orshy

der to evaluate the product and process the total system will be

studied including storage handling and transportation from the

point of production to the farm Information developed throughout

this work will be available to industry foreign and domestic so

that it can develop a production marketing and use base for utishy

lizing the product This level of technology is rapidly being achieved

for SCU which received major emphasis in the previous study additional

agronomic economic and engineering data both with rice and with other

crops will be obtained to complement the previous findings

This project must be broad and combine a variety of professhy

sional disciplines but it is necessary to retain the flexibility to

move forward in specific directions as Improvements in products occur

This is necessary to insure that improved products identified in this

project can ultimately be made available to farmers zegrdless of their

economic and social status and that sufficient data aro available so

that induetry can make soomd decisions regarding the foasibility for omshy

marcial production

Major objectives of this project are eommartted as tollovws

(1) Developing Iertilaers to wt the nutrient neD of oocitic

4I l VhICh are not set iconmically withtfopical Crops and

etoshytoov~tmtl| Nrtiliieoro or that can set thse ne- s fre

006eItCOMlY ky 4ir lfte the W91~1ici of teftlliaer ultil4tin

-8

(2) Proving the value of these improved materials to insure that

they will increase farmers income over a large enough area

to attract and Justify commercial production

(3) Developing the production technology for new fertilizers as

a basis for encouraging and advising potential commercial proshy

duction The integrated process designs will seek product

quality and economy while striving to minimize harmful emisshy

sions to air water and land

(4) Working through cooperating organizations and with leaders in

research extension and industry to develop and demonstrate

methods for introducing new fertilizers to farmers so that they

will be properly used when they become commercially available

-9-

SCOPE OF WORK

This project integrates agronomic economic and engineering

expertise into a single team in order to develop improved fertilizers

for a wide range of crops and soils in developing countries Considershy

able emphasis is given during the first eighteen months to collecting

the data needed to complete the evaluation of sulfur-coated urea and

ground rock phosphate for lowland rice Both materials then are

scheduled for demonstrations during the latter part of the project in

order to educate extension workers and farmers and to attract the fershy

tilizer industry into commercial production Considerable emphasis is

given to the economic evaluation of a total production-marketing-use

system for each material in contrast to alternative nutrient sources

The probability of commercial production of SCU and ground

rock phosphate can be enhanced by expanding their use to additional

crops and soils Thus the project is expanded in scope as compared

to the previous project on tailoring of fertilizers for rice in order

to test these materials on additional crops

The expanded work includes a major effort in screening and

testing new compounds and forms of fertilizers for various food crops

produced under tropical conditions Alt hough it if already known that

more effective andor lens expensive formn of nitrogen and phosphorus

are needed a literature survey will nerve an Lan additional guide to

important and presing fertilizer problems

-10-

Much of the work with fertilizers for both lowland rice and

upland crops will consist of field tests in Southeast Asia Africa and

Latin America Greenhouse and engineering studies will back up the field

research All field experiments are designed to provide at least an esshy

timate of costs and returns for each fertilizer tested

PROJECT PLANS FORFISCAL 1975

In this section the work for fiscal 1975 will be discussed

It should be remembered that the success of this project depends in a

large part upon maintaining sufficient flexibility so that work in inshy

dividual countries can be adapted to supplement and complement programs

already under way While guidelines and plans of work must be developed

so that the objectives of the project are clearly defined detailed

plans for specific countries or groups of countries must be developed

by consultation wth local cooperators

These plans will be discussed under the following three general

phases of the project

I Engineering and development

2 Agronomic testing and evaluation

3 Economic evaluations

Engineering and Development

Phosphate Rock

Methods have been proposed for relatively simple treatment of

phosphate rock (PR) to increase the availability of the phosphate to make

it more suitable for direct application to the soil These treatments

may be economically feasible in certain areas especially in view of the

current world fertilizer situation Considerable work has been done at

TVA studying means of altering PR and plans are being developed to inishy

tiate further developmental work and field testing of these materials durshy

ing fiscal 1975

- 12 -

Emphasis will be placed upon obtaining samples of phosphate

rock from deposits in developing countries and testing and improving

procedures for increasing their citrate solubility and tzius availabilshy

ity of the phosphorus From this laboratory screening process sevural

sources will be selected from which small amounts (50 to 100 pounds)

will be prepared for greenhouse and field experiments ou various soils

(as described under agronomic section)

From these results one or two locations (or countries) will

be selected for development of a pilot program to utilize local sources

of phosphate rock This program will involve production of the altered

PR and its agronomic evaluation and then educational programs with govshy

ernment and commercial representatives to introduce its use to the farmers

Sulfur-Coated Fertilizers

Some preliminary work has been done in which urea-potash mixshy

tures were coated with sulfur The 7-day release rates for the N and

K20 were 17 and 36 respectively from the coated product (22-0-11-30S

grade) This was the first effort in coating a compound fertilizer

with the new coating system

The widely differing release rates for the nutrients from

the coated compound product raise some interesting prospects for tailshy

oring the nutrient release rate of sulfur-coated products It might

be possible to cogranulate materials of varying water solubility and

sulfur-coat them to produce products with release rates that would apshy

proximate the timing of nutrient requirements of the crop The need

for this type of controlled-release product has been mentioned many

times by agronomists and may be especially applicable in multiple and

intercropping systems

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gr~a 1971

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- 24 shy

India--The results of four experiments conducted with flooded

transplanted rice in India by the All-India Coordinated Rice Project

Hyderabad are given in table 3 The response to N was excellent the

yield without N being only 41 of those obtained with basal applications

of N as uza With basal applications of SCU the yields were 20 higher

than with basal applications of urea and in the three experiments in

which urea applications were split yields with SCU were 18 higher than

yields with split applications of urea When comparing the average Nshy

response (kamp grainKg N) yields were increased 13 more by SCU than by

basal applications of urea

The data from one experiment with light irrigated rice in India

are given in table 4 yields were relatively low and differences between

N sources or method of application were not significant However yields

with SU tended to be higher than when all urea was applied at planting

but lower than when split applications of urea were applied Again yields

increased more than 13 more with SCU than with basal applications ofwere

ur

In tables 5 and 6 the yields of a short-duration transplanted

rice grown in irrigated light-textured soils at five locations in India

indicate that higher yields were obtained with SCU than with urea when apshy

plied as a basal application Yield increases due to basal N applications

were 502 greater with SCU than with urea However split applications of

resulted in yields equal to those obtained with basal applications ofurea

CU

The yields of direct-seeded upland rice grown at three locations

to India are given in table 7 and the relative yields in table 8 Yields

were low due to drought but good responses were nevertheless obtained for

- 25 -

Table 3

Effect of N Source and Time of Application on Yield of Paddy (Flooded) Rice in India 1972 (Summary of Reported Data from 4 Experiments)

Experimental Number Source Rate Method Yield Relative N-Response

and of of N of Yield Kg Grain

Season Nitrogen kgha Application mtha Kg N

- - - 196 34 -

Urea 120 Basal 573 100 314

11 Urea 120 80 + 40 611 107 345 Rabi SCU 120 Basal 713 124 430

12 - 0 - 202 30 -

Urea 125 Basal 682 100 384

Rabi Urea 125 35 + 20 + 35 + 35 633 95 344 SCU 125 Basal 781 115 463

13- 0 - 168 44

Urea 100 Basal 385 100 217

Kharif Urea 100 30 + 20 + 25 + 25 400 104 232 SCU 100 Basal 462 120 293

14 -

Urea -

125 -

Basal 355 650

55 100

-

236

Rabi SCU 125 Basal 781 120 341

-- 26 -

Table 4

Effect of N Source and Time of Application on Yield of Light Irrigated Rice in India 1972 (Summary of Reported Data From

One Experiment at Pattambi)

Experimental Number Source Rate Method Yield Relative N-Response

and of of N of Yield Kg Grain Season Nitrogen (kgha) Application (mtha) Q) Kg N

38 0 - 204 85 -Rabi Urea 120 Basal 241 100 308

Urea 120 60 + 0 + 30 + 30 267 ill 525 SCU 120 Basal 255 106 425

Table 5

Effect of N Source and Time of Application on Yields of Short-Duration Transplanted lice Variety Grown on Irrigated Light-Textured Soils at 5 Locations in India 1972

(Snmzarized From Reported Data)

Rate Grain Yields (MtHa) Source of N Method of N GrainI of N kgh Application Faizabod Karjat Mandva Pattabi laya Averaje X

- 291 266 211 19 340 260 -

Urea 100 Basal 386 407 361 285 482 3 124 Urea 100 50 + 25 + 25 399 430 434 334 6amp2 4A8 186

SCU 100 Basal 368 468 439 360 572 41 181

Table 6

Effect of I Source end Tlae of ApplIcattoo c RIstave Tle24 of a rt- rat1 T Lsd lice Vasrety Crin o Irrigated L41tshy1 at S Locitite mindi 1972

Rate ____________14_3

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of o tee t ~pe10iAEkm~t 1 w4C4400e

twoo TttWimI fl04it M 4 ~t w tamp A 11P o We

-40 tad 11fdIAW000 0tw A004s~lI7KVw totI Pt to))

t 164 044pi 44~4 WO 040Oipi0 ~om b~e1

rewIott- MN1 tVfI OOwK o l

Stt19 Of 0 SeOO M IbAWO AffikampI 00 Vt414 Ot VPtd 44 tM~wuOWe tni144 Ite W 1iw)ts 060

211 U e 1dit f

w 0 31 ~ 19 AA 116 1 AS Ma )4 ) At

wx451146

ISO 00) OM4 0101 9I

T60te

owel4440 00VII O A ofWM PwmeeA st rof (Amrol IMVf

Mt ot U 6q-wto~ COW i 4t~ eso

Tel of ate (01m itl it Iiuma tWuJt)

21L1L LW ufU~ vie 114 3 10 106

As 11 i 41 4 smg LAY1 $Of 41)

Tabl I

f~ttwi Ot 0 6wirce 81d At$ a vt1d at flUop4d Rico to Vitjorim (1ITA)All fortitfour to rsodkeet OA lC~OVPr4( 114 5iI 000

W Iotors Ftslanp tospg Irritd for Two thvk Afler flontiw wft rkwa~ Floo4d 191)

- -I-of LWAIM) (IS YJl- fl-----II)

-0 10)

AA MO 4 S4

4of O 149 6MID O 41110

KthD 00

- 38 -

Table 18

Yild of aemati-370 Rice at Punjab Agricultural Research

Institute in Pakistan in 1969-70 Grown Under

Couditions of Intermittent Flooding

Pate of application

=IL

o 0 67 67 100 100 67 67

100 100 67 67 200 100

Average for Sources

Ntha

AS 260 gres 279

320

Source f5

-

AS AS Ura Urea SCU SCU

Yield

Relative

93 100 115

(M)O

Yield

Increase Yield Due to N

(Ktlha) (mtha)

-212 245 033 274 062 260 048 297 085 315 103 325 112

Yield Increase

Relative

72048 067 100 108 161

(2)

- 39 shy

Short-statured high yielding rice varieties grown extenshy

sively in northern Peru require extremely high rates of conventional

N sources to achieve maximum yields The recovery of applied N is

extremely low due to the use of intermittent flooding This water

management system results in heavy N losses even with properly timed

split applications In search of simpler and more effective methods

of N management eight field experiments were conducted in the region

to evaluate sulfur-coated urea (SCU) an experimental slow-release N

source supplied by the Tennessee Valley Authority Rice yields were

increased an average of 59 more by pretransplant-incorporated SCU than

by urea or ammonium sulfate applied in the same manner SCU produced

excessive vegetative growth which resulted in yield reductions at high

N rates

Regardless of an assumed 48-higher unit N cost in SCU the

overall benefits of pretransplant-incorporated applications of SCU

were favorable since there was a decrease of 40 in the optimum rate

of N and the need for precise timing of application was eliminated

Pakistan--In Pakistan basal applications of AS urea and

SCU to rice grown under conditions of intermittent flooding in 1969-70

(table 18) indicate that SCU is a superior source of N as compared to

urea or AS when all N is applied at or before planting The data also

indicate that a yield response was obtained for P applications but a

comparison of N sources at each level of P indicates that no interaction

between N and P was present so that differences between N sources were

relatively the same at each level of P Yields were increased about 60

more when SCU was applied than when urea was applied Yield increases

with AS were only about 72 of the increase obtained with urea these reshy

sults do not agree with the generally-reported superiority of AS as comshy

pared to urea as a source of N for rice

- 40 -

In 1973 experiments were conducted in Pakistan using both

Basmati-370 and IRRI-6 varieties of rice grown under conditions of

When all N was applied at puddlingintermittent flooding (table 19)

or 12 at puddling and 12 at panicle initiation both AS and SCU were

superior to urea with SCU tending to be the most efficient source

However when N was applied 12 at transplanting and 12 at panicle

initiation SCU was the poorest source of N This would indicate that

the release of N from SCU applied at these times is too slow for optimwn

plant growth

In another experiment in Pakistan in 1973 no differences

in the effectiveness of urea AS or SCU were noted in the yields of

continuously-flooded rice (table 20) Again these results are conshy

sistent with earlier results which indicate no superiority for SCU

when rice is continuously flooded

Nitrogen Studies--Maize

A series of three experiments were conducted by IITA in

armo-Nigeria in 1972-73 comparing AS urea SCU and

CAN (calcium

nium nitrate) as sources of N for maize (table 21) A significant

yield response was obtained for N at each location but no conaistent

differences were noted amaong sources These results are consistent

with results at other locations which have not shown that SCU is a

superior source of N for maize grown over a period of 3 to 4 months

Nitrogen--Wheat

The yields of wheat in Pakistan in 1969-70 (tables 22 and

23) show that yields with SCU) tended to be lower than those with ureaJ

although at one locction where sorghum was grown followilng wheat with

Table 19

Yields of Basmati-370 and IRRI-6 Rice at Punjab Agricultural Experiment Station in Pakistan in 1973 Under

Conditions of Intermittent Flooding

Rate Yield Source of N Time of Yield (Mtha) Increase of N B-370 IRRI-6 Application Basmati-370 IRRI-6 Average (Mtha)

0 0 - 21 353 287 -

SCU 90 150 At Puddling 325 545 435 148

Urea 90 150 At Puddling 309 500 405 118

AS 90 150 At Puddling 324 529 427 140

SCU 90 150 Puddling 372 572 472 185 Panicle Initiation

Urea 90 150 Puddling 335 502 419 132 Panicle Initiation

AS 90 150 Puddling 353 529 441 154 Panicle Initiation

SCU 90 150 After Transplanting 312 562 437 150 Panicle Initiation

Urea 90 150 After Transplanting 340 624 482 195 Panicle Initiation

AS 90 150 After Transplanting 349 583 466 179 Panicle Initiation

All plots received 45 lbs P205acre as single superphosphate

Relative Yield Increase ()

Source of N At Puddling Puddling Panicle Transplant h Panicle

Urea 100 100 100 AS 119 117 92 SCU 125 140 77

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-48

Therean laiictw that It lbs P to th e am lukis

obosomhu rocks 0entk catetas rth Unrtdo costrat frwt) to

ht tse balt s Owosiv as that to TwP it rocks WM bo

fmtbt alteruutiv to MSso gotastte to~ Ik lee used to

ThUAIAd

Tht wMl dt gotmtmlaoti wout th possibility

of law Vhld free ww e1 e66001 4 It cooUt be YgWd Sutt

a4 10 0410 SWUSSM yt$4e TOP wUd predWr A r~ftIf fl~W t

1f f ot P the wuld phosphae rck TWOe viWMW efocitill b

true to low rttos t tsplusatiI P wi 9 Ma Liiam $S

amp4at r per Wforssota Mav two 64eed Wilk elikor It 44 of

P go Mi er 4A bg oftoP aon of tewmrowtni pboophals fwAh

It vwld be polotrd A Wevero wtht Is the jteld level that

W414 gk tko videm dtterem~j o(A 1 the 4~etamp tk~e~t

P11~0 pra~lpj prefer gre4r tuftlter for whlae

of hoaw ppltrstie Mhe to a dloedveaP for The PINSOO rocka

vkth m r II spotted 10 ftewil 4106Me tem

Nub studios we ovsosd o IVA vol gramleid a

forgof wee aMW pbsepbots A fths pemhawe evsielew us

Odellod to detMlee it otteettvmm of 11agotated Stoture of

mmfp MW phapa A (CI) sed graewletod pampAtlti arlolatod Pa

asowcs of P tof ttde ro The wreem proucts omre raGther

pemour~a ot P syag besmti andMi as elt ov so gpamwhr

iuipiqffhate(TS) low twseeo Is eftwiltve Is thet

W41 preeme wae oialain ire post-rItoi effriq to Stanlato the

pud6itt of Irto paddle Wee ofsdlseireplastiq

0 49 shy

lbs partially scldiaatede grawilated Ml prodlucts Vere isshy

toiwdiats in 5tftOvttWS54 betwee wroiPi ad TVP NotV5Ymf to

me coo were they mere twoe $a a etfective ao TIP 00 sipifleast

LVSUMI5 at0 efecto wore toun tor thee produteo Timely dtIampWde

FR (-t00 mmoh) Uia amp~rally oar affective than Owe gra8448r FOampprodt

featal twos o 6 aotetire s I

Nowvero it to felt that sfortber field euprtet vth

hese interials Amd ether typs of grometatodl Wter nre wrrautad

hater ceeuwodh that they have me areec poteatlal toi additoG

e tate wAne the sectte as OtawrI sed bovoloen turther

euperimeste vth few reck pboophar s0d with reck pbophat treated

to sehesa citrata selmtliy or to ha csaducted

Metbir sertes of tbme enprtaeats wae c~edtmcted by IITA

to Ut~rta copal TVP AOP APP aed it at see tecastisix (table 14)

No dot lalt sewseltles teh draw tree thee results simouely em pear to tlvdl bsww they do stwgpt tbat forthew work with

MR to werramid so tbme sels

Table 24

LttcttF Swce MaPlate 06 ieldot IM AWaia CoelsANS at IITA (Ugboda ad Apoin ail sorit) aid at Ike (AUaba s5i series)

1973

Plate ot IP Apinu 5 poundebods A1ab

Ocrol 0 Z94 419 M)

Tr ipl ruprphite 20 349 3799378

Triple vepput 40 M09 410$

Triple 6wp~~b1 4271 4344 42250

Ammotw-ritpophW to 4201 4124 4040

Amosim-rdop~phlt 40 4270 4106 4231

AM tuo-polpephats 20 404 4244 3794

~eai~mpelppepbuI 400)49 4094

Cee m-pbpbt to- 59

momee eph lto 0 4192

LSO (0 0$) 29 1025

Th WPII

- 51 shy

101Y114 tpeM-fI PEP~tbRP YO

1 ~ ~ gmw 1pc~biofl- 9 Kla4v4h

Upia U04 Copfind am Crehout Stet Rpano at (Ia4

rico t IF t rume6 orth~ Caralto phoophale rocl QAR) vaUN pqU41 to

roopon from cmonetrat4 gsporphophai (CIP) who ort$o4 oil k

was 45j itwas tafertor vb protioo4 oil p war OS Ib 4iffer~c

in rtc reepos to X cod14 oo bo ttrit4 4 4 hvsciag of boil p

~ Pt o r11221 0 tP

c theto the rhimecyllndor of rico tots par to)14M4i1 roeoi~t

ed oil emd PA prior to tho ont of an~robi4 cMioe AA~ oIifoshy

nAte bYpot t taet~d tO fC4sin t~r 4PWden0 Of f Ot(tivshy

ofOWailiJtyno o prefla4 all Put that 4t01etoo 14 tvsIk

of the Ott to prvvld a 014for C4m0 44 mI 1 o4sf

EfftC ftPet141on AIAM-0 V f401td 4 4iv 440 Mtft

Aa torfat VampP f4MWfCi4W04wt0amp to 4eturWlI Ot(Wel~drIC ft

Ot f tM6 the flooded Ott 00 14 04019I Pft0uAw Of gAr~s~lr

pkS$t M40b MP) Tw P1101 Piset Prodwie W-e 10M0di Wr04

(10-1) emW 0aretilp ddw01at4 P WAA firom Rrth M~flRU414~$

wee cowiared with fie Md reWim 44104 proo~fo) foruk oith laWItter

I v te-PR P OW1004 4 4 O Wf ottil OW ellt Oo

Oveiel1 the 40tt dmcruie to effetotww Wtollowui Co fme

PR tpaUIB1I ldoltmo PR (pamwlatr) offr~- ArmeuM) 0 orwi

- 52 -

Effect of N Sourc6 and Water Management on Response of Rice

toe Zn- M Giordano J J Mortvedt OP Engelstad and Greenhouse

Staff Several rotes of CO(14H2)2 and (H )2So4 vith or without ZnO

wore applied to flooded and nonflooded Crowley oil (limed to pH 75)

to determine response of Bluebelle rice to Zn Yields with both N

sources veotrgreator on flooded then on nonflooded soil In the abshy

ence of applied Zn total dry matter production vith CO(NH2)2 was

slightly lower than with (NH)2S04 on flooded soil and considerably

lover on nonflooded soil Concentration of Zn wan higher in straw and

grain of plants roun on flooded than on nonflooded soil Although

concentration of P was unaffected by N source or Zn rate there was

som indication that cranslocation of P from straw to grain may be

depressed in nouflooded rice Concentration of N was lower in straw

grown on flooded than on nonflooded soil due to apparent dilution

thereas both X sources resulted in similar N concentrations in straw

at all rates of N application the N concentration in grain increased

with 0 rAse

feSpongi gf(SM to Chjorospodiostte and Related P Sources--

Si Allen and Greonhoue Staff A greenhouse pot experiment was

couct44d with corn Brown on Hountview silt loam to compare the ofshy

fectlivees of chlorospodiosito (Chlor-l) with concentrated supershy

phosphate (CP) Thomas slag and North Carolina phosphate rock (NC-PR)

Oil-prillad urea-phophato rock (UPI) FeA1JMP 20 7 and monomthyl

phosphate were included in the experiment Based on yield of forage and

uptake of P by tvo crops each of 6-weeks duration the following conshy

stui were dravat

I Chlor-1 was slightly loss effective than CSI Thomas slaS or NC-PR

from which Chlor-l wae prepared

- 53 shy

2 Granular UPR was a poor source of P its effectiveness was greatly

increased by reducing the particle size to -35mesh

3 FeAlNH4P207 was unavailable to the crop

4 Monomethyl phosphate was equivalent toor slightly more effective-

than CSP

Research Indirectly Related to TVA-AID Project

Response of Several Rice Varieties to Zn in Moist or Flooded

Soil--P M Giordano J J Mortvedt and Greenhouse Several varieties

of rice from Mexico and the Dominican Republic currently under investishy

gation in Puerto Rico for adaptation to upland culture were compared with

some established United States varieties with regard to Zn response on

moist and flooded Crowley sil (pH 75) Chontalpa (Mexico) Bluebelle

(Texas) and Starbonnet (Arkansas) were most responsive to applied Zn

Juma (Dominican Republic) intermediate and Sinaloa (Mexico) and Calrose

(California) were the least responsive The Sinaloa varieties (Mexico)

appeared to be best adapted to non-flooded conditions whereas Chontalpa

and Calrose were poorest Concentrations of Zn generally were higher in

plants grown on flooded than moist soil

Pattern of Growth and Zinc Accumulation by Rice--P M Giordano

J J Mortvedt and Greenhouse Staff Rice plants were harvested at weekly

intervals from shortly after emergence through maturity The objective

was to determine the rate of growth and Zn uptake by a Zn responsive varshy

iety (Bluebelle) and a less Zn-responsive variety (Calrose) in the presence

or absence of Zn applied to Crowley sil (pHl 75) Dry matter production

of Calrose was linear with time of growth and of a similar magnitude until

heading with or without applied Zn Bluebelle followed a similar pattern

where Zn was applied However in the absence of applied Zn foliage yield

was reduced markedly

-54

Uptake of Zn was similar for both varieties whenZn was

applied Dry matter production and Zn uptake by the two varieties

also were comparable when Zn was applied However yield of Calrose

was much higher than that of Bluebelle in the absence of applied Zn

while Zn uptake was only slightly higher This suggests that the lesshy

ser responsiveness of Calrose to Zn may be due to more efficient utilishy

zation of Zn There was no indication of a greater demand for Zn durshy

ing reproduction in either variety as was suggested in earlier greenshy

house experiments

Response of Upland Rice to P and Zn--P M Giordano J J

Mortvedt and Greenhouse Staff Several rates of P and Zn were applied

to Crowley sil (limed to pH 75) in factorial combination to determine

whether differences in rice growth under flooded and nonflooded soil

conditions are related to plant nutrition Although straw yields were

slightly higher in nonflooded rice receiving adequate P and Zn grain

yields were higher in the flooded crop increased rates of F andor Zn

did not result in equal yields Except in the highest Zn rate (75 mg)

concentrations of Zn in both straw and grain were higher with flooding

Concentration of P increased with rate of applied P and was higher in

the grain or flooded than upland rice at a comparable P rate In conshy

trast concentrations of N were lower with flooding due in part to dilshy

ution from increased growth

Rice Response to N and P in Flooded and Unflooded Cultures--

G L Terman S E Allen and Greenhouse-Analytical Staff Rates of

N from 250 to 2000 ntpot and P from 0 to 1000 mtpot were applied for

Nato rice grown on Mountview sil and Sango sicl (625 kg of soil per

pot) Market yield response to N and P was obtained Yields of straw

- 55 shy

total yields N uptake and N recovery were higher on unflooded than

on flooded soil cultures Grain yields however were slightly higher

with flooding These results indicate that with adequate applied

nutrients especially of N rice yields without flooding can approach

or even equal those under flooding

Uptake of N P Ca Mg and Zn increased with yield response

to N and P while K uptake decreased on the Mountview soil Concentrations

of N and P increased with applied N and P respectively while concentrations

of other nutrients were diluted in most situations with yield response to N

or P

Results from this experiment show that amouats of N applied in

previous pot experiments for rice have been much too low especially if the

crop was grown to maturity

Response of Corn to S and N i UUASand Urea-S--S E Allen

and Greenhouse Staff Three greenhouse pot experiments were conducted to

measure response to S and N in ulfur coated urea (SCU) urea amonium

sulfate (UAS) and urea -S as well as estimate N losses from surface apshy

plied N sources

In Experiment 260 less than 20 of the S mixed with the soil

was recovered from SCU or urea-S granules by two crops of corn as comshy

pared to 45 or 80 from flowers of S or Na2SO 4 CLop response followed

a similar pattern

In Experiment 260-A N sources were surface applied and alshy

lowed to dry for two weeks before incorporation Into the soil and plantshy

ing Recovery of N by two crops of corn was 77-82 for AN an compared

to 37-70 for urea UAS urea-S and ICU Thus n this experiment loss

of N from urea did not appear to be re~dcud by light S-coatlngn or by Inshy

corporating S or AS in the granules

-S -

I xbprZnSlt a Wtch aU Meyto 0-Ai Wt f9r

higher reermo teOrtOrs cOM reSpWNO i r0100 Of N w

not oaisteontly related to sewe ot N In edl tust 0 ioltiUe Lim

lo in VMuwpped evlmtUTS 48 merind by seirest nte appresOehe

501 for uroa as cwarod to 210 for urea peepha

Rus- or Upse to LoAmIl34I a AriMed bI Earl U

MW NOWlsIIsIr-4 L Toman 5 1 Alln and eesese StNf rio

row on Sawg did (0 tpot) We 1l0l0 Ws feritiud vith 05is

of Npot mixod with the 6011 as aureCA NiAO) 1 Age god At Ures

was also itcluded at rtt t 05 10 end 15 of Upee Theas trealshy

onto were followed 4 wpdrsetago of U s AN wre 4C 10o or at I3n

Weeks toulin up to IS pot

A soil application of 10 pot rosulvod to the maim yield

at 4 weeks Tio4 sad percont prottis t intre raite tncreased rftishy

linearly with U applictalien IeseeItally all at the m iNd wit

the moil w domitrifted after flooding Grail end straw Ilelds vere

highly correlatod with tiliriag and vlh ubers of gralm arl

The results Widicat that 0$ to 10 a of Upot as orea or

NN bsuld be sied with the oil to stilate tiilrir with adshy

ditional 0 topireased later to increase grain lIds mad protia cmshy

tout

DIVISION 54- FERTILIZER TECHNOLOGY AND USE

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Widj 6vi of V46 745WI KU waso-W im Wow 0 is610SWAOMMwasa to t

VAp 1Mampd KV ppu~s dw whaim $i a a los Al w W

Ib Milvo urns of OWe d- musA as h~ s a IuIow 8 1 ue ip

-Wlidswf of 4 ofatsIW5vsS d M M5 i RSa pm~daps In ampup 1Powworw rue hevi A b

el eas goileN ruseW4 wo duffeeme bWOM isttouwi

14 gnp40 woSalrw 11ylo amreu Mwb Isevlow roosmN~ahIt s 60 W ~tsmAIM L n ~ ~~ ~

MM I PWrawA = rMla yowIeM oa

eUW as ymlh OW by IONamph avWlbl N The mubsr 1MM Pude M~ IsA aemOWeld

IWOes A rspeas Owed ai udlWwease

por bre

wals rIs O touprua KU=plaINamppNOMeses a

W UWhk 0 ASOoml ft A poWsdvutA adesae of amr Wns ai A 0r- 1ampdd Oehs IuRawy NO Pue podllosWewwe gmak asmpnle by dMiss is amle OWN pet -W yid I MuC)ad ampAn (WiplaeT16s mOW aOW aNo fhr ft ymIed------ obealud w3t 0 OW 40IsA a VM bpR ofthW d saw ns m aI efes R 24 ad 7

e 1 d

Ii

Iw NO ~sp 44I0 so

~ ~ I $4U tml

Tile 4-00dw x uiampOW74u 0qee of

_____k _ _ shy

~ - 56I 5

-f

irenY w -a

Tiles I sed I thm Au do sel oeppled upaoIks WIM0 0da ispI amd us Ou s 106 kg

h Eaap 8n 14 sMsa of abw~greuad PU Pau WW 1 u itb IUKho 0aaphelem s 60 Otarlmmh At ~ 0sU Ishiseoo Cook oiA N uiplasu mAasslaly abess A leel

v doese a WKWye Is ks Nha m 6 sa4to dafo aONmuw The appee swm Wsssof adde N4 alalaed by vuMb ifaa W C Was sekilumganSro Is

bs eabI wish as aVWWa uwewy nap (f5s)f ad Mashes reaMeY valaes of 48 0 S414 CWm

owdb imto US Wh s vs sf 3I mld 54S fro 2 aMd 3) A A

valves a hevwae u Iar Walh basl oswas dhe uwpatr bshava of

tb~msusasl appkausu of ofta sede s have aoweN

TOW opl taoe for AieweeW 4OsmWMbas Op peas As Tabl 4 sling sob Os awowully eom grams Piel level Thes oeulam Ma sed as IM

-02

792 60L WI W A)49R Pio VOL 37 197)

primS o r OeampAd WU toa Them fl~ w At NOSSe earno maisslea Ia N he mOWamplIO yik ampWd IMe aampWmW OWa Owe wa UMs of KU to 41 Oke ampWiiIamm be dkrnety ewspokawleM(a s8 te camtd wie a eapmoe by TVA pavw ltoi NA poundrmdaka4us vrimeW460 o to ilkidm ofWW (Mtemas MuOwe 1973) TVA mwi bawld on soi ficedims IampWp seg rudwiv s~s0abet ke WNmdoe ON 01 K Is12 NOSW ie fssewnmu Ie I QvaaIi rowp IMA) f9

)amp m lodk byO voebmsaIS8OpeaWfrats 11 OWNmi a I a W idisod 0 81 Now 111 nindat Wm fysmpseaamp (If tsO tUmtI IsM $P shoroV4mmo knflkvnf (foOdme nuw ae Ow OImstwe in SM pnmm8 af tXm 10 114PIS kequoian wo Mpfii

SC~po umd spop~o VWt alm 4emWal 1 4ink PCmirsra M 1 ad AI 14bmms

1MM Ww Even to doe shw wisht b-o -Wamp Ekb fed rbaimpal of14~ Am Smpound oS mv fAaMda

MGMe -M4 Wg kmuwadM 1Wr wih SCV4 Psmuck Wff It dlL Wm 1W led 0 1 oo teeA of aiwaisme aweeoid h

1Kach Vt V amp4W ILK t)sa 10 Nareps vm This ndY ub thee hbow apiptomuasa of gulfu-aw~sd of Cup lP~~tamsl wi(i

Woeo of woo or mlm Wmiot InIasem~Wsy (heede 6Am 0 F- ad PAicv IfM tsoPm 9W famp kw~is 04eet The r4 ggm I ampbpiIs OnwAu 4nvmkstm v PAraem A4fshy

e W d inSIWfh sil $ad doke IaefitV twoer) 1 Te to theo owie effu so booJ imik WOi 100 N

-d

Is re4aled uIwq~e~w Aueee atofurnw di Capsnm ptopeatls is a oommm eiws to 100 tom of 04404man d CtdUW 4M Anw K~a do Aamp apowee WPUaN powu eel H pae iaaa thAi SCUI isWW owr hmem ISsuppl N to the li ieee F A IM1 Nampa Obo~amie m

41MB ~ ~ m ~ ~0 0-- 0 140 The ffsemn of food Nn else9~e(Ud~ ~ ~ ~~ WooksaS eAWw pjed of ho~raw of IU effadam vfdva oft xhj0I 13iAl

DIVISION 8-9-SOIL MINERALOGY

Amorphomw CeetIup en XmWra Ssrfmls

L C koits Am~ 0 tmmkaAf

ommp A faieiaAMTRACT skiwe lo nW ampM sm wi4h

Walo by a onMm I dmivid hseidm6Wlk W~edesie s

peuiieles as is s e wpwigstee eded his S -em -om 0641 h4 hisW1mWOWb~ bfem peess Wimm kv Iee

Pa~~~eakr4awiS SeUeeiNaiA WOW 14e

PWWWW t HW f hea~I~~~~~a 0th

kog Ii ampI b 1111h1atAmOem aid itsaere~m-aelmoeug toolPe aal 111W mWa Wisg ag so~ ti~Wo booviot65k Th eme Iua 1111411uiwon it es 01000 AW~CWS ~muiseeteqqsheer21111 ionev

oO00 llb K0 ibad~ ~~ doj 140WI s o mimdW um

WLIMmAmMVL 1

lill mi oHow al of a be 1974oyais4gamm wsoc wwo

rdy i of OMAN toblind id sh os 00 IN bei m us salqs m kid Vw 1 a0Msw WFW isms waf e eeiWei he-4~~e gsa dulsi

os 0aMW ofmu WA l aduWs~Ib rowuvvl3maIpm s

CaO~OP aw AlNomI 4ornomd to9 IS is -l O SI g4he rpidyThus whim m dowu bWa 0 m m- ei u

d m M 0bmSaImu M-1 ofM6 h Intun to 7I

aiba maush WAesshwn~u9dSg a osusLwpI ~ v m

M PolsdAvoWdw Ons pugm~ low iwLW m We

of~U -a~ mo uNo

0401ts of 40

A e mun5d m i vvamp sa s ow bftIS i sa omdIs a w

edi1 hswopmo an ag am Iw anom erlwaPASneooie bnwoM po

o ~ do=lr 3s fluACWoSM Owaa VolM Ain b 400b adW g o as amob ofrMOWS A oo eWmaa ow $wofdi60 ow - ema

-v K Vcon l ap ad md ld KU lbs PoabumwA od w to domi a bembe 0b lt $014 i ampmomONo

4st diwemmSod i 6o pa P)ameakiksm4 m 04M t 1iV vs 0606 o IS ft dopsss of q madl w I10000014 t 44hs

arbs awasm 00 iztv Am-~~~i u5~ms ashu is byw

e~ihs diu~wsm ~phid W A0)ad Lobe d mi-~-- 1) 14 hald

bob~wh do is poPbe~mueus l to aVE tumad 40at iai ka as m

bdisc shmm Ammmd a Sm ofd~~~~~d~A ~ a~m olWshmo

OWNSrilgf ms as

Um~~srTmws~of 4 A ad to wy mis itm voW

IN~flA4T ampMww IV Kwo~t M1CI I POWMAIS amV VARw d01M11 W V

e~~Pum-p -f AOACoe~mfmmdso isedp Am PApmi sk adw Wsk m~ o P4 m

- omlos r umIWO1in pw

lie Uvplist i piw S p wsmoW N of t as so in~tabo 440 o rodgAsect M4Ammd meM ii INAq10ed~ Pib mdWWeiW 1w -w emit TU UFm 6AV 0W A fIN 00~ lb 0PANNO 4 drp OW~It~Oi Ofme _____f WACMW0IN WMVsol~lmO ft SNAO 40 do1Si - m Md y e b ii m

of of~phaow tw bmsdf toamplboe

AjflsutomW C1D-pCTP AD mSmZLT op 1 m ow ts Wdm of P om M

IaM 0t sdw a wn a8duws i ofV -w Mm P16I4 TWO a ewu i an

ov4mnk wsi 9 Mxfeu~i am emwm ismi0wmd fq W No ~~ - f mug Aitowe eutlkowbmTV is

amppowftdmi TiM 0 Tie OAA mo p)a Mwomoi dOn4m A)w

MW 0 604 0M mm yaM 01MWOfdi to tA0 M OOAW uinw OSOb

ap is~e I the ampo A A Mwof ~Do toit op aenu w~ifiOimem~ MAN ampW)

ItsAO se Y lieowawo u~w pkow-W1b pwf on a C Nohkw is f 0o1 s do~omW C mmU4

owud6moeft 4 Obind PINa~e

~4~~wreu -A---I ad

fit~~~~O 114 4 t I mMsmm m~

im ^aim4 Nomod 06maw ee Aist em moom a rA No fmiEo of emit

~ -0

65

0IL CL OC AMXR PROC VOL 38 1974

)aT1 S4I104 ow Lusanll Tawng isa tall Thai variety known for beingIwo nonshyi s s ) sensitive to photoperiod A split-plot design was used in

S e e these euperimeots with 4 rates of P (I1 22 44 and 88t i V IV k of Pha) applied a main plot treatments and with the OF It sourMes of P as subplot treatments There were two checkS plots in each rmplicate The extra check plot was included to permit the application of fresh TSP standard Jor the

It- ti 06 + i bull fa succeeding crop the p-4me of bi was to permit accurate d awrnwal of the mdual effectiveness of the phosphate

ftinSUbI rock The P fertilioers were broadcast on the mud andthen Worporald In the soil during the last harrowing At

whM N both On ACS indx ampM time of transplanting Immediately before the last harrow61t (4j 5 4 01 P s 3Mm o Vallonal in con n 100 kgha of N as ammonium sulfate and 33 kghaWO Of Spews ampm lIW thaabe rocks do ACS indes of K as polium chloride were applied A total of 40 wa in prepw O do ctih k otent kha of N a ammoniunt sulfate was applied later in twoir P The hew oNed amp wM W for 5 of gw topdrossingp with about 5cm depth of water on the plotsvV I aiOMveffeOctveee Three to six ldayold selings pr hillwW the ACS idex were planted00OWW wia Oft fo an c irNk I p Coen 20 by 20 cm part in straight rows Hand weeding was used

and insecticide were applied for Insect control Grain yieldw was masared by sampling 5 ml of each plot excluding border rows The date of heading in each treatment and theUNiN d pbM W Weks rin tOW USA UMe In Tale yed componnts at hafvel were also recorded

I filM rsperMS esOM kdwdua 1 t ab The average yields of ough (unhulled) rice for botha 84 OW O 8uo 4 Thala TM was a locations are ploutel in PIS 3 for the first crop (1969 wet

owou thRM seaso0) The Veamps yield response was obtained at Klonge (s) W lDtO t Of dMa of1tw W d l R Luang however a 4ute satisfactory yield response was

~Mk ^d TVA UJSD ad Kd UnIveS obtalned to applied P at Bangkhen as wellXUe LaM e R qwrw Ims The sod was do Relative aponomlAe effectiveness values were calculated

VOW (a ksA w edmwL t Poesesm h Vy for these data and am presented In Table 3 The valuesdAY buo if dIe ouh ne Pee wtk a Mlak vow 1009 for th first crop are plotled against ACS index in Fig 41 This Im M i6ti l 4bNd IO a0 O mkarnk for both locatio r relationship was linear for the

11400 ThCpH 0( lb pW IW 01 th UpeiaW so Sanodion location and curtiltnear for KIng Luang The was u i 4A sksamp lMaor nrusio model amparounted for 81 of theAmO$MI Aw jAAsue Swim T1 Snh Wd variation In the AE valu for Bantkhen a square root

Mems a Iw iv fern alh$ sedm haowg dayNW W t he plAL At tdo M tM aso W s as ctminued throufh eltaM t Ofpof -le lse wo am P OeNI VeOpls 1o ealluae tI lon4erm MIdual Offccls

A on W isset i a wse to hsh eapeel of these ooihss t ocks The baagkhon experimnent was letmiaI1DlVemisthis is a w hulu Lo g Tasug ia iasael aft - Msd residual Ves will be pr-Om crok TheseTwod esewm

SWWo

A

lP~U~7 ISIIPe1iuIWN e bsedisssin ian ghth siaoelalbe

984 0 6 O O - M s -s fWPas 11eSft W d Uo al a o

o

S4l~ lIIII I~l I 1f fl

( +

+ + + m + ++++-

++ +(++ + ++++ + ++ ++

- 66 -

ENOIMLSTAD ET AL RESPONSE BY FLOODED RICE TO PHOSPHATE ROCKS VARYING IN CITRATE SOLUBILITY

I I I I j0 I I

BANOKHEN BANGKHEN

pH 56 6 - 0o

TSP

NC

5~ ~ ~ L o 4 - -shy

4 ] - --------shy04

6S

|0 III 2 44 8r 66

I I I

a 1KLONG LUANG

pH 46 z KLONG LUANG

TSP Sc2 NCFL(N)

5 FLIC) J0 TU

oshy

4 ~40shy

3 bull eM0

I - I I I I I

0 II 22 44 88 0 5 10 15 20 IP APPLIED KO HA ABSOLUTE CITRAE SOLUBIITY INDEX

Fig 3-Yield of rough rice at Klong Luang and Bangkhen Rice Fig 4-Relative agronon effectiveness () of P sources ploz-Experiment Stations Thalmand as affected by rate and Source ted against citrate solubity Index for both Thailand field ex

of P applied (crop 1) periment (first crop only)

regression model accounted for 97 of the variation in sumably resulted from crop uptake and reaction with the RAE values at the Klong Luang location soil to form less soluble products Such effects may have

These experiments were continued during the dry season been more important at the lower rates since the two TSP of early 1970 to ascertain the residual effectiveness of the curyes converged at the highest rate of application various sources applied to the first crop No new P was These data from KIong Luang indicate that (i) residual applied except for the fresh TSP standard mentioned effects of all rocks except Mlcwuri were substantial (ii) above rhe experiment otherwise was conducted in a man the relationship between relative agronornic effectiveness ner similar to that followed in the first crop of the phosphate rocks and citrate solubility levels was

The response to both freshly applied ad residual P was largely obscured and (iii) the general superiority of TSP marked at the Klong Luang location and marginal at over phosphate rock in terms of effectiveiss persisted Bangkhen In fact at the latter location the response was through the second crop so small that little can be said regarding residual effectiveshyness The yield data from crop 2 at the Klong Luang DISCUSSION experiment are plotted in Fig 5 Greenhouse and field data presented in this paper show

Relative agronomic effectiveness values (Table 3) were clearly that there are substantial differences among phosshycalculated for the Klong Luang data using both the residual and freshly applied TSP as standards It is of Interest to note that the superiority of TSP over the phosphbte rocks Table 3-Relative agronomic effective values for field experishyments in Thailand persisted through the second crop The main difference in KlowlZmlnql~the residual effects is that with the exception of the MIs- s Crop 1 Crop 21 Crop 1-shysouri rock Ihe marked relationship between citratr-soluble WoiCarolina yl 59 76

phosphate rocks and RAE had largely rds norh) a 64P conltct of th Florida (eqlral is 6969 6

disapipeared In this acidic soil (pHi 46) P would by this I14o 69 63 40 ToonesS 31 65

limo be supplied by Intermediate reaction products In addl Missou 0 o lion to residues of the initial spatlte Ts P o 2 o 0

The TSP applied to the first crop declliv-d slightly In campIafcmWataesr e id ofeuhuloefor 22MA rates of PtColeouattd as aba u tlte td18 kS ratesp dlverage yield tM868 to 22 44

effectiveness relative to the freshly applied ISP This pre- of d s4

A

4

- 67 shy

-SOIL SCL SOC AMER I

KLONG LUANG CROP 2

Si 3

eN

TAPPLIEDKGHA

Fig 5-The residual effectiveness ovarious P sources for crop s compared with freshly applied TSP Klong Luang Rice

Experiment Station Thailand

phate rocks in terms of agronomic effectiveness for flooded

rice Further these differences can be predicted by means of citrate solubility or by the ACS index It appears that

the latter is more appropriate where the content of apatite varies among phospiate rocks The most soluble phosphate rocks approached but did not actually equal TSP in limit-iuig (maximum) yield in these experiments regardless of rate applied This agrees with the results of Ensminger Pearson and Armiger (4) One needs to consider the defi-nite posribility of same yield loss in zhoosing a phosphate

rock over TSP such yield losses must be weighed against the lower price of phosphate rock The explanation for such iosses may involve concentration of soluble P in the soil Khasawneh and Copeland (6) suggest that the growth rate of crop plants is a function of P concentration that can be maintained in the soil solution If P concentration is limiting or inadequate becawe of a lower dissolution rate of phosphate rock the growth iate ard uiiimate yield will be diminished accordingly

The RAE values bascd on yield increases reflect the agronomi effectiveness of these various sources relacve

to the TSP standard however these nould be supple-

mented by an economic analysis before rational choice can

be made The following calculations will provide an estimate of

the rclativ ecooomic effectiveness(REE)

Y t Ps aXpatREE -- 100

vahtercks t sphate or e b i- eor

Price of TSPkg fo

be Price of PRkg P

PROC VOL 38 1974 leO

90r

Wsoshy

0

60-LUSEPHOSPHATE ROCK

00 10 20

PTP PR

Fig 6-Relationship between relaZive effectiveness values (RAE) and the price ratios between TSP and phosphate rock Such a figure can be used in making a choice between these

sources

If REE exceeds 100 in this calculation the phosphate rock would be preferable to TSP

The REE calcuktaaa wre used in preparing an indifshyference curve (Fig 6) wherein RAE values are plotted

against PTsPPpR ratios The cu~rve itself connects those points at which REE equals 100 When exactly on the curve it makes no real economic difference what source is chosen After choosing a suitable price ratio one can then project upward from that ratio knowing the RAI

value (or estimating it from such data as shown in Fig 4 using citrate-soluble P content) one can then choose the source on the basis of both agronomic and economic conshysiderations For example if the price ratio is 25 and the RAE value of the phosphaite rock is greater than 40 the rock phosphate in question would be used However if the RAE value was less than 40 TSP would be a better choice There are indications that if the P in the more soluble phosphate ro~cks (North Carolina north Florida central Forida) is less than half as expensivz as that in TSP these rocks would be feasible altereaives to TSP on soils similar

to thoseused in Thailand This analysis does not take into account the possibility

of lower yields from use of phosphate rock In addition only a portion of the various yield response curves was used in this anlysis ie up to 22 kgha Beyond this

rate yield response was much less pronounced it could be argued that at less than maximum yields TSP would produce a certain yield at lower rates of P than would phosshy

pow ofrock This would especially be true for rates applioa example at Klong Luang 5500 kg of

rice pcr iectare could have been produced with either Ii kg of P as TSP or 44 kg of P as son of the more reacshy

tire phosphate rocks It should be pointed ot however

- 68 shy

(IIKIS amp YOUN( ARIFICIAL WEATIIERING OF OXIDIZED p[ll- IV

that this is the yield level that would show the widest difference such is the advantage of hindsight

Farmers generally prefer granular fertilizers for machine

or hand application This is a disadvantage for the phos-phate rocks which are normally arplied in finely divided form Recently experimental quantities of granular urea-

phosphate rock mixtures have been made by TVA Results of trials with these fertilizers will be reported elsewhere

LITERATURE CITED

1 Armiger W H and Maurice- Fried 1957 The plantavailability of various sources of phosphate rock Soil Sci Soc Amer Proc 21183-188

2 Bengston G W E C Sample and S E Allen 1974 Re-sponso of slash pine seedlings to P sGurces of varying ci-trato solubility Plant Soil (In press)

3 Caro JIt and W Hill 1956 Chard eristics and fer tilizcr value of phosphate rock from different fields J Agr Food Chem 4684-687

4 Ensminger I E R W Peirson and W II Atmiger1967 Effectivencs of rock phosphate as a source of phosshyphurus for plants US Dep Agr ARS Bull 4112S

5 Engelstad 0 P J G Getsinger anid I J Stangel 1972 Tailoring of fertiliers for rice cnnece Valley Author ftyNational Fertilicr Developmnent Center Hull Y-52

6 Khasawnch F E and Jane P Copcland 1971 (otton root growth and uptake of nutrievos relation oif phosph

rus uptake to quantity intensity and buffering capacit) Soil Sci Soc Amer Proc 37250-254

7 Lehr JR and G H McClellan 1972 A revised lIbora tory reactivity scale for evaljativg phosphate rocks for direct application Tennessee Valley Authcrity National Fertilizer Development Center lull Y-43

H Terman G L S EAllen and 0 P Engelstad 1970 Response by paddy cice to ratcs and suurces of appliedphosphorus Agron J63390-394

DIVISION S-9-SOIL MINERALOGY

Artificial Weathering of Oxidized Biotite IV The Inhibitory Effect of Potassium on Dissolution llate

R JGILKES AND R C YOUNG2

ABSTRACT

Rates of dissolution of oxidized biotites in OIM 001M ICI are severely depressed in the presence of IM KCI The amovnts of Al Mg Mn dissolved in the first eytraction are similir to those found without KCI however subsequent extractions remove these elements at 10-20 of the corresponding lICI rates This effect may be due to a decreased rate of vermiculite formation thereby reducing the effective basal area exposed to attack A decrease in dissolution rate with increasing ferric iron content was still apparent in the presence of IM KCI

Additional Index Words X-ray diffraction infrared aborp-

N EARLIER papers of this series the tole of biotite in soils

as a source of both macro and micronutrient elements

has been discussed ((Gilkes Young and Quirk 1972 1973ab) Experiments in artificial weathering uiing as va-

riety of extractants were undertaken to determiie the inlu-

ence of oxidation of octahedrally coordinated iron on the bull release of structural cations to solution The results of this

work demonstated that biotite behaves anomalously with respect to the other common ferromagnesian minerals found in soils Oxidation leads to the development of a high degree of resistance to cation exchange and dissolution Several authors have coiwludcd that decreased rates of K

Contribution from the Dep of Soi Science and Plant Nutri-tion Institute of Agriculture Univ of Western Australia Ned-lands 6009 Western Australia Received 29 Sept 1973 Ap-proved 8 Jan 1974

2 Senior Lecturer in Soil Science and Research Officer respeclively

replacement in electrolytes shown by oxidized biotites are

a result of the inclination of structural hydroxyl adjacent to newly created trivalent iron or vacant octahedral cation sites (Robert and Pedro 1959 Barshad and Kishk 1968) Gilkes et al (1973b) suggested that decreased rates of disshysolution of oxidized biotite in 0001 0t)l 0Af CI may also be due to the presence of inclined hydroxyl In this case a smaller surface area external and exposed intershylayer may be available for attack if K replacement by hyshydrogen ions occurs at a slower rate in oxidized biotites

Gastuche (1963) has shown that significant dissolution ofthe (IIM) biotile face may occur and it is easily demonshystrated that the proportion of exposed (001M) face in weathering biotites depends on the percentage K replaced

Rausell-Colom ct al (1965) have shown that hydrogen ions act in an identical fashion to metal cations in K exshy

change from micas In particular exchange c-f K by hydroshy

gen ions will be terminated or greatly reduced by high levels of K in solution Thus if dissolution of oxidized biotite by

acids is carried out at sufficiently high K levels to prevent vermiculization any differences in dissolution rate that may occur cannot simply be ascribed to differences in rates of K replacement The following results were obtained from such an experiment which unlike the experiment described in Parts I and II (Gilkes et al 1973ab) does not attempt to simulate natuiral - conditions

MATERIAILS AN) M HIiODS Further subsamples of the less than 0 hiotites used in K

excherandbaid disoo tu es (G iles e9n K exchange and acid dissolution studies (Gilkes et al1973ab) were used in these experiments Preparation of sequentiallyoxidized biotites without intermediate vermiculite formation is

Page 2: I70 - United States Agency for International Developmentto ascertan, but tgl.eetad, 1, L,. ("Tailoring of Pertiltiters for ice,'" TVA ulletin Y-52) states that the staft of IOi has

Progress Report of TVA-AID Project

TVA-02-74

Improved Fertilizers for Developing Countries

Agronomic Research

July 1 1974

International Fertilizer Development Staff

Tennessee Valley Authority

Huecle Shoala A14bam4

TABLE OFCONTENTS

Summary 1

Potential for Use of Sulfur-Coated Urea 3

Background and Objectives of Project

Scope of Work o bull 99

Project Plans for Fiscal 1975 bull 11

Engineering andDevelopment bull bull 0bull11

Agronomic Testing and Evaluation bull bull bull 14

Economic Evaluations

Workshop at Muscle Shoals a o bull bull bull 19

bull bull o bull bull bull 18

Literature Survey bull bull 19

Agronomic Research bull bull 21

Research by Overseas Cooperators bull 21

Greenhouse Research by TVA at Mlcle Shoals 51

57 Appendix

58Performance of Sulfur-Coated Urea for Rice In Peru

Response of Flooded Rice to Phosphtate Rocki 0 63

SUMMARY

This report is a project report covering the period from

December 1972 (when the bulletin Tailoring of Fertilizers for Rice

was issued) through June 1974 The present project is our expansion

of the previous project which was restricted to the use of fertilizer

for rice in that new and improved fertilizers are to be tested on a

number of tropical crops In addition to actual agronomic evaluations

of new materials increased emphasis will be placed on developing and

demonstrating methods of introducing new fertilizers to farmers so that

they will be properly used or they become commercially available

Testing of sulfur-coated urea (SCU) will be expanded to

include a number of additional crops such as sugar cane corn cassava

cottonbananas and cocoa Additional experiements vill be conducted

with rice to more precisely define the areas and conditions where the

use of SCU will be advantageous and to introduce its use to agricultural

workers and Industry representatives

Additional studies are planned vith rock phosphate to evaluate

its o(fectiveasee for direct applications and to study mans of increasing

its phosphorous availability by relatively tople muthoda for local

gomo aitionalV06 will be cOndvct44 with xronutolt4 msatvres of vorious

aterltele With rock p Wephut

smtprfallairy wVr to Ceonepl44 001teitn w4ltr g fut

of W41114090~f vowmllo It to felt thut ~ Ot 0~t ea I fo

0 setvl to 011folf OW 10offft 4 Aiee441bj ftiIOt

hepll4t 0 14W l0a khef t~ l to1141l(0

-2-

The need for fertilizers containing secondary andor microshy

nutrients will be evaluated in several countries where deficiencies

are known or suspected but where no commercial sources of these nutrients

are presently available

Additional data has been received from a number of countries

pertaining to the use of SCU for rice In general these data tend to

substantiate those previously reported in that SCU is a superior source

of N for rice grain under conditions of intermittent flooding but that

it is no better than conventional sources of N when conditions of intershy

mittent flooding or severe leaching do not exist A discussion of the

commercial potential of SCU in tropical agriculture follows this section

Insufficient data are available for tropical crops other than

rice to warrant any general conclusions at this time

-3-

POTENTIAL FOR USE OF SULFUR-COATED UREA

The major portion of the agronomic research reported herein

deals with the evaluation of SCU (sulfur-coated urea) as a source of

nitrogen for rice These results generally confirm those previously

reported by TVA (Tailoring of Fertilizers for Rice TVA Bulletin Y-52

December 1972) in that SCU is a superior source of nitrogen for rice

grown under conditions where flooding is delayed or intermittent

However the results of some experiments from India and West

Africa where rice was grown under conditions where only leaching and not

both leaching and dentrification would be expected to occur suggest that

SCU may be a superior source of N for rice grown under these conditions

as well In certain parts of the world large areas of floating or

deeply submerged rice are grown very little information relative to N

response i available but in general yields are comparatively low

Further research is planned to 4valuate SCU for rice grown under those

conditions

The exact areamp of rice grown in developing countries under

conditions where both leaching and donitrification can occur is diffitcult

to ascertan but tgleetad 1 L (Tailoring of Pertiltiters for ice

TVA ulletin Y-52) states that the staft of IOi has ea|aited that uvor

7I of the rice in outheat Asia So Arown under this type ofter meASe

sent Prelisneary bfbervetio eu est Oat at t l PsIblySoea (a4

ofe) of tw frie to Vat Atfica to gmrae 4nder delayd of totriltest

irwiM4 to FAD report MD00llIO owtoifar f rce rt Imvi

W1110010 teveW ftJ 4 We 04001406w 1 141410tIf 0 ferl4iiio 10

-4shy

applied at a rate of 60 kg Nha then approximately 2600000 mt of

N could profitably be used as SCU In 1972 33700000 mt of N was

used in the world and these figures suggest that as much as 8 of the

world consumption could potentially be expected to be applied as SCU

on rice

On a smaller scale approximately 114000 ha of rice are grown

in Peru nearly all of which is grown under conditions where SCU would

be the most desirable source of N Average rice yields in Peru are about

4000 kgha but research by Sanchez and coworkers (see attached report)

indicates that with ample N yields of 9000 kgha can be attained To

obtain these yields 25500 at of N as SCU would be needed compared to

42000 at of N as straight ure to obtain the same yield Thus SCU

would save 16500 tons of N or roughly 40 of the N needs

Results from India indicated that when equal amounts of N were

applied an average of about 1000 kgha more grain was produced on exshy

porLsentail plots This average figure included some areas where SCU was

not superior to AS In 1972 36500000 ha of rice were grown in India

with an average yield of 1616 kgha Proper use of SCU in place of

conventional form probably would not Increase yields an average of 1000

kghe under fam conditions as it would on the research plots but an

average of 500 k8 would be raoom ble This would rotult to an Increaa

of a50000 m of rice an Incras of 311 over the 197 production of

$90o000000 mt

The 40 04Melee Ore cited t dMWMaftampt tbe iAnCicoo in

ftc prodwilu peble Ihrow~h proer t o of 60 a wvrf of 0 for

fiff MWere- f04ieb di at Peded t1 1if1 pfJiiea1y 4i fie toshy

ditlsw winde Iee idveitu f~ rics a to JMe(0wiaihthe of 1CM La f

-5shy

precisely evaluate the economics of its use

Preliminary data indicated that SCU may be a superior source

of N for other tropical crops particularly long-season crops such as

sugar cane and pineapply grown in areas of high rainfall

The results of the wheat experiment followed by sorghum in

Pakistan in which the residual effects of SCU were evaluated suggest

that in intercropping and multiple cropping systems fertilizer nitroshy

gen may be applied in a slow-release form (SCU) at a convenient time in

the cropping system so that the nutrient elements will be released for

utilization by succeeding crops

Information already obtained indicate that SCU is a superior

source of N for crops grown on large enough areas to economically justify

its commercial production As more data are obtained with more crops

and from new areal the potential for its use will undoubtedly increase

Consequently as adequate supplies become available programs need to be

initiated in selected areas to introduce the use of SCU to agricultural

extension workers to the fertilizer industry end to farmers and to

encourage its coinercial production Since the cost per unit of N will

always be higher in SCU than in regular urea the use of SCU will be

econmically practical only under specific conditions and these restricshy

tions as to its use make it perative that effective education and

inforuation progra- be conducted prior to the comerctel Introduction

Of SU On 4 Wid eeie

-6-

BACKGROUND AND OBJECTIVES OF PROJECT

The present project is designed to capitalize on the momentum

and knowledge gained in the previous project Tailoring of Fertilizers

for Rice This project demonstrated that a superior nitrogen fertilshy

izer can be developed for tropical areas and that some relatively low

cost phosphate sources can be effectively utilized The present project

seeks to broaden the base for development of improved fertilizers through

a wider range of agronomic economic and engineering evaluations Preshy

viously the emphasis was placed on SCU as a nitrogen source and the dirshy

ect application of a limited number of selected phosphate rocks as phosshy

phorus sources for rice fertilization In this project a wider range of

fertilizer materials will be tested on a variety of upland crops such as

maize wheat sorghum and sugar cane cassava and others of national imshy

portance in various countries

Through its domestic fertilizer research and development proshy

gram TVA produces experimental fertilizer materials that may have poshy

tential for tropical soil conditions and crops With support from AID

in this project the capability viii exist to work toward improving fershy

tilitors for developing countrive through the necessary and logical soshy

quenco of production to ramer aceptonce to sess the potential for

co mrcial production

Pertilliers now being used in 4eveloping countriee relAtive

OeCOtcs And shortcoMiNge of the Mterials viii be Ovai6Isd Ktshy

true thel ena 4 4 0(fiashyporimrtAl product wlornriee pilot plt

ties OaI1 pl0t4 Will be W0bsutd to fcresMq tet in jre

tof f~wrisea with caomvstmwl siatofials rr f P0041610 161i

-7shy

screening will be done using soils of the area where the fertilizer

will be used Materials showing potential in greenhouse tests will

be further evaluated in actual field programs in selected countries

If successful at this stage economic and engineering data will be

compiled to assess the potential for commercial production In orshy

der to evaluate the product and process the total system will be

studied including storage handling and transportation from the

point of production to the farm Information developed throughout

this work will be available to industry foreign and domestic so

that it can develop a production marketing and use base for utishy

lizing the product This level of technology is rapidly being achieved

for SCU which received major emphasis in the previous study additional

agronomic economic and engineering data both with rice and with other

crops will be obtained to complement the previous findings

This project must be broad and combine a variety of professhy

sional disciplines but it is necessary to retain the flexibility to

move forward in specific directions as Improvements in products occur

This is necessary to insure that improved products identified in this

project can ultimately be made available to farmers zegrdless of their

economic and social status and that sufficient data aro available so

that induetry can make soomd decisions regarding the foasibility for omshy

marcial production

Major objectives of this project are eommartted as tollovws

(1) Developing Iertilaers to wt the nutrient neD of oocitic

4I l VhICh are not set iconmically withtfopical Crops and

etoshytoov~tmtl| Nrtiliieoro or that can set thse ne- s fre

006eItCOMlY ky 4ir lfte the W91~1ici of teftlliaer ultil4tin

-8

(2) Proving the value of these improved materials to insure that

they will increase farmers income over a large enough area

to attract and Justify commercial production

(3) Developing the production technology for new fertilizers as

a basis for encouraging and advising potential commercial proshy

duction The integrated process designs will seek product

quality and economy while striving to minimize harmful emisshy

sions to air water and land

(4) Working through cooperating organizations and with leaders in

research extension and industry to develop and demonstrate

methods for introducing new fertilizers to farmers so that they

will be properly used when they become commercially available

-9-

SCOPE OF WORK

This project integrates agronomic economic and engineering

expertise into a single team in order to develop improved fertilizers

for a wide range of crops and soils in developing countries Considershy

able emphasis is given during the first eighteen months to collecting

the data needed to complete the evaluation of sulfur-coated urea and

ground rock phosphate for lowland rice Both materials then are

scheduled for demonstrations during the latter part of the project in

order to educate extension workers and farmers and to attract the fershy

tilizer industry into commercial production Considerable emphasis is

given to the economic evaluation of a total production-marketing-use

system for each material in contrast to alternative nutrient sources

The probability of commercial production of SCU and ground

rock phosphate can be enhanced by expanding their use to additional

crops and soils Thus the project is expanded in scope as compared

to the previous project on tailoring of fertilizers for rice in order

to test these materials on additional crops

The expanded work includes a major effort in screening and

testing new compounds and forms of fertilizers for various food crops

produced under tropical conditions Alt hough it if already known that

more effective andor lens expensive formn of nitrogen and phosphorus

are needed a literature survey will nerve an Lan additional guide to

important and presing fertilizer problems

-10-

Much of the work with fertilizers for both lowland rice and

upland crops will consist of field tests in Southeast Asia Africa and

Latin America Greenhouse and engineering studies will back up the field

research All field experiments are designed to provide at least an esshy

timate of costs and returns for each fertilizer tested

PROJECT PLANS FORFISCAL 1975

In this section the work for fiscal 1975 will be discussed

It should be remembered that the success of this project depends in a

large part upon maintaining sufficient flexibility so that work in inshy

dividual countries can be adapted to supplement and complement programs

already under way While guidelines and plans of work must be developed

so that the objectives of the project are clearly defined detailed

plans for specific countries or groups of countries must be developed

by consultation wth local cooperators

These plans will be discussed under the following three general

phases of the project

I Engineering and development

2 Agronomic testing and evaluation

3 Economic evaluations

Engineering and Development

Phosphate Rock

Methods have been proposed for relatively simple treatment of

phosphate rock (PR) to increase the availability of the phosphate to make

it more suitable for direct application to the soil These treatments

may be economically feasible in certain areas especially in view of the

current world fertilizer situation Considerable work has been done at

TVA studying means of altering PR and plans are being developed to inishy

tiate further developmental work and field testing of these materials durshy

ing fiscal 1975

- 12 -

Emphasis will be placed upon obtaining samples of phosphate

rock from deposits in developing countries and testing and improving

procedures for increasing their citrate solubility and tzius availabilshy

ity of the phosphorus From this laboratory screening process sevural

sources will be selected from which small amounts (50 to 100 pounds)

will be prepared for greenhouse and field experiments ou various soils

(as described under agronomic section)

From these results one or two locations (or countries) will

be selected for development of a pilot program to utilize local sources

of phosphate rock This program will involve production of the altered

PR and its agronomic evaluation and then educational programs with govshy

ernment and commercial representatives to introduce its use to the farmers

Sulfur-Coated Fertilizers

Some preliminary work has been done in which urea-potash mixshy

tures were coated with sulfur The 7-day release rates for the N and

K20 were 17 and 36 respectively from the coated product (22-0-11-30S

grade) This was the first effort in coating a compound fertilizer

with the new coating system

The widely differing release rates for the nutrients from

the coated compound product raise some interesting prospects for tailshy

oring the nutrient release rate of sulfur-coated products It might

be possible to cogranulate materials of varying water solubility and

sulfur-coat them to produce products with release rates that would apshy

proximate the timing of nutrient requirements of the crop The need

for this type of controlled-release product has been mentioned many

times by agronomists and may be especially applicable in multiple and

intercropping systems

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Table 2

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gr~a 1971

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- 24 shy

India--The results of four experiments conducted with flooded

transplanted rice in India by the All-India Coordinated Rice Project

Hyderabad are given in table 3 The response to N was excellent the

yield without N being only 41 of those obtained with basal applications

of N as uza With basal applications of SCU the yields were 20 higher

than with basal applications of urea and in the three experiments in

which urea applications were split yields with SCU were 18 higher than

yields with split applications of urea When comparing the average Nshy

response (kamp grainKg N) yields were increased 13 more by SCU than by

basal applications of urea

The data from one experiment with light irrigated rice in India

are given in table 4 yields were relatively low and differences between

N sources or method of application were not significant However yields

with SU tended to be higher than when all urea was applied at planting

but lower than when split applications of urea were applied Again yields

increased more than 13 more with SCU than with basal applications ofwere

ur

In tables 5 and 6 the yields of a short-duration transplanted

rice grown in irrigated light-textured soils at five locations in India

indicate that higher yields were obtained with SCU than with urea when apshy

plied as a basal application Yield increases due to basal N applications

were 502 greater with SCU than with urea However split applications of

resulted in yields equal to those obtained with basal applications ofurea

CU

The yields of direct-seeded upland rice grown at three locations

to India are given in table 7 and the relative yields in table 8 Yields

were low due to drought but good responses were nevertheless obtained for

- 25 -

Table 3

Effect of N Source and Time of Application on Yield of Paddy (Flooded) Rice in India 1972 (Summary of Reported Data from 4 Experiments)

Experimental Number Source Rate Method Yield Relative N-Response

and of of N of Yield Kg Grain

Season Nitrogen kgha Application mtha Kg N

- - - 196 34 -

Urea 120 Basal 573 100 314

11 Urea 120 80 + 40 611 107 345 Rabi SCU 120 Basal 713 124 430

12 - 0 - 202 30 -

Urea 125 Basal 682 100 384

Rabi Urea 125 35 + 20 + 35 + 35 633 95 344 SCU 125 Basal 781 115 463

13- 0 - 168 44

Urea 100 Basal 385 100 217

Kharif Urea 100 30 + 20 + 25 + 25 400 104 232 SCU 100 Basal 462 120 293

14 -

Urea -

125 -

Basal 355 650

55 100

-

236

Rabi SCU 125 Basal 781 120 341

-- 26 -

Table 4

Effect of N Source and Time of Application on Yield of Light Irrigated Rice in India 1972 (Summary of Reported Data From

One Experiment at Pattambi)

Experimental Number Source Rate Method Yield Relative N-Response

and of of N of Yield Kg Grain Season Nitrogen (kgha) Application (mtha) Q) Kg N

38 0 - 204 85 -Rabi Urea 120 Basal 241 100 308

Urea 120 60 + 0 + 30 + 30 267 ill 525 SCU 120 Basal 255 106 425

Table 5

Effect of N Source and Time of Application on Yields of Short-Duration Transplanted lice Variety Grown on Irrigated Light-Textured Soils at 5 Locations in India 1972

(Snmzarized From Reported Data)

Rate Grain Yields (MtHa) Source of N Method of N GrainI of N kgh Application Faizabod Karjat Mandva Pattabi laya Averaje X

- 291 266 211 19 340 260 -

Urea 100 Basal 386 407 361 285 482 3 124 Urea 100 50 + 25 + 25 399 430 434 334 6amp2 4A8 186

SCU 100 Basal 368 468 439 360 572 41 181

Table 6

Effect of I Source end Tlae of ApplIcattoo c RIstave Tle24 of a rt- rat1 T Lsd lice Vasrety Crin o Irrigated L41tshy1 at S Locitite mindi 1972

Rate ____________14_3

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- 38 -

Table 18

Yild of aemati-370 Rice at Punjab Agricultural Research

Institute in Pakistan in 1969-70 Grown Under

Couditions of Intermittent Flooding

Pate of application

=IL

o 0 67 67 100 100 67 67

100 100 67 67 200 100

Average for Sources

Ntha

AS 260 gres 279

320

Source f5

-

AS AS Ura Urea SCU SCU

Yield

Relative

93 100 115

(M)O

Yield

Increase Yield Due to N

(Ktlha) (mtha)

-212 245 033 274 062 260 048 297 085 315 103 325 112

Yield Increase

Relative

72048 067 100 108 161

(2)

- 39 shy

Short-statured high yielding rice varieties grown extenshy

sively in northern Peru require extremely high rates of conventional

N sources to achieve maximum yields The recovery of applied N is

extremely low due to the use of intermittent flooding This water

management system results in heavy N losses even with properly timed

split applications In search of simpler and more effective methods

of N management eight field experiments were conducted in the region

to evaluate sulfur-coated urea (SCU) an experimental slow-release N

source supplied by the Tennessee Valley Authority Rice yields were

increased an average of 59 more by pretransplant-incorporated SCU than

by urea or ammonium sulfate applied in the same manner SCU produced

excessive vegetative growth which resulted in yield reductions at high

N rates

Regardless of an assumed 48-higher unit N cost in SCU the

overall benefits of pretransplant-incorporated applications of SCU

were favorable since there was a decrease of 40 in the optimum rate

of N and the need for precise timing of application was eliminated

Pakistan--In Pakistan basal applications of AS urea and

SCU to rice grown under conditions of intermittent flooding in 1969-70

(table 18) indicate that SCU is a superior source of N as compared to

urea or AS when all N is applied at or before planting The data also

indicate that a yield response was obtained for P applications but a

comparison of N sources at each level of P indicates that no interaction

between N and P was present so that differences between N sources were

relatively the same at each level of P Yields were increased about 60

more when SCU was applied than when urea was applied Yield increases

with AS were only about 72 of the increase obtained with urea these reshy

sults do not agree with the generally-reported superiority of AS as comshy

pared to urea as a source of N for rice

- 40 -

In 1973 experiments were conducted in Pakistan using both

Basmati-370 and IRRI-6 varieties of rice grown under conditions of

When all N was applied at puddlingintermittent flooding (table 19)

or 12 at puddling and 12 at panicle initiation both AS and SCU were

superior to urea with SCU tending to be the most efficient source

However when N was applied 12 at transplanting and 12 at panicle

initiation SCU was the poorest source of N This would indicate that

the release of N from SCU applied at these times is too slow for optimwn

plant growth

In another experiment in Pakistan in 1973 no differences

in the effectiveness of urea AS or SCU were noted in the yields of

continuously-flooded rice (table 20) Again these results are conshy

sistent with earlier results which indicate no superiority for SCU

when rice is continuously flooded

Nitrogen Studies--Maize

A series of three experiments were conducted by IITA in

armo-Nigeria in 1972-73 comparing AS urea SCU and

CAN (calcium

nium nitrate) as sources of N for maize (table 21) A significant

yield response was obtained for N at each location but no conaistent

differences were noted amaong sources These results are consistent

with results at other locations which have not shown that SCU is a

superior source of N for maize grown over a period of 3 to 4 months

Nitrogen--Wheat

The yields of wheat in Pakistan in 1969-70 (tables 22 and

23) show that yields with SCU) tended to be lower than those with ureaJ

although at one locction where sorghum was grown followilng wheat with

Table 19

Yields of Basmati-370 and IRRI-6 Rice at Punjab Agricultural Experiment Station in Pakistan in 1973 Under

Conditions of Intermittent Flooding

Rate Yield Source of N Time of Yield (Mtha) Increase of N B-370 IRRI-6 Application Basmati-370 IRRI-6 Average (Mtha)

0 0 - 21 353 287 -

SCU 90 150 At Puddling 325 545 435 148

Urea 90 150 At Puddling 309 500 405 118

AS 90 150 At Puddling 324 529 427 140

SCU 90 150 Puddling 372 572 472 185 Panicle Initiation

Urea 90 150 Puddling 335 502 419 132 Panicle Initiation

AS 90 150 Puddling 353 529 441 154 Panicle Initiation

SCU 90 150 After Transplanting 312 562 437 150 Panicle Initiation

Urea 90 150 After Transplanting 340 624 482 195 Panicle Initiation

AS 90 150 After Transplanting 349 583 466 179 Panicle Initiation

All plots received 45 lbs P205acre as single superphosphate

Relative Yield Increase ()

Source of N At Puddling Puddling Panicle Transplant h Panicle

Urea 100 100 100 AS 119 117 92 SCU 125 140 77

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~~0946 I s fW MM- It1444Wttfw W

mtbeft t~t fr~ 0 Omq 01 NoW Otfw wk41 4)

O4f ofSWsowfW W aaoq fm~ MOW 10d ANN W 4 4w fO44o0

StOowew ARM4 WON tffas 0t0ff1 OIPsem Itf

9w NOofb rsrft s fw ~ w-o 4domw op

tu ot t two4 wo of44 At~ut6 04

ftINi 4~

owl 141

wt it14

F woo 04 WFf

044ofmamp 1 g w

h91 WOO owl

ow tl

eIa 4tiamp tbat O14 w44m mAqi~f~M0Il

p itt wt M 4441 f l T aw IlaI~l vweAUl

0 04 M 4 iU4eOW

fi~qr 14edqAs 1W44tMiwty w It 14C

WOA Y~U i44001r i U 4

cb o~t

f~~~~~iqt toitib ws 4 ~t4p6W1 1 i1 a

I~oil~ It w4M

mt4o Ofu~Mampwt i oe 0a 1~4tatlt~ 14 wlpo 0amp p

p~ to Ai~ f

bosom

~ ~ ftfW

W~ t tieiis ptooo 00u14 ie0

by ~ ~ ei~t11i ~~t

M toI0 ww)

mwt Fwaabe

ItM 1 sIM~~slieg~ ~utom sdb

-48

Therean laiictw that It lbs P to th e am lukis

obosomhu rocks 0entk catetas rth Unrtdo costrat frwt) to

ht tse balt s Owosiv as that to TwP it rocks WM bo

fmtbt alteruutiv to MSso gotastte to~ Ik lee used to

ThUAIAd

Tht wMl dt gotmtmlaoti wout th possibility

of law Vhld free ww e1 e66001 4 It cooUt be YgWd Sutt

a4 10 0410 SWUSSM yt$4e TOP wUd predWr A r~ftIf fl~W t

1f f ot P the wuld phosphae rck TWOe viWMW efocitill b

true to low rttos t tsplusatiI P wi 9 Ma Liiam $S

amp4at r per Wforssota Mav two 64eed Wilk elikor It 44 of

P go Mi er 4A bg oftoP aon of tewmrowtni pboophals fwAh

It vwld be polotrd A Wevero wtht Is the jteld level that

W414 gk tko videm dtterem~j o(A 1 the 4~etamp tk~e~t

P11~0 pra~lpj prefer gre4r tuftlter for whlae

of hoaw ppltrstie Mhe to a dloedveaP for The PINSOO rocka

vkth m r II spotted 10 ftewil 4106Me tem

Nub studios we ovsosd o IVA vol gramleid a

forgof wee aMW pbsepbots A fths pemhawe evsielew us

Odellod to detMlee it otteettvmm of 11agotated Stoture of

mmfp MW phapa A (CI) sed graewletod pampAtlti arlolatod Pa

asowcs of P tof ttde ro The wreem proucts omre raGther

pemour~a ot P syag besmti andMi as elt ov so gpamwhr

iuipiqffhate(TS) low twseeo Is eftwiltve Is thet

W41 preeme wae oialain ire post-rItoi effriq to Stanlato the

pud6itt of Irto paddle Wee ofsdlseireplastiq

0 49 shy

lbs partially scldiaatede grawilated Ml prodlucts Vere isshy

toiwdiats in 5tftOvttWS54 betwee wroiPi ad TVP NotV5Ymf to

me coo were they mere twoe $a a etfective ao TIP 00 sipifleast

LVSUMI5 at0 efecto wore toun tor thee produteo Timely dtIampWde

FR (-t00 mmoh) Uia amp~rally oar affective than Owe gra8448r FOampprodt

featal twos o 6 aotetire s I

Nowvero it to felt that sfortber field euprtet vth

hese interials Amd ether typs of grometatodl Wter nre wrrautad

hater ceeuwodh that they have me areec poteatlal toi additoG

e tate wAne the sectte as OtawrI sed bovoloen turther

euperimeste vth few reck pboophar s0d with reck pbophat treated

to sehesa citrata selmtliy or to ha csaducted

Metbir sertes of tbme enprtaeats wae c~edtmcted by IITA

to Ut~rta copal TVP AOP APP aed it at see tecastisix (table 14)

No dot lalt sewseltles teh draw tree thee results simouely em pear to tlvdl bsww they do stwgpt tbat forthew work with

MR to werramid so tbme sels

Table 24

LttcttF Swce MaPlate 06 ieldot IM AWaia CoelsANS at IITA (Ugboda ad Apoin ail sorit) aid at Ike (AUaba s5i series)

1973

Plate ot IP Apinu 5 poundebods A1ab

Ocrol 0 Z94 419 M)

Tr ipl ruprphite 20 349 3799378

Triple vepput 40 M09 410$

Triple 6wp~~b1 4271 4344 42250

Ammotw-ritpophW to 4201 4124 4040

Amosim-rdop~phlt 40 4270 4106 4231

AM tuo-polpephats 20 404 4244 3794

~eai~mpelppepbuI 400)49 4094

Cee m-pbpbt to- 59

momee eph lto 0 4192

LSO (0 0$) 29 1025

Th WPII

- 51 shy

101Y114 tpeM-fI PEP~tbRP YO

1 ~ ~ gmw 1pc~biofl- 9 Kla4v4h

Upia U04 Copfind am Crehout Stet Rpano at (Ia4

rico t IF t rume6 orth~ Caralto phoophale rocl QAR) vaUN pqU41 to

roopon from cmonetrat4 gsporphophai (CIP) who ort$o4 oil k

was 45j itwas tafertor vb protioo4 oil p war OS Ib 4iffer~c

in rtc reepos to X cod14 oo bo ttrit4 4 4 hvsciag of boil p

~ Pt o r11221 0 tP

c theto the rhimecyllndor of rico tots par to)14M4i1 roeoi~t

ed oil emd PA prior to tho ont of an~robi4 cMioe AA~ oIifoshy

nAte bYpot t taet~d tO fC4sin t~r 4PWden0 Of f Ot(tivshy

ofOWailiJtyno o prefla4 all Put that 4t01etoo 14 tvsIk

of the Ott to prvvld a 014for C4m0 44 mI 1 o4sf

EfftC ftPet141on AIAM-0 V f401td 4 4iv 440 Mtft

Aa torfat VampP f4MWfCi4W04wt0amp to 4eturWlI Ot(Wel~drIC ft

Ot f tM6 the flooded Ott 00 14 04019I Pft0uAw Of gAr~s~lr

pkS$t M40b MP) Tw P1101 Piset Prodwie W-e 10M0di Wr04

(10-1) emW 0aretilp ddw01at4 P WAA firom Rrth M~flRU414~$

wee cowiared with fie Md reWim 44104 proo~fo) foruk oith laWItter

I v te-PR P OW1004 4 4 O Wf ottil OW ellt Oo

Oveiel1 the 40tt dmcruie to effetotww Wtollowui Co fme

PR tpaUIB1I ldoltmo PR (pamwlatr) offr~- ArmeuM) 0 orwi

- 52 -

Effect of N Sourc6 and Water Management on Response of Rice

toe Zn- M Giordano J J Mortvedt OP Engelstad and Greenhouse

Staff Several rotes of CO(14H2)2 and (H )2So4 vith or without ZnO

wore applied to flooded and nonflooded Crowley oil (limed to pH 75)

to determine response of Bluebelle rice to Zn Yields with both N

sources veotrgreator on flooded then on nonflooded soil In the abshy

ence of applied Zn total dry matter production vith CO(NH2)2 was

slightly lower than with (NH)2S04 on flooded soil and considerably

lover on nonflooded soil Concentration of Zn wan higher in straw and

grain of plants roun on flooded than on nonflooded soil Although

concentration of P was unaffected by N source or Zn rate there was

som indication that cranslocation of P from straw to grain may be

depressed in nouflooded rice Concentration of N was lower in straw

grown on flooded than on nonflooded soil due to apparent dilution

thereas both X sources resulted in similar N concentrations in straw

at all rates of N application the N concentration in grain increased

with 0 rAse

feSpongi gf(SM to Chjorospodiostte and Related P Sources--

Si Allen and Greonhoue Staff A greenhouse pot experiment was

couct44d with corn Brown on Hountview silt loam to compare the ofshy

fectlivees of chlorospodiosito (Chlor-l) with concentrated supershy

phosphate (CP) Thomas slag and North Carolina phosphate rock (NC-PR)

Oil-prillad urea-phophato rock (UPI) FeA1JMP 20 7 and monomthyl

phosphate were included in the experiment Based on yield of forage and

uptake of P by tvo crops each of 6-weeks duration the following conshy

stui were dravat

I Chlor-1 was slightly loss effective than CSI Thomas slaS or NC-PR

from which Chlor-l wae prepared

- 53 shy

2 Granular UPR was a poor source of P its effectiveness was greatly

increased by reducing the particle size to -35mesh

3 FeAlNH4P207 was unavailable to the crop

4 Monomethyl phosphate was equivalent toor slightly more effective-

than CSP

Research Indirectly Related to TVA-AID Project

Response of Several Rice Varieties to Zn in Moist or Flooded

Soil--P M Giordano J J Mortvedt and Greenhouse Several varieties

of rice from Mexico and the Dominican Republic currently under investishy

gation in Puerto Rico for adaptation to upland culture were compared with

some established United States varieties with regard to Zn response on

moist and flooded Crowley sil (pH 75) Chontalpa (Mexico) Bluebelle

(Texas) and Starbonnet (Arkansas) were most responsive to applied Zn

Juma (Dominican Republic) intermediate and Sinaloa (Mexico) and Calrose

(California) were the least responsive The Sinaloa varieties (Mexico)

appeared to be best adapted to non-flooded conditions whereas Chontalpa

and Calrose were poorest Concentrations of Zn generally were higher in

plants grown on flooded than moist soil

Pattern of Growth and Zinc Accumulation by Rice--P M Giordano

J J Mortvedt and Greenhouse Staff Rice plants were harvested at weekly

intervals from shortly after emergence through maturity The objective

was to determine the rate of growth and Zn uptake by a Zn responsive varshy

iety (Bluebelle) and a less Zn-responsive variety (Calrose) in the presence

or absence of Zn applied to Crowley sil (pHl 75) Dry matter production

of Calrose was linear with time of growth and of a similar magnitude until

heading with or without applied Zn Bluebelle followed a similar pattern

where Zn was applied However in the absence of applied Zn foliage yield

was reduced markedly

-54

Uptake of Zn was similar for both varieties whenZn was

applied Dry matter production and Zn uptake by the two varieties

also were comparable when Zn was applied However yield of Calrose

was much higher than that of Bluebelle in the absence of applied Zn

while Zn uptake was only slightly higher This suggests that the lesshy

ser responsiveness of Calrose to Zn may be due to more efficient utilishy

zation of Zn There was no indication of a greater demand for Zn durshy

ing reproduction in either variety as was suggested in earlier greenshy

house experiments

Response of Upland Rice to P and Zn--P M Giordano J J

Mortvedt and Greenhouse Staff Several rates of P and Zn were applied

to Crowley sil (limed to pH 75) in factorial combination to determine

whether differences in rice growth under flooded and nonflooded soil

conditions are related to plant nutrition Although straw yields were

slightly higher in nonflooded rice receiving adequate P and Zn grain

yields were higher in the flooded crop increased rates of F andor Zn

did not result in equal yields Except in the highest Zn rate (75 mg)

concentrations of Zn in both straw and grain were higher with flooding

Concentration of P increased with rate of applied P and was higher in

the grain or flooded than upland rice at a comparable P rate In conshy

trast concentrations of N were lower with flooding due in part to dilshy

ution from increased growth

Rice Response to N and P in Flooded and Unflooded Cultures--

G L Terman S E Allen and Greenhouse-Analytical Staff Rates of

N from 250 to 2000 ntpot and P from 0 to 1000 mtpot were applied for

Nato rice grown on Mountview sil and Sango sicl (625 kg of soil per

pot) Market yield response to N and P was obtained Yields of straw

- 55 shy

total yields N uptake and N recovery were higher on unflooded than

on flooded soil cultures Grain yields however were slightly higher

with flooding These results indicate that with adequate applied

nutrients especially of N rice yields without flooding can approach

or even equal those under flooding

Uptake of N P Ca Mg and Zn increased with yield response

to N and P while K uptake decreased on the Mountview soil Concentrations

of N and P increased with applied N and P respectively while concentrations

of other nutrients were diluted in most situations with yield response to N

or P

Results from this experiment show that amouats of N applied in

previous pot experiments for rice have been much too low especially if the

crop was grown to maturity

Response of Corn to S and N i UUASand Urea-S--S E Allen

and Greenhouse Staff Three greenhouse pot experiments were conducted to

measure response to S and N in ulfur coated urea (SCU) urea amonium

sulfate (UAS) and urea -S as well as estimate N losses from surface apshy

plied N sources

In Experiment 260 less than 20 of the S mixed with the soil

was recovered from SCU or urea-S granules by two crops of corn as comshy

pared to 45 or 80 from flowers of S or Na2SO 4 CLop response followed

a similar pattern

In Experiment 260-A N sources were surface applied and alshy

lowed to dry for two weeks before incorporation Into the soil and plantshy

ing Recovery of N by two crops of corn was 77-82 for AN an compared

to 37-70 for urea UAS urea-S and ICU Thus n this experiment loss

of N from urea did not appear to be re~dcud by light S-coatlngn or by Inshy

corporating S or AS in the granules

-S -

I xbprZnSlt a Wtch aU Meyto 0-Ai Wt f9r

higher reermo teOrtOrs cOM reSpWNO i r0100 Of N w

not oaisteontly related to sewe ot N In edl tust 0 ioltiUe Lim

lo in VMuwpped evlmtUTS 48 merind by seirest nte appresOehe

501 for uroa as cwarod to 210 for urea peepha

Rus- or Upse to LoAmIl34I a AriMed bI Earl U

MW NOWlsIIsIr-4 L Toman 5 1 Alln and eesese StNf rio

row on Sawg did (0 tpot) We 1l0l0 Ws feritiud vith 05is

of Npot mixod with the 6011 as aureCA NiAO) 1 Age god At Ures

was also itcluded at rtt t 05 10 end 15 of Upee Theas trealshy

onto were followed 4 wpdrsetago of U s AN wre 4C 10o or at I3n

Weeks toulin up to IS pot

A soil application of 10 pot rosulvod to the maim yield

at 4 weeks Tio4 sad percont prottis t intre raite tncreased rftishy

linearly with U applictalien IeseeItally all at the m iNd wit

the moil w domitrifted after flooding Grail end straw Ilelds vere

highly correlatod with tiliriag and vlh ubers of gralm arl

The results Widicat that 0$ to 10 a of Upot as orea or

NN bsuld be sied with the oil to stilate tiilrir with adshy

ditional 0 topireased later to increase grain lIds mad protia cmshy

tout

DIVISION 54- FERTILIZER TECHNOLOGY AND USE

N$eumWe of Mt5p4Amomd 1k PindW hswk4PhI fl fRw cW ims we

Jmnwacr VW owm m

a~~00 - 0 6 A-~ -~~ PN 40OMOM X 00 Wolm n moo mot $Pto4I 4l 4 W

1 -0 Is vom omoo ~~o - W1 sfw 4E00-aU

WI pw shy-M Iampeo _10 00 mo N - o wo limoshyM~m a UAa oomw W0- -0 f40 44 MP 0v~f04i-lsm 0 PA 40of 0 0 W -W ov a Wo 006

-n-t -4adf -m W ftf

9P~~aw otom i ow sm li ilia it - ~0~f 11 40S adob 11-11 __ 9w

i A ~~~~06o ~a A VOW 4 WK-ok rie Ww -0 no 4me

00 to- W 0Nwo ww AO t

-t umi om ftaw-0

- - lh -i N N iiSolf so -ma w vow -mv__M

-~AdAjA- 44 ow 0ma 0MAW a war -mo d0 00 M o WooP 0

0kR N4 a~ow Mf o

- -kn Am C4 pos 0 WW -I

to$w formoop 1 so

Qm0fte Iwo 00 SAtow

a

WPMaa~I m ww

lvZW~16W IT

I

vt~~ - foa Gom

r-7- tw

A ijdMA~ trMO

otait m adtoo iMOaiq

sMs aIwO tP- owWIs

mU MW4 0e S w 96 lo ow- CO=

I~

bq

-- -P~~~~ -- M S um IN 0VSAww dvIs0O E0 two I 41

OV WNA w N$ lp It 40A 04 ON w 0^ 0 PW1t~~~~~~~dap~~ frO

Is WAV OUw Af 41W 0A

1A 0

1o wI0~ WSW adWOWi

MOM 4 so mo 00A

w m wO~ WWF __ootm

Wm^~~~~~~ ~~ A tookoto 00wmf

M~~~~MOt 0f O

040 wd m40 Awowmm

bo^ w

ro a W4

~~

womb ~mmnt I-VI~ bp

5i irn0 pwm k~ oiuwe OsMn0 Wsw e Wr~m mw6

_______Noon_Iamp__ arn ag bos m W we ap

=ib ad a $4Ws Om ThSU

mod m m406mi 1m towir - m bowI~~~AV UPuiWd a04aup hwu 000sW~11lito -- o ~ImWq mow~gnn w a ho emotwi

4~ 49akduemg6momm ~ do nedOwrnd~ o

ICU wONMOVAON w4wWR - - o 44 O Tha 40 pu4 am

hum 11 is 4111 s - sg am VW f wq 4WuM dhCi m ehamv alpso 0

-w No memwiauu so-s 1141 -f oer wwn malow Wufmmm inM UCd m I a to dip 90

- ~~ w emw euIv oflme em ~ ed~faiOeWMOWleA fC~ dim~e4s- 1um00 s uwos w siwp 3 0V es wiiu d um w

aram ad as~6 ma pgt -oI A -$-d r00= m PW Of

ff~~~- am diwda Vs Wow at 4g eltpowm woo OI teeMA AMamdmOMisan A d1 Tm WNW m4 uwwemm mmmM

Aa It mom A I b 0 ~isi ~amp~V5on m ad No wwho 1 $IV Am t t~i mmOwm a- S Am im spwwmft KV-b Osiswvn wogie

opoOw suf No~ Ow MW MCI pt~bi asiwhNd bl-d muim of woo w NN

toI4 0 06d 00 wo A Md N WILSAl DuIKWION oo A Nw U am ONq ep

ow VAN pmw amp4 li a4 WdUb p vw sopwaft a-ftgw -ee theptd OW 6 - a

at MW em matshyW M offm of4 W twampwmwausoo wo asdm65m Auamp Ahbwu in 4ih asTal ON~ al oem IN Maie dmAd A a own did ofe w17 I inM mimman Ofd ofimruwf gas Pius di aMe Kwe auw a dow iNPOOIN tmo a SO$SO~4W

MWaSM BT ALI Mh USIA UW MlO RMC i WOW TW A-~ka ad 1 1 li laiiII111I

0 -6 -1 -- - -- Ie-- - -shyis

101 ~

alm~ sas ~~~ ms a a~

ase appuadmen 44 ea ad semk Who pm4WWS lowftsIU wo WOMO dobowl ICUSJW h

A Poad KU apbos as dw sileft in as a aWhps k asIU__

pro alfp al 0 WN Is obaml~ of th es Wls pouvy Ofts oeWMed N

$ae fapree ulesaseup IfIwotohaffe St

40WilinAn 06 kw Ma ho 00 e IW aftakrw splerefAnhffsb m esmem

I$Ow Ip ampMI pasi 1ead eu an Toud 2l

Widj 6vi of V46 745WI KU waso-W im Wow 0 is610SWAOMMwasa to t

VAp 1Mampd KV ppu~s dw whaim $i a a los Al w W

Ib Milvo urns of OWe d- musA as h~ s a IuIow 8 1 ue ip

-Wlidswf of 4 ofatsIW5vsS d M M5 i RSa pm~daps In ampup 1Powworw rue hevi A b

el eas goileN ruseW4 wo duffeeme bWOM isttouwi

14 gnp40 woSalrw 11ylo amreu Mwb Isevlow roosmN~ahIt s 60 W ~tsmAIM L n ~ ~~ ~

MM I PWrawA = rMla yowIeM oa

eUW as ymlh OW by IONamph avWlbl N The mubsr 1MM Pude M~ IsA aemOWeld

IWOes A rspeas Owed ai udlWwease

por bre

wals rIs O touprua KU=plaINamppNOMeses a

W UWhk 0 ASOoml ft A poWsdvutA adesae of amr Wns ai A 0r- 1ampdd Oehs IuRawy NO Pue podllosWewwe gmak asmpnle by dMiss is amle OWN pet -W yid I MuC)ad ampAn (WiplaeT16s mOW aOW aNo fhr ft ymIed------ obealud w3t 0 OW 40IsA a VM bpR ofthW d saw ns m aI efes R 24 ad 7

e 1 d

Ii

Iw NO ~sp 44I0 so

~ ~ I $4U tml

Tile 4-00dw x uiampOW74u 0qee of

_____k _ _ shy

~ - 56I 5

-f

irenY w -a

Tiles I sed I thm Au do sel oeppled upaoIks WIM0 0da ispI amd us Ou s 106 kg

h Eaap 8n 14 sMsa of abw~greuad PU Pau WW 1 u itb IUKho 0aaphelem s 60 Otarlmmh At ~ 0sU Ishiseoo Cook oiA N uiplasu mAasslaly abess A leel

v doese a WKWye Is ks Nha m 6 sa4to dafo aONmuw The appee swm Wsssof adde N4 alalaed by vuMb ifaa W C Was sekilumganSro Is

bs eabI wish as aVWWa uwewy nap (f5s)f ad Mashes reaMeY valaes of 48 0 S414 CWm

owdb imto US Wh s vs sf 3I mld 54S fro 2 aMd 3) A A

valves a hevwae u Iar Walh basl oswas dhe uwpatr bshava of

tb~msusasl appkausu of ofta sede s have aoweN

TOW opl taoe for AieweeW 4OsmWMbas Op peas As Tabl 4 sling sob Os awowully eom grams Piel level Thes oeulam Ma sed as IM

-02

792 60L WI W A)49R Pio VOL 37 197)

primS o r OeampAd WU toa Them fl~ w At NOSSe earno maisslea Ia N he mOWamplIO yik ampWd IMe aampWmW OWa Owe wa UMs of KU to 41 Oke ampWiiIamm be dkrnety ewspokawleM(a s8 te camtd wie a eapmoe by TVA pavw ltoi NA poundrmdaka4us vrimeW460 o to ilkidm ofWW (Mtemas MuOwe 1973) TVA mwi bawld on soi ficedims IampWp seg rudwiv s~s0abet ke WNmdoe ON 01 K Is12 NOSW ie fssewnmu Ie I QvaaIi rowp IMA) f9

)amp m lodk byO voebmsaIS8OpeaWfrats 11 OWNmi a I a W idisod 0 81 Now 111 nindat Wm fysmpseaamp (If tsO tUmtI IsM $P shoroV4mmo knflkvnf (foOdme nuw ae Ow OImstwe in SM pnmm8 af tXm 10 114PIS kequoian wo Mpfii

SC~po umd spop~o VWt alm 4emWal 1 4ink PCmirsra M 1 ad AI 14bmms

1MM Ww Even to doe shw wisht b-o -Wamp Ekb fed rbaimpal of14~ Am Smpound oS mv fAaMda

MGMe -M4 Wg kmuwadM 1Wr wih SCV4 Psmuck Wff It dlL Wm 1W led 0 1 oo teeA of aiwaisme aweeoid h

1Kach Vt V amp4W ILK t)sa 10 Nareps vm This ndY ub thee hbow apiptomuasa of gulfu-aw~sd of Cup lP~~tamsl wi(i

Woeo of woo or mlm Wmiot InIasem~Wsy (heede 6Am 0 F- ad PAicv IfM tsoPm 9W famp kw~is 04eet The r4 ggm I ampbpiIs OnwAu 4nvmkstm v PAraem A4fshy

e W d inSIWfh sil $ad doke IaefitV twoer) 1 Te to theo owie effu so booJ imik WOi 100 N

-d

Is re4aled uIwq~e~w Aueee atofurnw di Capsnm ptopeatls is a oommm eiws to 100 tom of 04404man d CtdUW 4M Anw K~a do Aamp apowee WPUaN powu eel H pae iaaa thAi SCUI isWW owr hmem ISsuppl N to the li ieee F A IM1 Nampa Obo~amie m

41MB ~ ~ m ~ ~0 0-- 0 140 The ffsemn of food Nn else9~e(Ud~ ~ ~ ~~ WooksaS eAWw pjed of ho~raw of IU effadam vfdva oft xhj0I 13iAl

DIVISION 8-9-SOIL MINERALOGY

Amorphomw CeetIup en XmWra Ssrfmls

L C koits Am~ 0 tmmkaAf

ommp A faieiaAMTRACT skiwe lo nW ampM sm wi4h

Walo by a onMm I dmivid hseidm6Wlk W~edesie s

peuiieles as is s e wpwigstee eded his S -em -om 0641 h4 hisW1mWOWb~ bfem peess Wimm kv Iee

Pa~~~eakr4awiS SeUeeiNaiA WOW 14e

PWWWW t HW f hea~I~~~~~a 0th

kog Ii ampI b 1111h1atAmOem aid itsaere~m-aelmoeug toolPe aal 111W mWa Wisg ag so~ ti~Wo booviot65k Th eme Iua 1111411uiwon it es 01000 AW~CWS ~muiseeteqqsheer21111 ionev

oO00 llb K0 ibad~ ~~ doj 140WI s o mimdW um

WLIMmAmMVL 1

lill mi oHow al of a be 1974oyais4gamm wsoc wwo

rdy i of OMAN toblind id sh os 00 IN bei m us salqs m kid Vw 1 a0Msw WFW isms waf e eeiWei he-4~~e gsa dulsi

os 0aMW ofmu WA l aduWs~Ib rowuvvl3maIpm s

CaO~OP aw AlNomI 4ornomd to9 IS is -l O SI g4he rpidyThus whim m dowu bWa 0 m m- ei u

d m M 0bmSaImu M-1 ofM6 h Intun to 7I

aiba maush WAesshwn~u9dSg a osusLwpI ~ v m

M PolsdAvoWdw Ons pugm~ low iwLW m We

of~U -a~ mo uNo

0401ts of 40

A e mun5d m i vvamp sa s ow bftIS i sa omdIs a w

edi1 hswopmo an ag am Iw anom erlwaPASneooie bnwoM po

o ~ do=lr 3s fluACWoSM Owaa VolM Ain b 400b adW g o as amob ofrMOWS A oo eWmaa ow $wofdi60 ow - ema

-v K Vcon l ap ad md ld KU lbs PoabumwA od w to domi a bembe 0b lt $014 i ampmomONo

4st diwemmSod i 6o pa P)ameakiksm4 m 04M t 1iV vs 0606 o IS ft dopsss of q madl w I10000014 t 44hs

arbs awasm 00 iztv Am-~~~i u5~ms ashu is byw

e~ihs diu~wsm ~phid W A0)ad Lobe d mi-~-- 1) 14 hald

bob~wh do is poPbe~mueus l to aVE tumad 40at iai ka as m

bdisc shmm Ammmd a Sm ofd~~~~~d~A ~ a~m olWshmo

OWNSrilgf ms as

Um~~srTmws~of 4 A ad to wy mis itm voW

IN~flA4T ampMww IV Kwo~t M1CI I POWMAIS amV VARw d01M11 W V

e~~Pum-p -f AOACoe~mfmmdso isedp Am PApmi sk adw Wsk m~ o P4 m

- omlos r umIWO1in pw

lie Uvplist i piw S p wsmoW N of t as so in~tabo 440 o rodgAsect M4Ammd meM ii INAq10ed~ Pib mdWWeiW 1w -w emit TU UFm 6AV 0W A fIN 00~ lb 0PANNO 4 drp OW~It~Oi Ofme _____f WACMW0IN WMVsol~lmO ft SNAO 40 do1Si - m Md y e b ii m

of of~phaow tw bmsdf toamplboe

AjflsutomW C1D-pCTP AD mSmZLT op 1 m ow ts Wdm of P om M

IaM 0t sdw a wn a8duws i ofV -w Mm P16I4 TWO a ewu i an

ov4mnk wsi 9 Mxfeu~i am emwm ismi0wmd fq W No ~~ - f mug Aitowe eutlkowbmTV is

amppowftdmi TiM 0 Tie OAA mo p)a Mwomoi dOn4m A)w

MW 0 604 0M mm yaM 01MWOfdi to tA0 M OOAW uinw OSOb

ap is~e I the ampo A A Mwof ~Do toit op aenu w~ifiOimem~ MAN ampW)

ItsAO se Y lieowawo u~w pkow-W1b pwf on a C Nohkw is f 0o1 s do~omW C mmU4

owud6moeft 4 Obind PINa~e

~4~~wreu -A---I ad

fit~~~~O 114 4 t I mMsmm m~

im ^aim4 Nomod 06maw ee Aist em moom a rA No fmiEo of emit

~ -0

65

0IL CL OC AMXR PROC VOL 38 1974

)aT1 S4I104 ow Lusanll Tawng isa tall Thai variety known for beingIwo nonshyi s s ) sensitive to photoperiod A split-plot design was used in

S e e these euperimeots with 4 rates of P (I1 22 44 and 88t i V IV k of Pha) applied a main plot treatments and with the OF It sourMes of P as subplot treatments There were two checkS plots in each rmplicate The extra check plot was included to permit the application of fresh TSP standard Jor the

It- ti 06 + i bull fa succeeding crop the p-4me of bi was to permit accurate d awrnwal of the mdual effectiveness of the phosphate

ftinSUbI rock The P fertilioers were broadcast on the mud andthen Worporald In the soil during the last harrowing At

whM N both On ACS indx ampM time of transplanting Immediately before the last harrow61t (4j 5 4 01 P s 3Mm o Vallonal in con n 100 kgha of N as ammonium sulfate and 33 kghaWO Of Spews ampm lIW thaabe rocks do ACS indes of K as polium chloride were applied A total of 40 wa in prepw O do ctih k otent kha of N a ammoniunt sulfate was applied later in twoir P The hew oNed amp wM W for 5 of gw topdrossingp with about 5cm depth of water on the plotsvV I aiOMveffeOctveee Three to six ldayold selings pr hillwW the ACS idex were planted00OWW wia Oft fo an c irNk I p Coen 20 by 20 cm part in straight rows Hand weeding was used

and insecticide were applied for Insect control Grain yieldw was masared by sampling 5 ml of each plot excluding border rows The date of heading in each treatment and theUNiN d pbM W Weks rin tOW USA UMe In Tale yed componnts at hafvel were also recorded

I filM rsperMS esOM kdwdua 1 t ab The average yields of ough (unhulled) rice for botha 84 OW O 8uo 4 Thala TM was a locations are ploutel in PIS 3 for the first crop (1969 wet

owou thRM seaso0) The Veamps yield response was obtained at Klonge (s) W lDtO t Of dMa of1tw W d l R Luang however a 4ute satisfactory yield response was

~Mk ^d TVA UJSD ad Kd UnIveS obtalned to applied P at Bangkhen as wellXUe LaM e R qwrw Ims The sod was do Relative aponomlAe effectiveness values were calculated

VOW (a ksA w edmwL t Poesesm h Vy for these data and am presented In Table 3 The valuesdAY buo if dIe ouh ne Pee wtk a Mlak vow 1009 for th first crop are plotled against ACS index in Fig 41 This Im M i6ti l 4bNd IO a0 O mkarnk for both locatio r relationship was linear for the

11400 ThCpH 0( lb pW IW 01 th UpeiaW so Sanodion location and curtiltnear for KIng Luang The was u i 4A sksamp lMaor nrusio model amparounted for 81 of theAmO$MI Aw jAAsue Swim T1 Snh Wd variation In the AE valu for Bantkhen a square root

Mems a Iw iv fern alh$ sedm haowg dayNW W t he plAL At tdo M tM aso W s as ctminued throufh eltaM t Ofpof -le lse wo am P OeNI VeOpls 1o ealluae tI lon4erm MIdual Offccls

A on W isset i a wse to hsh eapeel of these ooihss t ocks The baagkhon experimnent was letmiaI1DlVemisthis is a w hulu Lo g Tasug ia iasael aft - Msd residual Ves will be pr-Om crok TheseTwod esewm

SWWo

A

lP~U~7 ISIIPe1iuIWN e bsedisssin ian ghth siaoelalbe

984 0 6 O O - M s -s fWPas 11eSft W d Uo al a o

o

S4l~ lIIII I~l I 1f fl

( +

+ + + m + ++++-

++ +(++ + ++++ + ++ ++

- 66 -

ENOIMLSTAD ET AL RESPONSE BY FLOODED RICE TO PHOSPHATE ROCKS VARYING IN CITRATE SOLUBILITY

I I I I j0 I I

BANOKHEN BANGKHEN

pH 56 6 - 0o

TSP

NC

5~ ~ ~ L o 4 - -shy

4 ] - --------shy04

6S

|0 III 2 44 8r 66

I I I

a 1KLONG LUANG

pH 46 z KLONG LUANG

TSP Sc2 NCFL(N)

5 FLIC) J0 TU

oshy

4 ~40shy

3 bull eM0

I - I I I I I

0 II 22 44 88 0 5 10 15 20 IP APPLIED KO HA ABSOLUTE CITRAE SOLUBIITY INDEX

Fig 3-Yield of rough rice at Klong Luang and Bangkhen Rice Fig 4-Relative agronon effectiveness () of P sources ploz-Experiment Stations Thalmand as affected by rate and Source ted against citrate solubity Index for both Thailand field ex

of P applied (crop 1) periment (first crop only)

regression model accounted for 97 of the variation in sumably resulted from crop uptake and reaction with the RAE values at the Klong Luang location soil to form less soluble products Such effects may have

These experiments were continued during the dry season been more important at the lower rates since the two TSP of early 1970 to ascertain the residual effectiveness of the curyes converged at the highest rate of application various sources applied to the first crop No new P was These data from KIong Luang indicate that (i) residual applied except for the fresh TSP standard mentioned effects of all rocks except Mlcwuri were substantial (ii) above rhe experiment otherwise was conducted in a man the relationship between relative agronornic effectiveness ner similar to that followed in the first crop of the phosphate rocks and citrate solubility levels was

The response to both freshly applied ad residual P was largely obscured and (iii) the general superiority of TSP marked at the Klong Luang location and marginal at over phosphate rock in terms of effectiveiss persisted Bangkhen In fact at the latter location the response was through the second crop so small that little can be said regarding residual effectiveshyness The yield data from crop 2 at the Klong Luang DISCUSSION experiment are plotted in Fig 5 Greenhouse and field data presented in this paper show

Relative agronomic effectiveness values (Table 3) were clearly that there are substantial differences among phosshycalculated for the Klong Luang data using both the residual and freshly applied TSP as standards It is of Interest to note that the superiority of TSP over the phosphbte rocks Table 3-Relative agronomic effective values for field experishyments in Thailand persisted through the second crop The main difference in KlowlZmlnql~the residual effects is that with the exception of the MIs- s Crop 1 Crop 21 Crop 1-shysouri rock Ihe marked relationship between citratr-soluble WoiCarolina yl 59 76

phosphate rocks and RAE had largely rds norh) a 64P conltct of th Florida (eqlral is 6969 6

disapipeared In this acidic soil (pHi 46) P would by this I14o 69 63 40 ToonesS 31 65

limo be supplied by Intermediate reaction products In addl Missou 0 o lion to residues of the initial spatlte Ts P o 2 o 0

The TSP applied to the first crop declliv-d slightly In campIafcmWataesr e id ofeuhuloefor 22MA rates of PtColeouattd as aba u tlte td18 kS ratesp dlverage yield tM868 to 22 44

effectiveness relative to the freshly applied ISP This pre- of d s4

A

4

- 67 shy

-SOIL SCL SOC AMER I

KLONG LUANG CROP 2

Si 3

eN

TAPPLIEDKGHA

Fig 5-The residual effectiveness ovarious P sources for crop s compared with freshly applied TSP Klong Luang Rice

Experiment Station Thailand

phate rocks in terms of agronomic effectiveness for flooded

rice Further these differences can be predicted by means of citrate solubility or by the ACS index It appears that

the latter is more appropriate where the content of apatite varies among phospiate rocks The most soluble phosphate rocks approached but did not actually equal TSP in limit-iuig (maximum) yield in these experiments regardless of rate applied This agrees with the results of Ensminger Pearson and Armiger (4) One needs to consider the defi-nite posribility of same yield loss in zhoosing a phosphate

rock over TSP such yield losses must be weighed against the lower price of phosphate rock The explanation for such iosses may involve concentration of soluble P in the soil Khasawneh and Copeland (6) suggest that the growth rate of crop plants is a function of P concentration that can be maintained in the soil solution If P concentration is limiting or inadequate becawe of a lower dissolution rate of phosphate rock the growth iate ard uiiimate yield will be diminished accordingly

The RAE values bascd on yield increases reflect the agronomi effectiveness of these various sources relacve

to the TSP standard however these nould be supple-

mented by an economic analysis before rational choice can

be made The following calculations will provide an estimate of

the rclativ ecooomic effectiveness(REE)

Y t Ps aXpatREE -- 100

vahtercks t sphate or e b i- eor

Price of TSPkg fo

be Price of PRkg P

PROC VOL 38 1974 leO

90r

Wsoshy

0

60-LUSEPHOSPHATE ROCK

00 10 20

PTP PR

Fig 6-Relationship between relaZive effectiveness values (RAE) and the price ratios between TSP and phosphate rock Such a figure can be used in making a choice between these

sources

If REE exceeds 100 in this calculation the phosphate rock would be preferable to TSP

The REE calcuktaaa wre used in preparing an indifshyference curve (Fig 6) wherein RAE values are plotted

against PTsPPpR ratios The cu~rve itself connects those points at which REE equals 100 When exactly on the curve it makes no real economic difference what source is chosen After choosing a suitable price ratio one can then project upward from that ratio knowing the RAI

value (or estimating it from such data as shown in Fig 4 using citrate-soluble P content) one can then choose the source on the basis of both agronomic and economic conshysiderations For example if the price ratio is 25 and the RAE value of the phosphaite rock is greater than 40 the rock phosphate in question would be used However if the RAE value was less than 40 TSP would be a better choice There are indications that if the P in the more soluble phosphate ro~cks (North Carolina north Florida central Forida) is less than half as expensivz as that in TSP these rocks would be feasible altereaives to TSP on soils similar

to thoseused in Thailand This analysis does not take into account the possibility

of lower yields from use of phosphate rock In addition only a portion of the various yield response curves was used in this anlysis ie up to 22 kgha Beyond this

rate yield response was much less pronounced it could be argued that at less than maximum yields TSP would produce a certain yield at lower rates of P than would phosshy

pow ofrock This would especially be true for rates applioa example at Klong Luang 5500 kg of

rice pcr iectare could have been produced with either Ii kg of P as TSP or 44 kg of P as son of the more reacshy

tire phosphate rocks It should be pointed ot however

- 68 shy

(IIKIS amp YOUN( ARIFICIAL WEATIIERING OF OXIDIZED p[ll- IV

that this is the yield level that would show the widest difference such is the advantage of hindsight

Farmers generally prefer granular fertilizers for machine

or hand application This is a disadvantage for the phos-phate rocks which are normally arplied in finely divided form Recently experimental quantities of granular urea-

phosphate rock mixtures have been made by TVA Results of trials with these fertilizers will be reported elsewhere

LITERATURE CITED

1 Armiger W H and Maurice- Fried 1957 The plantavailability of various sources of phosphate rock Soil Sci Soc Amer Proc 21183-188

2 Bengston G W E C Sample and S E Allen 1974 Re-sponso of slash pine seedlings to P sGurces of varying ci-trato solubility Plant Soil (In press)

3 Caro JIt and W Hill 1956 Chard eristics and fer tilizcr value of phosphate rock from different fields J Agr Food Chem 4684-687

4 Ensminger I E R W Peirson and W II Atmiger1967 Effectivencs of rock phosphate as a source of phosshyphurus for plants US Dep Agr ARS Bull 4112S

5 Engelstad 0 P J G Getsinger anid I J Stangel 1972 Tailoring of fertiliers for rice cnnece Valley Author ftyNational Fertilicr Developmnent Center Hull Y-52

6 Khasawnch F E and Jane P Copcland 1971 (otton root growth and uptake of nutrievos relation oif phosph

rus uptake to quantity intensity and buffering capacit) Soil Sci Soc Amer Proc 37250-254

7 Lehr JR and G H McClellan 1972 A revised lIbora tory reactivity scale for evaljativg phosphate rocks for direct application Tennessee Valley Authcrity National Fertilizer Development Center lull Y-43

H Terman G L S EAllen and 0 P Engelstad 1970 Response by paddy cice to ratcs and suurces of appliedphosphorus Agron J63390-394

DIVISION S-9-SOIL MINERALOGY

Artificial Weathering of Oxidized Biotite IV The Inhibitory Effect of Potassium on Dissolution llate

R JGILKES AND R C YOUNG2

ABSTRACT

Rates of dissolution of oxidized biotites in OIM 001M ICI are severely depressed in the presence of IM KCI The amovnts of Al Mg Mn dissolved in the first eytraction are similir to those found without KCI however subsequent extractions remove these elements at 10-20 of the corresponding lICI rates This effect may be due to a decreased rate of vermiculite formation thereby reducing the effective basal area exposed to attack A decrease in dissolution rate with increasing ferric iron content was still apparent in the presence of IM KCI

Additional Index Words X-ray diffraction infrared aborp-

N EARLIER papers of this series the tole of biotite in soils

as a source of both macro and micronutrient elements

has been discussed ((Gilkes Young and Quirk 1972 1973ab) Experiments in artificial weathering uiing as va-

riety of extractants were undertaken to determiie the inlu-

ence of oxidation of octahedrally coordinated iron on the bull release of structural cations to solution The results of this

work demonstated that biotite behaves anomalously with respect to the other common ferromagnesian minerals found in soils Oxidation leads to the development of a high degree of resistance to cation exchange and dissolution Several authors have coiwludcd that decreased rates of K

Contribution from the Dep of Soi Science and Plant Nutri-tion Institute of Agriculture Univ of Western Australia Ned-lands 6009 Western Australia Received 29 Sept 1973 Ap-proved 8 Jan 1974

2 Senior Lecturer in Soil Science and Research Officer respeclively

replacement in electrolytes shown by oxidized biotites are

a result of the inclination of structural hydroxyl adjacent to newly created trivalent iron or vacant octahedral cation sites (Robert and Pedro 1959 Barshad and Kishk 1968) Gilkes et al (1973b) suggested that decreased rates of disshysolution of oxidized biotite in 0001 0t)l 0Af CI may also be due to the presence of inclined hydroxyl In this case a smaller surface area external and exposed intershylayer may be available for attack if K replacement by hyshydrogen ions occurs at a slower rate in oxidized biotites

Gastuche (1963) has shown that significant dissolution ofthe (IIM) biotile face may occur and it is easily demonshystrated that the proportion of exposed (001M) face in weathering biotites depends on the percentage K replaced

Rausell-Colom ct al (1965) have shown that hydrogen ions act in an identical fashion to metal cations in K exshy

change from micas In particular exchange c-f K by hydroshy

gen ions will be terminated or greatly reduced by high levels of K in solution Thus if dissolution of oxidized biotite by

acids is carried out at sufficiently high K levels to prevent vermiculization any differences in dissolution rate that may occur cannot simply be ascribed to differences in rates of K replacement The following results were obtained from such an experiment which unlike the experiment described in Parts I and II (Gilkes et al 1973ab) does not attempt to simulate natuiral - conditions

MATERIAILS AN) M HIiODS Further subsamples of the less than 0 hiotites used in K

excherandbaid disoo tu es (G iles e9n K exchange and acid dissolution studies (Gilkes et al1973ab) were used in these experiments Preparation of sequentiallyoxidized biotites without intermediate vermiculite formation is

Page 3: I70 - United States Agency for International Developmentto ascertan, but tgl.eetad, 1, L,. ("Tailoring of Pertiltiters for ice,'" TVA ulletin Y-52) states that the staft of IOi has

TABLE OFCONTENTS

Summary 1

Potential for Use of Sulfur-Coated Urea 3

Background and Objectives of Project

Scope of Work o bull 99

Project Plans for Fiscal 1975 bull 11

Engineering andDevelopment bull bull 0bull11

Agronomic Testing and Evaluation bull bull bull 14

Economic Evaluations

Workshop at Muscle Shoals a o bull bull bull 19

bull bull o bull bull bull 18

Literature Survey bull bull 19

Agronomic Research bull bull 21

Research by Overseas Cooperators bull 21

Greenhouse Research by TVA at Mlcle Shoals 51

57 Appendix

58Performance of Sulfur-Coated Urea for Rice In Peru

Response of Flooded Rice to Phosphtate Rocki 0 63

SUMMARY

This report is a project report covering the period from

December 1972 (when the bulletin Tailoring of Fertilizers for Rice

was issued) through June 1974 The present project is our expansion

of the previous project which was restricted to the use of fertilizer

for rice in that new and improved fertilizers are to be tested on a

number of tropical crops In addition to actual agronomic evaluations

of new materials increased emphasis will be placed on developing and

demonstrating methods of introducing new fertilizers to farmers so that

they will be properly used or they become commercially available

Testing of sulfur-coated urea (SCU) will be expanded to

include a number of additional crops such as sugar cane corn cassava

cottonbananas and cocoa Additional experiements vill be conducted

with rice to more precisely define the areas and conditions where the

use of SCU will be advantageous and to introduce its use to agricultural

workers and Industry representatives

Additional studies are planned vith rock phosphate to evaluate

its o(fectiveasee for direct applications and to study mans of increasing

its phosphorous availability by relatively tople muthoda for local

gomo aitionalV06 will be cOndvct44 with xronutolt4 msatvres of vorious

aterltele With rock p Wephut

smtprfallairy wVr to Ceonepl44 001teitn w4ltr g fut

of W41114090~f vowmllo It to felt thut ~ Ot 0~t ea I fo

0 setvl to 011folf OW 10offft 4 Aiee441bj ftiIOt

hepll4t 0 14W l0a khef t~ l to1141l(0

-2-

The need for fertilizers containing secondary andor microshy

nutrients will be evaluated in several countries where deficiencies

are known or suspected but where no commercial sources of these nutrients

are presently available

Additional data has been received from a number of countries

pertaining to the use of SCU for rice In general these data tend to

substantiate those previously reported in that SCU is a superior source

of N for rice grain under conditions of intermittent flooding but that

it is no better than conventional sources of N when conditions of intershy

mittent flooding or severe leaching do not exist A discussion of the

commercial potential of SCU in tropical agriculture follows this section

Insufficient data are available for tropical crops other than

rice to warrant any general conclusions at this time

-3-

POTENTIAL FOR USE OF SULFUR-COATED UREA

The major portion of the agronomic research reported herein

deals with the evaluation of SCU (sulfur-coated urea) as a source of

nitrogen for rice These results generally confirm those previously

reported by TVA (Tailoring of Fertilizers for Rice TVA Bulletin Y-52

December 1972) in that SCU is a superior source of nitrogen for rice

grown under conditions where flooding is delayed or intermittent

However the results of some experiments from India and West

Africa where rice was grown under conditions where only leaching and not

both leaching and dentrification would be expected to occur suggest that

SCU may be a superior source of N for rice grown under these conditions

as well In certain parts of the world large areas of floating or

deeply submerged rice are grown very little information relative to N

response i available but in general yields are comparatively low

Further research is planned to 4valuate SCU for rice grown under those

conditions

The exact areamp of rice grown in developing countries under

conditions where both leaching and donitrification can occur is diffitcult

to ascertan but tgleetad 1 L (Tailoring of Pertiltiters for ice

TVA ulletin Y-52) states that the staft of IOi has ea|aited that uvor

7I of the rice in outheat Asia So Arown under this type ofter meASe

sent Prelisneary bfbervetio eu est Oat at t l PsIblySoea (a4

ofe) of tw frie to Vat Atfica to gmrae 4nder delayd of totriltest

irwiM4 to FAD report MD00llIO owtoifar f rce rt Imvi

W1110010 teveW ftJ 4 We 04001406w 1 141410tIf 0 ferl4iiio 10

-4shy

applied at a rate of 60 kg Nha then approximately 2600000 mt of

N could profitably be used as SCU In 1972 33700000 mt of N was

used in the world and these figures suggest that as much as 8 of the

world consumption could potentially be expected to be applied as SCU

on rice

On a smaller scale approximately 114000 ha of rice are grown

in Peru nearly all of which is grown under conditions where SCU would

be the most desirable source of N Average rice yields in Peru are about

4000 kgha but research by Sanchez and coworkers (see attached report)

indicates that with ample N yields of 9000 kgha can be attained To

obtain these yields 25500 at of N as SCU would be needed compared to

42000 at of N as straight ure to obtain the same yield Thus SCU

would save 16500 tons of N or roughly 40 of the N needs

Results from India indicated that when equal amounts of N were

applied an average of about 1000 kgha more grain was produced on exshy

porLsentail plots This average figure included some areas where SCU was

not superior to AS In 1972 36500000 ha of rice were grown in India

with an average yield of 1616 kgha Proper use of SCU in place of

conventional form probably would not Increase yields an average of 1000

kghe under fam conditions as it would on the research plots but an

average of 500 k8 would be raoom ble This would rotult to an Increaa

of a50000 m of rice an Incras of 311 over the 197 production of

$90o000000 mt

The 40 04Melee Ore cited t dMWMaftampt tbe iAnCicoo in

ftc prodwilu peble Ihrow~h proer t o of 60 a wvrf of 0 for

fiff MWere- f04ieb di at Peded t1 1if1 pfJiiea1y 4i fie toshy

ditlsw winde Iee idveitu f~ rics a to JMe(0wiaihthe of 1CM La f

-5shy

precisely evaluate the economics of its use

Preliminary data indicated that SCU may be a superior source

of N for other tropical crops particularly long-season crops such as

sugar cane and pineapply grown in areas of high rainfall

The results of the wheat experiment followed by sorghum in

Pakistan in which the residual effects of SCU were evaluated suggest

that in intercropping and multiple cropping systems fertilizer nitroshy

gen may be applied in a slow-release form (SCU) at a convenient time in

the cropping system so that the nutrient elements will be released for

utilization by succeeding crops

Information already obtained indicate that SCU is a superior

source of N for crops grown on large enough areas to economically justify

its commercial production As more data are obtained with more crops

and from new areal the potential for its use will undoubtedly increase

Consequently as adequate supplies become available programs need to be

initiated in selected areas to introduce the use of SCU to agricultural

extension workers to the fertilizer industry end to farmers and to

encourage its coinercial production Since the cost per unit of N will

always be higher in SCU than in regular urea the use of SCU will be

econmically practical only under specific conditions and these restricshy

tions as to its use make it perative that effective education and

inforuation progra- be conducted prior to the comerctel Introduction

Of SU On 4 Wid eeie

-6-

BACKGROUND AND OBJECTIVES OF PROJECT

The present project is designed to capitalize on the momentum

and knowledge gained in the previous project Tailoring of Fertilizers

for Rice This project demonstrated that a superior nitrogen fertilshy

izer can be developed for tropical areas and that some relatively low

cost phosphate sources can be effectively utilized The present project

seeks to broaden the base for development of improved fertilizers through

a wider range of agronomic economic and engineering evaluations Preshy

viously the emphasis was placed on SCU as a nitrogen source and the dirshy

ect application of a limited number of selected phosphate rocks as phosshy

phorus sources for rice fertilization In this project a wider range of

fertilizer materials will be tested on a variety of upland crops such as

maize wheat sorghum and sugar cane cassava and others of national imshy

portance in various countries

Through its domestic fertilizer research and development proshy

gram TVA produces experimental fertilizer materials that may have poshy

tential for tropical soil conditions and crops With support from AID

in this project the capability viii exist to work toward improving fershy

tilitors for developing countrive through the necessary and logical soshy

quenco of production to ramer aceptonce to sess the potential for

co mrcial production

Pertilliers now being used in 4eveloping countriee relAtive

OeCOtcs And shortcoMiNge of the Mterials viii be Ovai6Isd Ktshy

true thel ena 4 4 0(fiashyporimrtAl product wlornriee pilot plt

ties OaI1 pl0t4 Will be W0bsutd to fcresMq tet in jre

tof f~wrisea with caomvstmwl siatofials rr f P0041610 161i

-7shy

screening will be done using soils of the area where the fertilizer

will be used Materials showing potential in greenhouse tests will

be further evaluated in actual field programs in selected countries

If successful at this stage economic and engineering data will be

compiled to assess the potential for commercial production In orshy

der to evaluate the product and process the total system will be

studied including storage handling and transportation from the

point of production to the farm Information developed throughout

this work will be available to industry foreign and domestic so

that it can develop a production marketing and use base for utishy

lizing the product This level of technology is rapidly being achieved

for SCU which received major emphasis in the previous study additional

agronomic economic and engineering data both with rice and with other

crops will be obtained to complement the previous findings

This project must be broad and combine a variety of professhy

sional disciplines but it is necessary to retain the flexibility to

move forward in specific directions as Improvements in products occur

This is necessary to insure that improved products identified in this

project can ultimately be made available to farmers zegrdless of their

economic and social status and that sufficient data aro available so

that induetry can make soomd decisions regarding the foasibility for omshy

marcial production

Major objectives of this project are eommartted as tollovws

(1) Developing Iertilaers to wt the nutrient neD of oocitic

4I l VhICh are not set iconmically withtfopical Crops and

etoshytoov~tmtl| Nrtiliieoro or that can set thse ne- s fre

006eItCOMlY ky 4ir lfte the W91~1ici of teftlliaer ultil4tin

-8

(2) Proving the value of these improved materials to insure that

they will increase farmers income over a large enough area

to attract and Justify commercial production

(3) Developing the production technology for new fertilizers as

a basis for encouraging and advising potential commercial proshy

duction The integrated process designs will seek product

quality and economy while striving to minimize harmful emisshy

sions to air water and land

(4) Working through cooperating organizations and with leaders in

research extension and industry to develop and demonstrate

methods for introducing new fertilizers to farmers so that they

will be properly used when they become commercially available

-9-

SCOPE OF WORK

This project integrates agronomic economic and engineering

expertise into a single team in order to develop improved fertilizers

for a wide range of crops and soils in developing countries Considershy

able emphasis is given during the first eighteen months to collecting

the data needed to complete the evaluation of sulfur-coated urea and

ground rock phosphate for lowland rice Both materials then are

scheduled for demonstrations during the latter part of the project in

order to educate extension workers and farmers and to attract the fershy

tilizer industry into commercial production Considerable emphasis is

given to the economic evaluation of a total production-marketing-use

system for each material in contrast to alternative nutrient sources

The probability of commercial production of SCU and ground

rock phosphate can be enhanced by expanding their use to additional

crops and soils Thus the project is expanded in scope as compared

to the previous project on tailoring of fertilizers for rice in order

to test these materials on additional crops

The expanded work includes a major effort in screening and

testing new compounds and forms of fertilizers for various food crops

produced under tropical conditions Alt hough it if already known that

more effective andor lens expensive formn of nitrogen and phosphorus

are needed a literature survey will nerve an Lan additional guide to

important and presing fertilizer problems

-10-

Much of the work with fertilizers for both lowland rice and

upland crops will consist of field tests in Southeast Asia Africa and

Latin America Greenhouse and engineering studies will back up the field

research All field experiments are designed to provide at least an esshy

timate of costs and returns for each fertilizer tested

PROJECT PLANS FORFISCAL 1975

In this section the work for fiscal 1975 will be discussed

It should be remembered that the success of this project depends in a

large part upon maintaining sufficient flexibility so that work in inshy

dividual countries can be adapted to supplement and complement programs

already under way While guidelines and plans of work must be developed

so that the objectives of the project are clearly defined detailed

plans for specific countries or groups of countries must be developed

by consultation wth local cooperators

These plans will be discussed under the following three general

phases of the project

I Engineering and development

2 Agronomic testing and evaluation

3 Economic evaluations

Engineering and Development

Phosphate Rock

Methods have been proposed for relatively simple treatment of

phosphate rock (PR) to increase the availability of the phosphate to make

it more suitable for direct application to the soil These treatments

may be economically feasible in certain areas especially in view of the

current world fertilizer situation Considerable work has been done at

TVA studying means of altering PR and plans are being developed to inishy

tiate further developmental work and field testing of these materials durshy

ing fiscal 1975

- 12 -

Emphasis will be placed upon obtaining samples of phosphate

rock from deposits in developing countries and testing and improving

procedures for increasing their citrate solubility and tzius availabilshy

ity of the phosphorus From this laboratory screening process sevural

sources will be selected from which small amounts (50 to 100 pounds)

will be prepared for greenhouse and field experiments ou various soils

(as described under agronomic section)

From these results one or two locations (or countries) will

be selected for development of a pilot program to utilize local sources

of phosphate rock This program will involve production of the altered

PR and its agronomic evaluation and then educational programs with govshy

ernment and commercial representatives to introduce its use to the farmers

Sulfur-Coated Fertilizers

Some preliminary work has been done in which urea-potash mixshy

tures were coated with sulfur The 7-day release rates for the N and

K20 were 17 and 36 respectively from the coated product (22-0-11-30S

grade) This was the first effort in coating a compound fertilizer

with the new coating system

The widely differing release rates for the nutrients from

the coated compound product raise some interesting prospects for tailshy

oring the nutrient release rate of sulfur-coated products It might

be possible to cogranulate materials of varying water solubility and

sulfur-coat them to produce products with release rates that would apshy

proximate the timing of nutrient requirements of the crop The need

for this type of controlled-release product has been mentioned many

times by agronomists and may be especially applicable in multiple and

intercropping systems

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Table 2

Mttct of 0 Sourco aampW $At On Upt~ks of 0 by Two Varitgtos of Paddy Rice

gr~a 1971

~ MMUampL~ ~L ~ nYLALI~ 11 lemall

I ie

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- 24 shy

India--The results of four experiments conducted with flooded

transplanted rice in India by the All-India Coordinated Rice Project

Hyderabad are given in table 3 The response to N was excellent the

yield without N being only 41 of those obtained with basal applications

of N as uza With basal applications of SCU the yields were 20 higher

than with basal applications of urea and in the three experiments in

which urea applications were split yields with SCU were 18 higher than

yields with split applications of urea When comparing the average Nshy

response (kamp grainKg N) yields were increased 13 more by SCU than by

basal applications of urea

The data from one experiment with light irrigated rice in India

are given in table 4 yields were relatively low and differences between

N sources or method of application were not significant However yields

with SU tended to be higher than when all urea was applied at planting

but lower than when split applications of urea were applied Again yields

increased more than 13 more with SCU than with basal applications ofwere

ur

In tables 5 and 6 the yields of a short-duration transplanted

rice grown in irrigated light-textured soils at five locations in India

indicate that higher yields were obtained with SCU than with urea when apshy

plied as a basal application Yield increases due to basal N applications

were 502 greater with SCU than with urea However split applications of

resulted in yields equal to those obtained with basal applications ofurea

CU

The yields of direct-seeded upland rice grown at three locations

to India are given in table 7 and the relative yields in table 8 Yields

were low due to drought but good responses were nevertheless obtained for

- 25 -

Table 3

Effect of N Source and Time of Application on Yield of Paddy (Flooded) Rice in India 1972 (Summary of Reported Data from 4 Experiments)

Experimental Number Source Rate Method Yield Relative N-Response

and of of N of Yield Kg Grain

Season Nitrogen kgha Application mtha Kg N

- - - 196 34 -

Urea 120 Basal 573 100 314

11 Urea 120 80 + 40 611 107 345 Rabi SCU 120 Basal 713 124 430

12 - 0 - 202 30 -

Urea 125 Basal 682 100 384

Rabi Urea 125 35 + 20 + 35 + 35 633 95 344 SCU 125 Basal 781 115 463

13- 0 - 168 44

Urea 100 Basal 385 100 217

Kharif Urea 100 30 + 20 + 25 + 25 400 104 232 SCU 100 Basal 462 120 293

14 -

Urea -

125 -

Basal 355 650

55 100

-

236

Rabi SCU 125 Basal 781 120 341

-- 26 -

Table 4

Effect of N Source and Time of Application on Yield of Light Irrigated Rice in India 1972 (Summary of Reported Data From

One Experiment at Pattambi)

Experimental Number Source Rate Method Yield Relative N-Response

and of of N of Yield Kg Grain Season Nitrogen (kgha) Application (mtha) Q) Kg N

38 0 - 204 85 -Rabi Urea 120 Basal 241 100 308

Urea 120 60 + 0 + 30 + 30 267 ill 525 SCU 120 Basal 255 106 425

Table 5

Effect of N Source and Time of Application on Yields of Short-Duration Transplanted lice Variety Grown on Irrigated Light-Textured Soils at 5 Locations in India 1972

(Snmzarized From Reported Data)

Rate Grain Yields (MtHa) Source of N Method of N GrainI of N kgh Application Faizabod Karjat Mandva Pattabi laya Averaje X

- 291 266 211 19 340 260 -

Urea 100 Basal 386 407 361 285 482 3 124 Urea 100 50 + 25 + 25 399 430 434 334 6amp2 4A8 186

SCU 100 Basal 368 468 439 360 572 41 181

Table 6

Effect of I Source end Tlae of ApplIcattoo c RIstave Tle24 of a rt- rat1 T Lsd lice Vasrety Crin o Irrigated L41tshy1 at S Locitite mindi 1972

Rate ____________14_3

Source of X N~tbad of Of X An 1 tat14 1 acr X__T1 4v tatW ttva

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Tabl I

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W Iotors Ftslanp tospg Irritd for Two thvk Afler flontiw wft rkwa~ Floo4d 191)

- -I-of LWAIM) (IS YJl- fl-----II)

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- 38 -

Table 18

Yild of aemati-370 Rice at Punjab Agricultural Research

Institute in Pakistan in 1969-70 Grown Under

Couditions of Intermittent Flooding

Pate of application

=IL

o 0 67 67 100 100 67 67

100 100 67 67 200 100

Average for Sources

Ntha

AS 260 gres 279

320

Source f5

-

AS AS Ura Urea SCU SCU

Yield

Relative

93 100 115

(M)O

Yield

Increase Yield Due to N

(Ktlha) (mtha)

-212 245 033 274 062 260 048 297 085 315 103 325 112

Yield Increase

Relative

72048 067 100 108 161

(2)

- 39 shy

Short-statured high yielding rice varieties grown extenshy

sively in northern Peru require extremely high rates of conventional

N sources to achieve maximum yields The recovery of applied N is

extremely low due to the use of intermittent flooding This water

management system results in heavy N losses even with properly timed

split applications In search of simpler and more effective methods

of N management eight field experiments were conducted in the region

to evaluate sulfur-coated urea (SCU) an experimental slow-release N

source supplied by the Tennessee Valley Authority Rice yields were

increased an average of 59 more by pretransplant-incorporated SCU than

by urea or ammonium sulfate applied in the same manner SCU produced

excessive vegetative growth which resulted in yield reductions at high

N rates

Regardless of an assumed 48-higher unit N cost in SCU the

overall benefits of pretransplant-incorporated applications of SCU

were favorable since there was a decrease of 40 in the optimum rate

of N and the need for precise timing of application was eliminated

Pakistan--In Pakistan basal applications of AS urea and

SCU to rice grown under conditions of intermittent flooding in 1969-70

(table 18) indicate that SCU is a superior source of N as compared to

urea or AS when all N is applied at or before planting The data also

indicate that a yield response was obtained for P applications but a

comparison of N sources at each level of P indicates that no interaction

between N and P was present so that differences between N sources were

relatively the same at each level of P Yields were increased about 60

more when SCU was applied than when urea was applied Yield increases

with AS were only about 72 of the increase obtained with urea these reshy

sults do not agree with the generally-reported superiority of AS as comshy

pared to urea as a source of N for rice

- 40 -

In 1973 experiments were conducted in Pakistan using both

Basmati-370 and IRRI-6 varieties of rice grown under conditions of

When all N was applied at puddlingintermittent flooding (table 19)

or 12 at puddling and 12 at panicle initiation both AS and SCU were

superior to urea with SCU tending to be the most efficient source

However when N was applied 12 at transplanting and 12 at panicle

initiation SCU was the poorest source of N This would indicate that

the release of N from SCU applied at these times is too slow for optimwn

plant growth

In another experiment in Pakistan in 1973 no differences

in the effectiveness of urea AS or SCU were noted in the yields of

continuously-flooded rice (table 20) Again these results are conshy

sistent with earlier results which indicate no superiority for SCU

when rice is continuously flooded

Nitrogen Studies--Maize

A series of three experiments were conducted by IITA in

armo-Nigeria in 1972-73 comparing AS urea SCU and

CAN (calcium

nium nitrate) as sources of N for maize (table 21) A significant

yield response was obtained for N at each location but no conaistent

differences were noted amaong sources These results are consistent

with results at other locations which have not shown that SCU is a

superior source of N for maize grown over a period of 3 to 4 months

Nitrogen--Wheat

The yields of wheat in Pakistan in 1969-70 (tables 22 and

23) show that yields with SCU) tended to be lower than those with ureaJ

although at one locction where sorghum was grown followilng wheat with

Table 19

Yields of Basmati-370 and IRRI-6 Rice at Punjab Agricultural Experiment Station in Pakistan in 1973 Under

Conditions of Intermittent Flooding

Rate Yield Source of N Time of Yield (Mtha) Increase of N B-370 IRRI-6 Application Basmati-370 IRRI-6 Average (Mtha)

0 0 - 21 353 287 -

SCU 90 150 At Puddling 325 545 435 148

Urea 90 150 At Puddling 309 500 405 118

AS 90 150 At Puddling 324 529 427 140

SCU 90 150 Puddling 372 572 472 185 Panicle Initiation

Urea 90 150 Puddling 335 502 419 132 Panicle Initiation

AS 90 150 Puddling 353 529 441 154 Panicle Initiation

SCU 90 150 After Transplanting 312 562 437 150 Panicle Initiation

Urea 90 150 After Transplanting 340 624 482 195 Panicle Initiation

AS 90 150 After Transplanting 349 583 466 179 Panicle Initiation

All plots received 45 lbs P205acre as single superphosphate

Relative Yield Increase ()

Source of N At Puddling Puddling Panicle Transplant h Panicle

Urea 100 100 100 AS 119 117 92 SCU 125 140 77

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-48

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amp4at r per Wforssota Mav two 64eed Wilk elikor It 44 of

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It vwld be polotrd A Wevero wtht Is the jteld level that

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P11~0 pra~lpj prefer gre4r tuftlter for whlae

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mmfp MW phapa A (CI) sed graewletod pampAtlti arlolatod Pa

asowcs of P tof ttde ro The wreem proucts omre raGther

pemour~a ot P syag besmti andMi as elt ov so gpamwhr

iuipiqffhate(TS) low twseeo Is eftwiltve Is thet

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pud6itt of Irto paddle Wee ofsdlseireplastiq

0 49 shy

lbs partially scldiaatede grawilated Ml prodlucts Vere isshy

toiwdiats in 5tftOvttWS54 betwee wroiPi ad TVP NotV5Ymf to

me coo were they mere twoe $a a etfective ao TIP 00 sipifleast

LVSUMI5 at0 efecto wore toun tor thee produteo Timely dtIampWde

FR (-t00 mmoh) Uia amp~rally oar affective than Owe gra8448r FOampprodt

featal twos o 6 aotetire s I

Nowvero it to felt that sfortber field euprtet vth

hese interials Amd ether typs of grometatodl Wter nre wrrautad

hater ceeuwodh that they have me areec poteatlal toi additoG

e tate wAne the sectte as OtawrI sed bovoloen turther

euperimeste vth few reck pboophar s0d with reck pbophat treated

to sehesa citrata selmtliy or to ha csaducted

Metbir sertes of tbme enprtaeats wae c~edtmcted by IITA

to Ut~rta copal TVP AOP APP aed it at see tecastisix (table 14)

No dot lalt sewseltles teh draw tree thee results simouely em pear to tlvdl bsww they do stwgpt tbat forthew work with

MR to werramid so tbme sels

Table 24

LttcttF Swce MaPlate 06 ieldot IM AWaia CoelsANS at IITA (Ugboda ad Apoin ail sorit) aid at Ike (AUaba s5i series)

1973

Plate ot IP Apinu 5 poundebods A1ab

Ocrol 0 Z94 419 M)

Tr ipl ruprphite 20 349 3799378

Triple vepput 40 M09 410$

Triple 6wp~~b1 4271 4344 42250

Ammotw-ritpophW to 4201 4124 4040

Amosim-rdop~phlt 40 4270 4106 4231

AM tuo-polpephats 20 404 4244 3794

~eai~mpelppepbuI 400)49 4094

Cee m-pbpbt to- 59

momee eph lto 0 4192

LSO (0 0$) 29 1025

Th WPII

- 51 shy

101Y114 tpeM-fI PEP~tbRP YO

1 ~ ~ gmw 1pc~biofl- 9 Kla4v4h

Upia U04 Copfind am Crehout Stet Rpano at (Ia4

rico t IF t rume6 orth~ Caralto phoophale rocl QAR) vaUN pqU41 to

roopon from cmonetrat4 gsporphophai (CIP) who ort$o4 oil k

was 45j itwas tafertor vb protioo4 oil p war OS Ib 4iffer~c

in rtc reepos to X cod14 oo bo ttrit4 4 4 hvsciag of boil p

~ Pt o r11221 0 tP

c theto the rhimecyllndor of rico tots par to)14M4i1 roeoi~t

ed oil emd PA prior to tho ont of an~robi4 cMioe AA~ oIifoshy

nAte bYpot t taet~d tO fC4sin t~r 4PWden0 Of f Ot(tivshy

ofOWailiJtyno o prefla4 all Put that 4t01etoo 14 tvsIk

of the Ott to prvvld a 014for C4m0 44 mI 1 o4sf

EfftC ftPet141on AIAM-0 V f401td 4 4iv 440 Mtft

Aa torfat VampP f4MWfCi4W04wt0amp to 4eturWlI Ot(Wel~drIC ft

Ot f tM6 the flooded Ott 00 14 04019I Pft0uAw Of gAr~s~lr

pkS$t M40b MP) Tw P1101 Piset Prodwie W-e 10M0di Wr04

(10-1) emW 0aretilp ddw01at4 P WAA firom Rrth M~flRU414~$

wee cowiared with fie Md reWim 44104 proo~fo) foruk oith laWItter

I v te-PR P OW1004 4 4 O Wf ottil OW ellt Oo

Oveiel1 the 40tt dmcruie to effetotww Wtollowui Co fme

PR tpaUIB1I ldoltmo PR (pamwlatr) offr~- ArmeuM) 0 orwi

- 52 -

Effect of N Sourc6 and Water Management on Response of Rice

toe Zn- M Giordano J J Mortvedt OP Engelstad and Greenhouse

Staff Several rotes of CO(14H2)2 and (H )2So4 vith or without ZnO

wore applied to flooded and nonflooded Crowley oil (limed to pH 75)

to determine response of Bluebelle rice to Zn Yields with both N

sources veotrgreator on flooded then on nonflooded soil In the abshy

ence of applied Zn total dry matter production vith CO(NH2)2 was

slightly lower than with (NH)2S04 on flooded soil and considerably

lover on nonflooded soil Concentration of Zn wan higher in straw and

grain of plants roun on flooded than on nonflooded soil Although

concentration of P was unaffected by N source or Zn rate there was

som indication that cranslocation of P from straw to grain may be

depressed in nouflooded rice Concentration of N was lower in straw

grown on flooded than on nonflooded soil due to apparent dilution

thereas both X sources resulted in similar N concentrations in straw

at all rates of N application the N concentration in grain increased

with 0 rAse

feSpongi gf(SM to Chjorospodiostte and Related P Sources--

Si Allen and Greonhoue Staff A greenhouse pot experiment was

couct44d with corn Brown on Hountview silt loam to compare the ofshy

fectlivees of chlorospodiosito (Chlor-l) with concentrated supershy

phosphate (CP) Thomas slag and North Carolina phosphate rock (NC-PR)

Oil-prillad urea-phophato rock (UPI) FeA1JMP 20 7 and monomthyl

phosphate were included in the experiment Based on yield of forage and

uptake of P by tvo crops each of 6-weeks duration the following conshy

stui were dravat

I Chlor-1 was slightly loss effective than CSI Thomas slaS or NC-PR

from which Chlor-l wae prepared

- 53 shy

2 Granular UPR was a poor source of P its effectiveness was greatly

increased by reducing the particle size to -35mesh

3 FeAlNH4P207 was unavailable to the crop

4 Monomethyl phosphate was equivalent toor slightly more effective-

than CSP

Research Indirectly Related to TVA-AID Project

Response of Several Rice Varieties to Zn in Moist or Flooded

Soil--P M Giordano J J Mortvedt and Greenhouse Several varieties

of rice from Mexico and the Dominican Republic currently under investishy

gation in Puerto Rico for adaptation to upland culture were compared with

some established United States varieties with regard to Zn response on

moist and flooded Crowley sil (pH 75) Chontalpa (Mexico) Bluebelle

(Texas) and Starbonnet (Arkansas) were most responsive to applied Zn

Juma (Dominican Republic) intermediate and Sinaloa (Mexico) and Calrose

(California) were the least responsive The Sinaloa varieties (Mexico)

appeared to be best adapted to non-flooded conditions whereas Chontalpa

and Calrose were poorest Concentrations of Zn generally were higher in

plants grown on flooded than moist soil

Pattern of Growth and Zinc Accumulation by Rice--P M Giordano

J J Mortvedt and Greenhouse Staff Rice plants were harvested at weekly

intervals from shortly after emergence through maturity The objective

was to determine the rate of growth and Zn uptake by a Zn responsive varshy

iety (Bluebelle) and a less Zn-responsive variety (Calrose) in the presence

or absence of Zn applied to Crowley sil (pHl 75) Dry matter production

of Calrose was linear with time of growth and of a similar magnitude until

heading with or without applied Zn Bluebelle followed a similar pattern

where Zn was applied However in the absence of applied Zn foliage yield

was reduced markedly

-54

Uptake of Zn was similar for both varieties whenZn was

applied Dry matter production and Zn uptake by the two varieties

also were comparable when Zn was applied However yield of Calrose

was much higher than that of Bluebelle in the absence of applied Zn

while Zn uptake was only slightly higher This suggests that the lesshy

ser responsiveness of Calrose to Zn may be due to more efficient utilishy

zation of Zn There was no indication of a greater demand for Zn durshy

ing reproduction in either variety as was suggested in earlier greenshy

house experiments

Response of Upland Rice to P and Zn--P M Giordano J J

Mortvedt and Greenhouse Staff Several rates of P and Zn were applied

to Crowley sil (limed to pH 75) in factorial combination to determine

whether differences in rice growth under flooded and nonflooded soil

conditions are related to plant nutrition Although straw yields were

slightly higher in nonflooded rice receiving adequate P and Zn grain

yields were higher in the flooded crop increased rates of F andor Zn

did not result in equal yields Except in the highest Zn rate (75 mg)

concentrations of Zn in both straw and grain were higher with flooding

Concentration of P increased with rate of applied P and was higher in

the grain or flooded than upland rice at a comparable P rate In conshy

trast concentrations of N were lower with flooding due in part to dilshy

ution from increased growth

Rice Response to N and P in Flooded and Unflooded Cultures--

G L Terman S E Allen and Greenhouse-Analytical Staff Rates of

N from 250 to 2000 ntpot and P from 0 to 1000 mtpot were applied for

Nato rice grown on Mountview sil and Sango sicl (625 kg of soil per

pot) Market yield response to N and P was obtained Yields of straw

- 55 shy

total yields N uptake and N recovery were higher on unflooded than

on flooded soil cultures Grain yields however were slightly higher

with flooding These results indicate that with adequate applied

nutrients especially of N rice yields without flooding can approach

or even equal those under flooding

Uptake of N P Ca Mg and Zn increased with yield response

to N and P while K uptake decreased on the Mountview soil Concentrations

of N and P increased with applied N and P respectively while concentrations

of other nutrients were diluted in most situations with yield response to N

or P

Results from this experiment show that amouats of N applied in

previous pot experiments for rice have been much too low especially if the

crop was grown to maturity

Response of Corn to S and N i UUASand Urea-S--S E Allen

and Greenhouse Staff Three greenhouse pot experiments were conducted to

measure response to S and N in ulfur coated urea (SCU) urea amonium

sulfate (UAS) and urea -S as well as estimate N losses from surface apshy

plied N sources

In Experiment 260 less than 20 of the S mixed with the soil

was recovered from SCU or urea-S granules by two crops of corn as comshy

pared to 45 or 80 from flowers of S or Na2SO 4 CLop response followed

a similar pattern

In Experiment 260-A N sources were surface applied and alshy

lowed to dry for two weeks before incorporation Into the soil and plantshy

ing Recovery of N by two crops of corn was 77-82 for AN an compared

to 37-70 for urea UAS urea-S and ICU Thus n this experiment loss

of N from urea did not appear to be re~dcud by light S-coatlngn or by Inshy

corporating S or AS in the granules

-S -

I xbprZnSlt a Wtch aU Meyto 0-Ai Wt f9r

higher reermo teOrtOrs cOM reSpWNO i r0100 Of N w

not oaisteontly related to sewe ot N In edl tust 0 ioltiUe Lim

lo in VMuwpped evlmtUTS 48 merind by seirest nte appresOehe

501 for uroa as cwarod to 210 for urea peepha

Rus- or Upse to LoAmIl34I a AriMed bI Earl U

MW NOWlsIIsIr-4 L Toman 5 1 Alln and eesese StNf rio

row on Sawg did (0 tpot) We 1l0l0 Ws feritiud vith 05is

of Npot mixod with the 6011 as aureCA NiAO) 1 Age god At Ures

was also itcluded at rtt t 05 10 end 15 of Upee Theas trealshy

onto were followed 4 wpdrsetago of U s AN wre 4C 10o or at I3n

Weeks toulin up to IS pot

A soil application of 10 pot rosulvod to the maim yield

at 4 weeks Tio4 sad percont prottis t intre raite tncreased rftishy

linearly with U applictalien IeseeItally all at the m iNd wit

the moil w domitrifted after flooding Grail end straw Ilelds vere

highly correlatod with tiliriag and vlh ubers of gralm arl

The results Widicat that 0$ to 10 a of Upot as orea or

NN bsuld be sied with the oil to stilate tiilrir with adshy

ditional 0 topireased later to increase grain lIds mad protia cmshy

tout

DIVISION 54- FERTILIZER TECHNOLOGY AND USE

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valves a hevwae u Iar Walh basl oswas dhe uwpatr bshava of

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TOW opl taoe for AieweeW 4OsmWMbas Op peas As Tabl 4 sling sob Os awowully eom grams Piel level Thes oeulam Ma sed as IM

-02

792 60L WI W A)49R Pio VOL 37 197)

primS o r OeampAd WU toa Them fl~ w At NOSSe earno maisslea Ia N he mOWamplIO yik ampWd IMe aampWmW OWa Owe wa UMs of KU to 41 Oke ampWiiIamm be dkrnety ewspokawleM(a s8 te camtd wie a eapmoe by TVA pavw ltoi NA poundrmdaka4us vrimeW460 o to ilkidm ofWW (Mtemas MuOwe 1973) TVA mwi bawld on soi ficedims IampWp seg rudwiv s~s0abet ke WNmdoe ON 01 K Is12 NOSW ie fssewnmu Ie I QvaaIi rowp IMA) f9

)amp m lodk byO voebmsaIS8OpeaWfrats 11 OWNmi a I a W idisod 0 81 Now 111 nindat Wm fysmpseaamp (If tsO tUmtI IsM $P shoroV4mmo knflkvnf (foOdme nuw ae Ow OImstwe in SM pnmm8 af tXm 10 114PIS kequoian wo Mpfii

SC~po umd spop~o VWt alm 4emWal 1 4ink PCmirsra M 1 ad AI 14bmms

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DIVISION 8-9-SOIL MINERALOGY

Amorphomw CeetIup en XmWra Ssrfmls

L C koits Am~ 0 tmmkaAf

ommp A faieiaAMTRACT skiwe lo nW ampM sm wi4h

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peuiieles as is s e wpwigstee eded his S -em -om 0641 h4 hisW1mWOWb~ bfem peess Wimm kv Iee

Pa~~~eakr4awiS SeUeeiNaiA WOW 14e

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oO00 llb K0 ibad~ ~~ doj 140WI s o mimdW um

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os 0aMW ofmu WA l aduWs~Ib rowuvvl3maIpm s

CaO~OP aw AlNomI 4ornomd to9 IS is -l O SI g4he rpidyThus whim m dowu bWa 0 m m- ei u

d m M 0bmSaImu M-1 ofM6 h Intun to 7I

aiba maush WAesshwn~u9dSg a osusLwpI ~ v m

M PolsdAvoWdw Ons pugm~ low iwLW m We

of~U -a~ mo uNo

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A e mun5d m i vvamp sa s ow bftIS i sa omdIs a w

edi1 hswopmo an ag am Iw anom erlwaPASneooie bnwoM po

o ~ do=lr 3s fluACWoSM Owaa VolM Ain b 400b adW g o as amob ofrMOWS A oo eWmaa ow $wofdi60 ow - ema

-v K Vcon l ap ad md ld KU lbs PoabumwA od w to domi a bembe 0b lt $014 i ampmomONo

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arbs awasm 00 iztv Am-~~~i u5~ms ashu is byw

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bdisc shmm Ammmd a Sm ofd~~~~~d~A ~ a~m olWshmo

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- omlos r umIWO1in pw

lie Uvplist i piw S p wsmoW N of t as so in~tabo 440 o rodgAsect M4Ammd meM ii INAq10ed~ Pib mdWWeiW 1w -w emit TU UFm 6AV 0W A fIN 00~ lb 0PANNO 4 drp OW~It~Oi Ofme _____f WACMW0IN WMVsol~lmO ft SNAO 40 do1Si - m Md y e b ii m

of of~phaow tw bmsdf toamplboe

AjflsutomW C1D-pCTP AD mSmZLT op 1 m ow ts Wdm of P om M

IaM 0t sdw a wn a8duws i ofV -w Mm P16I4 TWO a ewu i an

ov4mnk wsi 9 Mxfeu~i am emwm ismi0wmd fq W No ~~ - f mug Aitowe eutlkowbmTV is

amppowftdmi TiM 0 Tie OAA mo p)a Mwomoi dOn4m A)w

MW 0 604 0M mm yaM 01MWOfdi to tA0 M OOAW uinw OSOb

ap is~e I the ampo A A Mwof ~Do toit op aenu w~ifiOimem~ MAN ampW)

ItsAO se Y lieowawo u~w pkow-W1b pwf on a C Nohkw is f 0o1 s do~omW C mmU4

owud6moeft 4 Obind PINa~e

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~ -0

65

0IL CL OC AMXR PROC VOL 38 1974

)aT1 S4I104 ow Lusanll Tawng isa tall Thai variety known for beingIwo nonshyi s s ) sensitive to photoperiod A split-plot design was used in

S e e these euperimeots with 4 rates of P (I1 22 44 and 88t i V IV k of Pha) applied a main plot treatments and with the OF It sourMes of P as subplot treatments There were two checkS plots in each rmplicate The extra check plot was included to permit the application of fresh TSP standard Jor the

It- ti 06 + i bull fa succeeding crop the p-4me of bi was to permit accurate d awrnwal of the mdual effectiveness of the phosphate

ftinSUbI rock The P fertilioers were broadcast on the mud andthen Worporald In the soil during the last harrowing At

whM N both On ACS indx ampM time of transplanting Immediately before the last harrow61t (4j 5 4 01 P s 3Mm o Vallonal in con n 100 kgha of N as ammonium sulfate and 33 kghaWO Of Spews ampm lIW thaabe rocks do ACS indes of K as polium chloride were applied A total of 40 wa in prepw O do ctih k otent kha of N a ammoniunt sulfate was applied later in twoir P The hew oNed amp wM W for 5 of gw topdrossingp with about 5cm depth of water on the plotsvV I aiOMveffeOctveee Three to six ldayold selings pr hillwW the ACS idex were planted00OWW wia Oft fo an c irNk I p Coen 20 by 20 cm part in straight rows Hand weeding was used

and insecticide were applied for Insect control Grain yieldw was masared by sampling 5 ml of each plot excluding border rows The date of heading in each treatment and theUNiN d pbM W Weks rin tOW USA UMe In Tale yed componnts at hafvel were also recorded

I filM rsperMS esOM kdwdua 1 t ab The average yields of ough (unhulled) rice for botha 84 OW O 8uo 4 Thala TM was a locations are ploutel in PIS 3 for the first crop (1969 wet

owou thRM seaso0) The Veamps yield response was obtained at Klonge (s) W lDtO t Of dMa of1tw W d l R Luang however a 4ute satisfactory yield response was

~Mk ^d TVA UJSD ad Kd UnIveS obtalned to applied P at Bangkhen as wellXUe LaM e R qwrw Ims The sod was do Relative aponomlAe effectiveness values were calculated

VOW (a ksA w edmwL t Poesesm h Vy for these data and am presented In Table 3 The valuesdAY buo if dIe ouh ne Pee wtk a Mlak vow 1009 for th first crop are plotled against ACS index in Fig 41 This Im M i6ti l 4bNd IO a0 O mkarnk for both locatio r relationship was linear for the

11400 ThCpH 0( lb pW IW 01 th UpeiaW so Sanodion location and curtiltnear for KIng Luang The was u i 4A sksamp lMaor nrusio model amparounted for 81 of theAmO$MI Aw jAAsue Swim T1 Snh Wd variation In the AE valu for Bantkhen a square root

Mems a Iw iv fern alh$ sedm haowg dayNW W t he plAL At tdo M tM aso W s as ctminued throufh eltaM t Ofpof -le lse wo am P OeNI VeOpls 1o ealluae tI lon4erm MIdual Offccls

A on W isset i a wse to hsh eapeel of these ooihss t ocks The baagkhon experimnent was letmiaI1DlVemisthis is a w hulu Lo g Tasug ia iasael aft - Msd residual Ves will be pr-Om crok TheseTwod esewm

SWWo

A

lP~U~7 ISIIPe1iuIWN e bsedisssin ian ghth siaoelalbe

984 0 6 O O - M s -s fWPas 11eSft W d Uo al a o

o

S4l~ lIIII I~l I 1f fl

( +

+ + + m + ++++-

++ +(++ + ++++ + ++ ++

- 66 -

ENOIMLSTAD ET AL RESPONSE BY FLOODED RICE TO PHOSPHATE ROCKS VARYING IN CITRATE SOLUBILITY

I I I I j0 I I

BANOKHEN BANGKHEN

pH 56 6 - 0o

TSP

NC

5~ ~ ~ L o 4 - -shy

4 ] - --------shy04

6S

|0 III 2 44 8r 66

I I I

a 1KLONG LUANG

pH 46 z KLONG LUANG

TSP Sc2 NCFL(N)

5 FLIC) J0 TU

oshy

4 ~40shy

3 bull eM0

I - I I I I I

0 II 22 44 88 0 5 10 15 20 IP APPLIED KO HA ABSOLUTE CITRAE SOLUBIITY INDEX

Fig 3-Yield of rough rice at Klong Luang and Bangkhen Rice Fig 4-Relative agronon effectiveness () of P sources ploz-Experiment Stations Thalmand as affected by rate and Source ted against citrate solubity Index for both Thailand field ex

of P applied (crop 1) periment (first crop only)

regression model accounted for 97 of the variation in sumably resulted from crop uptake and reaction with the RAE values at the Klong Luang location soil to form less soluble products Such effects may have

These experiments were continued during the dry season been more important at the lower rates since the two TSP of early 1970 to ascertain the residual effectiveness of the curyes converged at the highest rate of application various sources applied to the first crop No new P was These data from KIong Luang indicate that (i) residual applied except for the fresh TSP standard mentioned effects of all rocks except Mlcwuri were substantial (ii) above rhe experiment otherwise was conducted in a man the relationship between relative agronornic effectiveness ner similar to that followed in the first crop of the phosphate rocks and citrate solubility levels was

The response to both freshly applied ad residual P was largely obscured and (iii) the general superiority of TSP marked at the Klong Luang location and marginal at over phosphate rock in terms of effectiveiss persisted Bangkhen In fact at the latter location the response was through the second crop so small that little can be said regarding residual effectiveshyness The yield data from crop 2 at the Klong Luang DISCUSSION experiment are plotted in Fig 5 Greenhouse and field data presented in this paper show

Relative agronomic effectiveness values (Table 3) were clearly that there are substantial differences among phosshycalculated for the Klong Luang data using both the residual and freshly applied TSP as standards It is of Interest to note that the superiority of TSP over the phosphbte rocks Table 3-Relative agronomic effective values for field experishyments in Thailand persisted through the second crop The main difference in KlowlZmlnql~the residual effects is that with the exception of the MIs- s Crop 1 Crop 21 Crop 1-shysouri rock Ihe marked relationship between citratr-soluble WoiCarolina yl 59 76

phosphate rocks and RAE had largely rds norh) a 64P conltct of th Florida (eqlral is 6969 6

disapipeared In this acidic soil (pHi 46) P would by this I14o 69 63 40 ToonesS 31 65

limo be supplied by Intermediate reaction products In addl Missou 0 o lion to residues of the initial spatlte Ts P o 2 o 0

The TSP applied to the first crop declliv-d slightly In campIafcmWataesr e id ofeuhuloefor 22MA rates of PtColeouattd as aba u tlte td18 kS ratesp dlverage yield tM868 to 22 44

effectiveness relative to the freshly applied ISP This pre- of d s4

A

4

- 67 shy

-SOIL SCL SOC AMER I

KLONG LUANG CROP 2

Si 3

eN

TAPPLIEDKGHA

Fig 5-The residual effectiveness ovarious P sources for crop s compared with freshly applied TSP Klong Luang Rice

Experiment Station Thailand

phate rocks in terms of agronomic effectiveness for flooded

rice Further these differences can be predicted by means of citrate solubility or by the ACS index It appears that

the latter is more appropriate where the content of apatite varies among phospiate rocks The most soluble phosphate rocks approached but did not actually equal TSP in limit-iuig (maximum) yield in these experiments regardless of rate applied This agrees with the results of Ensminger Pearson and Armiger (4) One needs to consider the defi-nite posribility of same yield loss in zhoosing a phosphate

rock over TSP such yield losses must be weighed against the lower price of phosphate rock The explanation for such iosses may involve concentration of soluble P in the soil Khasawneh and Copeland (6) suggest that the growth rate of crop plants is a function of P concentration that can be maintained in the soil solution If P concentration is limiting or inadequate becawe of a lower dissolution rate of phosphate rock the growth iate ard uiiimate yield will be diminished accordingly

The RAE values bascd on yield increases reflect the agronomi effectiveness of these various sources relacve

to the TSP standard however these nould be supple-

mented by an economic analysis before rational choice can

be made The following calculations will provide an estimate of

the rclativ ecooomic effectiveness(REE)

Y t Ps aXpatREE -- 100

vahtercks t sphate or e b i- eor

Price of TSPkg fo

be Price of PRkg P

PROC VOL 38 1974 leO

90r

Wsoshy

0

60-LUSEPHOSPHATE ROCK

00 10 20

PTP PR

Fig 6-Relationship between relaZive effectiveness values (RAE) and the price ratios between TSP and phosphate rock Such a figure can be used in making a choice between these

sources

If REE exceeds 100 in this calculation the phosphate rock would be preferable to TSP

The REE calcuktaaa wre used in preparing an indifshyference curve (Fig 6) wherein RAE values are plotted

against PTsPPpR ratios The cu~rve itself connects those points at which REE equals 100 When exactly on the curve it makes no real economic difference what source is chosen After choosing a suitable price ratio one can then project upward from that ratio knowing the RAI

value (or estimating it from such data as shown in Fig 4 using citrate-soluble P content) one can then choose the source on the basis of both agronomic and economic conshysiderations For example if the price ratio is 25 and the RAE value of the phosphaite rock is greater than 40 the rock phosphate in question would be used However if the RAE value was less than 40 TSP would be a better choice There are indications that if the P in the more soluble phosphate ro~cks (North Carolina north Florida central Forida) is less than half as expensivz as that in TSP these rocks would be feasible altereaives to TSP on soils similar

to thoseused in Thailand This analysis does not take into account the possibility

of lower yields from use of phosphate rock In addition only a portion of the various yield response curves was used in this anlysis ie up to 22 kgha Beyond this

rate yield response was much less pronounced it could be argued that at less than maximum yields TSP would produce a certain yield at lower rates of P than would phosshy

pow ofrock This would especially be true for rates applioa example at Klong Luang 5500 kg of

rice pcr iectare could have been produced with either Ii kg of P as TSP or 44 kg of P as son of the more reacshy

tire phosphate rocks It should be pointed ot however

- 68 shy

(IIKIS amp YOUN( ARIFICIAL WEATIIERING OF OXIDIZED p[ll- IV

that this is the yield level that would show the widest difference such is the advantage of hindsight

Farmers generally prefer granular fertilizers for machine

or hand application This is a disadvantage for the phos-phate rocks which are normally arplied in finely divided form Recently experimental quantities of granular urea-

phosphate rock mixtures have been made by TVA Results of trials with these fertilizers will be reported elsewhere

LITERATURE CITED

1 Armiger W H and Maurice- Fried 1957 The plantavailability of various sources of phosphate rock Soil Sci Soc Amer Proc 21183-188

2 Bengston G W E C Sample and S E Allen 1974 Re-sponso of slash pine seedlings to P sGurces of varying ci-trato solubility Plant Soil (In press)

3 Caro JIt and W Hill 1956 Chard eristics and fer tilizcr value of phosphate rock from different fields J Agr Food Chem 4684-687

4 Ensminger I E R W Peirson and W II Atmiger1967 Effectivencs of rock phosphate as a source of phosshyphurus for plants US Dep Agr ARS Bull 4112S

5 Engelstad 0 P J G Getsinger anid I J Stangel 1972 Tailoring of fertiliers for rice cnnece Valley Author ftyNational Fertilicr Developmnent Center Hull Y-52

6 Khasawnch F E and Jane P Copcland 1971 (otton root growth and uptake of nutrievos relation oif phosph

rus uptake to quantity intensity and buffering capacit) Soil Sci Soc Amer Proc 37250-254

7 Lehr JR and G H McClellan 1972 A revised lIbora tory reactivity scale for evaljativg phosphate rocks for direct application Tennessee Valley Authcrity National Fertilizer Development Center lull Y-43

H Terman G L S EAllen and 0 P Engelstad 1970 Response by paddy cice to ratcs and suurces of appliedphosphorus Agron J63390-394

DIVISION S-9-SOIL MINERALOGY

Artificial Weathering of Oxidized Biotite IV The Inhibitory Effect of Potassium on Dissolution llate

R JGILKES AND R C YOUNG2

ABSTRACT

Rates of dissolution of oxidized biotites in OIM 001M ICI are severely depressed in the presence of IM KCI The amovnts of Al Mg Mn dissolved in the first eytraction are similir to those found without KCI however subsequent extractions remove these elements at 10-20 of the corresponding lICI rates This effect may be due to a decreased rate of vermiculite formation thereby reducing the effective basal area exposed to attack A decrease in dissolution rate with increasing ferric iron content was still apparent in the presence of IM KCI

Additional Index Words X-ray diffraction infrared aborp-

N EARLIER papers of this series the tole of biotite in soils

as a source of both macro and micronutrient elements

has been discussed ((Gilkes Young and Quirk 1972 1973ab) Experiments in artificial weathering uiing as va-

riety of extractants were undertaken to determiie the inlu-

ence of oxidation of octahedrally coordinated iron on the bull release of structural cations to solution The results of this

work demonstated that biotite behaves anomalously with respect to the other common ferromagnesian minerals found in soils Oxidation leads to the development of a high degree of resistance to cation exchange and dissolution Several authors have coiwludcd that decreased rates of K

Contribution from the Dep of Soi Science and Plant Nutri-tion Institute of Agriculture Univ of Western Australia Ned-lands 6009 Western Australia Received 29 Sept 1973 Ap-proved 8 Jan 1974

2 Senior Lecturer in Soil Science and Research Officer respeclively

replacement in electrolytes shown by oxidized biotites are

a result of the inclination of structural hydroxyl adjacent to newly created trivalent iron or vacant octahedral cation sites (Robert and Pedro 1959 Barshad and Kishk 1968) Gilkes et al (1973b) suggested that decreased rates of disshysolution of oxidized biotite in 0001 0t)l 0Af CI may also be due to the presence of inclined hydroxyl In this case a smaller surface area external and exposed intershylayer may be available for attack if K replacement by hyshydrogen ions occurs at a slower rate in oxidized biotites

Gastuche (1963) has shown that significant dissolution ofthe (IIM) biotile face may occur and it is easily demonshystrated that the proportion of exposed (001M) face in weathering biotites depends on the percentage K replaced

Rausell-Colom ct al (1965) have shown that hydrogen ions act in an identical fashion to metal cations in K exshy

change from micas In particular exchange c-f K by hydroshy

gen ions will be terminated or greatly reduced by high levels of K in solution Thus if dissolution of oxidized biotite by

acids is carried out at sufficiently high K levels to prevent vermiculization any differences in dissolution rate that may occur cannot simply be ascribed to differences in rates of K replacement The following results were obtained from such an experiment which unlike the experiment described in Parts I and II (Gilkes et al 1973ab) does not attempt to simulate natuiral - conditions

MATERIAILS AN) M HIiODS Further subsamples of the less than 0 hiotites used in K

excherandbaid disoo tu es (G iles e9n K exchange and acid dissolution studies (Gilkes et al1973ab) were used in these experiments Preparation of sequentiallyoxidized biotites without intermediate vermiculite formation is

Page 4: I70 - United States Agency for International Developmentto ascertan, but tgl.eetad, 1, L,. ("Tailoring of Pertiltiters for ice,'" TVA ulletin Y-52) states that the staft of IOi has

SUMMARY

This report is a project report covering the period from

December 1972 (when the bulletin Tailoring of Fertilizers for Rice

was issued) through June 1974 The present project is our expansion

of the previous project which was restricted to the use of fertilizer

for rice in that new and improved fertilizers are to be tested on a

number of tropical crops In addition to actual agronomic evaluations

of new materials increased emphasis will be placed on developing and

demonstrating methods of introducing new fertilizers to farmers so that

they will be properly used or they become commercially available

Testing of sulfur-coated urea (SCU) will be expanded to

include a number of additional crops such as sugar cane corn cassava

cottonbananas and cocoa Additional experiements vill be conducted

with rice to more precisely define the areas and conditions where the

use of SCU will be advantageous and to introduce its use to agricultural

workers and Industry representatives

Additional studies are planned vith rock phosphate to evaluate

its o(fectiveasee for direct applications and to study mans of increasing

its phosphorous availability by relatively tople muthoda for local

gomo aitionalV06 will be cOndvct44 with xronutolt4 msatvres of vorious

aterltele With rock p Wephut

smtprfallairy wVr to Ceonepl44 001teitn w4ltr g fut

of W41114090~f vowmllo It to felt thut ~ Ot 0~t ea I fo

0 setvl to 011folf OW 10offft 4 Aiee441bj ftiIOt

hepll4t 0 14W l0a khef t~ l to1141l(0

-2-

The need for fertilizers containing secondary andor microshy

nutrients will be evaluated in several countries where deficiencies

are known or suspected but where no commercial sources of these nutrients

are presently available

Additional data has been received from a number of countries

pertaining to the use of SCU for rice In general these data tend to

substantiate those previously reported in that SCU is a superior source

of N for rice grain under conditions of intermittent flooding but that

it is no better than conventional sources of N when conditions of intershy

mittent flooding or severe leaching do not exist A discussion of the

commercial potential of SCU in tropical agriculture follows this section

Insufficient data are available for tropical crops other than

rice to warrant any general conclusions at this time

-3-

POTENTIAL FOR USE OF SULFUR-COATED UREA

The major portion of the agronomic research reported herein

deals with the evaluation of SCU (sulfur-coated urea) as a source of

nitrogen for rice These results generally confirm those previously

reported by TVA (Tailoring of Fertilizers for Rice TVA Bulletin Y-52

December 1972) in that SCU is a superior source of nitrogen for rice

grown under conditions where flooding is delayed or intermittent

However the results of some experiments from India and West

Africa where rice was grown under conditions where only leaching and not

both leaching and dentrification would be expected to occur suggest that

SCU may be a superior source of N for rice grown under these conditions

as well In certain parts of the world large areas of floating or

deeply submerged rice are grown very little information relative to N

response i available but in general yields are comparatively low

Further research is planned to 4valuate SCU for rice grown under those

conditions

The exact areamp of rice grown in developing countries under

conditions where both leaching and donitrification can occur is diffitcult

to ascertan but tgleetad 1 L (Tailoring of Pertiltiters for ice

TVA ulletin Y-52) states that the staft of IOi has ea|aited that uvor

7I of the rice in outheat Asia So Arown under this type ofter meASe

sent Prelisneary bfbervetio eu est Oat at t l PsIblySoea (a4

ofe) of tw frie to Vat Atfica to gmrae 4nder delayd of totriltest

irwiM4 to FAD report MD00llIO owtoifar f rce rt Imvi

W1110010 teveW ftJ 4 We 04001406w 1 141410tIf 0 ferl4iiio 10

-4shy

applied at a rate of 60 kg Nha then approximately 2600000 mt of

N could profitably be used as SCU In 1972 33700000 mt of N was

used in the world and these figures suggest that as much as 8 of the

world consumption could potentially be expected to be applied as SCU

on rice

On a smaller scale approximately 114000 ha of rice are grown

in Peru nearly all of which is grown under conditions where SCU would

be the most desirable source of N Average rice yields in Peru are about

4000 kgha but research by Sanchez and coworkers (see attached report)

indicates that with ample N yields of 9000 kgha can be attained To

obtain these yields 25500 at of N as SCU would be needed compared to

42000 at of N as straight ure to obtain the same yield Thus SCU

would save 16500 tons of N or roughly 40 of the N needs

Results from India indicated that when equal amounts of N were

applied an average of about 1000 kgha more grain was produced on exshy

porLsentail plots This average figure included some areas where SCU was

not superior to AS In 1972 36500000 ha of rice were grown in India

with an average yield of 1616 kgha Proper use of SCU in place of

conventional form probably would not Increase yields an average of 1000

kghe under fam conditions as it would on the research plots but an

average of 500 k8 would be raoom ble This would rotult to an Increaa

of a50000 m of rice an Incras of 311 over the 197 production of

$90o000000 mt

The 40 04Melee Ore cited t dMWMaftampt tbe iAnCicoo in

ftc prodwilu peble Ihrow~h proer t o of 60 a wvrf of 0 for

fiff MWere- f04ieb di at Peded t1 1if1 pfJiiea1y 4i fie toshy

ditlsw winde Iee idveitu f~ rics a to JMe(0wiaihthe of 1CM La f

-5shy

precisely evaluate the economics of its use

Preliminary data indicated that SCU may be a superior source

of N for other tropical crops particularly long-season crops such as

sugar cane and pineapply grown in areas of high rainfall

The results of the wheat experiment followed by sorghum in

Pakistan in which the residual effects of SCU were evaluated suggest

that in intercropping and multiple cropping systems fertilizer nitroshy

gen may be applied in a slow-release form (SCU) at a convenient time in

the cropping system so that the nutrient elements will be released for

utilization by succeeding crops

Information already obtained indicate that SCU is a superior

source of N for crops grown on large enough areas to economically justify

its commercial production As more data are obtained with more crops

and from new areal the potential for its use will undoubtedly increase

Consequently as adequate supplies become available programs need to be

initiated in selected areas to introduce the use of SCU to agricultural

extension workers to the fertilizer industry end to farmers and to

encourage its coinercial production Since the cost per unit of N will

always be higher in SCU than in regular urea the use of SCU will be

econmically practical only under specific conditions and these restricshy

tions as to its use make it perative that effective education and

inforuation progra- be conducted prior to the comerctel Introduction

Of SU On 4 Wid eeie

-6-

BACKGROUND AND OBJECTIVES OF PROJECT

The present project is designed to capitalize on the momentum

and knowledge gained in the previous project Tailoring of Fertilizers

for Rice This project demonstrated that a superior nitrogen fertilshy

izer can be developed for tropical areas and that some relatively low

cost phosphate sources can be effectively utilized The present project

seeks to broaden the base for development of improved fertilizers through

a wider range of agronomic economic and engineering evaluations Preshy

viously the emphasis was placed on SCU as a nitrogen source and the dirshy

ect application of a limited number of selected phosphate rocks as phosshy

phorus sources for rice fertilization In this project a wider range of

fertilizer materials will be tested on a variety of upland crops such as

maize wheat sorghum and sugar cane cassava and others of national imshy

portance in various countries

Through its domestic fertilizer research and development proshy

gram TVA produces experimental fertilizer materials that may have poshy

tential for tropical soil conditions and crops With support from AID

in this project the capability viii exist to work toward improving fershy

tilitors for developing countrive through the necessary and logical soshy

quenco of production to ramer aceptonce to sess the potential for

co mrcial production

Pertilliers now being used in 4eveloping countriee relAtive

OeCOtcs And shortcoMiNge of the Mterials viii be Ovai6Isd Ktshy

true thel ena 4 4 0(fiashyporimrtAl product wlornriee pilot plt

ties OaI1 pl0t4 Will be W0bsutd to fcresMq tet in jre

tof f~wrisea with caomvstmwl siatofials rr f P0041610 161i

-7shy

screening will be done using soils of the area where the fertilizer

will be used Materials showing potential in greenhouse tests will

be further evaluated in actual field programs in selected countries

If successful at this stage economic and engineering data will be

compiled to assess the potential for commercial production In orshy

der to evaluate the product and process the total system will be

studied including storage handling and transportation from the

point of production to the farm Information developed throughout

this work will be available to industry foreign and domestic so

that it can develop a production marketing and use base for utishy

lizing the product This level of technology is rapidly being achieved

for SCU which received major emphasis in the previous study additional

agronomic economic and engineering data both with rice and with other

crops will be obtained to complement the previous findings

This project must be broad and combine a variety of professhy

sional disciplines but it is necessary to retain the flexibility to

move forward in specific directions as Improvements in products occur

This is necessary to insure that improved products identified in this

project can ultimately be made available to farmers zegrdless of their

economic and social status and that sufficient data aro available so

that induetry can make soomd decisions regarding the foasibility for omshy

marcial production

Major objectives of this project are eommartted as tollovws

(1) Developing Iertilaers to wt the nutrient neD of oocitic

4I l VhICh are not set iconmically withtfopical Crops and

etoshytoov~tmtl| Nrtiliieoro or that can set thse ne- s fre

006eItCOMlY ky 4ir lfte the W91~1ici of teftlliaer ultil4tin

-8

(2) Proving the value of these improved materials to insure that

they will increase farmers income over a large enough area

to attract and Justify commercial production

(3) Developing the production technology for new fertilizers as

a basis for encouraging and advising potential commercial proshy

duction The integrated process designs will seek product

quality and economy while striving to minimize harmful emisshy

sions to air water and land

(4) Working through cooperating organizations and with leaders in

research extension and industry to develop and demonstrate

methods for introducing new fertilizers to farmers so that they

will be properly used when they become commercially available

-9-

SCOPE OF WORK

This project integrates agronomic economic and engineering

expertise into a single team in order to develop improved fertilizers

for a wide range of crops and soils in developing countries Considershy

able emphasis is given during the first eighteen months to collecting

the data needed to complete the evaluation of sulfur-coated urea and

ground rock phosphate for lowland rice Both materials then are

scheduled for demonstrations during the latter part of the project in

order to educate extension workers and farmers and to attract the fershy

tilizer industry into commercial production Considerable emphasis is

given to the economic evaluation of a total production-marketing-use

system for each material in contrast to alternative nutrient sources

The probability of commercial production of SCU and ground

rock phosphate can be enhanced by expanding their use to additional

crops and soils Thus the project is expanded in scope as compared

to the previous project on tailoring of fertilizers for rice in order

to test these materials on additional crops

The expanded work includes a major effort in screening and

testing new compounds and forms of fertilizers for various food crops

produced under tropical conditions Alt hough it if already known that

more effective andor lens expensive formn of nitrogen and phosphorus

are needed a literature survey will nerve an Lan additional guide to

important and presing fertilizer problems

-10-

Much of the work with fertilizers for both lowland rice and

upland crops will consist of field tests in Southeast Asia Africa and

Latin America Greenhouse and engineering studies will back up the field

research All field experiments are designed to provide at least an esshy

timate of costs and returns for each fertilizer tested

PROJECT PLANS FORFISCAL 1975

In this section the work for fiscal 1975 will be discussed

It should be remembered that the success of this project depends in a

large part upon maintaining sufficient flexibility so that work in inshy

dividual countries can be adapted to supplement and complement programs

already under way While guidelines and plans of work must be developed

so that the objectives of the project are clearly defined detailed

plans for specific countries or groups of countries must be developed

by consultation wth local cooperators

These plans will be discussed under the following three general

phases of the project

I Engineering and development

2 Agronomic testing and evaluation

3 Economic evaluations

Engineering and Development

Phosphate Rock

Methods have been proposed for relatively simple treatment of

phosphate rock (PR) to increase the availability of the phosphate to make

it more suitable for direct application to the soil These treatments

may be economically feasible in certain areas especially in view of the

current world fertilizer situation Considerable work has been done at

TVA studying means of altering PR and plans are being developed to inishy

tiate further developmental work and field testing of these materials durshy

ing fiscal 1975

- 12 -

Emphasis will be placed upon obtaining samples of phosphate

rock from deposits in developing countries and testing and improving

procedures for increasing their citrate solubility and tzius availabilshy

ity of the phosphorus From this laboratory screening process sevural

sources will be selected from which small amounts (50 to 100 pounds)

will be prepared for greenhouse and field experiments ou various soils

(as described under agronomic section)

From these results one or two locations (or countries) will

be selected for development of a pilot program to utilize local sources

of phosphate rock This program will involve production of the altered

PR and its agronomic evaluation and then educational programs with govshy

ernment and commercial representatives to introduce its use to the farmers

Sulfur-Coated Fertilizers

Some preliminary work has been done in which urea-potash mixshy

tures were coated with sulfur The 7-day release rates for the N and

K20 were 17 and 36 respectively from the coated product (22-0-11-30S

grade) This was the first effort in coating a compound fertilizer

with the new coating system

The widely differing release rates for the nutrients from

the coated compound product raise some interesting prospects for tailshy

oring the nutrient release rate of sulfur-coated products It might

be possible to cogranulate materials of varying water solubility and

sulfur-coat them to produce products with release rates that would apshy

proximate the timing of nutrient requirements of the crop The need

for this type of controlled-release product has been mentioned many

times by agronomists and may be especially applicable in multiple and

intercropping systems

inawa~~aUww e t of~ wdtop~s WRisr 4owt~

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m- 4A4 4AWWO 44 $4amp iuamp-4)Ia ampW x~I~4~

~ i~P 4 4 wl 444 41A ~4 4~~E4166 I144 4t~w i14

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0uI 4044~Me ~ ~ N4

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) o~4w4 4444~S Is~4~4 ol I i A 4~ ~

4Ii I~4I4M$~ ~I

QOWIf XVif k

4004 004o4f U A

-w i4 I~~~

40440wo oow IVTA 44qol 644

4I~~~4J 00S4 4410 114w- A44W Wamp ~

6WViso4wb f vfpo w

w0OIA - i f iIS

f4 A 00 1 o4

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TOM I

Cs VWA1 t lw Vairtile ot P44Y 44c KW MI1

fiat Wm~~JL U Lem~ampuJampAJ Wat IO

~ 941~1 41 ~~~~j~~qt~~8IJ WtS dobu

Table 2

Mttct of 0 Sourco aampW $At On Upt~ks of 0 by Two Varitgtos of Paddy Rice

gr~a 1971

~ MMUampL~ ~L ~ nYLALI~ 11 lemall

I ie

W0 v slit III I) tQo9

KvN 1 17 111 1119

or 444M7

111a

i1$0N ~ It$ 121

1$

x IV ~404 tot Vsr 1 P1 41 w otv 1

- 24 shy

India--The results of four experiments conducted with flooded

transplanted rice in India by the All-India Coordinated Rice Project

Hyderabad are given in table 3 The response to N was excellent the

yield without N being only 41 of those obtained with basal applications

of N as uza With basal applications of SCU the yields were 20 higher

than with basal applications of urea and in the three experiments in

which urea applications were split yields with SCU were 18 higher than

yields with split applications of urea When comparing the average Nshy

response (kamp grainKg N) yields were increased 13 more by SCU than by

basal applications of urea

The data from one experiment with light irrigated rice in India

are given in table 4 yields were relatively low and differences between

N sources or method of application were not significant However yields

with SU tended to be higher than when all urea was applied at planting

but lower than when split applications of urea were applied Again yields

increased more than 13 more with SCU than with basal applications ofwere

ur

In tables 5 and 6 the yields of a short-duration transplanted

rice grown in irrigated light-textured soils at five locations in India

indicate that higher yields were obtained with SCU than with urea when apshy

plied as a basal application Yield increases due to basal N applications

were 502 greater with SCU than with urea However split applications of

resulted in yields equal to those obtained with basal applications ofurea

CU

The yields of direct-seeded upland rice grown at three locations

to India are given in table 7 and the relative yields in table 8 Yields

were low due to drought but good responses were nevertheless obtained for

- 25 -

Table 3

Effect of N Source and Time of Application on Yield of Paddy (Flooded) Rice in India 1972 (Summary of Reported Data from 4 Experiments)

