effect of the exchange current density (j 0 ) on the the current density (j): j(t) = j 0 {exp [- nf...
TRANSCRIPT
![Page 1: Effect of the exchange current density (j 0 ) on the the current density (j): j(t) = j 0 {exp [- nF /RT] - exp[(1- )nF /RT]}](https://reader036.vdocuments.us/reader036/viewer/2022062317/5a4d1b017f8b9ab059986b50/html5/thumbnails/1.jpg)
Effect of the exchange current density (j0) on the the current density (j):
j(t) = j0 {exp [-nF/RT] - exp[(1-)nF/RT]}
![Page 2: Effect of the exchange current density (j 0 ) on the the current density (j): j(t) = j 0 {exp [- nF /RT] - exp[(1- )nF /RT]}](https://reader036.vdocuments.us/reader036/viewer/2022062317/5a4d1b017f8b9ab059986b50/html5/thumbnails/2.jpg)
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j0 = 10-2 A = 0.5
j / mA
/ mV-600 -400 -200 200 400 6000
![Page 3: Effect of the exchange current density (j 0 ) on the the current density (j): j(t) = j 0 {exp [- nF /RT] - exp[(1- )nF /RT]}](https://reader036.vdocuments.us/reader036/viewer/2022062317/5a4d1b017f8b9ab059986b50/html5/thumbnails/3.jpg)
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0
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200j / mA
/ mV
j0 = 10-3 A = 0.5
-600 -400 -200 200 400 6000
![Page 4: Effect of the exchange current density (j 0 ) on the the current density (j): j(t) = j 0 {exp [- nF /RT] - exp[(1- )nF /RT]}](https://reader036.vdocuments.us/reader036/viewer/2022062317/5a4d1b017f8b9ab059986b50/html5/thumbnails/4.jpg)
-600-400-2000200400600
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0
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200j / mA
/ mV
j0 = 10-4 A = 0.5
-600 -400 -200 200 400 6000
![Page 5: Effect of the exchange current density (j 0 ) on the the current density (j): j(t) = j 0 {exp [- nF /RT] - exp[(1- )nF /RT]}](https://reader036.vdocuments.us/reader036/viewer/2022062317/5a4d1b017f8b9ab059986b50/html5/thumbnails/5.jpg)
-600-400-2000200400600
-200
-150
-100
-50
0
50
100
150
200j / mA
/ mV
j0 = 10-5 A = 0.5
-600 -400 -200 200 400 6000
![Page 6: Effect of the exchange current density (j 0 ) on the the current density (j): j(t) = j 0 {exp [- nF /RT] - exp[(1- )nF /RT]}](https://reader036.vdocuments.us/reader036/viewer/2022062317/5a4d1b017f8b9ab059986b50/html5/thumbnails/6.jpg)
-600-400-2000200400600
-200
-150
-100
-50
0
50
100
150
200j / mA
/ mV
j0 = 10-6 A = 0.5
-600 -400 -200 200 400 6000
![Page 7: Effect of the exchange current density (j 0 ) on the the current density (j): j(t) = j 0 {exp [- nF /RT] - exp[(1- )nF /RT]}](https://reader036.vdocuments.us/reader036/viewer/2022062317/5a4d1b017f8b9ab059986b50/html5/thumbnails/7.jpg)
-600-400-2000200400600
-200
-150
-100
-50
0
50
100
150
200j / mA
/ mV
j0 = 10-7 A = 0.5
-600 -400 -200 200 400 6000
![Page 8: Effect of the exchange current density (j 0 ) on the the current density (j): j(t) = j 0 {exp [- nF /RT] - exp[(1- )nF /RT]}](https://reader036.vdocuments.us/reader036/viewer/2022062317/5a4d1b017f8b9ab059986b50/html5/thumbnails/8.jpg)
-600-400-2000200400600
-200
-150
-100
-50
0
50
100
150
200j / mA
/ mV
j0 = 10-8 A = 0.5
-600 -400 -200 200 400 6000
![Page 9: Effect of the exchange current density (j 0 ) on the the current density (j): j(t) = j 0 {exp [- nF /RT] - exp[(1- )nF /RT]}](https://reader036.vdocuments.us/reader036/viewer/2022062317/5a4d1b017f8b9ab059986b50/html5/thumbnails/9.jpg)
-600-400-2000200400600
-200
-150
-100
-50
0
50
100
150
200j / mA
/ mV
j0 = 10-9 A = 0.5
-600 -400 -200 200 400 6000
![Page 10: Effect of the exchange current density (j 0 ) on the the current density (j): j(t) = j 0 {exp [- nF /RT] - exp[(1- )nF /RT]}](https://reader036.vdocuments.us/reader036/viewer/2022062317/5a4d1b017f8b9ab059986b50/html5/thumbnails/10.jpg)
