Download - Steven Chu at BASF Science Symposium
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BASF Science Symposium Smart energy for a sustainable future
9 – 10 March, 2015
Energy and Climate Change and how to transition to a sustainable
world
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In 1898, Sir William Crookes delivers an address his inaugural lecture as President of the BriHsh AssociaHon for the Advancement of Science.
“It is the chemist who must come to the rescue of the threatened communiHes. It is through the laboratory that starvaHon may
ulHmately be turned to plenty.”
“England and all civilized naHons stand in in deadly peril of not having
enough to eat.”
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Fritz Haber: 1918 Carl Bosch: 1931
Gerhard Ertl: 2007
At the beginning of the industrial revoluHon there
were 700 M people.
The Haber-‐Bosch process enabled us to feed a world that doubled in
populaHon.
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“The baWle to feed all of humanity is over ... In the 1970s and 1980s hundreds of millions of people will
starve to death in spite of any crash programs embarked upon now.”
Prof. Paul Ehrlich Stanford Biologist
The Popula+on Bomb (1968)
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Norman Borlaug is awarded the Nobel Prize in 1970
Borlaug bred disease-‐resistant, dwarf strains of wheat with thick stems that could support heavier kernels. His plants didn’t collapse a]er rapid growth spurts due to nitrogen ferHlizer used in the poor soils.
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Source: Food and Agriculture Organiza4on (FAO), United Na4ons
World ProducHon of Grain (1961 – 2004)
1960: Popula4on = 3 B
2005: Popula4on = 6.5 B
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Today, there are ~7.3 billion people. By ~2050 we will grow to ~ 9 billion.
Are technological “fixes” merely postponing disaster?
High-fertility: 2.5 children
Low-fertility 1.6
Medium-fertility: 2.0 children
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“Our ability to find and extract fossil fuels continues
to improve, and economically recoverable reservoirs
around the world are likely to keep pace with the
rising demand for decades.”
Steven Chu and Arun Majumdar, Nature (2012)
Will we run out of oil and natural gas?
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U.S. Oil Production (1945 – 2012) U.S. is the biggest producer of oil + nat. gas liquids + ethanol
2013 ~ 7.5 M bbls/day
2014 ~ 8.5 M bbls/day
U.S. oil production from tight oil is ~ 4.5 M bbls/day
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Potential shale gas and tight oil reservoirs can change the energy landscape of the Americas, Asia and Europe.
The rest of the world may have 10 4mes more 4ght oil and shale gas than the U.S. Also: heavy oil, deep water oil, oil sands …
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With all of the new oil and natural gas supplies, is the world energy
problem solved?
We have an Energy - Climate Change problem.
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2014 was the hottest year on record. 14 of the 15 warmest years have all occurred in the 21st century.
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© 2013 Munich Re
NatCatSERVICE Weather-related loss events worldwide 1980 – 2013 Number of events
Meteorological events (Tropical storm, extra-‐tropical storm, convecHve storm, local storm)
Hydrological events (Flood, mass movement)
Climatological events (Extreme temperature, drought, forest fire)
200
400
600
800
1 000
1980 1982 1984 1986 1988 1990 1992 1994 1996 1998 2000 2002 2004 2006 2008 2010 2012
Number
© 2014 Münchener Rückversicherungs-‐Gesellscha], Geo Risks Research, NatCatSERVICE – As at February 2014
88% of World-wide losses were weather related
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Rate of sea level rise Jan 1993 – Aug 2014
3.2 mm/year, roughly 3x faster than
1870 – 1940
Recent rate of sea level rise compared to historical record
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Muir Glacier, Alaska
August 31, 2004 August 13, 1941
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Gravity Recovery and Climate Experiment (GRACE) Change in distance between 2 satellites is used to calculate the local gravity
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Ground water in California measured by the GRACE satellite
Since 2011, the Sacramento and San Joaquim river basins are losing 15 km3 of water each year. Half is due to ground water pumping in the Central Valley.
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25 year delay aTer the onset of smoking
Smoking increases the risk of • Lung cancer: 25x • Coronary heart disease: 2x - 4x • Stroke: 2x – 4x
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Harbin, China
ParHculate maWer PM2.5 (< 2.5 μm) and PM10 are especially deadly. 36% increase in lung cancer per 10 μg/m3 (The Lancet Oncology, 2014)
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Harbin, China
ParHculate maWer PM2.5 (< 2.5 μm) and PM10 are especially deadly. 36% increase in lung cancer per 10 μg/m3 (The Lancet Oncology, 2014)
PM2.5 measurements at U.S. Embassy in Beijing (Jan 2013) Yearly average = 194 μg/m3
Smoking rooms in U.S.
airports
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25 year delay aTer the onset of smoking
The damage already done to our environment may not be known for a century.
How long will CO2 remain in the atmosphere?
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• Energy trends in fossil energy: oil and natural gas
• An epidemiological approach to climate change
• How science and technology will make clean energy the low cost option.
Outline of talk
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“The Stone Age came to an end not for a lack of stones and the oil age will end, but not for a lack of oil.”
-‐ Sheik Ahmed Zaki Yamani, former Saudi Oil Minister
We transitioned to better solutions.
If we don’t find better solutions, the oil, gas and coal will be used.
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Energy efficiency
Clean energy sources
Science and technology can and must help change the current path we are on.