Experimental Number Source Rate Method Yield Relative N-Response

and of of N of Yield Kg Grain

Season Nitrogen kgha Application mtha Kg N

- - - 196 34 -

Urea 120 Basal 573 100 314

11 Urea 120 80 + 40 611 107 345 Rabi SCU 120 Basal 713 124 430

12 - 0 - 202 30 -

Urea 125 Basal 682 100 384

Rabi Urea 125 35 + 20 + 35 + 35 633 95 344 SCU 125 Basal 781 115 463

13- 0 - 168 44

Urea 100 Basal 385 100 217

Kharif Urea 100 30 + 20 + 25 + 25 400 104 232 SCU 100 Basal 462 120 293

14 -

Urea -

125 -

Basal 355 650

55 100

-

236

Rabi SCU 125 Basal 781 120 341

-- 26 -

Table 4

Effect of N Source and Time of Application on Yield of Light Irrigated Rice in India 1972 (Summary of Reported Data From

One Experiment at Pattambi)

Experimental Number Source Rate Method Yield Relative N-Response

and of of N of Yield Kg Grain Season Nitrogen (kgha) Application (mtha) Q) Kg N

38 0 - 204 85 -Rabi Urea 120 Basal 241 100 308

Urea 120 60 + 0 + 30 + 30 267 ill 525 SCU 120 Basal 255 106 425

Table 5

Effect of N Source and Time of Application on Yields of Short-Duration Transplanted lice Variety Grown on Irrigated Light-Textured Soils at 5 Locations in India 1972

(Snmzarized From Reported Data)

Rate Grain Yields (MtHa) Source of N Method of N GrainI of N kgh Application Faizabod Karjat Mandva Pattabi laya Averaje X

- 291 266 211 19 340 260 -

Urea 100 Basal 386 407 361 285 482 3 124 Urea 100 50 + 25 + 25 399 430 434 334 6amp2 4A8 186

SCU 100 Basal 368 468 439 360 572 41 181

Table 6

Effect of I Source end Tlae of ApplIcattoo c RIstave Tle24 of a rt- rat1 T Lsd lice Vasrety Crin o Irrigated L41tshy1 at S Locitite mindi 1972

Rate ____________14_3

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W Iotors Ftslanp tospg Irritd for Two thvk Afler flontiw wft rkwa~ Floo4d 191)

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- 38 -

Table 18

Yild of aemati-370 Rice at Punjab Agricultural Research

Institute in Pakistan in 1969-70 Grown Under

Couditions of Intermittent Flooding

Pate of application

=IL

o 0 67 67 100 100 67 67

100 100 67 67 200 100

Average for Sources

Ntha

AS 260 gres 279

320

Source f5

-

AS AS Ura Urea SCU SCU

Yield

Relative

93 100 115

(M)O

Yield

Increase Yield Due to N

(Ktlha) (mtha)

-212 245 033 274 062 260 048 297 085 315 103 325 112

Yield Increase

Relative

72048 067 100 108 161

(2)

- 39 shy

Short-statured high yielding rice varieties grown extenshy

sively in northern Peru require extremely high rates of conventional

N sources to achieve maximum yields The recovery of applied N is

extremely low due to the use of intermittent flooding This water

management system results in heavy N losses even with properly timed

split applications In search of simpler and more effective methods

of N management eight field experiments were conducted in the region

to evaluate sulfur-coated urea (SCU) an experimental slow-release N

source supplied by the Tennessee Valley Authority Rice yields were

increased an average of 59 more by pretransplant-incorporated SCU than

by urea or ammonium sulfate applied in the same manner SCU produced

excessive vegetative growth which resulted in yield reductions at high

N rates

Regardless of an assumed 48-higher unit N cost in SCU the

overall benefits of pretransplant-incorporated applications of SCU

were favorable since there was a decrease of 40 in the optimum rate

of N and the need for precise timing of application was eliminated

Pakistan--In Pakistan basal applications of AS urea and

SCU to rice grown under conditions of intermittent flooding in 1969-70

(table 18) indicate that SCU is a superior source of N as compared to

urea or AS when all N is applied at or before planting The data also

indicate that a yield response was obtained for P applications but a

comparison of N sources at each level of P indicates that no interaction

between N and P was present so that differences between N sources were

relatively the same at each level of P Yields were increased about 60

more when SCU was applied than when urea was applied Yield increases

with AS were only about 72 of the increase obtained with urea these reshy

sults do not agree with the generally-reported superiority of AS as comshy

pared to urea as a source of N for rice

- 40 -

In 1973 experiments were conducted in Pakistan using both

Basmati-370 and IRRI-6 varieties of rice grown under conditions of

When all N was applied at puddlingintermittent flooding (table 19)

or 12 at puddling and 12 at panicle initiation both AS and SCU were

superior to urea with SCU tending to be the most efficient source

However when N was applied 12 at transplanting and 12 at panicle

initiation SCU was the poorest source of N This would indicate that

the release of N from SCU applied at these times is too slow for optimwn

plant growth

In another experiment in Pakistan in 1973 no differences

in the effectiveness of urea AS or SCU were noted in the yields of

continuously-flooded rice (table 20) Again these results are conshy

sistent with earlier results which indicate no superiority for SCU

when rice is continuously flooded

Nitrogen Studies--Maize

A series of three experiments were conducted by IITA in

armo-Nigeria in 1972-73 comparing AS urea SCU and

CAN (calcium

nium nitrate) as sources of N for maize (table 21) A significant

yield response was obtained for N at each location but no conaistent

differences were noted amaong sources These results are consistent

with results at other locations which have not shown that SCU is a

superior source of N for maize grown over a period of 3 to 4 months

Nitrogen--Wheat

The yields of wheat in Pakistan in 1969-70 (tables 22 and

23) show that yields with SCU) tended to be lower than those with ureaJ

although at one locction where sorghum was grown followilng wheat with

Table 19

Yields of Basmati-370 and IRRI-6 Rice at Punjab Agricultural Experiment Station in Pakistan in 1973 Under

Conditions of Intermittent Flooding

Rate Yield Source of N Time of Yield (Mtha) Increase of N B-370 IRRI-6 Application Basmati-370 IRRI-6 Average (Mtha)

0 0 - 21 353 287 -

SCU 90 150 At Puddling 325 545 435 148

Urea 90 150 At Puddling 309 500 405 118

AS 90 150 At Puddling 324 529 427 140

SCU 90 150 Puddling 372 572 472 185 Panicle Initiation

Urea 90 150 Puddling 335 502 419 132 Panicle Initiation

AS 90 150 Puddling 353 529 441 154 Panicle Initiation

SCU 90 150 After Transplanting 312 562 437 150 Panicle Initiation

Urea 90 150 After Transplanting 340 624 482 195 Panicle Initiation

AS 90 150 After Transplanting 349 583 466 179 Panicle Initiation

All plots received 45 lbs P205acre as single superphosphate

Relative Yield Increase ()

Source of N At Puddling Puddling Panicle Transplant h Panicle

Urea 100 100 100 AS 119 117 92 SCU 125 140 77

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to sehesa citrata selmtliy or to ha csaducted

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to Ut~rta copal TVP AOP APP aed it at see tecastisix (table 14)

No dot lalt sewseltles teh draw tree thee results simouely em pear to tlvdl bsww they do stwgpt tbat forthew work with

MR to werramid so tbme sels

Table 24

LttcttF Swce MaPlate 06 ieldot IM AWaia CoelsANS at IITA (Ugboda ad Apoin ail sorit) aid at Ike (AUaba s5i series)

1973

Plate ot IP Apinu 5 poundebods A1ab

Ocrol 0 Z94 419 M)

Tr ipl ruprphite 20 349 3799378

Triple vepput 40 M09 410$

Triple 6wp~~b1 4271 4344 42250

Ammotw-ritpophW to 4201 4124 4040

Amosim-rdop~phlt 40 4270 4106 4231

AM tuo-polpephats 20 404 4244 3794

~eai~mpelppepbuI 400)49 4094

Cee m-pbpbt to- 59

momee eph lto 0 4192

LSO (0 0$) 29 1025

Th WPII

- 51 shy

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1 ~ ~ gmw 1pc~biofl- 9 Kla4v4h

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rico t IF t rume6 orth~ Caralto phoophale rocl QAR) vaUN pqU41 to

roopon from cmonetrat4 gsporphophai (CIP) who ort$o4 oil k

was 45j itwas tafertor vb protioo4 oil p war OS Ib 4iffer~c

in rtc reepos to X cod14 oo bo ttrit4 4 4 hvsciag of boil p

~ Pt o r11221 0 tP

c theto the rhimecyllndor of rico tots par to)14M4i1 roeoi~t

ed oil emd PA prior to tho ont of an~robi4 cMioe AA~ oIifoshy

nAte bYpot t taet~d tO fC4sin t~r 4PWden0 Of f Ot(tivshy

ofOWailiJtyno o prefla4 all Put that 4t01etoo 14 tvsIk

of the Ott to prvvld a 014for C4m0 44 mI 1 o4sf

EfftC ftPet141on AIAM-0 V f401td 4 4iv 440 Mtft

Aa torfat VampP f4MWfCi4W04wt0amp to 4eturWlI Ot(Wel~drIC ft

Ot f tM6 the flooded Ott 00 14 04019I Pft0uAw Of gAr~s~lr

pkS$t M40b MP) Tw P1101 Piset Prodwie W-e 10M0di Wr04

(10-1) emW 0aretilp ddw01at4 P WAA firom Rrth M~flRU414~$

wee cowiared with fie Md reWim 44104 proo~fo) foruk oith laWItter

I v te-PR P OW1004 4 4 O Wf ottil OW ellt Oo

Oveiel1 the 40tt dmcruie to effetotww Wtollowui Co fme

PR tpaUIB1I ldoltmo PR (pamwlatr) offr~- ArmeuM) 0 orwi

- 52 -

Effect of N Sourc6 and Water Management on Response of Rice

toe Zn- M Giordano J J Mortvedt OP Engelstad and Greenhouse

Staff Several rotes of CO(14H2)2 and (H )2So4 vith or without ZnO

wore applied to flooded and nonflooded Crowley oil (limed to pH 75)

to determine response of Bluebelle rice to Zn Yields with both N

sources veotrgreator on flooded then on nonflooded soil In the abshy

ence of applied Zn total dry matter production vith CO(NH2)2 was

slightly lower than with (NH)2S04 on flooded soil and considerably

lover on nonflooded soil Concentration of Zn wan higher in straw and

grain of plants roun on flooded than on nonflooded soil Although

concentration of P was unaffected by N source or Zn rate there was

som indication that cranslocation of P from straw to grain may be

depressed in nouflooded rice Concentration of N was lower in straw

grown on flooded than on nonflooded soil due to apparent dilution

thereas both X sources resulted in similar N concentrations in straw

at all rates of N application the N concentration in grain increased

with 0 rAse

feSpongi gf(SM to Chjorospodiostte and Related P Sources--

Si Allen and Greonhoue Staff A greenhouse pot experiment was

couct44d with corn Brown on Hountview silt loam to compare the ofshy

fectlivees of chlorospodiosito (Chlor-l) with concentrated supershy

phosphate (CP) Thomas slag and North Carolina phosphate rock (NC-PR)

Oil-prillad urea-phophato rock (UPI) FeA1JMP 20 7 and monomthyl

phosphate were included in the experiment Based on yield of forage and

uptake of P by tvo crops each of 6-weeks duration the following conshy

stui were dravat

I Chlor-1 was slightly loss effective than CSI Thomas slaS or NC-PR

from which Chlor-l wae prepared

- 53 shy

2 Granular UPR was a poor source of P its effectiveness was greatly

increased by reducing the particle size to -35mesh

3 FeAlNH4P207 was unavailable to the crop

4 Monomethyl phosphate was equivalent toor slightly more effective-

than CSP

Research Indirectly Related to TVA-AID Project

Response of Several Rice Varieties to Zn in Moist or Flooded

Soil--P M Giordano J J Mortvedt and Greenhouse Several varieties

of rice from Mexico and the Dominican Republic currently under investishy

gation in Puerto Rico for adaptation to upland culture were compared with

some established United States varieties with regard to Zn response on

moist and flooded Crowley sil (pH 75) Chontalpa (Mexico) Bluebelle

(Texas) and Starbonnet (Arkansas) were most responsive to applied Zn

Juma (Dominican Republic) intermediate and Sinaloa (Mexico) and Calrose

(California) were the least responsive The Sinaloa varieties (Mexico)

appeared to be best adapted to non-flooded conditions whereas Chontalpa

and Calrose were poorest Concentrations of Zn generally were higher in

plants grown on flooded than moist soil

Pattern of Growth and Zinc Accumulation by Rice--P M Giordano

J J Mortvedt and Greenhouse Staff Rice plants were harvested at weekly

intervals from shortly after emergence through maturity The objective

was to determine the rate of growth and Zn uptake by a Zn responsive varshy

iety (Bluebelle) and a less Zn-responsive variety (Calrose) in the presence

or absence of Zn applied to Crowley sil (pHl 75) Dry matter production

of Calrose was linear with time of growth and of a similar magnitude until

heading with or without applied Zn Bluebelle followed a similar pattern

where Zn was applied However in the absence of applied Zn foliage yield

was reduced markedly

-54

Uptake of Zn was similar for both varieties whenZn was

applied Dry matter production and Zn uptake by the two varieties

also were comparable when Zn was applied However yield of Calrose

was much higher than that of Bluebelle in the absence of applied Zn

while Zn uptake was only slightly higher This suggests that the lesshy

ser responsiveness of Calrose to Zn may be due to more efficient utilishy

zation of Zn There was no indication of a greater demand for Zn durshy

ing reproduction in either variety as was suggested in earlier greenshy

house experiments

Response of Upland Rice to P and Zn--P M Giordano J J

Mortvedt and Greenhouse Staff Several rates of P and Zn were applied

to Crowley sil (limed to pH 75) in factorial combination to determine

whether differences in rice growth under flooded and nonflooded soil

conditions are related to plant nutrition Although straw yields were

slightly higher in nonflooded rice receiving adequate P and Zn grain

yields were higher in the flooded crop increased rates of F andor Zn

did not result in equal yields Except in the highest Zn rate (75 mg)

concentrations of Zn in both straw and grain were higher with flooding

Concentration of P increased with rate of applied P and was higher in

the grain or flooded than upland rice at a comparable P rate In conshy

trast concentrations of N were lower with flooding due in part to dilshy

ution from increased growth

Rice Response to N and P in Flooded and Unflooded Cultures--

G L Terman S E Allen and Greenhouse-Analytical Staff Rates of

N from 250 to 2000 ntpot and P from 0 to 1000 mtpot were applied for

Nato rice grown on Mountview sil and Sango sicl (625 kg of soil per

pot) Market yield response to N and P was obtained Yields of straw

- 55 shy

total yields N uptake and N recovery were higher on unflooded than

on flooded soil cultures Grain yields however were slightly higher

with flooding These results indicate that with adequate applied

nutrients especially of N rice yields without flooding can approach

or even equal those under flooding

Uptake of N P Ca Mg and Zn increased with yield response

to N and P while K uptake decreased on the Mountview soil Concentrations

of N and P increased with applied N and P respectively while concentrations

of other nutrients were diluted in most situations with yield response to N

or P

Results from this experiment show that amouats of N applied in

previous pot experiments for rice have been much too low especially if the

crop was grown to maturity

Response of Corn to S and N i UUASand Urea-S--S E Allen

and Greenhouse Staff Three greenhouse pot experiments were conducted to

measure response to S and N in ulfur coated urea (SCU) urea amonium

sulfate (UAS) and urea -S as well as estimate N losses from surface apshy

plied N sources

In Experiment 260 less than 20 of the S mixed with the soil

was recovered from SCU or urea-S granules by two crops of corn as comshy

pared to 45 or 80 from flowers of S or Na2SO 4 CLop response followed

a similar pattern

In Experiment 260-A N sources were surface applied and alshy

lowed to dry for two weeks before incorporation Into the soil and plantshy

ing Recovery of N by two crops of corn was 77-82 for AN an compared

to 37-70 for urea UAS urea-S and ICU Thus n this experiment loss

of N from urea did not appear to be re~dcud by light S-coatlngn or by Inshy

corporating S or AS in the granules

-S -

I xbprZnSlt a Wtch aU Meyto 0-Ai Wt f9r

higher reermo teOrtOrs cOM reSpWNO i r0100 Of N w

not oaisteontly related to sewe ot N In edl tust 0 ioltiUe Lim

lo in VMuwpped evlmtUTS 48 merind by seirest nte appresOehe

501 for uroa as cwarod to 210 for urea peepha

Rus- or Upse to LoAmIl34I a AriMed bI Earl U

MW NOWlsIIsIr-4 L Toman 5 1 Alln and eesese StNf rio

row on Sawg did (0 tpot) We 1l0l0 Ws feritiud vith 05is

of Npot mixod with the 6011 as aureCA NiAO) 1 Age god At Ures

was also itcluded at rtt t 05 10 end 15 of Upee Theas trealshy

onto were followed 4 wpdrsetago of U s AN wre 4C 10o or at I3n

Weeks toulin up to IS pot

A soil application of 10 pot rosulvod to the maim yield

at 4 weeks Tio4 sad percont prottis t intre raite tncreased rftishy

linearly with U applictalien IeseeItally all at the m iNd wit

the moil w domitrifted after flooding Grail end straw Ilelds vere

highly correlatod with tiliriag and vlh ubers of gralm arl

The results Widicat that 0$ to 10 a of Upot as orea or

NN bsuld be sied with the oil to stilate tiilrir with adshy

ditional 0 topireased later to increase grain lIds mad protia cmshy

tout

DIVISION 54- FERTILIZER TECHNOLOGY AND USE

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-02

792 60L WI W A)49R Pio VOL 37 197)

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DIVISION 8-9-SOIL MINERALOGY

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65

0IL CL OC AMXR PROC VOL 38 1974

)aT1 S4I104 ow Lusanll Tawng isa tall Thai variety known for beingIwo nonshyi s s ) sensitive to photoperiod A split-plot design was used in

S e e these euperimeots with 4 rates of P (I1 22 44 and 88t i V IV k of Pha) applied a main plot treatments and with the OF It sourMes of P as subplot treatments There were two checkS plots in each rmplicate The extra check plot was included to permit the application of fresh TSP standard Jor the

It- ti 06 + i bull fa succeeding crop the p-4me of bi was to permit accurate d awrnwal of the mdual effectiveness of the phosphate

ftinSUbI rock The P fertilioers were broadcast on the mud andthen Worporald In the soil during the last harrowing At

whM N both On ACS indx ampM time of transplanting Immediately before the last harrow61t (4j 5 4 01 P s 3Mm o Vallonal in con n 100 kgha of N as ammonium sulfate and 33 kghaWO Of Spews ampm lIW thaabe rocks do ACS indes of K as polium chloride were applied A total of 40 wa in prepw O do ctih k otent kha of N a ammoniunt sulfate was applied later in twoir P The hew oNed amp wM W for 5 of gw topdrossingp with about 5cm depth of water on the plotsvV I aiOMveffeOctveee Three to six ldayold selings pr hillwW the ACS idex were planted00OWW wia Oft fo an c irNk I p Coen 20 by 20 cm part in straight rows Hand weeding was used

and insecticide were applied for Insect control Grain yieldw was masared by sampling 5 ml of each plot excluding border rows The date of heading in each treatment and theUNiN d pbM W Weks rin tOW USA UMe In Tale yed componnts at hafvel were also recorded

I filM rsperMS esOM kdwdua 1 t ab The average yields of ough (unhulled) rice for botha 84 OW O 8uo 4 Thala TM was a locations are ploutel in PIS 3 for the first crop (1969 wet

owou thRM seaso0) The Veamps yield response was obtained at Klonge (s) W lDtO t Of dMa of1tw W d l R Luang however a 4ute satisfactory yield response was

~Mk ^d TVA UJSD ad Kd UnIveS obtalned to applied P at Bangkhen as wellXUe LaM e R qwrw Ims The sod was do Relative aponomlAe effectiveness values were calculated

VOW (a ksA w edmwL t Poesesm h Vy for these data and am presented In Table 3 The valuesdAY buo if dIe ouh ne Pee wtk a Mlak vow 1009 for th first crop are plotled against ACS index in Fig 41 This Im M i6ti l 4bNd IO a0 O mkarnk for both locatio r relationship was linear for the

11400 ThCpH 0( lb pW IW 01 th UpeiaW so Sanodion location and curtiltnear for KIng Luang The was u i 4A sksamp lMaor nrusio model amparounted for 81 of theAmO$MI Aw jAAsue Swim T1 Snh Wd variation In the AE valu for Bantkhen a square root

Mems a Iw iv fern alh$ sedm haowg dayNW W t he plAL At tdo M tM aso W s as ctminued throufh eltaM t Ofpof -le lse wo am P OeNI VeOpls 1o ealluae tI lon4erm MIdual Offccls

A on W isset i a wse to hsh eapeel of these ooihss t ocks The baagkhon experimnent was letmiaI1DlVemisthis is a w hulu Lo g Tasug ia iasael aft - Msd residual Ves will be pr-Om crok TheseTwod esewm

SWWo

A

lP~U~7 ISIIPe1iuIWN e bsedisssin ian ghth siaoelalbe

984 0 6 O O - M s -s fWPas 11eSft W d Uo al a o

o

S4l~ lIIII I~l I 1f fl

( +

+ + + m + ++++-

++ +(++ + ++++ + ++ ++

- 66 -

ENOIMLSTAD ET AL RESPONSE BY FLOODED RICE TO PHOSPHATE ROCKS VARYING IN CITRATE SOLUBILITY

I I I I j0 I I

BANOKHEN BANGKHEN

pH 56 6 - 0o

TSP

NC

5~ ~ ~ L o 4 - -shy

4 ] - --------shy04

6S

|0 III 2 44 8r 66

I I I

a 1KLONG LUANG

pH 46 z KLONG LUANG

TSP Sc2 NCFL(N)

5 FLIC) J0 TU

oshy

4 ~40shy

3 bull eM0

I - I I I I I

0 II 22 44 88 0 5 10 15 20 IP APPLIED KO HA ABSOLUTE CITRAE SOLUBIITY INDEX

Fig 3-Yield of rough rice at Klong Luang and Bangkhen Rice Fig 4-Relative agronon effectiveness () of P sources ploz-Experiment Stations Thalmand as affected by rate and Source ted against citrate solubity Index for both Thailand field ex

of P applied (crop 1) periment (first crop only)

regression model accounted for 97 of the variation in sumably resulted from crop uptake and reaction with the RAE values at the Klong Luang location soil to form less soluble products Such effects may have

These experiments were continued during the dry season been more important at the lower rates since the two TSP of early 1970 to ascertain the residual effectiveness of the curyes converged at the highest rate of application various sources applied to the first crop No new P was These data from KIong Luang indicate that (i) residual applied except for the fresh TSP standard mentioned effects of all rocks except Mlcwuri were substantial (ii) above rhe experiment otherwise was conducted in a man the relationship between relative agronornic effectiveness ner similar to that followed in the first crop of the phosphate rocks and citrate solubility levels was

The response to both freshly applied ad residual P was largely obscured and (iii) the general superiority of TSP marked at the Klong Luang location and marginal at over phosphate rock in terms of effectiveiss persisted Bangkhen In fact at the latter location the response was through the second crop so small that little can be said regarding residual effectiveshyness The yield data from crop 2 at the Klong Luang DISCUSSION experiment are plotted in Fig 5 Greenhouse and field data presented in this paper show

Relative agronomic effectiveness values (Table 3) were clearly that there are substantial differences among phosshycalculated for the Klong Luang data using both the residual and freshly applied TSP as standards It is of Interest to note that the superiority of TSP over the phosphbte rocks Table 3-Relative agronomic effective values for field experishyments in Thailand persisted through the second crop The main difference in KlowlZmlnql~the residual effects is that with the exception of the MIs- s Crop 1 Crop 21 Crop 1-shysouri rock Ihe marked relationship between citratr-soluble WoiCarolina yl 59 76

phosphate rocks and RAE had largely rds norh) a 64P conltct of th Florida (eqlral is 6969 6

disapipeared In this acidic soil (pHi 46) P would by this I14o 69 63 40 ToonesS 31 65

limo be supplied by Intermediate reaction products In addl Missou 0 o lion to residues of the initial spatlte Ts P o 2 o 0

The TSP applied to the first crop declliv-d slightly In campIafcmWataesr e id ofeuhuloefor 22MA rates of PtColeouattd as aba u tlte td18 kS ratesp dlverage yield tM868 to 22 44

effectiveness relative to the freshly applied ISP This pre- of d s4

A

4

- 67 shy

-SOIL SCL SOC AMER I

KLONG LUANG CROP 2

Si 3

eN

TAPPLIEDKGHA

Fig 5-The residual effectiveness ovarious P sources for crop s compared with freshly applied TSP Klong Luang Rice

Experiment Station Thailand

phate rocks in terms of agronomic effectiveness for flooded

rice Further these differences can be predicted by means of citrate solubility or by the ACS index It appears that

the latter is more appropriate where the content of apatite varies among phospiate rocks The most soluble phosphate rocks approached but did not actually equal TSP in limit-iuig (maximum) yield in these experiments regardless of rate applied This agrees with the results of Ensminger Pearson and Armiger (4) One needs to consider the defi-nite posribility of same yield loss in zhoosing a phosphate

rock over TSP such yield losses must be weighed against the lower price of phosphate rock The explanation for such iosses may involve concentration of soluble P in the soil Khasawneh and Copeland (6) suggest that the growth rate of crop plants is a function of P concentration that can be maintained in the soil solution If P concentration is limiting or inadequate becawe of a lower dissolution rate of phosphate rock the growth iate ard uiiimate yield will be diminished accordingly

The RAE values bascd on yield increases reflect the agronomi effectiveness of these various sources relacve

to the TSP standard however these nould be supple-

mented by an economic analysis before rational choice can

be made The following calculations will provide an estimate of

the rclativ ecooomic effectiveness(REE)

Y t Ps aXpatREE -- 100

vahtercks t sphate or e b i- eor

Price of TSPkg fo

be Price of PRkg P

PROC VOL 38 1974 leO

90r

Wsoshy

0

60-LUSEPHOSPHATE ROCK

00 10 20

PTP PR

Fig 6-Relationship between relaZive effectiveness values (RAE) and the price ratios between TSP and phosphate rock Such a figure can be used in making a choice between these

sources

If REE exceeds 100 in this calculation the phosphate rock would be preferable to TSP

The REE calcuktaaa wre used in preparing an indifshyference curve (Fig 6) wherein RAE values are plotted

against PTsPPpR ratios The cu~rve itself connects those points at which REE equals 100 When exactly on the curve it makes no real economic difference what source is chosen After choosing a suitable price ratio one can then project upward from that ratio knowing the RAI

value (or estimating it from such data as shown in Fig 4 using citrate-soluble P content) one can then choose the source on the basis of both agronomic and economic conshysiderations For example if the price ratio is 25 and the RAE value of the phosphaite rock is greater than 40 the rock phosphate in question would be used However if the RAE value was less than 40 TSP would be a better choice There are indications that if the P in the more soluble phosphate ro~cks (North Carolina north Florida central Forida) is less than half as expensivz as that in TSP these rocks would be feasible altereaives to TSP on soils similar

to thoseused in Thailand This analysis does not take into account the possibility

of lower yields from use of phosphate rock In addition only a portion of the various yield response curves was used in this anlysis ie up to 22 kgha Beyond this

rate yield response was much less pronounced it could be argued that at less than maximum yields TSP would produce a certain yield at lower rates of P than would phosshy

pow ofrock This would especially be true for rates applioa example at Klong Luang 5500 kg of

rice pcr iectare could have been produced with either Ii kg of P as TSP or 44 kg of P as son of the more reacshy

tire phosphate rocks It should be pointed ot however

- 68 shy

(IIKIS amp YOUN( ARIFICIAL WEATIIERING OF OXIDIZED p[ll- IV

that this is the yield level that would show the widest difference such is the advantage of hindsight

Farmers generally prefer granular fertilizers for machine

or hand application This is a disadvantage for the phos-phate rocks which are normally arplied in finely divided form Recently experimental quantities of granular urea-

phosphate rock mixtures have been made by TVA Results of trials with these fertilizers will be reported elsewhere

LITERATURE CITED

1 Armiger W H and Maurice- Fried 1957 The plantavailability of various sources of phosphate rock Soil Sci Soc Amer Proc 21183-188

2 Bengston G W E C Sample and S E Allen 1974 Re-sponso of slash pine seedlings to P sGurces of varying ci-trato solubility Plant Soil (In press)

3 Caro JIt and W Hill 1956 Chard eristics and fer tilizcr value of phosphate rock from different fields J Agr Food Chem 4684-687

4 Ensminger I E R W Peirson and W II Atmiger1967 Effectivencs of rock phosphate as a source of phosshyphurus for plants US Dep Agr ARS Bull 4112S

5 Engelstad 0 P J G Getsinger anid I J Stangel 1972 Tailoring of fertiliers for rice cnnece Valley Author ftyNational Fertilicr Developmnent Center Hull Y-52

6 Khasawnch F E and Jane P Copcland 1971 (otton root growth and uptake of nutrievos relation oif phosph

rus uptake to quantity intensity and buffering capacit) Soil Sci Soc Amer Proc 37250-254

7 Lehr JR and G H McClellan 1972 A revised lIbora tory reactivity scale for evaljativg phosphate rocks for direct application Tennessee Valley Authcrity National Fertilizer Development Center lull Y-43

H Terman G L S EAllen and 0 P Engelstad 1970 Response by paddy cice to ratcs and suurces of appliedphosphorus Agron J63390-394

DIVISION S-9-SOIL MINERALOGY

Artificial Weathering of Oxidized Biotite IV The Inhibitory Effect of Potassium on Dissolution llate

R JGILKES AND R C YOUNG2

ABSTRACT

Rates of dissolution of oxidized biotites in OIM 001M ICI are severely depressed in the presence of IM KCI The amovnts of Al Mg Mn dissolved in the first eytraction are similir to those found without KCI however subsequent extractions remove these elements at 10-20 of the corresponding lICI rates This effect may be due to a decreased rate of vermiculite formation thereby reducing the effective basal area exposed to attack A decrease in dissolution rate with increasing ferric iron content was still apparent in the presence of IM KCI

Additional Index Words X-ray diffraction infrared aborp-

N EARLIER papers of this series the tole of biotite in soils

as a source of both macro and micronutrient elements

has been discussed ((Gilkes Young and Quirk 1972 1973ab) Experiments in artificial weathering uiing as va-

riety of extractants were undertaken to determiie the inlu-

ence of oxidation of octahedrally coordinated iron on the bull release of structural cations to solution The results of this

work demonstated that biotite behaves anomalously with respect to the other common ferromagnesian minerals found in soils Oxidation leads to the development of a high degree of resistance to cation exchange and dissolution Several authors have coiwludcd that decreased rates of K

Contribution from the Dep of Soi Science and Plant Nutri-tion Institute of Agriculture Univ of Western Australia Ned-lands 6009 Western Australia Received 29 Sept 1973 Ap-proved 8 Jan 1974

2 Senior Lecturer in Soil Science and Research Officer respeclively

replacement in electrolytes shown by oxidized biotites are

a result of the inclination of structural hydroxyl adjacent to newly created trivalent iron or vacant octahedral cation sites (Robert and Pedro 1959 Barshad and Kishk 1968) Gilkes et al (1973b) suggested that decreased rates of disshysolution of oxidized biotite in 0001 0t)l 0Af CI may also be due to the presence of inclined hydroxyl In this case a smaller surface area external and exposed intershylayer may be available for attack if K replacement by hyshydrogen ions occurs at a slower rate in oxidized biotites

Gastuche (1963) has shown that significant dissolution ofthe (IIM) biotile face may occur and it is easily demonshystrated that the proportion of exposed (001M) face in weathering biotites depends on the percentage K replaced

Rausell-Colom ct al (1965) have shown that hydrogen ions act in an identical fashion to metal cations in K exshy

change from micas In particular exchange c-f K by hydroshy

gen ions will be terminated or greatly reduced by high levels of K in solution Thus if dissolution of oxidized biotite by

acids is carried out at sufficiently high K levels to prevent vermiculization any differences in dissolution rate that may occur cannot simply be ascribed to differences in rates of K replacement The following results were obtained from such an experiment which unlike the experiment described in Parts I and II (Gilkes et al 1973ab) does not attempt to simulate natuiral - conditions

MATERIAILS AN) M HIiODS Further subsamples of the less than 0 hiotites used in K

excherandbaid disoo tu es (G iles e9n K exchange and acid dissolution studies (Gilkes et al1973ab) were used in these experiments Preparation of sequentiallyoxidized biotites without intermediate vermiculite formation is

Page 5: I70 - United States Agency for International Developmentto ascertan, but tgl.eetad, 1, L,. ("Tailoring of Pertiltiters for ice,'" TVA ulletin Y-52) states that the staft of IOi has

-2-

The need for fertilizers containing secondary andor microshy

nutrients will be evaluated in several countries where deficiencies

are known or suspected but where no commercial sources of these nutrients

are presently available

Additional data has been received from a number of countries

pertaining to the use of SCU for rice In general these data tend to

substantiate those previously reported in that SCU is a superior source

of N for rice grain under conditions of intermittent flooding but that

it is no better than conventional sources of N when conditions of intershy

mittent flooding or severe leaching do not exist A discussion of the

commercial potential of SCU in tropical agriculture follows this section

Insufficient data are available for tropical crops other than

rice to warrant any general conclusions at this time

-3-

POTENTIAL FOR USE OF SULFUR-COATED UREA

The major portion of the agronomic research reported herein

deals with the evaluation of SCU (sulfur-coated urea) as a source of

nitrogen for rice These results generally confirm those previously

reported by TVA (Tailoring of Fertilizers for Rice TVA Bulletin Y-52

December 1972) in that SCU is a superior source of nitrogen for rice

grown under conditions where flooding is delayed or intermittent

However the results of some experiments from India and West

Africa where rice was grown under conditions where only leaching and not

both leaching and dentrification would be expected to occur suggest that

SCU may be a superior source of N for rice grown under these conditions

as well In certain parts of the world large areas of floating or

deeply submerged rice are grown very little information relative to N

response i available but in general yields are comparatively low

Further research is planned to 4valuate SCU for rice grown under those

conditions

The exact areamp of rice grown in developing countries under

conditions where both leaching and donitrification can occur is diffitcult

to ascertan but tgleetad 1 L (Tailoring of Pertiltiters for ice

TVA ulletin Y-52) states that the staft of IOi has ea|aited that uvor

7I of the rice in outheat Asia So Arown under this type ofter meASe

sent Prelisneary bfbervetio eu est Oat at t l PsIblySoea (a4

ofe) of tw frie to Vat Atfica to gmrae 4nder delayd of totriltest

irwiM4 to FAD report MD00llIO owtoifar f rce rt Imvi

W1110010 teveW ftJ 4 We 04001406w 1 141410tIf 0 ferl4iiio 10

-4shy

applied at a rate of 60 kg Nha then approximately 2600000 mt of

N could profitably be used as SCU In 1972 33700000 mt of N was

used in the world and these figures suggest that as much as 8 of the

world consumption could potentially be expected to be applied as SCU

on rice

On a smaller scale approximately 114000 ha of rice are grown

in Peru nearly all of which is grown under conditions where SCU would

be the most desirable source of N Average rice yields in Peru are about

4000 kgha but research by Sanchez and coworkers (see attached report)

indicates that with ample N yields of 9000 kgha can be attained To

obtain these yields 25500 at of N as SCU would be needed compared to

42000 at of N as straight ure to obtain the same yield Thus SCU

would save 16500 tons of N or roughly 40 of the N needs

Results from India indicated that when equal amounts of N were

applied an average of about 1000 kgha more grain was produced on exshy

porLsentail plots This average figure included some areas where SCU was

not superior to AS In 1972 36500000 ha of rice were grown in India

with an average yield of 1616 kgha Proper use of SCU in place of

conventional form probably would not Increase yields an average of 1000

kghe under fam conditions as it would on the research plots but an

average of 500 k8 would be raoom ble This would rotult to an Increaa

of a50000 m of rice an Incras of 311 over the 197 production of

$90o000000 mt

The 40 04Melee Ore cited t dMWMaftampt tbe iAnCicoo in

ftc prodwilu peble Ihrow~h proer t o of 60 a wvrf of 0 for

fiff MWere- f04ieb di at Peded t1 1if1 pfJiiea1y 4i fie toshy

ditlsw winde Iee idveitu f~ rics a to JMe(0wiaihthe of 1CM La f

-5shy

precisely evaluate the economics of its use

Preliminary data indicated that SCU may be a superior source

of N for other tropical crops particularly long-season crops such as

sugar cane and pineapply grown in areas of high rainfall

The results of the wheat experiment followed by sorghum in

Pakistan in which the residual effects of SCU were evaluated suggest

that in intercropping and multiple cropping systems fertilizer nitroshy

gen may be applied in a slow-release form (SCU) at a convenient time in

the cropping system so that the nutrient elements will be released for

utilization by succeeding crops

Information already obtained indicate that SCU is a superior

source of N for crops grown on large enough areas to economically justify

its commercial production As more data are obtained with more crops

and from new areal the potential for its use will undoubtedly increase

Consequently as adequate supplies become available programs need to be

initiated in selected areas to introduce the use of SCU to agricultural

extension workers to the fertilizer industry end to farmers and to

encourage its coinercial production Since the cost per unit of N will

always be higher in SCU than in regular urea the use of SCU will be

econmically practical only under specific conditions and these restricshy

tions as to its use make it perative that effective education and

inforuation progra- be conducted prior to the comerctel Introduction

Of SU On 4 Wid eeie

-6-

BACKGROUND AND OBJECTIVES OF PROJECT

The present project is designed to capitalize on the momentum

and knowledge gained in the previous project Tailoring of Fertilizers

for Rice This project demonstrated that a superior nitrogen fertilshy

izer can be developed for tropical areas and that some relatively low

cost phosphate sources can be effectively utilized The present project

seeks to broaden the base for development of improved fertilizers through

a wider range of agronomic economic and engineering evaluations Preshy

viously the emphasis was placed on SCU as a nitrogen source and the dirshy

ect application of a limited number of selected phosphate rocks as phosshy

phorus sources for rice fertilization In this project a wider range of

fertilizer materials will be tested on a variety of upland crops such as

maize wheat sorghum and sugar cane cassava and others of national imshy

portance in various countries

Through its domestic fertilizer research and development proshy

gram TVA produces experimental fertilizer materials that may have poshy

tential for tropical soil conditions and crops With support from AID

in this project the capability viii exist to work toward improving fershy

tilitors for developing countrive through the necessary and logical soshy

quenco of production to ramer aceptonce to sess the potential for

co mrcial production

Pertilliers now being used in 4eveloping countriee relAtive

OeCOtcs And shortcoMiNge of the Mterials viii be Ovai6Isd Ktshy

true thel ena 4 4 0(fiashyporimrtAl product wlornriee pilot plt

ties OaI1 pl0t4 Will be W0bsutd to fcresMq tet in jre

tof f~wrisea with caomvstmwl siatofials rr f P0041610 161i

-7shy

screening will be done using soils of the area where the fertilizer

will be used Materials showing potential in greenhouse tests will

be further evaluated in actual field programs in selected countries

If successful at this stage economic and engineering data will be

compiled to assess the potential for commercial production In orshy

der to evaluate the product and process the total system will be

studied including storage handling and transportation from the

point of production to the farm Information developed throughout

this work will be available to industry foreign and domestic so

that it can develop a production marketing and use base for utishy

lizing the product This level of technology is rapidly being achieved

for SCU which received major emphasis in the previous study additional

agronomic economic and engineering data both with rice and with other

crops will be obtained to complement the previous findings

This project must be broad and combine a variety of professhy

sional disciplines but it is necessary to retain the flexibility to

move forward in specific directions as Improvements in products occur

This is necessary to insure that improved products identified in this

project can ultimately be made available to farmers zegrdless of their

economic and social status and that sufficient data aro available so

that induetry can make soomd decisions regarding the foasibility for omshy

marcial production

Major objectives of this project are eommartted as tollovws

(1) Developing Iertilaers to wt the nutrient neD of oocitic

4I l VhICh are not set iconmically withtfopical Crops and

etoshytoov~tmtl| Nrtiliieoro or that can set thse ne- s fre

006eItCOMlY ky 4ir lfte the W91~1ici of teftlliaer ultil4tin

-8

(2) Proving the value of these improved materials to insure that

they will increase farmers income over a large enough area

to attract and Justify commercial production

(3) Developing the production technology for new fertilizers as

a basis for encouraging and advising potential commercial proshy

duction The integrated process designs will seek product

quality and economy while striving to minimize harmful emisshy

sions to air water and land

(4) Working through cooperating organizations and with leaders in

research extension and industry to develop and demonstrate

methods for introducing new fertilizers to farmers so that they

will be properly used when they become commercially available

-9-

SCOPE OF WORK

This project integrates agronomic economic and engineering

expertise into a single team in order to develop improved fertilizers

for a wide range of crops and soils in developing countries Considershy

able emphasis is given during the first eighteen months to collecting

the data needed to complete the evaluation of sulfur-coated urea and

ground rock phosphate for lowland rice Both materials then are

scheduled for demonstrations during the latter part of the project in

order to educate extension workers and farmers and to attract the fershy

tilizer industry into commercial production Considerable emphasis is

given to the economic evaluation of a total production-marketing-use

system for each material in contrast to alternative nutrient sources

The probability of commercial production of SCU and ground

rock phosphate can be enhanced by expanding their use to additional

crops and soils Thus the project is expanded in scope as compared

to the previous project on tailoring of fertilizers for rice in order

to test these materials on additional crops

The expanded work includes a major effort in screening and

testing new compounds and forms of fertilizers for various food crops

produced under tropical conditions Alt hough it if already known that

more effective andor lens expensive formn of nitrogen and phosphorus

are needed a literature survey will nerve an Lan additional guide to

important and presing fertilizer problems

-10-

Much of the work with fertilizers for both lowland rice and

upland crops will consist of field tests in Southeast Asia Africa and

Latin America Greenhouse and engineering studies will back up the field

research All field experiments are designed to provide at least an esshy

timate of costs and returns for each fertilizer tested

PROJECT PLANS FORFISCAL 1975

In this section the work for fiscal 1975 will be discussed

It should be remembered that the success of this project depends in a

large part upon maintaining sufficient flexibility so that work in inshy

dividual countries can be adapted to supplement and complement programs

already under way While guidelines and plans of work must be developed

so that the objectives of the project are clearly defined detailed

plans for specific countries or groups of countries must be developed

by consultation wth local cooperators

These plans will be discussed under the following three general

phases of the project

I Engineering and development

2 Agronomic testing and evaluation

3 Economic evaluations

Engineering and Development

Phosphate Rock

Methods have been proposed for relatively simple treatment of

phosphate rock (PR) to increase the availability of the phosphate to make

it more suitable for direct application to the soil These treatments

may be economically feasible in certain areas especially in view of the

current world fertilizer situation Considerable work has been done at

TVA studying means of altering PR and plans are being developed to inishy

tiate further developmental work and field testing of these materials durshy

ing fiscal 1975

- 12 -

Emphasis will be placed upon obtaining samples of phosphate

rock from deposits in developing countries and testing and improving

procedures for increasing their citrate solubility and tzius availabilshy

ity of the phosphorus From this laboratory screening process sevural

sources will be selected from which small amounts (50 to 100 pounds)

will be prepared for greenhouse and field experiments ou various soils

(as described under agronomic section)

From these results one or two locations (or countries) will

be selected for development of a pilot program to utilize local sources

of phosphate rock This program will involve production of the altered

PR and its agronomic evaluation and then educational programs with govshy

ernment and commercial representatives to introduce its use to the farmers

Sulfur-Coated Fertilizers

Some preliminary work has been done in which urea-potash mixshy

tures were coated with sulfur The 7-day release rates for the N and

K20 were 17 and 36 respectively from the coated product (22-0-11-30S

grade) This was the first effort in coating a compound fertilizer

with the new coating system

The widely differing release rates for the nutrients from

the coated compound product raise some interesting prospects for tailshy

oring the nutrient release rate of sulfur-coated products It might

be possible to cogranulate materials of varying water solubility and

sulfur-coat them to produce products with release rates that would apshy

proximate the timing of nutrient requirements of the crop The need

for this type of controlled-release product has been mentioned many

times by agronomists and may be especially applicable in multiple and

intercropping systems

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Table 2

Mttct of 0 Sourco aampW $At On Upt~ks of 0 by Two Varitgtos of Paddy Rice

gr~a 1971

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- 24 shy

India--The results of four experiments conducted with flooded

transplanted rice in India by the All-India Coordinated Rice Project

Hyderabad are given in table 3 The response to N was excellent the

yield without N being only 41 of those obtained with basal applications

of N as uza With basal applications of SCU the yields were 20 higher

than with basal applications of urea and in the three experiments in

which urea applications were split yields with SCU were 18 higher than

yields with split applications of urea When comparing the average Nshy

response (kamp grainKg N) yields were increased 13 more by SCU than by

basal applications of urea

The data from one experiment with light irrigated rice in India

are given in table 4 yields were relatively low and differences between

N sources or method of application were not significant However yields

with SU tended to be higher than when all urea was applied at planting

but lower than when split applications of urea were applied Again yields

increased more than 13 more with SCU than with basal applications ofwere

ur

In tables 5 and 6 the yields of a short-duration transplanted

rice grown in irrigated light-textured soils at five locations in India

indicate that higher yields were obtained with SCU than with urea when apshy

plied as a basal application Yield increases due to basal N applications

were 502 greater with SCU than with urea However split applications of

resulted in yields equal to those obtained with basal applications ofurea

CU

The yields of direct-seeded upland rice grown at three locations

to India are given in table 7 and the relative yields in table 8 Yields

were low due to drought but good responses were nevertheless obtained for

- 25 -

Table 3

Effect of N Source and Time of Application on Yield of Paddy (Flooded) Rice in India 1972 (Summary of Reported Data from 4 Experiments)

Experimental Number Source Rate Method Yield Relative N-Response

and of of N of Yield Kg Grain

Season Nitrogen kgha Application mtha Kg N

- - - 196 34 -

Urea 120 Basal 573 100 314

11 Urea 120 80 + 40 611 107 345 Rabi SCU 120 Basal 713 124 430

12 - 0 - 202 30 -

Urea 125 Basal 682 100 384

Rabi Urea 125 35 + 20 + 35 + 35 633 95 344 SCU 125 Basal 781 115 463

13- 0 - 168 44

Urea 100 Basal 385 100 217

Kharif Urea 100 30 + 20 + 25 + 25 400 104 232 SCU 100 Basal 462 120 293

14 -

Urea -

125 -

Basal 355 650

55 100

-

236

Rabi SCU 125 Basal 781 120 341

-- 26 -

Table 4

Effect of N Source and Time of Application on Yield of Light Irrigated Rice in India 1972 (Summary of Reported Data From

One Experiment at Pattambi)

Experimental Number Source Rate Method Yield Relative N-Response

and of of N of Yield Kg Grain Season Nitrogen (kgha) Application (mtha) Q) Kg N

38 0 - 204 85 -Rabi Urea 120 Basal 241 100 308

Urea 120 60 + 0 + 30 + 30 267 ill 525 SCU 120 Basal 255 106 425

Table 5

Effect of N Source and Time of Application on Yields of Short-Duration Transplanted lice Variety Grown on Irrigated Light-Textured Soils at 5 Locations in India 1972

(Snmzarized From Reported Data)

Rate Grain Yields (MtHa) Source of N Method of N GrainI of N kgh Application Faizabod Karjat Mandva Pattabi laya Averaje X

- 291 266 211 19 340 260 -

Urea 100 Basal 386 407 361 285 482 3 124 Urea 100 50 + 25 + 25 399 430 434 334 6amp2 4A8 186

SCU 100 Basal 368 468 439 360 572 41 181

Table 6

Effect of I Source end Tlae of ApplIcattoo c RIstave Tle24 of a rt- rat1 T Lsd lice Vasrety Crin o Irrigated L41tshy1 at S Locitite mindi 1972

Rate ____________14_3

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- 38 -

Table 18

Yild of aemati-370 Rice at Punjab Agricultural Research

Institute in Pakistan in 1969-70 Grown Under

Couditions of Intermittent Flooding

Pate of application

=IL

o 0 67 67 100 100 67 67

100 100 67 67 200 100

Average for Sources

Ntha

AS 260 gres 279

320

Source f5

-

AS AS Ura Urea SCU SCU

Yield

Relative

93 100 115

(M)O

Yield

Increase Yield Due to N

(Ktlha) (mtha)

-212 245 033 274 062 260 048 297 085 315 103 325 112

Yield Increase

Relative

72048 067 100 108 161

(2)

- 39 shy

Short-statured high yielding rice varieties grown extenshy

sively in northern Peru require extremely high rates of conventional

N sources to achieve maximum yields The recovery of applied N is

extremely low due to the use of intermittent flooding This water

management system results in heavy N losses even with properly timed

split applications In search of simpler and more effective methods

of N management eight field experiments were conducted in the region

to evaluate sulfur-coated urea (SCU) an experimental slow-release N

source supplied by the Tennessee Valley Authority Rice yields were

increased an average of 59 more by pretransplant-incorporated SCU than

by urea or ammonium sulfate applied in the same manner SCU produced

excessive vegetative growth which resulted in yield reductions at high

N rates

Regardless of an assumed 48-higher unit N cost in SCU the

overall benefits of pretransplant-incorporated applications of SCU

were favorable since there was a decrease of 40 in the optimum rate

of N and the need for precise timing of application was eliminated

Pakistan--In Pakistan basal applications of AS urea and

SCU to rice grown under conditions of intermittent flooding in 1969-70

(table 18) indicate that SCU is a superior source of N as compared to

urea or AS when all N is applied at or before planting The data also

indicate that a yield response was obtained for P applications but a

comparison of N sources at each level of P indicates that no interaction

between N and P was present so that differences between N sources were

relatively the same at each level of P Yields were increased about 60

more when SCU was applied than when urea was applied Yield increases

with AS were only about 72 of the increase obtained with urea these reshy

sults do not agree with the generally-reported superiority of AS as comshy

pared to urea as a source of N for rice

- 40 -

In 1973 experiments were conducted in Pakistan using both

Basmati-370 and IRRI-6 varieties of rice grown under conditions of

When all N was applied at puddlingintermittent flooding (table 19)

or 12 at puddling and 12 at panicle initiation both AS and SCU were

superior to urea with SCU tending to be the most efficient source

However when N was applied 12 at transplanting and 12 at panicle

initiation SCU was the poorest source of N This would indicate that

the release of N from SCU applied at these times is too slow for optimwn

plant growth

In another experiment in Pakistan in 1973 no differences

in the effectiveness of urea AS or SCU were noted in the yields of

continuously-flooded rice (table 20) Again these results are conshy

sistent with earlier results which indicate no superiority for SCU

when rice is continuously flooded

Nitrogen Studies--Maize

A series of three experiments were conducted by IITA in

armo-Nigeria in 1972-73 comparing AS urea SCU and

CAN (calcium

nium nitrate) as sources of N for maize (table 21) A significant

yield response was obtained for N at each location but no conaistent

differences were noted amaong sources These results are consistent

with results at other locations which have not shown that SCU is a

superior source of N for maize grown over a period of 3 to 4 months

Nitrogen--Wheat

The yields of wheat in Pakistan in 1969-70 (tables 22 and

23) show that yields with SCU) tended to be lower than those with ureaJ

although at one locction where sorghum was grown followilng wheat with

Table 19

Yields of Basmati-370 and IRRI-6 Rice at Punjab Agricultural Experiment Station in Pakistan in 1973 Under

Conditions of Intermittent Flooding

Rate Yield Source of N Time of Yield (Mtha) Increase of N B-370 IRRI-6 Application Basmati-370 IRRI-6 Average (Mtha)

0 0 - 21 353 287 -

SCU 90 150 At Puddling 325 545 435 148

Urea 90 150 At Puddling 309 500 405 118

AS 90 150 At Puddling 324 529 427 140

SCU 90 150 Puddling 372 572 472 185 Panicle Initiation

Urea 90 150 Puddling 335 502 419 132 Panicle Initiation

AS 90 150 Puddling 353 529 441 154 Panicle Initiation

SCU 90 150 After Transplanting 312 562 437 150 Panicle Initiation

Urea 90 150 After Transplanting 340 624 482 195 Panicle Initiation

AS 90 150 After Transplanting 349 583 466 179 Panicle Initiation

All plots received 45 lbs P205acre as single superphosphate

Relative Yield Increase ()

Source of N At Puddling Puddling Panicle Transplant h Panicle

Urea 100 100 100 AS 119 117 92 SCU 125 140 77

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-48

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obosomhu rocks 0entk catetas rth Unrtdo costrat frwt) to

ht tse balt s Owosiv as that to TwP it rocks WM bo

fmtbt alteruutiv to MSso gotastte to~ Ik lee used to

ThUAIAd

Tht wMl dt gotmtmlaoti wout th possibility

of law Vhld free ww e1 e66001 4 It cooUt be YgWd Sutt

a4 10 0410 SWUSSM yt$4e TOP wUd predWr A r~ftIf fl~W t

1f f ot P the wuld phosphae rck TWOe viWMW efocitill b

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amp4at r per Wforssota Mav two 64eed Wilk elikor It 44 of

P go Mi er 4A bg oftoP aon of tewmrowtni pboophals fwAh

It vwld be polotrd A Wevero wtht Is the jteld level that

W414 gk tko videm dtterem~j o(A 1 the 4~etamp tk~e~t

P11~0 pra~lpj prefer gre4r tuftlter for whlae

of hoaw ppltrstie Mhe to a dloedveaP for The PINSOO rocka

vkth m r II spotted 10 ftewil 4106Me tem

Nub studios we ovsosd o IVA vol gramleid a

forgof wee aMW pbsepbots A fths pemhawe evsielew us

Odellod to detMlee it otteettvmm of 11agotated Stoture of

mmfp MW phapa A (CI) sed graewletod pampAtlti arlolatod Pa

asowcs of P tof ttde ro The wreem proucts omre raGther

pemour~a ot P syag besmti andMi as elt ov so gpamwhr

iuipiqffhate(TS) low twseeo Is eftwiltve Is thet

W41 preeme wae oialain ire post-rItoi effriq to Stanlato the

pud6itt of Irto paddle Wee ofsdlseireplastiq

0 49 shy

lbs partially scldiaatede grawilated Ml prodlucts Vere isshy

toiwdiats in 5tftOvttWS54 betwee wroiPi ad TVP NotV5Ymf to

me coo were they mere twoe $a a etfective ao TIP 00 sipifleast

LVSUMI5 at0 efecto wore toun tor thee produteo Timely dtIampWde

FR (-t00 mmoh) Uia amp~rally oar affective than Owe gra8448r FOampprodt

featal twos o 6 aotetire s I

Nowvero it to felt that sfortber field euprtet vth

hese interials Amd ether typs of grometatodl Wter nre wrrautad

hater ceeuwodh that they have me areec poteatlal toi additoG

e tate wAne the sectte as OtawrI sed bovoloen turther

euperimeste vth few reck pboophar s0d with reck pbophat treated

to sehesa citrata selmtliy or to ha csaducted

Metbir sertes of tbme enprtaeats wae c~edtmcted by IITA

to Ut~rta copal TVP AOP APP aed it at see tecastisix (table 14)

No dot lalt sewseltles teh draw tree thee results simouely em pear to tlvdl bsww they do stwgpt tbat forthew work with

MR to werramid so tbme sels

Table 24

LttcttF Swce MaPlate 06 ieldot IM AWaia CoelsANS at IITA (Ugboda ad Apoin ail sorit) aid at Ike (AUaba s5i series)

1973

Plate ot IP Apinu 5 poundebods A1ab

Ocrol 0 Z94 419 M)

Tr ipl ruprphite 20 349 3799378

Triple vepput 40 M09 410$

Triple 6wp~~b1 4271 4344 42250

Ammotw-ritpophW to 4201 4124 4040

Amosim-rdop~phlt 40 4270 4106 4231

AM tuo-polpephats 20 404 4244 3794

~eai~mpelppepbuI 400)49 4094

Cee m-pbpbt to- 59

momee eph lto 0 4192

LSO (0 0$) 29 1025

Th WPII

- 51 shy

101Y114 tpeM-fI PEP~tbRP YO

1 ~ ~ gmw 1pc~biofl- 9 Kla4v4h

Upia U04 Copfind am Crehout Stet Rpano at (Ia4

rico t IF t rume6 orth~ Caralto phoophale rocl QAR) vaUN pqU41 to

roopon from cmonetrat4 gsporphophai (CIP) who ort$o4 oil k

was 45j itwas tafertor vb protioo4 oil p war OS Ib 4iffer~c

in rtc reepos to X cod14 oo bo ttrit4 4 4 hvsciag of boil p

~ Pt o r11221 0 tP

c theto the rhimecyllndor of rico tots par to)14M4i1 roeoi~t

ed oil emd PA prior to tho ont of an~robi4 cMioe AA~ oIifoshy

nAte bYpot t taet~d tO fC4sin t~r 4PWden0 Of f Ot(tivshy

ofOWailiJtyno o prefla4 all Put that 4t01etoo 14 tvsIk

of the Ott to prvvld a 014for C4m0 44 mI 1 o4sf

EfftC ftPet141on AIAM-0 V f401td 4 4iv 440 Mtft

Aa torfat VampP f4MWfCi4W04wt0amp to 4eturWlI Ot(Wel~drIC ft

Ot f tM6 the flooded Ott 00 14 04019I Pft0uAw Of gAr~s~lr

pkS$t M40b MP) Tw P1101 Piset Prodwie W-e 10M0di Wr04

(10-1) emW 0aretilp ddw01at4 P WAA firom Rrth M~flRU414~$

wee cowiared with fie Md reWim 44104 proo~fo) foruk oith laWItter

I v te-PR P OW1004 4 4 O Wf ottil OW ellt Oo

Oveiel1 the 40tt dmcruie to effetotww Wtollowui Co fme

PR tpaUIB1I ldoltmo PR (pamwlatr) offr~- ArmeuM) 0 orwi

- 52 -

Effect of N Sourc6 and Water Management on Response of Rice

toe Zn- M Giordano J J Mortvedt OP Engelstad and Greenhouse

Staff Several rotes of CO(14H2)2 and (H )2So4 vith or without ZnO

wore applied to flooded and nonflooded Crowley oil (limed to pH 75)

to determine response of Bluebelle rice to Zn Yields with both N

sources veotrgreator on flooded then on nonflooded soil In the abshy

ence of applied Zn total dry matter production vith CO(NH2)2 was

slightly lower than with (NH)2S04 on flooded soil and considerably

lover on nonflooded soil Concentration of Zn wan higher in straw and

grain of plants roun on flooded than on nonflooded soil Although

concentration of P was unaffected by N source or Zn rate there was

som indication that cranslocation of P from straw to grain may be

depressed in nouflooded rice Concentration of N was lower in straw

grown on flooded than on nonflooded soil due to apparent dilution

thereas both X sources resulted in similar N concentrations in straw

at all rates of N application the N concentration in grain increased

with 0 rAse

feSpongi gf(SM to Chjorospodiostte and Related P Sources--

Si Allen and Greonhoue Staff A greenhouse pot experiment was

couct44d with corn Brown on Hountview silt loam to compare the ofshy

fectlivees of chlorospodiosito (Chlor-l) with concentrated supershy

phosphate (CP) Thomas slag and North Carolina phosphate rock (NC-PR)

Oil-prillad urea-phophato rock (UPI) FeA1JMP 20 7 and monomthyl

phosphate were included in the experiment Based on yield of forage and

uptake of P by tvo crops each of 6-weeks duration the following conshy

stui were dravat

I Chlor-1 was slightly loss effective than CSI Thomas slaS or NC-PR

from which Chlor-l wae prepared

- 53 shy

2 Granular UPR was a poor source of P its effectiveness was greatly

increased by reducing the particle size to -35mesh

3 FeAlNH4P207 was unavailable to the crop

4 Monomethyl phosphate was equivalent toor slightly more effective-

than CSP

Research Indirectly Related to TVA-AID Project

Response of Several Rice Varieties to Zn in Moist or Flooded

Soil--P M Giordano J J Mortvedt and Greenhouse Several varieties

of rice from Mexico and the Dominican Republic currently under investishy

gation in Puerto Rico for adaptation to upland culture were compared with

some established United States varieties with regard to Zn response on

moist and flooded Crowley sil (pH 75) Chontalpa (Mexico) Bluebelle

(Texas) and Starbonnet (Arkansas) were most responsive to applied Zn

Juma (Dominican Republic) intermediate and Sinaloa (Mexico) and Calrose

(California) were the least responsive The Sinaloa varieties (Mexico)

appeared to be best adapted to non-flooded conditions whereas Chontalpa

and Calrose were poorest Concentrations of Zn generally were higher in

plants grown on flooded than moist soil

Pattern of Growth and Zinc Accumulation by Rice--P M Giordano

J J Mortvedt and Greenhouse Staff Rice plants were harvested at weekly

intervals from shortly after emergence through maturity The objective

was to determine the rate of growth and Zn uptake by a Zn responsive varshy

iety (Bluebelle) and a less Zn-responsive variety (Calrose) in the presence

or absence of Zn applied to Crowley sil (pHl 75) Dry matter production

of Calrose was linear with time of growth and of a similar magnitude until

heading with or without applied Zn Bluebelle followed a similar pattern

where Zn was applied However in the absence of applied Zn foliage yield

was reduced markedly

-54

Uptake of Zn was similar for both varieties whenZn was

applied Dry matter production and Zn uptake by the two varieties

also were comparable when Zn was applied However yield of Calrose

was much higher than that of Bluebelle in the absence of applied Zn

while Zn uptake was only slightly higher This suggests that the lesshy

ser responsiveness of Calrose to Zn may be due to more efficient utilishy

zation of Zn There was no indication of a greater demand for Zn durshy

ing reproduction in either variety as was suggested in earlier greenshy

house experiments

Response of Upland Rice to P and Zn--P M Giordano J J

Mortvedt and Greenhouse Staff Several rates of P and Zn were applied

to Crowley sil (limed to pH 75) in factorial combination to determine

whether differences in rice growth under flooded and nonflooded soil

conditions are related to plant nutrition Although straw yields were

slightly higher in nonflooded rice receiving adequate P and Zn grain

yields were higher in the flooded crop increased rates of F andor Zn

did not result in equal yields Except in the highest Zn rate (75 mg)

concentrations of Zn in both straw and grain were higher with flooding

Concentration of P increased with rate of applied P and was higher in

the grain or flooded than upland rice at a comparable P rate In conshy

trast concentrations of N were lower with flooding due in part to dilshy

ution from increased growth

Rice Response to N and P in Flooded and Unflooded Cultures--

G L Terman S E Allen and Greenhouse-Analytical Staff Rates of

N from 250 to 2000 ntpot and P from 0 to 1000 mtpot were applied for

Nato rice grown on Mountview sil and Sango sicl (625 kg of soil per

pot) Market yield response to N and P was obtained Yields of straw

- 55 shy

total yields N uptake and N recovery were higher on unflooded than

on flooded soil cultures Grain yields however were slightly higher

with flooding These results indicate that with adequate applied

nutrients especially of N rice yields without flooding can approach

or even equal those under flooding

Uptake of N P Ca Mg and Zn increased with yield response

to N and P while K uptake decreased on the Mountview soil Concentrations

of N and P increased with applied N and P respectively while concentrations

of other nutrients were diluted in most situations with yield response to N

or P

Results from this experiment show that amouats of N applied in

previous pot experiments for rice have been much too low especially if the

crop was grown to maturity

Response of Corn to S and N i UUASand Urea-S--S E Allen

and Greenhouse Staff Three greenhouse pot experiments were conducted to

measure response to S and N in ulfur coated urea (SCU) urea amonium

sulfate (UAS) and urea -S as well as estimate N losses from surface apshy

plied N sources

In Experiment 260 less than 20 of the S mixed with the soil

was recovered from SCU or urea-S granules by two crops of corn as comshy

pared to 45 or 80 from flowers of S or Na2SO 4 CLop response followed

a similar pattern

In Experiment 260-A N sources were surface applied and alshy

lowed to dry for two weeks before incorporation Into the soil and plantshy

ing Recovery of N by two crops of corn was 77-82 for AN an compared

to 37-70 for urea UAS urea-S and ICU Thus n this experiment loss

of N from urea did not appear to be re~dcud by light S-coatlngn or by Inshy

corporating S or AS in the granules

-S -

I xbprZnSlt a Wtch aU Meyto 0-Ai Wt f9r

higher reermo teOrtOrs cOM reSpWNO i r0100 Of N w

not oaisteontly related to sewe ot N In edl tust 0 ioltiUe Lim

lo in VMuwpped evlmtUTS 48 merind by seirest nte appresOehe

501 for uroa as cwarod to 210 for urea peepha

Rus- or Upse to LoAmIl34I a AriMed bI Earl U

MW NOWlsIIsIr-4 L Toman 5 1 Alln and eesese StNf rio

row on Sawg did (0 tpot) We 1l0l0 Ws feritiud vith 05is

of Npot mixod with the 6011 as aureCA NiAO) 1 Age god At Ures

was also itcluded at rtt t 05 10 end 15 of Upee Theas trealshy

onto were followed 4 wpdrsetago of U s AN wre 4C 10o or at I3n

Weeks toulin up to IS pot

A soil application of 10 pot rosulvod to the maim yield

at 4 weeks Tio4 sad percont prottis t intre raite tncreased rftishy

linearly with U applictalien IeseeItally all at the m iNd wit

the moil w domitrifted after flooding Grail end straw Ilelds vere

highly correlatod with tiliriag and vlh ubers of gralm arl

The results Widicat that 0$ to 10 a of Upot as orea or

NN bsuld be sied with the oil to stilate tiilrir with adshy

ditional 0 topireased later to increase grain lIds mad protia cmshy

tout

DIVISION 54- FERTILIZER TECHNOLOGY AND USE

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-02

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e W d inSIWfh sil $ad doke IaefitV twoer) 1 Te to theo owie effu so booJ imik WOi 100 N

-d

Is re4aled uIwq~e~w Aueee atofurnw di Capsnm ptopeatls is a oommm eiws to 100 tom of 04404man d CtdUW 4M Anw K~a do Aamp apowee WPUaN powu eel H pae iaaa thAi SCUI isWW owr hmem ISsuppl N to the li ieee F A IM1 Nampa Obo~amie m

41MB ~ ~ m ~ ~0 0-- 0 140 The ffsemn of food Nn else9~e(Ud~ ~ ~ ~~ WooksaS eAWw pjed of ho~raw of IU effadam vfdva oft xhj0I 13iAl

DIVISION 8-9-SOIL MINERALOGY

Amorphomw CeetIup en XmWra Ssrfmls

L C koits Am~ 0 tmmkaAf

ommp A faieiaAMTRACT skiwe lo nW ampM sm wi4h

Walo by a onMm I dmivid hseidm6Wlk W~edesie s

peuiieles as is s e wpwigstee eded his S -em -om 0641 h4 hisW1mWOWb~ bfem peess Wimm kv Iee

Pa~~~eakr4awiS SeUeeiNaiA WOW 14e

PWWWW t HW f hea~I~~~~~a 0th

kog Ii ampI b 1111h1atAmOem aid itsaere~m-aelmoeug toolPe aal 111W mWa Wisg ag so~ ti~Wo booviot65k Th eme Iua 1111411uiwon it es 01000 AW~CWS ~muiseeteqqsheer21111 ionev

oO00 llb K0 ibad~ ~~ doj 140WI s o mimdW um

WLIMmAmMVL 1

lill mi oHow al of a be 1974oyais4gamm wsoc wwo

rdy i of OMAN toblind id sh os 00 IN bei m us salqs m kid Vw 1 a0Msw WFW isms waf e eeiWei he-4~~e gsa dulsi

os 0aMW ofmu WA l aduWs~Ib rowuvvl3maIpm s

CaO~OP aw AlNomI 4ornomd to9 IS is -l O SI g4he rpidyThus whim m dowu bWa 0 m m- ei u

d m M 0bmSaImu M-1 ofM6 h Intun to 7I

aiba maush WAesshwn~u9dSg a osusLwpI ~ v m

M PolsdAvoWdw Ons pugm~ low iwLW m We

of~U -a~ mo uNo

0401ts of 40

A e mun5d m i vvamp sa s ow bftIS i sa omdIs a w

edi1 hswopmo an ag am Iw anom erlwaPASneooie bnwoM po

o ~ do=lr 3s fluACWoSM Owaa VolM Ain b 400b adW g o as amob ofrMOWS A oo eWmaa ow $wofdi60 ow - ema

-v K Vcon l ap ad md ld KU lbs PoabumwA od w to domi a bembe 0b lt $014 i ampmomONo

4st diwemmSod i 6o pa P)ameakiksm4 m 04M t 1iV vs 0606 o IS ft dopsss of q madl w I10000014 t 44hs

arbs awasm 00 iztv Am-~~~i u5~ms ashu is byw

e~ihs diu~wsm ~phid W A0)ad Lobe d mi-~-- 1) 14 hald

bob~wh do is poPbe~mueus l to aVE tumad 40at iai ka as m

bdisc shmm Ammmd a Sm ofd~~~~~d~A ~ a~m olWshmo

OWNSrilgf ms as

Um~~srTmws~of 4 A ad to wy mis itm voW

IN~flA4T ampMww IV Kwo~t M1CI I POWMAIS amV VARw d01M11 W V

e~~Pum-p -f AOACoe~mfmmdso isedp Am PApmi sk adw Wsk m~ o P4 m

- omlos r umIWO1in pw

lie Uvplist i piw S p wsmoW N of t as so in~tabo 440 o rodgAsect M4Ammd meM ii INAq10ed~ Pib mdWWeiW 1w -w emit TU UFm 6AV 0W A fIN 00~ lb 0PANNO 4 drp OW~It~Oi Ofme _____f WACMW0IN WMVsol~lmO ft SNAO 40 do1Si - m Md y e b ii m

of of~phaow tw bmsdf toamplboe

AjflsutomW C1D-pCTP AD mSmZLT op 1 m ow ts Wdm of P om M

IaM 0t sdw a wn a8duws i ofV -w Mm P16I4 TWO a ewu i an

ov4mnk wsi 9 Mxfeu~i am emwm ismi0wmd fq W No ~~ - f mug Aitowe eutlkowbmTV is

amppowftdmi TiM 0 Tie OAA mo p)a Mwomoi dOn4m A)w

MW 0 604 0M mm yaM 01MWOfdi to tA0 M OOAW uinw OSOb

ap is~e I the ampo A A Mwof ~Do toit op aenu w~ifiOimem~ MAN ampW)

ItsAO se Y lieowawo u~w pkow-W1b pwf on a C Nohkw is f 0o1 s do~omW C mmU4

owud6moeft 4 Obind PINa~e

~4~~wreu -A---I ad

fit~~~~O 114 4 t I mMsmm m~

im ^aim4 Nomod 06maw ee Aist em moom a rA No fmiEo of emit

~ -0

65

0IL CL OC AMXR PROC VOL 38 1974

)aT1 S4I104 ow Lusanll Tawng isa tall Thai variety known for beingIwo nonshyi s s ) sensitive to photoperiod A split-plot design was used in

S e e these euperimeots with 4 rates of P (I1 22 44 and 88t i V IV k of Pha) applied a main plot treatments and with the OF It sourMes of P as subplot treatments There were two checkS plots in each rmplicate The extra check plot was included to permit the application of fresh TSP standard Jor the

It- ti 06 + i bull fa succeeding crop the p-4me of bi was to permit accurate d awrnwal of the mdual effectiveness of the phosphate

ftinSUbI rock The P fertilioers were broadcast on the mud andthen Worporald In the soil during the last harrowing At

whM N both On ACS indx ampM time of transplanting Immediately before the last harrow61t (4j 5 4 01 P s 3Mm o Vallonal in con n 100 kgha of N as ammonium sulfate and 33 kghaWO Of Spews ampm lIW thaabe rocks do ACS indes of K as polium chloride were applied A total of 40 wa in prepw O do ctih k otent kha of N a ammoniunt sulfate was applied later in twoir P The hew oNed amp wM W for 5 of gw topdrossingp with about 5cm depth of water on the plotsvV I aiOMveffeOctveee Three to six ldayold selings pr hillwW the ACS idex were planted00OWW wia Oft fo an c irNk I p Coen 20 by 20 cm part in straight rows Hand weeding was used

and insecticide were applied for Insect control Grain yieldw was masared by sampling 5 ml of each plot excluding border rows The date of heading in each treatment and theUNiN d pbM W Weks rin tOW USA UMe In Tale yed componnts at hafvel were also recorded

I filM rsperMS esOM kdwdua 1 t ab The average yields of ough (unhulled) rice for botha 84 OW O 8uo 4 Thala TM was a locations are ploutel in PIS 3 for the first crop (1969 wet

owou thRM seaso0) The Veamps yield response was obtained at Klonge (s) W lDtO t Of dMa of1tw W d l R Luang however a 4ute satisfactory yield response was

~Mk ^d TVA UJSD ad Kd UnIveS obtalned to applied P at Bangkhen as wellXUe LaM e R qwrw Ims The sod was do Relative aponomlAe effectiveness values were calculated

VOW (a ksA w edmwL t Poesesm h Vy for these data and am presented In Table 3 The valuesdAY buo if dIe ouh ne Pee wtk a Mlak vow 1009 for th first crop are plotled against ACS index in Fig 41 This Im M i6ti l 4bNd IO a0 O mkarnk for both locatio r relationship was linear for the

11400 ThCpH 0( lb pW IW 01 th UpeiaW so Sanodion location and curtiltnear for KIng Luang The was u i 4A sksamp lMaor nrusio model amparounted for 81 of theAmO$MI Aw jAAsue Swim T1 Snh Wd variation In the AE valu for Bantkhen a square root

Mems a Iw iv fern alh$ sedm haowg dayNW W t he plAL At tdo M tM aso W s as ctminued throufh eltaM t Ofpof -le lse wo am P OeNI VeOpls 1o ealluae tI lon4erm MIdual Offccls

A on W isset i a wse to hsh eapeel of these ooihss t ocks The baagkhon experimnent was letmiaI1DlVemisthis is a w hulu Lo g Tasug ia iasael aft - Msd residual Ves will be pr-Om crok TheseTwod esewm

SWWo

A

lP~U~7 ISIIPe1iuIWN e bsedisssin ian ghth siaoelalbe

984 0 6 O O - M s -s fWPas 11eSft W d Uo al a o

o

S4l~ lIIII I~l I 1f fl

( +

+ + + m + ++++-

++ +(++ + ++++ + ++ ++

- 66 -

ENOIMLSTAD ET AL RESPONSE BY FLOODED RICE TO PHOSPHATE ROCKS VARYING IN CITRATE SOLUBILITY

I I I I j0 I I

BANOKHEN BANGKHEN

pH 56 6 - 0o

TSP

NC

5~ ~ ~ L o 4 - -shy

4 ] - --------shy04

6S

|0 III 2 44 8r 66

I I I

a 1KLONG LUANG

pH 46 z KLONG LUANG

TSP Sc2 NCFL(N)

5 FLIC) J0 TU

oshy

4 ~40shy

3 bull eM0

I - I I I I I

0 II 22 44 88 0 5 10 15 20 IP APPLIED KO HA ABSOLUTE CITRAE SOLUBIITY INDEX

Fig 3-Yield of rough rice at Klong Luang and Bangkhen Rice Fig 4-Relative agronon effectiveness () of P sources ploz-Experiment Stations Thalmand as affected by rate and Source ted against citrate solubity Index for both Thailand field ex

of P applied (crop 1) periment (first crop only)

regression model accounted for 97 of the variation in sumably resulted from crop uptake and reaction with the RAE values at the Klong Luang location soil to form less soluble products Such effects may have

These experiments were continued during the dry season been more important at the lower rates since the two TSP of early 1970 to ascertain the residual effectiveness of the curyes converged at the highest rate of application various sources applied to the first crop No new P was These data from KIong Luang indicate that (i) residual applied except for the fresh TSP standard mentioned effects of all rocks except Mlcwuri were substantial (ii) above rhe experiment otherwise was conducted in a man the relationship between relative agronornic effectiveness ner similar to that followed in the first crop of the phosphate rocks and citrate solubility levels was

The response to both freshly applied ad residual P was largely obscured and (iii) the general superiority of TSP marked at the Klong Luang location and marginal at over phosphate rock in terms of effectiveiss persisted Bangkhen In fact at the latter location the response was through the second crop so small that little can be said regarding residual effectiveshyness The yield data from crop 2 at the Klong Luang DISCUSSION experiment are plotted in Fig 5 Greenhouse and field data presented in this paper show

Relative agronomic effectiveness values (Table 3) were clearly that there are substantial differences among phosshycalculated for the Klong Luang data using both the residual and freshly applied TSP as standards It is of Interest to note that the superiority of TSP over the phosphbte rocks Table 3-Relative agronomic effective values for field experishyments in Thailand persisted through the second crop The main difference in KlowlZmlnql~the residual effects is that with the exception of the MIs- s Crop 1 Crop 21 Crop 1-shysouri rock Ihe marked relationship between citratr-soluble WoiCarolina yl 59 76

phosphate rocks and RAE had largely rds norh) a 64P conltct of th Florida (eqlral is 6969 6

disapipeared In this acidic soil (pHi 46) P would by this I14o 69 63 40 ToonesS 31 65

limo be supplied by Intermediate reaction products In addl Missou 0 o lion to residues of the initial spatlte Ts P o 2 o 0

The TSP applied to the first crop declliv-d slightly In campIafcmWataesr e id ofeuhuloefor 22MA rates of PtColeouattd as aba u tlte td18 kS ratesp dlverage yield tM868 to 22 44

effectiveness relative to the freshly applied ISP This pre- of d s4

A

4

- 67 shy

-SOIL SCL SOC AMER I

KLONG LUANG CROP 2

Si 3

eN

TAPPLIEDKGHA

Fig 5-The residual effectiveness ovarious P sources for crop s compared with freshly applied TSP Klong Luang Rice

Experiment Station Thailand

phate rocks in terms of agronomic effectiveness for flooded

rice Further these differences can be predicted by means of citrate solubility or by the ACS index It appears that

the latter is more appropriate where the content of apatite varies among phospiate rocks The most soluble phosphate rocks approached but did not actually equal TSP in limit-iuig (maximum) yield in these experiments regardless of rate applied This agrees with the results of Ensminger Pearson and Armiger (4) One needs to consider the defi-nite posribility of same yield loss in zhoosing a phosphate

rock over TSP such yield losses must be weighed against the lower price of phosphate rock The explanation for such iosses may involve concentration of soluble P in the soil Khasawneh and Copeland (6) suggest that the growth rate of crop plants is a function of P concentration that can be maintained in the soil solution If P concentration is limiting or inadequate becawe of a lower dissolution rate of phosphate rock the growth iate ard uiiimate yield will be diminished accordingly

The RAE values bascd on yield increases reflect the agronomi effectiveness of these various sources relacve

to the TSP standard however these nould be supple-

mented by an economic analysis before rational choice can

be made The following calculations will provide an estimate of

the rclativ ecooomic effectiveness(REE)

Y t Ps aXpatREE -- 100

vahtercks t sphate or e b i- eor

Price of TSPkg fo

be Price of PRkg P

PROC VOL 38 1974 leO

90r

Wsoshy

0

60-LUSEPHOSPHATE ROCK

00 10 20

PTP PR

Fig 6-Relationship between relaZive effectiveness values (RAE) and the price ratios between TSP and phosphate rock Such a figure can be used in making a choice between these

sources

If REE exceeds 100 in this calculation the phosphate rock would be preferable to TSP

The REE calcuktaaa wre used in preparing an indifshyference curve (Fig 6) wherein RAE values are plotted

against PTsPPpR ratios The cu~rve itself connects those points at which REE equals 100 When exactly on the curve it makes no real economic difference what source is chosen After choosing a suitable price ratio one can then project upward from that ratio knowing the RAI

value (or estimating it from such data as shown in Fig 4 using citrate-soluble P content) one can then choose the source on the basis of both agronomic and economic conshysiderations For example if the price ratio is 25 and the RAE value of the phosphaite rock is greater than 40 the rock phosphate in question would be used However if the RAE value was less than 40 TSP would be a better choice There are indications that if the P in the more soluble phosphate ro~cks (North Carolina north Florida central Forida) is less than half as expensivz as that in TSP these rocks would be feasible altereaives to TSP on soils similar

to thoseused in Thailand This analysis does not take into account the possibility

of lower yields from use of phosphate rock In addition only a portion of the various yield response curves was used in this anlysis ie up to 22 kgha Beyond this

rate yield response was much less pronounced it could be argued that at less than maximum yields TSP would produce a certain yield at lower rates of P than would phosshy

pow ofrock This would especially be true for rates applioa example at Klong Luang 5500 kg of

rice pcr iectare could have been produced with either Ii kg of P as TSP or 44 kg of P as son of the more reacshy

tire phosphate rocks It should be pointed ot however

- 68 shy

(IIKIS amp YOUN( ARIFICIAL WEATIIERING OF OXIDIZED p[ll- IV

that this is the yield level that would show the widest difference such is the advantage of hindsight

Farmers generally prefer granular fertilizers for machine

or hand application This is a disadvantage for the phos-phate rocks which are normally arplied in finely divided form Recently experimental quantities of granular urea-

phosphate rock mixtures have been made by TVA Results of trials with these fertilizers will be reported elsewhere

LITERATURE CITED

1 Armiger W H and Maurice- Fried 1957 The plantavailability of various sources of phosphate rock Soil Sci Soc Amer Proc 21183-188

2 Bengston G W E C Sample and S E Allen 1974 Re-sponso of slash pine seedlings to P sGurces of varying ci-trato solubility Plant Soil (In press)

3 Caro JIt and W Hill 1956 Chard eristics and fer tilizcr value of phosphate rock from different fields J Agr Food Chem 4684-687

4 Ensminger I E R W Peirson and W II Atmiger1967 Effectivencs of rock phosphate as a source of phosshyphurus for plants US Dep Agr ARS Bull 4112S

5 Engelstad 0 P J G Getsinger anid I J Stangel 1972 Tailoring of fertiliers for rice cnnece Valley Author ftyNational Fertilicr Developmnent Center Hull Y-52

6 Khasawnch F E and Jane P Copcland 1971 (otton root growth and uptake of nutrievos relation oif phosph

rus uptake to quantity intensity and buffering capacit) Soil Sci Soc Amer Proc 37250-254

7 Lehr JR and G H McClellan 1972 A revised lIbora tory reactivity scale for evaljativg phosphate rocks for direct application Tennessee Valley Authcrity National Fertilizer Development Center lull Y-43

H Terman G L S EAllen and 0 P Engelstad 1970 Response by paddy cice to ratcs and suurces of appliedphosphorus Agron J63390-394

DIVISION S-9-SOIL MINERALOGY

Artificial Weathering of Oxidized Biotite IV The Inhibitory Effect of Potassium on Dissolution llate

R JGILKES AND R C YOUNG2

ABSTRACT

Rates of dissolution of oxidized biotites in OIM 001M ICI are severely depressed in the presence of IM KCI The amovnts of Al Mg Mn dissolved in the first eytraction are similir to those found without KCI however subsequent extractions remove these elements at 10-20 of the corresponding lICI rates This effect may be due to a decreased rate of vermiculite formation thereby reducing the effective basal area exposed to attack A decrease in dissolution rate with increasing ferric iron content was still apparent in the presence of IM KCI

Additional Index Words X-ray diffraction infrared aborp-

N EARLIER papers of this series the tole of biotite in soils

as a source of both macro and micronutrient elements

has been discussed ((Gilkes Young and Quirk 1972 1973ab) Experiments in artificial weathering uiing as va-

riety of extractants were undertaken to determiie the inlu-

ence of oxidation of octahedrally coordinated iron on the bull release of structural cations to solution The results of this

work demonstated that biotite behaves anomalously with respect to the other common ferromagnesian minerals found in soils Oxidation leads to the development of a high degree of resistance to cation exchange and dissolution Several authors have coiwludcd that decreased rates of K

Contribution from the Dep of Soi Science and Plant Nutri-tion Institute of Agriculture Univ of Western Australia Ned-lands 6009 Western Australia Received 29 Sept 1973 Ap-proved 8 Jan 1974

2 Senior Lecturer in Soil Science and Research Officer respeclively

replacement in electrolytes shown by oxidized biotites are

a result of the inclination of structural hydroxyl adjacent to newly created trivalent iron or vacant octahedral cation sites (Robert and Pedro 1959 Barshad and Kishk 1968) Gilkes et al (1973b) suggested that decreased rates of disshysolution of oxidized biotite in 0001 0t)l 0Af CI may also be due to the presence of inclined hydroxyl In this case a smaller surface area external and exposed intershylayer may be available for attack if K replacement by hyshydrogen ions occurs at a slower rate in oxidized biotites

Gastuche (1963) has shown that significant dissolution ofthe (IIM) biotile face may occur and it is easily demonshystrated that the proportion of exposed (001M) face in weathering biotites depends on the percentage K replaced

Rausell-Colom ct al (1965) have shown that hydrogen ions act in an identical fashion to metal cations in K exshy

change from micas In particular exchange c-f K by hydroshy

gen ions will be terminated or greatly reduced by high levels of K in solution Thus if dissolution of oxidized biotite by

acids is carried out at sufficiently high K levels to prevent vermiculization any differences in dissolution rate that may occur cannot simply be ascribed to differences in rates of K replacement The following results were obtained from such an experiment which unlike the experiment described in Parts I and II (Gilkes et al 1973ab) does not attempt to simulate natuiral - conditions

MATERIAILS AN) M HIiODS Further subsamples of the less than 0 hiotites used in K

excherandbaid disoo tu es (G iles e9n K exchange and acid dissolution studies (Gilkes et al1973ab) were used in these experiments Preparation of sequentiallyoxidized biotites without intermediate vermiculite formation is

Page 6: I70 - United States Agency for International Developmentto ascertan, but tgl.eetad, 1, L,. ("Tailoring of Pertiltiters for ice,'" TVA ulletin Y-52) states that the staft of IOi has

-3-

POTENTIAL FOR USE OF SULFUR-COATED UREA

The major portion of the agronomic research reported herein

deals with the evaluation of SCU (sulfur-coated urea) as a source of

nitrogen for rice These results generally confirm those previously

reported by TVA (Tailoring of Fertilizers for Rice TVA Bulletin Y-52

December 1972) in that SCU is a superior source of nitrogen for rice

grown under conditions where flooding is delayed or intermittent

However the results of some experiments from India and West

Africa where rice was grown under conditions where only leaching and not

both leaching and dentrification would be expected to occur suggest that

SCU may be a superior source of N for rice grown under these conditions

as well In certain parts of the world large areas of floating or

deeply submerged rice are grown very little information relative to N

response i available but in general yields are comparatively low

Further research is planned to 4valuate SCU for rice grown under those

conditions

The exact areamp of rice grown in developing countries under

conditions where both leaching and donitrification can occur is diffitcult

to ascertan but tgleetad 1 L (Tailoring of Pertiltiters for ice

TVA ulletin Y-52) states that the staft of IOi has ea|aited that uvor

7I of the rice in outheat Asia So Arown under this type ofter meASe

sent Prelisneary bfbervetio eu est Oat at t l PsIblySoea (a4

ofe) of tw frie to Vat Atfica to gmrae 4nder delayd of totriltest

irwiM4 to FAD report MD00llIO owtoifar f rce rt Imvi

W1110010 teveW ftJ 4 We 04001406w 1 141410tIf 0 ferl4iiio 10

-4shy

applied at a rate of 60 kg Nha then approximately 2600000 mt of

N could profitably be used as SCU In 1972 33700000 mt of N was

used in the world and these figures suggest that as much as 8 of the

world consumption could potentially be expected to be applied as SCU

on rice

On a smaller scale approximately 114000 ha of rice are grown

in Peru nearly all of which is grown under conditions where SCU would

be the most desirable source of N Average rice yields in Peru are about

4000 kgha but research by Sanchez and coworkers (see attached report)

indicates that with ample N yields of 9000 kgha can be attained To

obtain these yields 25500 at of N as SCU would be needed compared to

42000 at of N as straight ure to obtain the same yield Thus SCU

would save 16500 tons of N or roughly 40 of the N needs

Results from India indicated that when equal amounts of N were

applied an average of about 1000 kgha more grain was produced on exshy

porLsentail plots This average figure included some areas where SCU was

not superior to AS In 1972 36500000 ha of rice were grown in India

with an average yield of 1616 kgha Proper use of SCU in place of

conventional form probably would not Increase yields an average of 1000

kghe under fam conditions as it would on the research plots but an

average of 500 k8 would be raoom ble This would rotult to an Increaa

of a50000 m of rice an Incras of 311 over the 197 production of

$90o000000 mt

The 40 04Melee Ore cited t dMWMaftampt tbe iAnCicoo in

ftc prodwilu peble Ihrow~h proer t o of 60 a wvrf of 0 for

fiff MWere- f04ieb di at Peded t1 1if1 pfJiiea1y 4i fie toshy

ditlsw winde Iee idveitu f~ rics a to JMe(0wiaihthe of 1CM La f

-5shy

precisely evaluate the economics of its use

Preliminary data indicated that SCU may be a superior source

of N for other tropical crops particularly long-season crops such as

sugar cane and pineapply grown in areas of high rainfall

The results of the wheat experiment followed by sorghum in

Pakistan in which the residual effects of SCU were evaluated suggest

that in intercropping and multiple cropping systems fertilizer nitroshy

gen may be applied in a slow-release form (SCU) at a convenient time in

the cropping system so that the nutrient elements will be released for

utilization by succeeding crops

Information already obtained indicate that SCU is a superior

source of N for crops grown on large enough areas to economically justify

its commercial production As more data are obtained with more crops

and from new areal the potential for its use will undoubtedly increase

Consequently as adequate supplies become available programs need to be

initiated in selected areas to introduce the use of SCU to agricultural

extension workers to the fertilizer industry end to farmers and to

encourage its coinercial production Since the cost per unit of N will

always be higher in SCU than in regular urea the use of SCU will be

econmically practical only under specific conditions and these restricshy

tions as to its use make it perative that effective education and

inforuation progra- be conducted prior to the comerctel Introduction

Of SU On 4 Wid eeie

-6-

BACKGROUND AND OBJECTIVES OF PROJECT

The present project is designed to capitalize on the momentum

and knowledge gained in the previous project Tailoring of Fertilizers

for Rice This project demonstrated that a superior nitrogen fertilshy

izer can be developed for tropical areas and that some relatively low

cost phosphate sources can be effectively utilized The present project

seeks to broaden the base for development of improved fertilizers through

a wider range of agronomic economic and engineering evaluations Preshy

viously the emphasis was placed on SCU as a nitrogen source and the dirshy

ect application of a limited number of selected phosphate rocks as phosshy

phorus sources for rice fertilization In this project a wider range of

fertilizer materials will be tested on a variety of upland crops such as

maize wheat sorghum and sugar cane cassava and others of national imshy

portance in various countries

Through its domestic fertilizer research and development proshy

gram TVA produces experimental fertilizer materials that may have poshy

tential for tropical soil conditions and crops With support from AID

in this project the capability viii exist to work toward improving fershy

tilitors for developing countrive through the necessary and logical soshy

quenco of production to ramer aceptonce to sess the potential for

co mrcial production

Pertilliers now being used in 4eveloping countriee relAtive

OeCOtcs And shortcoMiNge of the Mterials viii be Ovai6Isd Ktshy

true thel ena 4 4 0(fiashyporimrtAl product wlornriee pilot plt

ties OaI1 pl0t4 Will be W0bsutd to fcresMq tet in jre

tof f~wrisea with caomvstmwl siatofials rr f P0041610 161i

-7shy

screening will be done using soils of the area where the fertilizer

will be used Materials showing potential in greenhouse tests will

be further evaluated in actual field programs in selected countries

If successful at this stage economic and engineering data will be

compiled to assess the potential for commercial production In orshy

der to evaluate the product and process the total system will be

studied including storage handling and transportation from the

point of production to the farm Information developed throughout

this work will be available to industry foreign and domestic so

that it can develop a production marketing and use base for utishy

lizing the product This level of technology is rapidly being achieved

for SCU which received major emphasis in the previous study additional

agronomic economic and engineering data both with rice and with other

crops will be obtained to complement the previous findings

This project must be broad and combine a variety of professhy

sional disciplines but it is necessary to retain the flexibility to

move forward in specific directions as Improvements in products occur

This is necessary to insure that improved products identified in this

project can ultimately be made available to farmers zegrdless of their

economic and social status and that sufficient data aro available so

that induetry can make soomd decisions regarding the foasibility for omshy

marcial production

Major objectives of this project are eommartted as tollovws

(1) Developing Iertilaers to wt the nutrient neD of oocitic

4I l VhICh are not set iconmically withtfopical Crops and

etoshytoov~tmtl| Nrtiliieoro or that can set thse ne- s fre

006eItCOMlY ky 4ir lfte the W91~1ici of teftlliaer ultil4tin

-8

(2) Proving the value of these improved materials to insure that

they will increase farmers income over a large enough area

to attract and Justify commercial production

(3) Developing the production technology for new fertilizers as

a basis for encouraging and advising potential commercial proshy

duction The integrated process designs will seek product

quality and economy while striving to minimize harmful emisshy

sions to air water and land

(4) Working through cooperating organizations and with leaders in

research extension and industry to develop and demonstrate

methods for introducing new fertilizers to farmers so that they

will be properly used when they become commercially available

-9-

SCOPE OF WORK

This project integrates agronomic economic and engineering

expertise into a single team in order to develop improved fertilizers

for a wide range of crops and soils in developing countries Considershy

able emphasis is given during the first eighteen months to collecting

the data needed to complete the evaluation of sulfur-coated urea and

ground rock phosphate for lowland rice Both materials then are

scheduled for demonstrations during the latter part of the project in

order to educate extension workers and farmers and to attract the fershy

tilizer industry into commercial production Considerable emphasis is

given to the economic evaluation of a total production-marketing-use

system for each material in contrast to alternative nutrient sources

The probability of commercial production of SCU and ground

rock phosphate can be enhanced by expanding their use to additional

crops and soils Thus the project is expanded in scope as compared

to the previous project on tailoring of fertilizers for rice in order

to test these materials on additional crops

The expanded work includes a major effort in screening and

testing new compounds and forms of fertilizers for various food crops

produced under tropical conditions Alt hough it if already known that

more effective andor lens expensive formn of nitrogen and phosphorus

are needed a literature survey will nerve an Lan additional guide to

important and presing fertilizer problems

-10-

Much of the work with fertilizers for both lowland rice and

upland crops will consist of field tests in Southeast Asia Africa and

Latin America Greenhouse and engineering studies will back up the field

research All field experiments are designed to provide at least an esshy

timate of costs and returns for each fertilizer tested

PROJECT PLANS FORFISCAL 1975

In this section the work for fiscal 1975 will be discussed

It should be remembered that the success of this project depends in a

large part upon maintaining sufficient flexibility so that work in inshy

dividual countries can be adapted to supplement and complement programs

already under way While guidelines and plans of work must be developed

so that the objectives of the project are clearly defined detailed

plans for specific countries or groups of countries must be developed

by consultation wth local cooperators

These plans will be discussed under the following three general

phases of the project

I Engineering and development

2 Agronomic testing and evaluation

3 Economic evaluations

Engineering and Development

Phosphate Rock

Methods have been proposed for relatively simple treatment of

phosphate rock (PR) to increase the availability of the phosphate to make

it more suitable for direct application to the soil These treatments

may be economically feasible in certain areas especially in view of the

current world fertilizer situation Considerable work has been done at

TVA studying means of altering PR and plans are being developed to inishy

tiate further developmental work and field testing of these materials durshy

ing fiscal 1975

- 12 -

Emphasis will be placed upon obtaining samples of phosphate

rock from deposits in developing countries and testing and improving

procedures for increasing their citrate solubility and tzius availabilshy

ity of the phosphorus From this laboratory screening process sevural

sources will be selected from which small amounts (50 to 100 pounds)

will be prepared for greenhouse and field experiments ou various soils

(as described under agronomic section)

From these results one or two locations (or countries) will

be selected for development of a pilot program to utilize local sources

of phosphate rock This program will involve production of the altered

PR and its agronomic evaluation and then educational programs with govshy

ernment and commercial representatives to introduce its use to the farmers

Sulfur-Coated Fertilizers

Some preliminary work has been done in which urea-potash mixshy

tures were coated with sulfur The 7-day release rates for the N and

K20 were 17 and 36 respectively from the coated product (22-0-11-30S

grade) This was the first effort in coating a compound fertilizer

with the new coating system

The widely differing release rates for the nutrients from

the coated compound product raise some interesting prospects for tailshy

oring the nutrient release rate of sulfur-coated products It might

be possible to cogranulate materials of varying water solubility and

sulfur-coat them to produce products with release rates that would apshy

proximate the timing of nutrient requirements of the crop The need

for this type of controlled-release product has been mentioned many

times by agronomists and may be especially applicable in multiple and

intercropping systems

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Table 2

Mttct of 0 Sourco aampW $At On Upt~ks of 0 by Two Varitgtos of Paddy Rice

gr~a 1971

~ MMUampL~ ~L ~ nYLALI~ 11 lemall

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- 24 shy

India--The results of four experiments conducted with flooded

transplanted rice in India by the All-India Coordinated Rice Project

Hyderabad are given in table 3 The response to N was excellent the

yield without N being only 41 of those obtained with basal applications

of N as uza With basal applications of SCU the yields were 20 higher

than with basal applications of urea and in the three experiments in

which urea applications were split yields with SCU were 18 higher than

yields with split applications of urea When comparing the average Nshy

response (kamp grainKg N) yields were increased 13 more by SCU than by

basal applications of urea

The data from one experiment with light irrigated rice in India

are given in table 4 yields were relatively low and differences between

N sources or method of application were not significant However yields

with SU tended to be higher than when all urea was applied at planting

but lower than when split applications of urea were applied Again yields

increased more than 13 more with SCU than with basal applications ofwere

ur

In tables 5 and 6 the yields of a short-duration transplanted

rice grown in irrigated light-textured soils at five locations in India

indicate that higher yields were obtained with SCU than with urea when apshy

plied as a basal application Yield increases due to basal N applications

were 502 greater with SCU than with urea However split applications of

resulted in yields equal to those obtained with basal applications ofurea

CU

The yields of direct-seeded upland rice grown at three locations

to India are given in table 7 and the relative yields in table 8 Yields

were low due to drought but good responses were nevertheless obtained for

- 25 -

Table 3

Effect of N Source and Time of Application on Yield of Paddy (Flooded) Rice in India 1972 (Summary of Reported Data from 4 Experiments)

Experimental Number Source Rate Method Yield Relative N-Response

and of of N of Yield Kg Grain

Season Nitrogen kgha Application mtha Kg N

- - - 196 34 -

Urea 120 Basal 573 100 314

11 Urea 120 80 + 40 611 107 345 Rabi SCU 120 Basal 713 124 430

12 - 0 - 202 30 -

Urea 125 Basal 682 100 384

Rabi Urea 125 35 + 20 + 35 + 35 633 95 344 SCU 125 Basal 781 115 463

13- 0 - 168 44

Urea 100 Basal 385 100 217

Kharif Urea 100 30 + 20 + 25 + 25 400 104 232 SCU 100 Basal 462 120 293

14 -

Urea -

125 -

Basal 355 650

55 100

-

236

Rabi SCU 125 Basal 781 120 341

-- 26 -

Table 4

Effect of N Source and Time of Application on Yield of Light Irrigated Rice in India 1972 (Summary of Reported Data From

One Experiment at Pattambi)

Experimental Number Source Rate Method Yield Relative N-Response

and of of N of Yield Kg Grain Season Nitrogen (kgha) Application (mtha) Q) Kg N

38 0 - 204 85 -Rabi Urea 120 Basal 241 100 308

Urea 120 60 + 0 + 30 + 30 267 ill 525 SCU 120 Basal 255 106 425

Table 5

Effect of N Source and Time of Application on Yields of Short-Duration Transplanted lice Variety Grown on Irrigated Light-Textured Soils at 5 Locations in India 1972

(Snmzarized From Reported Data)

Rate Grain Yields (MtHa) Source of N Method of N GrainI of N kgh Application Faizabod Karjat Mandva Pattabi laya Averaje X

- 291 266 211 19 340 260 -

Urea 100 Basal 386 407 361 285 482 3 124 Urea 100 50 + 25 + 25 399 430 434 334 6amp2 4A8 186

SCU 100 Basal 368 468 439 360 572 41 181

Table 6

Effect of I Source end Tlae of ApplIcattoo c RIstave Tle24 of a rt- rat1 T Lsd lice Vasrety Crin o Irrigated L41tshy1 at S Locitite mindi 1972

Rate ____________14_3

Source of X N~tbad of Of X An 1 tat14 1 acr X__T1 4v tatW ttva

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W Iotors Ftslanp tospg Irritd for Two thvk Afler flontiw wft rkwa~ Floo4d 191)

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- 38 -

Table 18

Yild of aemati-370 Rice at Punjab Agricultural Research

Institute in Pakistan in 1969-70 Grown Under

Couditions of Intermittent Flooding

Pate of application

=IL

o 0 67 67 100 100 67 67

100 100 67 67 200 100

Average for Sources

Ntha

AS 260 gres 279

320

Source f5

-

AS AS Ura Urea SCU SCU

Yield

Relative

93 100 115

(M)O

Yield

Increase Yield Due to N

(Ktlha) (mtha)

-212 245 033 274 062 260 048 297 085 315 103 325 112

Yield Increase

Relative

72048 067 100 108 161

(2)

- 39 shy

Short-statured high yielding rice varieties grown extenshy

sively in northern Peru require extremely high rates of conventional

N sources to achieve maximum yields The recovery of applied N is

extremely low due to the use of intermittent flooding This water

management system results in heavy N losses even with properly timed

split applications In search of simpler and more effective methods

of N management eight field experiments were conducted in the region

to evaluate sulfur-coated urea (SCU) an experimental slow-release N

source supplied by the Tennessee Valley Authority Rice yields were

increased an average of 59 more by pretransplant-incorporated SCU than

by urea or ammonium sulfate applied in the same manner SCU produced

excessive vegetative growth which resulted in yield reductions at high

N rates

Regardless of an assumed 48-higher unit N cost in SCU the

overall benefits of pretransplant-incorporated applications of SCU

were favorable since there was a decrease of 40 in the optimum rate

of N and the need for precise timing of application was eliminated

Pakistan--In Pakistan basal applications of AS urea and

SCU to rice grown under conditions of intermittent flooding in 1969-70

(table 18) indicate that SCU is a superior source of N as compared to

urea or AS when all N is applied at or before planting The data also

indicate that a yield response was obtained for P applications but a

comparison of N sources at each level of P indicates that no interaction

between N and P was present so that differences between N sources were

relatively the same at each level of P Yields were increased about 60

more when SCU was applied than when urea was applied Yield increases

with AS were only about 72 of the increase obtained with urea these reshy

sults do not agree with the generally-reported superiority of AS as comshy

pared to urea as a source of N for rice

- 40 -

In 1973 experiments were conducted in Pakistan using both

Basmati-370 and IRRI-6 varieties of rice grown under conditions of

When all N was applied at puddlingintermittent flooding (table 19)

or 12 at puddling and 12 at panicle initiation both AS and SCU were

superior to urea with SCU tending to be the most efficient source

However when N was applied 12 at transplanting and 12 at panicle

initiation SCU was the poorest source of N This would indicate that

the release of N from SCU applied at these times is too slow for optimwn

plant growth

In another experiment in Pakistan in 1973 no differences

in the effectiveness of urea AS or SCU were noted in the yields of

continuously-flooded rice (table 20) Again these results are conshy

sistent with earlier results which indicate no superiority for SCU

when rice is continuously flooded

Nitrogen Studies--Maize

A series of three experiments were conducted by IITA in

armo-Nigeria in 1972-73 comparing AS urea SCU and

CAN (calcium

nium nitrate) as sources of N for maize (table 21) A significant

yield response was obtained for N at each location but no conaistent

differences were noted amaong sources These results are consistent

with results at other locations which have not shown that SCU is a

superior source of N for maize grown over a period of 3 to 4 months

Nitrogen--Wheat

The yields of wheat in Pakistan in 1969-70 (tables 22 and

23) show that yields with SCU) tended to be lower than those with ureaJ

although at one locction where sorghum was grown followilng wheat with

Table 19

Yields of Basmati-370 and IRRI-6 Rice at Punjab Agricultural Experiment Station in Pakistan in 1973 Under

Conditions of Intermittent Flooding

Rate Yield Source of N Time of Yield (Mtha) Increase of N B-370 IRRI-6 Application Basmati-370 IRRI-6 Average (Mtha)

0 0 - 21 353 287 -

SCU 90 150 At Puddling 325 545 435 148

Urea 90 150 At Puddling 309 500 405 118

AS 90 150 At Puddling 324 529 427 140

SCU 90 150 Puddling 372 572 472 185 Panicle Initiation

Urea 90 150 Puddling 335 502 419 132 Panicle Initiation

AS 90 150 Puddling 353 529 441 154 Panicle Initiation

SCU 90 150 After Transplanting 312 562 437 150 Panicle Initiation

Urea 90 150 After Transplanting 340 624 482 195 Panicle Initiation

AS 90 150 After Transplanting 349 583 466 179 Panicle Initiation

All plots received 45 lbs P205acre as single superphosphate

Relative Yield Increase ()

Source of N At Puddling Puddling Panicle Transplant h Panicle

Urea 100 100 100 AS 119 117 92 SCU 125 140 77

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-48

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mmfp MW phapa A (CI) sed graewletod pampAtlti arlolatod Pa

asowcs of P tof ttde ro The wreem proucts omre raGther

pemour~a ot P syag besmti andMi as elt ov so gpamwhr

iuipiqffhate(TS) low twseeo Is eftwiltve Is thet

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pud6itt of Irto paddle Wee ofsdlseireplastiq

0 49 shy

lbs partially scldiaatede grawilated Ml prodlucts Vere isshy

toiwdiats in 5tftOvttWS54 betwee wroiPi ad TVP NotV5Ymf to

me coo were they mere twoe $a a etfective ao TIP 00 sipifleast

LVSUMI5 at0 efecto wore toun tor thee produteo Timely dtIampWde

FR (-t00 mmoh) Uia amp~rally oar affective than Owe gra8448r FOampprodt

featal twos o 6 aotetire s I

Nowvero it to felt that sfortber field euprtet vth

hese interials Amd ether typs of grometatodl Wter nre wrrautad

hater ceeuwodh that they have me areec poteatlal toi additoG

e tate wAne the sectte as OtawrI sed bovoloen turther

euperimeste vth few reck pboophar s0d with reck pbophat treated

to sehesa citrata selmtliy or to ha csaducted

Metbir sertes of tbme enprtaeats wae c~edtmcted by IITA

to Ut~rta copal TVP AOP APP aed it at see tecastisix (table 14)

No dot lalt sewseltles teh draw tree thee results simouely em pear to tlvdl bsww they do stwgpt tbat forthew work with

MR to werramid so tbme sels

Table 24

LttcttF Swce MaPlate 06 ieldot IM AWaia CoelsANS at IITA (Ugboda ad Apoin ail sorit) aid at Ike (AUaba s5i series)

1973

Plate ot IP Apinu 5 poundebods A1ab

Ocrol 0 Z94 419 M)

Tr ipl ruprphite 20 349 3799378

Triple vepput 40 M09 410$

Triple 6wp~~b1 4271 4344 42250

Ammotw-ritpophW to 4201 4124 4040

Amosim-rdop~phlt 40 4270 4106 4231

AM tuo-polpephats 20 404 4244 3794

~eai~mpelppepbuI 400)49 4094

Cee m-pbpbt to- 59

momee eph lto 0 4192

LSO (0 0$) 29 1025

Th WPII

- 51 shy

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1 ~ ~ gmw 1pc~biofl- 9 Kla4v4h

Upia U04 Copfind am Crehout Stet Rpano at (Ia4

rico t IF t rume6 orth~ Caralto phoophale rocl QAR) vaUN pqU41 to

roopon from cmonetrat4 gsporphophai (CIP) who ort$o4 oil k

was 45j itwas tafertor vb protioo4 oil p war OS Ib 4iffer~c

in rtc reepos to X cod14 oo bo ttrit4 4 4 hvsciag of boil p

~ Pt o r11221 0 tP

c theto the rhimecyllndor of rico tots par to)14M4i1 roeoi~t

ed oil emd PA prior to tho ont of an~robi4 cMioe AA~ oIifoshy

nAte bYpot t taet~d tO fC4sin t~r 4PWden0 Of f Ot(tivshy

ofOWailiJtyno o prefla4 all Put that 4t01etoo 14 tvsIk

of the Ott to prvvld a 014for C4m0 44 mI 1 o4sf

EfftC ftPet141on AIAM-0 V f401td 4 4iv 440 Mtft

Aa torfat VampP f4MWfCi4W04wt0amp to 4eturWlI Ot(Wel~drIC ft

Ot f tM6 the flooded Ott 00 14 04019I Pft0uAw Of gAr~s~lr

pkS$t M40b MP) Tw P1101 Piset Prodwie W-e 10M0di Wr04

(10-1) emW 0aretilp ddw01at4 P WAA firom Rrth M~flRU414~$

wee cowiared with fie Md reWim 44104 proo~fo) foruk oith laWItter

I v te-PR P OW1004 4 4 O Wf ottil OW ellt Oo

Oveiel1 the 40tt dmcruie to effetotww Wtollowui Co fme

PR tpaUIB1I ldoltmo PR (pamwlatr) offr~- ArmeuM) 0 orwi

- 52 -

Effect of N Sourc6 and Water Management on Response of Rice

toe Zn- M Giordano J J Mortvedt OP Engelstad and Greenhouse

Staff Several rotes of CO(14H2)2 and (H )2So4 vith or without ZnO

wore applied to flooded and nonflooded Crowley oil (limed to pH 75)

to determine response of Bluebelle rice to Zn Yields with both N

sources veotrgreator on flooded then on nonflooded soil In the abshy

ence of applied Zn total dry matter production vith CO(NH2)2 was

slightly lower than with (NH)2S04 on flooded soil and considerably

lover on nonflooded soil Concentration of Zn wan higher in straw and

grain of plants roun on flooded than on nonflooded soil Although

concentration of P was unaffected by N source or Zn rate there was

som indication that cranslocation of P from straw to grain may be

depressed in nouflooded rice Concentration of N was lower in straw

grown on flooded than on nonflooded soil due to apparent dilution

thereas both X sources resulted in similar N concentrations in straw

at all rates of N application the N concentration in grain increased

with 0 rAse

feSpongi gf(SM to Chjorospodiostte and Related P Sources--

Si Allen and Greonhoue Staff A greenhouse pot experiment was

couct44d with corn Brown on Hountview silt loam to compare the ofshy

fectlivees of chlorospodiosito (Chlor-l) with concentrated supershy

phosphate (CP) Thomas slag and North Carolina phosphate rock (NC-PR)

Oil-prillad urea-phophato rock (UPI) FeA1JMP 20 7 and monomthyl

phosphate were included in the experiment Based on yield of forage and

uptake of P by tvo crops each of 6-weeks duration the following conshy

stui were dravat

I Chlor-1 was slightly loss effective than CSI Thomas slaS or NC-PR

from which Chlor-l wae prepared

- 53 shy

2 Granular UPR was a poor source of P its effectiveness was greatly

increased by reducing the particle size to -35mesh

3 FeAlNH4P207 was unavailable to the crop

4 Monomethyl phosphate was equivalent toor slightly more effective-

than CSP

Research Indirectly Related to TVA-AID Project

Response of Several Rice Varieties to Zn in Moist or Flooded

Soil--P M Giordano J J Mortvedt and Greenhouse Several varieties

of rice from Mexico and the Dominican Republic currently under investishy

gation in Puerto Rico for adaptation to upland culture were compared with

some established United States varieties with regard to Zn response on

moist and flooded Crowley sil (pH 75) Chontalpa (Mexico) Bluebelle

(Texas) and Starbonnet (Arkansas) were most responsive to applied Zn

Juma (Dominican Republic) intermediate and Sinaloa (Mexico) and Calrose

(California) were the least responsive The Sinaloa varieties (Mexico)

appeared to be best adapted to non-flooded conditions whereas Chontalpa

and Calrose were poorest Concentrations of Zn generally were higher in

plants grown on flooded than moist soil

Pattern of Growth and Zinc Accumulation by Rice--P M Giordano

J J Mortvedt and Greenhouse Staff Rice plants were harvested at weekly

intervals from shortly after emergence through maturity The objective

was to determine the rate of growth and Zn uptake by a Zn responsive varshy

iety (Bluebelle) and a less Zn-responsive variety (Calrose) in the presence

or absence of Zn applied to Crowley sil (pHl 75) Dry matter production

of Calrose was linear with time of growth and of a similar magnitude until

heading with or without applied Zn Bluebelle followed a similar pattern

where Zn was applied However in the absence of applied Zn foliage yield

was reduced markedly

-54

Uptake of Zn was similar for both varieties whenZn was

applied Dry matter production and Zn uptake by the two varieties

also were comparable when Zn was applied However yield of Calrose

was much higher than that of Bluebelle in the absence of applied Zn

while Zn uptake was only slightly higher This suggests that the lesshy

ser responsiveness of Calrose to Zn may be due to more efficient utilishy

zation of Zn There was no indication of a greater demand for Zn durshy

ing reproduction in either variety as was suggested in earlier greenshy

house experiments

Response of Upland Rice to P and Zn--P M Giordano J J

Mortvedt and Greenhouse Staff Several rates of P and Zn were applied

to Crowley sil (limed to pH 75) in factorial combination to determine

whether differences in rice growth under flooded and nonflooded soil

conditions are related to plant nutrition Although straw yields were

slightly higher in nonflooded rice receiving adequate P and Zn grain

yields were higher in the flooded crop increased rates of F andor Zn

did not result in equal yields Except in the highest Zn rate (75 mg)

concentrations of Zn in both straw and grain were higher with flooding

Concentration of P increased with rate of applied P and was higher in

the grain or flooded than upland rice at a comparable P rate In conshy

trast concentrations of N were lower with flooding due in part to dilshy

ution from increased growth

Rice Response to N and P in Flooded and Unflooded Cultures--

G L Terman S E Allen and Greenhouse-Analytical Staff Rates of

N from 250 to 2000 ntpot and P from 0 to 1000 mtpot were applied for

Nato rice grown on Mountview sil and Sango sicl (625 kg of soil per

pot) Market yield response to N and P was obtained Yields of straw

- 55 shy

total yields N uptake and N recovery were higher on unflooded than

on flooded soil cultures Grain yields however were slightly higher

with flooding These results indicate that with adequate applied

nutrients especially of N rice yields without flooding can approach

or even equal those under flooding

Uptake of N P Ca Mg and Zn increased with yield response

to N and P while K uptake decreased on the Mountview soil Concentrations

of N and P increased with applied N and P respectively while concentrations

of other nutrients were diluted in most situations with yield response to N

or P

Results from this experiment show that amouats of N applied in

previous pot experiments for rice have been much too low especially if the

crop was grown to maturity

Response of Corn to S and N i UUASand Urea-S--S E Allen

and Greenhouse Staff Three greenhouse pot experiments were conducted to

measure response to S and N in ulfur coated urea (SCU) urea amonium

sulfate (UAS) and urea -S as well as estimate N losses from surface apshy

plied N sources

In Experiment 260 less than 20 of the S mixed with the soil

was recovered from SCU or urea-S granules by two crops of corn as comshy

pared to 45 or 80 from flowers of S or Na2SO 4 CLop response followed

a similar pattern

In Experiment 260-A N sources were surface applied and alshy

lowed to dry for two weeks before incorporation Into the soil and plantshy

ing Recovery of N by two crops of corn was 77-82 for AN an compared

to 37-70 for urea UAS urea-S and ICU Thus n this experiment loss

of N from urea did not appear to be re~dcud by light S-coatlngn or by Inshy

corporating S or AS in the granules

-S -

I xbprZnSlt a Wtch aU Meyto 0-Ai Wt f9r

higher reermo teOrtOrs cOM reSpWNO i r0100 Of N w

not oaisteontly related to sewe ot N In edl tust 0 ioltiUe Lim

lo in VMuwpped evlmtUTS 48 merind by seirest nte appresOehe

501 for uroa as cwarod to 210 for urea peepha

Rus- or Upse to LoAmIl34I a AriMed bI Earl U

MW NOWlsIIsIr-4 L Toman 5 1 Alln and eesese StNf rio

row on Sawg did (0 tpot) We 1l0l0 Ws feritiud vith 05is

of Npot mixod with the 6011 as aureCA NiAO) 1 Age god At Ures

was also itcluded at rtt t 05 10 end 15 of Upee Theas trealshy

onto were followed 4 wpdrsetago of U s AN wre 4C 10o or at I3n

Weeks toulin up to IS pot

A soil application of 10 pot rosulvod to the maim yield

at 4 weeks Tio4 sad percont prottis t intre raite tncreased rftishy

linearly with U applictalien IeseeItally all at the m iNd wit

the moil w domitrifted after flooding Grail end straw Ilelds vere

highly correlatod with tiliriag and vlh ubers of gralm arl

The results Widicat that 0$ to 10 a of Upot as orea or

NN bsuld be sied with the oil to stilate tiilrir with adshy

ditional 0 topireased later to increase grain lIds mad protia cmshy

tout

DIVISION 54- FERTILIZER TECHNOLOGY AND USE

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valves a hevwae u Iar Walh basl oswas dhe uwpatr bshava of

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TOW opl taoe for AieweeW 4OsmWMbas Op peas As Tabl 4 sling sob Os awowully eom grams Piel level Thes oeulam Ma sed as IM

-02

792 60L WI W A)49R Pio VOL 37 197)

primS o r OeampAd WU toa Them fl~ w At NOSSe earno maisslea Ia N he mOWamplIO yik ampWd IMe aampWmW OWa Owe wa UMs of KU to 41 Oke ampWiiIamm be dkrnety ewspokawleM(a s8 te camtd wie a eapmoe by TVA pavw ltoi NA poundrmdaka4us vrimeW460 o to ilkidm ofWW (Mtemas MuOwe 1973) TVA mwi bawld on soi ficedims IampWp seg rudwiv s~s0abet ke WNmdoe ON 01 K Is12 NOSW ie fssewnmu Ie I QvaaIi rowp IMA) f9

)amp m lodk byO voebmsaIS8OpeaWfrats 11 OWNmi a I a W idisod 0 81 Now 111 nindat Wm fysmpseaamp (If tsO tUmtI IsM $P shoroV4mmo knflkvnf (foOdme nuw ae Ow OImstwe in SM pnmm8 af tXm 10 114PIS kequoian wo Mpfii

SC~po umd spop~o VWt alm 4emWal 1 4ink PCmirsra M 1 ad AI 14bmms

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DIVISION 8-9-SOIL MINERALOGY

Amorphomw CeetIup en XmWra Ssrfmls

L C koits Am~ 0 tmmkaAf

ommp A faieiaAMTRACT skiwe lo nW ampM sm wi4h

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peuiieles as is s e wpwigstee eded his S -em -om 0641 h4 hisW1mWOWb~ bfem peess Wimm kv Iee

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os 0aMW ofmu WA l aduWs~Ib rowuvvl3maIpm s

CaO~OP aw AlNomI 4ornomd to9 IS is -l O SI g4he rpidyThus whim m dowu bWa 0 m m- ei u

d m M 0bmSaImu M-1 ofM6 h Intun to 7I

aiba maush WAesshwn~u9dSg a osusLwpI ~ v m

M PolsdAvoWdw Ons pugm~ low iwLW m We

of~U -a~ mo uNo

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A e mun5d m i vvamp sa s ow bftIS i sa omdIs a w

edi1 hswopmo an ag am Iw anom erlwaPASneooie bnwoM po

o ~ do=lr 3s fluACWoSM Owaa VolM Ain b 400b adW g o as amob ofrMOWS A oo eWmaa ow $wofdi60 ow - ema

-v K Vcon l ap ad md ld KU lbs PoabumwA od w to domi a bembe 0b lt $014 i ampmomONo

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bdisc shmm Ammmd a Sm ofd~~~~~d~A ~ a~m olWshmo

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- omlos r umIWO1in pw

lie Uvplist i piw S p wsmoW N of t as so in~tabo 440 o rodgAsect M4Ammd meM ii INAq10ed~ Pib mdWWeiW 1w -w emit TU UFm 6AV 0W A fIN 00~ lb 0PANNO 4 drp OW~It~Oi Ofme _____f WACMW0IN WMVsol~lmO ft SNAO 40 do1Si - m Md y e b ii m

of of~phaow tw bmsdf toamplboe

AjflsutomW C1D-pCTP AD mSmZLT op 1 m ow ts Wdm of P om M

IaM 0t sdw a wn a8duws i ofV -w Mm P16I4 TWO a ewu i an

ov4mnk wsi 9 Mxfeu~i am emwm ismi0wmd fq W No ~~ - f mug Aitowe eutlkowbmTV is

amppowftdmi TiM 0 Tie OAA mo p)a Mwomoi dOn4m A)w

MW 0 604 0M mm yaM 01MWOfdi to tA0 M OOAW uinw OSOb

ap is~e I the ampo A A Mwof ~Do toit op aenu w~ifiOimem~ MAN ampW)

ItsAO se Y lieowawo u~w pkow-W1b pwf on a C Nohkw is f 0o1 s do~omW C mmU4

owud6moeft 4 Obind PINa~e

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~ -0

65

0IL CL OC AMXR PROC VOL 38 1974

)aT1 S4I104 ow Lusanll Tawng isa tall Thai variety known for beingIwo nonshyi s s ) sensitive to photoperiod A split-plot design was used in

S e e these euperimeots with 4 rates of P (I1 22 44 and 88t i V IV k of Pha) applied a main plot treatments and with the OF It sourMes of P as subplot treatments There were two checkS plots in each rmplicate The extra check plot was included to permit the application of fresh TSP standard Jor the

It- ti 06 + i bull fa succeeding crop the p-4me of bi was to permit accurate d awrnwal of the mdual effectiveness of the phosphate

ftinSUbI rock The P fertilioers were broadcast on the mud andthen Worporald In the soil during the last harrowing At

whM N both On ACS indx ampM time of transplanting Immediately before the last harrow61t (4j 5 4 01 P s 3Mm o Vallonal in con n 100 kgha of N as ammonium sulfate and 33 kghaWO Of Spews ampm lIW thaabe rocks do ACS indes of K as polium chloride were applied A total of 40 wa in prepw O do ctih k otent kha of N a ammoniunt sulfate was applied later in twoir P The hew oNed amp wM W for 5 of gw topdrossingp with about 5cm depth of water on the plotsvV I aiOMveffeOctveee Three to six ldayold selings pr hillwW the ACS idex were planted00OWW wia Oft fo an c irNk I p Coen 20 by 20 cm part in straight rows Hand weeding was used

and insecticide were applied for Insect control Grain yieldw was masared by sampling 5 ml of each plot excluding border rows The date of heading in each treatment and theUNiN d pbM W Weks rin tOW USA UMe In Tale yed componnts at hafvel were also recorded

I filM rsperMS esOM kdwdua 1 t ab The average yields of ough (unhulled) rice for botha 84 OW O 8uo 4 Thala TM was a locations are ploutel in PIS 3 for the first crop (1969 wet

owou thRM seaso0) The Veamps yield response was obtained at Klonge (s) W lDtO t Of dMa of1tw W d l R Luang however a 4ute satisfactory yield response was

~Mk ^d TVA UJSD ad Kd UnIveS obtalned to applied P at Bangkhen as wellXUe LaM e R qwrw Ims The sod was do Relative aponomlAe effectiveness values were calculated

VOW (a ksA w edmwL t Poesesm h Vy for these data and am presented In Table 3 The valuesdAY buo if dIe ouh ne Pee wtk a Mlak vow 1009 for th first crop are plotled against ACS index in Fig 41 This Im M i6ti l 4bNd IO a0 O mkarnk for both locatio r relationship was linear for the

11400 ThCpH 0( lb pW IW 01 th UpeiaW so Sanodion location and curtiltnear for KIng Luang The was u i 4A sksamp lMaor nrusio model amparounted for 81 of theAmO$MI Aw jAAsue Swim T1 Snh Wd variation In the AE valu for Bantkhen a square root

Mems a Iw iv fern alh$ sedm haowg dayNW W t he plAL At tdo M tM aso W s as ctminued throufh eltaM t Ofpof -le lse wo am P OeNI VeOpls 1o ealluae tI lon4erm MIdual Offccls

A on W isset i a wse to hsh eapeel of these ooihss t ocks The baagkhon experimnent was letmiaI1DlVemisthis is a w hulu Lo g Tasug ia iasael aft - Msd residual Ves will be pr-Om crok TheseTwod esewm

SWWo

A

lP~U~7 ISIIPe1iuIWN e bsedisssin ian ghth siaoelalbe

984 0 6 O O - M s -s fWPas 11eSft W d Uo al a o

o

S4l~ lIIII I~l I 1f fl

( +

+ + + m + ++++-

++ +(++ + ++++ + ++ ++

- 66 -

ENOIMLSTAD ET AL RESPONSE BY FLOODED RICE TO PHOSPHATE ROCKS VARYING IN CITRATE SOLUBILITY

I I I I j0 I I

BANOKHEN BANGKHEN

pH 56 6 - 0o

TSP

NC

5~ ~ ~ L o 4 - -shy

4 ] - --------shy04

6S

|0 III 2 44 8r 66

I I I

a 1KLONG LUANG

pH 46 z KLONG LUANG

TSP Sc2 NCFL(N)

5 FLIC) J0 TU

oshy

4 ~40shy

3 bull eM0

I - I I I I I

0 II 22 44 88 0 5 10 15 20 IP APPLIED KO HA ABSOLUTE CITRAE SOLUBIITY INDEX

Fig 3-Yield of rough rice at Klong Luang and Bangkhen Rice Fig 4-Relative agronon effectiveness () of P sources ploz-Experiment Stations Thalmand as affected by rate and Source ted against citrate solubity Index for both Thailand field ex

of P applied (crop 1) periment (first crop only)

regression model accounted for 97 of the variation in sumably resulted from crop uptake and reaction with the RAE values at the Klong Luang location soil to form less soluble products Such effects may have

These experiments were continued during the dry season been more important at the lower rates since the two TSP of early 1970 to ascertain the residual effectiveness of the curyes converged at the highest rate of application various sources applied to the first crop No new P was These data from KIong Luang indicate that (i) residual applied except for the fresh TSP standard mentioned effects of all rocks except Mlcwuri were substantial (ii) above rhe experiment otherwise was conducted in a man the relationship between relative agronornic effectiveness ner similar to that followed in the first crop of the phosphate rocks and citrate solubility levels was

The response to both freshly applied ad residual P was largely obscured and (iii) the general superiority of TSP marked at the Klong Luang location and marginal at over phosphate rock in terms of effectiveiss persisted Bangkhen In fact at the latter location the response was through the second crop so small that little can be said regarding residual effectiveshyness The yield data from crop 2 at the Klong Luang DISCUSSION experiment are plotted in Fig 5 Greenhouse and field data presented in this paper show

Relative agronomic effectiveness values (Table 3) were clearly that there are substantial differences among phosshycalculated for the Klong Luang data using both the residual and freshly applied TSP as standards It is of Interest to note that the superiority of TSP over the phosphbte rocks Table 3-Relative agronomic effective values for field experishyments in Thailand persisted through the second crop The main difference in KlowlZmlnql~the residual effects is that with the exception of the MIs- s Crop 1 Crop 21 Crop 1-shysouri rock Ihe marked relationship between citratr-soluble WoiCarolina yl 59 76

phosphate rocks and RAE had largely rds norh) a 64P conltct of th Florida (eqlral is 6969 6

disapipeared In this acidic soil (pHi 46) P would by this I14o 69 63 40 ToonesS 31 65

limo be supplied by Intermediate reaction products In addl Missou 0 o lion to residues of the initial spatlte Ts P o 2 o 0

The TSP applied to the first crop declliv-d slightly In campIafcmWataesr e id ofeuhuloefor 22MA rates of PtColeouattd as aba u tlte td18 kS ratesp dlverage yield tM868 to 22 44

effectiveness relative to the freshly applied ISP This pre- of d s4

A

4

- 67 shy

-SOIL SCL SOC AMER I

KLONG LUANG CROP 2

Si 3

eN

TAPPLIEDKGHA

Fig 5-The residual effectiveness ovarious P sources for crop s compared with freshly applied TSP Klong Luang Rice

Experiment Station Thailand

phate rocks in terms of agronomic effectiveness for flooded

rice Further these differences can be predicted by means of citrate solubility or by the ACS index It appears that

the latter is more appropriate where the content of apatite varies among phospiate rocks The most soluble phosphate rocks approached but did not actually equal TSP in limit-iuig (maximum) yield in these experiments regardless of rate applied This agrees with the results of Ensminger Pearson and Armiger (4) One needs to consider the defi-nite posribility of same yield loss in zhoosing a phosphate

rock over TSP such yield losses must be weighed against the lower price of phosphate rock The explanation for such iosses may involve concentration of soluble P in the soil Khasawneh and Copeland (6) suggest that the growth rate of crop plants is a function of P concentration that can be maintained in the soil solution If P concentration is limiting or inadequate becawe of a lower dissolution rate of phosphate rock the growth iate ard uiiimate yield will be diminished accordingly

The RAE values bascd on yield increases reflect the agronomi effectiveness of these various sources relacve

to the TSP standard however these nould be supple-

mented by an economic analysis before rational choice can

be made The following calculations will provide an estimate of

the rclativ ecooomic effectiveness(REE)

Y t Ps aXpatREE -- 100

vahtercks t sphate or e b i- eor

Price of TSPkg fo

be Price of PRkg P

PROC VOL 38 1974 leO

90r

Wsoshy

0

60-LUSEPHOSPHATE ROCK

00 10 20

PTP PR

Fig 6-Relationship between relaZive effectiveness values (RAE) and the price ratios between TSP and phosphate rock Such a figure can be used in making a choice between these

sources

If REE exceeds 100 in this calculation the phosphate rock would be preferable to TSP

The REE calcuktaaa wre used in preparing an indifshyference curve (Fig 6) wherein RAE values are plotted

against PTsPPpR ratios The cu~rve itself connects those points at which REE equals 100 When exactly on the curve it makes no real economic difference what source is chosen After choosing a suitable price ratio one can then project upward from that ratio knowing the RAI

value (or estimating it from such data as shown in Fig 4 using citrate-soluble P content) one can then choose the source on the basis of both agronomic and economic conshysiderations For example if the price ratio is 25 and the RAE value of the phosphaite rock is greater than 40 the rock phosphate in question would be used However if the RAE value was less than 40 TSP would be a better choice There are indications that if the P in the more soluble phosphate ro~cks (North Carolina north Florida central Forida) is less than half as expensivz as that in TSP these rocks would be feasible altereaives to TSP on soils similar

to thoseused in Thailand This analysis does not take into account the possibility

of lower yields from use of phosphate rock In addition only a portion of the various yield response curves was used in this anlysis ie up to 22 kgha Beyond this

rate yield response was much less pronounced it could be argued that at less than maximum yields TSP would produce a certain yield at lower rates of P than would phosshy

pow ofrock This would especially be true for rates applioa example at Klong Luang 5500 kg of

rice pcr iectare could have been produced with either Ii kg of P as TSP or 44 kg of P as son of the more reacshy

tire phosphate rocks It should be pointed ot however

- 68 shy

(IIKIS amp YOUN( ARIFICIAL WEATIIERING OF OXIDIZED p[ll- IV

that this is the yield level that would show the widest difference such is the advantage of hindsight

Farmers generally prefer granular fertilizers for machine

or hand application This is a disadvantage for the phos-phate rocks which are normally arplied in finely divided form Recently experimental quantities of granular urea-

phosphate rock mixtures have been made by TVA Results of trials with these fertilizers will be reported elsewhere

LITERATURE CITED

1 Armiger W H and Maurice- Fried 1957 The plantavailability of various sources of phosphate rock Soil Sci Soc Amer Proc 21183-188

2 Bengston G W E C Sample and S E Allen 1974 Re-sponso of slash pine seedlings to P sGurces of varying ci-trato solubility Plant Soil (In press)

3 Caro JIt and W Hill 1956 Chard eristics and fer tilizcr value of phosphate rock from different fields J Agr Food Chem 4684-687

4 Ensminger I E R W Peirson and W II Atmiger1967 Effectivencs of rock phosphate as a source of phosshyphurus for plants US Dep Agr ARS Bull 4112S

5 Engelstad 0 P J G Getsinger anid I J Stangel 1972 Tailoring of fertiliers for rice cnnece Valley Author ftyNational Fertilicr Developmnent Center Hull Y-52

6 Khasawnch F E and Jane P Copcland 1971 (otton root growth and uptake of nutrievos relation oif phosph

rus uptake to quantity intensity and buffering capacit) Soil Sci Soc Amer Proc 37250-254

7 Lehr JR and G H McClellan 1972 A revised lIbora tory reactivity scale for evaljativg phosphate rocks for direct application Tennessee Valley Authcrity National Fertilizer Development Center lull Y-43

H Terman G L S EAllen and 0 P Engelstad 1970 Response by paddy cice to ratcs and suurces of appliedphosphorus Agron J63390-394

DIVISION S-9-SOIL MINERALOGY

Artificial Weathering of Oxidized Biotite IV The Inhibitory Effect of Potassium on Dissolution llate

R JGILKES AND R C YOUNG2

ABSTRACT

Rates of dissolution of oxidized biotites in OIM 001M ICI are severely depressed in the presence of IM KCI The amovnts of Al Mg Mn dissolved in the first eytraction are similir to those found without KCI however subsequent extractions remove these elements at 10-20 of the corresponding lICI rates This effect may be due to a decreased rate of vermiculite formation thereby reducing the effective basal area exposed to attack A decrease in dissolution rate with increasing ferric iron content was still apparent in the presence of IM KCI

Additional Index Words X-ray diffraction infrared aborp-

N EARLIER papers of this series the tole of biotite in soils

as a source of both macro and micronutrient elements

has been discussed ((Gilkes Young and Quirk 1972 1973ab) Experiments in artificial weathering uiing as va-

riety of extractants were undertaken to determiie the inlu-

ence of oxidation of octahedrally coordinated iron on the bull release of structural cations to solution The results of this

work demonstated that biotite behaves anomalously with respect to the other common ferromagnesian minerals found in soils Oxidation leads to the development of a high degree of resistance to cation exchange and dissolution Several authors have coiwludcd that decreased rates of K

Contribution from the Dep of Soi Science and Plant Nutri-tion Institute of Agriculture Univ of Western Australia Ned-lands 6009 Western Australia Received 29 Sept 1973 Ap-proved 8 Jan 1974

2 Senior Lecturer in Soil Science and Research Officer respeclively

replacement in electrolytes shown by oxidized biotites are

a result of the inclination of structural hydroxyl adjacent to newly created trivalent iron or vacant octahedral cation sites (Robert and Pedro 1959 Barshad and Kishk 1968) Gilkes et al (1973b) suggested that decreased rates of disshysolution of oxidized biotite in 0001 0t)l 0Af CI may also be due to the presence of inclined hydroxyl In this case a smaller surface area external and exposed intershylayer may be available for attack if K replacement by hyshydrogen ions occurs at a slower rate in oxidized biotites

Gastuche (1963) has shown that significant dissolution ofthe (IIM) biotile face may occur and it is easily demonshystrated that the proportion of exposed (001M) face in weathering biotites depends on the percentage K replaced

Rausell-Colom ct al (1965) have shown that hydrogen ions act in an identical fashion to metal cations in K exshy

change from micas In particular exchange c-f K by hydroshy

gen ions will be terminated or greatly reduced by high levels of K in solution Thus if dissolution of oxidized biotite by

acids is carried out at sufficiently high K levels to prevent vermiculization any differences in dissolution rate that may occur cannot simply be ascribed to differences in rates of K replacement The following results were obtained from such an experiment which unlike the experiment described in Parts I and II (Gilkes et al 1973ab) does not attempt to simulate natuiral - conditions

MATERIAILS AN) M HIiODS Further subsamples of the less than 0 hiotites used in K

excherandbaid disoo tu es (G iles e9n K exchange and acid dissolution studies (Gilkes et al1973ab) were used in these experiments Preparation of sequentiallyoxidized biotites without intermediate vermiculite formation is

Page 7: I70 - United States Agency for International Developmentto ascertan, but tgl.eetad, 1, L,. ("Tailoring of Pertiltiters for ice,'" TVA ulletin Y-52) states that the staft of IOi has

-4shy

applied at a rate of 60 kg Nha then approximately 2600000 mt of

N could profitably be used as SCU In 1972 33700000 mt of N was

used in the world and these figures suggest that as much as 8 of the

world consumption could potentially be expected to be applied as SCU

on rice

On a smaller scale approximately 114000 ha of rice are grown

in Peru nearly all of which is grown under conditions where SCU would

be the most desirable source of N Average rice yields in Peru are about

4000 kgha but research by Sanchez and coworkers (see attached report)

indicates that with ample N yields of 9000 kgha can be attained To

obtain these yields 25500 at of N as SCU would be needed compared to

42000 at of N as straight ure to obtain the same yield Thus SCU

would save 16500 tons of N or roughly 40 of the N needs

Results from India indicated that when equal amounts of N were

applied an average of about 1000 kgha more grain was produced on exshy

porLsentail plots This average figure included some areas where SCU was

not superior to AS In 1972 36500000 ha of rice were grown in India

with an average yield of 1616 kgha Proper use of SCU in place of

conventional form probably would not Increase yields an average of 1000

kghe under fam conditions as it would on the research plots but an

average of 500 k8 would be raoom ble This would rotult to an Increaa

of a50000 m of rice an Incras of 311 over the 197 production of

$90o000000 mt

The 40 04Melee Ore cited t dMWMaftampt tbe iAnCicoo in

ftc prodwilu peble Ihrow~h proer t o of 60 a wvrf of 0 for

fiff MWere- f04ieb di at Peded t1 1if1 pfJiiea1y 4i fie toshy

ditlsw winde Iee idveitu f~ rics a to JMe(0wiaihthe of 1CM La f

-5shy

precisely evaluate the economics of its use

Preliminary data indicated that SCU may be a superior source

of N for other tropical crops particularly long-season crops such as

sugar cane and pineapply grown in areas of high rainfall

The results of the wheat experiment followed by sorghum in

Pakistan in which the residual effects of SCU were evaluated suggest

that in intercropping and multiple cropping systems fertilizer nitroshy

gen may be applied in a slow-release form (SCU) at a convenient time in

the cropping system so that the nutrient elements will be released for

utilization by succeeding crops

Information already obtained indicate that SCU is a superior

source of N for crops grown on large enough areas to economically justify

its commercial production As more data are obtained with more crops

and from new areal the potential for its use will undoubtedly increase

Consequently as adequate supplies become available programs need to be

initiated in selected areas to introduce the use of SCU to agricultural

extension workers to the fertilizer industry end to farmers and to

encourage its coinercial production Since the cost per unit of N will

always be higher in SCU than in regular urea the use of SCU will be

econmically practical only under specific conditions and these restricshy

tions as to its use make it perative that effective education and

inforuation progra- be conducted prior to the comerctel Introduction

Of SU On 4 Wid eeie

-6-

BACKGROUND AND OBJECTIVES OF PROJECT

The present project is designed to capitalize on the momentum

and knowledge gained in the previous project Tailoring of Fertilizers

for Rice This project demonstrated that a superior nitrogen fertilshy

izer can be developed for tropical areas and that some relatively low

cost phosphate sources can be effectively utilized The present project

seeks to broaden the base for development of improved fertilizers through

a wider range of agronomic economic and engineering evaluations Preshy

viously the emphasis was placed on SCU as a nitrogen source and the dirshy

ect application of a limited number of selected phosphate rocks as phosshy

phorus sources for rice fertilization In this project a wider range of

fertilizer materials will be tested on a variety of upland crops such as

maize wheat sorghum and sugar cane cassava and others of national imshy

portance in various countries

Through its domestic fertilizer research and development proshy

gram TVA produces experimental fertilizer materials that may have poshy

tential for tropical soil conditions and crops With support from AID

in this project the capability viii exist to work toward improving fershy

tilitors for developing countrive through the necessary and logical soshy

quenco of production to ramer aceptonce to sess the potential for

co mrcial production

Pertilliers now being used in 4eveloping countriee relAtive

OeCOtcs And shortcoMiNge of the Mterials viii be Ovai6Isd Ktshy

true thel ena 4 4 0(fiashyporimrtAl product wlornriee pilot plt

ties OaI1 pl0t4 Will be W0bsutd to fcresMq tet in jre

tof f~wrisea with caomvstmwl siatofials rr f P0041610 161i

-7shy

screening will be done using soils of the area where the fertilizer

will be used Materials showing potential in greenhouse tests will

be further evaluated in actual field programs in selected countries

If successful at this stage economic and engineering data will be

compiled to assess the potential for commercial production In orshy

der to evaluate the product and process the total system will be

studied including storage handling and transportation from the

point of production to the farm Information developed throughout

this work will be available to industry foreign and domestic so

that it can develop a production marketing and use base for utishy

lizing the product This level of technology is rapidly being achieved

for SCU which received major emphasis in the previous study additional

agronomic economic and engineering data both with rice and with other

crops will be obtained to complement the previous findings

This project must be broad and combine a variety of professhy

sional disciplines but it is necessary to retain the flexibility to

move forward in specific directions as Improvements in products occur

This is necessary to insure that improved products identified in this

project can ultimately be made available to farmers zegrdless of their

economic and social status and that sufficient data aro available so

that induetry can make soomd decisions regarding the foasibility for omshy

marcial production

Major objectives of this project are eommartted as tollovws

(1) Developing Iertilaers to wt the nutrient neD of oocitic

4I l VhICh are not set iconmically withtfopical Crops and

etoshytoov~tmtl| Nrtiliieoro or that can set thse ne- s fre

006eItCOMlY ky 4ir lfte the W91~1ici of teftlliaer ultil4tin

-8

(2) Proving the value of these improved materials to insure that

they will increase farmers income over a large enough area

to attract and Justify commercial production

(3) Developing the production technology for new fertilizers as

a basis for encouraging and advising potential commercial proshy

duction The integrated process designs will seek product

quality and economy while striving to minimize harmful emisshy

sions to air water and land

(4) Working through cooperating organizations and with leaders in

research extension and industry to develop and demonstrate

methods for introducing new fertilizers to farmers so that they

will be properly used when they become commercially available

-9-

SCOPE OF WORK

This project integrates agronomic economic and engineering

expertise into a single team in order to develop improved fertilizers

for a wide range of crops and soils in developing countries Considershy

able emphasis is given during the first eighteen months to collecting

the data needed to complete the evaluation of sulfur-coated urea and

ground rock phosphate for lowland rice Both materials then are

scheduled for demonstrations during the latter part of the project in

order to educate extension workers and farmers and to attract the fershy

tilizer industry into commercial production Considerable emphasis is

given to the economic evaluation of a total production-marketing-use

system for each material in contrast to alternative nutrient sources

The probability of commercial production of SCU and ground

rock phosphate can be enhanced by expanding their use to additional

crops and soils Thus the project is expanded in scope as compared

to the previous project on tailoring of fertilizers for rice in order

to test these materials on additional crops

The expanded work includes a major effort in screening and

testing new compounds and forms of fertilizers for various food crops

produced under tropical conditions Alt hough it if already known that

more effective andor lens expensive formn of nitrogen and phosphorus

are needed a literature survey will nerve an Lan additional guide to

important and presing fertilizer problems

-10-

Much of the work with fertilizers for both lowland rice and

upland crops will consist of field tests in Southeast Asia Africa and

Latin America Greenhouse and engineering studies will back up the field

research All field experiments are designed to provide at least an esshy

timate of costs and returns for each fertilizer tested

PROJECT PLANS FORFISCAL 1975

In this section the work for fiscal 1975 will be discussed

It should be remembered that the success of this project depends in a

large part upon maintaining sufficient flexibility so that work in inshy

dividual countries can be adapted to supplement and complement programs

already under way While guidelines and plans of work must be developed

so that the objectives of the project are clearly defined detailed

plans for specific countries or groups of countries must be developed

by consultation wth local cooperators

These plans will be discussed under the following three general

phases of the project

I Engineering and development

2 Agronomic testing and evaluation

3 Economic evaluations

Engineering and Development

Phosphate Rock

Methods have been proposed for relatively simple treatment of

phosphate rock (PR) to increase the availability of the phosphate to make

it more suitable for direct application to the soil These treatments

may be economically feasible in certain areas especially in view of the

current world fertilizer situation Considerable work has been done at

TVA studying means of altering PR and plans are being developed to inishy

tiate further developmental work and field testing of these materials durshy

ing fiscal 1975

- 12 -

Emphasis will be placed upon obtaining samples of phosphate

rock from deposits in developing countries and testing and improving

procedures for increasing their citrate solubility and tzius availabilshy

ity of the phosphorus From this laboratory screening process sevural

sources will be selected from which small amounts (50 to 100 pounds)

will be prepared for greenhouse and field experiments ou various soils

(as described under agronomic section)

From these results one or two locations (or countries) will

be selected for development of a pilot program to utilize local sources

of phosphate rock This program will involve production of the altered

PR and its agronomic evaluation and then educational programs with govshy

ernment and commercial representatives to introduce its use to the farmers

Sulfur-Coated Fertilizers

Some preliminary work has been done in which urea-potash mixshy

tures were coated with sulfur The 7-day release rates for the N and

K20 were 17 and 36 respectively from the coated product (22-0-11-30S

grade) This was the first effort in coating a compound fertilizer

with the new coating system

The widely differing release rates for the nutrients from

the coated compound product raise some interesting prospects for tailshy

oring the nutrient release rate of sulfur-coated products It might

be possible to cogranulate materials of varying water solubility and

sulfur-coat them to produce products with release rates that would apshy

proximate the timing of nutrient requirements of the crop The need

for this type of controlled-release product has been mentioned many

times by agronomists and may be especially applicable in multiple and

intercropping systems

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Table 2

Mttct of 0 Sourco aampW $At On Upt~ks of 0 by Two Varitgtos of Paddy Rice

gr~a 1971

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- 24 shy

India--The results of four experiments conducted with flooded

transplanted rice in India by the All-India Coordinated Rice Project

Hyderabad are given in table 3 The response to N was excellent the

yield without N being only 41 of those obtained with basal applications

of N as uza With basal applications of SCU the yields were 20 higher

than with basal applications of urea and in the three experiments in

which urea applications were split yields with SCU were 18 higher than

yields with split applications of urea When comparing the average Nshy

response (kamp grainKg N) yields were increased 13 more by SCU than by

basal applications of urea

The data from one experiment with light irrigated rice in India

are given in table 4 yields were relatively low and differences between

N sources or method of application were not significant However yields

with SU tended to be higher than when all urea was applied at planting

but lower than when split applications of urea were applied Again yields

increased more than 13 more with SCU than with basal applications ofwere

ur

In tables 5 and 6 the yields of a short-duration transplanted

rice grown in irrigated light-textured soils at five locations in India

indicate that higher yields were obtained with SCU than with urea when apshy

plied as a basal application Yield increases due to basal N applications

were 502 greater with SCU than with urea However split applications of

resulted in yields equal to those obtained with basal applications ofurea

CU

The yields of direct-seeded upland rice grown at three locations

to India are given in table 7 and the relative yields in table 8 Yields

were low due to drought but good responses were nevertheless obtained for

- 25 -

Table 3

Effect of N Source and Time of Application on Yield of Paddy (Flooded) Rice in India 1972 (Summary of Reported Data from 4 Experiments)

Experimental Number Source Rate Method Yield Relative N-Response

and of of N of Yield Kg Grain

Season Nitrogen kgha Application mtha Kg N

- - - 196 34 -

Urea 120 Basal 573 100 314

11 Urea 120 80 + 40 611 107 345 Rabi SCU 120 Basal 713 124 430

12 - 0 - 202 30 -

Urea 125 Basal 682 100 384

Rabi Urea 125 35 + 20 + 35 + 35 633 95 344 SCU 125 Basal 781 115 463

13- 0 - 168 44

Urea 100 Basal 385 100 217

Kharif Urea 100 30 + 20 + 25 + 25 400 104 232 SCU 100 Basal 462 120 293

14 -

Urea -

125 -

Basal 355 650

55 100

-

236

Rabi SCU 125 Basal 781 120 341

-- 26 -

Table 4

Effect of N Source and Time of Application on Yield of Light Irrigated Rice in India 1972 (Summary of Reported Data From

One Experiment at Pattambi)

Experimental Number Source Rate Method Yield Relative N-Response

and of of N of Yield Kg Grain Season Nitrogen (kgha) Application (mtha) Q) Kg N

38 0 - 204 85 -Rabi Urea 120 Basal 241 100 308

Urea 120 60 + 0 + 30 + 30 267 ill 525 SCU 120 Basal 255 106 425

Table 5

Effect of N Source and Time of Application on Yields of Short-Duration Transplanted lice Variety Grown on Irrigated Light-Textured Soils at 5 Locations in India 1972

(Snmzarized From Reported Data)

Rate Grain Yields (MtHa) Source of N Method of N GrainI of N kgh Application Faizabod Karjat Mandva Pattabi laya Averaje X

- 291 266 211 19 340 260 -

Urea 100 Basal 386 407 361 285 482 3 124 Urea 100 50 + 25 + 25 399 430 434 334 6amp2 4A8 186

SCU 100 Basal 368 468 439 360 572 41 181

Table 6

Effect of I Source end Tlae of ApplIcattoo c RIstave Tle24 of a rt- rat1 T Lsd lice Vasrety Crin o Irrigated L41tshy1 at S Locitite mindi 1972

Rate ____________14_3

Source of X N~tbad of Of X An 1 tat14 1 acr X__T1 4v tatW ttva

- - - all 7i i

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21L1L LW ufU~ vie 114 3 10 106

As 11 i 41 4 smg LAY1 $Of 41)

Tabl I

f~ttwi Ot 0 6wirce 81d At$ a vt1d at flUop4d Rico to Vitjorim (1ITA)All fortitfour to rsodkeet OA lC~OVPr4( 114 5iI 000

W Iotors Ftslanp tospg Irritd for Two thvk Afler flontiw wft rkwa~ Floo4d 191)

- -I-of LWAIM) (IS YJl- fl-----II)

-0 10)

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4of O 149 6MID O 41110

KthD 00

- 38 -

Table 18

Yild of aemati-370 Rice at Punjab Agricultural Research

Institute in Pakistan in 1969-70 Grown Under

Couditions of Intermittent Flooding

Pate of application

=IL

o 0 67 67 100 100 67 67

100 100 67 67 200 100

Average for Sources

Ntha

AS 260 gres 279

320

Source f5

-

AS AS Ura Urea SCU SCU

Yield

Relative

93 100 115

(M)O

Yield

Increase Yield Due to N

(Ktlha) (mtha)

-212 245 033 274 062 260 048 297 085 315 103 325 112

Yield Increase

Relative

72048 067 100 108 161

(2)

- 39 shy

Short-statured high yielding rice varieties grown extenshy

sively in northern Peru require extremely high rates of conventional

N sources to achieve maximum yields The recovery of applied N is

extremely low due to the use of intermittent flooding This water

management system results in heavy N losses even with properly timed

split applications In search of simpler and more effective methods

of N management eight field experiments were conducted in the region

to evaluate sulfur-coated urea (SCU) an experimental slow-release N

source supplied by the Tennessee Valley Authority Rice yields were

increased an average of 59 more by pretransplant-incorporated SCU than

by urea or ammonium sulfate applied in the same manner SCU produced

excessive vegetative growth which resulted in yield reductions at high

N rates

Regardless of an assumed 48-higher unit N cost in SCU the

overall benefits of pretransplant-incorporated applications of SCU

were favorable since there was a decrease of 40 in the optimum rate

of N and the need for precise timing of application was eliminated

Pakistan--In Pakistan basal applications of AS urea and

SCU to rice grown under conditions of intermittent flooding in 1969-70

(table 18) indicate that SCU is a superior source of N as compared to

urea or AS when all N is applied at or before planting The data also

indicate that a yield response was obtained for P applications but a

comparison of N sources at each level of P indicates that no interaction

between N and P was present so that differences between N sources were

relatively the same at each level of P Yields were increased about 60

more when SCU was applied than when urea was applied Yield increases

with AS were only about 72 of the increase obtained with urea these reshy

sults do not agree with the generally-reported superiority of AS as comshy

pared to urea as a source of N for rice

- 40 -

In 1973 experiments were conducted in Pakistan using both

Basmati-370 and IRRI-6 varieties of rice grown under conditions of

When all N was applied at puddlingintermittent flooding (table 19)

or 12 at puddling and 12 at panicle initiation both AS and SCU were

superior to urea with SCU tending to be the most efficient source

However when N was applied 12 at transplanting and 12 at panicle

initiation SCU was the poorest source of N This would indicate that

the release of N from SCU applied at these times is too slow for optimwn

plant growth

In another experiment in Pakistan in 1973 no differences

in the effectiveness of urea AS or SCU were noted in the yields of

continuously-flooded rice (table 20) Again these results are conshy

sistent with earlier results which indicate no superiority for SCU

when rice is continuously flooded

Nitrogen Studies--Maize

A series of three experiments were conducted by IITA in

armo-Nigeria in 1972-73 comparing AS urea SCU and

CAN (calcium

nium nitrate) as sources of N for maize (table 21) A significant

yield response was obtained for N at each location but no conaistent

differences were noted amaong sources These results are consistent

with results at other locations which have not shown that SCU is a

superior source of N for maize grown over a period of 3 to 4 months

Nitrogen--Wheat

The yields of wheat in Pakistan in 1969-70 (tables 22 and

23) show that yields with SCU) tended to be lower than those with ureaJ

although at one locction where sorghum was grown followilng wheat with

Table 19

Yields of Basmati-370 and IRRI-6 Rice at Punjab Agricultural Experiment Station in Pakistan in 1973 Under

Conditions of Intermittent Flooding

Rate Yield Source of N Time of Yield (Mtha) Increase of N B-370 IRRI-6 Application Basmati-370 IRRI-6 Average (Mtha)

0 0 - 21 353 287 -

SCU 90 150 At Puddling 325 545 435 148

Urea 90 150 At Puddling 309 500 405 118

AS 90 150 At Puddling 324 529 427 140

SCU 90 150 Puddling 372 572 472 185 Panicle Initiation

Urea 90 150 Puddling 335 502 419 132 Panicle Initiation

AS 90 150 Puddling 353 529 441 154 Panicle Initiation

SCU 90 150 After Transplanting 312 562 437 150 Panicle Initiation

Urea 90 150 After Transplanting 340 624 482 195 Panicle Initiation

AS 90 150 After Transplanting 349 583 466 179 Panicle Initiation

All plots received 45 lbs P205acre as single superphosphate

Relative Yield Increase ()

Source of N At Puddling Puddling Panicle Transplant h Panicle

Urea 100 100 100 AS 119 117 92 SCU 125 140 77

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-48

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obosomhu rocks 0entk catetas rth Unrtdo costrat frwt) to

ht tse balt s Owosiv as that to TwP it rocks WM bo

fmtbt alteruutiv to MSso gotastte to~ Ik lee used to

ThUAIAd

Tht wMl dt gotmtmlaoti wout th possibility

of law Vhld free ww e1 e66001 4 It cooUt be YgWd Sutt

a4 10 0410 SWUSSM yt$4e TOP wUd predWr A r~ftIf fl~W t

1f f ot P the wuld phosphae rck TWOe viWMW efocitill b

true to low rttos t tsplusatiI P wi 9 Ma Liiam $S

amp4at r per Wforssota Mav two 64eed Wilk elikor It 44 of

P go Mi er 4A bg oftoP aon of tewmrowtni pboophals fwAh

It vwld be polotrd A Wevero wtht Is the jteld level that

W414 gk tko videm dtterem~j o(A 1 the 4~etamp tk~e~t

P11~0 pra~lpj prefer gre4r tuftlter for whlae

of hoaw ppltrstie Mhe to a dloedveaP for The PINSOO rocka

vkth m r II spotted 10 ftewil 4106Me tem

Nub studios we ovsosd o IVA vol gramleid a

forgof wee aMW pbsepbots A fths pemhawe evsielew us

Odellod to detMlee it otteettvmm of 11agotated Stoture of

mmfp MW phapa A (CI) sed graewletod pampAtlti arlolatod Pa

asowcs of P tof ttde ro The wreem proucts omre raGther

pemour~a ot P syag besmti andMi as elt ov so gpamwhr

iuipiqffhate(TS) low twseeo Is eftwiltve Is thet

W41 preeme wae oialain ire post-rItoi effriq to Stanlato the

pud6itt of Irto paddle Wee ofsdlseireplastiq

0 49 shy

lbs partially scldiaatede grawilated Ml prodlucts Vere isshy

toiwdiats in 5tftOvttWS54 betwee wroiPi ad TVP NotV5Ymf to

me coo were they mere twoe $a a etfective ao TIP 00 sipifleast

LVSUMI5 at0 efecto wore toun tor thee produteo Timely dtIampWde

FR (-t00 mmoh) Uia amp~rally oar affective than Owe gra8448r FOampprodt

featal twos o 6 aotetire s I

Nowvero it to felt that sfortber field euprtet vth

hese interials Amd ether typs of grometatodl Wter nre wrrautad

hater ceeuwodh that they have me areec poteatlal toi additoG

e tate wAne the sectte as OtawrI sed bovoloen turther

euperimeste vth few reck pboophar s0d with reck pbophat treated

to sehesa citrata selmtliy or to ha csaducted

Metbir sertes of tbme enprtaeats wae c~edtmcted by IITA

to Ut~rta copal TVP AOP APP aed it at see tecastisix (table 14)

No dot lalt sewseltles teh draw tree thee results simouely em pear to tlvdl bsww they do stwgpt tbat forthew work with

MR to werramid so tbme sels

Table 24

LttcttF Swce MaPlate 06 ieldot IM AWaia CoelsANS at IITA (Ugboda ad Apoin ail sorit) aid at Ike (AUaba s5i series)

1973

Plate ot IP Apinu 5 poundebods A1ab

Ocrol 0 Z94 419 M)

Tr ipl ruprphite 20 349 3799378

Triple vepput 40 M09 410$

Triple 6wp~~b1 4271 4344 42250

Ammotw-ritpophW to 4201 4124 4040

Amosim-rdop~phlt 40 4270 4106 4231

AM tuo-polpephats 20 404 4244 3794

~eai~mpelppepbuI 400)49 4094

Cee m-pbpbt to- 59

momee eph lto 0 4192

LSO (0 0$) 29 1025

Th WPII

- 51 shy

101Y114 tpeM-fI PEP~tbRP YO

1 ~ ~ gmw 1pc~biofl- 9 Kla4v4h

Upia U04 Copfind am Crehout Stet Rpano at (Ia4

rico t IF t rume6 orth~ Caralto phoophale rocl QAR) vaUN pqU41 to

roopon from cmonetrat4 gsporphophai (CIP) who ort$o4 oil k

was 45j itwas tafertor vb protioo4 oil p war OS Ib 4iffer~c

in rtc reepos to X cod14 oo bo ttrit4 4 4 hvsciag of boil p

~ Pt o r11221 0 tP

c theto the rhimecyllndor of rico tots par to)14M4i1 roeoi~t

ed oil emd PA prior to tho ont of an~robi4 cMioe AA~ oIifoshy

nAte bYpot t taet~d tO fC4sin t~r 4PWden0 Of f Ot(tivshy

ofOWailiJtyno o prefla4 all Put that 4t01etoo 14 tvsIk

of the Ott to prvvld a 014for C4m0 44 mI 1 o4sf

EfftC ftPet141on AIAM-0 V f401td 4 4iv 440 Mtft

Aa torfat VampP f4MWfCi4W04wt0amp to 4eturWlI Ot(Wel~drIC ft

Ot f tM6 the flooded Ott 00 14 04019I Pft0uAw Of gAr~s~lr

pkS$t M40b MP) Tw P1101 Piset Prodwie W-e 10M0di Wr04

(10-1) emW 0aretilp ddw01at4 P WAA firom Rrth M~flRU414~$

wee cowiared with fie Md reWim 44104 proo~fo) foruk oith laWItter

I v te-PR P OW1004 4 4 O Wf ottil OW ellt Oo

Oveiel1 the 40tt dmcruie to effetotww Wtollowui Co fme

PR tpaUIB1I ldoltmo PR (pamwlatr) offr~- ArmeuM) 0 orwi

- 52 -

Effect of N Sourc6 and Water Management on Response of Rice

toe Zn- M Giordano J J Mortvedt OP Engelstad and Greenhouse

Staff Several rotes of CO(14H2)2 and (H )2So4 vith or without ZnO

wore applied to flooded and nonflooded Crowley oil (limed to pH 75)

to determine response of Bluebelle rice to Zn Yields with both N

sources veotrgreator on flooded then on nonflooded soil In the abshy

ence of applied Zn total dry matter production vith CO(NH2)2 was

slightly lower than with (NH)2S04 on flooded soil and considerably

lover on nonflooded soil Concentration of Zn wan higher in straw and

grain of plants roun on flooded than on nonflooded soil Although

concentration of P was unaffected by N source or Zn rate there was

som indication that cranslocation of P from straw to grain may be

depressed in nouflooded rice Concentration of N was lower in straw

grown on flooded than on nonflooded soil due to apparent dilution

thereas both X sources resulted in similar N concentrations in straw

at all rates of N application the N concentration in grain increased

with 0 rAse

feSpongi gf(SM to Chjorospodiostte and Related P Sources--

Si Allen and Greonhoue Staff A greenhouse pot experiment was

couct44d with corn Brown on Hountview silt loam to compare the ofshy

fectlivees of chlorospodiosito (Chlor-l) with concentrated supershy

phosphate (CP) Thomas slag and North Carolina phosphate rock (NC-PR)

Oil-prillad urea-phophato rock (UPI) FeA1JMP 20 7 and monomthyl

phosphate were included in the experiment Based on yield of forage and

uptake of P by tvo crops each of 6-weeks duration the following conshy

stui were dravat

I Chlor-1 was slightly loss effective than CSI Thomas slaS or NC-PR

from which Chlor-l wae prepared

- 53 shy

2 Granular UPR was a poor source of P its effectiveness was greatly

increased by reducing the particle size to -35mesh

3 FeAlNH4P207 was unavailable to the crop

4 Monomethyl phosphate was equivalent toor slightly more effective-

than CSP

Research Indirectly Related to TVA-AID Project

Response of Several Rice Varieties to Zn in Moist or Flooded

Soil--P M Giordano J J Mortvedt and Greenhouse Several varieties

of rice from Mexico and the Dominican Republic currently under investishy

gation in Puerto Rico for adaptation to upland culture were compared with

some established United States varieties with regard to Zn response on

moist and flooded Crowley sil (pH 75) Chontalpa (Mexico) Bluebelle

(Texas) and Starbonnet (Arkansas) were most responsive to applied Zn

Juma (Dominican Republic) intermediate and Sinaloa (Mexico) and Calrose

(California) were the least responsive The Sinaloa varieties (Mexico)

appeared to be best adapted to non-flooded conditions whereas Chontalpa

and Calrose were poorest Concentrations of Zn generally were higher in

plants grown on flooded than moist soil

Pattern of Growth and Zinc Accumulation by Rice--P M Giordano

J J Mortvedt and Greenhouse Staff Rice plants were harvested at weekly

intervals from shortly after emergence through maturity The objective

was to determine the rate of growth and Zn uptake by a Zn responsive varshy

iety (Bluebelle) and a less Zn-responsive variety (Calrose) in the presence

or absence of Zn applied to Crowley sil (pHl 75) Dry matter production

of Calrose was linear with time of growth and of a similar magnitude until

heading with or without applied Zn Bluebelle followed a similar pattern

where Zn was applied However in the absence of applied Zn foliage yield

was reduced markedly

-54

Uptake of Zn was similar for both varieties whenZn was

applied Dry matter production and Zn uptake by the two varieties

also were comparable when Zn was applied However yield of Calrose

was much higher than that of Bluebelle in the absence of applied Zn

while Zn uptake was only slightly higher This suggests that the lesshy

ser responsiveness of Calrose to Zn may be due to more efficient utilishy

zation of Zn There was no indication of a greater demand for Zn durshy

ing reproduction in either variety as was suggested in earlier greenshy

house experiments

Response of Upland Rice to P and Zn--P M Giordano J J

Mortvedt and Greenhouse Staff Several rates of P and Zn were applied

to Crowley sil (limed to pH 75) in factorial combination to determine

whether differences in rice growth under flooded and nonflooded soil

conditions are related to plant nutrition Although straw yields were

slightly higher in nonflooded rice receiving adequate P and Zn grain

yields were higher in the flooded crop increased rates of F andor Zn

did not result in equal yields Except in the highest Zn rate (75 mg)

concentrations of Zn in both straw and grain were higher with flooding

Concentration of P increased with rate of applied P and was higher in

the grain or flooded than upland rice at a comparable P rate In conshy

trast concentrations of N were lower with flooding due in part to dilshy

ution from increased growth

Rice Response to N and P in Flooded and Unflooded Cultures--

G L Terman S E Allen and Greenhouse-Analytical Staff Rates of

N from 250 to 2000 ntpot and P from 0 to 1000 mtpot were applied for

Nato rice grown on Mountview sil and Sango sicl (625 kg of soil per

pot) Market yield response to N and P was obtained Yields of straw

- 55 shy

total yields N uptake and N recovery were higher on unflooded than

on flooded soil cultures Grain yields however were slightly higher

with flooding These results indicate that with adequate applied

nutrients especially of N rice yields without flooding can approach

or even equal those under flooding

Uptake of N P Ca Mg and Zn increased with yield response

to N and P while K uptake decreased on the Mountview soil Concentrations

of N and P increased with applied N and P respectively while concentrations

of other nutrients were diluted in most situations with yield response to N

or P

Results from this experiment show that amouats of N applied in

previous pot experiments for rice have been much too low especially if the

crop was grown to maturity

Response of Corn to S and N i UUASand Urea-S--S E Allen

and Greenhouse Staff Three greenhouse pot experiments were conducted to

measure response to S and N in ulfur coated urea (SCU) urea amonium

sulfate (UAS) and urea -S as well as estimate N losses from surface apshy

plied N sources

In Experiment 260 less than 20 of the S mixed with the soil

was recovered from SCU or urea-S granules by two crops of corn as comshy

pared to 45 or 80 from flowers of S or Na2SO 4 CLop response followed

a similar pattern

In Experiment 260-A N sources were surface applied and alshy

lowed to dry for two weeks before incorporation Into the soil and plantshy

ing Recovery of N by two crops of corn was 77-82 for AN an compared

to 37-70 for urea UAS urea-S and ICU Thus n this experiment loss

of N from urea did not appear to be re~dcud by light S-coatlngn or by Inshy

corporating S or AS in the granules

-S -

I xbprZnSlt a Wtch aU Meyto 0-Ai Wt f9r

higher reermo teOrtOrs cOM reSpWNO i r0100 Of N w

not oaisteontly related to sewe ot N In edl tust 0 ioltiUe Lim

lo in VMuwpped evlmtUTS 48 merind by seirest nte appresOehe

501 for uroa as cwarod to 210 for urea peepha

Rus- or Upse to LoAmIl34I a AriMed bI Earl U

MW NOWlsIIsIr-4 L Toman 5 1 Alln and eesese StNf rio

row on Sawg did (0 tpot) We 1l0l0 Ws feritiud vith 05is

of Npot mixod with the 6011 as aureCA NiAO) 1 Age god At Ures

was also itcluded at rtt t 05 10 end 15 of Upee Theas trealshy

onto were followed 4 wpdrsetago of U s AN wre 4C 10o or at I3n

Weeks toulin up to IS pot

A soil application of 10 pot rosulvod to the maim yield

at 4 weeks Tio4 sad percont prottis t intre raite tncreased rftishy

linearly with U applictalien IeseeItally all at the m iNd wit

the moil w domitrifted after flooding Grail end straw Ilelds vere

highly correlatod with tiliriag and vlh ubers of gralm arl

The results Widicat that 0$ to 10 a of Upot as orea or

NN bsuld be sied with the oil to stilate tiilrir with adshy

ditional 0 topireased later to increase grain lIds mad protia cmshy

tout

DIVISION 54- FERTILIZER TECHNOLOGY AND USE

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-f

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h Eaap 8n 14 sMsa of abw~greuad PU Pau WW 1 u itb IUKho 0aaphelem s 60 Otarlmmh At ~ 0sU Ishiseoo Cook oiA N uiplasu mAasslaly abess A leel

v doese a WKWye Is ks Nha m 6 sa4to dafo aONmuw The appee swm Wsssof adde N4 alalaed by vuMb ifaa W C Was sekilumganSro Is

bs eabI wish as aVWWa uwewy nap (f5s)f ad Mashes reaMeY valaes of 48 0 S414 CWm

owdb imto US Wh s vs sf 3I mld 54S fro 2 aMd 3) A A

valves a hevwae u Iar Walh basl oswas dhe uwpatr bshava of

tb~msusasl appkausu of ofta sede s have aoweN

TOW opl taoe for AieweeW 4OsmWMbas Op peas As Tabl 4 sling sob Os awowully eom grams Piel level Thes oeulam Ma sed as IM

-02

792 60L WI W A)49R Pio VOL 37 197)

primS o r OeampAd WU toa Them fl~ w At NOSSe earno maisslea Ia N he mOWamplIO yik ampWd IMe aampWmW OWa Owe wa UMs of KU to 41 Oke ampWiiIamm be dkrnety ewspokawleM(a s8 te camtd wie a eapmoe by TVA pavw ltoi NA poundrmdaka4us vrimeW460 o to ilkidm ofWW (Mtemas MuOwe 1973) TVA mwi bawld on soi ficedims IampWp seg rudwiv s~s0abet ke WNmdoe ON 01 K Is12 NOSW ie fssewnmu Ie I QvaaIi rowp IMA) f9

)amp m lodk byO voebmsaIS8OpeaWfrats 11 OWNmi a I a W idisod 0 81 Now 111 nindat Wm fysmpseaamp (If tsO tUmtI IsM $P shoroV4mmo knflkvnf (foOdme nuw ae Ow OImstwe in SM pnmm8 af tXm 10 114PIS kequoian wo Mpfii

SC~po umd spop~o VWt alm 4emWal 1 4ink PCmirsra M 1 ad AI 14bmms

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MGMe -M4 Wg kmuwadM 1Wr wih SCV4 Psmuck Wff It dlL Wm 1W led 0 1 oo teeA of aiwaisme aweeoid h

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-d

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41MB ~ ~ m ~ ~0 0-- 0 140 The ffsemn of food Nn else9~e(Ud~ ~ ~ ~~ WooksaS eAWw pjed of ho~raw of IU effadam vfdva oft xhj0I 13iAl

DIVISION 8-9-SOIL MINERALOGY

Amorphomw CeetIup en XmWra Ssrfmls

L C koits Am~ 0 tmmkaAf

ommp A faieiaAMTRACT skiwe lo nW ampM sm wi4h

Walo by a onMm I dmivid hseidm6Wlk W~edesie s

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Pa~~~eakr4awiS SeUeeiNaiA WOW 14e

PWWWW t HW f hea~I~~~~~a 0th

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d m M 0bmSaImu M-1 ofM6 h Intun to 7I

aiba maush WAesshwn~u9dSg a osusLwpI ~ v m

M PolsdAvoWdw Ons pugm~ low iwLW m We

of~U -a~ mo uNo

0401ts of 40

A e mun5d m i vvamp sa s ow bftIS i sa omdIs a w

edi1 hswopmo an ag am Iw anom erlwaPASneooie bnwoM po

o ~ do=lr 3s fluACWoSM Owaa VolM Ain b 400b adW g o as amob ofrMOWS A oo eWmaa ow $wofdi60 ow - ema

-v K Vcon l ap ad md ld KU lbs PoabumwA od w to domi a bembe 0b lt $014 i ampmomONo

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arbs awasm 00 iztv Am-~~~i u5~ms ashu is byw

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- omlos r umIWO1in pw

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of of~phaow tw bmsdf toamplboe

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ov4mnk wsi 9 Mxfeu~i am emwm ismi0wmd fq W No ~~ - f mug Aitowe eutlkowbmTV is

amppowftdmi TiM 0 Tie OAA mo p)a Mwomoi dOn4m A)w

MW 0 604 0M mm yaM 01MWOfdi to tA0 M OOAW uinw OSOb

ap is~e I the ampo A A Mwof ~Do toit op aenu w~ifiOimem~ MAN ampW)

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owud6moeft 4 Obind PINa~e

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~ -0

65

0IL CL OC AMXR PROC VOL 38 1974

)aT1 S4I104 ow Lusanll Tawng isa tall Thai variety known for beingIwo nonshyi s s ) sensitive to photoperiod A split-plot design was used in

S e e these euperimeots with 4 rates of P (I1 22 44 and 88t i V IV k of Pha) applied a main plot treatments and with the OF It sourMes of P as subplot treatments There were two checkS plots in each rmplicate The extra check plot was included to permit the application of fresh TSP standard Jor the

It- ti 06 + i bull fa succeeding crop the p-4me of bi was to permit accurate d awrnwal of the mdual effectiveness of the phosphate

ftinSUbI rock The P fertilioers were broadcast on the mud andthen Worporald In the soil during the last harrowing At

whM N both On ACS indx ampM time of transplanting Immediately before the last harrow61t (4j 5 4 01 P s 3Mm o Vallonal in con n 100 kgha of N as ammonium sulfate and 33 kghaWO Of Spews ampm lIW thaabe rocks do ACS indes of K as polium chloride were applied A total of 40 wa in prepw O do ctih k otent kha of N a ammoniunt sulfate was applied later in twoir P The hew oNed amp wM W for 5 of gw topdrossingp with about 5cm depth of water on the plotsvV I aiOMveffeOctveee Three to six ldayold selings pr hillwW the ACS idex were planted00OWW wia Oft fo an c irNk I p Coen 20 by 20 cm part in straight rows Hand weeding was used

and insecticide were applied for Insect control Grain yieldw was masared by sampling 5 ml of each plot excluding border rows The date of heading in each treatment and theUNiN d pbM W Weks rin tOW USA UMe In Tale yed componnts at hafvel were also recorded

I filM rsperMS esOM kdwdua 1 t ab The average yields of ough (unhulled) rice for botha 84 OW O 8uo 4 Thala TM was a locations are ploutel in PIS 3 for the first crop (1969 wet

owou thRM seaso0) The Veamps yield response was obtained at Klonge (s) W lDtO t Of dMa of1tw W d l R Luang however a 4ute satisfactory yield response was

~Mk ^d TVA UJSD ad Kd UnIveS obtalned to applied P at Bangkhen as wellXUe LaM e R qwrw Ims The sod was do Relative aponomlAe effectiveness values were calculated

VOW (a ksA w edmwL t Poesesm h Vy for these data and am presented In Table 3 The valuesdAY buo if dIe ouh ne Pee wtk a Mlak vow 1009 for th first crop are plotled against ACS index in Fig 41 This Im M i6ti l 4bNd IO a0 O mkarnk for both locatio r relationship was linear for the

11400 ThCpH 0( lb pW IW 01 th UpeiaW so Sanodion location and curtiltnear for KIng Luang The was u i 4A sksamp lMaor nrusio model amparounted for 81 of theAmO$MI Aw jAAsue Swim T1 Snh Wd variation In the AE valu for Bantkhen a square root

Mems a Iw iv fern alh$ sedm haowg dayNW W t he plAL At tdo M tM aso W s as ctminued throufh eltaM t Ofpof -le lse wo am P OeNI VeOpls 1o ealluae tI lon4erm MIdual Offccls

A on W isset i a wse to hsh eapeel of these ooihss t ocks The baagkhon experimnent was letmiaI1DlVemisthis is a w hulu Lo g Tasug ia iasael aft - Msd residual Ves will be pr-Om crok TheseTwod esewm

SWWo

A

lP~U~7 ISIIPe1iuIWN e bsedisssin ian ghth siaoelalbe

984 0 6 O O - M s -s fWPas 11eSft W d Uo al a o

o

S4l~ lIIII I~l I 1f fl

( +

+ + + m + ++++-

++ +(++ + ++++ + ++ ++

- 66 -

ENOIMLSTAD ET AL RESPONSE BY FLOODED RICE TO PHOSPHATE ROCKS VARYING IN CITRATE SOLUBILITY

I I I I j0 I I

BANOKHEN BANGKHEN

pH 56 6 - 0o

TSP

NC

5~ ~ ~ L o 4 - -shy

4 ] - --------shy04

6S

|0 III 2 44 8r 66

I I I

a 1KLONG LUANG

pH 46 z KLONG LUANG

TSP Sc2 NCFL(N)

5 FLIC) J0 TU

oshy

4 ~40shy

3 bull eM0

I - I I I I I

0 II 22 44 88 0 5 10 15 20 IP APPLIED KO HA ABSOLUTE CITRAE SOLUBIITY INDEX

Fig 3-Yield of rough rice at Klong Luang and Bangkhen Rice Fig 4-Relative agronon effectiveness () of P sources ploz-Experiment Stations Thalmand as affected by rate and Source ted against citrate solubity Index for both Thailand field ex

of P applied (crop 1) periment (first crop only)

regression model accounted for 97 of the variation in sumably resulted from crop uptake and reaction with the RAE values at the Klong Luang location soil to form less soluble products Such effects may have

These experiments were continued during the dry season been more important at the lower rates since the two TSP of early 1970 to ascertain the residual effectiveness of the curyes converged at the highest rate of application various sources applied to the first crop No new P was These data from KIong Luang indicate that (i) residual applied except for the fresh TSP standard mentioned effects of all rocks except Mlcwuri were substantial (ii) above rhe experiment otherwise was conducted in a man the relationship between relative agronornic effectiveness ner similar to that followed in the first crop of the phosphate rocks and citrate solubility levels was

The response to both freshly applied ad residual P was largely obscured and (iii) the general superiority of TSP marked at the Klong Luang location and marginal at over phosphate rock in terms of effectiveiss persisted Bangkhen In fact at the latter location the response was through the second crop so small that little can be said regarding residual effectiveshyness The yield data from crop 2 at the Klong Luang DISCUSSION experiment are plotted in Fig 5 Greenhouse and field data presented in this paper show

Relative agronomic effectiveness values (Table 3) were clearly that there are substantial differences among phosshycalculated for the Klong Luang data using both the residual and freshly applied TSP as standards It is of Interest to note that the superiority of TSP over the phosphbte rocks Table 3-Relative agronomic effective values for field experishyments in Thailand persisted through the second crop The main difference in KlowlZmlnql~the residual effects is that with the exception of the MIs- s Crop 1 Crop 21 Crop 1-shysouri rock Ihe marked relationship between citratr-soluble WoiCarolina yl 59 76

phosphate rocks and RAE had largely rds norh) a 64P conltct of th Florida (eqlral is 6969 6

disapipeared In this acidic soil (pHi 46) P would by this I14o 69 63 40 ToonesS 31 65

limo be supplied by Intermediate reaction products In addl Missou 0 o lion to residues of the initial spatlte Ts P o 2 o 0

The TSP applied to the first crop declliv-d slightly In campIafcmWataesr e id ofeuhuloefor 22MA rates of PtColeouattd as aba u tlte td18 kS ratesp dlverage yield tM868 to 22 44

effectiveness relative to the freshly applied ISP This pre- of d s4

A

4

- 67 shy

-SOIL SCL SOC AMER I

KLONG LUANG CROP 2

Si 3

eN

TAPPLIEDKGHA

Fig 5-The residual effectiveness ovarious P sources for crop s compared with freshly applied TSP Klong Luang Rice

Experiment Station Thailand

phate rocks in terms of agronomic effectiveness for flooded

rice Further these differences can be predicted by means of citrate solubility or by the ACS index It appears that

the latter is more appropriate where the content of apatite varies among phospiate rocks The most soluble phosphate rocks approached but did not actually equal TSP in limit-iuig (maximum) yield in these experiments regardless of rate applied This agrees with the results of Ensminger Pearson and Armiger (4) One needs to consider the defi-nite posribility of same yield loss in zhoosing a phosphate

rock over TSP such yield losses must be weighed against the lower price of phosphate rock The explanation for such iosses may involve concentration of soluble P in the soil Khasawneh and Copeland (6) suggest that the growth rate of crop plants is a function of P concentration that can be maintained in the soil solution If P concentration is limiting or inadequate becawe of a lower dissolution rate of phosphate rock the growth iate ard uiiimate yield will be diminished accordingly

The RAE values bascd on yield increases reflect the agronomi effectiveness of these various sources relacve

to the TSP standard however these nould be supple-

mented by an economic analysis before rational choice can

be made The following calculations will provide an estimate of

the rclativ ecooomic effectiveness(REE)

Y t Ps aXpatREE -- 100

vahtercks t sphate or e b i- eor

Price of TSPkg fo

be Price of PRkg P

PROC VOL 38 1974 leO

90r

Wsoshy

0

60-LUSEPHOSPHATE ROCK

00 10 20

PTP PR

Fig 6-Relationship between relaZive effectiveness values (RAE) and the price ratios between TSP and phosphate rock Such a figure can be used in making a choice between these

sources

If REE exceeds 100 in this calculation the phosphate rock would be preferable to TSP

The REE calcuktaaa wre used in preparing an indifshyference curve (Fig 6) wherein RAE values are plotted

against PTsPPpR ratios The cu~rve itself connects those points at which REE equals 100 When exactly on the curve it makes no real economic difference what source is chosen After choosing a suitable price ratio one can then project upward from that ratio knowing the RAI

value (or estimating it from such data as shown in Fig 4 using citrate-soluble P content) one can then choose the source on the basis of both agronomic and economic conshysiderations For example if the price ratio is 25 and the RAE value of the phosphaite rock is greater than 40 the rock phosphate in question would be used However if the RAE value was less than 40 TSP would be a better choice There are indications that if the P in the more soluble phosphate ro~cks (North Carolina north Florida central Forida) is less than half as expensivz as that in TSP these rocks would be feasible altereaives to TSP on soils similar

to thoseused in Thailand This analysis does not take into account the possibility

of lower yields from use of phosphate rock In addition only a portion of the various yield response curves was used in this anlysis ie up to 22 kgha Beyond this

rate yield response was much less pronounced it could be argued that at less than maximum yields TSP would produce a certain yield at lower rates of P than would phosshy

pow ofrock This would especially be true for rates applioa example at Klong Luang 5500 kg of

rice pcr iectare could have been produced with either Ii kg of P as TSP or 44 kg of P as son of the more reacshy

tire phosphate rocks It should be pointed ot however

- 68 shy

(IIKIS amp YOUN( ARIFICIAL WEATIIERING OF OXIDIZED p[ll- IV

that this is the yield level that would show the widest difference such is the advantage of hindsight

Farmers generally prefer granular fertilizers for machine

or hand application This is a disadvantage for the phos-phate rocks which are normally arplied in finely divided form Recently experimental quantities of granular urea-

phosphate rock mixtures have been made by TVA Results of trials with these fertilizers will be reported elsewhere

LITERATURE CITED

1 Armiger W H and Maurice- Fried 1957 The plantavailability of various sources of phosphate rock Soil Sci Soc Amer Proc 21183-188

2 Bengston G W E C Sample and S E Allen 1974 Re-sponso of slash pine seedlings to P sGurces of varying ci-trato solubility Plant Soil (In press)

3 Caro JIt and W Hill 1956 Chard eristics and fer tilizcr value of phosphate rock from different fields J Agr Food Chem 4684-687

4 Ensminger I E R W Peirson and W II Atmiger1967 Effectivencs of rock phosphate as a source of phosshyphurus for plants US Dep Agr ARS Bull 4112S

5 Engelstad 0 P J G Getsinger anid I J Stangel 1972 Tailoring of fertiliers for rice cnnece Valley Author ftyNational Fertilicr Developmnent Center Hull Y-52

6 Khasawnch F E and Jane P Copcland 1971 (otton root growth and uptake of nutrievos relation oif phosph

rus uptake to quantity intensity and buffering capacit) Soil Sci Soc Amer Proc 37250-254

7 Lehr JR and G H McClellan 1972 A revised lIbora tory reactivity scale for evaljativg phosphate rocks for direct application Tennessee Valley Authcrity National Fertilizer Development Center lull Y-43

H Terman G L S EAllen and 0 P Engelstad 1970 Response by paddy cice to ratcs and suurces of appliedphosphorus Agron J63390-394

DIVISION S-9-SOIL MINERALOGY

Artificial Weathering of Oxidized Biotite IV The Inhibitory Effect of Potassium on Dissolution llate

R JGILKES AND R C YOUNG2

ABSTRACT

Rates of dissolution of oxidized biotites in OIM 001M ICI are severely depressed in the presence of IM KCI The amovnts of Al Mg Mn dissolved in the first eytraction are similir to those found without KCI however subsequent extractions remove these elements at 10-20 of the corresponding lICI rates This effect may be due to a decreased rate of vermiculite formation thereby reducing the effective basal area exposed to attack A decrease in dissolution rate with increasing ferric iron content was still apparent in the presence of IM KCI

Additional Index Words X-ray diffraction infrared aborp-

N EARLIER papers of this series the tole of biotite in soils

as a source of both macro and micronutrient elements

has been discussed ((Gilkes Young and Quirk 1972 1973ab) Experiments in artificial weathering uiing as va-

riety of extractants were undertaken to determiie the inlu-

ence of oxidation of octahedrally coordinated iron on the bull release of structural cations to solution The results of this

work demonstated that biotite behaves anomalously with respect to the other common ferromagnesian minerals found in soils Oxidation leads to the development of a high degree of resistance to cation exchange and dissolution Several authors have coiwludcd that decreased rates of K

Contribution from the Dep of Soi Science and Plant Nutri-tion Institute of Agriculture Univ of Western Australia Ned-lands 6009 Western Australia Received 29 Sept 1973 Ap-proved 8 Jan 1974

2 Senior Lecturer in Soil Science and Research Officer respeclively

replacement in electrolytes shown by oxidized biotites are

a result of the inclination of structural hydroxyl adjacent to newly created trivalent iron or vacant octahedral cation sites (Robert and Pedro 1959 Barshad and Kishk 1968) Gilkes et al (1973b) suggested that decreased rates of disshysolution of oxidized biotite in 0001 0t)l 0Af CI may also be due to the presence of inclined hydroxyl In this case a smaller surface area external and exposed intershylayer may be available for attack if K replacement by hyshydrogen ions occurs at a slower rate in oxidized biotites

Gastuche (1963) has shown that significant dissolution ofthe (IIM) biotile face may occur and it is easily demonshystrated that the proportion of exposed (001M) face in weathering biotites depends on the percentage K replaced

Rausell-Colom ct al (1965) have shown that hydrogen ions act in an identical fashion to metal cations in K exshy

change from micas In particular exchange c-f K by hydroshy

gen ions will be terminated or greatly reduced by high levels of K in solution Thus if dissolution of oxidized biotite by

acids is carried out at sufficiently high K levels to prevent vermiculization any differences in dissolution rate that may occur cannot simply be ascribed to differences in rates of K replacement The following results were obtained from such an experiment which unlike the experiment described in Parts I and II (Gilkes et al 1973ab) does not attempt to simulate natuiral - conditions

MATERIAILS AN) M HIiODS Further subsamples of the less than 0 hiotites used in K

excherandbaid disoo tu es (G iles e9n K exchange and acid dissolution studies (Gilkes et al1973ab) were used in these experiments Preparation of sequentiallyoxidized biotites without intermediate vermiculite formation is

