elementary introduction to subdoppler laser spectroscopy...

55
united nations educational, scientific and cultural organization the i international centre for theoretical physics international atomic energy agency SMR 1302- 16 WINTER SCHOOL ON LASER SPECTROSCOPY AND APPLICATIONS 19 February - 2 March 2001 Elementary Introduction to Subdoppler Laser Spectroscopy Part I and II M. INGUSCIO L.E.N.S. - Lab. Europeo di Spettroscopie Non Lineari Largo Enrico Fermi, 2 - Firenze, Italy These are preliminary lecture notes, intended only for distribution to participants. strada costiera, I I - 34014 trieste italy - tel.+39 04022401 I I fax +39 040224163 - [email protected] - www.ictp.trieste.it

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Page 1: Elementary Introduction to Subdoppler Laser Spectroscopy ...indico.ictp.it/event/a0111/contribution/0/material/0/0.pdf · 19 February - 2 March 2001 Elementary Introduction to Subdoppler

united nationseducational, scientific

and culturalorganization

theiinternational centre for theoretical physics

international atomicenergy agency

SMR 1302- 16

WINTER SCHOOL ON LASER SPECTROSCOPY AND APPLICATIONS

19 February - 2 March 2001

Elementary Introductionto

Subdoppler Laser Spectroscopy

Part I and II

M. INGUSCIOL.E.N.S. - Lab. Europeo di Spettroscopie Non Lineari

Largo Enrico Fermi, 2 - Firenze, Italy

These are preliminary lecture notes, intended only for distribution to participants.

strada costiera, I I - 34014 trieste italy - tel.+39 04022401 I I fax +39 040224163 - [email protected] - www.ictp.trieste.it

Page 2: Elementary Introduction to Subdoppler Laser Spectroscopy ...indico.ictp.it/event/a0111/contribution/0/material/0/0.pdf · 19 February - 2 March 2001 Elementary Introduction to Subdoppler
Page 3: Elementary Introduction to Subdoppler Laser Spectroscopy ...indico.ictp.it/event/a0111/contribution/0/material/0/0.pdf · 19 February - 2 March 2001 Elementary Introduction to Subdoppler

t leyya^t

Cdset

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Page 4: Elementary Introduction to Subdoppler Laser Spectroscopy ...indico.ictp.it/event/a0111/contribution/0/material/0/0.pdf · 19 February - 2 March 2001 Elementary Introduction to Subdoppler

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v

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Page 5: Elementary Introduction to Subdoppler Laser Spectroscopy ...indico.ictp.it/event/a0111/contribution/0/material/0/0.pdf · 19 February - 2 March 2001 Elementary Introduction to Subdoppler

FREQUENCY (U. A.)

inch

-3

Page 6: Elementary Introduction to Subdoppler Laser Spectroscopy ...indico.ictp.it/event/a0111/contribution/0/material/0/0.pdf · 19 February - 2 March 2001 Elementary Introduction to Subdoppler

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frequency (U. A.)

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Page 7: Elementary Introduction to Subdoppler Laser Spectroscopy ...indico.ictp.it/event/a0111/contribution/0/material/0/0.pdf · 19 February - 2 March 2001 Elementary Introduction to Subdoppler

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Page 8: Elementary Introduction to Subdoppler Laser Spectroscopy ...indico.ictp.it/event/a0111/contribution/0/material/0/0.pdf · 19 February - 2 March 2001 Elementary Introduction to Subdoppler

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Page 9: Elementary Introduction to Subdoppler Laser Spectroscopy ...indico.ictp.it/event/a0111/contribution/0/material/0/0.pdf · 19 February - 2 March 2001 Elementary Introduction to Subdoppler

(a)

SATURATION SPECTROMETER

ABSORPTIONCEUL

•SATURATINGBEAM

•7

Page 10: Elementary Introduction to Subdoppler Laser Spectroscopy ...indico.ictp.it/event/a0111/contribution/0/material/0/0.pdf · 19 February - 2 March 2001 Elementary Introduction to Subdoppler