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R. van Buskirk, C. Kantner, B. Gerke and S, Chu, Environ. Res. LeW. 9 114010 (2014) The effect of appliance standards on total cost and purchase price
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R. van Buskirk, C. Kantner, B. Gerke and S, Chu, Environ. Res. LeW. 9 114010 (2014) The effect of appliance standards on total cost and purchase price
Refrigerator cost declines by 28% for each doubling of producHon. Energy saved in the U.S. each year is more than 270 TWh = 30 nuclear reactors operaHng at 1
GW 24 hours a day, 365 days a year.
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The Model T Ford (1908 – 1927) transformed transportation by making it “a able”
Henry Ford 4-‐cylinder 2.9 liter engine: 20 -‐22 hp
Ford 3-‐cylinder 1.0 liter engine: 123 hp
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The Boeing 787 uses 30% of the fuel of the 707,
carries 70% more passengers.
Its 2 jets have 80% more thrust than the 4 engines of the 707.
Market forces drove fuel economy in airplanes
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Energy efficiency
Clean energy sources
Science and technology can and must help change the current path we are on.
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100 meter wind tower 2.3 MW turbine: 93 meter diameter blades, 115 meters high.
Wind turbines are more reliable, efficient and bigger
The Wright Brothers’ first flight was 36.6 meters
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U.S. wind energy costs and installed capacity (1980 – 2012). Long-term contracts at 3¢/kWh.
New natural gas is 5¢/kWh at $4/MMBtu
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Solar Resources in the U.S. Germany and Spain
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US Solar PPA Prices Jul 08 – Jul 2014 ($/MWh) Utility-scale solar energy is Texas is equal to the cost of new
natural gas at $4/Million Btu!
$ /M
Wh
Wholesale prices went from 19¢ to 5¢/kWh in 6 years
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United States Solar Electricity Generation 1985 – 2013
My time as U.S. Secretary
of Energy
Solar energy accounts for only 0.25% of all electricity generated in the U.S. in 2013.
U.S. now has ~ 12 GW of installed capacity.
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Solar efficiency of Perovskite solar cells: 3% (2009) in 2009 è 20% (2014)
Perovskite solar energy conversion
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Bloomberg New Energy Finance: Total cost of lithium ion battery packs for EVs and PHEVs
Tesla Giga Factory baYery pack cost?
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Volumetric energy density of Li-ion batteries (courtesy Panasonic) 18650 Panasonic
silicon anode Li-‐ion
4-‐fold increase in energy density since commercial introduc4on.
Amprius 720 W/L
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Tesla battery uses ~ 250 Wh/kg batteries.
Maximum theoretical energy density (Wh/kg)
85 kWh = 425 kg ~ 1200 lbs ~ $36,000 @ $425/kWh
Yi Cui and I are working on a lithium-‐ sulfur baWery that may increase the energy density 5x and the charging rate 10x of today’s baWeries.
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$1,000/kW and $160/kWh
10,000 cycles (30 years)
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Progress in Batteries and other forms of energy “storage”
Pump water when the wind blows or the sun shines
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Solar modules and batteries that operate at at a wide range of temperatures can bring inexpensive electricity for LED
lighting, cell phones, refrigeration, water purification. Water can be pumped, purified and stored for months.
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U.S. Electrical Grid System (> 230 kV)
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China has installed a 2000 km 800 kV DC line. Less than 7% of the energy is lost in conversion and transmission.
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High power-high voltage IGBT transistors can revolutionize HVDV transmission lines and Flexible AC Transmission
Need: improved dielectric materials HVDC undersea and
underground power lines.
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A prototype 1 MW, 20 kV SiC transistor. (Cree, 2013)
Improved high frequency, high voltage power electronics for
inverters, converters
Need: High power – high voltage Diamond IGBT transistors.
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350 million ]3 of natural gas/day are flared in the Bakken formaHon. A single natural gas burner is as loud as a commercial jet engine.
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Statoil, GE, Ferus Natural Gas Fuels: Sept. 2014 the expansion of a pilot project to capture flare gas to power Statoil's six drill rigs and one frac fleet in North Dakota.
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Need: portable Gas-to-Liquid platforms powered by natural gas that would have been flared.
Can we use 30% wall-plug efficient lasers or other methods operating on natural gas
power to drive GTL reactions?
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Commercial uses of CO2
• EOR + associated sequestraHon • Methane coal-‐bed and hydrate extracHon + associated sequestraHon
• Enhanced geothermal energy
If we can capture carbon dioxide at < $15/ton, many opportunities in the capture and utilization
of CO2 may become economically attractive.
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My challenge to chemists (Seeking the 21st century “Haber–Bosch” solution)
Liquid chemical energy storage: e.g. use excess night time electricity to split water into
H2 and O2 and combine with CO2 captured from power, cement and steel production to make liquid fuels that can be shipped and
stored anywhere in the world.
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We need improved methods for splitting water for H2 and the reduction of captured
CO2 for hydrocarbon production.
• Electrochemical conversion • Photochemical conversion
• Biological conversion
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Octane
Decane
Cetane
Captured CO2
H2O
?
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In a world of 50% intermittent wind and solar energy, there will be significant surplus
electricity.
Even today, night-time electricity sell for ~ 0.5 - 2 cents/kWh
In a world when renewable surplus electricity becomes very inexpensive, can we engineer
industrial chemical processing to take advantage of this intermittent energy?
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Earthrise from Apollo 8 (December 24, 1968)
"We came all this way to explore the moon and the most important thing is that we discovered the Earth.”
Bill Anders, Apollo 8 Astronaut 57
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There is an ancient Native American saying:
“We do not inherit the land from our ancestors, we borrow it from our children.”
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