Page 8: I70 - United States Agency for International Developmentto ascertan, but tgl.eetad, 1, L,. ("Tailoring of Pertiltiters for ice,'" TVA ulletin Y-52) states that the staft of IOi has

-5shy

precisely evaluate the economics of its use

Preliminary data indicated that SCU may be a superior source

of N for other tropical crops particularly long-season crops such as

sugar cane and pineapply grown in areas of high rainfall

The results of the wheat experiment followed by sorghum in

Pakistan in which the residual effects of SCU were evaluated suggest

that in intercropping and multiple cropping systems fertilizer nitroshy

gen may be applied in a slow-release form (SCU) at a convenient time in

the cropping system so that the nutrient elements will be released for

utilization by succeeding crops

Information already obtained indicate that SCU is a superior

source of N for crops grown on large enough areas to economically justify

its commercial production As more data are obtained with more crops

and from new areal the potential for its use will undoubtedly increase

Consequently as adequate supplies become available programs need to be

initiated in selected areas to introduce the use of SCU to agricultural

extension workers to the fertilizer industry end to farmers and to

encourage its coinercial production Since the cost per unit of N will

always be higher in SCU than in regular urea the use of SCU will be

econmically practical only under specific conditions and these restricshy

tions as to its use make it perative that effective education and

inforuation progra- be conducted prior to the comerctel Introduction

Of SU On 4 Wid eeie

-6-

BACKGROUND AND OBJECTIVES OF PROJECT

The present project is designed to capitalize on the momentum

and knowledge gained in the previous project Tailoring of Fertilizers

for Rice This project demonstrated that a superior nitrogen fertilshy

izer can be developed for tropical areas and that some relatively low

cost phosphate sources can be effectively utilized The present project

seeks to broaden the base for development of improved fertilizers through

a wider range of agronomic economic and engineering evaluations Preshy

viously the emphasis was placed on SCU as a nitrogen source and the dirshy

ect application of a limited number of selected phosphate rocks as phosshy

phorus sources for rice fertilization In this project a wider range of

fertilizer materials will be tested on a variety of upland crops such as

maize wheat sorghum and sugar cane cassava and others of national imshy

portance in various countries

Through its domestic fertilizer research and development proshy

gram TVA produces experimental fertilizer materials that may have poshy

tential for tropical soil conditions and crops With support from AID

in this project the capability viii exist to work toward improving fershy

tilitors for developing countrive through the necessary and logical soshy

quenco of production to ramer aceptonce to sess the potential for

co mrcial production

Pertilliers now being used in 4eveloping countriee relAtive

OeCOtcs And shortcoMiNge of the Mterials viii be Ovai6Isd Ktshy

true thel ena 4 4 0(fiashyporimrtAl product wlornriee pilot plt

ties OaI1 pl0t4 Will be W0bsutd to fcresMq tet in jre

tof f~wrisea with caomvstmwl siatofials rr f P0041610 161i

-7shy

screening will be done using soils of the area where the fertilizer

will be used Materials showing potential in greenhouse tests will

be further evaluated in actual field programs in selected countries

If successful at this stage economic and engineering data will be

compiled to assess the potential for commercial production In orshy

der to evaluate the product and process the total system will be

studied including storage handling and transportation from the

point of production to the farm Information developed throughout

this work will be available to industry foreign and domestic so

that it can develop a production marketing and use base for utishy

lizing the product This level of technology is rapidly being achieved

for SCU which received major emphasis in the previous study additional

agronomic economic and engineering data both with rice and with other

crops will be obtained to complement the previous findings

This project must be broad and combine a variety of professhy

sional disciplines but it is necessary to retain the flexibility to

move forward in specific directions as Improvements in products occur

This is necessary to insure that improved products identified in this

project can ultimately be made available to farmers zegrdless of their

economic and social status and that sufficient data aro available so

that induetry can make soomd decisions regarding the foasibility for omshy

marcial production

Major objectives of this project are eommartted as tollovws

(1) Developing Iertilaers to wt the nutrient neD of oocitic

4I l VhICh are not set iconmically withtfopical Crops and

etoshytoov~tmtl| Nrtiliieoro or that can set thse ne- s fre

006eItCOMlY ky 4ir lfte the W91~1ici of teftlliaer ultil4tin

-8

(2) Proving the value of these improved materials to insure that

they will increase farmers income over a large enough area

to attract and Justify commercial production

(3) Developing the production technology for new fertilizers as

a basis for encouraging and advising potential commercial proshy

duction The integrated process designs will seek product

quality and economy while striving to minimize harmful emisshy

sions to air water and land

(4) Working through cooperating organizations and with leaders in

research extension and industry to develop and demonstrate

methods for introducing new fertilizers to farmers so that they

will be properly used when they become commercially available

-9-

SCOPE OF WORK

This project integrates agronomic economic and engineering

expertise into a single team in order to develop improved fertilizers

for a wide range of crops and soils in developing countries Considershy

able emphasis is given during the first eighteen months to collecting

the data needed to complete the evaluation of sulfur-coated urea and

ground rock phosphate for lowland rice Both materials then are

scheduled for demonstrations during the latter part of the project in

order to educate extension workers and farmers and to attract the fershy

tilizer industry into commercial production Considerable emphasis is

given to the economic evaluation of a total production-marketing-use

system for each material in contrast to alternative nutrient sources

The probability of commercial production of SCU and ground

rock phosphate can be enhanced by expanding their use to additional

crops and soils Thus the project is expanded in scope as compared

to the previous project on tailoring of fertilizers for rice in order

to test these materials on additional crops

The expanded work includes a major effort in screening and

testing new compounds and forms of fertilizers for various food crops

produced under tropical conditions Alt hough it if already known that

more effective andor lens expensive formn of nitrogen and phosphorus

are needed a literature survey will nerve an Lan additional guide to

important and presing fertilizer problems

-10-

Much of the work with fertilizers for both lowland rice and

upland crops will consist of field tests in Southeast Asia Africa and

Latin America Greenhouse and engineering studies will back up the field

research All field experiments are designed to provide at least an esshy

timate of costs and returns for each fertilizer tested

PROJECT PLANS FORFISCAL 1975

In this section the work for fiscal 1975 will be discussed

It should be remembered that the success of this project depends in a

large part upon maintaining sufficient flexibility so that work in inshy

dividual countries can be adapted to supplement and complement programs

already under way While guidelines and plans of work must be developed

so that the objectives of the project are clearly defined detailed

plans for specific countries or groups of countries must be developed

by consultation wth local cooperators

These plans will be discussed under the following three general

phases of the project

I Engineering and development

2 Agronomic testing and evaluation

3 Economic evaluations

Engineering and Development

Phosphate Rock

Methods have been proposed for relatively simple treatment of

phosphate rock (PR) to increase the availability of the phosphate to make

it more suitable for direct application to the soil These treatments

may be economically feasible in certain areas especially in view of the

current world fertilizer situation Considerable work has been done at

TVA studying means of altering PR and plans are being developed to inishy

tiate further developmental work and field testing of these materials durshy

ing fiscal 1975

- 12 -

Emphasis will be placed upon obtaining samples of phosphate

rock from deposits in developing countries and testing and improving

procedures for increasing their citrate solubility and tzius availabilshy

ity of the phosphorus From this laboratory screening process sevural

sources will be selected from which small amounts (50 to 100 pounds)

will be prepared for greenhouse and field experiments ou various soils

(as described under agronomic section)

From these results one or two locations (or countries) will

be selected for development of a pilot program to utilize local sources

of phosphate rock This program will involve production of the altered

PR and its agronomic evaluation and then educational programs with govshy

ernment and commercial representatives to introduce its use to the farmers

Sulfur-Coated Fertilizers

Some preliminary work has been done in which urea-potash mixshy

tures were coated with sulfur The 7-day release rates for the N and

K20 were 17 and 36 respectively from the coated product (22-0-11-30S

grade) This was the first effort in coating a compound fertilizer

with the new coating system

The widely differing release rates for the nutrients from

the coated compound product raise some interesting prospects for tailshy

oring the nutrient release rate of sulfur-coated products It might

be possible to cogranulate materials of varying water solubility and

sulfur-coat them to produce products with release rates that would apshy

proximate the timing of nutrient requirements of the crop The need

for this type of controlled-release product has been mentioned many

times by agronomists and may be especially applicable in multiple and

intercropping systems

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Table 2

Mttct of 0 Sourco aampW $At On Upt~ks of 0 by Two Varitgtos of Paddy Rice

gr~a 1971

~ MMUampL~ ~L ~ nYLALI~ 11 lemall

I ie

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- 24 shy

India--The results of four experiments conducted with flooded

transplanted rice in India by the All-India Coordinated Rice Project

Hyderabad are given in table 3 The response to N was excellent the

yield without N being only 41 of those obtained with basal applications

of N as uza With basal applications of SCU the yields were 20 higher

than with basal applications of urea and in the three experiments in

which urea applications were split yields with SCU were 18 higher than

yields with split applications of urea When comparing the average Nshy

response (kamp grainKg N) yields were increased 13 more by SCU than by

basal applications of urea

The data from one experiment with light irrigated rice in India

are given in table 4 yields were relatively low and differences between

N sources or method of application were not significant However yields

with SU tended to be higher than when all urea was applied at planting

but lower than when split applications of urea were applied Again yields

increased more than 13 more with SCU than with basal applications ofwere

ur

In tables 5 and 6 the yields of a short-duration transplanted

rice grown in irrigated light-textured soils at five locations in India

indicate that higher yields were obtained with SCU than with urea when apshy

plied as a basal application Yield increases due to basal N applications

were 502 greater with SCU than with urea However split applications of

resulted in yields equal to those obtained with basal applications ofurea

CU

The yields of direct-seeded upland rice grown at three locations

to India are given in table 7 and the relative yields in table 8 Yields

were low due to drought but good responses were nevertheless obtained for

- 25 -

Table 3

Effect of N Source and Time of Application on Yield of Paddy (Flooded) Rice in India 1972 (Summary of Reported Data from 4 Experiments)

Experimental Number Source Rate Method Yield Relative N-Response

and of of N of Yield Kg Grain

Season Nitrogen kgha Application mtha Kg N

- - - 196 34 -

Urea 120 Basal 573 100 314

11 Urea 120 80 + 40 611 107 345 Rabi SCU 120 Basal 713 124 430

12 - 0 - 202 30 -

Urea 125 Basal 682 100 384

Rabi Urea 125 35 + 20 + 35 + 35 633 95 344 SCU 125 Basal 781 115 463

13- 0 - 168 44

Urea 100 Basal 385 100 217

Kharif Urea 100 30 + 20 + 25 + 25 400 104 232 SCU 100 Basal 462 120 293

14 -

Urea -

125 -

Basal 355 650

55 100

-

236

Rabi SCU 125 Basal 781 120 341

-- 26 -

Table 4

Effect of N Source and Time of Application on Yield of Light Irrigated Rice in India 1972 (Summary of Reported Data From

One Experiment at Pattambi)

Experimental Number Source Rate Method Yield Relative N-Response

and of of N of Yield Kg Grain Season Nitrogen (kgha) Application (mtha) Q) Kg N

38 0 - 204 85 -Rabi Urea 120 Basal 241 100 308

Urea 120 60 + 0 + 30 + 30 267 ill 525 SCU 120 Basal 255 106 425

Table 5

Effect of N Source and Time of Application on Yields of Short-Duration Transplanted lice Variety Grown on Irrigated Light-Textured Soils at 5 Locations in India 1972

(Snmzarized From Reported Data)

Rate Grain Yields (MtHa) Source of N Method of N GrainI of N kgh Application Faizabod Karjat Mandva Pattabi laya Averaje X

- 291 266 211 19 340 260 -

Urea 100 Basal 386 407 361 285 482 3 124 Urea 100 50 + 25 + 25 399 430 434 334 6amp2 4A8 186

SCU 100 Basal 368 468 439 360 572 41 181

Table 6

Effect of I Source end Tlae of ApplIcattoo c RIstave Tle24 of a rt- rat1 T Lsd lice Vasrety Crin o Irrigated L41tshy1 at S Locitite mindi 1972

Rate ____________14_3

Source of X N~tbad of Of X An 1 tat14 1 acr X__T1 4v tatW ttva

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- 38 -

Table 18

Yild of aemati-370 Rice at Punjab Agricultural Research

Institute in Pakistan in 1969-70 Grown Under

Couditions of Intermittent Flooding

Pate of application

=IL

o 0 67 67 100 100 67 67

100 100 67 67 200 100

Average for Sources

Ntha

AS 260 gres 279

320

Source f5

-

AS AS Ura Urea SCU SCU

Yield

Relative

93 100 115

(M)O

Yield

Increase Yield Due to N

(Ktlha) (mtha)

-212 245 033 274 062 260 048 297 085 315 103 325 112

Yield Increase

Relative

72048 067 100 108 161

(2)

- 39 shy

Short-statured high yielding rice varieties grown extenshy

sively in northern Peru require extremely high rates of conventional

N sources to achieve maximum yields The recovery of applied N is

extremely low due to the use of intermittent flooding This water

management system results in heavy N losses even with properly timed

split applications In search of simpler and more effective methods

of N management eight field experiments were conducted in the region

to evaluate sulfur-coated urea (SCU) an experimental slow-release N

source supplied by the Tennessee Valley Authority Rice yields were

increased an average of 59 more by pretransplant-incorporated SCU than

by urea or ammonium sulfate applied in the same manner SCU produced

excessive vegetative growth which resulted in yield reductions at high

N rates

Regardless of an assumed 48-higher unit N cost in SCU the

overall benefits of pretransplant-incorporated applications of SCU

were favorable since there was a decrease of 40 in the optimum rate

of N and the need for precise timing of application was eliminated

Pakistan--In Pakistan basal applications of AS urea and

SCU to rice grown under conditions of intermittent flooding in 1969-70

(table 18) indicate that SCU is a superior source of N as compared to

urea or AS when all N is applied at or before planting The data also

indicate that a yield response was obtained for P applications but a

comparison of N sources at each level of P indicates that no interaction

between N and P was present so that differences between N sources were

relatively the same at each level of P Yields were increased about 60

more when SCU was applied than when urea was applied Yield increases

with AS were only about 72 of the increase obtained with urea these reshy

sults do not agree with the generally-reported superiority of AS as comshy

pared to urea as a source of N for rice

- 40 -

In 1973 experiments were conducted in Pakistan using both

Basmati-370 and IRRI-6 varieties of rice grown under conditions of

When all N was applied at puddlingintermittent flooding (table 19)

or 12 at puddling and 12 at panicle initiation both AS and SCU were

superior to urea with SCU tending to be the most efficient source

However when N was applied 12 at transplanting and 12 at panicle

initiation SCU was the poorest source of N This would indicate that

the release of N from SCU applied at these times is too slow for optimwn

plant growth

In another experiment in Pakistan in 1973 no differences

in the effectiveness of urea AS or SCU were noted in the yields of

continuously-flooded rice (table 20) Again these results are conshy

sistent with earlier results which indicate no superiority for SCU

when rice is continuously flooded

Nitrogen Studies--Maize

A series of three experiments were conducted by IITA in

armo-Nigeria in 1972-73 comparing AS urea SCU and

CAN (calcium

nium nitrate) as sources of N for maize (table 21) A significant

yield response was obtained for N at each location but no conaistent

differences were noted amaong sources These results are consistent

with results at other locations which have not shown that SCU is a

superior source of N for maize grown over a period of 3 to 4 months

Nitrogen--Wheat

The yields of wheat in Pakistan in 1969-70 (tables 22 and

23) show that yields with SCU) tended to be lower than those with ureaJ

although at one locction where sorghum was grown followilng wheat with

Table 19

Yields of Basmati-370 and IRRI-6 Rice at Punjab Agricultural Experiment Station in Pakistan in 1973 Under

Conditions of Intermittent Flooding

Rate Yield Source of N Time of Yield (Mtha) Increase of N B-370 IRRI-6 Application Basmati-370 IRRI-6 Average (Mtha)

0 0 - 21 353 287 -

SCU 90 150 At Puddling 325 545 435 148

Urea 90 150 At Puddling 309 500 405 118

AS 90 150 At Puddling 324 529 427 140

SCU 90 150 Puddling 372 572 472 185 Panicle Initiation

Urea 90 150 Puddling 335 502 419 132 Panicle Initiation

AS 90 150 Puddling 353 529 441 154 Panicle Initiation

SCU 90 150 After Transplanting 312 562 437 150 Panicle Initiation

Urea 90 150 After Transplanting 340 624 482 195 Panicle Initiation

AS 90 150 After Transplanting 349 583 466 179 Panicle Initiation

All plots received 45 lbs P205acre as single superphosphate

Relative Yield Increase ()

Source of N At Puddling Puddling Panicle Transplant h Panicle

Urea 100 100 100 AS 119 117 92 SCU 125 140 77

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-48

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asowcs of P tof ttde ro The wreem proucts omre raGther

pemour~a ot P syag besmti andMi as elt ov so gpamwhr

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toiwdiats in 5tftOvttWS54 betwee wroiPi ad TVP NotV5Ymf to

me coo were they mere twoe $a a etfective ao TIP 00 sipifleast

LVSUMI5 at0 efecto wore toun tor thee produteo Timely dtIampWde

FR (-t00 mmoh) Uia amp~rally oar affective than Owe gra8448r FOampprodt

featal twos o 6 aotetire s I

Nowvero it to felt that sfortber field euprtet vth

hese interials Amd ether typs of grometatodl Wter nre wrrautad

hater ceeuwodh that they have me areec poteatlal toi additoG

e tate wAne the sectte as OtawrI sed bovoloen turther

euperimeste vth few reck pboophar s0d with reck pbophat treated

to sehesa citrata selmtliy or to ha csaducted

Metbir sertes of tbme enprtaeats wae c~edtmcted by IITA

to Ut~rta copal TVP AOP APP aed it at see tecastisix (table 14)

No dot lalt sewseltles teh draw tree thee results simouely em pear to tlvdl bsww they do stwgpt tbat forthew work with

MR to werramid so tbme sels

Table 24

LttcttF Swce MaPlate 06 ieldot IM AWaia CoelsANS at IITA (Ugboda ad Apoin ail sorit) aid at Ike (AUaba s5i series)

1973

Plate ot IP Apinu 5 poundebods A1ab

Ocrol 0 Z94 419 M)

Tr ipl ruprphite 20 349 3799378

Triple vepput 40 M09 410$

Triple 6wp~~b1 4271 4344 42250

Ammotw-ritpophW to 4201 4124 4040

Amosim-rdop~phlt 40 4270 4106 4231

AM tuo-polpephats 20 404 4244 3794

~eai~mpelppepbuI 400)49 4094

Cee m-pbpbt to- 59

momee eph lto 0 4192

LSO (0 0$) 29 1025

Th WPII

- 51 shy

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1 ~ ~ gmw 1pc~biofl- 9 Kla4v4h

Upia U04 Copfind am Crehout Stet Rpano at (Ia4

rico t IF t rume6 orth~ Caralto phoophale rocl QAR) vaUN pqU41 to

roopon from cmonetrat4 gsporphophai (CIP) who ort$o4 oil k

was 45j itwas tafertor vb protioo4 oil p war OS Ib 4iffer~c

in rtc reepos to X cod14 oo bo ttrit4 4 4 hvsciag of boil p

~ Pt o r11221 0 tP

c theto the rhimecyllndor of rico tots par to)14M4i1 roeoi~t

ed oil emd PA prior to tho ont of an~robi4 cMioe AA~ oIifoshy

nAte bYpot t taet~d tO fC4sin t~r 4PWden0 Of f Ot(tivshy

ofOWailiJtyno o prefla4 all Put that 4t01etoo 14 tvsIk

of the Ott to prvvld a 014for C4m0 44 mI 1 o4sf

EfftC ftPet141on AIAM-0 V f401td 4 4iv 440 Mtft

Aa torfat VampP f4MWfCi4W04wt0amp to 4eturWlI Ot(Wel~drIC ft

Ot f tM6 the flooded Ott 00 14 04019I Pft0uAw Of gAr~s~lr

pkS$t M40b MP) Tw P1101 Piset Prodwie W-e 10M0di Wr04

(10-1) emW 0aretilp ddw01at4 P WAA firom Rrth M~flRU414~$

wee cowiared with fie Md reWim 44104 proo~fo) foruk oith laWItter

I v te-PR P OW1004 4 4 O Wf ottil OW ellt Oo

Oveiel1 the 40tt dmcruie to effetotww Wtollowui Co fme

PR tpaUIB1I ldoltmo PR (pamwlatr) offr~- ArmeuM) 0 orwi

- 52 -

Effect of N Sourc6 and Water Management on Response of Rice

toe Zn- M Giordano J J Mortvedt OP Engelstad and Greenhouse

Staff Several rotes of CO(14H2)2 and (H )2So4 vith or without ZnO

wore applied to flooded and nonflooded Crowley oil (limed to pH 75)

to determine response of Bluebelle rice to Zn Yields with both N

sources veotrgreator on flooded then on nonflooded soil In the abshy

ence of applied Zn total dry matter production vith CO(NH2)2 was

slightly lower than with (NH)2S04 on flooded soil and considerably

lover on nonflooded soil Concentration of Zn wan higher in straw and

grain of plants roun on flooded than on nonflooded soil Although

concentration of P was unaffected by N source or Zn rate there was

som indication that cranslocation of P from straw to grain may be

depressed in nouflooded rice Concentration of N was lower in straw

grown on flooded than on nonflooded soil due to apparent dilution

thereas both X sources resulted in similar N concentrations in straw

at all rates of N application the N concentration in grain increased

with 0 rAse

feSpongi gf(SM to Chjorospodiostte and Related P Sources--

Si Allen and Greonhoue Staff A greenhouse pot experiment was

couct44d with corn Brown on Hountview silt loam to compare the ofshy

fectlivees of chlorospodiosito (Chlor-l) with concentrated supershy

phosphate (CP) Thomas slag and North Carolina phosphate rock (NC-PR)

Oil-prillad urea-phophato rock (UPI) FeA1JMP 20 7 and monomthyl

phosphate were included in the experiment Based on yield of forage and

uptake of P by tvo crops each of 6-weeks duration the following conshy

stui were dravat

I Chlor-1 was slightly loss effective than CSI Thomas slaS or NC-PR

from which Chlor-l wae prepared

- 53 shy

2 Granular UPR was a poor source of P its effectiveness was greatly

increased by reducing the particle size to -35mesh

3 FeAlNH4P207 was unavailable to the crop

4 Monomethyl phosphate was equivalent toor slightly more effective-

than CSP

Research Indirectly Related to TVA-AID Project

Response of Several Rice Varieties to Zn in Moist or Flooded

Soil--P M Giordano J J Mortvedt and Greenhouse Several varieties

of rice from Mexico and the Dominican Republic currently under investishy

gation in Puerto Rico for adaptation to upland culture were compared with

some established United States varieties with regard to Zn response on

moist and flooded Crowley sil (pH 75) Chontalpa (Mexico) Bluebelle

(Texas) and Starbonnet (Arkansas) were most responsive to applied Zn

Juma (Dominican Republic) intermediate and Sinaloa (Mexico) and Calrose

(California) were the least responsive The Sinaloa varieties (Mexico)

appeared to be best adapted to non-flooded conditions whereas Chontalpa

and Calrose were poorest Concentrations of Zn generally were higher in

plants grown on flooded than moist soil

Pattern of Growth and Zinc Accumulation by Rice--P M Giordano

J J Mortvedt and Greenhouse Staff Rice plants were harvested at weekly

intervals from shortly after emergence through maturity The objective

was to determine the rate of growth and Zn uptake by a Zn responsive varshy

iety (Bluebelle) and a less Zn-responsive variety (Calrose) in the presence

or absence of Zn applied to Crowley sil (pHl 75) Dry matter production

of Calrose was linear with time of growth and of a similar magnitude until

heading with or without applied Zn Bluebelle followed a similar pattern

where Zn was applied However in the absence of applied Zn foliage yield

was reduced markedly

-54

Uptake of Zn was similar for both varieties whenZn was

applied Dry matter production and Zn uptake by the two varieties

also were comparable when Zn was applied However yield of Calrose

was much higher than that of Bluebelle in the absence of applied Zn

while Zn uptake was only slightly higher This suggests that the lesshy

ser responsiveness of Calrose to Zn may be due to more efficient utilishy

zation of Zn There was no indication of a greater demand for Zn durshy

ing reproduction in either variety as was suggested in earlier greenshy

house experiments

Response of Upland Rice to P and Zn--P M Giordano J J

Mortvedt and Greenhouse Staff Several rates of P and Zn were applied

to Crowley sil (limed to pH 75) in factorial combination to determine

whether differences in rice growth under flooded and nonflooded soil

conditions are related to plant nutrition Although straw yields were

slightly higher in nonflooded rice receiving adequate P and Zn grain

yields were higher in the flooded crop increased rates of F andor Zn

did not result in equal yields Except in the highest Zn rate (75 mg)

concentrations of Zn in both straw and grain were higher with flooding

Concentration of P increased with rate of applied P and was higher in

the grain or flooded than upland rice at a comparable P rate In conshy

trast concentrations of N were lower with flooding due in part to dilshy

ution from increased growth

Rice Response to N and P in Flooded and Unflooded Cultures--

G L Terman S E Allen and Greenhouse-Analytical Staff Rates of

N from 250 to 2000 ntpot and P from 0 to 1000 mtpot were applied for

Nato rice grown on Mountview sil and Sango sicl (625 kg of soil per

pot) Market yield response to N and P was obtained Yields of straw

- 55 shy

total yields N uptake and N recovery were higher on unflooded than

on flooded soil cultures Grain yields however were slightly higher

with flooding These results indicate that with adequate applied

nutrients especially of N rice yields without flooding can approach

or even equal those under flooding

Uptake of N P Ca Mg and Zn increased with yield response

to N and P while K uptake decreased on the Mountview soil Concentrations

of N and P increased with applied N and P respectively while concentrations

of other nutrients were diluted in most situations with yield response to N

or P

Results from this experiment show that amouats of N applied in

previous pot experiments for rice have been much too low especially if the

crop was grown to maturity

Response of Corn to S and N i UUASand Urea-S--S E Allen

and Greenhouse Staff Three greenhouse pot experiments were conducted to

measure response to S and N in ulfur coated urea (SCU) urea amonium

sulfate (UAS) and urea -S as well as estimate N losses from surface apshy

plied N sources

In Experiment 260 less than 20 of the S mixed with the soil

was recovered from SCU or urea-S granules by two crops of corn as comshy

pared to 45 or 80 from flowers of S or Na2SO 4 CLop response followed

a similar pattern

In Experiment 260-A N sources were surface applied and alshy

lowed to dry for two weeks before incorporation Into the soil and plantshy

ing Recovery of N by two crops of corn was 77-82 for AN an compared

to 37-70 for urea UAS urea-S and ICU Thus n this experiment loss

of N from urea did not appear to be re~dcud by light S-coatlngn or by Inshy

corporating S or AS in the granules

-S -

I xbprZnSlt a Wtch aU Meyto 0-Ai Wt f9r

higher reermo teOrtOrs cOM reSpWNO i r0100 Of N w

not oaisteontly related to sewe ot N In edl tust 0 ioltiUe Lim

lo in VMuwpped evlmtUTS 48 merind by seirest nte appresOehe

501 for uroa as cwarod to 210 for urea peepha

Rus- or Upse to LoAmIl34I a AriMed bI Earl U

MW NOWlsIIsIr-4 L Toman 5 1 Alln and eesese StNf rio

row on Sawg did (0 tpot) We 1l0l0 Ws feritiud vith 05is

of Npot mixod with the 6011 as aureCA NiAO) 1 Age god At Ures

was also itcluded at rtt t 05 10 end 15 of Upee Theas trealshy

onto were followed 4 wpdrsetago of U s AN wre 4C 10o or at I3n

Weeks toulin up to IS pot

A soil application of 10 pot rosulvod to the maim yield

at 4 weeks Tio4 sad percont prottis t intre raite tncreased rftishy

linearly with U applictalien IeseeItally all at the m iNd wit

the moil w domitrifted after flooding Grail end straw Ilelds vere

highly correlatod with tiliriag and vlh ubers of gralm arl

The results Widicat that 0$ to 10 a of Upot as orea or

NN bsuld be sied with the oil to stilate tiilrir with adshy

ditional 0 topireased later to increase grain lIds mad protia cmshy

tout

DIVISION 54- FERTILIZER TECHNOLOGY AND USE

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TOW opl taoe for AieweeW 4OsmWMbas Op peas As Tabl 4 sling sob Os awowully eom grams Piel level Thes oeulam Ma sed as IM

-02

792 60L WI W A)49R Pio VOL 37 197)

primS o r OeampAd WU toa Them fl~ w At NOSSe earno maisslea Ia N he mOWamplIO yik ampWd IMe aampWmW OWa Owe wa UMs of KU to 41 Oke ampWiiIamm be dkrnety ewspokawleM(a s8 te camtd wie a eapmoe by TVA pavw ltoi NA poundrmdaka4us vrimeW460 o to ilkidm ofWW (Mtemas MuOwe 1973) TVA mwi bawld on soi ficedims IampWp seg rudwiv s~s0abet ke WNmdoe ON 01 K Is12 NOSW ie fssewnmu Ie I QvaaIi rowp IMA) f9

)amp m lodk byO voebmsaIS8OpeaWfrats 11 OWNmi a I a W idisod 0 81 Now 111 nindat Wm fysmpseaamp (If tsO tUmtI IsM $P shoroV4mmo knflkvnf (foOdme nuw ae Ow OImstwe in SM pnmm8 af tXm 10 114PIS kequoian wo Mpfii

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DIVISION 8-9-SOIL MINERALOGY

Amorphomw CeetIup en XmWra Ssrfmls

L C koits Am~ 0 tmmkaAf

ommp A faieiaAMTRACT skiwe lo nW ampM sm wi4h

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CaO~OP aw AlNomI 4ornomd to9 IS is -l O SI g4he rpidyThus whim m dowu bWa 0 m m- ei u

d m M 0bmSaImu M-1 ofM6 h Intun to 7I

aiba maush WAesshwn~u9dSg a osusLwpI ~ v m

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- omlos r umIWO1in pw

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of of~phaow tw bmsdf toamplboe

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ov4mnk wsi 9 Mxfeu~i am emwm ismi0wmd fq W No ~~ - f mug Aitowe eutlkowbmTV is

amppowftdmi TiM 0 Tie OAA mo p)a Mwomoi dOn4m A)w

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65

0IL CL OC AMXR PROC VOL 38 1974

)aT1 S4I104 ow Lusanll Tawng isa tall Thai variety known for beingIwo nonshyi s s ) sensitive to photoperiod A split-plot design was used in

S e e these euperimeots with 4 rates of P (I1 22 44 and 88t i V IV k of Pha) applied a main plot treatments and with the OF It sourMes of P as subplot treatments There were two checkS plots in each rmplicate The extra check plot was included to permit the application of fresh TSP standard Jor the

It- ti 06 + i bull fa succeeding crop the p-4me of bi was to permit accurate d awrnwal of the mdual effectiveness of the phosphate

ftinSUbI rock The P fertilioers were broadcast on the mud andthen Worporald In the soil during the last harrowing At

whM N both On ACS indx ampM time of transplanting Immediately before the last harrow61t (4j 5 4 01 P s 3Mm o Vallonal in con n 100 kgha of N as ammonium sulfate and 33 kghaWO Of Spews ampm lIW thaabe rocks do ACS indes of K as polium chloride were applied A total of 40 wa in prepw O do ctih k otent kha of N a ammoniunt sulfate was applied later in twoir P The hew oNed amp wM W for 5 of gw topdrossingp with about 5cm depth of water on the plotsvV I aiOMveffeOctveee Three to six ldayold selings pr hillwW the ACS idex were planted00OWW wia Oft fo an c irNk I p Coen 20 by 20 cm part in straight rows Hand weeding was used

and insecticide were applied for Insect control Grain yieldw was masared by sampling 5 ml of each plot excluding border rows The date of heading in each treatment and theUNiN d pbM W Weks rin tOW USA UMe In Tale yed componnts at hafvel were also recorded

I filM rsperMS esOM kdwdua 1 t ab The average yields of ough (unhulled) rice for botha 84 OW O 8uo 4 Thala TM was a locations are ploutel in PIS 3 for the first crop (1969 wet

owou thRM seaso0) The Veamps yield response was obtained at Klonge (s) W lDtO t Of dMa of1tw W d l R Luang however a 4ute satisfactory yield response was

~Mk ^d TVA UJSD ad Kd UnIveS obtalned to applied P at Bangkhen as wellXUe LaM e R qwrw Ims The sod was do Relative aponomlAe effectiveness values were calculated

VOW (a ksA w edmwL t Poesesm h Vy for these data and am presented In Table 3 The valuesdAY buo if dIe ouh ne Pee wtk a Mlak vow 1009 for th first crop are plotled against ACS index in Fig 41 This Im M i6ti l 4bNd IO a0 O mkarnk for both locatio r relationship was linear for the

11400 ThCpH 0( lb pW IW 01 th UpeiaW so Sanodion location and curtiltnear for KIng Luang The was u i 4A sksamp lMaor nrusio model amparounted for 81 of theAmO$MI Aw jAAsue Swim T1 Snh Wd variation In the AE valu for Bantkhen a square root

Mems a Iw iv fern alh$ sedm haowg dayNW W t he plAL At tdo M tM aso W s as ctminued throufh eltaM t Ofpof -le lse wo am P OeNI VeOpls 1o ealluae tI lon4erm MIdual Offccls

A on W isset i a wse to hsh eapeel of these ooihss t ocks The baagkhon experimnent was letmiaI1DlVemisthis is a w hulu Lo g Tasug ia iasael aft - Msd residual Ves will be pr-Om crok TheseTwod esewm

SWWo

A

lP~U~7 ISIIPe1iuIWN e bsedisssin ian ghth siaoelalbe

984 0 6 O O - M s -s fWPas 11eSft W d Uo al a o

o

S4l~ lIIII I~l I 1f fl

( +

+ + + m + ++++-

++ +(++ + ++++ + ++ ++

- 66 -

ENOIMLSTAD ET AL RESPONSE BY FLOODED RICE TO PHOSPHATE ROCKS VARYING IN CITRATE SOLUBILITY

I I I I j0 I I

BANOKHEN BANGKHEN

pH 56 6 - 0o

TSP

NC

5~ ~ ~ L o 4 - -shy

4 ] - --------shy04

6S

|0 III 2 44 8r 66

I I I

a 1KLONG LUANG

pH 46 z KLONG LUANG

TSP Sc2 NCFL(N)

5 FLIC) J0 TU

oshy

4 ~40shy

3 bull eM0

I - I I I I I

0 II 22 44 88 0 5 10 15 20 IP APPLIED KO HA ABSOLUTE CITRAE SOLUBIITY INDEX

Fig 3-Yield of rough rice at Klong Luang and Bangkhen Rice Fig 4-Relative agronon effectiveness () of P sources ploz-Experiment Stations Thalmand as affected by rate and Source ted against citrate solubity Index for both Thailand field ex

of P applied (crop 1) periment (first crop only)

regression model accounted for 97 of the variation in sumably resulted from crop uptake and reaction with the RAE values at the Klong Luang location soil to form less soluble products Such effects may have

These experiments were continued during the dry season been more important at the lower rates since the two TSP of early 1970 to ascertain the residual effectiveness of the curyes converged at the highest rate of application various sources applied to the first crop No new P was These data from KIong Luang indicate that (i) residual applied except for the fresh TSP standard mentioned effects of all rocks except Mlcwuri were substantial (ii) above rhe experiment otherwise was conducted in a man the relationship between relative agronornic effectiveness ner similar to that followed in the first crop of the phosphate rocks and citrate solubility levels was

The response to both freshly applied ad residual P was largely obscured and (iii) the general superiority of TSP marked at the Klong Luang location and marginal at over phosphate rock in terms of effectiveiss persisted Bangkhen In fact at the latter location the response was through the second crop so small that little can be said regarding residual effectiveshyness The yield data from crop 2 at the Klong Luang DISCUSSION experiment are plotted in Fig 5 Greenhouse and field data presented in this paper show

Relative agronomic effectiveness values (Table 3) were clearly that there are substantial differences among phosshycalculated for the Klong Luang data using both the residual and freshly applied TSP as standards It is of Interest to note that the superiority of TSP over the phosphbte rocks Table 3-Relative agronomic effective values for field experishyments in Thailand persisted through the second crop The main difference in KlowlZmlnql~the residual effects is that with the exception of the MIs- s Crop 1 Crop 21 Crop 1-shysouri rock Ihe marked relationship between citratr-soluble WoiCarolina yl 59 76

phosphate rocks and RAE had largely rds norh) a 64P conltct of th Florida (eqlral is 6969 6

disapipeared In this acidic soil (pHi 46) P would by this I14o 69 63 40 ToonesS 31 65

limo be supplied by Intermediate reaction products In addl Missou 0 o lion to residues of the initial spatlte Ts P o 2 o 0

The TSP applied to the first crop declliv-d slightly In campIafcmWataesr e id ofeuhuloefor 22MA rates of PtColeouattd as aba u tlte td18 kS ratesp dlverage yield tM868 to 22 44

effectiveness relative to the freshly applied ISP This pre- of d s4

A

4

- 67 shy

-SOIL SCL SOC AMER I

KLONG LUANG CROP 2

Si 3

eN

TAPPLIEDKGHA

Fig 5-The residual effectiveness ovarious P sources for crop s compared with freshly applied TSP Klong Luang Rice

Experiment Station Thailand

phate rocks in terms of agronomic effectiveness for flooded

rice Further these differences can be predicted by means of citrate solubility or by the ACS index It appears that

the latter is more appropriate where the content of apatite varies among phospiate rocks The most soluble phosphate rocks approached but did not actually equal TSP in limit-iuig (maximum) yield in these experiments regardless of rate applied This agrees with the results of Ensminger Pearson and Armiger (4) One needs to consider the defi-nite posribility of same yield loss in zhoosing a phosphate

rock over TSP such yield losses must be weighed against the lower price of phosphate rock The explanation for such iosses may involve concentration of soluble P in the soil Khasawneh and Copeland (6) suggest that the growth rate of crop plants is a function of P concentration that can be maintained in the soil solution If P concentration is limiting or inadequate becawe of a lower dissolution rate of phosphate rock the growth iate ard uiiimate yield will be diminished accordingly

The RAE values bascd on yield increases reflect the agronomi effectiveness of these various sources relacve

to the TSP standard however these nould be supple-

mented by an economic analysis before rational choice can

be made The following calculations will provide an estimate of

the rclativ ecooomic effectiveness(REE)

Y t Ps aXpatREE -- 100

vahtercks t sphate or e b i- eor

Price of TSPkg fo

be Price of PRkg P

PROC VOL 38 1974 leO

90r

Wsoshy

0

60-LUSEPHOSPHATE ROCK

00 10 20

PTP PR

Fig 6-Relationship between relaZive effectiveness values (RAE) and the price ratios between TSP and phosphate rock Such a figure can be used in making a choice between these

sources

If REE exceeds 100 in this calculation the phosphate rock would be preferable to TSP

The REE calcuktaaa wre used in preparing an indifshyference curve (Fig 6) wherein RAE values are plotted

against PTsPPpR ratios The cu~rve itself connects those points at which REE equals 100 When exactly on the curve it makes no real economic difference what source is chosen After choosing a suitable price ratio one can then project upward from that ratio knowing the RAI

value (or estimating it from such data as shown in Fig 4 using citrate-soluble P content) one can then choose the source on the basis of both agronomic and economic conshysiderations For example if the price ratio is 25 and the RAE value of the phosphaite rock is greater than 40 the rock phosphate in question would be used However if the RAE value was less than 40 TSP would be a better choice There are indications that if the P in the more soluble phosphate ro~cks (North Carolina north Florida central Forida) is less than half as expensivz as that in TSP these rocks would be feasible altereaives to TSP on soils similar

to thoseused in Thailand This analysis does not take into account the possibility

of lower yields from use of phosphate rock In addition only a portion of the various yield response curves was used in this anlysis ie up to 22 kgha Beyond this

rate yield response was much less pronounced it could be argued that at less than maximum yields TSP would produce a certain yield at lower rates of P than would phosshy

pow ofrock This would especially be true for rates applioa example at Klong Luang 5500 kg of

rice pcr iectare could have been produced with either Ii kg of P as TSP or 44 kg of P as son of the more reacshy

tire phosphate rocks It should be pointed ot however

- 68 shy

(IIKIS amp YOUN( ARIFICIAL WEATIIERING OF OXIDIZED p[ll- IV

that this is the yield level that would show the widest difference such is the advantage of hindsight

Farmers generally prefer granular fertilizers for machine

or hand application This is a disadvantage for the phos-phate rocks which are normally arplied in finely divided form Recently experimental quantities of granular urea-

phosphate rock mixtures have been made by TVA Results of trials with these fertilizers will be reported elsewhere

LITERATURE CITED

1 Armiger W H and Maurice- Fried 1957 The plantavailability of various sources of phosphate rock Soil Sci Soc Amer Proc 21183-188

2 Bengston G W E C Sample and S E Allen 1974 Re-sponso of slash pine seedlings to P sGurces of varying ci-trato solubility Plant Soil (In press)

3 Caro JIt and W Hill 1956 Chard eristics and fer tilizcr value of phosphate rock from different fields J Agr Food Chem 4684-687

4 Ensminger I E R W Peirson and W II Atmiger1967 Effectivencs of rock phosphate as a source of phosshyphurus for plants US Dep Agr ARS Bull 4112S

5 Engelstad 0 P J G Getsinger anid I J Stangel 1972 Tailoring of fertiliers for rice cnnece Valley Author ftyNational Fertilicr Developmnent Center Hull Y-52

6 Khasawnch F E and Jane P Copcland 1971 (otton root growth and uptake of nutrievos relation oif phosph

rus uptake to quantity intensity and buffering capacit) Soil Sci Soc Amer Proc 37250-254

7 Lehr JR and G H McClellan 1972 A revised lIbora tory reactivity scale for evaljativg phosphate rocks for direct application Tennessee Valley Authcrity National Fertilizer Development Center lull Y-43

H Terman G L S EAllen and 0 P Engelstad 1970 Response by paddy cice to ratcs and suurces of appliedphosphorus Agron J63390-394

DIVISION S-9-SOIL MINERALOGY

Artificial Weathering of Oxidized Biotite IV The Inhibitory Effect of Potassium on Dissolution llate

R JGILKES AND R C YOUNG2

ABSTRACT

Rates of dissolution of oxidized biotites in OIM 001M ICI are severely depressed in the presence of IM KCI The amovnts of Al Mg Mn dissolved in the first eytraction are similir to those found without KCI however subsequent extractions remove these elements at 10-20 of the corresponding lICI rates This effect may be due to a decreased rate of vermiculite formation thereby reducing the effective basal area exposed to attack A decrease in dissolution rate with increasing ferric iron content was still apparent in the presence of IM KCI

Additional Index Words X-ray diffraction infrared aborp-

N EARLIER papers of this series the tole of biotite in soils

as a source of both macro and micronutrient elements

has been discussed ((Gilkes Young and Quirk 1972 1973ab) Experiments in artificial weathering uiing as va-

riety of extractants were undertaken to determiie the inlu-

ence of oxidation of octahedrally coordinated iron on the bull release of structural cations to solution The results of this

work demonstated that biotite behaves anomalously with respect to the other common ferromagnesian minerals found in soils Oxidation leads to the development of a high degree of resistance to cation exchange and dissolution Several authors have coiwludcd that decreased rates of K

Contribution from the Dep of Soi Science and Plant Nutri-tion Institute of Agriculture Univ of Western Australia Ned-lands 6009 Western Australia Received 29 Sept 1973 Ap-proved 8 Jan 1974

2 Senior Lecturer in Soil Science and Research Officer respeclively

replacement in electrolytes shown by oxidized biotites are

a result of the inclination of structural hydroxyl adjacent to newly created trivalent iron or vacant octahedral cation sites (Robert and Pedro 1959 Barshad and Kishk 1968) Gilkes et al (1973b) suggested that decreased rates of disshysolution of oxidized biotite in 0001 0t)l 0Af CI may also be due to the presence of inclined hydroxyl In this case a smaller surface area external and exposed intershylayer may be available for attack if K replacement by hyshydrogen ions occurs at a slower rate in oxidized biotites

Gastuche (1963) has shown that significant dissolution ofthe (IIM) biotile face may occur and it is easily demonshystrated that the proportion of exposed (001M) face in weathering biotites depends on the percentage K replaced

Rausell-Colom ct al (1965) have shown that hydrogen ions act in an identical fashion to metal cations in K exshy

change from micas In particular exchange c-f K by hydroshy

gen ions will be terminated or greatly reduced by high levels of K in solution Thus if dissolution of oxidized biotite by

acids is carried out at sufficiently high K levels to prevent vermiculization any differences in dissolution rate that may occur cannot simply be ascribed to differences in rates of K replacement The following results were obtained from such an experiment which unlike the experiment described in Parts I and II (Gilkes et al 1973ab) does not attempt to simulate natuiral - conditions

MATERIAILS AN) M HIiODS Further subsamples of the less than 0 hiotites used in K

excherandbaid disoo tu es (G iles e9n K exchange and acid dissolution studies (Gilkes et al1973ab) were used in these experiments Preparation of sequentiallyoxidized biotites without intermediate vermiculite formation is

Page 9: I70 - United States Agency for International Developmentto ascertan, but tgl.eetad, 1, L,. ("Tailoring of Pertiltiters for ice,'" TVA ulletin Y-52) states that the staft of IOi has

-6-

BACKGROUND AND OBJECTIVES OF PROJECT

The present project is designed to capitalize on the momentum

and knowledge gained in the previous project Tailoring of Fertilizers

for Rice This project demonstrated that a superior nitrogen fertilshy

izer can be developed for tropical areas and that some relatively low

cost phosphate sources can be effectively utilized The present project

seeks to broaden the base for development of improved fertilizers through

a wider range of agronomic economic and engineering evaluations Preshy

viously the emphasis was placed on SCU as a nitrogen source and the dirshy

ect application of a limited number of selected phosphate rocks as phosshy

phorus sources for rice fertilization In this project a wider range of

fertilizer materials will be tested on a variety of upland crops such as

maize wheat sorghum and sugar cane cassava and others of national imshy

portance in various countries

Through its domestic fertilizer research and development proshy

gram TVA produces experimental fertilizer materials that may have poshy

tential for tropical soil conditions and crops With support from AID

in this project the capability viii exist to work toward improving fershy

tilitors for developing countrive through the necessary and logical soshy

quenco of production to ramer aceptonce to sess the potential for

co mrcial production

Pertilliers now being used in 4eveloping countriee relAtive

OeCOtcs And shortcoMiNge of the Mterials viii be Ovai6Isd Ktshy

true thel ena 4 4 0(fiashyporimrtAl product wlornriee pilot plt

ties OaI1 pl0t4 Will be W0bsutd to fcresMq tet in jre

tof f~wrisea with caomvstmwl siatofials rr f P0041610 161i

-7shy

screening will be done using soils of the area where the fertilizer

will be used Materials showing potential in greenhouse tests will

be further evaluated in actual field programs in selected countries

If successful at this stage economic and engineering data will be

compiled to assess the potential for commercial production In orshy

der to evaluate the product and process the total system will be

studied including storage handling and transportation from the

point of production to the farm Information developed throughout

this work will be available to industry foreign and domestic so

that it can develop a production marketing and use base for utishy

lizing the product This level of technology is rapidly being achieved

for SCU which received major emphasis in the previous study additional

agronomic economic and engineering data both with rice and with other

crops will be obtained to complement the previous findings

This project must be broad and combine a variety of professhy

sional disciplines but it is necessary to retain the flexibility to

move forward in specific directions as Improvements in products occur

This is necessary to insure that improved products identified in this

project can ultimately be made available to farmers zegrdless of their

economic and social status and that sufficient data aro available so

that induetry can make soomd decisions regarding the foasibility for omshy

marcial production

Major objectives of this project are eommartted as tollovws

(1) Developing Iertilaers to wt the nutrient neD of oocitic

4I l VhICh are not set iconmically withtfopical Crops and

etoshytoov~tmtl| Nrtiliieoro or that can set thse ne- s fre

006eItCOMlY ky 4ir lfte the W91~1ici of teftlliaer ultil4tin

-8

(2) Proving the value of these improved materials to insure that

they will increase farmers income over a large enough area

to attract and Justify commercial production

(3) Developing the production technology for new fertilizers as

a basis for encouraging and advising potential commercial proshy

duction The integrated process designs will seek product

quality and economy while striving to minimize harmful emisshy

sions to air water and land

(4) Working through cooperating organizations and with leaders in

research extension and industry to develop and demonstrate

methods for introducing new fertilizers to farmers so that they

will be properly used when they become commercially available

-9-

SCOPE OF WORK

This project integrates agronomic economic and engineering

expertise into a single team in order to develop improved fertilizers

for a wide range of crops and soils in developing countries Considershy

able emphasis is given during the first eighteen months to collecting

the data needed to complete the evaluation of sulfur-coated urea and

ground rock phosphate for lowland rice Both materials then are

scheduled for demonstrations during the latter part of the project in

order to educate extension workers and farmers and to attract the fershy

tilizer industry into commercial production Considerable emphasis is

given to the economic evaluation of a total production-marketing-use

system for each material in contrast to alternative nutrient sources

The probability of commercial production of SCU and ground

rock phosphate can be enhanced by expanding their use to additional

crops and soils Thus the project is expanded in scope as compared

to the previous project on tailoring of fertilizers for rice in order

to test these materials on additional crops

The expanded work includes a major effort in screening and

testing new compounds and forms of fertilizers for various food crops

produced under tropical conditions Alt hough it if already known that

more effective andor lens expensive formn of nitrogen and phosphorus

are needed a literature survey will nerve an Lan additional guide to

important and presing fertilizer problems

-10-

Much of the work with fertilizers for both lowland rice and

upland crops will consist of field tests in Southeast Asia Africa and

Latin America Greenhouse and engineering studies will back up the field

research All field experiments are designed to provide at least an esshy

timate of costs and returns for each fertilizer tested

PROJECT PLANS FORFISCAL 1975

In this section the work for fiscal 1975 will be discussed

It should be remembered that the success of this project depends in a

large part upon maintaining sufficient flexibility so that work in inshy

dividual countries can be adapted to supplement and complement programs

already under way While guidelines and plans of work must be developed

so that the objectives of the project are clearly defined detailed

plans for specific countries or groups of countries must be developed

by consultation wth local cooperators

These plans will be discussed under the following three general

phases of the project

I Engineering and development

2 Agronomic testing and evaluation

3 Economic evaluations

Engineering and Development

Phosphate Rock

Methods have been proposed for relatively simple treatment of

phosphate rock (PR) to increase the availability of the phosphate to make

it more suitable for direct application to the soil These treatments

may be economically feasible in certain areas especially in view of the

current world fertilizer situation Considerable work has been done at

TVA studying means of altering PR and plans are being developed to inishy

tiate further developmental work and field testing of these materials durshy

ing fiscal 1975

- 12 -

Emphasis will be placed upon obtaining samples of phosphate

rock from deposits in developing countries and testing and improving

procedures for increasing their citrate solubility and tzius availabilshy

ity of the phosphorus From this laboratory screening process sevural

sources will be selected from which small amounts (50 to 100 pounds)

will be prepared for greenhouse and field experiments ou various soils

(as described under agronomic section)

From these results one or two locations (or countries) will

be selected for development of a pilot program to utilize local sources

of phosphate rock This program will involve production of the altered

PR and its agronomic evaluation and then educational programs with govshy

ernment and commercial representatives to introduce its use to the farmers

Sulfur-Coated Fertilizers

Some preliminary work has been done in which urea-potash mixshy

tures were coated with sulfur The 7-day release rates for the N and

K20 were 17 and 36 respectively from the coated product (22-0-11-30S

grade) This was the first effort in coating a compound fertilizer

with the new coating system

The widely differing release rates for the nutrients from

the coated compound product raise some interesting prospects for tailshy

oring the nutrient release rate of sulfur-coated products It might

be possible to cogranulate materials of varying water solubility and

sulfur-coat them to produce products with release rates that would apshy

proximate the timing of nutrient requirements of the crop The need

for this type of controlled-release product has been mentioned many

times by agronomists and may be especially applicable in multiple and

intercropping systems

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Table 2

Mttct of 0 Sourco aampW $At On Upt~ks of 0 by Two Varitgtos of Paddy Rice

gr~a 1971

~ MMUampL~ ~L ~ nYLALI~ 11 lemall

I ie

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or 444M7

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- 24 shy

India--The results of four experiments conducted with flooded

transplanted rice in India by the All-India Coordinated Rice Project

Hyderabad are given in table 3 The response to N was excellent the

yield without N being only 41 of those obtained with basal applications

of N as uza With basal applications of SCU the yields were 20 higher

than with basal applications of urea and in the three experiments in

which urea applications were split yields with SCU were 18 higher than

yields with split applications of urea When comparing the average Nshy

response (kamp grainKg N) yields were increased 13 more by SCU than by

basal applications of urea

The data from one experiment with light irrigated rice in India

are given in table 4 yields were relatively low and differences between

N sources or method of application were not significant However yields

with SU tended to be higher than when all urea was applied at planting

but lower than when split applications of urea were applied Again yields

increased more than 13 more with SCU than with basal applications ofwere

ur

In tables 5 and 6 the yields of a short-duration transplanted

rice grown in irrigated light-textured soils at five locations in India

indicate that higher yields were obtained with SCU than with urea when apshy

plied as a basal application Yield increases due to basal N applications

were 502 greater with SCU than with urea However split applications of

resulted in yields equal to those obtained with basal applications ofurea

CU

The yields of direct-seeded upland rice grown at three locations

to India are given in table 7 and the relative yields in table 8 Yields

were low due to drought but good responses were nevertheless obtained for

- 25 -

Table 3

Effect of N Source and Time of Application on Yield of Paddy (Flooded) Rice in India 1972 (Summary of Reported Data from 4 Experiments)

Experimental Number Source Rate Method Yield Relative N-Response

and of of N of Yield Kg Grain

Season Nitrogen kgha Application mtha Kg N

- - - 196 34 -

Urea 120 Basal 573 100 314

11 Urea 120 80 + 40 611 107 345 Rabi SCU 120 Basal 713 124 430

12 - 0 - 202 30 -

Urea 125 Basal 682 100 384

Rabi Urea 125 35 + 20 + 35 + 35 633 95 344 SCU 125 Basal 781 115 463

13- 0 - 168 44

Urea 100 Basal 385 100 217

Kharif Urea 100 30 + 20 + 25 + 25 400 104 232 SCU 100 Basal 462 120 293

14 -

Urea -

125 -

Basal 355 650

55 100

-

236

Rabi SCU 125 Basal 781 120 341

-- 26 -

Table 4

Effect of N Source and Time of Application on Yield of Light Irrigated Rice in India 1972 (Summary of Reported Data From

One Experiment at Pattambi)

Experimental Number Source Rate Method Yield Relative N-Response

and of of N of Yield Kg Grain Season Nitrogen (kgha) Application (mtha) Q) Kg N

38 0 - 204 85 -Rabi Urea 120 Basal 241 100 308

Urea 120 60 + 0 + 30 + 30 267 ill 525 SCU 120 Basal 255 106 425

Table 5

Effect of N Source and Time of Application on Yields of Short-Duration Transplanted lice Variety Grown on Irrigated Light-Textured Soils at 5 Locations in India 1972

(Snmzarized From Reported Data)

Rate Grain Yields (MtHa) Source of N Method of N GrainI of N kgh Application Faizabod Karjat Mandva Pattabi laya Averaje X

- 291 266 211 19 340 260 -

Urea 100 Basal 386 407 361 285 482 3 124 Urea 100 50 + 25 + 25 399 430 434 334 6amp2 4A8 186

SCU 100 Basal 368 468 439 360 572 41 181

Table 6

Effect of I Source end Tlae of ApplIcattoo c RIstave Tle24 of a rt- rat1 T Lsd lice Vasrety Crin o Irrigated L41tshy1 at S Locitite mindi 1972

Rate ____________14_3

Source of X N~tbad of Of X An 1 tat14 1 acr X__T1 4v tatW ttva

- - - all 7i i

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21L1L LW ufU~ vie 114 3 10 106

As 11 i 41 4 smg LAY1 $Of 41)

Tabl I

f~ttwi Ot 0 6wirce 81d At$ a vt1d at flUop4d Rico to Vitjorim (1ITA)All fortitfour to rsodkeet OA lC~OVPr4( 114 5iI 000

W Iotors Ftslanp tospg Irritd for Two thvk Afler flontiw wft rkwa~ Floo4d 191)

- -I-of LWAIM) (IS YJl- fl-----II)

-0 10)

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4of O 149 6MID O 41110

KthD 00

- 38 -

Table 18

Yild of aemati-370 Rice at Punjab Agricultural Research

Institute in Pakistan in 1969-70 Grown Under

Couditions of Intermittent Flooding

Pate of application

=IL

o 0 67 67 100 100 67 67

100 100 67 67 200 100

Average for Sources

Ntha

AS 260 gres 279

320

Source f5

-

AS AS Ura Urea SCU SCU

Yield

Relative

93 100 115

(M)O

Yield

Increase Yield Due to N

(Ktlha) (mtha)

-212 245 033 274 062 260 048 297 085 315 103 325 112

Yield Increase

Relative

72048 067 100 108 161

(2)

- 39 shy

Short-statured high yielding rice varieties grown extenshy

sively in northern Peru require extremely high rates of conventional

N sources to achieve maximum yields The recovery of applied N is

extremely low due to the use of intermittent flooding This water

management system results in heavy N losses even with properly timed

split applications In search of simpler and more effective methods

of N management eight field experiments were conducted in the region

to evaluate sulfur-coated urea (SCU) an experimental slow-release N

source supplied by the Tennessee Valley Authority Rice yields were

increased an average of 59 more by pretransplant-incorporated SCU than

by urea or ammonium sulfate applied in the same manner SCU produced

excessive vegetative growth which resulted in yield reductions at high

N rates

Regardless of an assumed 48-higher unit N cost in SCU the

overall benefits of pretransplant-incorporated applications of SCU

were favorable since there was a decrease of 40 in the optimum rate

of N and the need for precise timing of application was eliminated

Pakistan--In Pakistan basal applications of AS urea and

SCU to rice grown under conditions of intermittent flooding in 1969-70

(table 18) indicate that SCU is a superior source of N as compared to

urea or AS when all N is applied at or before planting The data also

indicate that a yield response was obtained for P applications but a

comparison of N sources at each level of P indicates that no interaction

between N and P was present so that differences between N sources were

relatively the same at each level of P Yields were increased about 60

more when SCU was applied than when urea was applied Yield increases

with AS were only about 72 of the increase obtained with urea these reshy

sults do not agree with the generally-reported superiority of AS as comshy

pared to urea as a source of N for rice

- 40 -

In 1973 experiments were conducted in Pakistan using both

Basmati-370 and IRRI-6 varieties of rice grown under conditions of

When all N was applied at puddlingintermittent flooding (table 19)

or 12 at puddling and 12 at panicle initiation both AS and SCU were

superior to urea with SCU tending to be the most efficient source

However when N was applied 12 at transplanting and 12 at panicle

initiation SCU was the poorest source of N This would indicate that

the release of N from SCU applied at these times is too slow for optimwn

plant growth

In another experiment in Pakistan in 1973 no differences

in the effectiveness of urea AS or SCU were noted in the yields of

continuously-flooded rice (table 20) Again these results are conshy

sistent with earlier results which indicate no superiority for SCU

when rice is continuously flooded

Nitrogen Studies--Maize

A series of three experiments were conducted by IITA in

armo-Nigeria in 1972-73 comparing AS urea SCU and

CAN (calcium

nium nitrate) as sources of N for maize (table 21) A significant

yield response was obtained for N at each location but no conaistent

differences were noted amaong sources These results are consistent

with results at other locations which have not shown that SCU is a

superior source of N for maize grown over a period of 3 to 4 months

Nitrogen--Wheat

The yields of wheat in Pakistan in 1969-70 (tables 22 and

23) show that yields with SCU) tended to be lower than those with ureaJ

although at one locction where sorghum was grown followilng wheat with

Table 19

Yields of Basmati-370 and IRRI-6 Rice at Punjab Agricultural Experiment Station in Pakistan in 1973 Under

Conditions of Intermittent Flooding

Rate Yield Source of N Time of Yield (Mtha) Increase of N B-370 IRRI-6 Application Basmati-370 IRRI-6 Average (Mtha)

0 0 - 21 353 287 -

SCU 90 150 At Puddling 325 545 435 148

Urea 90 150 At Puddling 309 500 405 118

AS 90 150 At Puddling 324 529 427 140

SCU 90 150 Puddling 372 572 472 185 Panicle Initiation

Urea 90 150 Puddling 335 502 419 132 Panicle Initiation

AS 90 150 Puddling 353 529 441 154 Panicle Initiation

SCU 90 150 After Transplanting 312 562 437 150 Panicle Initiation

Urea 90 150 After Transplanting 340 624 482 195 Panicle Initiation

AS 90 150 After Transplanting 349 583 466 179 Panicle Initiation

All plots received 45 lbs P205acre as single superphosphate

Relative Yield Increase ()

Source of N At Puddling Puddling Panicle Transplant h Panicle

Urea 100 100 100 AS 119 117 92 SCU 125 140 77

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-48

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obosomhu rocks 0entk catetas rth Unrtdo costrat frwt) to

ht tse balt s Owosiv as that to TwP it rocks WM bo

fmtbt alteruutiv to MSso gotastte to~ Ik lee used to

ThUAIAd

Tht wMl dt gotmtmlaoti wout th possibility

of law Vhld free ww e1 e66001 4 It cooUt be YgWd Sutt

a4 10 0410 SWUSSM yt$4e TOP wUd predWr A r~ftIf fl~W t

1f f ot P the wuld phosphae rck TWOe viWMW efocitill b

true to low rttos t tsplusatiI P wi 9 Ma Liiam $S

amp4at r per Wforssota Mav two 64eed Wilk elikor It 44 of

P go Mi er 4A bg oftoP aon of tewmrowtni pboophals fwAh

It vwld be polotrd A Wevero wtht Is the jteld level that

W414 gk tko videm dtterem~j o(A 1 the 4~etamp tk~e~t

P11~0 pra~lpj prefer gre4r tuftlter for whlae

of hoaw ppltrstie Mhe to a dloedveaP for The PINSOO rocka

vkth m r II spotted 10 ftewil 4106Me tem

Nub studios we ovsosd o IVA vol gramleid a

forgof wee aMW pbsepbots A fths pemhawe evsielew us

Odellod to detMlee it otteettvmm of 11agotated Stoture of

mmfp MW phapa A (CI) sed graewletod pampAtlti arlolatod Pa

asowcs of P tof ttde ro The wreem proucts omre raGther

pemour~a ot P syag besmti andMi as elt ov so gpamwhr

iuipiqffhate(TS) low twseeo Is eftwiltve Is thet

W41 preeme wae oialain ire post-rItoi effriq to Stanlato the

pud6itt of Irto paddle Wee ofsdlseireplastiq

0 49 shy

lbs partially scldiaatede grawilated Ml prodlucts Vere isshy

toiwdiats in 5tftOvttWS54 betwee wroiPi ad TVP NotV5Ymf to

me coo were they mere twoe $a a etfective ao TIP 00 sipifleast

LVSUMI5 at0 efecto wore toun tor thee produteo Timely dtIampWde

FR (-t00 mmoh) Uia amp~rally oar affective than Owe gra8448r FOampprodt

featal twos o 6 aotetire s I

Nowvero it to felt that sfortber field euprtet vth

hese interials Amd ether typs of grometatodl Wter nre wrrautad

hater ceeuwodh that they have me areec poteatlal toi additoG

e tate wAne the sectte as OtawrI sed bovoloen turther

euperimeste vth few reck pboophar s0d with reck pbophat treated

to sehesa citrata selmtliy or to ha csaducted

Metbir sertes of tbme enprtaeats wae c~edtmcted by IITA

to Ut~rta copal TVP AOP APP aed it at see tecastisix (table 14)

No dot lalt sewseltles teh draw tree thee results simouely em pear to tlvdl bsww they do stwgpt tbat forthew work with

MR to werramid so tbme sels

Table 24

LttcttF Swce MaPlate 06 ieldot IM AWaia CoelsANS at IITA (Ugboda ad Apoin ail sorit) aid at Ike (AUaba s5i series)

1973

Plate ot IP Apinu 5 poundebods A1ab

Ocrol 0 Z94 419 M)

Tr ipl ruprphite 20 349 3799378

Triple vepput 40 M09 410$

Triple 6wp~~b1 4271 4344 42250

Ammotw-ritpophW to 4201 4124 4040

Amosim-rdop~phlt 40 4270 4106 4231

AM tuo-polpephats 20 404 4244 3794

~eai~mpelppepbuI 400)49 4094

Cee m-pbpbt to- 59

momee eph lto 0 4192

LSO (0 0$) 29 1025

Th WPII

- 51 shy

101Y114 tpeM-fI PEP~tbRP YO

1 ~ ~ gmw 1pc~biofl- 9 Kla4v4h

Upia U04 Copfind am Crehout Stet Rpano at (Ia4

rico t IF t rume6 orth~ Caralto phoophale rocl QAR) vaUN pqU41 to

roopon from cmonetrat4 gsporphophai (CIP) who ort$o4 oil k

was 45j itwas tafertor vb protioo4 oil p war OS Ib 4iffer~c

in rtc reepos to X cod14 oo bo ttrit4 4 4 hvsciag of boil p

~ Pt o r11221 0 tP

c theto the rhimecyllndor of rico tots par to)14M4i1 roeoi~t

ed oil emd PA prior to tho ont of an~robi4 cMioe AA~ oIifoshy

nAte bYpot t taet~d tO fC4sin t~r 4PWden0 Of f Ot(tivshy

ofOWailiJtyno o prefla4 all Put that 4t01etoo 14 tvsIk

of the Ott to prvvld a 014for C4m0 44 mI 1 o4sf

EfftC ftPet141on AIAM-0 V f401td 4 4iv 440 Mtft

Aa torfat VampP f4MWfCi4W04wt0amp to 4eturWlI Ot(Wel~drIC ft

Ot f tM6 the flooded Ott 00 14 04019I Pft0uAw Of gAr~s~lr

pkS$t M40b MP) Tw P1101 Piset Prodwie W-e 10M0di Wr04

(10-1) emW 0aretilp ddw01at4 P WAA firom Rrth M~flRU414~$

wee cowiared with fie Md reWim 44104 proo~fo) foruk oith laWItter

I v te-PR P OW1004 4 4 O Wf ottil OW ellt Oo

Oveiel1 the 40tt dmcruie to effetotww Wtollowui Co fme

PR tpaUIB1I ldoltmo PR (pamwlatr) offr~- ArmeuM) 0 orwi

- 52 -

Effect of N Sourc6 and Water Management on Response of Rice

toe Zn- M Giordano J J Mortvedt OP Engelstad and Greenhouse

Staff Several rotes of CO(14H2)2 and (H )2So4 vith or without ZnO

wore applied to flooded and nonflooded Crowley oil (limed to pH 75)

to determine response of Bluebelle rice to Zn Yields with both N

sources veotrgreator on flooded then on nonflooded soil In the abshy

ence of applied Zn total dry matter production vith CO(NH2)2 was

slightly lower than with (NH)2S04 on flooded soil and considerably

lover on nonflooded soil Concentration of Zn wan higher in straw and

grain of plants roun on flooded than on nonflooded soil Although

concentration of P was unaffected by N source or Zn rate there was

som indication that cranslocation of P from straw to grain may be

depressed in nouflooded rice Concentration of N was lower in straw

grown on flooded than on nonflooded soil due to apparent dilution

thereas both X sources resulted in similar N concentrations in straw

at all rates of N application the N concentration in grain increased

with 0 rAse

feSpongi gf(SM to Chjorospodiostte and Related P Sources--

Si Allen and Greonhoue Staff A greenhouse pot experiment was

couct44d with corn Brown on Hountview silt loam to compare the ofshy

fectlivees of chlorospodiosito (Chlor-l) with concentrated supershy

phosphate (CP) Thomas slag and North Carolina phosphate rock (NC-PR)

Oil-prillad urea-phophato rock (UPI) FeA1JMP 20 7 and monomthyl

phosphate were included in the experiment Based on yield of forage and

uptake of P by tvo crops each of 6-weeks duration the following conshy

stui were dravat

I Chlor-1 was slightly loss effective than CSI Thomas slaS or NC-PR

from which Chlor-l wae prepared

- 53 shy

2 Granular UPR was a poor source of P its effectiveness was greatly

increased by reducing the particle size to -35mesh

3 FeAlNH4P207 was unavailable to the crop

4 Monomethyl phosphate was equivalent toor slightly more effective-

than CSP

Research Indirectly Related to TVA-AID Project

Response of Several Rice Varieties to Zn in Moist or Flooded

Soil--P M Giordano J J Mortvedt and Greenhouse Several varieties

of rice from Mexico and the Dominican Republic currently under investishy

gation in Puerto Rico for adaptation to upland culture were compared with

some established United States varieties with regard to Zn response on

moist and flooded Crowley sil (pH 75) Chontalpa (Mexico) Bluebelle

(Texas) and Starbonnet (Arkansas) were most responsive to applied Zn

Juma (Dominican Republic) intermediate and Sinaloa (Mexico) and Calrose

(California) were the least responsive The Sinaloa varieties (Mexico)

appeared to be best adapted to non-flooded conditions whereas Chontalpa

and Calrose were poorest Concentrations of Zn generally were higher in

plants grown on flooded than moist soil

Pattern of Growth and Zinc Accumulation by Rice--P M Giordano

J J Mortvedt and Greenhouse Staff Rice plants were harvested at weekly

intervals from shortly after emergence through maturity The objective

was to determine the rate of growth and Zn uptake by a Zn responsive varshy

iety (Bluebelle) and a less Zn-responsive variety (Calrose) in the presence

or absence of Zn applied to Crowley sil (pHl 75) Dry matter production

of Calrose was linear with time of growth and of a similar magnitude until

heading with or without applied Zn Bluebelle followed a similar pattern

where Zn was applied However in the absence of applied Zn foliage yield

was reduced markedly

-54

Uptake of Zn was similar for both varieties whenZn was

applied Dry matter production and Zn uptake by the two varieties

also were comparable when Zn was applied However yield of Calrose

was much higher than that of Bluebelle in the absence of applied Zn

while Zn uptake was only slightly higher This suggests that the lesshy

ser responsiveness of Calrose to Zn may be due to more efficient utilishy

zation of Zn There was no indication of a greater demand for Zn durshy

ing reproduction in either variety as was suggested in earlier greenshy

house experiments

Response of Upland Rice to P and Zn--P M Giordano J J

Mortvedt and Greenhouse Staff Several rates of P and Zn were applied

to Crowley sil (limed to pH 75) in factorial combination to determine

whether differences in rice growth under flooded and nonflooded soil

conditions are related to plant nutrition Although straw yields were

slightly higher in nonflooded rice receiving adequate P and Zn grain

yields were higher in the flooded crop increased rates of F andor Zn

did not result in equal yields Except in the highest Zn rate (75 mg)

concentrations of Zn in both straw and grain were higher with flooding

Concentration of P increased with rate of applied P and was higher in

the grain or flooded than upland rice at a comparable P rate In conshy

trast concentrations of N were lower with flooding due in part to dilshy

ution from increased growth

Rice Response to N and P in Flooded and Unflooded Cultures--

G L Terman S E Allen and Greenhouse-Analytical Staff Rates of

N from 250 to 2000 ntpot and P from 0 to 1000 mtpot were applied for

Nato rice grown on Mountview sil and Sango sicl (625 kg of soil per

pot) Market yield response to N and P was obtained Yields of straw

- 55 shy

total yields N uptake and N recovery were higher on unflooded than

on flooded soil cultures Grain yields however were slightly higher

with flooding These results indicate that with adequate applied

nutrients especially of N rice yields without flooding can approach

or even equal those under flooding

Uptake of N P Ca Mg and Zn increased with yield response

to N and P while K uptake decreased on the Mountview soil Concentrations

of N and P increased with applied N and P respectively while concentrations

of other nutrients were diluted in most situations with yield response to N

or P

Results from this experiment show that amouats of N applied in

previous pot experiments for rice have been much too low especially if the

crop was grown to maturity

Response of Corn to S and N i UUASand Urea-S--S E Allen

and Greenhouse Staff Three greenhouse pot experiments were conducted to

measure response to S and N in ulfur coated urea (SCU) urea amonium

sulfate (UAS) and urea -S as well as estimate N losses from surface apshy

plied N sources

In Experiment 260 less than 20 of the S mixed with the soil

was recovered from SCU or urea-S granules by two crops of corn as comshy

pared to 45 or 80 from flowers of S or Na2SO 4 CLop response followed

a similar pattern

In Experiment 260-A N sources were surface applied and alshy

lowed to dry for two weeks before incorporation Into the soil and plantshy

ing Recovery of N by two crops of corn was 77-82 for AN an compared

to 37-70 for urea UAS urea-S and ICU Thus n this experiment loss

of N from urea did not appear to be re~dcud by light S-coatlngn or by Inshy

corporating S or AS in the granules

-S -

I xbprZnSlt a Wtch aU Meyto 0-Ai Wt f9r

higher reermo teOrtOrs cOM reSpWNO i r0100 Of N w

not oaisteontly related to sewe ot N In edl tust 0 ioltiUe Lim

lo in VMuwpped evlmtUTS 48 merind by seirest nte appresOehe

501 for uroa as cwarod to 210 for urea peepha

Rus- or Upse to LoAmIl34I a AriMed bI Earl U

MW NOWlsIIsIr-4 L Toman 5 1 Alln and eesese StNf rio

row on Sawg did (0 tpot) We 1l0l0 Ws feritiud vith 05is

of Npot mixod with the 6011 as aureCA NiAO) 1 Age god At Ures

was also itcluded at rtt t 05 10 end 15 of Upee Theas trealshy

onto were followed 4 wpdrsetago of U s AN wre 4C 10o or at I3n

Weeks toulin up to IS pot

A soil application of 10 pot rosulvod to the maim yield

at 4 weeks Tio4 sad percont prottis t intre raite tncreased rftishy

linearly with U applictalien IeseeItally all at the m iNd wit

the moil w domitrifted after flooding Grail end straw Ilelds vere

highly correlatod with tiliriag and vlh ubers of gralm arl

The results Widicat that 0$ to 10 a of Upot as orea or

NN bsuld be sied with the oil to stilate tiilrir with adshy

ditional 0 topireased later to increase grain lIds mad protia cmshy

tout

DIVISION 54- FERTILIZER TECHNOLOGY AND USE

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~ ~ I $4U tml

Tile 4-00dw x uiampOW74u 0qee of

_____k _ _ shy

~ - 56I 5

-f

irenY w -a

Tiles I sed I thm Au do sel oeppled upaoIks WIM0 0da ispI amd us Ou s 106 kg

h Eaap 8n 14 sMsa of abw~greuad PU Pau WW 1 u itb IUKho 0aaphelem s 60 Otarlmmh At ~ 0sU Ishiseoo Cook oiA N uiplasu mAasslaly abess A leel

v doese a WKWye Is ks Nha m 6 sa4to dafo aONmuw The appee swm Wsssof adde N4 alalaed by vuMb ifaa W C Was sekilumganSro Is

bs eabI wish as aVWWa uwewy nap (f5s)f ad Mashes reaMeY valaes of 48 0 S414 CWm

owdb imto US Wh s vs sf 3I mld 54S fro 2 aMd 3) A A

valves a hevwae u Iar Walh basl oswas dhe uwpatr bshava of

tb~msusasl appkausu of ofta sede s have aoweN

TOW opl taoe for AieweeW 4OsmWMbas Op peas As Tabl 4 sling sob Os awowully eom grams Piel level Thes oeulam Ma sed as IM

-02

792 60L WI W A)49R Pio VOL 37 197)

primS o r OeampAd WU toa Them fl~ w At NOSSe earno maisslea Ia N he mOWamplIO yik ampWd IMe aampWmW OWa Owe wa UMs of KU to 41 Oke ampWiiIamm be dkrnety ewspokawleM(a s8 te camtd wie a eapmoe by TVA pavw ltoi NA poundrmdaka4us vrimeW460 o to ilkidm ofWW (Mtemas MuOwe 1973) TVA mwi bawld on soi ficedims IampWp seg rudwiv s~s0abet ke WNmdoe ON 01 K Is12 NOSW ie fssewnmu Ie I QvaaIi rowp IMA) f9

)amp m lodk byO voebmsaIS8OpeaWfrats 11 OWNmi a I a W idisod 0 81 Now 111 nindat Wm fysmpseaamp (If tsO tUmtI IsM $P shoroV4mmo knflkvnf (foOdme nuw ae Ow OImstwe in SM pnmm8 af tXm 10 114PIS kequoian wo Mpfii

SC~po umd spop~o VWt alm 4emWal 1 4ink PCmirsra M 1 ad AI 14bmms

1MM Ww Even to doe shw wisht b-o -Wamp Ekb fed rbaimpal of14~ Am Smpound oS mv fAaMda

MGMe -M4 Wg kmuwadM 1Wr wih SCV4 Psmuck Wff It dlL Wm 1W led 0 1 oo teeA of aiwaisme aweeoid h

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-d

Is re4aled uIwq~e~w Aueee atofurnw di Capsnm ptopeatls is a oommm eiws to 100 tom of 04404man d CtdUW 4M Anw K~a do Aamp apowee WPUaN powu eel H pae iaaa thAi SCUI isWW owr hmem ISsuppl N to the li ieee F A IM1 Nampa Obo~amie m

41MB ~ ~ m ~ ~0 0-- 0 140 The ffsemn of food Nn else9~e(Ud~ ~ ~ ~~ WooksaS eAWw pjed of ho~raw of IU effadam vfdva oft xhj0I 13iAl

DIVISION 8-9-SOIL MINERALOGY

Amorphomw CeetIup en XmWra Ssrfmls

L C koits Am~ 0 tmmkaAf

ommp A faieiaAMTRACT skiwe lo nW ampM sm wi4h

Walo by a onMm I dmivid hseidm6Wlk W~edesie s

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Pa~~~eakr4awiS SeUeeiNaiA WOW 14e

PWWWW t HW f hea~I~~~~~a 0th

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os 0aMW ofmu WA l aduWs~Ib rowuvvl3maIpm s

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d m M 0bmSaImu M-1 ofM6 h Intun to 7I

aiba maush WAesshwn~u9dSg a osusLwpI ~ v m

M PolsdAvoWdw Ons pugm~ low iwLW m We

of~U -a~ mo uNo

0401ts of 40

A e mun5d m i vvamp sa s ow bftIS i sa omdIs a w

edi1 hswopmo an ag am Iw anom erlwaPASneooie bnwoM po

o ~ do=lr 3s fluACWoSM Owaa VolM Ain b 400b adW g o as amob ofrMOWS A oo eWmaa ow $wofdi60 ow - ema

-v K Vcon l ap ad md ld KU lbs PoabumwA od w to domi a bembe 0b lt $014 i ampmomONo

4st diwemmSod i 6o pa P)ameakiksm4 m 04M t 1iV vs 0606 o IS ft dopsss of q madl w I10000014 t 44hs

arbs awasm 00 iztv Am-~~~i u5~ms ashu is byw

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- omlos r umIWO1in pw

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of of~phaow tw bmsdf toamplboe

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ov4mnk wsi 9 Mxfeu~i am emwm ismi0wmd fq W No ~~ - f mug Aitowe eutlkowbmTV is

amppowftdmi TiM 0 Tie OAA mo p)a Mwomoi dOn4m A)w

MW 0 604 0M mm yaM 01MWOfdi to tA0 M OOAW uinw OSOb

ap is~e I the ampo A A Mwof ~Do toit op aenu w~ifiOimem~ MAN ampW)

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owud6moeft 4 Obind PINa~e

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~ -0

65

0IL CL OC AMXR PROC VOL 38 1974

)aT1 S4I104 ow Lusanll Tawng isa tall Thai variety known for beingIwo nonshyi s s ) sensitive to photoperiod A split-plot design was used in

S e e these euperimeots with 4 rates of P (I1 22 44 and 88t i V IV k of Pha) applied a main plot treatments and with the OF It sourMes of P as subplot treatments There were two checkS plots in each rmplicate The extra check plot was included to permit the application of fresh TSP standard Jor the

It- ti 06 + i bull fa succeeding crop the p-4me of bi was to permit accurate d awrnwal of the mdual effectiveness of the phosphate

ftinSUbI rock The P fertilioers were broadcast on the mud andthen Worporald In the soil during the last harrowing At

whM N both On ACS indx ampM time of transplanting Immediately before the last harrow61t (4j 5 4 01 P s 3Mm o Vallonal in con n 100 kgha of N as ammonium sulfate and 33 kghaWO Of Spews ampm lIW thaabe rocks do ACS indes of K as polium chloride were applied A total of 40 wa in prepw O do ctih k otent kha of N a ammoniunt sulfate was applied later in twoir P The hew oNed amp wM W for 5 of gw topdrossingp with about 5cm depth of water on the plotsvV I aiOMveffeOctveee Three to six ldayold selings pr hillwW the ACS idex were planted00OWW wia Oft fo an c irNk I p Coen 20 by 20 cm part in straight rows Hand weeding was used

and insecticide were applied for Insect control Grain yieldw was masared by sampling 5 ml of each plot excluding border rows The date of heading in each treatment and theUNiN d pbM W Weks rin tOW USA UMe In Tale yed componnts at hafvel were also recorded

I filM rsperMS esOM kdwdua 1 t ab The average yields of ough (unhulled) rice for botha 84 OW O 8uo 4 Thala TM was a locations are ploutel in PIS 3 for the first crop (1969 wet

owou thRM seaso0) The Veamps yield response was obtained at Klonge (s) W lDtO t Of dMa of1tw W d l R Luang however a 4ute satisfactory yield response was

~Mk ^d TVA UJSD ad Kd UnIveS obtalned to applied P at Bangkhen as wellXUe LaM e R qwrw Ims The sod was do Relative aponomlAe effectiveness values were calculated

VOW (a ksA w edmwL t Poesesm h Vy for these data and am presented In Table 3 The valuesdAY buo if dIe ouh ne Pee wtk a Mlak vow 1009 for th first crop are plotled against ACS index in Fig 41 This Im M i6ti l 4bNd IO a0 O mkarnk for both locatio r relationship was linear for the

11400 ThCpH 0( lb pW IW 01 th UpeiaW so Sanodion location and curtiltnear for KIng Luang The was u i 4A sksamp lMaor nrusio model amparounted for 81 of theAmO$MI Aw jAAsue Swim T1 Snh Wd variation In the AE valu for Bantkhen a square root

Mems a Iw iv fern alh$ sedm haowg dayNW W t he plAL At tdo M tM aso W s as ctminued throufh eltaM t Ofpof -le lse wo am P OeNI VeOpls 1o ealluae tI lon4erm MIdual Offccls

A on W isset i a wse to hsh eapeel of these ooihss t ocks The baagkhon experimnent was letmiaI1DlVemisthis is a w hulu Lo g Tasug ia iasael aft - Msd residual Ves will be pr-Om crok TheseTwod esewm

SWWo

A

lP~U~7 ISIIPe1iuIWN e bsedisssin ian ghth siaoelalbe

984 0 6 O O - M s -s fWPas 11eSft W d Uo al a o

o

S4l~ lIIII I~l I 1f fl

( +

+ + + m + ++++-

++ +(++ + ++++ + ++ ++

- 66 -

ENOIMLSTAD ET AL RESPONSE BY FLOODED RICE TO PHOSPHATE ROCKS VARYING IN CITRATE SOLUBILITY

I I I I j0 I I

BANOKHEN BANGKHEN

pH 56 6 - 0o

TSP

NC

5~ ~ ~ L o 4 - -shy

4 ] - --------shy04

6S

|0 III 2 44 8r 66

I I I

a 1KLONG LUANG

pH 46 z KLONG LUANG

TSP Sc2 NCFL(N)

5 FLIC) J0 TU

oshy

4 ~40shy

3 bull eM0

I - I I I I I

0 II 22 44 88 0 5 10 15 20 IP APPLIED KO HA ABSOLUTE CITRAE SOLUBIITY INDEX

Fig 3-Yield of rough rice at Klong Luang and Bangkhen Rice Fig 4-Relative agronon effectiveness () of P sources ploz-Experiment Stations Thalmand as affected by rate and Source ted against citrate solubity Index for both Thailand field ex

of P applied (crop 1) periment (first crop only)

regression model accounted for 97 of the variation in sumably resulted from crop uptake and reaction with the RAE values at the Klong Luang location soil to form less soluble products Such effects may have

These experiments were continued during the dry season been more important at the lower rates since the two TSP of early 1970 to ascertain the residual effectiveness of the curyes converged at the highest rate of application various sources applied to the first crop No new P was These data from KIong Luang indicate that (i) residual applied except for the fresh TSP standard mentioned effects of all rocks except Mlcwuri were substantial (ii) above rhe experiment otherwise was conducted in a man the relationship between relative agronornic effectiveness ner similar to that followed in the first crop of the phosphate rocks and citrate solubility levels was

The response to both freshly applied ad residual P was largely obscured and (iii) the general superiority of TSP marked at the Klong Luang location and marginal at over phosphate rock in terms of effectiveiss persisted Bangkhen In fact at the latter location the response was through the second crop so small that little can be said regarding residual effectiveshyness The yield data from crop 2 at the Klong Luang DISCUSSION experiment are plotted in Fig 5 Greenhouse and field data presented in this paper show

Relative agronomic effectiveness values (Table 3) were clearly that there are substantial differences among phosshycalculated for the Klong Luang data using both the residual and freshly applied TSP as standards It is of Interest to note that the superiority of TSP over the phosphbte rocks Table 3-Relative agronomic effective values for field experishyments in Thailand persisted through the second crop The main difference in KlowlZmlnql~the residual effects is that with the exception of the MIs- s Crop 1 Crop 21 Crop 1-shysouri rock Ihe marked relationship between citratr-soluble WoiCarolina yl 59 76

phosphate rocks and RAE had largely rds norh) a 64P conltct of th Florida (eqlral is 6969 6

disapipeared In this acidic soil (pHi 46) P would by this I14o 69 63 40 ToonesS 31 65

limo be supplied by Intermediate reaction products In addl Missou 0 o lion to residues of the initial spatlte Ts P o 2 o 0

The TSP applied to the first crop declliv-d slightly In campIafcmWataesr e id ofeuhuloefor 22MA rates of PtColeouattd as aba u tlte td18 kS ratesp dlverage yield tM868 to 22 44

effectiveness relative to the freshly applied ISP This pre- of d s4

A

4

- 67 shy

-SOIL SCL SOC AMER I

KLONG LUANG CROP 2

Si 3

eN

TAPPLIEDKGHA

Fig 5-The residual effectiveness ovarious P sources for crop s compared with freshly applied TSP Klong Luang Rice

Experiment Station Thailand

phate rocks in terms of agronomic effectiveness for flooded

rice Further these differences can be predicted by means of citrate solubility or by the ACS index It appears that

the latter is more appropriate where the content of apatite varies among phospiate rocks The most soluble phosphate rocks approached but did not actually equal TSP in limit-iuig (maximum) yield in these experiments regardless of rate applied This agrees with the results of Ensminger Pearson and Armiger (4) One needs to consider the defi-nite posribility of same yield loss in zhoosing a phosphate

rock over TSP such yield losses must be weighed against the lower price of phosphate rock The explanation for such iosses may involve concentration of soluble P in the soil Khasawneh and Copeland (6) suggest that the growth rate of crop plants is a function of P concentration that can be maintained in the soil solution If P concentration is limiting or inadequate becawe of a lower dissolution rate of phosphate rock the growth iate ard uiiimate yield will be diminished accordingly

The RAE values bascd on yield increases reflect the agronomi effectiveness of these various sources relacve

to the TSP standard however these nould be supple-

mented by an economic analysis before rational choice can

be made The following calculations will provide an estimate of

the rclativ ecooomic effectiveness(REE)

Y t Ps aXpatREE -- 100

vahtercks t sphate or e b i- eor

Price of TSPkg fo

be Price of PRkg P

PROC VOL 38 1974 leO

90r

Wsoshy

0

60-LUSEPHOSPHATE ROCK

00 10 20

PTP PR

Fig 6-Relationship between relaZive effectiveness values (RAE) and the price ratios between TSP and phosphate rock Such a figure can be used in making a choice between these

sources

If REE exceeds 100 in this calculation the phosphate rock would be preferable to TSP

The REE calcuktaaa wre used in preparing an indifshyference curve (Fig 6) wherein RAE values are plotted

against PTsPPpR ratios The cu~rve itself connects those points at which REE equals 100 When exactly on the curve it makes no real economic difference what source is chosen After choosing a suitable price ratio one can then project upward from that ratio knowing the RAI

value (or estimating it from such data as shown in Fig 4 using citrate-soluble P content) one can then choose the source on the basis of both agronomic and economic conshysiderations For example if the price ratio is 25 and the RAE value of the phosphaite rock is greater than 40 the rock phosphate in question would be used However if the RAE value was less than 40 TSP would be a better choice There are indications that if the P in the more soluble phosphate ro~cks (North Carolina north Florida central Forida) is less than half as expensivz as that in TSP these rocks would be feasible altereaives to TSP on soils similar

to thoseused in Thailand This analysis does not take into account the possibility

of lower yields from use of phosphate rock In addition only a portion of the various yield response curves was used in this anlysis ie up to 22 kgha Beyond this

rate yield response was much less pronounced it could be argued that at less than maximum yields TSP would produce a certain yield at lower rates of P than would phosshy

pow ofrock This would especially be true for rates applioa example at Klong Luang 5500 kg of

rice pcr iectare could have been produced with either Ii kg of P as TSP or 44 kg of P as son of the more reacshy

tire phosphate rocks It should be pointed ot however

- 68 shy

(IIKIS amp YOUN( ARIFICIAL WEATIIERING OF OXIDIZED p[ll- IV

that this is the yield level that would show the widest difference such is the advantage of hindsight

Farmers generally prefer granular fertilizers for machine

or hand application This is a disadvantage for the phos-phate rocks which are normally arplied in finely divided form Recently experimental quantities of granular urea-

phosphate rock mixtures have been made by TVA Results of trials with these fertilizers will be reported elsewhere

LITERATURE CITED

1 Armiger W H and Maurice- Fried 1957 The plantavailability of various sources of phosphate rock Soil Sci Soc Amer Proc 21183-188

2 Bengston G W E C Sample and S E Allen 1974 Re-sponso of slash pine seedlings to P sGurces of varying ci-trato solubility Plant Soil (In press)

3 Caro JIt and W Hill 1956 Chard eristics and fer tilizcr value of phosphate rock from different fields J Agr Food Chem 4684-687

4 Ensminger I E R W Peirson and W II Atmiger1967 Effectivencs of rock phosphate as a source of phosshyphurus for plants US Dep Agr ARS Bull 4112S

5 Engelstad 0 P J G Getsinger anid I J Stangel 1972 Tailoring of fertiliers for rice cnnece Valley Author ftyNational Fertilicr Developmnent Center Hull Y-52

6 Khasawnch F E and Jane P Copcland 1971 (otton root growth and uptake of nutrievos relation oif phosph

rus uptake to quantity intensity and buffering capacit) Soil Sci Soc Amer Proc 37250-254

7 Lehr JR and G H McClellan 1972 A revised lIbora tory reactivity scale for evaljativg phosphate rocks for direct application Tennessee Valley Authcrity National Fertilizer Development Center lull Y-43

H Terman G L S EAllen and 0 P Engelstad 1970 Response by paddy cice to ratcs and suurces of appliedphosphorus Agron J63390-394

DIVISION S-9-SOIL MINERALOGY

Artificial Weathering of Oxidized Biotite IV The Inhibitory Effect of Potassium on Dissolution llate

R JGILKES AND R C YOUNG2

ABSTRACT

Rates of dissolution of oxidized biotites in OIM 001M ICI are severely depressed in the presence of IM KCI The amovnts of Al Mg Mn dissolved in the first eytraction are similir to those found without KCI however subsequent extractions remove these elements at 10-20 of the corresponding lICI rates This effect may be due to a decreased rate of vermiculite formation thereby reducing the effective basal area exposed to attack A decrease in dissolution rate with increasing ferric iron content was still apparent in the presence of IM KCI

Additional Index Words X-ray diffraction infrared aborp-

N EARLIER papers of this series the tole of biotite in soils

as a source of both macro and micronutrient elements

has been discussed ((Gilkes Young and Quirk 1972 1973ab) Experiments in artificial weathering uiing as va-

riety of extractants were undertaken to determiie the inlu-

ence of oxidation of octahedrally coordinated iron on the bull release of structural cations to solution The results of this

work demonstated that biotite behaves anomalously with respect to the other common ferromagnesian minerals found in soils Oxidation leads to the development of a high degree of resistance to cation exchange and dissolution Several authors have coiwludcd that decreased rates of K

Contribution from the Dep of Soi Science and Plant Nutri-tion Institute of Agriculture Univ of Western Australia Ned-lands 6009 Western Australia Received 29 Sept 1973 Ap-proved 8 Jan 1974

2 Senior Lecturer in Soil Science and Research Officer respeclively

replacement in electrolytes shown by oxidized biotites are

a result of the inclination of structural hydroxyl adjacent to newly created trivalent iron or vacant octahedral cation sites (Robert and Pedro 1959 Barshad and Kishk 1968) Gilkes et al (1973b) suggested that decreased rates of disshysolution of oxidized biotite in 0001 0t)l 0Af CI may also be due to the presence of inclined hydroxyl In this case a smaller surface area external and exposed intershylayer may be available for attack if K replacement by hyshydrogen ions occurs at a slower rate in oxidized biotites

Gastuche (1963) has shown that significant dissolution ofthe (IIM) biotile face may occur and it is easily demonshystrated that the proportion of exposed (001M) face in weathering biotites depends on the percentage K replaced

Rausell-Colom ct al (1965) have shown that hydrogen ions act in an identical fashion to metal cations in K exshy

change from micas In particular exchange c-f K by hydroshy

gen ions will be terminated or greatly reduced by high levels of K in solution Thus if dissolution of oxidized biotite by

acids is carried out at sufficiently high K levels to prevent vermiculization any differences in dissolution rate that may occur cannot simply be ascribed to differences in rates of K replacement The following results were obtained from such an experiment which unlike the experiment described in Parts I and II (Gilkes et al 1973ab) does not attempt to simulate natuiral - conditions

MATERIAILS AN) M HIiODS Further subsamples of the less than 0 hiotites used in K

excherandbaid disoo tu es (G iles e9n K exchange and acid dissolution studies (Gilkes et al1973ab) were used in these experiments Preparation of sequentiallyoxidized biotites without intermediate vermiculite formation is

Page 10: I70 - United States Agency for International Developmentto ascertan, but tgl.eetad, 1, L,. ("Tailoring of Pertiltiters for ice,'" TVA ulletin Y-52) states that the staft of IOi has

-7shy

screening will be done using soils of the area where the fertilizer

will be used Materials showing potential in greenhouse tests will

be further evaluated in actual field programs in selected countries

If successful at this stage economic and engineering data will be

compiled to assess the potential for commercial production In orshy

der to evaluate the product and process the total system will be

studied including storage handling and transportation from the

point of production to the farm Information developed throughout

this work will be available to industry foreign and domestic so

that it can develop a production marketing and use base for utishy

lizing the product This level of technology is rapidly being achieved

for SCU which received major emphasis in the previous study additional

agronomic economic and engineering data both with rice and with other

crops will be obtained to complement the previous findings

This project must be broad and combine a variety of professhy

sional disciplines but it is necessary to retain the flexibility to

move forward in specific directions as Improvements in products occur

This is necessary to insure that improved products identified in this

project can ultimately be made available to farmers zegrdless of their

economic and social status and that sufficient data aro available so

that induetry can make soomd decisions regarding the foasibility for omshy

marcial production

Major objectives of this project are eommartted as tollovws

(1) Developing Iertilaers to wt the nutrient neD of oocitic

4I l VhICh are not set iconmically withtfopical Crops and

etoshytoov~tmtl| Nrtiliieoro or that can set thse ne- s fre

006eItCOMlY ky 4ir lfte the W91~1ici of teftlliaer ultil4tin

-8

(2) Proving the value of these improved materials to insure that

they will increase farmers income over a large enough area

to attract and Justify commercial production

(3) Developing the production technology for new fertilizers as

a basis for encouraging and advising potential commercial proshy

duction The integrated process designs will seek product

quality and economy while striving to minimize harmful emisshy

sions to air water and land

(4) Working through cooperating organizations and with leaders in

research extension and industry to develop and demonstrate

methods for introducing new fertilizers to farmers so that they

will be properly used when they become commercially available

-9-

SCOPE OF WORK

This project integrates agronomic economic and engineering

expertise into a single team in order to develop improved fertilizers

for a wide range of crops and soils in developing countries Considershy

able emphasis is given during the first eighteen months to collecting

the data needed to complete the evaluation of sulfur-coated urea and

ground rock phosphate for lowland rice Both materials then are

scheduled for demonstrations during the latter part of the project in

order to educate extension workers and farmers and to attract the fershy

tilizer industry into commercial production Considerable emphasis is

given to the economic evaluation of a total production-marketing-use

system for each material in contrast to alternative nutrient sources

The probability of commercial production of SCU and ground

rock phosphate can be enhanced by expanding their use to additional

crops and soils Thus the project is expanded in scope as compared

to the previous project on tailoring of fertilizers for rice in order

to test these materials on additional crops

The expanded work includes a major effort in screening and

testing new compounds and forms of fertilizers for various food crops

produced under tropical conditions Alt hough it if already known that

more effective andor lens expensive formn of nitrogen and phosphorus

are needed a literature survey will nerve an Lan additional guide to

important and presing fertilizer problems

-10-

Much of the work with fertilizers for both lowland rice and

upland crops will consist of field tests in Southeast Asia Africa and

Latin America Greenhouse and engineering studies will back up the field

research All field experiments are designed to provide at least an esshy

timate of costs and returns for each fertilizer tested

PROJECT PLANS FORFISCAL 1975

In this section the work for fiscal 1975 will be discussed

It should be remembered that the success of this project depends in a

large part upon maintaining sufficient flexibility so that work in inshy

dividual countries can be adapted to supplement and complement programs

already under way While guidelines and plans of work must be developed

so that the objectives of the project are clearly defined detailed

plans for specific countries or groups of countries must be developed

by consultation wth local cooperators

These plans will be discussed under the following three general

phases of the project

I Engineering and development

2 Agronomic testing and evaluation

3 Economic evaluations

Engineering and Development

Phosphate Rock

Methods have been proposed for relatively simple treatment of

phosphate rock (PR) to increase the availability of the phosphate to make

it more suitable for direct application to the soil These treatments

may be economically feasible in certain areas especially in view of the

current world fertilizer situation Considerable work has been done at

TVA studying means of altering PR and plans are being developed to inishy

tiate further developmental work and field testing of these materials durshy

ing fiscal 1975

- 12 -

Emphasis will be placed upon obtaining samples of phosphate

rock from deposits in developing countries and testing and improving

procedures for increasing their citrate solubility and tzius availabilshy

ity of the phosphorus From this laboratory screening process sevural

sources will be selected from which small amounts (50 to 100 pounds)

will be prepared for greenhouse and field experiments ou various soils

(as described under agronomic section)

From these results one or two locations (or countries) will

be selected for development of a pilot program to utilize local sources

of phosphate rock This program will involve production of the altered

PR and its agronomic evaluation and then educational programs with govshy

ernment and commercial representatives to introduce its use to the farmers

Sulfur-Coated Fertilizers

Some preliminary work has been done in which urea-potash mixshy

tures were coated with sulfur The 7-day release rates for the N and

K20 were 17 and 36 respectively from the coated product (22-0-11-30S

grade) This was the first effort in coating a compound fertilizer

with the new coating system

The widely differing release rates for the nutrients from

the coated compound product raise some interesting prospects for tailshy

oring the nutrient release rate of sulfur-coated products It might

be possible to cogranulate materials of varying water solubility and

sulfur-coat them to produce products with release rates that would apshy

proximate the timing of nutrient requirements of the crop The need

for this type of controlled-release product has been mentioned many

times by agronomists and may be especially applicable in multiple and

intercropping systems

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Table 2

Mttct of 0 Sourco aampW $At On Upt~ks of 0 by Two Varitgtos of Paddy Rice

gr~a 1971

~ MMUampL~ ~L ~ nYLALI~ 11 lemall

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- 24 shy

India--The results of four experiments conducted with flooded

transplanted rice in India by the All-India Coordinated Rice Project

Hyderabad are given in table 3 The response to N was excellent the

yield without N being only 41 of those obtained with basal applications

of N as uza With basal applications of SCU the yields were 20 higher

than with basal applications of urea and in the three experiments in

which urea applications were split yields with SCU were 18 higher than

yields with split applications of urea When comparing the average Nshy

response (kamp grainKg N) yields were increased 13 more by SCU than by

basal applications of urea

The data from one experiment with light irrigated rice in India

are given in table 4 yields were relatively low and differences between

N sources or method of application were not significant However yields

with SU tended to be higher than when all urea was applied at planting

but lower than when split applications of urea were applied Again yields

increased more than 13 more with SCU than with basal applications ofwere

ur

In tables 5 and 6 the yields of a short-duration transplanted

rice grown in irrigated light-textured soils at five locations in India

indicate that higher yields were obtained with SCU than with urea when apshy

plied as a basal application Yield increases due to basal N applications

were 502 greater with SCU than with urea However split applications of

resulted in yields equal to those obtained with basal applications ofurea

CU

The yields of direct-seeded upland rice grown at three locations

to India are given in table 7 and the relative yields in table 8 Yields

were low due to drought but good responses were nevertheless obtained for

- 25 -

Table 3

Effect of N Source and Time of Application on Yield of Paddy (Flooded) Rice in India 1972 (Summary of Reported Data from 4 Experiments)

Experimental Number Source Rate Method Yield Relative N-Response

and of of N of Yield Kg Grain

Season Nitrogen kgha Application mtha Kg N

- - - 196 34 -

Urea 120 Basal 573 100 314

11 Urea 120 80 + 40 611 107 345 Rabi SCU 120 Basal 713 124 430

12 - 0 - 202 30 -

Urea 125 Basal 682 100 384

Rabi Urea 125 35 + 20 + 35 + 35 633 95 344 SCU 125 Basal 781 115 463

13- 0 - 168 44

Urea 100 Basal 385 100 217

Kharif Urea 100 30 + 20 + 25 + 25 400 104 232 SCU 100 Basal 462 120 293

14 -

Urea -

125 -

Basal 355 650

55 100

-

236

Rabi SCU 125 Basal 781 120 341

-- 26 -

Table 4

Effect of N Source and Time of Application on Yield of Light Irrigated Rice in India 1972 (Summary of Reported Data From

One Experiment at Pattambi)

Experimental Number Source Rate Method Yield Relative N-Response

and of of N of Yield Kg Grain Season Nitrogen (kgha) Application (mtha) Q) Kg N

38 0 - 204 85 -Rabi Urea 120 Basal 241 100 308

Urea 120 60 + 0 + 30 + 30 267 ill 525 SCU 120 Basal 255 106 425

Table 5

Effect of N Source and Time of Application on Yields of Short-Duration Transplanted lice Variety Grown on Irrigated Light-Textured Soils at 5 Locations in India 1972

(Snmzarized From Reported Data)

Rate Grain Yields (MtHa) Source of N Method of N GrainI of N kgh Application Faizabod Karjat Mandva Pattabi laya Averaje X

- 291 266 211 19 340 260 -

Urea 100 Basal 386 407 361 285 482 3 124 Urea 100 50 + 25 + 25 399 430 434 334 6amp2 4A8 186

SCU 100 Basal 368 468 439 360 572 41 181

Table 6

Effect of I Source end Tlae of ApplIcattoo c RIstave Tle24 of a rt- rat1 T Lsd lice Vasrety Crin o Irrigated L41tshy1 at S Locitite mindi 1972

Rate ____________14_3

Source of X N~tbad of Of X An 1 tat14 1 acr X__T1 4v tatW ttva

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W Iotors Ftslanp tospg Irritd for Two thvk Afler flontiw wft rkwa~ Floo4d 191)

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- 38 -

Table 18

Yild of aemati-370 Rice at Punjab Agricultural Research

Institute in Pakistan in 1969-70 Grown Under

Couditions of Intermittent Flooding

Pate of application

=IL

o 0 67 67 100 100 67 67

100 100 67 67 200 100

Average for Sources

Ntha

AS 260 gres 279

320

Source f5

-

AS AS Ura Urea SCU SCU

Yield

Relative

93 100 115

(M)O

Yield

Increase Yield Due to N

(Ktlha) (mtha)

-212 245 033 274 062 260 048 297 085 315 103 325 112

Yield Increase

Relative

72048 067 100 108 161

(2)

- 39 shy

Short-statured high yielding rice varieties grown extenshy

sively in northern Peru require extremely high rates of conventional

N sources to achieve maximum yields The recovery of applied N is

extremely low due to the use of intermittent flooding This water

management system results in heavy N losses even with properly timed

split applications In search of simpler and more effective methods

of N management eight field experiments were conducted in the region

to evaluate sulfur-coated urea (SCU) an experimental slow-release N

source supplied by the Tennessee Valley Authority Rice yields were

increased an average of 59 more by pretransplant-incorporated SCU than

by urea or ammonium sulfate applied in the same manner SCU produced

excessive vegetative growth which resulted in yield reductions at high

N rates

Regardless of an assumed 48-higher unit N cost in SCU the

overall benefits of pretransplant-incorporated applications of SCU

were favorable since there was a decrease of 40 in the optimum rate

of N and the need for precise timing of application was eliminated

Pakistan--In Pakistan basal applications of AS urea and

SCU to rice grown under conditions of intermittent flooding in 1969-70

(table 18) indicate that SCU is a superior source of N as compared to

urea or AS when all N is applied at or before planting The data also

indicate that a yield response was obtained for P applications but a

comparison of N sources at each level of P indicates that no interaction

between N and P was present so that differences between N sources were

relatively the same at each level of P Yields were increased about 60

more when SCU was applied than when urea was applied Yield increases

with AS were only about 72 of the increase obtained with urea these reshy

sults do not agree with the generally-reported superiority of AS as comshy

pared to urea as a source of N for rice

- 40 -

In 1973 experiments were conducted in Pakistan using both

Basmati-370 and IRRI-6 varieties of rice grown under conditions of

When all N was applied at puddlingintermittent flooding (table 19)

or 12 at puddling and 12 at panicle initiation both AS and SCU were

superior to urea with SCU tending to be the most efficient source

However when N was applied 12 at transplanting and 12 at panicle

initiation SCU was the poorest source of N This would indicate that

the release of N from SCU applied at these times is too slow for optimwn

plant growth

In another experiment in Pakistan in 1973 no differences

in the effectiveness of urea AS or SCU were noted in the yields of

continuously-flooded rice (table 20) Again these results are conshy

sistent with earlier results which indicate no superiority for SCU

when rice is continuously flooded

Nitrogen Studies--Maize

A series of three experiments were conducted by IITA in

armo-Nigeria in 1972-73 comparing AS urea SCU and

CAN (calcium

nium nitrate) as sources of N for maize (table 21) A significant

yield response was obtained for N at each location but no conaistent

differences were noted amaong sources These results are consistent

with results at other locations which have not shown that SCU is a

superior source of N for maize grown over a period of 3 to 4 months

Nitrogen--Wheat

The yields of wheat in Pakistan in 1969-70 (tables 22 and

23) show that yields with SCU) tended to be lower than those with ureaJ

although at one locction where sorghum was grown followilng wheat with

Table 19

Yields of Basmati-370 and IRRI-6 Rice at Punjab Agricultural Experiment Station in Pakistan in 1973 Under

Conditions of Intermittent Flooding

Rate Yield Source of N Time of Yield (Mtha) Increase of N B-370 IRRI-6 Application Basmati-370 IRRI-6 Average (Mtha)

0 0 - 21 353 287 -

SCU 90 150 At Puddling 325 545 435 148

Urea 90 150 At Puddling 309 500 405 118

AS 90 150 At Puddling 324 529 427 140

SCU 90 150 Puddling 372 572 472 185 Panicle Initiation

Urea 90 150 Puddling 335 502 419 132 Panicle Initiation

AS 90 150 Puddling 353 529 441 154 Panicle Initiation

SCU 90 150 After Transplanting 312 562 437 150 Panicle Initiation

Urea 90 150 After Transplanting 340 624 482 195 Panicle Initiation

AS 90 150 After Transplanting 349 583 466 179 Panicle Initiation

All plots received 45 lbs P205acre as single superphosphate

Relative Yield Increase ()

Source of N At Puddling Puddling Panicle Transplant h Panicle

Urea 100 100 100 AS 119 117 92 SCU 125 140 77

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-48

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asowcs of P tof ttde ro The wreem proucts omre raGther

pemour~a ot P syag besmti andMi as elt ov so gpamwhr

iuipiqffhate(TS) low twseeo Is eftwiltve Is thet

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pud6itt of Irto paddle Wee ofsdlseireplastiq

0 49 shy

lbs partially scldiaatede grawilated Ml prodlucts Vere isshy

toiwdiats in 5tftOvttWS54 betwee wroiPi ad TVP NotV5Ymf to

me coo were they mere twoe $a a etfective ao TIP 00 sipifleast

LVSUMI5 at0 efecto wore toun tor thee produteo Timely dtIampWde

FR (-t00 mmoh) Uia amp~rally oar affective than Owe gra8448r FOampprodt

featal twos o 6 aotetire s I

Nowvero it to felt that sfortber field euprtet vth

hese interials Amd ether typs of grometatodl Wter nre wrrautad

hater ceeuwodh that they have me areec poteatlal toi additoG

e tate wAne the sectte as OtawrI sed bovoloen turther

euperimeste vth few reck pboophar s0d with reck pbophat treated

to sehesa citrata selmtliy or to ha csaducted

Metbir sertes of tbme enprtaeats wae c~edtmcted by IITA

to Ut~rta copal TVP AOP APP aed it at see tecastisix (table 14)

No dot lalt sewseltles teh draw tree thee results simouely em pear to tlvdl bsww they do stwgpt tbat forthew work with

MR to werramid so tbme sels

Table 24

LttcttF Swce MaPlate 06 ieldot IM AWaia CoelsANS at IITA (Ugboda ad Apoin ail sorit) aid at Ike (AUaba s5i series)

1973

Plate ot IP Apinu 5 poundebods A1ab

Ocrol 0 Z94 419 M)

Tr ipl ruprphite 20 349 3799378

Triple vepput 40 M09 410$

Triple 6wp~~b1 4271 4344 42250

Ammotw-ritpophW to 4201 4124 4040

Amosim-rdop~phlt 40 4270 4106 4231

AM tuo-polpephats 20 404 4244 3794

~eai~mpelppepbuI 400)49 4094

Cee m-pbpbt to- 59

momee eph lto 0 4192

LSO (0 0$) 29 1025

Th WPII

- 51 shy

101Y114 tpeM-fI PEP~tbRP YO

1 ~ ~ gmw 1pc~biofl- 9 Kla4v4h

Upia U04 Copfind am Crehout Stet Rpano at (Ia4

rico t IF t rume6 orth~ Caralto phoophale rocl QAR) vaUN pqU41 to

roopon from cmonetrat4 gsporphophai (CIP) who ort$o4 oil k

was 45j itwas tafertor vb protioo4 oil p war OS Ib 4iffer~c

in rtc reepos to X cod14 oo bo ttrit4 4 4 hvsciag of boil p

~ Pt o r11221 0 tP

c theto the rhimecyllndor of rico tots par to)14M4i1 roeoi~t

ed oil emd PA prior to tho ont of an~robi4 cMioe AA~ oIifoshy

nAte bYpot t taet~d tO fC4sin t~r 4PWden0 Of f Ot(tivshy

ofOWailiJtyno o prefla4 all Put that 4t01etoo 14 tvsIk

of the Ott to prvvld a 014for C4m0 44 mI 1 o4sf

EfftC ftPet141on AIAM-0 V f401td 4 4iv 440 Mtft

Aa torfat VampP f4MWfCi4W04wt0amp to 4eturWlI Ot(Wel~drIC ft

Ot f tM6 the flooded Ott 00 14 04019I Pft0uAw Of gAr~s~lr

pkS$t M40b MP) Tw P1101 Piset Prodwie W-e 10M0di Wr04

(10-1) emW 0aretilp ddw01at4 P WAA firom Rrth M~flRU414~$

wee cowiared with fie Md reWim 44104 proo~fo) foruk oith laWItter

I v te-PR P OW1004 4 4 O Wf ottil OW ellt Oo

Oveiel1 the 40tt dmcruie to effetotww Wtollowui Co fme

PR tpaUIB1I ldoltmo PR (pamwlatr) offr~- ArmeuM) 0 orwi

- 52 -

Effect of N Sourc6 and Water Management on Response of Rice

toe Zn- M Giordano J J Mortvedt OP Engelstad and Greenhouse

Staff Several rotes of CO(14H2)2 and (H )2So4 vith or without ZnO

wore applied to flooded and nonflooded Crowley oil (limed to pH 75)

to determine response of Bluebelle rice to Zn Yields with both N

sources veotrgreator on flooded then on nonflooded soil In the abshy

ence of applied Zn total dry matter production vith CO(NH2)2 was

slightly lower than with (NH)2S04 on flooded soil and considerably

lover on nonflooded soil Concentration of Zn wan higher in straw and

grain of plants roun on flooded than on nonflooded soil Although

concentration of P was unaffected by N source or Zn rate there was

som indication that cranslocation of P from straw to grain may be

depressed in nouflooded rice Concentration of N was lower in straw

grown on flooded than on nonflooded soil due to apparent dilution

thereas both X sources resulted in similar N concentrations in straw

at all rates of N application the N concentration in grain increased

with 0 rAse

feSpongi gf(SM to Chjorospodiostte and Related P Sources--

Si Allen and Greonhoue Staff A greenhouse pot experiment was

couct44d with corn Brown on Hountview silt loam to compare the ofshy

fectlivees of chlorospodiosito (Chlor-l) with concentrated supershy

phosphate (CP) Thomas slag and North Carolina phosphate rock (NC-PR)

Oil-prillad urea-phophato rock (UPI) FeA1JMP 20 7 and monomthyl

phosphate were included in the experiment Based on yield of forage and

uptake of P by tvo crops each of 6-weeks duration the following conshy

stui were dravat

I Chlor-1 was slightly loss effective than CSI Thomas slaS or NC-PR

from which Chlor-l wae prepared

- 53 shy

2 Granular UPR was a poor source of P its effectiveness was greatly

increased by reducing the particle size to -35mesh

3 FeAlNH4P207 was unavailable to the crop

4 Monomethyl phosphate was equivalent toor slightly more effective-

than CSP

Research Indirectly Related to TVA-AID Project

Response of Several Rice Varieties to Zn in Moist or Flooded

Soil--P M Giordano J J Mortvedt and Greenhouse Several varieties

of rice from Mexico and the Dominican Republic currently under investishy

gation in Puerto Rico for adaptation to upland culture were compared with

some established United States varieties with regard to Zn response on

moist and flooded Crowley sil (pH 75) Chontalpa (Mexico) Bluebelle

(Texas) and Starbonnet (Arkansas) were most responsive to applied Zn

Juma (Dominican Republic) intermediate and Sinaloa (Mexico) and Calrose

(California) were the least responsive The Sinaloa varieties (Mexico)

appeared to be best adapted to non-flooded conditions whereas Chontalpa

and Calrose were poorest Concentrations of Zn generally were higher in

plants grown on flooded than moist soil

Pattern of Growth and Zinc Accumulation by Rice--P M Giordano

J J Mortvedt and Greenhouse Staff Rice plants were harvested at weekly

intervals from shortly after emergence through maturity The objective

was to determine the rate of growth and Zn uptake by a Zn responsive varshy

iety (Bluebelle) and a less Zn-responsive variety (Calrose) in the presence

or absence of Zn applied to Crowley sil (pHl 75) Dry matter production

of Calrose was linear with time of growth and of a similar magnitude until

heading with or without applied Zn Bluebelle followed a similar pattern

where Zn was applied However in the absence of applied Zn foliage yield

was reduced markedly

-54

Uptake of Zn was similar for both varieties whenZn was

applied Dry matter production and Zn uptake by the two varieties

also were comparable when Zn was applied However yield of Calrose

was much higher than that of Bluebelle in the absence of applied Zn

while Zn uptake was only slightly higher This suggests that the lesshy

ser responsiveness of Calrose to Zn may be due to more efficient utilishy

zation of Zn There was no indication of a greater demand for Zn durshy

ing reproduction in either variety as was suggested in earlier greenshy

house experiments

Response of Upland Rice to P and Zn--P M Giordano J J

Mortvedt and Greenhouse Staff Several rates of P and Zn were applied

to Crowley sil (limed to pH 75) in factorial combination to determine

whether differences in rice growth under flooded and nonflooded soil

conditions are related to plant nutrition Although straw yields were

slightly higher in nonflooded rice receiving adequate P and Zn grain

yields were higher in the flooded crop increased rates of F andor Zn

did not result in equal yields Except in the highest Zn rate (75 mg)

concentrations of Zn in both straw and grain were higher with flooding

Concentration of P increased with rate of applied P and was higher in

the grain or flooded than upland rice at a comparable P rate In conshy

trast concentrations of N were lower with flooding due in part to dilshy

ution from increased growth

Rice Response to N and P in Flooded and Unflooded Cultures--

G L Terman S E Allen and Greenhouse-Analytical Staff Rates of

N from 250 to 2000 ntpot and P from 0 to 1000 mtpot were applied for

Nato rice grown on Mountview sil and Sango sicl (625 kg of soil per

pot) Market yield response to N and P was obtained Yields of straw

- 55 shy

total yields N uptake and N recovery were higher on unflooded than

on flooded soil cultures Grain yields however were slightly higher

with flooding These results indicate that with adequate applied

nutrients especially of N rice yields without flooding can approach

or even equal those under flooding

Uptake of N P Ca Mg and Zn increased with yield response

to N and P while K uptake decreased on the Mountview soil Concentrations

of N and P increased with applied N and P respectively while concentrations

of other nutrients were diluted in most situations with yield response to N

or P

Results from this experiment show that amouats of N applied in

previous pot experiments for rice have been much too low especially if the

crop was grown to maturity

Response of Corn to S and N i UUASand Urea-S--S E Allen

and Greenhouse Staff Three greenhouse pot experiments were conducted to

measure response to S and N in ulfur coated urea (SCU) urea amonium

sulfate (UAS) and urea -S as well as estimate N losses from surface apshy

plied N sources

In Experiment 260 less than 20 of the S mixed with the soil

was recovered from SCU or urea-S granules by two crops of corn as comshy

pared to 45 or 80 from flowers of S or Na2SO 4 CLop response followed

a similar pattern

In Experiment 260-A N sources were surface applied and alshy

lowed to dry for two weeks before incorporation Into the soil and plantshy

ing Recovery of N by two crops of corn was 77-82 for AN an compared

to 37-70 for urea UAS urea-S and ICU Thus n this experiment loss

of N from urea did not appear to be re~dcud by light S-coatlngn or by Inshy

corporating S or AS in the granules

-S -

I xbprZnSlt a Wtch aU Meyto 0-Ai Wt f9r

higher reermo teOrtOrs cOM reSpWNO i r0100 Of N w

not oaisteontly related to sewe ot N In edl tust 0 ioltiUe Lim

lo in VMuwpped evlmtUTS 48 merind by seirest nte appresOehe

501 for uroa as cwarod to 210 for urea peepha

Rus- or Upse to LoAmIl34I a AriMed bI Earl U

MW NOWlsIIsIr-4 L Toman 5 1 Alln and eesese StNf rio

row on Sawg did (0 tpot) We 1l0l0 Ws feritiud vith 05is

of Npot mixod with the 6011 as aureCA NiAO) 1 Age god At Ures

was also itcluded at rtt t 05 10 end 15 of Upee Theas trealshy

onto were followed 4 wpdrsetago of U s AN wre 4C 10o or at I3n

Weeks toulin up to IS pot

A soil application of 10 pot rosulvod to the maim yield

at 4 weeks Tio4 sad percont prottis t intre raite tncreased rftishy

linearly with U applictalien IeseeItally all at the m iNd wit

the moil w domitrifted after flooding Grail end straw Ilelds vere

highly correlatod with tiliriag and vlh ubers of gralm arl

The results Widicat that 0$ to 10 a of Upot as orea or

NN bsuld be sied with the oil to stilate tiilrir with adshy

ditional 0 topireased later to increase grain lIds mad protia cmshy

tout

DIVISION 54- FERTILIZER TECHNOLOGY AND USE

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valves a hevwae u Iar Walh basl oswas dhe uwpatr bshava of

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TOW opl taoe for AieweeW 4OsmWMbas Op peas As Tabl 4 sling sob Os awowully eom grams Piel level Thes oeulam Ma sed as IM

-02

792 60L WI W A)49R Pio VOL 37 197)

primS o r OeampAd WU toa Them fl~ w At NOSSe earno maisslea Ia N he mOWamplIO yik ampWd IMe aampWmW OWa Owe wa UMs of KU to 41 Oke ampWiiIamm be dkrnety ewspokawleM(a s8 te camtd wie a eapmoe by TVA pavw ltoi NA poundrmdaka4us vrimeW460 o to ilkidm ofWW (Mtemas MuOwe 1973) TVA mwi bawld on soi ficedims IampWp seg rudwiv s~s0abet ke WNmdoe ON 01 K Is12 NOSW ie fssewnmu Ie I QvaaIi rowp IMA) f9

)amp m lodk byO voebmsaIS8OpeaWfrats 11 OWNmi a I a W idisod 0 81 Now 111 nindat Wm fysmpseaamp (If tsO tUmtI IsM $P shoroV4mmo knflkvnf (foOdme nuw ae Ow OImstwe in SM pnmm8 af tXm 10 114PIS kequoian wo Mpfii

SC~po umd spop~o VWt alm 4emWal 1 4ink PCmirsra M 1 ad AI 14bmms

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DIVISION 8-9-SOIL MINERALOGY

Amorphomw CeetIup en XmWra Ssrfmls

L C koits Am~ 0 tmmkaAf

ommp A faieiaAMTRACT skiwe lo nW ampM sm wi4h

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peuiieles as is s e wpwigstee eded his S -em -om 0641 h4 hisW1mWOWb~ bfem peess Wimm kv Iee

Pa~~~eakr4awiS SeUeeiNaiA WOW 14e

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oO00 llb K0 ibad~ ~~ doj 140WI s o mimdW um

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os 0aMW ofmu WA l aduWs~Ib rowuvvl3maIpm s

CaO~OP aw AlNomI 4ornomd to9 IS is -l O SI g4he rpidyThus whim m dowu bWa 0 m m- ei u

d m M 0bmSaImu M-1 ofM6 h Intun to 7I

aiba maush WAesshwn~u9dSg a osusLwpI ~ v m

M PolsdAvoWdw Ons pugm~ low iwLW m We

of~U -a~ mo uNo

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A e mun5d m i vvamp sa s ow bftIS i sa omdIs a w

edi1 hswopmo an ag am Iw anom erlwaPASneooie bnwoM po

o ~ do=lr 3s fluACWoSM Owaa VolM Ain b 400b adW g o as amob ofrMOWS A oo eWmaa ow $wofdi60 ow - ema

-v K Vcon l ap ad md ld KU lbs PoabumwA od w to domi a bembe 0b lt $014 i ampmomONo

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arbs awasm 00 iztv Am-~~~i u5~ms ashu is byw

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bdisc shmm Ammmd a Sm ofd~~~~~d~A ~ a~m olWshmo

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- omlos r umIWO1in pw

lie Uvplist i piw S p wsmoW N of t as so in~tabo 440 o rodgAsect M4Ammd meM ii INAq10ed~ Pib mdWWeiW 1w -w emit TU UFm 6AV 0W A fIN 00~ lb 0PANNO 4 drp OW~It~Oi Ofme _____f WACMW0IN WMVsol~lmO ft SNAO 40 do1Si - m Md y e b ii m

of of~phaow tw bmsdf toamplboe

AjflsutomW C1D-pCTP AD mSmZLT op 1 m ow ts Wdm of P om M

IaM 0t sdw a wn a8duws i ofV -w Mm P16I4 TWO a ewu i an

ov4mnk wsi 9 Mxfeu~i am emwm ismi0wmd fq W No ~~ - f mug Aitowe eutlkowbmTV is

amppowftdmi TiM 0 Tie OAA mo p)a Mwomoi dOn4m A)w

MW 0 604 0M mm yaM 01MWOfdi to tA0 M OOAW uinw OSOb

ap is~e I the ampo A A Mwof ~Do toit op aenu w~ifiOimem~ MAN ampW)

ItsAO se Y lieowawo u~w pkow-W1b pwf on a C Nohkw is f 0o1 s do~omW C mmU4

owud6moeft 4 Obind PINa~e

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~ -0

65

0IL CL OC AMXR PROC VOL 38 1974

)aT1 S4I104 ow Lusanll Tawng isa tall Thai variety known for beingIwo nonshyi s s ) sensitive to photoperiod A split-plot design was used in

S e e these euperimeots with 4 rates of P (I1 22 44 and 88t i V IV k of Pha) applied a main plot treatments and with the OF It sourMes of P as subplot treatments There were two checkS plots in each rmplicate The extra check plot was included to permit the application of fresh TSP standard Jor the

It- ti 06 + i bull fa succeeding crop the p-4me of bi was to permit accurate d awrnwal of the mdual effectiveness of the phosphate

ftinSUbI rock The P fertilioers were broadcast on the mud andthen Worporald In the soil during the last harrowing At

whM N both On ACS indx ampM time of transplanting Immediately before the last harrow61t (4j 5 4 01 P s 3Mm o Vallonal in con n 100 kgha of N as ammonium sulfate and 33 kghaWO Of Spews ampm lIW thaabe rocks do ACS indes of K as polium chloride were applied A total of 40 wa in prepw O do ctih k otent kha of N a ammoniunt sulfate was applied later in twoir P The hew oNed amp wM W for 5 of gw topdrossingp with about 5cm depth of water on the plotsvV I aiOMveffeOctveee Three to six ldayold selings pr hillwW the ACS idex were planted00OWW wia Oft fo an c irNk I p Coen 20 by 20 cm part in straight rows Hand weeding was used

and insecticide were applied for Insect control Grain yieldw was masared by sampling 5 ml of each plot excluding border rows The date of heading in each treatment and theUNiN d pbM W Weks rin tOW USA UMe In Tale yed componnts at hafvel were also recorded

I filM rsperMS esOM kdwdua 1 t ab The average yields of ough (unhulled) rice for botha 84 OW O 8uo 4 Thala TM was a locations are ploutel in PIS 3 for the first crop (1969 wet

owou thRM seaso0) The Veamps yield response was obtained at Klonge (s) W lDtO t Of dMa of1tw W d l R Luang however a 4ute satisfactory yield response was

~Mk ^d TVA UJSD ad Kd UnIveS obtalned to applied P at Bangkhen as wellXUe LaM e R qwrw Ims The sod was do Relative aponomlAe effectiveness values were calculated

VOW (a ksA w edmwL t Poesesm h Vy for these data and am presented In Table 3 The valuesdAY buo if dIe ouh ne Pee wtk a Mlak vow 1009 for th first crop are plotled against ACS index in Fig 41 This Im M i6ti l 4bNd IO a0 O mkarnk for both locatio r relationship was linear for the

11400 ThCpH 0( lb pW IW 01 th UpeiaW so Sanodion location and curtiltnear for KIng Luang The was u i 4A sksamp lMaor nrusio model amparounted for 81 of theAmO$MI Aw jAAsue Swim T1 Snh Wd variation In the AE valu for Bantkhen a square root

Mems a Iw iv fern alh$ sedm haowg dayNW W t he plAL At tdo M tM aso W s as ctminued throufh eltaM t Ofpof -le lse wo am P OeNI VeOpls 1o ealluae tI lon4erm MIdual Offccls

A on W isset i a wse to hsh eapeel of these ooihss t ocks The baagkhon experimnent was letmiaI1DlVemisthis is a w hulu Lo g Tasug ia iasael aft - Msd residual Ves will be pr-Om crok TheseTwod esewm

SWWo

A

lP~U~7 ISIIPe1iuIWN e bsedisssin ian ghth siaoelalbe

984 0 6 O O - M s -s fWPas 11eSft W d Uo al a o

o

S4l~ lIIII I~l I 1f fl

( +

+ + + m + ++++-

++ +(++ + ++++ + ++ ++

- 66 -

ENOIMLSTAD ET AL RESPONSE BY FLOODED RICE TO PHOSPHATE ROCKS VARYING IN CITRATE SOLUBILITY

I I I I j0 I I

BANOKHEN BANGKHEN

pH 56 6 - 0o

TSP

NC

5~ ~ ~ L o 4 - -shy

4 ] - --------shy04

6S

|0 III 2 44 8r 66

I I I

a 1KLONG LUANG

pH 46 z KLONG LUANG

TSP Sc2 NCFL(N)

5 FLIC) J0 TU

oshy

4 ~40shy

3 bull eM0

I - I I I I I

0 II 22 44 88 0 5 10 15 20 IP APPLIED KO HA ABSOLUTE CITRAE SOLUBIITY INDEX

Fig 3-Yield of rough rice at Klong Luang and Bangkhen Rice Fig 4-Relative agronon effectiveness () of P sources ploz-Experiment Stations Thalmand as affected by rate and Source ted against citrate solubity Index for both Thailand field ex

of P applied (crop 1) periment (first crop only)

regression model accounted for 97 of the variation in sumably resulted from crop uptake and reaction with the RAE values at the Klong Luang location soil to form less soluble products Such effects may have

These experiments were continued during the dry season been more important at the lower rates since the two TSP of early 1970 to ascertain the residual effectiveness of the curyes converged at the highest rate of application various sources applied to the first crop No new P was These data from KIong Luang indicate that (i) residual applied except for the fresh TSP standard mentioned effects of all rocks except Mlcwuri were substantial (ii) above rhe experiment otherwise was conducted in a man the relationship between relative agronornic effectiveness ner similar to that followed in the first crop of the phosphate rocks and citrate solubility levels was

The response to both freshly applied ad residual P was largely obscured and (iii) the general superiority of TSP marked at the Klong Luang location and marginal at over phosphate rock in terms of effectiveiss persisted Bangkhen In fact at the latter location the response was through the second crop so small that little can be said regarding residual effectiveshyness The yield data from crop 2 at the Klong Luang DISCUSSION experiment are plotted in Fig 5 Greenhouse and field data presented in this paper show

Relative agronomic effectiveness values (Table 3) were clearly that there are substantial differences among phosshycalculated for the Klong Luang data using both the residual and freshly applied TSP as standards It is of Interest to note that the superiority of TSP over the phosphbte rocks Table 3-Relative agronomic effective values for field experishyments in Thailand persisted through the second crop The main difference in KlowlZmlnql~the residual effects is that with the exception of the MIs- s Crop 1 Crop 21 Crop 1-shysouri rock Ihe marked relationship between citratr-soluble WoiCarolina yl 59 76

phosphate rocks and RAE had largely rds norh) a 64P conltct of th Florida (eqlral is 6969 6

disapipeared In this acidic soil (pHi 46) P would by this I14o 69 63 40 ToonesS 31 65

limo be supplied by Intermediate reaction products In addl Missou 0 o lion to residues of the initial spatlte Ts P o 2 o 0

The TSP applied to the first crop declliv-d slightly In campIafcmWataesr e id ofeuhuloefor 22MA rates of PtColeouattd as aba u tlte td18 kS ratesp dlverage yield tM868 to 22 44

effectiveness relative to the freshly applied ISP This pre- of d s4

A

4

- 67 shy

-SOIL SCL SOC AMER I

KLONG LUANG CROP 2

Si 3

eN

TAPPLIEDKGHA

Fig 5-The residual effectiveness ovarious P sources for crop s compared with freshly applied TSP Klong Luang Rice

Experiment Station Thailand

phate rocks in terms of agronomic effectiveness for flooded

rice Further these differences can be predicted by means of citrate solubility or by the ACS index It appears that

the latter is more appropriate where the content of apatite varies among phospiate rocks The most soluble phosphate rocks approached but did not actually equal TSP in limit-iuig (maximum) yield in these experiments regardless of rate applied This agrees with the results of Ensminger Pearson and Armiger (4) One needs to consider the defi-nite posribility of same yield loss in zhoosing a phosphate

rock over TSP such yield losses must be weighed against the lower price of phosphate rock The explanation for such iosses may involve concentration of soluble P in the soil Khasawneh and Copeland (6) suggest that the growth rate of crop plants is a function of P concentration that can be maintained in the soil solution If P concentration is limiting or inadequate becawe of a lower dissolution rate of phosphate rock the growth iate ard uiiimate yield will be diminished accordingly

The RAE values bascd on yield increases reflect the agronomi effectiveness of these various sources relacve

to the TSP standard however these nould be supple-

mented by an economic analysis before rational choice can

be made The following calculations will provide an estimate of

the rclativ ecooomic effectiveness(REE)

Y t Ps aXpatREE -- 100

vahtercks t sphate or e b i- eor

Price of TSPkg fo

be Price of PRkg P

PROC VOL 38 1974 leO

90r

Wsoshy

0

60-LUSEPHOSPHATE ROCK

00 10 20

PTP PR

Fig 6-Relationship between relaZive effectiveness values (RAE) and the price ratios between TSP and phosphate rock Such a figure can be used in making a choice between these

sources

If REE exceeds 100 in this calculation the phosphate rock would be preferable to TSP

The REE calcuktaaa wre used in preparing an indifshyference curve (Fig 6) wherein RAE values are plotted

against PTsPPpR ratios The cu~rve itself connects those points at which REE equals 100 When exactly on the curve it makes no real economic difference what source is chosen After choosing a suitable price ratio one can then project upward from that ratio knowing the RAI

value (or estimating it from such data as shown in Fig 4 using citrate-soluble P content) one can then choose the source on the basis of both agronomic and economic conshysiderations For example if the price ratio is 25 and the RAE value of the phosphaite rock is greater than 40 the rock phosphate in question would be used However if the RAE value was less than 40 TSP would be a better choice There are indications that if the P in the more soluble phosphate ro~cks (North Carolina north Florida central Forida) is less than half as expensivz as that in TSP these rocks would be feasible altereaives to TSP on soils similar

to thoseused in Thailand This analysis does not take into account the possibility

of lower yields from use of phosphate rock In addition only a portion of the various yield response curves was used in this anlysis ie up to 22 kgha Beyond this

rate yield response was much less pronounced it could be argued that at less than maximum yields TSP would produce a certain yield at lower rates of P than would phosshy

pow ofrock This would especially be true for rates applioa example at Klong Luang 5500 kg of

rice pcr iectare could have been produced with either Ii kg of P as TSP or 44 kg of P as son of the more reacshy

tire phosphate rocks It should be pointed ot however

- 68 shy

(IIKIS amp YOUN( ARIFICIAL WEATIIERING OF OXIDIZED p[ll- IV

that this is the yield level that would show the widest difference such is the advantage of hindsight

Farmers generally prefer granular fertilizers for machine

or hand application This is a disadvantage for the phos-phate rocks which are normally arplied in finely divided form Recently experimental quantities of granular urea-

phosphate rock mixtures have been made by TVA Results of trials with these fertilizers will be reported elsewhere

LITERATURE CITED

1 Armiger W H and Maurice- Fried 1957 The plantavailability of various sources of phosphate rock Soil Sci Soc Amer Proc 21183-188

2 Bengston G W E C Sample and S E Allen 1974 Re-sponso of slash pine seedlings to P sGurces of varying ci-trato solubility Plant Soil (In press)

3 Caro JIt and W Hill 1956 Chard eristics and fer tilizcr value of phosphate rock from different fields J Agr Food Chem 4684-687

4 Ensminger I E R W Peirson and W II Atmiger1967 Effectivencs of rock phosphate as a source of phosshyphurus for plants US Dep Agr ARS Bull 4112S

5 Engelstad 0 P J G Getsinger anid I J Stangel 1972 Tailoring of fertiliers for rice cnnece Valley Author ftyNational Fertilicr Developmnent Center Hull Y-52

6 Khasawnch F E and Jane P Copcland 1971 (otton root growth and uptake of nutrievos relation oif phosph

rus uptake to quantity intensity and buffering capacit) Soil Sci Soc Amer Proc 37250-254

7 Lehr JR and G H McClellan 1972 A revised lIbora tory reactivity scale for evaljativg phosphate rocks for direct application Tennessee Valley Authcrity National Fertilizer Development Center lull Y-43

H Terman G L S EAllen and 0 P Engelstad 1970 Response by paddy cice to ratcs and suurces of appliedphosphorus Agron J63390-394

DIVISION S-9-SOIL MINERALOGY

Artificial Weathering of Oxidized Biotite IV The Inhibitory Effect of Potassium on Dissolution llate

R JGILKES AND R C YOUNG2

ABSTRACT

Rates of dissolution of oxidized biotites in OIM 001M ICI are severely depressed in the presence of IM KCI The amovnts of Al Mg Mn dissolved in the first eytraction are similir to those found without KCI however subsequent extractions remove these elements at 10-20 of the corresponding lICI rates This effect may be due to a decreased rate of vermiculite formation thereby reducing the effective basal area exposed to attack A decrease in dissolution rate with increasing ferric iron content was still apparent in the presence of IM KCI

Additional Index Words X-ray diffraction infrared aborp-

N EARLIER papers of this series the tole of biotite in soils

as a source of both macro and micronutrient elements

has been discussed ((Gilkes Young and Quirk 1972 1973ab) Experiments in artificial weathering uiing as va-

riety of extractants were undertaken to determiie the inlu-

ence of oxidation of octahedrally coordinated iron on the bull release of structural cations to solution The results of this

work demonstated that biotite behaves anomalously with respect to the other common ferromagnesian minerals found in soils Oxidation leads to the development of a high degree of resistance to cation exchange and dissolution Several authors have coiwludcd that decreased rates of K

Contribution from the Dep of Soi Science and Plant Nutri-tion Institute of Agriculture Univ of Western Australia Ned-lands 6009 Western Australia Received 29 Sept 1973 Ap-proved 8 Jan 1974

2 Senior Lecturer in Soil Science and Research Officer respeclively

replacement in electrolytes shown by oxidized biotites are

a result of the inclination of structural hydroxyl adjacent to newly created trivalent iron or vacant octahedral cation sites (Robert and Pedro 1959 Barshad and Kishk 1968) Gilkes et al (1973b) suggested that decreased rates of disshysolution of oxidized biotite in 0001 0t)l 0Af CI may also be due to the presence of inclined hydroxyl In this case a smaller surface area external and exposed intershylayer may be available for attack if K replacement by hyshydrogen ions occurs at a slower rate in oxidized biotites

Gastuche (1963) has shown that significant dissolution ofthe (IIM) biotile face may occur and it is easily demonshystrated that the proportion of exposed (001M) face in weathering biotites depends on the percentage K replaced

Rausell-Colom ct al (1965) have shown that hydrogen ions act in an identical fashion to metal cations in K exshy

change from micas In particular exchange c-f K by hydroshy

gen ions will be terminated or greatly reduced by high levels of K in solution Thus if dissolution of oxidized biotite by

acids is carried out at sufficiently high K levels to prevent vermiculization any differences in dissolution rate that may occur cannot simply be ascribed to differences in rates of K replacement The following results were obtained from such an experiment which unlike the experiment described in Parts I and II (Gilkes et al 1973ab) does not attempt to simulate natuiral - conditions

MATERIAILS AN) M HIiODS Further subsamples of the less than 0 hiotites used in K

excherandbaid disoo tu es (G iles e9n K exchange and acid dissolution studies (Gilkes et al1973ab) were used in these experiments Preparation of sequentiallyoxidized biotites without intermediate vermiculite formation is

Page 11: I70 - United States Agency for International Developmentto ascertan, but tgl.eetad, 1, L,. ("Tailoring of Pertiltiters for ice,'" TVA ulletin Y-52) states that the staft of IOi has

-8

(2) Proving the value of these improved materials to insure that

they will increase farmers income over a large enough area

to attract and Justify commercial production

(3) Developing the production technology for new fertilizers as

a basis for encouraging and advising potential commercial proshy

duction The integrated process designs will seek product

quality and economy while striving to minimize harmful emisshy

sions to air water and land

(4) Working through cooperating organizations and with leaders in

research extension and industry to develop and demonstrate

methods for introducing new fertilizers to farmers so that they

will be properly used when they become commercially available

-9-

SCOPE OF WORK

This project integrates agronomic economic and engineering

expertise into a single team in order to develop improved fertilizers

for a wide range of crops and soils in developing countries Considershy

able emphasis is given during the first eighteen months to collecting

the data needed to complete the evaluation of sulfur-coated urea and

ground rock phosphate for lowland rice Both materials then are

scheduled for demonstrations during the latter part of the project in

order to educate extension workers and farmers and to attract the fershy

tilizer industry into commercial production Considerable emphasis is

given to the economic evaluation of a total production-marketing-use

system for each material in contrast to alternative nutrient sources

The probability of commercial production of SCU and ground

rock phosphate can be enhanced by expanding their use to additional

crops and soils Thus the project is expanded in scope as compared

to the previous project on tailoring of fertilizers for rice in order

to test these materials on additional crops

The expanded work includes a major effort in screening and

testing new compounds and forms of fertilizers for various food crops

produced under tropical conditions Alt hough it if already known that

more effective andor lens expensive formn of nitrogen and phosphorus

are needed a literature survey will nerve an Lan additional guide to

important and presing fertilizer problems

-10-

Much of the work with fertilizers for both lowland rice and

upland crops will consist of field tests in Southeast Asia Africa and

Latin America Greenhouse and engineering studies will back up the field

research All field experiments are designed to provide at least an esshy

timate of costs and returns for each fertilizer tested

PROJECT PLANS FORFISCAL 1975

In this section the work for fiscal 1975 will be discussed

It should be remembered that the success of this project depends in a

large part upon maintaining sufficient flexibility so that work in inshy

dividual countries can be adapted to supplement and complement programs

already under way While guidelines and plans of work must be developed

so that the objectives of the project are clearly defined detailed

plans for specific countries or groups of countries must be developed

by consultation wth local cooperators

These plans will be discussed under the following three general

phases of the project

I Engineering and development

2 Agronomic testing and evaluation

3 Economic evaluations

Engineering and Development

Phosphate Rock

Methods have been proposed for relatively simple treatment of

phosphate rock (PR) to increase the availability of the phosphate to make

it more suitable for direct application to the soil These treatments

may be economically feasible in certain areas especially in view of the

current world fertilizer situation Considerable work has been done at

TVA studying means of altering PR and plans are being developed to inishy

tiate further developmental work and field testing of these materials durshy

ing fiscal 1975

- 12 -

Emphasis will be placed upon obtaining samples of phosphate

rock from deposits in developing countries and testing and improving

procedures for increasing their citrate solubility and tzius availabilshy

ity of the phosphorus From this laboratory screening process sevural

sources will be selected from which small amounts (50 to 100 pounds)

will be prepared for greenhouse and field experiments ou various soils

(as described under agronomic section)

From these results one or two locations (or countries) will

be selected for development of a pilot program to utilize local sources

of phosphate rock This program will involve production of the altered

PR and its agronomic evaluation and then educational programs with govshy

ernment and commercial representatives to introduce its use to the farmers

Sulfur-Coated Fertilizers

Some preliminary work has been done in which urea-potash mixshy

tures were coated with sulfur The 7-day release rates for the N and

K20 were 17 and 36 respectively from the coated product (22-0-11-30S

grade) This was the first effort in coating a compound fertilizer

with the new coating system

The widely differing release rates for the nutrients from

the coated compound product raise some interesting prospects for tailshy

oring the nutrient release rate of sulfur-coated products It might

be possible to cogranulate materials of varying water solubility and

sulfur-coat them to produce products with release rates that would apshy

proximate the timing of nutrient requirements of the crop The need

for this type of controlled-release product has been mentioned many

times by agronomists and may be especially applicable in multiple and

intercropping systems

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gr~a 1971

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- 24 shy

India--The results of four experiments conducted with flooded

transplanted rice in India by the All-India Coordinated Rice Project

Hyderabad are given in table 3 The response to N was excellent the

yield without N being only 41 of those obtained with basal applications

of N as uza With basal applications of SCU the yields were 20 higher

than with basal applications of urea and in the three experiments in

which urea applications were split yields with SCU were 18 higher than

yields with split applications of urea When comparing the average Nshy

response (kamp grainKg N) yields were increased 13 more by SCU than by

basal applications of urea

The data from one experiment with light irrigated rice in India

are given in table 4 yields were relatively low and differences between

N sources or method of application were not significant However yields

with SU tended to be higher than when all urea was applied at planting

but lower than when split applications of urea were applied Again yields

increased more than 13 more with SCU than with basal applications ofwere

ur

In tables 5 and 6 the yields of a short-duration transplanted

rice grown in irrigated light-textured soils at five locations in India

indicate that higher yields were obtained with SCU than with urea when apshy

plied as a basal application Yield increases due to basal N applications

were 502 greater with SCU than with urea However split applications of

resulted in yields equal to those obtained with basal applications ofurea

CU

The yields of direct-seeded upland rice grown at three locations

to India are given in table 7 and the relative yields in table 8 Yields

were low due to drought but good responses were nevertheless obtained for

- 25 -

Table 3

Effect of N Source and Time of Application on Yield of Paddy (Flooded) Rice in India 1972 (Summary of Reported Data from 4 Experiments)

Experimental Number Source Rate Method Yield Relative N-Response

and of of N of Yield Kg Grain

Season Nitrogen kgha Application mtha Kg N

- - - 196 34 -

Urea 120 Basal 573 100 314

11 Urea 120 80 + 40 611 107 345 Rabi SCU 120 Basal 713 124 430

12 - 0 - 202 30 -

Urea 125 Basal 682 100 384

Rabi Urea 125 35 + 20 + 35 + 35 633 95 344 SCU 125 Basal 781 115 463

13- 0 - 168 44

Urea 100 Basal 385 100 217

Kharif Urea 100 30 + 20 + 25 + 25 400 104 232 SCU 100 Basal 462 120 293

14 -

Urea -

125 -

Basal 355 650

55 100

-

236

Rabi SCU 125 Basal 781 120 341

-- 26 -

Table 4

Effect of N Source and Time of Application on Yield of Light Irrigated Rice in India 1972 (Summary of Reported Data From

One Experiment at Pattambi)

Experimental Number Source Rate Method Yield Relative N-Response

and of of N of Yield Kg Grain Season Nitrogen (kgha) Application (mtha) Q) Kg N

38 0 - 204 85 -Rabi Urea 120 Basal 241 100 308

Urea 120 60 + 0 + 30 + 30 267 ill 525 SCU 120 Basal 255 106 425

Table 5

Effect of N Source and Time of Application on Yields of Short-Duration Transplanted lice Variety Grown on Irrigated Light-Textured Soils at 5 Locations in India 1972

(Snmzarized From Reported Data)

Rate Grain Yields (MtHa) Source of N Method of N GrainI of N kgh Application Faizabod Karjat Mandva Pattabi laya Averaje X

- 291 266 211 19 340 260 -

Urea 100 Basal 386 407 361 285 482 3 124 Urea 100 50 + 25 + 25 399 430 434 334 6amp2 4A8 186

SCU 100 Basal 368 468 439 360 572 41 181

Table 6

Effect of I Source end Tlae of ApplIcattoo c RIstave Tle24 of a rt- rat1 T Lsd lice Vasrety Crin o Irrigated L41tshy1 at S Locitite mindi 1972

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- 38 -

Table 18

Yild of aemati-370 Rice at Punjab Agricultural Research

Institute in Pakistan in 1969-70 Grown Under

Couditions of Intermittent Flooding

Pate of application

=IL

o 0 67 67 100 100 67 67

100 100 67 67 200 100

Average for Sources

Ntha

AS 260 gres 279

320

Source f5

-

AS AS Ura Urea SCU SCU

Yield

Relative

93 100 115

(M)O

Yield

Increase Yield Due to N

(Ktlha) (mtha)

-212 245 033 274 062 260 048 297 085 315 103 325 112

Yield Increase

Relative

72048 067 100 108 161

(2)

- 39 shy

Short-statured high yielding rice varieties grown extenshy

sively in northern Peru require extremely high rates of conventional

N sources to achieve maximum yields The recovery of applied N is

extremely low due to the use of intermittent flooding This water

management system results in heavy N losses even with properly timed

split applications In search of simpler and more effective methods

of N management eight field experiments were conducted in the region

to evaluate sulfur-coated urea (SCU) an experimental slow-release N

source supplied by the Tennessee Valley Authority Rice yields were

increased an average of 59 more by pretransplant-incorporated SCU than

by urea or ammonium sulfate applied in the same manner SCU produced

excessive vegetative growth which resulted in yield reductions at high

N rates

Regardless of an assumed 48-higher unit N cost in SCU the

overall benefits of pretransplant-incorporated applications of SCU

were favorable since there was a decrease of 40 in the optimum rate

of N and the need for precise timing of application was eliminated

Pakistan--In Pakistan basal applications of AS urea and

SCU to rice grown under conditions of intermittent flooding in 1969-70

(table 18) indicate that SCU is a superior source of N as compared to

urea or AS when all N is applied at or before planting The data also

indicate that a yield response was obtained for P applications but a

comparison of N sources at each level of P indicates that no interaction

between N and P was present so that differences between N sources were

relatively the same at each level of P Yields were increased about 60

more when SCU was applied than when urea was applied Yield increases

with AS were only about 72 of the increase obtained with urea these reshy

sults do not agree with the generally-reported superiority of AS as comshy

pared to urea as a source of N for rice

- 40 -

In 1973 experiments were conducted in Pakistan using both

Basmati-370 and IRRI-6 varieties of rice grown under conditions of

When all N was applied at puddlingintermittent flooding (table 19)

or 12 at puddling and 12 at panicle initiation both AS and SCU were

superior to urea with SCU tending to be the most efficient source

However when N was applied 12 at transplanting and 12 at panicle

initiation SCU was the poorest source of N This would indicate that

the release of N from SCU applied at these times is too slow for optimwn

plant growth

In another experiment in Pakistan in 1973 no differences

in the effectiveness of urea AS or SCU were noted in the yields of

continuously-flooded rice (table 20) Again these results are conshy

sistent with earlier results which indicate no superiority for SCU

when rice is continuously flooded

Nitrogen Studies--Maize

A series of three experiments were conducted by IITA in

armo-Nigeria in 1972-73 comparing AS urea SCU and

CAN (calcium

nium nitrate) as sources of N for maize (table 21) A significant

yield response was obtained for N at each location but no conaistent

differences were noted amaong sources These results are consistent

with results at other locations which have not shown that SCU is a

superior source of N for maize grown over a period of 3 to 4 months

Nitrogen--Wheat

The yields of wheat in Pakistan in 1969-70 (tables 22 and

23) show that yields with SCU) tended to be lower than those with ureaJ

although at one locction where sorghum was grown followilng wheat with

Table 19

Yields of Basmati-370 and IRRI-6 Rice at Punjab Agricultural Experiment Station in Pakistan in 1973 Under

Conditions of Intermittent Flooding

Rate Yield Source of N Time of Yield (Mtha) Increase of N B-370 IRRI-6 Application Basmati-370 IRRI-6 Average (Mtha)

0 0 - 21 353 287 -

SCU 90 150 At Puddling 325 545 435 148

Urea 90 150 At Puddling 309 500 405 118

AS 90 150 At Puddling 324 529 427 140

SCU 90 150 Puddling 372 572 472 185 Panicle Initiation

Urea 90 150 Puddling 335 502 419 132 Panicle Initiation

AS 90 150 Puddling 353 529 441 154 Panicle Initiation

SCU 90 150 After Transplanting 312 562 437 150 Panicle Initiation

Urea 90 150 After Transplanting 340 624 482 195 Panicle Initiation

AS 90 150 After Transplanting 349 583 466 179 Panicle Initiation

All plots received 45 lbs P205acre as single superphosphate

Relative Yield Increase ()

Source of N At Puddling Puddling Panicle Transplant h Panicle

Urea 100 100 100 AS 119 117 92 SCU 125 140 77

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-48

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obosomhu rocks 0entk catetas rth Unrtdo costrat frwt) to

ht tse balt s Owosiv as that to TwP it rocks WM bo

fmtbt alteruutiv to MSso gotastte to~ Ik lee used to

ThUAIAd

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a4 10 0410 SWUSSM yt$4e TOP wUd predWr A r~ftIf fl~W t

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amp4at r per Wforssota Mav two 64eed Wilk elikor It 44 of

P go Mi er 4A bg oftoP aon of tewmrowtni pboophals fwAh

It vwld be polotrd A Wevero wtht Is the jteld level that

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P11~0 pra~lpj prefer gre4r tuftlter for whlae

of hoaw ppltrstie Mhe to a dloedveaP for The PINSOO rocka

vkth m r II spotted 10 ftewil 4106Me tem

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mmfp MW phapa A (CI) sed graewletod pampAtlti arlolatod Pa

asowcs of P tof ttde ro The wreem proucts omre raGther

pemour~a ot P syag besmti andMi as elt ov so gpamwhr

iuipiqffhate(TS) low twseeo Is eftwiltve Is thet

W41 preeme wae oialain ire post-rItoi effriq to Stanlato the

pud6itt of Irto paddle Wee ofsdlseireplastiq

0 49 shy

lbs partially scldiaatede grawilated Ml prodlucts Vere isshy

toiwdiats in 5tftOvttWS54 betwee wroiPi ad TVP NotV5Ymf to

me coo were they mere twoe $a a etfective ao TIP 00 sipifleast

LVSUMI5 at0 efecto wore toun tor thee produteo Timely dtIampWde

FR (-t00 mmoh) Uia amp~rally oar affective than Owe gra8448r FOampprodt

featal twos o 6 aotetire s I

Nowvero it to felt that sfortber field euprtet vth

hese interials Amd ether typs of grometatodl Wter nre wrrautad

hater ceeuwodh that they have me areec poteatlal toi additoG

e tate wAne the sectte as OtawrI sed bovoloen turther

euperimeste vth few reck pboophar s0d with reck pbophat treated

to sehesa citrata selmtliy or to ha csaducted

Metbir sertes of tbme enprtaeats wae c~edtmcted by IITA

to Ut~rta copal TVP AOP APP aed it at see tecastisix (table 14)

No dot lalt sewseltles teh draw tree thee results simouely em pear to tlvdl bsww they do stwgpt tbat forthew work with

MR to werramid so tbme sels

Table 24

LttcttF Swce MaPlate 06 ieldot IM AWaia CoelsANS at IITA (Ugboda ad Apoin ail sorit) aid at Ike (AUaba s5i series)

1973

Plate ot IP Apinu 5 poundebods A1ab

Ocrol 0 Z94 419 M)

Tr ipl ruprphite 20 349 3799378

Triple vepput 40 M09 410$

Triple 6wp~~b1 4271 4344 42250

Ammotw-ritpophW to 4201 4124 4040

Amosim-rdop~phlt 40 4270 4106 4231

AM tuo-polpephats 20 404 4244 3794

~eai~mpelppepbuI 400)49 4094

Cee m-pbpbt to- 59

momee eph lto 0 4192

LSO (0 0$) 29 1025

Th WPII

- 51 shy

101Y114 tpeM-fI PEP~tbRP YO

1 ~ ~ gmw 1pc~biofl- 9 Kla4v4h

Upia U04 Copfind am Crehout Stet Rpano at (Ia4

rico t IF t rume6 orth~ Caralto phoophale rocl QAR) vaUN pqU41 to

roopon from cmonetrat4 gsporphophai (CIP) who ort$o4 oil k

was 45j itwas tafertor vb protioo4 oil p war OS Ib 4iffer~c

in rtc reepos to X cod14 oo bo ttrit4 4 4 hvsciag of boil p

~ Pt o r11221 0 tP

c theto the rhimecyllndor of rico tots par to)14M4i1 roeoi~t

ed oil emd PA prior to tho ont of an~robi4 cMioe AA~ oIifoshy

nAte bYpot t taet~d tO fC4sin t~r 4PWden0 Of f Ot(tivshy

ofOWailiJtyno o prefla4 all Put that 4t01etoo 14 tvsIk

of the Ott to prvvld a 014for C4m0 44 mI 1 o4sf

EfftC ftPet141on AIAM-0 V f401td 4 4iv 440 Mtft

Aa torfat VampP f4MWfCi4W04wt0amp to 4eturWlI Ot(Wel~drIC ft

Ot f tM6 the flooded Ott 00 14 04019I Pft0uAw Of gAr~s~lr

pkS$t M40b MP) Tw P1101 Piset Prodwie W-e 10M0di Wr04

(10-1) emW 0aretilp ddw01at4 P WAA firom Rrth M~flRU414~$

wee cowiared with fie Md reWim 44104 proo~fo) foruk oith laWItter

I v te-PR P OW1004 4 4 O Wf ottil OW ellt Oo

Oveiel1 the 40tt dmcruie to effetotww Wtollowui Co fme

PR tpaUIB1I ldoltmo PR (pamwlatr) offr~- ArmeuM) 0 orwi

- 52 -

Effect of N Sourc6 and Water Management on Response of Rice

toe Zn- M Giordano J J Mortvedt OP Engelstad and Greenhouse

Staff Several rotes of CO(14H2)2 and (H )2So4 vith or without ZnO

wore applied to flooded and nonflooded Crowley oil (limed to pH 75)

to determine response of Bluebelle rice to Zn Yields with both N

sources veotrgreator on flooded then on nonflooded soil In the abshy

ence of applied Zn total dry matter production vith CO(NH2)2 was

slightly lower than with (NH)2S04 on flooded soil and considerably

lover on nonflooded soil Concentration of Zn wan higher in straw and

grain of plants roun on flooded than on nonflooded soil Although

concentration of P was unaffected by N source or Zn rate there was

som indication that cranslocation of P from straw to grain may be

depressed in nouflooded rice Concentration of N was lower in straw

grown on flooded than on nonflooded soil due to apparent dilution

thereas both X sources resulted in similar N concentrations in straw

at all rates of N application the N concentration in grain increased

with 0 rAse

feSpongi gf(SM to Chjorospodiostte and Related P Sources--

Si Allen and Greonhoue Staff A greenhouse pot experiment was

couct44d with corn Brown on Hountview silt loam to compare the ofshy

fectlivees of chlorospodiosito (Chlor-l) with concentrated supershy

phosphate (CP) Thomas slag and North Carolina phosphate rock (NC-PR)

Oil-prillad urea-phophato rock (UPI) FeA1JMP 20 7 and monomthyl

phosphate were included in the experiment Based on yield of forage and

uptake of P by tvo crops each of 6-weeks duration the following conshy

stui were dravat

I Chlor-1 was slightly loss effective than CSI Thomas slaS or NC-PR

from which Chlor-l wae prepared

- 53 shy

2 Granular UPR was a poor source of P its effectiveness was greatly

increased by reducing the particle size to -35mesh

3 FeAlNH4P207 was unavailable to the crop

4 Monomethyl phosphate was equivalent toor slightly more effective-

than CSP

Research Indirectly Related to TVA-AID Project

Response of Several Rice Varieties to Zn in Moist or Flooded

Soil--P M Giordano J J Mortvedt and Greenhouse Several varieties

of rice from Mexico and the Dominican Republic currently under investishy

gation in Puerto Rico for adaptation to upland culture were compared with

some established United States varieties with regard to Zn response on

moist and flooded Crowley sil (pH 75) Chontalpa (Mexico) Bluebelle

(Texas) and Starbonnet (Arkansas) were most responsive to applied Zn

Juma (Dominican Republic) intermediate and Sinaloa (Mexico) and Calrose

(California) were the least responsive The Sinaloa varieties (Mexico)

appeared to be best adapted to non-flooded conditions whereas Chontalpa

and Calrose were poorest Concentrations of Zn generally were higher in

plants grown on flooded than moist soil

Pattern of Growth and Zinc Accumulation by Rice--P M Giordano

J J Mortvedt and Greenhouse Staff Rice plants were harvested at weekly

intervals from shortly after emergence through maturity The objective

was to determine the rate of growth and Zn uptake by a Zn responsive varshy

iety (Bluebelle) and a less Zn-responsive variety (Calrose) in the presence

or absence of Zn applied to Crowley sil (pHl 75) Dry matter production

of Calrose was linear with time of growth and of a similar magnitude until

heading with or without applied Zn Bluebelle followed a similar pattern

where Zn was applied However in the absence of applied Zn foliage yield

was reduced markedly

-54

Uptake of Zn was similar for both varieties whenZn was

applied Dry matter production and Zn uptake by the two varieties

also were comparable when Zn was applied However yield of Calrose

was much higher than that of Bluebelle in the absence of applied Zn

while Zn uptake was only slightly higher This suggests that the lesshy

ser responsiveness of Calrose to Zn may be due to more efficient utilishy

zation of Zn There was no indication of a greater demand for Zn durshy

ing reproduction in either variety as was suggested in earlier greenshy

house experiments

Response of Upland Rice to P and Zn--P M Giordano J J

Mortvedt and Greenhouse Staff Several rates of P and Zn were applied

to Crowley sil (limed to pH 75) in factorial combination to determine

whether differences in rice growth under flooded and nonflooded soil

conditions are related to plant nutrition Although straw yields were

slightly higher in nonflooded rice receiving adequate P and Zn grain

yields were higher in the flooded crop increased rates of F andor Zn

did not result in equal yields Except in the highest Zn rate (75 mg)

concentrations of Zn in both straw and grain were higher with flooding

Concentration of P increased with rate of applied P and was higher in

the grain or flooded than upland rice at a comparable P rate In conshy

trast concentrations of N were lower with flooding due in part to dilshy

ution from increased growth

Rice Response to N and P in Flooded and Unflooded Cultures--

G L Terman S E Allen and Greenhouse-Analytical Staff Rates of

N from 250 to 2000 ntpot and P from 0 to 1000 mtpot were applied for

Nato rice grown on Mountview sil and Sango sicl (625 kg of soil per

pot) Market yield response to N and P was obtained Yields of straw

- 55 shy

total yields N uptake and N recovery were higher on unflooded than

on flooded soil cultures Grain yields however were slightly higher

with flooding These results indicate that with adequate applied

nutrients especially of N rice yields without flooding can approach

or even equal those under flooding

Uptake of N P Ca Mg and Zn increased with yield response

to N and P while K uptake decreased on the Mountview soil Concentrations

of N and P increased with applied N and P respectively while concentrations

of other nutrients were diluted in most situations with yield response to N

or P

Results from this experiment show that amouats of N applied in

previous pot experiments for rice have been much too low especially if the

crop was grown to maturity

Response of Corn to S and N i UUASand Urea-S--S E Allen

and Greenhouse Staff Three greenhouse pot experiments were conducted to

measure response to S and N in ulfur coated urea (SCU) urea amonium

sulfate (UAS) and urea -S as well as estimate N losses from surface apshy

plied N sources

In Experiment 260 less than 20 of the S mixed with the soil

was recovered from SCU or urea-S granules by two crops of corn as comshy

pared to 45 or 80 from flowers of S or Na2SO 4 CLop response followed

a similar pattern

In Experiment 260-A N sources were surface applied and alshy

lowed to dry for two weeks before incorporation Into the soil and plantshy

ing Recovery of N by two crops of corn was 77-82 for AN an compared

to 37-70 for urea UAS urea-S and ICU Thus n this experiment loss

of N from urea did not appear to be re~dcud by light S-coatlngn or by Inshy

corporating S or AS in the granules

-S -

I xbprZnSlt a Wtch aU Meyto 0-Ai Wt f9r

higher reermo teOrtOrs cOM reSpWNO i r0100 Of N w

not oaisteontly related to sewe ot N In edl tust 0 ioltiUe Lim

lo in VMuwpped evlmtUTS 48 merind by seirest nte appresOehe

501 for uroa as cwarod to 210 for urea peepha

Rus- or Upse to LoAmIl34I a AriMed bI Earl U

MW NOWlsIIsIr-4 L Toman 5 1 Alln and eesese StNf rio

row on Sawg did (0 tpot) We 1l0l0 Ws feritiud vith 05is

of Npot mixod with the 6011 as aureCA NiAO) 1 Age god At Ures

was also itcluded at rtt t 05 10 end 15 of Upee Theas trealshy

onto were followed 4 wpdrsetago of U s AN wre 4C 10o or at I3n

Weeks toulin up to IS pot

A soil application of 10 pot rosulvod to the maim yield

at 4 weeks Tio4 sad percont prottis t intre raite tncreased rftishy

linearly with U applictalien IeseeItally all at the m iNd wit

the moil w domitrifted after flooding Grail end straw Ilelds vere

highly correlatod with tiliriag and vlh ubers of gralm arl

The results Widicat that 0$ to 10 a of Upot as orea or

NN bsuld be sied with the oil to stilate tiilrir with adshy

ditional 0 topireased later to increase grain lIds mad protia cmshy

tout

DIVISION 54- FERTILIZER TECHNOLOGY AND USE

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-02

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e W d inSIWfh sil $ad doke IaefitV twoer) 1 Te to theo owie effu so booJ imik WOi 100 N

-d

Is re4aled uIwq~e~w Aueee atofurnw di Capsnm ptopeatls is a oommm eiws to 100 tom of 04404man d CtdUW 4M Anw K~a do Aamp apowee WPUaN powu eel H pae iaaa thAi SCUI isWW owr hmem ISsuppl N to the li ieee F A IM1 Nampa Obo~amie m

41MB ~ ~ m ~ ~0 0-- 0 140 The ffsemn of food Nn else9~e(Ud~ ~ ~ ~~ WooksaS eAWw pjed of ho~raw of IU effadam vfdva oft xhj0I 13iAl

DIVISION 8-9-SOIL MINERALOGY

Amorphomw CeetIup en XmWra Ssrfmls

L C koits Am~ 0 tmmkaAf

ommp A faieiaAMTRACT skiwe lo nW ampM sm wi4h

Walo by a onMm I dmivid hseidm6Wlk W~edesie s

peuiieles as is s e wpwigstee eded his S -em -om 0641 h4 hisW1mWOWb~ bfem peess Wimm kv Iee

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PWWWW t HW f hea~I~~~~~a 0th

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d m M 0bmSaImu M-1 ofM6 h Intun to 7I

aiba maush WAesshwn~u9dSg a osusLwpI ~ v m

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of~U -a~ mo uNo

0401ts of 40

A e mun5d m i vvamp sa s ow bftIS i sa omdIs a w

edi1 hswopmo an ag am Iw anom erlwaPASneooie bnwoM po

o ~ do=lr 3s fluACWoSM Owaa VolM Ain b 400b adW g o as amob ofrMOWS A oo eWmaa ow $wofdi60 ow - ema

-v K Vcon l ap ad md ld KU lbs PoabumwA od w to domi a bembe 0b lt $014 i ampmomONo

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of of~phaow tw bmsdf toamplboe

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ov4mnk wsi 9 Mxfeu~i am emwm ismi0wmd fq W No ~~ - f mug Aitowe eutlkowbmTV is

amppowftdmi TiM 0 Tie OAA mo p)a Mwomoi dOn4m A)w

MW 0 604 0M mm yaM 01MWOfdi to tA0 M OOAW uinw OSOb

ap is~e I the ampo A A Mwof ~Do toit op aenu w~ifiOimem~ MAN ampW)

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~ -0

65

0IL CL OC AMXR PROC VOL 38 1974

)aT1 S4I104 ow Lusanll Tawng isa tall Thai variety known for beingIwo nonshyi s s ) sensitive to photoperiod A split-plot design was used in

S e e these euperimeots with 4 rates of P (I1 22 44 and 88t i V IV k of Pha) applied a main plot treatments and with the OF It sourMes of P as subplot treatments There were two checkS plots in each rmplicate The extra check plot was included to permit the application of fresh TSP standard Jor the

It- ti 06 + i bull fa succeeding crop the p-4me of bi was to permit accurate d awrnwal of the mdual effectiveness of the phosphate

ftinSUbI rock The P fertilioers were broadcast on the mud andthen Worporald In the soil during the last harrowing At

whM N both On ACS indx ampM time of transplanting Immediately before the last harrow61t (4j 5 4 01 P s 3Mm o Vallonal in con n 100 kgha of N as ammonium sulfate and 33 kghaWO Of Spews ampm lIW thaabe rocks do ACS indes of K as polium chloride were applied A total of 40 wa in prepw O do ctih k otent kha of N a ammoniunt sulfate was applied later in twoir P The hew oNed amp wM W for 5 of gw topdrossingp with about 5cm depth of water on the plotsvV I aiOMveffeOctveee Three to six ldayold selings pr hillwW the ACS idex were planted00OWW wia Oft fo an c irNk I p Coen 20 by 20 cm part in straight rows Hand weeding was used

and insecticide were applied for Insect control Grain yieldw was masared by sampling 5 ml of each plot excluding border rows The date of heading in each treatment and theUNiN d pbM W Weks rin tOW USA UMe In Tale yed componnts at hafvel were also recorded

I filM rsperMS esOM kdwdua 1 t ab The average yields of ough (unhulled) rice for botha 84 OW O 8uo 4 Thala TM was a locations are ploutel in PIS 3 for the first crop (1969 wet

owou thRM seaso0) The Veamps yield response was obtained at Klonge (s) W lDtO t Of dMa of1tw W d l R Luang however a 4ute satisfactory yield response was

~Mk ^d TVA UJSD ad Kd UnIveS obtalned to applied P at Bangkhen as wellXUe LaM e R qwrw Ims The sod was do Relative aponomlAe effectiveness values were calculated

VOW (a ksA w edmwL t Poesesm h Vy for these data and am presented In Table 3 The valuesdAY buo if dIe ouh ne Pee wtk a Mlak vow 1009 for th first crop are plotled against ACS index in Fig 41 This Im M i6ti l 4bNd IO a0 O mkarnk for both locatio r relationship was linear for the

11400 ThCpH 0( lb pW IW 01 th UpeiaW so Sanodion location and curtiltnear for KIng Luang The was u i 4A sksamp lMaor nrusio model amparounted for 81 of theAmO$MI Aw jAAsue Swim T1 Snh Wd variation In the AE valu for Bantkhen a square root

Mems a Iw iv fern alh$ sedm haowg dayNW W t he plAL At tdo M tM aso W s as ctminued throufh eltaM t Ofpof -le lse wo am P OeNI VeOpls 1o ealluae tI lon4erm MIdual Offccls

A on W isset i a wse to hsh eapeel of these ooihss t ocks The baagkhon experimnent was letmiaI1DlVemisthis is a w hulu Lo g Tasug ia iasael aft - Msd residual Ves will be pr-Om crok TheseTwod esewm

SWWo

A

lP~U~7 ISIIPe1iuIWN e bsedisssin ian ghth siaoelalbe

984 0 6 O O - M s -s fWPas 11eSft W d Uo al a o

o

S4l~ lIIII I~l I 1f fl

( +

+ + + m + ++++-

++ +(++ + ++++ + ++ ++

- 66 -

ENOIMLSTAD ET AL RESPONSE BY FLOODED RICE TO PHOSPHATE ROCKS VARYING IN CITRATE SOLUBILITY

I I I I j0 I I

BANOKHEN BANGKHEN

pH 56 6 - 0o

TSP

NC

5~ ~ ~ L o 4 - -shy

4 ] - --------shy04

6S

|0 III 2 44 8r 66

I I I

a 1KLONG LUANG

pH 46 z KLONG LUANG

TSP Sc2 NCFL(N)

5 FLIC) J0 TU

oshy

4 ~40shy

3 bull eM0

I - I I I I I

0 II 22 44 88 0 5 10 15 20 IP APPLIED KO HA ABSOLUTE CITRAE SOLUBIITY INDEX

Fig 3-Yield of rough rice at Klong Luang and Bangkhen Rice Fig 4-Relative agronon effectiveness () of P sources ploz-Experiment Stations Thalmand as affected by rate and Source ted against citrate solubity Index for both Thailand field ex

of P applied (crop 1) periment (first crop only)

regression model accounted for 97 of the variation in sumably resulted from crop uptake and reaction with the RAE values at the Klong Luang location soil to form less soluble products Such effects may have

These experiments were continued during the dry season been more important at the lower rates since the two TSP of early 1970 to ascertain the residual effectiveness of the curyes converged at the highest rate of application various sources applied to the first crop No new P was These data from KIong Luang indicate that (i) residual applied except for the fresh TSP standard mentioned effects of all rocks except Mlcwuri were substantial (ii) above rhe experiment otherwise was conducted in a man the relationship between relative agronornic effectiveness ner similar to that followed in the first crop of the phosphate rocks and citrate solubility levels was

The response to both freshly applied ad residual P was largely obscured and (iii) the general superiority of TSP marked at the Klong Luang location and marginal at over phosphate rock in terms of effectiveiss persisted Bangkhen In fact at the latter location the response was through the second crop so small that little can be said regarding residual effectiveshyness The yield data from crop 2 at the Klong Luang DISCUSSION experiment are plotted in Fig 5 Greenhouse and field data presented in this paper show

Relative agronomic effectiveness values (Table 3) were clearly that there are substantial differences among phosshycalculated for the Klong Luang data using both the residual and freshly applied TSP as standards It is of Interest to note that the superiority of TSP over the phosphbte rocks Table 3-Relative agronomic effective values for field experishyments in Thailand persisted through the second crop The main difference in KlowlZmlnql~the residual effects is that with the exception of the MIs- s Crop 1 Crop 21 Crop 1-shysouri rock Ihe marked relationship between citratr-soluble WoiCarolina yl 59 76

phosphate rocks and RAE had largely rds norh) a 64P conltct of th Florida (eqlral is 6969 6

disapipeared In this acidic soil (pHi 46) P would by this I14o 69 63 40 ToonesS 31 65

limo be supplied by Intermediate reaction products In addl Missou 0 o lion to residues of the initial spatlte Ts P o 2 o 0

The TSP applied to the first crop declliv-d slightly In campIafcmWataesr e id ofeuhuloefor 22MA rates of PtColeouattd as aba u tlte td18 kS ratesp dlverage yield tM868 to 22 44

effectiveness relative to the freshly applied ISP This pre- of d s4

A

4

- 67 shy

-SOIL SCL SOC AMER I

KLONG LUANG CROP 2

Si 3

eN

TAPPLIEDKGHA

Fig 5-The residual effectiveness ovarious P sources for crop s compared with freshly applied TSP Klong Luang Rice

Experiment Station Thailand

phate rocks in terms of agronomic effectiveness for flooded

rice Further these differences can be predicted by means of citrate solubility or by the ACS index It appears that

the latter is more appropriate where the content of apatite varies among phospiate rocks The most soluble phosphate rocks approached but did not actually equal TSP in limit-iuig (maximum) yield in these experiments regardless of rate applied This agrees with the results of Ensminger Pearson and Armiger (4) One needs to consider the defi-nite posribility of same yield loss in zhoosing a phosphate

rock over TSP such yield losses must be weighed against the lower price of phosphate rock The explanation for such iosses may involve concentration of soluble P in the soil Khasawneh and Copeland (6) suggest that the growth rate of crop plants is a function of P concentration that can be maintained in the soil solution If P concentration is limiting or inadequate becawe of a lower dissolution rate of phosphate rock the growth iate ard uiiimate yield will be diminished accordingly

The RAE values bascd on yield increases reflect the agronomi effectiveness of these various sources relacve

to the TSP standard however these nould be supple-

mented by an economic analysis before rational choice can

be made The following calculations will provide an estimate of

the rclativ ecooomic effectiveness(REE)

Y t Ps aXpatREE -- 100

vahtercks t sphate or e b i- eor

Price of TSPkg fo

be Price of PRkg P

PROC VOL 38 1974 leO

90r

Wsoshy

0

60-LUSEPHOSPHATE ROCK

00 10 20

PTP PR

Fig 6-Relationship between relaZive effectiveness values (RAE) and the price ratios between TSP and phosphate rock Such a figure can be used in making a choice between these

sources

If REE exceeds 100 in this calculation the phosphate rock would be preferable to TSP

The REE calcuktaaa wre used in preparing an indifshyference curve (Fig 6) wherein RAE values are plotted

against PTsPPpR ratios The cu~rve itself connects those points at which REE equals 100 When exactly on the curve it makes no real economic difference what source is chosen After choosing a suitable price ratio one can then project upward from that ratio knowing the RAI

value (or estimating it from such data as shown in Fig 4 using citrate-soluble P content) one can then choose the source on the basis of both agronomic and economic conshysiderations For example if the price ratio is 25 and the RAE value of the phosphaite rock is greater than 40 the rock phosphate in question would be used However if the RAE value was less than 40 TSP would be a better choice There are indications that if the P in the more soluble phosphate ro~cks (North Carolina north Florida central Forida) is less than half as expensivz as that in TSP these rocks would be feasible altereaives to TSP on soils similar

to thoseused in Thailand This analysis does not take into account the possibility

of lower yields from use of phosphate rock In addition only a portion of the various yield response curves was used in this anlysis ie up to 22 kgha Beyond this

rate yield response was much less pronounced it could be argued that at less than maximum yields TSP would produce a certain yield at lower rates of P than would phosshy

pow ofrock This would especially be true for rates applioa example at Klong Luang 5500 kg of

rice pcr iectare could have been produced with either Ii kg of P as TSP or 44 kg of P as son of the more reacshy

tire phosphate rocks It should be pointed ot however

- 68 shy

(IIKIS amp YOUN( ARIFICIAL WEATIIERING OF OXIDIZED p[ll- IV

that this is the yield level that would show the widest difference such is the advantage of hindsight

Farmers generally prefer granular fertilizers for machine

or hand application This is a disadvantage for the phos-phate rocks which are normally arplied in finely divided form Recently experimental quantities of granular urea-

phosphate rock mixtures have been made by TVA Results of trials with these fertilizers will be reported elsewhere

LITERATURE CITED

1 Armiger W H and Maurice- Fried 1957 The plantavailability of various sources of phosphate rock Soil Sci Soc Amer Proc 21183-188

2 Bengston G W E C Sample and S E Allen 1974 Re-sponso of slash pine seedlings to P sGurces of varying ci-trato solubility Plant Soil (In press)

3 Caro JIt and W Hill 1956 Chard eristics and fer tilizcr value of phosphate rock from different fields J Agr Food Chem 4684-687

4 Ensminger I E R W Peirson and W II Atmiger1967 Effectivencs of rock phosphate as a source of phosshyphurus for plants US Dep Agr ARS Bull 4112S

5 Engelstad 0 P J G Getsinger anid I J Stangel 1972 Tailoring of fertiliers for rice cnnece Valley Author ftyNational Fertilicr Developmnent Center Hull Y-52

6 Khasawnch F E and Jane P Copcland 1971 (otton root growth and uptake of nutrievos relation oif phosph

rus uptake to quantity intensity and buffering capacit) Soil Sci Soc Amer Proc 37250-254

7 Lehr JR and G H McClellan 1972 A revised lIbora tory reactivity scale for evaljativg phosphate rocks for direct application Tennessee Valley Authcrity National Fertilizer Development Center lull Y-43

H Terman G L S EAllen and 0 P Engelstad 1970 Response by paddy cice to ratcs and suurces of appliedphosphorus Agron J63390-394

DIVISION S-9-SOIL MINERALOGY

Artificial Weathering of Oxidized Biotite IV The Inhibitory Effect of Potassium on Dissolution llate

R JGILKES AND R C YOUNG2

ABSTRACT

Rates of dissolution of oxidized biotites in OIM 001M ICI are severely depressed in the presence of IM KCI The amovnts of Al Mg Mn dissolved in the first eytraction are similir to those found without KCI however subsequent extractions remove these elements at 10-20 of the corresponding lICI rates This effect may be due to a decreased rate of vermiculite formation thereby reducing the effective basal area exposed to attack A decrease in dissolution rate with increasing ferric iron content was still apparent in the presence of IM KCI

Additional Index Words X-ray diffraction infrared aborp-

N EARLIER papers of this series the tole of biotite in soils

as a source of both macro and micronutrient elements

has been discussed ((Gilkes Young and Quirk 1972 1973ab) Experiments in artificial weathering uiing as va-

riety of extractants were undertaken to determiie the inlu-

ence of oxidation of octahedrally coordinated iron on the bull release of structural cations to solution The results of this

work demonstated that biotite behaves anomalously with respect to the other common ferromagnesian minerals found in soils Oxidation leads to the development of a high degree of resistance to cation exchange and dissolution Several authors have coiwludcd that decreased rates of K

Contribution from the Dep of Soi Science and Plant Nutri-tion Institute of Agriculture Univ of Western Australia Ned-lands 6009 Western Australia Received 29 Sept 1973 Ap-proved 8 Jan 1974

2 Senior Lecturer in Soil Science and Research Officer respeclively

replacement in electrolytes shown by oxidized biotites are

a result of the inclination of structural hydroxyl adjacent to newly created trivalent iron or vacant octahedral cation sites (Robert and Pedro 1959 Barshad and Kishk 1968) Gilkes et al (1973b) suggested that decreased rates of disshysolution of oxidized biotite in 0001 0t)l 0Af CI may also be due to the presence of inclined hydroxyl In this case a smaller surface area external and exposed intershylayer may be available for attack if K replacement by hyshydrogen ions occurs at a slower rate in oxidized biotites

Gastuche (1963) has shown that significant dissolution ofthe (IIM) biotile face may occur and it is easily demonshystrated that the proportion of exposed (001M) face in weathering biotites depends on the percentage K replaced

Rausell-Colom ct al (1965) have shown that hydrogen ions act in an identical fashion to metal cations in K exshy

change from micas In particular exchange c-f K by hydroshy

gen ions will be terminated or greatly reduced by high levels of K in solution Thus if dissolution of oxidized biotite by

acids is carried out at sufficiently high K levels to prevent vermiculization any differences in dissolution rate that may occur cannot simply be ascribed to differences in rates of K replacement The following results were obtained from such an experiment which unlike the experiment described in Parts I and II (Gilkes et al 1973ab) does not attempt to simulate natuiral - conditions

MATERIAILS AN) M HIiODS Further subsamples of the less than 0 hiotites used in K

excherandbaid disoo tu es (G iles e9n K exchange and acid dissolution studies (Gilkes et al1973ab) were used in these experiments Preparation of sequentiallyoxidized biotites without intermediate vermiculite formation is

Page 12: I70 - United States Agency for International Developmentto ascertan, but tgl.eetad, 1, L,. ("Tailoring of Pertiltiters for ice,'" TVA ulletin Y-52) states that the staft of IOi has

-9-

SCOPE OF WORK

This project integrates agronomic economic and engineering

expertise into a single team in order to develop improved fertilizers

for a wide range of crops and soils in developing countries Considershy

able emphasis is given during the first eighteen months to collecting

the data needed to complete the evaluation of sulfur-coated urea and

ground rock phosphate for lowland rice Both materials then are

scheduled for demonstrations during the latter part of the project in

order to educate extension workers and farmers and to attract the fershy

tilizer industry into commercial production Considerable emphasis is

given to the economic evaluation of a total production-marketing-use

system for each material in contrast to alternative nutrient sources

The probability of commercial production of SCU and ground

rock phosphate can be enhanced by expanding their use to additional

crops and soils Thus the project is expanded in scope as compared

to the previous project on tailoring of fertilizers for rice in order

to test these materials on additional crops

The expanded work includes a major effort in screening and

testing new compounds and forms of fertilizers for various food crops

produced under tropical conditions Alt hough it if already known that

more effective andor lens expensive formn of nitrogen and phosphorus

are needed a literature survey will nerve an Lan additional guide to

important and presing fertilizer problems

-10-

Much of the work with fertilizers for both lowland rice and

upland crops will consist of field tests in Southeast Asia Africa and

Latin America Greenhouse and engineering studies will back up the field

research All field experiments are designed to provide at least an esshy

timate of costs and returns for each fertilizer tested

PROJECT PLANS FORFISCAL 1975

In this section the work for fiscal 1975 will be discussed

It should be remembered that the success of this project depends in a

large part upon maintaining sufficient flexibility so that work in inshy

dividual countries can be adapted to supplement and complement programs

already under way While guidelines and plans of work must be developed

so that the objectives of the project are clearly defined detailed

plans for specific countries or groups of countries must be developed

by consultation wth local cooperators

These plans will be discussed under the following three general

phases of the project

I Engineering and development

2 Agronomic testing and evaluation

3 Economic evaluations

Engineering and Development

Phosphate Rock

Methods have been proposed for relatively simple treatment of

phosphate rock (PR) to increase the availability of the phosphate to make

it more suitable for direct application to the soil These treatments

may be economically feasible in certain areas especially in view of the

current world fertilizer situation Considerable work has been done at

TVA studying means of altering PR and plans are being developed to inishy

tiate further developmental work and field testing of these materials durshy

ing fiscal 1975

- 12 -

Emphasis will be placed upon obtaining samples of phosphate

rock from deposits in developing countries and testing and improving

procedures for increasing their citrate solubility and tzius availabilshy

ity of the phosphorus From this laboratory screening process sevural

sources will be selected from which small amounts (50 to 100 pounds)

will be prepared for greenhouse and field experiments ou various soils

(as described under agronomic section)

From these results one or two locations (or countries) will

be selected for development of a pilot program to utilize local sources

of phosphate rock This program will involve production of the altered

PR and its agronomic evaluation and then educational programs with govshy

ernment and commercial representatives to introduce its use to the farmers

Sulfur-Coated Fertilizers

Some preliminary work has been done in which urea-potash mixshy

tures were coated with sulfur The 7-day release rates for the N and

K20 were 17 and 36 respectively from the coated product (22-0-11-30S

grade) This was the first effort in coating a compound fertilizer

with the new coating system

The widely differing release rates for the nutrients from

the coated compound product raise some interesting prospects for tailshy

oring the nutrient release rate of sulfur-coated products It might

be possible to cogranulate materials of varying water solubility and

sulfur-coat them to produce products with release rates that would apshy

proximate the timing of nutrient requirements of the crop The need

for this type of controlled-release product has been mentioned many

times by agronomists and may be especially applicable in multiple and

intercropping systems

inawa~~aUww e t of~ wdtop~s WRisr 4owt~

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catAt all PIed$ l low 40- 7~4a1 ff ~~44 F 0i 44$4

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~4 4 40~40 4 4CI mkfSw4Wh4 4wo~q~M

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~ i~P 4 4 wl 444 41A ~4 4~~E4166 I144 4t~w i14

4wamp444sa444 Awt4~ PA 4l $WX qO j44 at4 44w la44 C~ to~ v-40

io- s4aq4 4Wvs i 44t amp 4W 4-1ampo-v 4tI 44041 4 4~ kikamp3o 41

0)6 4-44 Wl 44 4444 OV l44 i444 441 0 4NW44bk 1V420A

~~O P44 44is ~ ~4 Aloti~S~3vool41~

0uI 4044~Me ~ ~ N4

4 jk-4il4 9-4 jio4 4 4I4wSj- ~ 4 sZiamp 44s)

) o~4w4 4444~S Is~4~4 ol I i A 4~ ~

4Ii I~4I4M$~ ~I

QOWIf XVif k

4004 004o4f U A

-w i4 I~~~

40440wo oow IVTA 44qol 644

4I~~~4J 00S4 4410 114w- A44W Wamp ~

6WViso4wb f vfpo w

w0OIA - i f iIS

f4 A 00 1 o4

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TOM I

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fiat Wm~~JL U Lem~ampuJampAJ Wat IO