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Page 11: Elementary Introduction to Subdoppler Laser Spectroscopy ...indico.ictp.it/event/a0111/contribution/0/material/0/0.pdf · 19 February - 2 March 2001 Elementary Introduction to Subdoppler

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uti Mtur*t1o«

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AA/2)

Page 12: Elementary Introduction to Subdoppler Laser Spectroscopy ...indico.ictp.it/event/a0111/contribution/0/material/0/0.pdf · 19 February - 2 March 2001 Elementary Introduction to Subdoppler

HYDROGEN TERMS

= 13.53eV

J 10.15 —

a p yBALMER SERIES

/o

Page 13: Elementary Introduction to Subdoppler Laser Spectroscopy ...indico.ictp.it/event/a0111/contribution/0/material/0/0.pdf · 19 February - 2 March 2001 Elementary Introduction to Subdoppler

A *£'•<

LAMB SHIFT

0 10 GHz

Page 14: Elementary Introduction to Subdoppler Laser Spectroscopy ...indico.ictp.it/event/a0111/contribution/0/material/0/0.pdf · 19 February - 2 March 2001 Elementary Introduction to Subdoppler

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Page 15: Elementary Introduction to Subdoppler Laser Spectroscopy ...indico.ictp.it/event/a0111/contribution/0/material/0/0.pdf · 19 February - 2 March 2001 Elementary Introduction to Subdoppler

6074 HB

6 A

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Page 16: Elementary Introduction to Subdoppler Laser Spectroscopy ...indico.ictp.it/event/a0111/contribution/0/material/0/0.pdf · 19 February - 2 March 2001 Elementary Introduction to Subdoppler

e i n Q >'

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Page 17: Elementary Introduction to Subdoppler Laser Spectroscopy ...indico.ictp.it/event/a0111/contribution/0/material/0/0.pdf · 19 February - 2 March 2001 Elementary Introduction to Subdoppler

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Page 18: Elementary Introduction to Subdoppler Laser Spectroscopy ...indico.ictp.it/event/a0111/contribution/0/material/0/0.pdf · 19 February - 2 March 2001 Elementary Introduction to Subdoppler

X

V laser

-I?

Page 19: Elementary Introduction to Subdoppler Laser Spectroscopy ...indico.ictp.it/event/a0111/contribution/0/material/0/0.pdf · 19 February - 2 March 2001 Elementary Introduction to Subdoppler

ON LUCE POL-

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fcpf *f nr /

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Page 20: Elementary Introduction to Subdoppler Laser Spectroscopy ...indico.ictp.it/event/a0111/contribution/0/material/0/0.pdf · 19 February - 2 March 2001 Elementary Introduction to Subdoppler

X/4 PLATE

LASER

POLARIZER

SPATIAL? FILTER

Page 21: Elementary Introduction to Subdoppler Laser Spectroscopy ...indico.ictp.it/event/a0111/contribution/0/material/0/0.pdf · 19 February - 2 March 2001 Elementary Introduction to Subdoppler

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Fig. 15 Reglstrsdcne In fluorescenza stlmolata di una regions dellospcttro deila molecola dl I , e confronto con le rlghe tabulate

81

Oo-

Page 22: Elementary Introduction to Subdoppler Laser Spectroscopy ...indico.ictp.it/event/a0111/contribution/0/material/0/0.pdf · 19 February - 2 March 2001 Elementary Introduction to Subdoppler

4S, "3

Fig. 22 Struttura iperflna della rnolacola dl lodio •Profilo dl sssorbimento con hzcio opposlo saturante

Page 23: Elementary Introduction to Subdoppler Laser Spectroscopy ...indico.ictp.it/event/a0111/contribution/0/material/0/0.pdf · 19 February - 2 March 2001 Elementary Introduction to Subdoppler