j(t) = j0 { exp [-nF/RT] - exp[(1-)nF/RT] }
represented together with the forward and backward components
Variation of j as a function of j0:
![Page 11: Effect of the exchange current density (j 0 ) on the the current density (j): j(t) = j 0 {exp [- nF /RT] - exp[(1- )nF /RT]}](https://reader036.vdocuments.us/reader036/viewer/2022062317/5a4d1b017f8b9ab059986b50/html5/thumbnails/11.jpg)
-600-400-2000200400600
-200
-150
-100
-50
0
50
100
150
200j / mA
/ mV
j0 = 10-2 A = 0.5
total current anodic partial current cathodic partial current
-600 -400 -200 200 400 6000
![Page 12: Effect of the exchange current density (j 0 ) on the the current density (j): j(t) = j 0 {exp [- nF /RT] - exp[(1- )nF /RT]}](https://reader036.vdocuments.us/reader036/viewer/2022062317/5a4d1b017f8b9ab059986b50/html5/thumbnails/12.jpg)
-600-400-2000200400600
-200
-150
-100
-50
0
50
100
150
200j / mA
/ mV
j0 = 10-3 A = 0.5
total current anodic partial current cathodic partial current
-600 -400 -200 200 400 6000
![Page 13: Effect of the exchange current density (j 0 ) on the the current density (j): j(t) = j 0 {exp [- nF /RT] - exp[(1- )nF /RT]}](https://reader036.vdocuments.us/reader036/viewer/2022062317/5a4d1b017f8b9ab059986b50/html5/thumbnails/13.jpg)
-600-400-2000200400600
-200
-150
-100
-50
0
50
100
150
200j / mA
/ mV
j0 = 10-4 A = 0.5
total current anodic partial current cathodic partial current
-600 -400 -200 200 400 6000
![Page 14: Effect of the exchange current density (j 0 ) on the the current density (j): j(t) = j 0 {exp [- nF /RT] - exp[(1- )nF /RT]}](https://reader036.vdocuments.us/reader036/viewer/2022062317/5a4d1b017f8b9ab059986b50/html5/thumbnails/14.jpg)
-600-400-2000200400600
-200
-150
-100
-50
0
50
100
150
200j / mA
/ mV
total current anodic partial current cathodic partial current
-600 -400 -200 200 400 6000
j0 = 10-5 A = 0.5
![Page 15: Effect of the exchange current density (j 0 ) on the the current density (j): j(t) = j 0 {exp [- nF /RT] - exp[(1- )nF /RT]}](https://reader036.vdocuments.us/reader036/viewer/2022062317/5a4d1b017f8b9ab059986b50/html5/thumbnails/15.jpg)
-600-400-2000200400600
-200
-150
-100
-50
0
50
100
150
200j / mA
/ mV
total current anodic partial current cathodic partial current
-600 -400 -200 200 400 6000
j0 = 10-6 A = 0.5
![Page 16: Effect of the exchange current density (j 0 ) on the the current density (j): j(t) = j 0 {exp [- nF /RT] - exp[(1- )nF /RT]}](https://reader036.vdocuments.us/reader036/viewer/2022062317/5a4d1b017f8b9ab059986b50/html5/thumbnails/16.jpg)
-600-400-2000200400600
-200
-150
-100
-50
0
50
100
150
200j / mA
/ mV
j0 = 10-7 A = 0.5
total current anodic partial current cathodic partial current
-600 -400 -200 200 400 6000
![Page 17: Effect of the exchange current density (j 0 ) on the the current density (j): j(t) = j 0 {exp [- nF /RT] - exp[(1- )nF /RT]}](https://reader036.vdocuments.us/reader036/viewer/2022062317/5a4d1b017f8b9ab059986b50/html5/thumbnails/17.jpg)
-600-400-2000200400600
-200
-150
-100
-50
0
50
100
150
200j / mA
/ mV
total current anodic partial current cathodic partial current
j0 = 10-8 A = 0.5
-600 -400 -200 200 400 6000
![Page 18: Effect of the exchange current density (j 0 ) on the the current density (j): j(t) = j 0 {exp [- nF /RT] - exp[(1- )nF /RT]}](https://reader036.vdocuments.us/reader036/viewer/2022062317/5a4d1b017f8b9ab059986b50/html5/thumbnails/18.jpg)
-200
-150
-100
-50
0
50
100
150
200j / mA
/ mV
j0 = 10-9 A = 0.5
total current anodic partial current cathodic partial current
-600 -400 -200 200 400 6000