~ 941~1 41 ~~~~j~~qt~~8IJ WtS dobu

Table 2

Mttct of 0 Sourco aampW $At On Upt~ks of 0 by Two Varitgtos of Paddy Rice

gr~a 1971

~ MMUampL~ ~L ~ nYLALI~ 11 lemall

I ie

W0 v slit III I) tQo9

KvN 1 17 111 1119

or 444M7

111a

i1$0N ~ It$ 121

1$

x IV ~404 tot Vsr 1 P1 41 w otv 1

- 24 shy

India--The results of four experiments conducted with flooded

transplanted rice in India by the All-India Coordinated Rice Project

Hyderabad are given in table 3 The response to N was excellent the

yield without N being only 41 of those obtained with basal applications

of N as uza With basal applications of SCU the yields were 20 higher

than with basal applications of urea and in the three experiments in

which urea applications were split yields with SCU were 18 higher than

yields with split applications of urea When comparing the average Nshy

response (kamp grainKg N) yields were increased 13 more by SCU than by

basal applications of urea

The data from one experiment with light irrigated rice in India

are given in table 4 yields were relatively low and differences between

N sources or method of application were not significant However yields

with SU tended to be higher than when all urea was applied at planting

but lower than when split applications of urea were applied Again yields

increased more than 13 more with SCU than with basal applications ofwere

ur

In tables 5 and 6 the yields of a short-duration transplanted

rice grown in irrigated light-textured soils at five locations in India

indicate that higher yields were obtained with SCU than with urea when apshy

plied as a basal application Yield increases due to basal N applications

were 502 greater with SCU than with urea However split applications of

resulted in yields equal to those obtained with basal applications ofurea

CU

The yields of direct-seeded upland rice grown at three locations

to India are given in table 7 and the relative yields in table 8 Yields

were low due to drought but good responses were nevertheless obtained for

- 25 -

Table 3

Effect of N Source and Time of Application on Yield of Paddy (Flooded) Rice in India 1972 (Summary of Reported Data from 4 Experiments)

Experimental Number Source Rate Method Yield Relative N-Response

and of of N of Yield Kg Grain

Season Nitrogen kgha Application mtha Kg N

- - - 196 34 -

Urea 120 Basal 573 100 314

11 Urea 120 80 + 40 611 107 345 Rabi SCU 120 Basal 713 124 430

12 - 0 - 202 30 -

Urea 125 Basal 682 100 384

Rabi Urea 125 35 + 20 + 35 + 35 633 95 344 SCU 125 Basal 781 115 463

13- 0 - 168 44

Urea 100 Basal 385 100 217

Kharif Urea 100 30 + 20 + 25 + 25 400 104 232 SCU 100 Basal 462 120 293

14 -

Urea -

125 -

Basal 355 650

55 100

-

236

Rabi SCU 125 Basal 781 120 341

-- 26 -

Table 4

Effect of N Source and Time of Application on Yield of Light Irrigated Rice in India 1972 (Summary of Reported Data From

One Experiment at Pattambi)

Experimental Number Source Rate Method Yield Relative N-Response

and of of N of Yield Kg Grain Season Nitrogen (kgha) Application (mtha) Q) Kg N

38 0 - 204 85 -Rabi Urea 120 Basal 241 100 308

Urea 120 60 + 0 + 30 + 30 267 ill 525 SCU 120 Basal 255 106 425

Table 5

Effect of N Source and Time of Application on Yields of Short-Duration Transplanted lice Variety Grown on Irrigated Light-Textured Soils at 5 Locations in India 1972

(Snmzarized From Reported Data)

Rate Grain Yields (MtHa) Source of N Method of N GrainI of N kgh Application Faizabod Karjat Mandva Pattabi laya Averaje X

- 291 266 211 19 340 260 -

Urea 100 Basal 386 407 361 285 482 3 124 Urea 100 50 + 25 + 25 399 430 434 334 6amp2 4A8 186

SCU 100 Basal 368 468 439 360 572 41 181

Table 6

Effect of I Source end Tlae of ApplIcattoo c RIstave Tle24 of a rt- rat1 T Lsd lice Vasrety Crin o Irrigated L41tshy1 at S Locitite mindi 1972

Rate ____________14_3

Source of X N~tbad of Of X An 1 tat14 1 acr X__T1 4v tatW ttva

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W Iotors Ftslanp tospg Irritd for Two thvk Afler flontiw wft rkwa~ Floo4d 191)

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- 38 -

Table 18

Yild of aemati-370 Rice at Punjab Agricultural Research

Institute in Pakistan in 1969-70 Grown Under

Couditions of Intermittent Flooding

Pate of application

=IL

o 0 67 67 100 100 67 67

100 100 67 67 200 100

Average for Sources

Ntha

AS 260 gres 279

320

Source f5

-

AS AS Ura Urea SCU SCU

Yield

Relative

93 100 115

(M)O

Yield

Increase Yield Due to N

(Ktlha) (mtha)

-212 245 033 274 062 260 048 297 085 315 103 325 112

Yield Increase

Relative

72048 067 100 108 161

(2)

- 39 shy

Short-statured high yielding rice varieties grown extenshy

sively in northern Peru require extremely high rates of conventional

N sources to achieve maximum yields The recovery of applied N is

extremely low due to the use of intermittent flooding This water

management system results in heavy N losses even with properly timed

split applications In search of simpler and more effective methods

of N management eight field experiments were conducted in the region

to evaluate sulfur-coated urea (SCU) an experimental slow-release N

source supplied by the Tennessee Valley Authority Rice yields were

increased an average of 59 more by pretransplant-incorporated SCU than

by urea or ammonium sulfate applied in the same manner SCU produced

excessive vegetative growth which resulted in yield reductions at high

N rates

Regardless of an assumed 48-higher unit N cost in SCU the

overall benefits of pretransplant-incorporated applications of SCU

were favorable since there was a decrease of 40 in the optimum rate

of N and the need for precise timing of application was eliminated

Pakistan--In Pakistan basal applications of AS urea and

SCU to rice grown under conditions of intermittent flooding in 1969-70

(table 18) indicate that SCU is a superior source of N as compared to

urea or AS when all N is applied at or before planting The data also

indicate that a yield response was obtained for P applications but a

comparison of N sources at each level of P indicates that no interaction

between N and P was present so that differences between N sources were

relatively the same at each level of P Yields were increased about 60

more when SCU was applied than when urea was applied Yield increases

with AS were only about 72 of the increase obtained with urea these reshy

sults do not agree with the generally-reported superiority of AS as comshy

pared to urea as a source of N for rice

- 40 -

In 1973 experiments were conducted in Pakistan using both

Basmati-370 and IRRI-6 varieties of rice grown under conditions of

When all N was applied at puddlingintermittent flooding (table 19)

or 12 at puddling and 12 at panicle initiation both AS and SCU were

superior to urea with SCU tending to be the most efficient source

However when N was applied 12 at transplanting and 12 at panicle

initiation SCU was the poorest source of N This would indicate that

the release of N from SCU applied at these times is too slow for optimwn

plant growth

In another experiment in Pakistan in 1973 no differences

in the effectiveness of urea AS or SCU were noted in the yields of

continuously-flooded rice (table 20) Again these results are conshy

sistent with earlier results which indicate no superiority for SCU

when rice is continuously flooded

Nitrogen Studies--Maize

A series of three experiments were conducted by IITA in

armo-Nigeria in 1972-73 comparing AS urea SCU and

CAN (calcium

nium nitrate) as sources of N for maize (table 21) A significant

yield response was obtained for N at each location but no conaistent

differences were noted amaong sources These results are consistent

with results at other locations which have not shown that SCU is a

superior source of N for maize grown over a period of 3 to 4 months

Nitrogen--Wheat

The yields of wheat in Pakistan in 1969-70 (tables 22 and

23) show that yields with SCU) tended to be lower than those with ureaJ

although at one locction where sorghum was grown followilng wheat with

Table 19

Yields of Basmati-370 and IRRI-6 Rice at Punjab Agricultural Experiment Station in Pakistan in 1973 Under

Conditions of Intermittent Flooding

Rate Yield Source of N Time of Yield (Mtha) Increase of N B-370 IRRI-6 Application Basmati-370 IRRI-6 Average (Mtha)

0 0 - 21 353 287 -

SCU 90 150 At Puddling 325 545 435 148

Urea 90 150 At Puddling 309 500 405 118

AS 90 150 At Puddling 324 529 427 140

SCU 90 150 Puddling 372 572 472 185 Panicle Initiation

Urea 90 150 Puddling 335 502 419 132 Panicle Initiation

AS 90 150 Puddling 353 529 441 154 Panicle Initiation

SCU 90 150 After Transplanting 312 562 437 150 Panicle Initiation

Urea 90 150 After Transplanting 340 624 482 195 Panicle Initiation

AS 90 150 After Transplanting 349 583 466 179 Panicle Initiation

All plots received 45 lbs P205acre as single superphosphate

Relative Yield Increase ()

Source of N At Puddling Puddling Panicle Transplant h Panicle

Urea 100 100 100 AS 119 117 92 SCU 125 140 77

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-48

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pemour~a ot P syag besmti andMi as elt ov so gpamwhr

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pud6itt of Irto paddle Wee ofsdlseireplastiq

0 49 shy

lbs partially scldiaatede grawilated Ml prodlucts Vere isshy

toiwdiats in 5tftOvttWS54 betwee wroiPi ad TVP NotV5Ymf to

me coo were they mere twoe $a a etfective ao TIP 00 sipifleast

LVSUMI5 at0 efecto wore toun tor thee produteo Timely dtIampWde

FR (-t00 mmoh) Uia amp~rally oar affective than Owe gra8448r FOampprodt

featal twos o 6 aotetire s I

Nowvero it to felt that sfortber field euprtet vth

hese interials Amd ether typs of grometatodl Wter nre wrrautad

hater ceeuwodh that they have me areec poteatlal toi additoG

e tate wAne the sectte as OtawrI sed bovoloen turther

euperimeste vth few reck pboophar s0d with reck pbophat treated

to sehesa citrata selmtliy or to ha csaducted

Metbir sertes of tbme enprtaeats wae c~edtmcted by IITA

to Ut~rta copal TVP AOP APP aed it at see tecastisix (table 14)

No dot lalt sewseltles teh draw tree thee results simouely em pear to tlvdl bsww they do stwgpt tbat forthew work with

MR to werramid so tbme sels

Table 24

LttcttF Swce MaPlate 06 ieldot IM AWaia CoelsANS at IITA (Ugboda ad Apoin ail sorit) aid at Ike (AUaba s5i series)

1973

Plate ot IP Apinu 5 poundebods A1ab

Ocrol 0 Z94 419 M)

Tr ipl ruprphite 20 349 3799378

Triple vepput 40 M09 410$

Triple 6wp~~b1 4271 4344 42250

Ammotw-ritpophW to 4201 4124 4040

Amosim-rdop~phlt 40 4270 4106 4231

AM tuo-polpephats 20 404 4244 3794

~eai~mpelppepbuI 400)49 4094

Cee m-pbpbt to- 59

momee eph lto 0 4192

LSO (0 0$) 29 1025

Th WPII

- 51 shy

101Y114 tpeM-fI PEP~tbRP YO

1 ~ ~ gmw 1pc~biofl- 9 Kla4v4h

Upia U04 Copfind am Crehout Stet Rpano at (Ia4

rico t IF t rume6 orth~ Caralto phoophale rocl QAR) vaUN pqU41 to

roopon from cmonetrat4 gsporphophai (CIP) who ort$o4 oil k

was 45j itwas tafertor vb protioo4 oil p war OS Ib 4iffer~c

in rtc reepos to X cod14 oo bo ttrit4 4 4 hvsciag of boil p

~ Pt o r11221 0 tP

c theto the rhimecyllndor of rico tots par to)14M4i1 roeoi~t

ed oil emd PA prior to tho ont of an~robi4 cMioe AA~ oIifoshy

nAte bYpot t taet~d tO fC4sin t~r 4PWden0 Of f Ot(tivshy

ofOWailiJtyno o prefla4 all Put that 4t01etoo 14 tvsIk

of the Ott to prvvld a 014for C4m0 44 mI 1 o4sf

EfftC ftPet141on AIAM-0 V f401td 4 4iv 440 Mtft

Aa torfat VampP f4MWfCi4W04wt0amp to 4eturWlI Ot(Wel~drIC ft

Ot f tM6 the flooded Ott 00 14 04019I Pft0uAw Of gAr~s~lr

pkS$t M40b MP) Tw P1101 Piset Prodwie W-e 10M0di Wr04

(10-1) emW 0aretilp ddw01at4 P WAA firom Rrth M~flRU414~$

wee cowiared with fie Md reWim 44104 proo~fo) foruk oith laWItter

I v te-PR P OW1004 4 4 O Wf ottil OW ellt Oo

Oveiel1 the 40tt dmcruie to effetotww Wtollowui Co fme

PR tpaUIB1I ldoltmo PR (pamwlatr) offr~- ArmeuM) 0 orwi

- 52 -

Effect of N Sourc6 and Water Management on Response of Rice

toe Zn- M Giordano J J Mortvedt OP Engelstad and Greenhouse

Staff Several rotes of CO(14H2)2 and (H )2So4 vith or without ZnO

wore applied to flooded and nonflooded Crowley oil (limed to pH 75)

to determine response of Bluebelle rice to Zn Yields with both N

sources veotrgreator on flooded then on nonflooded soil In the abshy

ence of applied Zn total dry matter production vith CO(NH2)2 was

slightly lower than with (NH)2S04 on flooded soil and considerably

lover on nonflooded soil Concentration of Zn wan higher in straw and

grain of plants roun on flooded than on nonflooded soil Although

concentration of P was unaffected by N source or Zn rate there was

som indication that cranslocation of P from straw to grain may be

depressed in nouflooded rice Concentration of N was lower in straw

grown on flooded than on nonflooded soil due to apparent dilution

thereas both X sources resulted in similar N concentrations in straw

at all rates of N application the N concentration in grain increased

with 0 rAse

feSpongi gf(SM to Chjorospodiostte and Related P Sources--

Si Allen and Greonhoue Staff A greenhouse pot experiment was

couct44d with corn Brown on Hountview silt loam to compare the ofshy

fectlivees of chlorospodiosito (Chlor-l) with concentrated supershy

phosphate (CP) Thomas slag and North Carolina phosphate rock (NC-PR)

Oil-prillad urea-phophato rock (UPI) FeA1JMP 20 7 and monomthyl

phosphate were included in the experiment Based on yield of forage and

uptake of P by tvo crops each of 6-weeks duration the following conshy

stui were dravat

I Chlor-1 was slightly loss effective than CSI Thomas slaS or NC-PR

from which Chlor-l wae prepared

- 53 shy

2 Granular UPR was a poor source of P its effectiveness was greatly

increased by reducing the particle size to -35mesh

3 FeAlNH4P207 was unavailable to the crop

4 Monomethyl phosphate was equivalent toor slightly more effective-

than CSP

Research Indirectly Related to TVA-AID Project

Response of Several Rice Varieties to Zn in Moist or Flooded

Soil--P M Giordano J J Mortvedt and Greenhouse Several varieties

of rice from Mexico and the Dominican Republic currently under investishy

gation in Puerto Rico for adaptation to upland culture were compared with

some established United States varieties with regard to Zn response on

moist and flooded Crowley sil (pH 75) Chontalpa (Mexico) Bluebelle

(Texas) and Starbonnet (Arkansas) were most responsive to applied Zn

Juma (Dominican Republic) intermediate and Sinaloa (Mexico) and Calrose

(California) were the least responsive The Sinaloa varieties (Mexico)

appeared to be best adapted to non-flooded conditions whereas Chontalpa

and Calrose were poorest Concentrations of Zn generally were higher in

plants grown on flooded than moist soil

Pattern of Growth and Zinc Accumulation by Rice--P M Giordano

J J Mortvedt and Greenhouse Staff Rice plants were harvested at weekly

intervals from shortly after emergence through maturity The objective

was to determine the rate of growth and Zn uptake by a Zn responsive varshy

iety (Bluebelle) and a less Zn-responsive variety (Calrose) in the presence

or absence of Zn applied to Crowley sil (pHl 75) Dry matter production

of Calrose was linear with time of growth and of a similar magnitude until

heading with or without applied Zn Bluebelle followed a similar pattern

where Zn was applied However in the absence of applied Zn foliage yield

was reduced markedly

-54

Uptake of Zn was similar for both varieties whenZn was

applied Dry matter production and Zn uptake by the two varieties

also were comparable when Zn was applied However yield of Calrose

was much higher than that of Bluebelle in the absence of applied Zn

while Zn uptake was only slightly higher This suggests that the lesshy

ser responsiveness of Calrose to Zn may be due to more efficient utilishy

zation of Zn There was no indication of a greater demand for Zn durshy

ing reproduction in either variety as was suggested in earlier greenshy

house experiments

Response of Upland Rice to P and Zn--P M Giordano J J

Mortvedt and Greenhouse Staff Several rates of P and Zn were applied

to Crowley sil (limed to pH 75) in factorial combination to determine

whether differences in rice growth under flooded and nonflooded soil

conditions are related to plant nutrition Although straw yields were

slightly higher in nonflooded rice receiving adequate P and Zn grain

yields were higher in the flooded crop increased rates of F andor Zn

did not result in equal yields Except in the highest Zn rate (75 mg)

concentrations of Zn in both straw and grain were higher with flooding

Concentration of P increased with rate of applied P and was higher in

the grain or flooded than upland rice at a comparable P rate In conshy

trast concentrations of N were lower with flooding due in part to dilshy

ution from increased growth

Rice Response to N and P in Flooded and Unflooded Cultures--

G L Terman S E Allen and Greenhouse-Analytical Staff Rates of

N from 250 to 2000 ntpot and P from 0 to 1000 mtpot were applied for

Nato rice grown on Mountview sil and Sango sicl (625 kg of soil per

pot) Market yield response to N and P was obtained Yields of straw

- 55 shy

total yields N uptake and N recovery were higher on unflooded than

on flooded soil cultures Grain yields however were slightly higher

with flooding These results indicate that with adequate applied

nutrients especially of N rice yields without flooding can approach

or even equal those under flooding

Uptake of N P Ca Mg and Zn increased with yield response

to N and P while K uptake decreased on the Mountview soil Concentrations

of N and P increased with applied N and P respectively while concentrations

of other nutrients were diluted in most situations with yield response to N

or P

Results from this experiment show that amouats of N applied in

previous pot experiments for rice have been much too low especially if the

crop was grown to maturity

Response of Corn to S and N i UUASand Urea-S--S E Allen

and Greenhouse Staff Three greenhouse pot experiments were conducted to

measure response to S and N in ulfur coated urea (SCU) urea amonium

sulfate (UAS) and urea -S as well as estimate N losses from surface apshy

plied N sources

In Experiment 260 less than 20 of the S mixed with the soil

was recovered from SCU or urea-S granules by two crops of corn as comshy

pared to 45 or 80 from flowers of S or Na2SO 4 CLop response followed

a similar pattern

In Experiment 260-A N sources were surface applied and alshy

lowed to dry for two weeks before incorporation Into the soil and plantshy

ing Recovery of N by two crops of corn was 77-82 for AN an compared

to 37-70 for urea UAS urea-S and ICU Thus n this experiment loss

of N from urea did not appear to be re~dcud by light S-coatlngn or by Inshy

corporating S or AS in the granules

-S -

I xbprZnSlt a Wtch aU Meyto 0-Ai Wt f9r

higher reermo teOrtOrs cOM reSpWNO i r0100 Of N w

not oaisteontly related to sewe ot N In edl tust 0 ioltiUe Lim

lo in VMuwpped evlmtUTS 48 merind by seirest nte appresOehe

501 for uroa as cwarod to 210 for urea peepha

Rus- or Upse to LoAmIl34I a AriMed bI Earl U

MW NOWlsIIsIr-4 L Toman 5 1 Alln and eesese StNf rio

row on Sawg did (0 tpot) We 1l0l0 Ws feritiud vith 05is

of Npot mixod with the 6011 as aureCA NiAO) 1 Age god At Ures

was also itcluded at rtt t 05 10 end 15 of Upee Theas trealshy

onto were followed 4 wpdrsetago of U s AN wre 4C 10o or at I3n

Weeks toulin up to IS pot

A soil application of 10 pot rosulvod to the maim yield

at 4 weeks Tio4 sad percont prottis t intre raite tncreased rftishy

linearly with U applictalien IeseeItally all at the m iNd wit

the moil w domitrifted after flooding Grail end straw Ilelds vere

highly correlatod with tiliriag and vlh ubers of gralm arl

The results Widicat that 0$ to 10 a of Upot as orea or

NN bsuld be sied with the oil to stilate tiilrir with adshy

ditional 0 topireased later to increase grain lIds mad protia cmshy

tout

DIVISION 54- FERTILIZER TECHNOLOGY AND USE

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-02

792 60L WI W A)49R Pio VOL 37 197)

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DIVISION 8-9-SOIL MINERALOGY

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~ -0

65

0IL CL OC AMXR PROC VOL 38 1974

)aT1 S4I104 ow Lusanll Tawng isa tall Thai variety known for beingIwo nonshyi s s ) sensitive to photoperiod A split-plot design was used in

S e e these euperimeots with 4 rates of P (I1 22 44 and 88t i V IV k of Pha) applied a main plot treatments and with the OF It sourMes of P as subplot treatments There were two checkS plots in each rmplicate The extra check plot was included to permit the application of fresh TSP standard Jor the

It- ti 06 + i bull fa succeeding crop the p-4me of bi was to permit accurate d awrnwal of the mdual effectiveness of the phosphate

ftinSUbI rock The P fertilioers were broadcast on the mud andthen Worporald In the soil during the last harrowing At

whM N both On ACS indx ampM time of transplanting Immediately before the last harrow61t (4j 5 4 01 P s 3Mm o Vallonal in con n 100 kgha of N as ammonium sulfate and 33 kghaWO Of Spews ampm lIW thaabe rocks do ACS indes of K as polium chloride were applied A total of 40 wa in prepw O do ctih k otent kha of N a ammoniunt sulfate was applied later in twoir P The hew oNed amp wM W for 5 of gw topdrossingp with about 5cm depth of water on the plotsvV I aiOMveffeOctveee Three to six ldayold selings pr hillwW the ACS idex were planted00OWW wia Oft fo an c irNk I p Coen 20 by 20 cm part in straight rows Hand weeding was used

and insecticide were applied for Insect control Grain yieldw was masared by sampling 5 ml of each plot excluding border rows The date of heading in each treatment and theUNiN d pbM W Weks rin tOW USA UMe In Tale yed componnts at hafvel were also recorded

I filM rsperMS esOM kdwdua 1 t ab The average yields of ough (unhulled) rice for botha 84 OW O 8uo 4 Thala TM was a locations are ploutel in PIS 3 for the first crop (1969 wet

owou thRM seaso0) The Veamps yield response was obtained at Klonge (s) W lDtO t Of dMa of1tw W d l R Luang however a 4ute satisfactory yield response was

~Mk ^d TVA UJSD ad Kd UnIveS obtalned to applied P at Bangkhen as wellXUe LaM e R qwrw Ims The sod was do Relative aponomlAe effectiveness values were calculated

VOW (a ksA w edmwL t Poesesm h Vy for these data and am presented In Table 3 The valuesdAY buo if dIe ouh ne Pee wtk a Mlak vow 1009 for th first crop are plotled against ACS index in Fig 41 This Im M i6ti l 4bNd IO a0 O mkarnk for both locatio r relationship was linear for the

11400 ThCpH 0( lb pW IW 01 th UpeiaW so Sanodion location and curtiltnear for KIng Luang The was u i 4A sksamp lMaor nrusio model amparounted for 81 of theAmO$MI Aw jAAsue Swim T1 Snh Wd variation In the AE valu for Bantkhen a square root

Mems a Iw iv fern alh$ sedm haowg dayNW W t he plAL At tdo M tM aso W s as ctminued throufh eltaM t Ofpof -le lse wo am P OeNI VeOpls 1o ealluae tI lon4erm MIdual Offccls

A on W isset i a wse to hsh eapeel of these ooihss t ocks The baagkhon experimnent was letmiaI1DlVemisthis is a w hulu Lo g Tasug ia iasael aft - Msd residual Ves will be pr-Om crok TheseTwod esewm

SWWo

A

lP~U~7 ISIIPe1iuIWN e bsedisssin ian ghth siaoelalbe

984 0 6 O O - M s -s fWPas 11eSft W d Uo al a o

o

S4l~ lIIII I~l I 1f fl

( +

+ + + m + ++++-

++ +(++ + ++++ + ++ ++

- 66 -

ENOIMLSTAD ET AL RESPONSE BY FLOODED RICE TO PHOSPHATE ROCKS VARYING IN CITRATE SOLUBILITY

I I I I j0 I I

BANOKHEN BANGKHEN

pH 56 6 - 0o

TSP

NC

5~ ~ ~ L o 4 - -shy

4 ] - --------shy04

6S

|0 III 2 44 8r 66

I I I

a 1KLONG LUANG

pH 46 z KLONG LUANG

TSP Sc2 NCFL(N)

5 FLIC) J0 TU

oshy

4 ~40shy

3 bull eM0

I - I I I I I

0 II 22 44 88 0 5 10 15 20 IP APPLIED KO HA ABSOLUTE CITRAE SOLUBIITY INDEX

Fig 3-Yield of rough rice at Klong Luang and Bangkhen Rice Fig 4-Relative agronon effectiveness () of P sources ploz-Experiment Stations Thalmand as affected by rate and Source ted against citrate solubity Index for both Thailand field ex

of P applied (crop 1) periment (first crop only)

regression model accounted for 97 of the variation in sumably resulted from crop uptake and reaction with the RAE values at the Klong Luang location soil to form less soluble products Such effects may have

These experiments were continued during the dry season been more important at the lower rates since the two TSP of early 1970 to ascertain the residual effectiveness of the curyes converged at the highest rate of application various sources applied to the first crop No new P was These data from KIong Luang indicate that (i) residual applied except for the fresh TSP standard mentioned effects of all rocks except Mlcwuri were substantial (ii) above rhe experiment otherwise was conducted in a man the relationship between relative agronornic effectiveness ner similar to that followed in the first crop of the phosphate rocks and citrate solubility levels was

The response to both freshly applied ad residual P was largely obscured and (iii) the general superiority of TSP marked at the Klong Luang location and marginal at over phosphate rock in terms of effectiveiss persisted Bangkhen In fact at the latter location the response was through the second crop so small that little can be said regarding residual effectiveshyness The yield data from crop 2 at the Klong Luang DISCUSSION experiment are plotted in Fig 5 Greenhouse and field data presented in this paper show

Relative agronomic effectiveness values (Table 3) were clearly that there are substantial differences among phosshycalculated for the Klong Luang data using both the residual and freshly applied TSP as standards It is of Interest to note that the superiority of TSP over the phosphbte rocks Table 3-Relative agronomic effective values for field experishyments in Thailand persisted through the second crop The main difference in KlowlZmlnql~the residual effects is that with the exception of the MIs- s Crop 1 Crop 21 Crop 1-shysouri rock Ihe marked relationship between citratr-soluble WoiCarolina yl 59 76

phosphate rocks and RAE had largely rds norh) a 64P conltct of th Florida (eqlral is 6969 6

disapipeared In this acidic soil (pHi 46) P would by this I14o 69 63 40 ToonesS 31 65

limo be supplied by Intermediate reaction products In addl Missou 0 o lion to residues of the initial spatlte Ts P o 2 o 0

The TSP applied to the first crop declliv-d slightly In campIafcmWataesr e id ofeuhuloefor 22MA rates of PtColeouattd as aba u tlte td18 kS ratesp dlverage yield tM868 to 22 44

effectiveness relative to the freshly applied ISP This pre- of d s4

A

4

- 67 shy

-SOIL SCL SOC AMER I

KLONG LUANG CROP 2

Si 3

eN

TAPPLIEDKGHA

Fig 5-The residual effectiveness ovarious P sources for crop s compared with freshly applied TSP Klong Luang Rice

Experiment Station Thailand

phate rocks in terms of agronomic effectiveness for flooded

rice Further these differences can be predicted by means of citrate solubility or by the ACS index It appears that

the latter is more appropriate where the content of apatite varies among phospiate rocks The most soluble phosphate rocks approached but did not actually equal TSP in limit-iuig (maximum) yield in these experiments regardless of rate applied This agrees with the results of Ensminger Pearson and Armiger (4) One needs to consider the defi-nite posribility of same yield loss in zhoosing a phosphate

rock over TSP such yield losses must be weighed against the lower price of phosphate rock The explanation for such iosses may involve concentration of soluble P in the soil Khasawneh and Copeland (6) suggest that the growth rate of crop plants is a function of P concentration that can be maintained in the soil solution If P concentration is limiting or inadequate becawe of a lower dissolution rate of phosphate rock the growth iate ard uiiimate yield will be diminished accordingly

The RAE values bascd on yield increases reflect the agronomi effectiveness of these various sources relacve

to the TSP standard however these nould be supple-

mented by an economic analysis before rational choice can

be made The following calculations will provide an estimate of

the rclativ ecooomic effectiveness(REE)

Y t Ps aXpatREE -- 100

vahtercks t sphate or e b i- eor

Price of TSPkg fo

be Price of PRkg P

PROC VOL 38 1974 leO

90r

Wsoshy

0

60-LUSEPHOSPHATE ROCK

00 10 20

PTP PR

Fig 6-Relationship between relaZive effectiveness values (RAE) and the price ratios between TSP and phosphate rock Such a figure can be used in making a choice between these

sources

If REE exceeds 100 in this calculation the phosphate rock would be preferable to TSP

The REE calcuktaaa wre used in preparing an indifshyference curve (Fig 6) wherein RAE values are plotted

against PTsPPpR ratios The cu~rve itself connects those points at which REE equals 100 When exactly on the curve it makes no real economic difference what source is chosen After choosing a suitable price ratio one can then project upward from that ratio knowing the RAI

value (or estimating it from such data as shown in Fig 4 using citrate-soluble P content) one can then choose the source on the basis of both agronomic and economic conshysiderations For example if the price ratio is 25 and the RAE value of the phosphaite rock is greater than 40 the rock phosphate in question would be used However if the RAE value was less than 40 TSP would be a better choice There are indications that if the P in the more soluble phosphate ro~cks (North Carolina north Florida central Forida) is less than half as expensivz as that in TSP these rocks would be feasible altereaives to TSP on soils similar

to thoseused in Thailand This analysis does not take into account the possibility

of lower yields from use of phosphate rock In addition only a portion of the various yield response curves was used in this anlysis ie up to 22 kgha Beyond this

rate yield response was much less pronounced it could be argued that at less than maximum yields TSP would produce a certain yield at lower rates of P than would phosshy

pow ofrock This would especially be true for rates applioa example at Klong Luang 5500 kg of

rice pcr iectare could have been produced with either Ii kg of P as TSP or 44 kg of P as son of the more reacshy

tire phosphate rocks It should be pointed ot however

- 68 shy

(IIKIS amp YOUN( ARIFICIAL WEATIIERING OF OXIDIZED p[ll- IV

that this is the yield level that would show the widest difference such is the advantage of hindsight

Farmers generally prefer granular fertilizers for machine

or hand application This is a disadvantage for the phos-phate rocks which are normally arplied in finely divided form Recently experimental quantities of granular urea-

phosphate rock mixtures have been made by TVA Results of trials with these fertilizers will be reported elsewhere

LITERATURE CITED

1 Armiger W H and Maurice- Fried 1957 The plantavailability of various sources of phosphate rock Soil Sci Soc Amer Proc 21183-188

2 Bengston G W E C Sample and S E Allen 1974 Re-sponso of slash pine seedlings to P sGurces of varying ci-trato solubility Plant Soil (In press)

3 Caro JIt and W Hill 1956 Chard eristics and fer tilizcr value of phosphate rock from different fields J Agr Food Chem 4684-687

4 Ensminger I E R W Peirson and W II Atmiger1967 Effectivencs of rock phosphate as a source of phosshyphurus for plants US Dep Agr ARS Bull 4112S

5 Engelstad 0 P J G Getsinger anid I J Stangel 1972 Tailoring of fertiliers for rice cnnece Valley Author ftyNational Fertilicr Developmnent Center Hull Y-52

6 Khasawnch F E and Jane P Copcland 1971 (otton root growth and uptake of nutrievos relation oif phosph

rus uptake to quantity intensity and buffering capacit) Soil Sci Soc Amer Proc 37250-254

7 Lehr JR and G H McClellan 1972 A revised lIbora tory reactivity scale for evaljativg phosphate rocks for direct application Tennessee Valley Authcrity National Fertilizer Development Center lull Y-43

H Terman G L S EAllen and 0 P Engelstad 1970 Response by paddy cice to ratcs and suurces of appliedphosphorus Agron J63390-394

DIVISION S-9-SOIL MINERALOGY

Artificial Weathering of Oxidized Biotite IV The Inhibitory Effect of Potassium on Dissolution llate

R JGILKES AND R C YOUNG2

ABSTRACT

Rates of dissolution of oxidized biotites in OIM 001M ICI are severely depressed in the presence of IM KCI The amovnts of Al Mg Mn dissolved in the first eytraction are similir to those found without KCI however subsequent extractions remove these elements at 10-20 of the corresponding lICI rates This effect may be due to a decreased rate of vermiculite formation thereby reducing the effective basal area exposed to attack A decrease in dissolution rate with increasing ferric iron content was still apparent in the presence of IM KCI

Additional Index Words X-ray diffraction infrared aborp-

N EARLIER papers of this series the tole of biotite in soils

as a source of both macro and micronutrient elements

has been discussed ((Gilkes Young and Quirk 1972 1973ab) Experiments in artificial weathering uiing as va-

riety of extractants were undertaken to determiie the inlu-

ence of oxidation of octahedrally coordinated iron on the bull release of structural cations to solution The results of this

work demonstated that biotite behaves anomalously with respect to the other common ferromagnesian minerals found in soils Oxidation leads to the development of a high degree of resistance to cation exchange and dissolution Several authors have coiwludcd that decreased rates of K

Contribution from the Dep of Soi Science and Plant Nutri-tion Institute of Agriculture Univ of Western Australia Ned-lands 6009 Western Australia Received 29 Sept 1973 Ap-proved 8 Jan 1974

2 Senior Lecturer in Soil Science and Research Officer respeclively

replacement in electrolytes shown by oxidized biotites are

a result of the inclination of structural hydroxyl adjacent to newly created trivalent iron or vacant octahedral cation sites (Robert and Pedro 1959 Barshad and Kishk 1968) Gilkes et al (1973b) suggested that decreased rates of disshysolution of oxidized biotite in 0001 0t)l 0Af CI may also be due to the presence of inclined hydroxyl In this case a smaller surface area external and exposed intershylayer may be available for attack if K replacement by hyshydrogen ions occurs at a slower rate in oxidized biotites

Gastuche (1963) has shown that significant dissolution ofthe (IIM) biotile face may occur and it is easily demonshystrated that the proportion of exposed (001M) face in weathering biotites depends on the percentage K replaced

Rausell-Colom ct al (1965) have shown that hydrogen ions act in an identical fashion to metal cations in K exshy

change from micas In particular exchange c-f K by hydroshy

gen ions will be terminated or greatly reduced by high levels of K in solution Thus if dissolution of oxidized biotite by

acids is carried out at sufficiently high K levels to prevent vermiculization any differences in dissolution rate that may occur cannot simply be ascribed to differences in rates of K replacement The following results were obtained from such an experiment which unlike the experiment described in Parts I and II (Gilkes et al 1973ab) does not attempt to simulate natuiral - conditions

MATERIAILS AN) M HIiODS Further subsamples of the less than 0 hiotites used in K

excherandbaid disoo tu es (G iles e9n K exchange and acid dissolution studies (Gilkes et al1973ab) were used in these experiments Preparation of sequentiallyoxidized biotites without intermediate vermiculite formation is

Page 13: I70 - United States Agency for International Developmentto ascertan, but tgl.eetad, 1, L,. ("Tailoring of Pertiltiters for ice,'" TVA ulletin Y-52) states that the staft of IOi has

-10-

Much of the work with fertilizers for both lowland rice and

upland crops will consist of field tests in Southeast Asia Africa and

Latin America Greenhouse and engineering studies will back up the field

research All field experiments are designed to provide at least an esshy

timate of costs and returns for each fertilizer tested

PROJECT PLANS FORFISCAL 1975

In this section the work for fiscal 1975 will be discussed

It should be remembered that the success of this project depends in a

large part upon maintaining sufficient flexibility so that work in inshy

dividual countries can be adapted to supplement and complement programs

already under way While guidelines and plans of work must be developed

so that the objectives of the project are clearly defined detailed

plans for specific countries or groups of countries must be developed

by consultation wth local cooperators

These plans will be discussed under the following three general

phases of the project

I Engineering and development

2 Agronomic testing and evaluation

3 Economic evaluations

Engineering and Development

Phosphate Rock

Methods have been proposed for relatively simple treatment of

phosphate rock (PR) to increase the availability of the phosphate to make

it more suitable for direct application to the soil These treatments

may be economically feasible in certain areas especially in view of the

current world fertilizer situation Considerable work has been done at

TVA studying means of altering PR and plans are being developed to inishy

tiate further developmental work and field testing of these materials durshy

ing fiscal 1975

- 12 -

Emphasis will be placed upon obtaining samples of phosphate

rock from deposits in developing countries and testing and improving

procedures for increasing their citrate solubility and tzius availabilshy

ity of the phosphorus From this laboratory screening process sevural

sources will be selected from which small amounts (50 to 100 pounds)

will be prepared for greenhouse and field experiments ou various soils

(as described under agronomic section)

From these results one or two locations (or countries) will

be selected for development of a pilot program to utilize local sources

of phosphate rock This program will involve production of the altered

PR and its agronomic evaluation and then educational programs with govshy

ernment and commercial representatives to introduce its use to the farmers

Sulfur-Coated Fertilizers

Some preliminary work has been done in which urea-potash mixshy

tures were coated with sulfur The 7-day release rates for the N and

K20 were 17 and 36 respectively from the coated product (22-0-11-30S

grade) This was the first effort in coating a compound fertilizer

with the new coating system

The widely differing release rates for the nutrients from

the coated compound product raise some interesting prospects for tailshy

oring the nutrient release rate of sulfur-coated products It might

be possible to cogranulate materials of varying water solubility and

sulfur-coat them to produce products with release rates that would apshy

proximate the timing of nutrient requirements of the crop The need

for this type of controlled-release product has been mentioned many

times by agronomists and may be especially applicable in multiple and

intercropping systems

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Table 2

Mttct of 0 Sourco aampW $At On Upt~ks of 0 by Two Varitgtos of Paddy Rice

gr~a 1971

~ MMUampL~ ~L ~ nYLALI~ 11 lemall

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- 24 shy

India--The results of four experiments conducted with flooded

transplanted rice in India by the All-India Coordinated Rice Project

Hyderabad are given in table 3 The response to N was excellent the

yield without N being only 41 of those obtained with basal applications

of N as uza With basal applications of SCU the yields were 20 higher

than with basal applications of urea and in the three experiments in

which urea applications were split yields with SCU were 18 higher than

yields with split applications of urea When comparing the average Nshy

response (kamp grainKg N) yields were increased 13 more by SCU than by

basal applications of urea

The data from one experiment with light irrigated rice in India

are given in table 4 yields were relatively low and differences between

N sources or method of application were not significant However yields

with SU tended to be higher than when all urea was applied at planting

but lower than when split applications of urea were applied Again yields

increased more than 13 more with SCU than with basal applications ofwere

ur

In tables 5 and 6 the yields of a short-duration transplanted

rice grown in irrigated light-textured soils at five locations in India

indicate that higher yields were obtained with SCU than with urea when apshy

plied as a basal application Yield increases due to basal N applications

were 502 greater with SCU than with urea However split applications of

resulted in yields equal to those obtained with basal applications ofurea

CU

The yields of direct-seeded upland rice grown at three locations

to India are given in table 7 and the relative yields in table 8 Yields

were low due to drought but good responses were nevertheless obtained for

- 25 -

Table 3

Effect of N Source and Time of Application on Yield of Paddy (Flooded) Rice in India 1972 (Summary of Reported Data from 4 Experiments)

Experimental Number Source Rate Method Yield Relative N-Response

and of of N of Yield Kg Grain

Season Nitrogen kgha Application mtha Kg N

- - - 196 34 -

Urea 120 Basal 573 100 314

11 Urea 120 80 + 40 611 107 345 Rabi SCU 120 Basal 713 124 430

12 - 0 - 202 30 -

Urea 125 Basal 682 100 384

Rabi Urea 125 35 + 20 + 35 + 35 633 95 344 SCU 125 Basal 781 115 463

13- 0 - 168 44

Urea 100 Basal 385 100 217

Kharif Urea 100 30 + 20 + 25 + 25 400 104 232 SCU 100 Basal 462 120 293

14 -

Urea -

125 -

Basal 355 650

55 100

-

236

Rabi SCU 125 Basal 781 120 341

-- 26 -

Table 4

Effect of N Source and Time of Application on Yield of Light Irrigated Rice in India 1972 (Summary of Reported Data From

One Experiment at Pattambi)

Experimental Number Source Rate Method Yield Relative N-Response

and of of N of Yield Kg Grain Season Nitrogen (kgha) Application (mtha) Q) Kg N

38 0 - 204 85 -Rabi Urea 120 Basal 241 100 308

Urea 120 60 + 0 + 30 + 30 267 ill 525 SCU 120 Basal 255 106 425

Table 5

Effect of N Source and Time of Application on Yields of Short-Duration Transplanted lice Variety Grown on Irrigated Light-Textured Soils at 5 Locations in India 1972

(Snmzarized From Reported Data)

Rate Grain Yields (MtHa) Source of N Method of N GrainI of N kgh Application Faizabod Karjat Mandva Pattabi laya Averaje X

- 291 266 211 19 340 260 -

Urea 100 Basal 386 407 361 285 482 3 124 Urea 100 50 + 25 + 25 399 430 434 334 6amp2 4A8 186

SCU 100 Basal 368 468 439 360 572 41 181

Table 6

Effect of I Source end Tlae of ApplIcattoo c RIstave Tle24 of a rt- rat1 T Lsd lice Vasrety Crin o Irrigated L41tshy1 at S Locitite mindi 1972

Rate ____________14_3

Source of X N~tbad of Of X An 1 tat14 1 acr X__T1 4v tatW ttva

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W Iotors Ftslanp tospg Irritd for Two thvk Afler flontiw wft rkwa~ Floo4d 191)

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- 38 -

Table 18

Yild of aemati-370 Rice at Punjab Agricultural Research

Institute in Pakistan in 1969-70 Grown Under

Couditions of Intermittent Flooding

Pate of application

=IL

o 0 67 67 100 100 67 67

100 100 67 67 200 100

Average for Sources

Ntha

AS 260 gres 279

320

Source f5

-

AS AS Ura Urea SCU SCU

Yield

Relative

93 100 115

(M)O

Yield

Increase Yield Due to N

(Ktlha) (mtha)

-212 245 033 274 062 260 048 297 085 315 103 325 112

Yield Increase

Relative

72048 067 100 108 161

(2)

- 39 shy

Short-statured high yielding rice varieties grown extenshy

sively in northern Peru require extremely high rates of conventional

N sources to achieve maximum yields The recovery of applied N is

extremely low due to the use of intermittent flooding This water

management system results in heavy N losses even with properly timed

split applications In search of simpler and more effective methods

of N management eight field experiments were conducted in the region

to evaluate sulfur-coated urea (SCU) an experimental slow-release N

source supplied by the Tennessee Valley Authority Rice yields were

increased an average of 59 more by pretransplant-incorporated SCU than

by urea or ammonium sulfate applied in the same manner SCU produced

excessive vegetative growth which resulted in yield reductions at high

N rates

Regardless of an assumed 48-higher unit N cost in SCU the

overall benefits of pretransplant-incorporated applications of SCU

were favorable since there was a decrease of 40 in the optimum rate

of N and the need for precise timing of application was eliminated

Pakistan--In Pakistan basal applications of AS urea and

SCU to rice grown under conditions of intermittent flooding in 1969-70

(table 18) indicate that SCU is a superior source of N as compared to

urea or AS when all N is applied at or before planting The data also

indicate that a yield response was obtained for P applications but a

comparison of N sources at each level of P indicates that no interaction

between N and P was present so that differences between N sources were

relatively the same at each level of P Yields were increased about 60

more when SCU was applied than when urea was applied Yield increases

with AS were only about 72 of the increase obtained with urea these reshy

sults do not agree with the generally-reported superiority of AS as comshy

pared to urea as a source of N for rice

- 40 -

In 1973 experiments were conducted in Pakistan using both

Basmati-370 and IRRI-6 varieties of rice grown under conditions of

When all N was applied at puddlingintermittent flooding (table 19)

or 12 at puddling and 12 at panicle initiation both AS and SCU were

superior to urea with SCU tending to be the most efficient source

However when N was applied 12 at transplanting and 12 at panicle

initiation SCU was the poorest source of N This would indicate that

the release of N from SCU applied at these times is too slow for optimwn

plant growth

In another experiment in Pakistan in 1973 no differences

in the effectiveness of urea AS or SCU were noted in the yields of

continuously-flooded rice (table 20) Again these results are conshy

sistent with earlier results which indicate no superiority for SCU

when rice is continuously flooded

Nitrogen Studies--Maize

A series of three experiments were conducted by IITA in

armo-Nigeria in 1972-73 comparing AS urea SCU and

CAN (calcium

nium nitrate) as sources of N for maize (table 21) A significant

yield response was obtained for N at each location but no conaistent

differences were noted amaong sources These results are consistent

with results at other locations which have not shown that SCU is a

superior source of N for maize grown over a period of 3 to 4 months

Nitrogen--Wheat

The yields of wheat in Pakistan in 1969-70 (tables 22 and

23) show that yields with SCU) tended to be lower than those with ureaJ

although at one locction where sorghum was grown followilng wheat with

Table 19

Yields of Basmati-370 and IRRI-6 Rice at Punjab Agricultural Experiment Station in Pakistan in 1973 Under

Conditions of Intermittent Flooding

Rate Yield Source of N Time of Yield (Mtha) Increase of N B-370 IRRI-6 Application Basmati-370 IRRI-6 Average (Mtha)

0 0 - 21 353 287 -

SCU 90 150 At Puddling 325 545 435 148

Urea 90 150 At Puddling 309 500 405 118

AS 90 150 At Puddling 324 529 427 140

SCU 90 150 Puddling 372 572 472 185 Panicle Initiation

Urea 90 150 Puddling 335 502 419 132 Panicle Initiation

AS 90 150 Puddling 353 529 441 154 Panicle Initiation

SCU 90 150 After Transplanting 312 562 437 150 Panicle Initiation

Urea 90 150 After Transplanting 340 624 482 195 Panicle Initiation

AS 90 150 After Transplanting 349 583 466 179 Panicle Initiation

All plots received 45 lbs P205acre as single superphosphate

Relative Yield Increase ()

Source of N At Puddling Puddling Panicle Transplant h Panicle

Urea 100 100 100 AS 119 117 92 SCU 125 140 77

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pemour~a ot P syag besmti andMi as elt ov so gpamwhr

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0 49 shy

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toiwdiats in 5tftOvttWS54 betwee wroiPi ad TVP NotV5Ymf to

me coo were they mere twoe $a a etfective ao TIP 00 sipifleast

LVSUMI5 at0 efecto wore toun tor thee produteo Timely dtIampWde

FR (-t00 mmoh) Uia amp~rally oar affective than Owe gra8448r FOampprodt

featal twos o 6 aotetire s I

Nowvero it to felt that sfortber field euprtet vth

hese interials Amd ether typs of grometatodl Wter nre wrrautad

hater ceeuwodh that they have me areec poteatlal toi additoG

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euperimeste vth few reck pboophar s0d with reck pbophat treated

to sehesa citrata selmtliy or to ha csaducted

Metbir sertes of tbme enprtaeats wae c~edtmcted by IITA

to Ut~rta copal TVP AOP APP aed it at see tecastisix (table 14)

No dot lalt sewseltles teh draw tree thee results simouely em pear to tlvdl bsww they do stwgpt tbat forthew work with

MR to werramid so tbme sels

Table 24

LttcttF Swce MaPlate 06 ieldot IM AWaia CoelsANS at IITA (Ugboda ad Apoin ail sorit) aid at Ike (AUaba s5i series)

1973

Plate ot IP Apinu 5 poundebods A1ab

Ocrol 0 Z94 419 M)

Tr ipl ruprphite 20 349 3799378

Triple vepput 40 M09 410$

Triple 6wp~~b1 4271 4344 42250

Ammotw-ritpophW to 4201 4124 4040

Amosim-rdop~phlt 40 4270 4106 4231

AM tuo-polpephats 20 404 4244 3794

~eai~mpelppepbuI 400)49 4094

Cee m-pbpbt to- 59

momee eph lto 0 4192

LSO (0 0$) 29 1025

Th WPII

- 51 shy

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roopon from cmonetrat4 gsporphophai (CIP) who ort$o4 oil k

was 45j itwas tafertor vb protioo4 oil p war OS Ib 4iffer~c

in rtc reepos to X cod14 oo bo ttrit4 4 4 hvsciag of boil p

~ Pt o r11221 0 tP

c theto the rhimecyllndor of rico tots par to)14M4i1 roeoi~t

ed oil emd PA prior to tho ont of an~robi4 cMioe AA~ oIifoshy

nAte bYpot t taet~d tO fC4sin t~r 4PWden0 Of f Ot(tivshy

ofOWailiJtyno o prefla4 all Put that 4t01etoo 14 tvsIk

of the Ott to prvvld a 014for C4m0 44 mI 1 o4sf

EfftC ftPet141on AIAM-0 V f401td 4 4iv 440 Mtft

Aa torfat VampP f4MWfCi4W04wt0amp to 4eturWlI Ot(Wel~drIC ft

Ot f tM6 the flooded Ott 00 14 04019I Pft0uAw Of gAr~s~lr

pkS$t M40b MP) Tw P1101 Piset Prodwie W-e 10M0di Wr04

(10-1) emW 0aretilp ddw01at4 P WAA firom Rrth M~flRU414~$

wee cowiared with fie Md reWim 44104 proo~fo) foruk oith laWItter

I v te-PR P OW1004 4 4 O Wf ottil OW ellt Oo

Oveiel1 the 40tt dmcruie to effetotww Wtollowui Co fme

PR tpaUIB1I ldoltmo PR (pamwlatr) offr~- ArmeuM) 0 orwi

- 52 -

Effect of N Sourc6 and Water Management on Response of Rice

toe Zn- M Giordano J J Mortvedt OP Engelstad and Greenhouse

Staff Several rotes of CO(14H2)2 and (H )2So4 vith or without ZnO

wore applied to flooded and nonflooded Crowley oil (limed to pH 75)

to determine response of Bluebelle rice to Zn Yields with both N

sources veotrgreator on flooded then on nonflooded soil In the abshy

ence of applied Zn total dry matter production vith CO(NH2)2 was

slightly lower than with (NH)2S04 on flooded soil and considerably

lover on nonflooded soil Concentration of Zn wan higher in straw and

grain of plants roun on flooded than on nonflooded soil Although

concentration of P was unaffected by N source or Zn rate there was

som indication that cranslocation of P from straw to grain may be

depressed in nouflooded rice Concentration of N was lower in straw

grown on flooded than on nonflooded soil due to apparent dilution

thereas both X sources resulted in similar N concentrations in straw

at all rates of N application the N concentration in grain increased

with 0 rAse

feSpongi gf(SM to Chjorospodiostte and Related P Sources--

Si Allen and Greonhoue Staff A greenhouse pot experiment was

couct44d with corn Brown on Hountview silt loam to compare the ofshy

fectlivees of chlorospodiosito (Chlor-l) with concentrated supershy

phosphate (CP) Thomas slag and North Carolina phosphate rock (NC-PR)

Oil-prillad urea-phophato rock (UPI) FeA1JMP 20 7 and monomthyl

phosphate were included in the experiment Based on yield of forage and

uptake of P by tvo crops each of 6-weeks duration the following conshy

stui were dravat

I Chlor-1 was slightly loss effective than CSI Thomas slaS or NC-PR

from which Chlor-l wae prepared

- 53 shy

2 Granular UPR was a poor source of P its effectiveness was greatly

increased by reducing the particle size to -35mesh

3 FeAlNH4P207 was unavailable to the crop

4 Monomethyl phosphate was equivalent toor slightly more effective-

than CSP

Research Indirectly Related to TVA-AID Project

Response of Several Rice Varieties to Zn in Moist or Flooded

Soil--P M Giordano J J Mortvedt and Greenhouse Several varieties

of rice from Mexico and the Dominican Republic currently under investishy

gation in Puerto Rico for adaptation to upland culture were compared with

some established United States varieties with regard to Zn response on

moist and flooded Crowley sil (pH 75) Chontalpa (Mexico) Bluebelle

(Texas) and Starbonnet (Arkansas) were most responsive to applied Zn

Juma (Dominican Republic) intermediate and Sinaloa (Mexico) and Calrose

(California) were the least responsive The Sinaloa varieties (Mexico)

appeared to be best adapted to non-flooded conditions whereas Chontalpa

and Calrose were poorest Concentrations of Zn generally were higher in

plants grown on flooded than moist soil

Pattern of Growth and Zinc Accumulation by Rice--P M Giordano

J J Mortvedt and Greenhouse Staff Rice plants were harvested at weekly

intervals from shortly after emergence through maturity The objective

was to determine the rate of growth and Zn uptake by a Zn responsive varshy

iety (Bluebelle) and a less Zn-responsive variety (Calrose) in the presence

or absence of Zn applied to Crowley sil (pHl 75) Dry matter production

of Calrose was linear with time of growth and of a similar magnitude until

heading with or without applied Zn Bluebelle followed a similar pattern

where Zn was applied However in the absence of applied Zn foliage yield

was reduced markedly

-54

Uptake of Zn was similar for both varieties whenZn was

applied Dry matter production and Zn uptake by the two varieties

also were comparable when Zn was applied However yield of Calrose

was much higher than that of Bluebelle in the absence of applied Zn

while Zn uptake was only slightly higher This suggests that the lesshy

ser responsiveness of Calrose to Zn may be due to more efficient utilishy

zation of Zn There was no indication of a greater demand for Zn durshy

ing reproduction in either variety as was suggested in earlier greenshy

house experiments

Response of Upland Rice to P and Zn--P M Giordano J J

Mortvedt and Greenhouse Staff Several rates of P and Zn were applied

to Crowley sil (limed to pH 75) in factorial combination to determine

whether differences in rice growth under flooded and nonflooded soil

conditions are related to plant nutrition Although straw yields were

slightly higher in nonflooded rice receiving adequate P and Zn grain

yields were higher in the flooded crop increased rates of F andor Zn

did not result in equal yields Except in the highest Zn rate (75 mg)

concentrations of Zn in both straw and grain were higher with flooding

Concentration of P increased with rate of applied P and was higher in

the grain or flooded than upland rice at a comparable P rate In conshy

trast concentrations of N were lower with flooding due in part to dilshy

ution from increased growth

Rice Response to N and P in Flooded and Unflooded Cultures--

G L Terman S E Allen and Greenhouse-Analytical Staff Rates of

N from 250 to 2000 ntpot and P from 0 to 1000 mtpot were applied for

Nato rice grown on Mountview sil and Sango sicl (625 kg of soil per

pot) Market yield response to N and P was obtained Yields of straw

- 55 shy

total yields N uptake and N recovery were higher on unflooded than

on flooded soil cultures Grain yields however were slightly higher

with flooding These results indicate that with adequate applied

nutrients especially of N rice yields without flooding can approach

or even equal those under flooding

Uptake of N P Ca Mg and Zn increased with yield response

to N and P while K uptake decreased on the Mountview soil Concentrations

of N and P increased with applied N and P respectively while concentrations

of other nutrients were diluted in most situations with yield response to N

or P

Results from this experiment show that amouats of N applied in

previous pot experiments for rice have been much too low especially if the

crop was grown to maturity

Response of Corn to S and N i UUASand Urea-S--S E Allen

and Greenhouse Staff Three greenhouse pot experiments were conducted to

measure response to S and N in ulfur coated urea (SCU) urea amonium

sulfate (UAS) and urea -S as well as estimate N losses from surface apshy

plied N sources

In Experiment 260 less than 20 of the S mixed with the soil

was recovered from SCU or urea-S granules by two crops of corn as comshy

pared to 45 or 80 from flowers of S or Na2SO 4 CLop response followed

a similar pattern

In Experiment 260-A N sources were surface applied and alshy

lowed to dry for two weeks before incorporation Into the soil and plantshy

ing Recovery of N by two crops of corn was 77-82 for AN an compared

to 37-70 for urea UAS urea-S and ICU Thus n this experiment loss

of N from urea did not appear to be re~dcud by light S-coatlngn or by Inshy

corporating S or AS in the granules

-S -

I xbprZnSlt a Wtch aU Meyto 0-Ai Wt f9r

higher reermo teOrtOrs cOM reSpWNO i r0100 Of N w

not oaisteontly related to sewe ot N In edl tust 0 ioltiUe Lim

lo in VMuwpped evlmtUTS 48 merind by seirest nte appresOehe

501 for uroa as cwarod to 210 for urea peepha

Rus- or Upse to LoAmIl34I a AriMed bI Earl U

MW NOWlsIIsIr-4 L Toman 5 1 Alln and eesese StNf rio

row on Sawg did (0 tpot) We 1l0l0 Ws feritiud vith 05is

of Npot mixod with the 6011 as aureCA NiAO) 1 Age god At Ures

was also itcluded at rtt t 05 10 end 15 of Upee Theas trealshy

onto were followed 4 wpdrsetago of U s AN wre 4C 10o or at I3n

Weeks toulin up to IS pot

A soil application of 10 pot rosulvod to the maim yield

at 4 weeks Tio4 sad percont prottis t intre raite tncreased rftishy

linearly with U applictalien IeseeItally all at the m iNd wit

the moil w domitrifted after flooding Grail end straw Ilelds vere

highly correlatod with tiliriag and vlh ubers of gralm arl

The results Widicat that 0$ to 10 a of Upot as orea or

NN bsuld be sied with the oil to stilate tiilrir with adshy

ditional 0 topireased later to increase grain lIds mad protia cmshy

tout

DIVISION 54- FERTILIZER TECHNOLOGY AND USE

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valves a hevwae u Iar Walh basl oswas dhe uwpatr bshava of

tb~msusasl appkausu of ofta sede s have aoweN

TOW opl taoe for AieweeW 4OsmWMbas Op peas As Tabl 4 sling sob Os awowully eom grams Piel level Thes oeulam Ma sed as IM

-02

792 60L WI W A)49R Pio VOL 37 197)

primS o r OeampAd WU toa Them fl~ w At NOSSe earno maisslea Ia N he mOWamplIO yik ampWd IMe aampWmW OWa Owe wa UMs of KU to 41 Oke ampWiiIamm be dkrnety ewspokawleM(a s8 te camtd wie a eapmoe by TVA pavw ltoi NA poundrmdaka4us vrimeW460 o to ilkidm ofWW (Mtemas MuOwe 1973) TVA mwi bawld on soi ficedims IampWp seg rudwiv s~s0abet ke WNmdoe ON 01 K Is12 NOSW ie fssewnmu Ie I QvaaIi rowp IMA) f9

)amp m lodk byO voebmsaIS8OpeaWfrats 11 OWNmi a I a W idisod 0 81 Now 111 nindat Wm fysmpseaamp (If tsO tUmtI IsM $P shoroV4mmo knflkvnf (foOdme nuw ae Ow OImstwe in SM pnmm8 af tXm 10 114PIS kequoian wo Mpfii

SC~po umd spop~o VWt alm 4emWal 1 4ink PCmirsra M 1 ad AI 14bmms

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DIVISION 8-9-SOIL MINERALOGY

Amorphomw CeetIup en XmWra Ssrfmls

L C koits Am~ 0 tmmkaAf

ommp A faieiaAMTRACT skiwe lo nW ampM sm wi4h

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d m M 0bmSaImu M-1 ofM6 h Intun to 7I

aiba maush WAesshwn~u9dSg a osusLwpI ~ v m

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of~U -a~ mo uNo

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edi1 hswopmo an ag am Iw anom erlwaPASneooie bnwoM po

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ov4mnk wsi 9 Mxfeu~i am emwm ismi0wmd fq W No ~~ - f mug Aitowe eutlkowbmTV is

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~ -0

65

0IL CL OC AMXR PROC VOL 38 1974

)aT1 S4I104 ow Lusanll Tawng isa tall Thai variety known for beingIwo nonshyi s s ) sensitive to photoperiod A split-plot design was used in

S e e these euperimeots with 4 rates of P (I1 22 44 and 88t i V IV k of Pha) applied a main plot treatments and with the OF It sourMes of P as subplot treatments There were two checkS plots in each rmplicate The extra check plot was included to permit the application of fresh TSP standard Jor the

It- ti 06 + i bull fa succeeding crop the p-4me of bi was to permit accurate d awrnwal of the mdual effectiveness of the phosphate

ftinSUbI rock The P fertilioers were broadcast on the mud andthen Worporald In the soil during the last harrowing At

whM N both On ACS indx ampM time of transplanting Immediately before the last harrow61t (4j 5 4 01 P s 3Mm o Vallonal in con n 100 kgha of N as ammonium sulfate and 33 kghaWO Of Spews ampm lIW thaabe rocks do ACS indes of K as polium chloride were applied A total of 40 wa in prepw O do ctih k otent kha of N a ammoniunt sulfate was applied later in twoir P The hew oNed amp wM W for 5 of gw topdrossingp with about 5cm depth of water on the plotsvV I aiOMveffeOctveee Three to six ldayold selings pr hillwW the ACS idex were planted00OWW wia Oft fo an c irNk I p Coen 20 by 20 cm part in straight rows Hand weeding was used

and insecticide were applied for Insect control Grain yieldw was masared by sampling 5 ml of each plot excluding border rows The date of heading in each treatment and theUNiN d pbM W Weks rin tOW USA UMe In Tale yed componnts at hafvel were also recorded

I filM rsperMS esOM kdwdua 1 t ab The average yields of ough (unhulled) rice for botha 84 OW O 8uo 4 Thala TM was a locations are ploutel in PIS 3 for the first crop (1969 wet

owou thRM seaso0) The Veamps yield response was obtained at Klonge (s) W lDtO t Of dMa of1tw W d l R Luang however a 4ute satisfactory yield response was

~Mk ^d TVA UJSD ad Kd UnIveS obtalned to applied P at Bangkhen as wellXUe LaM e R qwrw Ims The sod was do Relative aponomlAe effectiveness values were calculated

VOW (a ksA w edmwL t Poesesm h Vy for these data and am presented In Table 3 The valuesdAY buo if dIe ouh ne Pee wtk a Mlak vow 1009 for th first crop are plotled against ACS index in Fig 41 This Im M i6ti l 4bNd IO a0 O mkarnk for both locatio r relationship was linear for the

11400 ThCpH 0( lb pW IW 01 th UpeiaW so Sanodion location and curtiltnear for KIng Luang The was u i 4A sksamp lMaor nrusio model amparounted for 81 of theAmO$MI Aw jAAsue Swim T1 Snh Wd variation In the AE valu for Bantkhen a square root

Mems a Iw iv fern alh$ sedm haowg dayNW W t he plAL At tdo M tM aso W s as ctminued throufh eltaM t Ofpof -le lse wo am P OeNI VeOpls 1o ealluae tI lon4erm MIdual Offccls

A on W isset i a wse to hsh eapeel of these ooihss t ocks The baagkhon experimnent was letmiaI1DlVemisthis is a w hulu Lo g Tasug ia iasael aft - Msd residual Ves will be pr-Om crok TheseTwod esewm

SWWo

A

lP~U~7 ISIIPe1iuIWN e bsedisssin ian ghth siaoelalbe

984 0 6 O O - M s -s fWPas 11eSft W d Uo al a o

o

S4l~ lIIII I~l I 1f fl

( +

+ + + m + ++++-

++ +(++ + ++++ + ++ ++

- 66 -

ENOIMLSTAD ET AL RESPONSE BY FLOODED RICE TO PHOSPHATE ROCKS VARYING IN CITRATE SOLUBILITY

I I I I j0 I I

BANOKHEN BANGKHEN

pH 56 6 - 0o

TSP

NC

5~ ~ ~ L o 4 - -shy

4 ] - --------shy04

6S

|0 III 2 44 8r 66

I I I

a 1KLONG LUANG

pH 46 z KLONG LUANG

TSP Sc2 NCFL(N)

5 FLIC) J0 TU

oshy

4 ~40shy

3 bull eM0

I - I I I I I

0 II 22 44 88 0 5 10 15 20 IP APPLIED KO HA ABSOLUTE CITRAE SOLUBIITY INDEX

Fig 3-Yield of rough rice at Klong Luang and Bangkhen Rice Fig 4-Relative agronon effectiveness () of P sources ploz-Experiment Stations Thalmand as affected by rate and Source ted against citrate solubity Index for both Thailand field ex

of P applied (crop 1) periment (first crop only)

regression model accounted for 97 of the variation in sumably resulted from crop uptake and reaction with the RAE values at the Klong Luang location soil to form less soluble products Such effects may have

These experiments were continued during the dry season been more important at the lower rates since the two TSP of early 1970 to ascertain the residual effectiveness of the curyes converged at the highest rate of application various sources applied to the first crop No new P was These data from KIong Luang indicate that (i) residual applied except for the fresh TSP standard mentioned effects of all rocks except Mlcwuri were substantial (ii) above rhe experiment otherwise was conducted in a man the relationship between relative agronornic effectiveness ner similar to that followed in the first crop of the phosphate rocks and citrate solubility levels was

The response to both freshly applied ad residual P was largely obscured and (iii) the general superiority of TSP marked at the Klong Luang location and marginal at over phosphate rock in terms of effectiveiss persisted Bangkhen In fact at the latter location the response was through the second crop so small that little can be said regarding residual effectiveshyness The yield data from crop 2 at the Klong Luang DISCUSSION experiment are plotted in Fig 5 Greenhouse and field data presented in this paper show

Relative agronomic effectiveness values (Table 3) were clearly that there are substantial differences among phosshycalculated for the Klong Luang data using both the residual and freshly applied TSP as standards It is of Interest to note that the superiority of TSP over the phosphbte rocks Table 3-Relative agronomic effective values for field experishyments in Thailand persisted through the second crop The main difference in KlowlZmlnql~the residual effects is that with the exception of the MIs- s Crop 1 Crop 21 Crop 1-shysouri rock Ihe marked relationship between citratr-soluble WoiCarolina yl 59 76

phosphate rocks and RAE had largely rds norh) a 64P conltct of th Florida (eqlral is 6969 6

disapipeared In this acidic soil (pHi 46) P would by this I14o 69 63 40 ToonesS 31 65

limo be supplied by Intermediate reaction products In addl Missou 0 o lion to residues of the initial spatlte Ts P o 2 o 0

The TSP applied to the first crop declliv-d slightly In campIafcmWataesr e id ofeuhuloefor 22MA rates of PtColeouattd as aba u tlte td18 kS ratesp dlverage yield tM868 to 22 44

effectiveness relative to the freshly applied ISP This pre- of d s4

A

4

- 67 shy

-SOIL SCL SOC AMER I

KLONG LUANG CROP 2

Si 3

eN

TAPPLIEDKGHA

Fig 5-The residual effectiveness ovarious P sources for crop s compared with freshly applied TSP Klong Luang Rice

Experiment Station Thailand

phate rocks in terms of agronomic effectiveness for flooded

rice Further these differences can be predicted by means of citrate solubility or by the ACS index It appears that

the latter is more appropriate where the content of apatite varies among phospiate rocks The most soluble phosphate rocks approached but did not actually equal TSP in limit-iuig (maximum) yield in these experiments regardless of rate applied This agrees with the results of Ensminger Pearson and Armiger (4) One needs to consider the defi-nite posribility of same yield loss in zhoosing a phosphate

rock over TSP such yield losses must be weighed against the lower price of phosphate rock The explanation for such iosses may involve concentration of soluble P in the soil Khasawneh and Copeland (6) suggest that the growth rate of crop plants is a function of P concentration that can be maintained in the soil solution If P concentration is limiting or inadequate becawe of a lower dissolution rate of phosphate rock the growth iate ard uiiimate yield will be diminished accordingly

The RAE values bascd on yield increases reflect the agronomi effectiveness of these various sources relacve

to the TSP standard however these nould be supple-

mented by an economic analysis before rational choice can

be made The following calculations will provide an estimate of

the rclativ ecooomic effectiveness(REE)

Y t Ps aXpatREE -- 100

vahtercks t sphate or e b i- eor

Price of TSPkg fo

be Price of PRkg P

PROC VOL 38 1974 leO

90r

Wsoshy

0

60-LUSEPHOSPHATE ROCK

00 10 20

PTP PR

Fig 6-Relationship between relaZive effectiveness values (RAE) and the price ratios between TSP and phosphate rock Such a figure can be used in making a choice between these

sources

If REE exceeds 100 in this calculation the phosphate rock would be preferable to TSP

The REE calcuktaaa wre used in preparing an indifshyference curve (Fig 6) wherein RAE values are plotted

against PTsPPpR ratios The cu~rve itself connects those points at which REE equals 100 When exactly on the curve it makes no real economic difference what source is chosen After choosing a suitable price ratio one can then project upward from that ratio knowing the RAI

value (or estimating it from such data as shown in Fig 4 using citrate-soluble P content) one can then choose the source on the basis of both agronomic and economic conshysiderations For example if the price ratio is 25 and the RAE value of the phosphaite rock is greater than 40 the rock phosphate in question would be used However if the RAE value was less than 40 TSP would be a better choice There are indications that if the P in the more soluble phosphate ro~cks (North Carolina north Florida central Forida) is less than half as expensivz as that in TSP these rocks would be feasible altereaives to TSP on soils similar

to thoseused in Thailand This analysis does not take into account the possibility

of lower yields from use of phosphate rock In addition only a portion of the various yield response curves was used in this anlysis ie up to 22 kgha Beyond this

rate yield response was much less pronounced it could be argued that at less than maximum yields TSP would produce a certain yield at lower rates of P than would phosshy

pow ofrock This would especially be true for rates applioa example at Klong Luang 5500 kg of

rice pcr iectare could have been produced with either Ii kg of P as TSP or 44 kg of P as son of the more reacshy

tire phosphate rocks It should be pointed ot however

- 68 shy

(IIKIS amp YOUN( ARIFICIAL WEATIIERING OF OXIDIZED p[ll- IV

that this is the yield level that would show the widest difference such is the advantage of hindsight

Farmers generally prefer granular fertilizers for machine

or hand application This is a disadvantage for the phos-phate rocks which are normally arplied in finely divided form Recently experimental quantities of granular urea-

phosphate rock mixtures have been made by TVA Results of trials with these fertilizers will be reported elsewhere

LITERATURE CITED

1 Armiger W H and Maurice- Fried 1957 The plantavailability of various sources of phosphate rock Soil Sci Soc Amer Proc 21183-188

2 Bengston G W E C Sample and S E Allen 1974 Re-sponso of slash pine seedlings to P sGurces of varying ci-trato solubility Plant Soil (In press)

3 Caro JIt and W Hill 1956 Chard eristics and fer tilizcr value of phosphate rock from different fields J Agr Food Chem 4684-687

4 Ensminger I E R W Peirson and W II Atmiger1967 Effectivencs of rock phosphate as a source of phosshyphurus for plants US Dep Agr ARS Bull 4112S

5 Engelstad 0 P J G Getsinger anid I J Stangel 1972 Tailoring of fertiliers for rice cnnece Valley Author ftyNational Fertilicr Developmnent Center Hull Y-52

6 Khasawnch F E and Jane P Copcland 1971 (otton root growth and uptake of nutrievos relation oif phosph

rus uptake to quantity intensity and buffering capacit) Soil Sci Soc Amer Proc 37250-254

7 Lehr JR and G H McClellan 1972 A revised lIbora tory reactivity scale for evaljativg phosphate rocks for direct application Tennessee Valley Authcrity National Fertilizer Development Center lull Y-43

H Terman G L S EAllen and 0 P Engelstad 1970 Response by paddy cice to ratcs and suurces of appliedphosphorus Agron J63390-394

DIVISION S-9-SOIL MINERALOGY

Artificial Weathering of Oxidized Biotite IV The Inhibitory Effect of Potassium on Dissolution llate

R JGILKES AND R C YOUNG2

ABSTRACT

Rates of dissolution of oxidized biotites in OIM 001M ICI are severely depressed in the presence of IM KCI The amovnts of Al Mg Mn dissolved in the first eytraction are similir to those found without KCI however subsequent extractions remove these elements at 10-20 of the corresponding lICI rates This effect may be due to a decreased rate of vermiculite formation thereby reducing the effective basal area exposed to attack A decrease in dissolution rate with increasing ferric iron content was still apparent in the presence of IM KCI

Additional Index Words X-ray diffraction infrared aborp-

N EARLIER papers of this series the tole of biotite in soils

as a source of both macro and micronutrient elements

has been discussed ((Gilkes Young and Quirk 1972 1973ab) Experiments in artificial weathering uiing as va-

riety of extractants were undertaken to determiie the inlu-

ence of oxidation of octahedrally coordinated iron on the bull release of structural cations to solution The results of this

work demonstated that biotite behaves anomalously with respect to the other common ferromagnesian minerals found in soils Oxidation leads to the development of a high degree of resistance to cation exchange and dissolution Several authors have coiwludcd that decreased rates of K

Contribution from the Dep of Soi Science and Plant Nutri-tion Institute of Agriculture Univ of Western Australia Ned-lands 6009 Western Australia Received 29 Sept 1973 Ap-proved 8 Jan 1974

2 Senior Lecturer in Soil Science and Research Officer respeclively

replacement in electrolytes shown by oxidized biotites are

a result of the inclination of structural hydroxyl adjacent to newly created trivalent iron or vacant octahedral cation sites (Robert and Pedro 1959 Barshad and Kishk 1968) Gilkes et al (1973b) suggested that decreased rates of disshysolution of oxidized biotite in 0001 0t)l 0Af CI may also be due to the presence of inclined hydroxyl In this case a smaller surface area external and exposed intershylayer may be available for attack if K replacement by hyshydrogen ions occurs at a slower rate in oxidized biotites

Gastuche (1963) has shown that significant dissolution ofthe (IIM) biotile face may occur and it is easily demonshystrated that the proportion of exposed (001M) face in weathering biotites depends on the percentage K replaced

Rausell-Colom ct al (1965) have shown that hydrogen ions act in an identical fashion to metal cations in K exshy

change from micas In particular exchange c-f K by hydroshy

gen ions will be terminated or greatly reduced by high levels of K in solution Thus if dissolution of oxidized biotite by

acids is carried out at sufficiently high K levels to prevent vermiculization any differences in dissolution rate that may occur cannot simply be ascribed to differences in rates of K replacement The following results were obtained from such an experiment which unlike the experiment described in Parts I and II (Gilkes et al 1973ab) does not attempt to simulate natuiral - conditions

MATERIAILS AN) M HIiODS Further subsamples of the less than 0 hiotites used in K

excherandbaid disoo tu es (G iles e9n K exchange and acid dissolution studies (Gilkes et al1973ab) were used in these experiments Preparation of sequentiallyoxidized biotites without intermediate vermiculite formation is

Page 14: I70 - United States Agency for International Developmentto ascertan, but tgl.eetad, 1, L,. ("Tailoring of Pertiltiters for ice,'" TVA ulletin Y-52) states that the staft of IOi has

PROJECT PLANS FORFISCAL 1975

In this section the work for fiscal 1975 will be discussed

It should be remembered that the success of this project depends in a

large part upon maintaining sufficient flexibility so that work in inshy

dividual countries can be adapted to supplement and complement programs

already under way While guidelines and plans of work must be developed

so that the objectives of the project are clearly defined detailed

plans for specific countries or groups of countries must be developed

by consultation wth local cooperators

These plans will be discussed under the following three general

phases of the project

I Engineering and development

2 Agronomic testing and evaluation

3 Economic evaluations

Engineering and Development

Phosphate Rock

Methods have been proposed for relatively simple treatment of

phosphate rock (PR) to increase the availability of the phosphate to make

it more suitable for direct application to the soil These treatments

may be economically feasible in certain areas especially in view of the

current world fertilizer situation Considerable work has been done at

TVA studying means of altering PR and plans are being developed to inishy

tiate further developmental work and field testing of these materials durshy

ing fiscal 1975

- 12 -

Emphasis will be placed upon obtaining samples of phosphate

rock from deposits in developing countries and testing and improving

procedures for increasing their citrate solubility and tzius availabilshy

ity of the phosphorus From this laboratory screening process sevural

sources will be selected from which small amounts (50 to 100 pounds)

will be prepared for greenhouse and field experiments ou various soils

(as described under agronomic section)

From these results one or two locations (or countries) will

be selected for development of a pilot program to utilize local sources

of phosphate rock This program will involve production of the altered

PR and its agronomic evaluation and then educational programs with govshy

ernment and commercial representatives to introduce its use to the farmers

Sulfur-Coated Fertilizers

Some preliminary work has been done in which urea-potash mixshy

tures were coated with sulfur The 7-day release rates for the N and

K20 were 17 and 36 respectively from the coated product (22-0-11-30S

grade) This was the first effort in coating a compound fertilizer

with the new coating system

The widely differing release rates for the nutrients from

the coated compound product raise some interesting prospects for tailshy

oring the nutrient release rate of sulfur-coated products It might

be possible to cogranulate materials of varying water solubility and

sulfur-coat them to produce products with release rates that would apshy

proximate the timing of nutrient requirements of the crop The need

for this type of controlled-release product has been mentioned many

times by agronomists and may be especially applicable in multiple and

intercropping systems

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Table 2

Mttct of 0 Sourco aampW $At On Upt~ks of 0 by Two Varitgtos of Paddy Rice

gr~a 1971

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- 24 shy

India--The results of four experiments conducted with flooded

transplanted rice in India by the All-India Coordinated Rice Project

Hyderabad are given in table 3 The response to N was excellent the

yield without N being only 41 of those obtained with basal applications

of N as uza With basal applications of SCU the yields were 20 higher

than with basal applications of urea and in the three experiments in

which urea applications were split yields with SCU were 18 higher than

yields with split applications of urea When comparing the average Nshy

response (kamp grainKg N) yields were increased 13 more by SCU than by

basal applications of urea

The data from one experiment with light irrigated rice in India

are given in table 4 yields were relatively low and differences between

N sources or method of application were not significant However yields

with SU tended to be higher than when all urea was applied at planting

but lower than when split applications of urea were applied Again yields

increased more than 13 more with SCU than with basal applications ofwere

ur

In tables 5 and 6 the yields of a short-duration transplanted

rice grown in irrigated light-textured soils at five locations in India

indicate that higher yields were obtained with SCU than with urea when apshy

plied as a basal application Yield increases due to basal N applications

were 502 greater with SCU than with urea However split applications of

resulted in yields equal to those obtained with basal applications ofurea

CU

The yields of direct-seeded upland rice grown at three locations

to India are given in table 7 and the relative yields in table 8 Yields

were low due to drought but good responses were nevertheless obtained for

- 25 -

Table 3

Effect of N Source and Time of Application on Yield of Paddy (Flooded) Rice in India 1972 (Summary of Reported Data from 4 Experiments)

Experimental Number Source Rate Method Yield Relative N-Response

and of of N of Yield Kg Grain

Season Nitrogen kgha Application mtha Kg N

- - - 196 34 -

Urea 120 Basal 573 100 314

11 Urea 120 80 + 40 611 107 345 Rabi SCU 120 Basal 713 124 430

12 - 0 - 202 30 -

Urea 125 Basal 682 100 384

Rabi Urea 125 35 + 20 + 35 + 35 633 95 344 SCU 125 Basal 781 115 463

13- 0 - 168 44

Urea 100 Basal 385 100 217

Kharif Urea 100 30 + 20 + 25 + 25 400 104 232 SCU 100 Basal 462 120 293

14 -

Urea -

125 -

Basal 355 650

55 100

-

236

Rabi SCU 125 Basal 781 120 341

-- 26 -

Table 4

Effect of N Source and Time of Application on Yield of Light Irrigated Rice in India 1972 (Summary of Reported Data From

One Experiment at Pattambi)

Experimental Number Source Rate Method Yield Relative N-Response

and of of N of Yield Kg Grain Season Nitrogen (kgha) Application (mtha) Q) Kg N

38 0 - 204 85 -Rabi Urea 120 Basal 241 100 308

Urea 120 60 + 0 + 30 + 30 267 ill 525 SCU 120 Basal 255 106 425

Table 5

Effect of N Source and Time of Application on Yields of Short-Duration Transplanted lice Variety Grown on Irrigated Light-Textured Soils at 5 Locations in India 1972

(Snmzarized From Reported Data)

Rate Grain Yields (MtHa) Source of N Method of N GrainI of N kgh Application Faizabod Karjat Mandva Pattabi laya Averaje X

- 291 266 211 19 340 260 -

Urea 100 Basal 386 407 361 285 482 3 124 Urea 100 50 + 25 + 25 399 430 434 334 6amp2 4A8 186

SCU 100 Basal 368 468 439 360 572 41 181

Table 6

Effect of I Source end Tlae of ApplIcattoo c RIstave Tle24 of a rt- rat1 T Lsd lice Vasrety Crin o Irrigated L41tshy1 at S Locitite mindi 1972

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- 38 -

Table 18

Yild of aemati-370 Rice at Punjab Agricultural Research

Institute in Pakistan in 1969-70 Grown Under

Couditions of Intermittent Flooding

Pate of application

=IL

o 0 67 67 100 100 67 67

100 100 67 67 200 100

Average for Sources

Ntha

AS 260 gres 279

320

Source f5

-

AS AS Ura Urea SCU SCU

Yield

Relative

93 100 115

(M)O

Yield

Increase Yield Due to N

(Ktlha) (mtha)

-212 245 033 274 062 260 048 297 085 315 103 325 112

Yield Increase

Relative

72048 067 100 108 161

(2)

- 39 shy

Short-statured high yielding rice varieties grown extenshy

sively in northern Peru require extremely high rates of conventional

N sources to achieve maximum yields The recovery of applied N is

extremely low due to the use of intermittent flooding This water

management system results in heavy N losses even with properly timed

split applications In search of simpler and more effective methods

of N management eight field experiments were conducted in the region

to evaluate sulfur-coated urea (SCU) an experimental slow-release N

source supplied by the Tennessee Valley Authority Rice yields were

increased an average of 59 more by pretransplant-incorporated SCU than

by urea or ammonium sulfate applied in the same manner SCU produced

excessive vegetative growth which resulted in yield reductions at high

N rates

Regardless of an assumed 48-higher unit N cost in SCU the

overall benefits of pretransplant-incorporated applications of SCU

were favorable since there was a decrease of 40 in the optimum rate

of N and the need for precise timing of application was eliminated

Pakistan--In Pakistan basal applications of AS urea and

SCU to rice grown under conditions of intermittent flooding in 1969-70

(table 18) indicate that SCU is a superior source of N as compared to

urea or AS when all N is applied at or before planting The data also

indicate that a yield response was obtained for P applications but a

comparison of N sources at each level of P indicates that no interaction

between N and P was present so that differences between N sources were

relatively the same at each level of P Yields were increased about 60

more when SCU was applied than when urea was applied Yield increases

with AS were only about 72 of the increase obtained with urea these reshy

sults do not agree with the generally-reported superiority of AS as comshy

pared to urea as a source of N for rice

- 40 -

In 1973 experiments were conducted in Pakistan using both

Basmati-370 and IRRI-6 varieties of rice grown under conditions of

When all N was applied at puddlingintermittent flooding (table 19)

or 12 at puddling and 12 at panicle initiation both AS and SCU were

superior to urea with SCU tending to be the most efficient source

However when N was applied 12 at transplanting and 12 at panicle

initiation SCU was the poorest source of N This would indicate that

the release of N from SCU applied at these times is too slow for optimwn

plant growth

In another experiment in Pakistan in 1973 no differences

in the effectiveness of urea AS or SCU were noted in the yields of

continuously-flooded rice (table 20) Again these results are conshy

sistent with earlier results which indicate no superiority for SCU

when rice is continuously flooded

Nitrogen Studies--Maize

A series of three experiments were conducted by IITA in

armo-Nigeria in 1972-73 comparing AS urea SCU and

CAN (calcium

nium nitrate) as sources of N for maize (table 21) A significant

yield response was obtained for N at each location but no conaistent

differences were noted amaong sources These results are consistent

with results at other locations which have not shown that SCU is a

superior source of N for maize grown over a period of 3 to 4 months

Nitrogen--Wheat

The yields of wheat in Pakistan in 1969-70 (tables 22 and

23) show that yields with SCU) tended to be lower than those with ureaJ

although at one locction where sorghum was grown followilng wheat with

Table 19

Yields of Basmati-370 and IRRI-6 Rice at Punjab Agricultural Experiment Station in Pakistan in 1973 Under

Conditions of Intermittent Flooding

Rate Yield Source of N Time of Yield (Mtha) Increase of N B-370 IRRI-6 Application Basmati-370 IRRI-6 Average (Mtha)

0 0 - 21 353 287 -

SCU 90 150 At Puddling 325 545 435 148

Urea 90 150 At Puddling 309 500 405 118

AS 90 150 At Puddling 324 529 427 140

SCU 90 150 Puddling 372 572 472 185 Panicle Initiation

Urea 90 150 Puddling 335 502 419 132 Panicle Initiation

AS 90 150 Puddling 353 529 441 154 Panicle Initiation

SCU 90 150 After Transplanting 312 562 437 150 Panicle Initiation

Urea 90 150 After Transplanting 340 624 482 195 Panicle Initiation

AS 90 150 After Transplanting 349 583 466 179 Panicle Initiation

All plots received 45 lbs P205acre as single superphosphate

Relative Yield Increase ()

Source of N At Puddling Puddling Panicle Transplant h Panicle

Urea 100 100 100 AS 119 117 92 SCU 125 140 77

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-48

Therean laiictw that It lbs P to th e am lukis

obosomhu rocks 0entk catetas rth Unrtdo costrat frwt) to

ht tse balt s Owosiv as that to TwP it rocks WM bo

fmtbt alteruutiv to MSso gotastte to~ Ik lee used to

ThUAIAd

Tht wMl dt gotmtmlaoti wout th possibility

of law Vhld free ww e1 e66001 4 It cooUt be YgWd Sutt

a4 10 0410 SWUSSM yt$4e TOP wUd predWr A r~ftIf fl~W t

1f f ot P the wuld phosphae rck TWOe viWMW efocitill b

true to low rttos t tsplusatiI P wi 9 Ma Liiam $S

amp4at r per Wforssota Mav two 64eed Wilk elikor It 44 of

P go Mi er 4A bg oftoP aon of tewmrowtni pboophals fwAh

It vwld be polotrd A Wevero wtht Is the jteld level that

W414 gk tko videm dtterem~j o(A 1 the 4~etamp tk~e~t

P11~0 pra~lpj prefer gre4r tuftlter for whlae

of hoaw ppltrstie Mhe to a dloedveaP for The PINSOO rocka

vkth m r II spotted 10 ftewil 4106Me tem

Nub studios we ovsosd o IVA vol gramleid a

forgof wee aMW pbsepbots A fths pemhawe evsielew us

Odellod to detMlee it otteettvmm of 11agotated Stoture of

mmfp MW phapa A (CI) sed graewletod pampAtlti arlolatod Pa

asowcs of P tof ttde ro The wreem proucts omre raGther

pemour~a ot P syag besmti andMi as elt ov so gpamwhr

iuipiqffhate(TS) low twseeo Is eftwiltve Is thet

W41 preeme wae oialain ire post-rItoi effriq to Stanlato the

pud6itt of Irto paddle Wee ofsdlseireplastiq

0 49 shy

lbs partially scldiaatede grawilated Ml prodlucts Vere isshy

toiwdiats in 5tftOvttWS54 betwee wroiPi ad TVP NotV5Ymf to

me coo were they mere twoe $a a etfective ao TIP 00 sipifleast

LVSUMI5 at0 efecto wore toun tor thee produteo Timely dtIampWde

FR (-t00 mmoh) Uia amp~rally oar affective than Owe gra8448r FOampprodt

featal twos o 6 aotetire s I

Nowvero it to felt that sfortber field euprtet vth

hese interials Amd ether typs of grometatodl Wter nre wrrautad

hater ceeuwodh that they have me areec poteatlal toi additoG

e tate wAne the sectte as OtawrI sed bovoloen turther

euperimeste vth few reck pboophar s0d with reck pbophat treated

to sehesa citrata selmtliy or to ha csaducted

Metbir sertes of tbme enprtaeats wae c~edtmcted by IITA

to Ut~rta copal TVP AOP APP aed it at see tecastisix (table 14)

No dot lalt sewseltles teh draw tree thee results simouely em pear to tlvdl bsww they do stwgpt tbat forthew work with

MR to werramid so tbme sels

Table 24

LttcttF Swce MaPlate 06 ieldot IM AWaia CoelsANS at IITA (Ugboda ad Apoin ail sorit) aid at Ike (AUaba s5i series)

1973

Plate ot IP Apinu 5 poundebods A1ab

Ocrol 0 Z94 419 M)

Tr ipl ruprphite 20 349 3799378

Triple vepput 40 M09 410$

Triple 6wp~~b1 4271 4344 42250

Ammotw-ritpophW to 4201 4124 4040

Amosim-rdop~phlt 40 4270 4106 4231

AM tuo-polpephats 20 404 4244 3794

~eai~mpelppepbuI 400)49 4094

Cee m-pbpbt to- 59

momee eph lto 0 4192

LSO (0 0$) 29 1025

Th WPII

- 51 shy

101Y114 tpeM-fI PEP~tbRP YO

1 ~ ~ gmw 1pc~biofl- 9 Kla4v4h

Upia U04 Copfind am Crehout Stet Rpano at (Ia4

rico t IF t rume6 orth~ Caralto phoophale rocl QAR) vaUN pqU41 to

roopon from cmonetrat4 gsporphophai (CIP) who ort$o4 oil k

was 45j itwas tafertor vb protioo4 oil p war OS Ib 4iffer~c

in rtc reepos to X cod14 oo bo ttrit4 4 4 hvsciag of boil p

~ Pt o r11221 0 tP

c theto the rhimecyllndor of rico tots par to)14M4i1 roeoi~t

ed oil emd PA prior to tho ont of an~robi4 cMioe AA~ oIifoshy

nAte bYpot t taet~d tO fC4sin t~r 4PWden0 Of f Ot(tivshy

ofOWailiJtyno o prefla4 all Put that 4t01etoo 14 tvsIk

of the Ott to prvvld a 014for C4m0 44 mI 1 o4sf

EfftC ftPet141on AIAM-0 V f401td 4 4iv 440 Mtft

Aa torfat VampP f4MWfCi4W04wt0amp to 4eturWlI Ot(Wel~drIC ft

Ot f tM6 the flooded Ott 00 14 04019I Pft0uAw Of gAr~s~lr

pkS$t M40b MP) Tw P1101 Piset Prodwie W-e 10M0di Wr04

(10-1) emW 0aretilp ddw01at4 P WAA firom Rrth M~flRU414~$

wee cowiared with fie Md reWim 44104 proo~fo) foruk oith laWItter

I v te-PR P OW1004 4 4 O Wf ottil OW ellt Oo

Oveiel1 the 40tt dmcruie to effetotww Wtollowui Co fme

PR tpaUIB1I ldoltmo PR (pamwlatr) offr~- ArmeuM) 0 orwi

- 52 -

Effect of N Sourc6 and Water Management on Response of Rice

toe Zn- M Giordano J J Mortvedt OP Engelstad and Greenhouse

Staff Several rotes of CO(14H2)2 and (H )2So4 vith or without ZnO

wore applied to flooded and nonflooded Crowley oil (limed to pH 75)

to determine response of Bluebelle rice to Zn Yields with both N

sources veotrgreator on flooded then on nonflooded soil In the abshy

ence of applied Zn total dry matter production vith CO(NH2)2 was

slightly lower than with (NH)2S04 on flooded soil and considerably

lover on nonflooded soil Concentration of Zn wan higher in straw and

grain of plants roun on flooded than on nonflooded soil Although

concentration of P was unaffected by N source or Zn rate there was

som indication that cranslocation of P from straw to grain may be

depressed in nouflooded rice Concentration of N was lower in straw

grown on flooded than on nonflooded soil due to apparent dilution

thereas both X sources resulted in similar N concentrations in straw

at all rates of N application the N concentration in grain increased

with 0 rAse

feSpongi gf(SM to Chjorospodiostte and Related P Sources--

Si Allen and Greonhoue Staff A greenhouse pot experiment was

couct44d with corn Brown on Hountview silt loam to compare the ofshy

fectlivees of chlorospodiosito (Chlor-l) with concentrated supershy

phosphate (CP) Thomas slag and North Carolina phosphate rock (NC-PR)

Oil-prillad urea-phophato rock (UPI) FeA1JMP 20 7 and monomthyl

phosphate were included in the experiment Based on yield of forage and

uptake of P by tvo crops each of 6-weeks duration the following conshy

stui were dravat

I Chlor-1 was slightly loss effective than CSI Thomas slaS or NC-PR

from which Chlor-l wae prepared

- 53 shy

2 Granular UPR was a poor source of P its effectiveness was greatly

increased by reducing the particle size to -35mesh

3 FeAlNH4P207 was unavailable to the crop

4 Monomethyl phosphate was equivalent toor slightly more effective-

than CSP

Research Indirectly Related to TVA-AID Project

Response of Several Rice Varieties to Zn in Moist or Flooded

Soil--P M Giordano J J Mortvedt and Greenhouse Several varieties

of rice from Mexico and the Dominican Republic currently under investishy

gation in Puerto Rico for adaptation to upland culture were compared with

some established United States varieties with regard to Zn response on

moist and flooded Crowley sil (pH 75) Chontalpa (Mexico) Bluebelle

(Texas) and Starbonnet (Arkansas) were most responsive to applied Zn

Juma (Dominican Republic) intermediate and Sinaloa (Mexico) and Calrose

(California) were the least responsive The Sinaloa varieties (Mexico)

appeared to be best adapted to non-flooded conditions whereas Chontalpa

and Calrose were poorest Concentrations of Zn generally were higher in

plants grown on flooded than moist soil

Pattern of Growth and Zinc Accumulation by Rice--P M Giordano

J J Mortvedt and Greenhouse Staff Rice plants were harvested at weekly

intervals from shortly after emergence through maturity The objective

was to determine the rate of growth and Zn uptake by a Zn responsive varshy

iety (Bluebelle) and a less Zn-responsive variety (Calrose) in the presence

or absence of Zn applied to Crowley sil (pHl 75) Dry matter production

of Calrose was linear with time of growth and of a similar magnitude until

heading with or without applied Zn Bluebelle followed a similar pattern

where Zn was applied However in the absence of applied Zn foliage yield

was reduced markedly

-54

Uptake of Zn was similar for both varieties whenZn was

applied Dry matter production and Zn uptake by the two varieties

also were comparable when Zn was applied However yield of Calrose

was much higher than that of Bluebelle in the absence of applied Zn

while Zn uptake was only slightly higher This suggests that the lesshy

ser responsiveness of Calrose to Zn may be due to more efficient utilishy

zation of Zn There was no indication of a greater demand for Zn durshy

ing reproduction in either variety as was suggested in earlier greenshy

house experiments

Response of Upland Rice to P and Zn--P M Giordano J J

Mortvedt and Greenhouse Staff Several rates of P and Zn were applied

to Crowley sil (limed to pH 75) in factorial combination to determine

whether differences in rice growth under flooded and nonflooded soil

conditions are related to plant nutrition Although straw yields were

slightly higher in nonflooded rice receiving adequate P and Zn grain

yields were higher in the flooded crop increased rates of F andor Zn

did not result in equal yields Except in the highest Zn rate (75 mg)

concentrations of Zn in both straw and grain were higher with flooding

Concentration of P increased with rate of applied P and was higher in

the grain or flooded than upland rice at a comparable P rate In conshy

trast concentrations of N were lower with flooding due in part to dilshy

ution from increased growth

Rice Response to N and P in Flooded and Unflooded Cultures--

G L Terman S E Allen and Greenhouse-Analytical Staff Rates of

N from 250 to 2000 ntpot and P from 0 to 1000 mtpot were applied for

Nato rice grown on Mountview sil and Sango sicl (625 kg of soil per

pot) Market yield response to N and P was obtained Yields of straw

- 55 shy

total yields N uptake and N recovery were higher on unflooded than

on flooded soil cultures Grain yields however were slightly higher

with flooding These results indicate that with adequate applied

nutrients especially of N rice yields without flooding can approach

or even equal those under flooding

Uptake of N P Ca Mg and Zn increased with yield response

to N and P while K uptake decreased on the Mountview soil Concentrations

of N and P increased with applied N and P respectively while concentrations

of other nutrients were diluted in most situations with yield response to N

or P

Results from this experiment show that amouats of N applied in

previous pot experiments for rice have been much too low especially if the

crop was grown to maturity

Response of Corn to S and N i UUASand Urea-S--S E Allen

and Greenhouse Staff Three greenhouse pot experiments were conducted to

measure response to S and N in ulfur coated urea (SCU) urea amonium

sulfate (UAS) and urea -S as well as estimate N losses from surface apshy

plied N sources

In Experiment 260 less than 20 of the S mixed with the soil

was recovered from SCU or urea-S granules by two crops of corn as comshy

pared to 45 or 80 from flowers of S or Na2SO 4 CLop response followed

a similar pattern

In Experiment 260-A N sources were surface applied and alshy

lowed to dry for two weeks before incorporation Into the soil and plantshy

ing Recovery of N by two crops of corn was 77-82 for AN an compared

to 37-70 for urea UAS urea-S and ICU Thus n this experiment loss

of N from urea did not appear to be re~dcud by light S-coatlngn or by Inshy

corporating S or AS in the granules

-S -

I xbprZnSlt a Wtch aU Meyto 0-Ai Wt f9r

higher reermo teOrtOrs cOM reSpWNO i r0100 Of N w

not oaisteontly related to sewe ot N In edl tust 0 ioltiUe Lim

lo in VMuwpped evlmtUTS 48 merind by seirest nte appresOehe

501 for uroa as cwarod to 210 for urea peepha

Rus- or Upse to LoAmIl34I a AriMed bI Earl U

MW NOWlsIIsIr-4 L Toman 5 1 Alln and eesese StNf rio

row on Sawg did (0 tpot) We 1l0l0 Ws feritiud vith 05is

of Npot mixod with the 6011 as aureCA NiAO) 1 Age god At Ures

was also itcluded at rtt t 05 10 end 15 of Upee Theas trealshy

onto were followed 4 wpdrsetago of U s AN wre 4C 10o or at I3n

Weeks toulin up to IS pot

A soil application of 10 pot rosulvod to the maim yield

at 4 weeks Tio4 sad percont prottis t intre raite tncreased rftishy

linearly with U applictalien IeseeItally all at the m iNd wit

the moil w domitrifted after flooding Grail end straw Ilelds vere

highly correlatod with tiliriag and vlh ubers of gralm arl

The results Widicat that 0$ to 10 a of Upot as orea or

NN bsuld be sied with the oil to stilate tiilrir with adshy

ditional 0 topireased later to increase grain lIds mad protia cmshy

tout

DIVISION 54- FERTILIZER TECHNOLOGY AND USE

N$eumWe of Mt5p4Amomd 1k PindW hswk4PhI fl fRw cW ims we

Jmnwacr VW owm m

a~~00 - 0 6 A-~ -~~ PN 40OMOM X 00 Wolm n moo mot $Pto4I 4l 4 W

1 -0 Is vom omoo ~~o - W1 sfw 4E00-aU

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-n-t -4adf -m W ftf

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i A ~~~~06o ~a A VOW 4 WK-ok rie Ww -0 no 4me

00 to- W 0Nwo ww AO t

-t umi om ftaw-0

- - lh -i N N iiSolf so -ma w vow -mv__M

-~AdAjA- 44 ow 0ma 0MAW a war -mo d0 00 M o WooP 0

0kR N4 a~ow Mf o

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_______Noon_Iamp__ arn ag bos m W we ap

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mod m m406mi 1m towir - m bowI~~~AV UPuiWd a04aup hwu 000sW~11lito -- o ~ImWq mow~gnn w a ho emotwi

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ICU wONMOVAON w4wWR - - o 44 O Tha 40 pu4 am

hum 11 is 4111 s - sg am VW f wq 4WuM dhCi m ehamv alpso 0

-w No memwiauu so-s 1141 -f oer wwn malow Wufmmm inM UCd m I a to dip 90

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ff~~~- am diwda Vs Wow at 4g eltpowm woo OI teeMA AMamdmOMisan A d1 Tm WNW m4 uwwemm mmmM

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opoOw suf No~ Ow MW MCI pt~bi asiwhNd bl-d muim of woo w NN

toI4 0 06d 00 wo A Md N WILSAl DuIKWION oo A Nw U am ONq ep

ow VAN pmw amp4 li a4 WdUb p vw sopwaft a-ftgw -ee theptd OW 6 - a

at MW em matshyW M offm of4 W twampwmwausoo wo asdm65m Auamp Ahbwu in 4ih asTal ON~ al oem IN Maie dmAd A a own did ofe w17 I inM mimman Ofd ofimruwf gas Pius di aMe Kwe auw a dow iNPOOIN tmo a SO$SO~4W

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ase appuadmen 44 ea ad semk Who pm4WWS lowftsIU wo WOMO dobowl ICUSJW h

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pro alfp al 0 WN Is obaml~ of th es Wls pouvy Ofts oeWMed N

$ae fapree ulesaseup IfIwotohaffe St

40WilinAn 06 kw Ma ho 00 e IW aftakrw splerefAnhffsb m esmem

I$Ow Ip ampMI pasi 1ead eu an Toud 2l

Widj 6vi of V46 745WI KU waso-W im Wow 0 is610SWAOMMwasa to t

VAp 1Mampd KV ppu~s dw whaim $i a a los Al w W

Ib Milvo urns of OWe d- musA as h~ s a IuIow 8 1 ue ip

-Wlidswf of 4 ofatsIW5vsS d M M5 i RSa pm~daps In ampup 1Powworw rue hevi A b

el eas goileN ruseW4 wo duffeeme bWOM isttouwi

14 gnp40 woSalrw 11ylo amreu Mwb Isevlow roosmN~ahIt s 60 W ~tsmAIM L n ~ ~~ ~

MM I PWrawA = rMla yowIeM oa

eUW as ymlh OW by IONamph avWlbl N The mubsr 1MM Pude M~ IsA aemOWeld

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por bre

wals rIs O touprua KU=plaINamppNOMeses a

W UWhk 0 ASOoml ft A poWsdvutA adesae of amr Wns ai A 0r- 1ampdd Oehs IuRawy NO Pue podllosWewwe gmak asmpnle by dMiss is amle OWN pet -W yid I MuC)ad ampAn (WiplaeT16s mOW aOW aNo fhr ft ymIed------ obealud w3t 0 OW 40IsA a VM bpR ofthW d saw ns m aI efes R 24 ad 7

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Tile 4-00dw x uiampOW74u 0qee of

_____k _ _ shy

~ - 56I 5

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Tiles I sed I thm Au do sel oeppled upaoIks WIM0 0da ispI amd us Ou s 106 kg

h Eaap 8n 14 sMsa of abw~greuad PU Pau WW 1 u itb IUKho 0aaphelem s 60 Otarlmmh At ~ 0sU Ishiseoo Cook oiA N uiplasu mAasslaly abess A leel

v doese a WKWye Is ks Nha m 6 sa4to dafo aONmuw The appee swm Wsssof adde N4 alalaed by vuMb ifaa W C Was sekilumganSro Is

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owdb imto US Wh s vs sf 3I mld 54S fro 2 aMd 3) A A

valves a hevwae u Iar Walh basl oswas dhe uwpatr bshava of

tb~msusasl appkausu of ofta sede s have aoweN

TOW opl taoe for AieweeW 4OsmWMbas Op peas As Tabl 4 sling sob Os awowully eom grams Piel level Thes oeulam Ma sed as IM

-02

792 60L WI W A)49R Pio VOL 37 197)

primS o r OeampAd WU toa Them fl~ w At NOSSe earno maisslea Ia N he mOWamplIO yik ampWd IMe aampWmW OWa Owe wa UMs of KU to 41 Oke ampWiiIamm be dkrnety ewspokawleM(a s8 te camtd wie a eapmoe by TVA pavw ltoi NA poundrmdaka4us vrimeW460 o to ilkidm ofWW (Mtemas MuOwe 1973) TVA mwi bawld on soi ficedims IampWp seg rudwiv s~s0abet ke WNmdoe ON 01 K Is12 NOSW ie fssewnmu Ie I QvaaIi rowp IMA) f9

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SC~po umd spop~o VWt alm 4emWal 1 4ink PCmirsra M 1 ad AI 14bmms

1MM Ww Even to doe shw wisht b-o -Wamp Ekb fed rbaimpal of14~ Am Smpound oS mv fAaMda

MGMe -M4 Wg kmuwadM 1Wr wih SCV4 Psmuck Wff It dlL Wm 1W led 0 1 oo teeA of aiwaisme aweeoid h

1Kach Vt V amp4W ILK t)sa 10 Nareps vm This ndY ub thee hbow apiptomuasa of gulfu-aw~sd of Cup lP~~tamsl wi(i

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e W d inSIWfh sil $ad doke IaefitV twoer) 1 Te to theo owie effu so booJ imik WOi 100 N

-d

Is re4aled uIwq~e~w Aueee atofurnw di Capsnm ptopeatls is a oommm eiws to 100 tom of 04404man d CtdUW 4M Anw K~a do Aamp apowee WPUaN powu eel H pae iaaa thAi SCUI isWW owr hmem ISsuppl N to the li ieee F A IM1 Nampa Obo~amie m

41MB ~ ~ m ~ ~0 0-- 0 140 The ffsemn of food Nn else9~e(Ud~ ~ ~ ~~ WooksaS eAWw pjed of ho~raw of IU effadam vfdva oft xhj0I 13iAl

DIVISION 8-9-SOIL MINERALOGY

Amorphomw CeetIup en XmWra Ssrfmls

L C koits Am~ 0 tmmkaAf

ommp A faieiaAMTRACT skiwe lo nW ampM sm wi4h

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~ -0

65

0IL CL OC AMXR PROC VOL 38 1974

)aT1 S4I104 ow Lusanll Tawng isa tall Thai variety known for beingIwo nonshyi s s ) sensitive to photoperiod A split-plot design was used in

S e e these euperimeots with 4 rates of P (I1 22 44 and 88t i V IV k of Pha) applied a main plot treatments and with the OF It sourMes of P as subplot treatments There were two checkS plots in each rmplicate The extra check plot was included to permit the application of fresh TSP standard Jor the

It- ti 06 + i bull fa succeeding crop the p-4me of bi was to permit accurate d awrnwal of the mdual effectiveness of the phosphate

ftinSUbI rock The P fertilioers were broadcast on the mud andthen Worporald In the soil during the last harrowing At

whM N both On ACS indx ampM time of transplanting Immediately before the last harrow61t (4j 5 4 01 P s 3Mm o Vallonal in con n 100 kgha of N as ammonium sulfate and 33 kghaWO Of Spews ampm lIW thaabe rocks do ACS indes of K as polium chloride were applied A total of 40 wa in prepw O do ctih k otent kha of N a ammoniunt sulfate was applied later in twoir P The hew oNed amp wM W for 5 of gw topdrossingp with about 5cm depth of water on the plotsvV I aiOMveffeOctveee Three to six ldayold selings pr hillwW the ACS idex were planted00OWW wia Oft fo an c irNk I p Coen 20 by 20 cm part in straight rows Hand weeding was used

and insecticide were applied for Insect control Grain yieldw was masared by sampling 5 ml of each plot excluding border rows The date of heading in each treatment and theUNiN d pbM W Weks rin tOW USA UMe In Tale yed componnts at hafvel were also recorded

I filM rsperMS esOM kdwdua 1 t ab The average yields of ough (unhulled) rice for botha 84 OW O 8uo 4 Thala TM was a locations are ploutel in PIS 3 for the first crop (1969 wet

owou thRM seaso0) The Veamps yield response was obtained at Klonge (s) W lDtO t Of dMa of1tw W d l R Luang however a 4ute satisfactory yield response was

~Mk ^d TVA UJSD ad Kd UnIveS obtalned to applied P at Bangkhen as wellXUe LaM e R qwrw Ims The sod was do Relative aponomlAe effectiveness values were calculated

VOW (a ksA w edmwL t Poesesm h Vy for these data and am presented In Table 3 The valuesdAY buo if dIe ouh ne Pee wtk a Mlak vow 1009 for th first crop are plotled against ACS index in Fig 41 This Im M i6ti l 4bNd IO a0 O mkarnk for both locatio r relationship was linear for the

11400 ThCpH 0( lb pW IW 01 th UpeiaW so Sanodion location and curtiltnear for KIng Luang The was u i 4A sksamp lMaor nrusio model amparounted for 81 of theAmO$MI Aw jAAsue Swim T1 Snh Wd variation In the AE valu for Bantkhen a square root

Mems a Iw iv fern alh$ sedm haowg dayNW W t he plAL At tdo M tM aso W s as ctminued throufh eltaM t Ofpof -le lse wo am P OeNI VeOpls 1o ealluae tI lon4erm MIdual Offccls

A on W isset i a wse to hsh eapeel of these ooihss t ocks The baagkhon experimnent was letmiaI1DlVemisthis is a w hulu Lo g Tasug ia iasael aft - Msd residual Ves will be pr-Om crok TheseTwod esewm

SWWo

A

lP~U~7 ISIIPe1iuIWN e bsedisssin ian ghth siaoelalbe

984 0 6 O O - M s -s fWPas 11eSft W d Uo al a o

o

S4l~ lIIII I~l I 1f fl

( +

+ + + m + ++++-

++ +(++ + ++++ + ++ ++

- 66 -

ENOIMLSTAD ET AL RESPONSE BY FLOODED RICE TO PHOSPHATE ROCKS VARYING IN CITRATE SOLUBILITY

I I I I j0 I I

BANOKHEN BANGKHEN

pH 56 6 - 0o

TSP

NC

5~ ~ ~ L o 4 - -shy

4 ] - --------shy04

6S

|0 III 2 44 8r 66

I I I

a 1KLONG LUANG

pH 46 z KLONG LUANG

TSP Sc2 NCFL(N)

5 FLIC) J0 TU

oshy

4 ~40shy

3 bull eM0

I - I I I I I

0 II 22 44 88 0 5 10 15 20 IP APPLIED KO HA ABSOLUTE CITRAE SOLUBIITY INDEX

Fig 3-Yield of rough rice at Klong Luang and Bangkhen Rice Fig 4-Relative agronon effectiveness () of P sources ploz-Experiment Stations Thalmand as affected by rate and Source ted against citrate solubity Index for both Thailand field ex

of P applied (crop 1) periment (first crop only)

regression model accounted for 97 of the variation in sumably resulted from crop uptake and reaction with the RAE values at the Klong Luang location soil to form less soluble products Such effects may have

These experiments were continued during the dry season been more important at the lower rates since the two TSP of early 1970 to ascertain the residual effectiveness of the curyes converged at the highest rate of application various sources applied to the first crop No new P was These data from KIong Luang indicate that (i) residual applied except for the fresh TSP standard mentioned effects of all rocks except Mlcwuri were substantial (ii) above rhe experiment otherwise was conducted in a man the relationship between relative agronornic effectiveness ner similar to that followed in the first crop of the phosphate rocks and citrate solubility levels was

The response to both freshly applied ad residual P was largely obscured and (iii) the general superiority of TSP marked at the Klong Luang location and marginal at over phosphate rock in terms of effectiveiss persisted Bangkhen In fact at the latter location the response was through the second crop so small that little can be said regarding residual effectiveshyness The yield data from crop 2 at the Klong Luang DISCUSSION experiment are plotted in Fig 5 Greenhouse and field data presented in this paper show

Relative agronomic effectiveness values (Table 3) were clearly that there are substantial differences among phosshycalculated for the Klong Luang data using both the residual and freshly applied TSP as standards It is of Interest to note that the superiority of TSP over the phosphbte rocks Table 3-Relative agronomic effective values for field experishyments in Thailand persisted through the second crop The main difference in KlowlZmlnql~the residual effects is that with the exception of the MIs- s Crop 1 Crop 21 Crop 1-shysouri rock Ihe marked relationship between citratr-soluble WoiCarolina yl 59 76

phosphate rocks and RAE had largely rds norh) a 64P conltct of th Florida (eqlral is 6969 6

disapipeared In this acidic soil (pHi 46) P would by this I14o 69 63 40 ToonesS 31 65

limo be supplied by Intermediate reaction products In addl Missou 0 o lion to residues of the initial spatlte Ts P o 2 o 0

The TSP applied to the first crop declliv-d slightly In campIafcmWataesr e id ofeuhuloefor 22MA rates of PtColeouattd as aba u tlte td18 kS ratesp dlverage yield tM868 to 22 44

effectiveness relative to the freshly applied ISP This pre- of d s4

A

4

- 67 shy

-SOIL SCL SOC AMER I

KLONG LUANG CROP 2

Si 3

eN

TAPPLIEDKGHA

Fig 5-The residual effectiveness ovarious P sources for crop s compared with freshly applied TSP Klong Luang Rice

Experiment Station Thailand

phate rocks in terms of agronomic effectiveness for flooded

rice Further these differences can be predicted by means of citrate solubility or by the ACS index It appears that

the latter is more appropriate where the content of apatite varies among phospiate rocks The most soluble phosphate rocks approached but did not actually equal TSP in limit-iuig (maximum) yield in these experiments regardless of rate applied This agrees with the results of Ensminger Pearson and Armiger (4) One needs to consider the defi-nite posribility of same yield loss in zhoosing a phosphate

rock over TSP such yield losses must be weighed against the lower price of phosphate rock The explanation for such iosses may involve concentration of soluble P in the soil Khasawneh and Copeland (6) suggest that the growth rate of crop plants is a function of P concentration that can be maintained in the soil solution If P concentration is limiting or inadequate becawe of a lower dissolution rate of phosphate rock the growth iate ard uiiimate yield will be diminished accordingly

The RAE values bascd on yield increases reflect the agronomi effectiveness of these various sources relacve

to the TSP standard however these nould be supple-

mented by an economic analysis before rational choice can

be made The following calculations will provide an estimate of

the rclativ ecooomic effectiveness(REE)

Y t Ps aXpatREE -- 100

vahtercks t sphate or e b i- eor

Price of TSPkg fo

be Price of PRkg P

PROC VOL 38 1974 leO

90r

Wsoshy

0

60-LUSEPHOSPHATE ROCK

00 10 20

PTP PR

Fig 6-Relationship between relaZive effectiveness values (RAE) and the price ratios between TSP and phosphate rock Such a figure can be used in making a choice between these

sources

If REE exceeds 100 in this calculation the phosphate rock would be preferable to TSP

The REE calcuktaaa wre used in preparing an indifshyference curve (Fig 6) wherein RAE values are plotted

against PTsPPpR ratios The cu~rve itself connects those points at which REE equals 100 When exactly on the curve it makes no real economic difference what source is chosen After choosing a suitable price ratio one can then project upward from that ratio knowing the RAI

value (or estimating it from such data as shown in Fig 4 using citrate-soluble P content) one can then choose the source on the basis of both agronomic and economic conshysiderations For example if the price ratio is 25 and the RAE value of the phosphaite rock is greater than 40 the rock phosphate in question would be used However if the RAE value was less than 40 TSP would be a better choice There are indications that if the P in the more soluble phosphate ro~cks (North Carolina north Florida central Forida) is less than half as expensivz as that in TSP these rocks would be feasible altereaives to TSP on soils similar

to thoseused in Thailand This analysis does not take into account the possibility

of lower yields from use of phosphate rock In addition only a portion of the various yield response curves was used in this anlysis ie up to 22 kgha Beyond this

rate yield response was much less pronounced it could be argued that at less than maximum yields TSP would produce a certain yield at lower rates of P than would phosshy

pow ofrock This would especially be true for rates applioa example at Klong Luang 5500 kg of

rice pcr iectare could have been produced with either Ii kg of P as TSP or 44 kg of P as son of the more reacshy

tire phosphate rocks It should be pointed ot however

- 68 shy

(IIKIS amp YOUN( ARIFICIAL WEATIIERING OF OXIDIZED p[ll- IV

that this is the yield level that would show the widest difference such is the advantage of hindsight

Farmers generally prefer granular fertilizers for machine

or hand application This is a disadvantage for the phos-phate rocks which are normally arplied in finely divided form Recently experimental quantities of granular urea-

phosphate rock mixtures have been made by TVA Results of trials with these fertilizers will be reported elsewhere

LITERATURE CITED

1 Armiger W H and Maurice- Fried 1957 The plantavailability of various sources of phosphate rock Soil Sci Soc Amer Proc 21183-188

2 Bengston G W E C Sample and S E Allen 1974 Re-sponso of slash pine seedlings to P sGurces of varying ci-trato solubility Plant Soil (In press)

3 Caro JIt and W Hill 1956 Chard eristics and fer tilizcr value of phosphate rock from different fields J Agr Food Chem 4684-687

4 Ensminger I E R W Peirson and W II Atmiger1967 Effectivencs of rock phosphate as a source of phosshyphurus for plants US Dep Agr ARS Bull 4112S

5 Engelstad 0 P J G Getsinger anid I J Stangel 1972 Tailoring of fertiliers for rice cnnece Valley Author ftyNational Fertilicr Developmnent Center Hull Y-52

6 Khasawnch F E and Jane P Copcland 1971 (otton root growth and uptake of nutrievos relation oif phosph

rus uptake to quantity intensity and buffering capacit) Soil Sci Soc Amer Proc 37250-254

7 Lehr JR and G H McClellan 1972 A revised lIbora tory reactivity scale for evaljativg phosphate rocks for direct application Tennessee Valley Authcrity National Fertilizer Development Center lull Y-43

H Terman G L S EAllen and 0 P Engelstad 1970 Response by paddy cice to ratcs and suurces of appliedphosphorus Agron J63390-394

DIVISION S-9-SOIL MINERALOGY

Artificial Weathering of Oxidized Biotite IV The Inhibitory Effect of Potassium on Dissolution llate

R JGILKES AND R C YOUNG2

ABSTRACT

Rates of dissolution of oxidized biotites in OIM 001M ICI are severely depressed in the presence of IM KCI The amovnts of Al Mg Mn dissolved in the first eytraction are similir to those found without KCI however subsequent extractions remove these elements at 10-20 of the corresponding lICI rates This effect may be due to a decreased rate of vermiculite formation thereby reducing the effective basal area exposed to attack A decrease in dissolution rate with increasing ferric iron content was still apparent in the presence of IM KCI

Additional Index Words X-ray diffraction infrared aborp-

N EARLIER papers of this series the tole of biotite in soils

as a source of both macro and micronutrient elements

has been discussed ((Gilkes Young and Quirk 1972 1973ab) Experiments in artificial weathering uiing as va-

riety of extractants were undertaken to determiie the inlu-

ence of oxidation of octahedrally coordinated iron on the bull release of structural cations to solution The results of this

work demonstated that biotite behaves anomalously with respect to the other common ferromagnesian minerals found in soils Oxidation leads to the development of a high degree of resistance to cation exchange and dissolution Several authors have coiwludcd that decreased rates of K

Contribution from the Dep of Soi Science and Plant Nutri-tion Institute of Agriculture Univ of Western Australia Ned-lands 6009 Western Australia Received 29 Sept 1973 Ap-proved 8 Jan 1974

2 Senior Lecturer in Soil Science and Research Officer respeclively

replacement in electrolytes shown by oxidized biotites are

a result of the inclination of structural hydroxyl adjacent to newly created trivalent iron or vacant octahedral cation sites (Robert and Pedro 1959 Barshad and Kishk 1968) Gilkes et al (1973b) suggested that decreased rates of disshysolution of oxidized biotite in 0001 0t)l 0Af CI may also be due to the presence of inclined hydroxyl In this case a smaller surface area external and exposed intershylayer may be available for attack if K replacement by hyshydrogen ions occurs at a slower rate in oxidized biotites

Gastuche (1963) has shown that significant dissolution ofthe (IIM) biotile face may occur and it is easily demonshystrated that the proportion of exposed (001M) face in weathering biotites depends on the percentage K replaced

Rausell-Colom ct al (1965) have shown that hydrogen ions act in an identical fashion to metal cations in K exshy

change from micas In particular exchange c-f K by hydroshy

gen ions will be terminated or greatly reduced by high levels of K in solution Thus if dissolution of oxidized biotite by

acids is carried out at sufficiently high K levels to prevent vermiculization any differences in dissolution rate that may occur cannot simply be ascribed to differences in rates of K replacement The following results were obtained from such an experiment which unlike the experiment described in Parts I and II (Gilkes et al 1973ab) does not attempt to simulate natuiral - conditions

MATERIAILS AN) M HIiODS Further subsamples of the less than 0 hiotites used in K

excherandbaid disoo tu es (G iles e9n K exchange and acid dissolution studies (Gilkes et al1973ab) were used in these experiments Preparation of sequentiallyoxidized biotites without intermediate vermiculite formation is

Page 15: I70 - United States Agency for International Developmentto ascertan, but tgl.eetad, 1, L,. ("Tailoring of Pertiltiters for ice,'" TVA ulletin Y-52) states that the staft of IOi has

- 12 -

Emphasis will be placed upon obtaining samples of phosphate

rock from deposits in developing countries and testing and improving

procedures for increasing their citrate solubility and tzius availabilshy

ity of the phosphorus From this laboratory screening process sevural

sources will be selected from which small amounts (50 to 100 pounds)

will be prepared for greenhouse and field experiments ou various soils

(as described under agronomic section)

From these results one or two locations (or countries) will

be selected for development of a pilot program to utilize local sources

of phosphate rock This program will involve production of the altered

PR and its agronomic evaluation and then educational programs with govshy

ernment and commercial representatives to introduce its use to the farmers

Sulfur-Coated Fertilizers

Some preliminary work has been done in which urea-potash mixshy

tures were coated with sulfur The 7-day release rates for the N and

K20 were 17 and 36 respectively from the coated product (22-0-11-30S

grade) This was the first effort in coating a compound fertilizer

with the new coating system

The widely differing release rates for the nutrients from

the coated compound product raise some interesting prospects for tailshy

oring the nutrient release rate of sulfur-coated products It might

be possible to cogranulate materials of varying water solubility and

sulfur-coat them to produce products with release rates that would apshy

proximate the timing of nutrient requirements of the crop The need

for this type of controlled-release product has been mentioned many

times by agronomists and may be especially applicable in multiple and

intercropping systems

inawa~~aUww e t of~ wdtop~s WRisr 4owt~

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catAt all PIed$ l low 40- 7~4a1 ff ~~44 F 0i 44$4

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~4 4 40~40 4 4CI mkfSw4Wh4 4wo~q~M

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4 4W4-44

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4 440 40A 14t 4M~ 40404448444w VA4 4 44 A4

i44lamp 44+AM AM400 4444 1 4IA4464 4-w4

ZA4 +4 4 4 p04f40 $A 410UW0004

Okfi A4~

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4~b~~ 444 AW4iU a-w $ 4 $ts

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~ i~P 4 4 wl 444 41A ~4 4~~E4166 I144 4t~w i14

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io- s4aq4 4Wvs i 44t amp 4W 4-1ampo-v 4tI 44041 4 4~ kikamp3o 41

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~~O P44 44is ~ ~4 Aloti~S~3vool41~

0uI 4044~Me ~ ~ N4

4 jk-4il4 9-4 jio4 4 4I4wSj- ~ 4 sZiamp 44s)

) o~4w4 4444~S Is~4~4 ol I i A 4~ ~

4Ii I~4I4M$~ ~I

QOWIf XVif k

4004 004o4f U A

-w i4 I~~~

40440wo oow IVTA 44qol 644

4I~~~4J 00S4 4410 114w- A44W Wamp ~

6WViso4wb f vfpo w

w0OIA - i f iIS

f4 A 00 1 o4

I1~wo ow4O4-40404f-4 ~

TOM I

Cs VWA1 t lw Vairtile ot P44Y 44c KW MI1

fiat Wm~~JL U Lem~ampuJampAJ Wat IO

~ 941~1 41 ~~~~j~~qt~~8IJ WtS dobu

Table 2

Mttct of 0 Sourco aampW $At On Upt~ks of 0 by Two Varitgtos of Paddy Rice

gr~a 1971

~ MMUampL~ ~L ~ nYLALI~ 11 lemall

I ie

W0 v slit III I) tQo9

KvN 1 17 111 1119

or 444M7

111a

i1$0N ~ It$ 121

1$

x IV ~404 tot Vsr 1 P1 41 w otv 1

- 24 shy

India--The results of four experiments conducted with flooded

transplanted rice in India by the All-India Coordinated Rice Project

Hyderabad are given in table 3 The response to N was excellent the

yield without N being only 41 of those obtained with basal applications

of N as uza With basal applications of SCU the yields were 20 higher

than with basal applications of urea and in the three experiments in

which urea applications were split yields with SCU were 18 higher than

yields with split applications of urea When comparing the average Nshy

response (kamp grainKg N) yields were increased 13 more by SCU than by

basal applications of urea

The data from one experiment with light irrigated rice in India

are given in table 4 yields were relatively low and differences between

N sources or method of application were not significant However yields

with SU tended to be higher than when all urea was applied at planting

but lower than when split applications of urea were applied Again yields

increased more than 13 more with SCU than with basal applications ofwere

ur

In tables 5 and 6 the yields of a short-duration transplanted

rice grown in irrigated light-textured soils at five locations in India

indicate that higher yields were obtained with SCU than with urea when apshy

plied as a basal application Yield increases due to basal N applications

were 502 greater with SCU than with urea However split applications of

resulted in yields equal to those obtained with basal applications ofurea

CU

The yields of direct-seeded upland rice grown at three locations

to India are given in table 7 and the relative yields in table 8 Yields

were low due to drought but good responses were nevertheless obtained for

- 25 -

Table 3

Effect of N Source and Time of Application on Yield of Paddy (Flooded) Rice in India 1972 (Summary of Reported Data from 4 Experiments)

Experimental Number Source Rate Method Yield Relative N-Response

and of of N of Yield Kg Grain

Season Nitrogen kgha Application mtha Kg N

- - - 196 34 -

Urea 120 Basal 573 100 314

11 Urea 120 80 + 40 611 107 345 Rabi SCU 120 Basal 713 124 430

12 - 0 - 202 30 -

Urea 125 Basal 682 100 384

Rabi Urea 125 35 + 20 + 35 + 35 633 95 344 SCU 125 Basal 781 115 463

13- 0 - 168 44

Urea 100 Basal 385 100 217

Kharif Urea 100 30 + 20 + 25 + 25 400 104 232 SCU 100 Basal 462 120 293

14 -

Urea -

125 -

Basal 355 650

55 100

-

236

Rabi SCU 125 Basal 781 120 341

-- 26 -

Table 4

Effect of N Source and Time of Application on Yield of Light Irrigated Rice in India 1972 (Summary of Reported Data From

One Experiment at Pattambi)

Experimental Number Source Rate Method Yield Relative N-Response

and of of N of Yield Kg Grain Season Nitrogen (kgha) Application (mtha) Q) Kg N

38 0 - 204 85 -Rabi Urea 120 Basal 241 100 308

Urea 120 60 + 0 + 30 + 30 267 ill 525 SCU 120 Basal 255 106 425

Table 5

Effect of N Source and Time of Application on Yields of Short-Duration Transplanted lice Variety Grown on Irrigated Light-Textured Soils at 5 Locations in India 1972

(Snmzarized From Reported Data)

Rate Grain Yields (MtHa) Source of N Method of N GrainI of N kgh Application Faizabod Karjat Mandva Pattabi laya Averaje X

- 291 266 211 19 340 260 -

Urea 100 Basal 386 407 361 285 482 3 124 Urea 100 50 + 25 + 25 399 430 434 334 6amp2 4A8 186

SCU 100 Basal 368 468 439 360 572 41 181

Table 6

Effect of I Source end Tlae of ApplIcattoo c RIstave Tle24 of a rt- rat1 T Lsd lice Vasrety Crin o Irrigated L41tshy1 at S Locitite mindi 1972

Rate ____________14_3

Source of X N~tbad of Of X An 1 tat14 1 acr X__T1 4v tatW ttva

- - - all 7i i

95l 119 1 1~ ~~~~~ an iI3lli i1

WRI

iwii4 i M

owo~

4

______m44-o

4 4

404 400

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44- 40

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Tabl I

f~ttwi Ot 0 6wirce 81d At$ a vt1d at flUop4d Rico to Vitjorim (1ITA)All fortitfour to rsodkeet OA lC~OVPr4( 114 5iI 000

W Iotors Ftslanp tospg Irritd for Two thvk Afler flontiw wft rkwa~ Floo4d 191)

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- 38 -

Table 18

Yild of aemati-370 Rice at Punjab Agricultural Research

Institute in Pakistan in 1969-70 Grown Under

Couditions of Intermittent Flooding

Pate of application

=IL

o 0 67 67 100 100 67 67

100 100 67 67 200 100

Average for Sources

Ntha

AS 260 gres 279

320

Source f5

-

AS AS Ura Urea SCU SCU

Yield

Relative

93 100 115

(M)O

Yield

Increase Yield Due to N

(Ktlha) (mtha)

-212 245 033 274 062 260 048 297 085 315 103 325 112

Yield Increase

Relative

72048 067 100 108 161

(2)

- 39 shy

Short-statured high yielding rice varieties grown extenshy

sively in northern Peru require extremely high rates of conventional

N sources to achieve maximum yields The recovery of applied N is

extremely low due to the use of intermittent flooding This water

management system results in heavy N losses even with properly timed

split applications In search of simpler and more effective methods

of N management eight field experiments were conducted in the region

to evaluate sulfur-coated urea (SCU) an experimental slow-release N

source supplied by the Tennessee Valley Authority Rice yields were

increased an average of 59 more by pretransplant-incorporated SCU than

by urea or ammonium sulfate applied in the same manner SCU produced

excessive vegetative growth which resulted in yield reductions at high

N rates

Regardless of an assumed 48-higher unit N cost in SCU the

overall benefits of pretransplant-incorporated applications of SCU

were favorable since there was a decrease of 40 in the optimum rate

of N and the need for precise timing of application was eliminated

Pakistan--In Pakistan basal applications of AS urea and

SCU to rice grown under conditions of intermittent flooding in 1969-70

(table 18) indicate that SCU is a superior source of N as compared to

urea or AS when all N is applied at or before planting The data also

indicate that a yield response was obtained for P applications but a

comparison of N sources at each level of P indicates that no interaction

between N and P was present so that differences between N sources were

relatively the same at each level of P Yields were increased about 60

more when SCU was applied than when urea was applied Yield increases

with AS were only about 72 of the increase obtained with urea these reshy

sults do not agree with the generally-reported superiority of AS as comshy

pared to urea as a source of N for rice

- 40 -

In 1973 experiments were conducted in Pakistan using both

Basmati-370 and IRRI-6 varieties of rice grown under conditions of

When all N was applied at puddlingintermittent flooding (table 19)

or 12 at puddling and 12 at panicle initiation both AS and SCU were

superior to urea with SCU tending to be the most efficient source

However when N was applied 12 at transplanting and 12 at panicle

initiation SCU was the poorest source of N This would indicate that

the release of N from SCU applied at these times is too slow for optimwn

plant growth

In another experiment in Pakistan in 1973 no differences

in the effectiveness of urea AS or SCU were noted in the yields of

continuously-flooded rice (table 20) Again these results are conshy

sistent with earlier results which indicate no superiority for SCU

when rice is continuously flooded

Nitrogen Studies--Maize

A series of three experiments were conducted by IITA in

armo-Nigeria in 1972-73 comparing AS urea SCU and

CAN (calcium

nium nitrate) as sources of N for maize (table 21) A significant

yield response was obtained for N at each location but no conaistent

differences were noted amaong sources These results are consistent

with results at other locations which have not shown that SCU is a

superior source of N for maize grown over a period of 3 to 4 months

Nitrogen--Wheat

The yields of wheat in Pakistan in 1969-70 (tables 22 and

23) show that yields with SCU) tended to be lower than those with ureaJ

although at one locction where sorghum was grown followilng wheat with

Table 19

Yields of Basmati-370 and IRRI-6 Rice at Punjab Agricultural Experiment Station in Pakistan in 1973 Under

Conditions of Intermittent Flooding

Rate Yield Source of N Time of Yield (Mtha) Increase of N B-370 IRRI-6 Application Basmati-370 IRRI-6 Average (Mtha)

0 0 - 21 353 287 -

SCU 90 150 At Puddling 325 545 435 148

Urea 90 150 At Puddling 309 500 405 118

AS 90 150 At Puddling 324 529 427 140

SCU 90 150 Puddling 372 572 472 185 Panicle Initiation

Urea 90 150 Puddling 335 502 419 132 Panicle Initiation

AS 90 150 Puddling 353 529 441 154 Panicle Initiation

SCU 90 150 After Transplanting 312 562 437 150 Panicle Initiation

Urea 90 150 After Transplanting 340 624 482 195 Panicle Initiation

AS 90 150 After Transplanting 349 583 466 179 Panicle Initiation

All plots received 45 lbs P205acre as single superphosphate

Relative Yield Increase ()

Source of N At Puddling Puddling Panicle Transplant h Panicle

Urea 100 100 100 AS 119 117 92 SCU 125 140 77

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P11~0 pra~lpj prefer gre4r tuftlter for whlae

of hoaw ppltrstie Mhe to a dloedveaP for The PINSOO rocka

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mmfp MW phapa A (CI) sed graewletod pampAtlti arlolatod Pa

asowcs of P tof ttde ro The wreem proucts omre raGther

pemour~a ot P syag besmti andMi as elt ov so gpamwhr

iuipiqffhate(TS) low twseeo Is eftwiltve Is thet

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pud6itt of Irto paddle Wee ofsdlseireplastiq

0 49 shy

lbs partially scldiaatede grawilated Ml prodlucts Vere isshy

toiwdiats in 5tftOvttWS54 betwee wroiPi ad TVP NotV5Ymf to

me coo were they mere twoe $a a etfective ao TIP 00 sipifleast

LVSUMI5 at0 efecto wore toun tor thee produteo Timely dtIampWde

FR (-t00 mmoh) Uia amp~rally oar affective than Owe gra8448r FOampprodt

featal twos o 6 aotetire s I

Nowvero it to felt that sfortber field euprtet vth

hese interials Amd ether typs of grometatodl Wter nre wrrautad

hater ceeuwodh that they have me areec poteatlal toi additoG

e tate wAne the sectte as OtawrI sed bovoloen turther

euperimeste vth few reck pboophar s0d with reck pbophat treated

to sehesa citrata selmtliy or to ha csaducted

Metbir sertes of tbme enprtaeats wae c~edtmcted by IITA

to Ut~rta copal TVP AOP APP aed it at see tecastisix (table 14)

No dot lalt sewseltles teh draw tree thee results simouely em pear to tlvdl bsww they do stwgpt tbat forthew work with

MR to werramid so tbme sels

Table 24

LttcttF Swce MaPlate 06 ieldot IM AWaia CoelsANS at IITA (Ugboda ad Apoin ail sorit) aid at Ike (AUaba s5i series)

1973

Plate ot IP Apinu 5 poundebods A1ab

Ocrol 0 Z94 419 M)

Tr ipl ruprphite 20 349 3799378

Triple vepput 40 M09 410$

Triple 6wp~~b1 4271 4344 42250

Ammotw-ritpophW to 4201 4124 4040

Amosim-rdop~phlt 40 4270 4106 4231

AM tuo-polpephats 20 404 4244 3794

~eai~mpelppepbuI 400)49 4094

Cee m-pbpbt to- 59

momee eph lto 0 4192

LSO (0 0$) 29 1025

Th WPII

- 51 shy

101Y114 tpeM-fI PEP~tbRP YO

1 ~ ~ gmw 1pc~biofl- 9 Kla4v4h

Upia U04 Copfind am Crehout Stet Rpano at (Ia4

rico t IF t rume6 orth~ Caralto phoophale rocl QAR) vaUN pqU41 to

roopon from cmonetrat4 gsporphophai (CIP) who ort$o4 oil k

was 45j itwas tafertor vb protioo4 oil p war OS Ib 4iffer~c

in rtc reepos to X cod14 oo bo ttrit4 4 4 hvsciag of boil p

~ Pt o r11221 0 tP

c theto the rhimecyllndor of rico tots par to)14M4i1 roeoi~t

ed oil emd PA prior to tho ont of an~robi4 cMioe AA~ oIifoshy

nAte bYpot t taet~d tO fC4sin t~r 4PWden0 Of f Ot(tivshy

ofOWailiJtyno o prefla4 all Put that 4t01etoo 14 tvsIk

of the Ott to prvvld a 014for C4m0 44 mI 1 o4sf

EfftC ftPet141on AIAM-0 V f401td 4 4iv 440 Mtft

Aa torfat VampP f4MWfCi4W04wt0amp to 4eturWlI Ot(Wel~drIC ft

Ot f tM6 the flooded Ott 00 14 04019I Pft0uAw Of gAr~s~lr

pkS$t M40b MP) Tw P1101 Piset Prodwie W-e 10M0di Wr04

(10-1) emW 0aretilp ddw01at4 P WAA firom Rrth M~flRU414~$

wee cowiared with fie Md reWim 44104 proo~fo) foruk oith laWItter

I v te-PR P OW1004 4 4 O Wf ottil OW ellt Oo

Oveiel1 the 40tt dmcruie to effetotww Wtollowui Co fme

PR tpaUIB1I ldoltmo PR (pamwlatr) offr~- ArmeuM) 0 orwi

- 52 -

Effect of N Sourc6 and Water Management on Response of Rice

toe Zn- M Giordano J J Mortvedt OP Engelstad and Greenhouse

Staff Several rotes of CO(14H2)2 and (H )2So4 vith or without ZnO

wore applied to flooded and nonflooded Crowley oil (limed to pH 75)

to determine response of Bluebelle rice to Zn Yields with both N

sources veotrgreator on flooded then on nonflooded soil In the abshy

ence of applied Zn total dry matter production vith CO(NH2)2 was

slightly lower than with (NH)2S04 on flooded soil and considerably

lover on nonflooded soil Concentration of Zn wan higher in straw and

grain of plants roun on flooded than on nonflooded soil Although

concentration of P was unaffected by N source or Zn rate there was

som indication that cranslocation of P from straw to grain may be

depressed in nouflooded rice Concentration of N was lower in straw

grown on flooded than on nonflooded soil due to apparent dilution

thereas both X sources resulted in similar N concentrations in straw

at all rates of N application the N concentration in grain increased

with 0 rAse

feSpongi gf(SM to Chjorospodiostte and Related P Sources--

Si Allen and Greonhoue Staff A greenhouse pot experiment was

couct44d with corn Brown on Hountview silt loam to compare the ofshy

fectlivees of chlorospodiosito (Chlor-l) with concentrated supershy

phosphate (CP) Thomas slag and North Carolina phosphate rock (NC-PR)

Oil-prillad urea-phophato rock (UPI) FeA1JMP 20 7 and monomthyl

phosphate were included in the experiment Based on yield of forage and

uptake of P by tvo crops each of 6-weeks duration the following conshy

stui were dravat

I Chlor-1 was slightly loss effective than CSI Thomas slaS or NC-PR

from which Chlor-l wae prepared

- 53 shy

2 Granular UPR was a poor source of P its effectiveness was greatly

increased by reducing the particle size to -35mesh

3 FeAlNH4P207 was unavailable to the crop

4 Monomethyl phosphate was equivalent toor slightly more effective-

than CSP

Research Indirectly Related to TVA-AID Project

Response of Several Rice Varieties to Zn in Moist or Flooded

Soil--P M Giordano J J Mortvedt and Greenhouse Several varieties

of rice from Mexico and the Dominican Republic currently under investishy

gation in Puerto Rico for adaptation to upland culture were compared with

some established United States varieties with regard to Zn response on

moist and flooded Crowley sil (pH 75) Chontalpa (Mexico) Bluebelle

(Texas) and Starbonnet (Arkansas) were most responsive to applied Zn

Juma (Dominican Republic) intermediate and Sinaloa (Mexico) and Calrose

(California) were the least responsive The Sinaloa varieties (Mexico)

appeared to be best adapted to non-flooded conditions whereas Chontalpa

and Calrose were poorest Concentrations of Zn generally were higher in

plants grown on flooded than moist soil

Pattern of Growth and Zinc Accumulation by Rice--P M Giordano

J J Mortvedt and Greenhouse Staff Rice plants were harvested at weekly

intervals from shortly after emergence through maturity The objective

was to determine the rate of growth and Zn uptake by a Zn responsive varshy

iety (Bluebelle) and a less Zn-responsive variety (Calrose) in the presence

or absence of Zn applied to Crowley sil (pHl 75) Dry matter production

of Calrose was linear with time of growth and of a similar magnitude until

heading with or without applied Zn Bluebelle followed a similar pattern

where Zn was applied However in the absence of applied Zn foliage yield

was reduced markedly

-54

Uptake of Zn was similar for both varieties whenZn was

applied Dry matter production and Zn uptake by the two varieties

also were comparable when Zn was applied However yield of Calrose

was much higher than that of Bluebelle in the absence of applied Zn

while Zn uptake was only slightly higher This suggests that the lesshy

ser responsiveness of Calrose to Zn may be due to more efficient utilishy

zation of Zn There was no indication of a greater demand for Zn durshy

ing reproduction in either variety as was suggested in earlier greenshy

house experiments

Response of Upland Rice to P and Zn--P M Giordano J J

Mortvedt and Greenhouse Staff Several rates of P and Zn were applied

to Crowley sil (limed to pH 75) in factorial combination to determine

whether differences in rice growth under flooded and nonflooded soil

conditions are related to plant nutrition Although straw yields were

slightly higher in nonflooded rice receiving adequate P and Zn grain

yields were higher in the flooded crop increased rates of F andor Zn

did not result in equal yields Except in the highest Zn rate (75 mg)

concentrations of Zn in both straw and grain were higher with flooding

Concentration of P increased with rate of applied P and was higher in

the grain or flooded than upland rice at a comparable P rate In conshy

trast concentrations of N were lower with flooding due in part to dilshy

ution from increased growth

Rice Response to N and P in Flooded and Unflooded Cultures--

G L Terman S E Allen and Greenhouse-Analytical Staff Rates of

N from 250 to 2000 ntpot and P from 0 to 1000 mtpot were applied for

Nato rice grown on Mountview sil and Sango sicl (625 kg of soil per

pot) Market yield response to N and P was obtained Yields of straw

- 55 shy

total yields N uptake and N recovery were higher on unflooded than

on flooded soil cultures Grain yields however were slightly higher

with flooding These results indicate that with adequate applied

nutrients especially of N rice yields without flooding can approach

or even equal those under flooding

Uptake of N P Ca Mg and Zn increased with yield response

to N and P while K uptake decreased on the Mountview soil Concentrations

of N and P increased with applied N and P respectively while concentrations

of other nutrients were diluted in most situations with yield response to N

or P

Results from this experiment show that amouats of N applied in

previous pot experiments for rice have been much too low especially if the

crop was grown to maturity

Response of Corn to S and N i UUASand Urea-S--S E Allen

and Greenhouse Staff Three greenhouse pot experiments were conducted to

measure response to S and N in ulfur coated urea (SCU) urea amonium

sulfate (UAS) and urea -S as well as estimate N losses from surface apshy

plied N sources

In Experiment 260 less than 20 of the S mixed with the soil

was recovered from SCU or urea-S granules by two crops of corn as comshy

pared to 45 or 80 from flowers of S or Na2SO 4 CLop response followed

a similar pattern

In Experiment 260-A N sources were surface applied and alshy

lowed to dry for two weeks before incorporation Into the soil and plantshy

ing Recovery of N by two crops of corn was 77-82 for AN an compared

to 37-70 for urea UAS urea-S and ICU Thus n this experiment loss

of N from urea did not appear to be re~dcud by light S-coatlngn or by Inshy

corporating S or AS in the granules

-S -

I xbprZnSlt a Wtch aU Meyto 0-Ai Wt f9r

higher reermo teOrtOrs cOM reSpWNO i r0100 Of N w

not oaisteontly related to sewe ot N In edl tust 0 ioltiUe Lim

lo in VMuwpped evlmtUTS 48 merind by seirest nte appresOehe

501 for uroa as cwarod to 210 for urea peepha

Rus- or Upse to LoAmIl34I a AriMed bI Earl U

MW NOWlsIIsIr-4 L Toman 5 1 Alln and eesese StNf rio

row on Sawg did (0 tpot) We 1l0l0 Ws feritiud vith 05is

of Npot mixod with the 6011 as aureCA NiAO) 1 Age god At Ures

was also itcluded at rtt t 05 10 end 15 of Upee Theas trealshy

onto were followed 4 wpdrsetago of U s AN wre 4C 10o or at I3n

Weeks toulin up to IS pot

A soil application of 10 pot rosulvod to the maim yield

at 4 weeks Tio4 sad percont prottis t intre raite tncreased rftishy

linearly with U applictalien IeseeItally all at the m iNd wit

the moil w domitrifted after flooding Grail end straw Ilelds vere

highly correlatod with tiliriag and vlh ubers of gralm arl

The results Widicat that 0$ to 10 a of Upot as orea or

NN bsuld be sied with the oil to stilate tiilrir with adshy

ditional 0 topireased later to increase grain lIds mad protia cmshy

tout

DIVISION 54- FERTILIZER TECHNOLOGY AND USE

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-02

792 60L WI W A)49R Pio VOL 37 197)

primS o r OeampAd WU toa Them fl~ w At NOSSe earno maisslea Ia N he mOWamplIO yik ampWd IMe aampWmW OWa Owe wa UMs of KU to 41 Oke ampWiiIamm be dkrnety ewspokawleM(a s8 te camtd wie a eapmoe by TVA pavw ltoi NA poundrmdaka4us vrimeW460 o to ilkidm ofWW (Mtemas MuOwe 1973) TVA mwi bawld on soi ficedims IampWp seg rudwiv s~s0abet ke WNmdoe ON 01 K Is12 NOSW ie fssewnmu Ie I QvaaIi rowp IMA) f9

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DIVISION 8-9-SOIL MINERALOGY

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65

0IL CL OC AMXR PROC VOL 38 1974

)aT1 S4I104 ow Lusanll Tawng isa tall Thai variety known for beingIwo nonshyi s s ) sensitive to photoperiod A split-plot design was used in

S e e these euperimeots with 4 rates of P (I1 22 44 and 88t i V IV k of Pha) applied a main plot treatments and with the OF It sourMes of P as subplot treatments There were two checkS plots in each rmplicate The extra check plot was included to permit the application of fresh TSP standard Jor the

It- ti 06 + i bull fa succeeding crop the p-4me of bi was to permit accurate d awrnwal of the mdual effectiveness of the phosphate

ftinSUbI rock The P fertilioers were broadcast on the mud andthen Worporald In the soil during the last harrowing At

whM N both On ACS indx ampM time of transplanting Immediately before the last harrow61t (4j 5 4 01 P s 3Mm o Vallonal in con n 100 kgha of N as ammonium sulfate and 33 kghaWO Of Spews ampm lIW thaabe rocks do ACS indes of K as polium chloride were applied A total of 40 wa in prepw O do ctih k otent kha of N a ammoniunt sulfate was applied later in twoir P The hew oNed amp wM W for 5 of gw topdrossingp with about 5cm depth of water on the plotsvV I aiOMveffeOctveee Three to six ldayold selings pr hillwW the ACS idex were planted00OWW wia Oft fo an c irNk I p Coen 20 by 20 cm part in straight rows Hand weeding was used

and insecticide were applied for Insect control Grain yieldw was masared by sampling 5 ml of each plot excluding border rows The date of heading in each treatment and theUNiN d pbM W Weks rin tOW USA UMe In Tale yed componnts at hafvel were also recorded

I filM rsperMS esOM kdwdua 1 t ab The average yields of ough (unhulled) rice for botha 84 OW O 8uo 4 Thala TM was a locations are ploutel in PIS 3 for the first crop (1969 wet

owou thRM seaso0) The Veamps yield response was obtained at Klonge (s) W lDtO t Of dMa of1tw W d l R Luang however a 4ute satisfactory yield response was

~Mk ^d TVA UJSD ad Kd UnIveS obtalned to applied P at Bangkhen as wellXUe LaM e R qwrw Ims The sod was do Relative aponomlAe effectiveness values were calculated

VOW (a ksA w edmwL t Poesesm h Vy for these data and am presented In Table 3 The valuesdAY buo if dIe ouh ne Pee wtk a Mlak vow 1009 for th first crop are plotled against ACS index in Fig 41 This Im M i6ti l 4bNd IO a0 O mkarnk for both locatio r relationship was linear for the

11400 ThCpH 0( lb pW IW 01 th UpeiaW so Sanodion location and curtiltnear for KIng Luang The was u i 4A sksamp lMaor nrusio model amparounted for 81 of theAmO$MI Aw jAAsue Swim T1 Snh Wd variation In the AE valu for Bantkhen a square root

Mems a Iw iv fern alh$ sedm haowg dayNW W t he plAL At tdo M tM aso W s as ctminued throufh eltaM t Ofpof -le lse wo am P OeNI VeOpls 1o ealluae tI lon4erm MIdual Offccls

A on W isset i a wse to hsh eapeel of these ooihss t ocks The baagkhon experimnent was letmiaI1DlVemisthis is a w hulu Lo g Tasug ia iasael aft - Msd residual Ves will be pr-Om crok TheseTwod esewm

SWWo

A

lP~U~7 ISIIPe1iuIWN e bsedisssin ian ghth siaoelalbe

984 0 6 O O - M s -s fWPas 11eSft W d Uo al a o

o

S4l~ lIIII I~l I 1f fl

( +

+ + + m + ++++-

++ +(++ + ++++ + ++ ++

- 66 -

ENOIMLSTAD ET AL RESPONSE BY FLOODED RICE TO PHOSPHATE ROCKS VARYING IN CITRATE SOLUBILITY

I I I I j0 I I

BANOKHEN BANGKHEN

pH 56 6 - 0o

TSP

NC

5~ ~ ~ L o 4 - -shy

4 ] - --------shy04

6S

|0 III 2 44 8r 66

I I I

a 1KLONG LUANG

pH 46 z KLONG LUANG

TSP Sc2 NCFL(N)

5 FLIC) J0 TU

oshy

4 ~40shy

3 bull eM0

I - I I I I I

0 II 22 44 88 0 5 10 15 20 IP APPLIED KO HA ABSOLUTE CITRAE SOLUBIITY INDEX

Fig 3-Yield of rough rice at Klong Luang and Bangkhen Rice Fig 4-Relative agronon effectiveness () of P sources ploz-Experiment Stations Thalmand as affected by rate and Source ted against citrate solubity Index for both Thailand field ex

of P applied (crop 1) periment (first crop only)

regression model accounted for 97 of the variation in sumably resulted from crop uptake and reaction with the RAE values at the Klong Luang location soil to form less soluble products Such effects may have

These experiments were continued during the dry season been more important at the lower rates since the two TSP of early 1970 to ascertain the residual effectiveness of the curyes converged at the highest rate of application various sources applied to the first crop No new P was These data from KIong Luang indicate that (i) residual applied except for the fresh TSP standard mentioned effects of all rocks except Mlcwuri were substantial (ii) above rhe experiment otherwise was conducted in a man the relationship between relative agronornic effectiveness ner similar to that followed in the first crop of the phosphate rocks and citrate solubility levels was

The response to both freshly applied ad residual P was largely obscured and (iii) the general superiority of TSP marked at the Klong Luang location and marginal at over phosphate rock in terms of effectiveiss persisted Bangkhen In fact at the latter location the response was through the second crop so small that little can be said regarding residual effectiveshyness The yield data from crop 2 at the Klong Luang DISCUSSION experiment are plotted in Fig 5 Greenhouse and field data presented in this paper show

Relative agronomic effectiveness values (Table 3) were clearly that there are substantial differences among phosshycalculated for the Klong Luang data using both the residual and freshly applied TSP as standards It is of Interest to note that the superiority of TSP over the phosphbte rocks Table 3-Relative agronomic effective values for field experishyments in Thailand persisted through the second crop The main difference in KlowlZmlnql~the residual effects is that with the exception of the MIs- s Crop 1 Crop 21 Crop 1-shysouri rock Ihe marked relationship between citratr-soluble WoiCarolina yl 59 76

phosphate rocks and RAE had largely rds norh) a 64P conltct of th Florida (eqlral is 6969 6

disapipeared In this acidic soil (pHi 46) P would by this I14o 69 63 40 ToonesS 31 65

limo be supplied by Intermediate reaction products In addl Missou 0 o lion to residues of the initial spatlte Ts P o 2 o 0

The TSP applied to the first crop declliv-d slightly In campIafcmWataesr e id ofeuhuloefor 22MA rates of PtColeouattd as aba u tlte td18 kS ratesp dlverage yield tM868 to 22 44

effectiveness relative to the freshly applied ISP This pre- of d s4

A

4

- 67 shy

-SOIL SCL SOC AMER I

KLONG LUANG CROP 2

Si 3

eN

TAPPLIEDKGHA

Fig 5-The residual effectiveness ovarious P sources for crop s compared with freshly applied TSP Klong Luang Rice

Experiment Station Thailand

phate rocks in terms of agronomic effectiveness for flooded

rice Further these differences can be predicted by means of citrate solubility or by the ACS index It appears that

the latter is more appropriate where the content of apatite varies among phospiate rocks The most soluble phosphate rocks approached but did not actually equal TSP in limit-iuig (maximum) yield in these experiments regardless of rate applied This agrees with the results of Ensminger Pearson and Armiger (4) One needs to consider the defi-nite posribility of same yield loss in zhoosing a phosphate

rock over TSP such yield losses must be weighed against the lower price of phosphate rock The explanation for such iosses may involve concentration of soluble P in the soil Khasawneh and Copeland (6) suggest that the growth rate of crop plants is a function of P concentration that can be maintained in the soil solution If P concentration is limiting or inadequate becawe of a lower dissolution rate of phosphate rock the growth iate ard uiiimate yield will be diminished accordingly

The RAE values bascd on yield increases reflect the agronomi effectiveness of these various sources relacve

to the TSP standard however these nould be supple-

mented by an economic analysis before rational choice can

be made The following calculations will provide an estimate of

the rclativ ecooomic effectiveness(REE)

Y t Ps aXpatREE -- 100

vahtercks t sphate or e b i- eor

Price of TSPkg fo

be Price of PRkg P

PROC VOL 38 1974 leO

90r

Wsoshy

0

60-LUSEPHOSPHATE ROCK

00 10 20

PTP PR

Fig 6-Relationship between relaZive effectiveness values (RAE) and the price ratios between TSP and phosphate rock Such a figure can be used in making a choice between these

sources

If REE exceeds 100 in this calculation the phosphate rock would be preferable to TSP

The REE calcuktaaa wre used in preparing an indifshyference curve (Fig 6) wherein RAE values are plotted

against PTsPPpR ratios The cu~rve itself connects those points at which REE equals 100 When exactly on the curve it makes no real economic difference what source is chosen After choosing a suitable price ratio one can then project upward from that ratio knowing the RAI

value (or estimating it from such data as shown in Fig 4 using citrate-soluble P content) one can then choose the source on the basis of both agronomic and economic conshysiderations For example if the price ratio is 25 and the RAE value of the phosphaite rock is greater than 40 the rock phosphate in question would be used However if the RAE value was less than 40 TSP would be a better choice There are indications that if the P in the more soluble phosphate ro~cks (North Carolina north Florida central Forida) is less than half as expensivz as that in TSP these rocks would be feasible altereaives to TSP on soils similar

to thoseused in Thailand This analysis does not take into account the possibility

of lower yields from use of phosphate rock In addition only a portion of the various yield response curves was used in this anlysis ie up to 22 kgha Beyond this

rate yield response was much less pronounced it could be argued that at less than maximum yields TSP would produce a certain yield at lower rates of P than would phosshy

pow ofrock This would especially be true for rates applioa example at Klong Luang 5500 kg of

rice pcr iectare could have been produced with either Ii kg of P as TSP or 44 kg of P as son of the more reacshy

tire phosphate rocks It should be pointed ot however

- 68 shy

(IIKIS amp YOUN( ARIFICIAL WEATIIERING OF OXIDIZED p[ll- IV

that this is the yield level that would show the widest difference such is the advantage of hindsight

Farmers generally prefer granular fertilizers for machine

or hand application This is a disadvantage for the phos-phate rocks which are normally arplied in finely divided form Recently experimental quantities of granular urea-

phosphate rock mixtures have been made by TVA Results of trials with these fertilizers will be reported elsewhere

LITERATURE CITED

1 Armiger W H and Maurice- Fried 1957 The plantavailability of various sources of phosphate rock Soil Sci Soc Amer Proc 21183-188

2 Bengston G W E C Sample and S E Allen 1974 Re-sponso of slash pine seedlings to P sGurces of varying ci-trato solubility Plant Soil (In press)

3 Caro JIt and W Hill 1956 Chard eristics and fer tilizcr value of phosphate rock from different fields J Agr Food Chem 4684-687

4 Ensminger I E R W Peirson and W II Atmiger1967 Effectivencs of rock phosphate as a source of phosshyphurus for plants US Dep Agr ARS Bull 4112S

5 Engelstad 0 P J G Getsinger anid I J Stangel 1972 Tailoring of fertiliers for rice cnnece Valley Author ftyNational Fertilicr Developmnent Center Hull Y-52

6 Khasawnch F E and Jane P Copcland 1971 (otton root growth and uptake of nutrievos relation oif phosph

rus uptake to quantity intensity and buffering capacit) Soil Sci Soc Amer Proc 37250-254

7 Lehr JR and G H McClellan 1972 A revised lIbora tory reactivity scale for evaljativg phosphate rocks for direct application Tennessee Valley Authcrity National Fertilizer Development Center lull Y-43

H Terman G L S EAllen and 0 P Engelstad 1970 Response by paddy cice to ratcs and suurces of appliedphosphorus Agron J63390-394

DIVISION S-9-SOIL MINERALOGY

Artificial Weathering of Oxidized Biotite IV The Inhibitory Effect of Potassium on Dissolution llate

R JGILKES AND R C YOUNG2

ABSTRACT

Rates of dissolution of oxidized biotites in OIM 001M ICI are severely depressed in the presence of IM KCI The amovnts of Al Mg Mn dissolved in the first eytraction are similir to those found without KCI however subsequent extractions remove these elements at 10-20 of the corresponding lICI rates This effect may be due to a decreased rate of vermiculite formation thereby reducing the effective basal area exposed to attack A decrease in dissolution rate with increasing ferric iron content was still apparent in the presence of IM KCI

Additional Index Words X-ray diffraction infrared aborp-

N EARLIER papers of this series the tole of biotite in soils

as a source of both macro and micronutrient elements

has been discussed ((Gilkes Young and Quirk 1972 1973ab) Experiments in artificial weathering uiing as va-

riety of extractants were undertaken to determiie the inlu-

ence of oxidation of octahedrally coordinated iron on the bull release of structural cations to solution The results of this

work demonstated that biotite behaves anomalously with respect to the other common ferromagnesian minerals found in soils Oxidation leads to the development of a high degree of resistance to cation exchange and dissolution Several authors have coiwludcd that decreased rates of K

Contribution from the Dep of Soi Science and Plant Nutri-tion Institute of Agriculture Univ of Western Australia Ned-lands 6009 Western Australia Received 29 Sept 1973 Ap-proved 8 Jan 1974

2 Senior Lecturer in Soil Science and Research Officer respeclively

replacement in electrolytes shown by oxidized biotites are

a result of the inclination of structural hydroxyl adjacent to newly created trivalent iron or vacant octahedral cation sites (Robert and Pedro 1959 Barshad and Kishk 1968) Gilkes et al (1973b) suggested that decreased rates of disshysolution of oxidized biotite in 0001 0t)l 0Af CI may also be due to the presence of inclined hydroxyl In this case a smaller surface area external and exposed intershylayer may be available for attack if K replacement by hyshydrogen ions occurs at a slower rate in oxidized biotites

Gastuche (1963) has shown that significant dissolution ofthe (IIM) biotile face may occur and it is easily demonshystrated that the proportion of exposed (001M) face in weathering biotites depends on the percentage K replaced

Rausell-Colom ct al (1965) have shown that hydrogen ions act in an identical fashion to metal cations in K exshy

change from micas In particular exchange c-f K by hydroshy

gen ions will be terminated or greatly reduced by high levels of K in solution Thus if dissolution of oxidized biotite by

acids is carried out at sufficiently high K levels to prevent vermiculization any differences in dissolution rate that may occur cannot simply be ascribed to differences in rates of K replacement The following results were obtained from such an experiment which unlike the experiment described in Parts I and II (Gilkes et al 1973ab) does not attempt to simulate natuiral - conditions

MATERIAILS AN) M HIiODS Further subsamples of the less than 0 hiotites used in K

excherandbaid disoo tu es (G iles e9n K exchange and acid dissolution studies (Gilkes et al1973ab) were used in these experiments Preparation of sequentiallyoxidized biotites without intermediate vermiculite formation is

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440 4 414 I440 US0A 4441 IIW iI40 AWc 4 I~qamp~

0 44 ow Alt~a0404 4 $a ~ia4I6

4w 44 4 A 9i)al 448404 AsjpW4114 voso444q

4~b~~ 444 AW4iU a-w $ 4 $ts

m- 4A4 4AWWO 44 $4amp iuamp-4)Ia ampW x~I~4~

~ i~P 4 4 wl 444 41A ~4 4~~E4166 I144 4t~w i14

4wamp444sa444 Awt4~ PA 4l $WX qO j44 at4 44w la44 C~ to~ v-40

io- s4aq4 4Wvs i 44t amp 4W 4-1ampo-v 4tI 44041 4 4~ kikamp3o 41

0)6 4-44 Wl 44 4444 OV l44 i444 441 0 4NW44bk 1V420A

~~O P44 44is ~ ~4 Aloti~S~3vool41~

0uI 4044~Me ~ ~ N4

4 jk-4il4 9-4 jio4 4 4I4wSj- ~ 4 sZiamp 44s)

) o~4w4 4444~S Is~4~4 ol I i A 4~ ~

4Ii I~4I4M$~ ~I

QOWIf XVif k

4004 004o4f U A

-w i4 I~~~

40440wo oow IVTA 44qol 644

4I~~~4J 00S4 4410 114w- A44W Wamp ~

6WViso4wb f vfpo w

w0OIA - i f iIS

f4 A 00 1 o4

I1~wo ow4O4-40404f-4 ~

TOM I

Cs VWA1 t lw Vairtile ot P44Y 44c KW MI1

fiat Wm~~JL U Lem~ampuJampAJ Wat IO

~ 941~1 41 ~~~~j~~qt~~8IJ WtS dobu

Table 2

Mttct of 0 Sourco aampW $At On Upt~ks of 0 by Two Varitgtos of Paddy Rice

gr~a 1971

~ MMUampL~ ~L ~ nYLALI~ 11 lemall

I ie

W0 v slit III I) tQo9

KvN 1 17 111 1119

or 444M7

111a

i1$0N ~ It$ 121

1$

x IV ~404 tot Vsr 1 P1 41 w otv 1

- 24 shy

India--The results of four experiments conducted with flooded

transplanted rice in India by the All-India Coordinated Rice Project

Hyderabad are given in table 3 The response to N was excellent the

yield without N being only 41 of those obtained with basal applications

of N as uza With basal applications of SCU the yields were 20 higher

than with basal applications of urea and in the three experiments in

which urea applications were split yields with SCU were 18 higher than

yields with split applications of urea When comparing the average Nshy

response (kamp grainKg N) yields were increased 13 more by SCU than by

basal applications of urea

The data from one experiment with light irrigated rice in India

are given in table 4 yields were relatively low and differences between

N sources or method of application were not significant However yields

with SU tended to be higher than when all urea was applied at planting

but lower than when split applications of urea were applied Again yields

increased more than 13 more with SCU than with basal applications ofwere

ur

In tables 5 and 6 the yields of a short-duration transplanted

rice grown in irrigated light-textured soils at five locations in India

indicate that higher yields were obtained with SCU than with urea when apshy

plied as a basal application Yield increases due to basal N applications

were 502 greater with SCU than with urea However split applications of

resulted in yields equal to those obtained with basal applications ofurea

CU

The yields of direct-seeded upland rice grown at three locations

to India are given in table 7 and the relative yields in table 8 Yields

were low due to drought but good responses were nevertheless obtained for

- 25 -

Table 3

Effect of N Source and Time of Application on Yield of Paddy (Flooded) Rice in India 1972 (Summary of Reported Data from 4 Experiments)

Experimental Number Source Rate Method Yield Relative N-Response

and of of N of Yield Kg Grain

Season Nitrogen kgha Application mtha Kg N

- - - 196 34 -

Urea 120 Basal 573 100 314

11 Urea 120 80 + 40 611 107 345 Rabi SCU 120 Basal 713 124 430

12 - 0 - 202 30 -

Urea 125 Basal 682 100 384

Rabi Urea 125 35 + 20 + 35 + 35 633 95 344 SCU 125 Basal 781 115 463

13- 0 - 168 44

Urea 100 Basal 385 100 217

Kharif Urea 100 30 + 20 + 25 + 25 400 104 232 SCU 100 Basal 462 120 293

14 -

Urea -

125 -

Basal 355 650

55 100

-

236

Rabi SCU 125 Basal 781 120 341

-- 26 -

Table 4

Effect of N Source and Time of Application on Yield of Light Irrigated Rice in India 1972 (Summary of Reported Data From

One Experiment at Pattambi)

Experimental Number Source Rate Method Yield Relative N-Response

and of of N of Yield Kg Grain Season Nitrogen (kgha) Application (mtha) Q) Kg N

38 0 - 204 85 -Rabi Urea 120 Basal 241 100 308

Urea 120 60 + 0 + 30 + 30 267 ill 525 SCU 120 Basal 255 106 425

Table 5

Effect of N Source and Time of Application on Yields of Short-Duration Transplanted lice Variety Grown on Irrigated Light-Textured Soils at 5 Locations in India 1972

(Snmzarized From Reported Data)

Rate Grain Yields (MtHa) Source of N Method of N GrainI of N kgh Application Faizabod Karjat Mandva Pattabi laya Averaje X

- 291 266 211 19 340 260 -

Urea 100 Basal 386 407 361 285 482 3 124 Urea 100 50 + 25 + 25 399 430 434 334 6amp2 4A8 186

SCU 100 Basal 368 468 439 360 572 41 181

Table 6

Effect of I Source end Tlae of ApplIcattoo c RIstave Tle24 of a rt- rat1 T Lsd lice Vasrety Crin o Irrigated L41tshy1 at S Locitite mindi 1972

Rate ____________14_3

Source of X N~tbad of Of X An 1 tat14 1 acr X__T1 4v tatW ttva

- - - all 7i i

95l 119 1 1~ ~~~~~ an iI3lli i1

WRI

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4

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404 400

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A 44a4P4 ~~ 44p $444m 04I-Aamp~ 114144

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04 o oa4414 -4V~iWO440

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4A -414+ 4amp v A44

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4w 444 1 400I WA 4i A

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toI4Gkoft t4ls04 14qobe itk 4roico at Vbeif us~ 47aamp 411

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Stt19 Of 0 SeOO M IbAWO AffikampI 00 Vt414 Ot VPtd 44 tM~wuOWe tni144 Ite W 1iw)ts 060

211 U e 1dit f

w 0 31 ~ 19 AA 116 1 AS Ma )4 ) At

wx451146

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owel4440 00VII O A ofWM PwmeeA st rof (Amrol IMVf

Mt ot U 6q-wto~ COW i 4t~ eso

Tel of ate (01m itl it Iiuma tWuJt)

21L1L LW ufU~ vie 114 3 10 106

As 11 i 41 4 smg LAY1 $Of 41)

Tabl I

f~ttwi Ot 0 6wirce 81d At$ a vt1d at flUop4d Rico to Vitjorim (1ITA)All fortitfour to rsodkeet OA lC~OVPr4( 114 5iI 000

W Iotors Ftslanp tospg Irritd for Two thvk Afler flontiw wft rkwa~ Floo4d 191)

- -I-of LWAIM) (IS YJl- fl-----II)

-0 10)

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4of O 149 6MID O 41110

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- 38 -

Table 18

Yild of aemati-370 Rice at Punjab Agricultural Research

Institute in Pakistan in 1969-70 Grown Under

Couditions of Intermittent Flooding

Pate of application

=IL

o 0 67 67 100 100 67 67

100 100 67 67 200 100

Average for Sources

Ntha

AS 260 gres 279

320

Source f5

-

AS AS Ura Urea SCU SCU

Yield

Relative

93 100 115

(M)O

Yield

Increase Yield Due to N

(Ktlha) (mtha)

-212 245 033 274 062 260 048 297 085 315 103 325 112

Yield Increase

Relative

72048 067 100 108 161

(2)

- 39 shy

Short-statured high yielding rice varieties grown extenshy

sively in northern Peru require extremely high rates of conventional

N sources to achieve maximum yields The recovery of applied N is

extremely low due to the use of intermittent flooding This water

management system results in heavy N losses even with properly timed

split applications In search of simpler and more effective methods

of N management eight field experiments were conducted in the region

to evaluate sulfur-coated urea (SCU) an experimental slow-release N

source supplied by the Tennessee Valley Authority Rice yields were

increased an average of 59 more by pretransplant-incorporated SCU than

by urea or ammonium sulfate applied in the same manner SCU produced

excessive vegetative growth which resulted in yield reductions at high

N rates

Regardless of an assumed 48-higher unit N cost in SCU the

overall benefits of pretransplant-incorporated applications of SCU

were favorable since there was a decrease of 40 in the optimum rate

of N and the need for precise timing of application was eliminated

Pakistan--In Pakistan basal applications of AS urea and

SCU to rice grown under conditions of intermittent flooding in 1969-70

(table 18) indicate that SCU is a superior source of N as compared to

urea or AS when all N is applied at or before planting The data also

indicate that a yield response was obtained for P applications but a

comparison of N sources at each level of P indicates that no interaction

between N and P was present so that differences between N sources were

relatively the same at each level of P Yields were increased about 60

more when SCU was applied than when urea was applied Yield increases

with AS were only about 72 of the increase obtained with urea these reshy

sults do not agree with the generally-reported superiority of AS as comshy

pared to urea as a source of N for rice

- 40 -

In 1973 experiments were conducted in Pakistan using both

Basmati-370 and IRRI-6 varieties of rice grown under conditions of

When all N was applied at puddlingintermittent flooding (table 19)

or 12 at puddling and 12 at panicle initiation both AS and SCU were

superior to urea with SCU tending to be the most efficient source

However when N was applied 12 at transplanting and 12 at panicle

initiation SCU was the poorest source of N This would indicate that

the release of N from SCU applied at these times is too slow for optimwn

plant growth

In another experiment in Pakistan in 1973 no differences

in the effectiveness of urea AS or SCU were noted in the yields of

continuously-flooded rice (table 20) Again these results are conshy

sistent with earlier results which indicate no superiority for SCU

when rice is continuously flooded

Nitrogen Studies--Maize

A series of three experiments were conducted by IITA in

armo-Nigeria in 1972-73 comparing AS urea SCU and

CAN (calcium

nium nitrate) as sources of N for maize (table 21) A significant

yield response was obtained for N at each location but no conaistent

differences were noted amaong sources These results are consistent

with results at other locations which have not shown that SCU is a

superior source of N for maize grown over a period of 3 to 4 months

Nitrogen--Wheat

The yields of wheat in Pakistan in 1969-70 (tables 22 and

23) show that yields with SCU) tended to be lower than those with ureaJ

although at one locction where sorghum was grown followilng wheat with

Table 19

Yields of Basmati-370 and IRRI-6 Rice at Punjab Agricultural Experiment Station in Pakistan in 1973 Under

Conditions of Intermittent Flooding

Rate Yield Source of N Time of Yield (Mtha) Increase of N B-370 IRRI-6 Application Basmati-370 IRRI-6 Average (Mtha)

0 0 - 21 353 287 -

SCU 90 150 At Puddling 325 545 435 148

Urea 90 150 At Puddling 309 500 405 118

AS 90 150 At Puddling 324 529 427 140

SCU 90 150 Puddling 372 572 472 185 Panicle Initiation

Urea 90 150 Puddling 335 502 419 132 Panicle Initiation

AS 90 150 Puddling 353 529 441 154 Panicle Initiation

SCU 90 150 After Transplanting 312 562 437 150 Panicle Initiation

Urea 90 150 After Transplanting 340 624 482 195 Panicle Initiation

AS 90 150 After Transplanting 349 583 466 179 Panicle Initiation

All plots received 45 lbs P205acre as single superphosphate

Relative Yield Increase ()

Source of N At Puddling Puddling Panicle Transplant h Panicle

Urea 100 100 100 AS 119 117 92 SCU 125 140 77

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-48

Therean laiictw that It lbs P to th e am lukis

obosomhu rocks 0entk catetas rth Unrtdo costrat frwt) to

ht tse balt s Owosiv as that to TwP it rocks WM bo

fmtbt alteruutiv to MSso gotastte to~ Ik lee used to

ThUAIAd

Tht wMl dt gotmtmlaoti wout th possibility

of law Vhld free ww e1 e66001 4 It cooUt be YgWd Sutt

a4 10 0410 SWUSSM yt$4e TOP wUd predWr A r~ftIf fl~W t

1f f ot P the wuld phosphae rck TWOe viWMW efocitill b

true to low rttos t tsplusatiI P wi 9 Ma Liiam $S

amp4at r per Wforssota Mav two 64eed Wilk elikor It 44 of

P go Mi er 4A bg oftoP aon of tewmrowtni pboophals fwAh

It vwld be polotrd A Wevero wtht Is the jteld level that

W414 gk tko videm dtterem~j o(A 1 the 4~etamp tk~e~t

P11~0 pra~lpj prefer gre4r tuftlter for whlae

of hoaw ppltrstie Mhe to a dloedveaP for The PINSOO rocka

vkth m r II spotted 10 ftewil 4106Me tem

Nub studios we ovsosd o IVA vol gramleid a

forgof wee aMW pbsepbots A fths pemhawe evsielew us

Odellod to detMlee it otteettvmm of 11agotated Stoture of

mmfp MW phapa A (CI) sed graewletod pampAtlti arlolatod Pa

asowcs of P tof ttde ro The wreem proucts omre raGther

pemour~a ot P syag besmti andMi as elt ov so gpamwhr

iuipiqffhate(TS) low twseeo Is eftwiltve Is thet

W41 preeme wae oialain ire post-rItoi effriq to Stanlato the

pud6itt of Irto paddle Wee ofsdlseireplastiq

0 49 shy

lbs partially scldiaatede grawilated Ml prodlucts Vere isshy

toiwdiats in 5tftOvttWS54 betwee wroiPi ad TVP NotV5Ymf to

me coo were they mere twoe $a a etfective ao TIP 00 sipifleast

LVSUMI5 at0 efecto wore toun tor thee produteo Timely dtIampWde

FR (-t00 mmoh) Uia amp~rally oar affective than Owe gra8448r FOampprodt

featal twos o 6 aotetire s I

Nowvero it to felt that sfortber field euprtet vth

hese interials Amd ether typs of grometatodl Wter nre wrrautad

hater ceeuwodh that they have me areec poteatlal toi additoG

e tate wAne the sectte as OtawrI sed bovoloen turther

euperimeste vth few reck pboophar s0d with reck pbophat treated

to sehesa citrata selmtliy or to ha csaducted

Metbir sertes of tbme enprtaeats wae c~edtmcted by IITA

to Ut~rta copal TVP AOP APP aed it at see tecastisix (table 14)

No dot lalt sewseltles teh draw tree thee results simouely em pear to tlvdl bsww they do stwgpt tbat forthew work with

MR to werramid so tbme sels

Table 24

LttcttF Swce MaPlate 06 ieldot IM AWaia CoelsANS at IITA (Ugboda ad Apoin ail sorit) aid at Ike (AUaba s5i series)

1973

Plate ot IP Apinu 5 poundebods A1ab

Ocrol 0 Z94 419 M)

Tr ipl ruprphite 20 349 3799378

Triple vepput 40 M09 410$

Triple 6wp~~b1 4271 4344 42250

Ammotw-ritpophW to 4201 4124 4040

Amosim-rdop~phlt 40 4270 4106 4231

AM tuo-polpephats 20 404 4244 3794

~eai~mpelppepbuI 400)49 4094

Cee m-pbpbt to- 59

momee eph lto 0 4192

LSO (0 0$) 29 1025

Th WPII

- 51 shy

101Y114 tpeM-fI PEP~tbRP YO

1 ~ ~ gmw 1pc~biofl- 9 Kla4v4h

Upia U04 Copfind am Crehout Stet Rpano at (Ia4

rico t IF t rume6 orth~ Caralto phoophale rocl QAR) vaUN pqU41 to

roopon from cmonetrat4 gsporphophai (CIP) who ort$o4 oil k

was 45j itwas tafertor vb protioo4 oil p war OS Ib 4iffer~c

in rtc reepos to X cod14 oo bo ttrit4 4 4 hvsciag of boil p

~ Pt o r11221 0 tP

c theto the rhimecyllndor of rico tots par to)14M4i1 roeoi~t

ed oil emd PA prior to tho ont of an~robi4 cMioe AA~ oIifoshy

nAte bYpot t taet~d tO fC4sin t~r 4PWden0 Of f Ot(tivshy

ofOWailiJtyno o prefla4 all Put that 4t01etoo 14 tvsIk

of the Ott to prvvld a 014for C4m0 44 mI 1 o4sf

EfftC ftPet141on AIAM-0 V f401td 4 4iv 440 Mtft

Aa torfat VampP f4MWfCi4W04wt0amp to 4eturWlI Ot(Wel~drIC ft

Ot f tM6 the flooded Ott 00 14 04019I Pft0uAw Of gAr~s~lr

pkS$t M40b MP) Tw P1101 Piset Prodwie W-e 10M0di Wr04

(10-1) emW 0aretilp ddw01at4 P WAA firom Rrth M~flRU414~$

wee cowiared with fie Md reWim 44104 proo~fo) foruk oith laWItter

I v te-PR P OW1004 4 4 O Wf ottil OW ellt Oo

Oveiel1 the 40tt dmcruie to effetotww Wtollowui Co fme

PR tpaUIB1I ldoltmo PR (pamwlatr) offr~- ArmeuM) 0 orwi

- 52 -

Effect of N Sourc6 and Water Management on Response of Rice

toe Zn- M Giordano J J Mortvedt OP Engelstad and Greenhouse

Staff Several rotes of CO(14H2)2 and (H )2So4 vith or without ZnO

wore applied to flooded and nonflooded Crowley oil (limed to pH 75)

to determine response of Bluebelle rice to Zn Yields with both N

sources veotrgreator on flooded then on nonflooded soil In the abshy

ence of applied Zn total dry matter production vith CO(NH2)2 was

slightly lower than with (NH)2S04 on flooded soil and considerably

lover on nonflooded soil Concentration of Zn wan higher in straw and

grain of plants roun on flooded than on nonflooded soil Although

concentration of P was unaffected by N source or Zn rate there was

som indication that cranslocation of P from straw to grain may be

depressed in nouflooded rice Concentration of N was lower in straw

grown on flooded than on nonflooded soil due to apparent dilution

thereas both X sources resulted in similar N concentrations in straw

at all rates of N application the N concentration in grain increased

with 0 rAse

feSpongi gf(SM to Chjorospodiostte and Related P Sources--

Si Allen and Greonhoue Staff A greenhouse pot experiment was

couct44d with corn Brown on Hountview silt loam to compare the ofshy

fectlivees of chlorospodiosito (Chlor-l) with concentrated supershy

phosphate (CP) Thomas slag and North Carolina phosphate rock (NC-PR)

Oil-prillad urea-phophato rock (UPI) FeA1JMP 20 7 and monomthyl

phosphate were included in the experiment Based on yield of forage and

uptake of P by tvo crops each of 6-weeks duration the following conshy

stui were dravat

I Chlor-1 was slightly loss effective than CSI Thomas slaS or NC-PR

from which Chlor-l wae prepared

- 53 shy

2 Granular UPR was a poor source of P its effectiveness was greatly

increased by reducing the particle size to -35mesh

3 FeAlNH4P207 was unavailable to the crop

4 Monomethyl phosphate was equivalent toor slightly more effective-

than CSP

Research Indirectly Related to TVA-AID Project

Response of Several Rice Varieties to Zn in Moist or Flooded

Soil--P M Giordano J J Mortvedt and Greenhouse Several varieties

of rice from Mexico and the Dominican Republic currently under investishy

gation in Puerto Rico for adaptation to upland culture were compared with

some established United States varieties with regard to Zn response on

moist and flooded Crowley sil (pH 75) Chontalpa (Mexico) Bluebelle

(Texas) and Starbonnet (Arkansas) were most responsive to applied Zn

Juma (Dominican Republic) intermediate and Sinaloa (Mexico) and Calrose

(California) were the least responsive The Sinaloa varieties (Mexico)

appeared to be best adapted to non-flooded conditions whereas Chontalpa

and Calrose were poorest Concentrations of Zn generally were higher in

plants grown on flooded than moist soil

Pattern of Growth and Zinc Accumulation by Rice--P M Giordano

J J Mortvedt and Greenhouse Staff Rice plants were harvested at weekly

intervals from shortly after emergence through maturity The objective

was to determine the rate of growth and Zn uptake by a Zn responsive varshy

iety (Bluebelle) and a less Zn-responsive variety (Calrose) in the presence

or absence of Zn applied to Crowley sil (pHl 75) Dry matter production

of Calrose was linear with time of growth and of a similar magnitude until

heading with or without applied Zn Bluebelle followed a similar pattern

where Zn was applied However in the absence of applied Zn foliage yield

was reduced markedly

-54

Uptake of Zn was similar for both varieties whenZn was

applied Dry matter production and Zn uptake by the two varieties

also were comparable when Zn was applied However yield of Calrose

was much higher than that of Bluebelle in the absence of applied Zn

while Zn uptake was only slightly higher This suggests that the lesshy

ser responsiveness of Calrose to Zn may be due to more efficient utilishy

zation of Zn There was no indication of a greater demand for Zn durshy

ing reproduction in either variety as was suggested in earlier greenshy

house experiments

Response of Upland Rice to P and Zn--P M Giordano J J

Mortvedt and Greenhouse Staff Several rates of P and Zn were applied

to Crowley sil (limed to pH 75) in factorial combination to determine

whether differences in rice growth under flooded and nonflooded soil

conditions are related to plant nutrition Although straw yields were

slightly higher in nonflooded rice receiving adequate P and Zn grain

yields were higher in the flooded crop increased rates of F andor Zn

did not result in equal yields Except in the highest Zn rate (75 mg)

concentrations of Zn in both straw and grain were higher with flooding

Concentration of P increased with rate of applied P and was higher in

the grain or flooded than upland rice at a comparable P rate In conshy

trast concentrations of N were lower with flooding due in part to dilshy

ution from increased growth

Rice Response to N and P in Flooded and Unflooded Cultures--

G L Terman S E Allen and Greenhouse-Analytical Staff Rates of

N from 250 to 2000 ntpot and P from 0 to 1000 mtpot were applied for

Nato rice grown on Mountview sil and Sango sicl (625 kg of soil per

pot) Market yield response to N and P was obtained Yields of straw

- 55 shy

total yields N uptake and N recovery were higher on unflooded than

on flooded soil cultures Grain yields however were slightly higher

with flooding These results indicate that with adequate applied

nutrients especially of N rice yields without flooding can approach

or even equal those under flooding

Uptake of N P Ca Mg and Zn increased with yield response

to N and P while K uptake decreased on the Mountview soil Concentrations

of N and P increased with applied N and P respectively while concentrations

of other nutrients were diluted in most situations with yield response to N

or P

Results from this experiment show that amouats of N applied in

previous pot experiments for rice have been much too low especially if the

crop was grown to maturity

Response of Corn to S and N i UUASand Urea-S--S E Allen

and Greenhouse Staff Three greenhouse pot experiments were conducted to

measure response to S and N in ulfur coated urea (SCU) urea amonium

sulfate (UAS) and urea -S as well as estimate N losses from surface apshy

plied N sources

In Experiment 260 less than 20 of the S mixed with the soil

was recovered from SCU or urea-S granules by two crops of corn as comshy

pared to 45 or 80 from flowers of S or Na2SO 4 CLop response followed

a similar pattern

In Experiment 260-A N sources were surface applied and alshy

lowed to dry for two weeks before incorporation Into the soil and plantshy

ing Recovery of N by two crops of corn was 77-82 for AN an compared

to 37-70 for urea UAS urea-S and ICU Thus n this experiment loss

of N from urea did not appear to be re~dcud by light S-coatlngn or by Inshy

corporating S or AS in the granules

-S -

I xbprZnSlt a Wtch aU Meyto 0-Ai Wt f9r

higher reermo teOrtOrs cOM reSpWNO i r0100 Of N w

not oaisteontly related to sewe ot N In edl tust 0 ioltiUe Lim

lo in VMuwpped evlmtUTS 48 merind by seirest nte appresOehe

501 for uroa as cwarod to 210 for urea peepha

Rus- or Upse to LoAmIl34I a AriMed bI Earl U

MW NOWlsIIsIr-4 L Toman 5 1 Alln and eesese StNf rio

row on Sawg did (0 tpot) We 1l0l0 Ws feritiud vith 05is

of Npot mixod with the 6011 as aureCA NiAO) 1 Age god At Ures

was also itcluded at rtt t 05 10 end 15 of Upee Theas trealshy

onto were followed 4 wpdrsetago of U s AN wre 4C 10o or at I3n

Weeks toulin up to IS pot

A soil application of 10 pot rosulvod to the maim yield

at 4 weeks Tio4 sad percont prottis t intre raite tncreased rftishy

linearly with U applictalien IeseeItally all at the m iNd wit

the moil w domitrifted after flooding Grail end straw Ilelds vere

highly correlatod with tiliriag and vlh ubers of gralm arl

The results Widicat that 0$ to 10 a of Upot as orea or

NN bsuld be sied with the oil to stilate tiilrir with adshy

ditional 0 topireased later to increase grain lIds mad protia cmshy

tout

DIVISION 54- FERTILIZER TECHNOLOGY AND USE

N$eumWe of Mt5p4Amomd 1k PindW hswk4PhI fl fRw cW ims we

Jmnwacr VW owm m

a~~00 - 0 6 A-~ -~~ PN 40OMOM X 00 Wolm n moo mot $Pto4I 4l 4 W

1 -0 Is vom omoo ~~o - W1 sfw 4E00-aU

WI pw shy-M Iampeo _10 00 mo N - o wo limoshyM~m a UAa oomw W0- -0 f40 44 MP 0v~f04i-lsm 0 PA 40of 0 0 W -W ov a Wo 006

-n-t -4adf -m W ftf

9P~~aw otom i ow sm li ilia it - ~0~f 11 40S adob 11-11 __ 9w

i A ~~~~06o ~a A VOW 4 WK-ok rie Ww -0 no 4me

00 to- W 0Nwo ww AO t

-t umi om ftaw-0

- - lh -i N N iiSolf so -ma w vow -mv__M

-~AdAjA- 44 ow 0ma 0MAW a war -mo d0 00 M o WooP 0

0kR N4 a~ow Mf o

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to$w formoop 1 so

Qm0fte Iwo 00 SAtow

a

WPMaa~I m ww

lvZW~16W IT

I

vt~~ - foa Gom

r-7- tw

A ijdMA~ trMO

otait m adtoo iMOaiq

sMs aIwO tP- owWIs

mU MW4 0e S w 96 lo ow- CO=

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bq

-- -P~~~~ -- M S um IN 0VSAww dvIs0O E0 two I 41

OV WNA w N$ lp It 40A 04 ON w 0^ 0 PW1t~~~~~~~dap~~ frO

Is WAV OUw Af 41W 0A

1A 0

1o wI0~ WSW adWOWi

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w m wO~ WWF __ootm

Wm^~~~~~~ ~~ A tookoto 00wmf

M~~~~MOt 0f O

040 wd m40 Awowmm

bo^ w

ro a W4

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womb ~mmnt I-VI~ bp

5i irn0 pwm k~ oiuwe OsMn0 Wsw e Wr~m mw6

_______Noon_Iamp__ arn ag bos m W we ap

=ib ad a $4Ws Om ThSU

mod m m406mi 1m towir - m bowI~~~AV UPuiWd a04aup hwu 000sW~11lito -- o ~ImWq mow~gnn w a ho emotwi