LHODf LAI . A1ME COTTON ORSAY-FRANCE

/

' i 1 1 1 ' ! ' ! m I HI Ill/fin in | in I,, n, S|

W f M U^T~^ ^ 1 7 r~ H 1U238 U24Q

Page 24: Elementary Introduction to Subdoppler Laser Spectroscopy ...indico.ictp.it/event/a0111/contribution/0/material/0/0.pdf · 19 February - 2 March 2001 Elementary Introduction to Subdoppler

OC\ OF

onI hfTo THE

on iT&ltoJBSS

M. Inguscic . "High Rsscl;. t ion Interraodu iated and Double Resonance

Atomic Spectroscopy in a Hollow Cathode*1 J . Phys . (Par is )44 C (1983) '

-23

Page 25: Elementary Introduction to Subdoppler Laser Spectroscopy ...indico.ictp.it/event/a0111/contribution/0/material/0/0.pdf · 19 February - 2 March 2001 Elementary Introduction to Subdoppler

Laser frequency

?OLA%\ZATION

igna

lio

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COIS)

• 9——*

CO

o

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- 1

86Sr

I i j . _ J 1—

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Page 26: Elementary Introduction to Subdoppler Laser Spectroscopy ...indico.ictp.it/event/a0111/contribution/0/material/0/0.pdf · 19 February - 2 March 2001 Elementary Introduction to Subdoppler

ABSORPT/0^ FROM Sr- /*> A HOUOUJetrtHop

Laser frequency

Page 27: Elementary Introduction to Subdoppler Laser Spectroscopy ...indico.ictp.it/event/a0111/contribution/0/material/0/0.pdf · 19 February - 2 March 2001 Elementary Introduction to Subdoppler

5€MiCOVD\JCTOfl DIODG LA

Peltier

-o

Diodo laser

Beam splitter

H% 9 p a r t 5Q w sec

Page 28: Elementary Introduction to Subdoppler Laser Spectroscopy ...indico.ictp.it/event/a0111/contribution/0/material/0/0.pdf · 19 February - 2 March 2001 Elementary Introduction to Subdoppler

•5 (.

ocCO

03

Laser frequency

Page 29: Elementary Introduction to Subdoppler Laser Spectroscopy ...indico.ictp.it/event/a0111/contribution/0/material/0/0.pdf · 19 February - 2 March 2001 Elementary Introduction to Subdoppler

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struck re j

c:KCOCO

C O

CO

C3CO

Cs]

TRIPLET QUINTET

3D_6s _ - 5 d

\605nm /-5s M

^ inm /616nm

777 nm i

* : 4 •

SINGLET

636nm " 3RJj0 (ground state)

* olffft'iulry is thto£ {~U< h t

Page 30: Elementary Introduction to Subdoppler Laser Spectroscopy ...indico.ictp.it/event/a0111/contribution/0/material/0/0.pdf · 19 February - 2 March 2001 Elementary Introduction to Subdoppler

grating

to recoKter

dischargeceil

rfoscillator

to recocder

b)

.2CO

i2

2ero torderivative signal

AvD-1.6GH2

_ zero light level (tor absorption)

Page 31: Elementary Introduction to Subdoppler Laser Spectroscopy ...indico.ictp.it/event/a0111/contribution/0/material/0/0.pdf · 19 February - 2 March 2001 Elementary Introduction to Subdoppler

A lums -i.i/iiiv

RF2 500mV 10ms

"RF1 '200mV J 10ms

7/z"

RFlgnd.

Page 32: Elementary Introduction to Subdoppler Laser Spectroscopy ...indico.ictp.it/event/a0111/contribution/0/material/0/0.pdf · 19 February - 2 March 2001 Elementary Introduction to Subdoppler

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./.,/f.

