Thermal processing of metal alloys
Control changes of mechanical, physical, electrical and other properties – always connected with structural or substructural changes in treated material
Each heat treatment consist of three main periods:
Aim of heat treatment is to achieve more or less thermodynamically equilibrium state (stable or metastable)
Thermal processing of metal alloys
Heat treatment (temperature effect)
• annealing (to get more stable state) reduce internal stress, reach softer and ductile structure, …
• hardening (to get metastable state) increases strength, hardness, wear resistance, …
Thermomechanical treatment
(effect of temperature and deformation)control of final structure and mechanical properties
Chemical heat treatment(effect of temperature and changes of the chemical composition)
to get different properties of surface layer as in core of the piece – higher hardness, better wear or corrosion resistance, …
Heat treatment of steels
Annealing
Lower critical temperature (without transformation)
• Process (recrystallization) annealing
• Stress relief annealing
• Spheroidizing
Upper critical temperature (partial or whole transformation)
• Normalizing
• Homogenization
Process (recrystallization) annealing
550 – 700 °C, 1- 5 hours, cooling in air
To change the structure and properties of cold worked (strain
hardened) steel.
Recovery and recrystallization processes occur.
Softening, increase ductility and uniform fine grain structure is
achieved.
Stress relief annealing
400 – 650 °C, 2 - 10 hours, very slow cooling in furnace
Reduce internal residual stresses (after machining, heat
treatment, …)
Spheroidizing (soft annealing)
700 °C, 5 – 25 hours, slow cooling to 600 °C in furnace, then cooling may continue in air.Spheroidite structure is developed
Used to improve machineability and toughness.
Normalizing
50 – 80 °C above upper critical temperature (phase diagram), cooling in air.Austenitization of the steel is required and cooling in accordance with CCT diagram to get uniform and fine grain structure.
Full annealing over A3 and A1 with furnace cooling.
Homogenization
1100 - 1200 °C (200 °C under solidus!)
To reduce structure and chemical composition inhomogeneities
after casting.
Hardening of steel
Purpose:
improve strength, hardness, wear resistance, …
Way:
Reach the martensite or bainite structure or their combination
How:
By quenching
CCT diagram
CCT diagram
Hardenability of the steel
• The martensitic transformation have to bee possible!
Carbon steel with at least 0,25 wt %.
• Hardened structure contain at least 50 % of martensite.
• Hardenability is defined by depth, in which the hardened structure is achieved.
Jominy end quench test