4~ 49akduemg6momm ~ do nedOwrnd~ o

ICU wONMOVAON w4wWR - - o 44 O Tha 40 pu4 am

hum 11 is 4111 s - sg am VW f wq 4WuM dhCi m ehamv alpso 0

-w No memwiauu so-s 1141 -f oer wwn malow Wufmmm inM UCd m I a to dip 90

- ~~ w emw euIv oflme em ~ ed~faiOeWMOWleA fC~ dim~e4s- 1um00 s uwos w siwp 3 0V es wiiu d um w

aram ad as~6 ma pgt -oI A -$-d r00= m PW Of

ff~~~- am diwda Vs Wow at 4g eltpowm woo OI teeMA AMamdmOMisan A d1 Tm WNW m4 uwwemm mmmM

Aa It mom A I b 0 ~isi ~amp~V5on m ad No wwho 1 $IV Am t t~i mmOwm a- S Am im spwwmft KV-b Osiswvn wogie

opoOw suf No~ Ow MW MCI pt~bi asiwhNd bl-d muim of woo w NN

toI4 0 06d 00 wo A Md N WILSAl DuIKWION oo A Nw U am ONq ep

ow VAN pmw amp4 li a4 WdUb p vw sopwaft a-ftgw -ee theptd OW 6 - a

at MW em matshyW M offm of4 W twampwmwausoo wo asdm65m Auamp Ahbwu in 4ih asTal ON~ al oem IN Maie dmAd A a own did ofe w17 I inM mimman Ofd ofimruwf gas Pius di aMe Kwe auw a dow iNPOOIN tmo a SO$SO~4W

MWaSM BT ALI Mh USIA UW MlO RMC i WOW TW A-~ka ad 1 1 li laiiII111I

0 -6 -1 -- - -- Ie-- - -shyis

101 ~

alm~ sas ~~~ ms a a~

ase appuadmen 44 ea ad semk Who pm4WWS lowftsIU wo WOMO dobowl ICUSJW h

A Poad KU apbos as dw sileft in as a aWhps k asIU__

pro alfp al 0 WN Is obaml~ of th es Wls pouvy Ofts oeWMed N

$ae fapree ulesaseup IfIwotohaffe St

40WilinAn 06 kw Ma ho 00 e IW aftakrw splerefAnhffsb m esmem

I$Ow Ip ampMI pasi 1ead eu an Toud 2l

Widj 6vi of V46 745WI KU waso-W im Wow 0 is610SWAOMMwasa to t

VAp 1Mampd KV ppu~s dw whaim $i a a los Al w W

Ib Milvo urns of OWe d- musA as h~ s a IuIow 8 1 ue ip

-Wlidswf of 4 ofatsIW5vsS d M M5 i RSa pm~daps In ampup 1Powworw rue hevi A b

el eas goileN ruseW4 wo duffeeme bWOM isttouwi

14 gnp40 woSalrw 11ylo amreu Mwb Isevlow roosmN~ahIt s 60 W ~tsmAIM L n ~ ~~ ~

MM I PWrawA = rMla yowIeM oa

eUW as ymlh OW by IONamph avWlbl N The mubsr 1MM Pude M~ IsA aemOWeld

IWOes A rspeas Owed ai udlWwease

por bre

wals rIs O touprua KU=plaINamppNOMeses a

W UWhk 0 ASOoml ft A poWsdvutA adesae of amr Wns ai A 0r- 1ampdd Oehs IuRawy NO Pue podllosWewwe gmak asmpnle by dMiss is amle OWN pet -W yid I MuC)ad ampAn (WiplaeT16s mOW aOW aNo fhr ft ymIed------ obealud w3t 0 OW 40IsA a VM bpR ofthW d saw ns m aI efes R 24 ad 7

e 1 d

Ii

Iw NO ~sp 44I0 so

~ ~ I $4U tml

Tile 4-00dw x uiampOW74u 0qee of

_____k _ _ shy

~ - 56I 5

-f

irenY w -a

Tiles I sed I thm Au do sel oeppled upaoIks WIM0 0da ispI amd us Ou s 106 kg

h Eaap 8n 14 sMsa of abw~greuad PU Pau WW 1 u itb IUKho 0aaphelem s 60 Otarlmmh At ~ 0sU Ishiseoo Cook oiA N uiplasu mAasslaly abess A leel

v doese a WKWye Is ks Nha m 6 sa4to dafo aONmuw The appee swm Wsssof adde N4 alalaed by vuMb ifaa W C Was sekilumganSro Is

bs eabI wish as aVWWa uwewy nap (f5s)f ad Mashes reaMeY valaes of 48 0 S414 CWm

owdb imto US Wh s vs sf 3I mld 54S fro 2 aMd 3) A A

valves a hevwae u Iar Walh basl oswas dhe uwpatr bshava of

tb~msusasl appkausu of ofta sede s have aoweN

TOW opl taoe for AieweeW 4OsmWMbas Op peas As Tabl 4 sling sob Os awowully eom grams Piel level Thes oeulam Ma sed as IM

-02

792 60L WI W A)49R Pio VOL 37 197)

primS o r OeampAd WU toa Them fl~ w At NOSSe earno maisslea Ia N he mOWamplIO yik ampWd IMe aampWmW OWa Owe wa UMs of KU to 41 Oke ampWiiIamm be dkrnety ewspokawleM(a s8 te camtd wie a eapmoe by TVA pavw ltoi NA poundrmdaka4us vrimeW460 o to ilkidm ofWW (Mtemas MuOwe 1973) TVA mwi bawld on soi ficedims IampWp seg rudwiv s~s0abet ke WNmdoe ON 01 K Is12 NOSW ie fssewnmu Ie I QvaaIi rowp IMA) f9

)amp m lodk byO voebmsaIS8OpeaWfrats 11 OWNmi a I a W idisod 0 81 Now 111 nindat Wm fysmpseaamp (If tsO tUmtI IsM $P shoroV4mmo knflkvnf (foOdme nuw ae Ow OImstwe in SM pnmm8 af tXm 10 114PIS kequoian wo Mpfii

SC~po umd spop~o VWt alm 4emWal 1 4ink PCmirsra M 1 ad AI 14bmms

1MM Ww Even to doe shw wisht b-o -Wamp Ekb fed rbaimpal of14~ Am Smpound oS mv fAaMda

MGMe -M4 Wg kmuwadM 1Wr wih SCV4 Psmuck Wff It dlL Wm 1W led 0 1 oo teeA of aiwaisme aweeoid h

1Kach Vt V amp4W ILK t)sa 10 Nareps vm This ndY ub thee hbow apiptomuasa of gulfu-aw~sd of Cup lP~~tamsl wi(i

Woeo of woo or mlm Wmiot InIasem~Wsy (heede 6Am 0 F- ad PAicv IfM tsoPm 9W famp kw~is 04eet The r4 ggm I ampbpiIs OnwAu 4nvmkstm v PAraem A4fshy

e W d inSIWfh sil $ad doke IaefitV twoer) 1 Te to theo owie effu so booJ imik WOi 100 N

-d

Is re4aled uIwq~e~w Aueee atofurnw di Capsnm ptopeatls is a oommm eiws to 100 tom of 04404man d CtdUW 4M Anw K~a do Aamp apowee WPUaN powu eel H pae iaaa thAi SCUI isWW owr hmem ISsuppl N to the li ieee F A IM1 Nampa Obo~amie m

41MB ~ ~ m ~ ~0 0-- 0 140 The ffsemn of food Nn else9~e(Ud~ ~ ~ ~~ WooksaS eAWw pjed of ho~raw of IU effadam vfdva oft xhj0I 13iAl

DIVISION 8-9-SOIL MINERALOGY

Amorphomw CeetIup en XmWra Ssrfmls

L C koits Am~ 0 tmmkaAf

ommp A faieiaAMTRACT skiwe lo nW ampM sm wi4h

Walo by a onMm I dmivid hseidm6Wlk W~edesie s

peuiieles as is s e wpwigstee eded his S -em -om 0641 h4 hisW1mWOWb~ bfem peess Wimm kv Iee

Pa~~~eakr4awiS SeUeeiNaiA WOW 14e

PWWWW t HW f hea~I~~~~~a 0th

kog Ii ampI b 1111h1atAmOem aid itsaere~m-aelmoeug toolPe aal 111W mWa Wisg ag so~ ti~Wo booviot65k Th eme Iua 1111411uiwon it es 01000 AW~CWS ~muiseeteqqsheer21111 ionev

oO00 llb K0 ibad~ ~~ doj 140WI s o mimdW um

WLIMmAmMVL 1

lill mi oHow al of a be 1974oyais4gamm wsoc wwo

rdy i of OMAN toblind id sh os 00 IN bei m us salqs m kid Vw 1 a0Msw WFW isms waf e eeiWei he-4~~e gsa dulsi

os 0aMW ofmu WA l aduWs~Ib rowuvvl3maIpm s

CaO~OP aw AlNomI 4ornomd to9 IS is -l O SI g4he rpidyThus whim m dowu bWa 0 m m- ei u

d m M 0bmSaImu M-1 ofM6 h Intun to 7I

aiba maush WAesshwn~u9dSg a osusLwpI ~ v m

M PolsdAvoWdw Ons pugm~ low iwLW m We

of~U -a~ mo uNo

0401ts of 40

A e mun5d m i vvamp sa s ow bftIS i sa omdIs a w

edi1 hswopmo an ag am Iw anom erlwaPASneooie bnwoM po

o ~ do=lr 3s fluACWoSM Owaa VolM Ain b 400b adW g o as amob ofrMOWS A oo eWmaa ow $wofdi60 ow - ema

-v K Vcon l ap ad md ld KU lbs PoabumwA od w to domi a bembe 0b lt $014 i ampmomONo

4st diwemmSod i 6o pa P)ameakiksm4 m 04M t 1iV vs 0606 o IS ft dopsss of q madl w I10000014 t 44hs

arbs awasm 00 iztv Am-~~~i u5~ms ashu is byw

e~ihs diu~wsm ~phid W A0)ad Lobe d mi-~-- 1) 14 hald

bob~wh do is poPbe~mueus l to aVE tumad 40at iai ka as m

bdisc shmm Ammmd a Sm ofd~~~~~d~A ~ a~m olWshmo

OWNSrilgf ms as

Um~~srTmws~of 4 A ad to wy mis itm voW

IN~flA4T ampMww IV Kwo~t M1CI I POWMAIS amV VARw d01M11 W V

e~~Pum-p -f AOACoe~mfmmdso isedp Am PApmi sk adw Wsk m~ o P4 m

- omlos r umIWO1in pw

lie Uvplist i piw S p wsmoW N of t as so in~tabo 440 o rodgAsect M4Ammd meM ii INAq10ed~ Pib mdWWeiW 1w -w emit TU UFm 6AV 0W A fIN 00~ lb 0PANNO 4 drp OW~It~Oi Ofme _____f WACMW0IN WMVsol~lmO ft SNAO 40 do1Si - m Md y e b ii m

of of~phaow tw bmsdf toamplboe

AjflsutomW C1D-pCTP AD mSmZLT op 1 m ow ts Wdm of P om M

IaM 0t sdw a wn a8duws i ofV -w Mm P16I4 TWO a ewu i an

ov4mnk wsi 9 Mxfeu~i am emwm ismi0wmd fq W No ~~ - f mug Aitowe eutlkowbmTV is

amppowftdmi TiM 0 Tie OAA mo p)a Mwomoi dOn4m A)w

MW 0 604 0M mm yaM 01MWOfdi to tA0 M OOAW uinw OSOb

ap is~e I the ampo A A Mwof ~Do toit op aenu w~ifiOimem~ MAN ampW)

ItsAO se Y lieowawo u~w pkow-W1b pwf on a C Nohkw is f 0o1 s do~omW C mmU4

owud6moeft 4 Obind PINa~e

~4~~wreu -A---I ad

fit~~~~O 114 4 t I mMsmm m~

im ^aim4 Nomod 06maw ee Aist em moom a rA No fmiEo of emit

~ -0

65

0IL CL OC AMXR PROC VOL 38 1974

)aT1 S4I104 ow Lusanll Tawng isa tall Thai variety known for beingIwo nonshyi s s ) sensitive to photoperiod A split-plot design was used in

S e e these euperimeots with 4 rates of P (I1 22 44 and 88t i V IV k of Pha) applied a main plot treatments and with the OF It sourMes of P as subplot treatments There were two checkS plots in each rmplicate The extra check plot was included to permit the application of fresh TSP standard Jor the

It- ti 06 + i bull fa succeeding crop the p-4me of bi was to permit accurate d awrnwal of the mdual effectiveness of the phosphate

ftinSUbI rock The P fertilioers were broadcast on the mud andthen Worporald In the soil during the last harrowing At

whM N both On ACS indx ampM time of transplanting Immediately before the last harrow61t (4j 5 4 01 P s 3Mm o Vallonal in con n 100 kgha of N as ammonium sulfate and 33 kghaWO Of Spews ampm lIW thaabe rocks do ACS indes of K as polium chloride were applied A total of 40 wa in prepw O do ctih k otent kha of N a ammoniunt sulfate was applied later in twoir P The hew oNed amp wM W for 5 of gw topdrossingp with about 5cm depth of water on the plotsvV I aiOMveffeOctveee Three to six ldayold selings pr hillwW the ACS idex were planted00OWW wia Oft fo an c irNk I p Coen 20 by 20 cm part in straight rows Hand weeding was used

and insecticide were applied for Insect control Grain yieldw was masared by sampling 5 ml of each plot excluding border rows The date of heading in each treatment and theUNiN d pbM W Weks rin tOW USA UMe In Tale yed componnts at hafvel were also recorded

I filM rsperMS esOM kdwdua 1 t ab The average yields of ough (unhulled) rice for botha 84 OW O 8uo 4 Thala TM was a locations are ploutel in PIS 3 for the first crop (1969 wet

owou thRM seaso0) The Veamps yield response was obtained at Klonge (s) W lDtO t Of dMa of1tw W d l R Luang however a 4ute satisfactory yield response was

~Mk ^d TVA UJSD ad Kd UnIveS obtalned to applied P at Bangkhen as wellXUe LaM e R qwrw Ims The sod was do Relative aponomlAe effectiveness values were calculated

VOW (a ksA w edmwL t Poesesm h Vy for these data and am presented In Table 3 The valuesdAY buo if dIe ouh ne Pee wtk a Mlak vow 1009 for th first crop are plotled against ACS index in Fig 41 This Im M i6ti l 4bNd IO a0 O mkarnk for both locatio r relationship was linear for the

11400 ThCpH 0( lb pW IW 01 th UpeiaW so Sanodion location and curtiltnear for KIng Luang The was u i 4A sksamp lMaor nrusio model amparounted for 81 of theAmO$MI Aw jAAsue Swim T1 Snh Wd variation In the AE valu for Bantkhen a square root

Mems a Iw iv fern alh$ sedm haowg dayNW W t he plAL At tdo M tM aso W s as ctminued throufh eltaM t Ofpof -le lse wo am P OeNI VeOpls 1o ealluae tI lon4erm MIdual Offccls

A on W isset i a wse to hsh eapeel of these ooihss t ocks The baagkhon experimnent was letmiaI1DlVemisthis is a w hulu Lo g Tasug ia iasael aft - Msd residual Ves will be pr-Om crok TheseTwod esewm

SWWo

A

lP~U~7 ISIIPe1iuIWN e bsedisssin ian ghth siaoelalbe

984 0 6 O O - M s -s fWPas 11eSft W d Uo al a o

o

S4l~ lIIII I~l I 1f fl

( +

+ + + m + ++++-

++ +(++ + ++++ + ++ ++

- 66 -

ENOIMLSTAD ET AL RESPONSE BY FLOODED RICE TO PHOSPHATE ROCKS VARYING IN CITRATE SOLUBILITY

I I I I j0 I I

BANOKHEN BANGKHEN

pH 56 6 - 0o

TSP

NC

5~ ~ ~ L o 4 - -shy

4 ] - --------shy04

6S

|0 III 2 44 8r 66

I I I

a 1KLONG LUANG

pH 46 z KLONG LUANG

TSP Sc2 NCFL(N)

5 FLIC) J0 TU

oshy

4 ~40shy

3 bull eM0

I - I I I I I

0 II 22 44 88 0 5 10 15 20 IP APPLIED KO HA ABSOLUTE CITRAE SOLUBIITY INDEX

Fig 3-Yield of rough rice at Klong Luang and Bangkhen Rice Fig 4-Relative agronon effectiveness () of P sources ploz-Experiment Stations Thalmand as affected by rate and Source ted against citrate solubity Index for both Thailand field ex

of P applied (crop 1) periment (first crop only)

regression model accounted for 97 of the variation in sumably resulted from crop uptake and reaction with the RAE values at the Klong Luang location soil to form less soluble products Such effects may have

These experiments were continued during the dry season been more important at the lower rates since the two TSP of early 1970 to ascertain the residual effectiveness of the curyes converged at the highest rate of application various sources applied to the first crop No new P was These data from KIong Luang indicate that (i) residual applied except for the fresh TSP standard mentioned effects of all rocks except Mlcwuri were substantial (ii) above rhe experiment otherwise was conducted in a man the relationship between relative agronornic effectiveness ner similar to that followed in the first crop of the phosphate rocks and citrate solubility levels was

The response to both freshly applied ad residual P was largely obscured and (iii) the general superiority of TSP marked at the Klong Luang location and marginal at over phosphate rock in terms of effectiveiss persisted Bangkhen In fact at the latter location the response was through the second crop so small that little can be said regarding residual effectiveshyness The yield data from crop 2 at the Klong Luang DISCUSSION experiment are plotted in Fig 5 Greenhouse and field data presented in this paper show

Relative agronomic effectiveness values (Table 3) were clearly that there are substantial differences among phosshycalculated for the Klong Luang data using both the residual and freshly applied TSP as standards It is of Interest to note that the superiority of TSP over the phosphbte rocks Table 3-Relative agronomic effective values for field experishyments in Thailand persisted through the second crop The main difference in KlowlZmlnql~the residual effects is that with the exception of the MIs- s Crop 1 Crop 21 Crop 1-shysouri rock Ihe marked relationship between citratr-soluble WoiCarolina yl 59 76

phosphate rocks and RAE had largely rds norh) a 64P conltct of th Florida (eqlral is 6969 6

disapipeared In this acidic soil (pHi 46) P would by this I14o 69 63 40 ToonesS 31 65

limo be supplied by Intermediate reaction products In addl Missou 0 o lion to residues of the initial spatlte Ts P o 2 o 0

The TSP applied to the first crop declliv-d slightly In campIafcmWataesr e id ofeuhuloefor 22MA rates of PtColeouattd as aba u tlte td18 kS ratesp dlverage yield tM868 to 22 44

effectiveness relative to the freshly applied ISP This pre- of d s4

A

4

- 67 shy

-SOIL SCL SOC AMER I

KLONG LUANG CROP 2

Si 3

eN

TAPPLIEDKGHA

Fig 5-The residual effectiveness ovarious P sources for crop s compared with freshly applied TSP Klong Luang Rice

Experiment Station Thailand

phate rocks in terms of agronomic effectiveness for flooded

rice Further these differences can be predicted by means of citrate solubility or by the ACS index It appears that

the latter is more appropriate where the content of apatite varies among phospiate rocks The most soluble phosphate rocks approached but did not actually equal TSP in limit-iuig (maximum) yield in these experiments regardless of rate applied This agrees with the results of Ensminger Pearson and Armiger (4) One needs to consider the defi-nite posribility of same yield loss in zhoosing a phosphate

rock over TSP such yield losses must be weighed against the lower price of phosphate rock The explanation for such iosses may involve concentration of soluble P in the soil Khasawneh and Copeland (6) suggest that the growth rate of crop plants is a function of P concentration that can be maintained in the soil solution If P concentration is limiting or inadequate becawe of a lower dissolution rate of phosphate rock the growth iate ard uiiimate yield will be diminished accordingly

The RAE values bascd on yield increases reflect the agronomi effectiveness of these various sources relacve

to the TSP standard however these nould be supple-

mented by an economic analysis before rational choice can

be made The following calculations will provide an estimate of

the rclativ ecooomic effectiveness(REE)

Y t Ps aXpatREE -- 100

vahtercks t sphate or e b i- eor

Price of TSPkg fo

be Price of PRkg P

PROC VOL 38 1974 leO

90r

Wsoshy

0

60-LUSEPHOSPHATE ROCK

00 10 20

PTP PR

Fig 6-Relationship between relaZive effectiveness values (RAE) and the price ratios between TSP and phosphate rock Such a figure can be used in making a choice between these

sources

If REE exceeds 100 in this calculation the phosphate rock would be preferable to TSP

The REE calcuktaaa wre used in preparing an indifshyference curve (Fig 6) wherein RAE values are plotted

against PTsPPpR ratios The cu~rve itself connects those points at which REE equals 100 When exactly on the curve it makes no real economic difference what source is chosen After choosing a suitable price ratio one can then project upward from that ratio knowing the RAI

value (or estimating it from such data as shown in Fig 4 using citrate-soluble P content) one can then choose the source on the basis of both agronomic and economic conshysiderations For example if the price ratio is 25 and the RAE value of the phosphaite rock is greater than 40 the rock phosphate in question would be used However if the RAE value was less than 40 TSP would be a better choice There are indications that if the P in the more soluble phosphate ro~cks (North Carolina north Florida central Forida) is less than half as expensivz as that in TSP these rocks would be feasible altereaives to TSP on soils similar

to thoseused in Thailand This analysis does not take into account the possibility

of lower yields from use of phosphate rock In addition only a portion of the various yield response curves was used in this anlysis ie up to 22 kgha Beyond this

rate yield response was much less pronounced it could be argued that at less than maximum yields TSP would produce a certain yield at lower rates of P than would phosshy

pow ofrock This would especially be true for rates applioa example at Klong Luang 5500 kg of

rice pcr iectare could have been produced with either Ii kg of P as TSP or 44 kg of P as son of the more reacshy

tire phosphate rocks It should be pointed ot however

- 68 shy

(IIKIS amp YOUN( ARIFICIAL WEATIIERING OF OXIDIZED p[ll- IV

that this is the yield level that would show the widest difference such is the advantage of hindsight

Farmers generally prefer granular fertilizers for machine

or hand application This is a disadvantage for the phos-phate rocks which are normally arplied in finely divided form Recently experimental quantities of granular urea-

phosphate rock mixtures have been made by TVA Results of trials with these fertilizers will be reported elsewhere

LITERATURE CITED

1 Armiger W H and Maurice- Fried 1957 The plantavailability of various sources of phosphate rock Soil Sci Soc Amer Proc 21183-188

2 Bengston G W E C Sample and S E Allen 1974 Re-sponso of slash pine seedlings to P sGurces of varying ci-trato solubility Plant Soil (In press)

3 Caro JIt and W Hill 1956 Chard eristics and fer tilizcr value of phosphate rock from different fields J Agr Food Chem 4684-687

4 Ensminger I E R W Peirson and W II Atmiger1967 Effectivencs of rock phosphate as a source of phosshyphurus for plants US Dep Agr ARS Bull 4112S

5 Engelstad 0 P J G Getsinger anid I J Stangel 1972 Tailoring of fertiliers for rice cnnece Valley Author ftyNational Fertilicr Developmnent Center Hull Y-52

6 Khasawnch F E and Jane P Copcland 1971 (otton root growth and uptake of nutrievos relation oif phosph

rus uptake to quantity intensity and buffering capacit) Soil Sci Soc Amer Proc 37250-254

7 Lehr JR and G H McClellan 1972 A revised lIbora tory reactivity scale for evaljativg phosphate rocks for direct application Tennessee Valley Authcrity National Fertilizer Development Center lull Y-43

H Terman G L S EAllen and 0 P Engelstad 1970 Response by paddy cice to ratcs and suurces of appliedphosphorus Agron J63390-394

DIVISION S-9-SOIL MINERALOGY

Artificial Weathering of Oxidized Biotite IV The Inhibitory Effect of Potassium on Dissolution llate

R JGILKES AND R C YOUNG2

ABSTRACT

Rates of dissolution of oxidized biotites in OIM 001M ICI are severely depressed in the presence of IM KCI The amovnts of Al Mg Mn dissolved in the first eytraction are similir to those found without KCI however subsequent extractions remove these elements at 10-20 of the corresponding lICI rates This effect may be due to a decreased rate of vermiculite formation thereby reducing the effective basal area exposed to attack A decrease in dissolution rate with increasing ferric iron content was still apparent in the presence of IM KCI

Additional Index Words X-ray diffraction infrared aborp-

N EARLIER papers of this series the tole of biotite in soils

as a source of both macro and micronutrient elements

has been discussed ((Gilkes Young and Quirk 1972 1973ab) Experiments in artificial weathering uiing as va-

riety of extractants were undertaken to determiie the inlu-

ence of oxidation of octahedrally coordinated iron on the bull release of structural cations to solution The results of this

work demonstated that biotite behaves anomalously with respect to the other common ferromagnesian minerals found in soils Oxidation leads to the development of a high degree of resistance to cation exchange and dissolution Several authors have coiwludcd that decreased rates of K

Contribution from the Dep of Soi Science and Plant Nutri-tion Institute of Agriculture Univ of Western Australia Ned-lands 6009 Western Australia Received 29 Sept 1973 Ap-proved 8 Jan 1974

2 Senior Lecturer in Soil Science and Research Officer respeclively

replacement in electrolytes shown by oxidized biotites are

a result of the inclination of structural hydroxyl adjacent to newly created trivalent iron or vacant octahedral cation sites (Robert and Pedro 1959 Barshad and Kishk 1968) Gilkes et al (1973b) suggested that decreased rates of disshysolution of oxidized biotite in 0001 0t)l 0Af CI may also be due to the presence of inclined hydroxyl In this case a smaller surface area external and exposed intershylayer may be available for attack if K replacement by hyshydrogen ions occurs at a slower rate in oxidized biotites

Gastuche (1963) has shown that significant dissolution ofthe (IIM) biotile face may occur and it is easily demonshystrated that the proportion of exposed (001M) face in weathering biotites depends on the percentage K replaced

Rausell-Colom ct al (1965) have shown that hydrogen ions act in an identical fashion to metal cations in K exshy

change from micas In particular exchange c-f K by hydroshy

gen ions will be terminated or greatly reduced by high levels of K in solution Thus if dissolution of oxidized biotite by

acids is carried out at sufficiently high K levels to prevent vermiculization any differences in dissolution rate that may occur cannot simply be ascribed to differences in rates of K replacement The following results were obtained from such an experiment which unlike the experiment described in Parts I and II (Gilkes et al 1973ab) does not attempt to simulate natuiral - conditions

MATERIAILS AN) M HIiODS Further subsamples of the less than 0 hiotites used in K

excherandbaid disoo tu es (G iles e9n K exchange and acid dissolution studies (Gilkes et al1973ab) were used in these experiments Preparation of sequentiallyoxidized biotites without intermediate vermiculite formation is

Page 17: I70 - United States Agency for International Developmentto ascertan, but tgl.eetad, 1, L,. ("Tailoring of Pertiltiters for ice,'" TVA ulletin Y-52) states that the staft of IOi has

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Table 2

Mttct of 0 Sourco aampW $At On Upt~ks of 0 by Two Varitgtos of Paddy Rice

gr~a 1971

~ MMUampL~ ~L ~ nYLALI~ 11 lemall

I ie

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- 24 shy

India--The results of four experiments conducted with flooded

transplanted rice in India by the All-India Coordinated Rice Project

Hyderabad are given in table 3 The response to N was excellent the

yield without N being only 41 of those obtained with basal applications

of N as uza With basal applications of SCU the yields were 20 higher

than with basal applications of urea and in the three experiments in

which urea applications were split yields with SCU were 18 higher than

yields with split applications of urea When comparing the average Nshy

response (kamp grainKg N) yields were increased 13 more by SCU than by

basal applications of urea

The data from one experiment with light irrigated rice in India

are given in table 4 yields were relatively low and differences between

N sources or method of application were not significant However yields

with SU tended to be higher than when all urea was applied at planting

but lower than when split applications of urea were applied Again yields

increased more than 13 more with SCU than with basal applications ofwere

ur

In tables 5 and 6 the yields of a short-duration transplanted

rice grown in irrigated light-textured soils at five locations in India

indicate that higher yields were obtained with SCU than with urea when apshy

plied as a basal application Yield increases due to basal N applications

were 502 greater with SCU than with urea However split applications of

resulted in yields equal to those obtained with basal applications ofurea

CU

The yields of direct-seeded upland rice grown at three locations

to India are given in table 7 and the relative yields in table 8 Yields

were low due to drought but good responses were nevertheless obtained for

- 25 -

Table 3

Effect of N Source and Time of Application on Yield of Paddy (Flooded) Rice in India 1972 (Summary of Reported Data from 4 Experiments)

Experimental Number Source Rate Method Yield Relative N-Response

and of of N of Yield Kg Grain

Season Nitrogen kgha Application mtha Kg N

- - - 196 34 -

Urea 120 Basal 573 100 314

11 Urea 120 80 + 40 611 107 345 Rabi SCU 120 Basal 713 124 430

12 - 0 - 202 30 -

Urea 125 Basal 682 100 384

Rabi Urea 125 35 + 20 + 35 + 35 633 95 344 SCU 125 Basal 781 115 463

13- 0 - 168 44

Urea 100 Basal 385 100 217

Kharif Urea 100 30 + 20 + 25 + 25 400 104 232 SCU 100 Basal 462 120 293

14 -

Urea -

125 -

Basal 355 650

55 100

-

236

Rabi SCU 125 Basal 781 120 341

-- 26 -

Table 4

Effect of N Source and Time of Application on Yield of Light Irrigated Rice in India 1972 (Summary of Reported Data From

One Experiment at Pattambi)

Experimental Number Source Rate Method Yield Relative N-Response

and of of N of Yield Kg Grain Season Nitrogen (kgha) Application (mtha) Q) Kg N

38 0 - 204 85 -Rabi Urea 120 Basal 241 100 308

Urea 120 60 + 0 + 30 + 30 267 ill 525 SCU 120 Basal 255 106 425

Table 5

Effect of N Source and Time of Application on Yields of Short-Duration Transplanted lice Variety Grown on Irrigated Light-Textured Soils at 5 Locations in India 1972

(Snmzarized From Reported Data)

Rate Grain Yields (MtHa) Source of N Method of N GrainI of N kgh Application Faizabod Karjat Mandva Pattabi laya Averaje X

- 291 266 211 19 340 260 -

Urea 100 Basal 386 407 361 285 482 3 124 Urea 100 50 + 25 + 25 399 430 434 334 6amp2 4A8 186

SCU 100 Basal 368 468 439 360 572 41 181

Table 6

Effect of I Source end Tlae of ApplIcattoo c RIstave Tle24 of a rt- rat1 T Lsd lice Vasrety Crin o Irrigated L41tshy1 at S Locitite mindi 1972

Rate ____________14_3

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- 38 -

Table 18

Yild of aemati-370 Rice at Punjab Agricultural Research

Institute in Pakistan in 1969-70 Grown Under

Couditions of Intermittent Flooding

Pate of application

=IL

o 0 67 67 100 100 67 67

100 100 67 67 200 100

Average for Sources

Ntha

AS 260 gres 279

320

Source f5

-

AS AS Ura Urea SCU SCU

Yield

Relative

93 100 115

(M)O

Yield

Increase Yield Due to N

(Ktlha) (mtha)

-212 245 033 274 062 260 048 297 085 315 103 325 112

Yield Increase

Relative

72048 067 100 108 161

(2)

- 39 shy

Short-statured high yielding rice varieties grown extenshy

sively in northern Peru require extremely high rates of conventional

N sources to achieve maximum yields The recovery of applied N is

extremely low due to the use of intermittent flooding This water

management system results in heavy N losses even with properly timed

split applications In search of simpler and more effective methods

of N management eight field experiments were conducted in the region

to evaluate sulfur-coated urea (SCU) an experimental slow-release N

source supplied by the Tennessee Valley Authority Rice yields were

increased an average of 59 more by pretransplant-incorporated SCU than

by urea or ammonium sulfate applied in the same manner SCU produced

excessive vegetative growth which resulted in yield reductions at high

N rates

Regardless of an assumed 48-higher unit N cost in SCU the

overall benefits of pretransplant-incorporated applications of SCU

were favorable since there was a decrease of 40 in the optimum rate

of N and the need for precise timing of application was eliminated

Pakistan--In Pakistan basal applications of AS urea and

SCU to rice grown under conditions of intermittent flooding in 1969-70

(table 18) indicate that SCU is a superior source of N as compared to

urea or AS when all N is applied at or before planting The data also

indicate that a yield response was obtained for P applications but a

comparison of N sources at each level of P indicates that no interaction

between N and P was present so that differences between N sources were

relatively the same at each level of P Yields were increased about 60

more when SCU was applied than when urea was applied Yield increases

with AS were only about 72 of the increase obtained with urea these reshy

sults do not agree with the generally-reported superiority of AS as comshy

pared to urea as a source of N for rice

- 40 -

In 1973 experiments were conducted in Pakistan using both

Basmati-370 and IRRI-6 varieties of rice grown under conditions of

When all N was applied at puddlingintermittent flooding (table 19)

or 12 at puddling and 12 at panicle initiation both AS and SCU were

superior to urea with SCU tending to be the most efficient source

However when N was applied 12 at transplanting and 12 at panicle

initiation SCU was the poorest source of N This would indicate that

the release of N from SCU applied at these times is too slow for optimwn

plant growth

In another experiment in Pakistan in 1973 no differences

in the effectiveness of urea AS or SCU were noted in the yields of

continuously-flooded rice (table 20) Again these results are conshy

sistent with earlier results which indicate no superiority for SCU

when rice is continuously flooded

Nitrogen Studies--Maize

A series of three experiments were conducted by IITA in

armo-Nigeria in 1972-73 comparing AS urea SCU and

CAN (calcium

nium nitrate) as sources of N for maize (table 21) A significant

yield response was obtained for N at each location but no conaistent

differences were noted amaong sources These results are consistent

with results at other locations which have not shown that SCU is a

superior source of N for maize grown over a period of 3 to 4 months

Nitrogen--Wheat

The yields of wheat in Pakistan in 1969-70 (tables 22 and

23) show that yields with SCU) tended to be lower than those with ureaJ

although at one locction where sorghum was grown followilng wheat with

Table 19

Yields of Basmati-370 and IRRI-6 Rice at Punjab Agricultural Experiment Station in Pakistan in 1973 Under

Conditions of Intermittent Flooding

Rate Yield Source of N Time of Yield (Mtha) Increase of N B-370 IRRI-6 Application Basmati-370 IRRI-6 Average (Mtha)

0 0 - 21 353 287 -

SCU 90 150 At Puddling 325 545 435 148

Urea 90 150 At Puddling 309 500 405 118

AS 90 150 At Puddling 324 529 427 140

SCU 90 150 Puddling 372 572 472 185 Panicle Initiation

Urea 90 150 Puddling 335 502 419 132 Panicle Initiation

AS 90 150 Puddling 353 529 441 154 Panicle Initiation

SCU 90 150 After Transplanting 312 562 437 150 Panicle Initiation

Urea 90 150 After Transplanting 340 624 482 195 Panicle Initiation

AS 90 150 After Transplanting 349 583 466 179 Panicle Initiation

All plots received 45 lbs P205acre as single superphosphate

Relative Yield Increase ()

Source of N At Puddling Puddling Panicle Transplant h Panicle

Urea 100 100 100 AS 119 117 92 SCU 125 140 77

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pemour~a ot P syag besmti andMi as elt ov so gpamwhr

iuipiqffhate(TS) low twseeo Is eftwiltve Is thet

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pud6itt of Irto paddle Wee ofsdlseireplastiq

0 49 shy

lbs partially scldiaatede grawilated Ml prodlucts Vere isshy

toiwdiats in 5tftOvttWS54 betwee wroiPi ad TVP NotV5Ymf to

me coo were they mere twoe $a a etfective ao TIP 00 sipifleast

LVSUMI5 at0 efecto wore toun tor thee produteo Timely dtIampWde

FR (-t00 mmoh) Uia amp~rally oar affective than Owe gra8448r FOampprodt

featal twos o 6 aotetire s I

Nowvero it to felt that sfortber field euprtet vth

hese interials Amd ether typs of grometatodl Wter nre wrrautad

hater ceeuwodh that they have me areec poteatlal toi additoG

e tate wAne the sectte as OtawrI sed bovoloen turther

euperimeste vth few reck pboophar s0d with reck pbophat treated

to sehesa citrata selmtliy or to ha csaducted

Metbir sertes of tbme enprtaeats wae c~edtmcted by IITA

to Ut~rta copal TVP AOP APP aed it at see tecastisix (table 14)

No dot lalt sewseltles teh draw tree thee results simouely em pear to tlvdl bsww they do stwgpt tbat forthew work with

MR to werramid so tbme sels

Table 24

LttcttF Swce MaPlate 06 ieldot IM AWaia CoelsANS at IITA (Ugboda ad Apoin ail sorit) aid at Ike (AUaba s5i series)

1973

Plate ot IP Apinu 5 poundebods A1ab

Ocrol 0 Z94 419 M)

Tr ipl ruprphite 20 349 3799378

Triple vepput 40 M09 410$

Triple 6wp~~b1 4271 4344 42250

Ammotw-ritpophW to 4201 4124 4040

Amosim-rdop~phlt 40 4270 4106 4231

AM tuo-polpephats 20 404 4244 3794

~eai~mpelppepbuI 400)49 4094

Cee m-pbpbt to- 59

momee eph lto 0 4192

LSO (0 0$) 29 1025

Th WPII

- 51 shy

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roopon from cmonetrat4 gsporphophai (CIP) who ort$o4 oil k

was 45j itwas tafertor vb protioo4 oil p war OS Ib 4iffer~c

in rtc reepos to X cod14 oo bo ttrit4 4 4 hvsciag of boil p

~ Pt o r11221 0 tP

c theto the rhimecyllndor of rico tots par to)14M4i1 roeoi~t

ed oil emd PA prior to tho ont of an~robi4 cMioe AA~ oIifoshy

nAte bYpot t taet~d tO fC4sin t~r 4PWden0 Of f Ot(tivshy

ofOWailiJtyno o prefla4 all Put that 4t01etoo 14 tvsIk

of the Ott to prvvld a 014for C4m0 44 mI 1 o4sf

EfftC ftPet141on AIAM-0 V f401td 4 4iv 440 Mtft

Aa torfat VampP f4MWfCi4W04wt0amp to 4eturWlI Ot(Wel~drIC ft

Ot f tM6 the flooded Ott 00 14 04019I Pft0uAw Of gAr~s~lr

pkS$t M40b MP) Tw P1101 Piset Prodwie W-e 10M0di Wr04

(10-1) emW 0aretilp ddw01at4 P WAA firom Rrth M~flRU414~$

wee cowiared with fie Md reWim 44104 proo~fo) foruk oith laWItter

I v te-PR P OW1004 4 4 O Wf ottil OW ellt Oo

Oveiel1 the 40tt dmcruie to effetotww Wtollowui Co fme

PR tpaUIB1I ldoltmo PR (pamwlatr) offr~- ArmeuM) 0 orwi

- 52 -

Effect of N Sourc6 and Water Management on Response of Rice

toe Zn- M Giordano J J Mortvedt OP Engelstad and Greenhouse

Staff Several rotes of CO(14H2)2 and (H )2So4 vith or without ZnO

wore applied to flooded and nonflooded Crowley oil (limed to pH 75)

to determine response of Bluebelle rice to Zn Yields with both N

sources veotrgreator on flooded then on nonflooded soil In the abshy

ence of applied Zn total dry matter production vith CO(NH2)2 was

slightly lower than with (NH)2S04 on flooded soil and considerably

lover on nonflooded soil Concentration of Zn wan higher in straw and

grain of plants roun on flooded than on nonflooded soil Although

concentration of P was unaffected by N source or Zn rate there was

som indication that cranslocation of P from straw to grain may be

depressed in nouflooded rice Concentration of N was lower in straw

grown on flooded than on nonflooded soil due to apparent dilution

thereas both X sources resulted in similar N concentrations in straw

at all rates of N application the N concentration in grain increased

with 0 rAse

feSpongi gf(SM to Chjorospodiostte and Related P Sources--

Si Allen and Greonhoue Staff A greenhouse pot experiment was

couct44d with corn Brown on Hountview silt loam to compare the ofshy

fectlivees of chlorospodiosito (Chlor-l) with concentrated supershy

phosphate (CP) Thomas slag and North Carolina phosphate rock (NC-PR)

Oil-prillad urea-phophato rock (UPI) FeA1JMP 20 7 and monomthyl

phosphate were included in the experiment Based on yield of forage and

uptake of P by tvo crops each of 6-weeks duration the following conshy

stui were dravat

I Chlor-1 was slightly loss effective than CSI Thomas slaS or NC-PR

from which Chlor-l wae prepared

- 53 shy

2 Granular UPR was a poor source of P its effectiveness was greatly

increased by reducing the particle size to -35mesh

3 FeAlNH4P207 was unavailable to the crop

4 Monomethyl phosphate was equivalent toor slightly more effective-

than CSP

Research Indirectly Related to TVA-AID Project

Response of Several Rice Varieties to Zn in Moist or Flooded

Soil--P M Giordano J J Mortvedt and Greenhouse Several varieties

of rice from Mexico and the Dominican Republic currently under investishy

gation in Puerto Rico for adaptation to upland culture were compared with

some established United States varieties with regard to Zn response on

moist and flooded Crowley sil (pH 75) Chontalpa (Mexico) Bluebelle

(Texas) and Starbonnet (Arkansas) were most responsive to applied Zn

Juma (Dominican Republic) intermediate and Sinaloa (Mexico) and Calrose

(California) were the least responsive The Sinaloa varieties (Mexico)

appeared to be best adapted to non-flooded conditions whereas Chontalpa

and Calrose were poorest Concentrations of Zn generally were higher in

plants grown on flooded than moist soil

Pattern of Growth and Zinc Accumulation by Rice--P M Giordano

J J Mortvedt and Greenhouse Staff Rice plants were harvested at weekly

intervals from shortly after emergence through maturity The objective

was to determine the rate of growth and Zn uptake by a Zn responsive varshy

iety (Bluebelle) and a less Zn-responsive variety (Calrose) in the presence

or absence of Zn applied to Crowley sil (pHl 75) Dry matter production

of Calrose was linear with time of growth and of a similar magnitude until

heading with or without applied Zn Bluebelle followed a similar pattern

where Zn was applied However in the absence of applied Zn foliage yield

was reduced markedly

-54

Uptake of Zn was similar for both varieties whenZn was

applied Dry matter production and Zn uptake by the two varieties

also were comparable when Zn was applied However yield of Calrose

was much higher than that of Bluebelle in the absence of applied Zn

while Zn uptake was only slightly higher This suggests that the lesshy

ser responsiveness of Calrose to Zn may be due to more efficient utilishy

zation of Zn There was no indication of a greater demand for Zn durshy

ing reproduction in either variety as was suggested in earlier greenshy

house experiments

Response of Upland Rice to P and Zn--P M Giordano J J

Mortvedt and Greenhouse Staff Several rates of P and Zn were applied

to Crowley sil (limed to pH 75) in factorial combination to determine

whether differences in rice growth under flooded and nonflooded soil

conditions are related to plant nutrition Although straw yields were

slightly higher in nonflooded rice receiving adequate P and Zn grain

yields were higher in the flooded crop increased rates of F andor Zn

did not result in equal yields Except in the highest Zn rate (75 mg)

concentrations of Zn in both straw and grain were higher with flooding

Concentration of P increased with rate of applied P and was higher in

the grain or flooded than upland rice at a comparable P rate In conshy

trast concentrations of N were lower with flooding due in part to dilshy

ution from increased growth

Rice Response to N and P in Flooded and Unflooded Cultures--

G L Terman S E Allen and Greenhouse-Analytical Staff Rates of

N from 250 to 2000 ntpot and P from 0 to 1000 mtpot were applied for

Nato rice grown on Mountview sil and Sango sicl (625 kg of soil per

pot) Market yield response to N and P was obtained Yields of straw

- 55 shy

total yields N uptake and N recovery were higher on unflooded than

on flooded soil cultures Grain yields however were slightly higher

with flooding These results indicate that with adequate applied

nutrients especially of N rice yields without flooding can approach

or even equal those under flooding

Uptake of N P Ca Mg and Zn increased with yield response

to N and P while K uptake decreased on the Mountview soil Concentrations

of N and P increased with applied N and P respectively while concentrations

of other nutrients were diluted in most situations with yield response to N

or P

Results from this experiment show that amouats of N applied in

previous pot experiments for rice have been much too low especially if the

crop was grown to maturity

Response of Corn to S and N i UUASand Urea-S--S E Allen

and Greenhouse Staff Three greenhouse pot experiments were conducted to

measure response to S and N in ulfur coated urea (SCU) urea amonium

sulfate (UAS) and urea -S as well as estimate N losses from surface apshy

plied N sources

In Experiment 260 less than 20 of the S mixed with the soil

was recovered from SCU or urea-S granules by two crops of corn as comshy

pared to 45 or 80 from flowers of S or Na2SO 4 CLop response followed

a similar pattern

In Experiment 260-A N sources were surface applied and alshy

lowed to dry for two weeks before incorporation Into the soil and plantshy

ing Recovery of N by two crops of corn was 77-82 for AN an compared

to 37-70 for urea UAS urea-S and ICU Thus n this experiment loss

of N from urea did not appear to be re~dcud by light S-coatlngn or by Inshy

corporating S or AS in the granules

-S -

I xbprZnSlt a Wtch aU Meyto 0-Ai Wt f9r

higher reermo teOrtOrs cOM reSpWNO i r0100 Of N w

not oaisteontly related to sewe ot N In edl tust 0 ioltiUe Lim

lo in VMuwpped evlmtUTS 48 merind by seirest nte appresOehe

501 for uroa as cwarod to 210 for urea peepha

Rus- or Upse to LoAmIl34I a AriMed bI Earl U

MW NOWlsIIsIr-4 L Toman 5 1 Alln and eesese StNf rio

row on Sawg did (0 tpot) We 1l0l0 Ws feritiud vith 05is

of Npot mixod with the 6011 as aureCA NiAO) 1 Age god At Ures

was also itcluded at rtt t 05 10 end 15 of Upee Theas trealshy

onto were followed 4 wpdrsetago of U s AN wre 4C 10o or at I3n

Weeks toulin up to IS pot

A soil application of 10 pot rosulvod to the maim yield

at 4 weeks Tio4 sad percont prottis t intre raite tncreased rftishy

linearly with U applictalien IeseeItally all at the m iNd wit

the moil w domitrifted after flooding Grail end straw Ilelds vere

highly correlatod with tiliriag and vlh ubers of gralm arl

The results Widicat that 0$ to 10 a of Upot as orea or

NN bsuld be sied with the oil to stilate tiilrir with adshy

ditional 0 topireased later to increase grain lIds mad protia cmshy

tout

DIVISION 54- FERTILIZER TECHNOLOGY AND USE

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el eas goileN ruseW4 wo duffeeme bWOM isttouwi

14 gnp40 woSalrw 11ylo amreu Mwb Isevlow roosmN~ahIt s 60 W ~tsmAIM L n ~ ~~ ~

MM I PWrawA = rMla yowIeM oa

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Tile 4-00dw x uiampOW74u 0qee of

_____k _ _ shy

~ - 56I 5

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irenY w -a

Tiles I sed I thm Au do sel oeppled upaoIks WIM0 0da ispI amd us Ou s 106 kg

h Eaap 8n 14 sMsa of abw~greuad PU Pau WW 1 u itb IUKho 0aaphelem s 60 Otarlmmh At ~ 0sU Ishiseoo Cook oiA N uiplasu mAasslaly abess A leel

v doese a WKWye Is ks Nha m 6 sa4to dafo aONmuw The appee swm Wsssof adde N4 alalaed by vuMb ifaa W C Was sekilumganSro Is

bs eabI wish as aVWWa uwewy nap (f5s)f ad Mashes reaMeY valaes of 48 0 S414 CWm

owdb imto US Wh s vs sf 3I mld 54S fro 2 aMd 3) A A

valves a hevwae u Iar Walh basl oswas dhe uwpatr bshava of

tb~msusasl appkausu of ofta sede s have aoweN

TOW opl taoe for AieweeW 4OsmWMbas Op peas As Tabl 4 sling sob Os awowully eom grams Piel level Thes oeulam Ma sed as IM

-02

792 60L WI W A)49R Pio VOL 37 197)

primS o r OeampAd WU toa Them fl~ w At NOSSe earno maisslea Ia N he mOWamplIO yik ampWd IMe aampWmW OWa Owe wa UMs of KU to 41 Oke ampWiiIamm be dkrnety ewspokawleM(a s8 te camtd wie a eapmoe by TVA pavw ltoi NA poundrmdaka4us vrimeW460 o to ilkidm ofWW (Mtemas MuOwe 1973) TVA mwi bawld on soi ficedims IampWp seg rudwiv s~s0abet ke WNmdoe ON 01 K Is12 NOSW ie fssewnmu Ie I QvaaIi rowp IMA) f9

)amp m lodk byO voebmsaIS8OpeaWfrats 11 OWNmi a I a W idisod 0 81 Now 111 nindat Wm fysmpseaamp (If tsO tUmtI IsM $P shoroV4mmo knflkvnf (foOdme nuw ae Ow OImstwe in SM pnmm8 af tXm 10 114PIS kequoian wo Mpfii

SC~po umd spop~o VWt alm 4emWal 1 4ink PCmirsra M 1 ad AI 14bmms

1MM Ww Even to doe shw wisht b-o -Wamp Ekb fed rbaimpal of14~ Am Smpound oS mv fAaMda

MGMe -M4 Wg kmuwadM 1Wr wih SCV4 Psmuck Wff It dlL Wm 1W led 0 1 oo teeA of aiwaisme aweeoid h

1Kach Vt V amp4W ILK t)sa 10 Nareps vm This ndY ub thee hbow apiptomuasa of gulfu-aw~sd of Cup lP~~tamsl wi(i

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41MB ~ ~ m ~ ~0 0-- 0 140 The ffsemn of food Nn else9~e(Ud~ ~ ~ ~~ WooksaS eAWw pjed of ho~raw of IU effadam vfdva oft xhj0I 13iAl

DIVISION 8-9-SOIL MINERALOGY

Amorphomw CeetIup en XmWra Ssrfmls

L C koits Am~ 0 tmmkaAf

ommp A faieiaAMTRACT skiwe lo nW ampM sm wi4h

Walo by a onMm I dmivid hseidm6Wlk W~edesie s

peuiieles as is s e wpwigstee eded his S -em -om 0641 h4 hisW1mWOWb~ bfem peess Wimm kv Iee

Pa~~~eakr4awiS SeUeeiNaiA WOW 14e

PWWWW t HW f hea~I~~~~~a 0th

kog Ii ampI b 1111h1atAmOem aid itsaere~m-aelmoeug toolPe aal 111W mWa Wisg ag so~ ti~Wo booviot65k Th eme Iua 1111411uiwon it es 01000 AW~CWS ~muiseeteqqsheer21111 ionev

oO00 llb K0 ibad~ ~~ doj 140WI s o mimdW um

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lill mi oHow al of a be 1974oyais4gamm wsoc wwo

rdy i of OMAN toblind id sh os 00 IN bei m us salqs m kid Vw 1 a0Msw WFW isms waf e eeiWei he-4~~e gsa dulsi

os 0aMW ofmu WA l aduWs~Ib rowuvvl3maIpm s

CaO~OP aw AlNomI 4ornomd to9 IS is -l O SI g4he rpidyThus whim m dowu bWa 0 m m- ei u

d m M 0bmSaImu M-1 ofM6 h Intun to 7I

aiba maush WAesshwn~u9dSg a osusLwpI ~ v m

M PolsdAvoWdw Ons pugm~ low iwLW m We

of~U -a~ mo uNo

0401ts of 40

A e mun5d m i vvamp sa s ow bftIS i sa omdIs a w

edi1 hswopmo an ag am Iw anom erlwaPASneooie bnwoM po

o ~ do=lr 3s fluACWoSM Owaa VolM Ain b 400b adW g o as amob ofrMOWS A oo eWmaa ow $wofdi60 ow - ema

-v K Vcon l ap ad md ld KU lbs PoabumwA od w to domi a bembe 0b lt $014 i ampmomONo

4st diwemmSod i 6o pa P)ameakiksm4 m 04M t 1iV vs 0606 o IS ft dopsss of q madl w I10000014 t 44hs

arbs awasm 00 iztv Am-~~~i u5~ms ashu is byw

e~ihs diu~wsm ~phid W A0)ad Lobe d mi-~-- 1) 14 hald

bob~wh do is poPbe~mueus l to aVE tumad 40at iai ka as m

bdisc shmm Ammmd a Sm ofd~~~~~d~A ~ a~m olWshmo

OWNSrilgf ms as

Um~~srTmws~of 4 A ad to wy mis itm voW

IN~flA4T ampMww IV Kwo~t M1CI I POWMAIS amV VARw d01M11 W V

e~~Pum-p -f AOACoe~mfmmdso isedp Am PApmi sk adw Wsk m~ o P4 m

- omlos r umIWO1in pw

lie Uvplist i piw S p wsmoW N of t as so in~tabo 440 o rodgAsect M4Ammd meM ii INAq10ed~ Pib mdWWeiW 1w -w emit TU UFm 6AV 0W A fIN 00~ lb 0PANNO 4 drp OW~It~Oi Ofme _____f WACMW0IN WMVsol~lmO ft SNAO 40 do1Si - m Md y e b ii m

of of~phaow tw bmsdf toamplboe

AjflsutomW C1D-pCTP AD mSmZLT op 1 m ow ts Wdm of P om M

IaM 0t sdw a wn a8duws i ofV -w Mm P16I4 TWO a ewu i an

ov4mnk wsi 9 Mxfeu~i am emwm ismi0wmd fq W No ~~ - f mug Aitowe eutlkowbmTV is

amppowftdmi TiM 0 Tie OAA mo p)a Mwomoi dOn4m A)w

MW 0 604 0M mm yaM 01MWOfdi to tA0 M OOAW uinw OSOb

ap is~e I the ampo A A Mwof ~Do toit op aenu w~ifiOimem~ MAN ampW)

ItsAO se Y lieowawo u~w pkow-W1b pwf on a C Nohkw is f 0o1 s do~omW C mmU4

owud6moeft 4 Obind PINa~e

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~ -0

65

0IL CL OC AMXR PROC VOL 38 1974

)aT1 S4I104 ow Lusanll Tawng isa tall Thai variety known for beingIwo nonshyi s s ) sensitive to photoperiod A split-plot design was used in

S e e these euperimeots with 4 rates of P (I1 22 44 and 88t i V IV k of Pha) applied a main plot treatments and with the OF It sourMes of P as subplot treatments There were two checkS plots in each rmplicate The extra check plot was included to permit the application of fresh TSP standard Jor the

It- ti 06 + i bull fa succeeding crop the p-4me of bi was to permit accurate d awrnwal of the mdual effectiveness of the phosphate

ftinSUbI rock The P fertilioers were broadcast on the mud andthen Worporald In the soil during the last harrowing At

whM N both On ACS indx ampM time of transplanting Immediately before the last harrow61t (4j 5 4 01 P s 3Mm o Vallonal in con n 100 kgha of N as ammonium sulfate and 33 kghaWO Of Spews ampm lIW thaabe rocks do ACS indes of K as polium chloride were applied A total of 40 wa in prepw O do ctih k otent kha of N a ammoniunt sulfate was applied later in twoir P The hew oNed amp wM W for 5 of gw topdrossingp with about 5cm depth of water on the plotsvV I aiOMveffeOctveee Three to six ldayold selings pr hillwW the ACS idex were planted00OWW wia Oft fo an c irNk I p Coen 20 by 20 cm part in straight rows Hand weeding was used

and insecticide were applied for Insect control Grain yieldw was masared by sampling 5 ml of each plot excluding border rows The date of heading in each treatment and theUNiN d pbM W Weks rin tOW USA UMe In Tale yed componnts at hafvel were also recorded

I filM rsperMS esOM kdwdua 1 t ab The average yields of ough (unhulled) rice for botha 84 OW O 8uo 4 Thala TM was a locations are ploutel in PIS 3 for the first crop (1969 wet

owou thRM seaso0) The Veamps yield response was obtained at Klonge (s) W lDtO t Of dMa of1tw W d l R Luang however a 4ute satisfactory yield response was

~Mk ^d TVA UJSD ad Kd UnIveS obtalned to applied P at Bangkhen as wellXUe LaM e R qwrw Ims The sod was do Relative aponomlAe effectiveness values were calculated

VOW (a ksA w edmwL t Poesesm h Vy for these data and am presented In Table 3 The valuesdAY buo if dIe ouh ne Pee wtk a Mlak vow 1009 for th first crop are plotled against ACS index in Fig 41 This Im M i6ti l 4bNd IO a0 O mkarnk for both locatio r relationship was linear for the

11400 ThCpH 0( lb pW IW 01 th UpeiaW so Sanodion location and curtiltnear for KIng Luang The was u i 4A sksamp lMaor nrusio model amparounted for 81 of theAmO$MI Aw jAAsue Swim T1 Snh Wd variation In the AE valu for Bantkhen a square root

Mems a Iw iv fern alh$ sedm haowg dayNW W t he plAL At tdo M tM aso W s as ctminued throufh eltaM t Ofpof -le lse wo am P OeNI VeOpls 1o ealluae tI lon4erm MIdual Offccls

A on W isset i a wse to hsh eapeel of these ooihss t ocks The baagkhon experimnent was letmiaI1DlVemisthis is a w hulu Lo g Tasug ia iasael aft - Msd residual Ves will be pr-Om crok TheseTwod esewm

SWWo

A

lP~U~7 ISIIPe1iuIWN e bsedisssin ian ghth siaoelalbe

984 0 6 O O - M s -s fWPas 11eSft W d Uo al a o

o

S4l~ lIIII I~l I 1f fl

( +

+ + + m + ++++-

++ +(++ + ++++ + ++ ++

- 66 -

ENOIMLSTAD ET AL RESPONSE BY FLOODED RICE TO PHOSPHATE ROCKS VARYING IN CITRATE SOLUBILITY

I I I I j0 I I

BANOKHEN BANGKHEN

pH 56 6 - 0o

TSP

NC

5~ ~ ~ L o 4 - -shy

4 ] - --------shy04

6S

|0 III 2 44 8r 66

I I I

a 1KLONG LUANG

pH 46 z KLONG LUANG

TSP Sc2 NCFL(N)

5 FLIC) J0 TU

oshy

4 ~40shy

3 bull eM0

I - I I I I I

0 II 22 44 88 0 5 10 15 20 IP APPLIED KO HA ABSOLUTE CITRAE SOLUBIITY INDEX

Fig 3-Yield of rough rice at Klong Luang and Bangkhen Rice Fig 4-Relative agronon effectiveness () of P sources ploz-Experiment Stations Thalmand as affected by rate and Source ted against citrate solubity Index for both Thailand field ex

of P applied (crop 1) periment (first crop only)

regression model accounted for 97 of the variation in sumably resulted from crop uptake and reaction with the RAE values at the Klong Luang location soil to form less soluble products Such effects may have

These experiments were continued during the dry season been more important at the lower rates since the two TSP of early 1970 to ascertain the residual effectiveness of the curyes converged at the highest rate of application various sources applied to the first crop No new P was These data from KIong Luang indicate that (i) residual applied except for the fresh TSP standard mentioned effects of all rocks except Mlcwuri were substantial (ii) above rhe experiment otherwise was conducted in a man the relationship between relative agronornic effectiveness ner similar to that followed in the first crop of the phosphate rocks and citrate solubility levels was

The response to both freshly applied ad residual P was largely obscured and (iii) the general superiority of TSP marked at the Klong Luang location and marginal at over phosphate rock in terms of effectiveiss persisted Bangkhen In fact at the latter location the response was through the second crop so small that little can be said regarding residual effectiveshyness The yield data from crop 2 at the Klong Luang DISCUSSION experiment are plotted in Fig 5 Greenhouse and field data presented in this paper show

Relative agronomic effectiveness values (Table 3) were clearly that there are substantial differences among phosshycalculated for the Klong Luang data using both the residual and freshly applied TSP as standards It is of Interest to note that the superiority of TSP over the phosphbte rocks Table 3-Relative agronomic effective values for field experishyments in Thailand persisted through the second crop The main difference in KlowlZmlnql~the residual effects is that with the exception of the MIs- s Crop 1 Crop 21 Crop 1-shysouri rock Ihe marked relationship between citratr-soluble WoiCarolina yl 59 76

phosphate rocks and RAE had largely rds norh) a 64P conltct of th Florida (eqlral is 6969 6

disapipeared In this acidic soil (pHi 46) P would by this I14o 69 63 40 ToonesS 31 65

limo be supplied by Intermediate reaction products In addl Missou 0 o lion to residues of the initial spatlte Ts P o 2 o 0

The TSP applied to the first crop declliv-d slightly In campIafcmWataesr e id ofeuhuloefor 22MA rates of PtColeouattd as aba u tlte td18 kS ratesp dlverage yield tM868 to 22 44

effectiveness relative to the freshly applied ISP This pre- of d s4

A

4

- 67 shy

-SOIL SCL SOC AMER I

KLONG LUANG CROP 2

Si 3

eN

TAPPLIEDKGHA

Fig 5-The residual effectiveness ovarious P sources for crop s compared with freshly applied TSP Klong Luang Rice

Experiment Station Thailand

phate rocks in terms of agronomic effectiveness for flooded

rice Further these differences can be predicted by means of citrate solubility or by the ACS index It appears that

the latter is more appropriate where the content of apatite varies among phospiate rocks The most soluble phosphate rocks approached but did not actually equal TSP in limit-iuig (maximum) yield in these experiments regardless of rate applied This agrees with the results of Ensminger Pearson and Armiger (4) One needs to consider the defi-nite posribility of same yield loss in zhoosing a phosphate

rock over TSP such yield losses must be weighed against the lower price of phosphate rock The explanation for such iosses may involve concentration of soluble P in the soil Khasawneh and Copeland (6) suggest that the growth rate of crop plants is a function of P concentration that can be maintained in the soil solution If P concentration is limiting or inadequate becawe of a lower dissolution rate of phosphate rock the growth iate ard uiiimate yield will be diminished accordingly

The RAE values bascd on yield increases reflect the agronomi effectiveness of these various sources relacve

to the TSP standard however these nould be supple-

mented by an economic analysis before rational choice can

be made The following calculations will provide an estimate of

the rclativ ecooomic effectiveness(REE)

Y t Ps aXpatREE -- 100

vahtercks t sphate or e b i- eor

Price of TSPkg fo

be Price of PRkg P

PROC VOL 38 1974 leO

90r

Wsoshy

0

60-LUSEPHOSPHATE ROCK

00 10 20

PTP PR

Fig 6-Relationship between relaZive effectiveness values (RAE) and the price ratios between TSP and phosphate rock Such a figure can be used in making a choice between these

sources

If REE exceeds 100 in this calculation the phosphate rock would be preferable to TSP

The REE calcuktaaa wre used in preparing an indifshyference curve (Fig 6) wherein RAE values are plotted

against PTsPPpR ratios The cu~rve itself connects those points at which REE equals 100 When exactly on the curve it makes no real economic difference what source is chosen After choosing a suitable price ratio one can then project upward from that ratio knowing the RAI

value (or estimating it from such data as shown in Fig 4 using citrate-soluble P content) one can then choose the source on the basis of both agronomic and economic conshysiderations For example if the price ratio is 25 and the RAE value of the phosphaite rock is greater than 40 the rock phosphate in question would be used However if the RAE value was less than 40 TSP would be a better choice There are indications that if the P in the more soluble phosphate ro~cks (North Carolina north Florida central Forida) is less than half as expensivz as that in TSP these rocks would be feasible altereaives to TSP on soils similar

to thoseused in Thailand This analysis does not take into account the possibility

of lower yields from use of phosphate rock In addition only a portion of the various yield response curves was used in this anlysis ie up to 22 kgha Beyond this

rate yield response was much less pronounced it could be argued that at less than maximum yields TSP would produce a certain yield at lower rates of P than would phosshy

pow ofrock This would especially be true for rates applioa example at Klong Luang 5500 kg of

rice pcr iectare could have been produced with either Ii kg of P as TSP or 44 kg of P as son of the more reacshy

tire phosphate rocks It should be pointed ot however

- 68 shy

(IIKIS amp YOUN( ARIFICIAL WEATIIERING OF OXIDIZED p[ll- IV

that this is the yield level that would show the widest difference such is the advantage of hindsight

Farmers generally prefer granular fertilizers for machine

or hand application This is a disadvantage for the phos-phate rocks which are normally arplied in finely divided form Recently experimental quantities of granular urea-

phosphate rock mixtures have been made by TVA Results of trials with these fertilizers will be reported elsewhere

LITERATURE CITED

1 Armiger W H and Maurice- Fried 1957 The plantavailability of various sources of phosphate rock Soil Sci Soc Amer Proc 21183-188

2 Bengston G W E C Sample and S E Allen 1974 Re-sponso of slash pine seedlings to P sGurces of varying ci-trato solubility Plant Soil (In press)

3 Caro JIt and W Hill 1956 Chard eristics and fer tilizcr value of phosphate rock from different fields J Agr Food Chem 4684-687

4 Ensminger I E R W Peirson and W II Atmiger1967 Effectivencs of rock phosphate as a source of phosshyphurus for plants US Dep Agr ARS Bull 4112S

5 Engelstad 0 P J G Getsinger anid I J Stangel 1972 Tailoring of fertiliers for rice cnnece Valley Author ftyNational Fertilicr Developmnent Center Hull Y-52

6 Khasawnch F E and Jane P Copcland 1971 (otton root growth and uptake of nutrievos relation oif phosph

rus uptake to quantity intensity and buffering capacit) Soil Sci Soc Amer Proc 37250-254

7 Lehr JR and G H McClellan 1972 A revised lIbora tory reactivity scale for evaljativg phosphate rocks for direct application Tennessee Valley Authcrity National Fertilizer Development Center lull Y-43

H Terman G L S EAllen and 0 P Engelstad 1970 Response by paddy cice to ratcs and suurces of appliedphosphorus Agron J63390-394

DIVISION S-9-SOIL MINERALOGY

Artificial Weathering of Oxidized Biotite IV The Inhibitory Effect of Potassium on Dissolution llate

R JGILKES AND R C YOUNG2

ABSTRACT

Rates of dissolution of oxidized biotites in OIM 001M ICI are severely depressed in the presence of IM KCI The amovnts of Al Mg Mn dissolved in the first eytraction are similir to those found without KCI however subsequent extractions remove these elements at 10-20 of the corresponding lICI rates This effect may be due to a decreased rate of vermiculite formation thereby reducing the effective basal area exposed to attack A decrease in dissolution rate with increasing ferric iron content was still apparent in the presence of IM KCI

Additional Index Words X-ray diffraction infrared aborp-

N EARLIER papers of this series the tole of biotite in soils

as a source of both macro and micronutrient elements

has been discussed ((Gilkes Young and Quirk 1972 1973ab) Experiments in artificial weathering uiing as va-

riety of extractants were undertaken to determiie the inlu-

ence of oxidation of octahedrally coordinated iron on the bull release of structural cations to solution The results of this

work demonstated that biotite behaves anomalously with respect to the other common ferromagnesian minerals found in soils Oxidation leads to the development of a high degree of resistance to cation exchange and dissolution Several authors have coiwludcd that decreased rates of K

Contribution from the Dep of Soi Science and Plant Nutri-tion Institute of Agriculture Univ of Western Australia Ned-lands 6009 Western Australia Received 29 Sept 1973 Ap-proved 8 Jan 1974

2 Senior Lecturer in Soil Science and Research Officer respeclively

replacement in electrolytes shown by oxidized biotites are

a result of the inclination of structural hydroxyl adjacent to newly created trivalent iron or vacant octahedral cation sites (Robert and Pedro 1959 Barshad and Kishk 1968) Gilkes et al (1973b) suggested that decreased rates of disshysolution of oxidized biotite in 0001 0t)l 0Af CI may also be due to the presence of inclined hydroxyl In this case a smaller surface area external and exposed intershylayer may be available for attack if K replacement by hyshydrogen ions occurs at a slower rate in oxidized biotites

Gastuche (1963) has shown that significant dissolution ofthe (IIM) biotile face may occur and it is easily demonshystrated that the proportion of exposed (001M) face in weathering biotites depends on the percentage K replaced

Rausell-Colom ct al (1965) have shown that hydrogen ions act in an identical fashion to metal cations in K exshy

change from micas In particular exchange c-f K by hydroshy

gen ions will be terminated or greatly reduced by high levels of K in solution Thus if dissolution of oxidized biotite by

acids is carried out at sufficiently high K levels to prevent vermiculization any differences in dissolution rate that may occur cannot simply be ascribed to differences in rates of K replacement The following results were obtained from such an experiment which unlike the experiment described in Parts I and II (Gilkes et al 1973ab) does not attempt to simulate natuiral - conditions

MATERIAILS AN) M HIiODS Further subsamples of the less than 0 hiotites used in K

excherandbaid disoo tu es (G iles e9n K exchange and acid dissolution studies (Gilkes et al1973ab) were used in these experiments Preparation of sequentiallyoxidized biotites without intermediate vermiculite formation is

Page 18: I70 - United States Agency for International Developmentto ascertan, but tgl.eetad, 1, L,. ("Tailoring of Pertiltiters for ice,'" TVA ulletin Y-52) states that the staft of IOi has

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Table 2

Mttct of 0 Sourco aampW $At On Upt~ks of 0 by Two Varitgtos of Paddy Rice

gr~a 1971

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- 24 shy

India--The results of four experiments conducted with flooded

transplanted rice in India by the All-India Coordinated Rice Project

Hyderabad are given in table 3 The response to N was excellent the

yield without N being only 41 of those obtained with basal applications

of N as uza With basal applications of SCU the yields were 20 higher

than with basal applications of urea and in the three experiments in

which urea applications were split yields with SCU were 18 higher than

yields with split applications of urea When comparing the average Nshy

response (kamp grainKg N) yields were increased 13 more by SCU than by

basal applications of urea

The data from one experiment with light irrigated rice in India

are given in table 4 yields were relatively low and differences between

N sources or method of application were not significant However yields

with SU tended to be higher than when all urea was applied at planting

but lower than when split applications of urea were applied Again yields

increased more than 13 more with SCU than with basal applications ofwere

ur

In tables 5 and 6 the yields of a short-duration transplanted

rice grown in irrigated light-textured soils at five locations in India

indicate that higher yields were obtained with SCU than with urea when apshy

plied as a basal application Yield increases due to basal N applications

were 502 greater with SCU than with urea However split applications of

resulted in yields equal to those obtained with basal applications ofurea

CU

The yields of direct-seeded upland rice grown at three locations

to India are given in table 7 and the relative yields in table 8 Yields

were low due to drought but good responses were nevertheless obtained for

- 25 -

Table 3

Effect of N Source and Time of Application on Yield of Paddy (Flooded) Rice in India 1972 (Summary of Reported Data from 4 Experiments)

Experimental Number Source Rate Method Yield Relative N-Response

and of of N of Yield Kg Grain

Season Nitrogen kgha Application mtha Kg N

- - - 196 34 -

Urea 120 Basal 573 100 314

11 Urea 120 80 + 40 611 107 345 Rabi SCU 120 Basal 713 124 430

12 - 0 - 202 30 -

Urea 125 Basal 682 100 384

Rabi Urea 125 35 + 20 + 35 + 35 633 95 344 SCU 125 Basal 781 115 463

13- 0 - 168 44

Urea 100 Basal 385 100 217

Kharif Urea 100 30 + 20 + 25 + 25 400 104 232 SCU 100 Basal 462 120 293

14 -

Urea -

125 -

Basal 355 650

55 100

-

236

Rabi SCU 125 Basal 781 120 341

-- 26 -

Table 4

Effect of N Source and Time of Application on Yield of Light Irrigated Rice in India 1972 (Summary of Reported Data From

One Experiment at Pattambi)

Experimental Number Source Rate Method Yield Relative N-Response

and of of N of Yield Kg Grain Season Nitrogen (kgha) Application (mtha) Q) Kg N

38 0 - 204 85 -Rabi Urea 120 Basal 241 100 308

Urea 120 60 + 0 + 30 + 30 267 ill 525 SCU 120 Basal 255 106 425

Table 5

Effect of N Source and Time of Application on Yields of Short-Duration Transplanted lice Variety Grown on Irrigated Light-Textured Soils at 5 Locations in India 1972

(Snmzarized From Reported Data)

Rate Grain Yields (MtHa) Source of N Method of N GrainI of N kgh Application Faizabod Karjat Mandva Pattabi laya Averaje X

- 291 266 211 19 340 260 -

Urea 100 Basal 386 407 361 285 482 3 124 Urea 100 50 + 25 + 25 399 430 434 334 6amp2 4A8 186

SCU 100 Basal 368 468 439 360 572 41 181

Table 6

Effect of I Source end Tlae of ApplIcattoo c RIstave Tle24 of a rt- rat1 T Lsd lice Vasrety Crin o Irrigated L41tshy1 at S Locitite mindi 1972

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- 38 -

Table 18

Yild of aemati-370 Rice at Punjab Agricultural Research

Institute in Pakistan in 1969-70 Grown Under

Couditions of Intermittent Flooding

Pate of application

=IL

o 0 67 67 100 100 67 67

100 100 67 67 200 100

Average for Sources

Ntha

AS 260 gres 279

320

Source f5

-

AS AS Ura Urea SCU SCU

Yield

Relative

93 100 115

(M)O

Yield

Increase Yield Due to N

(Ktlha) (mtha)

-212 245 033 274 062 260 048 297 085 315 103 325 112

Yield Increase

Relative

72048 067 100 108 161

(2)

- 39 shy

Short-statured high yielding rice varieties grown extenshy

sively in northern Peru require extremely high rates of conventional

N sources to achieve maximum yields The recovery of applied N is

extremely low due to the use of intermittent flooding This water

management system results in heavy N losses even with properly timed

split applications In search of simpler and more effective methods

of N management eight field experiments were conducted in the region

to evaluate sulfur-coated urea (SCU) an experimental slow-release N

source supplied by the Tennessee Valley Authority Rice yields were

increased an average of 59 more by pretransplant-incorporated SCU than

by urea or ammonium sulfate applied in the same manner SCU produced

excessive vegetative growth which resulted in yield reductions at high

N rates

Regardless of an assumed 48-higher unit N cost in SCU the

overall benefits of pretransplant-incorporated applications of SCU

were favorable since there was a decrease of 40 in the optimum rate

of N and the need for precise timing of application was eliminated

Pakistan--In Pakistan basal applications of AS urea and

SCU to rice grown under conditions of intermittent flooding in 1969-70

(table 18) indicate that SCU is a superior source of N as compared to

urea or AS when all N is applied at or before planting The data also

indicate that a yield response was obtained for P applications but a

comparison of N sources at each level of P indicates that no interaction

between N and P was present so that differences between N sources were

relatively the same at each level of P Yields were increased about 60

more when SCU was applied than when urea was applied Yield increases

with AS were only about 72 of the increase obtained with urea these reshy

sults do not agree with the generally-reported superiority of AS as comshy

pared to urea as a source of N for rice

- 40 -

In 1973 experiments were conducted in Pakistan using both

Basmati-370 and IRRI-6 varieties of rice grown under conditions of

When all N was applied at puddlingintermittent flooding (table 19)

or 12 at puddling and 12 at panicle initiation both AS and SCU were

superior to urea with SCU tending to be the most efficient source

However when N was applied 12 at transplanting and 12 at panicle

initiation SCU was the poorest source of N This would indicate that

the release of N from SCU applied at these times is too slow for optimwn

plant growth

In another experiment in Pakistan in 1973 no differences

in the effectiveness of urea AS or SCU were noted in the yields of

continuously-flooded rice (table 20) Again these results are conshy

sistent with earlier results which indicate no superiority for SCU

when rice is continuously flooded

Nitrogen Studies--Maize

A series of three experiments were conducted by IITA in

armo-Nigeria in 1972-73 comparing AS urea SCU and

CAN (calcium

nium nitrate) as sources of N for maize (table 21) A significant

yield response was obtained for N at each location but no conaistent

differences were noted amaong sources These results are consistent

with results at other locations which have not shown that SCU is a

superior source of N for maize grown over a period of 3 to 4 months

Nitrogen--Wheat

The yields of wheat in Pakistan in 1969-70 (tables 22 and

23) show that yields with SCU) tended to be lower than those with ureaJ

although at one locction where sorghum was grown followilng wheat with

Table 19

Yields of Basmati-370 and IRRI-6 Rice at Punjab Agricultural Experiment Station in Pakistan in 1973 Under

Conditions of Intermittent Flooding

Rate Yield Source of N Time of Yield (Mtha) Increase of N B-370 IRRI-6 Application Basmati-370 IRRI-6 Average (Mtha)

0 0 - 21 353 287 -

SCU 90 150 At Puddling 325 545 435 148

Urea 90 150 At Puddling 309 500 405 118

AS 90 150 At Puddling 324 529 427 140

SCU 90 150 Puddling 372 572 472 185 Panicle Initiation

Urea 90 150 Puddling 335 502 419 132 Panicle Initiation

AS 90 150 Puddling 353 529 441 154 Panicle Initiation

SCU 90 150 After Transplanting 312 562 437 150 Panicle Initiation

Urea 90 150 After Transplanting 340 624 482 195 Panicle Initiation

AS 90 150 After Transplanting 349 583 466 179 Panicle Initiation

All plots received 45 lbs P205acre as single superphosphate

Relative Yield Increase ()

Source of N At Puddling Puddling Panicle Transplant h Panicle

Urea 100 100 100 AS 119 117 92 SCU 125 140 77

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fmtbt alteruutiv to MSso gotastte to~ Ik lee used to

ThUAIAd

Tht wMl dt gotmtmlaoti wout th possibility

of law Vhld free ww e1 e66001 4 It cooUt be YgWd Sutt

a4 10 0410 SWUSSM yt$4e TOP wUd predWr A r~ftIf fl~W t

1f f ot P the wuld phosphae rck TWOe viWMW efocitill b

true to low rttos t tsplusatiI P wi 9 Ma Liiam $S

amp4at r per Wforssota Mav two 64eed Wilk elikor It 44 of

P go Mi er 4A bg oftoP aon of tewmrowtni pboophals fwAh

It vwld be polotrd A Wevero wtht Is the jteld level that

W414 gk tko videm dtterem~j o(A 1 the 4~etamp tk~e~t

P11~0 pra~lpj prefer gre4r tuftlter for whlae

of hoaw ppltrstie Mhe to a dloedveaP for The PINSOO rocka

vkth m r II spotted 10 ftewil 4106Me tem

Nub studios we ovsosd o IVA vol gramleid a

forgof wee aMW pbsepbots A fths pemhawe evsielew us

Odellod to detMlee it otteettvmm of 11agotated Stoture of

mmfp MW phapa A (CI) sed graewletod pampAtlti arlolatod Pa

asowcs of P tof ttde ro The wreem proucts omre raGther

pemour~a ot P syag besmti andMi as elt ov so gpamwhr

iuipiqffhate(TS) low twseeo Is eftwiltve Is thet

W41 preeme wae oialain ire post-rItoi effriq to Stanlato the

pud6itt of Irto paddle Wee ofsdlseireplastiq

0 49 shy

lbs partially scldiaatede grawilated Ml prodlucts Vere isshy

toiwdiats in 5tftOvttWS54 betwee wroiPi ad TVP NotV5Ymf to

me coo were they mere twoe $a a etfective ao TIP 00 sipifleast

LVSUMI5 at0 efecto wore toun tor thee produteo Timely dtIampWde

FR (-t00 mmoh) Uia amp~rally oar affective than Owe gra8448r FOampprodt

featal twos o 6 aotetire s I

Nowvero it to felt that sfortber field euprtet vth

hese interials Amd ether typs of grometatodl Wter nre wrrautad

hater ceeuwodh that they have me areec poteatlal toi additoG

e tate wAne the sectte as OtawrI sed bovoloen turther

euperimeste vth few reck pboophar s0d with reck pbophat treated

to sehesa citrata selmtliy or to ha csaducted

Metbir sertes of tbme enprtaeats wae c~edtmcted by IITA

to Ut~rta copal TVP AOP APP aed it at see tecastisix (table 14)

No dot lalt sewseltles teh draw tree thee results simouely em pear to tlvdl bsww they do stwgpt tbat forthew work with

MR to werramid so tbme sels

Table 24

LttcttF Swce MaPlate 06 ieldot IM AWaia CoelsANS at IITA (Ugboda ad Apoin ail sorit) aid at Ike (AUaba s5i series)

1973

Plate ot IP Apinu 5 poundebods A1ab

Ocrol 0 Z94 419 M)

Tr ipl ruprphite 20 349 3799378

Triple vepput 40 M09 410$

Triple 6wp~~b1 4271 4344 42250

Ammotw-ritpophW to 4201 4124 4040

Amosim-rdop~phlt 40 4270 4106 4231

AM tuo-polpephats 20 404 4244 3794

~eai~mpelppepbuI 400)49 4094

Cee m-pbpbt to- 59

momee eph lto 0 4192

LSO (0 0$) 29 1025

Th WPII

- 51 shy

101Y114 tpeM-fI PEP~tbRP YO

1 ~ ~ gmw 1pc~biofl- 9 Kla4v4h

Upia U04 Copfind am Crehout Stet Rpano at (Ia4

rico t IF t rume6 orth~ Caralto phoophale rocl QAR) vaUN pqU41 to

roopon from cmonetrat4 gsporphophai (CIP) who ort$o4 oil k

was 45j itwas tafertor vb protioo4 oil p war OS Ib 4iffer~c

in rtc reepos to X cod14 oo bo ttrit4 4 4 hvsciag of boil p

~ Pt o r11221 0 tP

c theto the rhimecyllndor of rico tots par to)14M4i1 roeoi~t

ed oil emd PA prior to tho ont of an~robi4 cMioe AA~ oIifoshy

nAte bYpot t taet~d tO fC4sin t~r 4PWden0 Of f Ot(tivshy

ofOWailiJtyno o prefla4 all Put that 4t01etoo 14 tvsIk

of the Ott to prvvld a 014for C4m0 44 mI 1 o4sf

EfftC ftPet141on AIAM-0 V f401td 4 4iv 440 Mtft

Aa torfat VampP f4MWfCi4W04wt0amp to 4eturWlI Ot(Wel~drIC ft

Ot f tM6 the flooded Ott 00 14 04019I Pft0uAw Of gAr~s~lr

pkS$t M40b MP) Tw P1101 Piset Prodwie W-e 10M0di Wr04

(10-1) emW 0aretilp ddw01at4 P WAA firom Rrth M~flRU414~$

wee cowiared with fie Md reWim 44104 proo~fo) foruk oith laWItter

I v te-PR P OW1004 4 4 O Wf ottil OW ellt Oo

Oveiel1 the 40tt dmcruie to effetotww Wtollowui Co fme

PR tpaUIB1I ldoltmo PR (pamwlatr) offr~- ArmeuM) 0 orwi

- 52 -

Effect of N Sourc6 and Water Management on Response of Rice

toe Zn- M Giordano J J Mortvedt OP Engelstad and Greenhouse

Staff Several rotes of CO(14H2)2 and (H )2So4 vith or without ZnO

wore applied to flooded and nonflooded Crowley oil (limed to pH 75)

to determine response of Bluebelle rice to Zn Yields with both N

sources veotrgreator on flooded then on nonflooded soil In the abshy

ence of applied Zn total dry matter production vith CO(NH2)2 was

slightly lower than with (NH)2S04 on flooded soil and considerably

lover on nonflooded soil Concentration of Zn wan higher in straw and

grain of plants roun on flooded than on nonflooded soil Although

concentration of P was unaffected by N source or Zn rate there was

som indication that cranslocation of P from straw to grain may be

depressed in nouflooded rice Concentration of N was lower in straw

grown on flooded than on nonflooded soil due to apparent dilution

thereas both X sources resulted in similar N concentrations in straw

at all rates of N application the N concentration in grain increased

with 0 rAse

feSpongi gf(SM to Chjorospodiostte and Related P Sources--

Si Allen and Greonhoue Staff A greenhouse pot experiment was

couct44d with corn Brown on Hountview silt loam to compare the ofshy

fectlivees of chlorospodiosito (Chlor-l) with concentrated supershy

phosphate (CP) Thomas slag and North Carolina phosphate rock (NC-PR)

Oil-prillad urea-phophato rock (UPI) FeA1JMP 20 7 and monomthyl

phosphate were included in the experiment Based on yield of forage and

uptake of P by tvo crops each of 6-weeks duration the following conshy

stui were dravat

I Chlor-1 was slightly loss effective than CSI Thomas slaS or NC-PR

from which Chlor-l wae prepared

- 53 shy

2 Granular UPR was a poor source of P its effectiveness was greatly

increased by reducing the particle size to -35mesh

3 FeAlNH4P207 was unavailable to the crop

4 Monomethyl phosphate was equivalent toor slightly more effective-

than CSP

Research Indirectly Related to TVA-AID Project

Response of Several Rice Varieties to Zn in Moist or Flooded

Soil--P M Giordano J J Mortvedt and Greenhouse Several varieties

of rice from Mexico and the Dominican Republic currently under investishy

gation in Puerto Rico for adaptation to upland culture were compared with

some established United States varieties with regard to Zn response on

moist and flooded Crowley sil (pH 75) Chontalpa (Mexico) Bluebelle

(Texas) and Starbonnet (Arkansas) were most responsive to applied Zn

Juma (Dominican Republic) intermediate and Sinaloa (Mexico) and Calrose

(California) were the least responsive The Sinaloa varieties (Mexico)

appeared to be best adapted to non-flooded conditions whereas Chontalpa

and Calrose were poorest Concentrations of Zn generally were higher in

plants grown on flooded than moist soil

Pattern of Growth and Zinc Accumulation by Rice--P M Giordano

J J Mortvedt and Greenhouse Staff Rice plants were harvested at weekly

intervals from shortly after emergence through maturity The objective

was to determine the rate of growth and Zn uptake by a Zn responsive varshy

iety (Bluebelle) and a less Zn-responsive variety (Calrose) in the presence

or absence of Zn applied to Crowley sil (pHl 75) Dry matter production

of Calrose was linear with time of growth and of a similar magnitude until

heading with or without applied Zn Bluebelle followed a similar pattern

where Zn was applied However in the absence of applied Zn foliage yield

was reduced markedly

-54

Uptake of Zn was similar for both varieties whenZn was

applied Dry matter production and Zn uptake by the two varieties

also were comparable when Zn was applied However yield of Calrose

was much higher than that of Bluebelle in the absence of applied Zn

while Zn uptake was only slightly higher This suggests that the lesshy

ser responsiveness of Calrose to Zn may be due to more efficient utilishy

zation of Zn There was no indication of a greater demand for Zn durshy

ing reproduction in either variety as was suggested in earlier greenshy

house experiments

Response of Upland Rice to P and Zn--P M Giordano J J

Mortvedt and Greenhouse Staff Several rates of P and Zn were applied

to Crowley sil (limed to pH 75) in factorial combination to determine

whether differences in rice growth under flooded and nonflooded soil

conditions are related to plant nutrition Although straw yields were

slightly higher in nonflooded rice receiving adequate P and Zn grain

yields were higher in the flooded crop increased rates of F andor Zn

did not result in equal yields Except in the highest Zn rate (75 mg)

concentrations of Zn in both straw and grain were higher with flooding

Concentration of P increased with rate of applied P and was higher in

the grain or flooded than upland rice at a comparable P rate In conshy

trast concentrations of N were lower with flooding due in part to dilshy

ution from increased growth

Rice Response to N and P in Flooded and Unflooded Cultures--

G L Terman S E Allen and Greenhouse-Analytical Staff Rates of

N from 250 to 2000 ntpot and P from 0 to 1000 mtpot were applied for

Nato rice grown on Mountview sil and Sango sicl (625 kg of soil per

pot) Market yield response to N and P was obtained Yields of straw

- 55 shy

total yields N uptake and N recovery were higher on unflooded than

on flooded soil cultures Grain yields however were slightly higher

with flooding These results indicate that with adequate applied

nutrients especially of N rice yields without flooding can approach

or even equal those under flooding

Uptake of N P Ca Mg and Zn increased with yield response

to N and P while K uptake decreased on the Mountview soil Concentrations

of N and P increased with applied N and P respectively while concentrations

of other nutrients were diluted in most situations with yield response to N

or P

Results from this experiment show that amouats of N applied in

previous pot experiments for rice have been much too low especially if the

crop was grown to maturity

Response of Corn to S and N i UUASand Urea-S--S E Allen

and Greenhouse Staff Three greenhouse pot experiments were conducted to

measure response to S and N in ulfur coated urea (SCU) urea amonium

sulfate (UAS) and urea -S as well as estimate N losses from surface apshy

plied N sources

In Experiment 260 less than 20 of the S mixed with the soil

was recovered from SCU or urea-S granules by two crops of corn as comshy

pared to 45 or 80 from flowers of S or Na2SO 4 CLop response followed

a similar pattern

In Experiment 260-A N sources were surface applied and alshy

lowed to dry for two weeks before incorporation Into the soil and plantshy

ing Recovery of N by two crops of corn was 77-82 for AN an compared

to 37-70 for urea UAS urea-S and ICU Thus n this experiment loss

of N from urea did not appear to be re~dcud by light S-coatlngn or by Inshy

corporating S or AS in the granules

-S -

I xbprZnSlt a Wtch aU Meyto 0-Ai Wt f9r

higher reermo teOrtOrs cOM reSpWNO i r0100 Of N w

not oaisteontly related to sewe ot N In edl tust 0 ioltiUe Lim

lo in VMuwpped evlmtUTS 48 merind by seirest nte appresOehe

501 for uroa as cwarod to 210 for urea peepha

Rus- or Upse to LoAmIl34I a AriMed bI Earl U

MW NOWlsIIsIr-4 L Toman 5 1 Alln and eesese StNf rio

row on Sawg did (0 tpot) We 1l0l0 Ws feritiud vith 05is

of Npot mixod with the 6011 as aureCA NiAO) 1 Age god At Ures

was also itcluded at rtt t 05 10 end 15 of Upee Theas trealshy

onto were followed 4 wpdrsetago of U s AN wre 4C 10o or at I3n

Weeks toulin up to IS pot

A soil application of 10 pot rosulvod to the maim yield

at 4 weeks Tio4 sad percont prottis t intre raite tncreased rftishy

linearly with U applictalien IeseeItally all at the m iNd wit

the moil w domitrifted after flooding Grail end straw Ilelds vere

highly correlatod with tiliriag and vlh ubers of gralm arl

The results Widicat that 0$ to 10 a of Upot as orea or

NN bsuld be sied with the oil to stilate tiilrir with adshy

ditional 0 topireased later to increase grain lIds mad protia cmshy

tout

DIVISION 54- FERTILIZER TECHNOLOGY AND USE

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TOW opl taoe for AieweeW 4OsmWMbas Op peas As Tabl 4 sling sob Os awowully eom grams Piel level Thes oeulam Ma sed as IM

-02

792 60L WI W A)49R Pio VOL 37 197)

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DIVISION 8-9-SOIL MINERALOGY

Amorphomw CeetIup en XmWra Ssrfmls

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ommp A faieiaAMTRACT skiwe lo nW ampM sm wi4h

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of of~phaow tw bmsdf toamplboe

AjflsutomW C1D-pCTP AD mSmZLT op 1 m ow ts Wdm of P om M

IaM 0t sdw a wn a8duws i ofV -w Mm P16I4 TWO a ewu i an

ov4mnk wsi 9 Mxfeu~i am emwm ismi0wmd fq W No ~~ - f mug Aitowe eutlkowbmTV is

amppowftdmi TiM 0 Tie OAA mo p)a Mwomoi dOn4m A)w

MW 0 604 0M mm yaM 01MWOfdi to tA0 M OOAW uinw OSOb

ap is~e I the ampo A A Mwof ~Do toit op aenu w~ifiOimem~ MAN ampW)

ItsAO se Y lieowawo u~w pkow-W1b pwf on a C Nohkw is f 0o1 s do~omW C mmU4

owud6moeft 4 Obind PINa~e

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fit~~~~O 114 4 t I mMsmm m~

im ^aim4 Nomod 06maw ee Aist em moom a rA No fmiEo of emit

~ -0

65

0IL CL OC AMXR PROC VOL 38 1974

)aT1 S4I104 ow Lusanll Tawng isa tall Thai variety known for beingIwo nonshyi s s ) sensitive to photoperiod A split-plot design was used in

S e e these euperimeots with 4 rates of P (I1 22 44 and 88t i V IV k of Pha) applied a main plot treatments and with the OF It sourMes of P as subplot treatments There were two checkS plots in each rmplicate The extra check plot was included to permit the application of fresh TSP standard Jor the

It- ti 06 + i bull fa succeeding crop the p-4me of bi was to permit accurate d awrnwal of the mdual effectiveness of the phosphate

ftinSUbI rock The P fertilioers were broadcast on the mud andthen Worporald In the soil during the last harrowing At

whM N both On ACS indx ampM time of transplanting Immediately before the last harrow61t (4j 5 4 01 P s 3Mm o Vallonal in con n 100 kgha of N as ammonium sulfate and 33 kghaWO Of Spews ampm lIW thaabe rocks do ACS indes of K as polium chloride were applied A total of 40 wa in prepw O do ctih k otent kha of N a ammoniunt sulfate was applied later in twoir P The hew oNed amp wM W for 5 of gw topdrossingp with about 5cm depth of water on the plotsvV I aiOMveffeOctveee Three to six ldayold selings pr hillwW the ACS idex were planted00OWW wia Oft fo an c irNk I p Coen 20 by 20 cm part in straight rows Hand weeding was used

and insecticide were applied for Insect control Grain yieldw was masared by sampling 5 ml of each plot excluding border rows The date of heading in each treatment and theUNiN d pbM W Weks rin tOW USA UMe In Tale yed componnts at hafvel were also recorded

I filM rsperMS esOM kdwdua 1 t ab The average yields of ough (unhulled) rice for botha 84 OW O 8uo 4 Thala TM was a locations are ploutel in PIS 3 for the first crop (1969 wet

owou thRM seaso0) The Veamps yield response was obtained at Klonge (s) W lDtO t Of dMa of1tw W d l R Luang however a 4ute satisfactory yield response was

~Mk ^d TVA UJSD ad Kd UnIveS obtalned to applied P at Bangkhen as wellXUe LaM e R qwrw Ims The sod was do Relative aponomlAe effectiveness values were calculated

VOW (a ksA w edmwL t Poesesm h Vy for these data and am presented In Table 3 The valuesdAY buo if dIe ouh ne Pee wtk a Mlak vow 1009 for th first crop are plotled against ACS index in Fig 41 This Im M i6ti l 4bNd IO a0 O mkarnk for both locatio r relationship was linear for the

11400 ThCpH 0( lb pW IW 01 th UpeiaW so Sanodion location and curtiltnear for KIng Luang The was u i 4A sksamp lMaor nrusio model amparounted for 81 of theAmO$MI Aw jAAsue Swim T1 Snh Wd variation In the AE valu for Bantkhen a square root

Mems a Iw iv fern alh$ sedm haowg dayNW W t he plAL At tdo M tM aso W s as ctminued throufh eltaM t Ofpof -le lse wo am P OeNI VeOpls 1o ealluae tI lon4erm MIdual Offccls

A on W isset i a wse to hsh eapeel of these ooihss t ocks The baagkhon experimnent was letmiaI1DlVemisthis is a w hulu Lo g Tasug ia iasael aft - Msd residual Ves will be pr-Om crok TheseTwod esewm

SWWo

A

lP~U~7 ISIIPe1iuIWN e bsedisssin ian ghth siaoelalbe

984 0 6 O O - M s -s fWPas 11eSft W d Uo al a o

o

S4l~ lIIII I~l I 1f fl

( +

+ + + m + ++++-

++ +(++ + ++++ + ++ ++

- 66 -

ENOIMLSTAD ET AL RESPONSE BY FLOODED RICE TO PHOSPHATE ROCKS VARYING IN CITRATE SOLUBILITY

I I I I j0 I I

BANOKHEN BANGKHEN

pH 56 6 - 0o

TSP

NC

5~ ~ ~ L o 4 - -shy

4 ] - --------shy04

6S

|0 III 2 44 8r 66

I I I

a 1KLONG LUANG

pH 46 z KLONG LUANG

TSP Sc2 NCFL(N)

5 FLIC) J0 TU

oshy

4 ~40shy

3 bull eM0

I - I I I I I

0 II 22 44 88 0 5 10 15 20 IP APPLIED KO HA ABSOLUTE CITRAE SOLUBIITY INDEX

Fig 3-Yield of rough rice at Klong Luang and Bangkhen Rice Fig 4-Relative agronon effectiveness () of P sources ploz-Experiment Stations Thalmand as affected by rate and Source ted against citrate solubity Index for both Thailand field ex

of P applied (crop 1) periment (first crop only)

regression model accounted for 97 of the variation in sumably resulted from crop uptake and reaction with the RAE values at the Klong Luang location soil to form less soluble products Such effects may have

These experiments were continued during the dry season been more important at the lower rates since the two TSP of early 1970 to ascertain the residual effectiveness of the curyes converged at the highest rate of application various sources applied to the first crop No new P was These data from KIong Luang indicate that (i) residual applied except for the fresh TSP standard mentioned effects of all rocks except Mlcwuri were substantial (ii) above rhe experiment otherwise was conducted in a man the relationship between relative agronornic effectiveness ner similar to that followed in the first crop of the phosphate rocks and citrate solubility levels was

The response to both freshly applied ad residual P was largely obscured and (iii) the general superiority of TSP marked at the Klong Luang location and marginal at over phosphate rock in terms of effectiveiss persisted Bangkhen In fact at the latter location the response was through the second crop so small that little can be said regarding residual effectiveshyness The yield data from crop 2 at the Klong Luang DISCUSSION experiment are plotted in Fig 5 Greenhouse and field data presented in this paper show

Relative agronomic effectiveness values (Table 3) were clearly that there are substantial differences among phosshycalculated for the Klong Luang data using both the residual and freshly applied TSP as standards It is of Interest to note that the superiority of TSP over the phosphbte rocks Table 3-Relative agronomic effective values for field experishyments in Thailand persisted through the second crop The main difference in KlowlZmlnql~the residual effects is that with the exception of the MIs- s Crop 1 Crop 21 Crop 1-shysouri rock Ihe marked relationship between citratr-soluble WoiCarolina yl 59 76

phosphate rocks and RAE had largely rds norh) a 64P conltct of th Florida (eqlral is 6969 6

disapipeared In this acidic soil (pHi 46) P would by this I14o 69 63 40 ToonesS 31 65

limo be supplied by Intermediate reaction products In addl Missou 0 o lion to residues of the initial spatlte Ts P o 2 o 0

The TSP applied to the first crop declliv-d slightly In campIafcmWataesr e id ofeuhuloefor 22MA rates of PtColeouattd as aba u tlte td18 kS ratesp dlverage yield tM868 to 22 44

effectiveness relative to the freshly applied ISP This pre- of d s4

A

4

- 67 shy

-SOIL SCL SOC AMER I

KLONG LUANG CROP 2

Si 3

eN

TAPPLIEDKGHA

Fig 5-The residual effectiveness ovarious P sources for crop s compared with freshly applied TSP Klong Luang Rice

Experiment Station Thailand

phate rocks in terms of agronomic effectiveness for flooded

rice Further these differences can be predicted by means of citrate solubility or by the ACS index It appears that

the latter is more appropriate where the content of apatite varies among phospiate rocks The most soluble phosphate rocks approached but did not actually equal TSP in limit-iuig (maximum) yield in these experiments regardless of rate applied This agrees with the results of Ensminger Pearson and Armiger (4) One needs to consider the defi-nite posribility of same yield loss in zhoosing a phosphate

rock over TSP such yield losses must be weighed against the lower price of phosphate rock The explanation for such iosses may involve concentration of soluble P in the soil Khasawneh and Copeland (6) suggest that the growth rate of crop plants is a function of P concentration that can be maintained in the soil solution If P concentration is limiting or inadequate becawe of a lower dissolution rate of phosphate rock the growth iate ard uiiimate yield will be diminished accordingly

The RAE values bascd on yield increases reflect the agronomi effectiveness of these various sources relacve

to the TSP standard however these nould be supple-

mented by an economic analysis before rational choice can

be made The following calculations will provide an estimate of

the rclativ ecooomic effectiveness(REE)

Y t Ps aXpatREE -- 100

vahtercks t sphate or e b i- eor

Price of TSPkg fo

be Price of PRkg P

PROC VOL 38 1974 leO

90r

Wsoshy

0

60-LUSEPHOSPHATE ROCK

00 10 20

PTP PR

Fig 6-Relationship between relaZive effectiveness values (RAE) and the price ratios between TSP and phosphate rock Such a figure can be used in making a choice between these

sources

If REE exceeds 100 in this calculation the phosphate rock would be preferable to TSP

The REE calcuktaaa wre used in preparing an indifshyference curve (Fig 6) wherein RAE values are plotted

against PTsPPpR ratios The cu~rve itself connects those points at which REE equals 100 When exactly on the curve it makes no real economic difference what source is chosen After choosing a suitable price ratio one can then project upward from that ratio knowing the RAI

value (or estimating it from such data as shown in Fig 4 using citrate-soluble P content) one can then choose the source on the basis of both agronomic and economic conshysiderations For example if the price ratio is 25 and the RAE value of the phosphaite rock is greater than 40 the rock phosphate in question would be used However if the RAE value was less than 40 TSP would be a better choice There are indications that if the P in the more soluble phosphate ro~cks (North Carolina north Florida central Forida) is less than half as expensivz as that in TSP these rocks would be feasible altereaives to TSP on soils similar

to thoseused in Thailand This analysis does not take into account the possibility

of lower yields from use of phosphate rock In addition only a portion of the various yield response curves was used in this anlysis ie up to 22 kgha Beyond this

rate yield response was much less pronounced it could be argued that at less than maximum yields TSP would produce a certain yield at lower rates of P than would phosshy

pow ofrock This would especially be true for rates applioa example at Klong Luang 5500 kg of

rice pcr iectare could have been produced with either Ii kg of P as TSP or 44 kg of P as son of the more reacshy

tire phosphate rocks It should be pointed ot however

- 68 shy

(IIKIS amp YOUN( ARIFICIAL WEATIIERING OF OXIDIZED p[ll- IV

that this is the yield level that would show the widest difference such is the advantage of hindsight

Farmers generally prefer granular fertilizers for machine

or hand application This is a disadvantage for the phos-phate rocks which are normally arplied in finely divided form Recently experimental quantities of granular urea-

phosphate rock mixtures have been made by TVA Results of trials with these fertilizers will be reported elsewhere

LITERATURE CITED

1 Armiger W H and Maurice- Fried 1957 The plantavailability of various sources of phosphate rock Soil Sci Soc Amer Proc 21183-188

2 Bengston G W E C Sample and S E Allen 1974 Re-sponso of slash pine seedlings to P sGurces of varying ci-trato solubility Plant Soil (In press)

3 Caro JIt and W Hill 1956 Chard eristics and fer tilizcr value of phosphate rock from different fields J Agr Food Chem 4684-687

4 Ensminger I E R W Peirson and W II Atmiger1967 Effectivencs of rock phosphate as a source of phosshyphurus for plants US Dep Agr ARS Bull 4112S

5 Engelstad 0 P J G Getsinger anid I J Stangel 1972 Tailoring of fertiliers for rice cnnece Valley Author ftyNational Fertilicr Developmnent Center Hull Y-52

6 Khasawnch F E and Jane P Copcland 1971 (otton root growth and uptake of nutrievos relation oif phosph

rus uptake to quantity intensity and buffering capacit) Soil Sci Soc Amer Proc 37250-254

7 Lehr JR and G H McClellan 1972 A revised lIbora tory reactivity scale for evaljativg phosphate rocks for direct application Tennessee Valley Authcrity National Fertilizer Development Center lull Y-43

H Terman G L S EAllen and 0 P Engelstad 1970 Response by paddy cice to ratcs and suurces of appliedphosphorus Agron J63390-394

DIVISION S-9-SOIL MINERALOGY

Artificial Weathering of Oxidized Biotite IV The Inhibitory Effect of Potassium on Dissolution llate

R JGILKES AND R C YOUNG2

ABSTRACT

Rates of dissolution of oxidized biotites in OIM 001M ICI are severely depressed in the presence of IM KCI The amovnts of Al Mg Mn dissolved in the first eytraction are similir to those found without KCI however subsequent extractions remove these elements at 10-20 of the corresponding lICI rates This effect may be due to a decreased rate of vermiculite formation thereby reducing the effective basal area exposed to attack A decrease in dissolution rate with increasing ferric iron content was still apparent in the presence of IM KCI

Additional Index Words X-ray diffraction infrared aborp-

N EARLIER papers of this series the tole of biotite in soils

as a source of both macro and micronutrient elements

has been discussed ((Gilkes Young and Quirk 1972 1973ab) Experiments in artificial weathering uiing as va-

riety of extractants were undertaken to determiie the inlu-

ence of oxidation of octahedrally coordinated iron on the bull release of structural cations to solution The results of this

work demonstated that biotite behaves anomalously with respect to the other common ferromagnesian minerals found in soils Oxidation leads to the development of a high degree of resistance to cation exchange and dissolution Several authors have coiwludcd that decreased rates of K

Contribution from the Dep of Soi Science and Plant Nutri-tion Institute of Agriculture Univ of Western Australia Ned-lands 6009 Western Australia Received 29 Sept 1973 Ap-proved 8 Jan 1974

2 Senior Lecturer in Soil Science and Research Officer respeclively

replacement in electrolytes shown by oxidized biotites are

a result of the inclination of structural hydroxyl adjacent to newly created trivalent iron or vacant octahedral cation sites (Robert and Pedro 1959 Barshad and Kishk 1968) Gilkes et al (1973b) suggested that decreased rates of disshysolution of oxidized biotite in 0001 0t)l 0Af CI may also be due to the presence of inclined hydroxyl In this case a smaller surface area external and exposed intershylayer may be available for attack if K replacement by hyshydrogen ions occurs at a slower rate in oxidized biotites

Gastuche (1963) has shown that significant dissolution ofthe (IIM) biotile face may occur and it is easily demonshystrated that the proportion of exposed (001M) face in weathering biotites depends on the percentage K replaced

Rausell-Colom ct al (1965) have shown that hydrogen ions act in an identical fashion to metal cations in K exshy

change from micas In particular exchange c-f K by hydroshy

gen ions will be terminated or greatly reduced by high levels of K in solution Thus if dissolution of oxidized biotite by

acids is carried out at sufficiently high K levels to prevent vermiculization any differences in dissolution rate that may occur cannot simply be ascribed to differences in rates of K replacement The following results were obtained from such an experiment which unlike the experiment described in Parts I and II (Gilkes et al 1973ab) does not attempt to simulate natuiral - conditions

MATERIAILS AN) M HIiODS Further subsamples of the less than 0 hiotites used in K

excherandbaid disoo tu es (G iles e9n K exchange and acid dissolution studies (Gilkes et al1973ab) were used in these experiments Preparation of sequentiallyoxidized biotites without intermediate vermiculite formation is

Page 19: I70 - United States Agency for International Developmentto ascertan, but tgl.eetad, 1, L,. ("Tailoring of Pertiltiters for ice,'" TVA ulletin Y-52) states that the staft of IOi has

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Table 2

Mttct of 0 Sourco aampW $At On Upt~ks of 0 by Two Varitgtos of Paddy Rice

gr~a 1971

~ MMUampL~ ~L ~ nYLALI~ 11 lemall

I ie

W0 v slit III I) tQo9

KvN 1 17 111 1119

or 444M7

111a

i1$0N ~ It$ 121

1$

x IV ~404 tot Vsr 1 P1 41 w otv 1

- 24 shy

India--The results of four experiments conducted with flooded

transplanted rice in India by the All-India Coordinated Rice Project

Hyderabad are given in table 3 The response to N was excellent the

yield without N being only 41 of those obtained with basal applications

of N as uza With basal applications of SCU the yields were 20 higher

than with basal applications of urea and in the three experiments in

which urea applications were split yields with SCU were 18 higher than

yields with split applications of urea When comparing the average Nshy

response (kamp grainKg N) yields were increased 13 more by SCU than by

basal applications of urea

The data from one experiment with light irrigated rice in India

are given in table 4 yields were relatively low and differences between

N sources or method of application were not significant However yields

with SU tended to be higher than when all urea was applied at planting

but lower than when split applications of urea were applied Again yields

increased more than 13 more with SCU than with basal applications ofwere

ur

In tables 5 and 6 the yields of a short-duration transplanted

rice grown in irrigated light-textured soils at five locations in India

indicate that higher yields were obtained with SCU than with urea when apshy

plied as a basal application Yield increases due to basal N applications

were 502 greater with SCU than with urea However split applications of

resulted in yields equal to those obtained with basal applications ofurea

CU

The yields of direct-seeded upland rice grown at three locations

to India are given in table 7 and the relative yields in table 8 Yields

were low due to drought but good responses were nevertheless obtained for

- 25 -

Table 3

Effect of N Source and Time of Application on Yield of Paddy (Flooded) Rice in India 1972 (Summary of Reported Data from 4 Experiments)

Experimental Number Source Rate Method Yield Relative N-Response

and of of N of Yield Kg Grain

Season Nitrogen kgha Application mtha Kg N

- - - 196 34 -

Urea 120 Basal 573 100 314

11 Urea 120 80 + 40 611 107 345 Rabi SCU 120 Basal 713 124 430

12 - 0 - 202 30 -

Urea 125 Basal 682 100 384

Rabi Urea 125 35 + 20 + 35 + 35 633 95 344 SCU 125 Basal 781 115 463

13- 0 - 168 44

Urea 100 Basal 385 100 217

Kharif Urea 100 30 + 20 + 25 + 25 400 104 232 SCU 100 Basal 462 120 293

14 -

Urea -

125 -

Basal 355 650

55 100

-

236

Rabi SCU 125 Basal 781 120 341

-- 26 -

Table 4

Effect of N Source and Time of Application on Yield of Light Irrigated Rice in India 1972 (Summary of Reported Data From

One Experiment at Pattambi)

Experimental Number Source Rate Method Yield Relative N-Response

and of of N of Yield Kg Grain Season Nitrogen (kgha) Application (mtha) Q) Kg N

38 0 - 204 85 -Rabi Urea 120 Basal 241 100 308

Urea 120 60 + 0 + 30 + 30 267 ill 525 SCU 120 Basal 255 106 425

Table 5

Effect of N Source and Time of Application on Yields of Short-Duration Transplanted lice Variety Grown on Irrigated Light-Textured Soils at 5 Locations in India 1972

(Snmzarized From Reported Data)

Rate Grain Yields (MtHa) Source of N Method of N GrainI of N kgh Application Faizabod Karjat Mandva Pattabi laya Averaje X

- 291 266 211 19 340 260 -

Urea 100 Basal 386 407 361 285 482 3 124 Urea 100 50 + 25 + 25 399 430 434 334 6amp2 4A8 186

SCU 100 Basal 368 468 439 360 572 41 181

Table 6

Effect of I Source end Tlae of ApplIcattoo c RIstave Tle24 of a rt- rat1 T Lsd lice Vasrety Crin o Irrigated L41tshy1 at S Locitite mindi 1972

Rate ____________14_3

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- 38 -

Table 18

Yild of aemati-370 Rice at Punjab Agricultural Research

Institute in Pakistan in 1969-70 Grown Under

Couditions of Intermittent Flooding

Pate of application

=IL

o 0 67 67 100 100 67 67

100 100 67 67 200 100

Average for Sources

Ntha

AS 260 gres 279

320

Source f5

-

AS AS Ura Urea SCU SCU

Yield

Relative

93 100 115

(M)O

Yield

Increase Yield Due to N

(Ktlha) (mtha)

-212 245 033 274 062 260 048 297 085 315 103 325 112

Yield Increase

Relative

72048 067 100 108 161

(2)

- 39 shy

Short-statured high yielding rice varieties grown extenshy

sively in northern Peru require extremely high rates of conventional

N sources to achieve maximum yields The recovery of applied N is

extremely low due to the use of intermittent flooding This water

management system results in heavy N losses even with properly timed

split applications In search of simpler and more effective methods

of N management eight field experiments were conducted in the region

to evaluate sulfur-coated urea (SCU) an experimental slow-release N

source supplied by the Tennessee Valley Authority Rice yields were

increased an average of 59 more by pretransplant-incorporated SCU than

by urea or ammonium sulfate applied in the same manner SCU produced

excessive vegetative growth which resulted in yield reductions at high

N rates

Regardless of an assumed 48-higher unit N cost in SCU the

overall benefits of pretransplant-incorporated applications of SCU

were favorable since there was a decrease of 40 in the optimum rate

of N and the need for precise timing of application was eliminated

Pakistan--In Pakistan basal applications of AS urea and

SCU to rice grown under conditions of intermittent flooding in 1969-70

(table 18) indicate that SCU is a superior source of N as compared to

urea or AS when all N is applied at or before planting The data also

indicate that a yield response was obtained for P applications but a

comparison of N sources at each level of P indicates that no interaction

between N and P was present so that differences between N sources were

relatively the same at each level of P Yields were increased about 60

more when SCU was applied than when urea was applied Yield increases

with AS were only about 72 of the increase obtained with urea these reshy

sults do not agree with the generally-reported superiority of AS as comshy

pared to urea as a source of N for rice

- 40 -

In 1973 experiments were conducted in Pakistan using both

Basmati-370 and IRRI-6 varieties of rice grown under conditions of

When all N was applied at puddlingintermittent flooding (table 19)

or 12 at puddling and 12 at panicle initiation both AS and SCU were

superior to urea with SCU tending to be the most efficient source

However when N was applied 12 at transplanting and 12 at panicle

initiation SCU was the poorest source of N This would indicate that

the release of N from SCU applied at these times is too slow for optimwn

plant growth

In another experiment in Pakistan in 1973 no differences

in the effectiveness of urea AS or SCU were noted in the yields of

continuously-flooded rice (table 20) Again these results are conshy

sistent with earlier results which indicate no superiority for SCU

when rice is continuously flooded

Nitrogen Studies--Maize

A series of three experiments were conducted by IITA in

armo-Nigeria in 1972-73 comparing AS urea SCU and

CAN (calcium

nium nitrate) as sources of N for maize (table 21) A significant

yield response was obtained for N at each location but no conaistent

differences were noted amaong sources These results are consistent

with results at other locations which have not shown that SCU is a

superior source of N for maize grown over a period of 3 to 4 months

Nitrogen--Wheat

The yields of wheat in Pakistan in 1969-70 (tables 22 and

23) show that yields with SCU) tended to be lower than those with ureaJ

although at one locction where sorghum was grown followilng wheat with

Table 19

Yields of Basmati-370 and IRRI-6 Rice at Punjab Agricultural Experiment Station in Pakistan in 1973 Under

Conditions of Intermittent Flooding

Rate Yield Source of N Time of Yield (Mtha) Increase of N B-370 IRRI-6 Application Basmati-370 IRRI-6 Average (Mtha)

0 0 - 21 353 287 -

SCU 90 150 At Puddling 325 545 435 148

Urea 90 150 At Puddling 309 500 405 118

AS 90 150 At Puddling 324 529 427 140

SCU 90 150 Puddling 372 572 472 185 Panicle Initiation

Urea 90 150 Puddling 335 502 419 132 Panicle Initiation

AS 90 150 Puddling 353 529 441 154 Panicle Initiation

SCU 90 150 After Transplanting 312 562 437 150 Panicle Initiation

Urea 90 150 After Transplanting 340 624 482 195 Panicle Initiation

AS 90 150 After Transplanting 349 583 466 179 Panicle Initiation

All plots received 45 lbs P205acre as single superphosphate

Relative Yield Increase ()

Source of N At Puddling Puddling Panicle Transplant h Panicle

Urea 100 100 100 AS 119 117 92 SCU 125 140 77

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-48

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ThUAIAd

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P11~0 pra~lpj prefer gre4r tuftlter for whlae

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asowcs of P tof ttde ro The wreem proucts omre raGther

pemour~a ot P syag besmti andMi as elt ov so gpamwhr

iuipiqffhate(TS) low twseeo Is eftwiltve Is thet

W41 preeme wae oialain ire post-rItoi effriq to Stanlato the

pud6itt of Irto paddle Wee ofsdlseireplastiq

0 49 shy

lbs partially scldiaatede grawilated Ml prodlucts Vere isshy

toiwdiats in 5tftOvttWS54 betwee wroiPi ad TVP NotV5Ymf to

me coo were they mere twoe $a a etfective ao TIP 00 sipifleast

LVSUMI5 at0 efecto wore toun tor thee produteo Timely dtIampWde

FR (-t00 mmoh) Uia amp~rally oar affective than Owe gra8448r FOampprodt

featal twos o 6 aotetire s I

Nowvero it to felt that sfortber field euprtet vth

hese interials Amd ether typs of grometatodl Wter nre wrrautad

hater ceeuwodh that they have me areec poteatlal toi additoG

e tate wAne the sectte as OtawrI sed bovoloen turther

euperimeste vth few reck pboophar s0d with reck pbophat treated

to sehesa citrata selmtliy or to ha csaducted

Metbir sertes of tbme enprtaeats wae c~edtmcted by IITA

to Ut~rta copal TVP AOP APP aed it at see tecastisix (table 14)

No dot lalt sewseltles teh draw tree thee results simouely em pear to tlvdl bsww they do stwgpt tbat forthew work with

MR to werramid so tbme sels

Table 24

LttcttF Swce MaPlate 06 ieldot IM AWaia CoelsANS at IITA (Ugboda ad Apoin ail sorit) aid at Ike (AUaba s5i series)

1973

Plate ot IP Apinu 5 poundebods A1ab

Ocrol 0 Z94 419 M)

Tr ipl ruprphite 20 349 3799378

Triple vepput 40 M09 410$

Triple 6wp~~b1 4271 4344 42250

Ammotw-ritpophW to 4201 4124 4040

Amosim-rdop~phlt 40 4270 4106 4231

AM tuo-polpephats 20 404 4244 3794

~eai~mpelppepbuI 400)49 4094

Cee m-pbpbt to- 59

momee eph lto 0 4192

LSO (0 0$) 29 1025

Th WPII

- 51 shy

101Y114 tpeM-fI PEP~tbRP YO

1 ~ ~ gmw 1pc~biofl- 9 Kla4v4h

Upia U04 Copfind am Crehout Stet Rpano at (Ia4

rico t IF t rume6 orth~ Caralto phoophale rocl QAR) vaUN pqU41 to

roopon from cmonetrat4 gsporphophai (CIP) who ort$o4 oil k

was 45j itwas tafertor vb protioo4 oil p war OS Ib 4iffer~c

in rtc reepos to X cod14 oo bo ttrit4 4 4 hvsciag of boil p

~ Pt o r11221 0 tP

c theto the rhimecyllndor of rico tots par to)14M4i1 roeoi~t

ed oil emd PA prior to tho ont of an~robi4 cMioe AA~ oIifoshy

nAte bYpot t taet~d tO fC4sin t~r 4PWden0 Of f Ot(tivshy

ofOWailiJtyno o prefla4 all Put that 4t01etoo 14 tvsIk

of the Ott to prvvld a 014for C4m0 44 mI 1 o4sf

EfftC ftPet141on AIAM-0 V f401td 4 4iv 440 Mtft

Aa torfat VampP f4MWfCi4W04wt0amp to 4eturWlI Ot(Wel~drIC ft

Ot f tM6 the flooded Ott 00 14 04019I Pft0uAw Of gAr~s~lr

pkS$t M40b MP) Tw P1101 Piset Prodwie W-e 10M0di Wr04

(10-1) emW 0aretilp ddw01at4 P WAA firom Rrth M~flRU414~$

wee cowiared with fie Md reWim 44104 proo~fo) foruk oith laWItter

I v te-PR P OW1004 4 4 O Wf ottil OW ellt Oo

Oveiel1 the 40tt dmcruie to effetotww Wtollowui Co fme

PR tpaUIB1I ldoltmo PR (pamwlatr) offr~- ArmeuM) 0 orwi

- 52 -

Effect of N Sourc6 and Water Management on Response of Rice

toe Zn- M Giordano J J Mortvedt OP Engelstad and Greenhouse

Staff Several rotes of CO(14H2)2 and (H )2So4 vith or without ZnO

wore applied to flooded and nonflooded Crowley oil (limed to pH 75)

to determine response of Bluebelle rice to Zn Yields with both N

sources veotrgreator on flooded then on nonflooded soil In the abshy

ence of applied Zn total dry matter production vith CO(NH2)2 was

slightly lower than with (NH)2S04 on flooded soil and considerably

lover on nonflooded soil Concentration of Zn wan higher in straw and

grain of plants roun on flooded than on nonflooded soil Although

concentration of P was unaffected by N source or Zn rate there was

som indication that cranslocation of P from straw to grain may be

depressed in nouflooded rice Concentration of N was lower in straw

grown on flooded than on nonflooded soil due to apparent dilution

thereas both X sources resulted in similar N concentrations in straw

at all rates of N application the N concentration in grain increased

with 0 rAse

feSpongi gf(SM to Chjorospodiostte and Related P Sources--

Si Allen and Greonhoue Staff A greenhouse pot experiment was

couct44d with corn Brown on Hountview silt loam to compare the ofshy

fectlivees of chlorospodiosito (Chlor-l) with concentrated supershy

phosphate (CP) Thomas slag and North Carolina phosphate rock (NC-PR)

Oil-prillad urea-phophato rock (UPI) FeA1JMP 20 7 and monomthyl

phosphate were included in the experiment Based on yield of forage and

uptake of P by tvo crops each of 6-weeks duration the following conshy

stui were dravat

I Chlor-1 was slightly loss effective than CSI Thomas slaS or NC-PR

from which Chlor-l wae prepared

- 53 shy

2 Granular UPR was a poor source of P its effectiveness was greatly

increased by reducing the particle size to -35mesh

3 FeAlNH4P207 was unavailable to the crop

4 Monomethyl phosphate was equivalent toor slightly more effective-

than CSP

Research Indirectly Related to TVA-AID Project

Response of Several Rice Varieties to Zn in Moist or Flooded

Soil--P M Giordano J J Mortvedt and Greenhouse Several varieties

of rice from Mexico and the Dominican Republic currently under investishy

gation in Puerto Rico for adaptation to upland culture were compared with

some established United States varieties with regard to Zn response on

moist and flooded Crowley sil (pH 75) Chontalpa (Mexico) Bluebelle

(Texas) and Starbonnet (Arkansas) were most responsive to applied Zn

Juma (Dominican Republic) intermediate and Sinaloa (Mexico) and Calrose

(California) were the least responsive The Sinaloa varieties (Mexico)

appeared to be best adapted to non-flooded conditions whereas Chontalpa

and Calrose were poorest Concentrations of Zn generally were higher in

plants grown on flooded than moist soil

Pattern of Growth and Zinc Accumulation by Rice--P M Giordano

J J Mortvedt and Greenhouse Staff Rice plants were harvested at weekly

intervals from shortly after emergence through maturity The objective

was to determine the rate of growth and Zn uptake by a Zn responsive varshy

iety (Bluebelle) and a less Zn-responsive variety (Calrose) in the presence

or absence of Zn applied to Crowley sil (pHl 75) Dry matter production

of Calrose was linear with time of growth and of a similar magnitude until

heading with or without applied Zn Bluebelle followed a similar pattern

where Zn was applied However in the absence of applied Zn foliage yield

was reduced markedly

-54

Uptake of Zn was similar for both varieties whenZn was

applied Dry matter production and Zn uptake by the two varieties

also were comparable when Zn was applied However yield of Calrose

was much higher than that of Bluebelle in the absence of applied Zn

while Zn uptake was only slightly higher This suggests that the lesshy

ser responsiveness of Calrose to Zn may be due to more efficient utilishy

zation of Zn There was no indication of a greater demand for Zn durshy

ing reproduction in either variety as was suggested in earlier greenshy

house experiments

Response of Upland Rice to P and Zn--P M Giordano J J

Mortvedt and Greenhouse Staff Several rates of P and Zn were applied

to Crowley sil (limed to pH 75) in factorial combination to determine

whether differences in rice growth under flooded and nonflooded soil

conditions are related to plant nutrition Although straw yields were

slightly higher in nonflooded rice receiving adequate P and Zn grain

yields were higher in the flooded crop increased rates of F andor Zn

did not result in equal yields Except in the highest Zn rate (75 mg)

concentrations of Zn in both straw and grain were higher with flooding

Concentration of P increased with rate of applied P and was higher in

the grain or flooded than upland rice at a comparable P rate In conshy

trast concentrations of N were lower with flooding due in part to dilshy

ution from increased growth

Rice Response to N and P in Flooded and Unflooded Cultures--

G L Terman S E Allen and Greenhouse-Analytical Staff Rates of

N from 250 to 2000 ntpot and P from 0 to 1000 mtpot were applied for

Nato rice grown on Mountview sil and Sango sicl (625 kg of soil per

pot) Market yield response to N and P was obtained Yields of straw

- 55 shy

total yields N uptake and N recovery were higher on unflooded than

on flooded soil cultures Grain yields however were slightly higher

with flooding These results indicate that with adequate applied

nutrients especially of N rice yields without flooding can approach

or even equal those under flooding

Uptake of N P Ca Mg and Zn increased with yield response

to N and P while K uptake decreased on the Mountview soil Concentrations

of N and P increased with applied N and P respectively while concentrations

of other nutrients were diluted in most situations with yield response to N

or P

Results from this experiment show that amouats of N applied in

previous pot experiments for rice have been much too low especially if the

crop was grown to maturity

Response of Corn to S and N i UUASand Urea-S--S E Allen

and Greenhouse Staff Three greenhouse pot experiments were conducted to

measure response to S and N in ulfur coated urea (SCU) urea amonium

sulfate (UAS) and urea -S as well as estimate N losses from surface apshy

plied N sources

In Experiment 260 less than 20 of the S mixed with the soil

was recovered from SCU or urea-S granules by two crops of corn as comshy

pared to 45 or 80 from flowers of S or Na2SO 4 CLop response followed

a similar pattern

In Experiment 260-A N sources were surface applied and alshy

lowed to dry for two weeks before incorporation Into the soil and plantshy

ing Recovery of N by two crops of corn was 77-82 for AN an compared

to 37-70 for urea UAS urea-S and ICU Thus n this experiment loss

of N from urea did not appear to be re~dcud by light S-coatlngn or by Inshy

corporating S or AS in the granules

-S -

I xbprZnSlt a Wtch aU Meyto 0-Ai Wt f9r

higher reermo teOrtOrs cOM reSpWNO i r0100 Of N w

not oaisteontly related to sewe ot N In edl tust 0 ioltiUe Lim

lo in VMuwpped evlmtUTS 48 merind by seirest nte appresOehe

501 for uroa as cwarod to 210 for urea peepha

Rus- or Upse to LoAmIl34I a AriMed bI Earl U

MW NOWlsIIsIr-4 L Toman 5 1 Alln and eesese StNf rio

row on Sawg did (0 tpot) We 1l0l0 Ws feritiud vith 05is

of Npot mixod with the 6011 as aureCA NiAO) 1 Age god At Ures

was also itcluded at rtt t 05 10 end 15 of Upee Theas trealshy

onto were followed 4 wpdrsetago of U s AN wre 4C 10o or at I3n

Weeks toulin up to IS pot

A soil application of 10 pot rosulvod to the maim yield

at 4 weeks Tio4 sad percont prottis t intre raite tncreased rftishy

linearly with U applictalien IeseeItally all at the m iNd wit

the moil w domitrifted after flooding Grail end straw Ilelds vere

highly correlatod with tiliriag and vlh ubers of gralm arl

The results Widicat that 0$ to 10 a of Upot as orea or

NN bsuld be sied with the oil to stilate tiilrir with adshy

ditional 0 topireased later to increase grain lIds mad protia cmshy

tout

DIVISION 54- FERTILIZER TECHNOLOGY AND USE

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-02

792 60L WI W A)49R Pio VOL 37 197)

primS o r OeampAd WU toa Them fl~ w At NOSSe earno maisslea Ia N he mOWamplIO yik ampWd IMe aampWmW OWa Owe wa UMs of KU to 41 Oke ampWiiIamm be dkrnety ewspokawleM(a s8 te camtd wie a eapmoe by TVA pavw ltoi NA poundrmdaka4us vrimeW460 o to ilkidm ofWW (Mtemas MuOwe 1973) TVA mwi bawld on soi ficedims IampWp seg rudwiv s~s0abet ke WNmdoe ON 01 K Is12 NOSW ie fssewnmu Ie I QvaaIi rowp IMA) f9

)amp m lodk byO voebmsaIS8OpeaWfrats 11 OWNmi a I a W idisod 0 81 Now 111 nindat Wm fysmpseaamp (If tsO tUmtI IsM $P shoroV4mmo knflkvnf (foOdme nuw ae Ow OImstwe in SM pnmm8 af tXm 10 114PIS kequoian wo Mpfii

SC~po umd spop~o VWt alm 4emWal 1 4ink PCmirsra M 1 ad AI 14bmms

1MM Ww Even to doe shw wisht b-o -Wamp Ekb fed rbaimpal of14~ Am Smpound oS mv fAaMda

MGMe -M4 Wg kmuwadM 1Wr wih SCV4 Psmuck Wff It dlL Wm 1W led 0 1 oo teeA of aiwaisme aweeoid h

1Kach Vt V amp4W ILK t)sa 10 Nareps vm This ndY ub thee hbow apiptomuasa of gulfu-aw~sd of Cup lP~~tamsl wi(i

Woeo of woo or mlm Wmiot InIasem~Wsy (heede 6Am 0 F- ad PAicv IfM tsoPm 9W famp kw~is 04eet The r4 ggm I ampbpiIs OnwAu 4nvmkstm v PAraem A4fshy

e W d inSIWfh sil $ad doke IaefitV twoer) 1 Te to theo owie effu so booJ imik WOi 100 N

-d

Is re4aled uIwq~e~w Aueee atofurnw di Capsnm ptopeatls is a oommm eiws to 100 tom of 04404man d CtdUW 4M Anw K~a do Aamp apowee WPUaN powu eel H pae iaaa thAi SCUI isWW owr hmem ISsuppl N to the li ieee F A IM1 Nampa Obo~amie m

41MB ~ ~ m ~ ~0 0-- 0 140 The ffsemn of food Nn else9~e(Ud~ ~ ~ ~~ WooksaS eAWw pjed of ho~raw of IU effadam vfdva oft xhj0I 13iAl

DIVISION 8-9-SOIL MINERALOGY

Amorphomw CeetIup en XmWra Ssrfmls

L C koits Am~ 0 tmmkaAf

ommp A faieiaAMTRACT skiwe lo nW ampM sm wi4h

Walo by a onMm I dmivid hseidm6Wlk W~edesie s

peuiieles as is s e wpwigstee eded his S -em -om 0641 h4 hisW1mWOWb~ bfem peess Wimm kv Iee

Pa~~~eakr4awiS SeUeeiNaiA WOW 14e

PWWWW t HW f hea~I~~~~~a 0th

kog Ii ampI b 1111h1atAmOem aid itsaere~m-aelmoeug toolPe aal 111W mWa Wisg ag so~ ti~Wo booviot65k Th eme Iua 1111411uiwon it es 01000 AW~CWS ~muiseeteqqsheer21111 ionev

oO00 llb K0 ibad~ ~~ doj 140WI s o mimdW um

WLIMmAmMVL 1

lill mi oHow al of a be 1974oyais4gamm wsoc wwo

rdy i of OMAN toblind id sh os 00 IN bei m us salqs m kid Vw 1 a0Msw WFW isms waf e eeiWei he-4~~e gsa dulsi

os 0aMW ofmu WA l aduWs~Ib rowuvvl3maIpm s

CaO~OP aw AlNomI 4ornomd to9 IS is -l O SI g4he rpidyThus whim m dowu bWa 0 m m- ei u

d m M 0bmSaImu M-1 ofM6 h Intun to 7I

aiba maush WAesshwn~u9dSg a osusLwpI ~ v m

M PolsdAvoWdw Ons pugm~ low iwLW m We

of~U -a~ mo uNo

0401ts of 40

A e mun5d m i vvamp sa s ow bftIS i sa omdIs a w

edi1 hswopmo an ag am Iw anom erlwaPASneooie bnwoM po

o ~ do=lr 3s fluACWoSM Owaa VolM Ain b 400b adW g o as amob ofrMOWS A oo eWmaa ow $wofdi60 ow - ema

-v K Vcon l ap ad md ld KU lbs PoabumwA od w to domi a bembe 0b lt $014 i ampmomONo

4st diwemmSod i 6o pa P)ameakiksm4 m 04M t 1iV vs 0606 o IS ft dopsss of q madl w I10000014 t 44hs

arbs awasm 00 iztv Am-~~~i u5~ms ashu is byw

e~ihs diu~wsm ~phid W A0)ad Lobe d mi-~-- 1) 14 hald

bob~wh do is poPbe~mueus l to aVE tumad 40at iai ka as m

bdisc shmm Ammmd a Sm ofd~~~~~d~A ~ a~m olWshmo

OWNSrilgf ms as

Um~~srTmws~of 4 A ad to wy mis itm voW

IN~flA4T ampMww IV Kwo~t M1CI I POWMAIS amV VARw d01M11 W V

e~~Pum-p -f AOACoe~mfmmdso isedp Am PApmi sk adw Wsk m~ o P4 m

- omlos r umIWO1in pw

lie Uvplist i piw S p wsmoW N of t as so in~tabo 440 o rodgAsect M4Ammd meM ii INAq10ed~ Pib mdWWeiW 1w -w emit TU UFm 6AV 0W A fIN 00~ lb 0PANNO 4 drp OW~It~Oi Ofme _____f WACMW0IN WMVsol~lmO ft SNAO 40 do1Si - m Md y e b ii m

of of~phaow tw bmsdf toamplboe

AjflsutomW C1D-pCTP AD mSmZLT op 1 m ow ts Wdm of P om M

IaM 0t sdw a wn a8duws i ofV -w Mm P16I4 TWO a ewu i an

ov4mnk wsi 9 Mxfeu~i am emwm ismi0wmd fq W No ~~ - f mug Aitowe eutlkowbmTV is

amppowftdmi TiM 0 Tie OAA mo p)a Mwomoi dOn4m A)w

MW 0 604 0M mm yaM 01MWOfdi to tA0 M OOAW uinw OSOb

ap is~e I the ampo A A Mwof ~Do toit op aenu w~ifiOimem~ MAN ampW)

ItsAO se Y lieowawo u~w pkow-W1b pwf on a C Nohkw is f 0o1 s do~omW C mmU4

owud6moeft 4 Obind PINa~e

~4~~wreu -A---I ad

fit~~~~O 114 4 t I mMsmm m~

im ^aim4 Nomod 06maw ee Aist em moom a rA No fmiEo of emit

~ -0

65

0IL CL OC AMXR PROC VOL 38 1974

)aT1 S4I104 ow Lusanll Tawng isa tall Thai variety known for beingIwo nonshyi s s ) sensitive to photoperiod A split-plot design was used in

S e e these euperimeots with 4 rates of P (I1 22 44 and 88t i V IV k of Pha) applied a main plot treatments and with the OF It sourMes of P as subplot treatments There were two checkS plots in each rmplicate The extra check plot was included to permit the application of fresh TSP standard Jor the

It- ti 06 + i bull fa succeeding crop the p-4me of bi was to permit accurate d awrnwal of the mdual effectiveness of the phosphate

ftinSUbI rock The P fertilioers were broadcast on the mud andthen Worporald In the soil during the last harrowing At

whM N both On ACS indx ampM time of transplanting Immediately before the last harrow61t (4j 5 4 01 P s 3Mm o Vallonal in con n 100 kgha of N as ammonium sulfate and 33 kghaWO Of Spews ampm lIW thaabe rocks do ACS indes of K as polium chloride were applied A total of 40 wa in prepw O do ctih k otent kha of N a ammoniunt sulfate was applied later in twoir P The hew oNed amp wM W for 5 of gw topdrossingp with about 5cm depth of water on the plotsvV I aiOMveffeOctveee Three to six ldayold selings pr hillwW the ACS idex were planted00OWW wia Oft fo an c irNk I p Coen 20 by 20 cm part in straight rows Hand weeding was used

and insecticide were applied for Insect control Grain yieldw was masared by sampling 5 ml of each plot excluding border rows The date of heading in each treatment and theUNiN d pbM W Weks rin tOW USA UMe In Tale yed componnts at hafvel were also recorded

I filM rsperMS esOM kdwdua 1 t ab The average yields of ough (unhulled) rice for botha 84 OW O 8uo 4 Thala TM was a locations are ploutel in PIS 3 for the first crop (1969 wet

owou thRM seaso0) The Veamps yield response was obtained at Klonge (s) W lDtO t Of dMa of1tw W d l R Luang however a 4ute satisfactory yield response was

~Mk ^d TVA UJSD ad Kd UnIveS obtalned to applied P at Bangkhen as wellXUe LaM e R qwrw Ims The sod was do Relative aponomlAe effectiveness values were calculated

VOW (a ksA w edmwL t Poesesm h Vy for these data and am presented In Table 3 The valuesdAY buo if dIe ouh ne Pee wtk a Mlak vow 1009 for th first crop are plotled against ACS index in Fig 41 This Im M i6ti l 4bNd IO a0 O mkarnk for both locatio r relationship was linear for the

11400 ThCpH 0( lb pW IW 01 th UpeiaW so Sanodion location and curtiltnear for KIng Luang The was u i 4A sksamp lMaor nrusio model amparounted for 81 of theAmO$MI Aw jAAsue Swim T1 Snh Wd variation In the AE valu for Bantkhen a square root

Mems a Iw iv fern alh$ sedm haowg dayNW W t he plAL At tdo M tM aso W s as ctminued throufh eltaM t Ofpof -le lse wo am P OeNI VeOpls 1o ealluae tI lon4erm MIdual Offccls

A on W isset i a wse to hsh eapeel of these ooihss t ocks The baagkhon experimnent was letmiaI1DlVemisthis is a w hulu Lo g Tasug ia iasael aft - Msd residual Ves will be pr-Om crok TheseTwod esewm

SWWo

A

lP~U~7 ISIIPe1iuIWN e bsedisssin ian ghth siaoelalbe

984 0 6 O O - M s -s fWPas 11eSft W d Uo al a o

o

S4l~ lIIII I~l I 1f fl

( +

+ + + m + ++++-

++ +(++ + ++++ + ++ ++

- 66 -

ENOIMLSTAD ET AL RESPONSE BY FLOODED RICE TO PHOSPHATE ROCKS VARYING IN CITRATE SOLUBILITY

I I I I j0 I I

BANOKHEN BANGKHEN

pH 56 6 - 0o

TSP

NC

5~ ~ ~ L o 4 - -shy

4 ] - --------shy04

6S

|0 III 2 44 8r 66

I I I

a 1KLONG LUANG

pH 46 z KLONG LUANG

TSP Sc2 NCFL(N)

5 FLIC) J0 TU

oshy

4 ~40shy

3 bull eM0

I - I I I I I

0 II 22 44 88 0 5 10 15 20 IP APPLIED KO HA ABSOLUTE CITRAE SOLUBIITY INDEX

Fig 3-Yield of rough rice at Klong Luang and Bangkhen Rice Fig 4-Relative agronon effectiveness () of P sources ploz-Experiment Stations Thalmand as affected by rate and Source ted against citrate solubity Index for both Thailand field ex

of P applied (crop 1) periment (first crop only)

regression model accounted for 97 of the variation in sumably resulted from crop uptake and reaction with the RAE values at the Klong Luang location soil to form less soluble products Such effects may have

These experiments were continued during the dry season been more important at the lower rates since the two TSP of early 1970 to ascertain the residual effectiveness of the curyes converged at the highest rate of application various sources applied to the first crop No new P was These data from KIong Luang indicate that (i) residual applied except for the fresh TSP standard mentioned effects of all rocks except Mlcwuri were substantial (ii) above rhe experiment otherwise was conducted in a man the relationship between relative agronornic effectiveness ner similar to that followed in the first crop of the phosphate rocks and citrate solubility levels was

The response to both freshly applied ad residual P was largely obscured and (iii) the general superiority of TSP marked at the Klong Luang location and marginal at over phosphate rock in terms of effectiveiss persisted Bangkhen In fact at the latter location the response was through the second crop so small that little can be said regarding residual effectiveshyness The yield data from crop 2 at the Klong Luang DISCUSSION experiment are plotted in Fig 5 Greenhouse and field data presented in this paper show

Relative agronomic effectiveness values (Table 3) were clearly that there are substantial differences among phosshycalculated for the Klong Luang data using both the residual and freshly applied TSP as standards It is of Interest to note that the superiority of TSP over the phosphbte rocks Table 3-Relative agronomic effective values for field experishyments in Thailand persisted through the second crop The main difference in KlowlZmlnql~the residual effects is that with the exception of the MIs- s Crop 1 Crop 21 Crop 1-shysouri rock Ihe marked relationship between citratr-soluble WoiCarolina yl 59 76

phosphate rocks and RAE had largely rds norh) a 64P conltct of th Florida (eqlral is 6969 6

disapipeared In this acidic soil (pHi 46) P would by this I14o 69 63 40 ToonesS 31 65

limo be supplied by Intermediate reaction products In addl Missou 0 o lion to residues of the initial spatlte Ts P o 2 o 0

The TSP applied to the first crop declliv-d slightly In campIafcmWataesr e id ofeuhuloefor 22MA rates of PtColeouattd as aba u tlte td18 kS ratesp dlverage yield tM868 to 22 44

effectiveness relative to the freshly applied ISP This pre- of d s4

A

4

- 67 shy

-SOIL SCL SOC AMER I

KLONG LUANG CROP 2

Si 3

eN

TAPPLIEDKGHA

Fig 5-The residual effectiveness ovarious P sources for crop s compared with freshly applied TSP Klong Luang Rice

Experiment Station Thailand

phate rocks in terms of agronomic effectiveness for flooded

rice Further these differences can be predicted by means of citrate solubility or by the ACS index It appears that

the latter is more appropriate where the content of apatite varies among phospiate rocks The most soluble phosphate rocks approached but did not actually equal TSP in limit-iuig (maximum) yield in these experiments regardless of rate applied This agrees with the results of Ensminger Pearson and Armiger (4) One needs to consider the defi-nite posribility of same yield loss in zhoosing a phosphate

rock over TSP such yield losses must be weighed against the lower price of phosphate rock The explanation for such iosses may involve concentration of soluble P in the soil Khasawneh and Copeland (6) suggest that the growth rate of crop plants is a function of P concentration that can be maintained in the soil solution If P concentration is limiting or inadequate becawe of a lower dissolution rate of phosphate rock the growth iate ard uiiimate yield will be diminished accordingly

The RAE values bascd on yield increases reflect the agronomi effectiveness of these various sources relacve

to the TSP standard however these nould be supple-

mented by an economic analysis before rational choice can

be made The following calculations will provide an estimate of

the rclativ ecooomic effectiveness(REE)

Y t Ps aXpatREE -- 100

vahtercks t sphate or e b i- eor

Price of TSPkg fo

be Price of PRkg P

PROC VOL 38 1974 leO

90r

Wsoshy

0

60-LUSEPHOSPHATE ROCK

00 10 20

PTP PR

Fig 6-Relationship between relaZive effectiveness values (RAE) and the price ratios between TSP and phosphate rock Such a figure can be used in making a choice between these

sources

If REE exceeds 100 in this calculation the phosphate rock would be preferable to TSP

The REE calcuktaaa wre used in preparing an indifshyference curve (Fig 6) wherein RAE values are plotted

against PTsPPpR ratios The cu~rve itself connects those points at which REE equals 100 When exactly on the curve it makes no real economic difference what source is chosen After choosing a suitable price ratio one can then project upward from that ratio knowing the RAI

value (or estimating it from such data as shown in Fig 4 using citrate-soluble P content) one can then choose the source on the basis of both agronomic and economic conshysiderations For example if the price ratio is 25 and the RAE value of the phosphaite rock is greater than 40 the rock phosphate in question would be used However if the RAE value was less than 40 TSP would be a better choice There are indications that if the P in the more soluble phosphate ro~cks (North Carolina north Florida central Forida) is less than half as expensivz as that in TSP these rocks would be feasible altereaives to TSP on soils similar

to thoseused in Thailand This analysis does not take into account the possibility

of lower yields from use of phosphate rock In addition only a portion of the various yield response curves was used in this anlysis ie up to 22 kgha Beyond this

rate yield response was much less pronounced it could be argued that at less than maximum yields TSP would produce a certain yield at lower rates of P than would phosshy

pow ofrock This would especially be true for rates applioa example at Klong Luang 5500 kg of

rice pcr iectare could have been produced with either Ii kg of P as TSP or 44 kg of P as son of the more reacshy

tire phosphate rocks It should be pointed ot however

- 68 shy

(IIKIS amp YOUN( ARIFICIAL WEATIIERING OF OXIDIZED p[ll- IV

that this is the yield level that would show the widest difference such is the advantage of hindsight

Farmers generally prefer granular fertilizers for machine

or hand application This is a disadvantage for the phos-phate rocks which are normally arplied in finely divided form Recently experimental quantities of granular urea-

phosphate rock mixtures have been made by TVA Results of trials with these fertilizers will be reported elsewhere

LITERATURE CITED

1 Armiger W H and Maurice- Fried 1957 The plantavailability of various sources of phosphate rock Soil Sci Soc Amer Proc 21183-188

2 Bengston G W E C Sample and S E Allen 1974 Re-sponso of slash pine seedlings to P sGurces of varying ci-trato solubility Plant Soil (In press)

3 Caro JIt and W Hill 1956 Chard eristics and fer tilizcr value of phosphate rock from different fields J Agr Food Chem 4684-687

4 Ensminger I E R W Peirson and W II Atmiger1967 Effectivencs of rock phosphate as a source of phosshyphurus for plants US Dep Agr ARS Bull 4112S

5 Engelstad 0 P J G Getsinger anid I J Stangel 1972 Tailoring of fertiliers for rice cnnece Valley Author ftyNational Fertilicr Developmnent Center Hull Y-52

6 Khasawnch F E and Jane P Copcland 1971 (otton root growth and uptake of nutrievos relation oif phosph

rus uptake to quantity intensity and buffering capacit) Soil Sci Soc Amer Proc 37250-254

7 Lehr JR and G H McClellan 1972 A revised lIbora tory reactivity scale for evaljativg phosphate rocks for direct application Tennessee Valley Authcrity National Fertilizer Development Center lull Y-43

H Terman G L S EAllen and 0 P Engelstad 1970 Response by paddy cice to ratcs and suurces of appliedphosphorus Agron J63390-394

DIVISION S-9-SOIL MINERALOGY

Artificial Weathering of Oxidized Biotite IV The Inhibitory Effect of Potassium on Dissolution llate

R JGILKES AND R C YOUNG2

ABSTRACT

Rates of dissolution of oxidized biotites in OIM 001M ICI are severely depressed in the presence of IM KCI The amovnts of Al Mg Mn dissolved in the first eytraction are similir to those found without KCI however subsequent extractions remove these elements at 10-20 of the corresponding lICI rates This effect may be due to a decreased rate of vermiculite formation thereby reducing the effective basal area exposed to attack A decrease in dissolution rate with increasing ferric iron content was still apparent in the presence of IM KCI

Additional Index Words X-ray diffraction infrared aborp-

N EARLIER papers of this series the tole of biotite in soils

as a source of both macro and micronutrient elements

has been discussed ((Gilkes Young and Quirk 1972 1973ab) Experiments in artificial weathering uiing as va-

riety of extractants were undertaken to determiie the inlu-

ence of oxidation of octahedrally coordinated iron on the bull release of structural cations to solution The results of this

work demonstated that biotite behaves anomalously with respect to the other common ferromagnesian minerals found in soils Oxidation leads to the development of a high degree of resistance to cation exchange and dissolution Several authors have coiwludcd that decreased rates of K

Contribution from the Dep of Soi Science and Plant Nutri-tion Institute of Agriculture Univ of Western Australia Ned-lands 6009 Western Australia Received 29 Sept 1973 Ap-proved 8 Jan 1974

2 Senior Lecturer in Soil Science and Research Officer respeclively

replacement in electrolytes shown by oxidized biotites are

a result of the inclination of structural hydroxyl adjacent to newly created trivalent iron or vacant octahedral cation sites (Robert and Pedro 1959 Barshad and Kishk 1968) Gilkes et al (1973b) suggested that decreased rates of disshysolution of oxidized biotite in 0001 0t)l 0Af CI may also be due to the presence of inclined hydroxyl In this case a smaller surface area external and exposed intershylayer may be available for attack if K replacement by hyshydrogen ions occurs at a slower rate in oxidized biotites

Gastuche (1963) has shown that significant dissolution ofthe (IIM) biotile face may occur and it is easily demonshystrated that the proportion of exposed (001M) face in weathering biotites depends on the percentage K replaced

Rausell-Colom ct al (1965) have shown that hydrogen ions act in an identical fashion to metal cations in K exshy

change from micas In particular exchange c-f K by hydroshy

gen ions will be terminated or greatly reduced by high levels of K in solution Thus if dissolution of oxidized biotite by

acids is carried out at sufficiently high K levels to prevent vermiculization any differences in dissolution rate that may occur cannot simply be ascribed to differences in rates of K replacement The following results were obtained from such an experiment which unlike the experiment described in Parts I and II (Gilkes et al 1973ab) does not attempt to simulate natuiral - conditions

MATERIAILS AN) M HIiODS Further subsamples of the less than 0 hiotites used in K

excherandbaid disoo tu es (G iles e9n K exchange and acid dissolution studies (Gilkes et al1973ab) were used in these experiments Preparation of sequentiallyoxidized biotites without intermediate vermiculite formation is

Page 20: I70 - United States Agency for International Developmentto ascertan, but tgl.eetad, 1, L,. ("Tailoring of Pertiltiters for ice,'" TVA ulletin Y-52) states that the staft of IOi has

Okfi A4~

~t~e ~I q44 iu-~ps6amp4 j

~M 6~4A4o4iwAA ~ri~~4w Sl a~a4M 414

644I 4a 44 44 ~ ~ L ~ ~ ~ ~~wAa~

440 4 414 I440 US0A 4441 IIW iI40 AWc 4 I~qamp~

0 44 ow Alt~a0404 4 $a ~ia4I6

4w 44 4 A 9i)al 448404 AsjpW4114 voso444q

4~b~~ 444 AW4iU a-w $ 4 $ts

m- 4A4 4AWWO 44 $4amp iuamp-4)Ia ampW x~I~4~

~ i~P 4 4 wl 444 41A ~4 4~~E4166 I144 4t~w i14

4wamp444sa444 Awt4~ PA 4l $WX qO j44 at4 44w la44 C~ to~ v-40

io- s4aq4 4Wvs i 44t amp 4W 4-1ampo-v 4tI 44041 4 4~ kikamp3o 41

0)6 4-44 Wl 44 4444 OV l44 i444 441 0 4NW44bk 1V420A

~~O P44 44is ~ ~4 Aloti~S~3vool41~

0uI 4044~Me ~ ~ N4

4 jk-4il4 9-4 jio4 4 4I4wSj- ~ 4 sZiamp 44s)

) o~4w4 4444~S Is~4~4 ol I i A 4~ ~

4Ii I~4I4M$~ ~I

QOWIf XVif k

4004 004o4f U A

-w i4 I~~~

40440wo oow IVTA 44qol 644

4I~~~4J 00S4 4410 114w- A44W Wamp ~

6WViso4wb f vfpo w

w0OIA - i f iIS

f4 A 00 1 o4

I1~wo ow4O4-40404f-4 ~

TOM I

Cs VWA1 t lw Vairtile ot P44Y 44c KW MI1

fiat Wm~~JL U Lem~ampuJampAJ Wat IO

~ 941~1 41 ~~~~j~~qt~~8IJ WtS dobu

Table 2

Mttct of 0 Sourco aampW $At On Upt~ks of 0 by Two Varitgtos of Paddy Rice

gr~a 1971

~ MMUampL~ ~L ~ nYLALI~ 11 lemall

I ie

W0 v slit III I) tQo9

KvN 1 17 111 1119

or 444M7

111a

i1$0N ~ It$ 121

1$

x IV ~404 tot Vsr 1 P1 41 w otv 1

- 24 shy

India--The results of four experiments conducted with flooded

transplanted rice in India by the All-India Coordinated Rice Project

Hyderabad are given in table 3 The response to N was excellent the

yield without N being only 41 of those obtained with basal applications

of N as uza With basal applications of SCU the yields were 20 higher

than with basal applications of urea and in the three experiments in

which urea applications were split yields with SCU were 18 higher than

yields with split applications of urea When comparing the average Nshy

response (kamp grainKg N) yields were increased 13 more by SCU than by

basal applications of urea

The data from one experiment with light irrigated rice in India

are given in table 4 yields were relatively low and differences between

N sources or method of application were not significant However yields

with SU tended to be higher than when all urea was applied at planting

but lower than when split applications of urea were applied Again yields

increased more than 13 more with SCU than with basal applications ofwere

ur

In tables 5 and 6 the yields of a short-duration transplanted

rice grown in irrigated light-textured soils at five locations in India

indicate that higher yields were obtained with SCU than with urea when apshy

plied as a basal application Yield increases due to basal N applications

were 502 greater with SCU than with urea However split applications of

resulted in yields equal to those obtained with basal applications ofurea

CU

The yields of direct-seeded upland rice grown at three locations

to India are given in table 7 and the relative yields in table 8 Yields

were low due to drought but good responses were nevertheless obtained for

- 25 -

Table 3

Effect of N Source and Time of Application on Yield of Paddy (Flooded) Rice in India 1972 (Summary of Reported Data from 4 Experiments)

Experimental Number Source Rate Method Yield Relative N-Response

and of of N of Yield Kg Grain

Season Nitrogen kgha Application mtha Kg N

- - - 196 34 -

Urea 120 Basal 573 100 314

11 Urea 120 80 + 40 611 107 345 Rabi SCU 120 Basal 713 124 430

12 - 0 - 202 30 -

Urea 125 Basal 682 100 384

Rabi Urea 125 35 + 20 + 35 + 35 633 95 344 SCU 125 Basal 781 115 463

13- 0 - 168 44

Urea 100 Basal 385 100 217

Kharif Urea 100 30 + 20 + 25 + 25 400 104 232 SCU 100 Basal 462 120 293

14 -

Urea -

125 -

Basal 355 650

55 100

-

236

Rabi SCU 125 Basal 781 120 341

-- 26 -

Table 4

Effect of N Source and Time of Application on Yield of Light Irrigated Rice in India 1972 (Summary of Reported Data From

One Experiment at Pattambi)

Experimental Number Source Rate Method Yield Relative N-Response

and of of N of Yield Kg Grain Season Nitrogen (kgha) Application (mtha) Q) Kg N

38 0 - 204 85 -Rabi Urea 120 Basal 241 100 308

Urea 120 60 + 0 + 30 + 30 267 ill 525 SCU 120 Basal 255 106 425

Table 5

Effect of N Source and Time of Application on Yields of Short-Duration Transplanted lice Variety Grown on Irrigated Light-Textured Soils at 5 Locations in India 1972

(Snmzarized From Reported Data)

Rate Grain Yields (MtHa) Source of N Method of N GrainI of N kgh Application Faizabod Karjat Mandva Pattabi laya Averaje X

- 291 266 211 19 340 260 -

Urea 100 Basal 386 407 361 285 482 3 124 Urea 100 50 + 25 + 25 399 430 434 334 6amp2 4A8 186

SCU 100 Basal 368 468 439 360 572 41 181

Table 6

Effect of I Source end Tlae of ApplIcattoo c RIstave Tle24 of a rt- rat1 T Lsd lice Vasrety Crin o Irrigated L41tshy1 at S Locitite mindi 1972

Rate ____________14_3

Source of X N~tbad of Of X An 1 tat14 1 acr X__T1 4v tatW ttva

- - - all 7i i

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Tabl I

f~ttwi Ot 0 6wirce 81d At$ a vt1d at flUop4d Rico to Vitjorim (1ITA)All fortitfour to rsodkeet OA lC~OVPr4( 114 5iI 000

W Iotors Ftslanp tospg Irritd for Two thvk Afler flontiw wft rkwa~ Floo4d 191)

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- 38 -

Table 18

Yild of aemati-370 Rice at Punjab Agricultural Research

Institute in Pakistan in 1969-70 Grown Under

Couditions of Intermittent Flooding

Pate of application

=IL

o 0 67 67 100 100 67 67

100 100 67 67 200 100

Average for Sources

Ntha

AS 260 gres 279

320

Source f5

-

AS AS Ura Urea SCU SCU

Yield

Relative

93 100 115

(M)O

Yield

Increase Yield Due to N

(Ktlha) (mtha)

-212 245 033 274 062 260 048 297 085 315 103 325 112

Yield Increase

Relative

72048 067 100 108 161

(2)

- 39 shy

Short-statured high yielding rice varieties grown extenshy

sively in northern Peru require extremely high rates of conventional

N sources to achieve maximum yields The recovery of applied N is

extremely low due to the use of intermittent flooding This water

management system results in heavy N losses even with properly timed

split applications In search of simpler and more effective methods

of N management eight field experiments were conducted in the region

to evaluate sulfur-coated urea (SCU) an experimental slow-release N

source supplied by the Tennessee Valley Authority Rice yields were

increased an average of 59 more by pretransplant-incorporated SCU than

by urea or ammonium sulfate applied in the same manner SCU produced

excessive vegetative growth which resulted in yield reductions at high

N rates

Regardless of an assumed 48-higher unit N cost in SCU the

overall benefits of pretransplant-incorporated applications of SCU

were favorable since there was a decrease of 40 in the optimum rate

of N and the need for precise timing of application was eliminated

Pakistan--In Pakistan basal applications of AS urea and

SCU to rice grown under conditions of intermittent flooding in 1969-70

(table 18) indicate that SCU is a superior source of N as compared to

urea or AS when all N is applied at or before planting The data also

indicate that a yield response was obtained for P applications but a

comparison of N sources at each level of P indicates that no interaction

between N and P was present so that differences between N sources were

relatively the same at each level of P Yields were increased about 60

more when SCU was applied than when urea was applied Yield increases

with AS were only about 72 of the increase obtained with urea these reshy

sults do not agree with the generally-reported superiority of AS as comshy

pared to urea as a source of N for rice

- 40 -

In 1973 experiments were conducted in Pakistan using both

Basmati-370 and IRRI-6 varieties of rice grown under conditions of

When all N was applied at puddlingintermittent flooding (table 19)

or 12 at puddling and 12 at panicle initiation both AS and SCU were

superior to urea with SCU tending to be the most efficient source

However when N was applied 12 at transplanting and 12 at panicle

initiation SCU was the poorest source of N This would indicate that

the release of N from SCU applied at these times is too slow for optimwn

plant growth

In another experiment in Pakistan in 1973 no differences

in the effectiveness of urea AS or SCU were noted in the yields of

continuously-flooded rice (table 20) Again these results are conshy

sistent with earlier results which indicate no superiority for SCU

when rice is continuously flooded

Nitrogen Studies--Maize

A series of three experiments were conducted by IITA in

armo-Nigeria in 1972-73 comparing AS urea SCU and

CAN (calcium

nium nitrate) as sources of N for maize (table 21) A significant

yield response was obtained for N at each location but no conaistent

differences were noted amaong sources These results are consistent

with results at other locations which have not shown that SCU is a

superior source of N for maize grown over a period of 3 to 4 months

Nitrogen--Wheat

The yields of wheat in Pakistan in 1969-70 (tables 22 and

23) show that yields with SCU) tended to be lower than those with ureaJ

although at one locction where sorghum was grown followilng wheat with

Table 19

Yields of Basmati-370 and IRRI-6 Rice at Punjab Agricultural Experiment Station in Pakistan in 1973 Under

Conditions of Intermittent Flooding

Rate Yield Source of N Time of Yield (Mtha) Increase of N B-370 IRRI-6 Application Basmati-370 IRRI-6 Average (Mtha)

0 0 - 21 353 287 -

SCU 90 150 At Puddling 325 545 435 148

Urea 90 150 At Puddling 309 500 405 118

AS 90 150 At Puddling 324 529 427 140

SCU 90 150 Puddling 372 572 472 185 Panicle Initiation

Urea 90 150 Puddling 335 502 419 132 Panicle Initiation

AS 90 150 Puddling 353 529 441 154 Panicle Initiation

SCU 90 150 After Transplanting 312 562 437 150 Panicle Initiation

Urea 90 150 After Transplanting 340 624 482 195 Panicle Initiation

AS 90 150 After Transplanting 349 583 466 179 Panicle Initiation

All plots received 45 lbs P205acre as single superphosphate

Relative Yield Increase ()

Source of N At Puddling Puddling Panicle Transplant h Panicle

Urea 100 100 100 AS 119 117 92 SCU 125 140 77

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ThUAIAd

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P11~0 pra~lpj prefer gre4r tuftlter for whlae

of hoaw ppltrstie Mhe to a dloedveaP for The PINSOO rocka

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mmfp MW phapa A (CI) sed graewletod pampAtlti arlolatod Pa

asowcs of P tof ttde ro The wreem proucts omre raGther

pemour~a ot P syag besmti andMi as elt ov so gpamwhr

iuipiqffhate(TS) low twseeo Is eftwiltve Is thet

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pud6itt of Irto paddle Wee ofsdlseireplastiq

0 49 shy

lbs partially scldiaatede grawilated Ml prodlucts Vere isshy

toiwdiats in 5tftOvttWS54 betwee wroiPi ad TVP NotV5Ymf to

me coo were they mere twoe $a a etfective ao TIP 00 sipifleast

LVSUMI5 at0 efecto wore toun tor thee produteo Timely dtIampWde

FR (-t00 mmoh) Uia amp~rally oar affective than Owe gra8448r FOampprodt

featal twos o 6 aotetire s I

Nowvero it to felt that sfortber field euprtet vth

hese interials Amd ether typs of grometatodl Wter nre wrrautad

hater ceeuwodh that they have me areec poteatlal toi additoG

e tate wAne the sectte as OtawrI sed bovoloen turther

euperimeste vth few reck pboophar s0d with reck pbophat treated

to sehesa citrata selmtliy or to ha csaducted

Metbir sertes of tbme enprtaeats wae c~edtmcted by IITA

to Ut~rta copal TVP AOP APP aed it at see tecastisix (table 14)

No dot lalt sewseltles teh draw tree thee results simouely em pear to tlvdl bsww they do stwgpt tbat forthew work with

MR to werramid so tbme sels

Table 24

LttcttF Swce MaPlate 06 ieldot IM AWaia CoelsANS at IITA (Ugboda ad Apoin ail sorit) aid at Ike (AUaba s5i series)

1973

Plate ot IP Apinu 5 poundebods A1ab

Ocrol 0 Z94 419 M)

Tr ipl ruprphite 20 349 3799378

Triple vepput 40 M09 410$

Triple 6wp~~b1 4271 4344 42250

Ammotw-ritpophW to 4201 4124 4040

Amosim-rdop~phlt 40 4270 4106 4231

AM tuo-polpephats 20 404 4244 3794

~eai~mpelppepbuI 400)49 4094

Cee m-pbpbt to- 59

momee eph lto 0 4192

LSO (0 0$) 29 1025

Th WPII

- 51 shy

101Y114 tpeM-fI PEP~tbRP YO

1 ~ ~ gmw 1pc~biofl- 9 Kla4v4h

Upia U04 Copfind am Crehout Stet Rpano at (Ia4

rico t IF t rume6 orth~ Caralto phoophale rocl QAR) vaUN pqU41 to

roopon from cmonetrat4 gsporphophai (CIP) who ort$o4 oil k

was 45j itwas tafertor vb protioo4 oil p war OS Ib 4iffer~c

in rtc reepos to X cod14 oo bo ttrit4 4 4 hvsciag of boil p

~ Pt o r11221 0 tP

c theto the rhimecyllndor of rico tots par to)14M4i1 roeoi~t

ed oil emd PA prior to tho ont of an~robi4 cMioe AA~ oIifoshy

nAte bYpot t taet~d tO fC4sin t~r 4PWden0 Of f Ot(tivshy

ofOWailiJtyno o prefla4 all Put that 4t01etoo 14 tvsIk

of the Ott to prvvld a 014for C4m0 44 mI 1 o4sf

EfftC ftPet141on AIAM-0 V f401td 4 4iv 440 Mtft

Aa torfat VampP f4MWfCi4W04wt0amp to 4eturWlI Ot(Wel~drIC ft

Ot f tM6 the flooded Ott 00 14 04019I Pft0uAw Of gAr~s~lr

pkS$t M40b MP) Tw P1101 Piset Prodwie W-e 10M0di Wr04

(10-1) emW 0aretilp ddw01at4 P WAA firom Rrth M~flRU414~$

wee cowiared with fie Md reWim 44104 proo~fo) foruk oith laWItter

I v te-PR P OW1004 4 4 O Wf ottil OW ellt Oo

Oveiel1 the 40tt dmcruie to effetotww Wtollowui Co fme

PR tpaUIB1I ldoltmo PR (pamwlatr) offr~- ArmeuM) 0 orwi

- 52 -

Effect of N Sourc6 and Water Management on Response of Rice

toe Zn- M Giordano J J Mortvedt OP Engelstad and Greenhouse

Staff Several rotes of CO(14H2)2 and (H )2So4 vith or without ZnO

wore applied to flooded and nonflooded Crowley oil (limed to pH 75)

to determine response of Bluebelle rice to Zn Yields with both N

sources veotrgreator on flooded then on nonflooded soil In the abshy

ence of applied Zn total dry matter production vith CO(NH2)2 was

slightly lower than with (NH)2S04 on flooded soil and considerably

lover on nonflooded soil Concentration of Zn wan higher in straw and

grain of plants roun on flooded than on nonflooded soil Although

concentration of P was unaffected by N source or Zn rate there was

som indication that cranslocation of P from straw to grain may be

depressed in nouflooded rice Concentration of N was lower in straw

grown on flooded than on nonflooded soil due to apparent dilution

thereas both X sources resulted in similar N concentrations in straw

at all rates of N application the N concentration in grain increased

with 0 rAse

feSpongi gf(SM to Chjorospodiostte and Related P Sources--

Si Allen and Greonhoue Staff A greenhouse pot experiment was

couct44d with corn Brown on Hountview silt loam to compare the ofshy

fectlivees of chlorospodiosito (Chlor-l) with concentrated supershy

phosphate (CP) Thomas slag and North Carolina phosphate rock (NC-PR)

Oil-prillad urea-phophato rock (UPI) FeA1JMP 20 7 and monomthyl

phosphate were included in the experiment Based on yield of forage and

uptake of P by tvo crops each of 6-weeks duration the following conshy

stui were dravat

I Chlor-1 was slightly loss effective than CSI Thomas slaS or NC-PR

from which Chlor-l wae prepared

- 53 shy

2 Granular UPR was a poor source of P its effectiveness was greatly

increased by reducing the particle size to -35mesh

3 FeAlNH4P207 was unavailable to the crop

4 Monomethyl phosphate was equivalent toor slightly more effective-

than CSP

Research Indirectly Related to TVA-AID Project

Response of Several Rice Varieties to Zn in Moist or Flooded

Soil--P M Giordano J J Mortvedt and Greenhouse Several varieties

of rice from Mexico and the Dominican Republic currently under investishy

gation in Puerto Rico for adaptation to upland culture were compared with

some established United States varieties with regard to Zn response on

moist and flooded Crowley sil (pH 75) Chontalpa (Mexico) Bluebelle

(Texas) and Starbonnet (Arkansas) were most responsive to applied Zn

Juma (Dominican Republic) intermediate and Sinaloa (Mexico) and Calrose

(California) were the least responsive The Sinaloa varieties (Mexico)

appeared to be best adapted to non-flooded conditions whereas Chontalpa

and Calrose were poorest Concentrations of Zn generally were higher in

plants grown on flooded than moist soil

Pattern of Growth and Zinc Accumulation by Rice--P M Giordano

J J Mortvedt and Greenhouse Staff Rice plants were harvested at weekly

intervals from shortly after emergence through maturity The objective

was to determine the rate of growth and Zn uptake by a Zn responsive varshy

iety (Bluebelle) and a less Zn-responsive variety (Calrose) in the presence

or absence of Zn applied to Crowley sil (pHl 75) Dry matter production

of Calrose was linear with time of growth and of a similar magnitude until

heading with or without applied Zn Bluebelle followed a similar pattern

where Zn was applied However in the absence of applied Zn foliage yield

was reduced markedly

-54

Uptake of Zn was similar for both varieties whenZn was

applied Dry matter production and Zn uptake by the two varieties

also were comparable when Zn was applied However yield of Calrose

was much higher than that of Bluebelle in the absence of applied Zn

while Zn uptake was only slightly higher This suggests that the lesshy

ser responsiveness of Calrose to Zn may be due to more efficient utilishy

zation of Zn There was no indication of a greater demand for Zn durshy

ing reproduction in either variety as was suggested in earlier greenshy

house experiments

Response of Upland Rice to P and Zn--P M Giordano J J

Mortvedt and Greenhouse Staff Several rates of P and Zn were applied

to Crowley sil (limed to pH 75) in factorial combination to determine

whether differences in rice growth under flooded and nonflooded soil

conditions are related to plant nutrition Although straw yields were

slightly higher in nonflooded rice receiving adequate P and Zn grain

yields were higher in the flooded crop increased rates of F andor Zn

did not result in equal yields Except in the highest Zn rate (75 mg)

concentrations of Zn in both straw and grain were higher with flooding

Concentration of P increased with rate of applied P and was higher in

the grain or flooded than upland rice at a comparable P rate In conshy

trast concentrations of N were lower with flooding due in part to dilshy

ution from increased growth

Rice Response to N and P in Flooded and Unflooded Cultures--

G L Terman S E Allen and Greenhouse-Analytical Staff Rates of

N from 250 to 2000 ntpot and P from 0 to 1000 mtpot were applied for

Nato rice grown on Mountview sil and Sango sicl (625 kg of soil per

pot) Market yield response to N and P was obtained Yields of straw

- 55 shy

total yields N uptake and N recovery were higher on unflooded than

on flooded soil cultures Grain yields however were slightly higher

with flooding These results indicate that with adequate applied

nutrients especially of N rice yields without flooding can approach

or even equal those under flooding

Uptake of N P Ca Mg and Zn increased with yield response

to N and P while K uptake decreased on the Mountview soil Concentrations

of N and P increased with applied N and P respectively while concentrations

of other nutrients were diluted in most situations with yield response to N

or P

Results from this experiment show that amouats of N applied in

previous pot experiments for rice have been much too low especially if the

crop was grown to maturity

Response of Corn to S and N i UUASand Urea-S--S E Allen

and Greenhouse Staff Three greenhouse pot experiments were conducted to

measure response to S and N in ulfur coated urea (SCU) urea amonium

sulfate (UAS) and urea -S as well as estimate N losses from surface apshy

plied N sources

In Experiment 260 less than 20 of the S mixed with the soil

was recovered from SCU or urea-S granules by two crops of corn as comshy

pared to 45 or 80 from flowers of S or Na2SO 4 CLop response followed

a similar pattern

In Experiment 260-A N sources were surface applied and alshy

lowed to dry for two weeks before incorporation Into the soil and plantshy

ing Recovery of N by two crops of corn was 77-82 for AN an compared

to 37-70 for urea UAS urea-S and ICU Thus n this experiment loss

of N from urea did not appear to be re~dcud by light S-coatlngn or by Inshy

corporating S or AS in the granules

-S -

I xbprZnSlt a Wtch aU Meyto 0-Ai Wt f9r

higher reermo teOrtOrs cOM reSpWNO i r0100 Of N w

not oaisteontly related to sewe ot N In edl tust 0 ioltiUe Lim

lo in VMuwpped evlmtUTS 48 merind by seirest nte appresOehe

501 for uroa as cwarod to 210 for urea peepha

Rus- or Upse to LoAmIl34I a AriMed bI Earl U

MW NOWlsIIsIr-4 L Toman 5 1 Alln and eesese StNf rio

row on Sawg did (0 tpot) We 1l0l0 Ws feritiud vith 05is

of Npot mixod with the 6011 as aureCA NiAO) 1 Age god At Ures

was also itcluded at rtt t 05 10 end 15 of Upee Theas trealshy

onto were followed 4 wpdrsetago of U s AN wre 4C 10o or at I3n

Weeks toulin up to IS pot

A soil application of 10 pot rosulvod to the maim yield

at 4 weeks Tio4 sad percont prottis t intre raite tncreased rftishy

linearly with U applictalien IeseeItally all at the m iNd wit

the moil w domitrifted after flooding Grail end straw Ilelds vere

highly correlatod with tiliriag and vlh ubers of gralm arl

The results Widicat that 0$ to 10 a of Upot as orea or

NN bsuld be sied with the oil to stilate tiilrir with adshy

ditional 0 topireased later to increase grain lIds mad protia cmshy

tout

DIVISION 54- FERTILIZER TECHNOLOGY AND USE

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-02

792 60L WI W A)49R Pio VOL 37 197)

primS o r OeampAd WU toa Them fl~ w At NOSSe earno maisslea Ia N he mOWamplIO yik ampWd IMe aampWmW OWa Owe wa UMs of KU to 41 Oke ampWiiIamm be dkrnety ewspokawleM(a s8 te camtd wie a eapmoe by TVA pavw ltoi NA poundrmdaka4us vrimeW460 o to ilkidm ofWW (Mtemas MuOwe 1973) TVA mwi bawld on soi ficedims IampWp seg rudwiv s~s0abet ke WNmdoe ON 01 K Is12 NOSW ie fssewnmu Ie I QvaaIi rowp IMA) f9

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DIVISION 8-9-SOIL MINERALOGY

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65

0IL CL OC AMXR PROC VOL 38 1974

)aT1 S4I104 ow Lusanll Tawng isa tall Thai variety known for beingIwo nonshyi s s ) sensitive to photoperiod A split-plot design was used in

S e e these euperimeots with 4 rates of P (I1 22 44 and 88t i V IV k of Pha) applied a main plot treatments and with the OF It sourMes of P as subplot treatments There were two checkS plots in each rmplicate The extra check plot was included to permit the application of fresh TSP standard Jor the

It- ti 06 + i bull fa succeeding crop the p-4me of bi was to permit accurate d awrnwal of the mdual effectiveness of the phosphate

ftinSUbI rock The P fertilioers were broadcast on the mud andthen Worporald In the soil during the last harrowing At

whM N both On ACS indx ampM time of transplanting Immediately before the last harrow61t (4j 5 4 01 P s 3Mm o Vallonal in con n 100 kgha of N as ammonium sulfate and 33 kghaWO Of Spews ampm lIW thaabe rocks do ACS indes of K as polium chloride were applied A total of 40 wa in prepw O do ctih k otent kha of N a ammoniunt sulfate was applied later in twoir P The hew oNed amp wM W for 5 of gw topdrossingp with about 5cm depth of water on the plotsvV I aiOMveffeOctveee Three to six ldayold selings pr hillwW the ACS idex were planted00OWW wia Oft fo an c irNk I p Coen 20 by 20 cm part in straight rows Hand weeding was used

and insecticide were applied for Insect control Grain yieldw was masared by sampling 5 ml of each plot excluding border rows The date of heading in each treatment and theUNiN d pbM W Weks rin tOW USA UMe In Tale yed componnts at hafvel were also recorded

I filM rsperMS esOM kdwdua 1 t ab The average yields of ough (unhulled) rice for botha 84 OW O 8uo 4 Thala TM was a locations are ploutel in PIS 3 for the first crop (1969 wet

owou thRM seaso0) The Veamps yield response was obtained at Klonge (s) W lDtO t Of dMa of1tw W d l R Luang however a 4ute satisfactory yield response was

~Mk ^d TVA UJSD ad Kd UnIveS obtalned to applied P at Bangkhen as wellXUe LaM e R qwrw Ims The sod was do Relative aponomlAe effectiveness values were calculated

VOW (a ksA w edmwL t Poesesm h Vy for these data and am presented In Table 3 The valuesdAY buo if dIe ouh ne Pee wtk a Mlak vow 1009 for th first crop are plotled against ACS index in Fig 41 This Im M i6ti l 4bNd IO a0 O mkarnk for both locatio r relationship was linear for the

11400 ThCpH 0( lb pW IW 01 th UpeiaW so Sanodion location and curtiltnear for KIng Luang The was u i 4A sksamp lMaor nrusio model amparounted for 81 of theAmO$MI Aw jAAsue Swim T1 Snh Wd variation In the AE valu for Bantkhen a square root

Mems a Iw iv fern alh$ sedm haowg dayNW W t he plAL At tdo M tM aso W s as ctminued throufh eltaM t Ofpof -le lse wo am P OeNI VeOpls 1o ealluae tI lon4erm MIdual Offccls

A on W isset i a wse to hsh eapeel of these ooihss t ocks The baagkhon experimnent was letmiaI1DlVemisthis is a w hulu Lo g Tasug ia iasael aft - Msd residual Ves will be pr-Om crok TheseTwod esewm

SWWo

A

lP~U~7 ISIIPe1iuIWN e bsedisssin ian ghth siaoelalbe

984 0 6 O O - M s -s fWPas 11eSft W d Uo al a o

o

S4l~ lIIII I~l I 1f fl

( +

+ + + m + ++++-

++ +(++ + ++++ + ++ ++

- 66 -

ENOIMLSTAD ET AL RESPONSE BY FLOODED RICE TO PHOSPHATE ROCKS VARYING IN CITRATE SOLUBILITY

I I I I j0 I I

BANOKHEN BANGKHEN

pH 56 6 - 0o

TSP

NC

5~ ~ ~ L o 4 - -shy

4 ] - --------shy04

6S

|0 III 2 44 8r 66

I I I

a 1KLONG LUANG

pH 46 z KLONG LUANG

TSP Sc2 NCFL(N)

5 FLIC) J0 TU

oshy

4 ~40shy

3 bull eM0

I - I I I I I

0 II 22 44 88 0 5 10 15 20 IP APPLIED KO HA ABSOLUTE CITRAE SOLUBIITY INDEX

Fig 3-Yield of rough rice at Klong Luang and Bangkhen Rice Fig 4-Relative agronon effectiveness () of P sources ploz-Experiment Stations Thalmand as affected by rate and Source ted against citrate solubity Index for both Thailand field ex

of P applied (crop 1) periment (first crop only)

regression model accounted for 97 of the variation in sumably resulted from crop uptake and reaction with the RAE values at the Klong Luang location soil to form less soluble products Such effects may have

These experiments were continued during the dry season been more important at the lower rates since the two TSP of early 1970 to ascertain the residual effectiveness of the curyes converged at the highest rate of application various sources applied to the first crop No new P was These data from KIong Luang indicate that (i) residual applied except for the fresh TSP standard mentioned effects of all rocks except Mlcwuri were substantial (ii) above rhe experiment otherwise was conducted in a man the relationship between relative agronornic effectiveness ner similar to that followed in the first crop of the phosphate rocks and citrate solubility levels was

The response to both freshly applied ad residual P was largely obscured and (iii) the general superiority of TSP marked at the Klong Luang location and marginal at over phosphate rock in terms of effectiveiss persisted Bangkhen In fact at the latter location the response was through the second crop so small that little can be said regarding residual effectiveshyness The yield data from crop 2 at the Klong Luang DISCUSSION experiment are plotted in Fig 5 Greenhouse and field data presented in this paper show

Relative agronomic effectiveness values (Table 3) were clearly that there are substantial differences among phosshycalculated for the Klong Luang data using both the residual and freshly applied TSP as standards It is of Interest to note that the superiority of TSP over the phosphbte rocks Table 3-Relative agronomic effective values for field experishyments in Thailand persisted through the second crop The main difference in KlowlZmlnql~the residual effects is that with the exception of the MIs- s Crop 1 Crop 21 Crop 1-shysouri rock Ihe marked relationship between citratr-soluble WoiCarolina yl 59 76

phosphate rocks and RAE had largely rds norh) a 64P conltct of th Florida (eqlral is 6969 6

disapipeared In this acidic soil (pHi 46) P would by this I14o 69 63 40 ToonesS 31 65

limo be supplied by Intermediate reaction products In addl Missou 0 o lion to residues of the initial spatlte Ts P o 2 o 0

The TSP applied to the first crop declliv-d slightly In campIafcmWataesr e id ofeuhuloefor 22MA rates of PtColeouattd as aba u tlte td18 kS ratesp dlverage yield tM868 to 22 44

effectiveness relative to the freshly applied ISP This pre- of d s4

A

4

- 67 shy

-SOIL SCL SOC AMER I

KLONG LUANG CROP 2

Si 3

eN

TAPPLIEDKGHA

Fig 5-The residual effectiveness ovarious P sources for crop s compared with freshly applied TSP Klong Luang Rice

Experiment Station Thailand

phate rocks in terms of agronomic effectiveness for flooded

rice Further these differences can be predicted by means of citrate solubility or by the ACS index It appears that

the latter is more appropriate where the content of apatite varies among phospiate rocks The most soluble phosphate rocks approached but did not actually equal TSP in limit-iuig (maximum) yield in these experiments regardless of rate applied This agrees with the results of Ensminger Pearson and Armiger (4) One needs to consider the defi-nite posribility of same yield loss in zhoosing a phosphate

rock over TSP such yield losses must be weighed against the lower price of phosphate rock The explanation for such iosses may involve concentration of soluble P in the soil Khasawneh and Copeland (6) suggest that the growth rate of crop plants is a function of P concentration that can be maintained in the soil solution If P concentration is limiting or inadequate becawe of a lower dissolution rate of phosphate rock the growth iate ard uiiimate yield will be diminished accordingly

The RAE values bascd on yield increases reflect the agronomi effectiveness of these various sources relacve

to the TSP standard however these nould be supple-

mented by an economic analysis before rational choice can

be made The following calculations will provide an estimate of

the rclativ ecooomic effectiveness(REE)

Y t Ps aXpatREE -- 100

vahtercks t sphate or e b i- eor

Price of TSPkg fo

be Price of PRkg P

PROC VOL 38 1974 leO

90r

Wsoshy

0

60-LUSEPHOSPHATE ROCK

00 10 20

PTP PR

Fig 6-Relationship between relaZive effectiveness values (RAE) and the price ratios between TSP and phosphate rock Such a figure can be used in making a choice between these

sources

If REE exceeds 100 in this calculation the phosphate rock would be preferable to TSP

The REE calcuktaaa wre used in preparing an indifshyference curve (Fig 6) wherein RAE values are plotted

against PTsPPpR ratios The cu~rve itself connects those points at which REE equals 100 When exactly on the curve it makes no real economic difference what source is chosen After choosing a suitable price ratio one can then project upward from that ratio knowing the RAI

value (or estimating it from such data as shown in Fig 4 using citrate-soluble P content) one can then choose the source on the basis of both agronomic and economic conshysiderations For example if the price ratio is 25 and the RAE value of the phosphaite rock is greater than 40 the rock phosphate in question would be used However if the RAE value was less than 40 TSP would be a better choice There are indications that if the P in the more soluble phosphate ro~cks (North Carolina north Florida central Forida) is less than half as expensivz as that in TSP these rocks would be feasible altereaives to TSP on soils similar

to thoseused in Thailand This analysis does not take into account the possibility

of lower yields from use of phosphate rock In addition only a portion of the various yield response curves was used in this anlysis ie up to 22 kgha Beyond this

rate yield response was much less pronounced it could be argued that at less than maximum yields TSP would produce a certain yield at lower rates of P than would phosshy

pow ofrock This would especially be true for rates applioa example at Klong Luang 5500 kg of

rice pcr iectare could have been produced with either Ii kg of P as TSP or 44 kg of P as son of the more reacshy

tire phosphate rocks It should be pointed ot however

- 68 shy

(IIKIS amp YOUN( ARIFICIAL WEATIIERING OF OXIDIZED p[ll- IV

that this is the yield level that would show the widest difference such is the advantage of hindsight

Farmers generally prefer granular fertilizers for machine

or hand application This is a disadvantage for the phos-phate rocks which are normally arplied in finely divided form Recently experimental quantities of granular urea-

phosphate rock mixtures have been made by TVA Results of trials with these fertilizers will be reported elsewhere

LITERATURE CITED

1 Armiger W H and Maurice- Fried 1957 The plantavailability of various sources of phosphate rock Soil Sci Soc Amer Proc 21183-188

2 Bengston G W E C Sample and S E Allen 1974 Re-sponso of slash pine seedlings to P sGurces of varying ci-trato solubility Plant Soil (In press)

3 Caro JIt and W Hill 1956 Chard eristics and fer tilizcr value of phosphate rock from different fields J Agr Food Chem 4684-687

4 Ensminger I E R W Peirson and W II Atmiger1967 Effectivencs of rock phosphate as a source of phosshyphurus for plants US Dep Agr ARS Bull 4112S

5 Engelstad 0 P J G Getsinger anid I J Stangel 1972 Tailoring of fertiliers for rice cnnece Valley Author ftyNational Fertilicr Developmnent Center Hull Y-52

6 Khasawnch F E and Jane P Copcland 1971 (otton root growth and uptake of nutrievos relation oif phosph

rus uptake to quantity intensity and buffering capacit) Soil Sci Soc Amer Proc 37250-254

7 Lehr JR and G H McClellan 1972 A revised lIbora tory reactivity scale for evaljativg phosphate rocks for direct application Tennessee Valley Authcrity National Fertilizer Development Center lull Y-43

H Terman G L S EAllen and 0 P Engelstad 1970 Response by paddy cice to ratcs and suurces of appliedphosphorus Agron J63390-394

DIVISION S-9-SOIL MINERALOGY

Artificial Weathering of Oxidized Biotite IV The Inhibitory Effect of Potassium on Dissolution llate

R JGILKES AND R C YOUNG2

ABSTRACT

Rates of dissolution of oxidized biotites in OIM 001M ICI are severely depressed in the presence of IM KCI The amovnts of Al Mg Mn dissolved in the first eytraction are similir to those found without KCI however subsequent extractions remove these elements at 10-20 of the corresponding lICI rates This effect may be due to a decreased rate of vermiculite formation thereby reducing the effective basal area exposed to attack A decrease in dissolution rate with increasing ferric iron content was still apparent in the presence of IM KCI

Additional Index Words X-ray diffraction infrared aborp-

N EARLIER papers of this series the tole of biotite in soils

as a source of both macro and micronutrient elements

has been discussed ((Gilkes Young and Quirk 1972 1973ab) Experiments in artificial weathering uiing as va-

riety of extractants were undertaken to determiie the inlu-

ence of oxidation of octahedrally coordinated iron on the bull release of structural cations to solution The results of this

work demonstated that biotite behaves anomalously with respect to the other common ferromagnesian minerals found in soils Oxidation leads to the development of a high degree of resistance to cation exchange and dissolution Several authors have coiwludcd that decreased rates of K

Contribution from the Dep of Soi Science and Plant Nutri-tion Institute of Agriculture Univ of Western Australia Ned-lands 6009 Western Australia Received 29 Sept 1973 Ap-proved 8 Jan 1974

2 Senior Lecturer in Soil Science and Research Officer respeclively

replacement in electrolytes shown by oxidized biotites are

a result of the inclination of structural hydroxyl adjacent to newly created trivalent iron or vacant octahedral cation sites (Robert and Pedro 1959 Barshad and Kishk 1968) Gilkes et al (1973b) suggested that decreased rates of disshysolution of oxidized biotite in 0001 0t)l 0Af CI may also be due to the presence of inclined hydroxyl In this case a smaller surface area external and exposed intershylayer may be available for attack if K replacement by hyshydrogen ions occurs at a slower rate in oxidized biotites