15 JBA.

Page 33: Elementary Introduction to Subdoppler Laser Spectroscopy ...indico.ictp.it/event/a0111/contribution/0/material/0/0.pdf · 19 February - 2 March 2001 Elementary Introduction to Subdoppler

MODULATION

«?- •

•> /

ALIGNMENT

Page 34: Elementary Introduction to Subdoppler Laser Spectroscopy ...indico.ictp.it/event/a0111/contribution/0/material/0/0.pdf · 19 February - 2 March 2001 Elementary Introduction to Subdoppler

CO

-33

Page 35: Elementary Introduction to Subdoppler Laser Spectroscopy ...indico.ictp.it/event/a0111/contribution/0/material/0/0.pdf · 19 February - 2 March 2001 Elementary Introduction to Subdoppler

u

-200 -100 0 100

A* (MHz)200

200.4 0.6Pressure (Torr)

0.8 1.0

I?. AJT>i AT!v >.

Page 36: Elementary Introduction to Subdoppler Laser Spectroscopy ...indico.ictp.it/event/a0111/contribution/0/material/0/0.pdf · 19 February - 2 March 2001 Elementary Introduction to Subdoppler

Hi%h

c/troScopy

H. kijv*ct9# 3

Page 37: Elementary Introduction to Subdoppler Laser Spectroscopy ...indico.ictp.it/event/a0111/contribution/0/material/0/0.pdf · 19 February - 2 March 2001 Elementary Introduction to Subdoppler

I 1

I

no \//sifeL6 -

' ? %

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Page 38: Elementary Introduction to Subdoppler Laser Spectroscopy ...indico.ictp.it/event/a0111/contribution/0/material/0/0.pdf · 19 February - 2 March 2001 Elementary Introduction to Subdoppler

rE *C - ,\ n ^

i o o

ATMOSPHERIC ABSORPTION

100

— SO —

*

/ (u) 05 to 1.7 ^m.

11111 j I H ^ HI it H is i i 11J i»J i i i I s 1111 il i i i 12} i i t ii i I !| I! U J M ii ] 1

5.7 mm Precipi table

Water 79°F

0 itttiiitiiiif iihmmntiitf iitiftviitninfll

1.8 2.0 2.2 2.4

(Mm)

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100

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0 i f l l f i M l l f i i f l l t f f i l l f l l l l l f l l f 1111 f l l l l i l ! f l it I f l l i ?l?111f l l f t l l f ? II h i ! I l l l l fl I l i t ! l i l l l t f t? I l l I f l f l l f f I l l f i fTHII i l \

3.5WaTelength

4.0

Page 39: Elementary Introduction to Subdoppler Laser Spectroscopy ...indico.ictp.it/event/a0111/contribution/0/material/0/0.pdf · 19 February - 2 March 2001 Elementary Introduction to Subdoppler

IFO

4.

Potencial energyT

70

o

M

Page 40: Elementary Introduction to Subdoppler Laser Spectroscopy ...indico.ictp.it/event/a0111/contribution/0/material/0/0.pdf · 19 February - 2 March 2001 Elementary Introduction to Subdoppler

9

D/R€CT

E(eV)

M )m me

K (orb.units)

8 Schematic diagram of the simplified band etruature

of (GaAl)Aa shoving the direct interbond laser

transition.

Af$# In fax

Page 41: Elementary Introduction to Subdoppler Laser Spectroscopy ...indico.ictp.it/event/a0111/contribution/0/material/0/0.pdf · 19 February - 2 March 2001 Elementary Introduction to Subdoppler

0\

ULTRAVIOLETH V1SIBLEH*

GaAsxSbi-xIn Asx Pi-x •

InxGai.xAs)i

Cd SxCd xZni . xS •••

i i I i 1

Pbx Sn< -x Se

j PbSi.xSeX | .| In AsxSbi

INFRARED

i i i I i n i0.1 0.5 1 5 10

LASER EMISSION WAVELENGTH ( p )