Gastuche (1963) has shown that significant dissolution ofthe (IIM) biotile face may occur and it is easily demonshystrated that the proportion of exposed (001M) face in weathering biotites depends on the percentage K replaced

Rausell-Colom ct al (1965) have shown that hydrogen ions act in an identical fashion to metal cations in K exshy

change from micas In particular exchange c-f K by hydroshy

gen ions will be terminated or greatly reduced by high levels of K in solution Thus if dissolution of oxidized biotite by

acids is carried out at sufficiently high K levels to prevent vermiculization any differences in dissolution rate that may occur cannot simply be ascribed to differences in rates of K replacement The following results were obtained from such an experiment which unlike the experiment described in Parts I and II (Gilkes et al 1973ab) does not attempt to simulate natuiral - conditions

MATERIAILS AN) M HIiODS Further subsamples of the less than 0 hiotites used in K

excherandbaid disoo tu es (G iles e9n K exchange and acid dissolution studies (Gilkes et al1973ab) were used in these experiments Preparation of sequentiallyoxidized biotites without intermediate vermiculite formation is

Page 21: I70 - United States Agency for International Developmentto ascertan, but tgl.eetad, 1, L,. ("Tailoring of Pertiltiters for ice,'" TVA ulletin Y-52) states that the staft of IOi has

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4I~~~4J 00S4 4410 114w- A44W Wamp ~

6WViso4wb f vfpo w

w0OIA - i f iIS

f4 A 00 1 o4

I1~wo ow4O4-40404f-4 ~

TOM I

Cs VWA1 t lw Vairtile ot P44Y 44c KW MI1

fiat Wm~~JL U Lem~ampuJampAJ Wat IO

~ 941~1 41 ~~~~j~~qt~~8IJ WtS dobu

Table 2

Mttct of 0 Sourco aampW $At On Upt~ks of 0 by Two Varitgtos of Paddy Rice

gr~a 1971

~ MMUampL~ ~L ~ nYLALI~ 11 lemall

I ie

W0 v slit III I) tQo9

KvN 1 17 111 1119

or 444M7

111a

i1$0N ~ It$ 121

1$

x IV ~404 tot Vsr 1 P1 41 w otv 1

- 24 shy

India--The results of four experiments conducted with flooded

transplanted rice in India by the All-India Coordinated Rice Project

Hyderabad are given in table 3 The response to N was excellent the

yield without N being only 41 of those obtained with basal applications

of N as uza With basal applications of SCU the yields were 20 higher

than with basal applications of urea and in the three experiments in

which urea applications were split yields with SCU were 18 higher than

yields with split applications of urea When comparing the average Nshy

response (kamp grainKg N) yields were increased 13 more by SCU than by

basal applications of urea

The data from one experiment with light irrigated rice in India

are given in table 4 yields were relatively low and differences between

N sources or method of application were not significant However yields

with SU tended to be higher than when all urea was applied at planting

but lower than when split applications of urea were applied Again yields

increased more than 13 more with SCU than with basal applications ofwere

ur

In tables 5 and 6 the yields of a short-duration transplanted

rice grown in irrigated light-textured soils at five locations in India

indicate that higher yields were obtained with SCU than with urea when apshy

plied as a basal application Yield increases due to basal N applications

were 502 greater with SCU than with urea However split applications of

resulted in yields equal to those obtained with basal applications ofurea

CU

The yields of direct-seeded upland rice grown at three locations

to India are given in table 7 and the relative yields in table 8 Yields

were low due to drought but good responses were nevertheless obtained for

- 25 -

Table 3

Effect of N Source and Time of Application on Yield of Paddy (Flooded) Rice in India 1972 (Summary of Reported Data from 4 Experiments)

Experimental Number Source Rate Method Yield Relative N-Response

and of of N of Yield Kg Grain

Season Nitrogen kgha Application mtha Kg N

- - - 196 34 -

Urea 120 Basal 573 100 314

11 Urea 120 80 + 40 611 107 345 Rabi SCU 120 Basal 713 124 430

12 - 0 - 202 30 -

Urea 125 Basal 682 100 384

Rabi Urea 125 35 + 20 + 35 + 35 633 95 344 SCU 125 Basal 781 115 463

13- 0 - 168 44

Urea 100 Basal 385 100 217

Kharif Urea 100 30 + 20 + 25 + 25 400 104 232 SCU 100 Basal 462 120 293

14 -

Urea -

125 -

Basal 355 650

55 100

-

236

Rabi SCU 125 Basal 781 120 341

-- 26 -

Table 4

Effect of N Source and Time of Application on Yield of Light Irrigated Rice in India 1972 (Summary of Reported Data From

One Experiment at Pattambi)

Experimental Number Source Rate Method Yield Relative N-Response

and of of N of Yield Kg Grain Season Nitrogen (kgha) Application (mtha) Q) Kg N

38 0 - 204 85 -Rabi Urea 120 Basal 241 100 308

Urea 120 60 + 0 + 30 + 30 267 ill 525 SCU 120 Basal 255 106 425

Table 5

Effect of N Source and Time of Application on Yields of Short-Duration Transplanted lice Variety Grown on Irrigated Light-Textured Soils at 5 Locations in India 1972

(Snmzarized From Reported Data)

Rate Grain Yields (MtHa) Source of N Method of N GrainI of N kgh Application Faizabod Karjat Mandva Pattabi laya Averaje X

- 291 266 211 19 340 260 -

Urea 100 Basal 386 407 361 285 482 3 124 Urea 100 50 + 25 + 25 399 430 434 334 6amp2 4A8 186

SCU 100 Basal 368 468 439 360 572 41 181

Table 6

Effect of I Source end Tlae of ApplIcattoo c RIstave Tle24 of a rt- rat1 T Lsd lice Vasrety Crin o Irrigated L41tshy1 at S Locitite mindi 1972

Rate ____________14_3

Source of X N~tbad of Of X An 1 tat14 1 acr X__T1 4v tatW ttva

- - - all 7i i

95l 119 1 1~ ~~~~~ an iI3lli i1

WRI

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21L1L LW ufU~ vie 114 3 10 106

As 11 i 41 4 smg LAY1 $Of 41)

Tabl I

f~ttwi Ot 0 6wirce 81d At$ a vt1d at flUop4d Rico to Vitjorim (1ITA)All fortitfour to rsodkeet OA lC~OVPr4( 114 5iI 000

W Iotors Ftslanp tospg Irritd for Two thvk Afler flontiw wft rkwa~ Floo4d 191)

- -I-of LWAIM) (IS YJl- fl-----II)

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- 38 -

Table 18

Yild of aemati-370 Rice at Punjab Agricultural Research

Institute in Pakistan in 1969-70 Grown Under

Couditions of Intermittent Flooding

Pate of application

=IL

o 0 67 67 100 100 67 67

100 100 67 67 200 100

Average for Sources

Ntha

AS 260 gres 279

320

Source f5

-

AS AS Ura Urea SCU SCU

Yield

Relative

93 100 115

(M)O

Yield

Increase Yield Due to N

(Ktlha) (mtha)

-212 245 033 274 062 260 048 297 085 315 103 325 112

Yield Increase

Relative

72048 067 100 108 161

(2)

- 39 shy

Short-statured high yielding rice varieties grown extenshy

sively in northern Peru require extremely high rates of conventional

N sources to achieve maximum yields The recovery of applied N is

extremely low due to the use of intermittent flooding This water

management system results in heavy N losses even with properly timed

split applications In search of simpler and more effective methods

of N management eight field experiments were conducted in the region

to evaluate sulfur-coated urea (SCU) an experimental slow-release N

source supplied by the Tennessee Valley Authority Rice yields were

increased an average of 59 more by pretransplant-incorporated SCU than

by urea or ammonium sulfate applied in the same manner SCU produced

excessive vegetative growth which resulted in yield reductions at high

N rates

Regardless of an assumed 48-higher unit N cost in SCU the

overall benefits of pretransplant-incorporated applications of SCU

were favorable since there was a decrease of 40 in the optimum rate

of N and the need for precise timing of application was eliminated

Pakistan--In Pakistan basal applications of AS urea and

SCU to rice grown under conditions of intermittent flooding in 1969-70

(table 18) indicate that SCU is a superior source of N as compared to

urea or AS when all N is applied at or before planting The data also

indicate that a yield response was obtained for P applications but a

comparison of N sources at each level of P indicates that no interaction

between N and P was present so that differences between N sources were

relatively the same at each level of P Yields were increased about 60

more when SCU was applied than when urea was applied Yield increases

with AS were only about 72 of the increase obtained with urea these reshy

sults do not agree with the generally-reported superiority of AS as comshy

pared to urea as a source of N for rice

- 40 -

In 1973 experiments were conducted in Pakistan using both

Basmati-370 and IRRI-6 varieties of rice grown under conditions of

When all N was applied at puddlingintermittent flooding (table 19)

or 12 at puddling and 12 at panicle initiation both AS and SCU were

superior to urea with SCU tending to be the most efficient source

However when N was applied 12 at transplanting and 12 at panicle

initiation SCU was the poorest source of N This would indicate that

the release of N from SCU applied at these times is too slow for optimwn

plant growth

In another experiment in Pakistan in 1973 no differences

in the effectiveness of urea AS or SCU were noted in the yields of

continuously-flooded rice (table 20) Again these results are conshy

sistent with earlier results which indicate no superiority for SCU

when rice is continuously flooded

Nitrogen Studies--Maize

A series of three experiments were conducted by IITA in

armo-Nigeria in 1972-73 comparing AS urea SCU and

CAN (calcium

nium nitrate) as sources of N for maize (table 21) A significant

yield response was obtained for N at each location but no conaistent

differences were noted amaong sources These results are consistent

with results at other locations which have not shown that SCU is a

superior source of N for maize grown over a period of 3 to 4 months

Nitrogen--Wheat

The yields of wheat in Pakistan in 1969-70 (tables 22 and

23) show that yields with SCU) tended to be lower than those with ureaJ

although at one locction where sorghum was grown followilng wheat with

Table 19

Yields of Basmati-370 and IRRI-6 Rice at Punjab Agricultural Experiment Station in Pakistan in 1973 Under

Conditions of Intermittent Flooding

Rate Yield Source of N Time of Yield (Mtha) Increase of N B-370 IRRI-6 Application Basmati-370 IRRI-6 Average (Mtha)

0 0 - 21 353 287 -

SCU 90 150 At Puddling 325 545 435 148

Urea 90 150 At Puddling 309 500 405 118

AS 90 150 At Puddling 324 529 427 140

SCU 90 150 Puddling 372 572 472 185 Panicle Initiation

Urea 90 150 Puddling 335 502 419 132 Panicle Initiation

AS 90 150 Puddling 353 529 441 154 Panicle Initiation

SCU 90 150 After Transplanting 312 562 437 150 Panicle Initiation

Urea 90 150 After Transplanting 340 624 482 195 Panicle Initiation

AS 90 150 After Transplanting 349 583 466 179 Panicle Initiation

All plots received 45 lbs P205acre as single superphosphate

Relative Yield Increase ()

Source of N At Puddling Puddling Panicle Transplant h Panicle

Urea 100 100 100 AS 119 117 92 SCU 125 140 77

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-48

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ht tse balt s Owosiv as that to TwP it rocks WM bo

fmtbt alteruutiv to MSso gotastte to~ Ik lee used to

ThUAIAd

Tht wMl dt gotmtmlaoti wout th possibility

of law Vhld free ww e1 e66001 4 It cooUt be YgWd Sutt

a4 10 0410 SWUSSM yt$4e TOP wUd predWr A r~ftIf fl~W t

1f f ot P the wuld phosphae rck TWOe viWMW efocitill b

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amp4at r per Wforssota Mav two 64eed Wilk elikor It 44 of

P go Mi er 4A bg oftoP aon of tewmrowtni pboophals fwAh

It vwld be polotrd A Wevero wtht Is the jteld level that

W414 gk tko videm dtterem~j o(A 1 the 4~etamp tk~e~t

P11~0 pra~lpj prefer gre4r tuftlter for whlae

of hoaw ppltrstie Mhe to a dloedveaP for The PINSOO rocka

vkth m r II spotted 10 ftewil 4106Me tem

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forgof wee aMW pbsepbots A fths pemhawe evsielew us

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mmfp MW phapa A (CI) sed graewletod pampAtlti arlolatod Pa

asowcs of P tof ttde ro The wreem proucts omre raGther

pemour~a ot P syag besmti andMi as elt ov so gpamwhr

iuipiqffhate(TS) low twseeo Is eftwiltve Is thet

W41 preeme wae oialain ire post-rItoi effriq to Stanlato the

pud6itt of Irto paddle Wee ofsdlseireplastiq

0 49 shy

lbs partially scldiaatede grawilated Ml prodlucts Vere isshy

toiwdiats in 5tftOvttWS54 betwee wroiPi ad TVP NotV5Ymf to

me coo were they mere twoe $a a etfective ao TIP 00 sipifleast

LVSUMI5 at0 efecto wore toun tor thee produteo Timely dtIampWde

FR (-t00 mmoh) Uia amp~rally oar affective than Owe gra8448r FOampprodt

featal twos o 6 aotetire s I

Nowvero it to felt that sfortber field euprtet vth

hese interials Amd ether typs of grometatodl Wter nre wrrautad

hater ceeuwodh that they have me areec poteatlal toi additoG

e tate wAne the sectte as OtawrI sed bovoloen turther

euperimeste vth few reck pboophar s0d with reck pbophat treated

to sehesa citrata selmtliy or to ha csaducted

Metbir sertes of tbme enprtaeats wae c~edtmcted by IITA

to Ut~rta copal TVP AOP APP aed it at see tecastisix (table 14)

No dot lalt sewseltles teh draw tree thee results simouely em pear to tlvdl bsww they do stwgpt tbat forthew work with

MR to werramid so tbme sels

Table 24

LttcttF Swce MaPlate 06 ieldot IM AWaia CoelsANS at IITA (Ugboda ad Apoin ail sorit) aid at Ike (AUaba s5i series)

1973

Plate ot IP Apinu 5 poundebods A1ab

Ocrol 0 Z94 419 M)

Tr ipl ruprphite 20 349 3799378

Triple vepput 40 M09 410$

Triple 6wp~~b1 4271 4344 42250

Ammotw-ritpophW to 4201 4124 4040

Amosim-rdop~phlt 40 4270 4106 4231

AM tuo-polpephats 20 404 4244 3794

~eai~mpelppepbuI 400)49 4094

Cee m-pbpbt to- 59

momee eph lto 0 4192

LSO (0 0$) 29 1025

Th WPII

- 51 shy

101Y114 tpeM-fI PEP~tbRP YO

1 ~ ~ gmw 1pc~biofl- 9 Kla4v4h

Upia U04 Copfind am Crehout Stet Rpano at (Ia4

rico t IF t rume6 orth~ Caralto phoophale rocl QAR) vaUN pqU41 to

roopon from cmonetrat4 gsporphophai (CIP) who ort$o4 oil k

was 45j itwas tafertor vb protioo4 oil p war OS Ib 4iffer~c

in rtc reepos to X cod14 oo bo ttrit4 4 4 hvsciag of boil p

~ Pt o r11221 0 tP

c theto the rhimecyllndor of rico tots par to)14M4i1 roeoi~t

ed oil emd PA prior to tho ont of an~robi4 cMioe AA~ oIifoshy

nAte bYpot t taet~d tO fC4sin t~r 4PWden0 Of f Ot(tivshy

ofOWailiJtyno o prefla4 all Put that 4t01etoo 14 tvsIk

of the Ott to prvvld a 014for C4m0 44 mI 1 o4sf

EfftC ftPet141on AIAM-0 V f401td 4 4iv 440 Mtft

Aa torfat VampP f4MWfCi4W04wt0amp to 4eturWlI Ot(Wel~drIC ft

Ot f tM6 the flooded Ott 00 14 04019I Pft0uAw Of gAr~s~lr

pkS$t M40b MP) Tw P1101 Piset Prodwie W-e 10M0di Wr04

(10-1) emW 0aretilp ddw01at4 P WAA firom Rrth M~flRU414~$

wee cowiared with fie Md reWim 44104 proo~fo) foruk oith laWItter

I v te-PR P OW1004 4 4 O Wf ottil OW ellt Oo

Oveiel1 the 40tt dmcruie to effetotww Wtollowui Co fme

PR tpaUIB1I ldoltmo PR (pamwlatr) offr~- ArmeuM) 0 orwi

- 52 -

Effect of N Sourc6 and Water Management on Response of Rice

toe Zn- M Giordano J J Mortvedt OP Engelstad and Greenhouse

Staff Several rotes of CO(14H2)2 and (H )2So4 vith or without ZnO

wore applied to flooded and nonflooded Crowley oil (limed to pH 75)

to determine response of Bluebelle rice to Zn Yields with both N

sources veotrgreator on flooded then on nonflooded soil In the abshy

ence of applied Zn total dry matter production vith CO(NH2)2 was

slightly lower than with (NH)2S04 on flooded soil and considerably

lover on nonflooded soil Concentration of Zn wan higher in straw and

grain of plants roun on flooded than on nonflooded soil Although

concentration of P was unaffected by N source or Zn rate there was

som indication that cranslocation of P from straw to grain may be

depressed in nouflooded rice Concentration of N was lower in straw

grown on flooded than on nonflooded soil due to apparent dilution

thereas both X sources resulted in similar N concentrations in straw

at all rates of N application the N concentration in grain increased

with 0 rAse

feSpongi gf(SM to Chjorospodiostte and Related P Sources--

Si Allen and Greonhoue Staff A greenhouse pot experiment was

couct44d with corn Brown on Hountview silt loam to compare the ofshy

fectlivees of chlorospodiosito (Chlor-l) with concentrated supershy

phosphate (CP) Thomas slag and North Carolina phosphate rock (NC-PR)

Oil-prillad urea-phophato rock (UPI) FeA1JMP 20 7 and monomthyl

phosphate were included in the experiment Based on yield of forage and

uptake of P by tvo crops each of 6-weeks duration the following conshy

stui were dravat

I Chlor-1 was slightly loss effective than CSI Thomas slaS or NC-PR

from which Chlor-l wae prepared

- 53 shy

2 Granular UPR was a poor source of P its effectiveness was greatly

increased by reducing the particle size to -35mesh

3 FeAlNH4P207 was unavailable to the crop

4 Monomethyl phosphate was equivalent toor slightly more effective-

than CSP

Research Indirectly Related to TVA-AID Project

Response of Several Rice Varieties to Zn in Moist or Flooded

Soil--P M Giordano J J Mortvedt and Greenhouse Several varieties

of rice from Mexico and the Dominican Republic currently under investishy

gation in Puerto Rico for adaptation to upland culture were compared with

some established United States varieties with regard to Zn response on

moist and flooded Crowley sil (pH 75) Chontalpa (Mexico) Bluebelle

(Texas) and Starbonnet (Arkansas) were most responsive to applied Zn

Juma (Dominican Republic) intermediate and Sinaloa (Mexico) and Calrose

(California) were the least responsive The Sinaloa varieties (Mexico)

appeared to be best adapted to non-flooded conditions whereas Chontalpa

and Calrose were poorest Concentrations of Zn generally were higher in

plants grown on flooded than moist soil

Pattern of Growth and Zinc Accumulation by Rice--P M Giordano

J J Mortvedt and Greenhouse Staff Rice plants were harvested at weekly

intervals from shortly after emergence through maturity The objective

was to determine the rate of growth and Zn uptake by a Zn responsive varshy

iety (Bluebelle) and a less Zn-responsive variety (Calrose) in the presence

or absence of Zn applied to Crowley sil (pHl 75) Dry matter production

of Calrose was linear with time of growth and of a similar magnitude until

heading with or without applied Zn Bluebelle followed a similar pattern

where Zn was applied However in the absence of applied Zn foliage yield

was reduced markedly

-54

Uptake of Zn was similar for both varieties whenZn was

applied Dry matter production and Zn uptake by the two varieties

also were comparable when Zn was applied However yield of Calrose

was much higher than that of Bluebelle in the absence of applied Zn

while Zn uptake was only slightly higher This suggests that the lesshy

ser responsiveness of Calrose to Zn may be due to more efficient utilishy

zation of Zn There was no indication of a greater demand for Zn durshy

ing reproduction in either variety as was suggested in earlier greenshy

house experiments

Response of Upland Rice to P and Zn--P M Giordano J J

Mortvedt and Greenhouse Staff Several rates of P and Zn were applied

to Crowley sil (limed to pH 75) in factorial combination to determine

whether differences in rice growth under flooded and nonflooded soil

conditions are related to plant nutrition Although straw yields were

slightly higher in nonflooded rice receiving adequate P and Zn grain

yields were higher in the flooded crop increased rates of F andor Zn

did not result in equal yields Except in the highest Zn rate (75 mg)

concentrations of Zn in both straw and grain were higher with flooding

Concentration of P increased with rate of applied P and was higher in

the grain or flooded than upland rice at a comparable P rate In conshy

trast concentrations of N were lower with flooding due in part to dilshy

ution from increased growth

Rice Response to N and P in Flooded and Unflooded Cultures--

G L Terman S E Allen and Greenhouse-Analytical Staff Rates of

N from 250 to 2000 ntpot and P from 0 to 1000 mtpot were applied for

Nato rice grown on Mountview sil and Sango sicl (625 kg of soil per

pot) Market yield response to N and P was obtained Yields of straw

- 55 shy

total yields N uptake and N recovery were higher on unflooded than

on flooded soil cultures Grain yields however were slightly higher

with flooding These results indicate that with adequate applied

nutrients especially of N rice yields without flooding can approach

or even equal those under flooding

Uptake of N P Ca Mg and Zn increased with yield response

to N and P while K uptake decreased on the Mountview soil Concentrations

of N and P increased with applied N and P respectively while concentrations

of other nutrients were diluted in most situations with yield response to N

or P

Results from this experiment show that amouats of N applied in

previous pot experiments for rice have been much too low especially if the

crop was grown to maturity

Response of Corn to S and N i UUASand Urea-S--S E Allen

and Greenhouse Staff Three greenhouse pot experiments were conducted to

measure response to S and N in ulfur coated urea (SCU) urea amonium

sulfate (UAS) and urea -S as well as estimate N losses from surface apshy

plied N sources

In Experiment 260 less than 20 of the S mixed with the soil

was recovered from SCU or urea-S granules by two crops of corn as comshy

pared to 45 or 80 from flowers of S or Na2SO 4 CLop response followed

a similar pattern

In Experiment 260-A N sources were surface applied and alshy

lowed to dry for two weeks before incorporation Into the soil and plantshy

ing Recovery of N by two crops of corn was 77-82 for AN an compared

to 37-70 for urea UAS urea-S and ICU Thus n this experiment loss

of N from urea did not appear to be re~dcud by light S-coatlngn or by Inshy

corporating S or AS in the granules

-S -

I xbprZnSlt a Wtch aU Meyto 0-Ai Wt f9r

higher reermo teOrtOrs cOM reSpWNO i r0100 Of N w

not oaisteontly related to sewe ot N In edl tust 0 ioltiUe Lim

lo in VMuwpped evlmtUTS 48 merind by seirest nte appresOehe

501 for uroa as cwarod to 210 for urea peepha

Rus- or Upse to LoAmIl34I a AriMed bI Earl U

MW NOWlsIIsIr-4 L Toman 5 1 Alln and eesese StNf rio

row on Sawg did (0 tpot) We 1l0l0 Ws feritiud vith 05is

of Npot mixod with the 6011 as aureCA NiAO) 1 Age god At Ures

was also itcluded at rtt t 05 10 end 15 of Upee Theas trealshy

onto were followed 4 wpdrsetago of U s AN wre 4C 10o or at I3n

Weeks toulin up to IS pot

A soil application of 10 pot rosulvod to the maim yield

at 4 weeks Tio4 sad percont prottis t intre raite tncreased rftishy

linearly with U applictalien IeseeItally all at the m iNd wit

the moil w domitrifted after flooding Grail end straw Ilelds vere

highly correlatod with tiliriag and vlh ubers of gralm arl

The results Widicat that 0$ to 10 a of Upot as orea or

NN bsuld be sied with the oil to stilate tiilrir with adshy

ditional 0 topireased later to increase grain lIds mad protia cmshy

tout

DIVISION 54- FERTILIZER TECHNOLOGY AND USE

N$eumWe of Mt5p4Amomd 1k PindW hswk4PhI fl fRw cW ims we

Jmnwacr VW owm m

a~~00 - 0 6 A-~ -~~ PN 40OMOM X 00 Wolm n moo mot $Pto4I 4l 4 W

1 -0 Is vom omoo ~~o - W1 sfw 4E00-aU

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-n-t -4adf -m W ftf

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i A ~~~~06o ~a A VOW 4 WK-ok rie Ww -0 no 4me

00 to- W 0Nwo ww AO t

-t umi om ftaw-0

- - lh -i N N iiSolf so -ma w vow -mv__M

-~AdAjA- 44 ow 0ma 0MAW a war -mo d0 00 M o WooP 0

0kR N4 a~ow Mf o

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to$w formoop 1 so

Qm0fte Iwo 00 SAtow

a

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I

vt~~ - foa Gom

r-7- tw

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otait m adtoo iMOaiq

sMs aIwO tP- owWIs

mU MW4 0e S w 96 lo ow- CO=

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Is WAV OUw Af 41W 0A

1A 0

1o wI0~ WSW adWOWi

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M~~~~MOt 0f O

040 wd m40 Awowmm

bo^ w

ro a W4

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womb ~mmnt I-VI~ bp

5i irn0 pwm k~ oiuwe OsMn0 Wsw e Wr~m mw6

_______Noon_Iamp__ arn ag bos m W we ap

=ib ad a $4Ws Om ThSU

mod m m406mi 1m towir - m bowI~~~AV UPuiWd a04aup hwu 000sW~11lito -- o ~ImWq mow~gnn w a ho emotwi

4~ 49akduemg6momm ~ do nedOwrnd~ o

ICU wONMOVAON w4wWR - - o 44 O Tha 40 pu4 am

hum 11 is 4111 s - sg am VW f wq 4WuM dhCi m ehamv alpso 0

-w No memwiauu so-s 1141 -f oer wwn malow Wufmmm inM UCd m I a to dip 90

- ~~ w emw euIv oflme em ~ ed~faiOeWMOWleA fC~ dim~e4s- 1um00 s uwos w siwp 3 0V es wiiu d um w

aram ad as~6 ma pgt -oI A -$-d r00= m PW Of

ff~~~- am diwda Vs Wow at 4g eltpowm woo OI teeMA AMamdmOMisan A d1 Tm WNW m4 uwwemm mmmM

Aa It mom A I b 0 ~isi ~amp~V5on m ad No wwho 1 $IV Am t t~i mmOwm a- S Am im spwwmft KV-b Osiswvn wogie

opoOw suf No~ Ow MW MCI pt~bi asiwhNd bl-d muim of woo w NN

toI4 0 06d 00 wo A Md N WILSAl DuIKWION oo A Nw U am ONq ep

ow VAN pmw amp4 li a4 WdUb p vw sopwaft a-ftgw -ee theptd OW 6 - a

at MW em matshyW M offm of4 W twampwmwausoo wo asdm65m Auamp Ahbwu in 4ih asTal ON~ al oem IN Maie dmAd A a own did ofe w17 I inM mimman Ofd ofimruwf gas Pius di aMe Kwe auw a dow iNPOOIN tmo a SO$SO~4W

MWaSM BT ALI Mh USIA UW MlO RMC i WOW TW A-~ka ad 1 1 li laiiII111I

0 -6 -1 -- - -- Ie-- - -shyis

101 ~

alm~ sas ~~~ ms a a~

ase appuadmen 44 ea ad semk Who pm4WWS lowftsIU wo WOMO dobowl ICUSJW h

A Poad KU apbos as dw sileft in as a aWhps k asIU__

pro alfp al 0 WN Is obaml~ of th es Wls pouvy Ofts oeWMed N

$ae fapree ulesaseup IfIwotohaffe St

40WilinAn 06 kw Ma ho 00 e IW aftakrw splerefAnhffsb m esmem

I$Ow Ip ampMI pasi 1ead eu an Toud 2l

Widj 6vi of V46 745WI KU waso-W im Wow 0 is610SWAOMMwasa to t

VAp 1Mampd KV ppu~s dw whaim $i a a los Al w W

Ib Milvo urns of OWe d- musA as h~ s a IuIow 8 1 ue ip

-Wlidswf of 4 ofatsIW5vsS d M M5 i RSa pm~daps In ampup 1Powworw rue hevi A b

el eas goileN ruseW4 wo duffeeme bWOM isttouwi

14 gnp40 woSalrw 11ylo amreu Mwb Isevlow roosmN~ahIt s 60 W ~tsmAIM L n ~ ~~ ~

MM I PWrawA = rMla yowIeM oa

eUW as ymlh OW by IONamph avWlbl N The mubsr 1MM Pude M~ IsA aemOWeld

IWOes A rspeas Owed ai udlWwease

por bre

wals rIs O touprua KU=plaINamppNOMeses a

W UWhk 0 ASOoml ft A poWsdvutA adesae of amr Wns ai A 0r- 1ampdd Oehs IuRawy NO Pue podllosWewwe gmak asmpnle by dMiss is amle OWN pet -W yid I MuC)ad ampAn (WiplaeT16s mOW aOW aNo fhr ft ymIed------ obealud w3t 0 OW 40IsA a VM bpR ofthW d saw ns m aI efes R 24 ad 7

e 1 d

Ii

Iw NO ~sp 44I0 so

~ ~ I $4U tml

Tile 4-00dw x uiampOW74u 0qee of

_____k _ _ shy

~ - 56I 5

-f

irenY w -a

Tiles I sed I thm Au do sel oeppled upaoIks WIM0 0da ispI amd us Ou s 106 kg

h Eaap 8n 14 sMsa of abw~greuad PU Pau WW 1 u itb IUKho 0aaphelem s 60 Otarlmmh At ~ 0sU Ishiseoo Cook oiA N uiplasu mAasslaly abess A leel

v doese a WKWye Is ks Nha m 6 sa4to dafo aONmuw The appee swm Wsssof adde N4 alalaed by vuMb ifaa W C Was sekilumganSro Is

bs eabI wish as aVWWa uwewy nap (f5s)f ad Mashes reaMeY valaes of 48 0 S414 CWm

owdb imto US Wh s vs sf 3I mld 54S fro 2 aMd 3) A A

valves a hevwae u Iar Walh basl oswas dhe uwpatr bshava of

tb~msusasl appkausu of ofta sede s have aoweN

TOW opl taoe for AieweeW 4OsmWMbas Op peas As Tabl 4 sling sob Os awowully eom grams Piel level Thes oeulam Ma sed as IM

-02

792 60L WI W A)49R Pio VOL 37 197)

primS o r OeampAd WU toa Them fl~ w At NOSSe earno maisslea Ia N he mOWamplIO yik ampWd IMe aampWmW OWa Owe wa UMs of KU to 41 Oke ampWiiIamm be dkrnety ewspokawleM(a s8 te camtd wie a eapmoe by TVA pavw ltoi NA poundrmdaka4us vrimeW460 o to ilkidm ofWW (Mtemas MuOwe 1973) TVA mwi bawld on soi ficedims IampWp seg rudwiv s~s0abet ke WNmdoe ON 01 K Is12 NOSW ie fssewnmu Ie I QvaaIi rowp IMA) f9

)amp m lodk byO voebmsaIS8OpeaWfrats 11 OWNmi a I a W idisod 0 81 Now 111 nindat Wm fysmpseaamp (If tsO tUmtI IsM $P shoroV4mmo knflkvnf (foOdme nuw ae Ow OImstwe in SM pnmm8 af tXm 10 114PIS kequoian wo Mpfii

SC~po umd spop~o VWt alm 4emWal 1 4ink PCmirsra M 1 ad AI 14bmms

1MM Ww Even to doe shw wisht b-o -Wamp Ekb fed rbaimpal of14~ Am Smpound oS mv fAaMda

MGMe -M4 Wg kmuwadM 1Wr wih SCV4 Psmuck Wff It dlL Wm 1W led 0 1 oo teeA of aiwaisme aweeoid h

1Kach Vt V amp4W ILK t)sa 10 Nareps vm This ndY ub thee hbow apiptomuasa of gulfu-aw~sd of Cup lP~~tamsl wi(i

Woeo of woo or mlm Wmiot InIasem~Wsy (heede 6Am 0 F- ad PAicv IfM tsoPm 9W famp kw~is 04eet The r4 ggm I ampbpiIs OnwAu 4nvmkstm v PAraem A4fshy

e W d inSIWfh sil $ad doke IaefitV twoer) 1 Te to theo owie effu so booJ imik WOi 100 N

-d

Is re4aled uIwq~e~w Aueee atofurnw di Capsnm ptopeatls is a oommm eiws to 100 tom of 04404man d CtdUW 4M Anw K~a do Aamp apowee WPUaN powu eel H pae iaaa thAi SCUI isWW owr hmem ISsuppl N to the li ieee F A IM1 Nampa Obo~amie m

41MB ~ ~ m ~ ~0 0-- 0 140 The ffsemn of food Nn else9~e(Ud~ ~ ~ ~~ WooksaS eAWw pjed of ho~raw of IU effadam vfdva oft xhj0I 13iAl

DIVISION 8-9-SOIL MINERALOGY

Amorphomw CeetIup en XmWra Ssrfmls

L C koits Am~ 0 tmmkaAf

ommp A faieiaAMTRACT skiwe lo nW ampM sm wi4h

Walo by a onMm I dmivid hseidm6Wlk W~edesie s

peuiieles as is s e wpwigstee eded his S -em -om 0641 h4 hisW1mWOWb~ bfem peess Wimm kv Iee

Pa~~~eakr4awiS SeUeeiNaiA WOW 14e

PWWWW t HW f hea~I~~~~~a 0th

kog Ii ampI b 1111h1atAmOem aid itsaere~m-aelmoeug toolPe aal 111W mWa Wisg ag so~ ti~Wo booviot65k Th eme Iua 1111411uiwon it es 01000 AW~CWS ~muiseeteqqsheer21111 ionev

oO00 llb K0 ibad~ ~~ doj 140WI s o mimdW um

WLIMmAmMVL 1

lill mi oHow al of a be 1974oyais4gamm wsoc wwo

rdy i of OMAN toblind id sh os 00 IN bei m us salqs m kid Vw 1 a0Msw WFW isms waf e eeiWei he-4~~e gsa dulsi

os 0aMW ofmu WA l aduWs~Ib rowuvvl3maIpm s

CaO~OP aw AlNomI 4ornomd to9 IS is -l O SI g4he rpidyThus whim m dowu bWa 0 m m- ei u

d m M 0bmSaImu M-1 ofM6 h Intun to 7I

aiba maush WAesshwn~u9dSg a osusLwpI ~ v m

M PolsdAvoWdw Ons pugm~ low iwLW m We

of~U -a~ mo uNo

0401ts of 40

A e mun5d m i vvamp sa s ow bftIS i sa omdIs a w

edi1 hswopmo an ag am Iw anom erlwaPASneooie bnwoM po

o ~ do=lr 3s fluACWoSM Owaa VolM Ain b 400b adW g o as amob ofrMOWS A oo eWmaa ow $wofdi60 ow - ema

-v K Vcon l ap ad md ld KU lbs PoabumwA od w to domi a bembe 0b lt $014 i ampmomONo

4st diwemmSod i 6o pa P)ameakiksm4 m 04M t 1iV vs 0606 o IS ft dopsss of q madl w I10000014 t 44hs

arbs awasm 00 iztv Am-~~~i u5~ms ashu is byw

e~ihs diu~wsm ~phid W A0)ad Lobe d mi-~-- 1) 14 hald

bob~wh do is poPbe~mueus l to aVE tumad 40at iai ka as m

bdisc shmm Ammmd a Sm ofd~~~~~d~A ~ a~m olWshmo

OWNSrilgf ms as

Um~~srTmws~of 4 A ad to wy mis itm voW

IN~flA4T ampMww IV Kwo~t M1CI I POWMAIS amV VARw d01M11 W V

e~~Pum-p -f AOACoe~mfmmdso isedp Am PApmi sk adw Wsk m~ o P4 m

- omlos r umIWO1in pw

lie Uvplist i piw S p wsmoW N of t as so in~tabo 440 o rodgAsect M4Ammd meM ii INAq10ed~ Pib mdWWeiW 1w -w emit TU UFm 6AV 0W A fIN 00~ lb 0PANNO 4 drp OW~It~Oi Ofme _____f WACMW0IN WMVsol~lmO ft SNAO 40 do1Si - m Md y e b ii m

of of~phaow tw bmsdf toamplboe

AjflsutomW C1D-pCTP AD mSmZLT op 1 m ow ts Wdm of P om M

IaM 0t sdw a wn a8duws i ofV -w Mm P16I4 TWO a ewu i an

ov4mnk wsi 9 Mxfeu~i am emwm ismi0wmd fq W No ~~ - f mug Aitowe eutlkowbmTV is

amppowftdmi TiM 0 Tie OAA mo p)a Mwomoi dOn4m A)w

MW 0 604 0M mm yaM 01MWOfdi to tA0 M OOAW uinw OSOb

ap is~e I the ampo A A Mwof ~Do toit op aenu w~ifiOimem~ MAN ampW)

ItsAO se Y lieowawo u~w pkow-W1b pwf on a C Nohkw is f 0o1 s do~omW C mmU4

owud6moeft 4 Obind PINa~e

~4~~wreu -A---I ad

fit~~~~O 114 4 t I mMsmm m~

im ^aim4 Nomod 06maw ee Aist em moom a rA No fmiEo of emit

~ -0

65

0IL CL OC AMXR PROC VOL 38 1974

)aT1 S4I104 ow Lusanll Tawng isa tall Thai variety known for beingIwo nonshyi s s ) sensitive to photoperiod A split-plot design was used in

S e e these euperimeots with 4 rates of P (I1 22 44 and 88t i V IV k of Pha) applied a main plot treatments and with the OF It sourMes of P as subplot treatments There were two checkS plots in each rmplicate The extra check plot was included to permit the application of fresh TSP standard Jor the

It- ti 06 + i bull fa succeeding crop the p-4me of bi was to permit accurate d awrnwal of the mdual effectiveness of the phosphate

ftinSUbI rock The P fertilioers were broadcast on the mud andthen Worporald In the soil during the last harrowing At

whM N both On ACS indx ampM time of transplanting Immediately before the last harrow61t (4j 5 4 01 P s 3Mm o Vallonal in con n 100 kgha of N as ammonium sulfate and 33 kghaWO Of Spews ampm lIW thaabe rocks do ACS indes of K as polium chloride were applied A total of 40 wa in prepw O do ctih k otent kha of N a ammoniunt sulfate was applied later in twoir P The hew oNed amp wM W for 5 of gw topdrossingp with about 5cm depth of water on the plotsvV I aiOMveffeOctveee Three to six ldayold selings pr hillwW the ACS idex were planted00OWW wia Oft fo an c irNk I p Coen 20 by 20 cm part in straight rows Hand weeding was used

and insecticide were applied for Insect control Grain yieldw was masared by sampling 5 ml of each plot excluding border rows The date of heading in each treatment and theUNiN d pbM W Weks rin tOW USA UMe In Tale yed componnts at hafvel were also recorded

I filM rsperMS esOM kdwdua 1 t ab The average yields of ough (unhulled) rice for botha 84 OW O 8uo 4 Thala TM was a locations are ploutel in PIS 3 for the first crop (1969 wet

owou thRM seaso0) The Veamps yield response was obtained at Klonge (s) W lDtO t Of dMa of1tw W d l R Luang however a 4ute satisfactory yield response was

~Mk ^d TVA UJSD ad Kd UnIveS obtalned to applied P at Bangkhen as wellXUe LaM e R qwrw Ims The sod was do Relative aponomlAe effectiveness values were calculated

VOW (a ksA w edmwL t Poesesm h Vy for these data and am presented In Table 3 The valuesdAY buo if dIe ouh ne Pee wtk a Mlak vow 1009 for th first crop are plotled against ACS index in Fig 41 This Im M i6ti l 4bNd IO a0 O mkarnk for both locatio r relationship was linear for the

11400 ThCpH 0( lb pW IW 01 th UpeiaW so Sanodion location and curtiltnear for KIng Luang The was u i 4A sksamp lMaor nrusio model amparounted for 81 of theAmO$MI Aw jAAsue Swim T1 Snh Wd variation In the AE valu for Bantkhen a square root

Mems a Iw iv fern alh$ sedm haowg dayNW W t he plAL At tdo M tM aso W s as ctminued throufh eltaM t Ofpof -le lse wo am P OeNI VeOpls 1o ealluae tI lon4erm MIdual Offccls

A on W isset i a wse to hsh eapeel of these ooihss t ocks The baagkhon experimnent was letmiaI1DlVemisthis is a w hulu Lo g Tasug ia iasael aft - Msd residual Ves will be pr-Om crok TheseTwod esewm

SWWo

A

lP~U~7 ISIIPe1iuIWN e bsedisssin ian ghth siaoelalbe

984 0 6 O O - M s -s fWPas 11eSft W d Uo al a o

o

S4l~ lIIII I~l I 1f fl

( +

+ + + m + ++++-

++ +(++ + ++++ + ++ ++

- 66 -

ENOIMLSTAD ET AL RESPONSE BY FLOODED RICE TO PHOSPHATE ROCKS VARYING IN CITRATE SOLUBILITY

I I I I j0 I I

BANOKHEN BANGKHEN

pH 56 6 - 0o

TSP

NC

5~ ~ ~ L o 4 - -shy

4 ] - --------shy04

6S

|0 III 2 44 8r 66

I I I

a 1KLONG LUANG

pH 46 z KLONG LUANG

TSP Sc2 NCFL(N)

5 FLIC) J0 TU

oshy

4 ~40shy

3 bull eM0

I - I I I I I

0 II 22 44 88 0 5 10 15 20 IP APPLIED KO HA ABSOLUTE CITRAE SOLUBIITY INDEX

Fig 3-Yield of rough rice at Klong Luang and Bangkhen Rice Fig 4-Relative agronon effectiveness () of P sources ploz-Experiment Stations Thalmand as affected by rate and Source ted against citrate solubity Index for both Thailand field ex

of P applied (crop 1) periment (first crop only)

regression model accounted for 97 of the variation in sumably resulted from crop uptake and reaction with the RAE values at the Klong Luang location soil to form less soluble products Such effects may have

These experiments were continued during the dry season been more important at the lower rates since the two TSP of early 1970 to ascertain the residual effectiveness of the curyes converged at the highest rate of application various sources applied to the first crop No new P was These data from KIong Luang indicate that (i) residual applied except for the fresh TSP standard mentioned effects of all rocks except Mlcwuri were substantial (ii) above rhe experiment otherwise was conducted in a man the relationship between relative agronornic effectiveness ner similar to that followed in the first crop of the phosphate rocks and citrate solubility levels was

The response to both freshly applied ad residual P was largely obscured and (iii) the general superiority of TSP marked at the Klong Luang location and marginal at over phosphate rock in terms of effectiveiss persisted Bangkhen In fact at the latter location the response was through the second crop so small that little can be said regarding residual effectiveshyness The yield data from crop 2 at the Klong Luang DISCUSSION experiment are plotted in Fig 5 Greenhouse and field data presented in this paper show

Relative agronomic effectiveness values (Table 3) were clearly that there are substantial differences among phosshycalculated for the Klong Luang data using both the residual and freshly applied TSP as standards It is of Interest to note that the superiority of TSP over the phosphbte rocks Table 3-Relative agronomic effective values for field experishyments in Thailand persisted through the second crop The main difference in KlowlZmlnql~the residual effects is that with the exception of the MIs- s Crop 1 Crop 21 Crop 1-shysouri rock Ihe marked relationship between citratr-soluble WoiCarolina yl 59 76

phosphate rocks and RAE had largely rds norh) a 64P conltct of th Florida (eqlral is 6969 6

disapipeared In this acidic soil (pHi 46) P would by this I14o 69 63 40 ToonesS 31 65

limo be supplied by Intermediate reaction products In addl Missou 0 o lion to residues of the initial spatlte Ts P o 2 o 0

The TSP applied to the first crop declliv-d slightly In campIafcmWataesr e id ofeuhuloefor 22MA rates of PtColeouattd as aba u tlte td18 kS ratesp dlverage yield tM868 to 22 44

effectiveness relative to the freshly applied ISP This pre- of d s4

A

4

- 67 shy

-SOIL SCL SOC AMER I

KLONG LUANG CROP 2

Si 3

eN

TAPPLIEDKGHA

Fig 5-The residual effectiveness ovarious P sources for crop s compared with freshly applied TSP Klong Luang Rice

Experiment Station Thailand

phate rocks in terms of agronomic effectiveness for flooded

rice Further these differences can be predicted by means of citrate solubility or by the ACS index It appears that

the latter is more appropriate where the content of apatite varies among phospiate rocks The most soluble phosphate rocks approached but did not actually equal TSP in limit-iuig (maximum) yield in these experiments regardless of rate applied This agrees with the results of Ensminger Pearson and Armiger (4) One needs to consider the defi-nite posribility of same yield loss in zhoosing a phosphate

rock over TSP such yield losses must be weighed against the lower price of phosphate rock The explanation for such iosses may involve concentration of soluble P in the soil Khasawneh and Copeland (6) suggest that the growth rate of crop plants is a function of P concentration that can be maintained in the soil solution If P concentration is limiting or inadequate becawe of a lower dissolution rate of phosphate rock the growth iate ard uiiimate yield will be diminished accordingly

The RAE values bascd on yield increases reflect the agronomi effectiveness of these various sources relacve

to the TSP standard however these nould be supple-

mented by an economic analysis before rational choice can

be made The following calculations will provide an estimate of

the rclativ ecooomic effectiveness(REE)

Y t Ps aXpatREE -- 100

vahtercks t sphate or e b i- eor

Price of TSPkg fo

be Price of PRkg P

PROC VOL 38 1974 leO

90r

Wsoshy

0

60-LUSEPHOSPHATE ROCK

00 10 20

PTP PR

Fig 6-Relationship between relaZive effectiveness values (RAE) and the price ratios between TSP and phosphate rock Such a figure can be used in making a choice between these

sources

If REE exceeds 100 in this calculation the phosphate rock would be preferable to TSP

The REE calcuktaaa wre used in preparing an indifshyference curve (Fig 6) wherein RAE values are plotted

against PTsPPpR ratios The cu~rve itself connects those points at which REE equals 100 When exactly on the curve it makes no real economic difference what source is chosen After choosing a suitable price ratio one can then project upward from that ratio knowing the RAI

value (or estimating it from such data as shown in Fig 4 using citrate-soluble P content) one can then choose the source on the basis of both agronomic and economic conshysiderations For example if the price ratio is 25 and the RAE value of the phosphaite rock is greater than 40 the rock phosphate in question would be used However if the RAE value was less than 40 TSP would be a better choice There are indications that if the P in the more soluble phosphate ro~cks (North Carolina north Florida central Forida) is less than half as expensivz as that in TSP these rocks would be feasible altereaives to TSP on soils similar

to thoseused in Thailand This analysis does not take into account the possibility

of lower yields from use of phosphate rock In addition only a portion of the various yield response curves was used in this anlysis ie up to 22 kgha Beyond this

rate yield response was much less pronounced it could be argued that at less than maximum yields TSP would produce a certain yield at lower rates of P than would phosshy

pow ofrock This would especially be true for rates applioa example at Klong Luang 5500 kg of

rice pcr iectare could have been produced with either Ii kg of P as TSP or 44 kg of P as son of the more reacshy

tire phosphate rocks It should be pointed ot however

- 68 shy

(IIKIS amp YOUN( ARIFICIAL WEATIIERING OF OXIDIZED p[ll- IV

that this is the yield level that would show the widest difference such is the advantage of hindsight

Farmers generally prefer granular fertilizers for machine

or hand application This is a disadvantage for the phos-phate rocks which are normally arplied in finely divided form Recently experimental quantities of granular urea-

phosphate rock mixtures have been made by TVA Results of trials with these fertilizers will be reported elsewhere

LITERATURE CITED

1 Armiger W H and Maurice- Fried 1957 The plantavailability of various sources of phosphate rock Soil Sci Soc Amer Proc 21183-188

2 Bengston G W E C Sample and S E Allen 1974 Re-sponso of slash pine seedlings to P sGurces of varying ci-trato solubility Plant Soil (In press)

3 Caro JIt and W Hill 1956 Chard eristics and fer tilizcr value of phosphate rock from different fields J Agr Food Chem 4684-687

4 Ensminger I E R W Peirson and W II Atmiger1967 Effectivencs of rock phosphate as a source of phosshyphurus for plants US Dep Agr ARS Bull 4112S

5 Engelstad 0 P J G Getsinger anid I J Stangel 1972 Tailoring of fertiliers for rice cnnece Valley Author ftyNational Fertilicr Developmnent Center Hull Y-52

6 Khasawnch F E and Jane P Copcland 1971 (otton root growth and uptake of nutrievos relation oif phosph

rus uptake to quantity intensity and buffering capacit) Soil Sci Soc Amer Proc 37250-254

7 Lehr JR and G H McClellan 1972 A revised lIbora tory reactivity scale for evaljativg phosphate rocks for direct application Tennessee Valley Authcrity National Fertilizer Development Center lull Y-43

H Terman G L S EAllen and 0 P Engelstad 1970 Response by paddy cice to ratcs and suurces of appliedphosphorus Agron J63390-394

DIVISION S-9-SOIL MINERALOGY

Artificial Weathering of Oxidized Biotite IV The Inhibitory Effect of Potassium on Dissolution llate

R JGILKES AND R C YOUNG2

ABSTRACT

Rates of dissolution of oxidized biotites in OIM 001M ICI are severely depressed in the presence of IM KCI The amovnts of Al Mg Mn dissolved in the first eytraction are similir to those found without KCI however subsequent extractions remove these elements at 10-20 of the corresponding lICI rates This effect may be due to a decreased rate of vermiculite formation thereby reducing the effective basal area exposed to attack A decrease in dissolution rate with increasing ferric iron content was still apparent in the presence of IM KCI

Additional Index Words X-ray diffraction infrared aborp-

N EARLIER papers of this series the tole of biotite in soils

as a source of both macro and micronutrient elements

has been discussed ((Gilkes Young and Quirk 1972 1973ab) Experiments in artificial weathering uiing as va-

riety of extractants were undertaken to determiie the inlu-

ence of oxidation of octahedrally coordinated iron on the bull release of structural cations to solution The results of this

work demonstated that biotite behaves anomalously with respect to the other common ferromagnesian minerals found in soils Oxidation leads to the development of a high degree of resistance to cation exchange and dissolution Several authors have coiwludcd that decreased rates of K

Contribution from the Dep of Soi Science and Plant Nutri-tion Institute of Agriculture Univ of Western Australia Ned-lands 6009 Western Australia Received 29 Sept 1973 Ap-proved 8 Jan 1974

2 Senior Lecturer in Soil Science and Research Officer respeclively

replacement in electrolytes shown by oxidized biotites are

a result of the inclination of structural hydroxyl adjacent to newly created trivalent iron or vacant octahedral cation sites (Robert and Pedro 1959 Barshad and Kishk 1968) Gilkes et al (1973b) suggested that decreased rates of disshysolution of oxidized biotite in 0001 0t)l 0Af CI may also be due to the presence of inclined hydroxyl In this case a smaller surface area external and exposed intershylayer may be available for attack if K replacement by hyshydrogen ions occurs at a slower rate in oxidized biotites

Gastuche (1963) has shown that significant dissolution ofthe (IIM) biotile face may occur and it is easily demonshystrated that the proportion of exposed (001M) face in weathering biotites depends on the percentage K replaced

Rausell-Colom ct al (1965) have shown that hydrogen ions act in an identical fashion to metal cations in K exshy

change from micas In particular exchange c-f K by hydroshy

gen ions will be terminated or greatly reduced by high levels of K in solution Thus if dissolution of oxidized biotite by

acids is carried out at sufficiently high K levels to prevent vermiculization any differences in dissolution rate that may occur cannot simply be ascribed to differences in rates of K replacement The following results were obtained from such an experiment which unlike the experiment described in Parts I and II (Gilkes et al 1973ab) does not attempt to simulate natuiral - conditions

MATERIAILS AN) M HIiODS Further subsamples of the less than 0 hiotites used in K

excherandbaid disoo tu es (G iles e9n K exchange and acid dissolution studies (Gilkes et al1973ab) were used in these experiments Preparation of sequentiallyoxidized biotites without intermediate vermiculite formation is

Page 22: I70 - United States Agency for International Developmentto ascertan, but tgl.eetad, 1, L,. ("Tailoring of Pertiltiters for ice,'" TVA ulletin Y-52) states that the staft of IOi has

0uI 4044~Me ~ ~ N4

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fiat Wm~~JL U Lem~ampuJampAJ Wat IO

~ 941~1 41 ~~~~j~~qt~~8IJ WtS dobu

Table 2

Mttct of 0 Sourco aampW $At On Upt~ks of 0 by Two Varitgtos of Paddy Rice

gr~a 1971

~ MMUampL~ ~L ~ nYLALI~ 11 lemall

I ie

W0 v slit III I) tQo9

KvN 1 17 111 1119

or 444M7

111a

i1$0N ~ It$ 121

1$

x IV ~404 tot Vsr 1 P1 41 w otv 1

- 24 shy

India--The results of four experiments conducted with flooded

transplanted rice in India by the All-India Coordinated Rice Project

Hyderabad are given in table 3 The response to N was excellent the

yield without N being only 41 of those obtained with basal applications

of N as uza With basal applications of SCU the yields were 20 higher

than with basal applications of urea and in the three experiments in

which urea applications were split yields with SCU were 18 higher than

yields with split applications of urea When comparing the average Nshy

response (kamp grainKg N) yields were increased 13 more by SCU than by

basal applications of urea

The data from one experiment with light irrigated rice in India

are given in table 4 yields were relatively low and differences between

N sources or method of application were not significant However yields

with SU tended to be higher than when all urea was applied at planting

but lower than when split applications of urea were applied Again yields

increased more than 13 more with SCU than with basal applications ofwere

ur

In tables 5 and 6 the yields of a short-duration transplanted

rice grown in irrigated light-textured soils at five locations in India

indicate that higher yields were obtained with SCU than with urea when apshy

plied as a basal application Yield increases due to basal N applications

were 502 greater with SCU than with urea However split applications of

resulted in yields equal to those obtained with basal applications ofurea

CU

The yields of direct-seeded upland rice grown at three locations

to India are given in table 7 and the relative yields in table 8 Yields

were low due to drought but good responses were nevertheless obtained for

- 25 -

Table 3

Effect of N Source and Time of Application on Yield of Paddy (Flooded) Rice in India 1972 (Summary of Reported Data from 4 Experiments)

Experimental Number Source Rate Method Yield Relative N-Response

and of of N of Yield Kg Grain

Season Nitrogen kgha Application mtha Kg N

- - - 196 34 -

Urea 120 Basal 573 100 314

11 Urea 120 80 + 40 611 107 345 Rabi SCU 120 Basal 713 124 430

12 - 0 - 202 30 -

Urea 125 Basal 682 100 384

Rabi Urea 125 35 + 20 + 35 + 35 633 95 344 SCU 125 Basal 781 115 463

13- 0 - 168 44

Urea 100 Basal 385 100 217

Kharif Urea 100 30 + 20 + 25 + 25 400 104 232 SCU 100 Basal 462 120 293

14 -

Urea -

125 -

Basal 355 650

55 100

-

236

Rabi SCU 125 Basal 781 120 341

-- 26 -

Table 4

Effect of N Source and Time of Application on Yield of Light Irrigated Rice in India 1972 (Summary of Reported Data From

One Experiment at Pattambi)

Experimental Number Source Rate Method Yield Relative N-Response

and of of N of Yield Kg Grain Season Nitrogen (kgha) Application (mtha) Q) Kg N

38 0 - 204 85 -Rabi Urea 120 Basal 241 100 308

Urea 120 60 + 0 + 30 + 30 267 ill 525 SCU 120 Basal 255 106 425

Table 5

Effect of N Source and Time of Application on Yields of Short-Duration Transplanted lice Variety Grown on Irrigated Light-Textured Soils at 5 Locations in India 1972

(Snmzarized From Reported Data)

Rate Grain Yields (MtHa) Source of N Method of N GrainI of N kgh Application Faizabod Karjat Mandva Pattabi laya Averaje X

- 291 266 211 19 340 260 -

Urea 100 Basal 386 407 361 285 482 3 124 Urea 100 50 + 25 + 25 399 430 434 334 6amp2 4A8 186

SCU 100 Basal 368 468 439 360 572 41 181

Table 6

Effect of I Source end Tlae of ApplIcattoo c RIstave Tle24 of a rt- rat1 T Lsd lice Vasrety Crin o Irrigated L41tshy1 at S Locitite mindi 1972

Rate ____________14_3

Source of X N~tbad of Of X An 1 tat14 1 acr X__T1 4v tatW ttva

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Tabl I

f~ttwi Ot 0 6wirce 81d At$ a vt1d at flUop4d Rico to Vitjorim (1ITA)All fortitfour to rsodkeet OA lC~OVPr4( 114 5iI 000

W Iotors Ftslanp tospg Irritd for Two thvk Afler flontiw wft rkwa~ Floo4d 191)

- -I-of LWAIM) (IS YJl- fl-----II)

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- 38 -

Table 18

Yild of aemati-370 Rice at Punjab Agricultural Research

Institute in Pakistan in 1969-70 Grown Under

Couditions of Intermittent Flooding

Pate of application

=IL

o 0 67 67 100 100 67 67

100 100 67 67 200 100

Average for Sources

Ntha

AS 260 gres 279

320

Source f5

-

AS AS Ura Urea SCU SCU

Yield

Relative

93 100 115

(M)O

Yield

Increase Yield Due to N

(Ktlha) (mtha)

-212 245 033 274 062 260 048 297 085 315 103 325 112

Yield Increase

Relative

72048 067 100 108 161

(2)

- 39 shy

Short-statured high yielding rice varieties grown extenshy

sively in northern Peru require extremely high rates of conventional

N sources to achieve maximum yields The recovery of applied N is

extremely low due to the use of intermittent flooding This water

management system results in heavy N losses even with properly timed

split applications In search of simpler and more effective methods

of N management eight field experiments were conducted in the region

to evaluate sulfur-coated urea (SCU) an experimental slow-release N

source supplied by the Tennessee Valley Authority Rice yields were

increased an average of 59 more by pretransplant-incorporated SCU than

by urea or ammonium sulfate applied in the same manner SCU produced

excessive vegetative growth which resulted in yield reductions at high

N rates

Regardless of an assumed 48-higher unit N cost in SCU the

overall benefits of pretransplant-incorporated applications of SCU

were favorable since there was a decrease of 40 in the optimum rate

of N and the need for precise timing of application was eliminated

Pakistan--In Pakistan basal applications of AS urea and

SCU to rice grown under conditions of intermittent flooding in 1969-70

(table 18) indicate that SCU is a superior source of N as compared to

urea or AS when all N is applied at or before planting The data also

indicate that a yield response was obtained for P applications but a

comparison of N sources at each level of P indicates that no interaction

between N and P was present so that differences between N sources were

relatively the same at each level of P Yields were increased about 60

more when SCU was applied than when urea was applied Yield increases

with AS were only about 72 of the increase obtained with urea these reshy

sults do not agree with the generally-reported superiority of AS as comshy

pared to urea as a source of N for rice

- 40 -

In 1973 experiments were conducted in Pakistan using both

Basmati-370 and IRRI-6 varieties of rice grown under conditions of

When all N was applied at puddlingintermittent flooding (table 19)

or 12 at puddling and 12 at panicle initiation both AS and SCU were

superior to urea with SCU tending to be the most efficient source

However when N was applied 12 at transplanting and 12 at panicle

initiation SCU was the poorest source of N This would indicate that

the release of N from SCU applied at these times is too slow for optimwn

plant growth

In another experiment in Pakistan in 1973 no differences

in the effectiveness of urea AS or SCU were noted in the yields of

continuously-flooded rice (table 20) Again these results are conshy

sistent with earlier results which indicate no superiority for SCU

when rice is continuously flooded

Nitrogen Studies--Maize

A series of three experiments were conducted by IITA in

armo-Nigeria in 1972-73 comparing AS urea SCU and

CAN (calcium

nium nitrate) as sources of N for maize (table 21) A significant

yield response was obtained for N at each location but no conaistent

differences were noted amaong sources These results are consistent

with results at other locations which have not shown that SCU is a

superior source of N for maize grown over a period of 3 to 4 months

Nitrogen--Wheat

The yields of wheat in Pakistan in 1969-70 (tables 22 and

23) show that yields with SCU) tended to be lower than those with ureaJ

although at one locction where sorghum was grown followilng wheat with

Table 19

Yields of Basmati-370 and IRRI-6 Rice at Punjab Agricultural Experiment Station in Pakistan in 1973 Under

Conditions of Intermittent Flooding

Rate Yield Source of N Time of Yield (Mtha) Increase of N B-370 IRRI-6 Application Basmati-370 IRRI-6 Average (Mtha)

0 0 - 21 353 287 -

SCU 90 150 At Puddling 325 545 435 148

Urea 90 150 At Puddling 309 500 405 118

AS 90 150 At Puddling 324 529 427 140

SCU 90 150 Puddling 372 572 472 185 Panicle Initiation

Urea 90 150 Puddling 335 502 419 132 Panicle Initiation

AS 90 150 Puddling 353 529 441 154 Panicle Initiation

SCU 90 150 After Transplanting 312 562 437 150 Panicle Initiation

Urea 90 150 After Transplanting 340 624 482 195 Panicle Initiation

AS 90 150 After Transplanting 349 583 466 179 Panicle Initiation

All plots received 45 lbs P205acre as single superphosphate

Relative Yield Increase ()

Source of N At Puddling Puddling Panicle Transplant h Panicle

Urea 100 100 100 AS 119 117 92 SCU 125 140 77

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mmfp MW phapa A (CI) sed graewletod pampAtlti arlolatod Pa

asowcs of P tof ttde ro The wreem proucts omre raGther

pemour~a ot P syag besmti andMi as elt ov so gpamwhr

iuipiqffhate(TS) low twseeo Is eftwiltve Is thet

W41 preeme wae oialain ire post-rItoi effriq to Stanlato the

pud6itt of Irto paddle Wee ofsdlseireplastiq

0 49 shy

lbs partially scldiaatede grawilated Ml prodlucts Vere isshy

toiwdiats in 5tftOvttWS54 betwee wroiPi ad TVP NotV5Ymf to

me coo were they mere twoe $a a etfective ao TIP 00 sipifleast

LVSUMI5 at0 efecto wore toun tor thee produteo Timely dtIampWde

FR (-t00 mmoh) Uia amp~rally oar affective than Owe gra8448r FOampprodt

featal twos o 6 aotetire s I

Nowvero it to felt that sfortber field euprtet vth

hese interials Amd ether typs of grometatodl Wter nre wrrautad

hater ceeuwodh that they have me areec poteatlal toi additoG

e tate wAne the sectte as OtawrI sed bovoloen turther

euperimeste vth few reck pboophar s0d with reck pbophat treated

to sehesa citrata selmtliy or to ha csaducted

Metbir sertes of tbme enprtaeats wae c~edtmcted by IITA

to Ut~rta copal TVP AOP APP aed it at see tecastisix (table 14)

No dot lalt sewseltles teh draw tree thee results simouely em pear to tlvdl bsww they do stwgpt tbat forthew work with

MR to werramid so tbme sels

Table 24

LttcttF Swce MaPlate 06 ieldot IM AWaia CoelsANS at IITA (Ugboda ad Apoin ail sorit) aid at Ike (AUaba s5i series)

1973

Plate ot IP Apinu 5 poundebods A1ab

Ocrol 0 Z94 419 M)

Tr ipl ruprphite 20 349 3799378

Triple vepput 40 M09 410$

Triple 6wp~~b1 4271 4344 42250

Ammotw-ritpophW to 4201 4124 4040

Amosim-rdop~phlt 40 4270 4106 4231

AM tuo-polpephats 20 404 4244 3794

~eai~mpelppepbuI 400)49 4094

Cee m-pbpbt to- 59

momee eph lto 0 4192

LSO (0 0$) 29 1025

Th WPII

- 51 shy

101Y114 tpeM-fI PEP~tbRP YO

1 ~ ~ gmw 1pc~biofl- 9 Kla4v4h

Upia U04 Copfind am Crehout Stet Rpano at (Ia4

rico t IF t rume6 orth~ Caralto phoophale rocl QAR) vaUN pqU41 to

roopon from cmonetrat4 gsporphophai (CIP) who ort$o4 oil k

was 45j itwas tafertor vb protioo4 oil p war OS Ib 4iffer~c

in rtc reepos to X cod14 oo bo ttrit4 4 4 hvsciag of boil p

~ Pt o r11221 0 tP

c theto the rhimecyllndor of rico tots par to)14M4i1 roeoi~t

ed oil emd PA prior to tho ont of an~robi4 cMioe AA~ oIifoshy

nAte bYpot t taet~d tO fC4sin t~r 4PWden0 Of f Ot(tivshy

ofOWailiJtyno o prefla4 all Put that 4t01etoo 14 tvsIk

of the Ott to prvvld a 014for C4m0 44 mI 1 o4sf

EfftC ftPet141on AIAM-0 V f401td 4 4iv 440 Mtft

Aa torfat VampP f4MWfCi4W04wt0amp to 4eturWlI Ot(Wel~drIC ft

Ot f tM6 the flooded Ott 00 14 04019I Pft0uAw Of gAr~s~lr

pkS$t M40b MP) Tw P1101 Piset Prodwie W-e 10M0di Wr04

(10-1) emW 0aretilp ddw01at4 P WAA firom Rrth M~flRU414~$

wee cowiared with fie Md reWim 44104 proo~fo) foruk oith laWItter

I v te-PR P OW1004 4 4 O Wf ottil OW ellt Oo

Oveiel1 the 40tt dmcruie to effetotww Wtollowui Co fme

PR tpaUIB1I ldoltmo PR (pamwlatr) offr~- ArmeuM) 0 orwi

- 52 -

Effect of N Sourc6 and Water Management on Response of Rice

toe Zn- M Giordano J J Mortvedt OP Engelstad and Greenhouse

Staff Several rotes of CO(14H2)2 and (H )2So4 vith or without ZnO

wore applied to flooded and nonflooded Crowley oil (limed to pH 75)

to determine response of Bluebelle rice to Zn Yields with both N

sources veotrgreator on flooded then on nonflooded soil In the abshy

ence of applied Zn total dry matter production vith CO(NH2)2 was

slightly lower than with (NH)2S04 on flooded soil and considerably

lover on nonflooded soil Concentration of Zn wan higher in straw and

grain of plants roun on flooded than on nonflooded soil Although

concentration of P was unaffected by N source or Zn rate there was

som indication that cranslocation of P from straw to grain may be

depressed in nouflooded rice Concentration of N was lower in straw

grown on flooded than on nonflooded soil due to apparent dilution

thereas both X sources resulted in similar N concentrations in straw

at all rates of N application the N concentration in grain increased

with 0 rAse

feSpongi gf(SM to Chjorospodiostte and Related P Sources--

Si Allen and Greonhoue Staff A greenhouse pot experiment was

couct44d with corn Brown on Hountview silt loam to compare the ofshy

fectlivees of chlorospodiosito (Chlor-l) with concentrated supershy

phosphate (CP) Thomas slag and North Carolina phosphate rock (NC-PR)

Oil-prillad urea-phophato rock (UPI) FeA1JMP 20 7 and monomthyl

phosphate were included in the experiment Based on yield of forage and

uptake of P by tvo crops each of 6-weeks duration the following conshy

stui were dravat

I Chlor-1 was slightly loss effective than CSI Thomas slaS or NC-PR

from which Chlor-l wae prepared

- 53 shy

2 Granular UPR was a poor source of P its effectiveness was greatly

increased by reducing the particle size to -35mesh

3 FeAlNH4P207 was unavailable to the crop

4 Monomethyl phosphate was equivalent toor slightly more effective-

than CSP

Research Indirectly Related to TVA-AID Project

Response of Several Rice Varieties to Zn in Moist or Flooded

Soil--P M Giordano J J Mortvedt and Greenhouse Several varieties

of rice from Mexico and the Dominican Republic currently under investishy

gation in Puerto Rico for adaptation to upland culture were compared with

some established United States varieties with regard to Zn response on

moist and flooded Crowley sil (pH 75) Chontalpa (Mexico) Bluebelle

(Texas) and Starbonnet (Arkansas) were most responsive to applied Zn

Juma (Dominican Republic) intermediate and Sinaloa (Mexico) and Calrose

(California) were the least responsive The Sinaloa varieties (Mexico)

appeared to be best adapted to non-flooded conditions whereas Chontalpa

and Calrose were poorest Concentrations of Zn generally were higher in

plants grown on flooded than moist soil

Pattern of Growth and Zinc Accumulation by Rice--P M Giordano

J J Mortvedt and Greenhouse Staff Rice plants were harvested at weekly

intervals from shortly after emergence through maturity The objective

was to determine the rate of growth and Zn uptake by a Zn responsive varshy

iety (Bluebelle) and a less Zn-responsive variety (Calrose) in the presence

or absence of Zn applied to Crowley sil (pHl 75) Dry matter production

of Calrose was linear with time of growth and of a similar magnitude until

heading with or without applied Zn Bluebelle followed a similar pattern

where Zn was applied However in the absence of applied Zn foliage yield

was reduced markedly

-54

Uptake of Zn was similar for both varieties whenZn was

applied Dry matter production and Zn uptake by the two varieties

also were comparable when Zn was applied However yield of Calrose

was much higher than that of Bluebelle in the absence of applied Zn

while Zn uptake was only slightly higher This suggests that the lesshy

ser responsiveness of Calrose to Zn may be due to more efficient utilishy

zation of Zn There was no indication of a greater demand for Zn durshy

ing reproduction in either variety as was suggested in earlier greenshy

house experiments

Response of Upland Rice to P and Zn--P M Giordano J J

Mortvedt and Greenhouse Staff Several rates of P and Zn were applied

to Crowley sil (limed to pH 75) in factorial combination to determine

whether differences in rice growth under flooded and nonflooded soil

conditions are related to plant nutrition Although straw yields were

slightly higher in nonflooded rice receiving adequate P and Zn grain

yields were higher in the flooded crop increased rates of F andor Zn

did not result in equal yields Except in the highest Zn rate (75 mg)

concentrations of Zn in both straw and grain were higher with flooding

Concentration of P increased with rate of applied P and was higher in

the grain or flooded than upland rice at a comparable P rate In conshy

trast concentrations of N were lower with flooding due in part to dilshy

ution from increased growth

Rice Response to N and P in Flooded and Unflooded Cultures--

G L Terman S E Allen and Greenhouse-Analytical Staff Rates of

N from 250 to 2000 ntpot and P from 0 to 1000 mtpot were applied for

Nato rice grown on Mountview sil and Sango sicl (625 kg of soil per

pot) Market yield response to N and P was obtained Yields of straw

- 55 shy

total yields N uptake and N recovery were higher on unflooded than

on flooded soil cultures Grain yields however were slightly higher

with flooding These results indicate that with adequate applied

nutrients especially of N rice yields without flooding can approach

or even equal those under flooding

Uptake of N P Ca Mg and Zn increased with yield response

to N and P while K uptake decreased on the Mountview soil Concentrations

of N and P increased with applied N and P respectively while concentrations

of other nutrients were diluted in most situations with yield response to N

or P

Results from this experiment show that amouats of N applied in

previous pot experiments for rice have been much too low especially if the

crop was grown to maturity

Response of Corn to S and N i UUASand Urea-S--S E Allen

and Greenhouse Staff Three greenhouse pot experiments were conducted to

measure response to S and N in ulfur coated urea (SCU) urea amonium

sulfate (UAS) and urea -S as well as estimate N losses from surface apshy

plied N sources

In Experiment 260 less than 20 of the S mixed with the soil

was recovered from SCU or urea-S granules by two crops of corn as comshy

pared to 45 or 80 from flowers of S or Na2SO 4 CLop response followed

a similar pattern

In Experiment 260-A N sources were surface applied and alshy

lowed to dry for two weeks before incorporation Into the soil and plantshy

ing Recovery of N by two crops of corn was 77-82 for AN an compared

to 37-70 for urea UAS urea-S and ICU Thus n this experiment loss

of N from urea did not appear to be re~dcud by light S-coatlngn or by Inshy

corporating S or AS in the granules

-S -

I xbprZnSlt a Wtch aU Meyto 0-Ai Wt f9r

higher reermo teOrtOrs cOM reSpWNO i r0100 Of N w

not oaisteontly related to sewe ot N In edl tust 0 ioltiUe Lim

lo in VMuwpped evlmtUTS 48 merind by seirest nte appresOehe

501 for uroa as cwarod to 210 for urea peepha

Rus- or Upse to LoAmIl34I a AriMed bI Earl U

MW NOWlsIIsIr-4 L Toman 5 1 Alln and eesese StNf rio

row on Sawg did (0 tpot) We 1l0l0 Ws feritiud vith 05is

of Npot mixod with the 6011 as aureCA NiAO) 1 Age god At Ures

was also itcluded at rtt t 05 10 end 15 of Upee Theas trealshy

onto were followed 4 wpdrsetago of U s AN wre 4C 10o or at I3n

Weeks toulin up to IS pot

A soil application of 10 pot rosulvod to the maim yield

at 4 weeks Tio4 sad percont prottis t intre raite tncreased rftishy

linearly with U applictalien IeseeItally all at the m iNd wit

the moil w domitrifted after flooding Grail end straw Ilelds vere

highly correlatod with tiliriag and vlh ubers of gralm arl

The results Widicat that 0$ to 10 a of Upot as orea or

NN bsuld be sied with the oil to stilate tiilrir with adshy

ditional 0 topireased later to increase grain lIds mad protia cmshy

tout

DIVISION 54- FERTILIZER TECHNOLOGY AND USE

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v doese a WKWye Is ks Nha m 6 sa4to dafo aONmuw The appee swm Wsssof adde N4 alalaed by vuMb ifaa W C Was sekilumganSro Is

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valves a hevwae u Iar Walh basl oswas dhe uwpatr bshava of

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TOW opl taoe for AieweeW 4OsmWMbas Op peas As Tabl 4 sling sob Os awowully eom grams Piel level Thes oeulam Ma sed as IM

-02

792 60L WI W A)49R Pio VOL 37 197)

primS o r OeampAd WU toa Them fl~ w At NOSSe earno maisslea Ia N he mOWamplIO yik ampWd IMe aampWmW OWa Owe wa UMs of KU to 41 Oke ampWiiIamm be dkrnety ewspokawleM(a s8 te camtd wie a eapmoe by TVA pavw ltoi NA poundrmdaka4us vrimeW460 o to ilkidm ofWW (Mtemas MuOwe 1973) TVA mwi bawld on soi ficedims IampWp seg rudwiv s~s0abet ke WNmdoe ON 01 K Is12 NOSW ie fssewnmu Ie I QvaaIi rowp IMA) f9

)amp m lodk byO voebmsaIS8OpeaWfrats 11 OWNmi a I a W idisod 0 81 Now 111 nindat Wm fysmpseaamp (If tsO tUmtI IsM $P shoroV4mmo knflkvnf (foOdme nuw ae Ow OImstwe in SM pnmm8 af tXm 10 114PIS kequoian wo Mpfii

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DIVISION 8-9-SOIL MINERALOGY

Amorphomw CeetIup en XmWra Ssrfmls

L C koits Am~ 0 tmmkaAf

ommp A faieiaAMTRACT skiwe lo nW ampM sm wi4h

Walo by a onMm I dmivid hseidm6Wlk W~edesie s

peuiieles as is s e wpwigstee eded his S -em -om 0641 h4 hisW1mWOWb~ bfem peess Wimm kv Iee

Pa~~~eakr4awiS SeUeeiNaiA WOW 14e

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os 0aMW ofmu WA l aduWs~Ib rowuvvl3maIpm s

CaO~OP aw AlNomI 4ornomd to9 IS is -l O SI g4he rpidyThus whim m dowu bWa 0 m m- ei u

d m M 0bmSaImu M-1 ofM6 h Intun to 7I

aiba maush WAesshwn~u9dSg a osusLwpI ~ v m

M PolsdAvoWdw Ons pugm~ low iwLW m We

of~U -a~ mo uNo

0401ts of 40

A e mun5d m i vvamp sa s ow bftIS i sa omdIs a w

edi1 hswopmo an ag am Iw anom erlwaPASneooie bnwoM po

o ~ do=lr 3s fluACWoSM Owaa VolM Ain b 400b adW g o as amob ofrMOWS A oo eWmaa ow $wofdi60 ow - ema

-v K Vcon l ap ad md ld KU lbs PoabumwA od w to domi a bembe 0b lt $014 i ampmomONo

4st diwemmSod i 6o pa P)ameakiksm4 m 04M t 1iV vs 0606 o IS ft dopsss of q madl w I10000014 t 44hs

arbs awasm 00 iztv Am-~~~i u5~ms ashu is byw

e~ihs diu~wsm ~phid W A0)ad Lobe d mi-~-- 1) 14 hald

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bdisc shmm Ammmd a Sm ofd~~~~~d~A ~ a~m olWshmo

OWNSrilgf ms as

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e~~Pum-p -f AOACoe~mfmmdso isedp Am PApmi sk adw Wsk m~ o P4 m

- omlos r umIWO1in pw

lie Uvplist i piw S p wsmoW N of t as so in~tabo 440 o rodgAsect M4Ammd meM ii INAq10ed~ Pib mdWWeiW 1w -w emit TU UFm 6AV 0W A fIN 00~ lb 0PANNO 4 drp OW~It~Oi Ofme _____f WACMW0IN WMVsol~lmO ft SNAO 40 do1Si - m Md y e b ii m

of of~phaow tw bmsdf toamplboe

AjflsutomW C1D-pCTP AD mSmZLT op 1 m ow ts Wdm of P om M

IaM 0t sdw a wn a8duws i ofV -w Mm P16I4 TWO a ewu i an

ov4mnk wsi 9 Mxfeu~i am emwm ismi0wmd fq W No ~~ - f mug Aitowe eutlkowbmTV is

amppowftdmi TiM 0 Tie OAA mo p)a Mwomoi dOn4m A)w

MW 0 604 0M mm yaM 01MWOfdi to tA0 M OOAW uinw OSOb

ap is~e I the ampo A A Mwof ~Do toit op aenu w~ifiOimem~ MAN ampW)

ItsAO se Y lieowawo u~w pkow-W1b pwf on a C Nohkw is f 0o1 s do~omW C mmU4

owud6moeft 4 Obind PINa~e

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im ^aim4 Nomod 06maw ee Aist em moom a rA No fmiEo of emit

~ -0

65

0IL CL OC AMXR PROC VOL 38 1974

)aT1 S4I104 ow Lusanll Tawng isa tall Thai variety known for beingIwo nonshyi s s ) sensitive to photoperiod A split-plot design was used in

S e e these euperimeots with 4 rates of P (I1 22 44 and 88t i V IV k of Pha) applied a main plot treatments and with the OF It sourMes of P as subplot treatments There were two checkS plots in each rmplicate The extra check plot was included to permit the application of fresh TSP standard Jor the

It- ti 06 + i bull fa succeeding crop the p-4me of bi was to permit accurate d awrnwal of the mdual effectiveness of the phosphate

ftinSUbI rock The P fertilioers were broadcast on the mud andthen Worporald In the soil during the last harrowing At

whM N both On ACS indx ampM time of transplanting Immediately before the last harrow61t (4j 5 4 01 P s 3Mm o Vallonal in con n 100 kgha of N as ammonium sulfate and 33 kghaWO Of Spews ampm lIW thaabe rocks do ACS indes of K as polium chloride were applied A total of 40 wa in prepw O do ctih k otent kha of N a ammoniunt sulfate was applied later in twoir P The hew oNed amp wM W for 5 of gw topdrossingp with about 5cm depth of water on the plotsvV I aiOMveffeOctveee Three to six ldayold selings pr hillwW the ACS idex were planted00OWW wia Oft fo an c irNk I p Coen 20 by 20 cm part in straight rows Hand weeding was used

and insecticide were applied for Insect control Grain yieldw was masared by sampling 5 ml of each plot excluding border rows The date of heading in each treatment and theUNiN d pbM W Weks rin tOW USA UMe In Tale yed componnts at hafvel were also recorded

I filM rsperMS esOM kdwdua 1 t ab The average yields of ough (unhulled) rice for botha 84 OW O 8uo 4 Thala TM was a locations are ploutel in PIS 3 for the first crop (1969 wet

owou thRM seaso0) The Veamps yield response was obtained at Klonge (s) W lDtO t Of dMa of1tw W d l R Luang however a 4ute satisfactory yield response was

~Mk ^d TVA UJSD ad Kd UnIveS obtalned to applied P at Bangkhen as wellXUe LaM e R qwrw Ims The sod was do Relative aponomlAe effectiveness values were calculated

VOW (a ksA w edmwL t Poesesm h Vy for these data and am presented In Table 3 The valuesdAY buo if dIe ouh ne Pee wtk a Mlak vow 1009 for th first crop are plotled against ACS index in Fig 41 This Im M i6ti l 4bNd IO a0 O mkarnk for both locatio r relationship was linear for the

11400 ThCpH 0( lb pW IW 01 th UpeiaW so Sanodion location and curtiltnear for KIng Luang The was u i 4A sksamp lMaor nrusio model amparounted for 81 of theAmO$MI Aw jAAsue Swim T1 Snh Wd variation In the AE valu for Bantkhen a square root

Mems a Iw iv fern alh$ sedm haowg dayNW W t he plAL At tdo M tM aso W s as ctminued throufh eltaM t Ofpof -le lse wo am P OeNI VeOpls 1o ealluae tI lon4erm MIdual Offccls

A on W isset i a wse to hsh eapeel of these ooihss t ocks The baagkhon experimnent was letmiaI1DlVemisthis is a w hulu Lo g Tasug ia iasael aft - Msd residual Ves will be pr-Om crok TheseTwod esewm

SWWo

A

lP~U~7 ISIIPe1iuIWN e bsedisssin ian ghth siaoelalbe

984 0 6 O O - M s -s fWPas 11eSft W d Uo al a o

o

S4l~ lIIII I~l I 1f fl

( +

+ + + m + ++++-

++ +(++ + ++++ + ++ ++

- 66 -

ENOIMLSTAD ET AL RESPONSE BY FLOODED RICE TO PHOSPHATE ROCKS VARYING IN CITRATE SOLUBILITY

I I I I j0 I I

BANOKHEN BANGKHEN

pH 56 6 - 0o

TSP

NC

5~ ~ ~ L o 4 - -shy

4 ] - --------shy04

6S

|0 III 2 44 8r 66

I I I

a 1KLONG LUANG

pH 46 z KLONG LUANG

TSP Sc2 NCFL(N)

5 FLIC) J0 TU

oshy

4 ~40shy

3 bull eM0

I - I I I I I

0 II 22 44 88 0 5 10 15 20 IP APPLIED KO HA ABSOLUTE CITRAE SOLUBIITY INDEX

Fig 3-Yield of rough rice at Klong Luang and Bangkhen Rice Fig 4-Relative agronon effectiveness () of P sources ploz-Experiment Stations Thalmand as affected by rate and Source ted against citrate solubity Index for both Thailand field ex

of P applied (crop 1) periment (first crop only)

regression model accounted for 97 of the variation in sumably resulted from crop uptake and reaction with the RAE values at the Klong Luang location soil to form less soluble products Such effects may have

These experiments were continued during the dry season been more important at the lower rates since the two TSP of early 1970 to ascertain the residual effectiveness of the curyes converged at the highest rate of application various sources applied to the first crop No new P was These data from KIong Luang indicate that (i) residual applied except for the fresh TSP standard mentioned effects of all rocks except Mlcwuri were substantial (ii) above rhe experiment otherwise was conducted in a man the relationship between relative agronornic effectiveness ner similar to that followed in the first crop of the phosphate rocks and citrate solubility levels was

The response to both freshly applied ad residual P was largely obscured and (iii) the general superiority of TSP marked at the Klong Luang location and marginal at over phosphate rock in terms of effectiveiss persisted Bangkhen In fact at the latter location the response was through the second crop so small that little can be said regarding residual effectiveshyness The yield data from crop 2 at the Klong Luang DISCUSSION experiment are plotted in Fig 5 Greenhouse and field data presented in this paper show

Relative agronomic effectiveness values (Table 3) were clearly that there are substantial differences among phosshycalculated for the Klong Luang data using both the residual and freshly applied TSP as standards It is of Interest to note that the superiority of TSP over the phosphbte rocks Table 3-Relative agronomic effective values for field experishyments in Thailand persisted through the second crop The main difference in KlowlZmlnql~the residual effects is that with the exception of the MIs- s Crop 1 Crop 21 Crop 1-shysouri rock Ihe marked relationship between citratr-soluble WoiCarolina yl 59 76

phosphate rocks and RAE had largely rds norh) a 64P conltct of th Florida (eqlral is 6969 6

disapipeared In this acidic soil (pHi 46) P would by this I14o 69 63 40 ToonesS 31 65

limo be supplied by Intermediate reaction products In addl Missou 0 o lion to residues of the initial spatlte Ts P o 2 o 0

The TSP applied to the first crop declliv-d slightly In campIafcmWataesr e id ofeuhuloefor 22MA rates of PtColeouattd as aba u tlte td18 kS ratesp dlverage yield tM868 to 22 44

effectiveness relative to the freshly applied ISP This pre- of d s4

A

4

- 67 shy

-SOIL SCL SOC AMER I

KLONG LUANG CROP 2

Si 3

eN

TAPPLIEDKGHA

Fig 5-The residual effectiveness ovarious P sources for crop s compared with freshly applied TSP Klong Luang Rice

Experiment Station Thailand

phate rocks in terms of agronomic effectiveness for flooded

rice Further these differences can be predicted by means of citrate solubility or by the ACS index It appears that

the latter is more appropriate where the content of apatite varies among phospiate rocks The most soluble phosphate rocks approached but did not actually equal TSP in limit-iuig (maximum) yield in these experiments regardless of rate applied This agrees with the results of Ensminger Pearson and Armiger (4) One needs to consider the defi-nite posribility of same yield loss in zhoosing a phosphate

rock over TSP such yield losses must be weighed against the lower price of phosphate rock The explanation for such iosses may involve concentration of soluble P in the soil Khasawneh and Copeland (6) suggest that the growth rate of crop plants is a function of P concentration that can be maintained in the soil solution If P concentration is limiting or inadequate becawe of a lower dissolution rate of phosphate rock the growth iate ard uiiimate yield will be diminished accordingly

The RAE values bascd on yield increases reflect the agronomi effectiveness of these various sources relacve

to the TSP standard however these nould be supple-

mented by an economic analysis before rational choice can

be made The following calculations will provide an estimate of

the rclativ ecooomic effectiveness(REE)

Y t Ps aXpatREE -- 100

vahtercks t sphate or e b i- eor

Price of TSPkg fo

be Price of PRkg P

PROC VOL 38 1974 leO

90r

Wsoshy

0

60-LUSEPHOSPHATE ROCK

00 10 20

PTP PR

Fig 6-Relationship between relaZive effectiveness values (RAE) and the price ratios between TSP and phosphate rock Such a figure can be used in making a choice between these

sources

If REE exceeds 100 in this calculation the phosphate rock would be preferable to TSP

The REE calcuktaaa wre used in preparing an indifshyference curve (Fig 6) wherein RAE values are plotted

against PTsPPpR ratios The cu~rve itself connects those points at which REE equals 100 When exactly on the curve it makes no real economic difference what source is chosen After choosing a suitable price ratio one can then project upward from that ratio knowing the RAI

value (or estimating it from such data as shown in Fig 4 using citrate-soluble P content) one can then choose the source on the basis of both agronomic and economic conshysiderations For example if the price ratio is 25 and the RAE value of the phosphaite rock is greater than 40 the rock phosphate in question would be used However if the RAE value was less than 40 TSP would be a better choice There are indications that if the P in the more soluble phosphate ro~cks (North Carolina north Florida central Forida) is less than half as expensivz as that in TSP these rocks would be feasible altereaives to TSP on soils similar

to thoseused in Thailand This analysis does not take into account the possibility

of lower yields from use of phosphate rock In addition only a portion of the various yield response curves was used in this anlysis ie up to 22 kgha Beyond this

rate yield response was much less pronounced it could be argued that at less than maximum yields TSP would produce a certain yield at lower rates of P than would phosshy

pow ofrock This would especially be true for rates applioa example at Klong Luang 5500 kg of

rice pcr iectare could have been produced with either Ii kg of P as TSP or 44 kg of P as son of the more reacshy

tire phosphate rocks It should be pointed ot however

- 68 shy

(IIKIS amp YOUN( ARIFICIAL WEATIIERING OF OXIDIZED p[ll- IV

that this is the yield level that would show the widest difference such is the advantage of hindsight

Farmers generally prefer granular fertilizers for machine

or hand application This is a disadvantage for the phos-phate rocks which are normally arplied in finely divided form Recently experimental quantities of granular urea-

phosphate rock mixtures have been made by TVA Results of trials with these fertilizers will be reported elsewhere

LITERATURE CITED

1 Armiger W H and Maurice- Fried 1957 The plantavailability of various sources of phosphate rock Soil Sci Soc Amer Proc 21183-188

2 Bengston G W E C Sample and S E Allen 1974 Re-sponso of slash pine seedlings to P sGurces of varying ci-trato solubility Plant Soil (In press)

3 Caro JIt and W Hill 1956 Chard eristics and fer tilizcr value of phosphate rock from different fields J Agr Food Chem 4684-687

4 Ensminger I E R W Peirson and W II Atmiger1967 Effectivencs of rock phosphate as a source of phosshyphurus for plants US Dep Agr ARS Bull 4112S

5 Engelstad 0 P J G Getsinger anid I J Stangel 1972 Tailoring of fertiliers for rice cnnece Valley Author ftyNational Fertilicr Developmnent Center Hull Y-52

6 Khasawnch F E and Jane P Copcland 1971 (otton root growth and uptake of nutrievos relation oif phosph

rus uptake to quantity intensity and buffering capacit) Soil Sci Soc Amer Proc 37250-254

7 Lehr JR and G H McClellan 1972 A revised lIbora tory reactivity scale for evaljativg phosphate rocks for direct application Tennessee Valley Authcrity National Fertilizer Development Center lull Y-43

H Terman G L S EAllen and 0 P Engelstad 1970 Response by paddy cice to ratcs and suurces of appliedphosphorus Agron J63390-394

DIVISION S-9-SOIL MINERALOGY

Artificial Weathering of Oxidized Biotite IV The Inhibitory Effect of Potassium on Dissolution llate

R JGILKES AND R C YOUNG2

ABSTRACT

Rates of dissolution of oxidized biotites in OIM 001M ICI are severely depressed in the presence of IM KCI The amovnts of Al Mg Mn dissolved in the first eytraction are similir to those found without KCI however subsequent extractions remove these elements at 10-20 of the corresponding lICI rates This effect may be due to a decreased rate of vermiculite formation thereby reducing the effective basal area exposed to attack A decrease in dissolution rate with increasing ferric iron content was still apparent in the presence of IM KCI

Additional Index Words X-ray diffraction infrared aborp-

N EARLIER papers of this series the tole of biotite in soils

as a source of both macro and micronutrient elements

has been discussed ((Gilkes Young and Quirk 1972 1973ab) Experiments in artificial weathering uiing as va-

riety of extractants were undertaken to determiie the inlu-

ence of oxidation of octahedrally coordinated iron on the bull release of structural cations to solution The results of this

work demonstated that biotite behaves anomalously with respect to the other common ferromagnesian minerals found in soils Oxidation leads to the development of a high degree of resistance to cation exchange and dissolution Several authors have coiwludcd that decreased rates of K

Contribution from the Dep of Soi Science and Plant Nutri-tion Institute of Agriculture Univ of Western Australia Ned-lands 6009 Western Australia Received 29 Sept 1973 Ap-proved 8 Jan 1974

2 Senior Lecturer in Soil Science and Research Officer respeclively

replacement in electrolytes shown by oxidized biotites are

a result of the inclination of structural hydroxyl adjacent to newly created trivalent iron or vacant octahedral cation sites (Robert and Pedro 1959 Barshad and Kishk 1968) Gilkes et al (1973b) suggested that decreased rates of disshysolution of oxidized biotite in 0001 0t)l 0Af CI may also be due to the presence of inclined hydroxyl In this case a smaller surface area external and exposed intershylayer may be available for attack if K replacement by hyshydrogen ions occurs at a slower rate in oxidized biotites

Gastuche (1963) has shown that significant dissolution ofthe (IIM) biotile face may occur and it is easily demonshystrated that the proportion of exposed (001M) face in weathering biotites depends on the percentage K replaced

Rausell-Colom ct al (1965) have shown that hydrogen ions act in an identical fashion to metal cations in K exshy

change from micas In particular exchange c-f K by hydroshy

gen ions will be terminated or greatly reduced by high levels of K in solution Thus if dissolution of oxidized biotite by

acids is carried out at sufficiently high K levels to prevent vermiculization any differences in dissolution rate that may occur cannot simply be ascribed to differences in rates of K replacement The following results were obtained from such an experiment which unlike the experiment described in Parts I and II (Gilkes et al 1973ab) does not attempt to simulate natuiral - conditions

MATERIAILS AN) M HIiODS Further subsamples of the less than 0 hiotites used in K

excherandbaid disoo tu es (G iles e9n K exchange and acid dissolution studies (Gilkes et al1973ab) were used in these experiments Preparation of sequentiallyoxidized biotites without intermediate vermiculite formation is

Page 23: I70 - United States Agency for International Developmentto ascertan, but tgl.eetad, 1, L,. ("Tailoring of Pertiltiters for ice,'" TVA ulletin Y-52) states that the staft of IOi has

4Ii I~4I4M$~ ~I

QOWIf XVif k

4004 004o4f U A

-w i4 I~~~

40440wo oow IVTA 44qol 644

4I~~~4J 00S4 4410 114w- A44W Wamp ~

6WViso4wb f vfpo w

w0OIA - i f iIS

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TOM I

Cs VWA1 t lw Vairtile ot P44Y 44c KW MI1

fiat Wm~~JL U Lem~ampuJampAJ Wat IO

~ 941~1 41 ~~~~j~~qt~~8IJ WtS dobu

Table 2

Mttct of 0 Sourco aampW $At On Upt~ks of 0 by Two Varitgtos of Paddy Rice

gr~a 1971

~ MMUampL~ ~L ~ nYLALI~ 11 lemall

I ie

W0 v slit III I) tQo9

KvN 1 17 111 1119

or 444M7

111a

i1$0N ~ It$ 121

1$

x IV ~404 tot Vsr 1 P1 41 w otv 1

- 24 shy

India--The results of four experiments conducted with flooded

transplanted rice in India by the All-India Coordinated Rice Project

Hyderabad are given in table 3 The response to N was excellent the

yield without N being only 41 of those obtained with basal applications

of N as uza With basal applications of SCU the yields were 20 higher

than with basal applications of urea and in the three experiments in

which urea applications were split yields with SCU were 18 higher than

yields with split applications of urea When comparing the average Nshy

response (kamp grainKg N) yields were increased 13 more by SCU than by

basal applications of urea

The data from one experiment with light irrigated rice in India

are given in table 4 yields were relatively low and differences between

N sources or method of application were not significant However yields

with SU tended to be higher than when all urea was applied at planting

but lower than when split applications of urea were applied Again yields

increased more than 13 more with SCU than with basal applications ofwere

ur

In tables 5 and 6 the yields of a short-duration transplanted

rice grown in irrigated light-textured soils at five locations in India

indicate that higher yields were obtained with SCU than with urea when apshy

plied as a basal application Yield increases due to basal N applications

were 502 greater with SCU than with urea However split applications of

resulted in yields equal to those obtained with basal applications ofurea

CU

The yields of direct-seeded upland rice grown at three locations

to India are given in table 7 and the relative yields in table 8 Yields

were low due to drought but good responses were nevertheless obtained for

- 25 -

Table 3

Effect of N Source and Time of Application on Yield of Paddy (Flooded) Rice in India 1972 (Summary of Reported Data from 4 Experiments)

Experimental Number Source Rate Method Yield Relative N-Response

and of of N of Yield Kg Grain

Season Nitrogen kgha Application mtha Kg N

- - - 196 34 -

Urea 120 Basal 573 100 314

11 Urea 120 80 + 40 611 107 345 Rabi SCU 120 Basal 713 124 430

12 - 0 - 202 30 -

Urea 125 Basal 682 100 384

Rabi Urea 125 35 + 20 + 35 + 35 633 95 344 SCU 125 Basal 781 115 463

13- 0 - 168 44

Urea 100 Basal 385 100 217

Kharif Urea 100 30 + 20 + 25 + 25 400 104 232 SCU 100 Basal 462 120 293

14 -

Urea -

125 -

Basal 355 650

55 100

-

236

Rabi SCU 125 Basal 781 120 341

-- 26 -

Table 4

Effect of N Source and Time of Application on Yield of Light Irrigated Rice in India 1972 (Summary of Reported Data From

One Experiment at Pattambi)

Experimental Number Source Rate Method Yield Relative N-Response

and of of N of Yield Kg Grain Season Nitrogen (kgha) Application (mtha) Q) Kg N

38 0 - 204 85 -Rabi Urea 120 Basal 241 100 308

Urea 120 60 + 0 + 30 + 30 267 ill 525 SCU 120 Basal 255 106 425

Table 5

Effect of N Source and Time of Application on Yields of Short-Duration Transplanted lice Variety Grown on Irrigated Light-Textured Soils at 5 Locations in India 1972

(Snmzarized From Reported Data)

Rate Grain Yields (MtHa) Source of N Method of N GrainI of N kgh Application Faizabod Karjat Mandva Pattabi laya Averaje X

- 291 266 211 19 340 260 -

Urea 100 Basal 386 407 361 285 482 3 124 Urea 100 50 + 25 + 25 399 430 434 334 6amp2 4A8 186

SCU 100 Basal 368 468 439 360 572 41 181

Table 6

Effect of I Source end Tlae of ApplIcattoo c RIstave Tle24 of a rt- rat1 T Lsd lice Vasrety Crin o Irrigated L41tshy1 at S Locitite mindi 1972

Rate ____________14_3

Source of X N~tbad of Of X An 1 tat14 1 acr X__T1 4v tatW ttva

- - - all 7i i

95l 119 1 1~ ~~~~~ an iI3lli i1

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404 400

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A 44a4P4 ~~ 44p $444m 04I-Aamp~ 114144

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04 o oa4414 -4V~iWO440

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Tel of ate (01m itl it Iiuma tWuJt)

21L1L LW ufU~ vie 114 3 10 106

As 11 i 41 4 smg LAY1 $Of 41)

Tabl I

f~ttwi Ot 0 6wirce 81d At$ a vt1d at flUop4d Rico to Vitjorim (1ITA)All fortitfour to rsodkeet OA lC~OVPr4( 114 5iI 000

W Iotors Ftslanp tospg Irritd for Two thvk Afler flontiw wft rkwa~ Floo4d 191)

- -I-of LWAIM) (IS YJl- fl-----II)

-0 10)

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KthD 00

- 38 -

Table 18

Yild of aemati-370 Rice at Punjab Agricultural Research

Institute in Pakistan in 1969-70 Grown Under

Couditions of Intermittent Flooding

Pate of application

=IL

o 0 67 67 100 100 67 67

100 100 67 67 200 100

Average for Sources

Ntha

AS 260 gres 279

320

Source f5

-

AS AS Ura Urea SCU SCU

Yield

Relative

93 100 115

(M)O

Yield

Increase Yield Due to N

(Ktlha) (mtha)

-212 245 033 274 062 260 048 297 085 315 103 325 112

Yield Increase

Relative

72048 067 100 108 161

(2)

- 39 shy

Short-statured high yielding rice varieties grown extenshy

sively in northern Peru require extremely high rates of conventional

N sources to achieve maximum yields The recovery of applied N is

extremely low due to the use of intermittent flooding This water

management system results in heavy N losses even with properly timed

split applications In search of simpler and more effective methods

of N management eight field experiments were conducted in the region

to evaluate sulfur-coated urea (SCU) an experimental slow-release N

source supplied by the Tennessee Valley Authority Rice yields were

increased an average of 59 more by pretransplant-incorporated SCU than

by urea or ammonium sulfate applied in the same manner SCU produced

excessive vegetative growth which resulted in yield reductions at high

N rates

Regardless of an assumed 48-higher unit N cost in SCU the

overall benefits of pretransplant-incorporated applications of SCU

were favorable since there was a decrease of 40 in the optimum rate

of N and the need for precise timing of application was eliminated

Pakistan--In Pakistan basal applications of AS urea and

SCU to rice grown under conditions of intermittent flooding in 1969-70

(table 18) indicate that SCU is a superior source of N as compared to

urea or AS when all N is applied at or before planting The data also

indicate that a yield response was obtained for P applications but a

comparison of N sources at each level of P indicates that no interaction

between N and P was present so that differences between N sources were

relatively the same at each level of P Yields were increased about 60

more when SCU was applied than when urea was applied Yield increases

with AS were only about 72 of the increase obtained with urea these reshy

sults do not agree with the generally-reported superiority of AS as comshy

pared to urea as a source of N for rice

- 40 -

In 1973 experiments were conducted in Pakistan using both

Basmati-370 and IRRI-6 varieties of rice grown under conditions of

When all N was applied at puddlingintermittent flooding (table 19)

or 12 at puddling and 12 at panicle initiation both AS and SCU were

superior to urea with SCU tending to be the most efficient source

However when N was applied 12 at transplanting and 12 at panicle

initiation SCU was the poorest source of N This would indicate that

the release of N from SCU applied at these times is too slow for optimwn

plant growth

In another experiment in Pakistan in 1973 no differences

in the effectiveness of urea AS or SCU were noted in the yields of

continuously-flooded rice (table 20) Again these results are conshy

sistent with earlier results which indicate no superiority for SCU

when rice is continuously flooded

Nitrogen Studies--Maize

A series of three experiments were conducted by IITA in

armo-Nigeria in 1972-73 comparing AS urea SCU and

CAN (calcium

nium nitrate) as sources of N for maize (table 21) A significant

yield response was obtained for N at each location but no conaistent

differences were noted amaong sources These results are consistent

with results at other locations which have not shown that SCU is a

superior source of N for maize grown over a period of 3 to 4 months

Nitrogen--Wheat

The yields of wheat in Pakistan in 1969-70 (tables 22 and

23) show that yields with SCU) tended to be lower than those with ureaJ

although at one locction where sorghum was grown followilng wheat with

Table 19

Yields of Basmati-370 and IRRI-6 Rice at Punjab Agricultural Experiment Station in Pakistan in 1973 Under

Conditions of Intermittent Flooding

Rate Yield Source of N Time of Yield (Mtha) Increase of N B-370 IRRI-6 Application Basmati-370 IRRI-6 Average (Mtha)

0 0 - 21 353 287 -

SCU 90 150 At Puddling 325 545 435 148

Urea 90 150 At Puddling 309 500 405 118

AS 90 150 At Puddling 324 529 427 140

SCU 90 150 Puddling 372 572 472 185 Panicle Initiation

Urea 90 150 Puddling 335 502 419 132 Panicle Initiation

AS 90 150 Puddling 353 529 441 154 Panicle Initiation

SCU 90 150 After Transplanting 312 562 437 150 Panicle Initiation

Urea 90 150 After Transplanting 340 624 482 195 Panicle Initiation

AS 90 150 After Transplanting 349 583 466 179 Panicle Initiation

All plots received 45 lbs P205acre as single superphosphate

Relative Yield Increase ()

Source of N At Puddling Puddling Panicle Transplant h Panicle

Urea 100 100 100 AS 119 117 92 SCU 125 140 77

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-48

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obosomhu rocks 0entk catetas rth Unrtdo costrat frwt) to

ht tse balt s Owosiv as that to TwP it rocks WM bo

fmtbt alteruutiv to MSso gotastte to~ Ik lee used to

ThUAIAd

Tht wMl dt gotmtmlaoti wout th possibility

of law Vhld free ww e1 e66001 4 It cooUt be YgWd Sutt

a4 10 0410 SWUSSM yt$4e TOP wUd predWr A r~ftIf fl~W t

1f f ot P the wuld phosphae rck TWOe viWMW efocitill b

true to low rttos t tsplusatiI P wi 9 Ma Liiam $S

amp4at r per Wforssota Mav two 64eed Wilk elikor It 44 of

P go Mi er 4A bg oftoP aon of tewmrowtni pboophals fwAh

It vwld be polotrd A Wevero wtht Is the jteld level that

W414 gk tko videm dtterem~j o(A 1 the 4~etamp tk~e~t

P11~0 pra~lpj prefer gre4r tuftlter for whlae

of hoaw ppltrstie Mhe to a dloedveaP for The PINSOO rocka

vkth m r II spotted 10 ftewil 4106Me tem

Nub studios we ovsosd o IVA vol gramleid a

forgof wee aMW pbsepbots A fths pemhawe evsielew us

Odellod to detMlee it otteettvmm of 11agotated Stoture of

mmfp MW phapa A (CI) sed graewletod pampAtlti arlolatod Pa

asowcs of P tof ttde ro The wreem proucts omre raGther

pemour~a ot P syag besmti andMi as elt ov so gpamwhr

iuipiqffhate(TS) low twseeo Is eftwiltve Is thet

W41 preeme wae oialain ire post-rItoi effriq to Stanlato the

pud6itt of Irto paddle Wee ofsdlseireplastiq

0 49 shy

lbs partially scldiaatede grawilated Ml prodlucts Vere isshy

toiwdiats in 5tftOvttWS54 betwee wroiPi ad TVP NotV5Ymf to

me coo were they mere twoe $a a etfective ao TIP 00 sipifleast

LVSUMI5 at0 efecto wore toun tor thee produteo Timely dtIampWde

FR (-t00 mmoh) Uia amp~rally oar affective than Owe gra8448r FOampprodt

featal twos o 6 aotetire s I

Nowvero it to felt that sfortber field euprtet vth

hese interials Amd ether typs of grometatodl Wter nre wrrautad

hater ceeuwodh that they have me areec poteatlal toi additoG

e tate wAne the sectte as OtawrI sed bovoloen turther

euperimeste vth few reck pboophar s0d with reck pbophat treated

to sehesa citrata selmtliy or to ha csaducted

Metbir sertes of tbme enprtaeats wae c~edtmcted by IITA

to Ut~rta copal TVP AOP APP aed it at see tecastisix (table 14)

No dot lalt sewseltles teh draw tree thee results simouely em pear to tlvdl bsww they do stwgpt tbat forthew work with

MR to werramid so tbme sels

Table 24

LttcttF Swce MaPlate 06 ieldot IM AWaia CoelsANS at IITA (Ugboda ad Apoin ail sorit) aid at Ike (AUaba s5i series)

1973

Plate ot IP Apinu 5 poundebods A1ab

Ocrol 0 Z94 419 M)

Tr ipl ruprphite 20 349 3799378

Triple vepput 40 M09 410$

Triple 6wp~~b1 4271 4344 42250

Ammotw-ritpophW to 4201 4124 4040

Amosim-rdop~phlt 40 4270 4106 4231

AM tuo-polpephats 20 404 4244 3794

~eai~mpelppepbuI 400)49 4094

Cee m-pbpbt to- 59

momee eph lto 0 4192

LSO (0 0$) 29 1025

Th WPII

- 51 shy

101Y114 tpeM-fI PEP~tbRP YO

1 ~ ~ gmw 1pc~biofl- 9 Kla4v4h

Upia U04 Copfind am Crehout Stet Rpano at (Ia4

rico t IF t rume6 orth~ Caralto phoophale rocl QAR) vaUN pqU41 to

roopon from cmonetrat4 gsporphophai (CIP) who ort$o4 oil k

was 45j itwas tafertor vb protioo4 oil p war OS Ib 4iffer~c

in rtc reepos to X cod14 oo bo ttrit4 4 4 hvsciag of boil p

~ Pt o r11221 0 tP

c theto the rhimecyllndor of rico tots par to)14M4i1 roeoi~t

ed oil emd PA prior to tho ont of an~robi4 cMioe AA~ oIifoshy

nAte bYpot t taet~d tO fC4sin t~r 4PWden0 Of f Ot(tivshy

ofOWailiJtyno o prefla4 all Put that 4t01etoo 14 tvsIk

of the Ott to prvvld a 014for C4m0 44 mI 1 o4sf

EfftC ftPet141on AIAM-0 V f401td 4 4iv 440 Mtft

Aa torfat VampP f4MWfCi4W04wt0amp to 4eturWlI Ot(Wel~drIC ft

Ot f tM6 the flooded Ott 00 14 04019I Pft0uAw Of gAr~s~lr

pkS$t M40b MP) Tw P1101 Piset Prodwie W-e 10M0di Wr04

(10-1) emW 0aretilp ddw01at4 P WAA firom Rrth M~flRU414~$

wee cowiared with fie Md reWim 44104 proo~fo) foruk oith laWItter

I v te-PR P OW1004 4 4 O Wf ottil OW ellt Oo

Oveiel1 the 40tt dmcruie to effetotww Wtollowui Co fme

PR tpaUIB1I ldoltmo PR (pamwlatr) offr~- ArmeuM) 0 orwi

- 52 -

Effect of N Sourc6 and Water Management on Response of Rice

toe Zn- M Giordano J J Mortvedt OP Engelstad and Greenhouse

Staff Several rotes of CO(14H2)2 and (H )2So4 vith or without ZnO

wore applied to flooded and nonflooded Crowley oil (limed to pH 75)

to determine response of Bluebelle rice to Zn Yields with both N

sources veotrgreator on flooded then on nonflooded soil In the abshy

ence of applied Zn total dry matter production vith CO(NH2)2 was

slightly lower than with (NH)2S04 on flooded soil and considerably

lover on nonflooded soil Concentration of Zn wan higher in straw and

grain of plants roun on flooded than on nonflooded soil Although

concentration of P was unaffected by N source or Zn rate there was

som indication that cranslocation of P from straw to grain may be

depressed in nouflooded rice Concentration of N was lower in straw

grown on flooded than on nonflooded soil due to apparent dilution

thereas both X sources resulted in similar N concentrations in straw

at all rates of N application the N concentration in grain increased

with 0 rAse

feSpongi gf(SM to Chjorospodiostte and Related P Sources--

Si Allen and Greonhoue Staff A greenhouse pot experiment was

couct44d with corn Brown on Hountview silt loam to compare the ofshy

fectlivees of chlorospodiosito (Chlor-l) with concentrated supershy

phosphate (CP) Thomas slag and North Carolina phosphate rock (NC-PR)

Oil-prillad urea-phophato rock (UPI) FeA1JMP 20 7 and monomthyl

phosphate were included in the experiment Based on yield of forage and

uptake of P by tvo crops each of 6-weeks duration the following conshy

stui were dravat

I Chlor-1 was slightly loss effective than CSI Thomas slaS or NC-PR

from which Chlor-l wae prepared

- 53 shy

2 Granular UPR was a poor source of P its effectiveness was greatly

increased by reducing the particle size to -35mesh

3 FeAlNH4P207 was unavailable to the crop

4 Monomethyl phosphate was equivalent toor slightly more effective-

than CSP

Research Indirectly Related to TVA-AID Project

Response of Several Rice Varieties to Zn in Moist or Flooded

Soil--P M Giordano J J Mortvedt and Greenhouse Several varieties

of rice from Mexico and the Dominican Republic currently under investishy

gation in Puerto Rico for adaptation to upland culture were compared with

some established United States varieties with regard to Zn response on

moist and flooded Crowley sil (pH 75) Chontalpa (Mexico) Bluebelle

(Texas) and Starbonnet (Arkansas) were most responsive to applied Zn

Juma (Dominican Republic) intermediate and Sinaloa (Mexico) and Calrose

(California) were the least responsive The Sinaloa varieties (Mexico)

appeared to be best adapted to non-flooded conditions whereas Chontalpa

and Calrose were poorest Concentrations of Zn generally were higher in

plants grown on flooded than moist soil

Pattern of Growth and Zinc Accumulation by Rice--P M Giordano

J J Mortvedt and Greenhouse Staff Rice plants were harvested at weekly

intervals from shortly after emergence through maturity The objective

was to determine the rate of growth and Zn uptake by a Zn responsive varshy

iety (Bluebelle) and a less Zn-responsive variety (Calrose) in the presence

or absence of Zn applied to Crowley sil (pHl 75) Dry matter production

of Calrose was linear with time of growth and of a similar magnitude until

heading with or without applied Zn Bluebelle followed a similar pattern

where Zn was applied However in the absence of applied Zn foliage yield

was reduced markedly

-54

Uptake of Zn was similar for both varieties whenZn was

applied Dry matter production and Zn uptake by the two varieties

also were comparable when Zn was applied However yield of Calrose

was much higher than that of Bluebelle in the absence of applied Zn

while Zn uptake was only slightly higher This suggests that the lesshy

ser responsiveness of Calrose to Zn may be due to more efficient utilishy

zation of Zn There was no indication of a greater demand for Zn durshy

ing reproduction in either variety as was suggested in earlier greenshy

house experiments

Response of Upland Rice to P and Zn--P M Giordano J J

Mortvedt and Greenhouse Staff Several rates of P and Zn were applied

to Crowley sil (limed to pH 75) in factorial combination to determine

whether differences in rice growth under flooded and nonflooded soil

conditions are related to plant nutrition Although straw yields were

slightly higher in nonflooded rice receiving adequate P and Zn grain

yields were higher in the flooded crop increased rates of F andor Zn

did not result in equal yields Except in the highest Zn rate (75 mg)

concentrations of Zn in both straw and grain were higher with flooding

Concentration of P increased with rate of applied P and was higher in

the grain or flooded than upland rice at a comparable P rate In conshy

trast concentrations of N were lower with flooding due in part to dilshy

ution from increased growth

Rice Response to N and P in Flooded and Unflooded Cultures--

G L Terman S E Allen and Greenhouse-Analytical Staff Rates of

N from 250 to 2000 ntpot and P from 0 to 1000 mtpot were applied for

Nato rice grown on Mountview sil and Sango sicl (625 kg of soil per

pot) Market yield response to N and P was obtained Yields of straw

- 55 shy

total yields N uptake and N recovery were higher on unflooded than

on flooded soil cultures Grain yields however were slightly higher

with flooding These results indicate that with adequate applied

nutrients especially of N rice yields without flooding can approach

or even equal those under flooding

Uptake of N P Ca Mg and Zn increased with yield response

to N and P while K uptake decreased on the Mountview soil Concentrations

of N and P increased with applied N and P respectively while concentrations

of other nutrients were diluted in most situations with yield response to N

or P

Results from this experiment show that amouats of N applied in

previous pot experiments for rice have been much too low especially if the

crop was grown to maturity

Response of Corn to S and N i UUASand Urea-S--S E Allen

and Greenhouse Staff Three greenhouse pot experiments were conducted to

measure response to S and N in ulfur coated urea (SCU) urea amonium

sulfate (UAS) and urea -S as well as estimate N losses from surface apshy

plied N sources

In Experiment 260 less than 20 of the S mixed with the soil

was recovered from SCU or urea-S granules by two crops of corn as comshy

pared to 45 or 80 from flowers of S or Na2SO 4 CLop response followed

a similar pattern

In Experiment 260-A N sources were surface applied and alshy

lowed to dry for two weeks before incorporation Into the soil and plantshy

ing Recovery of N by two crops of corn was 77-82 for AN an compared

to 37-70 for urea UAS urea-S and ICU Thus n this experiment loss

of N from urea did not appear to be re~dcud by light S-coatlngn or by Inshy

corporating S or AS in the granules

-S -

I xbprZnSlt a Wtch aU Meyto 0-Ai Wt f9r

higher reermo teOrtOrs cOM reSpWNO i r0100 Of N w

not oaisteontly related to sewe ot N In edl tust 0 ioltiUe Lim

lo in VMuwpped evlmtUTS 48 merind by seirest nte appresOehe

501 for uroa as cwarod to 210 for urea peepha

Rus- or Upse to LoAmIl34I a AriMed bI Earl U

MW NOWlsIIsIr-4 L Toman 5 1 Alln and eesese StNf rio

row on Sawg did (0 tpot) We 1l0l0 Ws feritiud vith 05is

of Npot mixod with the 6011 as aureCA NiAO) 1 Age god At Ures

was also itcluded at rtt t 05 10 end 15 of Upee Theas trealshy

onto were followed 4 wpdrsetago of U s AN wre 4C 10o or at I3n

Weeks toulin up to IS pot

A soil application of 10 pot rosulvod to the maim yield

at 4 weeks Tio4 sad percont prottis t intre raite tncreased rftishy

linearly with U applictalien IeseeItally all at the m iNd wit

the moil w domitrifted after flooding Grail end straw Ilelds vere

highly correlatod with tiliriag and vlh ubers of gralm arl

The results Widicat that 0$ to 10 a of Upot as orea or

NN bsuld be sied with the oil to stilate tiilrir with adshy

ditional 0 topireased later to increase grain lIds mad protia cmshy

tout

DIVISION 54- FERTILIZER TECHNOLOGY AND USE

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Tile 4-00dw x uiampOW74u 0qee of

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h Eaap 8n 14 sMsa of abw~greuad PU Pau WW 1 u itb IUKho 0aaphelem s 60 Otarlmmh At ~ 0sU Ishiseoo Cook oiA N uiplasu mAasslaly abess A leel

v doese a WKWye Is ks Nha m 6 sa4to dafo aONmuw The appee swm Wsssof adde N4 alalaed by vuMb ifaa W C Was sekilumganSro Is

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valves a hevwae u Iar Walh basl oswas dhe uwpatr bshava of

tb~msusasl appkausu of ofta sede s have aoweN

TOW opl taoe for AieweeW 4OsmWMbas Op peas As Tabl 4 sling sob Os awowully eom grams Piel level Thes oeulam Ma sed as IM

-02

792 60L WI W A)49R Pio VOL 37 197)

primS o r OeampAd WU toa Them fl~ w At NOSSe earno maisslea Ia N he mOWamplIO yik ampWd IMe aampWmW OWa Owe wa UMs of KU to 41 Oke ampWiiIamm be dkrnety ewspokawleM(a s8 te camtd wie a eapmoe by TVA pavw ltoi NA poundrmdaka4us vrimeW460 o to ilkidm ofWW (Mtemas MuOwe 1973) TVA mwi bawld on soi ficedims IampWp seg rudwiv s~s0abet ke WNmdoe ON 01 K Is12 NOSW ie fssewnmu Ie I QvaaIi rowp IMA) f9

)amp m lodk byO voebmsaIS8OpeaWfrats 11 OWNmi a I a W idisod 0 81 Now 111 nindat Wm fysmpseaamp (If tsO tUmtI IsM $P shoroV4mmo knflkvnf (foOdme nuw ae Ow OImstwe in SM pnmm8 af tXm 10 114PIS kequoian wo Mpfii

SC~po umd spop~o VWt alm 4emWal 1 4ink PCmirsra M 1 ad AI 14bmms

1MM Ww Even to doe shw wisht b-o -Wamp Ekb fed rbaimpal of14~ Am Smpound oS mv fAaMda

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DIVISION 8-9-SOIL MINERALOGY

Amorphomw CeetIup en XmWra Ssrfmls

L C koits Am~ 0 tmmkaAf

ommp A faieiaAMTRACT skiwe lo nW ampM sm wi4h

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peuiieles as is s e wpwigstee eded his S -em -om 0641 h4 hisW1mWOWb~ bfem peess Wimm kv Iee

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os 0aMW ofmu WA l aduWs~Ib rowuvvl3maIpm s

CaO~OP aw AlNomI 4ornomd to9 IS is -l O SI g4he rpidyThus whim m dowu bWa 0 m m- ei u

d m M 0bmSaImu M-1 ofM6 h Intun to 7I

aiba maush WAesshwn~u9dSg a osusLwpI ~ v m

M PolsdAvoWdw Ons pugm~ low iwLW m We

of~U -a~ mo uNo

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A e mun5d m i vvamp sa s ow bftIS i sa omdIs a w

edi1 hswopmo an ag am Iw anom erlwaPASneooie bnwoM po

o ~ do=lr 3s fluACWoSM Owaa VolM Ain b 400b adW g o as amob ofrMOWS A oo eWmaa ow $wofdi60 ow - ema

-v K Vcon l ap ad md ld KU lbs PoabumwA od w to domi a bembe 0b lt $014 i ampmomONo

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arbs awasm 00 iztv Am-~~~i u5~ms ashu is byw

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bdisc shmm Ammmd a Sm ofd~~~~~d~A ~ a~m olWshmo

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- omlos r umIWO1in pw

lie Uvplist i piw S p wsmoW N of t as so in~tabo 440 o rodgAsect M4Ammd meM ii INAq10ed~ Pib mdWWeiW 1w -w emit TU UFm 6AV 0W A fIN 00~ lb 0PANNO 4 drp OW~It~Oi Ofme _____f WACMW0IN WMVsol~lmO ft SNAO 40 do1Si - m Md y e b ii m

of of~phaow tw bmsdf toamplboe

AjflsutomW C1D-pCTP AD mSmZLT op 1 m ow ts Wdm of P om M

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ov4mnk wsi 9 Mxfeu~i am emwm ismi0wmd fq W No ~~ - f mug Aitowe eutlkowbmTV is

amppowftdmi TiM 0 Tie OAA mo p)a Mwomoi dOn4m A)w

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~ -0

65

0IL CL OC AMXR PROC VOL 38 1974

)aT1 S4I104 ow Lusanll Tawng isa tall Thai variety known for beingIwo nonshyi s s ) sensitive to photoperiod A split-plot design was used in

S e e these euperimeots with 4 rates of P (I1 22 44 and 88t i V IV k of Pha) applied a main plot treatments and with the OF It sourMes of P as subplot treatments There were two checkS plots in each rmplicate The extra check plot was included to permit the application of fresh TSP standard Jor the

It- ti 06 + i bull fa succeeding crop the p-4me of bi was to permit accurate d awrnwal of the mdual effectiveness of the phosphate

ftinSUbI rock The P fertilioers were broadcast on the mud andthen Worporald In the soil during the last harrowing At

whM N both On ACS indx ampM time of transplanting Immediately before the last harrow61t (4j 5 4 01 P s 3Mm o Vallonal in con n 100 kgha of N as ammonium sulfate and 33 kghaWO Of Spews ampm lIW thaabe rocks do ACS indes of K as polium chloride were applied A total of 40 wa in prepw O do ctih k otent kha of N a ammoniunt sulfate was applied later in twoir P The hew oNed amp wM W for 5 of gw topdrossingp with about 5cm depth of water on the plotsvV I aiOMveffeOctveee Three to six ldayold selings pr hillwW the ACS idex were planted00OWW wia Oft fo an c irNk I p Coen 20 by 20 cm part in straight rows Hand weeding was used

and insecticide were applied for Insect control Grain yieldw was masared by sampling 5 ml of each plot excluding border rows The date of heading in each treatment and theUNiN d pbM W Weks rin tOW USA UMe In Tale yed componnts at hafvel were also recorded

I filM rsperMS esOM kdwdua 1 t ab The average yields of ough (unhulled) rice for botha 84 OW O 8uo 4 Thala TM was a locations are ploutel in PIS 3 for the first crop (1969 wet

owou thRM seaso0) The Veamps yield response was obtained at Klonge (s) W lDtO t Of dMa of1tw W d l R Luang however a 4ute satisfactory yield response was

~Mk ^d TVA UJSD ad Kd UnIveS obtalned to applied P at Bangkhen as wellXUe LaM e R qwrw Ims The sod was do Relative aponomlAe effectiveness values were calculated

VOW (a ksA w edmwL t Poesesm h Vy for these data and am presented In Table 3 The valuesdAY buo if dIe ouh ne Pee wtk a Mlak vow 1009 for th first crop are plotled against ACS index in Fig 41 This Im M i6ti l 4bNd IO a0 O mkarnk for both locatio r relationship was linear for the

11400 ThCpH 0( lb pW IW 01 th UpeiaW so Sanodion location and curtiltnear for KIng Luang The was u i 4A sksamp lMaor nrusio model amparounted for 81 of theAmO$MI Aw jAAsue Swim T1 Snh Wd variation In the AE valu for Bantkhen a square root

Mems a Iw iv fern alh$ sedm haowg dayNW W t he plAL At tdo M tM aso W s as ctminued throufh eltaM t Ofpof -le lse wo am P OeNI VeOpls 1o ealluae tI lon4erm MIdual Offccls

A on W isset i a wse to hsh eapeel of these ooihss t ocks The baagkhon experimnent was letmiaI1DlVemisthis is a w hulu Lo g Tasug ia iasael aft - Msd residual Ves will be pr-Om crok TheseTwod esewm

SWWo

A

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o

S4l~ lIIII I~l I 1f fl

( +

+ + + m + ++++-

++ +(++ + ++++ + ++ ++

- 66 -

ENOIMLSTAD ET AL RESPONSE BY FLOODED RICE TO PHOSPHATE ROCKS VARYING IN CITRATE SOLUBILITY

I I I I j0 I I

BANOKHEN BANGKHEN

pH 56 6 - 0o

TSP

NC

5~ ~ ~ L o 4 - -shy

4 ] - --------shy04

6S

|0 III 2 44 8r 66

I I I

a 1KLONG LUANG

pH 46 z KLONG LUANG

TSP Sc2 NCFL(N)

5 FLIC) J0 TU

oshy

4 ~40shy

3 bull eM0

I - I I I I I

0 II 22 44 88 0 5 10 15 20 IP APPLIED KO HA ABSOLUTE CITRAE SOLUBIITY INDEX

Fig 3-Yield of rough rice at Klong Luang and Bangkhen Rice Fig 4-Relative agronon effectiveness () of P sources ploz-Experiment Stations Thalmand as affected by rate and Source ted against citrate solubity Index for both Thailand field ex

of P applied (crop 1) periment (first crop only)

regression model accounted for 97 of the variation in sumably resulted from crop uptake and reaction with the RAE values at the Klong Luang location soil to form less soluble products Such effects may have

These experiments were continued during the dry season been more important at the lower rates since the two TSP of early 1970 to ascertain the residual effectiveness of the curyes converged at the highest rate of application various sources applied to the first crop No new P was These data from KIong Luang indicate that (i) residual applied except for the fresh TSP standard mentioned effects of all rocks except Mlcwuri were substantial (ii) above rhe experiment otherwise was conducted in a man the relationship between relative agronornic effectiveness ner similar to that followed in the first crop of the phosphate rocks and citrate solubility levels was

The response to both freshly applied ad residual P was largely obscured and (iii) the general superiority of TSP marked at the Klong Luang location and marginal at over phosphate rock in terms of effectiveiss persisted Bangkhen In fact at the latter location the response was through the second crop so small that little can be said regarding residual effectiveshyness The yield data from crop 2 at the Klong Luang DISCUSSION experiment are plotted in Fig 5 Greenhouse and field data presented in this paper show

Relative agronomic effectiveness values (Table 3) were clearly that there are substantial differences among phosshycalculated for the Klong Luang data using both the residual and freshly applied TSP as standards It is of Interest to note that the superiority of TSP over the phosphbte rocks Table 3-Relative agronomic effective values for field experishyments in Thailand persisted through the second crop The main difference in KlowlZmlnql~the residual effects is that with the exception of the MIs- s Crop 1 Crop 21 Crop 1-shysouri rock Ihe marked relationship between citratr-soluble WoiCarolina yl 59 76

phosphate rocks and RAE had largely rds norh) a 64P conltct of th Florida (eqlral is 6969 6

disapipeared In this acidic soil (pHi 46) P would by this I14o 69 63 40 ToonesS 31 65

limo be supplied by Intermediate reaction products In addl Missou 0 o lion to residues of the initial spatlte Ts P o 2 o 0

The TSP applied to the first crop declliv-d slightly In campIafcmWataesr e id ofeuhuloefor 22MA rates of PtColeouattd as aba u tlte td18 kS ratesp dlverage yield tM868 to 22 44

effectiveness relative to the freshly applied ISP This pre- of d s4

A

4

- 67 shy

-SOIL SCL SOC AMER I

KLONG LUANG CROP 2

Si 3

eN

TAPPLIEDKGHA

Fig 5-The residual effectiveness ovarious P sources for crop s compared with freshly applied TSP Klong Luang Rice

Experiment Station Thailand

phate rocks in terms of agronomic effectiveness for flooded

rice Further these differences can be predicted by means of citrate solubility or by the ACS index It appears that

the latter is more appropriate where the content of apatite varies among phospiate rocks The most soluble phosphate rocks approached but did not actually equal TSP in limit-iuig (maximum) yield in these experiments regardless of rate applied This agrees with the results of Ensminger Pearson and Armiger (4) One needs to consider the defi-nite posribility of same yield loss in zhoosing a phosphate

rock over TSP such yield losses must be weighed against the lower price of phosphate rock The explanation for such iosses may involve concentration of soluble P in the soil Khasawneh and Copeland (6) suggest that the growth rate of crop plants is a function of P concentration that can be maintained in the soil solution If P concentration is limiting or inadequate becawe of a lower dissolution rate of phosphate rock the growth iate ard uiiimate yield will be diminished accordingly

The RAE values bascd on yield increases reflect the agronomi effectiveness of these various sources relacve

to the TSP standard however these nould be supple-

mented by an economic analysis before rational choice can

be made The following calculations will provide an estimate of

the rclativ ecooomic effectiveness(REE)

Y t Ps aXpatREE -- 100

vahtercks t sphate or e b i- eor

Price of TSPkg fo

be Price of PRkg P

PROC VOL 38 1974 leO

90r

Wsoshy

0

60-LUSEPHOSPHATE ROCK

00 10 20

PTP PR

Fig 6-Relationship between relaZive effectiveness values (RAE) and the price ratios between TSP and phosphate rock Such a figure can be used in making a choice between these

sources

If REE exceeds 100 in this calculation the phosphate rock would be preferable to TSP

The REE calcuktaaa wre used in preparing an indifshyference curve (Fig 6) wherein RAE values are plotted

against PTsPPpR ratios The cu~rve itself connects those points at which REE equals 100 When exactly on the curve it makes no real economic difference what source is chosen After choosing a suitable price ratio one can then project upward from that ratio knowing the RAI

value (or estimating it from such data as shown in Fig 4 using citrate-soluble P content) one can then choose the source on the basis of both agronomic and economic conshysiderations For example if the price ratio is 25 and the RAE value of the phosphaite rock is greater than 40 the rock phosphate in question would be used However if the RAE value was less than 40 TSP would be a better choice There are indications that if the P in the more soluble phosphate ro~cks (North Carolina north Florida central Forida) is less than half as expensivz as that in TSP these rocks would be feasible altereaives to TSP on soils similar

to thoseused in Thailand This analysis does not take into account the possibility

of lower yields from use of phosphate rock In addition only a portion of the various yield response curves was used in this anlysis ie up to 22 kgha Beyond this

rate yield response was much less pronounced it could be argued that at less than maximum yields TSP would produce a certain yield at lower rates of P than would phosshy

pow ofrock This would especially be true for rates applioa example at Klong Luang 5500 kg of

rice pcr iectare could have been produced with either Ii kg of P as TSP or 44 kg of P as son of the more reacshy

tire phosphate rocks It should be pointed ot however

- 68 shy

(IIKIS amp YOUN( ARIFICIAL WEATIIERING OF OXIDIZED p[ll- IV

that this is the yield level that would show the widest difference such is the advantage of hindsight

Farmers generally prefer granular fertilizers for machine

or hand application This is a disadvantage for the phos-phate rocks which are normally arplied in finely divided form Recently experimental quantities of granular urea-

phosphate rock mixtures have been made by TVA Results of trials with these fertilizers will be reported elsewhere

LITERATURE CITED

1 Armiger W H and Maurice- Fried 1957 The plantavailability of various sources of phosphate rock Soil Sci Soc Amer Proc 21183-188

2 Bengston G W E C Sample and S E Allen 1974 Re-sponso of slash pine seedlings to P sGurces of varying ci-trato solubility Plant Soil (In press)

3 Caro JIt and W Hill 1956 Chard eristics and fer tilizcr value of phosphate rock from different fields J Agr Food Chem 4684-687

4 Ensminger I E R W Peirson and W II Atmiger1967 Effectivencs of rock phosphate as a source of phosshyphurus for plants US Dep Agr ARS Bull 4112S

5 Engelstad 0 P J G Getsinger anid I J Stangel 1972 Tailoring of fertiliers for rice cnnece Valley Author ftyNational Fertilicr Developmnent Center Hull Y-52

6 Khasawnch F E and Jane P Copcland 1971 (otton root growth and uptake of nutrievos relation oif phosph

rus uptake to quantity intensity and buffering capacit) Soil Sci Soc Amer Proc 37250-254

7 Lehr JR and G H McClellan 1972 A revised lIbora tory reactivity scale for evaljativg phosphate rocks for direct application Tennessee Valley Authcrity National Fertilizer Development Center lull Y-43

H Terman G L S EAllen and 0 P Engelstad 1970 Response by paddy cice to ratcs and suurces of appliedphosphorus Agron J63390-394

DIVISION S-9-SOIL MINERALOGY

Artificial Weathering of Oxidized Biotite IV The Inhibitory Effect of Potassium on Dissolution llate

R JGILKES AND R C YOUNG2

ABSTRACT

Rates of dissolution of oxidized biotites in OIM 001M ICI are severely depressed in the presence of IM KCI The amovnts of Al Mg Mn dissolved in the first eytraction are similir to those found without KCI however subsequent extractions remove these elements at 10-20 of the corresponding lICI rates This effect may be due to a decreased rate of vermiculite formation thereby reducing the effective basal area exposed to attack A decrease in dissolution rate with increasing ferric iron content was still apparent in the presence of IM KCI

Additional Index Words X-ray diffraction infrared aborp-

N EARLIER papers of this series the tole of biotite in soils

as a source of both macro and micronutrient elements

has been discussed ((Gilkes Young and Quirk 1972 1973ab) Experiments in artificial weathering uiing as va-

riety of extractants were undertaken to determiie the inlu-

ence of oxidation of octahedrally coordinated iron on the bull release of structural cations to solution The results of this

work demonstated that biotite behaves anomalously with respect to the other common ferromagnesian minerals found in soils Oxidation leads to the development of a high degree of resistance to cation exchange and dissolution Several authors have coiwludcd that decreased rates of K

Contribution from the Dep of Soi Science and Plant Nutri-tion Institute of Agriculture Univ of Western Australia Ned-lands 6009 Western Australia Received 29 Sept 1973 Ap-proved 8 Jan 1974

2 Senior Lecturer in Soil Science and Research Officer respeclively

replacement in electrolytes shown by oxidized biotites are

a result of the inclination of structural hydroxyl adjacent to newly created trivalent iron or vacant octahedral cation sites (Robert and Pedro 1959 Barshad and Kishk 1968) Gilkes et al (1973b) suggested that decreased rates of disshysolution of oxidized biotite in 0001 0t)l 0Af CI may also be due to the presence of inclined hydroxyl In this case a smaller surface area external and exposed intershylayer may be available for attack if K replacement by hyshydrogen ions occurs at a slower rate in oxidized biotites

Gastuche (1963) has shown that significant dissolution ofthe (IIM) biotile face may occur and it is easily demonshystrated that the proportion of exposed (001M) face in weathering biotites depends on the percentage K replaced

Rausell-Colom ct al (1965) have shown that hydrogen ions act in an identical fashion to metal cations in K exshy

change from micas In particular exchange c-f K by hydroshy

gen ions will be terminated or greatly reduced by high levels of K in solution Thus if dissolution of oxidized biotite by

acids is carried out at sufficiently high K levels to prevent vermiculization any differences in dissolution rate that may occur cannot simply be ascribed to differences in rates of K replacement The following results were obtained from such an experiment which unlike the experiment described in Parts I and II (Gilkes et al 1973ab) does not attempt to simulate natuiral - conditions

MATERIAILS AN) M HIiODS Further subsamples of the less than 0 hiotites used in K

excherandbaid disoo tu es (G iles e9n K exchange and acid dissolution studies (Gilkes et al1973ab) were used in these experiments Preparation of sequentiallyoxidized biotites without intermediate vermiculite formation is

Page 24: I70 - United States Agency for International Developmentto ascertan, but tgl.eetad, 1, L,. ("Tailoring of Pertiltiters for ice,'" TVA ulletin Y-52) states that the staft of IOi has

QOWIf XVif k

4004 004o4f U A

-w i4 I~~~

40440wo oow IVTA 44qol 644

4I~~~4J 00S4 4410 114w- A44W Wamp ~

6WViso4wb f vfpo w

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Cs VWA1 t lw Vairtile ot P44Y 44c KW MI1

fiat Wm~~JL U Lem~ampuJampAJ Wat IO

~ 941~1 41 ~~~~j~~qt~~8IJ WtS dobu

Table 2

Mttct of 0 Sourco aampW $At On Upt~ks of 0 by Two Varitgtos of Paddy Rice

gr~a 1971

~ MMUampL~ ~L ~ nYLALI~ 11 lemall

I ie

W0 v slit III I) tQo9

KvN 1 17 111 1119

or 444M7

111a

i1$0N ~ It$ 121

1$

x IV ~404 tot Vsr 1 P1 41 w otv 1

- 24 shy

India--The results of four experiments conducted with flooded

transplanted rice in India by the All-India Coordinated Rice Project

Hyderabad are given in table 3 The response to N was excellent the

yield without N being only 41 of those obtained with basal applications

of N as uza With basal applications of SCU the yields were 20 higher

than with basal applications of urea and in the three experiments in

which urea applications were split yields with SCU were 18 higher than

yields with split applications of urea When comparing the average Nshy

response (kamp grainKg N) yields were increased 13 more by SCU than by

basal applications of urea

The data from one experiment with light irrigated rice in India

are given in table 4 yields were relatively low and differences between

N sources or method of application were not significant However yields

with SU tended to be higher than when all urea was applied at planting

but lower than when split applications of urea were applied Again yields

increased more than 13 more with SCU than with basal applications ofwere

ur

In tables 5 and 6 the yields of a short-duration transplanted

rice grown in irrigated light-textured soils at five locations in India

indicate that higher yields were obtained with SCU than with urea when apshy

plied as a basal application Yield increases due to basal N applications

were 502 greater with SCU than with urea However split applications of

resulted in yields equal to those obtained with basal applications ofurea

CU

The yields of direct-seeded upland rice grown at three locations

to India are given in table 7 and the relative yields in table 8 Yields

were low due to drought but good responses were nevertheless obtained for

- 25 -

Table 3

Effect of N Source and Time of Application on Yield of Paddy (Flooded) Rice in India 1972 (Summary of Reported Data from 4 Experiments)

Experimental Number Source Rate Method Yield Relative N-Response

and of of N of Yield Kg Grain

Season Nitrogen kgha Application mtha Kg N

- - - 196 34 -

Urea 120 Basal 573 100 314

11 Urea 120 80 + 40 611 107 345 Rabi SCU 120 Basal 713 124 430

12 - 0 - 202 30 -

Urea 125 Basal 682 100 384

Rabi Urea 125 35 + 20 + 35 + 35 633 95 344 SCU 125 Basal 781 115 463

13- 0 - 168 44

Urea 100 Basal 385 100 217

Kharif Urea 100 30 + 20 + 25 + 25 400 104 232 SCU 100 Basal 462 120 293

14 -

Urea -

125 -

Basal 355 650

55 100

-

236

Rabi SCU 125 Basal 781 120 341

-- 26 -

Table 4

Effect of N Source and Time of Application on Yield of Light Irrigated Rice in India 1972 (Summary of Reported Data From

One Experiment at Pattambi)

Experimental Number Source Rate Method Yield Relative N-Response

and of of N of Yield Kg Grain Season Nitrogen (kgha) Application (mtha) Q) Kg N

38 0 - 204 85 -Rabi Urea 120 Basal 241 100 308

Urea 120 60 + 0 + 30 + 30 267 ill 525 SCU 120 Basal 255 106 425

Table 5

Effect of N Source and Time of Application on Yields of Short-Duration Transplanted lice Variety Grown on Irrigated Light-Textured Soils at 5 Locations in India 1972

(Snmzarized From Reported Data)

Rate Grain Yields (MtHa) Source of N Method of N GrainI of N kgh Application Faizabod Karjat Mandva Pattabi laya Averaje X

- 291 266 211 19 340 260 -

Urea 100 Basal 386 407 361 285 482 3 124 Urea 100 50 + 25 + 25 399 430 434 334 6amp2 4A8 186

SCU 100 Basal 368 468 439 360 572 41 181

Table 6

Effect of I Source end Tlae of ApplIcattoo c RIstave Tle24 of a rt- rat1 T Lsd lice Vasrety Crin o Irrigated L41tshy1 at S Locitite mindi 1972

Rate ____________14_3

Source of X N~tbad of Of X An 1 tat14 1 acr X__T1 4v tatW ttva

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- 38 -

Table 18

Yild of aemati-370 Rice at Punjab Agricultural Research

Institute in Pakistan in 1969-70 Grown Under

Couditions of Intermittent Flooding

Pate of application

=IL

o 0 67 67 100 100 67 67

100 100 67 67 200 100

Average for Sources

Ntha

AS 260 gres 279

320

Source f5

-

AS AS Ura Urea SCU SCU

Yield

Relative

93 100 115

(M)O

Yield

Increase Yield Due to N

(Ktlha) (mtha)

-212 245 033 274 062 260 048 297 085 315 103 325 112

Yield Increase

Relative

72048 067 100 108 161

(2)

- 39 shy

Short-statured high yielding rice varieties grown extenshy

sively in northern Peru require extremely high rates of conventional

N sources to achieve maximum yields The recovery of applied N is

extremely low due to the use of intermittent flooding This water

management system results in heavy N losses even with properly timed

split applications In search of simpler and more effective methods

of N management eight field experiments were conducted in the region

to evaluate sulfur-coated urea (SCU) an experimental slow-release N

source supplied by the Tennessee Valley Authority Rice yields were

increased an average of 59 more by pretransplant-incorporated SCU than

by urea or ammonium sulfate applied in the same manner SCU produced

excessive vegetative growth which resulted in yield reductions at high

N rates

Regardless of an assumed 48-higher unit N cost in SCU the

overall benefits of pretransplant-incorporated applications of SCU

were favorable since there was a decrease of 40 in the optimum rate

of N and the need for precise timing of application was eliminated

Pakistan--In Pakistan basal applications of AS urea and

SCU to rice grown under conditions of intermittent flooding in 1969-70

(table 18) indicate that SCU is a superior source of N as compared to

urea or AS when all N is applied at or before planting The data also

indicate that a yield response was obtained for P applications but a

comparison of N sources at each level of P indicates that no interaction

between N and P was present so that differences between N sources were

relatively the same at each level of P Yields were increased about 60

more when SCU was applied than when urea was applied Yield increases

with AS were only about 72 of the increase obtained with urea these reshy

sults do not agree with the generally-reported superiority of AS as comshy

pared to urea as a source of N for rice

- 40 -

In 1973 experiments were conducted in Pakistan using both

Basmati-370 and IRRI-6 varieties of rice grown under conditions of

When all N was applied at puddlingintermittent flooding (table 19)

or 12 at puddling and 12 at panicle initiation both AS and SCU were

superior to urea with SCU tending to be the most efficient source

However when N was applied 12 at transplanting and 12 at panicle

initiation SCU was the poorest source of N This would indicate that

the release of N from SCU applied at these times is too slow for optimwn

plant growth

In another experiment in Pakistan in 1973 no differences

in the effectiveness of urea AS or SCU were noted in the yields of

continuously-flooded rice (table 20) Again these results are conshy

sistent with earlier results which indicate no superiority for SCU

when rice is continuously flooded

Nitrogen Studies--Maize

A series of three experiments were conducted by IITA in

armo-Nigeria in 1972-73 comparing AS urea SCU and

CAN (calcium

nium nitrate) as sources of N for maize (table 21) A significant

yield response was obtained for N at each location but no conaistent

differences were noted amaong sources These results are consistent

with results at other locations which have not shown that SCU is a

superior source of N for maize grown over a period of 3 to 4 months

Nitrogen--Wheat

The yields of wheat in Pakistan in 1969-70 (tables 22 and

23) show that yields with SCU) tended to be lower than those with ureaJ

although at one locction where sorghum was grown followilng wheat with

Table 19

Yields of Basmati-370 and IRRI-6 Rice at Punjab Agricultural Experiment Station in Pakistan in 1973 Under

Conditions of Intermittent Flooding

Rate Yield Source of N Time of Yield (Mtha) Increase of N B-370 IRRI-6 Application Basmati-370 IRRI-6 Average (Mtha)

0 0 - 21 353 287 -

SCU 90 150 At Puddling 325 545 435 148

Urea 90 150 At Puddling 309 500 405 118

AS 90 150 At Puddling 324 529 427 140

SCU 90 150 Puddling 372 572 472 185 Panicle Initiation

Urea 90 150 Puddling 335 502 419 132 Panicle Initiation

AS 90 150 Puddling 353 529 441 154 Panicle Initiation

SCU 90 150 After Transplanting 312 562 437 150 Panicle Initiation

Urea 90 150 After Transplanting 340 624 482 195 Panicle Initiation

AS 90 150 After Transplanting 349 583 466 179 Panicle Initiation

All plots received 45 lbs P205acre as single superphosphate

Relative Yield Increase ()

Source of N At Puddling Puddling Panicle Transplant h Panicle

Urea 100 100 100 AS 119 117 92 SCU 125 140 77

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forgof wee aMW pbsepbots A fths pemhawe evsielew us

Odellod to detMlee it otteettvmm of 11agotated Stoture of

mmfp MW phapa A (CI) sed graewletod pampAtlti arlolatod Pa

asowcs of P tof ttde ro The wreem proucts omre raGther

pemour~a ot P syag besmti andMi as elt ov so gpamwhr

iuipiqffhate(TS) low twseeo Is eftwiltve Is thet

W41 preeme wae oialain ire post-rItoi effriq to Stanlato the

pud6itt of Irto paddle Wee ofsdlseireplastiq

0 49 shy

lbs partially scldiaatede grawilated Ml prodlucts Vere isshy

toiwdiats in 5tftOvttWS54 betwee wroiPi ad TVP NotV5Ymf to

me coo were they mere twoe $a a etfective ao TIP 00 sipifleast

LVSUMI5 at0 efecto wore toun tor thee produteo Timely dtIampWde

FR (-t00 mmoh) Uia amp~rally oar affective than Owe gra8448r FOampprodt

featal twos o 6 aotetire s I

Nowvero it to felt that sfortber field euprtet vth

hese interials Amd ether typs of grometatodl Wter nre wrrautad

hater ceeuwodh that they have me areec poteatlal toi additoG

e tate wAne the sectte as OtawrI sed bovoloen turther

euperimeste vth few reck pboophar s0d with reck pbophat treated

to sehesa citrata selmtliy or to ha csaducted

Metbir sertes of tbme enprtaeats wae c~edtmcted by IITA

to Ut~rta copal TVP AOP APP aed it at see tecastisix (table 14)

No dot lalt sewseltles teh draw tree thee results simouely em pear to tlvdl bsww they do stwgpt tbat forthew work with

MR to werramid so tbme sels

Table 24

LttcttF Swce MaPlate 06 ieldot IM AWaia CoelsANS at IITA (Ugboda ad Apoin ail sorit) aid at Ike (AUaba s5i series)

1973

Plate ot IP Apinu 5 poundebods A1ab

Ocrol 0 Z94 419 M)

Tr ipl ruprphite 20 349 3799378

Triple vepput 40 M09 410$

Triple 6wp~~b1 4271 4344 42250

Ammotw-ritpophW to 4201 4124 4040

Amosim-rdop~phlt 40 4270 4106 4231

AM tuo-polpephats 20 404 4244 3794

~eai~mpelppepbuI 400)49 4094

Cee m-pbpbt to- 59

momee eph lto 0 4192

LSO (0 0$) 29 1025

Th WPII

- 51 shy

101Y114 tpeM-fI PEP~tbRP YO

1 ~ ~ gmw 1pc~biofl- 9 Kla4v4h

Upia U04 Copfind am Crehout Stet Rpano at (Ia4

rico t IF t rume6 orth~ Caralto phoophale rocl QAR) vaUN pqU41 to

roopon from cmonetrat4 gsporphophai (CIP) who ort$o4 oil k

was 45j itwas tafertor vb protioo4 oil p war OS Ib 4iffer~c

in rtc reepos to X cod14 oo bo ttrit4 4 4 hvsciag of boil p

~ Pt o r11221 0 tP

c theto the rhimecyllndor of rico tots par to)14M4i1 roeoi~t

ed oil emd PA prior to tho ont of an~robi4 cMioe AA~ oIifoshy

nAte bYpot t taet~d tO fC4sin t~r 4PWden0 Of f Ot(tivshy

ofOWailiJtyno o prefla4 all Put that 4t01etoo 14 tvsIk

of the Ott to prvvld a 014for C4m0 44 mI 1 o4sf

EfftC ftPet141on AIAM-0 V f401td 4 4iv 440 Mtft

Aa torfat VampP f4MWfCi4W04wt0amp to 4eturWlI Ot(Wel~drIC ft

Ot f tM6 the flooded Ott 00 14 04019I Pft0uAw Of gAr~s~lr

pkS$t M40b MP) Tw P1101 Piset Prodwie W-e 10M0di Wr04

(10-1) emW 0aretilp ddw01at4 P WAA firom Rrth M~flRU414~$

wee cowiared with fie Md reWim 44104 proo~fo) foruk oith laWItter

I v te-PR P OW1004 4 4 O Wf ottil OW ellt Oo

Oveiel1 the 40tt dmcruie to effetotww Wtollowui Co fme

PR tpaUIB1I ldoltmo PR (pamwlatr) offr~- ArmeuM) 0 orwi

- 52 -

Effect of N Sourc6 and Water Management on Response of Rice

toe Zn- M Giordano J J Mortvedt OP Engelstad and Greenhouse

Staff Several rotes of CO(14H2)2 and (H )2So4 vith or without ZnO

wore applied to flooded and nonflooded Crowley oil (limed to pH 75)

to determine response of Bluebelle rice to Zn Yields with both N

sources veotrgreator on flooded then on nonflooded soil In the abshy

ence of applied Zn total dry matter production vith CO(NH2)2 was

slightly lower than with (NH)2S04 on flooded soil and considerably

lover on nonflooded soil Concentration of Zn wan higher in straw and

grain of plants roun on flooded than on nonflooded soil Although

concentration of P was unaffected by N source or Zn rate there was

som indication that cranslocation of P from straw to grain may be

depressed in nouflooded rice Concentration of N was lower in straw

grown on flooded than on nonflooded soil due to apparent dilution

thereas both X sources resulted in similar N concentrations in straw

at all rates of N application the N concentration in grain increased

with 0 rAse

feSpongi gf(SM to Chjorospodiostte and Related P Sources--

Si Allen and Greonhoue Staff A greenhouse pot experiment was

couct44d with corn Brown on Hountview silt loam to compare the ofshy

fectlivees of chlorospodiosito (Chlor-l) with concentrated supershy

phosphate (CP) Thomas slag and North Carolina phosphate rock (NC-PR)

Oil-prillad urea-phophato rock (UPI) FeA1JMP 20 7 and monomthyl

phosphate were included in the experiment Based on yield of forage and

uptake of P by tvo crops each of 6-weeks duration the following conshy

stui were dravat

I Chlor-1 was slightly loss effective than CSI Thomas slaS or NC-PR

from which Chlor-l wae prepared

- 53 shy

2 Granular UPR was a poor source of P its effectiveness was greatly

increased by reducing the particle size to -35mesh

3 FeAlNH4P207 was unavailable to the crop

4 Monomethyl phosphate was equivalent toor slightly more effective-

than CSP

Research Indirectly Related to TVA-AID Project

Response of Several Rice Varieties to Zn in Moist or Flooded

Soil--P M Giordano J J Mortvedt and Greenhouse Several varieties

of rice from Mexico and the Dominican Republic currently under investishy

gation in Puerto Rico for adaptation to upland culture were compared with

some established United States varieties with regard to Zn response on

moist and flooded Crowley sil (pH 75) Chontalpa (Mexico) Bluebelle

(Texas) and Starbonnet (Arkansas) were most responsive to applied Zn

Juma (Dominican Republic) intermediate and Sinaloa (Mexico) and Calrose

(California) were the least responsive The Sinaloa varieties (Mexico)

appeared to be best adapted to non-flooded conditions whereas Chontalpa

and Calrose were poorest Concentrations of Zn generally were higher in

plants grown on flooded than moist soil

Pattern of Growth and Zinc Accumulation by Rice--P M Giordano

J J Mortvedt and Greenhouse Staff Rice plants were harvested at weekly

intervals from shortly after emergence through maturity The objective

was to determine the rate of growth and Zn uptake by a Zn responsive varshy

iety (Bluebelle) and a less Zn-responsive variety (Calrose) in the presence

or absence of Zn applied to Crowley sil (pHl 75) Dry matter production

of Calrose was linear with time of growth and of a similar magnitude until

heading with or without applied Zn Bluebelle followed a similar pattern

where Zn was applied However in the absence of applied Zn foliage yield

was reduced markedly

-54

Uptake of Zn was similar for both varieties whenZn was

applied Dry matter production and Zn uptake by the two varieties

also were comparable when Zn was applied However yield of Calrose

was much higher than that of Bluebelle in the absence of applied Zn

while Zn uptake was only slightly higher This suggests that the lesshy

ser responsiveness of Calrose to Zn may be due to more efficient utilishy

zation of Zn There was no indication of a greater demand for Zn durshy

ing reproduction in either variety as was suggested in earlier greenshy

house experiments

Response of Upland Rice to P and Zn--P M Giordano J J

Mortvedt and Greenhouse Staff Several rates of P and Zn were applied

to Crowley sil (limed to pH 75) in factorial combination to determine

whether differences in rice growth under flooded and nonflooded soil

conditions are related to plant nutrition Although straw yields were

slightly higher in nonflooded rice receiving adequate P and Zn grain

yields were higher in the flooded crop increased rates of F andor Zn

did not result in equal yields Except in the highest Zn rate (75 mg)

concentrations of Zn in both straw and grain were higher with flooding

Concentration of P increased with rate of applied P and was higher in

the grain or flooded than upland rice at a comparable P rate In conshy

trast concentrations of N were lower with flooding due in part to dilshy

ution from increased growth

Rice Response to N and P in Flooded and Unflooded Cultures--

G L Terman S E Allen and Greenhouse-Analytical Staff Rates of

N from 250 to 2000 ntpot and P from 0 to 1000 mtpot were applied for

Nato rice grown on Mountview sil and Sango sicl (625 kg of soil per

pot) Market yield response to N and P was obtained Yields of straw

- 55 shy

total yields N uptake and N recovery were higher on unflooded than

on flooded soil cultures Grain yields however were slightly higher

with flooding These results indicate that with adequate applied

nutrients especially of N rice yields without flooding can approach

or even equal those under flooding

Uptake of N P Ca Mg and Zn increased with yield response

to N and P while K uptake decreased on the Mountview soil Concentrations

of N and P increased with applied N and P respectively while concentrations

of other nutrients were diluted in most situations with yield response to N

or P

Results from this experiment show that amouats of N applied in

previous pot experiments for rice have been much too low especially if the

crop was grown to maturity

Response of Corn to S and N i UUASand Urea-S--S E Allen

and Greenhouse Staff Three greenhouse pot experiments were conducted to

measure response to S and N in ulfur coated urea (SCU) urea amonium

sulfate (UAS) and urea -S as well as estimate N losses from surface apshy

plied N sources

In Experiment 260 less than 20 of the S mixed with the soil

was recovered from SCU or urea-S granules by two crops of corn as comshy

pared to 45 or 80 from flowers of S or Na2SO 4 CLop response followed

a similar pattern

In Experiment 260-A N sources were surface applied and alshy

lowed to dry for two weeks before incorporation Into the soil and plantshy

ing Recovery of N by two crops of corn was 77-82 for AN an compared

to 37-70 for urea UAS urea-S and ICU Thus n this experiment loss

of N from urea did not appear to be re~dcud by light S-coatlngn or by Inshy

corporating S or AS in the granules

-S -

I xbprZnSlt a Wtch aU Meyto 0-Ai Wt f9r

higher reermo teOrtOrs cOM reSpWNO i r0100 Of N w

not oaisteontly related to sewe ot N In edl tust 0 ioltiUe Lim

lo in VMuwpped evlmtUTS 48 merind by seirest nte appresOehe

501 for uroa as cwarod to 210 for urea peepha

Rus- or Upse to LoAmIl34I a AriMed bI Earl U

MW NOWlsIIsIr-4 L Toman 5 1 Alln and eesese StNf rio

row on Sawg did (0 tpot) We 1l0l0 Ws feritiud vith 05is

of Npot mixod with the 6011 as aureCA NiAO) 1 Age god At Ures

was also itcluded at rtt t 05 10 end 15 of Upee Theas trealshy

onto were followed 4 wpdrsetago of U s AN wre 4C 10o or at I3n

Weeks toulin up to IS pot

A soil application of 10 pot rosulvod to the maim yield

at 4 weeks Tio4 sad percont prottis t intre raite tncreased rftishy

linearly with U applictalien IeseeItally all at the m iNd wit

the moil w domitrifted after flooding Grail end straw Ilelds vere

highly correlatod with tiliriag and vlh ubers of gralm arl

The results Widicat that 0$ to 10 a of Upot as orea or

NN bsuld be sied with the oil to stilate tiilrir with adshy

ditional 0 topireased later to increase grain lIds mad protia cmshy

tout

DIVISION 54- FERTILIZER TECHNOLOGY AND USE

N$eumWe of Mt5p4Amomd 1k PindW hswk4PhI fl fRw cW ims we

Jmnwacr VW owm m

a~~00 - 0 6 A-~ -~~ PN 40OMOM X 00 Wolm n moo mot $Pto4I 4l 4 W

1 -0 Is vom omoo ~~o - W1 sfw 4E00-aU

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00 to- W 0Nwo ww AO t

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opoOw suf No~ Ow MW MCI pt~bi asiwhNd bl-d muim of woo w NN

toI4 0 06d 00 wo A Md N WILSAl DuIKWION oo A Nw U am ONq ep

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at MW em matshyW M offm of4 W twampwmwausoo wo asdm65m Auamp Ahbwu in 4ih asTal ON~ al oem IN Maie dmAd A a own did ofe w17 I inM mimman Ofd ofimruwf gas Pius di aMe Kwe auw a dow iNPOOIN tmo a SO$SO~4W

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pro alfp al 0 WN Is obaml~ of th es Wls pouvy Ofts oeWMed N

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40WilinAn 06 kw Ma ho 00 e IW aftakrw splerefAnhffsb m esmem

I$Ow Ip ampMI pasi 1ead eu an Toud 2l

Widj 6vi of V46 745WI KU waso-W im Wow 0 is610SWAOMMwasa to t

VAp 1Mampd KV ppu~s dw whaim $i a a los Al w W

Ib Milvo urns of OWe d- musA as h~ s a IuIow 8 1 ue ip

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el eas goileN ruseW4 wo duffeeme bWOM isttouwi

14 gnp40 woSalrw 11ylo amreu Mwb Isevlow roosmN~ahIt s 60 W ~tsmAIM L n ~ ~~ ~

MM I PWrawA = rMla yowIeM oa

eUW as ymlh OW by IONamph avWlbl N The mubsr 1MM Pude M~ IsA aemOWeld

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por bre

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Tile 4-00dw x uiampOW74u 0qee of

_____k _ _ shy

~ - 56I 5

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irenY w -a

Tiles I sed I thm Au do sel oeppled upaoIks WIM0 0da ispI amd us Ou s 106 kg

h Eaap 8n 14 sMsa of abw~greuad PU Pau WW 1 u itb IUKho 0aaphelem s 60 Otarlmmh At ~ 0sU Ishiseoo Cook oiA N uiplasu mAasslaly abess A leel

v doese a WKWye Is ks Nha m 6 sa4to dafo aONmuw The appee swm Wsssof adde N4 alalaed by vuMb ifaa W C Was sekilumganSro Is

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owdb imto US Wh s vs sf 3I mld 54S fro 2 aMd 3) A A

valves a hevwae u Iar Walh basl oswas dhe uwpatr bshava of

tb~msusasl appkausu of ofta sede s have aoweN

TOW opl taoe for AieweeW 4OsmWMbas Op peas As Tabl 4 sling sob Os awowully eom grams Piel level Thes oeulam Ma sed as IM

-02

792 60L WI W A)49R Pio VOL 37 197)

primS o r OeampAd WU toa Them fl~ w At NOSSe earno maisslea Ia N he mOWamplIO yik ampWd IMe aampWmW OWa Owe wa UMs of KU to 41 Oke ampWiiIamm be dkrnety ewspokawleM(a s8 te camtd wie a eapmoe by TVA pavw ltoi NA poundrmdaka4us vrimeW460 o to ilkidm ofWW (Mtemas MuOwe 1973) TVA mwi bawld on soi ficedims IampWp seg rudwiv s~s0abet ke WNmdoe ON 01 K Is12 NOSW ie fssewnmu Ie I QvaaIi rowp IMA) f9

)amp m lodk byO voebmsaIS8OpeaWfrats 11 OWNmi a I a W idisod 0 81 Now 111 nindat Wm fysmpseaamp (If tsO tUmtI IsM $P shoroV4mmo knflkvnf (foOdme nuw ae Ow OImstwe in SM pnmm8 af tXm 10 114PIS kequoian wo Mpfii

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DIVISION 8-9-SOIL MINERALOGY

Amorphomw CeetIup en XmWra Ssrfmls

L C koits Am~ 0 tmmkaAf

ommp A faieiaAMTRACT skiwe lo nW ampM sm wi4h

Walo by a onMm I dmivid hseidm6Wlk W~edesie s

peuiieles as is s e wpwigstee eded his S -em -om 0641 h4 hisW1mWOWb~ bfem peess Wimm kv Iee

Pa~~~eakr4awiS SeUeeiNaiA WOW 14e

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kog Ii ampI b 1111h1atAmOem aid itsaere~m-aelmoeug toolPe aal 111W mWa Wisg ag so~ ti~Wo booviot65k Th eme Iua 1111411uiwon it es 01000 AW~CWS ~muiseeteqqsheer21111 ionev

oO00 llb K0 ibad~ ~~ doj 140WI s o mimdW um

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lill mi oHow al of a be 1974oyais4gamm wsoc wwo

rdy i of OMAN toblind id sh os 00 IN bei m us salqs m kid Vw 1 a0Msw WFW isms waf e eeiWei he-4~~e gsa dulsi

os 0aMW ofmu WA l aduWs~Ib rowuvvl3maIpm s

CaO~OP aw AlNomI 4ornomd to9 IS is -l O SI g4he rpidyThus whim m dowu bWa 0 m m- ei u

d m M 0bmSaImu M-1 ofM6 h Intun to 7I

aiba maush WAesshwn~u9dSg a osusLwpI ~ v m

M PolsdAvoWdw Ons pugm~ low iwLW m We

of~U -a~ mo uNo

0401ts of 40

A e mun5d m i vvamp sa s ow bftIS i sa omdIs a w

edi1 hswopmo an ag am Iw anom erlwaPASneooie bnwoM po

o ~ do=lr 3s fluACWoSM Owaa VolM Ain b 400b adW g o as amob ofrMOWS A oo eWmaa ow $wofdi60 ow - ema

-v K Vcon l ap ad md ld KU lbs PoabumwA od w to domi a bembe 0b lt $014 i ampmomONo

4st diwemmSod i 6o pa P)ameakiksm4 m 04M t 1iV vs 0606 o IS ft dopsss of q madl w I10000014 t 44hs

arbs awasm 00 iztv Am-~~~i u5~ms ashu is byw

e~ihs diu~wsm ~phid W A0)ad Lobe d mi-~-- 1) 14 hald

bob~wh do is poPbe~mueus l to aVE tumad 40at iai ka as m

bdisc shmm Ammmd a Sm ofd~~~~~d~A ~ a~m olWshmo

OWNSrilgf ms as

Um~~srTmws~of 4 A ad to wy mis itm voW

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e~~Pum-p -f AOACoe~mfmmdso isedp Am PApmi sk adw Wsk m~ o P4 m

- omlos r umIWO1in pw

lie Uvplist i piw S p wsmoW N of t as so in~tabo 440 o rodgAsect M4Ammd meM ii INAq10ed~ Pib mdWWeiW 1w -w emit TU UFm 6AV 0W A fIN 00~ lb 0PANNO 4 drp OW~It~Oi Ofme _____f WACMW0IN WMVsol~lmO ft SNAO 40 do1Si - m Md y e b ii m

of of~phaow tw bmsdf toamplboe

AjflsutomW C1D-pCTP AD mSmZLT op 1 m ow ts Wdm of P om M

IaM 0t sdw a wn a8duws i ofV -w Mm P16I4 TWO a ewu i an

ov4mnk wsi 9 Mxfeu~i am emwm ismi0wmd fq W No ~~ - f mug Aitowe eutlkowbmTV is

amppowftdmi TiM 0 Tie OAA mo p)a Mwomoi dOn4m A)w

MW 0 604 0M mm yaM 01MWOfdi to tA0 M OOAW uinw OSOb

ap is~e I the ampo A A Mwof ~Do toit op aenu w~ifiOimem~ MAN ampW)

ItsAO se Y lieowawo u~w pkow-W1b pwf on a C Nohkw is f 0o1 s do~omW C mmU4

owud6moeft 4 Obind PINa~e

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~ -0

65

0IL CL OC AMXR PROC VOL 38 1974

)aT1 S4I104 ow Lusanll Tawng isa tall Thai variety known for beingIwo nonshyi s s ) sensitive to photoperiod A split-plot design was used in

S e e these euperimeots with 4 rates of P (I1 22 44 and 88t i V IV k of Pha) applied a main plot treatments and with the OF It sourMes of P as subplot treatments There were two checkS plots in each rmplicate The extra check plot was included to permit the application of fresh TSP standard Jor the

It- ti 06 + i bull fa succeeding crop the p-4me of bi was to permit accurate d awrnwal of the mdual effectiveness of the phosphate

ftinSUbI rock The P fertilioers were broadcast on the mud andthen Worporald In the soil during the last harrowing At

whM N both On ACS indx ampM time of transplanting Immediately before the last harrow61t (4j 5 4 01 P s 3Mm o Vallonal in con n 100 kgha of N as ammonium sulfate and 33 kghaWO Of Spews ampm lIW thaabe rocks do ACS indes of K as polium chloride were applied A total of 40 wa in prepw O do ctih k otent kha of N a ammoniunt sulfate was applied later in twoir P The hew oNed amp wM W for 5 of gw topdrossingp with about 5cm depth of water on the plotsvV I aiOMveffeOctveee Three to six ldayold selings pr hillwW the ACS idex were planted00OWW wia Oft fo an c irNk I p Coen 20 by 20 cm part in straight rows Hand weeding was used

and insecticide were applied for Insect control Grain yieldw was masared by sampling 5 ml of each plot excluding border rows The date of heading in each treatment and theUNiN d pbM W Weks rin tOW USA UMe In Tale yed componnts at hafvel were also recorded

I filM rsperMS esOM kdwdua 1 t ab The average yields of ough (unhulled) rice for botha 84 OW O 8uo 4 Thala TM was a locations are ploutel in PIS 3 for the first crop (1969 wet

owou thRM seaso0) The Veamps yield response was obtained at Klonge (s) W lDtO t Of dMa of1tw W d l R Luang however a 4ute satisfactory yield response was

~Mk ^d TVA UJSD ad Kd UnIveS obtalned to applied P at Bangkhen as wellXUe LaM e R qwrw Ims The sod was do Relative aponomlAe effectiveness values were calculated

VOW (a ksA w edmwL t Poesesm h Vy for these data and am presented In Table 3 The valuesdAY buo if dIe ouh ne Pee wtk a Mlak vow 1009 for th first crop are plotled against ACS index in Fig 41 This Im M i6ti l 4bNd IO a0 O mkarnk for both locatio r relationship was linear for the

11400 ThCpH 0( lb pW IW 01 th UpeiaW so Sanodion location and curtiltnear for KIng Luang The was u i 4A sksamp lMaor nrusio model amparounted for 81 of theAmO$MI Aw jAAsue Swim T1 Snh Wd variation In the AE valu for Bantkhen a square root

Mems a Iw iv fern alh$ sedm haowg dayNW W t he plAL At tdo M tM aso W s as ctminued throufh eltaM t Ofpof -le lse wo am P OeNI VeOpls 1o ealluae tI lon4erm MIdual Offccls

A on W isset i a wse to hsh eapeel of these ooihss t ocks The baagkhon experimnent was letmiaI1DlVemisthis is a w hulu Lo g Tasug ia iasael aft - Msd residual Ves will be pr-Om crok TheseTwod esewm

SWWo

A

lP~U~7 ISIIPe1iuIWN e bsedisssin ian ghth siaoelalbe

984 0 6 O O - M s -s fWPas 11eSft W d Uo al a o

o

S4l~ lIIII I~l I 1f fl

( +

+ + + m + ++++-

++ +(++ + ++++ + ++ ++

- 66 -

ENOIMLSTAD ET AL RESPONSE BY FLOODED RICE TO PHOSPHATE ROCKS VARYING IN CITRATE SOLUBILITY

I I I I j0 I I

BANOKHEN BANGKHEN

pH 56 6 - 0o

TSP

NC

5~ ~ ~ L o 4 - -shy

4 ] - --------shy04

6S

|0 III 2 44 8r 66

I I I

a 1KLONG LUANG

pH 46 z KLONG LUANG

TSP Sc2 NCFL(N)

5 FLIC) J0 TU

oshy

4 ~40shy

3 bull eM0

I - I I I I I

0 II 22 44 88 0 5 10 15 20 IP APPLIED KO HA ABSOLUTE CITRAE SOLUBIITY INDEX

Fig 3-Yield of rough rice at Klong Luang and Bangkhen Rice Fig 4-Relative agronon effectiveness () of P sources ploz-Experiment Stations Thalmand as affected by rate and Source ted against citrate solubity Index for both Thailand field ex

of P applied (crop 1) periment (first crop only)

regression model accounted for 97 of the variation in sumably resulted from crop uptake and reaction with the RAE values at the Klong Luang location soil to form less soluble products Such effects may have

These experiments were continued during the dry season been more important at the lower rates since the two TSP of early 1970 to ascertain the residual effectiveness of the curyes converged at the highest rate of application various sources applied to the first crop No new P was These data from KIong Luang indicate that (i) residual applied except for the fresh TSP standard mentioned effects of all rocks except Mlcwuri were substantial (ii) above rhe experiment otherwise was conducted in a man the relationship between relative agronornic effectiveness ner similar to that followed in the first crop of the phosphate rocks and citrate solubility levels was

The response to both freshly applied ad residual P was largely obscured and (iii) the general superiority of TSP marked at the Klong Luang location and marginal at over phosphate rock in terms of effectiveiss persisted Bangkhen In fact at the latter location the response was through the second crop so small that little can be said regarding residual effectiveshyness The yield data from crop 2 at the Klong Luang DISCUSSION experiment are plotted in Fig 5 Greenhouse and field data presented in this paper show

Relative agronomic effectiveness values (Table 3) were clearly that there are substantial differences among phosshycalculated for the Klong Luang data using both the residual and freshly applied TSP as standards It is of Interest to note that the superiority of TSP over the phosphbte rocks Table 3-Relative agronomic effective values for field experishyments in Thailand persisted through the second crop The main difference in KlowlZmlnql~the residual effects is that with the exception of the MIs- s Crop 1 Crop 21 Crop 1-shysouri rock Ihe marked relationship between citratr-soluble WoiCarolina yl 59 76

phosphate rocks and RAE had largely rds norh) a 64P conltct of th Florida (eqlral is 6969 6

disapipeared In this acidic soil (pHi 46) P would by this I14o 69 63 40 ToonesS 31 65

limo be supplied by Intermediate reaction products In addl Missou 0 o lion to residues of the initial spatlte Ts P o 2 o 0

The TSP applied to the first crop declliv-d slightly In campIafcmWataesr e id ofeuhuloefor 22MA rates of PtColeouattd as aba u tlte td18 kS ratesp dlverage yield tM868 to 22 44

effectiveness relative to the freshly applied ISP This pre- of d s4

A

4

- 67 shy

-SOIL SCL SOC AMER I

KLONG LUANG CROP 2

Si 3

eN

TAPPLIEDKGHA

Fig 5-The residual effectiveness ovarious P sources for crop s compared with freshly applied TSP Klong Luang Rice

Experiment Station Thailand

phate rocks in terms of agronomic effectiveness for flooded

rice Further these differences can be predicted by means of citrate solubility or by the ACS index It appears that

the latter is more appropriate where the content of apatite varies among phospiate rocks The most soluble phosphate rocks approached but did not actually equal TSP in limit-iuig (maximum) yield in these experiments regardless of rate applied This agrees with the results of Ensminger Pearson and Armiger (4) One needs to consider the defi-nite posribility of same yield loss in zhoosing a phosphate

rock over TSP such yield losses must be weighed against the lower price of phosphate rock The explanation for such iosses may involve concentration of soluble P in the soil Khasawneh and Copeland (6) suggest that the growth rate of crop plants is a function of P concentration that can be maintained in the soil solution If P concentration is limiting or inadequate becawe of a lower dissolution rate of phosphate rock the growth iate ard uiiimate yield will be diminished accordingly

The RAE values bascd on yield increases reflect the agronomi effectiveness of these various sources relacve

to the TSP standard however these nould be supple-

mented by an economic analysis before rational choice can

be made The following calculations will provide an estimate of

the rclativ ecooomic effectiveness(REE)

Y t Ps aXpatREE -- 100

vahtercks t sphate or e b i- eor

Price of TSPkg fo

be Price of PRkg P

PROC VOL 38 1974 leO

90r

Wsoshy

0

60-LUSEPHOSPHATE ROCK

00 10 20

PTP PR

Fig 6-Relationship between relaZive effectiveness values (RAE) and the price ratios between TSP and phosphate rock Such a figure can be used in making a choice between these

sources

If REE exceeds 100 in this calculation the phosphate rock would be preferable to TSP

The REE calcuktaaa wre used in preparing an indifshyference curve (Fig 6) wherein RAE values are plotted

against PTsPPpR ratios The cu~rve itself connects those points at which REE equals 100 When exactly on the curve it makes no real economic difference what source is chosen After choosing a suitable price ratio one can then project upward from that ratio knowing the RAI

value (or estimating it from such data as shown in Fig 4 using citrate-soluble P content) one can then choose the source on the basis of both agronomic and economic conshysiderations For example if the price ratio is 25 and the RAE value of the phosphaite rock is greater than 40 the rock phosphate in question would be used However if the RAE value was less than 40 TSP would be a better choice There are indications that if the P in the more soluble phosphate ro~cks (North Carolina north Florida central Forida) is less than half as expensivz as that in TSP these rocks would be feasible altereaives to TSP on soils similar

to thoseused in Thailand This analysis does not take into account the possibility

of lower yields from use of phosphate rock In addition only a portion of the various yield response curves was used in this anlysis ie up to 22 kgha Beyond this

rate yield response was much less pronounced it could be argued that at less than maximum yields TSP would produce a certain yield at lower rates of P than would phosshy

pow ofrock This would especially be true for rates applioa example at Klong Luang 5500 kg of

rice pcr iectare could have been produced with either Ii kg of P as TSP or 44 kg of P as son of the more reacshy

tire phosphate rocks It should be pointed ot however

- 68 shy

(IIKIS amp YOUN( ARIFICIAL WEATIIERING OF OXIDIZED p[ll- IV

that this is the yield level that would show the widest difference such is the advantage of hindsight

Farmers generally prefer granular fertilizers for machine

or hand application This is a disadvantage for the phos-phate rocks which are normally arplied in finely divided form Recently experimental quantities of granular urea-

phosphate rock mixtures have been made by TVA Results of trials with these fertilizers will be reported elsewhere

LITERATURE CITED

1 Armiger W H and Maurice- Fried 1957 The plantavailability of various sources of phosphate rock Soil Sci Soc Amer Proc 21183-188

2 Bengston G W E C Sample and S E Allen 1974 Re-sponso of slash pine seedlings to P sGurces of varying ci-trato solubility Plant Soil (In press)

3 Caro JIt and W Hill 1956 Chard eristics and fer tilizcr value of phosphate rock from different fields J Agr Food Chem 4684-687

4 Ensminger I E R W Peirson and W II Atmiger1967 Effectivencs of rock phosphate as a source of phosshyphurus for plants US Dep Agr ARS Bull 4112S

5 Engelstad 0 P J G Getsinger anid I J Stangel 1972 Tailoring of fertiliers for rice cnnece Valley Author ftyNational Fertilicr Developmnent Center Hull Y-52

6 Khasawnch F E and Jane P Copcland 1971 (otton root growth and uptake of nutrievos relation oif phosph

rus uptake to quantity intensity and buffering capacit) Soil Sci Soc Amer Proc 37250-254

7 Lehr JR and G H McClellan 1972 A revised lIbora tory reactivity scale for evaljativg phosphate rocks for direct application Tennessee Valley Authcrity National Fertilizer Development Center lull Y-43

H Terman G L S EAllen and 0 P Engelstad 1970 Response by paddy cice to ratcs and suurces of appliedphosphorus Agron J63390-394

DIVISION S-9-SOIL MINERALOGY

Artificial Weathering of Oxidized Biotite IV The Inhibitory Effect of Potassium on Dissolution llate

R JGILKES AND R C YOUNG2

ABSTRACT

Rates of dissolution of oxidized biotites in OIM 001M ICI are severely depressed in the presence of IM KCI The amovnts of Al Mg Mn dissolved in the first eytraction are similir to those found without KCI however subsequent extractions remove these elements at 10-20 of the corresponding lICI rates This effect may be due to a decreased rate of vermiculite formation thereby reducing the effective basal area exposed to attack A decrease in dissolution rate with increasing ferric iron content was still apparent in the presence of IM KCI

Additional Index Words X-ray diffraction infrared aborp-

N EARLIER papers of this series the tole of biotite in soils

as a source of both macro and micronutrient elements

has been discussed ((Gilkes Young and Quirk 1972 1973ab) Experiments in artificial weathering uiing as va-

riety of extractants were undertaken to determiie the inlu-

ence of oxidation of octahedrally coordinated iron on the bull release of structural cations to solution The results of this

work demonstated that biotite behaves anomalously with respect to the other common ferromagnesian minerals found in soils Oxidation leads to the development of a high degree of resistance to cation exchange and dissolution Several authors have coiwludcd that decreased rates of K

Contribution from the Dep of Soi Science and Plant Nutri-tion Institute of Agriculture Univ of Western Australia Ned-lands 6009 Western Australia Received 29 Sept 1973 Ap-proved 8 Jan 1974

2 Senior Lecturer in Soil Science and Research Officer respeclively

replacement in electrolytes shown by oxidized biotites are

a result of the inclination of structural hydroxyl adjacent to newly created trivalent iron or vacant octahedral cation sites (Robert and Pedro 1959 Barshad and Kishk 1968) Gilkes et al (1973b) suggested that decreased rates of disshysolution of oxidized biotite in 0001 0t)l 0Af CI may also be due to the presence of inclined hydroxyl In this case a smaller surface area external and exposed intershylayer may be available for attack if K replacement by hyshydrogen ions occurs at a slower rate in oxidized biotites

Gastuche (1963) has shown that significant dissolution ofthe (IIM) biotile face may occur and it is easily demonshystrated that the proportion of exposed (001M) face in weathering biotites depends on the percentage K replaced

Rausell-Colom ct al (1965) have shown that hydrogen ions act in an identical fashion to metal cations in K exshy

change from micas In particular exchange c-f K by hydroshy

gen ions will be terminated or greatly reduced by high levels of K in solution Thus if dissolution of oxidized biotite by

acids is carried out at sufficiently high K levels to prevent vermiculization any differences in dissolution rate that may occur cannot simply be ascribed to differences in rates of K replacement The following results were obtained from such an experiment which unlike the experiment described in Parts I and II (Gilkes et al 1973ab) does not attempt to simulate natuiral - conditions

MATERIAILS AN) M HIiODS Further subsamples of the less than 0 hiotites used in K

excherandbaid disoo tu es (G iles e9n K exchange and acid dissolution studies (Gilkes et al1973ab) were used in these experiments Preparation of sequentiallyoxidized biotites without intermediate vermiculite formation is

Page 25: I70 - United States Agency for International Developmentto ascertan, but tgl.eetad, 1, L,. ("Tailoring of Pertiltiters for ice,'" TVA ulletin Y-52) states that the staft of IOi has

TOM I

Cs VWA1 t lw Vairtile ot P44Y 44c KW MI1

fiat Wm~~JL U Lem~ampuJampAJ Wat IO

~ 941~1 41 ~~~~j~~qt~~8IJ WtS dobu

Table 2

Mttct of 0 Sourco aampW $At On Upt~ks of 0 by Two Varitgtos of Paddy Rice

gr~a 1971

~ MMUampL~ ~L ~ nYLALI~ 11 lemall

I ie

W0 v slit III I) tQo9

KvN 1 17 111 1119

or 444M7

111a

i1$0N ~ It$ 121

1$

x IV ~404 tot Vsr 1 P1 41 w otv 1

- 24 shy

India--The results of four experiments conducted with flooded

transplanted rice in India by the All-India Coordinated Rice Project

Hyderabad are given in table 3 The response to N was excellent the

yield without N being only 41 of those obtained with basal applications

of N as uza With basal applications of SCU the yields were 20 higher

than with basal applications of urea and in the three experiments in

which urea applications were split yields with SCU were 18 higher than

yields with split applications of urea When comparing the average Nshy

response (kamp grainKg N) yields were increased 13 more by SCU than by

basal applications of urea

The data from one experiment with light irrigated rice in India

are given in table 4 yields were relatively low and differences between

N sources or method of application were not significant However yields

with SU tended to be higher than when all urea was applied at planting

but lower than when split applications of urea were applied Again yields

increased more than 13 more with SCU than with basal applications ofwere

ur

In tables 5 and 6 the yields of a short-duration transplanted

rice grown in irrigated light-textured soils at five locations in India

indicate that higher yields were obtained with SCU than with urea when apshy

plied as a basal application Yield increases due to basal N applications

were 502 greater with SCU than with urea However split applications of

resulted in yields equal to those obtained with basal applications ofurea

CU

The yields of direct-seeded upland rice grown at three locations

to India are given in table 7 and the relative yields in table 8 Yields

were low due to drought but good responses were nevertheless obtained for

- 25 -

Table 3

Effect of N Source and Time of Application on Yield of Paddy (Flooded) Rice in India 1972 (Summary of Reported Data from 4 Experiments)

Experimental Number Source Rate Method Yield Relative N-Response

and of of N of Yield Kg Grain

Season Nitrogen kgha Application mtha Kg N

- - - 196 34 -

Urea 120 Basal 573 100 314

11 Urea 120 80 + 40 611 107 345 Rabi SCU 120 Basal 713 124 430

12 - 0 - 202 30 -

Urea 125 Basal 682 100 384

Rabi Urea 125 35 + 20 + 35 + 35 633 95 344 SCU 125 Basal 781 115 463

13- 0 - 168 44

Urea 100 Basal 385 100 217

Kharif Urea 100 30 + 20 + 25 + 25 400 104 232 SCU 100 Basal 462 120 293

14 -

Urea -

125 -

Basal 355 650

55 100

-

236

Rabi SCU 125 Basal 781 120 341

-- 26 -

Table 4

Effect of N Source and Time of Application on Yield of Light Irrigated Rice in India 1972 (Summary of Reported Data From

One Experiment at Pattambi)

Experimental Number Source Rate Method Yield Relative N-Response

and of of N of Yield Kg Grain Season Nitrogen (kgha) Application (mtha) Q) Kg N

38 0 - 204 85 -Rabi Urea 120 Basal 241 100 308

Urea 120 60 + 0 + 30 + 30 267 ill 525 SCU 120 Basal 255 106 425

Table 5

Effect of N Source and Time of Application on Yields of Short-Duration Transplanted lice Variety Grown on Irrigated Light-Textured Soils at 5 Locations in India 1972

(Snmzarized From Reported Data)

Rate Grain Yields (MtHa) Source of N Method of N GrainI of N kgh Application Faizabod Karjat Mandva Pattabi laya Averaje X

- 291 266 211 19 340 260 -

Urea 100 Basal 386 407 361 285 482 3 124 Urea 100 50 + 25 + 25 399 430 434 334 6amp2 4A8 186

SCU 100 Basal 368 468 439 360 572 41 181

Table 6

Effect of I Source end Tlae of ApplIcattoo c RIstave Tle24 of a rt- rat1 T Lsd lice Vasrety Crin o Irrigated L41tshy1 at S Locitite mindi 1972

Rate ____________14_3

Source of X N~tbad of Of X An 1 tat14 1 acr X__T1 4v tatW ttva

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Tabl I

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W Iotors Ftslanp tospg Irritd for Two thvk Afler flontiw wft rkwa~ Floo4d 191)

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- 38 -

Table 18

Yild of aemati-370 Rice at Punjab Agricultural Research

Institute in Pakistan in 1969-70 Grown Under

Couditions of Intermittent Flooding

Pate of application

=IL

o 0 67 67 100 100 67 67

100 100 67 67 200 100

Average for Sources

Ntha

AS 260 gres 279

320

Source f5

-

AS AS Ura Urea SCU SCU

Yield

Relative

93 100 115

(M)O

Yield

Increase Yield Due to N

(Ktlha) (mtha)

-212 245 033 274 062 260 048 297 085 315 103 325 112

Yield Increase

Relative

72048 067 100 108 161

(2)

- 39 shy

Short-statured high yielding rice varieties grown extenshy

sively in northern Peru require extremely high rates of conventional

N sources to achieve maximum yields The recovery of applied N is

extremely low due to the use of intermittent flooding This water

management system results in heavy N losses even with properly timed

split applications In search of simpler and more effective methods

of N management eight field experiments were conducted in the region

to evaluate sulfur-coated urea (SCU) an experimental slow-release N

source supplied by the Tennessee Valley Authority Rice yields were

increased an average of 59 more by pretransplant-incorporated SCU than

by urea or ammonium sulfate applied in the same manner SCU produced

excessive vegetative growth which resulted in yield reductions at high

N rates

Regardless of an assumed 48-higher unit N cost in SCU the

overall benefits of pretransplant-incorporated applications of SCU

were favorable since there was a decrease of 40 in the optimum rate

of N and the need for precise timing of application was eliminated

Pakistan--In Pakistan basal applications of AS urea and

SCU to rice grown under conditions of intermittent flooding in 1969-70

(table 18) indicate that SCU is a superior source of N as compared to

urea or AS when all N is applied at or before planting The data also

indicate that a yield response was obtained for P applications but a

comparison of N sources at each level of P indicates that no interaction

between N and P was present so that differences between N sources were

relatively the same at each level of P Yields were increased about 60

more when SCU was applied than when urea was applied Yield increases

with AS were only about 72 of the increase obtained with urea these reshy

sults do not agree with the generally-reported superiority of AS as comshy

pared to urea as a source of N for rice

- 40 -

In 1973 experiments were conducted in Pakistan using both

Basmati-370 and IRRI-6 varieties of rice grown under conditions of

When all N was applied at puddlingintermittent flooding (table 19)

or 12 at puddling and 12 at panicle initiation both AS and SCU were

superior to urea with SCU tending to be the most efficient source

However when N was applied 12 at transplanting and 12 at panicle

initiation SCU was the poorest source of N This would indicate that

the release of N from SCU applied at these times is too slow for optimwn

plant growth

In another experiment in Pakistan in 1973 no differences

in the effectiveness of urea AS or SCU were noted in the yields of

continuously-flooded rice (table 20) Again these results are conshy

sistent with earlier results which indicate no superiority for SCU

when rice is continuously flooded

Nitrogen Studies--Maize

A series of three experiments were conducted by IITA in

armo-Nigeria in 1972-73 comparing AS urea SCU and

CAN (calcium

nium nitrate) as sources of N for maize (table 21) A significant

yield response was obtained for N at each location but no conaistent

differences were noted amaong sources These results are consistent

with results at other locations which have not shown that SCU is a

superior source of N for maize grown over a period of 3 to 4 months

Nitrogen--Wheat

The yields of wheat in Pakistan in 1969-70 (tables 22 and

23) show that yields with SCU) tended to be lower than those with ureaJ

although at one locction where sorghum was grown followilng wheat with

Table 19

Yields of Basmati-370 and IRRI-6 Rice at Punjab Agricultural Experiment Station in Pakistan in 1973 Under