L40-160K

1 1 J L_1._1_L1

50 100

Emission wavelenghts of direct semiconductors

Page 42: Elementary Introduction to Subdoppler Laser Spectroscopy ...indico.ictp.it/event/a0111/contribution/0/material/0/0.pdf · 19 February - 2 March 2001 Elementary Introduction to Subdoppler

SHOT Wu

-S

a\0 "%0 olio SO

I

Page 43: Elementary Introduction to Subdoppler Laser Spectroscopy ...indico.ictp.it/event/a0111/contribution/0/material/0/0.pdf · 19 February - 2 March 2001 Elementary Introduction to Subdoppler

t § *

€ $P€CT&oscoPy

laser diode

to pz

I driverslowmod.

*lmonocromator

Jspectrum analizer

sealed off cell

fastmod. V

u uair in acet. in

ref. sign.

sweeper computer scope lock-in

Usample out

diff. ampl.

.7 f ,

Page 44: Elementary Introduction to Subdoppler Laser Spectroscopy ...indico.ictp.it/event/a0111/contribution/0/material/0/0.pdf · 19 February - 2 March 2001 Elementary Introduction to Subdoppler

PURE ABSORPTION SIGNAL FOR THE R{9)COMPONENT (C2H2)

a)

pressure = 10 Torrpaihiength = 1.5 meter

absorption = a few percent 3 ' OV-SA.-

X ~

330 MHz

DERIVATIVE SIGNAL

a = 10 Torrb = 36 mlorr

Vr - •

^

1 GHz 900 MHz

Limit of detection in absorption : 10'6. 1Hz detect, bandw.

Last limit using FM techniques : UP to 10'8

Air pressure detection limit :

Page 45: Elementary Introduction to Subdoppler Laser Spectroscopy ...indico.ictp.it/event/a0111/contribution/0/material/0/0.pdf · 19 February - 2 March 2001 Elementary Introduction to Subdoppler

/ x ; 1• i

^ /

MQDUWTrOAl

BY

laser diode

to current

; driver [— J_

moas t ) power supplym

LZJ Lsweeper computer

monochromator

Jspectrum analyzer

jabs. sign.

lock-in

-\• * • > : ' ; • . ' '•

•* n i N

Page 46: Elementary Introduction to Subdoppler Laser Spectroscopy ...indico.ictp.it/event/a0111/contribution/0/material/0/0.pdf · 19 February - 2 March 2001 Elementary Introduction to Subdoppler

i50nmlnGaAsP

.1.0 ev

t'".»: j i i i i i i iiM

n-ln PCladding

Layer

SCH Layer—i • — . -™-™-_»_»

(—;[mn/V—

\ ^4 InGaAs QWs

3 InGaAsP Barriers

100 ran InGaAsP| Grating Layer

"If" c

p-JnP/ Cladding Layer

~~ 100 mn p-M PSpacer Layer

MetalOxide

»nP p-ctad —

GratingMQW, SCH

Layers

InPn-dadand Substrate

Metal

InGaAsContact Layer

HR CoatingBack Facet

LR CoatingFront Facat

Physical structure and energy band diagram ofnear-infrared DFB lasers. "

IXE.COOPER,LASER

Page 47: Elementary Introduction to Subdoppler Laser Spectroscopy ...indico.ictp.it/event/a0111/contribution/0/material/0/0.pdf · 19 February - 2 March 2001 Elementary Introduction to Subdoppler

FT$ - £6]

I . WWi w'

1 0 0

90 -

7 01 Overtone

m

5450 5500 5550 5600 5650 5700 5750 5800

1 00

L 90 -Io3:

g 80 -

70 -

T* ; #;

2 Overtone

8150 8200 5250 8300 8350 8400 8450 8500

WAVE NUMBERS / cm ~ 1

-fc

Page 48: Elementary Introduction to Subdoppler Laser Spectroscopy ...indico.ictp.it/event/a0111/contribution/0/material/0/0.pdf · 19 February - 2 March 2001 Elementary Introduction to Subdoppler