Conditions of Intermittent Flooding

Rate Yield Source of N Time of Yield (Mtha) Increase of N B-370 IRRI-6 Application Basmati-370 IRRI-6 Average (Mtha)

0 0 - 21 353 287 -

SCU 90 150 At Puddling 325 545 435 148

Urea 90 150 At Puddling 309 500 405 118

AS 90 150 At Puddling 324 529 427 140

SCU 90 150 Puddling 372 572 472 185 Panicle Initiation

Urea 90 150 Puddling 335 502 419 132 Panicle Initiation

AS 90 150 Puddling 353 529 441 154 Panicle Initiation

SCU 90 150 After Transplanting 312 562 437 150 Panicle Initiation

Urea 90 150 After Transplanting 340 624 482 195 Panicle Initiation

AS 90 150 After Transplanting 349 583 466 179 Panicle Initiation

All plots received 45 lbs P205acre as single superphosphate

Relative Yield Increase ()

Source of N At Puddling Puddling Panicle Transplant h Panicle

Urea 100 100 100 AS 119 117 92 SCU 125 140 77

Tioe dt ftwiftuIl Fiat It 0 poundtfsew61 loO Iwon f Ott to lot) ow weIw Iamp

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aI~

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of~~ WW ii4 fia to IW41d4 OW 44tfMwf~ f 400 I~ 1I404 sr wii w4ft43 ~o

m FFO t 4W iFO 4AP 6WWt w0 I 4I 14f

I t Ot iMpt w 4 1 0404494 4It 4 t4A

O tow o0 4 VU0040W ti4uw A

~~0946 I s fW MM- It1444Wttfw W

mtbeft t~t fr~ 0 Omq 01 NoW Otfw wk41 4)

O4f ofSWsowfW W aaoq fm~ MOW 10d ANN W 4 4w fO44o0

StOowew ARM4 WON tffas 0t0ff1 OIPsem Itf

9w NOofb rsrft s fw ~ w-o 4domw op

tu ot t two4 wo of44 At~ut6 04

ftINi 4~

owl 141

wt it14

F woo 04 WFf

044ofmamp 1 g w

h91 WOO owl

ow tl

eIa 4tiamp tbat O14 w44m mAqi~f~M0Il

p itt wt M 4441 f l T aw IlaI~l vweAUl

0 04 M 4 iU4eOW

fi~qr 14edqAs 1W44tMiwty w It 14C

WOA Y~U i44001r i U 4

cb o~t

f~~~~~iqt toitib ws 4 ~t4p6W1 1 i1 a

I~oil~ It w4M

mt4o Ofu~Mampwt i oe 0a 1~4tatlt~ 14 wlpo 0amp p

p~ to Ai~ f

bosom

~ ~ ftfW

W~ t tieiis ptooo 00u14 ie0

by ~ ~ ei~t11i ~~t

M toI0 ww)

mwt Fwaabe

ItM 1 sIM~~slieg~ ~utom sdb

-48

Therean laiictw that It lbs P to th e am lukis

obosomhu rocks 0entk catetas rth Unrtdo costrat frwt) to

ht tse balt s Owosiv as that to TwP it rocks WM bo

fmtbt alteruutiv to MSso gotastte to~ Ik lee used to

ThUAIAd

Tht wMl dt gotmtmlaoti wout th possibility

of law Vhld free ww e1 e66001 4 It cooUt be YgWd Sutt

a4 10 0410 SWUSSM yt$4e TOP wUd predWr A r~ftIf fl~W t

1f f ot P the wuld phosphae rck TWOe viWMW efocitill b

true to low rttos t tsplusatiI P wi 9 Ma Liiam $S

amp4at r per Wforssota Mav two 64eed Wilk elikor It 44 of

P go Mi er 4A bg oftoP aon of tewmrowtni pboophals fwAh

It vwld be polotrd A Wevero wtht Is the jteld level that

W414 gk tko videm dtterem~j o(A 1 the 4~etamp tk~e~t

P11~0 pra~lpj prefer gre4r tuftlter for whlae

of hoaw ppltrstie Mhe to a dloedveaP for The PINSOO rocka

vkth m r II spotted 10 ftewil 4106Me tem

Nub studios we ovsosd o IVA vol gramleid a

forgof wee aMW pbsepbots A fths pemhawe evsielew us

Odellod to detMlee it otteettvmm of 11agotated Stoture of

mmfp MW phapa A (CI) sed graewletod pampAtlti arlolatod Pa

asowcs of P tof ttde ro The wreem proucts omre raGther

pemour~a ot P syag besmti andMi as elt ov so gpamwhr

iuipiqffhate(TS) low twseeo Is eftwiltve Is thet

W41 preeme wae oialain ire post-rItoi effriq to Stanlato the

pud6itt of Irto paddle Wee ofsdlseireplastiq

0 49 shy

lbs partially scldiaatede grawilated Ml prodlucts Vere isshy

toiwdiats in 5tftOvttWS54 betwee wroiPi ad TVP NotV5Ymf to

me coo were they mere twoe $a a etfective ao TIP 00 sipifleast

LVSUMI5 at0 efecto wore toun tor thee produteo Timely dtIampWde

FR (-t00 mmoh) Uia amp~rally oar affective than Owe gra8448r FOampprodt

featal twos o 6 aotetire s I

Nowvero it to felt that sfortber field euprtet vth

hese interials Amd ether typs of grometatodl Wter nre wrrautad

hater ceeuwodh that they have me areec poteatlal toi additoG

e tate wAne the sectte as OtawrI sed bovoloen turther

euperimeste vth few reck pboophar s0d with reck pbophat treated

to sehesa citrata selmtliy or to ha csaducted

Metbir sertes of tbme enprtaeats wae c~edtmcted by IITA

to Ut~rta copal TVP AOP APP aed it at see tecastisix (table 14)

No dot lalt sewseltles teh draw tree thee results simouely em pear to tlvdl bsww they do stwgpt tbat forthew work with

MR to werramid so tbme sels

Table 24

LttcttF Swce MaPlate 06 ieldot IM AWaia CoelsANS at IITA (Ugboda ad Apoin ail sorit) aid at Ike (AUaba s5i series)

1973

Plate ot IP Apinu 5 poundebods A1ab

Ocrol 0 Z94 419 M)

Tr ipl ruprphite 20 349 3799378

Triple vepput 40 M09 410$

Triple 6wp~~b1 4271 4344 42250

Ammotw-ritpophW to 4201 4124 4040

Amosim-rdop~phlt 40 4270 4106 4231

AM tuo-polpephats 20 404 4244 3794

~eai~mpelppepbuI 400)49 4094

Cee m-pbpbt to- 59

momee eph lto 0 4192

LSO (0 0$) 29 1025

Th WPII

- 51 shy

101Y114 tpeM-fI PEP~tbRP YO

1 ~ ~ gmw 1pc~biofl- 9 Kla4v4h

Upia U04 Copfind am Crehout Stet Rpano at (Ia4

rico t IF t rume6 orth~ Caralto phoophale rocl QAR) vaUN pqU41 to

roopon from cmonetrat4 gsporphophai (CIP) who ort$o4 oil k

was 45j itwas tafertor vb protioo4 oil p war OS Ib 4iffer~c

in rtc reepos to X cod14 oo bo ttrit4 4 4 hvsciag of boil p

~ Pt o r11221 0 tP

c theto the rhimecyllndor of rico tots par to)14M4i1 roeoi~t

ed oil emd PA prior to tho ont of an~robi4 cMioe AA~ oIifoshy

nAte bYpot t taet~d tO fC4sin t~r 4PWden0 Of f Ot(tivshy

ofOWailiJtyno o prefla4 all Put that 4t01etoo 14 tvsIk

of the Ott to prvvld a 014for C4m0 44 mI 1 o4sf

EfftC ftPet141on AIAM-0 V f401td 4 4iv 440 Mtft

Aa torfat VampP f4MWfCi4W04wt0amp to 4eturWlI Ot(Wel~drIC ft

Ot f tM6 the flooded Ott 00 14 04019I Pft0uAw Of gAr~s~lr

pkS$t M40b MP) Tw P1101 Piset Prodwie W-e 10M0di Wr04

(10-1) emW 0aretilp ddw01at4 P WAA firom Rrth M~flRU414~$

wee cowiared with fie Md reWim 44104 proo~fo) foruk oith laWItter

I v te-PR P OW1004 4 4 O Wf ottil OW ellt Oo

Oveiel1 the 40tt dmcruie to effetotww Wtollowui Co fme

PR tpaUIB1I ldoltmo PR (pamwlatr) offr~- ArmeuM) 0 orwi

- 52 -

Effect of N Sourc6 and Water Management on Response of Rice

toe Zn- M Giordano J J Mortvedt OP Engelstad and Greenhouse

Staff Several rotes of CO(14H2)2 and (H )2So4 vith or without ZnO

wore applied to flooded and nonflooded Crowley oil (limed to pH 75)

to determine response of Bluebelle rice to Zn Yields with both N

sources veotrgreator on flooded then on nonflooded soil In the abshy

ence of applied Zn total dry matter production vith CO(NH2)2 was

slightly lower than with (NH)2S04 on flooded soil and considerably

lover on nonflooded soil Concentration of Zn wan higher in straw and

grain of plants roun on flooded than on nonflooded soil Although

concentration of P was unaffected by N source or Zn rate there was

som indication that cranslocation of P from straw to grain may be

depressed in nouflooded rice Concentration of N was lower in straw

grown on flooded than on nonflooded soil due to apparent dilution

thereas both X sources resulted in similar N concentrations in straw

at all rates of N application the N concentration in grain increased

with 0 rAse

feSpongi gf(SM to Chjorospodiostte and Related P Sources--

Si Allen and Greonhoue Staff A greenhouse pot experiment was

couct44d with corn Brown on Hountview silt loam to compare the ofshy

fectlivees of chlorospodiosito (Chlor-l) with concentrated supershy

phosphate (CP) Thomas slag and North Carolina phosphate rock (NC-PR)

Oil-prillad urea-phophato rock (UPI) FeA1JMP 20 7 and monomthyl

phosphate were included in the experiment Based on yield of forage and

uptake of P by tvo crops each of 6-weeks duration the following conshy

stui were dravat

I Chlor-1 was slightly loss effective than CSI Thomas slaS or NC-PR

from which Chlor-l wae prepared

- 53 shy

2 Granular UPR was a poor source of P its effectiveness was greatly

increased by reducing the particle size to -35mesh

3 FeAlNH4P207 was unavailable to the crop

4 Monomethyl phosphate was equivalent toor slightly more effective-

than CSP

Research Indirectly Related to TVA-AID Project

Response of Several Rice Varieties to Zn in Moist or Flooded

Soil--P M Giordano J J Mortvedt and Greenhouse Several varieties

of rice from Mexico and the Dominican Republic currently under investishy

gation in Puerto Rico for adaptation to upland culture were compared with

some established United States varieties with regard to Zn response on

moist and flooded Crowley sil (pH 75) Chontalpa (Mexico) Bluebelle

(Texas) and Starbonnet (Arkansas) were most responsive to applied Zn

Juma (Dominican Republic) intermediate and Sinaloa (Mexico) and Calrose

(California) were the least responsive The Sinaloa varieties (Mexico)

appeared to be best adapted to non-flooded conditions whereas Chontalpa

and Calrose were poorest Concentrations of Zn generally were higher in

plants grown on flooded than moist soil

Pattern of Growth and Zinc Accumulation by Rice--P M Giordano

J J Mortvedt and Greenhouse Staff Rice plants were harvested at weekly

intervals from shortly after emergence through maturity The objective

was to determine the rate of growth and Zn uptake by a Zn responsive varshy

iety (Bluebelle) and a less Zn-responsive variety (Calrose) in the presence

or absence of Zn applied to Crowley sil (pHl 75) Dry matter production

of Calrose was linear with time of growth and of a similar magnitude until

heading with or without applied Zn Bluebelle followed a similar pattern

where Zn was applied However in the absence of applied Zn foliage yield

was reduced markedly

-54

Uptake of Zn was similar for both varieties whenZn was

applied Dry matter production and Zn uptake by the two varieties

also were comparable when Zn was applied However yield of Calrose

was much higher than that of Bluebelle in the absence of applied Zn

while Zn uptake was only slightly higher This suggests that the lesshy

ser responsiveness of Calrose to Zn may be due to more efficient utilishy

zation of Zn There was no indication of a greater demand for Zn durshy

ing reproduction in either variety as was suggested in earlier greenshy

house experiments

Response of Upland Rice to P and Zn--P M Giordano J J

Mortvedt and Greenhouse Staff Several rates of P and Zn were applied

to Crowley sil (limed to pH 75) in factorial combination to determine

whether differences in rice growth under flooded and nonflooded soil

conditions are related to plant nutrition Although straw yields were

slightly higher in nonflooded rice receiving adequate P and Zn grain

yields were higher in the flooded crop increased rates of F andor Zn

did not result in equal yields Except in the highest Zn rate (75 mg)

concentrations of Zn in both straw and grain were higher with flooding

Concentration of P increased with rate of applied P and was higher in

the grain or flooded than upland rice at a comparable P rate In conshy

trast concentrations of N were lower with flooding due in part to dilshy

ution from increased growth

Rice Response to N and P in Flooded and Unflooded Cultures--

G L Terman S E Allen and Greenhouse-Analytical Staff Rates of

N from 250 to 2000 ntpot and P from 0 to 1000 mtpot were applied for

Nato rice grown on Mountview sil and Sango sicl (625 kg of soil per

pot) Market yield response to N and P was obtained Yields of straw

- 55 shy

total yields N uptake and N recovery were higher on unflooded than

on flooded soil cultures Grain yields however were slightly higher

with flooding These results indicate that with adequate applied

nutrients especially of N rice yields without flooding can approach

or even equal those under flooding

Uptake of N P Ca Mg and Zn increased with yield response

to N and P while K uptake decreased on the Mountview soil Concentrations

of N and P increased with applied N and P respectively while concentrations

of other nutrients were diluted in most situations with yield response to N

or P

Results from this experiment show that amouats of N applied in

previous pot experiments for rice have been much too low especially if the

crop was grown to maturity

Response of Corn to S and N i UUASand Urea-S--S E Allen

and Greenhouse Staff Three greenhouse pot experiments were conducted to

measure response to S and N in ulfur coated urea (SCU) urea amonium

sulfate (UAS) and urea -S as well as estimate N losses from surface apshy

plied N sources

In Experiment 260 less than 20 of the S mixed with the soil

was recovered from SCU or urea-S granules by two crops of corn as comshy

pared to 45 or 80 from flowers of S or Na2SO 4 CLop response followed

a similar pattern

In Experiment 260-A N sources were surface applied and alshy

lowed to dry for two weeks before incorporation Into the soil and plantshy

ing Recovery of N by two crops of corn was 77-82 for AN an compared

to 37-70 for urea UAS urea-S and ICU Thus n this experiment loss

of N from urea did not appear to be re~dcud by light S-coatlngn or by Inshy

corporating S or AS in the granules

-S -

I xbprZnSlt a Wtch aU Meyto 0-Ai Wt f9r

higher reermo teOrtOrs cOM reSpWNO i r0100 Of N w

not oaisteontly related to sewe ot N In edl tust 0 ioltiUe Lim

lo in VMuwpped evlmtUTS 48 merind by seirest nte appresOehe

501 for uroa as cwarod to 210 for urea peepha

Rus- or Upse to LoAmIl34I a AriMed bI Earl U

MW NOWlsIIsIr-4 L Toman 5 1 Alln and eesese StNf rio

row on Sawg did (0 tpot) We 1l0l0 Ws feritiud vith 05is

of Npot mixod with the 6011 as aureCA NiAO) 1 Age god At Ures

was also itcluded at rtt t 05 10 end 15 of Upee Theas trealshy

onto were followed 4 wpdrsetago of U s AN wre 4C 10o or at I3n

Weeks toulin up to IS pot

A soil application of 10 pot rosulvod to the maim yield

at 4 weeks Tio4 sad percont prottis t intre raite tncreased rftishy

linearly with U applictalien IeseeItally all at the m iNd wit

the moil w domitrifted after flooding Grail end straw Ilelds vere

highly correlatod with tiliriag and vlh ubers of gralm arl

The results Widicat that 0$ to 10 a of Upot as orea or

NN bsuld be sied with the oil to stilate tiilrir with adshy

ditional 0 topireased later to increase grain lIds mad protia cmshy

tout

DIVISION 54- FERTILIZER TECHNOLOGY AND USE

N$eumWe of Mt5p4Amomd 1k PindW hswk4PhI fl fRw cW ims we

Jmnwacr VW owm m

a~~00 - 0 6 A-~ -~~ PN 40OMOM X 00 Wolm n moo mot $Pto4I 4l 4 W

1 -0 Is vom omoo ~~o - W1 sfw 4E00-aU

WI pw shy-M Iampeo _10 00 mo N - o wo limoshyM~m a UAa oomw W0- -0 f40 44 MP 0v~f04i-lsm 0 PA 40of 0 0 W -W ov a Wo 006

-n-t -4adf -m W ftf

9P~~aw otom i ow sm li ilia it - ~0~f 11 40S adob 11-11 __ 9w

i A ~~~~06o ~a A VOW 4 WK-ok rie Ww -0 no 4me

00 to- W 0Nwo ww AO t

-t umi om ftaw-0

- - lh -i N N iiSolf so -ma w vow -mv__M

-~AdAjA- 44 ow 0ma 0MAW a war -mo d0 00 M o WooP 0

0kR N4 a~ow Mf o

- -kn Am C4 pos 0 WW -I

to$w formoop 1 so

Qm0fte Iwo 00 SAtow

a

WPMaa~I m ww

lvZW~16W IT

I

vt~~ - foa Gom

r-7- tw

A ijdMA~ trMO

otait m adtoo iMOaiq

sMs aIwO tP- owWIs

mU MW4 0e S w 96 lo ow- CO=

I~

bq

-- -P~~~~ -- M S um IN 0VSAww dvIs0O E0 two I 41

OV WNA w N$ lp It 40A 04 ON w 0^ 0 PW1t~~~~~~~dap~~ frO

Is WAV OUw Af 41W 0A

1A 0

1o wI0~ WSW adWOWi

MOM 4 so mo 00A

w m wO~ WWF __ootm

Wm^~~~~~~ ~~ A tookoto 00wmf

M~~~~MOt 0f O

040 wd m40 Awowmm

bo^ w

ro a W4

~~

womb ~mmnt I-VI~ bp

5i irn0 pwm k~ oiuwe OsMn0 Wsw e Wr~m mw6

_______Noon_Iamp__ arn ag bos m W we ap

=ib ad a $4Ws Om ThSU

mod m m406mi 1m towir - m bowI~~~AV UPuiWd a04aup hwu 000sW~11lito -- o ~ImWq mow~gnn w a ho emotwi

4~ 49akduemg6momm ~ do nedOwrnd~ o

ICU wONMOVAON w4wWR - - o 44 O Tha 40 pu4 am

hum 11 is 4111 s - sg am VW f wq 4WuM dhCi m ehamv alpso 0

-w No memwiauu so-s 1141 -f oer wwn malow Wufmmm inM UCd m I a to dip 90

- ~~ w emw euIv oflme em ~ ed~faiOeWMOWleA fC~ dim~e4s- 1um00 s uwos w siwp 3 0V es wiiu d um w

aram ad as~6 ma pgt -oI A -$-d r00= m PW Of

ff~~~- am diwda Vs Wow at 4g eltpowm woo OI teeMA AMamdmOMisan A d1 Tm WNW m4 uwwemm mmmM

Aa It mom A I b 0 ~isi ~amp~V5on m ad No wwho 1 $IV Am t t~i mmOwm a- S Am im spwwmft KV-b Osiswvn wogie

opoOw suf No~ Ow MW MCI pt~bi asiwhNd bl-d muim of woo w NN

toI4 0 06d 00 wo A Md N WILSAl DuIKWION oo A Nw U am ONq ep

ow VAN pmw amp4 li a4 WdUb p vw sopwaft a-ftgw -ee theptd OW 6 - a

at MW em matshyW M offm of4 W twampwmwausoo wo asdm65m Auamp Ahbwu in 4ih asTal ON~ al oem IN Maie dmAd A a own did ofe w17 I inM mimman Ofd ofimruwf gas Pius di aMe Kwe auw a dow iNPOOIN tmo a SO$SO~4W

MWaSM BT ALI Mh USIA UW MlO RMC i WOW TW A-~ka ad 1 1 li laiiII111I

0 -6 -1 -- - -- Ie-- - -shyis

101 ~

alm~ sas ~~~ ms a a~

ase appuadmen 44 ea ad semk Who pm4WWS lowftsIU wo WOMO dobowl ICUSJW h

A Poad KU apbos as dw sileft in as a aWhps k asIU__

pro alfp al 0 WN Is obaml~ of th es Wls pouvy Ofts oeWMed N

$ae fapree ulesaseup IfIwotohaffe St

40WilinAn 06 kw Ma ho 00 e IW aftakrw splerefAnhffsb m esmem

I$Ow Ip ampMI pasi 1ead eu an Toud 2l

Widj 6vi of V46 745WI KU waso-W im Wow 0 is610SWAOMMwasa to t

VAp 1Mampd KV ppu~s dw whaim $i a a los Al w W

Ib Milvo urns of OWe d- musA as h~ s a IuIow 8 1 ue ip

-Wlidswf of 4 ofatsIW5vsS d M M5 i RSa pm~daps In ampup 1Powworw rue hevi A b

el eas goileN ruseW4 wo duffeeme bWOM isttouwi

14 gnp40 woSalrw 11ylo amreu Mwb Isevlow roosmN~ahIt s 60 W ~tsmAIM L n ~ ~~ ~

MM I PWrawA = rMla yowIeM oa

eUW as ymlh OW by IONamph avWlbl N The mubsr 1MM Pude M~ IsA aemOWeld

IWOes A rspeas Owed ai udlWwease

por bre

wals rIs O touprua KU=plaINamppNOMeses a

W UWhk 0 ASOoml ft A poWsdvutA adesae of amr Wns ai A 0r- 1ampdd Oehs IuRawy NO Pue podllosWewwe gmak asmpnle by dMiss is amle OWN pet -W yid I MuC)ad ampAn (WiplaeT16s mOW aOW aNo fhr ft ymIed------ obealud w3t 0 OW 40IsA a VM bpR ofthW d saw ns m aI efes R 24 ad 7

e 1 d

Ii

Iw NO ~sp 44I0 so

~ ~ I $4U tml

Tile 4-00dw x uiampOW74u 0qee of

_____k _ _ shy

~ - 56I 5

-f

irenY w -a

Tiles I sed I thm Au do sel oeppled upaoIks WIM0 0da ispI amd us Ou s 106 kg

h Eaap 8n 14 sMsa of abw~greuad PU Pau WW 1 u itb IUKho 0aaphelem s 60 Otarlmmh At ~ 0sU Ishiseoo Cook oiA N uiplasu mAasslaly abess A leel

v doese a WKWye Is ks Nha m 6 sa4to dafo aONmuw The appee swm Wsssof adde N4 alalaed by vuMb ifaa W C Was sekilumganSro Is

bs eabI wish as aVWWa uwewy nap (f5s)f ad Mashes reaMeY valaes of 48 0 S414 CWm

owdb imto US Wh s vs sf 3I mld 54S fro 2 aMd 3) A A

valves a hevwae u Iar Walh basl oswas dhe uwpatr bshava of

tb~msusasl appkausu of ofta sede s have aoweN

TOW opl taoe for AieweeW 4OsmWMbas Op peas As Tabl 4 sling sob Os awowully eom grams Piel level Thes oeulam Ma sed as IM

-02

792 60L WI W A)49R Pio VOL 37 197)

primS o r OeampAd WU toa Them fl~ w At NOSSe earno maisslea Ia N he mOWamplIO yik ampWd IMe aampWmW OWa Owe wa UMs of KU to 41 Oke ampWiiIamm be dkrnety ewspokawleM(a s8 te camtd wie a eapmoe by TVA pavw ltoi NA poundrmdaka4us vrimeW460 o to ilkidm ofWW (Mtemas MuOwe 1973) TVA mwi bawld on soi ficedims IampWp seg rudwiv s~s0abet ke WNmdoe ON 01 K Is12 NOSW ie fssewnmu Ie I QvaaIi rowp IMA) f9

)amp m lodk byO voebmsaIS8OpeaWfrats 11 OWNmi a I a W idisod 0 81 Now 111 nindat Wm fysmpseaamp (If tsO tUmtI IsM $P shoroV4mmo knflkvnf (foOdme nuw ae Ow OImstwe in SM pnmm8 af tXm 10 114PIS kequoian wo Mpfii

SC~po umd spop~o VWt alm 4emWal 1 4ink PCmirsra M 1 ad AI 14bmms

1MM Ww Even to doe shw wisht b-o -Wamp Ekb fed rbaimpal of14~ Am Smpound oS mv fAaMda

MGMe -M4 Wg kmuwadM 1Wr wih SCV4 Psmuck Wff It dlL Wm 1W led 0 1 oo teeA of aiwaisme aweeoid h

1Kach Vt V amp4W ILK t)sa 10 Nareps vm This ndY ub thee hbow apiptomuasa of gulfu-aw~sd of Cup lP~~tamsl wi(i

Woeo of woo or mlm Wmiot InIasem~Wsy (heede 6Am 0 F- ad PAicv IfM tsoPm 9W famp kw~is 04eet The r4 ggm I ampbpiIs OnwAu 4nvmkstm v PAraem A4fshy

e W d inSIWfh sil $ad doke IaefitV twoer) 1 Te to theo owie effu so booJ imik WOi 100 N

-d

Is re4aled uIwq~e~w Aueee atofurnw di Capsnm ptopeatls is a oommm eiws to 100 tom of 04404man d CtdUW 4M Anw K~a do Aamp apowee WPUaN powu eel H pae iaaa thAi SCUI isWW owr hmem ISsuppl N to the li ieee F A IM1 Nampa Obo~amie m

41MB ~ ~ m ~ ~0 0-- 0 140 The ffsemn of food Nn else9~e(Ud~ ~ ~ ~~ WooksaS eAWw pjed of ho~raw of IU effadam vfdva oft xhj0I 13iAl

DIVISION 8-9-SOIL MINERALOGY

Amorphomw CeetIup en XmWra Ssrfmls

L C koits Am~ 0 tmmkaAf

ommp A faieiaAMTRACT skiwe lo nW ampM sm wi4h

Walo by a onMm I dmivid hseidm6Wlk W~edesie s

peuiieles as is s e wpwigstee eded his S -em -om 0641 h4 hisW1mWOWb~ bfem peess Wimm kv Iee

Pa~~~eakr4awiS SeUeeiNaiA WOW 14e

PWWWW t HW f hea~I~~~~~a 0th

kog Ii ampI b 1111h1atAmOem aid itsaere~m-aelmoeug toolPe aal 111W mWa Wisg ag so~ ti~Wo booviot65k Th eme Iua 1111411uiwon it es 01000 AW~CWS ~muiseeteqqsheer21111 ionev

oO00 llb K0 ibad~ ~~ doj 140WI s o mimdW um

WLIMmAmMVL 1

lill mi oHow al of a be 1974oyais4gamm wsoc wwo

rdy i of OMAN toblind id sh os 00 IN bei m us salqs m kid Vw 1 a0Msw WFW isms waf e eeiWei he-4~~e gsa dulsi

os 0aMW ofmu WA l aduWs~Ib rowuvvl3maIpm s

CaO~OP aw AlNomI 4ornomd to9 IS is -l O SI g4he rpidyThus whim m dowu bWa 0 m m- ei u

d m M 0bmSaImu M-1 ofM6 h Intun to 7I

aiba maush WAesshwn~u9dSg a osusLwpI ~ v m

M PolsdAvoWdw Ons pugm~ low iwLW m We

of~U -a~ mo uNo

0401ts of 40

A e mun5d m i vvamp sa s ow bftIS i sa omdIs a w

edi1 hswopmo an ag am Iw anom erlwaPASneooie bnwoM po

o ~ do=lr 3s fluACWoSM Owaa VolM Ain b 400b adW g o as amob ofrMOWS A oo eWmaa ow $wofdi60 ow - ema

-v K Vcon l ap ad md ld KU lbs PoabumwA od w to domi a bembe 0b lt $014 i ampmomONo

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arbs awasm 00 iztv Am-~~~i u5~ms ashu is byw

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of of~phaow tw bmsdf toamplboe

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ov4mnk wsi 9 Mxfeu~i am emwm ismi0wmd fq W No ~~ - f mug Aitowe eutlkowbmTV is

amppowftdmi TiM 0 Tie OAA mo p)a Mwomoi dOn4m A)w

MW 0 604 0M mm yaM 01MWOfdi to tA0 M OOAW uinw OSOb

ap is~e I the ampo A A Mwof ~Do toit op aenu w~ifiOimem~ MAN ampW)

ItsAO se Y lieowawo u~w pkow-W1b pwf on a C Nohkw is f 0o1 s do~omW C mmU4

owud6moeft 4 Obind PINa~e

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~ -0

65

0IL CL OC AMXR PROC VOL 38 1974

)aT1 S4I104 ow Lusanll Tawng isa tall Thai variety known for beingIwo nonshyi s s ) sensitive to photoperiod A split-plot design was used in

S e e these euperimeots with 4 rates of P (I1 22 44 and 88t i V IV k of Pha) applied a main plot treatments and with the OF It sourMes of P as subplot treatments There were two checkS plots in each rmplicate The extra check plot was included to permit the application of fresh TSP standard Jor the

It- ti 06 + i bull fa succeeding crop the p-4me of bi was to permit accurate d awrnwal of the mdual effectiveness of the phosphate

ftinSUbI rock The P fertilioers were broadcast on the mud andthen Worporald In the soil during the last harrowing At

whM N both On ACS indx ampM time of transplanting Immediately before the last harrow61t (4j 5 4 01 P s 3Mm o Vallonal in con n 100 kgha of N as ammonium sulfate and 33 kghaWO Of Spews ampm lIW thaabe rocks do ACS indes of K as polium chloride were applied A total of 40 wa in prepw O do ctih k otent kha of N a ammoniunt sulfate was applied later in twoir P The hew oNed amp wM W for 5 of gw topdrossingp with about 5cm depth of water on the plotsvV I aiOMveffeOctveee Three to six ldayold selings pr hillwW the ACS idex were planted00OWW wia Oft fo an c irNk I p Coen 20 by 20 cm part in straight rows Hand weeding was used

and insecticide were applied for Insect control Grain yieldw was masared by sampling 5 ml of each plot excluding border rows The date of heading in each treatment and theUNiN d pbM W Weks rin tOW USA UMe In Tale yed componnts at hafvel were also recorded

I filM rsperMS esOM kdwdua 1 t ab The average yields of ough (unhulled) rice for botha 84 OW O 8uo 4 Thala TM was a locations are ploutel in PIS 3 for the first crop (1969 wet

owou thRM seaso0) The Veamps yield response was obtained at Klonge (s) W lDtO t Of dMa of1tw W d l R Luang however a 4ute satisfactory yield response was

~Mk ^d TVA UJSD ad Kd UnIveS obtalned to applied P at Bangkhen as wellXUe LaM e R qwrw Ims The sod was do Relative aponomlAe effectiveness values were calculated

VOW (a ksA w edmwL t Poesesm h Vy for these data and am presented In Table 3 The valuesdAY buo if dIe ouh ne Pee wtk a Mlak vow 1009 for th first crop are plotled against ACS index in Fig 41 This Im M i6ti l 4bNd IO a0 O mkarnk for both locatio r relationship was linear for the

11400 ThCpH 0( lb pW IW 01 th UpeiaW so Sanodion location and curtiltnear for KIng Luang The was u i 4A sksamp lMaor nrusio model amparounted for 81 of theAmO$MI Aw jAAsue Swim T1 Snh Wd variation In the AE valu for Bantkhen a square root

Mems a Iw iv fern alh$ sedm haowg dayNW W t he plAL At tdo M tM aso W s as ctminued throufh eltaM t Ofpof -le lse wo am P OeNI VeOpls 1o ealluae tI lon4erm MIdual Offccls

A on W isset i a wse to hsh eapeel of these ooihss t ocks The baagkhon experimnent was letmiaI1DlVemisthis is a w hulu Lo g Tasug ia iasael aft - Msd residual Ves will be pr-Om crok TheseTwod esewm

SWWo

A

lP~U~7 ISIIPe1iuIWN e bsedisssin ian ghth siaoelalbe

984 0 6 O O - M s -s fWPas 11eSft W d Uo al a o

o

S4l~ lIIII I~l I 1f fl

( +

+ + + m + ++++-

++ +(++ + ++++ + ++ ++

- 66 -

ENOIMLSTAD ET AL RESPONSE BY FLOODED RICE TO PHOSPHATE ROCKS VARYING IN CITRATE SOLUBILITY

I I I I j0 I I

BANOKHEN BANGKHEN

pH 56 6 - 0o

TSP

NC

5~ ~ ~ L o 4 - -shy

4 ] - --------shy04

6S

|0 III 2 44 8r 66

I I I

a 1KLONG LUANG

pH 46 z KLONG LUANG

TSP Sc2 NCFL(N)

5 FLIC) J0 TU

oshy

4 ~40shy

3 bull eM0

I - I I I I I

0 II 22 44 88 0 5 10 15 20 IP APPLIED KO HA ABSOLUTE CITRAE SOLUBIITY INDEX

Fig 3-Yield of rough rice at Klong Luang and Bangkhen Rice Fig 4-Relative agronon effectiveness () of P sources ploz-Experiment Stations Thalmand as affected by rate and Source ted against citrate solubity Index for both Thailand field ex

of P applied (crop 1) periment (first crop only)

regression model accounted for 97 of the variation in sumably resulted from crop uptake and reaction with the RAE values at the Klong Luang location soil to form less soluble products Such effects may have

These experiments were continued during the dry season been more important at the lower rates since the two TSP of early 1970 to ascertain the residual effectiveness of the curyes converged at the highest rate of application various sources applied to the first crop No new P was These data from KIong Luang indicate that (i) residual applied except for the fresh TSP standard mentioned effects of all rocks except Mlcwuri were substantial (ii) above rhe experiment otherwise was conducted in a man the relationship between relative agronornic effectiveness ner similar to that followed in the first crop of the phosphate rocks and citrate solubility levels was

The response to both freshly applied ad residual P was largely obscured and (iii) the general superiority of TSP marked at the Klong Luang location and marginal at over phosphate rock in terms of effectiveiss persisted Bangkhen In fact at the latter location the response was through the second crop so small that little can be said regarding residual effectiveshyness The yield data from crop 2 at the Klong Luang DISCUSSION experiment are plotted in Fig 5 Greenhouse and field data presented in this paper show

Relative agronomic effectiveness values (Table 3) were clearly that there are substantial differences among phosshycalculated for the Klong Luang data using both the residual and freshly applied TSP as standards It is of Interest to note that the superiority of TSP over the phosphbte rocks Table 3-Relative agronomic effective values for field experishyments in Thailand persisted through the second crop The main difference in KlowlZmlnql~the residual effects is that with the exception of the MIs- s Crop 1 Crop 21 Crop 1-shysouri rock Ihe marked relationship between citratr-soluble WoiCarolina yl 59 76

phosphate rocks and RAE had largely rds norh) a 64P conltct of th Florida (eqlral is 6969 6

disapipeared In this acidic soil (pHi 46) P would by this I14o 69 63 40 ToonesS 31 65

limo be supplied by Intermediate reaction products In addl Missou 0 o lion to residues of the initial spatlte Ts P o 2 o 0

The TSP applied to the first crop declliv-d slightly In campIafcmWataesr e id ofeuhuloefor 22MA rates of PtColeouattd as aba u tlte td18 kS ratesp dlverage yield tM868 to 22 44

effectiveness relative to the freshly applied ISP This pre- of d s4

A

4

- 67 shy

-SOIL SCL SOC AMER I

KLONG LUANG CROP 2

Si 3

eN

TAPPLIEDKGHA

Fig 5-The residual effectiveness ovarious P sources for crop s compared with freshly applied TSP Klong Luang Rice

Experiment Station Thailand

phate rocks in terms of agronomic effectiveness for flooded

rice Further these differences can be predicted by means of citrate solubility or by the ACS index It appears that

the latter is more appropriate where the content of apatite varies among phospiate rocks The most soluble phosphate rocks approached but did not actually equal TSP in limit-iuig (maximum) yield in these experiments regardless of rate applied This agrees with the results of Ensminger Pearson and Armiger (4) One needs to consider the defi-nite posribility of same yield loss in zhoosing a phosphate

rock over TSP such yield losses must be weighed against the lower price of phosphate rock The explanation for such iosses may involve concentration of soluble P in the soil Khasawneh and Copeland (6) suggest that the growth rate of crop plants is a function of P concentration that can be maintained in the soil solution If P concentration is limiting or inadequate becawe of a lower dissolution rate of phosphate rock the growth iate ard uiiimate yield will be diminished accordingly

The RAE values bascd on yield increases reflect the agronomi effectiveness of these various sources relacve

to the TSP standard however these nould be supple-

mented by an economic analysis before rational choice can

be made The following calculations will provide an estimate of

the rclativ ecooomic effectiveness(REE)

Y t Ps aXpatREE -- 100

vahtercks t sphate or e b i- eor

Price of TSPkg fo

be Price of PRkg P

PROC VOL 38 1974 leO

90r

Wsoshy

0

60-LUSEPHOSPHATE ROCK

00 10 20

PTP PR

Fig 6-Relationship between relaZive effectiveness values (RAE) and the price ratios between TSP and phosphate rock Such a figure can be used in making a choice between these

sources

If REE exceeds 100 in this calculation the phosphate rock would be preferable to TSP

The REE calcuktaaa wre used in preparing an indifshyference curve (Fig 6) wherein RAE values are plotted

against PTsPPpR ratios The cu~rve itself connects those points at which REE equals 100 When exactly on the curve it makes no real economic difference what source is chosen After choosing a suitable price ratio one can then project upward from that ratio knowing the RAI

value (or estimating it from such data as shown in Fig 4 using citrate-soluble P content) one can then choose the source on the basis of both agronomic and economic conshysiderations For example if the price ratio is 25 and the RAE value of the phosphaite rock is greater than 40 the rock phosphate in question would be used However if the RAE value was less than 40 TSP would be a better choice There are indications that if the P in the more soluble phosphate ro~cks (North Carolina north Florida central Forida) is less than half as expensivz as that in TSP these rocks would be feasible altereaives to TSP on soils similar

to thoseused in Thailand This analysis does not take into account the possibility

of lower yields from use of phosphate rock In addition only a portion of the various yield response curves was used in this anlysis ie up to 22 kgha Beyond this

rate yield response was much less pronounced it could be argued that at less than maximum yields TSP would produce a certain yield at lower rates of P than would phosshy

pow ofrock This would especially be true for rates applioa example at Klong Luang 5500 kg of

rice pcr iectare could have been produced with either Ii kg of P as TSP or 44 kg of P as son of the more reacshy

tire phosphate rocks It should be pointed ot however

- 68 shy

(IIKIS amp YOUN( ARIFICIAL WEATIIERING OF OXIDIZED p[ll- IV

that this is the yield level that would show the widest difference such is the advantage of hindsight

Farmers generally prefer granular fertilizers for machine

or hand application This is a disadvantage for the phos-phate rocks which are normally arplied in finely divided form Recently experimental quantities of granular urea-

phosphate rock mixtures have been made by TVA Results of trials with these fertilizers will be reported elsewhere

LITERATURE CITED

1 Armiger W H and Maurice- Fried 1957 The plantavailability of various sources of phosphate rock Soil Sci Soc Amer Proc 21183-188

2 Bengston G W E C Sample and S E Allen 1974 Re-sponso of slash pine seedlings to P sGurces of varying ci-trato solubility Plant Soil (In press)

3 Caro JIt and W Hill 1956 Chard eristics and fer tilizcr value of phosphate rock from different fields J Agr Food Chem 4684-687

4 Ensminger I E R W Peirson and W II Atmiger1967 Effectivencs of rock phosphate as a source of phosshyphurus for plants US Dep Agr ARS Bull 4112S

5 Engelstad 0 P J G Getsinger anid I J Stangel 1972 Tailoring of fertiliers for rice cnnece Valley Author ftyNational Fertilicr Developmnent Center Hull Y-52

6 Khasawnch F E and Jane P Copcland 1971 (otton root growth and uptake of nutrievos relation oif phosph

rus uptake to quantity intensity and buffering capacit) Soil Sci Soc Amer Proc 37250-254

7 Lehr JR and G H McClellan 1972 A revised lIbora tory reactivity scale for evaljativg phosphate rocks for direct application Tennessee Valley Authcrity National Fertilizer Development Center lull Y-43

H Terman G L S EAllen and 0 P Engelstad 1970 Response by paddy cice to ratcs and suurces of appliedphosphorus Agron J63390-394

DIVISION S-9-SOIL MINERALOGY

Artificial Weathering of Oxidized Biotite IV The Inhibitory Effect of Potassium on Dissolution llate

R JGILKES AND R C YOUNG2

ABSTRACT

Rates of dissolution of oxidized biotites in OIM 001M ICI are severely depressed in the presence of IM KCI The amovnts of Al Mg Mn dissolved in the first eytraction are similir to those found without KCI however subsequent extractions remove these elements at 10-20 of the corresponding lICI rates This effect may be due to a decreased rate of vermiculite formation thereby reducing the effective basal area exposed to attack A decrease in dissolution rate with increasing ferric iron content was still apparent in the presence of IM KCI

Additional Index Words X-ray diffraction infrared aborp-

N EARLIER papers of this series the tole of biotite in soils

as a source of both macro and micronutrient elements

has been discussed ((Gilkes Young and Quirk 1972 1973ab) Experiments in artificial weathering uiing as va-

riety of extractants were undertaken to determiie the inlu-

ence of oxidation of octahedrally coordinated iron on the bull release of structural cations to solution The results of this

work demonstated that biotite behaves anomalously with respect to the other common ferromagnesian minerals found in soils Oxidation leads to the development of a high degree of resistance to cation exchange and dissolution Several authors have coiwludcd that decreased rates of K

Contribution from the Dep of Soi Science and Plant Nutri-tion Institute of Agriculture Univ of Western Australia Ned-lands 6009 Western Australia Received 29 Sept 1973 Ap-proved 8 Jan 1974

2 Senior Lecturer in Soil Science and Research Officer respeclively

replacement in electrolytes shown by oxidized biotites are

a result of the inclination of structural hydroxyl adjacent to newly created trivalent iron or vacant octahedral cation sites (Robert and Pedro 1959 Barshad and Kishk 1968) Gilkes et al (1973b) suggested that decreased rates of disshysolution of oxidized biotite in 0001 0t)l 0Af CI may also be due to the presence of inclined hydroxyl In this case a smaller surface area external and exposed intershylayer may be available for attack if K replacement by hyshydrogen ions occurs at a slower rate in oxidized biotites

Gastuche (1963) has shown that significant dissolution ofthe (IIM) biotile face may occur and it is easily demonshystrated that the proportion of exposed (001M) face in weathering biotites depends on the percentage K replaced

Rausell-Colom ct al (1965) have shown that hydrogen ions act in an identical fashion to metal cations in K exshy

change from micas In particular exchange c-f K by hydroshy

gen ions will be terminated or greatly reduced by high levels of K in solution Thus if dissolution of oxidized biotite by

acids is carried out at sufficiently high K levels to prevent vermiculization any differences in dissolution rate that may occur cannot simply be ascribed to differences in rates of K replacement The following results were obtained from such an experiment which unlike the experiment described in Parts I and II (Gilkes et al 1973ab) does not attempt to simulate natuiral - conditions

MATERIAILS AN) M HIiODS Further subsamples of the less than 0 hiotites used in K

excherandbaid disoo tu es (G iles e9n K exchange and acid dissolution studies (Gilkes et al1973ab) were used in these experiments Preparation of sequentiallyoxidized biotites without intermediate vermiculite formation is

Page 26: I70 - United States Agency for International Developmentto ascertan, but tgl.eetad, 1, L,. ("Tailoring of Pertiltiters for ice,'" TVA ulletin Y-52) states that the staft of IOi has

Table 2

Mttct of 0 Sourco aampW $At On Upt~ks of 0 by Two Varitgtos of Paddy Rice

gr~a 1971

~ MMUampL~ ~L ~ nYLALI~ 11 lemall

I ie

W0 v slit III I) tQo9

KvN 1 17 111 1119

or 444M7

111a

i1$0N ~ It$ 121

1$

x IV ~404 tot Vsr 1 P1 41 w otv 1

- 24 shy

India--The results of four experiments conducted with flooded

transplanted rice in India by the All-India Coordinated Rice Project

Hyderabad are given in table 3 The response to N was excellent the

yield without N being only 41 of those obtained with basal applications

of N as uza With basal applications of SCU the yields were 20 higher

than with basal applications of urea and in the three experiments in

which urea applications were split yields with SCU were 18 higher than

yields with split applications of urea When comparing the average Nshy

response (kamp grainKg N) yields were increased 13 more by SCU than by

basal applications of urea

The data from one experiment with light irrigated rice in India

are given in table 4 yields were relatively low and differences between

N sources or method of application were not significant However yields

with SU tended to be higher than when all urea was applied at planting

but lower than when split applications of urea were applied Again yields

increased more than 13 more with SCU than with basal applications ofwere

ur

In tables 5 and 6 the yields of a short-duration transplanted

rice grown in irrigated light-textured soils at five locations in India

indicate that higher yields were obtained with SCU than with urea when apshy

plied as a basal application Yield increases due to basal N applications

were 502 greater with SCU than with urea However split applications of

resulted in yields equal to those obtained with basal applications ofurea

CU

The yields of direct-seeded upland rice grown at three locations

to India are given in table 7 and the relative yields in table 8 Yields

were low due to drought but good responses were nevertheless obtained for

- 25 -

Table 3

Effect of N Source and Time of Application on Yield of Paddy (Flooded) Rice in India 1972 (Summary of Reported Data from 4 Experiments)

Experimental Number Source Rate Method Yield Relative N-Response

and of of N of Yield Kg Grain

Season Nitrogen kgha Application mtha Kg N

- - - 196 34 -

Urea 120 Basal 573 100 314

11 Urea 120 80 + 40 611 107 345 Rabi SCU 120 Basal 713 124 430

12 - 0 - 202 30 -

Urea 125 Basal 682 100 384

Rabi Urea 125 35 + 20 + 35 + 35 633 95 344 SCU 125 Basal 781 115 463

13- 0 - 168 44

Urea 100 Basal 385 100 217

Kharif Urea 100 30 + 20 + 25 + 25 400 104 232 SCU 100 Basal 462 120 293

14 -

Urea -

125 -

Basal 355 650

55 100

-

236

Rabi SCU 125 Basal 781 120 341

-- 26 -

Table 4

Effect of N Source and Time of Application on Yield of Light Irrigated Rice in India 1972 (Summary of Reported Data From

One Experiment at Pattambi)

Experimental Number Source Rate Method Yield Relative N-Response

and of of N of Yield Kg Grain Season Nitrogen (kgha) Application (mtha) Q) Kg N

38 0 - 204 85 -Rabi Urea 120 Basal 241 100 308

Urea 120 60 + 0 + 30 + 30 267 ill 525 SCU 120 Basal 255 106 425

Table 5

Effect of N Source and Time of Application on Yields of Short-Duration Transplanted lice Variety Grown on Irrigated Light-Textured Soils at 5 Locations in India 1972

(Snmzarized From Reported Data)

Rate Grain Yields (MtHa) Source of N Method of N GrainI of N kgh Application Faizabod Karjat Mandva Pattabi laya Averaje X

- 291 266 211 19 340 260 -

Urea 100 Basal 386 407 361 285 482 3 124 Urea 100 50 + 25 + 25 399 430 434 334 6amp2 4A8 186

SCU 100 Basal 368 468 439 360 572 41 181

Table 6

Effect of I Source end Tlae of ApplIcattoo c RIstave Tle24 of a rt- rat1 T Lsd lice Vasrety Crin o Irrigated L41tshy1 at S Locitite mindi 1972

Rate ____________14_3

Source of X N~tbad of Of X An 1 tat14 1 acr X__T1 4v tatW ttva

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W Iotors Ftslanp tospg Irritd for Two thvk Afler flontiw wft rkwa~ Floo4d 191)

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- 38 -

Table 18

Yild of aemati-370 Rice at Punjab Agricultural Research

Institute in Pakistan in 1969-70 Grown Under

Couditions of Intermittent Flooding

Pate of application

=IL

o 0 67 67 100 100 67 67

100 100 67 67 200 100

Average for Sources

Ntha

AS 260 gres 279

320

Source f5

-

AS AS Ura Urea SCU SCU

Yield

Relative

93 100 115

(M)O

Yield

Increase Yield Due to N

(Ktlha) (mtha)

-212 245 033 274 062 260 048 297 085 315 103 325 112

Yield Increase

Relative

72048 067 100 108 161

(2)

- 39 shy

Short-statured high yielding rice varieties grown extenshy

sively in northern Peru require extremely high rates of conventional

N sources to achieve maximum yields The recovery of applied N is

extremely low due to the use of intermittent flooding This water

management system results in heavy N losses even with properly timed

split applications In search of simpler and more effective methods

of N management eight field experiments were conducted in the region

to evaluate sulfur-coated urea (SCU) an experimental slow-release N

source supplied by the Tennessee Valley Authority Rice yields were

increased an average of 59 more by pretransplant-incorporated SCU than

by urea or ammonium sulfate applied in the same manner SCU produced

excessive vegetative growth which resulted in yield reductions at high

N rates

Regardless of an assumed 48-higher unit N cost in SCU the

overall benefits of pretransplant-incorporated applications of SCU

were favorable since there was a decrease of 40 in the optimum rate

of N and the need for precise timing of application was eliminated

Pakistan--In Pakistan basal applications of AS urea and

SCU to rice grown under conditions of intermittent flooding in 1969-70

(table 18) indicate that SCU is a superior source of N as compared to

urea or AS when all N is applied at or before planting The data also

indicate that a yield response was obtained for P applications but a

comparison of N sources at each level of P indicates that no interaction

between N and P was present so that differences between N sources were

relatively the same at each level of P Yields were increased about 60

more when SCU was applied than when urea was applied Yield increases

with AS were only about 72 of the increase obtained with urea these reshy

sults do not agree with the generally-reported superiority of AS as comshy

pared to urea as a source of N for rice

- 40 -

In 1973 experiments were conducted in Pakistan using both

Basmati-370 and IRRI-6 varieties of rice grown under conditions of

When all N was applied at puddlingintermittent flooding (table 19)

or 12 at puddling and 12 at panicle initiation both AS and SCU were

superior to urea with SCU tending to be the most efficient source

However when N was applied 12 at transplanting and 12 at panicle

initiation SCU was the poorest source of N This would indicate that

the release of N from SCU applied at these times is too slow for optimwn

plant growth

In another experiment in Pakistan in 1973 no differences

in the effectiveness of urea AS or SCU were noted in the yields of

continuously-flooded rice (table 20) Again these results are conshy

sistent with earlier results which indicate no superiority for SCU

when rice is continuously flooded

Nitrogen Studies--Maize

A series of three experiments were conducted by IITA in

armo-Nigeria in 1972-73 comparing AS urea SCU and

CAN (calcium

nium nitrate) as sources of N for maize (table 21) A significant

yield response was obtained for N at each location but no conaistent

differences were noted amaong sources These results are consistent

with results at other locations which have not shown that SCU is a

superior source of N for maize grown over a period of 3 to 4 months

Nitrogen--Wheat

The yields of wheat in Pakistan in 1969-70 (tables 22 and

23) show that yields with SCU) tended to be lower than those with ureaJ

although at one locction where sorghum was grown followilng wheat with

Table 19

Yields of Basmati-370 and IRRI-6 Rice at Punjab Agricultural Experiment Station in Pakistan in 1973 Under

Conditions of Intermittent Flooding

Rate Yield Source of N Time of Yield (Mtha) Increase of N B-370 IRRI-6 Application Basmati-370 IRRI-6 Average (Mtha)

0 0 - 21 353 287 -

SCU 90 150 At Puddling 325 545 435 148

Urea 90 150 At Puddling 309 500 405 118

AS 90 150 At Puddling 324 529 427 140

SCU 90 150 Puddling 372 572 472 185 Panicle Initiation

Urea 90 150 Puddling 335 502 419 132 Panicle Initiation

AS 90 150 Puddling 353 529 441 154 Panicle Initiation

SCU 90 150 After Transplanting 312 562 437 150 Panicle Initiation

Urea 90 150 After Transplanting 340 624 482 195 Panicle Initiation

AS 90 150 After Transplanting 349 583 466 179 Panicle Initiation

All plots received 45 lbs P205acre as single superphosphate

Relative Yield Increase ()

Source of N At Puddling Puddling Panicle Transplant h Panicle

Urea 100 100 100 AS 119 117 92 SCU 125 140 77

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-48

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ht tse balt s Owosiv as that to TwP it rocks WM bo

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ThUAIAd

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a4 10 0410 SWUSSM yt$4e TOP wUd predWr A r~ftIf fl~W t

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P11~0 pra~lpj prefer gre4r tuftlter for whlae

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asowcs of P tof ttde ro The wreem proucts omre raGther

pemour~a ot P syag besmti andMi as elt ov so gpamwhr

iuipiqffhate(TS) low twseeo Is eftwiltve Is thet

W41 preeme wae oialain ire post-rItoi effriq to Stanlato the

pud6itt of Irto paddle Wee ofsdlseireplastiq

0 49 shy

lbs partially scldiaatede grawilated Ml prodlucts Vere isshy

toiwdiats in 5tftOvttWS54 betwee wroiPi ad TVP NotV5Ymf to

me coo were they mere twoe $a a etfective ao TIP 00 sipifleast

LVSUMI5 at0 efecto wore toun tor thee produteo Timely dtIampWde

FR (-t00 mmoh) Uia amp~rally oar affective than Owe gra8448r FOampprodt

featal twos o 6 aotetire s I

Nowvero it to felt that sfortber field euprtet vth

hese interials Amd ether typs of grometatodl Wter nre wrrautad

hater ceeuwodh that they have me areec poteatlal toi additoG

e tate wAne the sectte as OtawrI sed bovoloen turther

euperimeste vth few reck pboophar s0d with reck pbophat treated

to sehesa citrata selmtliy or to ha csaducted

Metbir sertes of tbme enprtaeats wae c~edtmcted by IITA

to Ut~rta copal TVP AOP APP aed it at see tecastisix (table 14)

No dot lalt sewseltles teh draw tree thee results simouely em pear to tlvdl bsww they do stwgpt tbat forthew work with

MR to werramid so tbme sels

Table 24

LttcttF Swce MaPlate 06 ieldot IM AWaia CoelsANS at IITA (Ugboda ad Apoin ail sorit) aid at Ike (AUaba s5i series)

1973

Plate ot IP Apinu 5 poundebods A1ab

Ocrol 0 Z94 419 M)

Tr ipl ruprphite 20 349 3799378

Triple vepput 40 M09 410$

Triple 6wp~~b1 4271 4344 42250

Ammotw-ritpophW to 4201 4124 4040

Amosim-rdop~phlt 40 4270 4106 4231

AM tuo-polpephats 20 404 4244 3794

~eai~mpelppepbuI 400)49 4094

Cee m-pbpbt to- 59

momee eph lto 0 4192

LSO (0 0$) 29 1025

Th WPII

- 51 shy

101Y114 tpeM-fI PEP~tbRP YO

1 ~ ~ gmw 1pc~biofl- 9 Kla4v4h

Upia U04 Copfind am Crehout Stet Rpano at (Ia4

rico t IF t rume6 orth~ Caralto phoophale rocl QAR) vaUN pqU41 to

roopon from cmonetrat4 gsporphophai (CIP) who ort$o4 oil k

was 45j itwas tafertor vb protioo4 oil p war OS Ib 4iffer~c

in rtc reepos to X cod14 oo bo ttrit4 4 4 hvsciag of boil p

~ Pt o r11221 0 tP

c theto the rhimecyllndor of rico tots par to)14M4i1 roeoi~t

ed oil emd PA prior to tho ont of an~robi4 cMioe AA~ oIifoshy

nAte bYpot t taet~d tO fC4sin t~r 4PWden0 Of f Ot(tivshy

ofOWailiJtyno o prefla4 all Put that 4t01etoo 14 tvsIk

of the Ott to prvvld a 014for C4m0 44 mI 1 o4sf

EfftC ftPet141on AIAM-0 V f401td 4 4iv 440 Mtft

Aa torfat VampP f4MWfCi4W04wt0amp to 4eturWlI Ot(Wel~drIC ft

Ot f tM6 the flooded Ott 00 14 04019I Pft0uAw Of gAr~s~lr

pkS$t M40b MP) Tw P1101 Piset Prodwie W-e 10M0di Wr04

(10-1) emW 0aretilp ddw01at4 P WAA firom Rrth M~flRU414~$

wee cowiared with fie Md reWim 44104 proo~fo) foruk oith laWItter

I v te-PR P OW1004 4 4 O Wf ottil OW ellt Oo

Oveiel1 the 40tt dmcruie to effetotww Wtollowui Co fme

PR tpaUIB1I ldoltmo PR (pamwlatr) offr~- ArmeuM) 0 orwi

- 52 -

Effect of N Sourc6 and Water Management on Response of Rice

toe Zn- M Giordano J J Mortvedt OP Engelstad and Greenhouse

Staff Several rotes of CO(14H2)2 and (H )2So4 vith or without ZnO

wore applied to flooded and nonflooded Crowley oil (limed to pH 75)

to determine response of Bluebelle rice to Zn Yields with both N

sources veotrgreator on flooded then on nonflooded soil In the abshy

ence of applied Zn total dry matter production vith CO(NH2)2 was

slightly lower than with (NH)2S04 on flooded soil and considerably

lover on nonflooded soil Concentration of Zn wan higher in straw and

grain of plants roun on flooded than on nonflooded soil Although

concentration of P was unaffected by N source or Zn rate there was

som indication that cranslocation of P from straw to grain may be

depressed in nouflooded rice Concentration of N was lower in straw

grown on flooded than on nonflooded soil due to apparent dilution

thereas both X sources resulted in similar N concentrations in straw

at all rates of N application the N concentration in grain increased

with 0 rAse

feSpongi gf(SM to Chjorospodiostte and Related P Sources--

Si Allen and Greonhoue Staff A greenhouse pot experiment was

couct44d with corn Brown on Hountview silt loam to compare the ofshy

fectlivees of chlorospodiosito (Chlor-l) with concentrated supershy

phosphate (CP) Thomas slag and North Carolina phosphate rock (NC-PR)

Oil-prillad urea-phophato rock (UPI) FeA1JMP 20 7 and monomthyl

phosphate were included in the experiment Based on yield of forage and

uptake of P by tvo crops each of 6-weeks duration the following conshy

stui were dravat

I Chlor-1 was slightly loss effective than CSI Thomas slaS or NC-PR

from which Chlor-l wae prepared

- 53 shy

2 Granular UPR was a poor source of P its effectiveness was greatly

increased by reducing the particle size to -35mesh

3 FeAlNH4P207 was unavailable to the crop

4 Monomethyl phosphate was equivalent toor slightly more effective-

than CSP

Research Indirectly Related to TVA-AID Project

Response of Several Rice Varieties to Zn in Moist or Flooded

Soil--P M Giordano J J Mortvedt and Greenhouse Several varieties

of rice from Mexico and the Dominican Republic currently under investishy

gation in Puerto Rico for adaptation to upland culture were compared with

some established United States varieties with regard to Zn response on

moist and flooded Crowley sil (pH 75) Chontalpa (Mexico) Bluebelle

(Texas) and Starbonnet (Arkansas) were most responsive to applied Zn

Juma (Dominican Republic) intermediate and Sinaloa (Mexico) and Calrose

(California) were the least responsive The Sinaloa varieties (Mexico)

appeared to be best adapted to non-flooded conditions whereas Chontalpa

and Calrose were poorest Concentrations of Zn generally were higher in

plants grown on flooded than moist soil

Pattern of Growth and Zinc Accumulation by Rice--P M Giordano

J J Mortvedt and Greenhouse Staff Rice plants were harvested at weekly

intervals from shortly after emergence through maturity The objective

was to determine the rate of growth and Zn uptake by a Zn responsive varshy

iety (Bluebelle) and a less Zn-responsive variety (Calrose) in the presence

or absence of Zn applied to Crowley sil (pHl 75) Dry matter production

of Calrose was linear with time of growth and of a similar magnitude until

heading with or without applied Zn Bluebelle followed a similar pattern

where Zn was applied However in the absence of applied Zn foliage yield

was reduced markedly

-54

Uptake of Zn was similar for both varieties whenZn was

applied Dry matter production and Zn uptake by the two varieties

also were comparable when Zn was applied However yield of Calrose

was much higher than that of Bluebelle in the absence of applied Zn

while Zn uptake was only slightly higher This suggests that the lesshy

ser responsiveness of Calrose to Zn may be due to more efficient utilishy

zation of Zn There was no indication of a greater demand for Zn durshy

ing reproduction in either variety as was suggested in earlier greenshy

house experiments

Response of Upland Rice to P and Zn--P M Giordano J J

Mortvedt and Greenhouse Staff Several rates of P and Zn were applied

to Crowley sil (limed to pH 75) in factorial combination to determine

whether differences in rice growth under flooded and nonflooded soil

conditions are related to plant nutrition Although straw yields were

slightly higher in nonflooded rice receiving adequate P and Zn grain

yields were higher in the flooded crop increased rates of F andor Zn

did not result in equal yields Except in the highest Zn rate (75 mg)

concentrations of Zn in both straw and grain were higher with flooding

Concentration of P increased with rate of applied P and was higher in

the grain or flooded than upland rice at a comparable P rate In conshy

trast concentrations of N were lower with flooding due in part to dilshy

ution from increased growth

Rice Response to N and P in Flooded and Unflooded Cultures--

G L Terman S E Allen and Greenhouse-Analytical Staff Rates of

N from 250 to 2000 ntpot and P from 0 to 1000 mtpot were applied for

Nato rice grown on Mountview sil and Sango sicl (625 kg of soil per

pot) Market yield response to N and P was obtained Yields of straw

- 55 shy

total yields N uptake and N recovery were higher on unflooded than

on flooded soil cultures Grain yields however were slightly higher

with flooding These results indicate that with adequate applied

nutrients especially of N rice yields without flooding can approach

or even equal those under flooding

Uptake of N P Ca Mg and Zn increased with yield response

to N and P while K uptake decreased on the Mountview soil Concentrations

of N and P increased with applied N and P respectively while concentrations

of other nutrients were diluted in most situations with yield response to N

or P

Results from this experiment show that amouats of N applied in

previous pot experiments for rice have been much too low especially if the

crop was grown to maturity

Response of Corn to S and N i UUASand Urea-S--S E Allen

and Greenhouse Staff Three greenhouse pot experiments were conducted to

measure response to S and N in ulfur coated urea (SCU) urea amonium

sulfate (UAS) and urea -S as well as estimate N losses from surface apshy

plied N sources

In Experiment 260 less than 20 of the S mixed with the soil

was recovered from SCU or urea-S granules by two crops of corn as comshy

pared to 45 or 80 from flowers of S or Na2SO 4 CLop response followed

a similar pattern

In Experiment 260-A N sources were surface applied and alshy

lowed to dry for two weeks before incorporation Into the soil and plantshy

ing Recovery of N by two crops of corn was 77-82 for AN an compared

to 37-70 for urea UAS urea-S and ICU Thus n this experiment loss

of N from urea did not appear to be re~dcud by light S-coatlngn or by Inshy

corporating S or AS in the granules

-S -

I xbprZnSlt a Wtch aU Meyto 0-Ai Wt f9r

higher reermo teOrtOrs cOM reSpWNO i r0100 Of N w

not oaisteontly related to sewe ot N In edl tust 0 ioltiUe Lim

lo in VMuwpped evlmtUTS 48 merind by seirest nte appresOehe

501 for uroa as cwarod to 210 for urea peepha

Rus- or Upse to LoAmIl34I a AriMed bI Earl U

MW NOWlsIIsIr-4 L Toman 5 1 Alln and eesese StNf rio

row on Sawg did (0 tpot) We 1l0l0 Ws feritiud vith 05is

of Npot mixod with the 6011 as aureCA NiAO) 1 Age god At Ures

was also itcluded at rtt t 05 10 end 15 of Upee Theas trealshy

onto were followed 4 wpdrsetago of U s AN wre 4C 10o or at I3n

Weeks toulin up to IS pot

A soil application of 10 pot rosulvod to the maim yield

at 4 weeks Tio4 sad percont prottis t intre raite tncreased rftishy

linearly with U applictalien IeseeItally all at the m iNd wit

the moil w domitrifted after flooding Grail end straw Ilelds vere

highly correlatod with tiliriag and vlh ubers of gralm arl

The results Widicat that 0$ to 10 a of Upot as orea or

NN bsuld be sied with the oil to stilate tiilrir with adshy

ditional 0 topireased later to increase grain lIds mad protia cmshy

tout

DIVISION 54- FERTILIZER TECHNOLOGY AND USE

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-02

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DIVISION 8-9-SOIL MINERALOGY

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65

0IL CL OC AMXR PROC VOL 38 1974

)aT1 S4I104 ow Lusanll Tawng isa tall Thai variety known for beingIwo nonshyi s s ) sensitive to photoperiod A split-plot design was used in

S e e these euperimeots with 4 rates of P (I1 22 44 and 88t i V IV k of Pha) applied a main plot treatments and with the OF It sourMes of P as subplot treatments There were two checkS plots in each rmplicate The extra check plot was included to permit the application of fresh TSP standard Jor the

It- ti 06 + i bull fa succeeding crop the p-4me of bi was to permit accurate d awrnwal of the mdual effectiveness of the phosphate

ftinSUbI rock The P fertilioers were broadcast on the mud andthen Worporald In the soil during the last harrowing At

whM N both On ACS indx ampM time of transplanting Immediately before the last harrow61t (4j 5 4 01 P s 3Mm o Vallonal in con n 100 kgha of N as ammonium sulfate and 33 kghaWO Of Spews ampm lIW thaabe rocks do ACS indes of K as polium chloride were applied A total of 40 wa in prepw O do ctih k otent kha of N a ammoniunt sulfate was applied later in twoir P The hew oNed amp wM W for 5 of gw topdrossingp with about 5cm depth of water on the plotsvV I aiOMveffeOctveee Three to six ldayold selings pr hillwW the ACS idex were planted00OWW wia Oft fo an c irNk I p Coen 20 by 20 cm part in straight rows Hand weeding was used

and insecticide were applied for Insect control Grain yieldw was masared by sampling 5 ml of each plot excluding border rows The date of heading in each treatment and theUNiN d pbM W Weks rin tOW USA UMe In Tale yed componnts at hafvel were also recorded

I filM rsperMS esOM kdwdua 1 t ab The average yields of ough (unhulled) rice for botha 84 OW O 8uo 4 Thala TM was a locations are ploutel in PIS 3 for the first crop (1969 wet

owou thRM seaso0) The Veamps yield response was obtained at Klonge (s) W lDtO t Of dMa of1tw W d l R Luang however a 4ute satisfactory yield response was

~Mk ^d TVA UJSD ad Kd UnIveS obtalned to applied P at Bangkhen as wellXUe LaM e R qwrw Ims The sod was do Relative aponomlAe effectiveness values were calculated

VOW (a ksA w edmwL t Poesesm h Vy for these data and am presented In Table 3 The valuesdAY buo if dIe ouh ne Pee wtk a Mlak vow 1009 for th first crop are plotled against ACS index in Fig 41 This Im M i6ti l 4bNd IO a0 O mkarnk for both locatio r relationship was linear for the

11400 ThCpH 0( lb pW IW 01 th UpeiaW so Sanodion location and curtiltnear for KIng Luang The was u i 4A sksamp lMaor nrusio model amparounted for 81 of theAmO$MI Aw jAAsue Swim T1 Snh Wd variation In the AE valu for Bantkhen a square root

Mems a Iw iv fern alh$ sedm haowg dayNW W t he plAL At tdo M tM aso W s as ctminued throufh eltaM t Ofpof -le lse wo am P OeNI VeOpls 1o ealluae tI lon4erm MIdual Offccls

A on W isset i a wse to hsh eapeel of these ooihss t ocks The baagkhon experimnent was letmiaI1DlVemisthis is a w hulu Lo g Tasug ia iasael aft - Msd residual Ves will be pr-Om crok TheseTwod esewm

SWWo

A

lP~U~7 ISIIPe1iuIWN e bsedisssin ian ghth siaoelalbe

984 0 6 O O - M s -s fWPas 11eSft W d Uo al a o

o

S4l~ lIIII I~l I 1f fl

( +

+ + + m + ++++-

++ +(++ + ++++ + ++ ++

- 66 -

ENOIMLSTAD ET AL RESPONSE BY FLOODED RICE TO PHOSPHATE ROCKS VARYING IN CITRATE SOLUBILITY

I I I I j0 I I

BANOKHEN BANGKHEN

pH 56 6 - 0o

TSP

NC

5~ ~ ~ L o 4 - -shy

4 ] - --------shy04

6S

|0 III 2 44 8r 66

I I I

a 1KLONG LUANG

pH 46 z KLONG LUANG

TSP Sc2 NCFL(N)

5 FLIC) J0 TU

oshy

4 ~40shy

3 bull eM0

I - I I I I I

0 II 22 44 88 0 5 10 15 20 IP APPLIED KO HA ABSOLUTE CITRAE SOLUBIITY INDEX

Fig 3-Yield of rough rice at Klong Luang and Bangkhen Rice Fig 4-Relative agronon effectiveness () of P sources ploz-Experiment Stations Thalmand as affected by rate and Source ted against citrate solubity Index for both Thailand field ex

of P applied (crop 1) periment (first crop only)

regression model accounted for 97 of the variation in sumably resulted from crop uptake and reaction with the RAE values at the Klong Luang location soil to form less soluble products Such effects may have

These experiments were continued during the dry season been more important at the lower rates since the two TSP of early 1970 to ascertain the residual effectiveness of the curyes converged at the highest rate of application various sources applied to the first crop No new P was These data from KIong Luang indicate that (i) residual applied except for the fresh TSP standard mentioned effects of all rocks except Mlcwuri were substantial (ii) above rhe experiment otherwise was conducted in a man the relationship between relative agronornic effectiveness ner similar to that followed in the first crop of the phosphate rocks and citrate solubility levels was

The response to both freshly applied ad residual P was largely obscured and (iii) the general superiority of TSP marked at the Klong Luang location and marginal at over phosphate rock in terms of effectiveiss persisted Bangkhen In fact at the latter location the response was through the second crop so small that little can be said regarding residual effectiveshyness The yield data from crop 2 at the Klong Luang DISCUSSION experiment are plotted in Fig 5 Greenhouse and field data presented in this paper show

Relative agronomic effectiveness values (Table 3) were clearly that there are substantial differences among phosshycalculated for the Klong Luang data using both the residual and freshly applied TSP as standards It is of Interest to note that the superiority of TSP over the phosphbte rocks Table 3-Relative agronomic effective values for field experishyments in Thailand persisted through the second crop The main difference in KlowlZmlnql~the residual effects is that with the exception of the MIs- s Crop 1 Crop 21 Crop 1-shysouri rock Ihe marked relationship between citratr-soluble WoiCarolina yl 59 76

phosphate rocks and RAE had largely rds norh) a 64P conltct of th Florida (eqlral is 6969 6

disapipeared In this acidic soil (pHi 46) P would by this I14o 69 63 40 ToonesS 31 65

limo be supplied by Intermediate reaction products In addl Missou 0 o lion to residues of the initial spatlte Ts P o 2 o 0

The TSP applied to the first crop declliv-d slightly In campIafcmWataesr e id ofeuhuloefor 22MA rates of PtColeouattd as aba u tlte td18 kS ratesp dlverage yield tM868 to 22 44

effectiveness relative to the freshly applied ISP This pre- of d s4

A

4

- 67 shy

-SOIL SCL SOC AMER I

KLONG LUANG CROP 2

Si 3

eN

TAPPLIEDKGHA

Fig 5-The residual effectiveness ovarious P sources for crop s compared with freshly applied TSP Klong Luang Rice

Experiment Station Thailand

phate rocks in terms of agronomic effectiveness for flooded

rice Further these differences can be predicted by means of citrate solubility or by the ACS index It appears that

the latter is more appropriate where the content of apatite varies among phospiate rocks The most soluble phosphate rocks approached but did not actually equal TSP in limit-iuig (maximum) yield in these experiments regardless of rate applied This agrees with the results of Ensminger Pearson and Armiger (4) One needs to consider the defi-nite posribility of same yield loss in zhoosing a phosphate

rock over TSP such yield losses must be weighed against the lower price of phosphate rock The explanation for such iosses may involve concentration of soluble P in the soil Khasawneh and Copeland (6) suggest that the growth rate of crop plants is a function of P concentration that can be maintained in the soil solution If P concentration is limiting or inadequate becawe of a lower dissolution rate of phosphate rock the growth iate ard uiiimate yield will be diminished accordingly

The RAE values bascd on yield increases reflect the agronomi effectiveness of these various sources relacve

to the TSP standard however these nould be supple-

mented by an economic analysis before rational choice can

be made The following calculations will provide an estimate of

the rclativ ecooomic effectiveness(REE)

Y t Ps aXpatREE -- 100

vahtercks t sphate or e b i- eor

Price of TSPkg fo

be Price of PRkg P

PROC VOL 38 1974 leO

90r

Wsoshy

0

60-LUSEPHOSPHATE ROCK

00 10 20

PTP PR

Fig 6-Relationship between relaZive effectiveness values (RAE) and the price ratios between TSP and phosphate rock Such a figure can be used in making a choice between these

sources

If REE exceeds 100 in this calculation the phosphate rock would be preferable to TSP

The REE calcuktaaa wre used in preparing an indifshyference curve (Fig 6) wherein RAE values are plotted

against PTsPPpR ratios The cu~rve itself connects those points at which REE equals 100 When exactly on the curve it makes no real economic difference what source is chosen After choosing a suitable price ratio one can then project upward from that ratio knowing the RAI

value (or estimating it from such data as shown in Fig 4 using citrate-soluble P content) one can then choose the source on the basis of both agronomic and economic conshysiderations For example if the price ratio is 25 and the RAE value of the phosphaite rock is greater than 40 the rock phosphate in question would be used However if the RAE value was less than 40 TSP would be a better choice There are indications that if the P in the more soluble phosphate ro~cks (North Carolina north Florida central Forida) is less than half as expensivz as that in TSP these rocks would be feasible altereaives to TSP on soils similar

to thoseused in Thailand This analysis does not take into account the possibility

of lower yields from use of phosphate rock In addition only a portion of the various yield response curves was used in this anlysis ie up to 22 kgha Beyond this

rate yield response was much less pronounced it could be argued that at less than maximum yields TSP would produce a certain yield at lower rates of P than would phosshy

pow ofrock This would especially be true for rates applioa example at Klong Luang 5500 kg of

rice pcr iectare could have been produced with either Ii kg of P as TSP or 44 kg of P as son of the more reacshy

tire phosphate rocks It should be pointed ot however

- 68 shy

(IIKIS amp YOUN( ARIFICIAL WEATIIERING OF OXIDIZED p[ll- IV

that this is the yield level that would show the widest difference such is the advantage of hindsight

Farmers generally prefer granular fertilizers for machine

or hand application This is a disadvantage for the phos-phate rocks which are normally arplied in finely divided form Recently experimental quantities of granular urea-

phosphate rock mixtures have been made by TVA Results of trials with these fertilizers will be reported elsewhere

LITERATURE CITED

1 Armiger W H and Maurice- Fried 1957 The plantavailability of various sources of phosphate rock Soil Sci Soc Amer Proc 21183-188

2 Bengston G W E C Sample and S E Allen 1974 Re-sponso of slash pine seedlings to P sGurces of varying ci-trato solubility Plant Soil (In press)

3 Caro JIt and W Hill 1956 Chard eristics and fer tilizcr value of phosphate rock from different fields J Agr Food Chem 4684-687

4 Ensminger I E R W Peirson and W II Atmiger1967 Effectivencs of rock phosphate as a source of phosshyphurus for plants US Dep Agr ARS Bull 4112S

5 Engelstad 0 P J G Getsinger anid I J Stangel 1972 Tailoring of fertiliers for rice cnnece Valley Author ftyNational Fertilicr Developmnent Center Hull Y-52

6 Khasawnch F E and Jane P Copcland 1971 (otton root growth and uptake of nutrievos relation oif phosph

rus uptake to quantity intensity and buffering capacit) Soil Sci Soc Amer Proc 37250-254

7 Lehr JR and G H McClellan 1972 A revised lIbora tory reactivity scale for evaljativg phosphate rocks for direct application Tennessee Valley Authcrity National Fertilizer Development Center lull Y-43

H Terman G L S EAllen and 0 P Engelstad 1970 Response by paddy cice to ratcs and suurces of appliedphosphorus Agron J63390-394

DIVISION S-9-SOIL MINERALOGY

Artificial Weathering of Oxidized Biotite IV The Inhibitory Effect of Potassium on Dissolution llate

R JGILKES AND R C YOUNG2

ABSTRACT

Rates of dissolution of oxidized biotites in OIM 001M ICI are severely depressed in the presence of IM KCI The amovnts of Al Mg Mn dissolved in the first eytraction are similir to those found without KCI however subsequent extractions remove these elements at 10-20 of the corresponding lICI rates This effect may be due to a decreased rate of vermiculite formation thereby reducing the effective basal area exposed to attack A decrease in dissolution rate with increasing ferric iron content was still apparent in the presence of IM KCI

Additional Index Words X-ray diffraction infrared aborp-

N EARLIER papers of this series the tole of biotite in soils

as a source of both macro and micronutrient elements

has been discussed ((Gilkes Young and Quirk 1972 1973ab) Experiments in artificial weathering uiing as va-

riety of extractants were undertaken to determiie the inlu-

ence of oxidation of octahedrally coordinated iron on the bull release of structural cations to solution The results of this

work demonstated that biotite behaves anomalously with respect to the other common ferromagnesian minerals found in soils Oxidation leads to the development of a high degree of resistance to cation exchange and dissolution Several authors have coiwludcd that decreased rates of K

Contribution from the Dep of Soi Science and Plant Nutri-tion Institute of Agriculture Univ of Western Australia Ned-lands 6009 Western Australia Received 29 Sept 1973 Ap-proved 8 Jan 1974

2 Senior Lecturer in Soil Science and Research Officer respeclively

replacement in electrolytes shown by oxidized biotites are

a result of the inclination of structural hydroxyl adjacent to newly created trivalent iron or vacant octahedral cation sites (Robert and Pedro 1959 Barshad and Kishk 1968) Gilkes et al (1973b) suggested that decreased rates of disshysolution of oxidized biotite in 0001 0t)l 0Af CI may also be due to the presence of inclined hydroxyl In this case a smaller surface area external and exposed intershylayer may be available for attack if K replacement by hyshydrogen ions occurs at a slower rate in oxidized biotites

Gastuche (1963) has shown that significant dissolution ofthe (IIM) biotile face may occur and it is easily demonshystrated that the proportion of exposed (001M) face in weathering biotites depends on the percentage K replaced

Rausell-Colom ct al (1965) have shown that hydrogen ions act in an identical fashion to metal cations in K exshy

change from micas In particular exchange c-f K by hydroshy

gen ions will be terminated or greatly reduced by high levels of K in solution Thus if dissolution of oxidized biotite by

acids is carried out at sufficiently high K levels to prevent vermiculization any differences in dissolution rate that may occur cannot simply be ascribed to differences in rates of K replacement The following results were obtained from such an experiment which unlike the experiment described in Parts I and II (Gilkes et al 1973ab) does not attempt to simulate natuiral - conditions

MATERIAILS AN) M HIiODS Further subsamples of the less than 0 hiotites used in K

excherandbaid disoo tu es (G iles e9n K exchange and acid dissolution studies (Gilkes et al1973ab) were used in these experiments Preparation of sequentiallyoxidized biotites without intermediate vermiculite formation is

Page 27: I70 - United States Agency for International Developmentto ascertan, but tgl.eetad, 1, L,. ("Tailoring of Pertiltiters for ice,'" TVA ulletin Y-52) states that the staft of IOi has

- 24 shy

India--The results of four experiments conducted with flooded

transplanted rice in India by the All-India Coordinated Rice Project

Hyderabad are given in table 3 The response to N was excellent the

yield without N being only 41 of those obtained with basal applications

of N as uza With basal applications of SCU the yields were 20 higher

than with basal applications of urea and in the three experiments in

which urea applications were split yields with SCU were 18 higher than

yields with split applications of urea When comparing the average Nshy

response (kamp grainKg N) yields were increased 13 more by SCU than by

basal applications of urea

The data from one experiment with light irrigated rice in India

are given in table 4 yields were relatively low and differences between

N sources or method of application were not significant However yields

with SU tended to be higher than when all urea was applied at planting

but lower than when split applications of urea were applied Again yields

increased more than 13 more with SCU than with basal applications ofwere

ur

In tables 5 and 6 the yields of a short-duration transplanted

rice grown in irrigated light-textured soils at five locations in India

indicate that higher yields were obtained with SCU than with urea when apshy

plied as a basal application Yield increases due to basal N applications

were 502 greater with SCU than with urea However split applications of

resulted in yields equal to those obtained with basal applications ofurea

CU

The yields of direct-seeded upland rice grown at three locations

to India are given in table 7 and the relative yields in table 8 Yields

were low due to drought but good responses were nevertheless obtained for

- 25 -

Table 3

Effect of N Source and Time of Application on Yield of Paddy (Flooded) Rice in India 1972 (Summary of Reported Data from 4 Experiments)

Experimental Number Source Rate Method Yield Relative N-Response

and of of N of Yield Kg Grain

Season Nitrogen kgha Application mtha Kg N

- - - 196 34 -

Urea 120 Basal 573 100 314

11 Urea 120 80 + 40 611 107 345 Rabi SCU 120 Basal 713 124 430

12 - 0 - 202 30 -

Urea 125 Basal 682 100 384

Rabi Urea 125 35 + 20 + 35 + 35 633 95 344 SCU 125 Basal 781 115 463

13- 0 - 168 44

Urea 100 Basal 385 100 217

Kharif Urea 100 30 + 20 + 25 + 25 400 104 232 SCU 100 Basal 462 120 293

14 -

Urea -

125 -

Basal 355 650

55 100

-

236

Rabi SCU 125 Basal 781 120 341

-- 26 -

Table 4

Effect of N Source and Time of Application on Yield of Light Irrigated Rice in India 1972 (Summary of Reported Data From

One Experiment at Pattambi)

Experimental Number Source Rate Method Yield Relative N-Response

and of of N of Yield Kg Grain Season Nitrogen (kgha) Application (mtha) Q) Kg N

38 0 - 204 85 -Rabi Urea 120 Basal 241 100 308

Urea 120 60 + 0 + 30 + 30 267 ill 525 SCU 120 Basal 255 106 425

Table 5

Effect of N Source and Time of Application on Yields of Short-Duration Transplanted lice Variety Grown on Irrigated Light-Textured Soils at 5 Locations in India 1972

(Snmzarized From Reported Data)

Rate Grain Yields (MtHa) Source of N Method of N GrainI of N kgh Application Faizabod Karjat Mandva Pattabi laya Averaje X

- 291 266 211 19 340 260 -

Urea 100 Basal 386 407 361 285 482 3 124 Urea 100 50 + 25 + 25 399 430 434 334 6amp2 4A8 186

SCU 100 Basal 368 468 439 360 572 41 181

Table 6

Effect of I Source end Tlae of ApplIcattoo c RIstave Tle24 of a rt- rat1 T Lsd lice Vasrety Crin o Irrigated L41tshy1 at S Locitite mindi 1972

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AA MO 4 S4

4of O 149 6MID O 41110

KthD 00

- 38 -

Table 18

Yild of aemati-370 Rice at Punjab Agricultural Research

Institute in Pakistan in 1969-70 Grown Under

Couditions of Intermittent Flooding

Pate of application

=IL

o 0 67 67 100 100 67 67

100 100 67 67 200 100

Average for Sources

Ntha

AS 260 gres 279

320

Source f5

-

AS AS Ura Urea SCU SCU

Yield

Relative

93 100 115

(M)O

Yield

Increase Yield Due to N

(Ktlha) (mtha)

-212 245 033 274 062 260 048 297 085 315 103 325 112

Yield Increase

Relative

72048 067 100 108 161

(2)

- 39 shy

Short-statured high yielding rice varieties grown extenshy

sively in northern Peru require extremely high rates of conventional

N sources to achieve maximum yields The recovery of applied N is

extremely low due to the use of intermittent flooding This water

management system results in heavy N losses even with properly timed

split applications In search of simpler and more effective methods

of N management eight field experiments were conducted in the region

to evaluate sulfur-coated urea (SCU) an experimental slow-release N

source supplied by the Tennessee Valley Authority Rice yields were

increased an average of 59 more by pretransplant-incorporated SCU than

by urea or ammonium sulfate applied in the same manner SCU produced

excessive vegetative growth which resulted in yield reductions at high

N rates

Regardless of an assumed 48-higher unit N cost in SCU the

overall benefits of pretransplant-incorporated applications of SCU

were favorable since there was a decrease of 40 in the optimum rate

of N and the need for precise timing of application was eliminated

Pakistan--In Pakistan basal applications of AS urea and

SCU to rice grown under conditions of intermittent flooding in 1969-70

(table 18) indicate that SCU is a superior source of N as compared to

urea or AS when all N is applied at or before planting The data also

indicate that a yield response was obtained for P applications but a

comparison of N sources at each level of P indicates that no interaction

between N and P was present so that differences between N sources were

relatively the same at each level of P Yields were increased about 60

more when SCU was applied than when urea was applied Yield increases

with AS were only about 72 of the increase obtained with urea these reshy

sults do not agree with the generally-reported superiority of AS as comshy

pared to urea as a source of N for rice

- 40 -

In 1973 experiments were conducted in Pakistan using both

Basmati-370 and IRRI-6 varieties of rice grown under conditions of

When all N was applied at puddlingintermittent flooding (table 19)

or 12 at puddling and 12 at panicle initiation both AS and SCU were

superior to urea with SCU tending to be the most efficient source

However when N was applied 12 at transplanting and 12 at panicle

initiation SCU was the poorest source of N This would indicate that

the release of N from SCU applied at these times is too slow for optimwn

plant growth

In another experiment in Pakistan in 1973 no differences

in the effectiveness of urea AS or SCU were noted in the yields of

continuously-flooded rice (table 20) Again these results are conshy

sistent with earlier results which indicate no superiority for SCU

when rice is continuously flooded

Nitrogen Studies--Maize

A series of three experiments were conducted by IITA in

armo-Nigeria in 1972-73 comparing AS urea SCU and

CAN (calcium

nium nitrate) as sources of N for maize (table 21) A significant

yield response was obtained for N at each location but no conaistent

differences were noted amaong sources These results are consistent

with results at other locations which have not shown that SCU is a

superior source of N for maize grown over a period of 3 to 4 months

Nitrogen--Wheat

The yields of wheat in Pakistan in 1969-70 (tables 22 and

23) show that yields with SCU) tended to be lower than those with ureaJ

although at one locction where sorghum was grown followilng wheat with

Table 19

Yields of Basmati-370 and IRRI-6 Rice at Punjab Agricultural Experiment Station in Pakistan in 1973 Under

Conditions of Intermittent Flooding

Rate Yield Source of N Time of Yield (Mtha) Increase of N B-370 IRRI-6 Application Basmati-370 IRRI-6 Average (Mtha)

0 0 - 21 353 287 -

SCU 90 150 At Puddling 325 545 435 148

Urea 90 150 At Puddling 309 500 405 118

AS 90 150 At Puddling 324 529 427 140

SCU 90 150 Puddling 372 572 472 185 Panicle Initiation

Urea 90 150 Puddling 335 502 419 132 Panicle Initiation

AS 90 150 Puddling 353 529 441 154 Panicle Initiation

SCU 90 150 After Transplanting 312 562 437 150 Panicle Initiation

Urea 90 150 After Transplanting 340 624 482 195 Panicle Initiation

AS 90 150 After Transplanting 349 583 466 179 Panicle Initiation

All plots received 45 lbs P205acre as single superphosphate

Relative Yield Increase ()

Source of N At Puddling Puddling Panicle Transplant h Panicle

Urea 100 100 100 AS 119 117 92 SCU 125 140 77

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-48

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ht tse balt s Owosiv as that to TwP it rocks WM bo

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ThUAIAd

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of law Vhld free ww e1 e66001 4 It cooUt be YgWd Sutt

a4 10 0410 SWUSSM yt$4e TOP wUd predWr A r~ftIf fl~W t

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P11~0 pra~lpj prefer gre4r tuftlter for whlae

of hoaw ppltrstie Mhe to a dloedveaP for The PINSOO rocka

vkth m r II spotted 10 ftewil 4106Me tem

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forgof wee aMW pbsepbots A fths pemhawe evsielew us

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mmfp MW phapa A (CI) sed graewletod pampAtlti arlolatod Pa

asowcs of P tof ttde ro The wreem proucts omre raGther

pemour~a ot P syag besmti andMi as elt ov so gpamwhr

iuipiqffhate(TS) low twseeo Is eftwiltve Is thet

W41 preeme wae oialain ire post-rItoi effriq to Stanlato the

pud6itt of Irto paddle Wee ofsdlseireplastiq

0 49 shy

lbs partially scldiaatede grawilated Ml prodlucts Vere isshy

toiwdiats in 5tftOvttWS54 betwee wroiPi ad TVP NotV5Ymf to

me coo were they mere twoe $a a etfective ao TIP 00 sipifleast

LVSUMI5 at0 efecto wore toun tor thee produteo Timely dtIampWde

FR (-t00 mmoh) Uia amp~rally oar affective than Owe gra8448r FOampprodt

featal twos o 6 aotetire s I

Nowvero it to felt that sfortber field euprtet vth

hese interials Amd ether typs of grometatodl Wter nre wrrautad

hater ceeuwodh that they have me areec poteatlal toi additoG

e tate wAne the sectte as OtawrI sed bovoloen turther

euperimeste vth few reck pboophar s0d with reck pbophat treated

to sehesa citrata selmtliy or to ha csaducted

Metbir sertes of tbme enprtaeats wae c~edtmcted by IITA

to Ut~rta copal TVP AOP APP aed it at see tecastisix (table 14)

No dot lalt sewseltles teh draw tree thee results simouely em pear to tlvdl bsww they do stwgpt tbat forthew work with

MR to werramid so tbme sels

Table 24

LttcttF Swce MaPlate 06 ieldot IM AWaia CoelsANS at IITA (Ugboda ad Apoin ail sorit) aid at Ike (AUaba s5i series)

1973

Plate ot IP Apinu 5 poundebods A1ab

Ocrol 0 Z94 419 M)

Tr ipl ruprphite 20 349 3799378

Triple vepput 40 M09 410$

Triple 6wp~~b1 4271 4344 42250

Ammotw-ritpophW to 4201 4124 4040

Amosim-rdop~phlt 40 4270 4106 4231

AM tuo-polpephats 20 404 4244 3794

~eai~mpelppepbuI 400)49 4094

Cee m-pbpbt to- 59

momee eph lto 0 4192

LSO (0 0$) 29 1025

Th WPII

- 51 shy

101Y114 tpeM-fI PEP~tbRP YO

1 ~ ~ gmw 1pc~biofl- 9 Kla4v4h

Upia U04 Copfind am Crehout Stet Rpano at (Ia4

rico t IF t rume6 orth~ Caralto phoophale rocl QAR) vaUN pqU41 to

roopon from cmonetrat4 gsporphophai (CIP) who ort$o4 oil k

was 45j itwas tafertor vb protioo4 oil p war OS Ib 4iffer~c

in rtc reepos to X cod14 oo bo ttrit4 4 4 hvsciag of boil p

~ Pt o r11221 0 tP

c theto the rhimecyllndor of rico tots par to)14M4i1 roeoi~t

ed oil emd PA prior to tho ont of an~robi4 cMioe AA~ oIifoshy

nAte bYpot t taet~d tO fC4sin t~r 4PWden0 Of f Ot(tivshy

ofOWailiJtyno o prefla4 all Put that 4t01etoo 14 tvsIk

of the Ott to prvvld a 014for C4m0 44 mI 1 o4sf

EfftC ftPet141on AIAM-0 V f401td 4 4iv 440 Mtft

Aa torfat VampP f4MWfCi4W04wt0amp to 4eturWlI Ot(Wel~drIC ft

Ot f tM6 the flooded Ott 00 14 04019I Pft0uAw Of gAr~s~lr

pkS$t M40b MP) Tw P1101 Piset Prodwie W-e 10M0di Wr04

(10-1) emW 0aretilp ddw01at4 P WAA firom Rrth M~flRU414~$

wee cowiared with fie Md reWim 44104 proo~fo) foruk oith laWItter

I v te-PR P OW1004 4 4 O Wf ottil OW ellt Oo

Oveiel1 the 40tt dmcruie to effetotww Wtollowui Co fme

PR tpaUIB1I ldoltmo PR (pamwlatr) offr~- ArmeuM) 0 orwi

- 52 -

Effect of N Sourc6 and Water Management on Response of Rice

toe Zn- M Giordano J J Mortvedt OP Engelstad and Greenhouse

Staff Several rotes of CO(14H2)2 and (H )2So4 vith or without ZnO

wore applied to flooded and nonflooded Crowley oil (limed to pH 75)

to determine response of Bluebelle rice to Zn Yields with both N

sources veotrgreator on flooded then on nonflooded soil In the abshy

ence of applied Zn total dry matter production vith CO(NH2)2 was

slightly lower than with (NH)2S04 on flooded soil and considerably

lover on nonflooded soil Concentration of Zn wan higher in straw and

grain of plants roun on flooded than on nonflooded soil Although

concentration of P was unaffected by N source or Zn rate there was

som indication that cranslocation of P from straw to grain may be

depressed in nouflooded rice Concentration of N was lower in straw

grown on flooded than on nonflooded soil due to apparent dilution

thereas both X sources resulted in similar N concentrations in straw

at all rates of N application the N concentration in grain increased

with 0 rAse

feSpongi gf(SM to Chjorospodiostte and Related P Sources--

Si Allen and Greonhoue Staff A greenhouse pot experiment was

couct44d with corn Brown on Hountview silt loam to compare the ofshy

fectlivees of chlorospodiosito (Chlor-l) with concentrated supershy

phosphate (CP) Thomas slag and North Carolina phosphate rock (NC-PR)

Oil-prillad urea-phophato rock (UPI) FeA1JMP 20 7 and monomthyl

phosphate were included in the experiment Based on yield of forage and

uptake of P by tvo crops each of 6-weeks duration the following conshy

stui were dravat

I Chlor-1 was slightly loss effective than CSI Thomas slaS or NC-PR

from which Chlor-l wae prepared

- 53 shy

2 Granular UPR was a poor source of P its effectiveness was greatly

increased by reducing the particle size to -35mesh

3 FeAlNH4P207 was unavailable to the crop

4 Monomethyl phosphate was equivalent toor slightly more effective-

than CSP

Research Indirectly Related to TVA-AID Project

Response of Several Rice Varieties to Zn in Moist or Flooded

Soil--P M Giordano J J Mortvedt and Greenhouse Several varieties

of rice from Mexico and the Dominican Republic currently under investishy

gation in Puerto Rico for adaptation to upland culture were compared with

some established United States varieties with regard to Zn response on

moist and flooded Crowley sil (pH 75) Chontalpa (Mexico) Bluebelle

(Texas) and Starbonnet (Arkansas) were most responsive to applied Zn

Juma (Dominican Republic) intermediate and Sinaloa (Mexico) and Calrose

(California) were the least responsive The Sinaloa varieties (Mexico)

appeared to be best adapted to non-flooded conditions whereas Chontalpa

and Calrose were poorest Concentrations of Zn generally were higher in

plants grown on flooded than moist soil

Pattern of Growth and Zinc Accumulation by Rice--P M Giordano

J J Mortvedt and Greenhouse Staff Rice plants were harvested at weekly

intervals from shortly after emergence through maturity The objective

was to determine the rate of growth and Zn uptake by a Zn responsive varshy

iety (Bluebelle) and a less Zn-responsive variety (Calrose) in the presence

or absence of Zn applied to Crowley sil (pHl 75) Dry matter production

of Calrose was linear with time of growth and of a similar magnitude until

heading with or without applied Zn Bluebelle followed a similar pattern

where Zn was applied However in the absence of applied Zn foliage yield

was reduced markedly

-54

Uptake of Zn was similar for both varieties whenZn was

applied Dry matter production and Zn uptake by the two varieties

also were comparable when Zn was applied However yield of Calrose

was much higher than that of Bluebelle in the absence of applied Zn

while Zn uptake was only slightly higher This suggests that the lesshy

ser responsiveness of Calrose to Zn may be due to more efficient utilishy

zation of Zn There was no indication of a greater demand for Zn durshy

ing reproduction in either variety as was suggested in earlier greenshy

house experiments

Response of Upland Rice to P and Zn--P M Giordano J J

Mortvedt and Greenhouse Staff Several rates of P and Zn were applied

to Crowley sil (limed to pH 75) in factorial combination to determine

whether differences in rice growth under flooded and nonflooded soil

conditions are related to plant nutrition Although straw yields were

slightly higher in nonflooded rice receiving adequate P and Zn grain

yields were higher in the flooded crop increased rates of F andor Zn

did not result in equal yields Except in the highest Zn rate (75 mg)

concentrations of Zn in both straw and grain were higher with flooding

Concentration of P increased with rate of applied P and was higher in

the grain or flooded than upland rice at a comparable P rate In conshy

trast concentrations of N were lower with flooding due in part to dilshy

ution from increased growth

Rice Response to N and P in Flooded and Unflooded Cultures--

G L Terman S E Allen and Greenhouse-Analytical Staff Rates of

N from 250 to 2000 ntpot and P from 0 to 1000 mtpot were applied for

Nato rice grown on Mountview sil and Sango sicl (625 kg of soil per

pot) Market yield response to N and P was obtained Yields of straw

- 55 shy

total yields N uptake and N recovery were higher on unflooded than

on flooded soil cultures Grain yields however were slightly higher

with flooding These results indicate that with adequate applied

nutrients especially of N rice yields without flooding can approach

or even equal those under flooding

Uptake of N P Ca Mg and Zn increased with yield response

to N and P while K uptake decreased on the Mountview soil Concentrations

of N and P increased with applied N and P respectively while concentrations

of other nutrients were diluted in most situations with yield response to N

or P

Results from this experiment show that amouats of N applied in

previous pot experiments for rice have been much too low especially if the

crop was grown to maturity

Response of Corn to S and N i UUASand Urea-S--S E Allen

and Greenhouse Staff Three greenhouse pot experiments were conducted to

measure response to S and N in ulfur coated urea (SCU) urea amonium

sulfate (UAS) and urea -S as well as estimate N losses from surface apshy

plied N sources

In Experiment 260 less than 20 of the S mixed with the soil

was recovered from SCU or urea-S granules by two crops of corn as comshy

pared to 45 or 80 from flowers of S or Na2SO 4 CLop response followed

a similar pattern

In Experiment 260-A N sources were surface applied and alshy

lowed to dry for two weeks before incorporation Into the soil and plantshy

ing Recovery of N by two crops of corn was 77-82 for AN an compared

to 37-70 for urea UAS urea-S and ICU Thus n this experiment loss

of N from urea did not appear to be re~dcud by light S-coatlngn or by Inshy

corporating S or AS in the granules

-S -

I xbprZnSlt a Wtch aU Meyto 0-Ai Wt f9r

higher reermo teOrtOrs cOM reSpWNO i r0100 Of N w

not oaisteontly related to sewe ot N In edl tust 0 ioltiUe Lim

lo in VMuwpped evlmtUTS 48 merind by seirest nte appresOehe

501 for uroa as cwarod to 210 for urea peepha

Rus- or Upse to LoAmIl34I a AriMed bI Earl U

MW NOWlsIIsIr-4 L Toman 5 1 Alln and eesese StNf rio

row on Sawg did (0 tpot) We 1l0l0 Ws feritiud vith 05is

of Npot mixod with the 6011 as aureCA NiAO) 1 Age god At Ures

was also itcluded at rtt t 05 10 end 15 of Upee Theas trealshy

onto were followed 4 wpdrsetago of U s AN wre 4C 10o or at I3n

Weeks toulin up to IS pot

A soil application of 10 pot rosulvod to the maim yield

at 4 weeks Tio4 sad percont prottis t intre raite tncreased rftishy

linearly with U applictalien IeseeItally all at the m iNd wit

the moil w domitrifted after flooding Grail end straw Ilelds vere

highly correlatod with tiliriag and vlh ubers of gralm arl

The results Widicat that 0$ to 10 a of Upot as orea or

NN bsuld be sied with the oil to stilate tiilrir with adshy

ditional 0 topireased later to increase grain lIds mad protia cmshy

tout

DIVISION 54- FERTILIZER TECHNOLOGY AND USE

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h Eaap 8n 14 sMsa of abw~greuad PU Pau WW 1 u itb IUKho 0aaphelem s 60 Otarlmmh At ~ 0sU Ishiseoo Cook oiA N uiplasu mAasslaly abess A leel

v doese a WKWye Is ks Nha m 6 sa4to dafo aONmuw The appee swm Wsssof adde N4 alalaed by vuMb ifaa W C Was sekilumganSro Is

bs eabI wish as aVWWa uwewy nap (f5s)f ad Mashes reaMeY valaes of 48 0 S414 CWm

owdb imto US Wh s vs sf 3I mld 54S fro 2 aMd 3) A A

valves a hevwae u Iar Walh basl oswas dhe uwpatr bshava of

tb~msusasl appkausu of ofta sede s have aoweN

TOW opl taoe for AieweeW 4OsmWMbas Op peas As Tabl 4 sling sob Os awowully eom grams Piel level Thes oeulam Ma sed as IM

-02

792 60L WI W A)49R Pio VOL 37 197)

primS o r OeampAd WU toa Them fl~ w At NOSSe earno maisslea Ia N he mOWamplIO yik ampWd IMe aampWmW OWa Owe wa UMs of KU to 41 Oke ampWiiIamm be dkrnety ewspokawleM(a s8 te camtd wie a eapmoe by TVA pavw ltoi NA poundrmdaka4us vrimeW460 o to ilkidm ofWW (Mtemas MuOwe 1973) TVA mwi bawld on soi ficedims IampWp seg rudwiv s~s0abet ke WNmdoe ON 01 K Is12 NOSW ie fssewnmu Ie I QvaaIi rowp IMA) f9

)amp m lodk byO voebmsaIS8OpeaWfrats 11 OWNmi a I a W idisod 0 81 Now 111 nindat Wm fysmpseaamp (If tsO tUmtI IsM $P shoroV4mmo knflkvnf (foOdme nuw ae Ow OImstwe in SM pnmm8 af tXm 10 114PIS kequoian wo Mpfii

SC~po umd spop~o VWt alm 4emWal 1 4ink PCmirsra M 1 ad AI 14bmms

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MGMe -M4 Wg kmuwadM 1Wr wih SCV4 Psmuck Wff It dlL Wm 1W led 0 1 oo teeA of aiwaisme aweeoid h

1Kach Vt V amp4W ILK t)sa 10 Nareps vm This ndY ub thee hbow apiptomuasa of gulfu-aw~sd of Cup lP~~tamsl wi(i

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e W d inSIWfh sil $ad doke IaefitV twoer) 1 Te to theo owie effu so booJ imik WOi 100 N

-d

Is re4aled uIwq~e~w Aueee atofurnw di Capsnm ptopeatls is a oommm eiws to 100 tom of 04404man d CtdUW 4M Anw K~a do Aamp apowee WPUaN powu eel H pae iaaa thAi SCUI isWW owr hmem ISsuppl N to the li ieee F A IM1 Nampa Obo~amie m

41MB ~ ~ m ~ ~0 0-- 0 140 The ffsemn of food Nn else9~e(Ud~ ~ ~ ~~ WooksaS eAWw pjed of ho~raw of IU effadam vfdva oft xhj0I 13iAl

DIVISION 8-9-SOIL MINERALOGY

Amorphomw CeetIup en XmWra Ssrfmls

L C koits Am~ 0 tmmkaAf

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~ -0

65

0IL CL OC AMXR PROC VOL 38 1974

)aT1 S4I104 ow Lusanll Tawng isa tall Thai variety known for beingIwo nonshyi s s ) sensitive to photoperiod A split-plot design was used in

S e e these euperimeots with 4 rates of P (I1 22 44 and 88t i V IV k of Pha) applied a main plot treatments and with the OF It sourMes of P as subplot treatments There were two checkS plots in each rmplicate The extra check plot was included to permit the application of fresh TSP standard Jor the

It- ti 06 + i bull fa succeeding crop the p-4me of bi was to permit accurate d awrnwal of the mdual effectiveness of the phosphate

ftinSUbI rock The P fertilioers were broadcast on the mud andthen Worporald In the soil during the last harrowing At

whM N both On ACS indx ampM time of transplanting Immediately before the last harrow61t (4j 5 4 01 P s 3Mm o Vallonal in con n 100 kgha of N as ammonium sulfate and 33 kghaWO Of Spews ampm lIW thaabe rocks do ACS indes of K as polium chloride were applied A total of 40 wa in prepw O do ctih k otent kha of N a ammoniunt sulfate was applied later in twoir P The hew oNed amp wM W for 5 of gw topdrossingp with about 5cm depth of water on the plotsvV I aiOMveffeOctveee Three to six ldayold selings pr hillwW the ACS idex were planted00OWW wia Oft fo an c irNk I p Coen 20 by 20 cm part in straight rows Hand weeding was used

and insecticide were applied for Insect control Grain yieldw was masared by sampling 5 ml of each plot excluding border rows The date of heading in each treatment and theUNiN d pbM W Weks rin tOW USA UMe In Tale yed componnts at hafvel were also recorded

I filM rsperMS esOM kdwdua 1 t ab The average yields of ough (unhulled) rice for botha 84 OW O 8uo 4 Thala TM was a locations are ploutel in PIS 3 for the first crop (1969 wet

owou thRM seaso0) The Veamps yield response was obtained at Klonge (s) W lDtO t Of dMa of1tw W d l R Luang however a 4ute satisfactory yield response was

~Mk ^d TVA UJSD ad Kd UnIveS obtalned to applied P at Bangkhen as wellXUe LaM e R qwrw Ims The sod was do Relative aponomlAe effectiveness values were calculated

VOW (a ksA w edmwL t Poesesm h Vy for these data and am presented In Table 3 The valuesdAY buo if dIe ouh ne Pee wtk a Mlak vow 1009 for th first crop are plotled against ACS index in Fig 41 This Im M i6ti l 4bNd IO a0 O mkarnk for both locatio r relationship was linear for the

11400 ThCpH 0( lb pW IW 01 th UpeiaW so Sanodion location and curtiltnear for KIng Luang The was u i 4A sksamp lMaor nrusio model amparounted for 81 of theAmO$MI Aw jAAsue Swim T1 Snh Wd variation In the AE valu for Bantkhen a square root

Mems a Iw iv fern alh$ sedm haowg dayNW W t he plAL At tdo M tM aso W s as ctminued throufh eltaM t Ofpof -le lse wo am P OeNI VeOpls 1o ealluae tI lon4erm MIdual Offccls

A on W isset i a wse to hsh eapeel of these ooihss t ocks The baagkhon experimnent was letmiaI1DlVemisthis is a w hulu Lo g Tasug ia iasael aft - Msd residual Ves will be pr-Om crok TheseTwod esewm

SWWo

A

lP~U~7 ISIIPe1iuIWN e bsedisssin ian ghth siaoelalbe

984 0 6 O O - M s -s fWPas 11eSft W d Uo al a o

o

S4l~ lIIII I~l I 1f fl

( +

+ + + m + ++++-

++ +(++ + ++++ + ++ ++

- 66 -

ENOIMLSTAD ET AL RESPONSE BY FLOODED RICE TO PHOSPHATE ROCKS VARYING IN CITRATE SOLUBILITY

I I I I j0 I I

BANOKHEN BANGKHEN

pH 56 6 - 0o

TSP

NC

5~ ~ ~ L o 4 - -shy

4 ] - --------shy04

6S

|0 III 2 44 8r 66

I I I

a 1KLONG LUANG

pH 46 z KLONG LUANG

TSP Sc2 NCFL(N)

5 FLIC) J0 TU

oshy

4 ~40shy

3 bull eM0

I - I I I I I

0 II 22 44 88 0 5 10 15 20 IP APPLIED KO HA ABSOLUTE CITRAE SOLUBIITY INDEX

Fig 3-Yield of rough rice at Klong Luang and Bangkhen Rice Fig 4-Relative agronon effectiveness () of P sources ploz-Experiment Stations Thalmand as affected by rate and Source ted against citrate solubity Index for both Thailand field ex

of P applied (crop 1) periment (first crop only)

regression model accounted for 97 of the variation in sumably resulted from crop uptake and reaction with the RAE values at the Klong Luang location soil to form less soluble products Such effects may have

These experiments were continued during the dry season been more important at the lower rates since the two TSP of early 1970 to ascertain the residual effectiveness of the curyes converged at the highest rate of application various sources applied to the first crop No new P was These data from KIong Luang indicate that (i) residual applied except for the fresh TSP standard mentioned effects of all rocks except Mlcwuri were substantial (ii) above rhe experiment otherwise was conducted in a man the relationship between relative agronornic effectiveness ner similar to that followed in the first crop of the phosphate rocks and citrate solubility levels was

The response to both freshly applied ad residual P was largely obscured and (iii) the general superiority of TSP marked at the Klong Luang location and marginal at over phosphate rock in terms of effectiveiss persisted Bangkhen In fact at the latter location the response was through the second crop so small that little can be said regarding residual effectiveshyness The yield data from crop 2 at the Klong Luang DISCUSSION experiment are plotted in Fig 5 Greenhouse and field data presented in this paper show

Relative agronomic effectiveness values (Table 3) were clearly that there are substantial differences among phosshycalculated for the Klong Luang data using both the residual and freshly applied TSP as standards It is of Interest to note that the superiority of TSP over the phosphbte rocks Table 3-Relative agronomic effective values for field experishyments in Thailand persisted through the second crop The main difference in KlowlZmlnql~the residual effects is that with the exception of the MIs- s Crop 1 Crop 21 Crop 1-shysouri rock Ihe marked relationship between citratr-soluble WoiCarolina yl 59 76

phosphate rocks and RAE had largely rds norh) a 64P conltct of th Florida (eqlral is 6969 6

disapipeared In this acidic soil (pHi 46) P would by this I14o 69 63 40 ToonesS 31 65

limo be supplied by Intermediate reaction products In addl Missou 0 o lion to residues of the initial spatlte Ts P o 2 o 0

The TSP applied to the first crop declliv-d slightly In campIafcmWataesr e id ofeuhuloefor 22MA rates of PtColeouattd as aba u tlte td18 kS ratesp dlverage yield tM868 to 22 44

effectiveness relative to the freshly applied ISP This pre- of d s4

A

4

- 67 shy

-SOIL SCL SOC AMER I

KLONG LUANG CROP 2

Si 3

eN

TAPPLIEDKGHA

Fig 5-The residual effectiveness ovarious P sources for crop s compared with freshly applied TSP Klong Luang Rice

Experiment Station Thailand

phate rocks in terms of agronomic effectiveness for flooded

rice Further these differences can be predicted by means of citrate solubility or by the ACS index It appears that

the latter is more appropriate where the content of apatite varies among phospiate rocks The most soluble phosphate rocks approached but did not actually equal TSP in limit-iuig (maximum) yield in these experiments regardless of rate applied This agrees with the results of Ensminger Pearson and Armiger (4) One needs to consider the defi-nite posribility of same yield loss in zhoosing a phosphate

rock over TSP such yield losses must be weighed against the lower price of phosphate rock The explanation for such iosses may involve concentration of soluble P in the soil Khasawneh and Copeland (6) suggest that the growth rate of crop plants is a function of P concentration that can be maintained in the soil solution If P concentration is limiting or inadequate becawe of a lower dissolution rate of phosphate rock the growth iate ard uiiimate yield will be diminished accordingly

The RAE values bascd on yield increases reflect the agronomi effectiveness of these various sources relacve

to the TSP standard however these nould be supple-

mented by an economic analysis before rational choice can

be made The following calculations will provide an estimate of

the rclativ ecooomic effectiveness(REE)

Y t Ps aXpatREE -- 100

vahtercks t sphate or e b i- eor

Price of TSPkg fo

be Price of PRkg P

PROC VOL 38 1974 leO

90r

Wsoshy

0

60-LUSEPHOSPHATE ROCK

00 10 20

PTP PR

Fig 6-Relationship between relaZive effectiveness values (RAE) and the price ratios between TSP and phosphate rock Such a figure can be used in making a choice between these

sources

If REE exceeds 100 in this calculation the phosphate rock would be preferable to TSP

The REE calcuktaaa wre used in preparing an indifshyference curve (Fig 6) wherein RAE values are plotted

against PTsPPpR ratios The cu~rve itself connects those points at which REE equals 100 When exactly on the curve it makes no real economic difference what source is chosen After choosing a suitable price ratio one can then project upward from that ratio knowing the RAI

value (or estimating it from such data as shown in Fig 4 using citrate-soluble P content) one can then choose the source on the basis of both agronomic and economic conshysiderations For example if the price ratio is 25 and the RAE value of the phosphaite rock is greater than 40 the rock phosphate in question would be used However if the RAE value was less than 40 TSP would be a better choice There are indications that if the P in the more soluble phosphate ro~cks (North Carolina north Florida central Forida) is less than half as expensivz as that in TSP these rocks would be feasible altereaives to TSP on soils similar

to thoseused in Thailand This analysis does not take into account the possibility

of lower yields from use of phosphate rock In addition only a portion of the various yield response curves was used in this anlysis ie up to 22 kgha Beyond this

rate yield response was much less pronounced it could be argued that at less than maximum yields TSP would produce a certain yield at lower rates of P than would phosshy

pow ofrock This would especially be true for rates applioa example at Klong Luang 5500 kg of

rice pcr iectare could have been produced with either Ii kg of P as TSP or 44 kg of P as son of the more reacshy

tire phosphate rocks It should be pointed ot however

- 68 shy

(IIKIS amp YOUN( ARIFICIAL WEATIIERING OF OXIDIZED p[ll- IV

that this is the yield level that would show the widest difference such is the advantage of hindsight

Farmers generally prefer granular fertilizers for machine

or hand application This is a disadvantage for the phos-phate rocks which are normally arplied in finely divided form Recently experimental quantities of granular urea-

phosphate rock mixtures have been made by TVA Results of trials with these fertilizers will be reported elsewhere

LITERATURE CITED

1 Armiger W H and Maurice- Fried 1957 The plantavailability of various sources of phosphate rock Soil Sci Soc Amer Proc 21183-188

2 Bengston G W E C Sample and S E Allen 1974 Re-sponso of slash pine seedlings to P sGurces of varying ci-trato solubility Plant Soil (In press)

3 Caro JIt and W Hill 1956 Chard eristics and fer tilizcr value of phosphate rock from different fields J Agr Food Chem 4684-687

4 Ensminger I E R W Peirson and W II Atmiger1967 Effectivencs of rock phosphate as a source of phosshyphurus for plants US Dep Agr ARS Bull 4112S

5 Engelstad 0 P J G Getsinger anid I J Stangel 1972 Tailoring of fertiliers for rice cnnece Valley Author ftyNational Fertilicr Developmnent Center Hull Y-52

6 Khasawnch F E and Jane P Copcland 1971 (otton root growth and uptake of nutrievos relation oif phosph

rus uptake to quantity intensity and buffering capacit) Soil Sci Soc Amer Proc 37250-254

7 Lehr JR and G H McClellan 1972 A revised lIbora tory reactivity scale for evaljativg phosphate rocks for direct application Tennessee Valley Authcrity National Fertilizer Development Center lull Y-43

H Terman G L S EAllen and 0 P Engelstad 1970 Response by paddy cice to ratcs and suurces of appliedphosphorus Agron J63390-394

DIVISION S-9-SOIL MINERALOGY

Artificial Weathering of Oxidized Biotite IV The Inhibitory Effect of Potassium on Dissolution llate

R JGILKES AND R C YOUNG2

ABSTRACT

Rates of dissolution of oxidized biotites in OIM 001M ICI are severely depressed in the presence of IM KCI The amovnts of Al Mg Mn dissolved in the first eytraction are similir to those found without KCI however subsequent extractions remove these elements at 10-20 of the corresponding lICI rates This effect may be due to a decreased rate of vermiculite formation thereby reducing the effective basal area exposed to attack A decrease in dissolution rate with increasing ferric iron content was still apparent in the presence of IM KCI

Additional Index Words X-ray diffraction infrared aborp-

N EARLIER papers of this series the tole of biotite in soils

as a source of both macro and micronutrient elements

has been discussed ((Gilkes Young and Quirk 1972 1973ab) Experiments in artificial weathering uiing as va-

riety of extractants were undertaken to determiie the inlu-

ence of oxidation of octahedrally coordinated iron on the bull release of structural cations to solution The results of this

work demonstated that biotite behaves anomalously with respect to the other common ferromagnesian minerals found in soils Oxidation leads to the development of a high degree of resistance to cation exchange and dissolution Several authors have coiwludcd that decreased rates of K

Contribution from the Dep of Soi Science and Plant Nutri-tion Institute of Agriculture Univ of Western Australia Ned-lands 6009 Western Australia Received 29 Sept 1973 Ap-proved 8 Jan 1974

2 Senior Lecturer in Soil Science and Research Officer respeclively

replacement in electrolytes shown by oxidized biotites are

a result of the inclination of structural hydroxyl adjacent to newly created trivalent iron or vacant octahedral cation sites (Robert and Pedro 1959 Barshad and Kishk 1968) Gilkes et al (1973b) suggested that decreased rates of disshysolution of oxidized biotite in 0001 0t)l 0Af CI may also be due to the presence of inclined hydroxyl In this case a smaller surface area external and exposed intershylayer may be available for attack if K replacement by hyshydrogen ions occurs at a slower rate in oxidized biotites

Gastuche (1963) has shown that significant dissolution ofthe (IIM) biotile face may occur and it is easily demonshystrated that the proportion of exposed (001M) face in weathering biotites depends on the percentage K replaced

Rausell-Colom ct al (1965) have shown that hydrogen ions act in an identical fashion to metal cations in K exshy

change from micas In particular exchange c-f K by hydroshy

gen ions will be terminated or greatly reduced by high levels of K in solution Thus if dissolution of oxidized biotite by

acids is carried out at sufficiently high K levels to prevent vermiculization any differences in dissolution rate that may occur cannot simply be ascribed to differences in rates of K replacement The following results were obtained from such an experiment which unlike the experiment described in Parts I and II (Gilkes et al 1973ab) does not attempt to simulate natuiral - conditions

MATERIAILS AN) M HIiODS Further subsamples of the less than 0 hiotites used in K

excherandbaid disoo tu es (G iles e9n K exchange and acid dissolution studies (Gilkes et al1973ab) were used in these experiments Preparation of sequentiallyoxidized biotites without intermediate vermiculite formation is

Page 28: I70 - United States Agency for International Developmentto ascertan, but tgl.eetad, 1, L,. ("Tailoring of Pertiltiters for ice,'" TVA ulletin Y-52) states that the staft of IOi has

- 25 -

Table 3

Effect of N Source and Time of Application on Yield of Paddy (Flooded) Rice in India 1972 (Summary of Reported Data from 4 Experiments)

Experimental Number Source Rate Method Yield Relative N-Response

and of of N of Yield Kg Grain

Season Nitrogen kgha Application mtha Kg N

- - - 196 34 -

Urea 120 Basal 573 100 314

11 Urea 120 80 + 40 611 107 345 Rabi SCU 120 Basal 713 124 430

12 - 0 - 202 30 -

Urea 125 Basal 682 100 384

Rabi Urea 125 35 + 20 + 35 + 35 633 95 344 SCU 125 Basal 781 115 463

13- 0 - 168 44

Urea 100 Basal 385 100 217

Kharif Urea 100 30 + 20 + 25 + 25 400 104 232 SCU 100 Basal 462 120 293

14 -

Urea -

125 -

Basal 355 650

55 100

-

236

Rabi SCU 125 Basal 781 120 341

-- 26 -

Table 4

Effect of N Source and Time of Application on Yield of Light Irrigated Rice in India 1972 (Summary of Reported Data From

One Experiment at Pattambi)

Experimental Number Source Rate Method Yield Relative N-Response

and of of N of Yield Kg Grain Season Nitrogen (kgha) Application (mtha) Q) Kg N

38 0 - 204 85 -Rabi Urea 120 Basal 241 100 308

Urea 120 60 + 0 + 30 + 30 267 ill 525 SCU 120 Basal 255 106 425

Table 5

Effect of N Source and Time of Application on Yields of Short-Duration Transplanted lice Variety Grown on Irrigated Light-Textured Soils at 5 Locations in India 1972

(Snmzarized From Reported Data)

Rate Grain Yields (MtHa) Source of N Method of N GrainI of N kgh Application Faizabod Karjat Mandva Pattabi laya Averaje X

- 291 266 211 19 340 260 -

Urea 100 Basal 386 407 361 285 482 3 124 Urea 100 50 + 25 + 25 399 430 434 334 6amp2 4A8 186

SCU 100 Basal 368 468 439 360 572 41 181

Table 6

Effect of I Source end Tlae of ApplIcattoo c RIstave Tle24 of a rt- rat1 T Lsd lice Vasrety Crin o Irrigated L41tshy1 at S Locitite mindi 1972

Rate ____________14_3

Source of X N~tbad of Of X An 1 tat14 1 acr X__T1 4v tatW ttva

- - - all 7i i

95l 119 1 1~ ~~~~~ an iI3lli i1

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rewIott- MN1 tVfI OOwK o l

Stt19 Of 0 SeOO M IbAWO AffikampI 00 Vt414 Ot VPtd 44 tM~wuOWe tni144 Ite W 1iw)ts 060

211 U e 1dit f

w 0 31 ~ 19 AA 116 1 AS Ma )4 ) At

wx451146

ISO 00) OM4 0101 9I

T60te

owel4440 00VII O A ofWM PwmeeA st rof (Amrol IMVf

Mt ot U 6q-wto~ COW i 4t~ eso

Tel of ate (01m itl it Iiuma tWuJt)

21L1L LW ufU~ vie 114 3 10 106

As 11 i 41 4 smg LAY1 $Of 41)

Tabl I

f~ttwi Ot 0 6wirce 81d At$ a vt1d at flUop4d Rico to Vitjorim (1ITA)All fortitfour to rsodkeet OA lC~OVPr4( 114 5iI 000

W Iotors Ftslanp tospg Irritd for Two thvk Afler flontiw wft rkwa~ Floo4d 191)

- -I-of LWAIM) (IS YJl- fl-----II)

-0 10)

AA MO 4 S4

4of O 149 6MID O 41110

KthD 00

- 38 -

Table 18

Yild of aemati-370 Rice at Punjab Agricultural Research

Institute in Pakistan in 1969-70 Grown Under

Couditions of Intermittent Flooding

Pate of application

=IL

o 0 67 67 100 100 67 67

100 100 67 67 200 100

Average for Sources

Ntha

AS 260 gres 279

320

Source f5

-

AS AS Ura Urea SCU SCU

Yield

Relative

93 100 115

(M)O

Yield

Increase Yield Due to N

(Ktlha) (mtha)

-212 245 033 274 062 260 048 297 085 315 103 325 112

Yield Increase

Relative

72048 067 100 108 161

(2)

- 39 shy

Short-statured high yielding rice varieties grown extenshy

sively in northern Peru require extremely high rates of conventional

N sources to achieve maximum yields The recovery of applied N is

extremely low due to the use of intermittent flooding This water

management system results in heavy N losses even with properly timed

split applications In search of simpler and more effective methods

of N management eight field experiments were conducted in the region

to evaluate sulfur-coated urea (SCU) an experimental slow-release N

source supplied by the Tennessee Valley Authority Rice yields were

increased an average of 59 more by pretransplant-incorporated SCU than

by urea or ammonium sulfate applied in the same manner SCU produced

excessive vegetative growth which resulted in yield reductions at high

N rates

Regardless of an assumed 48-higher unit N cost in SCU the

overall benefits of pretransplant-incorporated applications of SCU

were favorable since there was a decrease of 40 in the optimum rate

of N and the need for precise timing of application was eliminated

Pakistan--In Pakistan basal applications of AS urea and

SCU to rice grown under conditions of intermittent flooding in 1969-70

(table 18) indicate that SCU is a superior source of N as compared to

urea or AS when all N is applied at or before planting The data also

indicate that a yield response was obtained for P applications but a

comparison of N sources at each level of P indicates that no interaction

between N and P was present so that differences between N sources were

relatively the same at each level of P Yields were increased about 60

more when SCU was applied than when urea was applied Yield increases

with AS were only about 72 of the increase obtained with urea these reshy

sults do not agree with the generally-reported superiority of AS as comshy

pared to urea as a source of N for rice

- 40 -

In 1973 experiments were conducted in Pakistan using both

Basmati-370 and IRRI-6 varieties of rice grown under conditions of

When all N was applied at puddlingintermittent flooding (table 19)

or 12 at puddling and 12 at panicle initiation both AS and SCU were

superior to urea with SCU tending to be the most efficient source

However when N was applied 12 at transplanting and 12 at panicle

initiation SCU was the poorest source of N This would indicate that

the release of N from SCU applied at these times is too slow for optimwn

plant growth

In another experiment in Pakistan in 1973 no differences

in the effectiveness of urea AS or SCU were noted in the yields of

continuously-flooded rice (table 20) Again these results are conshy

sistent with earlier results which indicate no superiority for SCU

when rice is continuously flooded

Nitrogen Studies--Maize

A series of three experiments were conducted by IITA in

armo-Nigeria in 1972-73 comparing AS urea SCU and

CAN (calcium

nium nitrate) as sources of N for maize (table 21) A significant

yield response was obtained for N at each location but no conaistent

differences were noted amaong sources These results are consistent

with results at other locations which have not shown that SCU is a

superior source of N for maize grown over a period of 3 to 4 months

Nitrogen--Wheat

The yields of wheat in Pakistan in 1969-70 (tables 22 and

23) show that yields with SCU) tended to be lower than those with ureaJ

although at one locction where sorghum was grown followilng wheat with

Table 19

Yields of Basmati-370 and IRRI-6 Rice at Punjab Agricultural Experiment Station in Pakistan in 1973 Under

Conditions of Intermittent Flooding

Rate Yield Source of N Time of Yield (Mtha) Increase of N B-370 IRRI-6 Application Basmati-370 IRRI-6 Average (Mtha)

0 0 - 21 353 287 -

SCU 90 150 At Puddling 325 545 435 148

Urea 90 150 At Puddling 309 500 405 118

AS 90 150 At Puddling 324 529 427 140

SCU 90 150 Puddling 372 572 472 185 Panicle Initiation

Urea 90 150 Puddling 335 502 419 132 Panicle Initiation

AS 90 150 Puddling 353 529 441 154 Panicle Initiation

SCU 90 150 After Transplanting 312 562 437 150 Panicle Initiation

Urea 90 150 After Transplanting 340 624 482 195 Panicle Initiation

AS 90 150 After Transplanting 349 583 466 179 Panicle Initiation

All plots received 45 lbs P205acre as single superphosphate

Relative Yield Increase ()

Source of N At Puddling Puddling Panicle Transplant h Panicle

Urea 100 100 100 AS 119 117 92 SCU 125 140 77

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-48

Therean laiictw that It lbs P to th e am lukis

obosomhu rocks 0entk catetas rth Unrtdo costrat frwt) to

ht tse balt s Owosiv as that to TwP it rocks WM bo

fmtbt alteruutiv to MSso gotastte to~ Ik lee used to

ThUAIAd

Tht wMl dt gotmtmlaoti wout th possibility

of law Vhld free ww e1 e66001 4 It cooUt be YgWd Sutt

a4 10 0410 SWUSSM yt$4e TOP wUd predWr A r~ftIf fl~W t

1f f ot P the wuld phosphae rck TWOe viWMW efocitill b

true to low rttos t tsplusatiI P wi 9 Ma Liiam $S

amp4at r per Wforssota Mav two 64eed Wilk elikor It 44 of

P go Mi er 4A bg oftoP aon of tewmrowtni pboophals fwAh

It vwld be polotrd A Wevero wtht Is the jteld level that

W414 gk tko videm dtterem~j o(A 1 the 4~etamp tk~e~t

P11~0 pra~lpj prefer gre4r tuftlter for whlae

of hoaw ppltrstie Mhe to a dloedveaP for The PINSOO rocka

vkth m r II spotted 10 ftewil 4106Me tem

Nub studios we ovsosd o IVA vol gramleid a

forgof wee aMW pbsepbots A fths pemhawe evsielew us

Odellod to detMlee it otteettvmm of 11agotated Stoture of

mmfp MW phapa A (CI) sed graewletod pampAtlti arlolatod Pa

asowcs of P tof ttde ro The wreem proucts omre raGther

pemour~a ot P syag besmti andMi as elt ov so gpamwhr

iuipiqffhate(TS) low twseeo Is eftwiltve Is thet

W41 preeme wae oialain ire post-rItoi effriq to Stanlato the

pud6itt of Irto paddle Wee ofsdlseireplastiq

0 49 shy

lbs partially scldiaatede grawilated Ml prodlucts Vere isshy

toiwdiats in 5tftOvttWS54 betwee wroiPi ad TVP NotV5Ymf to

me coo were they mere twoe $a a etfective ao TIP 00 sipifleast

LVSUMI5 at0 efecto wore toun tor thee produteo Timely dtIampWde

FR (-t00 mmoh) Uia amp~rally oar affective than Owe gra8448r FOampprodt

featal twos o 6 aotetire s I

Nowvero it to felt that sfortber field euprtet vth

hese interials Amd ether typs of grometatodl Wter nre wrrautad

hater ceeuwodh that they have me areec poteatlal toi additoG

e tate wAne the sectte as OtawrI sed bovoloen turther

euperimeste vth few reck pboophar s0d with reck pbophat treated

to sehesa citrata selmtliy or to ha csaducted

Metbir sertes of tbme enprtaeats wae c~edtmcted by IITA

to Ut~rta copal TVP AOP APP aed it at see tecastisix (table 14)

No dot lalt sewseltles teh draw tree thee results simouely em pear to tlvdl bsww they do stwgpt tbat forthew work with

MR to werramid so tbme sels

Table 24

LttcttF Swce MaPlate 06 ieldot IM AWaia CoelsANS at IITA (Ugboda ad Apoin ail sorit) aid at Ike (AUaba s5i series)

1973

Plate ot IP Apinu 5 poundebods A1ab

Ocrol 0 Z94 419 M)

Tr ipl ruprphite 20 349 3799378

Triple vepput 40 M09 410$

Triple 6wp~~b1 4271 4344 42250

Ammotw-ritpophW to 4201 4124 4040

Amosim-rdop~phlt 40 4270 4106 4231

AM tuo-polpephats 20 404 4244 3794

~eai~mpelppepbuI 400)49 4094

Cee m-pbpbt to- 59

momee eph lto 0 4192

LSO (0 0$) 29 1025

Th WPII

- 51 shy

101Y114 tpeM-fI PEP~tbRP YO

1 ~ ~ gmw 1pc~biofl- 9 Kla4v4h

Upia U04 Copfind am Crehout Stet Rpano at (Ia4

rico t IF t rume6 orth~ Caralto phoophale rocl QAR) vaUN pqU41 to

roopon from cmonetrat4 gsporphophai (CIP) who ort$o4 oil k

was 45j itwas tafertor vb protioo4 oil p war OS Ib 4iffer~c

in rtc reepos to X cod14 oo bo ttrit4 4 4 hvsciag of boil p

~ Pt o r11221 0 tP

c theto the rhimecyllndor of rico tots par to)14M4i1 roeoi~t

ed oil emd PA prior to tho ont of an~robi4 cMioe AA~ oIifoshy

nAte bYpot t taet~d tO fC4sin t~r 4PWden0 Of f Ot(tivshy

ofOWailiJtyno o prefla4 all Put that 4t01etoo 14 tvsIk

of the Ott to prvvld a 014for C4m0 44 mI 1 o4sf

EfftC ftPet141on AIAM-0 V f401td 4 4iv 440 Mtft

Aa torfat VampP f4MWfCi4W04wt0amp to 4eturWlI Ot(Wel~drIC ft

Ot f tM6 the flooded Ott 00 14 04019I Pft0uAw Of gAr~s~lr

pkS$t M40b MP) Tw P1101 Piset Prodwie W-e 10M0di Wr04

(10-1) emW 0aretilp ddw01at4 P WAA firom Rrth M~flRU414~$

wee cowiared with fie Md reWim 44104 proo~fo) foruk oith laWItter

I v te-PR P OW1004 4 4 O Wf ottil OW ellt Oo

Oveiel1 the 40tt dmcruie to effetotww Wtollowui Co fme

PR tpaUIB1I ldoltmo PR (pamwlatr) offr~- ArmeuM) 0 orwi

- 52 -

Effect of N Sourc6 and Water Management on Response of Rice

toe Zn- M Giordano J J Mortvedt OP Engelstad and Greenhouse

Staff Several rotes of CO(14H2)2 and (H )2So4 vith or without ZnO

wore applied to flooded and nonflooded Crowley oil (limed to pH 75)

to determine response of Bluebelle rice to Zn Yields with both N

sources veotrgreator on flooded then on nonflooded soil In the abshy

ence of applied Zn total dry matter production vith CO(NH2)2 was

slightly lower than with (NH)2S04 on flooded soil and considerably

lover on nonflooded soil Concentration of Zn wan higher in straw and

grain of plants roun on flooded than on nonflooded soil Although

concentration of P was unaffected by N source or Zn rate there was

som indication that cranslocation of P from straw to grain may be

depressed in nouflooded rice Concentration of N was lower in straw

grown on flooded than on nonflooded soil due to apparent dilution

thereas both X sources resulted in similar N concentrations in straw

at all rates of N application the N concentration in grain increased

with 0 rAse

feSpongi gf(SM to Chjorospodiostte and Related P Sources--

Si Allen and Greonhoue Staff A greenhouse pot experiment was

couct44d with corn Brown on Hountview silt loam to compare the ofshy

fectlivees of chlorospodiosito (Chlor-l) with concentrated supershy

phosphate (CP) Thomas slag and North Carolina phosphate rock (NC-PR)

Oil-prillad urea-phophato rock (UPI) FeA1JMP 20 7 and monomthyl

phosphate were included in the experiment Based on yield of forage and

uptake of P by tvo crops each of 6-weeks duration the following conshy

stui were dravat

I Chlor-1 was slightly loss effective than CSI Thomas slaS or NC-PR

from which Chlor-l wae prepared

- 53 shy

2 Granular UPR was a poor source of P its effectiveness was greatly

increased by reducing the particle size to -35mesh

3 FeAlNH4P207 was unavailable to the crop

4 Monomethyl phosphate was equivalent toor slightly more effective-

than CSP

Research Indirectly Related to TVA-AID Project

Response of Several Rice Varieties to Zn in Moist or Flooded

Soil--P M Giordano J J Mortvedt and Greenhouse Several varieties

of rice from Mexico and the Dominican Republic currently under investishy

gation in Puerto Rico for adaptation to upland culture were compared with

some established United States varieties with regard to Zn response on

moist and flooded Crowley sil (pH 75) Chontalpa (Mexico) Bluebelle

(Texas) and Starbonnet (Arkansas) were most responsive to applied Zn

Juma (Dominican Republic) intermediate and Sinaloa (Mexico) and Calrose

(California) were the least responsive The Sinaloa varieties (Mexico)

appeared to be best adapted to non-flooded conditions whereas Chontalpa

and Calrose were poorest Concentrations of Zn generally were higher in

plants grown on flooded than moist soil

Pattern of Growth and Zinc Accumulation by Rice--P M Giordano

J J Mortvedt and Greenhouse Staff Rice plants were harvested at weekly

intervals from shortly after emergence through maturity The objective

was to determine the rate of growth and Zn uptake by a Zn responsive varshy

iety (Bluebelle) and a less Zn-responsive variety (Calrose) in the presence

or absence of Zn applied to Crowley sil (pHl 75) Dry matter production

of Calrose was linear with time of growth and of a similar magnitude until

heading with or without applied Zn Bluebelle followed a similar pattern

where Zn was applied However in the absence of applied Zn foliage yield

was reduced markedly

-54

Uptake of Zn was similar for both varieties whenZn was

applied Dry matter production and Zn uptake by the two varieties

also were comparable when Zn was applied However yield of Calrose

was much higher than that of Bluebelle in the absence of applied Zn

while Zn uptake was only slightly higher This suggests that the lesshy

ser responsiveness of Calrose to Zn may be due to more efficient utilishy

zation of Zn There was no indication of a greater demand for Zn durshy

ing reproduction in either variety as was suggested in earlier greenshy

house experiments

Response of Upland Rice to P and Zn--P M Giordano J J

Mortvedt and Greenhouse Staff Several rates of P and Zn were applied

to Crowley sil (limed to pH 75) in factorial combination to determine

whether differences in rice growth under flooded and nonflooded soil

conditions are related to plant nutrition Although straw yields were

slightly higher in nonflooded rice receiving adequate P and Zn grain

yields were higher in the flooded crop increased rates of F andor Zn

did not result in equal yields Except in the highest Zn rate (75 mg)

concentrations of Zn in both straw and grain were higher with flooding

Concentration of P increased with rate of applied P and was higher in

the grain or flooded than upland rice at a comparable P rate In conshy

trast concentrations of N were lower with flooding due in part to dilshy

ution from increased growth

Rice Response to N and P in Flooded and Unflooded Cultures--

G L Terman S E Allen and Greenhouse-Analytical Staff Rates of

N from 250 to 2000 ntpot and P from 0 to 1000 mtpot were applied for

Nato rice grown on Mountview sil and Sango sicl (625 kg of soil per

pot) Market yield response to N and P was obtained Yields of straw

- 55 shy

total yields N uptake and N recovery were higher on unflooded than

on flooded soil cultures Grain yields however were slightly higher

with flooding These results indicate that with adequate applied

nutrients especially of N rice yields without flooding can approach

or even equal those under flooding

Uptake of N P Ca Mg and Zn increased with yield response

to N and P while K uptake decreased on the Mountview soil Concentrations

of N and P increased with applied N and P respectively while concentrations

of other nutrients were diluted in most situations with yield response to N

or P

Results from this experiment show that amouats of N applied in

previous pot experiments for rice have been much too low especially if the

crop was grown to maturity

Response of Corn to S and N i UUASand Urea-S--S E Allen

and Greenhouse Staff Three greenhouse pot experiments were conducted to

measure response to S and N in ulfur coated urea (SCU) urea amonium

sulfate (UAS) and urea -S as well as estimate N losses from surface apshy

plied N sources

In Experiment 260 less than 20 of the S mixed with the soil

was recovered from SCU or urea-S granules by two crops of corn as comshy

pared to 45 or 80 from flowers of S or Na2SO 4 CLop response followed

a similar pattern

In Experiment 260-A N sources were surface applied and alshy

lowed to dry for two weeks before incorporation Into the soil and plantshy

ing Recovery of N by two crops of corn was 77-82 for AN an compared

to 37-70 for urea UAS urea-S and ICU Thus n this experiment loss

of N from urea did not appear to be re~dcud by light S-coatlngn or by Inshy

corporating S or AS in the granules

-S -

I xbprZnSlt a Wtch aU Meyto 0-Ai Wt f9r

higher reermo teOrtOrs cOM reSpWNO i r0100 Of N w

not oaisteontly related to sewe ot N In edl tust 0 ioltiUe Lim

lo in VMuwpped evlmtUTS 48 merind by seirest nte appresOehe

501 for uroa as cwarod to 210 for urea peepha

Rus- or Upse to LoAmIl34I a AriMed bI Earl U

MW NOWlsIIsIr-4 L Toman 5 1 Alln and eesese StNf rio

row on Sawg did (0 tpot) We 1l0l0 Ws feritiud vith 05is

of Npot mixod with the 6011 as aureCA NiAO) 1 Age god At Ures

was also itcluded at rtt t 05 10 end 15 of Upee Theas trealshy

onto were followed 4 wpdrsetago of U s AN wre 4C 10o or at I3n

Weeks toulin up to IS pot

A soil application of 10 pot rosulvod to the maim yield

at 4 weeks Tio4 sad percont prottis t intre raite tncreased rftishy

linearly with U applictalien IeseeItally all at the m iNd wit

the moil w domitrifted after flooding Grail end straw Ilelds vere

highly correlatod with tiliriag and vlh ubers of gralm arl

The results Widicat that 0$ to 10 a of Upot as orea or

NN bsuld be sied with the oil to stilate tiilrir with adshy

ditional 0 topireased later to increase grain lIds mad protia cmshy

tout

DIVISION 54- FERTILIZER TECHNOLOGY AND USE

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-02

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DIVISION 8-9-SOIL MINERALOGY

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65

0IL CL OC AMXR PROC VOL 38 1974

)aT1 S4I104 ow Lusanll Tawng isa tall Thai variety known for beingIwo nonshyi s s ) sensitive to photoperiod A split-plot design was used in

S e e these euperimeots with 4 rates of P (I1 22 44 and 88t i V IV k of Pha) applied a main plot treatments and with the OF It sourMes of P as subplot treatments There were two checkS plots in each rmplicate The extra check plot was included to permit the application of fresh TSP standard Jor the

It- ti 06 + i bull fa succeeding crop the p-4me of bi was to permit accurate d awrnwal of the mdual effectiveness of the phosphate

ftinSUbI rock The P fertilioers were broadcast on the mud andthen Worporald In the soil during the last harrowing At

whM N both On ACS indx ampM time of transplanting Immediately before the last harrow61t (4j 5 4 01 P s 3Mm o Vallonal in con n 100 kgha of N as ammonium sulfate and 33 kghaWO Of Spews ampm lIW thaabe rocks do ACS indes of K as polium chloride were applied A total of 40 wa in prepw O do ctih k otent kha of N a ammoniunt sulfate was applied later in twoir P The hew oNed amp wM W for 5 of gw topdrossingp with about 5cm depth of water on the plotsvV I aiOMveffeOctveee Three to six ldayold selings pr hillwW the ACS idex were planted00OWW wia Oft fo an c irNk I p Coen 20 by 20 cm part in straight rows Hand weeding was used

and insecticide were applied for Insect control Grain yieldw was masared by sampling 5 ml of each plot excluding border rows The date of heading in each treatment and theUNiN d pbM W Weks rin tOW USA UMe In Tale yed componnts at hafvel were also recorded

I filM rsperMS esOM kdwdua 1 t ab The average yields of ough (unhulled) rice for botha 84 OW O 8uo 4 Thala TM was a locations are ploutel in PIS 3 for the first crop (1969 wet

owou thRM seaso0) The Veamps yield response was obtained at Klonge (s) W lDtO t Of dMa of1tw W d l R Luang however a 4ute satisfactory yield response was

~Mk ^d TVA UJSD ad Kd UnIveS obtalned to applied P at Bangkhen as wellXUe LaM e R qwrw Ims The sod was do Relative aponomlAe effectiveness values were calculated

VOW (a ksA w edmwL t Poesesm h Vy for these data and am presented In Table 3 The valuesdAY buo if dIe ouh ne Pee wtk a Mlak vow 1009 for th first crop are plotled against ACS index in Fig 41 This Im M i6ti l 4bNd IO a0 O mkarnk for both locatio r relationship was linear for the

11400 ThCpH 0( lb pW IW 01 th UpeiaW so Sanodion location and curtiltnear for KIng Luang The was u i 4A sksamp lMaor nrusio model amparounted for 81 of theAmO$MI Aw jAAsue Swim T1 Snh Wd variation In the AE valu for Bantkhen a square root

Mems a Iw iv fern alh$ sedm haowg dayNW W t he plAL At tdo M tM aso W s as ctminued throufh eltaM t Ofpof -le lse wo am P OeNI VeOpls 1o ealluae tI lon4erm MIdual Offccls

A on W isset i a wse to hsh eapeel of these ooihss t ocks The baagkhon experimnent was letmiaI1DlVemisthis is a w hulu Lo g Tasug ia iasael aft - Msd residual Ves will be pr-Om crok TheseTwod esewm

SWWo

A

lP~U~7 ISIIPe1iuIWN e bsedisssin ian ghth siaoelalbe

984 0 6 O O - M s -s fWPas 11eSft W d Uo al a o

o

S4l~ lIIII I~l I 1f fl

( +

+ + + m + ++++-

++ +(++ + ++++ + ++ ++

- 66 -

ENOIMLSTAD ET AL RESPONSE BY FLOODED RICE TO PHOSPHATE ROCKS VARYING IN CITRATE SOLUBILITY

I I I I j0 I I

BANOKHEN BANGKHEN

pH 56 6 - 0o

TSP

NC

5~ ~ ~ L o 4 - -shy

4 ] - --------shy04

6S

|0 III 2 44 8r 66

I I I

a 1KLONG LUANG

pH 46 z KLONG LUANG

TSP Sc2 NCFL(N)

5 FLIC) J0 TU

oshy

4 ~40shy

3 bull eM0

I - I I I I I

0 II 22 44 88 0 5 10 15 20 IP APPLIED KO HA ABSOLUTE CITRAE SOLUBIITY INDEX

Fig 3-Yield of rough rice at Klong Luang and Bangkhen Rice Fig 4-Relative agronon effectiveness () of P sources ploz-Experiment Stations Thalmand as affected by rate and Source ted against citrate solubity Index for both Thailand field ex

of P applied (crop 1) periment (first crop only)

regression model accounted for 97 of the variation in sumably resulted from crop uptake and reaction with the RAE values at the Klong Luang location soil to form less soluble products Such effects may have

These experiments were continued during the dry season been more important at the lower rates since the two TSP of early 1970 to ascertain the residual effectiveness of the curyes converged at the highest rate of application various sources applied to the first crop No new P was These data from KIong Luang indicate that (i) residual applied except for the fresh TSP standard mentioned effects of all rocks except Mlcwuri were substantial (ii) above rhe experiment otherwise was conducted in a man the relationship between relative agronornic effectiveness ner similar to that followed in the first crop of the phosphate rocks and citrate solubility levels was

The response to both freshly applied ad residual P was largely obscured and (iii) the general superiority of TSP marked at the Klong Luang location and marginal at over phosphate rock in terms of effectiveiss persisted Bangkhen In fact at the latter location the response was through the second crop so small that little can be said regarding residual effectiveshyness The yield data from crop 2 at the Klong Luang DISCUSSION experiment are plotted in Fig 5 Greenhouse and field data presented in this paper show

Relative agronomic effectiveness values (Table 3) were clearly that there are substantial differences among phosshycalculated for the Klong Luang data using both the residual and freshly applied TSP as standards It is of Interest to note that the superiority of TSP over the phosphbte rocks Table 3-Relative agronomic effective values for field experishyments in Thailand persisted through the second crop The main difference in KlowlZmlnql~the residual effects is that with the exception of the MIs- s Crop 1 Crop 21 Crop 1-shysouri rock Ihe marked relationship between citratr-soluble WoiCarolina yl 59 76

phosphate rocks and RAE had largely rds norh) a 64P conltct of th Florida (eqlral is 6969 6

disapipeared In this acidic soil (pHi 46) P would by this I14o 69 63 40 ToonesS 31 65

limo be supplied by Intermediate reaction products In addl Missou 0 o lion to residues of the initial spatlte Ts P o 2 o 0

The TSP applied to the first crop declliv-d slightly In campIafcmWataesr e id ofeuhuloefor 22MA rates of PtColeouattd as aba u tlte td18 kS ratesp dlverage yield tM868 to 22 44

effectiveness relative to the freshly applied ISP This pre- of d s4

A

4

- 67 shy

-SOIL SCL SOC AMER I

KLONG LUANG CROP 2

Si 3

eN

TAPPLIEDKGHA

Fig 5-The residual effectiveness ovarious P sources for crop s compared with freshly applied TSP Klong Luang Rice

Experiment Station Thailand

phate rocks in terms of agronomic effectiveness for flooded

rice Further these differences can be predicted by means of citrate solubility or by the ACS index It appears that

the latter is more appropriate where the content of apatite varies among phospiate rocks The most soluble phosphate rocks approached but did not actually equal TSP in limit-iuig (maximum) yield in these experiments regardless of rate applied This agrees with the results of Ensminger Pearson and Armiger (4) One needs to consider the defi-nite posribility of same yield loss in zhoosing a phosphate

rock over TSP such yield losses must be weighed against the lower price of phosphate rock The explanation for such iosses may involve concentration of soluble P in the soil Khasawneh and Copeland (6) suggest that the growth rate of crop plants is a function of P concentration that can be maintained in the soil solution If P concentration is limiting or inadequate becawe of a lower dissolution rate of phosphate rock the growth iate ard uiiimate yield will be diminished accordingly

The RAE values bascd on yield increases reflect the agronomi effectiveness of these various sources relacve

to the TSP standard however these nould be supple-

mented by an economic analysis before rational choice can

be made The following calculations will provide an estimate of

the rclativ ecooomic effectiveness(REE)

Y t Ps aXpatREE -- 100

vahtercks t sphate or e b i- eor

Price of TSPkg fo

be Price of PRkg P

PROC VOL 38 1974 leO

90r

Wsoshy

0

60-LUSEPHOSPHATE ROCK

00 10 20

PTP PR

Fig 6-Relationship between relaZive effectiveness values (RAE) and the price ratios between TSP and phosphate rock Such a figure can be used in making a choice between these

sources

If REE exceeds 100 in this calculation the phosphate rock would be preferable to TSP

The REE calcuktaaa wre used in preparing an indifshyference curve (Fig 6) wherein RAE values are plotted

against PTsPPpR ratios The cu~rve itself connects those points at which REE equals 100 When exactly on the curve it makes no real economic difference what source is chosen After choosing a suitable price ratio one can then project upward from that ratio knowing the RAI

value (or estimating it from such data as shown in Fig 4 using citrate-soluble P content) one can then choose the source on the basis of both agronomic and economic conshysiderations For example if the price ratio is 25 and the RAE value of the phosphaite rock is greater than 40 the rock phosphate in question would be used However if the RAE value was less than 40 TSP would be a better choice There are indications that if the P in the more soluble phosphate ro~cks (North Carolina north Florida central Forida) is less than half as expensivz as that in TSP these rocks would be feasible altereaives to TSP on soils similar

to thoseused in Thailand This analysis does not take into account the possibility

of lower yields from use of phosphate rock In addition only a portion of the various yield response curves was used in this anlysis ie up to 22 kgha Beyond this

rate yield response was much less pronounced it could be argued that at less than maximum yields TSP would produce a certain yield at lower rates of P than would phosshy

pow ofrock This would especially be true for rates applioa example at Klong Luang 5500 kg of

rice pcr iectare could have been produced with either Ii kg of P as TSP or 44 kg of P as son of the more reacshy

tire phosphate rocks It should be pointed ot however

- 68 shy

(IIKIS amp YOUN( ARIFICIAL WEATIIERING OF OXIDIZED p[ll- IV

that this is the yield level that would show the widest difference such is the advantage of hindsight

Farmers generally prefer granular fertilizers for machine

or hand application This is a disadvantage for the phos-phate rocks which are normally arplied in finely divided form Recently experimental quantities of granular urea-

phosphate rock mixtures have been made by TVA Results of trials with these fertilizers will be reported elsewhere

LITERATURE CITED

1 Armiger W H and Maurice- Fried 1957 The plantavailability of various sources of phosphate rock Soil Sci Soc Amer Proc 21183-188

2 Bengston G W E C Sample and S E Allen 1974 Re-sponso of slash pine seedlings to P sGurces of varying ci-trato solubility Plant Soil (In press)

3 Caro JIt and W Hill 1956 Chard eristics and fer tilizcr value of phosphate rock from different fields J Agr Food Chem 4684-687

4 Ensminger I E R W Peirson and W II Atmiger1967 Effectivencs of rock phosphate as a source of phosshyphurus for plants US Dep Agr ARS Bull 4112S

5 Engelstad 0 P J G Getsinger anid I J Stangel 1972 Tailoring of fertiliers for rice cnnece Valley Author ftyNational Fertilicr Developmnent Center Hull Y-52

6 Khasawnch F E and Jane P Copcland 1971 (otton root growth and uptake of nutrievos relation oif phosph

rus uptake to quantity intensity and buffering capacit) Soil Sci Soc Amer Proc 37250-254

7 Lehr JR and G H McClellan 1972 A revised lIbora tory reactivity scale for evaljativg phosphate rocks for direct application Tennessee Valley Authcrity National Fertilizer Development Center lull Y-43

H Terman G L S EAllen and 0 P Engelstad 1970 Response by paddy cice to ratcs and suurces of appliedphosphorus Agron J63390-394

DIVISION S-9-SOIL MINERALOGY

Artificial Weathering of Oxidized Biotite IV The Inhibitory Effect of Potassium on Dissolution llate

R JGILKES AND R C YOUNG2

ABSTRACT

Rates of dissolution of oxidized biotites in OIM 001M ICI are severely depressed in the presence of IM KCI The amovnts of Al Mg Mn dissolved in the first eytraction are similir to those found without KCI however subsequent extractions remove these elements at 10-20 of the corresponding lICI rates This effect may be due to a decreased rate of vermiculite formation thereby reducing the effective basal area exposed to attack A decrease in dissolution rate with increasing ferric iron content was still apparent in the presence of IM KCI

Additional Index Words X-ray diffraction infrared aborp-

N EARLIER papers of this series the tole of biotite in soils

as a source of both macro and micronutrient elements

has been discussed ((Gilkes Young and Quirk 1972 1973ab) Experiments in artificial weathering uiing as va-

riety of extractants were undertaken to determiie the inlu-

ence of oxidation of octahedrally coordinated iron on the bull release of structural cations to solution The results of this

work demonstated that biotite behaves anomalously with respect to the other common ferromagnesian minerals found in soils Oxidation leads to the development of a high degree of resistance to cation exchange and dissolution Several authors have coiwludcd that decreased rates of K

Contribution from the Dep of Soi Science and Plant Nutri-tion Institute of Agriculture Univ of Western Australia Ned-lands 6009 Western Australia Received 29 Sept 1973 Ap-proved 8 Jan 1974

2 Senior Lecturer in Soil Science and Research Officer respeclively

replacement in electrolytes shown by oxidized biotites are

a result of the inclination of structural hydroxyl adjacent to newly created trivalent iron or vacant octahedral cation sites (Robert and Pedro 1959 Barshad and Kishk 1968) Gilkes et al (1973b) suggested that decreased rates of disshysolution of oxidized biotite in 0001 0t)l 0Af CI may also be due to the presence of inclined hydroxyl In this case a smaller surface area external and exposed intershylayer may be available for attack if K replacement by hyshydrogen ions occurs at a slower rate in oxidized biotites

Gastuche (1963) has shown that significant dissolution ofthe (IIM) biotile face may occur and it is easily demonshystrated that the proportion of exposed (001M) face in weathering biotites depends on the percentage K replaced

Rausell-Colom ct al (1965) have shown that hydrogen ions act in an identical fashion to metal cations in K exshy

change from micas In particular exchange c-f K by hydroshy

gen ions will be terminated or greatly reduced by high levels of K in solution Thus if dissolution of oxidized biotite by

acids is carried out at sufficiently high K levels to prevent vermiculization any differences in dissolution rate that may occur cannot simply be ascribed to differences in rates of K replacement The following results were obtained from such an experiment which unlike the experiment described in Parts I and II (Gilkes et al 1973ab) does not attempt to simulate natuiral - conditions

MATERIAILS AN) M HIiODS Further subsamples of the less than 0 hiotites used in K

excherandbaid disoo tu es (G iles e9n K exchange and acid dissolution studies (Gilkes et al1973ab) were used in these experiments Preparation of sequentiallyoxidized biotites without intermediate vermiculite formation is

Page 29: I70 - United States Agency for International Developmentto ascertan, but tgl.eetad, 1, L,. ("Tailoring of Pertiltiters for ice,'" TVA ulletin Y-52) states that the staft of IOi has

-- 26 -

Table 4

Effect of N Source and Time of Application on Yield of Light Irrigated Rice in India 1972 (Summary of Reported Data From

One Experiment at Pattambi)

Experimental Number Source Rate Method Yield Relative N-Response

and of of N of Yield Kg Grain Season Nitrogen (kgha) Application (mtha) Q) Kg N

38 0 - 204 85 -Rabi Urea 120 Basal 241 100 308

Urea 120 60 + 0 + 30 + 30 267 ill 525 SCU 120 Basal 255 106 425

Table 5

Effect of N Source and Time of Application on Yields of Short-Duration Transplanted lice Variety Grown on Irrigated Light-Textured Soils at 5 Locations in India 1972

(Snmzarized From Reported Data)

Rate Grain Yields (MtHa) Source of N Method of N GrainI of N kgh Application Faizabod Karjat Mandva Pattabi laya Averaje X

- 291 266 211 19 340 260 -

Urea 100 Basal 386 407 361 285 482 3 124 Urea 100 50 + 25 + 25 399 430 434 334 6amp2 4A8 186

SCU 100 Basal 368 468 439 360 572 41 181

Table 6

Effect of I Source end Tlae of ApplIcattoo c RIstave Tle24 of a rt- rat1 T Lsd lice Vasrety Crin o Irrigated L41tshy1 at S Locitite mindi 1972

Rate ____________14_3

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twoo TttWimI fl04it M 4 ~t w tamp A 11P o We

-40 tad 11fdIAW000 0tw A004s~lI7KVw totI Pt to))

t 164 044pi 44~4 WO 040Oipi0 ~om b~e1

rewIott- MN1 tVfI OOwK o l

Stt19 Of 0 SeOO M IbAWO AffikampI 00 Vt414 Ot VPtd 44 tM~wuOWe tni144 Ite W 1iw)ts 060

211 U e 1dit f

w 0 31 ~ 19 AA 116 1 AS Ma )4 ) At

wx451146

ISO 00) OM4 0101 9I

T60te

owel4440 00VII O A ofWM PwmeeA st rof (Amrol IMVf

Mt ot U 6q-wto~ COW i 4t~ eso

Tel of ate (01m itl it Iiuma tWuJt)

21L1L LW ufU~ vie 114 3 10 106

As 11 i 41 4 smg LAY1 $Of 41)

Tabl I

f~ttwi Ot 0 6wirce 81d At$ a vt1d at flUop4d Rico to Vitjorim (1ITA)All fortitfour to rsodkeet OA lC~OVPr4( 114 5iI 000

W Iotors Ftslanp tospg Irritd for Two thvk Afler flontiw wft rkwa~ Floo4d 191)

- -I-of LWAIM) (IS YJl- fl-----II)

-0 10)

AA MO 4 S4

4of O 149 6MID O 41110

KthD 00

- 38 -

Table 18

Yild of aemati-370 Rice at Punjab Agricultural Research

Institute in Pakistan in 1969-70 Grown Under

Couditions of Intermittent Flooding

Pate of application

=IL

o 0 67 67 100 100 67 67

100 100 67 67 200 100

Average for Sources

Ntha

AS 260 gres 279

320

Source f5

-

AS AS Ura Urea SCU SCU

Yield

Relative

93 100 115

(M)O

Yield

Increase Yield Due to N

(Ktlha) (mtha)

-212 245 033 274 062 260 048 297 085 315 103 325 112

Yield Increase

Relative

72048 067 100 108 161

(2)

- 39 shy

Short-statured high yielding rice varieties grown extenshy

sively in northern Peru require extremely high rates of conventional

N sources to achieve maximum yields The recovery of applied N is

extremely low due to the use of intermittent flooding This water

management system results in heavy N losses even with properly timed

split applications In search of simpler and more effective methods

of N management eight field experiments were conducted in the region

to evaluate sulfur-coated urea (SCU) an experimental slow-release N

source supplied by the Tennessee Valley Authority Rice yields were

increased an average of 59 more by pretransplant-incorporated SCU than

by urea or ammonium sulfate applied in the same manner SCU produced

excessive vegetative growth which resulted in yield reductions at high

N rates

Regardless of an assumed 48-higher unit N cost in SCU the

overall benefits of pretransplant-incorporated applications of SCU

were favorable since there was a decrease of 40 in the optimum rate

of N and the need for precise timing of application was eliminated

Pakistan--In Pakistan basal applications of AS urea and

SCU to rice grown under conditions of intermittent flooding in 1969-70

(table 18) indicate that SCU is a superior source of N as compared to

urea or AS when all N is applied at or before planting The data also

indicate that a yield response was obtained for P applications but a

comparison of N sources at each level of P indicates that no interaction

between N and P was present so that differences between N sources were

relatively the same at each level of P Yields were increased about 60

more when SCU was applied than when urea was applied Yield increases

with AS were only about 72 of the increase obtained with urea these reshy

sults do not agree with the generally-reported superiority of AS as comshy

pared to urea as a source of N for rice

- 40 -

In 1973 experiments were conducted in Pakistan using both

Basmati-370 and IRRI-6 varieties of rice grown under conditions of

When all N was applied at puddlingintermittent flooding (table 19)

or 12 at puddling and 12 at panicle initiation both AS and SCU were

superior to urea with SCU tending to be the most efficient source

However when N was applied 12 at transplanting and 12 at panicle

initiation SCU was the poorest source of N This would indicate that

the release of N from SCU applied at these times is too slow for optimwn

plant growth

In another experiment in Pakistan in 1973 no differences

in the effectiveness of urea AS or SCU were noted in the yields of

continuously-flooded rice (table 20) Again these results are conshy

sistent with earlier results which indicate no superiority for SCU

when rice is continuously flooded

Nitrogen Studies--Maize

A series of three experiments were conducted by IITA in

armo-Nigeria in 1972-73 comparing AS urea SCU and

CAN (calcium

nium nitrate) as sources of N for maize (table 21) A significant

yield response was obtained for N at each location but no conaistent

differences were noted amaong sources These results are consistent

with results at other locations which have not shown that SCU is a

superior source of N for maize grown over a period of 3 to 4 months

Nitrogen--Wheat

The yields of wheat in Pakistan in 1969-70 (tables 22 and

23) show that yields with SCU) tended to be lower than those with ureaJ

although at one locction where sorghum was grown followilng wheat with

Table 19

Yields of Basmati-370 and IRRI-6 Rice at Punjab Agricultural Experiment Station in Pakistan in 1973 Under

Conditions of Intermittent Flooding

Rate Yield Source of N Time of Yield (Mtha) Increase of N B-370 IRRI-6 Application Basmati-370 IRRI-6 Average (Mtha)

0 0 - 21 353 287 -

SCU 90 150 At Puddling 325 545 435 148

Urea 90 150 At Puddling 309 500 405 118

AS 90 150 At Puddling 324 529 427 140

SCU 90 150 Puddling 372 572 472 185 Panicle Initiation

Urea 90 150 Puddling 335 502 419 132 Panicle Initiation

AS 90 150 Puddling 353 529 441 154 Panicle Initiation

SCU 90 150 After Transplanting 312 562 437 150 Panicle Initiation

Urea 90 150 After Transplanting 340 624 482 195 Panicle Initiation

AS 90 150 After Transplanting 349 583 466 179 Panicle Initiation

All plots received 45 lbs P205acre as single superphosphate

Relative Yield Increase ()

Source of N At Puddling Puddling Panicle Transplant h Panicle

Urea 100 100 100 AS 119 117 92 SCU 125 140 77

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-48

Therean laiictw that It lbs P to th e am lukis

obosomhu rocks 0entk catetas rth Unrtdo costrat frwt) to

ht tse balt s Owosiv as that to TwP it rocks WM bo

fmtbt alteruutiv to MSso gotastte to~ Ik lee used to

ThUAIAd

Tht wMl dt gotmtmlaoti wout th possibility

of law Vhld free ww e1 e66001 4 It cooUt be YgWd Sutt

a4 10 0410 SWUSSM yt$4e TOP wUd predWr A r~ftIf fl~W t

1f f ot P the wuld phosphae rck TWOe viWMW efocitill b

true to low rttos t tsplusatiI P wi 9 Ma Liiam $S

amp4at r per Wforssota Mav two 64eed Wilk elikor It 44 of

P go Mi er 4A bg oftoP aon of tewmrowtni pboophals fwAh

It vwld be polotrd A Wevero wtht Is the jteld level that

W414 gk tko videm dtterem~j o(A 1 the 4~etamp tk~e~t

P11~0 pra~lpj prefer gre4r tuftlter for whlae

of hoaw ppltrstie Mhe to a dloedveaP for The PINSOO rocka

vkth m r II spotted 10 ftewil 4106Me tem

Nub studios we ovsosd o IVA vol gramleid a

forgof wee aMW pbsepbots A fths pemhawe evsielew us

Odellod to detMlee it otteettvmm of 11agotated Stoture of

mmfp MW phapa A (CI) sed graewletod pampAtlti arlolatod Pa

asowcs of P tof ttde ro The wreem proucts omre raGther

pemour~a ot P syag besmti andMi as elt ov so gpamwhr

iuipiqffhate(TS) low twseeo Is eftwiltve Is thet

W41 preeme wae oialain ire post-rItoi effriq to Stanlato the

pud6itt of Irto paddle Wee ofsdlseireplastiq

0 49 shy

lbs partially scldiaatede grawilated Ml prodlucts Vere isshy

toiwdiats in 5tftOvttWS54 betwee wroiPi ad TVP NotV5Ymf to

me coo were they mere twoe $a a etfective ao TIP 00 sipifleast

LVSUMI5 at0 efecto wore toun tor thee produteo Timely dtIampWde

FR (-t00 mmoh) Uia amp~rally oar affective than Owe gra8448r FOampprodt

featal twos o 6 aotetire s I

Nowvero it to felt that sfortber field euprtet vth

hese interials Amd ether typs of grometatodl Wter nre wrrautad

hater ceeuwodh that they have me areec poteatlal toi additoG

e tate wAne the sectte as OtawrI sed bovoloen turther

euperimeste vth few reck pboophar s0d with reck pbophat treated

to sehesa citrata selmtliy or to ha csaducted

Metbir sertes of tbme enprtaeats wae c~edtmcted by IITA

to Ut~rta copal TVP AOP APP aed it at see tecastisix (table 14)

No dot lalt sewseltles teh draw tree thee results simouely em pear to tlvdl bsww they do stwgpt tbat forthew work with

MR to werramid so tbme sels

Table 24

LttcttF Swce MaPlate 06 ieldot IM AWaia CoelsANS at IITA (Ugboda ad Apoin ail sorit) aid at Ike (AUaba s5i series)

1973

Plate ot IP Apinu 5 poundebods A1ab

Ocrol 0 Z94 419 M)

Tr ipl ruprphite 20 349 3799378

Triple vepput 40 M09 410$

Triple 6wp~~b1 4271 4344 42250

Ammotw-ritpophW to 4201 4124 4040

Amosim-rdop~phlt 40 4270 4106 4231

AM tuo-polpephats 20 404 4244 3794

~eai~mpelppepbuI 400)49 4094

Cee m-pbpbt to- 59

momee eph lto 0 4192

LSO (0 0$) 29 1025

Th WPII

- 51 shy

101Y114 tpeM-fI PEP~tbRP YO

1 ~ ~ gmw 1pc~biofl- 9 Kla4v4h

Upia U04 Copfind am Crehout Stet Rpano at (Ia4

rico t IF t rume6 orth~ Caralto phoophale rocl QAR) vaUN pqU41 to

roopon from cmonetrat4 gsporphophai (CIP) who ort$o4 oil k

was 45j itwas tafertor vb protioo4 oil p war OS Ib 4iffer~c

in rtc reepos to X cod14 oo bo ttrit4 4 4 hvsciag of boil p

~ Pt o r11221 0 tP

c theto the rhimecyllndor of rico tots par to)14M4i1 roeoi~t

ed oil emd PA prior to tho ont of an~robi4 cMioe AA~ oIifoshy

nAte bYpot t taet~d tO fC4sin t~r 4PWden0 Of f Ot(tivshy

ofOWailiJtyno o prefla4 all Put that 4t01etoo 14 tvsIk

of the Ott to prvvld a 014for C4m0 44 mI 1 o4sf

EfftC ftPet141on AIAM-0 V f401td 4 4iv 440 Mtft

Aa torfat VampP f4MWfCi4W04wt0amp to 4eturWlI Ot(Wel~drIC ft

Ot f tM6 the flooded Ott 00 14 04019I Pft0uAw Of gAr~s~lr

pkS$t M40b MP) Tw P1101 Piset Prodwie W-e 10M0di Wr04

(10-1) emW 0aretilp ddw01at4 P WAA firom Rrth M~flRU414~$

wee cowiared with fie Md reWim 44104 proo~fo) foruk oith laWItter

I v te-PR P OW1004 4 4 O Wf ottil OW ellt Oo

Oveiel1 the 40tt dmcruie to effetotww Wtollowui Co fme

PR tpaUIB1I ldoltmo PR (pamwlatr) offr~- ArmeuM) 0 orwi

- 52 -

Effect of N Sourc6 and Water Management on Response of Rice

toe Zn- M Giordano J J Mortvedt OP Engelstad and Greenhouse

Staff Several rotes of CO(14H2)2 and (H )2So4 vith or without ZnO

wore applied to flooded and nonflooded Crowley oil (limed to pH 75)

to determine response of Bluebelle rice to Zn Yields with both N

sources veotrgreator on flooded then on nonflooded soil In the abshy

ence of applied Zn total dry matter production vith CO(NH2)2 was

slightly lower than with (NH)2S04 on flooded soil and considerably

lover on nonflooded soil Concentration of Zn wan higher in straw and

grain of plants roun on flooded than on nonflooded soil Although

concentration of P was unaffected by N source or Zn rate there was

som indication that cranslocation of P from straw to grain may be

depressed in nouflooded rice Concentration of N was lower in straw

grown on flooded than on nonflooded soil due to apparent dilution

thereas both X sources resulted in similar N concentrations in straw

at all rates of N application the N concentration in grain increased

with 0 rAse

feSpongi gf(SM to Chjorospodiostte and Related P Sources--

Si Allen and Greonhoue Staff A greenhouse pot experiment was

couct44d with corn Brown on Hountview silt loam to compare the ofshy

fectlivees of chlorospodiosito (Chlor-l) with concentrated supershy

phosphate (CP) Thomas slag and North Carolina phosphate rock (NC-PR)

Oil-prillad urea-phophato rock (UPI) FeA1JMP 20 7 and monomthyl

phosphate were included in the experiment Based on yield of forage and

uptake of P by tvo crops each of 6-weeks duration the following conshy

stui were dravat

I Chlor-1 was slightly loss effective than CSI Thomas slaS or NC-PR

from which Chlor-l wae prepared

- 53 shy

2 Granular UPR was a poor source of P its effectiveness was greatly

increased by reducing the particle size to -35mesh

3 FeAlNH4P207 was unavailable to the crop

4 Monomethyl phosphate was equivalent toor slightly more effective-

than CSP

Research Indirectly Related to TVA-AID Project

Response of Several Rice Varieties to Zn in Moist or Flooded

Soil--P M Giordano J J Mortvedt and Greenhouse Several varieties

of rice from Mexico and the Dominican Republic currently under investishy

gation in Puerto Rico for adaptation to upland culture were compared with

some established United States varieties with regard to Zn response on

moist and flooded Crowley sil (pH 75) Chontalpa (Mexico) Bluebelle

(Texas) and Starbonnet (Arkansas) were most responsive to applied Zn

Juma (Dominican Republic) intermediate and Sinaloa (Mexico) and Calrose

(California) were the least responsive The Sinaloa varieties (Mexico)

appeared to be best adapted to non-flooded conditions whereas Chontalpa

and Calrose were poorest Concentrations of Zn generally were higher in

plants grown on flooded than moist soil

Pattern of Growth and Zinc Accumulation by Rice--P M Giordano

J J Mortvedt and Greenhouse Staff Rice plants were harvested at weekly

intervals from shortly after emergence through maturity The objective

was to determine the rate of growth and Zn uptake by a Zn responsive varshy

iety (Bluebelle) and a less Zn-responsive variety (Calrose) in the presence

or absence of Zn applied to Crowley sil (pHl 75) Dry matter production

of Calrose was linear with time of growth and of a similar magnitude until

heading with or without applied Zn Bluebelle followed a similar pattern

where Zn was applied However in the absence of applied Zn foliage yield

was reduced markedly

-54

Uptake of Zn was similar for both varieties whenZn was

applied Dry matter production and Zn uptake by the two varieties

also were comparable when Zn was applied However yield of Calrose

was much higher than that of Bluebelle in the absence of applied Zn

while Zn uptake was only slightly higher This suggests that the lesshy

ser responsiveness of Calrose to Zn may be due to more efficient utilishy

zation of Zn There was no indication of a greater demand for Zn durshy

ing reproduction in either variety as was suggested in earlier greenshy

house experiments

Response of Upland Rice to P and Zn--P M Giordano J J

Mortvedt and Greenhouse Staff Several rates of P and Zn were applied

to Crowley sil (limed to pH 75) in factorial combination to determine

whether differences in rice growth under flooded and nonflooded soil

conditions are related to plant nutrition Although straw yields were

slightly higher in nonflooded rice receiving adequate P and Zn grain

yields were higher in the flooded crop increased rates of F andor Zn

did not result in equal yields Except in the highest Zn rate (75 mg)

concentrations of Zn in both straw and grain were higher with flooding

Concentration of P increased with rate of applied P and was higher in

the grain or flooded than upland rice at a comparable P rate In conshy

trast concentrations of N were lower with flooding due in part to dilshy

ution from increased growth

Rice Response to N and P in Flooded and Unflooded Cultures--

G L Terman S E Allen and Greenhouse-Analytical Staff Rates of

N from 250 to 2000 ntpot and P from 0 to 1000 mtpot were applied for

Nato rice grown on Mountview sil and Sango sicl (625 kg of soil per

pot) Market yield response to N and P was obtained Yields of straw

- 55 shy

total yields N uptake and N recovery were higher on unflooded than

on flooded soil cultures Grain yields however were slightly higher

with flooding These results indicate that with adequate applied

nutrients especially of N rice yields without flooding can approach

or even equal those under flooding

Uptake of N P Ca Mg and Zn increased with yield response

to N and P while K uptake decreased on the Mountview soil Concentrations

of N and P increased with applied N and P respectively while concentrations

of other nutrients were diluted in most situations with yield response to N

or P

Results from this experiment show that amouats of N applied in

previous pot experiments for rice have been much too low especially if the

crop was grown to maturity

Response of Corn to S and N i UUASand Urea-S--S E Allen

and Greenhouse Staff Three greenhouse pot experiments were conducted to

measure response to S and N in ulfur coated urea (SCU) urea amonium

sulfate (UAS) and urea -S as well as estimate N losses from surface apshy

plied N sources

In Experiment 260 less than 20 of the S mixed with the soil

was recovered from SCU or urea-S granules by two crops of corn as comshy

pared to 45 or 80 from flowers of S or Na2SO 4 CLop response followed

a similar pattern

In Experiment 260-A N sources were surface applied and alshy

lowed to dry for two weeks before incorporation Into the soil and plantshy

ing Recovery of N by two crops of corn was 77-82 for AN an compared

to 37-70 for urea UAS urea-S and ICU Thus n this experiment loss

of N from urea did not appear to be re~dcud by light S-coatlngn or by Inshy

corporating S or AS in the granules

-S -

I xbprZnSlt a Wtch aU Meyto 0-Ai Wt f9r

higher reermo teOrtOrs cOM reSpWNO i r0100 Of N w

not oaisteontly related to sewe ot N In edl tust 0 ioltiUe Lim

lo in VMuwpped evlmtUTS 48 merind by seirest nte appresOehe

501 for uroa as cwarod to 210 for urea peepha

Rus- or Upse to LoAmIl34I a AriMed bI Earl U

MW NOWlsIIsIr-4 L Toman 5 1 Alln and eesese StNf rio

row on Sawg did (0 tpot) We 1l0l0 Ws feritiud vith 05is

of Npot mixod with the 6011 as aureCA NiAO) 1 Age god At Ures

was also itcluded at rtt t 05 10 end 15 of Upee Theas trealshy

onto were followed 4 wpdrsetago of U s AN wre 4C 10o or at I3n

Weeks toulin up to IS pot

A soil application of 10 pot rosulvod to the maim yield

at 4 weeks Tio4 sad percont prottis t intre raite tncreased rftishy

linearly with U applictalien IeseeItally all at the m iNd wit

the moil w domitrifted after flooding Grail end straw Ilelds vere

highly correlatod with tiliriag and vlh ubers of gralm arl

The results Widicat that 0$ to 10 a of Upot as orea or

NN bsuld be sied with the oil to stilate tiilrir with adshy

ditional 0 topireased later to increase grain lIds mad protia cmshy

tout

DIVISION 54- FERTILIZER TECHNOLOGY AND USE

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-02

792 60L WI W A)49R Pio VOL 37 197)

primS o r OeampAd WU toa Them fl~ w At NOSSe earno maisslea Ia N he mOWamplIO yik ampWd IMe aampWmW OWa Owe wa UMs of KU to 41 Oke ampWiiIamm be dkrnety ewspokawleM(a s8 te camtd wie a eapmoe by TVA pavw ltoi NA poundrmdaka4us vrimeW460 o to ilkidm ofWW (Mtemas MuOwe 1973) TVA mwi bawld on soi ficedims IampWp seg rudwiv s~s0abet ke WNmdoe ON 01 K Is12 NOSW ie fssewnmu Ie I QvaaIi rowp IMA) f9

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DIVISION 8-9-SOIL MINERALOGY

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65

0IL CL OC AMXR PROC VOL 38 1974

)aT1 S4I104 ow Lusanll Tawng isa tall Thai variety known for beingIwo nonshyi s s ) sensitive to photoperiod A split-plot design was used in

S e e these euperimeots with 4 rates of P (I1 22 44 and 88t i V IV k of Pha) applied a main plot treatments and with the OF It sourMes of P as subplot treatments There were two checkS plots in each rmplicate The extra check plot was included to permit the application of fresh TSP standard Jor the

It- ti 06 + i bull fa succeeding crop the p-4me of bi was to permit accurate d awrnwal of the mdual effectiveness of the phosphate

ftinSUbI rock The P fertilioers were broadcast on the mud andthen Worporald In the soil during the last harrowing At

whM N both On ACS indx ampM time of transplanting Immediately before the last harrow61t (4j 5 4 01 P s 3Mm o Vallonal in con n 100 kgha of N as ammonium sulfate and 33 kghaWO Of Spews ampm lIW thaabe rocks do ACS indes of K as polium chloride were applied A total of 40 wa in prepw O do ctih k otent kha of N a ammoniunt sulfate was applied later in twoir P The hew oNed amp wM W for 5 of gw topdrossingp with about 5cm depth of water on the plotsvV I aiOMveffeOctveee Three to six ldayold selings pr hillwW the ACS idex were planted00OWW wia Oft fo an c irNk I p Coen 20 by 20 cm part in straight rows Hand weeding was used

and insecticide were applied for Insect control Grain yieldw was masared by sampling 5 ml of each plot excluding border rows The date of heading in each treatment and theUNiN d pbM W Weks rin tOW USA UMe In Tale yed componnts at hafvel were also recorded

I filM rsperMS esOM kdwdua 1 t ab The average yields of ough (unhulled) rice for botha 84 OW O 8uo 4 Thala TM was a locations are ploutel in PIS 3 for the first crop (1969 wet

owou thRM seaso0) The Veamps yield response was obtained at Klonge (s) W lDtO t Of dMa of1tw W d l R Luang however a 4ute satisfactory yield response was

~Mk ^d TVA UJSD ad Kd UnIveS obtalned to applied P at Bangkhen as wellXUe LaM e R qwrw Ims The sod was do Relative aponomlAe effectiveness values were calculated

VOW (a ksA w edmwL t Poesesm h Vy for these data and am presented In Table 3 The valuesdAY buo if dIe ouh ne Pee wtk a Mlak vow 1009 for th first crop are plotled against ACS index in Fig 41 This Im M i6ti l 4bNd IO a0 O mkarnk for both locatio r relationship was linear for the

11400 ThCpH 0( lb pW IW 01 th UpeiaW so Sanodion location and curtiltnear for KIng Luang The was u i 4A sksamp lMaor nrusio model amparounted for 81 of theAmO$MI Aw jAAsue Swim T1 Snh Wd variation In the AE valu for Bantkhen a square root

Mems a Iw iv fern alh$ sedm haowg dayNW W t he plAL At tdo M tM aso W s as ctminued throufh eltaM t Ofpof -le lse wo am P OeNI VeOpls 1o ealluae tI lon4erm MIdual Offccls

A on W isset i a wse to hsh eapeel of these ooihss t ocks The baagkhon experimnent was letmiaI1DlVemisthis is a w hulu Lo g Tasug ia iasael aft - Msd residual Ves will be pr-Om crok TheseTwod esewm

SWWo

A

lP~U~7 ISIIPe1iuIWN e bsedisssin ian ghth siaoelalbe

984 0 6 O O - M s -s fWPas 11eSft W d Uo al a o

o

S4l~ lIIII I~l I 1f fl

( +

+ + + m + ++++-

++ +(++ + ++++ + ++ ++

- 66 -

ENOIMLSTAD ET AL RESPONSE BY FLOODED RICE TO PHOSPHATE ROCKS VARYING IN CITRATE SOLUBILITY

I I I I j0 I I

BANOKHEN BANGKHEN

pH 56 6 - 0o

TSP

NC

5~ ~ ~ L o 4 - -shy

4 ] - --------shy04

6S

|0 III 2 44 8r 66

I I I

a 1KLONG LUANG

pH 46 z KLONG LUANG

TSP Sc2 NCFL(N)

5 FLIC) J0 TU

oshy

4 ~40shy

3 bull eM0

I - I I I I I

0 II 22 44 88 0 5 10 15 20 IP APPLIED KO HA ABSOLUTE CITRAE SOLUBIITY INDEX

Fig 3-Yield of rough rice at Klong Luang and Bangkhen Rice Fig 4-Relative agronon effectiveness () of P sources ploz-Experiment Stations Thalmand as affected by rate and Source ted against citrate solubity Index for both Thailand field ex

of P applied (crop 1) periment (first crop only)

regression model accounted for 97 of the variation in sumably resulted from crop uptake and reaction with the RAE values at the Klong Luang location soil to form less soluble products Such effects may have

These experiments were continued during the dry season been more important at the lower rates since the two TSP of early 1970 to ascertain the residual effectiveness of the curyes converged at the highest rate of application various sources applied to the first crop No new P was These data from KIong Luang indicate that (i) residual applied except for the fresh TSP standard mentioned effects of all rocks except Mlcwuri were substantial (ii) above rhe experiment otherwise was conducted in a man the relationship between relative agronornic effectiveness ner similar to that followed in the first crop of the phosphate rocks and citrate solubility levels was

The response to both freshly applied ad residual P was largely obscured and (iii) the general superiority of TSP marked at the Klong Luang location and marginal at over phosphate rock in terms of effectiveiss persisted Bangkhen In fact at the latter location the response was through the second crop so small that little can be said regarding residual effectiveshyness The yield data from crop 2 at the Klong Luang DISCUSSION experiment are plotted in Fig 5 Greenhouse and field data presented in this paper show

Relative agronomic effectiveness values (Table 3) were clearly that there are substantial differences among phosshycalculated for the Klong Luang data using both the residual and freshly applied TSP as standards It is of Interest to note that the superiority of TSP over the phosphbte rocks Table 3-Relative agronomic effective values for field experishyments in Thailand persisted through the second crop The main difference in KlowlZmlnql~the residual effects is that with the exception of the MIs- s Crop 1 Crop 21 Crop 1-shysouri rock Ihe marked relationship between citratr-soluble WoiCarolina yl 59 76

phosphate rocks and RAE had largely rds norh) a 64P conltct of th Florida (eqlral is 6969 6

disapipeared In this acidic soil (pHi 46) P would by this I14o 69 63 40 ToonesS 31 65

limo be supplied by Intermediate reaction products In addl Missou 0 o lion to residues of the initial spatlte Ts P o 2 o 0

The TSP applied to the first crop declliv-d slightly In campIafcmWataesr e id ofeuhuloefor 22MA rates of PtColeouattd as aba u tlte td18 kS ratesp dlverage yield tM868 to 22 44

effectiveness relative to the freshly applied ISP This pre- of d s4

A

4

- 67 shy

-SOIL SCL SOC AMER I

KLONG LUANG CROP 2

Si 3

eN

TAPPLIEDKGHA

Fig 5-The residual effectiveness ovarious P sources for crop s compared with freshly applied TSP Klong Luang Rice

Experiment Station Thailand

phate rocks in terms of agronomic effectiveness for flooded

rice Further these differences can be predicted by means of citrate solubility or by the ACS index It appears that

the latter is more appropriate where the content of apatite varies among phospiate rocks The most soluble phosphate rocks approached but did not actually equal TSP in limit-iuig (maximum) yield in these experiments regardless of rate applied This agrees with the results of Ensminger Pearson and Armiger (4) One needs to consider the defi-nite posribility of same yield loss in zhoosing a phosphate

rock over TSP such yield losses must be weighed against the lower price of phosphate rock The explanation for such iosses may involve concentration of soluble P in the soil Khasawneh and Copeland (6) suggest that the growth rate of crop plants is a function of P concentration that can be maintained in the soil solution If P concentration is limiting or inadequate becawe of a lower dissolution rate of phosphate rock the growth iate ard uiiimate yield will be diminished accordingly

The RAE values bascd on yield increases reflect the agronomi effectiveness of these various sources relacve

to the TSP standard however these nould be supple-

mented by an economic analysis before rational choice can

be made The following calculations will provide an estimate of

the rclativ ecooomic effectiveness(REE)

Y t Ps aXpatREE -- 100

vahtercks t sphate or e b i- eor

Price of TSPkg fo

be Price of PRkg P

PROC VOL 38 1974 leO

90r

Wsoshy

0

60-LUSEPHOSPHATE ROCK

00 10 20

PTP PR

Fig 6-Relationship between relaZive effectiveness values (RAE) and the price ratios between TSP and phosphate rock Such a figure can be used in making a choice between these

sources

If REE exceeds 100 in this calculation the phosphate rock would be preferable to TSP

The REE calcuktaaa wre used in preparing an indifshyference curve (Fig 6) wherein RAE values are plotted

against PTsPPpR ratios The cu~rve itself connects those points at which REE equals 100 When exactly on the curve it makes no real economic difference what source is chosen After choosing a suitable price ratio one can then project upward from that ratio knowing the RAI

value (or estimating it from such data as shown in Fig 4 using citrate-soluble P content) one can then choose the source on the basis of both agronomic and economic conshysiderations For example if the price ratio is 25 and the RAE value of the phosphaite rock is greater than 40 the rock phosphate in question would be used However if the RAE value was less than 40 TSP would be a better choice There are indications that if the P in the more soluble phosphate ro~cks (North Carolina north Florida central Forida) is less than half as expensivz as that in TSP these rocks would be feasible altereaives to TSP on soils similar

to thoseused in Thailand This analysis does not take into account the possibility

of lower yields from use of phosphate rock In addition only a portion of the various yield response curves was used in this anlysis ie up to 22 kgha Beyond this

rate yield response was much less pronounced it could be argued that at less than maximum yields TSP would produce a certain yield at lower rates of P than would phosshy

pow ofrock This would especially be true for rates applioa example at Klong Luang 5500 kg of

rice pcr iectare could have been produced with either Ii kg of P as TSP or 44 kg of P as son of the more reacshy

tire phosphate rocks It should be pointed ot however

- 68 shy

(IIKIS amp YOUN( ARIFICIAL WEATIIERING OF OXIDIZED p[ll- IV

that this is the yield level that would show the widest difference such is the advantage of hindsight

Farmers generally prefer granular fertilizers for machine

or hand application This is a disadvantage for the phos-phate rocks which are normally arplied in finely divided form Recently experimental quantities of granular urea-

phosphate rock mixtures have been made by TVA Results of trials with these fertilizers will be reported elsewhere

LITERATURE CITED

1 Armiger W H and Maurice- Fried 1957 The plantavailability of various sources of phosphate rock Soil Sci Soc Amer Proc 21183-188

2 Bengston G W E C Sample and S E Allen 1974 Re-sponso of slash pine seedlings to P sGurces of varying ci-trato solubility Plant Soil (In press)

3 Caro JIt and W Hill 1956 Chard eristics and fer tilizcr value of phosphate rock from different fields J Agr Food Chem 4684-687

4 Ensminger I E R W Peirson and W II Atmiger1967 Effectivencs of rock phosphate as a source of phosshyphurus for plants US Dep Agr ARS Bull 4112S

5 Engelstad 0 P J G Getsinger anid I J Stangel 1972 Tailoring of fertiliers for rice cnnece Valley Author ftyNational Fertilicr Developmnent Center Hull Y-52

6 Khasawnch F E and Jane P Copcland 1971 (otton root growth and uptake of nutrievos relation oif phosph

rus uptake to quantity intensity and buffering capacit) Soil Sci Soc Amer Proc 37250-254

7 Lehr JR and G H McClellan 1972 A revised lIbora tory reactivity scale for evaljativg phosphate rocks for direct application Tennessee Valley Authcrity National Fertilizer Development Center lull Y-43

H Terman G L S EAllen and 0 P Engelstad 1970 Response by paddy cice to ratcs and suurces of appliedphosphorus Agron J63390-394

DIVISION S-9-SOIL MINERALOGY

Artificial Weathering of Oxidized Biotite IV The Inhibitory Effect of Potassium on Dissolution llate

R JGILKES AND R C YOUNG2

ABSTRACT

Rates of dissolution of oxidized biotites in OIM 001M ICI are severely depressed in the presence of IM KCI The amovnts of Al Mg Mn dissolved in the first eytraction are similir to those found without KCI however subsequent extractions remove these elements at 10-20 of the corresponding lICI rates This effect may be due to a decreased rate of vermiculite formation thereby reducing the effective basal area exposed to attack A decrease in dissolution rate with increasing ferric iron content was still apparent in the presence of IM KCI

Additional Index Words X-ray diffraction infrared aborp-

N EARLIER papers of this series the tole of biotite in soils

as a source of both macro and micronutrient elements

has been discussed ((Gilkes Young and Quirk 1972 1973ab) Experiments in artificial weathering uiing as va-

riety of extractants were undertaken to determiie the inlu-

ence of oxidation of octahedrally coordinated iron on the bull release of structural cations to solution The results of this

work demonstated that biotite behaves anomalously with respect to the other common ferromagnesian minerals found in soils Oxidation leads to the development of a high degree of resistance to cation exchange and dissolution Several authors have coiwludcd that decreased rates of K

Contribution from the Dep of Soi Science and Plant Nutri-tion Institute of Agriculture Univ of Western Australia Ned-lands 6009 Western Australia Received 29 Sept 1973 Ap-proved 8 Jan 1974

2 Senior Lecturer in Soil Science and Research Officer respeclively

replacement in electrolytes shown by oxidized biotites are

a result of the inclination of structural hydroxyl adjacent to newly created trivalent iron or vacant octahedral cation sites (Robert and Pedro 1959 Barshad and Kishk 1968) Gilkes et al (1973b) suggested that decreased rates of disshysolution of oxidized biotite in 0001 0t)l 0Af CI may also be due to the presence of inclined hydroxyl In this case a smaller surface area external and exposed intershylayer may be available for attack if K replacement by hyshydrogen ions occurs at a slower rate in oxidized biotites

Gastuche (1963) has shown that significant dissolution ofthe (IIM) biotile face may occur and it is easily demonshystrated that the proportion of exposed (001M) face in weathering biotites depends on the percentage K replaced

Rausell-Colom ct al (1965) have shown that hydrogen ions act in an identical fashion to metal cations in K exshy

change from micas In particular exchange c-f K by hydroshy

gen ions will be terminated or greatly reduced by high levels of K in solution Thus if dissolution of oxidized biotite by

acids is carried out at sufficiently high K levels to prevent vermiculization any differences in dissolution rate that may occur cannot simply be ascribed to differences in rates of K replacement The following results were obtained from such an experiment which unlike the experiment described in Parts I and II (Gilkes et al 1973ab) does not attempt to simulate natuiral - conditions

MATERIAILS AN) M HIiODS Further subsamples of the less than 0 hiotites used in K

excherandbaid disoo tu es (G iles e9n K exchange and acid dissolution studies (Gilkes et al1973ab) were used in these experiments Preparation of sequentiallyoxidized biotites without intermediate vermiculite formation is

Page 30: I70 - United States Agency for International Developmentto ascertan, but tgl.eetad, 1, L,. ("Tailoring of Pertiltiters for ice,'" TVA ulletin Y-52) states that the staft of IOi has

Table 5

Effect of N Source and Time of Application on Yields of Short-Duration Transplanted lice Variety Grown on Irrigated Light-Textured Soils at 5 Locations in India 1972

(Snmzarized From Reported Data)

Rate Grain Yields (MtHa) Source of N Method of N GrainI of N kgh Application Faizabod Karjat Mandva Pattabi laya Averaje X

- 291 266 211 19 340 260 -

Urea 100 Basal 386 407 361 285 482 3 124 Urea 100 50 + 25 + 25 399 430 434 334 6amp2 4A8 186

SCU 100 Basal 368 468 439 360 572 41 181

Table 6

Effect of I Source end Tlae of ApplIcattoo c RIstave Tle24 of a rt- rat1 T Lsd lice Vasrety Crin o Irrigated L41tshy1 at S Locitite mindi 1972

Rate ____________14_3

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t 164 044pi 44~4 WO 040Oipi0 ~om b~e1

rewIott- MN1 tVfI OOwK o l

Stt19 Of 0 SeOO M IbAWO AffikampI 00 Vt414 Ot VPtd 44 tM~wuOWe tni144 Ite W 1iw)ts 060

211 U e 1dit f

w 0 31 ~ 19 AA 116 1 AS Ma )4 ) At

wx451146

ISO 00) OM4 0101 9I

T60te

owel4440 00VII O A ofWM PwmeeA st rof (Amrol IMVf

Mt ot U 6q-wto~ COW i 4t~ eso

Tel of ate (01m itl it Iiuma tWuJt)

21L1L LW ufU~ vie 114 3 10 106

As 11 i 41 4 smg LAY1 $Of 41)

Tabl I

f~ttwi Ot 0 6wirce 81d At$ a vt1d at flUop4d Rico to Vitjorim (1ITA)All fortitfour to rsodkeet OA lC~OVPr4( 114 5iI 000

W Iotors Ftslanp tospg Irritd for Two thvk Afler flontiw wft rkwa~ Floo4d 191)

- -I-of LWAIM) (IS YJl- fl-----II)

-0 10)

AA MO 4 S4

4of O 149 6MID O 41110

KthD 00

- 38 -

Table 18

Yild of aemati-370 Rice at Punjab Agricultural Research

Institute in Pakistan in 1969-70 Grown Under

Couditions of Intermittent Flooding

Pate of application

=IL

o 0 67 67 100 100 67 67

100 100 67 67 200 100

Average for Sources

Ntha

AS 260 gres 279

320

Source f5

-

AS AS Ura Urea SCU SCU

Yield

Relative

93 100 115

(M)O

Yield

Increase Yield Due to N

(Ktlha) (mtha)

-212 245 033 274 062 260 048 297 085 315 103 325 112

Yield Increase

Relative

72048 067 100 108 161

(2)

- 39 shy

Short-statured high yielding rice varieties grown extenshy

sively in northern Peru require extremely high rates of conventional

N sources to achieve maximum yields The recovery of applied N is

extremely low due to the use of intermittent flooding This water

management system results in heavy N losses even with properly timed

split applications In search of simpler and more effective methods

of N management eight field experiments were conducted in the region

to evaluate sulfur-coated urea (SCU) an experimental slow-release N

source supplied by the Tennessee Valley Authority Rice yields were

increased an average of 59 more by pretransplant-incorporated SCU than

by urea or ammonium sulfate applied in the same manner SCU produced

excessive vegetative growth which resulted in yield reductions at high

N rates

Regardless of an assumed 48-higher unit N cost in SCU the

overall benefits of pretransplant-incorporated applications of SCU

were favorable since there was a decrease of 40 in the optimum rate

of N and the need for precise timing of application was eliminated

Pakistan--In Pakistan basal applications of AS urea and

SCU to rice grown under conditions of intermittent flooding in 1969-70

(table 18) indicate that SCU is a superior source of N as compared to

urea or AS when all N is applied at or before planting The data also

indicate that a yield response was obtained for P applications but a

comparison of N sources at each level of P indicates that no interaction

between N and P was present so that differences between N sources were

relatively the same at each level of P Yields were increased about 60

more when SCU was applied than when urea was applied Yield increases

with AS were only about 72 of the increase obtained with urea these reshy

sults do not agree with the generally-reported superiority of AS as comshy

pared to urea as a source of N for rice

- 40 -

In 1973 experiments were conducted in Pakistan using both

Basmati-370 and IRRI-6 varieties of rice grown under conditions of

When all N was applied at puddlingintermittent flooding (table 19)

or 12 at puddling and 12 at panicle initiation both AS and SCU were

superior to urea with SCU tending to be the most efficient source

However when N was applied 12 at transplanting and 12 at panicle

initiation SCU was the poorest source of N This would indicate that

the release of N from SCU applied at these times is too slow for optimwn

plant growth

In another experiment in Pakistan in 1973 no differences

in the effectiveness of urea AS or SCU were noted in the yields of

continuously-flooded rice (table 20) Again these results are conshy

sistent with earlier results which indicate no superiority for SCU

when rice is continuously flooded

Nitrogen Studies--Maize

A series of three experiments were conducted by IITA in

armo-Nigeria in 1972-73 comparing AS urea SCU and

CAN (calcium

nium nitrate) as sources of N for maize (table 21) A significant

yield response was obtained for N at each location but no conaistent

differences were noted amaong sources These results are consistent

with results at other locations which have not shown that SCU is a

superior source of N for maize grown over a period of 3 to 4 months

Nitrogen--Wheat

The yields of wheat in Pakistan in 1969-70 (tables 22 and

23) show that yields with SCU) tended to be lower than those with ureaJ

although at one locction where sorghum was grown followilng wheat with

Table 19

Yields of Basmati-370 and IRRI-6 Rice at Punjab Agricultural Experiment Station in Pakistan in 1973 Under

Conditions of Intermittent Flooding

Rate Yield Source of N Time of Yield (Mtha) Increase of N B-370 IRRI-6 Application Basmati-370 IRRI-6 Average (Mtha)

0 0 - 21 353 287 -

SCU 90 150 At Puddling 325 545 435 148

Urea 90 150 At Puddling 309 500 405 118

AS 90 150 At Puddling 324 529 427 140

SCU 90 150 Puddling 372 572 472 185 Panicle Initiation

Urea 90 150 Puddling 335 502 419 132 Panicle Initiation

AS 90 150 Puddling 353 529 441 154 Panicle Initiation

SCU 90 150 After Transplanting 312 562 437 150 Panicle Initiation

Urea 90 150 After Transplanting 340 624 482 195 Panicle Initiation

AS 90 150 After Transplanting 349 583 466 179 Panicle Initiation

All plots received 45 lbs P205acre as single superphosphate

Relative Yield Increase ()

Source of N At Puddling Puddling Panicle Transplant h Panicle

Urea 100 100 100 AS 119 117 92 SCU 125 140 77

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-48

Therean laiictw that It lbs P to th e am lukis

obosomhu rocks 0entk catetas rth Unrtdo costrat frwt) to

ht tse balt s Owosiv as that to TwP it rocks WM bo

fmtbt alteruutiv to MSso gotastte to~ Ik lee used to

ThUAIAd

Tht wMl dt gotmtmlaoti wout th possibility

of law Vhld free ww e1 e66001 4 It cooUt be YgWd Sutt

a4 10 0410 SWUSSM yt$4e TOP wUd predWr A r~ftIf fl~W t

1f f ot P the wuld phosphae rck TWOe viWMW efocitill b

true to low rttos t tsplusatiI P wi 9 Ma Liiam $S

amp4at r per Wforssota Mav two 64eed Wilk elikor It 44 of

P go Mi er 4A bg oftoP aon of tewmrowtni pboophals fwAh

It vwld be polotrd A Wevero wtht Is the jteld level that

W414 gk tko videm dtterem~j o(A 1 the 4~etamp tk~e~t

P11~0 pra~lpj prefer gre4r tuftlter for whlae

of hoaw ppltrstie Mhe to a dloedveaP for The PINSOO rocka

vkth m r II spotted 10 ftewil 4106Me tem

Nub studios we ovsosd o IVA vol gramleid a

forgof wee aMW pbsepbots A fths pemhawe evsielew us

Odellod to detMlee it otteettvmm of 11agotated Stoture of

mmfp MW phapa A (CI) sed graewletod pampAtlti arlolatod Pa

asowcs of P tof ttde ro The wreem proucts omre raGther

pemour~a ot P syag besmti andMi as elt ov so gpamwhr

iuipiqffhate(TS) low twseeo Is eftwiltve Is thet

W41 preeme wae oialain ire post-rItoi effriq to Stanlato the

pud6itt of Irto paddle Wee ofsdlseireplastiq

0 49 shy

lbs partially scldiaatede grawilated Ml prodlucts Vere isshy

toiwdiats in 5tftOvttWS54 betwee wroiPi ad TVP NotV5Ymf to

me coo were they mere twoe $a a etfective ao TIP 00 sipifleast

LVSUMI5 at0 efecto wore toun tor thee produteo Timely dtIampWde

FR (-t00 mmoh) Uia amp~rally oar affective than Owe gra8448r FOampprodt

featal twos o 6 aotetire s I

Nowvero it to felt that sfortber field euprtet vth

hese interials Amd ether typs of grometatodl Wter nre wrrautad

hater ceeuwodh that they have me areec poteatlal toi additoG

e tate wAne the sectte as OtawrI sed bovoloen turther

euperimeste vth few reck pboophar s0d with reck pbophat treated

to sehesa citrata selmtliy or to ha csaducted

Metbir sertes of tbme enprtaeats wae c~edtmcted by IITA

to Ut~rta copal TVP AOP APP aed it at see tecastisix (table 14)

No dot lalt sewseltles teh draw tree thee results simouely em pear to tlvdl bsww they do stwgpt tbat forthew work with

MR to werramid so tbme sels

Table 24

LttcttF Swce MaPlate 06 ieldot IM AWaia CoelsANS at IITA (Ugboda ad Apoin ail sorit) aid at Ike (AUaba s5i series)

1973

Plate ot IP Apinu 5 poundebods A1ab

Ocrol 0 Z94 419 M)

Tr ipl ruprphite 20 349 3799378

Triple vepput 40 M09 410$

Triple 6wp~~b1 4271 4344 42250

Ammotw-ritpophW to 4201 4124 4040

Amosim-rdop~phlt 40 4270 4106 4231

AM tuo-polpephats 20 404 4244 3794

~eai~mpelppepbuI 400)49 4094

Cee m-pbpbt to- 59

momee eph lto 0 4192

LSO (0 0$) 29 1025

Th WPII

- 51 shy

101Y114 tpeM-fI PEP~tbRP YO

1 ~ ~ gmw 1pc~biofl- 9 Kla4v4h

Upia U04 Copfind am Crehout Stet Rpano at (Ia4

rico t IF t rume6 orth~ Caralto phoophale rocl QAR) vaUN pqU41 to

roopon from cmonetrat4 gsporphophai (CIP) who ort$o4 oil k

was 45j itwas tafertor vb protioo4 oil p war OS Ib 4iffer~c

in rtc reepos to X cod14 oo bo ttrit4 4 4 hvsciag of boil p

~ Pt o r11221 0 tP

c theto the rhimecyllndor of rico tots par to)14M4i1 roeoi~t

ed oil emd PA prior to tho ont of an~robi4 cMioe AA~ oIifoshy

nAte bYpot t taet~d tO fC4sin t~r 4PWden0 Of f Ot(tivshy

ofOWailiJtyno o prefla4 all Put that 4t01etoo 14 tvsIk

of the Ott to prvvld a 014for C4m0 44 mI 1 o4sf

EfftC ftPet141on AIAM-0 V f401td 4 4iv 440 Mtft

Aa torfat VampP f4MWfCi4W04wt0amp to 4eturWlI Ot(Wel~drIC ft

Ot f tM6 the flooded Ott 00 14 04019I Pft0uAw Of gAr~s~lr

pkS$t M40b MP) Tw P1101 Piset Prodwie W-e 10M0di Wr04

(10-1) emW 0aretilp ddw01at4 P WAA firom Rrth M~flRU414~$

wee cowiared with fie Md reWim 44104 proo~fo) foruk oith laWItter

I v te-PR P OW1004 4 4 O Wf ottil OW ellt Oo

Oveiel1 the 40tt dmcruie to effetotww Wtollowui Co fme

PR tpaUIB1I ldoltmo PR (pamwlatr) offr~- ArmeuM) 0 orwi

- 52 -

Effect of N Sourc6 and Water Management on Response of Rice

toe Zn- M Giordano J J Mortvedt OP Engelstad and Greenhouse

Staff Several rotes of CO(14H2)2 and (H )2So4 vith or without ZnO

wore applied to flooded and nonflooded Crowley oil (limed to pH 75)

to determine response of Bluebelle rice to Zn Yields with both N

sources veotrgreator on flooded then on nonflooded soil In the abshy

ence of applied Zn total dry matter production vith CO(NH2)2 was

slightly lower than with (NH)2S04 on flooded soil and considerably

lover on nonflooded soil Concentration of Zn wan higher in straw and

grain of plants roun on flooded than on nonflooded soil Although

concentration of P was unaffected by N source or Zn rate there was

som indication that cranslocation of P from straw to grain may be

depressed in nouflooded rice Concentration of N was lower in straw

grown on flooded than on nonflooded soil due to apparent dilution

thereas both X sources resulted in similar N concentrations in straw

at all rates of N application the N concentration in grain increased

with 0 rAse

feSpongi gf(SM to Chjorospodiostte and Related P Sources--

Si Allen and Greonhoue Staff A greenhouse pot experiment was

couct44d with corn Brown on Hountview silt loam to compare the ofshy

fectlivees of chlorospodiosito (Chlor-l) with concentrated supershy

phosphate (CP) Thomas slag and North Carolina phosphate rock (NC-PR)

Oil-prillad urea-phophato rock (UPI) FeA1JMP 20 7 and monomthyl

phosphate were included in the experiment Based on yield of forage and

uptake of P by tvo crops each of 6-weeks duration the following conshy

stui were dravat

I Chlor-1 was slightly loss effective than CSI Thomas slaS or NC-PR

from which Chlor-l wae prepared

- 53 shy

2 Granular UPR was a poor source of P its effectiveness was greatly

increased by reducing the particle size to -35mesh

3 FeAlNH4P207 was unavailable to the crop

4 Monomethyl phosphate was equivalent toor slightly more effective-

than CSP

Research Indirectly Related to TVA-AID Project

Response of Several Rice Varieties to Zn in Moist or Flooded

Soil--P M Giordano J J Mortvedt and Greenhouse Several varieties

of rice from Mexico and the Dominican Republic currently under investishy

gation in Puerto Rico for adaptation to upland culture were compared with

some established United States varieties with regard to Zn response on

moist and flooded Crowley sil (pH 75) Chontalpa (Mexico) Bluebelle

(Texas) and Starbonnet (Arkansas) were most responsive to applied Zn

Juma (Dominican Republic) intermediate and Sinaloa (Mexico) and Calrose

(California) were the least responsive The Sinaloa varieties (Mexico)

appeared to be best adapted to non-flooded conditions whereas Chontalpa

and Calrose were poorest Concentrations of Zn generally were higher in

plants grown on flooded than moist soil

Pattern of Growth and Zinc Accumulation by Rice--P M Giordano

J J Mortvedt and Greenhouse Staff Rice plants were harvested at weekly

intervals from shortly after emergence through maturity The objective

was to determine the rate of growth and Zn uptake by a Zn responsive varshy

iety (Bluebelle) and a less Zn-responsive variety (Calrose) in the presence

or absence of Zn applied to Crowley sil (pHl 75) Dry matter production

of Calrose was linear with time of growth and of a similar magnitude until

heading with or without applied Zn Bluebelle followed a similar pattern

where Zn was applied However in the absence of applied Zn foliage yield

was reduced markedly

-54

Uptake of Zn was similar for both varieties whenZn was

applied Dry matter production and Zn uptake by the two varieties

also were comparable when Zn was applied However yield of Calrose

was much higher than that of Bluebelle in the absence of applied Zn

while Zn uptake was only slightly higher This suggests that the lesshy

ser responsiveness of Calrose to Zn may be due to more efficient utilishy

zation of Zn There was no indication of a greater demand for Zn durshy

ing reproduction in either variety as was suggested in earlier greenshy

house experiments

Response of Upland Rice to P and Zn--P M Giordano J J

Mortvedt and Greenhouse Staff Several rates of P and Zn were applied

to Crowley sil (limed to pH 75) in factorial combination to determine

whether differences in rice growth under flooded and nonflooded soil

conditions are related to plant nutrition Although straw yields were

slightly higher in nonflooded rice receiving adequate P and Zn grain

yields were higher in the flooded crop increased rates of F andor Zn

did not result in equal yields Except in the highest Zn rate (75 mg)

concentrations of Zn in both straw and grain were higher with flooding

Concentration of P increased with rate of applied P and was higher in

the grain or flooded than upland rice at a comparable P rate In conshy

trast concentrations of N were lower with flooding due in part to dilshy

ution from increased growth

Rice Response to N and P in Flooded and Unflooded Cultures--

G L Terman S E Allen and Greenhouse-Analytical Staff Rates of

N from 250 to 2000 ntpot and P from 0 to 1000 mtpot were applied for

Nato rice grown on Mountview sil and Sango sicl (625 kg of soil per

pot) Market yield response to N and P was obtained Yields of straw

- 55 shy

total yields N uptake and N recovery were higher on unflooded than

on flooded soil cultures Grain yields however were slightly higher

with flooding These results indicate that with adequate applied

nutrients especially of N rice yields without flooding can approach

or even equal those under flooding

Uptake of N P Ca Mg and Zn increased with yield response

to N and P while K uptake decreased on the Mountview soil Concentrations

of N and P increased with applied N and P respectively while concentrations

of other nutrients were diluted in most situations with yield response to N

or P

Results from this experiment show that amouats of N applied in

previous pot experiments for rice have been much too low especially if the

crop was grown to maturity

Response of Corn to S and N i UUASand Urea-S--S E Allen

and Greenhouse Staff Three greenhouse pot experiments were conducted to

measure response to S and N in ulfur coated urea (SCU) urea amonium

sulfate (UAS) and urea -S as well as estimate N losses from surface apshy

plied N sources

In Experiment 260 less than 20 of the S mixed with the soil

was recovered from SCU or urea-S granules by two crops of corn as comshy

pared to 45 or 80 from flowers of S or Na2SO 4 CLop response followed

a similar pattern

In Experiment 260-A N sources were surface applied and alshy

lowed to dry for two weeks before incorporation Into the soil and plantshy

ing Recovery of N by two crops of corn was 77-82 for AN an compared

to 37-70 for urea UAS urea-S and ICU Thus n this experiment loss

of N from urea did not appear to be re~dcud by light S-coatlngn or by Inshy

corporating S or AS in the granules

-S -

I xbprZnSlt a Wtch aU Meyto 0-Ai Wt f9r

higher reermo teOrtOrs cOM reSpWNO i r0100 Of N w

not oaisteontly related to sewe ot N In edl tust 0 ioltiUe Lim

lo in VMuwpped evlmtUTS 48 merind by seirest nte appresOehe

501 for uroa as cwarod to 210 for urea peepha

Rus- or Upse to LoAmIl34I a AriMed bI Earl U

MW NOWlsIIsIr-4 L Toman 5 1 Alln and eesese StNf rio

row on Sawg did (0 tpot) We 1l0l0 Ws feritiud vith 05is

of Npot mixod with the 6011 as aureCA NiAO) 1 Age god At Ures

was also itcluded at rtt t 05 10 end 15 of Upee Theas trealshy

onto were followed 4 wpdrsetago of U s AN wre 4C 10o or at I3n

Weeks toulin up to IS pot

A soil application of 10 pot rosulvod to the maim yield

at 4 weeks Tio4 sad percont prottis t intre raite tncreased rftishy

linearly with U applictalien IeseeItally all at the m iNd wit

the moil w domitrifted after flooding Grail end straw Ilelds vere

highly correlatod with tiliriag and vlh ubers of gralm arl

The results Widicat that 0$ to 10 a of Upot as orea or

NN bsuld be sied with the oil to stilate tiilrir with adshy

ditional 0 topireased later to increase grain lIds mad protia cmshy

tout

DIVISION 54- FERTILIZER TECHNOLOGY AND USE

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-02

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DIVISION 8-9-SOIL MINERALOGY

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65

0IL CL OC AMXR PROC VOL 38 1974

)aT1 S4I104 ow Lusanll Tawng isa tall Thai variety known for beingIwo nonshyi s s ) sensitive to photoperiod A split-plot design was used in

S e e these euperimeots with 4 rates of P (I1 22 44 and 88t i V IV k of Pha) applied a main plot treatments and with the OF It sourMes of P as subplot treatments There were two checkS plots in each rmplicate The extra check plot was included to permit the application of fresh TSP standard Jor the

It- ti 06 + i bull fa succeeding crop the p-4me of bi was to permit accurate d awrnwal of the mdual effectiveness of the phosphate

ftinSUbI rock The P fertilioers were broadcast on the mud andthen Worporald In the soil during the last harrowing At

whM N both On ACS indx ampM time of transplanting Immediately before the last harrow61t (4j 5 4 01 P s 3Mm o Vallonal in con n 100 kgha of N as ammonium sulfate and 33 kghaWO Of Spews ampm lIW thaabe rocks do ACS indes of K as polium chloride were applied A total of 40 wa in prepw O do ctih k otent kha of N a ammoniunt sulfate was applied later in twoir P The hew oNed amp wM W for 5 of gw topdrossingp with about 5cm depth of water on the plotsvV I aiOMveffeOctveee Three to six ldayold selings pr hillwW the ACS idex were planted00OWW wia Oft fo an c irNk I p Coen 20 by 20 cm part in straight rows Hand weeding was used

and insecticide were applied for Insect control Grain yieldw was masared by sampling 5 ml of each plot excluding border rows The date of heading in each treatment and theUNiN d pbM W Weks rin tOW USA UMe In Tale yed componnts at hafvel were also recorded

I filM rsperMS esOM kdwdua 1 t ab The average yields of ough (unhulled) rice for botha 84 OW O 8uo 4 Thala TM was a locations are ploutel in PIS 3 for the first crop (1969 wet

owou thRM seaso0) The Veamps yield response was obtained at Klonge (s) W lDtO t Of dMa of1tw W d l R Luang however a 4ute satisfactory yield response was

~Mk ^d TVA UJSD ad Kd UnIveS obtalned to applied P at Bangkhen as wellXUe LaM e R qwrw Ims The sod was do Relative aponomlAe effectiveness values were calculated

VOW (a ksA w edmwL t Poesesm h Vy for these data and am presented In Table 3 The valuesdAY buo if dIe ouh ne Pee wtk a Mlak vow 1009 for th first crop are plotled against ACS index in Fig 41 This Im M i6ti l 4bNd IO a0 O mkarnk for both locatio r relationship was linear for the

11400 ThCpH 0( lb pW IW 01 th UpeiaW so Sanodion location and curtiltnear for KIng Luang The was u i 4A sksamp lMaor nrusio model amparounted for 81 of theAmO$MI Aw jAAsue Swim T1 Snh Wd variation In the AE valu for Bantkhen a square root

Mems a Iw iv fern alh$ sedm haowg dayNW W t he plAL At tdo M tM aso W s as ctminued throufh eltaM t Ofpof -le lse wo am P OeNI VeOpls 1o ealluae tI lon4erm MIdual Offccls

A on W isset i a wse to hsh eapeel of these ooihss t ocks The baagkhon experimnent was letmiaI1DlVemisthis is a w hulu Lo g Tasug ia iasael aft - Msd residual Ves will be pr-Om crok TheseTwod esewm

SWWo

A

lP~U~7 ISIIPe1iuIWN e bsedisssin ian ghth siaoelalbe

984 0 6 O O - M s -s fWPas 11eSft W d Uo al a o

o

S4l~ lIIII I~l I 1f fl

( +

+ + + m + ++++-

++ +(++ + ++++ + ++ ++

- 66 -

ENOIMLSTAD ET AL RESPONSE BY FLOODED RICE TO PHOSPHATE ROCKS VARYING IN CITRATE SOLUBILITY

I I I I j0 I I

BANOKHEN BANGKHEN

pH 56 6 - 0o

TSP

NC

5~ ~ ~ L o 4 - -shy

4 ] - --------shy04

6S

|0 III 2 44 8r 66

I I I

a 1KLONG LUANG

pH 46 z KLONG LUANG

TSP Sc2 NCFL(N)

5 FLIC) J0 TU

oshy

4 ~40shy

3 bull eM0

I - I I I I I

0 II 22 44 88 0 5 10 15 20 IP APPLIED KO HA ABSOLUTE CITRAE SOLUBIITY INDEX

Fig 3-Yield of rough rice at Klong Luang and Bangkhen Rice Fig 4-Relative agronon effectiveness () of P sources ploz-Experiment Stations Thalmand as affected by rate and Source ted against citrate solubity Index for both Thailand field ex

of P applied (crop 1) periment (first crop only)

regression model accounted for 97 of the variation in sumably resulted from crop uptake and reaction with the RAE values at the Klong Luang location soil to form less soluble products Such effects may have

These experiments were continued during the dry season been more important at the lower rates since the two TSP of early 1970 to ascertain the residual effectiveness of the curyes converged at the highest rate of application various sources applied to the first crop No new P was These data from KIong Luang indicate that (i) residual applied except for the fresh TSP standard mentioned effects of all rocks except Mlcwuri were substantial (ii) above rhe experiment otherwise was conducted in a man the relationship between relative agronornic effectiveness ner similar to that followed in the first crop of the phosphate rocks and citrate solubility levels was

The response to both freshly applied ad residual P was largely obscured and (iii) the general superiority of TSP marked at the Klong Luang location and marginal at over phosphate rock in terms of effectiveiss persisted Bangkhen In fact at the latter location the response was through the second crop so small that little can be said regarding residual effectiveshyness The yield data from crop 2 at the Klong Luang DISCUSSION experiment are plotted in Fig 5 Greenhouse and field data presented in this paper show

Relative agronomic effectiveness values (Table 3) were clearly that there are substantial differences among phosshycalculated for the Klong Luang data using both the residual and freshly applied TSP as standards It is of Interest to note that the superiority of TSP over the phosphbte rocks Table 3-Relative agronomic effective values for field experishyments in Thailand persisted through the second crop The main difference in KlowlZmlnql~the residual effects is that with the exception of the MIs- s Crop 1 Crop 21 Crop 1-shysouri rock Ihe marked relationship between citratr-soluble WoiCarolina yl 59 76

phosphate rocks and RAE had largely rds norh) a 64P conltct of th Florida (eqlral is 6969 6

disapipeared In this acidic soil (pHi 46) P would by this I14o 69 63 40 ToonesS 31 65

limo be supplied by Intermediate reaction products In addl Missou 0 o lion to residues of the initial spatlte Ts P o 2 o 0

The TSP applied to the first crop declliv-d slightly In campIafcmWataesr e id ofeuhuloefor 22MA rates of PtColeouattd as aba u tlte td18 kS ratesp dlverage yield tM868 to 22 44

effectiveness relative to the freshly applied ISP This pre- of d s4

A

4

- 67 shy

-SOIL SCL SOC AMER I

KLONG LUANG CROP 2

Si 3

eN

TAPPLIEDKGHA

Fig 5-The residual effectiveness ovarious P sources for crop s compared with freshly applied TSP Klong Luang Rice

Experiment Station Thailand

phate rocks in terms of agronomic effectiveness for flooded

rice Further these differences can be predicted by means of citrate solubility or by the ACS index It appears that

the latter is more appropriate where the content of apatite varies among phospiate rocks The most soluble phosphate rocks approached but did not actually equal TSP in limit-iuig (maximum) yield in these experiments regardless of rate applied This agrees with the results of Ensminger Pearson and Armiger (4) One needs to consider the defi-nite posribility of same yield loss in zhoosing a phosphate

rock over TSP such yield losses must be weighed against the lower price of phosphate rock The explanation for such iosses may involve concentration of soluble P in the soil Khasawneh and Copeland (6) suggest that the growth rate of crop plants is a function of P concentration that can be maintained in the soil solution If P concentration is limiting or inadequate becawe of a lower dissolution rate of phosphate rock the growth iate ard uiiimate yield will be diminished accordingly

The RAE values bascd on yield increases reflect the agronomi effectiveness of these various sources relacve

to the TSP standard however these nould be supple-

mented by an economic analysis before rational choice can

be made The following calculations will provide an estimate of

the rclativ ecooomic effectiveness(REE)

Y t Ps aXpatREE -- 100

vahtercks t sphate or e b i- eor

Price of TSPkg fo

be Price of PRkg P

PROC VOL 38 1974 leO

90r

Wsoshy

0

60-LUSEPHOSPHATE ROCK

00 10 20

PTP PR

Fig 6-Relationship between relaZive effectiveness values (RAE) and the price ratios between TSP and phosphate rock Such a figure can be used in making a choice between these

sources

If REE exceeds 100 in this calculation the phosphate rock would be preferable to TSP

The REE calcuktaaa wre used in preparing an indifshyference curve (Fig 6) wherein RAE values are plotted

against PTsPPpR ratios The cu~rve itself connects those points at which REE equals 100 When exactly on the curve it makes no real economic difference what source is chosen After choosing a suitable price ratio one can then project upward from that ratio knowing the RAI

value (or estimating it from such data as shown in Fig 4 using citrate-soluble P content) one can then choose the source on the basis of both agronomic and economic conshysiderations For example if the price ratio is 25 and the RAE value of the phosphaite rock is greater than 40 the rock phosphate in question would be used However if the RAE value was less than 40 TSP would be a better choice There are indications that if the P in the more soluble phosphate ro~cks (North Carolina north Florida central Forida) is less than half as expensivz as that in TSP these rocks would be feasible altereaives to TSP on soils similar

to thoseused in Thailand This analysis does not take into account the possibility

of lower yields from use of phosphate rock In addition only a portion of the various yield response curves was used in this anlysis ie up to 22 kgha Beyond this

rate yield response was much less pronounced it could be argued that at less than maximum yields TSP would produce a certain yield at lower rates of P than would phosshy

pow ofrock This would especially be true for rates applioa example at Klong Luang 5500 kg of

rice pcr iectare could have been produced with either Ii kg of P as TSP or 44 kg of P as son of the more reacshy

tire phosphate rocks It should be pointed ot however

- 68 shy

(IIKIS amp YOUN( ARIFICIAL WEATIIERING OF OXIDIZED p[ll- IV

that this is the yield level that would show the widest difference such is the advantage of hindsight

Farmers generally prefer granular fertilizers for machine

or hand application This is a disadvantage for the phos-phate rocks which are normally arplied in finely divided form Recently experimental quantities of granular urea-

phosphate rock mixtures have been made by TVA Results of trials with these fertilizers will be reported elsewhere

LITERATURE CITED

1 Armiger W H and Maurice- Fried 1957 The plantavailability of various sources of phosphate rock Soil Sci Soc Amer Proc 21183-188

2 Bengston G W E C Sample and S E Allen 1974 Re-sponso of slash pine seedlings to P sGurces of varying ci-trato solubility Plant Soil (In press)

3 Caro JIt and W Hill 1956 Chard eristics and fer tilizcr value of phosphate rock from different fields J Agr Food Chem 4684-687

4 Ensminger I E R W Peirson and W II Atmiger1967 Effectivencs of rock phosphate as a source of phosshyphurus for plants US Dep Agr ARS Bull 4112S

5 Engelstad 0 P J G Getsinger anid I J Stangel 1972 Tailoring of fertiliers for rice cnnece Valley Author ftyNational Fertilicr Developmnent Center Hull Y-52

6 Khasawnch F E and Jane P Copcland 1971 (otton root growth and uptake of nutrievos relation oif phosph

rus uptake to quantity intensity and buffering capacit) Soil Sci Soc Amer Proc 37250-254

7 Lehr JR and G H McClellan 1972 A revised lIbora tory reactivity scale for evaljativg phosphate rocks for direct application Tennessee Valley Authcrity National Fertilizer Development Center lull Y-43

H Terman G L S EAllen and 0 P Engelstad 1970 Response by paddy cice to ratcs and suurces of appliedphosphorus Agron J63390-394

DIVISION S-9-SOIL MINERALOGY

Artificial Weathering of Oxidized Biotite IV The Inhibitory Effect of Potassium on Dissolution llate

R JGILKES AND R C YOUNG2

ABSTRACT

Rates of dissolution of oxidized biotites in OIM 001M ICI are severely depressed in the presence of IM KCI The amovnts of Al Mg Mn dissolved in the first eytraction are similir to those found without KCI however subsequent extractions remove these elements at 10-20 of the corresponding lICI rates This effect may be due to a decreased rate of vermiculite formation thereby reducing the effective basal area exposed to attack A decrease in dissolution rate with increasing ferric iron content was still apparent in the presence of IM KCI

Additional Index Words X-ray diffraction infrared aborp-

N EARLIER papers of this series the tole of biotite in soils

as a source of both macro and micronutrient elements

has been discussed ((Gilkes Young and Quirk 1972 1973ab) Experiments in artificial weathering uiing as va-

riety of extractants were undertaken to determiie the inlu-

ence of oxidation of octahedrally coordinated iron on the bull release of structural cations to solution The results of this

work demonstated that biotite behaves anomalously with respect to the other common ferromagnesian minerals found in soils Oxidation leads to the development of a high degree of resistance to cation exchange and dissolution Several authors have coiwludcd that decreased rates of K

Contribution from the Dep of Soi Science and Plant Nutri-tion Institute of Agriculture Univ of Western Australia Ned-lands 6009 Western Australia Received 29 Sept 1973 Ap-proved 8 Jan 1974

2 Senior Lecturer in Soil Science and Research Officer respeclively

replacement in electrolytes shown by oxidized biotites are

a result of the inclination of structural hydroxyl adjacent to newly created trivalent iron or vacant octahedral cation sites (Robert and Pedro 1959 Barshad and Kishk 1968) Gilkes et al (1973b) suggested that decreased rates of disshysolution of oxidized biotite in 0001 0t)l 0Af CI may also be due to the presence of inclined hydroxyl In this case a smaller surface area external and exposed intershylayer may be available for attack if K replacement by hyshydrogen ions occurs at a slower rate in oxidized biotites

Gastuche (1963) has shown that significant dissolution ofthe (IIM) biotile face may occur and it is easily demonshystrated that the proportion of exposed (001M) face in weathering biotites depends on the percentage K replaced

Rausell-Colom ct al (1965) have shown that hydrogen ions act in an identical fashion to metal cations in K exshy

change from micas In particular exchange c-f K by hydroshy

gen ions will be terminated or greatly reduced by high levels of K in solution Thus if dissolution of oxidized biotite by

acids is carried out at sufficiently high K levels to prevent vermiculization any differences in dissolution rate that may occur cannot simply be ascribed to differences in rates of K replacement The following results were obtained from such an experiment which unlike the experiment described in Parts I and II (Gilkes et al 1973ab) does not attempt to simulate natuiral - conditions

MATERIAILS AN) M HIiODS Further subsamples of the less than 0 hiotites used in K

excherandbaid disoo tu es (G iles e9n K exchange and acid dissolution studies (Gilkes et al1973ab) were used in these experiments Preparation of sequentiallyoxidized biotites without intermediate vermiculite formation is

Page 31: I70 - United States Agency for International Developmentto ascertan, but tgl.eetad, 1, L,. ("Tailoring of Pertiltiters for ice,'" TVA ulletin Y-52) states that the staft of IOi has

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4of O 149 6MID O 41110

KthD 00

- 38 -

Table 18

Yild of aemati-370 Rice at Punjab Agricultural Research

Institute in Pakistan in 1969-70 Grown Under

Couditions of Intermittent Flooding

Pate of application

=IL

o 0 67 67 100 100 67 67

100 100 67 67 200 100

Average for Sources

Ntha

AS 260 gres 279

320

Source f5

-

AS AS Ura Urea SCU SCU

Yield

Relative

93 100 115

(M)O

Yield

Increase Yield Due to N

(Ktlha) (mtha)

-212 245 033 274 062 260 048 297 085 315 103 325 112

Yield Increase

Relative

72048 067 100 108 161

(2)

- 39 shy

Short-statured high yielding rice varieties grown extenshy

sively in northern Peru require extremely high rates of conventional

N sources to achieve maximum yields The recovery of applied N is

extremely low due to the use of intermittent flooding This water

management system results in heavy N losses even with properly timed

split applications In search of simpler and more effective methods

of N management eight field experiments were conducted in the region

to evaluate sulfur-coated urea (SCU) an experimental slow-release N

source supplied by the Tennessee Valley Authority Rice yields were

increased an average of 59 more by pretransplant-incorporated SCU than

by urea or ammonium sulfate applied in the same manner SCU produced

excessive vegetative growth which resulted in yield reductions at high

N rates

Regardless of an assumed 48-higher unit N cost in SCU the

overall benefits of pretransplant-incorporated applications of SCU

were favorable since there was a decrease of 40 in the optimum rate

of N and the need for precise timing of application was eliminated

Pakistan--In Pakistan basal applications of AS urea and

SCU to rice grown under conditions of intermittent flooding in 1969-70

(table 18) indicate that SCU is a superior source of N as compared to

urea or AS when all N is applied at or before planting The data also

indicate that a yield response was obtained for P applications but a

comparison of N sources at each level of P indicates that no interaction

between N and P was present so that differences between N sources were

relatively the same at each level of P Yields were increased about 60

more when SCU was applied than when urea was applied Yield increases

with AS were only about 72 of the increase obtained with urea these reshy

sults do not agree with the generally-reported superiority of AS as comshy

pared to urea as a source of N for rice

- 40 -

In 1973 experiments were conducted in Pakistan using both

Basmati-370 and IRRI-6 varieties of rice grown under conditions of

When all N was applied at puddlingintermittent flooding (table 19)

or 12 at puddling and 12 at panicle initiation both AS and SCU were

superior to urea with SCU tending to be the most efficient source

However when N was applied 12 at transplanting and 12 at panicle

initiation SCU was the poorest source of N This would indicate that

the release of N from SCU applied at these times is too slow for optimwn

plant growth

In another experiment in Pakistan in 1973 no differences

in the effectiveness of urea AS or SCU were noted in the yields of

continuously-flooded rice (table 20) Again these results are conshy

sistent with earlier results which indicate no superiority for SCU

when rice is continuously flooded

Nitrogen Studies--Maize

A series of three experiments were conducted by IITA in

armo-Nigeria in 1972-73 comparing AS urea SCU and

CAN (calcium

nium nitrate) as sources of N for maize (table 21) A significant

yield response was obtained for N at each location but no conaistent

differences were noted amaong sources These results are consistent

with results at other locations which have not shown that SCU is a

superior source of N for maize grown over a period of 3 to 4 months

Nitrogen--Wheat

The yields of wheat in Pakistan in 1969-70 (tables 22 and

23) show that yields with SCU) tended to be lower than those with ureaJ

although at one locction where sorghum was grown followilng wheat with

Table 19

Yields of Basmati-370 and IRRI-6 Rice at Punjab Agricultural Experiment Station in Pakistan in 1973 Under

Conditions of Intermittent Flooding

Rate Yield Source of N Time of Yield (Mtha) Increase of N B-370 IRRI-6 Application Basmati-370 IRRI-6 Average (Mtha)

0 0 - 21 353 287 -

SCU 90 150 At Puddling 325 545 435 148

Urea 90 150 At Puddling 309 500 405 118

AS 90 150 At Puddling 324 529 427 140

SCU 90 150 Puddling 372 572 472 185 Panicle Initiation

Urea 90 150 Puddling 335 502 419 132 Panicle Initiation

AS 90 150 Puddling 353 529 441 154 Panicle Initiation

SCU 90 150 After Transplanting 312 562 437 150 Panicle Initiation

Urea 90 150 After Transplanting 340 624 482 195 Panicle Initiation

AS 90 150 After Transplanting 349 583 466 179 Panicle Initiation

All plots received 45 lbs P205acre as single superphosphate

Relative Yield Increase ()

Source of N At Puddling Puddling Panicle Transplant h Panicle

Urea 100 100 100 AS 119 117 92 SCU 125 140 77

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-48

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ht tse balt s Owosiv as that to TwP it rocks WM bo

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ThUAIAd

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P11~0 pra~lpj prefer gre4r tuftlter for whlae

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asowcs of P tof ttde ro The wreem proucts omre raGther

pemour~a ot P syag besmti andMi as elt ov so gpamwhr

iuipiqffhate(TS) low twseeo Is eftwiltve Is thet

W41 preeme wae oialain ire post-rItoi effriq to Stanlato the

pud6itt of Irto paddle Wee ofsdlseireplastiq

0 49 shy

lbs partially scldiaatede grawilated Ml prodlucts Vere isshy

toiwdiats in 5tftOvttWS54 betwee wroiPi ad TVP NotV5Ymf to

me coo were they mere twoe $a a etfective ao TIP 00 sipifleast

LVSUMI5 at0 efecto wore toun tor thee produteo Timely dtIampWde

FR (-t00 mmoh) Uia amp~rally oar affective than Owe gra8448r FOampprodt

featal twos o 6 aotetire s I

Nowvero it to felt that sfortber field euprtet vth

hese interials Amd ether typs of grometatodl Wter nre wrrautad

hater ceeuwodh that they have me areec poteatlal toi additoG

e tate wAne the sectte as OtawrI sed bovoloen turther

euperimeste vth few reck pboophar s0d with reck pbophat treated

to sehesa citrata selmtliy or to ha csaducted

Metbir sertes of tbme enprtaeats wae c~edtmcted by IITA

to Ut~rta copal TVP AOP APP aed it at see tecastisix (table 14)

No dot lalt sewseltles teh draw tree thee results simouely em pear to tlvdl bsww they do stwgpt tbat forthew work with

MR to werramid so tbme sels

Table 24

LttcttF Swce MaPlate 06 ieldot IM AWaia CoelsANS at IITA (Ugboda ad Apoin ail sorit) aid at Ike (AUaba s5i series)

1973

Plate ot IP Apinu 5 poundebods A1ab

Ocrol 0 Z94 419 M)

Tr ipl ruprphite 20 349 3799378

Triple vepput 40 M09 410$

Triple 6wp~~b1 4271 4344 42250

Ammotw-ritpophW to 4201 4124 4040

Amosim-rdop~phlt 40 4270 4106 4231

AM tuo-polpephats 20 404 4244 3794

~eai~mpelppepbuI 400)49 4094

Cee m-pbpbt to- 59

momee eph lto 0 4192

LSO (0 0$) 29 1025

Th WPII

- 51 shy

101Y114 tpeM-fI PEP~tbRP YO

1 ~ ~ gmw 1pc~biofl- 9 Kla4v4h

Upia U04 Copfind am Crehout Stet Rpano at (Ia4

rico t IF t rume6 orth~ Caralto phoophale rocl QAR) vaUN pqU41 to

roopon from cmonetrat4 gsporphophai (CIP) who ort$o4 oil k

was 45j itwas tafertor vb protioo4 oil p war OS Ib 4iffer~c

in rtc reepos to X cod14 oo bo ttrit4 4 4 hvsciag of boil p

~ Pt o r11221 0 tP

c theto the rhimecyllndor of rico tots par to)14M4i1 roeoi~t

ed oil emd PA prior to tho ont of an~robi4 cMioe AA~ oIifoshy

nAte bYpot t taet~d tO fC4sin t~r 4PWden0 Of f Ot(tivshy

ofOWailiJtyno o prefla4 all Put that 4t01etoo 14 tvsIk

of the Ott to prvvld a 014for C4m0 44 mI 1 o4sf

EfftC ftPet141on AIAM-0 V f401td 4 4iv 440 Mtft

Aa torfat VampP f4MWfCi4W04wt0amp to 4eturWlI Ot(Wel~drIC ft

Ot f tM6 the flooded Ott 00 14 04019I Pft0uAw Of gAr~s~lr

pkS$t M40b MP) Tw P1101 Piset Prodwie W-e 10M0di Wr04

(10-1) emW 0aretilp ddw01at4 P WAA firom Rrth M~flRU414~$

wee cowiared with fie Md reWim 44104 proo~fo) foruk oith laWItter

I v te-PR P OW1004 4 4 O Wf ottil OW ellt Oo

Oveiel1 the 40tt dmcruie to effetotww Wtollowui Co fme

PR tpaUIB1I ldoltmo PR (pamwlatr) offr~- ArmeuM) 0 orwi

- 52 -

Effect of N Sourc6 and Water Management on Response of Rice

toe Zn- M Giordano J J Mortvedt OP Engelstad and Greenhouse

Staff Several rotes of CO(14H2)2 and (H )2So4 vith or without ZnO

wore applied to flooded and nonflooded Crowley oil (limed to pH 75)

to determine response of Bluebelle rice to Zn Yields with both N

sources veotrgreator on flooded then on nonflooded soil In the abshy

ence of applied Zn total dry matter production vith CO(NH2)2 was

slightly lower than with (NH)2S04 on flooded soil and considerably

lover on nonflooded soil Concentration of Zn wan higher in straw and

grain of plants roun on flooded than on nonflooded soil Although

concentration of P was unaffected by N source or Zn rate there was

som indication that cranslocation of P from straw to grain may be

depressed in nouflooded rice Concentration of N was lower in straw

grown on flooded than on nonflooded soil due to apparent dilution

thereas both X sources resulted in similar N concentrations in straw

at all rates of N application the N concentration in grain increased

with 0 rAse

feSpongi gf(SM to Chjorospodiostte and Related P Sources--

Si Allen and Greonhoue Staff A greenhouse pot experiment was

couct44d with corn Brown on Hountview silt loam to compare the ofshy

fectlivees of chlorospodiosito (Chlor-l) with concentrated supershy

phosphate (CP) Thomas slag and North Carolina phosphate rock (NC-PR)

Oil-prillad urea-phophato rock (UPI) FeA1JMP 20 7 and monomthyl

phosphate were included in the experiment Based on yield of forage and

uptake of P by tvo crops each of 6-weeks duration the following conshy

stui were dravat

I Chlor-1 was slightly loss effective than CSI Thomas slaS or NC-PR

from which Chlor-l wae prepared

- 53 shy

2 Granular UPR was a poor source of P its effectiveness was greatly

increased by reducing the particle size to -35mesh

3 FeAlNH4P207 was unavailable to the crop

4 Monomethyl phosphate was equivalent toor slightly more effective-

than CSP

Research Indirectly Related to TVA-AID Project

Response of Several Rice Varieties to Zn in Moist or Flooded

Soil--P M Giordano J J Mortvedt and Greenhouse Several varieties

of rice from Mexico and the Dominican Republic currently under investishy

gation in Puerto Rico for adaptation to upland culture were compared with

some established United States varieties with regard to Zn response on

moist and flooded Crowley sil (pH 75) Chontalpa (Mexico) Bluebelle

(Texas) and Starbonnet (Arkansas) were most responsive to applied Zn

Juma (Dominican Republic) intermediate and Sinaloa (Mexico) and Calrose

(California) were the least responsive The Sinaloa varieties (Mexico)

appeared to be best adapted to non-flooded conditions whereas Chontalpa

and Calrose were poorest Concentrations of Zn generally were higher in

plants grown on flooded than moist soil

Pattern of Growth and Zinc Accumulation by Rice--P M Giordano

J J Mortvedt and Greenhouse Staff Rice plants were harvested at weekly

intervals from shortly after emergence through maturity The objective

was to determine the rate of growth and Zn uptake by a Zn responsive varshy

iety (Bluebelle) and a less Zn-responsive variety (Calrose) in the presence

or absence of Zn applied to Crowley sil (pHl 75) Dry matter production

of Calrose was linear with time of growth and of a similar magnitude until

heading with or without applied Zn Bluebelle followed a similar pattern

where Zn was applied However in the absence of applied Zn foliage yield

was reduced markedly

-54

Uptake of Zn was similar for both varieties whenZn was

applied Dry matter production and Zn uptake by the two varieties

also were comparable when Zn was applied However yield of Calrose

was much higher than that of Bluebelle in the absence of applied Zn

while Zn uptake was only slightly higher This suggests that the lesshy

ser responsiveness of Calrose to Zn may be due to more efficient utilishy

zation of Zn There was no indication of a greater demand for Zn durshy

ing reproduction in either variety as was suggested in earlier greenshy

house experiments

Response of Upland Rice to P and Zn--P M Giordano J J

Mortvedt and Greenhouse Staff Several rates of P and Zn were applied

to Crowley sil (limed to pH 75) in factorial combination to determine

whether differences in rice growth under flooded and nonflooded soil

conditions are related to plant nutrition Although straw yields were

slightly higher in nonflooded rice receiving adequate P and Zn grain

yields were higher in the flooded crop increased rates of F andor Zn

did not result in equal yields Except in the highest Zn rate (75 mg)

concentrations of Zn in both straw and grain were higher with flooding

Concentration of P increased with rate of applied P and was higher in

the grain or flooded than upland rice at a comparable P rate In conshy

trast concentrations of N were lower with flooding due in part to dilshy

ution from increased growth

Rice Response to N and P in Flooded and Unflooded Cultures--

G L Terman S E Allen and Greenhouse-Analytical Staff Rates of

N from 250 to 2000 ntpot and P from 0 to 1000 mtpot were applied for

Nato rice grown on Mountview sil and Sango sicl (625 kg of soil per

pot) Market yield response to N and P was obtained Yields of straw

- 55 shy

total yields N uptake and N recovery were higher on unflooded than

on flooded soil cultures Grain yields however were slightly higher

with flooding These results indicate that with adequate applied

nutrients especially of N rice yields without flooding can approach

or even equal those under flooding

Uptake of N P Ca Mg and Zn increased with yield response

to N and P while K uptake decreased on the Mountview soil Concentrations

of N and P increased with applied N and P respectively while concentrations

of other nutrients were diluted in most situations with yield response to N

or P

Results from this experiment show that amouats of N applied in

previous pot experiments for rice have been much too low especially if the

crop was grown to maturity

Response of Corn to S and N i UUASand Urea-S--S E Allen

and Greenhouse Staff Three greenhouse pot experiments were conducted to

measure response to S and N in ulfur coated urea (SCU) urea amonium

sulfate (UAS) and urea -S as well as estimate N losses from surface apshy

plied N sources

In Experiment 260 less than 20 of the S mixed with the soil

was recovered from SCU or urea-S granules by two crops of corn as comshy

pared to 45 or 80 from flowers of S or Na2SO 4 CLop response followed

a similar pattern

In Experiment 260-A N sources were surface applied and alshy

lowed to dry for two weeks before incorporation Into the soil and plantshy

ing Recovery of N by two crops of corn was 77-82 for AN an compared

to 37-70 for urea UAS urea-S and ICU Thus n this experiment loss

of N from urea did not appear to be re~dcud by light S-coatlngn or by Inshy

corporating S or AS in the granules

-S -

I xbprZnSlt a Wtch aU Meyto 0-Ai Wt f9r

higher reermo teOrtOrs cOM reSpWNO i r0100 Of N w

not oaisteontly related to sewe ot N In edl tust 0 ioltiUe Lim

lo in VMuwpped evlmtUTS 48 merind by seirest nte appresOehe

501 for uroa as cwarod to 210 for urea peepha

Rus- or Upse to LoAmIl34I a AriMed bI Earl U

MW NOWlsIIsIr-4 L Toman 5 1 Alln and eesese StNf rio

row on Sawg did (0 tpot) We 1l0l0 Ws feritiud vith 05is

of Npot mixod with the 6011 as aureCA NiAO) 1 Age god At Ures

was also itcluded at rtt t 05 10 end 15 of Upee Theas trealshy

onto were followed 4 wpdrsetago of U s AN wre 4C 10o or at I3n

Weeks toulin up to IS pot

A soil application of 10 pot rosulvod to the maim yield

at 4 weeks Tio4 sad percont prottis t intre raite tncreased rftishy

linearly with U applictalien IeseeItally all at the m iNd wit

the moil w domitrifted after flooding Grail end straw Ilelds vere

highly correlatod with tiliriag and vlh ubers of gralm arl

The results Widicat that 0$ to 10 a of Upot as orea or

NN bsuld be sied with the oil to stilate tiilrir with adshy

ditional 0 topireased later to increase grain lIds mad protia cmshy

tout

DIVISION 54- FERTILIZER TECHNOLOGY AND USE

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v doese a WKWye Is ks Nha m 6 sa4to dafo aONmuw The appee swm Wsssof adde N4 alalaed by vuMb ifaa W C Was sekilumganSro Is

bs eabI wish as aVWWa uwewy nap (f5s)f ad Mashes reaMeY valaes of 48 0 S414 CWm

owdb imto US Wh s vs sf 3I mld 54S fro 2 aMd 3) A A

valves a hevwae u Iar Walh basl oswas dhe uwpatr bshava of

tb~msusasl appkausu of ofta sede s have aoweN

TOW opl taoe for AieweeW 4OsmWMbas Op peas As Tabl 4 sling sob Os awowully eom grams Piel level Thes oeulam Ma sed as IM

-02

792 60L WI W A)49R Pio VOL 37 197)

primS o r OeampAd WU toa Them fl~ w At NOSSe earno maisslea Ia N he mOWamplIO yik ampWd IMe aampWmW OWa Owe wa UMs of KU to 41 Oke ampWiiIamm be dkrnety ewspokawleM(a s8 te camtd wie a eapmoe by TVA pavw ltoi NA poundrmdaka4us vrimeW460 o to ilkidm ofWW (Mtemas MuOwe 1973) TVA mwi bawld on soi ficedims IampWp seg rudwiv s~s0abet ke WNmdoe ON 01 K Is12 NOSW ie fssewnmu Ie I QvaaIi rowp IMA) f9

)amp m lodk byO voebmsaIS8OpeaWfrats 11 OWNmi a I a W idisod 0 81 Now 111 nindat Wm fysmpseaamp (If tsO tUmtI IsM $P shoroV4mmo knflkvnf (foOdme nuw ae Ow OImstwe in SM pnmm8 af tXm 10 114PIS kequoian wo Mpfii

SC~po umd spop~o VWt alm 4emWal 1 4ink PCmirsra M 1 ad AI 14bmms

1MM Ww Even to doe shw wisht b-o -Wamp Ekb fed rbaimpal of14~ Am Smpound oS mv fAaMda

MGMe -M4 Wg kmuwadM 1Wr wih SCV4 Psmuck Wff It dlL Wm 1W led 0 1 oo teeA of aiwaisme aweeoid h

1Kach Vt V amp4W ILK t)sa 10 Nareps vm This ndY ub thee hbow apiptomuasa of gulfu-aw~sd of Cup lP~~tamsl wi(i

Woeo of woo or mlm Wmiot InIasem~Wsy (heede 6Am 0 F- ad PAicv IfM tsoPm 9W famp kw~is 04eet The r4 ggm I ampbpiIs OnwAu 4nvmkstm v PAraem A4fshy

e W d inSIWfh sil $ad doke IaefitV twoer) 1 Te to theo owie effu so booJ imik WOi 100 N

-d

Is re4aled uIwq~e~w Aueee atofurnw di Capsnm ptopeatls is a oommm eiws to 100 tom of 04404man d CtdUW 4M Anw K~a do Aamp apowee WPUaN powu eel H pae iaaa thAi SCUI isWW owr hmem ISsuppl N to the li ieee F A IM1 Nampa Obo~amie m

41MB ~ ~ m ~ ~0 0-- 0 140 The ffsemn of food Nn else9~e(Ud~ ~ ~ ~~ WooksaS eAWw pjed of ho~raw of IU effadam vfdva oft xhj0I 13iAl

DIVISION 8-9-SOIL MINERALOGY

Amorphomw CeetIup en XmWra Ssrfmls

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of~U -a~ mo uNo

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arbs awasm 00 iztv Am-~~~i u5~ms ashu is byw

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amppowftdmi TiM 0 Tie OAA mo p)a Mwomoi dOn4m A)w

MW 0 604 0M mm yaM 01MWOfdi to tA0 M OOAW uinw OSOb

ap is~e I the ampo A A Mwof ~Do toit op aenu w~ifiOimem~ MAN ampW)

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~ -0

65

0IL CL OC AMXR PROC VOL 38 1974

)aT1 S4I104 ow Lusanll Tawng isa tall Thai variety known for beingIwo nonshyi s s ) sensitive to photoperiod A split-plot design was used in

S e e these euperimeots with 4 rates of P (I1 22 44 and 88t i V IV k of Pha) applied a main plot treatments and with the OF It sourMes of P as subplot treatments There were two checkS plots in each rmplicate The extra check plot was included to permit the application of fresh TSP standard Jor the

It- ti 06 + i bull fa succeeding crop the p-4me of bi was to permit accurate d awrnwal of the mdual effectiveness of the phosphate

ftinSUbI rock The P fertilioers were broadcast on the mud andthen Worporald In the soil during the last harrowing At

whM N both On ACS indx ampM time of transplanting Immediately before the last harrow61t (4j 5 4 01 P s 3Mm o Vallonal in con n 100 kgha of N as ammonium sulfate and 33 kghaWO Of Spews ampm lIW thaabe rocks do ACS indes of K as polium chloride were applied A total of 40 wa in prepw O do ctih k otent kha of N a ammoniunt sulfate was applied later in twoir P The hew oNed amp wM W for 5 of gw topdrossingp with about 5cm depth of water on the plotsvV I aiOMveffeOctveee Three to six ldayold selings pr hillwW the ACS idex were planted00OWW wia Oft fo an c irNk I p Coen 20 by 20 cm part in straight rows Hand weeding was used

and insecticide were applied for Insect control Grain yieldw was masared by sampling 5 ml of each plot excluding border rows The date of heading in each treatment and theUNiN d pbM W Weks rin tOW USA UMe In Tale yed componnts at hafvel were also recorded

I filM rsperMS esOM kdwdua 1 t ab The average yields of ough (unhulled) rice for botha 84 OW O 8uo 4 Thala TM was a locations are ploutel in PIS 3 for the first crop (1969 wet

owou thRM seaso0) The Veamps yield response was obtained at Klonge (s) W lDtO t Of dMa of1tw W d l R Luang however a 4ute satisfactory yield response was

~Mk ^d TVA UJSD ad Kd UnIveS obtalned to applied P at Bangkhen as wellXUe LaM e R qwrw Ims The sod was do Relative aponomlAe effectiveness values were calculated

VOW (a ksA w edmwL t Poesesm h Vy for these data and am presented In Table 3 The valuesdAY buo if dIe ouh ne Pee wtk a Mlak vow 1009 for th first crop are plotled against ACS index in Fig 41 This Im M i6ti l 4bNd IO a0 O mkarnk for both locatio r relationship was linear for the

11400 ThCpH 0( lb pW IW 01 th UpeiaW so Sanodion location and curtiltnear for KIng Luang The was u i 4A sksamp lMaor nrusio model amparounted for 81 of theAmO$MI Aw jAAsue Swim T1 Snh Wd variation In the AE valu for Bantkhen a square root

Mems a Iw iv fern alh$ sedm haowg dayNW W t he plAL At tdo M tM aso W s as ctminued throufh eltaM t Ofpof -le lse wo am P OeNI VeOpls 1o ealluae tI lon4erm MIdual Offccls

A on W isset i a wse to hsh eapeel of these ooihss t ocks The baagkhon experimnent was letmiaI1DlVemisthis is a w hulu Lo g Tasug ia iasael aft - Msd residual Ves will be pr-Om crok TheseTwod esewm

SWWo

A

lP~U~7 ISIIPe1iuIWN e bsedisssin ian ghth siaoelalbe

984 0 6 O O - M s -s fWPas 11eSft W d Uo al a o

o

S4l~ lIIII I~l I 1f fl

( +

+ + + m + ++++-

++ +(++ + ++++ + ++ ++

- 66 -

ENOIMLSTAD ET AL RESPONSE BY FLOODED RICE TO PHOSPHATE ROCKS VARYING IN CITRATE SOLUBILITY

I I I I j0 I I

BANOKHEN BANGKHEN

pH 56 6 - 0o

TSP

NC

5~ ~ ~ L o 4 - -shy

4 ] - --------shy04

6S

|0 III 2 44 8r 66

I I I

a 1KLONG LUANG

pH 46 z KLONG LUANG

TSP Sc2 NCFL(N)

5 FLIC) J0 TU

oshy

4 ~40shy

3 bull eM0

I - I I I I I

0 II 22 44 88 0 5 10 15 20 IP APPLIED KO HA ABSOLUTE CITRAE SOLUBIITY INDEX

Fig 3-Yield of rough rice at Klong Luang and Bangkhen Rice Fig 4-Relative agronon effectiveness () of P sources ploz-Experiment Stations Thalmand as affected by rate and Source ted against citrate solubity Index for both Thailand field ex

of P applied (crop 1) periment (first crop only)

regression model accounted for 97 of the variation in sumably resulted from crop uptake and reaction with the RAE values at the Klong Luang location soil to form less soluble products Such effects may have

These experiments were continued during the dry season been more important at the lower rates since the two TSP of early 1970 to ascertain the residual effectiveness of the curyes converged at the highest rate of application various sources applied to the first crop No new P was These data from KIong Luang indicate that (i) residual applied except for the fresh TSP standard mentioned effects of all rocks except Mlcwuri were substantial (ii) above rhe experiment otherwise was conducted in a man the relationship between relative agronornic effectiveness ner similar to that followed in the first crop of the phosphate rocks and citrate solubility levels was

The response to both freshly applied ad residual P was largely obscured and (iii) the general superiority of TSP marked at the Klong Luang location and marginal at over phosphate rock in terms of effectiveiss persisted Bangkhen In fact at the latter location the response was through the second crop so small that little can be said regarding residual effectiveshyness The yield data from crop 2 at the Klong Luang DISCUSSION experiment are plotted in Fig 5 Greenhouse and field data presented in this paper show

Relative agronomic effectiveness values (Table 3) were clearly that there are substantial differences among phosshycalculated for the Klong Luang data using both the residual and freshly applied TSP as standards It is of Interest to note that the superiority of TSP over the phosphbte rocks Table 3-Relative agronomic effective values for field experishyments in Thailand persisted through the second crop The main difference in KlowlZmlnql~the residual effects is that with the exception of the MIs- s Crop 1 Crop 21 Crop 1-shysouri rock Ihe marked relationship between citratr-soluble WoiCarolina yl 59 76

phosphate rocks and RAE had largely rds norh) a 64P conltct of th Florida (eqlral is 6969 6

disapipeared In this acidic soil (pHi 46) P would by this I14o 69 63 40 ToonesS 31 65

limo be supplied by Intermediate reaction products In addl Missou 0 o lion to residues of the initial spatlte Ts P o 2 o 0

The TSP applied to the first crop declliv-d slightly In campIafcmWataesr e id ofeuhuloefor 22MA rates of PtColeouattd as aba u tlte td18 kS ratesp dlverage yield tM868 to 22 44

effectiveness relative to the freshly applied ISP This pre- of d s4

A

4

- 67 shy

-SOIL SCL SOC AMER I

KLONG LUANG CROP 2

Si 3

eN

TAPPLIEDKGHA

Fig 5-The residual effectiveness ovarious P sources for crop s compared with freshly applied TSP Klong Luang Rice

Experiment Station Thailand

phate rocks in terms of agronomic effectiveness for flooded

rice Further these differences can be predicted by means of citrate solubility or by the ACS index It appears that

the latter is more appropriate where the content of apatite varies among phospiate rocks The most soluble phosphate rocks approached but did not actually equal TSP in limit-iuig (maximum) yield in these experiments regardless of rate applied This agrees with the results of Ensminger Pearson and Armiger (4) One needs to consider the defi-nite posribility of same yield loss in zhoosing a phosphate

rock over TSP such yield losses must be weighed against the lower price of phosphate rock The explanation for such iosses may involve concentration of soluble P in the soil Khasawneh and Copeland (6) suggest that the growth rate of crop plants is a function of P concentration that can be maintained in the soil solution If P concentration is limiting or inadequate becawe of a lower dissolution rate of phosphate rock the growth iate ard uiiimate yield will be diminished accordingly

The RAE values bascd on yield increases reflect the agronomi effectiveness of these various sources relacve

to the TSP standard however these nould be supple-

mented by an economic analysis before rational choice can

be made The following calculations will provide an estimate of

the rclativ ecooomic effectiveness(REE)

Y t Ps aXpatREE -- 100

vahtercks t sphate or e b i- eor

Price of TSPkg fo

be Price of PRkg P

PROC VOL 38 1974 leO

90r

Wsoshy

0

60-LUSEPHOSPHATE ROCK

00 10 20

PTP PR

Fig 6-Relationship between relaZive effectiveness values (RAE) and the price ratios between TSP and phosphate rock Such a figure can be used in making a choice between these

sources

If REE exceeds 100 in this calculation the phosphate rock would be preferable to TSP

The REE calcuktaaa wre used in preparing an indifshyference curve (Fig 6) wherein RAE values are plotted

against PTsPPpR ratios The cu~rve itself connects those points at which REE equals 100 When exactly on the curve it makes no real economic difference what source is chosen After choosing a suitable price ratio one can then project upward from that ratio knowing the RAI

value (or estimating it from such data as shown in Fig 4 using citrate-soluble P content) one can then choose the source on the basis of both agronomic and economic conshysiderations For example if the price ratio is 25 and the RAE value of the phosphaite rock is greater than 40 the rock phosphate in question would be used However if the RAE value was less than 40 TSP would be a better choice There are indications that if the P in the more soluble phosphate ro~cks (North Carolina north Florida central Forida) is less than half as expensivz as that in TSP these rocks would be feasible altereaives to TSP on soils similar

to thoseused in Thailand This analysis does not take into account the possibility

of lower yields from use of phosphate rock In addition only a portion of the various yield response curves was used in this anlysis ie up to 22 kgha Beyond this

rate yield response was much less pronounced it could be argued that at less than maximum yields TSP would produce a certain yield at lower rates of P than would phosshy

pow ofrock This would especially be true for rates applioa example at Klong Luang 5500 kg of

rice pcr iectare could have been produced with either Ii kg of P as TSP or 44 kg of P as son of the more reacshy

tire phosphate rocks It should be pointed ot however

- 68 shy

(IIKIS amp YOUN( ARIFICIAL WEATIIERING OF OXIDIZED p[ll- IV

that this is the yield level that would show the widest difference such is the advantage of hindsight

Farmers generally prefer granular fertilizers for machine

or hand application This is a disadvantage for the phos-phate rocks which are normally arplied in finely divided form Recently experimental quantities of granular urea-

phosphate rock mixtures have been made by TVA Results of trials with these fertilizers will be reported elsewhere

LITERATURE CITED

1 Armiger W H and Maurice- Fried 1957 The plantavailability of various sources of phosphate rock Soil Sci Soc Amer Proc 21183-188

2 Bengston G W E C Sample and S E Allen 1974 Re-sponso of slash pine seedlings to P sGurces of varying ci-trato solubility Plant Soil (In press)

3 Caro JIt and W Hill 1956 Chard eristics and fer tilizcr value of phosphate rock from different fields J Agr Food Chem 4684-687

4 Ensminger I E R W Peirson and W II Atmiger1967 Effectivencs of rock phosphate as a source of phosshyphurus for plants US Dep Agr ARS Bull 4112S

5 Engelstad 0 P J G Getsinger anid I J Stangel 1972 Tailoring of fertiliers for rice cnnece Valley Author ftyNational Fertilicr Developmnent Center Hull Y-52

6 Khasawnch F E and Jane P Copcland 1971 (otton root growth and uptake of nutrievos relation oif phosph

rus uptake to quantity intensity and buffering capacit) Soil Sci Soc Amer Proc 37250-254

7 Lehr JR and G H McClellan 1972 A revised lIbora tory reactivity scale for evaljativg phosphate rocks for direct application Tennessee Valley Authcrity National Fertilizer Development Center lull Y-43

H Terman G L S EAllen and 0 P Engelstad 1970 Response by paddy cice to ratcs and suurces of appliedphosphorus Agron J63390-394

DIVISION S-9-SOIL MINERALOGY

Artificial Weathering of Oxidized Biotite IV The Inhibitory Effect of Potassium on Dissolution llate

R JGILKES AND R C YOUNG2

ABSTRACT

Rates of dissolution of oxidized biotites in OIM 001M ICI are severely depressed in the presence of IM KCI The amovnts of Al Mg Mn dissolved in the first eytraction are similir to those found without KCI however subsequent extractions remove these elements at 10-20 of the corresponding lICI rates This effect may be due to a decreased rate of vermiculite formation thereby reducing the effective basal area exposed to attack A decrease in dissolution rate with increasing ferric iron content was still apparent in the presence of IM KCI

Additional Index Words X-ray diffraction infrared aborp-

N EARLIER papers of this series the tole of biotite in soils

as a source of both macro and micronutrient elements

has been discussed ((Gilkes Young and Quirk 1972 1973ab) Experiments in artificial weathering uiing as va-

riety of extractants were undertaken to determiie the inlu-

ence of oxidation of octahedrally coordinated iron on the bull release of structural cations to solution The results of this

work demonstated that biotite behaves anomalously with respect to the other common ferromagnesian minerals found in soils Oxidation leads to the development of a high degree of resistance to cation exchange and dissolution Several authors have coiwludcd that decreased rates of K

Contribution from the Dep of Soi Science and Plant Nutri-tion Institute of Agriculture Univ of Western Australia Ned-lands 6009 Western Australia Received 29 Sept 1973 Ap-proved 8 Jan 1974

2 Senior Lecturer in Soil Science and Research Officer respeclively

replacement in electrolytes shown by oxidized biotites are

a result of the inclination of structural hydroxyl adjacent to newly created trivalent iron or vacant octahedral cation sites (Robert and Pedro 1959 Barshad and Kishk 1968) Gilkes et al (1973b) suggested that decreased rates of disshysolution of oxidized biotite in 0001 0t)l 0Af CI may also be due to the presence of inclined hydroxyl In this case a smaller surface area external and exposed intershylayer may be available for attack if K replacement by hyshydrogen ions occurs at a slower rate in oxidized biotites

Gastuche (1963) has shown that significant dissolution ofthe (IIM) biotile face may occur and it is easily demonshystrated that the proportion of exposed (001M) face in weathering biotites depends on the percentage K replaced

Rausell-Colom ct al (1965) have shown that hydrogen ions act in an identical fashion to metal cations in K exshy

change from micas In particular exchange c-f K by hydroshy

gen ions will be terminated or greatly reduced by high levels of K in solution Thus if dissolution of oxidized biotite by

acids is carried out at sufficiently high K levels to prevent vermiculization any differences in dissolution rate that may occur cannot simply be ascribed to differences in rates of K replacement The following results were obtained from such an experiment which unlike the experiment described in Parts I and II (Gilkes et al 1973ab) does not attempt to simulate natuiral - conditions

MATERIAILS AN) M HIiODS Further subsamples of the less than 0 hiotites used in K

excherandbaid disoo tu es (G iles e9n K exchange and acid dissolution studies (Gilkes et al1973ab) were used in these experiments Preparation of sequentiallyoxidized biotites without intermediate vermiculite formation is

Page 32: I70 - United States Agency for International Developmentto ascertan, but tgl.eetad, 1, L,. ("Tailoring of Pertiltiters for ice,'" TVA ulletin Y-52) states that the staft of IOi has

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W Iotors Ftslanp tospg Irritd for Two thvk Afler flontiw wft rkwa~ Floo4d 191)

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- 38 -

Table 18

Yild of aemati-370 Rice at Punjab Agricultural Research

Institute in Pakistan in 1969-70 Grown Under

Couditions of Intermittent Flooding

Pate of application

=IL

o 0 67 67 100 100 67 67

100 100 67 67 200 100

Average for Sources

Ntha

AS 260 gres 279

320

Source f5

-

AS AS Ura Urea SCU SCU

Yield

Relative

93 100 115

(M)O

Yield

Increase Yield Due to N

(Ktlha) (mtha)

-212 245 033 274 062 260 048 297 085 315 103 325 112

Yield Increase

Relative

72048 067 100 108 161

(2)

- 39 shy

Short-statured high yielding rice varieties grown extenshy

sively in northern Peru require extremely high rates of conventional

N sources to achieve maximum yields The recovery of applied N is

extremely low due to the use of intermittent flooding This water

management system results in heavy N losses even with properly timed

split applications In search of simpler and more effective methods

of N management eight field experiments were conducted in the region

to evaluate sulfur-coated urea (SCU) an experimental slow-release N

source supplied by the Tennessee Valley Authority Rice yields were

increased an average of 59 more by pretransplant-incorporated SCU than

by urea or ammonium sulfate applied in the same manner SCU produced

excessive vegetative growth which resulted in yield reductions at high

N rates

Regardless of an assumed 48-higher unit N cost in SCU the

overall benefits of pretransplant-incorporated applications of SCU

were favorable since there was a decrease of 40 in the optimum rate

of N and the need for precise timing of application was eliminated

Pakistan--In Pakistan basal applications of AS urea and

SCU to rice grown under conditions of intermittent flooding in 1969-70

(table 18) indicate that SCU is a superior source of N as compared to

urea or AS when all N is applied at or before planting The data also

indicate that a yield response was obtained for P applications but a

comparison of N sources at each level of P indicates that no interaction

between N and P was present so that differences between N sources were

relatively the same at each level of P Yields were increased about 60

more when SCU was applied than when urea was applied Yield increases

with AS were only about 72 of the increase obtained with urea these reshy

sults do not agree with the generally-reported superiority of AS as comshy

pared to urea as a source of N for rice

- 40 -

In 1973 experiments were conducted in Pakistan using both

Basmati-370 and IRRI-6 varieties of rice grown under conditions of

When all N was applied at puddlingintermittent flooding (table 19)

or 12 at puddling and 12 at panicle initiation both AS and SCU were

superior to urea with SCU tending to be the most efficient source

However when N was applied 12 at transplanting and 12 at panicle

initiation SCU was the poorest source of N This would indicate that

the release of N from SCU applied at these times is too slow for optimwn

plant growth

In another experiment in Pakistan in 1973 no differences

in the effectiveness of urea AS or SCU were noted in the yields of

continuously-flooded rice (table 20) Again these results are conshy

sistent with earlier results which indicate no superiority for SCU

when rice is continuously flooded

Nitrogen Studies--Maize

A series of three experiments were conducted by IITA in

armo-Nigeria in 1972-73 comparing AS urea SCU and

CAN (calcium

nium nitrate) as sources of N for maize (table 21) A significant

yield response was obtained for N at each location but no conaistent

differences were noted amaong sources These results are consistent

with results at other locations which have not shown that SCU is a

superior source of N for maize grown over a period of 3 to 4 months

Nitrogen--Wheat

The yields of wheat in Pakistan in 1969-70 (tables 22 and

23) show that yields with SCU) tended to be lower than those with ureaJ

although at one locction where sorghum was grown followilng wheat with

Table 19

Yields of Basmati-370 and IRRI-6 Rice at Punjab Agricultural Experiment Station in Pakistan in 1973 Under

Conditions of Intermittent Flooding

Rate Yield Source of N Time of Yield (Mtha) Increase of N B-370 IRRI-6 Application Basmati-370 IRRI-6 Average (Mtha)

0 0 - 21 353 287 -

SCU 90 150 At Puddling 325 545 435 148

Urea 90 150 At Puddling 309 500 405 118

AS 90 150 At Puddling 324 529 427 140

SCU 90 150 Puddling 372 572 472 185 Panicle Initiation

Urea 90 150 Puddling 335 502 419 132 Panicle Initiation

AS 90 150 Puddling 353 529 441 154 Panicle Initiation

SCU 90 150 After Transplanting 312 562 437 150 Panicle Initiation

Urea 90 150 After Transplanting 340 624 482 195 Panicle Initiation

AS 90 150 After Transplanting 349 583 466 179 Panicle Initiation

All plots received 45 lbs P205acre as single superphosphate

Relative Yield Increase ()

Source of N At Puddling Puddling Panicle Transplant h Panicle

Urea 100 100 100 AS 119 117 92 SCU 125 140 77

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-48

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ThUAIAd

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P11~0 pra~lpj prefer gre4r tuftlter for whlae

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asowcs of P tof ttde ro The wreem proucts omre raGther

pemour~a ot P syag besmti andMi as elt ov so gpamwhr

iuipiqffhate(TS) low twseeo Is eftwiltve Is thet

W41 preeme wae oialain ire post-rItoi effriq to Stanlato the

pud6itt of Irto paddle Wee ofsdlseireplastiq

0 49 shy

lbs partially scldiaatede grawilated Ml prodlucts Vere isshy

toiwdiats in 5tftOvttWS54 betwee wroiPi ad TVP NotV5Ymf to

me coo were they mere twoe $a a etfective ao TIP 00 sipifleast

LVSUMI5 at0 efecto wore toun tor thee produteo Timely dtIampWde

FR (-t00 mmoh) Uia amp~rally oar affective than Owe gra8448r FOampprodt

featal twos o 6 aotetire s I

Nowvero it to felt that sfortber field euprtet vth

hese interials Amd ether typs of grometatodl Wter nre wrrautad

hater ceeuwodh that they have me areec poteatlal toi additoG

e tate wAne the sectte as OtawrI sed bovoloen turther

euperimeste vth few reck pboophar s0d with reck pbophat treated

to sehesa citrata selmtliy or to ha csaducted

Metbir sertes of tbme enprtaeats wae c~edtmcted by IITA

to Ut~rta copal TVP AOP APP aed it at see tecastisix (table 14)

No dot lalt sewseltles teh draw tree thee results simouely em pear to tlvdl bsww they do stwgpt tbat forthew work with

MR to werramid so tbme sels

Table 24

LttcttF Swce MaPlate 06 ieldot IM AWaia CoelsANS at IITA (Ugboda ad Apoin ail sorit) aid at Ike (AUaba s5i series)

1973

Plate ot IP Apinu 5 poundebods A1ab

Ocrol 0 Z94 419 M)

Tr ipl ruprphite 20 349 3799378

Triple vepput 40 M09 410$

Triple 6wp~~b1 4271 4344 42250

Ammotw-ritpophW to 4201 4124 4040

Amosim-rdop~phlt 40 4270 4106 4231

AM tuo-polpephats 20 404 4244 3794

~eai~mpelppepbuI 400)49 4094

Cee m-pbpbt to- 59

momee eph lto 0 4192

LSO (0 0$) 29 1025

Th WPII

- 51 shy

101Y114 tpeM-fI PEP~tbRP YO

1 ~ ~ gmw 1pc~biofl- 9 Kla4v4h

Upia U04 Copfind am Crehout Stet Rpano at (Ia4

rico t IF t rume6 orth~ Caralto phoophale rocl QAR) vaUN pqU41 to

roopon from cmonetrat4 gsporphophai (CIP) who ort$o4 oil k

was 45j itwas tafertor vb protioo4 oil p war OS Ib 4iffer~c

in rtc reepos to X cod14 oo bo ttrit4 4 4 hvsciag of boil p

~ Pt o r11221 0 tP

c theto the rhimecyllndor of rico tots par to)14M4i1 roeoi~t

ed oil emd PA prior to tho ont of an~robi4 cMioe AA~ oIifoshy

nAte bYpot t taet~d tO fC4sin t~r 4PWden0 Of f Ot(tivshy

ofOWailiJtyno o prefla4 all Put that 4t01etoo 14 tvsIk

of the Ott to prvvld a 014for C4m0 44 mI 1 o4sf

EfftC ftPet141on AIAM-0 V f401td 4 4iv 440 Mtft

Aa torfat VampP f4MWfCi4W04wt0amp to 4eturWlI Ot(Wel~drIC ft

Ot f tM6 the flooded Ott 00 14 04019I Pft0uAw Of gAr~s~lr

pkS$t M40b MP) Tw P1101 Piset Prodwie W-e 10M0di Wr04

(10-1) emW 0aretilp ddw01at4 P WAA firom Rrth M~flRU414~$

wee cowiared with fie Md reWim 44104 proo~fo) foruk oith laWItter

I v te-PR P OW1004 4 4 O Wf ottil OW ellt Oo

Oveiel1 the 40tt dmcruie to effetotww Wtollowui Co fme

PR tpaUIB1I ldoltmo PR (pamwlatr) offr~- ArmeuM) 0 orwi

- 52 -

Effect of N Sourc6 and Water Management on Response of Rice

toe Zn- M Giordano J J Mortvedt OP Engelstad and Greenhouse

Staff Several rotes of CO(14H2)2 and (H )2So4 vith or without ZnO

wore applied to flooded and nonflooded Crowley oil (limed to pH 75)

to determine response of Bluebelle rice to Zn Yields with both N

sources veotrgreator on flooded then on nonflooded soil In the abshy

ence of applied Zn total dry matter production vith CO(NH2)2 was

slightly lower than with (NH)2S04 on flooded soil and considerably

lover on nonflooded soil Concentration of Zn wan higher in straw and

grain of plants roun on flooded than on nonflooded soil Although

concentration of P was unaffected by N source or Zn rate there was

som indication that cranslocation of P from straw to grain may be

depressed in nouflooded rice Concentration of N was lower in straw

grown on flooded than on nonflooded soil due to apparent dilution

thereas both X sources resulted in similar N concentrations in straw

at all rates of N application the N concentration in grain increased

with 0 rAse

feSpongi gf(SM to Chjorospodiostte and Related P Sources--

Si Allen and Greonhoue Staff A greenhouse pot experiment was

couct44d with corn Brown on Hountview silt loam to compare the ofshy

fectlivees of chlorospodiosito (Chlor-l) with concentrated supershy

phosphate (CP) Thomas slag and North Carolina phosphate rock (NC-PR)

Oil-prillad urea-phophato rock (UPI) FeA1JMP 20 7 and monomthyl

phosphate were included in the experiment Based on yield of forage and

uptake of P by tvo crops each of 6-weeks duration the following conshy

stui were dravat

I Chlor-1 was slightly loss effective than CSI Thomas slaS or NC-PR

from which Chlor-l wae prepared

- 53 shy

2 Granular UPR was a poor source of P its effectiveness was greatly

increased by reducing the particle size to -35mesh

3 FeAlNH4P207 was unavailable to the crop

4 Monomethyl phosphate was equivalent toor slightly more effective-

than CSP

Research Indirectly Related to TVA-AID Project

Response of Several Rice Varieties to Zn in Moist or Flooded

Soil--P M Giordano J J Mortvedt and Greenhouse Several varieties

of rice from Mexico and the Dominican Republic currently under investishy

gation in Puerto Rico for adaptation to upland culture were compared with

some established United States varieties with regard to Zn response on

moist and flooded Crowley sil (pH 75) Chontalpa (Mexico) Bluebelle

(Texas) and Starbonnet (Arkansas) were most responsive to applied Zn

Juma (Dominican Republic) intermediate and Sinaloa (Mexico) and Calrose

(California) were the least responsive The Sinaloa varieties (Mexico)

appeared to be best adapted to non-flooded conditions whereas Chontalpa

and Calrose were poorest Concentrations of Zn generally were higher in

plants grown on flooded than moist soil

Pattern of Growth and Zinc Accumulation by Rice--P M Giordano

J J Mortvedt and Greenhouse Staff Rice plants were harvested at weekly

intervals from shortly after emergence through maturity The objective

was to determine the rate of growth and Zn uptake by a Zn responsive varshy

iety (Bluebelle) and a less Zn-responsive variety (Calrose) in the presence

or absence of Zn applied to Crowley sil (pHl 75) Dry matter production

of Calrose was linear with time of growth and of a similar magnitude until

heading with or without applied Zn Bluebelle followed a similar pattern

where Zn was applied However in the absence of applied Zn foliage yield

was reduced markedly

-54

Uptake of Zn was similar for both varieties whenZn was

applied Dry matter production and Zn uptake by the two varieties

also were comparable when Zn was applied However yield of Calrose

was much higher than that of Bluebelle in the absence of applied Zn

while Zn uptake was only slightly higher This suggests that the lesshy

ser responsiveness of Calrose to Zn may be due to more efficient utilishy

zation of Zn There was no indication of a greater demand for Zn durshy

ing reproduction in either variety as was suggested in earlier greenshy

house experiments

Response of Upland Rice to P and Zn--P M Giordano J J

Mortvedt and Greenhouse Staff Several rates of P and Zn were applied

to Crowley sil (limed to pH 75) in factorial combination to determine

whether differences in rice growth under flooded and nonflooded soil

conditions are related to plant nutrition Although straw yields were

slightly higher in nonflooded rice receiving adequate P and Zn grain

yields were higher in the flooded crop increased rates of F andor Zn

did not result in equal yields Except in the highest Zn rate (75 mg)

concentrations of Zn in both straw and grain were higher with flooding

Concentration of P increased with rate of applied P and was higher in

the grain or flooded than upland rice at a comparable P rate In conshy

trast concentrations of N were lower with flooding due in part to dilshy

ution from increased growth

Rice Response to N and P in Flooded and Unflooded Cultures--

G L Terman S E Allen and Greenhouse-Analytical Staff Rates of

N from 250 to 2000 ntpot and P from 0 to 1000 mtpot were applied for

Nato rice grown on Mountview sil and Sango sicl (625 kg of soil per

pot) Market yield response to N and P was obtained Yields of straw

- 55 shy

total yields N uptake and N recovery were higher on unflooded than

on flooded soil cultures Grain yields however were slightly higher

with flooding These results indicate that with adequate applied

nutrients especially of N rice yields without flooding can approach

or even equal those under flooding

Uptake of N P Ca Mg and Zn increased with yield response

to N and P while K uptake decreased on the Mountview soil Concentrations

of N and P increased with applied N and P respectively while concentrations

of other nutrients were diluted in most situations with yield response to N

or P

Results from this experiment show that amouats of N applied in

previous pot experiments for rice have been much too low especially if the

crop was grown to maturity

Response of Corn to S and N i UUASand Urea-S--S E Allen

and Greenhouse Staff Three greenhouse pot experiments were conducted to

measure response to S and N in ulfur coated urea (SCU) urea amonium

sulfate (UAS) and urea -S as well as estimate N losses from surface apshy

plied N sources

In Experiment 260 less than 20 of the S mixed with the soil

was recovered from SCU or urea-S granules by two crops of corn as comshy

pared to 45 or 80 from flowers of S or Na2SO 4 CLop response followed

a similar pattern

In Experiment 260-A N sources were surface applied and alshy

lowed to dry for two weeks before incorporation Into the soil and plantshy

ing Recovery of N by two crops of corn was 77-82 for AN an compared

to 37-70 for urea UAS urea-S and ICU Thus n this experiment loss

of N from urea did not appear to be re~dcud by light S-coatlngn or by Inshy

corporating S or AS in the granules

-S -

I xbprZnSlt a Wtch aU Meyto 0-Ai Wt f9r

higher reermo teOrtOrs cOM reSpWNO i r0100 Of N w

not oaisteontly related to sewe ot N In edl tust 0 ioltiUe Lim

lo in VMuwpped evlmtUTS 48 merind by seirest nte appresOehe

501 for uroa as cwarod to 210 for urea peepha

Rus- or Upse to LoAmIl34I a AriMed bI Earl U

MW NOWlsIIsIr-4 L Toman 5 1 Alln and eesese StNf rio

row on Sawg did (0 tpot) We 1l0l0 Ws feritiud vith 05is

of Npot mixod with the 6011 as aureCA NiAO) 1 Age god At Ures

was also itcluded at rtt t 05 10 end 15 of Upee Theas trealshy

onto were followed 4 wpdrsetago of U s AN wre 4C 10o or at I3n

Weeks toulin up to IS pot

A soil application of 10 pot rosulvod to the maim yield

at 4 weeks Tio4 sad percont prottis t intre raite tncreased rftishy

linearly with U applictalien IeseeItally all at the m iNd wit

the moil w domitrifted after flooding Grail end straw Ilelds vere

highly correlatod with tiliriag and vlh ubers of gralm arl

The results Widicat that 0$ to 10 a of Upot as orea or

NN bsuld be sied with the oil to stilate tiilrir with adshy

ditional 0 topireased later to increase grain lIds mad protia cmshy

tout

DIVISION 54- FERTILIZER TECHNOLOGY AND USE

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-02

792 60L WI W A)49R Pio VOL 37 197)

primS o r OeampAd WU toa Them fl~ w At NOSSe earno maisslea Ia N he mOWamplIO yik ampWd IMe aampWmW OWa Owe wa UMs of KU to 41 Oke ampWiiIamm be dkrnety ewspokawleM(a s8 te camtd wie a eapmoe by TVA pavw ltoi NA poundrmdaka4us vrimeW460 o to ilkidm ofWW (Mtemas MuOwe 1973) TVA mwi bawld on soi ficedims IampWp seg rudwiv s~s0abet ke WNmdoe ON 01 K Is12 NOSW ie fssewnmu Ie I QvaaIi rowp IMA) f9

)amp m lodk byO voebmsaIS8OpeaWfrats 11 OWNmi a I a W idisod 0 81 Now 111 nindat Wm fysmpseaamp (If tsO tUmtI IsM $P shoroV4mmo knflkvnf (foOdme nuw ae Ow OImstwe in SM pnmm8 af tXm 10 114PIS kequoian wo Mpfii

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MGMe -M4 Wg kmuwadM 1Wr wih SCV4 Psmuck Wff It dlL Wm 1W led 0 1 oo teeA of aiwaisme aweeoid h

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-d

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DIVISION 8-9-SOIL MINERALOGY

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65

0IL CL OC AMXR PROC VOL 38 1974

)aT1 S4I104 ow Lusanll Tawng isa tall Thai variety known for beingIwo nonshyi s s ) sensitive to photoperiod A split-plot design was used in

S e e these euperimeots with 4 rates of P (I1 22 44 and 88t i V IV k of Pha) applied a main plot treatments and with the OF It sourMes of P as subplot treatments There were two checkS plots in each rmplicate The extra check plot was included to permit the application of fresh TSP standard Jor the

It- ti 06 + i bull fa succeeding crop the p-4me of bi was to permit accurate d awrnwal of the mdual effectiveness of the phosphate

ftinSUbI rock The P fertilioers were broadcast on the mud andthen Worporald In the soil during the last harrowing At

whM N both On ACS indx ampM time of transplanting Immediately before the last harrow61t (4j 5 4 01 P s 3Mm o Vallonal in con n 100 kgha of N as ammonium sulfate and 33 kghaWO Of Spews ampm lIW thaabe rocks do ACS indes of K as polium chloride were applied A total of 40 wa in prepw O do ctih k otent kha of N a ammoniunt sulfate was applied later in twoir P The hew oNed amp wM W for 5 of gw topdrossingp with about 5cm depth of water on the plotsvV I aiOMveffeOctveee Three to six ldayold selings pr hillwW the ACS idex were planted00OWW wia Oft fo an c irNk I p Coen 20 by 20 cm part in straight rows Hand weeding was used

and insecticide were applied for Insect control Grain yieldw was masared by sampling 5 ml of each plot excluding border rows The date of heading in each treatment and theUNiN d pbM W Weks rin tOW USA UMe In Tale yed componnts at hafvel were also recorded

I filM rsperMS esOM kdwdua 1 t ab The average yields of ough (unhulled) rice for botha 84 OW O 8uo 4 Thala TM was a locations are ploutel in PIS 3 for the first crop (1969 wet

owou thRM seaso0) The Veamps yield response was obtained at Klonge (s) W lDtO t Of dMa of1tw W d l R Luang however a 4ute satisfactory yield response was

~Mk ^d TVA UJSD ad Kd UnIveS obtalned to applied P at Bangkhen as wellXUe LaM e R qwrw Ims The sod was do Relative aponomlAe effectiveness values were calculated

VOW (a ksA w edmwL t Poesesm h Vy for these data and am presented In Table 3 The valuesdAY buo if dIe ouh ne Pee wtk a Mlak vow 1009 for th first crop are plotled against ACS index in Fig 41 This Im M i6ti l 4bNd IO a0 O mkarnk for both locatio r relationship was linear for the

11400 ThCpH 0( lb pW IW 01 th UpeiaW so Sanodion location and curtiltnear for KIng Luang The was u i 4A sksamp lMaor nrusio model amparounted for 81 of theAmO$MI Aw jAAsue Swim T1 Snh Wd variation In the AE valu for Bantkhen a square root

Mems a Iw iv fern alh$ sedm haowg dayNW W t he plAL At tdo M tM aso W s as ctminued throufh eltaM t Ofpof -le lse wo am P OeNI VeOpls 1o ealluae tI lon4erm MIdual Offccls

A on W isset i a wse to hsh eapeel of these ooihss t ocks The baagkhon experimnent was letmiaI1DlVemisthis is a w hulu Lo g Tasug ia iasael aft - Msd residual Ves will be pr-Om crok TheseTwod esewm

SWWo

A

lP~U~7 ISIIPe1iuIWN e bsedisssin ian ghth siaoelalbe

984 0 6 O O - M s -s fWPas 11eSft W d Uo al a o

o

S4l~ lIIII I~l I 1f fl

( +

+ + + m + ++++-

++ +(++ + ++++ + ++ ++

- 66 -

ENOIMLSTAD ET AL RESPONSE BY FLOODED RICE TO PHOSPHATE ROCKS VARYING IN CITRATE SOLUBILITY

I I I I j0 I I

BANOKHEN BANGKHEN

pH 56 6 - 0o

TSP

NC

5~ ~ ~ L o 4 - -shy

4 ] - --------shy04

6S

|0 III 2 44 8r 66

I I I

a 1KLONG LUANG

pH 46 z KLONG LUANG

TSP Sc2 NCFL(N)

5 FLIC) J0 TU

oshy

4 ~40shy

3 bull eM0

I - I I I I I

0 II 22 44 88 0 5 10 15 20 IP APPLIED KO HA ABSOLUTE CITRAE SOLUBIITY INDEX

Fig 3-Yield of rough rice at Klong Luang and Bangkhen Rice Fig 4-Relative agronon effectiveness () of P sources ploz-Experiment Stations Thalmand as affected by rate and Source ted against citrate solubity Index for both Thailand field ex

of P applied (crop 1) periment (first crop only)

regression model accounted for 97 of the variation in sumably resulted from crop uptake and reaction with the RAE values at the Klong Luang location soil to form less soluble products Such effects may have

These experiments were continued during the dry season been more important at the lower rates since the two TSP of early 1970 to ascertain the residual effectiveness of the curyes converged at the highest rate of application various sources applied to the first crop No new P was These data from KIong Luang indicate that (i) residual applied except for the fresh TSP standard mentioned effects of all rocks except Mlcwuri were substantial (ii) above rhe experiment otherwise was conducted in a man the relationship between relative agronornic effectiveness ner similar to that followed in the first crop of the phosphate rocks and citrate solubility levels was

The response to both freshly applied ad residual P was largely obscured and (iii) the general superiority of TSP marked at the Klong Luang location and marginal at over phosphate rock in terms of effectiveiss persisted Bangkhen In fact at the latter location the response was through the second crop so small that little can be said regarding residual effectiveshyness The yield data from crop 2 at the Klong Luang DISCUSSION experiment are plotted in Fig 5 Greenhouse and field data presented in this paper show

Relative agronomic effectiveness values (Table 3) were clearly that there are substantial differences among phosshycalculated for the Klong Luang data using both the residual and freshly applied TSP as standards It is of Interest to note that the superiority of TSP over the phosphbte rocks Table 3-Relative agronomic effective values for field experishyments in Thailand persisted through the second crop The main difference in KlowlZmlnql~the residual effects is that with the exception of the MIs- s Crop 1 Crop 21 Crop 1-shysouri rock Ihe marked relationship between citratr-soluble WoiCarolina yl 59 76

phosphate rocks and RAE had largely rds norh) a 64P conltct of th Florida (eqlral is 6969 6

disapipeared In this acidic soil (pHi 46) P would by this I14o 69 63 40 ToonesS 31 65

limo be supplied by Intermediate reaction products In addl Missou 0 o lion to residues of the initial spatlte Ts P o 2 o 0

The TSP applied to the first crop declliv-d slightly In campIafcmWataesr e id ofeuhuloefor 22MA rates of PtColeouattd as aba u tlte td18 kS ratesp dlverage yield tM868 to 22 44

effectiveness relative to the freshly applied ISP This pre- of d s4

A

4

- 67 shy

-SOIL SCL SOC AMER I

KLONG LUANG CROP 2

Si 3

eN

TAPPLIEDKGHA

Fig 5-The residual effectiveness ovarious P sources for crop s compared with freshly applied TSP Klong Luang Rice

Experiment Station Thailand

phate rocks in terms of agronomic effectiveness for flooded

rice Further these differences can be predicted by means of citrate solubility or by the ACS index It appears that

the latter is more appropriate where the content of apatite varies among phospiate rocks The most soluble phosphate rocks approached but did not actually equal TSP in limit-iuig (maximum) yield in these experiments regardless of rate applied This agrees with the results of Ensminger Pearson and Armiger (4) One needs to consider the defi-nite posribility of same yield loss in zhoosing a phosphate

rock over TSP such yield losses must be weighed against the lower price of phosphate rock The explanation for such iosses may involve concentration of soluble P in the soil Khasawneh and Copeland (6) suggest that the growth rate of crop plants is a function of P concentration that can be maintained in the soil solution If P concentration is limiting or inadequate becawe of a lower dissolution rate of phosphate rock the growth iate ard uiiimate yield will be diminished accordingly

The RAE values bascd on yield increases reflect the agronomi effectiveness of these various sources relacve

to the TSP standard however these nould be supple-

mented by an economic analysis before rational choice can

be made The following calculations will provide an estimate of

the rclativ ecooomic effectiveness(REE)

Y t Ps aXpatREE -- 100

vahtercks t sphate or e b i- eor

Price of TSPkg fo

be Price of PRkg P

PROC VOL 38 1974 leO

90r

Wsoshy

0

60-LUSEPHOSPHATE ROCK

00 10 20

PTP PR

Fig 6-Relationship between relaZive effectiveness values (RAE) and the price ratios between TSP and phosphate rock Such a figure can be used in making a choice between these

sources

If REE exceeds 100 in this calculation the phosphate rock would be preferable to TSP

The REE calcuktaaa wre used in preparing an indifshyference curve (Fig 6) wherein RAE values are plotted

against PTsPPpR ratios The cu~rve itself connects those points at which REE equals 100 When exactly on the curve it makes no real economic difference what source is chosen After choosing a suitable price ratio one can then project upward from that ratio knowing the RAI

value (or estimating it from such data as shown in Fig 4 using citrate-soluble P content) one can then choose the source on the basis of both agronomic and economic conshysiderations For example if the price ratio is 25 and the RAE value of the phosphaite rock is greater than 40 the rock phosphate in question would be used However if the RAE value was less than 40 TSP would be a better choice There are indications that if the P in the more soluble phosphate ro~cks (North Carolina north Florida central Forida) is less than half as expensivz as that in TSP these rocks would be feasible altereaives to TSP on soils similar

to thoseused in Thailand This analysis does not take into account the possibility

of lower yields from use of phosphate rock In addition only a portion of the various yield response curves was used in this anlysis ie up to 22 kgha Beyond this

rate yield response was much less pronounced it could be argued that at less than maximum yields TSP would produce a certain yield at lower rates of P than would phosshy

pow ofrock This would especially be true for rates applioa example at Klong Luang 5500 kg of

rice pcr iectare could have been produced with either Ii kg of P as TSP or 44 kg of P as son of the more reacshy

tire phosphate rocks It should be pointed ot however

- 68 shy

(IIKIS amp YOUN( ARIFICIAL WEATIIERING OF OXIDIZED p[ll- IV

that this is the yield level that would show the widest difference such is the advantage of hindsight

Farmers generally prefer granular fertilizers for machine

or hand application This is a disadvantage for the phos-phate rocks which are normally arplied in finely divided form Recently experimental quantities of granular urea-

phosphate rock mixtures have been made by TVA Results of trials with these fertilizers will be reported elsewhere

LITERATURE CITED

1 Armiger W H and Maurice- Fried 1957 The plantavailability of various sources of phosphate rock Soil Sci Soc Amer Proc 21183-188

2 Bengston G W E C Sample and S E Allen 1974 Re-sponso of slash pine seedlings to P sGurces of varying ci-trato solubility Plant Soil (In press)

3 Caro JIt and W Hill 1956 Chard eristics and fer tilizcr value of phosphate rock from different fields J Agr Food Chem 4684-687

4 Ensminger I E R W Peirson and W II Atmiger1967 Effectivencs of rock phosphate as a source of phosshyphurus for plants US Dep Agr ARS Bull 4112S

5 Engelstad 0 P J G Getsinger anid I J Stangel 1972 Tailoring of fertiliers for rice cnnece Valley Author ftyNational Fertilicr Developmnent Center Hull Y-52

6 Khasawnch F E and Jane P Copcland 1971 (otton root growth and uptake of nutrievos relation oif phosph

rus uptake to quantity intensity and buffering capacit) Soil Sci Soc Amer Proc 37250-254

7 Lehr JR and G H McClellan 1972 A revised lIbora tory reactivity scale for evaljativg phosphate rocks for direct application Tennessee Valley Authcrity National Fertilizer Development Center lull Y-43

H Terman G L S EAllen and 0 P Engelstad 1970 Response by paddy cice to ratcs and suurces of appliedphosphorus Agron J63390-394

DIVISION S-9-SOIL MINERALOGY

Artificial Weathering of Oxidized Biotite IV The Inhibitory Effect of Potassium on Dissolution llate

R JGILKES AND R C YOUNG2

ABSTRACT

Rates of dissolution of oxidized biotites in OIM 001M ICI are severely depressed in the presence of IM KCI The amovnts of Al Mg Mn dissolved in the first eytraction are similir to those found without KCI however subsequent extractions remove these elements at 10-20 of the corresponding lICI rates This effect may be due to a decreased rate of vermiculite formation thereby reducing the effective basal area exposed to attack A decrease in dissolution rate with increasing ferric iron content was still apparent in the presence of IM KCI

Additional Index Words X-ray diffraction infrared aborp-

N EARLIER papers of this series the tole of biotite in soils

as a source of both macro and micronutrient elements

has been discussed ((Gilkes Young and Quirk 1972 1973ab) Experiments in artificial weathering uiing as va-

riety of extractants were undertaken to determiie the inlu-

ence of oxidation of octahedrally coordinated iron on the bull release of structural cations to solution The results of this

work demonstated that biotite behaves anomalously with respect to the other common ferromagnesian minerals found in soils Oxidation leads to the development of a high degree of resistance to cation exchange and dissolution Several authors have coiwludcd that decreased rates of K

Contribution from the Dep of Soi Science and Plant Nutri-tion Institute of Agriculture Univ of Western Australia Ned-lands 6009 Western Australia Received 29 Sept 1973 Ap-proved 8 Jan 1974

2 Senior Lecturer in Soil Science and Research Officer respeclively

replacement in electrolytes shown by oxidized biotites are

a result of the inclination of structural hydroxyl adjacent to newly created trivalent iron or vacant octahedral cation sites (Robert and Pedro 1959 Barshad and Kishk 1968) Gilkes et al (1973b) suggested that decreased rates of disshysolution of oxidized biotite in 0001 0t)l 0Af CI may also be due to the presence of inclined hydroxyl In this case a smaller surface area external and exposed intershylayer may be available for attack if K replacement by hyshydrogen ions occurs at a slower rate in oxidized biotites

Gastuche (1963) has shown that significant dissolution ofthe (IIM) biotile face may occur and it is easily demonshystrated that the proportion of exposed (001M) face in weathering biotites depends on the percentage K replaced

Rausell-Colom ct al (1965) have shown that hydrogen ions act in an identical fashion to metal cations in K exshy

change from micas In particular exchange c-f K by hydroshy

gen ions will be terminated or greatly reduced by high levels of K in solution Thus if dissolution of oxidized biotite by

acids is carried out at sufficiently high K levels to prevent vermiculization any differences in dissolution rate that may occur cannot simply be ascribed to differences in rates of K replacement The following results were obtained from such an experiment which unlike the experiment described in Parts I and II (Gilkes et al 1973ab) does not attempt to simulate natuiral - conditions

MATERIAILS AN) M HIiODS Further subsamples of the less than 0 hiotites used in K

excherandbaid disoo tu es (G iles e9n K exchange and acid dissolution studies (Gilkes et al1973ab) were used in these experiments Preparation of sequentiallyoxidized biotites without intermediate vermiculite formation is

Page 33: I70 - United States Agency for International Developmentto ascertan, but tgl.eetad, 1, L,. ("Tailoring of Pertiltiters for ice,'" TVA ulletin Y-52) states that the staft of IOi has

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Tabl I

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W Iotors Ftslanp tospg Irritd for Two thvk Afler flontiw wft rkwa~ Floo4d 191)

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- 38 -

Table 18

Yild of aemati-370 Rice at Punjab Agricultural Research

Institute in Pakistan in 1969-70 Grown Under

Couditions of Intermittent Flooding

Pate of application

=IL

o 0 67 67 100 100 67 67

100 100 67 67 200 100

Average for Sources

Ntha

AS 260 gres 279

320

Source f5

-

AS AS Ura Urea SCU SCU

Yield

Relative

93 100 115

(M)O

Yield

Increase Yield Due to N

(Ktlha) (mtha)

-212 245 033 274 062 260 048 297 085 315 103 325 112

Yield Increase

Relative

72048 067 100 108 161

(2)

- 39 shy

Short-statured high yielding rice varieties grown extenshy

sively in northern Peru require extremely high rates of conventional

N sources to achieve maximum yields The recovery of applied N is

extremely low due to the use of intermittent flooding This water

management system results in heavy N losses even with properly timed

split applications In search of simpler and more effective methods

of N management eight field experiments were conducted in the region

to evaluate sulfur-coated urea (SCU) an experimental slow-release N

source supplied by the Tennessee Valley Authority Rice yields were

increased an average of 59 more by pretransplant-incorporated SCU than

by urea or ammonium sulfate applied in the same manner SCU produced

excessive vegetative growth which resulted in yield reductions at high

N rates

Regardless of an assumed 48-higher unit N cost in SCU the

overall benefits of pretransplant-incorporated applications of SCU

were favorable since there was a decrease of 40 in the optimum rate

of N and the need for precise timing of application was eliminated

Pakistan--In Pakistan basal applications of AS urea and

SCU to rice grown under conditions of intermittent flooding in 1969-70

(table 18) indicate that SCU is a superior source of N as compared to

urea or AS when all N is applied at or before planting The data also

indicate that a yield response was obtained for P applications but a

comparison of N sources at each level of P indicates that no interaction

between N and P was present so that differences between N sources were

relatively the same at each level of P Yields were increased about 60

more when SCU was applied than when urea was applied Yield increases

with AS were only about 72 of the increase obtained with urea these reshy

sults do not agree with the generally-reported superiority of AS as comshy

pared to urea as a source of N for rice

- 40 -

In 1973 experiments were conducted in Pakistan using both

Basmati-370 and IRRI-6 varieties of rice grown under conditions of

When all N was applied at puddlingintermittent flooding (table 19)

or 12 at puddling and 12 at panicle initiation both AS and SCU were

superior to urea with SCU tending to be the most efficient source

However when N was applied 12 at transplanting and 12 at panicle

initiation SCU was the poorest source of N This would indicate that

the release of N from SCU applied at these times is too slow for optimwn

plant growth

In another experiment in Pakistan in 1973 no differences

in the effectiveness of urea AS or SCU were noted in the yields of

continuously-flooded rice (table 20) Again these results are conshy

sistent with earlier results which indicate no superiority for SCU

when rice is continuously flooded

Nitrogen Studies--Maize

A series of three experiments were conducted by IITA in

armo-Nigeria in 1972-73 comparing AS urea SCU and

CAN (calcium

nium nitrate) as sources of N for maize (table 21) A significant

yield response was obtained for N at each location but no conaistent

differences were noted amaong sources These results are consistent

with results at other locations which have not shown that SCU is a

superior source of N for maize grown over a period of 3 to 4 months

Nitrogen--Wheat

The yields of wheat in Pakistan in 1969-70 (tables 22 and

23) show that yields with SCU) tended to be lower than those with ureaJ

although at one locction where sorghum was grown followilng wheat with

Table 19

Yields of Basmati-370 and IRRI-6 Rice at Punjab Agricultural Experiment Station in Pakistan in 1973 Under

Conditions of Intermittent Flooding

Rate Yield Source of N Time of Yield (Mtha) Increase of N B-370 IRRI-6 Application Basmati-370 IRRI-6 Average (Mtha)

0 0 - 21 353 287 -

SCU 90 150 At Puddling 325 545 435 148

Urea 90 150 At Puddling 309 500 405 118

AS 90 150 At Puddling 324 529 427 140

SCU 90 150 Puddling 372 572 472 185 Panicle Initiation

Urea 90 150 Puddling 335 502 419 132 Panicle Initiation

AS 90 150 Puddling 353 529 441 154 Panicle Initiation

SCU 90 150 After Transplanting 312 562 437 150 Panicle Initiation

Urea 90 150 After Transplanting 340 624 482 195 Panicle Initiation

AS 90 150 After Transplanting 349 583 466 179 Panicle Initiation

All plots received 45 lbs P205acre as single superphosphate

Relative Yield Increase ()

Source of N At Puddling Puddling Panicle Transplant h Panicle

Urea 100 100 100 AS 119 117 92 SCU 125 140 77

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-48

Therean laiictw that It lbs P to th e am lukis

obosomhu rocks 0entk catetas rth Unrtdo costrat frwt) to

ht tse balt s Owosiv as that to TwP it rocks WM bo

fmtbt alteruutiv to MSso gotastte to~ Ik lee used to

ThUAIAd

Tht wMl dt gotmtmlaoti wout th possibility

of law Vhld free ww e1 e66001 4 It cooUt be YgWd Sutt

a4 10 0410 SWUSSM yt$4e TOP wUd predWr A r~ftIf fl~W t

1f f ot P the wuld phosphae rck TWOe viWMW efocitill b

true to low rttos t tsplusatiI P wi 9 Ma Liiam $S

amp4at r per Wforssota Mav two 64eed Wilk elikor It 44 of

P go Mi er 4A bg oftoP aon of tewmrowtni pboophals fwAh

It vwld be polotrd A Wevero wtht Is the jteld level that

W414 gk tko videm dtterem~j o(A 1 the 4~etamp tk~e~t

P11~0 pra~lpj prefer gre4r tuftlter for whlae

of hoaw ppltrstie Mhe to a dloedveaP for The PINSOO rocka

vkth m r II spotted 10 ftewil 4106Me tem

Nub studios we ovsosd o IVA vol gramleid a

forgof wee aMW pbsepbots A fths pemhawe evsielew us

Odellod to detMlee it otteettvmm of 11agotated Stoture of

mmfp MW phapa A (CI) sed graewletod pampAtlti arlolatod Pa

asowcs of P tof ttde ro The wreem proucts omre raGther

pemour~a ot P syag besmti andMi as elt ov so gpamwhr

iuipiqffhate(TS) low twseeo Is eftwiltve Is thet

W41 preeme wae oialain ire post-rItoi effriq to Stanlato the

pud6itt of Irto paddle Wee ofsdlseireplastiq

0 49 shy

lbs partially scldiaatede grawilated Ml prodlucts Vere isshy

toiwdiats in 5tftOvttWS54 betwee wroiPi ad TVP NotV5Ymf to

me coo were they mere twoe $a a etfective ao TIP 00 sipifleast

LVSUMI5 at0 efecto wore toun tor thee produteo Timely dtIampWde

FR (-t00 mmoh) Uia amp~rally oar affective than Owe gra8448r FOampprodt

featal twos o 6 aotetire s I

Nowvero it to felt that sfortber field euprtet vth

hese interials Amd ether typs of grometatodl Wter nre wrrautad

hater ceeuwodh that they have me areec poteatlal toi additoG

e tate wAne the sectte as OtawrI sed bovoloen turther

euperimeste vth few reck pboophar s0d with reck pbophat treated

to sehesa citrata selmtliy or to ha csaducted

Metbir sertes of tbme enprtaeats wae c~edtmcted by IITA

to Ut~rta copal TVP AOP APP aed it at see tecastisix (table 14)

No dot lalt sewseltles teh draw tree thee results simouely em pear to tlvdl bsww they do stwgpt tbat forthew work with

MR to werramid so tbme sels

Table 24

LttcttF Swce MaPlate 06 ieldot IM AWaia CoelsANS at IITA (Ugboda ad Apoin ail sorit) aid at Ike (AUaba s5i series)

1973

Plate ot IP Apinu 5 poundebods A1ab

Ocrol 0 Z94 419 M)

Tr ipl ruprphite 20 349 3799378

Triple vepput 40 M09 410$

Triple 6wp~~b1 4271 4344 42250

Ammotw-ritpophW to 4201 4124 4040

Amosim-rdop~phlt 40 4270 4106 4231

AM tuo-polpephats 20 404 4244 3794

~eai~mpelppepbuI 400)49 4094

Cee m-pbpbt to- 59

momee eph lto 0 4192

LSO (0 0$) 29 1025

Th WPII

- 51 shy

101Y114 tpeM-fI PEP~tbRP YO

1 ~ ~ gmw 1pc~biofl- 9 Kla4v4h

Upia U04 Copfind am Crehout Stet Rpano at (Ia4

rico t IF t rume6 orth~ Caralto phoophale rocl QAR) vaUN pqU41 to

roopon from cmonetrat4 gsporphophai (CIP) who ort$o4 oil k

was 45j itwas tafertor vb protioo4 oil p war OS Ib 4iffer~c

in rtc reepos to X cod14 oo bo ttrit4 4 4 hvsciag of boil p

~ Pt o r11221 0 tP

c theto the rhimecyllndor of rico tots par to)14M4i1 roeoi~t

ed oil emd PA prior to tho ont of an~robi4 cMioe AA~ oIifoshy

nAte bYpot t taet~d tO fC4sin t~r 4PWden0 Of f Ot(tivshy

ofOWailiJtyno o prefla4 all Put that 4t01etoo 14 tvsIk

of the Ott to prvvld a 014for C4m0 44 mI 1 o4sf

EfftC ftPet141on AIAM-0 V f401td 4 4iv 440 Mtft

Aa torfat VampP f4MWfCi4W04wt0amp to 4eturWlI Ot(Wel~drIC ft

Ot f tM6 the flooded Ott 00 14 04019I Pft0uAw Of gAr~s~lr

pkS$t M40b MP) Tw P1101 Piset Prodwie W-e 10M0di Wr04

(10-1) emW 0aretilp ddw01at4 P WAA firom Rrth M~flRU414~$

wee cowiared with fie Md reWim 44104 proo~fo) foruk oith laWItter

I v te-PR P OW1004 4 4 O Wf ottil OW ellt Oo

Oveiel1 the 40tt dmcruie to effetotww Wtollowui Co fme

PR tpaUIB1I ldoltmo PR (pamwlatr) offr~- ArmeuM) 0 orwi

- 52 -

Effect of N Sourc6 and Water Management on Response of Rice

toe Zn- M Giordano J J Mortvedt OP Engelstad and Greenhouse

Staff Several rotes of CO(14H2)2 and (H )2So4 vith or without ZnO

wore applied to flooded and nonflooded Crowley oil (limed to pH 75)

to determine response of Bluebelle rice to Zn Yields with both N

sources veotrgreator on flooded then on nonflooded soil In the abshy

ence of applied Zn total dry matter production vith CO(NH2)2 was

slightly lower than with (NH)2S04 on flooded soil and considerably

lover on nonflooded soil Concentration of Zn wan higher in straw and

grain of plants roun on flooded than on nonflooded soil Although

concentration of P was unaffected by N source or Zn rate there was

som indication that cranslocation of P from straw to grain may be

depressed in nouflooded rice Concentration of N was lower in straw

grown on flooded than on nonflooded soil due to apparent dilution

thereas both X sources resulted in similar N concentrations in straw

at all rates of N application the N concentration in grain increased

with 0 rAse

feSpongi gf(SM to Chjorospodiostte and Related P Sources--

Si Allen and Greonhoue Staff A greenhouse pot experiment was

couct44d with corn Brown on Hountview silt loam to compare the ofshy

fectlivees of chlorospodiosito (Chlor-l) with concentrated supershy

phosphate (CP) Thomas slag and North Carolina phosphate rock (NC-PR)

Oil-prillad urea-phophato rock (UPI) FeA1JMP 20 7 and monomthyl

phosphate were included in the experiment Based on yield of forage and

uptake of P by tvo crops each of 6-weeks duration the following conshy

stui were dravat

I Chlor-1 was slightly loss effective than CSI Thomas slaS or NC-PR

from which Chlor-l wae prepared

- 53 shy

2 Granular UPR was a poor source of P its effectiveness was greatly

increased by reducing the particle size to -35mesh

3 FeAlNH4P207 was unavailable to the crop

4 Monomethyl phosphate was equivalent toor slightly more effective-

than CSP

Research Indirectly Related to TVA-AID Project

Response of Several Rice Varieties to Zn in Moist or Flooded

Soil--P M Giordano J J Mortvedt and Greenhouse Several varieties

of rice from Mexico and the Dominican Republic currently under investishy

gation in Puerto Rico for adaptation to upland culture were compared with

some established United States varieties with regard to Zn response on

moist and flooded Crowley sil (pH 75) Chontalpa (Mexico) Bluebelle

(Texas) and Starbonnet (Arkansas) were most responsive to applied Zn

Juma (Dominican Republic) intermediate and Sinaloa (Mexico) and Calrose

(California) were the least responsive The Sinaloa varieties (Mexico)

appeared to be best adapted to non-flooded conditions whereas Chontalpa

and Calrose were poorest Concentrations of Zn generally were higher in

plants grown on flooded than moist soil

Pattern of Growth and Zinc Accumulation by Rice--P M Giordano

J J Mortvedt and Greenhouse Staff Rice plants were harvested at weekly

intervals from shortly after emergence through maturity The objective

was to determine the rate of growth and Zn uptake by a Zn responsive varshy

iety (Bluebelle) and a less Zn-responsive variety (Calrose) in the presence

or absence of Zn applied to Crowley sil (pHl 75) Dry matter production

of Calrose was linear with time of growth and of a similar magnitude until

heading with or without applied Zn Bluebelle followed a similar pattern

where Zn was applied However in the absence of applied Zn foliage yield

was reduced markedly

-54

Uptake of Zn was similar for both varieties whenZn was

applied Dry matter production and Zn uptake by the two varieties

also were comparable when Zn was applied However yield of Calrose

was much higher than that of Bluebelle in the absence of applied Zn

while Zn uptake was only slightly higher This suggests that the lesshy

ser responsiveness of Calrose to Zn may be due to more efficient utilishy

zation of Zn There was no indication of a greater demand for Zn durshy

ing reproduction in either variety as was suggested in earlier greenshy

house experiments

Response of Upland Rice to P and Zn--P M Giordano J J

Mortvedt and Greenhouse Staff Several rates of P and Zn were applied

to Crowley sil (limed to pH 75) in factorial combination to determine

whether differences in rice growth under flooded and nonflooded soil

conditions are related to plant nutrition Although straw yields were

slightly higher in nonflooded rice receiving adequate P and Zn grain

yields were higher in the flooded crop increased rates of F andor Zn

did not result in equal yields Except in the highest Zn rate (75 mg)

concentrations of Zn in both straw and grain were higher with flooding

Concentration of P increased with rate of applied P and was higher in

the grain or flooded than upland rice at a comparable P rate In conshy

trast concentrations of N were lower with flooding due in part to dilshy

ution from increased growth

Rice Response to N and P in Flooded and Unflooded Cultures--

G L Terman S E Allen and Greenhouse-Analytical Staff Rates of

N from 250 to 2000 ntpot and P from 0 to 1000 mtpot were applied for

Nato rice grown on Mountview sil and Sango sicl (625 kg of soil per

pot) Market yield response to N and P was obtained Yields of straw

- 55 shy

total yields N uptake and N recovery were higher on unflooded than

on flooded soil cultures Grain yields however were slightly higher

with flooding These results indicate that with adequate applied

nutrients especially of N rice yields without flooding can approach

or even equal those under flooding

Uptake of N P Ca Mg and Zn increased with yield response

to N and P while K uptake decreased on the Mountview soil Concentrations

of N and P increased with applied N and P respectively while concentrations

of other nutrients were diluted in most situations with yield response to N

or P

Results from this experiment show that amouats of N applied in

previous pot experiments for rice have been much too low especially if the

crop was grown to maturity

Response of Corn to S and N i UUASand Urea-S--S E Allen

and Greenhouse Staff Three greenhouse pot experiments were conducted to

measure response to S and N in ulfur coated urea (SCU) urea amonium

sulfate (UAS) and urea -S as well as estimate N losses from surface apshy

plied N sources

In Experiment 260 less than 20 of the S mixed with the soil

was recovered from SCU or urea-S granules by two crops of corn as comshy

pared to 45 or 80 from flowers of S or Na2SO 4 CLop response followed

a similar pattern

In Experiment 260-A N sources were surface applied and alshy

lowed to dry for two weeks before incorporation Into the soil and plantshy

ing Recovery of N by two crops of corn was 77-82 for AN an compared

to 37-70 for urea UAS urea-S and ICU Thus n this experiment loss

of N from urea did not appear to be re~dcud by light S-coatlngn or by Inshy

corporating S or AS in the granules

-S -

I xbprZnSlt a Wtch aU Meyto 0-Ai Wt f9r

higher reermo teOrtOrs cOM reSpWNO i r0100 Of N w

not oaisteontly related to sewe ot N In edl tust 0 ioltiUe Lim

lo in VMuwpped evlmtUTS 48 merind by seirest nte appresOehe

501 for uroa as cwarod to 210 for urea peepha

Rus- or Upse to LoAmIl34I a AriMed bI Earl U

MW NOWlsIIsIr-4 L Toman 5 1 Alln and eesese StNf rio

row on Sawg did (0 tpot) We 1l0l0 Ws feritiud vith 05is

of Npot mixod with the 6011 as aureCA NiAO) 1 Age god At Ures

was also itcluded at rtt t 05 10 end 15 of Upee Theas trealshy

onto were followed 4 wpdrsetago of U s AN wre 4C 10o or at I3n

Weeks toulin up to IS pot

A soil application of 10 pot rosulvod to the maim yield

at 4 weeks Tio4 sad percont prottis t intre raite tncreased rftishy

linearly with U applictalien IeseeItally all at the m iNd wit

the moil w domitrifted after flooding Grail end straw Ilelds vere

highly correlatod with tiliriag and vlh ubers of gralm arl

The results Widicat that 0$ to 10 a of Upot as orea or

NN bsuld be sied with the oil to stilate tiilrir with adshy

ditional 0 topireased later to increase grain lIds mad protia cmshy

tout

DIVISION 54- FERTILIZER TECHNOLOGY AND USE

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-02

792 60L WI W A)49R Pio VOL 37 197)

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DIVISION 8-9-SOIL MINERALOGY

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65

0IL CL OC AMXR PROC VOL 38 1974

)aT1 S4I104 ow Lusanll Tawng isa tall Thai variety known for beingIwo nonshyi s s ) sensitive to photoperiod A split-plot design was used in

S e e these euperimeots with 4 rates of P (I1 22 44 and 88t i V IV k of Pha) applied a main plot treatments and with the OF It sourMes of P as subplot treatments There were two checkS plots in each rmplicate The extra check plot was included to permit the application of fresh TSP standard Jor the

It- ti 06 + i bull fa succeeding crop the p-4me of bi was to permit accurate d awrnwal of the mdual effectiveness of the phosphate

ftinSUbI rock The P fertilioers were broadcast on the mud andthen Worporald In the soil during the last harrowing At

whM N both On ACS indx ampM time of transplanting Immediately before the last harrow61t (4j 5 4 01 P s 3Mm o Vallonal in con n 100 kgha of N as ammonium sulfate and 33 kghaWO Of Spews ampm lIW thaabe rocks do ACS indes of K as polium chloride were applied A total of 40 wa in prepw O do ctih k otent kha of N a ammoniunt sulfate was applied later in twoir P The hew oNed amp wM W for 5 of gw topdrossingp with about 5cm depth of water on the plotsvV I aiOMveffeOctveee Three to six ldayold selings pr hillwW the ACS idex were planted00OWW wia Oft fo an c irNk I p Coen 20 by 20 cm part in straight rows Hand weeding was used

and insecticide were applied for Insect control Grain yieldw was masared by sampling 5 ml of each plot excluding border rows The date of heading in each treatment and theUNiN d pbM W Weks rin tOW USA UMe In Tale yed componnts at hafvel were also recorded

I filM rsperMS esOM kdwdua 1 t ab The average yields of ough (unhulled) rice for botha 84 OW O 8uo 4 Thala TM was a locations are ploutel in PIS 3 for the first crop (1969 wet

owou thRM seaso0) The Veamps yield response was obtained at Klonge (s) W lDtO t Of dMa of1tw W d l R Luang however a 4ute satisfactory yield response was

~Mk ^d TVA UJSD ad Kd UnIveS obtalned to applied P at Bangkhen as wellXUe LaM e R qwrw Ims The sod was do Relative aponomlAe effectiveness values were calculated

VOW (a ksA w edmwL t Poesesm h Vy for these data and am presented In Table 3 The valuesdAY buo if dIe ouh ne Pee wtk a Mlak vow 1009 for th first crop are plotled against ACS index in Fig 41 This Im M i6ti l 4bNd IO a0 O mkarnk for both locatio r relationship was linear for the

11400 ThCpH 0( lb pW IW 01 th UpeiaW so Sanodion location and curtiltnear for KIng Luang The was u i 4A sksamp lMaor nrusio model amparounted for 81 of theAmO$MI Aw jAAsue Swim T1 Snh Wd variation In the AE valu for Bantkhen a square root

Mems a Iw iv fern alh$ sedm haowg dayNW W t he plAL At tdo M tM aso W s as ctminued throufh eltaM t Ofpof -le lse wo am P OeNI VeOpls 1o ealluae tI lon4erm MIdual Offccls

A on W isset i a wse to hsh eapeel of these ooihss t ocks The baagkhon experimnent was letmiaI1DlVemisthis is a w hulu Lo g Tasug ia iasael aft - Msd residual Ves will be pr-Om crok TheseTwod esewm

SWWo

A

lP~U~7 ISIIPe1iuIWN e bsedisssin ian ghth siaoelalbe

984 0 6 O O - M s -s fWPas 11eSft W d Uo al a o

o

S4l~ lIIII I~l I 1f fl

( +

+ + + m + ++++-

++ +(++ + ++++ + ++ ++

- 66 -

ENOIMLSTAD ET AL RESPONSE BY FLOODED RICE TO PHOSPHATE ROCKS VARYING IN CITRATE SOLUBILITY

I I I I j0 I I

BANOKHEN BANGKHEN

pH 56 6 - 0o

TSP

NC

5~ ~ ~ L o 4 - -shy

4 ] - --------shy04

6S

|0 III 2 44 8r 66

I I I

a 1KLONG LUANG

pH 46 z KLONG LUANG

TSP Sc2 NCFL(N)

5 FLIC) J0 TU

oshy

4 ~40shy

3 bull eM0

I - I I I I I

0 II 22 44 88 0 5 10 15 20 IP APPLIED KO HA ABSOLUTE CITRAE SOLUBIITY INDEX

Fig 3-Yield of rough rice at Klong Luang and Bangkhen Rice Fig 4-Relative agronon effectiveness () of P sources ploz-Experiment Stations Thalmand as affected by rate and Source ted against citrate solubity Index for both Thailand field ex

of P applied (crop 1) periment (first crop only)

regression model accounted for 97 of the variation in sumably resulted from crop uptake and reaction with the RAE values at the Klong Luang location soil to form less soluble products Such effects may have

These experiments were continued during the dry season been more important at the lower rates since the two TSP of early 1970 to ascertain the residual effectiveness of the curyes converged at the highest rate of application various sources applied to the first crop No new P was These data from KIong Luang indicate that (i) residual applied except for the fresh TSP standard mentioned effects of all rocks except Mlcwuri were substantial (ii) above rhe experiment otherwise was conducted in a man the relationship between relative agronornic effectiveness ner similar to that followed in the first crop of the phosphate rocks and citrate solubility levels was

The response to both freshly applied ad residual P was largely obscured and (iii) the general superiority of TSP marked at the Klong Luang location and marginal at over phosphate rock in terms of effectiveiss persisted Bangkhen In fact at the latter location the response was through the second crop so small that little can be said regarding residual effectiveshyness The yield data from crop 2 at the Klong Luang DISCUSSION experiment are plotted in Fig 5 Greenhouse and field data presented in this paper show

Relative agronomic effectiveness values (Table 3) were clearly that there are substantial differences among phosshycalculated for the Klong Luang data using both the residual and freshly applied TSP as standards It is of Interest to note that the superiority of TSP over the phosphbte rocks Table 3-Relative agronomic effective values for field experishyments in Thailand persisted through the second crop The main difference in KlowlZmlnql~the residual effects is that with the exception of the MIs- s Crop 1 Crop 21 Crop 1-shysouri rock Ihe marked relationship between citratr-soluble WoiCarolina yl 59 76

phosphate rocks and RAE had largely rds norh) a 64P conltct of th Florida (eqlral is 6969 6

disapipeared In this acidic soil (pHi 46) P would by this I14o 69 63 40 ToonesS 31 65

limo be supplied by Intermediate reaction products In addl Missou 0 o lion to residues of the initial spatlte Ts P o 2 o 0

The TSP applied to the first crop declliv-d slightly In campIafcmWataesr e id ofeuhuloefor 22MA rates of PtColeouattd as aba u tlte td18 kS ratesp dlverage yield tM868 to 22 44

effectiveness relative to the freshly applied ISP This pre- of d s4

A

4

- 67 shy

-SOIL SCL SOC AMER I

KLONG LUANG CROP 2

Si 3

eN

TAPPLIEDKGHA

Fig 5-The residual effectiveness ovarious P sources for crop s compared with freshly applied TSP Klong Luang Rice

Experiment Station Thailand

phate rocks in terms of agronomic effectiveness for flooded

rice Further these differences can be predicted by means of citrate solubility or by the ACS index It appears that

the latter is more appropriate where the content of apatite varies among phospiate rocks The most soluble phosphate rocks approached but did not actually equal TSP in limit-iuig (maximum) yield in these experiments regardless of rate applied This agrees with the results of Ensminger Pearson and Armiger (4) One needs to consider the defi-nite posribility of same yield loss in zhoosing a phosphate

rock over TSP such yield losses must be weighed against the lower price of phosphate rock The explanation for such iosses may involve concentration of soluble P in the soil Khasawneh and Copeland (6) suggest that the growth rate of crop plants is a function of P concentration that can be maintained in the soil solution If P concentration is limiting or inadequate becawe of a lower dissolution rate of phosphate rock the growth iate ard uiiimate yield will be diminished accordingly

The RAE values bascd on yield increases reflect the agronomi effectiveness of these various sources relacve

to the TSP standard however these nould be supple-

mented by an economic analysis before rational choice can

be made The following calculations will provide an estimate of

the rclativ ecooomic effectiveness(REE)

Y t Ps aXpatREE -- 100

vahtercks t sphate or e b i- eor

Price of TSPkg fo

be Price of PRkg P

PROC VOL 38 1974 leO

90r

Wsoshy

0

60-LUSEPHOSPHATE ROCK

00 10 20

PTP PR

Fig 6-Relationship between relaZive effectiveness values (RAE) and the price ratios between TSP and phosphate rock Such a figure can be used in making a choice between these

sources

If REE exceeds 100 in this calculation the phosphate rock would be preferable to TSP

The REE calcuktaaa wre used in preparing an indifshyference curve (Fig 6) wherein RAE values are plotted

against PTsPPpR ratios The cu~rve itself connects those points at which REE equals 100 When exactly on the curve it makes no real economic difference what source is chosen After choosing a suitable price ratio one can then project upward from that ratio knowing the RAI

value (or estimating it from such data as shown in Fig 4 using citrate-soluble P content) one can then choose the source on the basis of both agronomic and economic conshysiderations For example if the price ratio is 25 and the RAE value of the phosphaite rock is greater than 40 the rock phosphate in question would be used However if the RAE value was less than 40 TSP would be a better choice There are indications that if the P in the more soluble phosphate ro~cks (North Carolina north Florida central Forida) is less than half as expensivz as that in TSP these rocks would be feasible altereaives to TSP on soils similar

to thoseused in Thailand This analysis does not take into account the possibility

of lower yields from use of phosphate rock In addition only a portion of the various yield response curves was used in this anlysis ie up to 22 kgha Beyond this

rate yield response was much less pronounced it could be argued that at less than maximum yields TSP would produce a certain yield at lower rates of P than would phosshy

pow ofrock This would especially be true for rates applioa example at Klong Luang 5500 kg of

rice pcr iectare could have been produced with either Ii kg of P as TSP or 44 kg of P as son of the more reacshy

tire phosphate rocks It should be pointed ot however

- 68 shy

(IIKIS amp YOUN( ARIFICIAL WEATIIERING OF OXIDIZED p[ll- IV

that this is the yield level that would show the widest difference such is the advantage of hindsight

Farmers generally prefer granular fertilizers for machine

or hand application This is a disadvantage for the phos-phate rocks which are normally arplied in finely divided form Recently experimental quantities of granular urea-

phosphate rock mixtures have been made by TVA Results of trials with these fertilizers will be reported elsewhere

LITERATURE CITED

1 Armiger W H and Maurice- Fried 1957 The plantavailability of various sources of phosphate rock Soil Sci Soc Amer Proc 21183-188

2 Bengston G W E C Sample and S E Allen 1974 Re-sponso of slash pine seedlings to P sGurces of varying ci-trato solubility Plant Soil (In press)

3 Caro JIt and W Hill 1956 Chard eristics and fer tilizcr value of phosphate rock from different fields J Agr Food Chem 4684-687

4 Ensminger I E R W Peirson and W II Atmiger1967 Effectivencs of rock phosphate as a source of phosshyphurus for plants US Dep Agr ARS Bull 4112S

5 Engelstad 0 P J G Getsinger anid I J Stangel 1972 Tailoring of fertiliers for rice cnnece Valley Author ftyNational Fertilicr Developmnent Center Hull Y-52

6 Khasawnch F E and Jane P Copcland 1971 (otton root growth and uptake of nutrievos relation oif phosph

rus uptake to quantity intensity and buffering capacit) Soil Sci Soc Amer Proc 37250-254

7 Lehr JR and G H McClellan 1972 A revised lIbora tory reactivity scale for evaljativg phosphate rocks for direct application Tennessee Valley Authcrity National Fertilizer Development Center lull Y-43

H Terman G L S EAllen and 0 P Engelstad 1970 Response by paddy cice to ratcs and suurces of appliedphosphorus Agron J63390-394

DIVISION S-9-SOIL MINERALOGY

Artificial Weathering of Oxidized Biotite IV The Inhibitory Effect of Potassium on Dissolution llate

R JGILKES AND R C YOUNG2

ABSTRACT

Rates of dissolution of oxidized biotites in OIM 001M ICI are severely depressed in the presence of IM KCI The amovnts of Al Mg Mn dissolved in the first eytraction are similir to those found without KCI however subsequent extractions remove these elements at 10-20 of the corresponding lICI rates This effect may be due to a decreased rate of vermiculite formation thereby reducing the effective basal area exposed to attack A decrease in dissolution rate with increasing ferric iron content was still apparent in the presence of IM KCI

Additional Index Words X-ray diffraction infrared aborp-

N EARLIER papers of this series the tole of biotite in soils

as a source of both macro and micronutrient elements

has been discussed ((Gilkes Young and Quirk 1972 1973ab) Experiments in artificial weathering uiing as va-

riety of extractants were undertaken to determiie the inlu-

ence of oxidation of octahedrally coordinated iron on the bull release of structural cations to solution The results of this

work demonstated that biotite behaves anomalously with respect to the other common ferromagnesian minerals found in soils Oxidation leads to the development of a high degree of resistance to cation exchange and dissolution Several authors have coiwludcd that decreased rates of K

Contribution from the Dep of Soi Science and Plant Nutri-tion Institute of Agriculture Univ of Western Australia Ned-lands 6009 Western Australia Received 29 Sept 1973 Ap-proved 8 Jan 1974

2 Senior Lecturer in Soil Science and Research Officer respeclively

replacement in electrolytes shown by oxidized biotites are

a result of the inclination of structural hydroxyl adjacent to newly created trivalent iron or vacant octahedral cation sites (Robert and Pedro 1959 Barshad and Kishk 1968) Gilkes et al (1973b) suggested that decreased rates of disshysolution of oxidized biotite in 0001 0t)l 0Af CI may also be due to the presence of inclined hydroxyl In this case a smaller surface area external and exposed intershylayer may be available for attack if K replacement by hyshydrogen ions occurs at a slower rate in oxidized biotites

Gastuche (1963) has shown that significant dissolution ofthe (IIM) biotile face may occur and it is easily demonshystrated that the proportion of exposed (001M) face in weathering biotites depends on the percentage K replaced

Rausell-Colom ct al (1965) have shown that hydrogen ions act in an identical fashion to metal cations in K exshy

change from micas In particular exchange c-f K by hydroshy

gen ions will be terminated or greatly reduced by high levels of K in solution Thus if dissolution of oxidized biotite by

acids is carried out at sufficiently high K levels to prevent vermiculization any differences in dissolution rate that may occur cannot simply be ascribed to differences in rates of K replacement The following results were obtained from such an experiment which unlike the experiment described in Parts I and II (Gilkes et al 1973ab) does not attempt to simulate natuiral - conditions

MATERIAILS AN) M HIiODS Further subsamples of the less than 0 hiotites used in K

excherandbaid disoo tu es (G iles e9n K exchange and acid dissolution studies (Gilkes et al1973ab) were used in these experiments Preparation of sequentiallyoxidized biotites without intermediate vermiculite formation is

Page 34: I70 - United States Agency for International Developmentto ascertan, but tgl.eetad, 1, L,. ("Tailoring of Pertiltiters for ice,'" TVA ulletin Y-52) states that the staft of IOi has

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Tabl I

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W Iotors Ftslanp tospg Irritd for Two thvk Afler flontiw wft rkwa~ Floo4d 191)

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- 38 -

Table 18

Yild of aemati-370 Rice at Punjab Agricultural Research

Institute in Pakistan in 1969-70 Grown Under

Couditions of Intermittent Flooding

Pate of application

=IL

o 0 67 67 100 100 67 67

100 100 67 67 200 100

Average for Sources

Ntha

AS 260 gres 279

320

Source f5

-

AS AS Ura Urea SCU SCU

Yield

Relative

93 100 115

(M)O

Yield

Increase Yield Due to N

(Ktlha) (mtha)

-212 245 033 274 062 260 048 297 085 315 103 325 112

Yield Increase

Relative

72048 067 100 108 161

(2)

- 39 shy

Short-statured high yielding rice varieties grown extenshy

sively in northern Peru require extremely high rates of conventional

N sources to achieve maximum yields The recovery of applied N is

extremely low due to the use of intermittent flooding This water

management system results in heavy N losses even with properly timed

split applications In search of simpler and more effective methods

of N management eight field experiments were conducted in the region

to evaluate sulfur-coated urea (SCU) an experimental slow-release N

source supplied by the Tennessee Valley Authority Rice yields were

increased an average of 59 more by pretransplant-incorporated SCU than

by urea or ammonium sulfate applied in the same manner SCU produced

excessive vegetative growth which resulted in yield reductions at high

N rates

Regardless of an assumed 48-higher unit N cost in SCU the

overall benefits of pretransplant-incorporated applications of SCU

were favorable since there was a decrease of 40 in the optimum rate

of N and the need for precise timing of application was eliminated

Pakistan--In Pakistan basal applications of AS urea and

SCU to rice grown under conditions of intermittent flooding in 1969-70

(table 18) indicate that SCU is a superior source of N as compared to

urea or AS when all N is applied at or before planting The data also

indicate that a yield response was obtained for P applications but a

comparison of N sources at each level of P indicates that no interaction

between N and P was present so that differences between N sources were

relatively the same at each level of P Yields were increased about 60

more when SCU was applied than when urea was applied Yield increases

with AS were only about 72 of the increase obtained with urea these reshy

sults do not agree with the generally-reported superiority of AS as comshy

pared to urea as a source of N for rice

- 40 -

In 1973 experiments were conducted in Pakistan using both

Basmati-370 and IRRI-6 varieties of rice grown under conditions of

When all N was applied at puddlingintermittent flooding (table 19)

or 12 at puddling and 12 at panicle initiation both AS and SCU were

superior to urea with SCU tending to be the most efficient source

However when N was applied 12 at transplanting and 12 at panicle

initiation SCU was the poorest source of N This would indicate that

the release of N from SCU applied at these times is too slow for optimwn

plant growth

In another experiment in Pakistan in 1973 no differences

in the effectiveness of urea AS or SCU were noted in the yields of

continuously-flooded rice (table 20) Again these results are conshy

sistent with earlier results which indicate no superiority for SCU

when rice is continuously flooded

Nitrogen Studies--Maize

A series of three experiments were conducted by IITA in

armo-Nigeria in 1972-73 comparing AS urea SCU and

CAN (calcium

nium nitrate) as sources of N for maize (table 21) A significant

yield response was obtained for N at each location but no conaistent

differences were noted amaong sources These results are consistent

with results at other locations which have not shown that SCU is a

superior source of N for maize grown over a period of 3 to 4 months

Nitrogen--Wheat

The yields of wheat in Pakistan in 1969-70 (tables 22 and

23) show that yields with SCU) tended to be lower than those with ureaJ

although at one locction where sorghum was grown followilng wheat with

Table 19

Yields of Basmati-370 and IRRI-6 Rice at Punjab Agricultural Experiment Station in Pakistan in 1973 Under

Conditions of Intermittent Flooding

Rate Yield Source of N Time of Yield (Mtha) Increase of N B-370 IRRI-6 Application Basmati-370 IRRI-6 Average (Mtha)

0 0 - 21 353 287 -

SCU 90 150 At Puddling 325 545 435 148

Urea 90 150 At Puddling 309 500 405 118

AS 90 150 At Puddling 324 529 427 140

SCU 90 150 Puddling 372 572 472 185 Panicle Initiation

Urea 90 150 Puddling 335 502 419 132 Panicle Initiation

AS 90 150 Puddling 353 529 441 154 Panicle Initiation

SCU 90 150 After Transplanting 312 562 437 150 Panicle Initiation

Urea 90 150 After Transplanting 340 624 482 195 Panicle Initiation

AS 90 150 After Transplanting 349 583 466 179 Panicle Initiation

All plots received 45 lbs P205acre as single superphosphate

Relative Yield Increase ()

Source of N At Puddling Puddling Panicle Transplant h Panicle

Urea 100 100 100 AS 119 117 92 SCU 125 140 77

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aI~

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of~~ WW ii4 fia to IW41d4 OW 44tfMwf~ f 400 I~ 1I404 sr wii w4ft43 ~o

m FFO t 4W iFO 4AP 6WWt w0 I 4I 14f

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mtbeft t~t fr~ 0 Omq 01 NoW Otfw wk41 4)

O4f ofSWsowfW W aaoq fm~ MOW 10d ANN W 4 4w fO44o0

StOowew ARM4 WON tffas 0t0ff1 OIPsem Itf

9w NOofb rsrft s fw ~ w-o 4domw op

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wt it14

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ow tl

eIa 4tiamp tbat O14 w44m mAqi~f~M0Il

p itt wt M 4441 f l T aw IlaI~l vweAUl

0 04 M 4 iU4eOW

fi~qr 14edqAs 1W44tMiwty w It 14C

WOA Y~U i44001r i U 4

cb o~t

f~~~~~iqt toitib ws 4 ~t4p6W1 1 i1 a

I~oil~ It w4M

mt4o Ofu~Mampwt i oe 0a 1~4tatlt~ 14 wlpo 0amp p

p~ to Ai~ f

bosom

~ ~ ftfW

W~ t tieiis ptooo 00u14 ie0

by ~ ~ ei~t11i ~~t

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mwt Fwaabe

ItM 1 sIM~~slieg~ ~utom sdb

-48

Therean laiictw that It lbs P to th e am lukis

obosomhu rocks 0entk catetas rth Unrtdo costrat frwt) to

ht tse balt s Owosiv as that to TwP it rocks WM bo

fmtbt alteruutiv to MSso gotastte to~ Ik lee used to

ThUAIAd

Tht wMl dt gotmtmlaoti wout th possibility

of law Vhld free ww e1 e66001 4 It cooUt be YgWd Sutt

a4 10 0410 SWUSSM yt$4e TOP wUd predWr A r~ftIf fl~W t

1f f ot P the wuld phosphae rck TWOe viWMW efocitill b

true to low rttos t tsplusatiI P wi 9 Ma Liiam $S

amp4at r per Wforssota Mav two 64eed Wilk elikor It 44 of

P go Mi er 4A bg oftoP aon of tewmrowtni pboophals fwAh

It vwld be polotrd A Wevero wtht Is the jteld level that

W414 gk tko videm dtterem~j o(A 1 the 4~etamp tk~e~t

P11~0 pra~lpj prefer gre4r tuftlter for whlae

of hoaw ppltrstie Mhe to a dloedveaP for The PINSOO rocka

vkth m r II spotted 10 ftewil 4106Me tem

Nub studios we ovsosd o IVA vol gramleid a

forgof wee aMW pbsepbots A fths pemhawe evsielew us

Odellod to detMlee it otteettvmm of 11agotated Stoture of

mmfp MW phapa A (CI) sed graewletod pampAtlti arlolatod Pa

asowcs of P tof ttde ro The wreem proucts omre raGther

pemour~a ot P syag besmti andMi as elt ov so gpamwhr

iuipiqffhate(TS) low twseeo Is eftwiltve Is thet

W41 preeme wae oialain ire post-rItoi effriq to Stanlato the

pud6itt of Irto paddle Wee ofsdlseireplastiq

0 49 shy

lbs partially scldiaatede grawilated Ml prodlucts Vere isshy

toiwdiats in 5tftOvttWS54 betwee wroiPi ad TVP NotV5Ymf to

me coo were they mere twoe $a a etfective ao TIP 00 sipifleast

LVSUMI5 at0 efecto wore toun tor thee produteo Timely dtIampWde

FR (-t00 mmoh) Uia amp~rally oar affective than Owe gra8448r FOampprodt

featal twos o 6 aotetire s I

Nowvero it to felt that sfortber field euprtet vth

hese interials Amd ether typs of grometatodl Wter nre wrrautad

hater ceeuwodh that they have me areec poteatlal toi additoG

e tate wAne the sectte as OtawrI sed bovoloen turther

euperimeste vth few reck pboophar s0d with reck pbophat treated

to sehesa citrata selmtliy or to ha csaducted

Metbir sertes of tbme enprtaeats wae c~edtmcted by IITA

to Ut~rta copal TVP AOP APP aed it at see tecastisix (table 14)

No dot lalt sewseltles teh draw tree thee results simouely em pear to tlvdl bsww they do stwgpt tbat forthew work with

MR to werramid so tbme sels

Table 24

LttcttF Swce MaPlate 06 ieldot IM AWaia CoelsANS at IITA (Ugboda ad Apoin ail sorit) aid at Ike (AUaba s5i series)

1973

Plate ot IP Apinu 5 poundebods A1ab

Ocrol 0 Z94 419 M)

Tr ipl ruprphite 20 349 3799378

Triple vepput 40 M09 410$

Triple 6wp~~b1 4271 4344 42250

Ammotw-ritpophW to 4201 4124 4040

Amosim-rdop~phlt 40 4270 4106 4231

AM tuo-polpephats 20 404 4244 3794

~eai~mpelppepbuI 400)49 4094

Cee m-pbpbt to- 59

momee eph lto 0 4192

LSO (0 0$) 29 1025

Th WPII

- 51 shy

101Y114 tpeM-fI PEP~tbRP YO

1 ~ ~ gmw 1pc~biofl- 9 Kla4v4h

Upia U04 Copfind am Crehout Stet Rpano at (Ia4

rico t IF t rume6 orth~ Caralto phoophale rocl QAR) vaUN pqU41 to

roopon from cmonetrat4 gsporphophai (CIP) who ort$o4 oil k

was 45j itwas tafertor vb protioo4 oil p war OS Ib 4iffer~c

in rtc reepos to X cod14 oo bo ttrit4 4 4 hvsciag of boil p

~ Pt o r11221 0 tP

c theto the rhimecyllndor of rico tots par to)14M4i1 roeoi~t

ed oil emd PA prior to tho ont of an~robi4 cMioe AA~ oIifoshy

nAte bYpot t taet~d tO fC4sin t~r 4PWden0 Of f Ot(tivshy

ofOWailiJtyno o prefla4 all Put that 4t01etoo 14 tvsIk

of the Ott to prvvld a 014for C4m0 44 mI 1 o4sf

EfftC ftPet141on AIAM-0 V f401td 4 4iv 440 Mtft

Aa torfat VampP f4MWfCi4W04wt0amp to 4eturWlI Ot(Wel~drIC ft

Ot f tM6 the flooded Ott 00 14 04019I Pft0uAw Of gAr~s~lr

pkS$t M40b MP) Tw P1101 Piset Prodwie W-e 10M0di Wr04

(10-1) emW 0aretilp ddw01at4 P WAA firom Rrth M~flRU414~$

wee cowiared with fie Md reWim 44104 proo~fo) foruk oith laWItter

I v te-PR P OW1004 4 4 O Wf ottil OW ellt Oo

Oveiel1 the 40tt dmcruie to effetotww Wtollowui Co fme

PR tpaUIB1I ldoltmo PR (pamwlatr) offr~- ArmeuM) 0 orwi

- 52 -

Effect of N Sourc6 and Water Management on Response of Rice

toe Zn- M Giordano J J Mortvedt OP Engelstad and Greenhouse

Staff Several rotes of CO(14H2)2 and (H )2So4 vith or without ZnO

wore applied to flooded and nonflooded Crowley oil (limed to pH 75)

to determine response of Bluebelle rice to Zn Yields with both N

sources veotrgreator on flooded then on nonflooded soil In the abshy

ence of applied Zn total dry matter production vith CO(NH2)2 was

slightly lower than with (NH)2S04 on flooded soil and considerably

lover on nonflooded soil Concentration of Zn wan higher in straw and

grain of plants roun on flooded than on nonflooded soil Although

concentration of P was unaffected by N source or Zn rate there was

som indication that cranslocation of P from straw to grain may be

depressed in nouflooded rice Concentration of N was lower in straw

grown on flooded than on nonflooded soil due to apparent dilution

thereas both X sources resulted in similar N concentrations in straw

at all rates of N application the N concentration in grain increased

with 0 rAse

feSpongi gf(SM to Chjorospodiostte and Related P Sources--

Si Allen and Greonhoue Staff A greenhouse pot experiment was

couct44d with corn Brown on Hountview silt loam to compare the ofshy

fectlivees of chlorospodiosito (Chlor-l) with concentrated supershy

phosphate (CP) Thomas slag and North Carolina phosphate rock (NC-PR)

Oil-prillad urea-phophato rock (UPI) FeA1JMP 20 7 and monomthyl

phosphate were included in the experiment Based on yield of forage and

uptake of P by tvo crops each of 6-weeks duration the following conshy

stui were dravat

I Chlor-1 was slightly loss effective than CSI Thomas slaS or NC-PR

from which Chlor-l wae prepared

- 53 shy

2 Granular UPR was a poor source of P its effectiveness was greatly

increased by reducing the particle size to -35mesh

3 FeAlNH4P207 was unavailable to the crop

4 Monomethyl phosphate was equivalent toor slightly more effective-

than CSP

Research Indirectly Related to TVA-AID Project

Response of Several Rice Varieties to Zn in Moist or Flooded

Soil--P M Giordano J J Mortvedt and Greenhouse Several varieties

of rice from Mexico and the Dominican Republic currently under investishy

gation in Puerto Rico for adaptation to upland culture were compared with

some established United States varieties with regard to Zn response on

moist and flooded Crowley sil (pH 75) Chontalpa (Mexico) Bluebelle

(Texas) and Starbonnet (Arkansas) were most responsive to applied Zn

Juma (Dominican Republic) intermediate and Sinaloa (Mexico) and Calrose

(California) were the least responsive The Sinaloa varieties (Mexico)

appeared to be best adapted to non-flooded conditions whereas Chontalpa

and Calrose were poorest Concentrations of Zn generally were higher in

plants grown on flooded than moist soil

Pattern of Growth and Zinc Accumulation by Rice--P M Giordano

J J Mortvedt and Greenhouse Staff Rice plants were harvested at weekly

intervals from shortly after emergence through maturity The objective

was to determine the rate of growth and Zn uptake by a Zn responsive varshy

iety (Bluebelle) and a less Zn-responsive variety (Calrose) in the presence

or absence of Zn applied to Crowley sil (pHl 75) Dry matter production

of Calrose was linear with time of growth and of a similar magnitude until

heading with or without applied Zn Bluebelle followed a similar pattern

where Zn was applied However in the absence of applied Zn foliage yield

was reduced markedly

-54

Uptake of Zn was similar for both varieties whenZn was

applied Dry matter production and Zn uptake by the two varieties

also were comparable when Zn was applied However yield of Calrose

was much higher than that of Bluebelle in the absence of applied Zn

while Zn uptake was only slightly higher This suggests that the lesshy

ser responsiveness of Calrose to Zn may be due to more efficient utilishy

zation of Zn There was no indication of a greater demand for Zn durshy

ing reproduction in either variety as was suggested in earlier greenshy

house experiments

Response of Upland Rice to P and Zn--P M Giordano J J

Mortvedt and Greenhouse Staff Several rates of P and Zn were applied

to Crowley sil (limed to pH 75) in factorial combination to determine

whether differences in rice growth under flooded and nonflooded soil

conditions are related to plant nutrition Although straw yields were

slightly higher in nonflooded rice receiving adequate P and Zn grain

yields were higher in the flooded crop increased rates of F andor Zn

did not result in equal yields Except in the highest Zn rate (75 mg)

concentrations of Zn in both straw and grain were higher with flooding

Concentration of P increased with rate of applied P and was higher in

the grain or flooded than upland rice at a comparable P rate In conshy

trast concentrations of N were lower with flooding due in part to dilshy

ution from increased growth

Rice Response to N and P in Flooded and Unflooded Cultures--

G L Terman S E Allen and Greenhouse-Analytical Staff Rates of

N from 250 to 2000 ntpot and P from 0 to 1000 mtpot were applied for

Nato rice grown on Mountview sil and Sango sicl (625 kg of soil per

pot) Market yield response to N and P was obtained Yields of straw

- 55 shy

total yields N uptake and N recovery were higher on unflooded than

on flooded soil cultures Grain yields however were slightly higher

with flooding These results indicate that with adequate applied

nutrients especially of N rice yields without flooding can approach

or even equal those under flooding

Uptake of N P Ca Mg and Zn increased with yield response

to N and P while K uptake decreased on the Mountview soil Concentrations

of N and P increased with applied N and P respectively while concentrations

of other nutrients were diluted in most situations with yield response to N

or P

Results from this experiment show that amouats of N applied in

previous pot experiments for rice have been much too low especially if the

crop was grown to maturity

Response of Corn to S and N i UUASand Urea-S--S E Allen

and Greenhouse Staff Three greenhouse pot experiments were conducted to

measure response to S and N in ulfur coated urea (SCU) urea amonium

sulfate (UAS) and urea -S as well as estimate N losses from surface apshy

plied N sources

In Experiment 260 less than 20 of the S mixed with the soil

was recovered from SCU or urea-S granules by two crops of corn as comshy

pared to 45 or 80 from flowers of S or Na2SO 4 CLop response followed

a similar pattern

In Experiment 260-A N sources were surface applied and alshy

lowed to dry for two weeks before incorporation Into the soil and plantshy

ing Recovery of N by two crops of corn was 77-82 for AN an compared

to 37-70 for urea UAS urea-S and ICU Thus n this experiment loss

of N from urea did not appear to be re~dcud by light S-coatlngn or by Inshy

corporating S or AS in the granules

-S -

I xbprZnSlt a Wtch aU Meyto 0-Ai Wt f9r

higher reermo teOrtOrs cOM reSpWNO i r0100 Of N w

not oaisteontly related to sewe ot N In edl tust 0 ioltiUe Lim

lo in VMuwpped evlmtUTS 48 merind by seirest nte appresOehe

501 for uroa as cwarod to 210 for urea peepha

Rus- or Upse to LoAmIl34I a AriMed bI Earl U

MW NOWlsIIsIr-4 L Toman 5 1 Alln and eesese StNf rio

row on Sawg did (0 tpot) We 1l0l0 Ws feritiud vith 05is

of Npot mixod with the 6011 as aureCA NiAO) 1 Age god At Ures

was also itcluded at rtt t 05 10 end 15 of Upee Theas trealshy

onto were followed 4 wpdrsetago of U s AN wre 4C 10o or at I3n

Weeks toulin up to IS pot

A soil application of 10 pot rosulvod to the maim yield

at 4 weeks Tio4 sad percont prottis t intre raite tncreased rftishy

linearly with U applictalien IeseeItally all at the m iNd wit

the moil w domitrifted after flooding Grail end straw Ilelds vere

highly correlatod with tiliriag and vlh ubers of gralm arl

The results Widicat that 0$ to 10 a of Upot as orea or

NN bsuld be sied with the oil to stilate tiilrir with adshy

ditional 0 topireased later to increase grain lIds mad protia cmshy

tout

DIVISION 54- FERTILIZER TECHNOLOGY AND USE

N$eumWe of Mt5p4Amomd 1k PindW hswk4PhI fl fRw cW ims we

Jmnwacr VW owm m

a~~00 - 0 6 A-~ -~~ PN 40OMOM X 00 Wolm n moo mot $Pto4I 4l 4 W

1 -0 Is vom omoo ~~o - W1 sfw 4E00-aU

WI pw shy-M Iampeo _10 00 mo N - o wo limoshyM~m a UAa oomw W0- -0 f40 44 MP 0v~f04i-lsm 0 PA 40of 0 0 W -W ov a Wo 006

-n-t -4adf -m W ftf

9P~~aw otom i ow sm li ilia it - ~0~f 11 40S adob 11-11 __ 9w

i A ~~~~06o ~a A VOW 4 WK-ok rie Ww -0 no 4me

00 to- W 0Nwo ww AO t

-t umi om ftaw-0

- - lh -i N N iiSolf so -ma w vow -mv__M

-~AdAjA- 44 ow 0ma 0MAW a war -mo d0 00 M o WooP 0

0kR N4 a~ow Mf o

- -kn Am C4 pos 0 WW -I

to$w formoop 1 so

Qm0fte Iwo 00 SAtow

a

WPMaa~I m ww

lvZW~16W IT

I

vt~~ - foa Gom

r-7- tw

A ijdMA~ trMO

otait m adtoo iMOaiq

sMs aIwO tP- owWIs

mU MW4 0e S w 96 lo ow- CO=

I~

bq

-- -P~~~~ -- M S um IN 0VSAww dvIs0O E0 two I 41

OV WNA w N$ lp It 40A 04 ON w 0^ 0 PW1t~~~~~~~dap~~ frO

Is WAV OUw Af 41W 0A

1A 0

1o wI0~ WSW adWOWi

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w m wO~ WWF __ootm

Wm^~~~~~~ ~~ A tookoto 00wmf

M~~~~MOt 0f O

040 wd m40 Awowmm

bo^ w

ro a W4

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womb ~mmnt I-VI~ bp

5i irn0 pwm k~ oiuwe OsMn0 Wsw e Wr~m mw6

_______Noon_Iamp__ arn ag bos m W we ap

=ib ad a $4Ws Om ThSU

mod m m406mi 1m towir - m bowI~~~AV UPuiWd a04aup hwu 000sW~11lito -- o ~ImWq mow~gnn w a ho emotwi

4~ 49akduemg6momm ~ do nedOwrnd~ o

ICU wONMOVAON w4wWR - - o 44 O Tha 40 pu4 am

hum 11 is 4111 s - sg am VW f wq 4WuM dhCi m ehamv alpso 0

-w No memwiauu so-s 1141 -f oer wwn malow Wufmmm inM UCd m I a to dip 90

- ~~ w emw euIv oflme em ~ ed~faiOeWMOWleA fC~ dim~e4s- 1um00 s uwos w siwp 3 0V es wiiu d um w

aram ad as~6 ma pgt -oI A -$-d r00= m PW Of

ff~~~- am diwda Vs Wow at 4g eltpowm woo OI teeMA AMamdmOMisan A d1 Tm WNW m4 uwwemm mmmM

Aa It mom A I b 0 ~isi ~amp~V5on m ad No wwho 1 $IV Am t t~i mmOwm a- S Am im spwwmft KV-b Osiswvn wogie

opoOw suf No~ Ow MW MCI pt~bi asiwhNd bl-d muim of woo w NN

toI4 0 06d 00 wo A Md N WILSAl DuIKWION oo A Nw U am ONq ep

ow VAN pmw amp4 li a4 WdUb p vw sopwaft a-ftgw -ee theptd OW 6 - a

at MW em matshyW M offm of4 W twampwmwausoo wo asdm65m Auamp Ahbwu in 4ih asTal ON~ al oem IN Maie dmAd A a own did ofe w17 I inM mimman Ofd ofimruwf gas Pius di aMe Kwe auw a dow iNPOOIN tmo a SO$SO~4W

MWaSM BT ALI Mh USIA UW MlO RMC i WOW TW A-~ka ad 1 1 li laiiII111I

0 -6 -1 -- - -- Ie-- - -shyis

101 ~

alm~ sas ~~~ ms a a~

ase appuadmen 44 ea ad semk Who pm4WWS lowftsIU wo WOMO dobowl ICUSJW h

A Poad KU apbos as dw sileft in as a aWhps k asIU__

pro alfp al 0 WN Is obaml~ of th es Wls pouvy Ofts oeWMed N

$ae fapree ulesaseup IfIwotohaffe St

40WilinAn 06 kw Ma ho 00 e IW aftakrw splerefAnhffsb m esmem

I$Ow Ip ampMI pasi 1ead eu an Toud 2l

Widj 6vi of V46 745WI KU waso-W im Wow 0 is610SWAOMMwasa to t

VAp 1Mampd KV ppu~s dw whaim $i a a los Al w W

Ib Milvo urns of OWe d- musA as h~ s a IuIow 8 1 ue ip

-Wlidswf of 4 ofatsIW5vsS d M M5 i RSa pm~daps In ampup 1Powworw rue hevi A b

el eas goileN ruseW4 wo duffeeme bWOM isttouwi

14 gnp40 woSalrw 11ylo amreu Mwb Isevlow roosmN~ahIt s 60 W ~tsmAIM L n ~ ~~ ~

MM I PWrawA = rMla yowIeM oa

eUW as ymlh OW by IONamph avWlbl N The mubsr 1MM Pude M~ IsA aemOWeld

IWOes A rspeas Owed ai udlWwease

por bre

wals rIs O touprua KU=plaINamppNOMeses a

W UWhk 0 ASOoml ft A poWsdvutA adesae of amr Wns ai A 0r- 1ampdd Oehs IuRawy NO Pue podllosWewwe gmak asmpnle by dMiss is amle OWN pet -W yid I MuC)ad ampAn (WiplaeT16s mOW aOW aNo fhr ft ymIed------ obealud w3t 0 OW 40IsA a VM bpR ofthW d saw ns m aI efes R 24 ad 7

e 1 d

Ii

Iw NO ~sp 44I0 so

~ ~ I $4U tml

Tile 4-00dw x uiampOW74u 0qee of

_____k _ _ shy

~ - 56I 5

-f

irenY w -a

Tiles I sed I thm Au do sel oeppled upaoIks WIM0 0da ispI amd us Ou s 106 kg

h Eaap 8n 14 sMsa of abw~greuad PU Pau WW 1 u itb IUKho 0aaphelem s 60 Otarlmmh At ~ 0sU Ishiseoo Cook oiA N uiplasu mAasslaly abess A leel

v doese a WKWye Is ks Nha m 6 sa4to dafo aONmuw The appee swm Wsssof adde N4 alalaed by vuMb ifaa W C Was sekilumganSro Is

bs eabI wish as aVWWa uwewy nap (f5s)f ad Mashes reaMeY valaes of 48 0 S414 CWm

owdb imto US Wh s vs sf 3I mld 54S fro 2 aMd 3) A A

valves a hevwae u Iar Walh basl oswas dhe uwpatr bshava of

tb~msusasl appkausu of ofta sede s have aoweN

TOW opl taoe for AieweeW 4OsmWMbas Op peas As Tabl 4 sling sob Os awowully eom grams Piel level Thes oeulam Ma sed as IM

-02

792 60L WI W A)49R Pio VOL 37 197)

primS o r OeampAd WU toa Them fl~ w At NOSSe earno maisslea Ia N he mOWamplIO yik ampWd IMe aampWmW OWa Owe wa UMs of KU to 41 Oke ampWiiIamm be dkrnety ewspokawleM(a s8 te camtd wie a eapmoe by TVA pavw ltoi NA poundrmdaka4us vrimeW460 o to ilkidm ofWW (Mtemas MuOwe 1973) TVA mwi bawld on soi ficedims IampWp seg rudwiv s~s0abet ke WNmdoe ON 01 K Is12 NOSW ie fssewnmu Ie I QvaaIi rowp IMA) f9

)amp m lodk byO voebmsaIS8OpeaWfrats 11 OWNmi a I a W idisod 0 81 Now 111 nindat Wm fysmpseaamp (If tsO tUmtI IsM $P shoroV4mmo knflkvnf (foOdme nuw ae Ow OImstwe in SM pnmm8 af tXm 10 114PIS kequoian wo Mpfii

SC~po umd spop~o VWt alm 4emWal 1 4ink PCmirsra M 1 ad AI 14bmms

1MM Ww Even to doe shw wisht b-o -Wamp Ekb fed rbaimpal of14~ Am Smpound oS mv fAaMda

MGMe -M4 Wg kmuwadM 1Wr wih SCV4 Psmuck Wff It dlL Wm 1W led 0 1 oo teeA of aiwaisme aweeoid h

1Kach Vt V amp4W ILK t)sa 10 Nareps vm This ndY ub thee hbow apiptomuasa of gulfu-aw~sd of Cup lP~~tamsl wi(i

Woeo of woo or mlm Wmiot InIasem~Wsy (heede 6Am 0 F- ad PAicv IfM tsoPm 9W famp kw~is 04eet The r4 ggm I ampbpiIs OnwAu 4nvmkstm v PAraem A4fshy

e W d inSIWfh sil $ad doke IaefitV twoer) 1 Te to theo owie effu so booJ imik WOi 100 N

-d

Is re4aled uIwq~e~w Aueee atofurnw di Capsnm ptopeatls is a oommm eiws to 100 tom of 04404man d CtdUW 4M Anw K~a do Aamp apowee WPUaN powu eel H pae iaaa thAi SCUI isWW owr hmem ISsuppl N to the li ieee F A IM1 Nampa Obo~amie m

41MB ~ ~ m ~ ~0 0-- 0 140 The ffsemn of food Nn else9~e(Ud~ ~ ~ ~~ WooksaS eAWw pjed of ho~raw of IU effadam vfdva oft xhj0I 13iAl

DIVISION 8-9-SOIL MINERALOGY

Amorphomw CeetIup en XmWra Ssrfmls

L C koits Am~ 0 tmmkaAf

ommp A faieiaAMTRACT skiwe lo nW ampM sm wi4h

Walo by a onMm I dmivid hseidm6Wlk W~edesie s

peuiieles as is s e wpwigstee eded his S -em -om 0641 h4 hisW1mWOWb~ bfem peess Wimm kv Iee

Pa~~~eakr4awiS SeUeeiNaiA WOW 14e

PWWWW t HW f hea~I~~~~~a 0th

kog Ii ampI b 1111h1atAmOem aid itsaere~m-aelmoeug toolPe aal 111W mWa Wisg ag so~ ti~Wo booviot65k Th eme Iua 1111411uiwon it es 01000 AW~CWS ~muiseeteqqsheer21111 ionev

oO00 llb K0 ibad~ ~~ doj 140WI s o mimdW um

WLIMmAmMVL 1

lill mi oHow al of a be 1974oyais4gamm wsoc wwo

rdy i of OMAN toblind id sh os 00 IN bei m us salqs m kid Vw 1 a0Msw WFW isms waf e eeiWei he-4~~e gsa dulsi

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65

0IL CL OC AMXR PROC VOL 38 1974

)aT1 S4I104 ow Lusanll Tawng isa tall Thai variety known for beingIwo nonshyi s s ) sensitive to photoperiod A split-plot design was used in

S e e these euperimeots with 4 rates of P (I1 22 44 and 88t i V IV k of Pha) applied a main plot treatments and with the OF It sourMes of P as subplot treatments There were two checkS plots in each rmplicate The extra check plot was included to permit the application of fresh TSP standard Jor the

It- ti 06 + i bull fa succeeding crop the p-4me of bi was to permit accurate d awrnwal of the mdual effectiveness of the phosphate

ftinSUbI rock The P fertilioers were broadcast on the mud andthen Worporald In the soil during the last harrowing At

whM N both On ACS indx ampM time of transplanting Immediately before the last harrow61t (4j 5 4 01 P s 3Mm o Vallonal in con n 100 kgha of N as ammonium sulfate and 33 kghaWO Of Spews ampm lIW thaabe rocks do ACS indes of K as polium chloride were applied A total of 40 wa in prepw O do ctih k otent kha of N a ammoniunt sulfate was applied later in twoir P The hew oNed amp wM W for 5 of gw topdrossingp with about 5cm depth of water on the plotsvV I aiOMveffeOctveee Three to six ldayold selings pr hillwW the ACS idex were planted00OWW wia Oft fo an c irNk I p Coen 20 by 20 cm part in straight rows Hand weeding was used

and insecticide were applied for Insect control Grain yieldw was masared by sampling 5 ml of each plot excluding border rows The date of heading in each treatment and theUNiN d pbM W Weks rin tOW USA UMe In Tale yed componnts at hafvel were also recorded

I filM rsperMS esOM kdwdua 1 t ab The average yields of ough (unhulled) rice for botha 84 OW O 8uo 4 Thala TM was a locations are ploutel in PIS 3 for the first crop (1969 wet

owou thRM seaso0) The Veamps yield response was obtained at Klonge (s) W lDtO t Of dMa of1tw W d l R Luang however a 4ute satisfactory yield response was

~Mk ^d TVA UJSD ad Kd UnIveS obtalned to applied P at Bangkhen as wellXUe LaM e R qwrw Ims The sod was do Relative aponomlAe effectiveness values were calculated

VOW (a ksA w edmwL t Poesesm h Vy for these data and am presented In Table 3 The valuesdAY buo if dIe ouh ne Pee wtk a Mlak vow 1009 for th first crop are plotled against ACS index in Fig 41 This Im M i6ti l 4bNd IO a0 O mkarnk for both locatio r relationship was linear for the

11400 ThCpH 0( lb pW IW 01 th UpeiaW so Sanodion location and curtiltnear for KIng Luang The was u i 4A sksamp lMaor nrusio model amparounted for 81 of theAmO$MI Aw jAAsue Swim T1 Snh Wd variation In the AE valu for Bantkhen a square root

Mems a Iw iv fern alh$ sedm haowg dayNW W t he plAL At tdo M tM aso W s as ctminued throufh eltaM t Ofpof -le lse wo am P OeNI VeOpls 1o ealluae tI lon4erm MIdual Offccls

A on W isset i a wse to hsh eapeel of these ooihss t ocks The baagkhon experimnent was letmiaI1DlVemisthis is a w hulu Lo g Tasug ia iasael aft - Msd residual Ves will be pr-Om crok TheseTwod esewm

SWWo

A

lP~U~7 ISIIPe1iuIWN e bsedisssin ian ghth siaoelalbe

984 0 6 O O - M s -s fWPas 11eSft W d Uo al a o

o

S4l~ lIIII I~l I 1f fl

( +

+ + + m + ++++-

++ +(++ + ++++ + ++ ++

- 66 -

ENOIMLSTAD ET AL RESPONSE BY FLOODED RICE TO PHOSPHATE ROCKS VARYING IN CITRATE SOLUBILITY

I I I I j0 I I

BANOKHEN BANGKHEN

pH 56 6 - 0o

TSP

NC

5~ ~ ~ L o 4 - -shy

4 ] - --------shy04

6S

|0 III 2 44 8r 66

I I I

a 1KLONG LUANG

pH 46 z KLONG LUANG

TSP Sc2 NCFL(N)

5 FLIC) J0 TU

oshy

4 ~40shy

3 bull eM0

I - I I I I I

0 II 22 44 88 0 5 10 15 20 IP APPLIED KO HA ABSOLUTE CITRAE SOLUBIITY INDEX

Fig 3-Yield of rough rice at Klong Luang and Bangkhen Rice Fig 4-Relative agronon effectiveness () of P sources ploz-Experiment Stations Thalmand as affected by rate and Source ted against citrate solubity Index for both Thailand field ex

of P applied (crop 1) periment (first crop only)

regression model accounted for 97 of the variation in sumably resulted from crop uptake and reaction with the RAE values at the Klong Luang location soil to form less soluble products Such effects may have

These experiments were continued during the dry season been more important at the lower rates since the two TSP of early 1970 to ascertain the residual effectiveness of the curyes converged at the highest rate of application various sources applied to the first crop No new P was These data from KIong Luang indicate that (i) residual applied except for the fresh TSP standard mentioned effects of all rocks except Mlcwuri were substantial (ii) above rhe experiment otherwise was conducted in a man the relationship between relative agronornic effectiveness ner similar to that followed in the first crop of the phosphate rocks and citrate solubility levels was

The response to both freshly applied ad residual P was largely obscured and (iii) the general superiority of TSP marked at the Klong Luang location and marginal at over phosphate rock in terms of effectiveiss persisted Bangkhen In fact at the latter location the response was through the second crop so small that little can be said regarding residual effectiveshyness The yield data from crop 2 at the Klong Luang DISCUSSION experiment are plotted in Fig 5 Greenhouse and field data presented in this paper show

Relative agronomic effectiveness values (Table 3) were clearly that there are substantial differences among phosshycalculated for the Klong Luang data using both the residual and freshly applied TSP as standards It is of Interest to note that the superiority of TSP over the phosphbte rocks Table 3-Relative agronomic effective values for field experishyments in Thailand persisted through the second crop The main difference in KlowlZmlnql~the residual effects is that with the exception of the MIs- s Crop 1 Crop 21 Crop 1-shysouri rock Ihe marked relationship between citratr-soluble WoiCarolina yl 59 76

phosphate rocks and RAE had largely rds norh) a 64P conltct of th Florida (eqlral is 6969 6

disapipeared In this acidic soil (pHi 46) P would by this I14o 69 63 40 ToonesS 31 65

limo be supplied by Intermediate reaction products In addl Missou 0 o lion to residues of the initial spatlte Ts P o 2 o 0

The TSP applied to the first crop declliv-d slightly In campIafcmWataesr e id ofeuhuloefor 22MA rates of PtColeouattd as aba u tlte td18 kS ratesp dlverage yield tM868 to 22 44

effectiveness relative to the freshly applied ISP This pre- of d s4

A

4

- 67 shy

-SOIL SCL SOC AMER I

KLONG LUANG CROP 2

Si 3

eN

TAPPLIEDKGHA

Fig 5-The residual effectiveness ovarious P sources for crop s compared with freshly applied TSP Klong Luang Rice

Experiment Station Thailand

phate rocks in terms of agronomic effectiveness for flooded

rice Further these differences can be predicted by means of citrate solubility or by the ACS index It appears that

the latter is more appropriate where the content of apatite varies among phospiate rocks The most soluble phosphate rocks approached but did not actually equal TSP in limit-iuig (maximum) yield in these experiments regardless of rate applied This agrees with the results of Ensminger Pearson and Armiger (4) One needs to consider the defi-nite posribility of same yield loss in zhoosing a phosphate

rock over TSP such yield losses must be weighed against the lower price of phosphate rock The explanation for such iosses may involve concentration of soluble P in the soil Khasawneh and Copeland (6) suggest that the growth rate of crop plants is a function of P concentration that can be maintained in the soil solution If P concentration is limiting or inadequate becawe of a lower dissolution rate of phosphate rock the growth iate ard uiiimate yield will be diminished accordingly

The RAE values bascd on yield increases reflect the agronomi effectiveness of these various sources relacve

to the TSP standard however these nould be supple-

mented by an economic analysis before rational choice can

be made The following calculations will provide an estimate of

the rclativ ecooomic effectiveness(REE)

Y t Ps aXpatREE -- 100

vahtercks t sphate or e b i- eor

Price of TSPkg fo

be Price of PRkg P

PROC VOL 38 1974 leO

90r

Wsoshy

0

60-LUSEPHOSPHATE ROCK

00 10 20

PTP PR

Fig 6-Relationship between relaZive effectiveness values (RAE) and the price ratios between TSP and phosphate rock Such a figure can be used in making a choice between these

sources

If REE exceeds 100 in this calculation the phosphate rock would be preferable to TSP

The REE calcuktaaa wre used in preparing an indifshyference curve (Fig 6) wherein RAE values are plotted

against PTsPPpR ratios The cu~rve itself connects those points at which REE equals 100 When exactly on the curve it makes no real economic difference what source is chosen After choosing a suitable price ratio one can then project upward from that ratio knowing the RAI

value (or estimating it from such data as shown in Fig 4 using citrate-soluble P content) one can then choose the source on the basis of both agronomic and economic conshysiderations For example if the price ratio is 25 and the RAE value of the phosphaite rock is greater than 40 the rock phosphate in question would be used However if the RAE value was less than 40 TSP would be a better choice There are indications that if the P in the more soluble phosphate ro~cks (North Carolina north Florida central Forida) is less than half as expensivz as that in TSP these rocks would be feasible altereaives to TSP on soils similar

to thoseused in Thailand This analysis does not take into account the possibility

of lower yields from use of phosphate rock In addition only a portion of the various yield response curves was used in this anlysis ie up to 22 kgha Beyond this

rate yield response was much less pronounced it could be argued that at less than maximum yields TSP would produce a certain yield at lower rates of P than would phosshy

pow ofrock This would especially be true for rates applioa example at Klong Luang 5500 kg of

rice pcr iectare could have been produced with either Ii kg of P as TSP or 44 kg of P as son of the more reacshy

tire phosphate rocks It should be pointed ot however

- 68 shy

(IIKIS amp YOUN( ARIFICIAL WEATIIERING OF OXIDIZED p[ll- IV

that this is the yield level that would show the widest difference such is the advantage of hindsight

Farmers generally prefer granular fertilizers for machine

or hand application This is a disadvantage for the phos-phate rocks which are normally arplied in finely divided form Recently experimental quantities of granular urea-

phosphate rock mixtures have been made by TVA Results of trials with these fertilizers will be reported elsewhere

LITERATURE CITED

1 Armiger W H and Maurice- Fried 1957 The plantavailability of various sources of phosphate rock Soil Sci Soc Amer Proc 21183-188

2 Bengston G W E C Sample and S E Allen 1974 Re-sponso of slash pine seedlings to P sGurces of varying ci-trato solubility Plant Soil (In press)

3 Caro JIt and W Hill 1956 Chard eristics and fer tilizcr value of phosphate rock from different fields J Agr Food Chem 4684-687

4 Ensminger I E R W Peirson and W II Atmiger1967 Effectivencs of rock phosphate as a source of phosshyphurus for plants US Dep Agr ARS Bull 4112S

5 Engelstad 0 P J G Getsinger anid I J Stangel 1972 Tailoring of fertiliers for rice cnnece Valley Author ftyNational Fertilicr Developmnent Center Hull Y-52

6 Khasawnch F E and Jane P Copcland 1971 (otton root growth and uptake of nutrievos relation oif phosph

rus uptake to quantity intensity and buffering capacit) Soil Sci Soc Amer Proc 37250-254

7 Lehr JR and G H McClellan 1972 A revised lIbora tory reactivity scale for evaljativg phosphate rocks for direct application Tennessee Valley Authcrity National Fertilizer Development Center lull Y-43

H Terman G L S EAllen and 0 P Engelstad 1970 Response by paddy cice to ratcs and suurces of appliedphosphorus Agron J63390-394

DIVISION S-9-SOIL MINERALOGY

Artificial Weathering of Oxidized Biotite IV The Inhibitory Effect of Potassium on Dissolution llate

R JGILKES AND R C YOUNG2

ABSTRACT

Rates of dissolution of oxidized biotites in OIM 001M ICI are severely depressed in the presence of IM KCI The amovnts of Al Mg Mn dissolved in the first eytraction are similir to those found without KCI however subsequent extractions remove these elements at 10-20 of the corresponding lICI rates This effect may be due to a decreased rate of vermiculite formation thereby reducing the effective basal area exposed to attack A decrease in dissolution rate with increasing ferric iron content was still apparent in the presence of IM KCI

Additional Index Words X-ray diffraction infrared aborp-

N EARLIER papers of this series the tole of biotite in soils

as a source of both macro and micronutrient elements

has been discussed ((Gilkes Young and Quirk 1972 1973ab) Experiments in artificial weathering uiing as va-

riety of extractants were undertaken to determiie the inlu-

ence of oxidation of octahedrally coordinated iron on the bull release of structural cations to solution The results of this

work demonstated that biotite behaves anomalously with respect to the other common ferromagnesian minerals found in soils Oxidation leads to the development of a high degree of resistance to cation exchange and dissolution Several authors have coiwludcd that decreased rates of K

Contribution from the Dep of Soi Science and Plant Nutri-tion Institute of Agriculture Univ of Western Australia Ned-lands 6009 Western Australia Received 29 Sept 1973 Ap-proved 8 Jan 1974

2 Senior Lecturer in Soil Science and Research Officer respeclively

replacement in electrolytes shown by oxidized biotites are

a result of the inclination of structural hydroxyl adjacent to newly created trivalent iron or vacant octahedral cation sites (Robert and Pedro 1959 Barshad and Kishk 1968) Gilkes et al (1973b) suggested that decreased rates of disshysolution of oxidized biotite in 0001 0t)l 0Af CI may also be due to the presence of inclined hydroxyl In this case a smaller surface area external and exposed intershylayer may be available for attack if K replacement by hyshydrogen ions occurs at a slower rate in oxidized biotites

Gastuche (1963) has shown that significant dissolution ofthe (IIM) biotile face may occur and it is easily demonshystrated that the proportion of exposed (001M) face in weathering biotites depends on the percentage K replaced

Rausell-Colom ct al (1965) have shown that hydrogen ions act in an identical fashion to metal cations in K exshy

change from micas In particular exchange c-f K by hydroshy

gen ions will be terminated or greatly reduced by high levels of K in solution Thus if dissolution of oxidized biotite by

acids is carried out at sufficiently high K levels to prevent vermiculization any differences in dissolution rate that may occur cannot simply be ascribed to differences in rates of K replacement The following results were obtained from such an experiment which unlike the experiment described in Parts I and II (Gilkes et al 1973ab) does not attempt to simulate natuiral - conditions

MATERIAILS AN) M HIiODS Further subsamples of the less than 0 hiotites used in K

excherandbaid disoo tu es (G iles e9n K exchange and acid dissolution studies (Gilkes et al1973ab) were used in these experiments Preparation of sequentiallyoxidized biotites without intermediate vermiculite formation is

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