HQ

OF

500/Wz

Page 49: Elementary Introduction to Subdoppler Laser Spectroscopy ...indico.ictp.it/event/a0111/contribution/0/material/0/0.pdf · 19 February - 2 March 2001 Elementary Introduction to Subdoppler

Detection of HCl on the first and second overtones

at 1.7 jum and 1.2 jam using semiconductor diode lasers

C. Corsi1, S. Czhudzynsky2, F. D'Amato3, M. De Rosa4, K. Ernst2

LENS-INFM1 Dip. di Neuroscienze, Univ. Firenze; 2 Dip. di Fisica, Univ. Warsaw;

3 ENEA, Frascati; 4 SIT, Firenze

Ig

1000 c

47 ppm/m HClp=100Torr(N)

S/N=154

Frequency (arb. u.)

1 10 100

Concentration (ppm/m)1000

Page 50: Elementary Introduction to Subdoppler Laser Spectroscopy ...indico.ictp.it/event/a0111/contribution/0/material/0/0.pdf · 19 February - 2 March 2001 Elementary Introduction to Subdoppler

Overtone Spectra of CO and CO In the 1.5^m region

^ 1.0

com"I 0,5mc(0

0,0

^ 1.0

o"SCO

1mc

0,5

0.0

COIP,in

!. i

nn

1,56

1,56

n nW I

nn

1,58

Wavelength

i n

1,60

•U-

Page 51: Elementary Introduction to Subdoppler Laser Spectroscopy ...indico.ictp.it/event/a0111/contribution/0/material/0/0.pdf · 19 February - 2 March 2001 Elementary Introduction to Subdoppler

! h ;LT4Ki tc -^ 15 o / i •>5

Absorption [arb,]

o

oo

11

1c3O

N3OO

oo

T 1 1 r—1

t v. ^

* - j —

• "H r.Li

4 j

Page 52: Elementary Introduction to Subdoppler Laser Spectroscopy ...indico.ictp.it/event/a0111/contribution/0/material/0/0.pdf · 19 February - 2 March 2001 Elementary Introduction to Subdoppler

I

r/

Page 53: Elementary Introduction to Subdoppler Laser Spectroscopy ...indico.ictp.it/event/a0111/contribution/0/material/0/0.pdf · 19 February - 2 March 2001 Elementary Introduction to Subdoppler

1

f5

too

4o

CO concentration (arb)2

IV)1

00!

roo1 1

(Oro•

roi

roi

IOro

oO

'~J

CO concentration (arb)

8

o -

p pbi

pb ob co

i r i

O

23-SEP-1997 11'-24 +39 55 224072 94* S.0S '-SEP-1997 11:24 +39 55 224072 94*:

Page 54: Elementary Introduction to Subdoppler Laser Spectroscopy ...indico.ictp.it/event/a0111/contribution/0/material/0/0.pdf · 19 February - 2 March 2001 Elementary Introduction to Subdoppler

Why using diode lasers for monitoring gases?

fast response time (ms)

selectivity

• non-intrusiveness

6MVlR0Mrte/JTAL

sensitivity

—^

low energy consumption

^ AT PPM L6V6L

low costIN SITU "

small-size

remote sensing—b

Page 55: Elementary Introduction to Subdoppler Laser Spectroscopy ...indico.ictp.it/event/a0111/contribution/0/material/0/0.pdf · 19 February - 2 March 2001 Elementary Introduction to Subdoppler

Abdications

-Control of combustion processes

O2, CO, HC1

-Detection of hazardous gases

CO, H2S, CH4i

-Monitoring of exhaust gases

CO, CO2

-Monitoring of e^mission gases in power plants

NH3

Medical Applications

-Non invasive diagnostic of human breath

12CO2,13CO2, NH3, C2H6

Geophysical Applications

-Monitoring of volcanic gases

H2S, H2O, CO2